Ministerial Joint Decree No. 518/2002. Harmonization of the national legislative frame with Commission Directive 2002/69/EC laying down the sampling methods and the methods of analysis for the official controls of dioxins and the determination of dioxin-like PCBs in foodstuffs

5329 E<i>HiviEPiI THI KYBEPNHIEnI THI EAAHNIKHI aHMOKPATIAI TEYXOI ~EYTEPO nEPIEXOMENA AnO<l>AIEII Evapµ6vtari TrJc; ESvtKr')c; Noµo8wfac; npoc; TrJV msri­ y(a 2002/69/E.K. Tr]c; EmTponr')c; Twv Eupwna"iKwv KOLvOTr')Twv (EE L 209/6.8.2002) «yta Ka8optaµ6 Twv µe86owv oetyµmo>-.17ljJ(ac; Km Twv µe86owv QVOAUOr]c; yLa TOV en(Or]µO 8AE:YXO TWV OLO~LVWV KQL TOV npoaotoptaµ6 TWV nap6µ0LWV µe TLc; OLO~(vec; PCBs ma Tp6<ptµa».... ..... ...... ..... ..... ..... ..... ..... ...... ... 2 5330 E<l>HMEPII THI KYBEPNHIEnI (TEYXOI ~EYTEPO) ~pt8. 518/2002 (2) Evapµ6vtari TrJc; ESvtKr')c; NoµoSw[ac; npoc; TflV Oc5riy[a 2002/69/E.K. TrJc; EmTponr')c;TWv Eupwna'iKwv KOLvoTr')­ Twv (EE L 209/6.8.2002) «yLa Ka8optaµ6 TWV µe86owv oetyµmOArJljJ[ac; KOL TWV µe86owv av6AuITT]c; yta TOV en[ariµo e},.,eyx o Twv oto~tvwv KOL Tov npoaotoptaµ6 TWV napoµOLWV µe TLc; OLO~(vec; PCBs ma Tp6qJLµa». ovnovPrm: OIKONOMIAI KAI OIKONOMIKQN 'Exovrnc; unolj.Jri: 1. To eyypacpo TrJc; Llteu8uvaric; neptf36Movrnc; TOU 18 VLKOU Xriµdou Tou Kp6rnuc; apt8. 5304/18.12.2002. 2. Ttc; OLQTQ~f:Lc; TOU 6p8pou 1 (nap. 1, 2 KOL 3) TOU N. 1338/1983 «Ecpapµoyr') Tou KotvoTLKou LltKa[ou» (<l>.E.K. 34/A/1983) 6nwc; TpOTIOTIOLl78rJK8 an6 TO 6.p8po 6 TOU N. 1440/1984 «Luµµernxr') TrJc; EM6ooc; mo Kecp6AOLo, ma ano8eµmtK6. KOL mtc; npof3Mlj.Jetc; TrJc; Eupwna'iKr')c; Tp6 nel;ac; Enevouaewv, mo Kecp&OLo TrJc; Eupwna'iKr')c; KOL­ VOTrJToc; AvSpaKoc; KOLX6Au[3oc; KOL Tou Opyavtaµou Ecpo­ otaaµou EYPATOM» (<l>.E.K. 70/N1984) Ka8wc; KOL TO 6.p­ Spo 65 TOU N. 1892/1990 (<l>.E.K. 101/N1990). E<l>HMEPII THI KYBEPNHIEnI (TEYXOI .6.EYTEPO) 5331 3. To eo6cpto o n1c; nap. 8 Tou 6p8pou 6 Tou N6µou 4328/1929 (<l>.E.K. 272/A/1929) «nep( aum6aewc; revtKou Xriµdou TOU Kp6TOuc;», 6nwc; aVTlKOTam6817Ke an6 Tl7V nap6ypa<po 6Tou 6p8pou 11 TOU N6µou 2343/95, (<l>.E.K. 211 / A/ 11 . 1 0. 1995). 4. To 6p8po 4 TOU Lltm6yµmoc; T17c; 3117c; 0KTw[3p(ou 1929 «nep( KaVOVlOµOU Tl7<:; /1£lTOUpy(ac; KQl TWV epyaatWV Tou AvwT6Tou X17µtKou ruµ[3ouMou» (<l>.E.K. 391/A/1929). 5. To 6p8po 1 Tou N6µou 115/1975 «nep(Tpononot11aewc; Ol0TOS8WVTlVWVTOU N. 4328/1929» (<l>.E.K. 172/A/1975). 6. Ta n.Ll. 284/1988 KOl 543/1989 «Opyavtaµ6c; TOU Ynoupydou OtKovoµtKWV» (<l>.E.K. 128 Kat 165/A/1988 Kat 229/A/1989). 7. T17v an6cpaa17 1078204/927 /0006 A/6.8. 1992 «nepto­ ptaµ6c; IuM.oytKWV Opy6vwv TOU Ynoupydou OtKovoµt­ KWV» TWV Ynoupywv npoeop(ac; KQl OlKOVOµlKWV» (<l>.E.K. 517/8/1992). 8. T17v 1100383/1330/A0006/31.10.2001 K0tv11 an6<pa017 TOU npw8unoupyou KOl TOU Ynoupyou OtKOVOµlKWV «Ka 8optaµ6c; apµOOlOTl7TWV TWV Y<punoupywv OtKOVOµlKWV» (<l>.E.K. 1485/8/2001). 9. Ttc; Ol0TOS8l<:; TOU 6p8pou 29A TOU N. 1558/1985 (<l>.E.K. 137/A/1985) 6nwc;TO 6p8po auT6 npome817Ke µe TO 6p8po 27 Tou N. 2081/1992 (<l>.E.K. 154/A/1992) Kat aVTlKOTam6817Ke an6 TO 6p8po 1 nap. 2a TOU N. 2469/ 1997 (38A) Km TO yeyov6c; 6Tt an6 T17v napouaa an6cpa017 oev npoKOA.eLTat oan6v17 ae [36poc; Tou KpmtKou npou­ nohoytaµou, anocpaari:;ouµe: EyKp(vouµe Tl7V an6<pa017 apt8. 518/2002TOU AVWTQTOU X17µtKou ruµ[3ouMou 17 ono(a e11.11cp817 KOT6 Tll auveop(a017 Tl7<:; 23.1.2003 KQl l7 ono(a 8X8l W<:; 8Sl7<:;: rENIKO XHMEIO TOY KPATOYI ANOTATO XHMIKO IYM8OY/\IO EyKplvouµ8 -r17v 8vapµ6vl017 -rr,c; E8vtK1'7c; Noµo88alac; npoc; T17v Oo17y(a 2002/69/E. K. Tll<:; EmTpon11c; Twv Eupw­ na·iKwv KotvOTl7TWV (EE L 209/6.8.2002) «yta Ka8optaµ6 Twv µe86owv oetyµmo11.17ljJ(ac; Kat Twv µe86owv av611.u­ a17c;, yta TOV en(017µ0 e11.evxo TWV OlOSlVWV KOl TOV npoa­ Ol0ptaµ6 TWV nap6µotwv µe Tl<:; Otos(vec; PCBs ma TpO<pl­ µa», we; es11c;: Ap8po 1 H oetyµmo11.17ljJ(a yta TOV en(017µ0 eheyxo TWV emneowv auyKeVTpw017c; Twv otostvwv, Twv cpoupav(wv Kat Twv na­ p6µ0twv µe Tl<:; otos(vec; PC8s Ka8wc; KOl O npoaotoptaµ6c; Tl7<:; auyKeVTpwa17c; auTWV ma Tp6<ptµa npayµmonOleLTOl auµcpwva µe Ttc; µe86oouc; nou neptyp6<poVTm mo na­ p6pT17µa I. Ap8po2 H npoeTOtµaa(a Tou odyµmoc; Kat ot µe8000t av611.u017c; nou XPllatµonOlOUVTOl yta TOV en(a17µ0 8A8YXO TWV emne­ OWV Twv otostvwv, Twv cpoupav(wv Kat Twv nap6µ0twv µe Tl<:; otos(vec; PC8s ma Tp6<ptµa eLVQl auµ<pwva µe TO Kpl­ Tl7pla nou neptyp6<poVTm mo nap6pT17µa II. nAPAPTHMAI ME0Ob.OI b.ElrMATO/\HlJJIAI rlA TON EnlLHMO E/\ErXO TON EnlnE.llON TON b.10::INON (PCDD/PCDF) KAI TON nPOL.lllOPIIMO TON nAPOMOION ME TII b.10::INEI PC8s IE OPIIMENA TPO<l>IMA 1. AVTtKdµevo Kat neo(o ecpapµoy11c; Ta oe(yµma nou npoop(l;oVTm yta Tov en(017µ0 eheyxo TWV emneOWV nepl8KTlKOTl7Tac; TWV Tpo<p(µwv ae Ol0SLV8<:; (PCDD/ PCDF), Ka8wc; Kat yta Tov npoaotoptaµ6 T17c; ne­ pteKTtK6T17TOc; TWV Tpo<p(µwv ae nap6µ0ta µe Tl<:; Ol0SLV8<:; PC8s(1l 11.aµf36voVTm auµcpwva µe Ttc; µe86oouc; nou nept­ yp6<poVTm KOTWT8pW. Ta OUVOAlKQ oe(yµma nou anOKTl7 817Kav µe TOV Tp6no auT6 8ewpOUVTQl we; aVTmpoawneu­ TlKO Twv napT(owv 11 unonapT(owv an6 Ttc; ono(ec; 11.aµf36 VOVTOl. H auµµ6pcpwa17 µe TO avwTma en(neoa nou Ka8op(l;oVTat mov Kavovtaµ6 (EK) apt8. 