Ministerial Joint Decree No. 551/2005 on the harmonization of the national legislation with Commission Directive 2004/16/EC laying down the sampling methods and the methods of analysis for the official control of the levels of tin in canned foods

0 6847 ~ E<l>HMEPII THI KVBEPNHIEnI THI EJ\J\HNIKHI ~HMOKPATIAI TEYXOI flEYTEPO Ap. <l>uAAou 489 nEPIEXOMENA AnO<l>AIEII Evapµ6vtari TrJc; ESvtKr')c; Noµo8w(ac; npoc; TrJV O5riy. 2004/16/EK {EEL 42/13.2.2004), Tij<; Enrrpon:fic;-ri7c; 12ric; <l>el3pouap(ou 2004 yta TrJV Ka8tepwari Tp6 nwv 5etyµmoArJljJ(ac; Km µe865wv av6Auaric; yta TOV en(ariµo 8A8YXO TWV µey(mwv nepL8KTLKOTl7TWV KaamTepou ae Kovaepl3ec; Tpocp(µwv ................... .. Apt8. 551 (1) Evapµ6vLOrJ TrJc; E8VLKr')c; Noµo8ea(ac; npoc; TrJV O5riy. 2004/16/EK (EEL 42/13.2.2004), TrJc; EmTponr')c; TrJc; 12ric; <l>el3pouap(ou 2004 yta TrJV Ka8tepwari Tp6nwv 5etyµmOArJljJ(ac; Km µe865wv av6},,uaric; yta TOV en(ari­ µo e},,eyxo TWV µey(mwv nepL8KTLKOTl7TWV KaamTepou ae Kovaepl3ec; Tpocp(µwv. 0 vnovProI KAI Y<l>YnOYPrOI OIKONOMIAI KAI OIKONOMIKQN 'Exovrnc; unoljJri: 1. To eyypacpo TrJc; f'.L8U8UVar]c; nepLl3000VTOc; TOU re­ VLKOU Xriµefou Tou Kp6rnuc; apt8. 3021723/3840/2004. 2. Ttc; 5tm6setc; TOU 6p8pou 1 (nap. 1, 2 KQL 3) TOU N. 1338/1983 «Ecpapµoyr') TOU KOLVOTLKOU l'.LKa[ou» (<l>.E.K. 34/A'/1983) 6nwc; TpononOLr')8rJK8 an6 TO 6p8po 6 TOU N. 13 AnptA.LOU 2005 1440/1984 «Luµµnoxr') TrJc; EM65oc; mo Kecp@mo, ma ano8eµmtK6 KOL mtc; npol3MljJetc; TrJc; Eupwna'iKr')c; Tp6 ne½ac; EnevMaewv, mo Kecp@mo TrJc; Eupwna'iKr')c; KOL­ VOTrJToc; AvSpaKoc; Km X6Aul3oc; Km Tou Opyavtaµou Ecpo 5taaµou EYPATOM» (<l>.E.K. 70/A'/1984) Ka8wc; KQL TO 6p 8po 65 TOU N. 1892/1990 (<l>.E.K. 101/A/1990). 3. To e56cpLO 5 TrJc; nap. 8 TOU 6p8pou 6 TOU N6µou 4328/1929 (<l>.E.K. 272/A/1929) «nep(aum6aewc; revtKou Xriµdou TOU Kp6TOuc;», 6nwc; avnKmam68rJK8 an6 TrJV nap6ypacpo 6Tou 6p8pou 11 Tou N6µou 2343/95, (<l>.E.K. 211/A/11.10.1995). 4. To 6p8po 4 Tou l'.tm6yµmoc; TrJc; 31 ric; OKTwl3p(ou 1929 «nep( KaVOVLOµOU TrJc; Af:LTOUpy(ac; KQL TWV epyamciJv TouAvwT6TOuXrJµLKOU LUµl3ouMou» (<l>.E.K. 391/A/1929). 5. To 6p8po 1 Tou N6µou 115/1975 «nep[ TpononOLr')ae­ wc; 5tm6sewv TLVWV TOU N. 4328/1929» (<l>.E.K. 172/A/ 1975). 6. Ta n.t:.. 284/1988 Km 543/1989 «Opyavtaµ6c; Tou Ynoupydou OtKovoµtKcilv» (<l>.E.K. 128 KOL 165/A/1988 KOL 229/A/1989). 7. Triv an6cpaari 1078204/927/0006 A/6.8.1992 «nepto­ ptaµ6c; LUMoyLKwv Opy6vwv Tou Ynoupyefou OtKovoµL­ Kwv» TWV Ynoupywv npoe5p(ac; KQL OLKOVOµLKWV» (<l>.E.K. 517/B'/1992). 8. Triv un' apt8. 14650/l'.IOE85/17.3.2004 (<l>.E.K. 519/B'/ 17.3.2004) Kotvr') An6cpaari Tou npw8unoupyou Km Tou Ynoupyou OtKovoµ(ac; Km OtKovoµLKwv «Ka8optaµ6c; ap­ µo5toTr')Twv TWV Ycpunoupywv OLKovoµ[ac; KQL OLKOVOµL­ KWV». 