Ministerial Decree No. 50941/40 on the carriage of dangerous goods

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'to OtYex8ewpriµ!vo x!lµevo ffji;; Eupw1texrx71i;; ~uµcpw­ vi~ "(Lex ffjV 8te8v7) 08tx71 µe'texcpopix emxtvMvwv eµ1topeuµix'twv (ADR) ffjt; 1 rii;; Mexiou 1985, 'tO 01toio CJ£ 1tpw'to'tu1to CJ'tTjV ex"("(ALXT) "(AWCJCJex xotL CJ£ µe'tixcppex<JT) CJ't'TjV £AATjVLXT) E)(EL wi;; e~71i;;: APl0MOI G>YMOY 104 898 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI .dEYTEPO) ECONOMIC COMMISSION FOR EUROPE INLAND TRANSPORT COMMITTEE European Agreement concerning the international carriage of dangerous good s by road (ADR) and protocol of signature done at Geneva on 30 September 1957 VOLUME I (Agreement, Protocol of signature and Annex A) UNITED NATIONS New York, 1985 FOREWORD The text below comprises, in addition to the Agreement itsel( and the Protocol of sig­ nature, the annexes in tlie-form in which they entered into force on 29 July 1968 as well as the amendments thereto up to 1 May 1985. The secretariat of the Economic Commission for Europe wishes to acknowledge its appreciation and thanks to the International Road Transport Union (IRU) for the aid it has provided to expedite the preparation and publication of this revised edition of the European Agreement concerning the International Carriage of Dangerous Goods by Road (ADR). EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD (ADR) THE CONTRACTING PARTIES, DESIRING to increase the safety of international transport by road, HA VE AGREED as follows: Article I For the purpose of this Agreement, (a) the term "vehicle" shall mean motor vehicles, articulated vehi­ cles, trailers and semi-trailers, as defined in article 4 of the Conven­ tion on Road Traffic of I 9 September 1949, other than vehicles be­ longing to or under the orders of the armed forces of a Contracting Party;· (b) the term "dangerous goods" shall mean those substances and articles the international carriage by road of which is prohibited by, or authorized only on certain conditions by, ·Annexes A and B; (c) the term "international transport" shall mean any transport op­ eration performed on the territory of at least two Contracting Parties by vehicles defined in (a) above. Article 2 1. Subject to the provisions of article 4, paragraph 3, dangerous goods barred from carriage by Annex A shall not be accepted for in­ ternational transport. 2. Internationiµ transport of other dangerous goods shall be au thorized subject to compliance with: • (a) the conditions laid down in Annex A for the goods in q~es­ tion, in particular as regards their packaging and labelling, and (b) the conditions laid down in Annex B, in particular as regards the construction, equipment and operation of the vehicle car­ rying the goods in question, subject to the provisions of arti­ cle 4, paragraph 2. Article 3 The Annexes to this Agree~ent shall form an integral part thereof. Article 4 1. Each Contracting Party shall retain the right to regulate or pro­ hibit, for reasons other than safety during carriage, the entry of dan gerous goods into its territory. • 2. Vehicles in service on the territory of a Contracting Party at the time of entry into force of this Agreement or brought into service on such territory within two months after its entry into force shall be al-: lowed, for a period of three years from such entry into force, to per-· form the intemational transport of dangerous goods even if their con- ' struction and equipment do not entirely conform to the requirements : laid down in Annex B for the transport operation in question. Under:, special clauses of Annex B, however, this period may be reduced. ' 3. The Contracting Parties shall retain the right to arrange, by spe- •• cial bilateral or multilateral agreements, that certain of the dangerous, goods which under this Agreement are barred from all international transport may, subject to certain conditions, be accepted for interna-; -. tional transport on their territories, or that dangerous goods which un­ der this Agreement are acceptable for international transport only on· .. specified conditions may be accepted for international transport on their territories under conditions less stringent than those laid down in · the Annexes to this Agreement. The special bilateral or multilateral· • agreements referred to in this paragraph shall be communicated to •, the Secretary-General of the United Nations, who shall communicate them to the Contracting Parties which are not signatories to the said agreements. Article 5 The transport operations to which this Agreement applies shall re- •. main subject to national or international regulations applicable in . general to rnad traffic, international road transport and international . tr.. • Article 6 1. Countries members of the Economic Commission for Europe and countries admitted to the Commission in a consultative capacity : under paragraph 8 of the Commission's terms of reference may be­ come Contracting Parties to this Agreement. (a) by signing it; (b) by ratifying it after signing it subject to ratification; (c) by acceding to it. • -~ 2. Such countries as may participate in certain activities of the Eco­ nomic Commission for Europe in accordance 'with paragraph 11 of the Commission's terms of reference may become Contracting Par­ ties to this Agreement by acceding to it after its entry into force. 