466/2001 (EEL 77 /16.3.2001) «yta TOV Ka8optaµ6 µeylITTWVTlµWV avoxr']c; yta optaµevec; npoaµdsetc; ma Tp6<ptµa», Ka8op(l;eTOl µe [36017 TO en(neoa nou npoaotop(i'.;oVTm ma epyam17ptaK6 5etyµa-ra. 2. Optaµo( napT(oa: Avayvwp(mµ17 noa6T17TO Tpocp(µou, nou na­ pao(oeTm ae µ(a anoITTOAl7 KQl yta Tl7V ono(a Olammwve­ TQl an6 Ttc; apµ6otec; eheyKTtKec; apxec; 6Tt napoum61'.;et KOlVQ xapaKTl7plITTlKO, 6nwc; eLVQl l7 np08A8UOl7, l7 nOlKl­ A(a, TO dooc; auaKeuaa(ac;, o auaKeuam11c;, o anomoM­ ac; 1117 a11µav017. LTl7Vnep(mw017 TWV ljJaplWV KOl TWV 0/1.l­ eLJTlKWV npO"iOVTWV npenel KOl TO µeye8oc; TOU<:; va eLVQl auyKp(mµo. YnonapT(oa: Ka8optaµevo Tµl7µa µey6A17c; napT(oac; nou exet optmd, yta T17v ecpapµoy11 T17c; µe86oou oetyµa­ To11.17ljJ(ac; mo ev Myw opta8ev Tµl7µa. K68e unonapT(oa npenet va otaxwp(i'.;nm cpumK6 Km va µnope( va TauTo­ not178eL ITotxetwoec; odyµa: noa6T17TO uhtKou nou 11.aµf36vnm an6 eva µ6vo 017µdo T17c; napT(oac; 11 T17c; unonapT(oac;. ruvo11.tK6 odyµa: To auvotaaµevo auvoho 611.wv Twv motxetwowv oetyµ6Twv nou exouv 11.17cp8d an6 T17v napT(­ oa 11 T17v unonapT(oa. Epyam17ptnK6 odypa: avnnpom 1meuTtK6 Tpi]pa/noa6 Tl7TO Tou auvohtKou odyµmoc; nou npoop(i'.;eTOt yta av6 11.ua17 mo epyam11pto. (1) mvaKac; TEF n1c; nOY yLa T17v a~L0My17a17 TOu KLvouvou yLO Tov 6v8pwno µe [36017 rn auµnepaaµma T1']c; auveopia017c; T1']c; nayK6aµLac; Opy6vw017c; Yyeiac; m17 LTOKX6Aµ17 T1']c; fou17oiac;, 15-18 louv(ou 1997 [(Van den Berg etal., 1998) Toxic Equivalen­ cy Factors (TEFs) for PCBs, PCDDs, PCDFs for Humans and for Wildlife. Environmental Health Perspectives, 106(12), 775]. Oµo1:1oo1, ouofo, TLµtj TEF Oµo1:1oo1, ouo(i, T1µtj TEF l\.1~EV~o-napa-01o~(vo, («PCDD») «napoµma µEn, OlO~IVo," PCB M~-op8o PCB M~-op8o PCB 2,3,7,8-TCDD 1,2,3,7,8-PeCDD 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD 0,1 PCB 77 0,1 PCB81 PCB 126 1,2,3,4,6,7,8HpCDD PCB 169 OCDD 0,0001 t.1~0V~O(j)OUp6.v1a («PCDF») 2,3,7,8-TCDF 0, 1 1.2.3.7.8-PeCDF 0,05 2,3,4,7,8-PeCDF 0,5 1,2,3,4,7,8-HxCDF 0, 1 1,2,3,6,7,8-HxCDF 0, 1 1,2,3,7,8,9-HxCDF 0, 1 2,3,4,6, 7,8-HxCDF 0, 1 Movo-op8o PCB PCB 105 PCB 114 PCB 118 PCB 123 PCB 156 PCB 157 + Movo-op8o PCB 0,0001 0,0001 0,1 0,01 0,01 0,0001 0,0005 0,0001 0,0001 0,0005 0,0005 5332 E<l>HMEPII THI KYBEPNHIEnI (TEYXOI .6.EYTEPO) 1,2,3,4,6,7,8HpCDF 1,2,3,4,7,8,9HpCDF OCDF 0,01 0,01 0,0001 PCB 167 PCB 189 0,00001 0,0001 LUVTOµoypacp[ec; nou XPrJOLµonoll,Sr]KQV : T = TeTpa ' Pe = ne­ vra, Hx = e~a, Hp = em6, 0 = oKTa, COD = x"-wpoot[3ev~ooto~[vri, GDF = x11.wpootl3ev~ocpoup6vto, CB = xll.wpootcpmvull.to. 3. i8VLK8<:; 5tm6!;8L<:; 3.1. npoowmK6 H 58LyµmoAJ"]lj.J(a nptn8L va npayµmonotdTOL an6 8TIL­ q:>opTtoµtva yLO TO OKOTIO OUTO KOTaAAJ"]AO 8L5LK8Uµ8VO aTOµa, ouµcpwva µe TLc; LO)(UOUOec; OLOTO!;etc;. 3.2. npo"i6v an6 TO ono(o Aaµf36vovTOL 5dyµma K688 napT(5a, J"] ono(a np6K8LTOL va 8!;8TOOT8l, OTIOT8A8l OVTLK8lµ8VO !;8XWPLOTl1c; 58LyµmOAf]lj.J(ac;. 3.3. Mfapa npoq:>uAa!;ric; nou nptn8L va Aaµf36vovTOL Km6 TI"] 5t6pK8LQ TJ"]c; 58LyµmOAf]lj.J(ac; KOL TJ"]c; np08TOL­ µao(ac; Twv 58tyµ6Twv 8pyaOTf]p(ou, npfo8L va >,.,aµf36vo­ VTOL npOCj)UA6!;8Lc;, npOK8Lµtvou va OTIO(j)8UY8TOL OTIOL0 511noT8 aMo(wari, ri ono(a µnopd va µnaf36M8L TJ"]V n8 PL8KTLKOTJ"]TO TWV 5LO!;LVWV KOL TWV nap6µ0LWV µ8 5to!;(v8c; PCBs, va sn:17p£60£l apvrrnK6. -rev ava> .. u-rtK6 npocrOtopt 0µ6 OUTWV 11 TJ"]V OVTLTipOOWTI8UTLKOTJ"]TO TOU OUVOALKOU 5dyµmoc;. 3.4. LTOLX8Lw5ri 5dyµaTO Km6 TO µtTpo TOU npaKTLKOu, TO OTOLX8LW5J"] 5dyµma np8TI8l va Aaµf36VOVTOL an6 5LO(j)Op8TLK6 oriµda TJ"]c; nap­ T(5ac; 11 TJ"]c; unonapT(5ac;. K688 nap8KKALOJ"] an6 TI"] 5ta5L­ Kao(a auT'l nptneL va Kmayp6cpeTOL OTO npaKTLK6 6nwc; npof3MnnOL OTO oriµdo 3.8. 3.5. napaoK8U11 Tou ouvoALKou 5dyµmoc; To ouvoALK6 5dvua >,.,auB6v8TOL µ8 TT] ouvtvwan 6Awv TWV OTOLX8LW5wv 58Lyµ6T~V. To f36poc;TOu np8TI8L va 8LVOL TOUA.aXLOTOV 1 kg, 8KT6c; 8QV 58V 8LVOL 5uvm6v, TI,X. OTJ"]V n8p(mwari nou 8X8L AJ"]q:>8d yta 58tyµmoAJ"]lj.J(a µ(a µ6vo OUOK8UOOLO. 3.6. Yno5ta(p80f] TOU ouvoALKOu 5dyµmoc; 08 8pyaOTJ"]­ ptaK6 5dyµma yta oKonouc; 8Myxou, 5LKOLwµmoc; 6oKJ"]­ aric; npooq:>uy11c; 115tOLTf]O(ac;. Ta 6µ0La 8pyaOTf]pLaK6 5dyµaTO nou npoop(i;oVTOL yta OKonouc; 8A8YXOU, QOKJ"]OJ"]c; npooq:>uy11c; 11 A6youc; 5LOLTJ"]­ o(ac;, Aaµf36VOVTOL an6 TO oµoy8VOTIOLJ"]µ8VO OUVOALKO 5dyµa, napouo(a 8Knpoownwv Twv Apµo5(wv Apxwv ot ono(8c; dvOL 8TILq:>opTLoµtv8c; µ8 TOV rn(oriµo 8A8YXO Tpo­ q:>(µwv. Ta 6µ0La 8pyaOTf]pLaK6 5dyµma OUOKWai;oVTOL, oq:>pay(i;OVTOL, oriµa(vOVTOL KOL ano8J"]K8UOVTOL 6nwc; npo­ f3Mn8TOL OTO oriµda 3.7 KOL 3.8 TOU nap6VToc; napapT11 µmoc;. LUVT6008TOL oX8TLK6 npaKTLK6 TO ono(o unoyp6 q:>8TOL an6 TO 6TOµa nou nap(OTaVTOL OTJ"] A11lJ.lri Twv oµo(­ wv 8pyaOTf]plOKWV 58Lyµ6TWV. Km6 TOAOLTIO TO 5dyµma YLO QOKJ"]OJ"] npooq:>uy11c; 115LOLTJ"]O(ac; 8!;8T6i;oVTOL ouµq:>w­ va µe TLc; LO)(UOUOec; 5tm6!;etc;. 