9. Ttc; 5tm6setc; TOU 6p8pou 29 A TOU N. 1558/1985 (<l>.E.K. 137/A/1985) 6nwc;rn 6p8po auT6npome8rJKe µe TO 6p8po 27 TOU N. 2081/1992 (<l>.E.K. 154/A'/1992) KQL aVTLKaTam68rJK8 an6 TO 6p8po 1 nap. 2a TOU N. 2469/ 1997 (38 A) Km TO yeyov6c; OTL an6 TrJV napouaa an6cpa­ ari 5ev npoKOAefTm 5an6vri ae l36poc; Tou KpmtKou npo 0no},,oytaµou, anocpaa(½ouµe: EyKp[vouµe TrJV an6cpaari apt 8. 551 /2004 TOU AVWTQTOU XrJµLKOU LUµl3ouMou ri ono(a e},,r')cpSri Km6 TrJ auve5p(aari TrJc; 16/12/2004 Km ri onofa exet we; aKoAouSwc;: rENIKO XHMEIO TOY KPATOYL ANQTATO XHMIKO LYMBOY/\IO EyKp[vouµe TrJV evapµ6VLarJ TrJc; ESVLKr')c; Noµo8ea[ac; npoc; TrJV O5rJy(a 2004/16/EK (EEL 42/13.2.2004) TrJc; Em 6848 E<l>HMEPII THI KYBEPNHIEnI (TEYXOI .6.EYTEPO) Tponr')c; n1c; 12ric; <l>El3pouap(ou 2004 «yta TT]V Ka8tepwari Tp6nwv 5EtyµmoArJljJ(ac; Km µE865wv av6Auaric; yta TOV en(ar]µO 8AEYXO TWV µeyLOTWV TIEplEKTLKOTr')TWV KaOOLT8 pou aE Kovaepl3Ec; Tpocp(µwv» we; E~r')c;: Ap8po 1 OL 5ELyµmOAT]ljJ(Ec; yLa TOV en(ariµo 8AEYXO TWV µeyL­ OTWV TIEPLEKTLKOTr')TWV OE Kaaa(rnpo OTa Tp6cptµa npayµmonotouVTm auµcpwva µE TLc; µE865ouc; nou nEpL­ yp6cpovrnL mo nap6pTT]µa I TT]c; napouaac; an6cpaaric;. Ap8po2 H napaaKeur'] TWV 5ELyµ6TWV KQL ri XfJT]OLµOTIOLOUµEVf] µe8o5oc; aVaAUOT]c; yLa TOV en(ar]µO 8AEYXO TWV µeyLOTWV TIEPLEKTLKOTr')TWV OE KaaafTEpO OTa Tp6cptµa va aVTano­ Kp(VOVTQL OTa KpLTr')pLa nou TIEpLyp6cpOVTQL OTO nap6p­ TT]µa II TT]c; napouaac; an6cpaaric;. nAPAPTHMAI TPOnOI .t.Elf""MATO/\HlJJIAL rlA TON EnlLHMO E/\EIXO TON MfflHQN nEPIEKTIKOTHTQN LE KAEITEPO LE KONLEPBEL TPO<l>IMQN 1. AVTLKdµEvo Km nE5(o Ecpapµoyr')c; Ta 5E(yµma nou npoop(½oVTm yLa TOuc; en(ariµouc; EMyxouc; TT]c; nEpLEKTLKOTT]rnc; aE Kaaa(rnpo ma Tp6 cptµa, Aaµl36voVTm auµcpwva µE Ttc; AEmoµepELEc; nou avacpepOVTQL KQTWTepw. Ta OUVOALKQ 5dyµma nou Aaµl36voVTm Km6 Tov Tp6no auT6 8EwpouVTm we; aVTL­ npoawneuTLK6 TWV napT(5wv. H auµµ6pcpwari TWV napT(­ owv 6aov acpop6 Ttc; µeytmEc; nEpLEKTLKOTrJTEc; nou Ka8o­ p(½oVTm OTOV KaVOVLaµ6 (EK) apLS. 466/2001 npoaotop(­ ½ETQL aE auv6pTTJOT] µE nc; nEpLEKTLKOTT]TEc; nou otammwvoVTm ma EpyamriptaK6 odyµma. 2. Optaµo( napT(oa: H EK60TOTE napaotMµEvrJ npoaotop(mµri no­ a6TT]Ta Tpocp(µou, yLa TT]V ono(a EXEL Ol8UKplVLOTE( an6 TOV apµ65to 6TL napoum6½EL Kotv6 xapaKTrJPLITTLK6, 6nwc; d­ vm ri npoeAeuarJ, ri noLKLMa, TO d5oc; auaKeuaa(ac;, o au­ OKEuamr')c;, o anomoMac; r') ri ar')µavari. YnonapT(5a: Tµr')µa µEy6AT]c; napT(5ac; nou EXEL optmd yta TT]V Ecpapµoyr') TOU Tp6nou 5EtyµmoArJljJ(ac; OTO Ev A.6 yw opta8ev Tµr')µa. K68E unonapT(5a npenEL va 5taxwp(­ ½nm cpumK6 Km va dvm npoa5top(mµri. LTOLXELw5Ec; 5dyµa: noa6TT]Ta UALKOU nou Aaµl36vnm an6 eva µ6vo ariµdo TT]c; napT(5ac; r') TT]c; unonapT(5ac;. LUVOALK6 5dyµa: To auv5uaaµevo auvoAo 6Awv Twv ITTOLXELw5wv 5Etyµ6Twv nou exouv ArJcpSd an6 TrJV napT( 5a r') TrJV unonapT(5a. EpyamriptaK6 5dyµa: Lldyµa nou npoop(½ETaL yta TO Epyamr')pto. 3. IEVLKec; OLQTQ~ELc; 3.1. npoawmK6 H oEtyµmoArJljJ(a npenEL va npayµmonOLdTm an6 Em­ cpopTtaµevo yta TO OKOTIO auT6 6TOµo, auµcpwva µE TLc; taxuouaEc; oXETLKec; 5tm6~ELc;. 