3. The Agreement shall be open for signature until 15 December 1957. Thereafter, it ·shall be open for accession. 4. Ratification or accession shall be effected by the depositing of an instrumc,nt with the Secretary-General of the United Nations. Article 7 1. This agreement shall enter into force one month after the date on which the number of countries mentioned in article 6, paragraph 1, which have signed it without reservation of ratification or have de­ posited their instruments of ratification or accession has reached a total of five. However, the Annexes thereto shall not apply until-six months after the entry into force of the Agreement itself. E<l>HMEPlr THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 899 2. For any country ratifying or acceding to this Agreement after five of the countries referred to in article 6, paragraph 1, have signed it without reservation of ratification or have deposited their instru­ ments of ratification or accession, this Agreement shall enter into force one month after the said country has deposited its instrument of ratification or accession and the Annexes thereto shall apply for the said country either on the same date, if they are already in force by that date, or, if they are not in force by that date, on the date on which they apply under the provisions of paragraph 1 of this article. Article 8 I. Any contracting Party may denounce this Agreement by so noti­ fying the Secretary-General of the United Nations. 2. Denunciation shall take effect twelve months after the date of re­ ceipt by the Secretary-General of the notification of denunciation. Article 9 1. This Agreement shall cease to have effect if, after its entry into force, the number of Contracting Parties is less than five during twelve consecutive months. 2. In the event of the conclusion of a worldwide agreement for the regulation of the transport of dangerous goods, any provision of this Agreement which is contrary to any provision of the said worldwide agreement shall, from the date on which the latter enters into force, automatically cease to apply to relations between the Parties to this Agreement which become parties to the worldwide agreement, and shall automatically be replaced by the relevant provision of the said worldwide agreement. Article 10 1. Any country may, at the time of signing this Agreement without reservation of ratification or of depositing its instrument of ratification or accession or at any time thereafter, declare by notification ad­ dressed to the Secretary-General of the United Nations that this Agreement shall extend to all or any of the territories for the interna­ tional relations of which it is responsible. The Agreement and the an­ nexes thereto shall extend to the territory or territories named in the notification one month after it is received by the Secretary­ General. 2. Any country which has made a declaration under paragraph 1 of this article extending this Agreement to any territory for whose inter­ national relations it is responsible may denounce the Agreement sep­ arately in respect of the said territory in accordance with the provi­ sions of article 8. Article 11 1. Any dispute between two or more Contracting Parties concern­ ing the interpretation or application of this Agreement shall so far as possible be settled by negotiation between them. 2. Any dispute which is not settled by negotiation shall be submit­ ted to arbitration if any one of the Contracting Parties in dispute so requests and shall be referred accordingly to one or more arbitrators selected by agreement between the Parties in dispute. If within three months from the date of the request for arbitration the Parties in dis­ pute are unable to agree on the selection of an arbitrator or arbitra­ tors, any of those Parties may request the Secretary-General of the United Nations to nominate a single arbitrator to whom the dispute shall be referred for decision. . 3. The decision of the arbitrator or arbitrators appointed under paragraph 2 of this article shall be binding on the Contracting Parties in dispute. Article 12 1. Each Contracting Party may, at the time of signing, ratifying, or acceding to, this Agreement, declare that it does not consider itself bound by article 11. Other Contracting Parties shall not be bound by article 11 in respect of any Contracting Party which has entered such a reservation. 2. Any Contracting Party having entered a reservation as provided for.in paragraph 1 of this article may at any time withdraw such reser­ vation by notifying the Secretary-General of the United Nations. Article 13 1 •. After this Agreement has been in force for three years, any Con­ tracting Party may, by notification to the Secretary-General of the United Nations, request that a conference be convened for the pur­ pose of reviewing the text of the Agreement. The Secretary-General shall notify all Contracting Parties of the request and a review confer­ ence shall be convened by the Secretary-General if, within a period of four months following the date of notification by the Secretary­ General, not less than one-fourth of the Contracting Parties notify him of their concurrence with the request. . 