3.7. 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ILO K688 58LyµOTOAJ"]lj.J(a, np8TI8L va ou­ VTQOOOVTOL npaKTLKQ 58LyµmOAf]lj.J(ac;, TO ono(a K08L­ OTOUV 5uvm11 TJ"]V avayvwptori, xwp(c; aµq:>tof311TJ"]OJ"], TJ"]c; napT(5ac; an6 TJ"]V ono(a 8X8L AJ"]q:>8d TO 5dyµa, KOL nptn8L va avayp6q:>8TOL ri J"]µ8poµriv(a KOL o T6noc; 58LY­ µmoAf]lj.l(ac;, Ka8wc; KOL Ka8e OAAJ"] ouµTIAf]pWµOTLK11 TIAJ"]poq:>op(a, ri ono(a µnopd va anof3d xp11mµri yta TOV OVOAUTl1 4. LX85La 58LyµOTOAJ"]lj.J(ac; H µt8o5oc; 58LyµmoAJ"]lj.J(ac; nou 8q:>apµ61;8TOL nptn8L va 8!;aoq:>aM1;8L OTL TO ouvoALK6 5dyµa dvOL aVTmpoownw­ TLK6 TJ"]c; napT(5ac; nou np6K8LTOL va 8A8YX8d. Apt8µ6c; TWV OTOLX8LWOWV 08Lyµ6.TWV LTJ"]V TI8p(mwori TOU y6AOKToc; KOL TWV 8AOLWV, yLO TO ono(a µnopd va 88wpri8d 585oµtvri µta oµoy8v11c; KO­ Tavoµ11 Twv 8V >,.,6yw npooµd!;8wv 08 µLO 585oµtvri nap­ T(5a, dvOL apK8T6 va AJ"]q:>8ouv Tp(a OTOLX8Lw5ri 5dyµaTO av6 napT(5a yLO TJ"]V 5J"]µLoupy(a TOU OUVOALKOU 5dyµa­ TOc;. nptn8L va y(vnOL avaq:>op6 OTov apt8µ6 TJ"]c; napT( 5ac;. ILO TO 6Ma npo"i6VTO, 0 8AaXLOTOc; apt8µ6c; OTOL­ X8LW5wv 58Lyµ6TWV TIOU np8TI8L VO AJ"]Cj)80UV OTTO TJ"]V napT(5a nptn8L va dvOL auT6c; nou avaq:>8p8TOL OTov n(­ vaKa 1. To ouvoALK6 5dyµa nou ouyK8VTpwv8L 6>,.,a TO OTOLX8LW 5ri 5dyµma npfo8L va dvOL TOUA.aXLOTOV 1 kg (f3Mn8 ori­ µdo 3.5). Ta OTOLX8Lw5ri 5dyµma nptn8L va txouv nap6 µ0Lo f36poc;. To f36poc; 8v6c; OTOLX8Lw5ouc; 5dyµmoc; npt­ TI8L va dvOL TOUA.aXLOTOV 100 ypaµµ6pta. To f36poc; TOU OTOLX8Lw5ouc; 5dyµmoc; 8!;apT6TOL an6 TO µty88oc; Twv owµmt5(wv OTJ"]V napT(5a. K688 nap8KKALOJ"] an6 TI"] 5ta 5tKao(a OUTl1 np8TI8L va KOTayp6q:>8TOL OTO npOKTLKQ nou npof3MnoVTOL OTO ariµdo 3.8. Luµq:>wva µ8 Ttc; 5tm6!;8tc; TTjc; An6cpacrijc; 97 /7 4 7 /EK TTjc; EniTponf]c;, TTjc; 27ijc; 0h.LW­ f3p(ou 1997, YLO TOV K08optoµ6 TWV 8TILTI85wv KOL TWV ou­ )(VOTl1TWV 58LyµmOAJ"]lj.J(ac; 6nwc; npof3MnoVTOL OTJ"]V 051"]­ y(a 96/23/EK TOU Luµf3ouMou (EE L 303/6.11.1997) µ8 oKon6 TJ"]V av(xvwori optoµtvwv oumwv KOL KOTOAo(nwv nou OTIOVTWVTOL 08 optoµtva /;WLKQ npo"i6VTa, TO µty88oc; Tou 5dyµmoc; yta TO auy6 K6TOc; dvOL TouMXLOTov 5w 58Ka auy6 (yta napT(58c; 6nou TO npoi6v 5tm(88TOL xuµa, Ka8wc; KOL YLO napT(58c; nou OTIOT8AOUVTOL an6 µ8µovw­ µtv8c; OUOK8UOOL8<:;, TILVOK8<:; 1 KOL 2). nlNAKAL 1 EMXLOToc; apt8µ6c; OTOLX8LW5wv 58Lyµ6TWV nou np8TI8l va >,.,aµf36voVTOL an6 K688 napT(5a Bapoc;n1c;nap1[oac; (m; kg) EA□XLDTDC: ap18µ6c; OTOIXC:IWOWV oe1yµ□TWV TIOU npin£1 va Aaµ~OVOVTQI < 50 50 ewe; 500 > 500 3 5 10 E<l>HMEPII THI KYBEPNHIEnI (TEYXOI ~EYTEPO) 5333 E6.v ri napT(5a anoTeAdTm an6 µeµovwµevec; auaKeua­ a(ec;, T6Te o apL8µ6c; Twv auaKeuamwv nou npeneL va ArJ­ cp8ouv yLa va anornMaouv TO auvoALK6 5dyµa 5(vernL OTOV n(vaKa 2. nlNAKAL2 ApL8µ6c; auaKeuamwv (OTOLX8Lw5ri 5dyµma) nou npe­ neL va Aaµf36.vovrnL yLa va anornMaouv TO auvoALK6 5dy­ µa, e6.v ri napT(5a anoTeAdTm an6 µeµovwµevec; auaKeu­ aafec; ApL8µ6c; GUGK8UQOLWV rj µovaowv ava nap1[oa 1 ewc;25 26 iwc; 100 > 100 ApL8µ6c; GUGK8UQOLWV rj µovaowv TI0U npim:L va Aflcp8ouv M[a auaKeuaa[a rj µovaoa nep[nou 5%, 1ouMxLmov Mo auaKeu­ aa[ec; rj µovaoec; nep(nou 5%, KQT' QVWTQTO 6pLO 0£KQ GUGK8UQGl8C: rj µovaoec; 5. Luµf3m6TrJTa TrJc; napT(5ac; 11 TrJc; unonapT(5ac; µe TLc; npo5Laypacpec; To epyaOTl1PLO eMyxou nou avaMeL TO epyaOTrJpLaK6 5dyµa nou npoop(i'.;ernL yLa TrJV ecpapµoy11 µeTPWV eKTe­ AearJc;, npeneL va enavaA6.f3eL TrJV av@uari, OTrJV nep(­ mwari nou TO Aaµf3av6µevo anoTeAeaµa TrJc; npwTrJc; av6.Auaric; dvm ALy6Tepo an6 20% K6.Tw an6 TO µeyLOTO en(ne5o 11 n6.vw an6 TO µeyLOTO en(ne5o KOL va unoAoy(i'.;eL TrJ µecrri TLµl1 Twv anoTeAeaµ6.Twv. H napT(5a y(vernL 5e­ KTl1, e6.v TO anoTeAeaµa TrJc; npwTrJc; av6.Auaric; dvm ne­ pLaa6Tepo an6 20 % K6.Tw an6 TO µeyLOTO en(ne5o, 11, 6rnv dvm avayKaiec; Mo avaMaeLc;, e6.v ri µeari TLµl1 auµµop­ cpwvernL µe TO aVTLOTOLXO µeyLOTO en(ne5o, 6nwc; op(i'.;ernL OTOV KaVOVL0µ6 (EK) apL8. 466/2001. nAPAPTHMA II nPOETOIMALIA TOY .t.ElrMATOL KAI AnAITHLEIL rlA TIL ME00.60YL ANM YLHL nov XPHLIMOnOIOYNTAI KATA TON EnlLHMO EAErXO TON EnlnE.t.ON TON .6I0::IN'ON (PCDD/PCDF) KAI TON nPOLLllOPILMO TON nAPOMOION ME TIL .6I0::INEL PCBs LE OPILMENA, TPO<l>IMA 1. LT6xoc; Km ne5(o ecpapµoy11c; OL anmT11aeLc; auTec; npeneL va ecpapµ61'.;0VTQL OTQV ava­ AUOVTQL Tp6cpLµa yLa Tov enfariµo eA.evxo Twv emne5wv TWV 5LOSLVWV [TIOAUXAWpLwµevec; 5Lf3evc;o-napa-5Los(vec; (PCDD) Km noAUXAWpLwµeva 5Lf3evi'.;ocpoup6.vLa (PCDF)] KQL TOV npoa5LOpLaµ6 TWV nap6µ0LWV µe TLc; ()LOSlVf:c; PCBs. 0 EAf:YXOc; yLa TrJV napoua(a 5LosLvwv OTa Tp6cpLµa µno­ pe( va 5Lesax8d µe µta OTpaTrJYLK11 nou ea nepLAaµf36.veL µLa avaAUTLK11 µe8o5o 5LaAoy11c; (screening) npoKeLµevou va enLA.eyouv eKdva rn 5dyµarn µe en(ne5a 5LosLvwv Km nap6µ0LWV µe TLc; 5Los(vec; PCBs nou dvm ALYOTepo an6 30-40 % K6.Tw an6 TO en(ne5o nou ev5LacpepeL 11 unepf3a(­ veL TO en(ne5o nou ev5Lacpepet. H auyKeVTpwari 5LosLvwv OTa 5dyµarn eKdva µe ariµaVTLK6. en(ne5a npeneL va npoa5LopLOTd / emf3ef3mw8d µe µLa emf3ef3mwTLKl1 µe8o 5o. OL avaAUTLKec; µe8o50L 5LMoy11c; (screening) dvm µe8o 50L nou xprimµonoLouVTm yLa TrJV av(xveuari TrJc; napou­ a(ac; ()LOSLVWV KOL nap6µ0LWV µe 5Los(vec; PCBs OTO en(ne 5o ev5LacpepoVToc;. OL µe8o50L auTec; 8XOUVTrJV LKaVOTrJTa enesepyaa(ac; µey6.AWV TIOOOTl1TWV 5dyµmoc; KQL XPrJOl­ µonoLOUVTQL yLa TrJ 8S8TaOrJ µey6.AOU apL8µou 5eLyµ6.TWV yta TrJV aveupeari Twv 5eLyµ6.Twv µe m8avwc; 8eTLK6 ano­ TEAeaµa. 