3.2. npo"i6v an6 TO ono(o Aaµl36voVTm 5dyµma K68E npoc; av@uari napT(5a anornAd aVTLKdµEvo ~E­ xwptmr')c; 5EtyµmoArJljJ(ac;. 3.3. MeTpa npocpuAa~ric; nou npenEL va Aaµl36voVTm Km6 TT] 5t6pKELa TT]c; 5ELyµmOAT]ljJ(ac; KQL TT]c; npoE­ TOLµaa(ac; Twv 5Etyµ6Twv, npenEL va Aaµl36voVTm npocpu A.6~Etc; WITTE va anocpEuynm OLa5r')noTE aMo(wari, ri ono(a µnopd va TpononOLr')aEL TT]V nEpLEKTLKOTT]Ta aE Kaaa(TEPO, va enrJpE6aEL apvrJTLK6 TLc; avaMaEtc; r') TrJV avnnpoawnEUTLKOTT]Ta TOU OUVOALKOU 5dyµmoc;. 3.4. LTOLXELw5ri 5dyµma LTO µeTpO TOU 5UVQTOU, npenEL va Aaµl36VOVTQL OTOLXEL­ W5T] 5dyµma aE 5tacpopETLK6 ariµda TT]c; napT(5ac; r') TT]c; unonapT(5ac;. K68E napeKKALarJ an6 Tov Kav6va auT6v npenEL va Emariµa(vETm ma npaKTLK6. 3.5. napaaKeur') TOU OUVOALKOU odyµmoc; To OUVOALKO odyµa anOTEAf:lTQL an6 TT] auvevwari OAWV TWV OTOLXELW5wv 5ELyµ6TWV. AUTO TO OUVOALKO 5dyµa nµnys:-unnn1s:-1Tn1 rrrn s:-pynrrrr,p1n. 3.6. 'OµOLa EpyamriptaK6 5dyµma Ta 6µ0La EpyamriptaK6 5dyµma nou npoop(½oVTm yta µeTpa EMyxou Ecpapµoyr')c; TT]c; voµo8ea(ac;, yta 6aKrJOrJ npoacpuyr')c;, r') yta Myouc; 5tmTria(ac; Aaµl36voVTm an6 TO oµoyEvonotriµevo auvoALK6 5dyµa un6 Tov 6po 6TL ri 5ta 5tKaa(a auTr') dvm auµcpwvri npoc; Ttc; taxuouaEc; axntKec; ()LQTQ~ELc;. 3. 7. LUOKeuaa(a KQL anoOToAr') TWV 5ELyµ6TWV K68E 5dyµa Epyamrip(ou T(SETQL aE Ka8ap6 nEpLEKTrJ, an6 a5pavr') UAT], o ono(oc; napexEL TT]V KaTOOT]ArJ npo­ maa(a TOU 5dyµmoc; an6 OTIOL05r')noTE napciyoVTa Emµ6Auvaric; Km an6 onOLa5r')noTE l3Acil3ri nou µnopd va npOKUljJEL KQTQ TT] 5tcipKELa TT]c; µErncpop6c;. npenEL va Aaµl36vovrnL rn(aric; 6AEc; oL avayKa(Ec; npocpuA.ci~ELc; yta va anoTpand K68E aMo(wari TT]c; auvSearic; Tou Epya­ OTrJpLaKou 5dyµmoc;, ri ono(a µnopd va ETI8A8EL Km6 TT] 5tcipKELa TT]c; µErncpopcic; r') TT]c; ano8r')Keuaric;. 3.8. LcppciyLOT] KQL ar')µavari TWV 5ELyµciTWV K68E en(ariµo 5dyµa acppay(½nm mov T6no TT]c; i'il".IVI 1nTClAntl1fnc- Knl l".mrrnt 1nfvl".Tnl I ls:'. K/1\i'ilK() Tnl ITOTnTO.C' - - - I 1-- -- - - - -- IT - -- -i - - --- - - -- - 11-- --- - - - --- 1--- -- - - - - -- - - I -i auµcpwva µE Ttc; taxuouaEc; oXETLKec; 5tm6~Etc;. na K08E 5ELyµmOAT]ljJ(a, npenEL va OUVTQOOOVTQL npa­ KTLKQ 5ELyµmOAT]ljJ(ac;, rn ono(a Ka8LOTOUV 5uvmr') TT]V avayvwptari, xwp(c; aµcptal3r')TrJarJ, TT]c; napT(5ac; an6 TT]V ono(a EXEL AT]cp8d TO 5dyµa, Km npenEL va avaypcicpErnL ri T]µEpoµriv(a Km o T6noc; 5EtyµmoArJljJ(ac; Ka8wc; Km K68E 6Mri auµnAT]pwµmtKr') TIAT]pocpop(a, ri ono(a µnopd va anol3d xpr')mµri yLa TOV aVOAUTr'). 