'Exouv axe5LaOTd eL5LK6. yLa TrJV anocpuy11 ljJeu 5wc; apVrJTLKWV anOTf:AeCTµO.TWV. {")1 µ6An;a;:.f"'\I c-n1(3c-f3nlr,,n17~ c-l\/rtl µ6An;.:.f"'\I TTl"'\11 nnp6x o• 1\/ nA11peLc; 11 auµnArJpwµmLKec; TIArJpocpop(ec; nou 5(vouv TrJ 5UVQTOTrJTa, OL 5Los(vec; KQL Ta nap6µ0La µe 5Los(vec; PCBs va TaUTOTIOLOUVTQL KQL va npoa5Lop(i'.;OVTQL TIOOOTLKO. µe aacp11veLa OTO en(ne5o nou ev5LacpepeL. 2. IOTOpLKO EneL511 rn nepL[3aMOVTLK6. Km f3LOAOYLK6. 5dyµma (au­ µnepLA.aµf3avoµevwVTwv 5eLyµ6.TwVTpocp(µwv) yevLK6. ne­ pLexouv auv8ern µdyµma 5Lacp6pwv oµoeL5wv oumwv TrJc; oµ6.5ac; Twv 5LosLvwv, avamux8rJK8 rJ evvoLa Twv au­ VTeAeOTwv TOSLK11c; Lao5uvaµ(ac; (TEFs) wOTe va 5LeuKo­ Auv8d l'l asLoMyriari TOU KLV5uvou. OL OUVT8A80T8c; TEFs 5rJµLoupy118rJKav yLa va eKcpp6.aouv TLc; auyKeVTpwaeLc; TWV µeLyµ6.TWV TWV 2,3, 7,8-UTIOKQTf:OTrJµevwv PCDDs KQL PCDFs, KOL np6acpma, opLaµevwv µri-op8o KOL µovo-op 80 unoKmeOTriµevwv an6 XAWpLo PCBs (non-ortho and mono-ortho chlorine substituted PCBs) µe 5paOTLKOTrJTa nap6µ0La µe auT11 Twv 5LosLvwv ae TOSLK6. Lao5uvaµa (TEQ) 2,3, 7,8-TCDD (f3Mne unoariµdwari 1 TOU napapT11 µmoc; I). OL auyKeVTpwaeLc; Twv en( µepouc; oumwv ae K6.noLo 5e 5oµevo 5dyµa noManAam6.1'.;oVTm µe Tov aVT(OTOLXO au­ VT8Af:OTl1 TEF Km OTrJ auvexeLa a8po(i'.;oVTm yta va unoAo­ YLOTeL rJ OALK11 OUYKEVTpWOrJ TWV nap6µ0LWV µe TLc; 5LOSL­ vec; evwaewv, eKcppaaµevri ae TEQs. H f:VVOLa TOU «avwTaTOU op(ou auyKeVTpwaric;» anmTd TrJ XPrJOLµono(riari TOU op(ou TOU TIOOOTLKOU npoa5LOPL­ aµou yLa TrJ auµf30A11 K6.8e µri noaoTLK6. npoa5LopLaµevric; oµoeL5ouc; oua(ac; OTO TEQ. H f:VVOLa TOU «KaTWTQTOU op(ou auyKeVTpwaric;» anmTd TrJ xprimµonofriari Tou µriMv yta TrJ auµf30A11 K6.8e µri no­ aoTLK6. npoa5LopLaµevric; oµoeL5ouc; oua(ac; OTO TEQ. H 8VVOLa TOU «µeaou op(ou auyKEVTpwaric;» anmTd TrJ xprimµono(riari TOU µLOOU TOU op(ou TOU TIOOOTLKOU npoa 5LOpLaµou yLa TOV UTIOAOyLaµ6 TrJc; auµf30A11c; K6.8e µri no­ C"OTtK6. npocrOtoptcrµ8vr7c; oµoetOoUc; oucr(ac; crro TEQ. 3. AnmT11aeLc; 5Laacp6.A.Laric; noL6Trirnc; nou npeneL va TrJ­ pouVTm yta TrJV npoeTOLµaa(a Tou 5dyµmoc; • npenf:L Va Aaµf36.VOVTQL µeTpa yta TrJV anocpuy11 TrJc; 5LaOTaupouµevric; emµ6Auvaric; ( cross-contamination) ae K6.8e OT6.5LO TrJc; 5La5LKaa(ac; 5eLyµmOArJljJ(ac; KQL av@u­ aric;. • Ta 5dyµaTa npeneL va ano8rJK8UOVTm Km va µeTacpe­ poVTm ae 5oxda an6 yuaA(, Mouµ(vLo, noAunponuMvLo 11 noAum8uMvLo. npeneL va acpmpouVTm rn fxvri aK6vric; xapTLOU an6 TOV nepL8KTrJ TOU 5dyµmoc;. Ta yu6.A.LVa OKf:UrJ npeneL va senMVOVTQL µe 5LaMrnc; nou exouv nporiyouµevwc; eAeyxSd yLa TrJV napoua(a 5LosLvwv. • H ano811Keu0rJ Km ri µerncpop6. Twv 5eLyµ6.Twv npeneL VQ ()Lf:SO.Yf:TOL KQTO. TpOTIO WOT8 VQ 5LaTrJp8lTOL rJ QK8pOL6 TrJTa TOU 5dyµmoc; TOU Tpocp(µou. • Ecp6aov ev5dKvurnL, K6.8e epyaOTrJpLaK6 5dyµa npe­ neL va Me8ernL Km va avaµeLyvuernL ev5eAexwc; xprimµo­ noLwVTac; µLa 5La5LKaa(a nou exeL ano5eLx8d 6TL emTLiy­ x6.veL TrJV TIAl1Pl'l oµoyevonofriari (n.x va 5Lanepv6. eva K6 0KLvo µeye8ouc; onwv 1 mm) Km rn 5dyµma npeneL va SrJPOLVOVTOL npLV QTIO TrJV O.Af:OrJ, QV rJ TI8pL8KTLKOTrJTO 08 uypaa(a dvm noM uljJrJA.11. 5334 E<bHMEPII THI KYBEPNHIEnI (TEYXOI .aEYTEPO) • npem:L va 8KT8A.8lTQL av6ALICJr] TLicpAOU oefyµmoc; µe TT]V npayµmono(T]OT] TOLI OLIVOA.OLI TT]<:; avaALITLK'lC: OLaOL­ Kaa(ac; napaAefnovrnc; µ6vo TO oefyµa. • To l36poc; TOLI oefyµmoc; TIOLI XPT]OLµOTIOLf:lTQL yta TT]V EKXLIALOTJ npeneL va efvm apKeT6 yta va nAripo( TLC: anmTfJ­ aetc; 6aov ocpop6 TTJV eu0La8ria(o. • Yn6pXOLIV noAAec; LKaVOTIOLT]TLKec; f:LOLKec; oLaOLKaa(ec; npoeTOtµaa(ac; oefyµmoc;, no LI µnopouv va xprimµonOLTJ 8ouv yta rn LITIO esernari npo"i6vrn. OL OLaOLKaa(ec; npeneL Va 8TILKLipC1lVOVTQL auµcpwva µe TLC: OL88VWC: aTIOOf:KTec; Ka­ T8U8LIVT'lPL8<:; ypaµµec;. 