4. npoypciµµma 5EtyµmoArJljJ(ac; 0 Tp6noc; 5EtyµmoArJljJ(ac; nou Ecpapµ6½nm npenEL va E~aacpaAL½EL 6TL TO auvoALK6 5dyµa dvm aVTmpoawneu­ TLK6 TT]c; napT(5ac; nou np6KELTaL va EAEYX8EL 4. 1. Apt8µ6c; TWV OTOLXELW()WV 5ELyµciTWV 0 EAOXLITTOc; apt8µ6c; OTOLXELW5wv 5ELyµ6TWV nou ea AT]cp8ouv an6 Kovaepl3Ec; µtac; napT(5ac; dvm auT6c; nou avacpepErnL mov n(vaKa 1. Ta ITTOLXELw5ri 5dyµma nou Sa AT]cp8ouv an6 K68e Kovaepl3a npeneL va exouv na­ p6µ0LO l36poc;, nou ea EXEL we; anOT8AWµa eva OUVOALKO 5dyµa (l3MnE ariµdo 3.5). nfvaKac; 1 Apt8µ6c; KovaEpl3wv (ITTOLXELw5ri 5dyµma) nou Aaµl36 voVTm yta TT] 5taµ6pcpwari TOU auvoALKOU 5dyµmoc; Apt8µ6c; KOVOEpl3wv OTT]V Apt8µ6c; KOVOEpl3wv napT(5a r') TT]V unonapT(5a nou npenEL va AT]cp8ouv 1 ewe; 25 1 KOV08pl3a TOUAOXLOTOV 26 ewe; 100 2 KOVaepl3Ec; TOUAOXLOTOV > 100 5 KOV08pl3Ec; E<l>HMEPII THI KYBEPNHIEnI (TEYXOI ~EYTEPO) 6849 Ll"]µ8tWV8TQt 6Tt TQ µeytma 8TilTI80a 8(j)apµ6l;ovrnt ITTO TI8pt8X0µ8VO K088 KOV08pf3ac;, aM6 npOKEtµEVOU Va 8lVQl ouvm6v va npayµmonotriSd ri avw..uori, dvm avayKa(o va XPrimµonotriSd µta npooeyytari ouvoAtKl1<:; 5Etyµmo­ Afllj.J(ac;. Av TO anOT8AWµa Tf]c; avw..uanc; yta TO OUVOAtK6 odyµa 8lVQl xaµnMrnpo, aM6 KOVTQ ITTO µeytITTO 8TilTI800 KQl av UTIOPXOUV UTIOVOt8<:; OTt µEµovwµeV8<:; KOVOepf38<:; 8V 08X8TQl va un8pf3a(vouv TO µeytmo rn(nEoo, TOTE EvoexE­ TQl va dvm avayKa(o va otE~axSouv nEpmTepw epEuvEc;. 4.2. b.EtyµmoArJljJ(a mo m6oto Tf]c; AtavtKl1<:; nWAflOf]c; H 08tyµaTOAf]ljJ(a TWVTpO(j)(µwv ITTO ITTQOtO TOU AtaVtKOU Eµnop(ou npenEt va y(vErnt 6nou dvm ouvm6v ouµ(J)wva µE Ttc; napan6vw 5tm6~Etc; OEtyµmoArJljJ(ac;. 'Orav auT6 08V 8lVQl ouvm6 µnopouv va xpnmµonotriSouv 6M8c; anoTEAwµmtKec; otaotKao(Ec; OEtyµmoArJljJ(ac; mo m6 5to TrJc; AtavtK11<:; nwArioric;, µE TflV npoun6880fl 6Tt ota­ O(J)M(l;ouv 8TIQPK11 QVTlTipOOWTI8UTtKOTf]TQ Tf]c; napT(oac; mriv ono(a npayµmonotdrnt ri OEtyµmoArJljJ(a. 5. Luµµ6p(J)WOfl TrJc; napT(oac; 11 TrJc; unonapT(oac; µE Ttc; npootaypa(j)ec; To Epyam11pto EMyxou npenEt va avaMoEt TO Epya­ mriptaK6 odyµa nou npoop(l;ETm yta µeTpa EMyxou 8(j)apµoy11c; Tf]c; voµo8w(ac; TouMxtmov 08 Mo av8~6p­ Tf]T8<:; avaAU08tc; KQl va UTIOA.oy(l;8t TO µeoo 6po TWV ano­ T8A80µ6TWV. H napT(oa y(v8TQl an008KTl180V O µfooc; 6poc; 08V UTI8p­ f3a(v8t Tf]V aVTlITTOtXJl µeytITTf] n8pt8KTtKOTf]TQ [ 6nwc; op(i'.;8 TQl mov Kavovtoµ6 (EK) apt8. 466/2001], Aaµ[3avoµevric; un6lj.Jf] Tf]c; af38f3QlOTf]Tac; Tf]c; µeTpf]Of]c; KQl Tf]c; Ot6p8w­ anc; we; npoc; TflV av6KTrJOfl. H napT(Oa 08V ouµµop(j)WV8TQl µ8 TT] µeytITTf] TI8pt8KTt­ KOTf]TQ [6nwc; op(l;Ernt mov Kavovtoµ6 (EK) apt8. 466/2001], 86v o µfooc; 6poc;, a(J)ou 5top8w8d we; npoc; Tf]V aVOKTf]Of], UTI8pi3a(V8t TT] µeytITTf] TI8pt8KTtKOTf]TQ TIE­ pa an6 K688 AoytK11 aµ(J)tf30Ma, Aaµ[3avoµevnc; un6lj.Jfl TrJc; af38f3QlOTf]Tac; Tf]c; µeTpf]Of]c; KQl Tf]c; 5t6p8wanc; we; npoc; Tf]V aVOKTf]Of]. nAPAPTHMA II nAPALKEYH TON b.ElrMATON KAI KPITHPIAHA onOIA nPEnEI NAANTAnOKPINONTAI 01 ME00b.OI ANMYLHL rlA TON EnlLHMO E/\ErXO TON nEPIEKTIKOTHTON LE KALLITEPO HIL KONLEPBEL TPO<l>IMON 1. npo(J)uA6~Etc; Km yEvtKec; EKTtµ110Etc; yta Tov Kaoo(TE­ po BamK6c; m6xoc; dvm va Afl(J)Sd eva aVTmpoown8UTtK6 KQl oµotoy8V8<:; 8pyaITTf]ptaK6 odyµa XWp(c; Va un6p~8t 08UT8poyEV'l<:; Emµ6Auvori. 0 avMuT11c; npen8t va E~aO(J)aAtoEt 6Tt rn odyµarn oEv EmµoMvoVTm KaT6 Tfl 5t6pK8ta Tf]c; npo8Totµao(ac; TOuc;. 'Onou dvm ouvm6v, 6Aoc; o E~onAtoµ6c; nou EPXETm OE 8Tia(j)l1 µE TO odyµa np8TI8t VQ 8lVQl an6 aopavec; TIAQITTt­ KO, n.x. noAunponuMvto, noAUT8Tpa(j)8opom8uMvto (PTFE) K.An. Km npenEt va EXEt Ka8aptmd µE o~u WITTE va 8AaXtITTOTIOtOUVTQl Ot m8av6Tf]T8<:; Emµ6AUVOf]c;. rta Ttc; KOITTtKec; aKµec; µnopd va XPnmµonot8lTQl Ulj.Jf]Al1<:; not6 Tf]Tac; avo~dowTOc; xaAu[3ac;. To ouvoAo Tou odyµmoc; npo"i6VToc; nou napMaµf36 vETQl mo Epyam11pto npenEt va xprimµonotdTm yta TflV napaoK8Ul1 TOU UAtKou nou np6K8tTQl va 8~8TaITTEL M6 vov TQ noM AEmwc; oµoyEVOTIOtf]µeva odyµarn o(vouv avanapaywytµa anoTEMoµma. Ynapxouv noMec; otaOtKaO(Ec; napaOK8Ul1<:; 08tyµ6TWV, nou dvm ouvm6v va XPrimµonotriSouv yta Ta ouyKE­ Kptµeva npo"i6VTa µE tKaVOTIOtf]TtK6 Tp6no. AuTec; nou TI8 ptyp6(j)OVTQl ma np6TUna CEN «Determination of trace el­ ements - Performance criteria and general consideration» 88WpOUVTQl tKaVOTIOtf]TtKec; (nap. 1), 8VW KQl 6M8c; µno­ pdva dvm E~(oou eyKupEc;. 2. EnE~Epyao(a Tou odyµmoc; nou napaAaµf36vETQl mo Epyam11pto To TIA11PE<:; ouvoAtK6 odyµa ouv8M[3ETm oE AEmoµEP11 owµm(ota (8(J)6oov XPEt6l;Ernt) KQl avaµEtyvuETQl EmµEAW<:; ouµ(j)wva µ8 µta µe8ooo nou 8~aO(j)aAti'.;8t ano 0808tyµeva Tf]V TIAl1Pfl oµoyEVOTIOlf]Of]. 3. Ynoota(pwn TWV 08tyµ6Twv yta µeTpa EMyxou 8(j)apµoy11c; Tf]c; voµo8w(ac; KQl QOKf]Of] npOO(j)UY11<:; Ta 6µota odyµma nou npoop(l;oVTm yta µeTpa EMvxou E(J)apµoy11c; Tf]c; voµo8w(ac;, yta 6oKrJOfl npoo(J)uy11c;, 11 yta A.6youc; OtQlTf]O(ac;, Aaµf36vOVTQl an6 TO oµoy8VO­ notriµevo UAtK6 (OUVOAtK6 odyµa), un6 TOV 6po OTt n ota­ OtKao(a aUTl1 8lVQl ouµ(j)WVf] npoc; Ttc; toXUOU08<:; UX8TtK6 µE TT] 08tyµmOAf]ljJ(a OtQTQ~Etc;. 4. Me8oooc; av6Auaric; nou npenEt va XPrimµonotdrnt an6TO Epyam11pto Km anmT110Etc; UXETtK6 µE TOV EAEYXO Tou Epyamrip(ou 4. 