4. AnmTfJaetc; yta rn epyamfJpta • Tn c-pynmY)pin np6nc-1 un nnni5\c,11,n11'1n11uT17u nnn;;;."f"Tl"] µtac; µe86oOLI OTO eupoc; TWV emneowv OLiyKeVTpWarJC: noLI evotacpepet n.x. 0,5x, 1x Km 2x cpopec; To en(neoo ev­ otacpepoVToc; µe evav anooeKT6 OLIVT8A.80T'l OLaKuµavaric; yta enavaAaµl3av6µevec; avaMaetc;. fta Ta AemoµepfJ mOLxefa Twv KPLTT]p(wv anoooxfJc; l3Mne ariµefo 5. • To 6pLO TOLI TIOOOTLKOU TipOOOLOpLaµou yLa µLa µe8o­ OO eml3el3o(waric; npeneL vo dvOL mo eupoc; TOLI ev6c; ne­ µmoLI nep(noLI TOLI emneooLI evotacpepoVToc;, wme va otaacpaMi;nm 6TL OL anooeKTo( OLIVTeAemec; µernl3AT]T6 TT]rnc; TIAT]pOUVTQL OTO eupoc; TOLI emneoOLI f:VOLacpepo­ VTO<:;. • OL TQKTLKec; OOKLµec; TLicpAou oefyµmoc; KQL rn netp6 µma eµl30Ataaµou µe yvwmfJ noa6TT]Ta, Twv oetyµ6Twv fJ ri ov6ALIOTJ Twv oetyµ6Twv eMyxoLI (Km6 npoT(µriari, ecp6 aov dvm oLa8emµo, mmonotriµevoLI LIALK6 avacpop6c;) npeneL va eKrnAouVTm we; µeTpa eawrnpLK'lC: oLaacp6AL­ aric; TT]<:; TIOLOTT]Ta<:;. • H emTLIX'lC: aLIµµeTOX'l ae otepyamriptaK6 npoyp6µ­ µma TIOLI asLOAOVOUV TT]V m6pK8La TWV epyaOTT]plWV f:l­ VQL O KaMrnpoc; Tp6noc; an6oeLsTJC: TT]<:; LKaVOTT]TQC: yLa f:L­ OLKec; avail.uaetc;. Om6ao, ri emTLIX'lC: aLIµµeTOX'l ae otep­ yamriptaK6 npoyp6µµma, 6aov acpop6 n.x. oefyµarn eo6cpoLic; fJ anoxeTeuaewv oev anooetKvuet Km' av6yKTJ TT]V LKOVOTT]TO KOL ITTOV TOµeo TWV 08Lyµ6TWV TWV Tpocp(­ µwv fJ Twv i;woTpocpwv noLI napoLim61;oLiv xaµT]MTepa m(neoa µ6ALIVarJC:- LLivmwc;, ri aLivexfJc; aLIµµeTOX'l ae OLepyaOTT]pLaK6 npoyp6µµarn yLa TOV npoaoLOpLaµ6 TWV OLOSLVWV KQL TWV nap6µ0LWV µe TLC: OLOs(vec; PCBs ae LIA.L­ KQ aVT(OTOLXa µe TLC: /;WOTpocpec; / Tp6cptµa f:lVQL LITIOXP8W­ TLK'l. • LUµcpwvo µe TLC: OLOT6setc; TT]<:; Ooriy(oc; 93/99/EOK, TO epyamfJpta npenet va otammeuoVTm an6 avayvwptaµe­ voLic; opyavtaµouc; auµcpwva µe Tov Ooriy6 ISO 58 wme va esaacpaMi;ernL OTL rn epyamfJpta ecpapµ6i;OLIV µe86 00LIC: otaacp6Ataric; TTJC: not6TT]rnc;. H otan(meuari Twv ep­ yamrip(wv npenet va npayµmonotefTm auµcpwva µe TO np6TLino ISO /IEC/17025: 1999. 5. AnOLT'l08LC: TIOLI npeneL VO TT]pef µLa avaALITLK'l otaoL­ Kaa(a yLa TLC: OLOs(vec; KQL rn nap6µ0La µe OLOs(vec; PCBs BamKec; anmTfJaetc; yLa TT]V anoooxfJ TWV OLaOLKamwv av6ALIOTJC:: • Ylj.JTJA'l eumaeria(a Km xaµriM 6pta av(xveuaric;. 'Oaov acpop6 rn PCDDs Km rn PCDFs, TO 6pto av(xveuaric; np8TI8L va f:lVQL TT]<:; TOSTJC: TWV TILKOypaµµap(wv TEO ( 10 12g) f:SOLT(oc; TT]<:; ariµoVTLK'lC: TOSLKOTT]Tac; optaµe­ vwv an6 TLC: evwaetc; aLITec;. rvwp(i;oLIµe 6TL rn PCBs eµ­ cpav(i;oVTm ae LiljJTJAOTepa m(neoa an6 6TL rn PCDDs Km Ta PCDFs. na T(c; neptaa6Tepec; oµoetodc; oLia(ec; PCBs, ri eLimaeria(a mo cp6aµa Twv vavoypaµµap(wv ( 10' g) d­ vm fJori mapKfJc;. Om6ao, yta TT] µeTpTJarJ Twv mo TOsLKwv nap6µ0LWV µe TLC: otos(vec; oµoetowv OLIOLWV PCBs (Lo(wc; TWV µT]-Op8o LITIOKQTf:OTT]µeVWV OµOf:LOWV OLIOLWV) (non,­ ortho substituted congeners) npeneL va emTUyxaveTm T] (ota eumaeria(a 6nwc; Km yta rn PCDDs Km rn PCDFs. • Ylj.JT]A'l 8KA8KTLKOTT]TQ (eseLOlK8UarJ). Ta PCDDs, TQ PCDFs KOL TO nop6µ0Lo µe TLC: OLOs(vec; PCBs npeneL VO otaKp(voVTm an6 TLC: ooec; evwaetc;, no LI f:KXLIAli;oVTm µa­ l;( Km oL ono(ec; m8avwc; (oL evwaetc; noLI napeµnoo(i;oLiv) va napeup(aKoVTm ae aLiyKeVTpwaetc; -ewe; Km optaµevec; T6setc; µeye80Lic; LiljJT]AOTepec; an6 f:Kdvec; TWV npoc; av6 ALIOT] OLIOLWV TIOLI evotacpepOLIV. 1La TLC: µe8600LIC: aeptac; xpwµmoypacp(ac; / cpaaµmoµeTp(ac; µ61:;ac; (GC/MS) dvm u.vuynu;u. tJ,lU Olu.'f'Vt,JVI lV~I 1v1 I tJ,C,lU~~ lUJV olU.'f'~t-'Wv Vt,AV f:LOWV OLIOLWV, 6nwc; µernsu TWV TOSLKWV (n.x. TWV 08Kae­ m6 2,3,7,8-LITIOKQTeOTT]µevwv PCDD KQL PCDF KQL TWV nap6µ0LWV µe TLC: OLOs(vec; PCBs) KQL TWV oowv oµoeLOWV oLimwv. Ot l3toAoytKec; ooKtµaa(ec; npeneL va dvm ae Semi va npoaotop(i;oLIV TLC: TLµec; TEO 8TILA.8KTLK6 we; TO 6SpOL­ aµa Twv PCDDs, Twv PCDFs Km Twvnap6µ0Lwv µntc; oto­ s(vec; PCBs. • Ylj.JT]A'l aKp(l3eta (opS6TT]Ta Km mm6TT]Ta). 0 npoa­ otoptaµ6c; npeneL va napexet µLa eyKLIPTJ f:KTlµT]CJr] TT]<:; aAriSouc; aLiyKeVTpwaric; ae eva odyµa. H LiljJTJA'l aKp(l3eta (aKp(l3eLa TTJC: µeTpTJaric;: ri eyyuTT]Ta TTJC: aLIµcpwv(ac; µe­ rnsu TOLI anoTeAfoµmoc; TT]<:; µeTpT]arJC: KQL TT]<:; aAT]Souc; fJ anoooSdaac; TLµfJc; TOLI µeTpT]TfoLI) dvm avayKa(a yta va anocpeuxSe( ri an6pptlj.JTJ TOLI anoTeAfoµmoc; TTJC: av6 ALiarJC: TOLI odyµmoc; noLI eAfJcpST] 136ari µri mapKouc; astomm(ac; (poor reliability) YLa TT]V f:KTlµT]CJr] TOLI TEO. H aKp(l3eLa 8Kcpp6/;8TOL we; Op80TT]TO (otacpop6 µernsu TT]<:; µearic; TtµfJc; noLI µnpfJSTJKf: yLa µta avaALITfo oLia(a ae eva TILOTOTIOLT] µevo LIALKO KQL TT]<:; TILOTOTIOLT] µeVT]c; TLµfJ TT]<:;, 8Kcppaaµevri we; noaom6 TT]<:; TLµfJc; aLIT'lC:) KQL TILOTOTT]TQ (TJ mm6TT]Ta aLivfJSwc; LinoAoy(i;nm we; TLITILK'l an6KALarJ, aLIµneptAaµl3avoµevwv TTJC: mavaAT]lj.Jtµ6TT]rnc; Km ava­ napaywytµ6TT]rnc;, Km npoaotop(i;et TTJV eyyuTTJTa TTJC: OLIµcpwv(oc; µeTasu TWV anOT8A.80µ6TWV TIOLI eAfJcpSTjaav µe TT]V ecpapµoyfJ TT]<:; netpaµmLK'lC: OLaOLKaa(ac; apKeTec; cpopec; Lin6 npoKaSoptaµevec; aLivSfJKec;). Ot avaALITLKec; µeSooOL OLaAoyfJc; µnopouv va neptAaµ­ l36VOLIV l3toAoytKec; ooKLµaa(ec; Km µeS600Lic; GC/MS. Ot µeSooOL eml3el3a(waric; dvm µeSooOL LiljJTJAfJc; 8UKp(vetac; aeptac; XPWµmoypacp(ac; / LiljJTJAfJc; euKp(vetac; cpaaµmo­ µeTp(ac; µ61:;ac; (HRGC/HRMS). Ta aK6AoLISa KptTfJpta npenet va TTJpOuVTm OTT] OLIVOAL­ K'l TLµfJ TEQ : noao016 l!Jwow~ apv~TIKWV Op86T~TQ CV Mt80001 i51a/i.oy~~ (screening) Mt8oi501 rn1BEBa(wcrri~ < 1% < 30% 20 tw~ + 20 % <15% 6. EtoLKec; anmTfJaetc; yta µeS600Lic; GC/MS no LI npeneL va TT]pOUVTQL yLa TT]V esernari OLaAoyfJc; (screening) 'l yLa MyoLic; eml3el3a(waric;. • H npoaSfJKTJ eawTeptKwv npoTunwv PCDD/F LITIOKa­ Temriµevwv µe XAWplO OTLC: Secrete; 2,3,7,8 µe LOOTOTILK'l emafJµavari 13C (Km TWV 80WT8plKWV npOTUTIWV TWV na­ p6µ0LWV µe TLC: OL0SlV8<:; PCBs µe LOOTOTILK'l emafJµOVCJr] "C, av np6KeLTm va npoaotoptmouv nap6µ0La µe TLC: oto­ s(vec; PCBs) npeneL va npayµmonOLT]Sd noM vwp(c; OTT]V ECl>HMEPII THI KYBEPNHIEnI (TEYXOI ~EYTEPO) 5335 OPX'l 'l KOTO Tr]V evapsTJ TT]<:; µE8ooou OVOAUCJT]<:;, OT]AOO'l nptv ano TTJV EKXUALOTJ npoKELµevou va EmKupwSd ri ava 11.uTLKrJ otaotKaa[a. T ou11.6xtmov µta oµoetor'1c; oua[u ytu Ka8Eµ(a ano Ttc; oµo>-..oyEc; oµaoEc; PCDD/F Twv TETpa­ ewc; OKTO-XAWpLwµevwv oµo>-..oywv oµaowv (KOL TOUAOXL­ OTOV µLO oµOELO'lc; ouo(a KOL YLO K08Eµ(a ano Tlc; oµo>-..oyEc; oµaoEc; TWV napoµmwv µE Tl<:; OlOSLVEc; PCB, av npOKELTOl va npoOOLOplOTOUV napoµma µE OLOSLVE<:; PCB) npenEL va npomESd [ EvaMaKTLK6, Tou>-..axtmov µLO oµoEtofJc; ouo(a yta K68E oµaoa LOVTwv yLO cpaaµmoaKOn[a µ6l;ac; Kma­ ypacpfJc; ETILAEyµevwv LOVTWV (mass spectrometric se­ lected ion recording function) nou XPT]atµonotdTOL yta TTJV napaK0Aou811CJT1 Twv PCDD/F KOL Twv napoµmwv µE oto­ s[vEc; PCBs]. Yn6pXEL oacpfJc; npOT[µT]OT], Lo[wc; OTT]V nEp[­ ITTWOT] Twv µE8oowv Eml3El3a(wCJT]c;, OTT] XPrimµono(riori KOL Twv oEKOEm6 EOWTEPLKWV npoTunwv PCDD/F unoKa­ TEITTT]µevwv µE XAWpLO ITTL<:; 8eOEL<:; 2,3,7,8 µE LOOTOTILK'l EmafJµavori 13C KOL Tou ouvo>-..ou Twv owoEKa EOWTEPLKwv npOTUnWV TWV napoµOLWV µE TL<:; OLOSLVE<:; PCB µE LOOTOTIL­ K'l EmofJµavori 13C (av npoKELTOL va npoootoptmouv na­ poµma µE otos(vEc; PCB). npenEL en(CJT]c; va npoOOLOplOTOUV Ol oXETLKO( OUVTEAE­ mec; anoKptCJT]c; yLO EKetvEc; Ttc; oµoEtodc; ouo(Ec; yta Ttc; uI tu[i:;i; iSi:;v I lf.JUU L [8i:; L UL KUVt;vu uvu}\uyu I If.JU L uI LU µi:; tuu­ TOTILK'l EmofJµavori 13C, µE TT] XPrimµono(riCJTJ Twv KOTOA­ ATJAWV oLO>-..uµ6TWv l3a8µ0-voµT]CJT]c;. • rta TO Tpocptµa (j)UTLK'l<:; npoeAeuCJT]c; KOL TO Tpocptµa l;WLK'l<:; npoe>-..euoric; nou nEptexouv ALYOTEPO ano 10 % Al­ noc;, TJ npoo8fJKTJ TWV WWTEplKWV npoTunwv elVOL uno­ XPEWTLK'l npLV ano TT]V EKXUALCJT]. ILO TO TpOcpLµa l;WLK'l<:; npoeAeuCJT]c; nou nEptexouv nEptoooTEPO ano 1 o % Mnoc;, TO wwTEptK6 npoTUna µnopouv va npomE8ouv etTE nptv ano TT]V EKXUALCJT] elTE µETO TT]V EKXUALCJT] TOU Mnouc;. npe­ nEL va npayµmonot118d Km6M11>-..oc; eAEYXOC. aC:tomm(ac; (entKupwCJTJ) TT]c; anorn>-..wµmLKOTTJTOc; TT]c; EKXUALCJT]c;, ava>-..oya µE TO m6oto mo ono(o Eto6yoVTOL EOWTEpLK6 npoTUna KOL ava>-..oya µE TO av Ta anornMoµma avacpe­ poVTOL µE l36ori TO npo'iov fJ TO Mnoc;. • nptv ano TT]V OVOAUOT] GC/MS, npenEL va npOOTE8ouv eva fJ Mo npoTUno(-a) QVOKTT]CJT]c; (unoKOTQOTQITTO). • 0 eAEYXoc; av6KTTJCJT]c; dvOL avayKa(oc;. 1La TLc; µE8o­ oouc; Eml3El3a(woric;, ot avaKT'lOELc; Twv µEµovwµevwv EOWTEplKWV npOTUnWV npenEL VO KUµOLVOVTOL OTO EUpoc; Tou 60 ewe; 120 %. XaµT]MTEpEc; fJ UlJ.ITJAOTEpEc; avaKTfJ­ uu-; YLU µi:;µuvwµt;Vt;'-; uµuuOt;l'-; UUUlt;'-;, LOlW'-; Uf.JLUµt;VWV Ema- KOL OKTO-XAWptwµevwv OLl3Evl;ooLOSLVWV KOL OLl3Ev­ l;ocpoupav(wv, dvOL anooEKTec; uno Tov opo OTL ri ouµl30 A'l TOuc; OTT]V TLµfJ TEQ OEV unEpl3a(vEL TO 10 % TT]<:; ouvo­ AlK'l<:; TLµfJc; TEQ (l3amoµevri µovo OE PCDD/F). ILO Tl<:; µE­ Sooouc; ota>-..oyfJc; (screening), ot avaKTfJoEtc; npenEL va KUµa(VOVTOL OTO EUpoc; TOU 30 ewe; 140 %. • npenEL va npayµmonotetTOL otaxwptoµoc; Twv otost­ vwv ano Ttc; napEµl3aMoµEvEc; x>-..wptwµevEc; EvwoEtc;, onwc; TO PCBs KOL Ol XAWpLwµevOL Ol(j)OLVUALKO( OL8epEc; µE Tl<:; KOTOAAT]AE<:; XPWµmoypacp(ac;TE)(VLKec; (KOTO npOT(µT]­ CJT] µE mfJ>-..ri: florisil, a>-..ouµ(vac; fJ/KOL 6v8paKa). • O otaxwptoµoc; Twv tooµEpwv µE aepta XPWµmoypa­ cp(a npenEL va dvOL enapKfJc; ( < 25 % ano KopucpfJ OE KO­ pucpfJ µETOSU 1,2,3,4, 7,8-HxCDF KOL 1,2,3,6, 7,8-HxCDF). • 0 npoootoptoµoc; npenEL va npayµmonotT]Sd ouµ­ cpwva µnT] µe8ooo TT]<:; EPA 1613 ava8EwpT]OT] B: «Tetra­ through octa-chlorinated dioxins and furans by isotope di­ lution HRGC/HRMS» fJ K6nota 6MT] µE tooouvaµa KPLT'l­ pLO anooooric;. • H OLO(j)Opa µETOSU TOU OVWTOTOU Emneoou KOL TOU KO­ TWTOTOU Emneoou OUyKeVTpWCJT]<:; OEVnpenEL VO unEpl3a(­ VEL TO 20 % yta Ta Tpocptµa µe emµo11.uvari otoC:[vric; nep[­ nou 1 pg WHO-TEQ/g Mnouc; (l3amoµevri µovo OE PCDD/PCDF). f""ta TO Tpocptµa µE xaµri>-..fJ nEpLEKTLKOTTJTO OE Amap6 npenEL va LoXUOUV Ol LOLE<:; anOLT'lOELc; YLO TO en(­ nEOQ Emµo>-..uvCJT]c;, nEp(nou 1 pg WHO-TEQ/g npo'ioVToc;. rta xaµriMrnpa en(nEoa Emµo>-..uvCJT]c;, nx 0,50 pg WHO­ TEQ/g npo'iOVToc;, TJ Olacpop6 µETOSU QVWTOTOU op(ou ou­ yKeVTpwCJT]c; KOL KOTWTEpou op(ou ouyKeVTpworic; µnopd VO l3p(OKETOL OTO EUpoc; TOU 25 ewe; 40 %. 7. Me8oom av&uoric; ota>-..oyfJc; (screening) 7. 