1. Optoµo( OptoµevOl an6 TOuc; TI8pt000T8p0 Ota0800µevouc; Optoµouc; TIOU npen8t va XPf]atµonOtOUVTQl an6 TQ 8pya­ ITTl1pta 8lVQl Ot aK6AOU80l: r = EnavaArJlj.Jtµ6Tf]rn, f]Ttµ11 K6Tw an6Tf]V ono(a Mvmm va avaµevETm 6Tt ri an6AUTfl 5ta(J)op6 µErn~u TWV anOT8AWµ6Twv Mo µEµovwµevwv OOKtµwv, nou 11.aµpuvovrrn KuTw an6 ouv8r'1Kec; enava11.r1ljJLµ6TTJTac; (Of]Aao11 TO (oto odyµa, 0 (otoc; X8tptm11c;, 0 (otoc; 8~0 TIA.toµ6c;, TO (oto Epyam11pto Km µtKPl1 xpovtKl1 an6ma­ ori), f3p(OK8TQt 8VT6c; TWV op(wv Tf]c; 8t0tK11<:; m8av6Tf]Tac; (Km6 Kav6va 95 %) Km rnoµevwc; r = 2,8 X sr. sr = TumKl1 an6KAtOfl, unoAoytl;6µEvfl µE [36ori rn Afl(j)SeVTa anoTEAfoµma un6 ouv811 K8<:; rnavaAf]lj.Jtµ6Tf]TQ<:;. RSDr = LXETtK11 TUTilK11 an6KAtOrJ, unoAoytl;6µEVf] R sR RSDr µE [36cm rn anoTEAfoµarn nou 8Al1(J)8f]­ oav un6 ouv811Kec; rnaVOAf]lj.Jtµ6Tf]rnc; [(Sr/ X) x 100]. = Avanapaywytµ6Tf]TQ: Ttµ11 KQTW an6 Tf]V ono(a ouvaTm va avaµevnm 6Tt ri an6Au­ Tfl Ota(j)Op6 µErn~u TWV anOT8AWµOTWV TWV µEµovwµevwv OOKtµwv, nou 8Al1(j)8f]­ oav un6 ouv811KE<:; avanapaywytµ6Trirnc; (OrJA.ao11 yta TO (oto npo"i6v nou 8Al1(J)8fl an6 X8tptmec; 08 5t6(j)opa Epyam11pta, XPf]atµOTIOlWVTac; TT] TUTIOTIOtf]µEVf] µe8o­ oo OOKtµao(ac;), f3p(OK8TQl 8VT6c; optoµe­ vou op(ou m8av6Tf]rnc; (Km6 Kav6va 95%) KQl rnoµevwc; R = 2,8 x sR. = TumK11 an6KAtOf], UTIOAOytl;6µ8Vf] µ8 [36on Ta anoTEMoµma un6 ouv811KE<:; avana­ paywytµ6Trirnc;. = E(vm ri UXETtK11 TUTilK11 an6KAtOfl nou uno­ Aoy(l;ETQl µE [36ori rn anoTEMoµma nou 8Al1(J)8rJoav un6 ouv811KE<:; avanapayw 6850 E<l>HMEPII THI KYBEPNHIE!lI (TEYXOI ~EYTEPO) ytµ6nJTOc; [ (sR/) x 100], 6nou dvOL o µfooc; 6poc; TWV anoTeAwµaTWV yta 6Aa TO epyamf]pta KOL odyµOTa. HORRADr = H napOTl']POUµevri TLµf] RSDr OlOLpouµevri ot6 Tl']c; TLµf]c; RSDr nou uno>-..oy(i'.;nOL µe Tl']V e~[awari TOU Horwitz )(pl']OLµonOLW­ VTO<:; Tl']V un6ewri OTL r = 0,66R. HORRADr = l'] napOTrJpouµevri TLµf] RSPr OLOLpouµevri ot6 Tl']c; TLµf]c; RSPr nou uno>-..oy(i'.;eTOL µe Tl']V e~(awari TOU Horwitz (nap. 2). U = H eKTeTOµevri af3ef30LOTrJTO, µe TrJ XPrim µono(riari ev6c; auVTe>-..emf] KOAUlj.Jl']c; 2 nou Nvet rn[ne5o eµrna-roauv17c; nep[nou 95%. 4.2. revtKec; anOLTf]aetc; 0L µeeooOL OVOAUOl']<:; nou XPl']atµonOLOUVTOL yta TOV 8A8YXO TWV Tpocp(µwv npeneL VO OVTOnOKplVOVTOL OTL<:; OLOT0~8l<:; TWV 01'] µdwv 1 KOL 2 TOU napapTr] µOToc; Tl']c; 001']­ y(ac; 85/591/EOK TOU ruµf30UALOU, Tl']c; 20f]c; l:,.eKeµf3p(ou 1985, yta Tl']V Kaetepwari KOLVOTLKWV Tp6nwv oetyµOTOAl']­ ljJ(ac; KOL µee6owv OVClAUOl']<:; YLO TOV 8A8YXO TWV Tpocp(µwv. 4.3. ELOLKE<:; anOLTrJ08l<:; 'OTOv oev Kaeop(i'.;oVTOL auyKeKptµevec; µeeooOL yta Tov npoaotoptaµ6 Tou Kaaa(Tepou ae Kovaepf3ec; Tpocp(µwv ae KotvOTLK6 en(neoo, Ta epyamf]pta µnopouv va emM­ ~ouv OnOLOOr]nOT8 8TILKUpwµevl'j µeeooo un6 TOV 6po OTL l'] 8TILA8yµevl'j µeeoooc; lKOVOnOLeL TO KplTr]plO an60001']<:; nou avacpepoVTOL mov n(vaKa 2. H emKupwari npenet toa­ vtK6 va nepLAaµf36veL mmonotriµevo UALKO avacpopac;. nfVOK0<:;2 KptTf]pta an6ooaric; Twv µee6owv ava>-..uaric; yLO Kaaafrepo napaµnpoc; l:,.uvOT6Tl']TO ecpapµoyf]c; 'Opto av(xveuaric; 'OpLO