1 Etcrayt•JY'l LltacpopETLKec; ava>-..unKec; npooEyy(oELc; µnopouv va OLESOX80UV µE TT] XPT]OLµOnO(T]OT] µtac; OVOAUTLK'l<:; µE80 00U ota>-..oyfJc; (screening): µta Ka8apfJ npooeyytCJT] ota­ >-..oyfJc; (screening) KOL µta noooTLKfJ npooeyyLCJT]. npooeyyLCJT] OlOAoyfJc; H anoKplOT] TWV OELyµOTWV ouyKplVETOl µE OUT'l Evoc; odyµmoc; avacpopac; OTO ETILTIEOO EVOLOcpepoVToc;. Ta odyµma µE anoKpLCJTJ µtKpOTEPTJ ano TTJV avacpop6 8Ew­ pouVTOL apVT]TLK6, EVW EKdva µE Ulj.lT]AOTEPTJ anoKpLOTJ unoma YLO 8ETLKO. Ot anOLT'lOELc; : • LE K08E OELPO OOKLµwv npenEL va ouµnEplAT]cpSE( eva TU(j)AO odyµa KOL eva odyµa avacpopac;, nou EKXUALi:;OVTOL KOL ooKtµ6l;oVTOL TOUToxpova uno Ttc; (otEc; ouv8fJKEc;. To odyµa avacpopac; npenEL VO napoumal;El µLa oacpwc; UljJT]­ AOTEpT] anoKplCJT] OE ouyKplOT] µE TO TU(j)AO. • npenEL va ouµnEpLATJcpSouv npoo8ETO odyµma ava­ cpopac; 0,5x KOL 2x cpopec; TO en(nEOO EVOLacpepoVToc; WITTE va anooELXTd ri opSfJ anoooCJT] TT]c; ooKtµao(ac; mo Eupoc; TOU EVOLacpepoVToc; yta TOV eAEYXO TOU Emneoou nou EV­ otacpepEL. • KaT6 Tri UOKLµi'1 Q/1./1.WV unourpwµ6TWV, npem::L va anoOELXfel T] KOTOAAT]AOTT]TO TWV OELyµ6Twv avacpopac;, Km6 npoT(µriori µE To va ouµnEpLATJcp8ouv odyµma nou cpa(vETOL anoTo HPGC/HPMS va nEptexouv eva en(­ nEoo TEO napoµmo µE auTo Tou odyµmoc; avacpopac; 'l aMtwc; eva TU(j)AO odyµa Eµl30Ataoµevo OTO En(nEOO OUTO. • Ka8wc; oEv µnopouv va XPrimµonotriSouv wwTEPLK6 npoTUna OE l3LOAOYLKec; OOKLµao(Ec;, Ol OOKLµec; ETIOVOAT]­ ljJLµOTT]TOc; ELVOL nOAU CJT]µOVTLKec; npOKELµevou VO ano­ KTT1801'1v n>-npocpop(r.c; CJXE'.TLKO pr. Tl'lV TUTTLKT] nn6KALCTTl OTO nAa(ma µLa OELpac; OOKLµwv. 0 OUVTEAEITTfJc; OlOKU­ µavCJT]c; npenEL va dvOL K6Tw ano 30%. • ILO Tl<:; l3LOAOYLKec; OOKLµao(Ec; npenEL va OplOTOUV Ol EVWOEL<:;-ITTOXOL, Ol meavec; napEµnoo(OELc; KOL TO µeyLITTO avEKT6 en(nEoa Tucp>-..ou. nooOTLK'l npooeyyLOT] H noOOTLK'l npooeyyLCJT] anOLTEl TT] XP'lCJTJ OELpac; apOL­ wµevwv npoTunwv, Ka8aptoµo KOL µfapT]CJTJ EL<:; om>-..ouv fJ TPLTIAOUV, K08wc; KOL EMyxouc; TU(j)AOU KOL OVOKTT]CJT]c;. To anoTeAwµa µnope( va EKcppal;ETOl OE TEQ, uno8eTOVTac; OTL Ol EVWOELc; nou elVOL unEu8uvEc; yta TO afJµa OVTLOTOL­ xouv ITTTJV apxfJ Twv TEQ. AuTo µnope( va npayµmonmri­ Sd µE TT] XPrimµono(riCJTJ npoTunou otaMµmoc; TCDD (fJ npOTunou ota>-..uµmoc; µ[yµmoc; otoE;[vric;/cpoupav[ou) yta TT] oT]µtoupy(a µLac; Kaµnu>-..ric; l3a8µovoµT]CJT]c; yta TOV uno­ >-..oytoµo Tou Emneoou TEO mo EKXUALoµa KOL ouvEnwc; OTO odyµa. AUTO OTT] OUVeXELO OLOp8WVETOL yta TO EnlnE­ oo TEQ nou uno>-..oy(l;ETOL yta eva TucpM odyµa (yta va ATJ­ cp8ouv UnOljJT] Ol seVE<:; npooµ(SEL<:; nou npoepXOVTOL ano 5336 E<l>HMEPII THI KYBEPNHIEnI (TEYXOI ~EYTEPO) TOuc; otaMn:c; Km TLC: xriµtKtc; oua(8c; nou xprimµonouiSri­ Kav), KQL yLa Tf]V aVOKTf]OrJ (nou UTIOAoy(i'.;8TQL an6 TO rn(­ TI800 TEO a8 o8fyµa 8Mvxou not6Trirnc; KoVT6 mo 8nfn8 oo 8VotacptpoVToc;). E(vm avayKa(o va ariµrnu8d 6TL Tµtj­ µa TrJC: 8µcpavouc; anwA8tac; av6KTrJaric; µnopd va ocpdA8Tm a8 rn(opaaric; unompwµmoc; 17/Km a8 oLacpo­ ptc; µ8TaSU TWV TLµwv TEF ITTLC: l3LOAOYLK8C: OOKLµaa(8c; KQL TWV 8TilOf]µWV TLµwv TEF TIOU 6pL08 0 nOY. 7.2. AnmT'708LC: yLa TLC: µ886oouc; av6AUOrJC: nou XPrJOL­ µonOLOLJVTQL yta otaAoytj (screening) • Ot µtSooOL av6Auaric; GC/MS Km ot l3toAoytKtc; ooKL­ µaaf8c; µnopouv va xprimµonOLrJ8ouv yta otaAoytj (e:rrooning). r1n Tic; µc-AArtn11c; ~r;ri.A~ np6nc-1 \In ILU"'1\/f"\TTf"\I OLJVTQL Ol anmT'708LC: 6nwc; op(i'.;OVTQL OTO ariµdo 6. rta TLC: l3LOAOYLK8C: ooKtµaa(8c; µ8 l36ari Kunapa (cell based bioassays) op(i'.;oVTm 8LoLK8C: anmT'708LC: mo ariµdo 7.3 KQL yLa TLC: l3LOAOYLK8C: OOKLµaa(8c; µ8 l36ari OUOK8Uaa(8c; (kit-based bioassays) op(i'.;oVTm 8LOLK8C: anmTtja8LC: mo ariµdo 7.4. • LTotxda yLa Tov apt8µ6 Twv lj.18uowc; 88TLKWV KOL lj.18U­ owc; apVf]TLKWV anOT8AWµOTWV 8v6c; µ8y6AOU OUVOAOU 08Lyµ6TWV KOTW KQL n6vw an6TO µtyLITTO 8TilTI800 '7 TO rn(­ TI800 opOOrJC: 8lVQL avayKa(a 08 auyKplOf] µ8 Tf]V TI8pl8KTL­ KOTf]TQ a8 TEO 6nwc; npoaotop(i'.;8Tm µ8 µta rnLl38l3mwTL­ K'7 µt8ooo av6AUOf]c;. Ta npayµmLKO lj.18Uowc; apvf]TLKO noaom6 nptn8L va dvm K6Tw an6 1 %. To noaom6 TWV lj.lwowc; 88TLKWv o8tyµ6Twv nptn8L va dvm apK8T6 xaµri­ A.6 WITT8 ri XP'lOrJ TOU µfoou TrJC: otaAoytjc; (screening) va Kmamd XP'lOLµf]. • Ta 88TLK6 anOT8Afoµma np8TI8L n6VTa va 8TILl38l3mw­ VOVTQL µ8 8ml38l3mwTLK'7 µt8ooo av6Auaric; (HRGC/ HRMS). EmnMov, rn odyµma an6 tva wpu cp6aµa TEO npfo8L va 8ml38l3mwvoVTm µ8 µ886oouc; HRGC/HRMS (nep(nou 2 lwc; 10 70 -rwv apv1TnKWv i5eryµcirwv). Ol nA.i7 pocpop(8c; oX8TLKQ µ8 Tf]V oX80rJ µ8TaSU TWV aTIOT8AWµ6 TWV TrJC: l3LOAOYLK'7c; OOKLµaa(ac; KQL TWV anOT8AWµOTWV HRGC/HRMS npfo8L va Ka8(maVTm ota8tmµ8c;. 7.3. EtoLKtc; anmTtja8LC: yta l3LOAOYLK8C: OOKLµaa(8c; µ8 136ari Kunapa • Km6 TrJV 8KT8A80rJ µtac; l3LOAOYLK'7C: ooKtµaa(ac;, K688 OOKLµaa(a anam;( µLa 08Lp6 npOTUTIWV OLQAUµ6TWV TOU TCDD '7 TOU µdyµmoc; OLOs(vric;/cpoupav(ou (KaµnUArJ nAtjpouc; Maric;-an6Kptaric; µe R2 > 0,95). Om6ao, yta A.6 youc; otaAoytjc; (scree-ning) nptneL va XPrimµonOLri8d µLa KaµnuArJ xaµf]AWV auyKE:VTpwaewv, yLa Tf]V av6AUOrJ oetyµ6Twv xaµf]Awv 8mntowv auyK8VTpwaric;. • Mta auyK8VTpwari avacpop6c; TCDD (n8p(nou 3x cpo­ ptc;TO 6pLO TIOOOTLKOU npoaoLOptaµou) 08 tva 08ATl0 TIOL­ OTLKOU 8A8YXOU np8TI8L va xprimµonOL8lTQL yta Ta anOT8 Maµarn TrJC: l3LOAOYLK'1C: ooKtµaa(ac; Km6 TrJ ot6pK8La µtac; ma88ptjc; n8pt6oou. Mta 8vaAAaKTLK'7 Mari Sa tjrnv ri axeTLK'l an6KpLOrJ ev6c; odyµmoc; avacpop6c; ae au­ YKPLOrJ µg Tf] KaµnuArJ l3a8µov6µriaric; TCDD, Ka8wc; rJ an6Kptari Twv Kun6pwv µnopd va 8sapT6Tm an6 noA­ Aouc; nap6yoVTec;. • nptn8L va Kmayp6cpoVTm Km va 8MyxoVTm ota­ yp6µµma notoTLKou 8Myxou (nE) yta K688 dooc; uALKou avacpop6c; wme va otaacpaALITTf:l 6TL Ta anoTeMaµma d­ vm auµcpwva µ8 TLC: Of]AWµ8V8<:; KQT8U8UVT'7pl8<:; ypaµµtc;. • lota(T8pa yta TOU<:; UTIOAOYLOµouc; TWV TIOOOTLKWV npoaotoptaµwv, To odyµa nou npoKum8L an6 TrJV apa(w­ ari TWV 08Lyµ6TWV np8TI8L va dvm 8VT6c; TOU ypaµµLKOU Tµtjµmoc; TrJC: KaµnuArJC: avacpop6c;. l:.dyµma n6vw an6 TO ypaµµtK6 Tµtjµa TrJC: KaµnuArJC: avacpop6c; npfo8L va apmwvoVTm Km va npoaotopfi'.;oVTm eK vfou. LUV8nwc;, OUVLOTOTQL va npoaotop(i'.;OVTQL TOUAOXLITTOV Tp8LC: '7 TI8 ptaa6T8p8c; apmwa8LC: rnuT6XPova. • H noaomta(a TUTILK'l an6KALOrJ o8v nptn8L va dvm 6vw Tou 15 % a8 tva TpmA6 npoaotoptaµ6 yta K68e apa(­ wari odyµmoc; KQL OXL 6vw TOU 30 % µ8TaSU TPLWV av8 s6pTf]TWV TI8LpaµOTWV. • To 6pto TrJC: av(xvwaric; µnopd va Ka8optmd twc; 3x cpoptc; Tf]VTUTILK'7 an6KALOrJ TOU TUcpAOU TOU OLQAUTrJ 17 TrJC: an6Kptaric; unol368pou. Mta OAArJ npoatyytari dvm ri 8cpapµoy17 µtac; an6Kptaric; nou dvm 6vw TOU unol368pou (µs XPllar; sv6c; cruvT£P .. £a-r?l 5 cpoptc; TO Tucp> .. 6 -rou Cta.A .. U­ TrJ) nou unoAoy(i'.;ernL an6 TrJV KaµnuArJ l3a8µov6µriaric; TrJC: riµtpac;. To 6pLO TIOOOTLKOU npoaoLOpLaµou µnopd va Ka8optmd an6 5x twc; 6x cpoptc; TrJV TUTILK'l an6KALOrJ TOU TUcpAou Tou otaAUTrJ 17 TrJV an6KpLOrJ unol368pou 17 ri 8cpap­ µoy17 µtac; an6Kptaric; nou dvm aacpwc; n6vw an6 TO un6 l3a8po (µ8 XP'lOrJ 8v6c; OUVT8A80T'7 10 cpoptc;TO TU<pAO TOU oLaAUTrJ) nou unoAoy(i'.;8TQL an6 TrJV KaµnLIArJ l3a8µov6µri­ aric; TrJC: riµtpac;. 7.4. ELOLK8C: anmT'708LC:, yLa l3LOAOYLK8C:, OOKLµaa(ec; µg 136ari OUOK8Uaa(8c; nponapaaK8Uaaµtvwv aVTLopamri­ p(wv (test kits) 111 . 111 £1r,v exouv unoi3i>.ri8d □Koµa mmxda, r,µnoptKa i3toi>.oytKwv ooKtµamwv µr, i36ari auaKwaa(r,c; nponapaaKwaaµevwv □VTL­ opamT]p(wv (test-kits), nou va ota8eTOuv mapK17 r,uma8T]a(a KOL a~Lomm(a wmr, va xpriatµonmri9ouvyta otai>.oy17, oX8TLK6 µr, 1riv napoua(a oto~Lvwv ma anm1ouµr,va r,n(nr,oa or, odyµma 1po­ q,(µwv 17 c;ow1poq,wv. • npfo8L va TrJPOUVTQL OL ooriy(8c; TOU KQTaOK8UaOT17 yLa TrJV nponOLµaa(a odyµmoc; Km TLC: avaMa8tc;. • OL OUOK8Uaa(8c; nponapaaK8Uaaµtvwv aVTLopamri­ p(wv oOKLµwv (test kits) o8v nptn8L va xprimµonotouVTm µ8T6 TrJV f]µ8poµriv(a A'lSrJC: TOuc;. • £:.gv np8TI8l va XPrJOLµonoLOLJVTQL LIA.LKQ '7 OUOTQTLKQ nou npol3MTIOVTQL yLa Tf] XP'lOrJ TOUC: µ8 QAA8C: OUOK8Ua­ a(8c; nponapaaKwaaµtvwv aVTtopamrip(wv (kits). • OL OUOK8Uaa(8c; nponapaOK8Uaaµtvwv aVTLopamri­ p(wv ooKLµwv nptm:L va otmripouVTm ma nAa(ma Tou Ka 8optaµtvou cp6aµmoc; TrJC: 8epµoKpaa(ac; ano8tjK8UOrJC: Km va xprimµonotouVTm mriv Ka8optaµtvri 88pµoKpaa(a A8LTOupy(ac;. • To 6pLO av(xvwaric; yLa TLC: avoaOAOYLK8C: OOKLµaa(ec; Ka8op(i'.;8Tal we; 3x cpop8<:;Tf]VTUTILK'7 an6KALOrJ µ8136ari 08 Ka (10) 8TiaVaArJITTLK8<:; avaAU08L<:; TOU TU<pAOU OlaLpouµ8 VrJC: µ8 Tf]V TLµ'7 TrJC: KAlOrJC: TrJC: ypaµµLK'7<:; 8Sl0WOrJC: TIQ­ ALVop6µf]OrJ<:;. • 1La TLC: OOKLµtc; OTO 8pyam17pLO np8TI8L va xprimµo­ TIOLOLJVTQL np6TUna otaMµma avacpop6c; WOT8 va 8sa­ acpaALOT8l OTL ri an6Kpl0f] TOU npOTUTIOU Kuµa(v8TQL 8VT6c; 8v6c; anoo8KTOU 8upouc;. 8. 'EK880f] 8S8TaOrJC: Ecp6aov ri XPrimµonOLouµ8vrJ otaotKaa(a av6Auaric; TO Ka8tm6 ouvm6, rn anoT8Afoµma TrJC: av&uaric; nptn8L va n8pttxouv rn rn(n8oa Twv 8mµtpouc; PCDD/F Km oµo 8Lowv PCBs Km va Kmayp6cpoVTm rn(aric; TO KmwrnTo 6pLO auyK8VTpwaric;, avWTQTO 6pLO auyK8VTpwaric; KQL µt­ oo 6pLO auyK8VTpwaric; npOKE:Lµtvou va TI8pl8X8Tal tva <l>EK378 E<l>HMEPII THI KYBEPNHIEnI (TEYXOI ~EYTEPO) µeylOTO OUVOAO TIAT]pOcpOplWV KOTO TT]V UTIOf30Ar] TT]<:; 8K 880T]<:; Twv anoT8A8aµ6Twv WOT8 va ot8UKOALIV8Tat T] 8p­ µT]vda Twv anoT8A8aµ6Twv auµcpwva µ8 Ttc; 8totKec; anm­ Tf]08tc;. H 8K8WT] 8~8TOOT]c; npen8l 8TILOT]c; va TI8plAaµf36V8l TT]V nept8KTtK6T17Ta > .. tnt<5(wv TOU Oe(yµa-roc;, Ka9Wc; KQt Tl7 µ8 8000 nou xprimµon0tr']8T]K8 yta TTJV 8KXLIAlOTJ Atmo[wv. Ol QVQKTf]08l<:; TWV µ8µovwµevwv WWT8plKWV npOTU­ nwv npen8t va Ka8[mavrnt ota8emµ8c; OTTJV n8p[mwari nou dvm 8KT6c; Tou 8upouc; nou avacpep8Tal mo OT]µ8[o 6, OTT]V TI8p[mwari nou UTI8pf3a[v8TQl TO µeytOTO 8TILTI800 KQl 08 6M8c; TI8ptmwa8tc; Km6mv oX8TlKr'jc; a[TT]OT]c;. o np68opoc; N. XATZHXPHHlnHr Ta MeAT] H r paµµmeac; El\. nA/\1\APH .6. MANTEAHL, N. KATLIMnAr, .6. MnorKOY, M. OIKO­ NOMOY, K. AYrGYHAKHr, B. TLOYKA/\Ar, I. 1ArAIAr. H loXU<:; TT]<:; napouaac; an6cpaOT]c; apx[i'.;8l an6 TT] OT]µO­ a[war'j TT]<:; OTT]V EcpT]µ8p[oa TT]<:; Kuf38pVf]08Wc;. H an6cpaari auTr'j va oriµomw8d OTTJV EcpT]µ8p[oa TT]<:; Kuf38pvr'ja8wc;. A8r']va, 14 MapT[ou 2003 OIYnOYP,01 OIKONOMIAL KAI Y<DYn. OIKONOMIAL KAI OIKONOMIKON OIKONOMIKON NIK. XPIH0.6.0YAAKHI AnOHOAOI <l>QTIA.6.HI 5337