nOOOTLKOnOLl']Ol']<:; AKp(f3eta AVClKTl']Ol'] Ttµf]/LXOALO Tp6cptµa nou Kaeop(i'.;oVTOL ITTOV KOVOVL0µ6 (EK) apte. 242/2004 5 mg/kg KOT' avwTOTO 6pto 10 mg/kg KOT' avwTOTO 6pto Ttµec; HORRATr fJ HORRATr µLKp6Tepec; TOU 1,5 ITTl'] OLep yaml'jplOKrJ OOKLµf] emKupw­ aric; 80-105 % ( 6nwc; avacpep8TOL ITTl'] OLepyaml'jplOKrJ OOKLµf]) Xwp(c; cpaaµOTLKE<:; napeµf3o­ Mc; fJ napeµf30Mc; nou ocpd AOVTOL mo un6mpwµa 4.3.1. KplTrJPLO an6ooaric; - npoaeyyLOl'j auvapTl']Ol']c; af3ef30L6Tl']TO<:; Qm6ao, µnopd en(aric; va XPrimµonotried µLO npoaey­ ytari af3ef30L6TrJTOc; yta va eKTLµried ri KOTOAArJAOTrJTO Tl']c; µee6oou av@uaric; nou npenet va xprimµonotried an6 TO epyamf]pto. To epyamf]pto µnopd va XPrimµonOLf]aet µta µeeooo ri ono(a ea napayet anoTeMaµOTa eVT6c; Twv op(wv µtac; µeyLITTl']<:; TUTILKr]<:; af3ef30LOTl']TO<:;. H µeyLITTl'] TUTILKrJ af3ef30LOTl']TO µnope( va uno>-..oytmd xprimµonotwVTac; Tov aK6>-..oueo Tuno: Uf = ✓ [(LOD/2)' + (0.2C)'] 6nou: Uf eLVOL l'] µeyLITTl'] TUTILKrJ af3ef30LOTl']TO LOO dvOL TO 6pto av(xveuaric; Tl']c; µee6oou C dvOL ri auyKeVTpwari evotacpepoVToc;. Eav µLO OVOAUTLKr] µeeoooc; napexet anOT8AfoµOTa µe µnpf]aetc; af3ef30L6Tl']TO<:; µtKp6Tepec; an6 TrJ µeytmri TU­ TILKrJ af3ef30L6TrJTO, ri µeeoooc; ea dvOL e~(aou KOTOAArJArJ µe 8KelVl'] nou OVTanoKp(veTOL ma xapOKTrJPLITTLKCl an6 ooaric; nou o(voVTOL mov n(vaKa 2. 4.4. Yno>-..oytaµ6c; TOU noaomou OVOKTl']Ol']c; KOL KOTO­ ypacpfJ TWV anOT8AWµOTWV To OVOAUTLKO anoTeAeaµa KOTaypacpeTOL un6 OLOp 0 Tp6noc; KOTaypacpf]c; KOL TO noaom6 av6KTl']OrJc; npe­ net va OVOKOLVWVOVTOL. To anoTe>-..wµa TrJc; ava>-..uaric;, acpou otopewed we; npoc; Tl']V OVOKTl']Ol'], XPl']OLµOnOLeLTOl YLO TOV 8A8YXO Tl']<:; auµµ6pcpwaric; (SMne napapTl']µa I ariµdo 5). 0 avaAuTf]c; npenet va >-..aµf36vet un6lj.JrJ TL<:; «Harmonised Guidelines for the Use of Recovery Information in Analyti­ cal Measurement» (nap. 3) («Evapµovtaµevec; KOTeueu­ VTrJptec; ypaµµec; YLO Tl'] XPrJOl'] n>-..ripocpoptwv OVClKTl']Ol']c; mriv avaAUTLKrJ µeTprJOrJ») nou auveTO~av OL IUPAC/IS0/ AOAC. AUT8<:; Ol KOTeueuVTr]ptec; ypaµµec; 8TILKOUpOUV ITTOV KO­ eoptaµ6 TWV napay6VTWV OVClKTl']Ol']c;. Ta anoTe>-..foµOTa Tl']c; av6Auaric; npenet va avacpepo­ VTOL we; x + /- U 6nou x dvOL TO anoTeAwµa Tl']c; ava>-..uaric; KOL LJ l'] af3ef30LOTl']TO Tl']<:; µeTpl']Ol']<:;. 4.5. np6TUna noLOTl']TO<:; TWV epyamrip(wv Ta epyamf]pta npeneL va OVTanoKplVOVTOL ITTL<:; OLOTCl­ ~eLc; Tl']c; ooriy(ac; 93/99/EOK Tou ruµf3ouMou, Tl']c; 291']<:; 0KTwf3p(ou 1993, axntK6 µe TO np6aeeTO µfapa nou acpo­ pouv TOV eTILOl']µO 8A8YXO TWV Tpocp(µwv. 4.6. /\omec; 8KTLµf]aetc; yta Tl']V OVClAUOl'] l:,.oKLµaa(a en6pK8LO<:; ruµµeTOXrJ ae KOTaMri>-..ec; ooKtµaa(ec; eMyxou enap­ Ketac;, Ol ono(ec; OVTanoKp(voVTOL OTO «International Har­ monised Protocol for the Proficiency Testing of (Chemical) Analytical Laboratories» (nap. 4) nou exet auVTaxed un6 Tl']V OLy(oa TWV IUPAC/IS0/AOAC. Optaµevec; an6 auTec; TL<:; ooKtµaa(ec; nept>-..aµf36vouv auyKeKptµeva Tov npoaotoptaµ6 Kaaa(Tepou ma Tp6 cptµa. ruvtm6TOL ri auµµeTOxfJ ae auTou Tou doouc; TrJ oo­ Ktµaa(a KOL 6xt ae Kanota yevtK6Tepou neptexoµevou yLO Tov npoaotoptaµ6 µeTaMwv ma Tp6cptµa. EawTeptK6c; e>-..evxoc; nOLOTl']TO<:; Ta epyamf]pta npenet va dvOL ae eeari va anooetKvu­ ouv OTL OtaeeTOUV OLOOLKaa(ec; WWT8plKOU eMvxou nOL6 Tl']TOc;. 'Onwc; yLO napaoetyµa TL<:; «IS0/AOAC/IUPAC Guide­ lines on Internal Quality Control in Analytical Chemistry Laboratories» (nap. 5). napaaKeuf] odyµOToc; npeneL va Al']cped µeptµva wme va e~aacpOALITTeL OTL 6>-..oc; o Kaaa(Tepoc; mo odyµa >-..aµf36veTOL ae ot6Au µa yta OVOAUOl']. ELOLK6Tepa, avayvwp(i'.;eTOL 6TL ri OLOOLKaa(a ota>-..uaric; odyµOToc; npenet va dvOL TeTota nou va µriv Kaetc;avet Kaµ(a uopo>-..uµevri evwari Sn IV (nx evwaetc; 6nwc; Kaa­ mTeptK6 O~eLOLO Sn02, Sn(OH)4, Sn02.H20). E<l>HMEPII THI KYBEPNHIEnI (TEYXOI .aEYTEPO) Ta napacrKeuacrµeva 5efyµma 5tm17pouvrm ae 5 mol/I HCI. Om6cro, o SnCl4 dvm noM m17TLK6c; KOL 8TOL TO 5ta­ Mµma 5ev npenet va uno[36Jv...ovrm ae [3pacrµ6. nAPAnOMnEL 1. BS EN 13804:2002: Foodstuffs - Determination of trace elements - Performance criteria, general consider­ ations and sample preparation, CEN, Rue de Stassart 36, B-1050 Brussels. 2. W Horwitz, «Evaluation of Analytical Methods for Reg­ ulation of Foods and Drugs», Anal. Chem., 1982, 54, 67A 76A. 3. ISO/AOAC/IUPAC Harmonised Guidelines for the Use of Recovery Information in Analytical Measurement. Edited Michael Thompson, Steven LR Ellison, Ales Fajgelj, Paul Wil­ letts and Roger Wood, Pure Appl. Chem., 1999, 71, 337- 348. 4. ISO/AOAC/IUPAC International Harmonised Protocol for Proficiency Testing of (Chemical) Analytical Labo­ ratories, Edited by M Thompson and R Wood, Pure Appl. Chem., 1993, 65, 2123 - 2144 (Also published in J. AOAC Inter­ national, 1993, 76,926). 5. ISO/AOAC/IUPAC International Harmonised Guide­ lines for Internal Quality Control in Analytical Chemistry Laboratories, Edited by M Thompson and R Wood, Pure Appl. Chem., 1995, 67, 649 - 666. 0 nPOELlPOL a.a. 0 ANTlnPOELlPOL 11.MANTE/\HL H 1PAMMATEAL El\. nAMAPH TA ME/\H: N. Kma(µnac;, t::, Mn6aKou, A. nana8avaa(ou, K. Auyoum6K17c;, r. Ltaµavr6c;, I. rayMac;, n. Apyup(ou. H LO)(uc; n1c; napoucrac; an6cpaaric; apx(~eL an6 Tfl 5riµo­ cr(eucrr'J T'l<:; m17v Eq:>17µep(5a T'l<:; Ku[3epvtjcrewc;. H an6q:>acrri auTr') va 517µomeu8ef m17v Eq:>17µep(5a T'l<:; Ku[3epvr')crewc;. A8r')va, 4 AnptMou 2005 OIYnOYP,01 OIKONOMIA.l: KAI OIKONOMIKON m1Prm: AAOrOIKOY<l>HI YcPYn. OIKONOMIAL KAI OIKONOMIKON MAM PErKOYZAI 6851