2. I~ a conference is convened in accordance with paragraph 1 of this article, the Secretary-General shall notify all the Contracting Par­ ties and invite them to submit within a period of three months such proposals as they may wish the Conference to consider. The Secretar­ y-General shall circulate to all Contracting Parties the provisional agenda for the conference, together with the texts of such proposals, at least three months before the date on which the conference is to meet. . 3. The Secretary-General shall invite to any conference convened m accordance with this article all countries referred to in article 6, paragraph 1, and countries which have become Contracting Parties under article 6, paragraph 2. Article 14 1. Independently of the revision procedure provided for in article 13, any Contracting Party may propose one or more amendments to the Annexes to this Agreement. To that end it shall transmit the text thereof to the Secretary-General of the United Nations. The Secretar­ y-General may also propose amendments to the Annexes to this Agreement for the purpose of ensuring concordance between those Annexes and other international agreements concerning the carriage of dangerous goods. 2. The Secretary-General shall transmit any proposal made under paragraph 1 of this article to all Contracting Parties and inform thereof the other countries referred to in article 6, paragraph 1. 3. Any proposed amendment to the Annexes.shall be deemed to be accepted unless, within three months from the date on which the Sec­ retary-General circulates it, at least o ne-third of the Contracting Par­ ties, or five of them if one thinnix1ceeds that figure, have given the Secretary-General written notification of their objection to the pro­ posed amendment. If the amendment is deemed to be accepted, it shall enter into force for all the Contracting Parties, either on the expiry of a further period of three months or, in cases where similar amendments have been or are likely to be made to the other interna­ tional agreements referred to in paragraph 1 of this article, on the expiry of a period the duration of which shall be determined by the Secretary-General in such a way as to allow, wherever possible, th si­ multan~ous entry into force of the amendment and those that have been or are likely to be made to such other agreements; such period shall not, however, be of less than one month's duration. 4. The Secretary-General shall, as soon as possible, notify·all Con­ tracting Parties and all the countries referred to in article 6, para­ graph 1, of any objection which may be received from the Contracting Parties to a proposed amendment. 5. If the proposed amendment to the Annexes is not deemed to be accepted, but if at least one Contracting Party other than the Con­ tracting Party which proposed the amendment has given the Secretar­ y-General written notification of its agreement to the proposal, a meeting of all the Contracting Parties and all the countries referred to in article 6, paragraph 1, shall be convened by the Secretary-General within there months after the expiry of the period of three months within which, under paragraph 3 of this article, notification must be given of objection to the amendment. The Secretary-General may also invite to such meeting representatives of: (a) intergovernmental organizations which are concerned with transport matters; (b) international non-governmental organizations whose activi­ ties are directly related to the transport of dangerous goods in the territories of the Contracting Parties. 6. Any amendment adopted by more than half the total number of Contracting Parties at a meeting convened in accordance with para­ graph 5 of this article shall enter into force for all Contracting Parties in accordance with the procedure agreed at such meeting by the ma­ jority of the Contracting Parties attending it. 900 ECJ>HMEPII THI KYBEPNHIEOI (TEYXOI aEYTEPO) Article 15 In addition to the notifications provided for in articles 13 and 14, the Secretary-General of the United Nations shall notify the countries referred to in article 6, paragraph 1, and the countries which have be­ come Contracting Parties under article 6, paragraph 2, of (a) signatures, ratifications and accessions in accordance with article 6; (b) the dates on which this Agr:eement and the Annexes thereto ·enter into force in accordance with article 7; (c) denunciations in accordance with article 8; (d) the termination of the Agreement in accordance with article 9; (e) notifications and denunciations received in accordance with article 10; • (f) declarations and notifications received in accordance with article 12, paragraphs 1 and 2; (g) the acceptance and date of entry into force of amendments in accordance with article 14, paragraphs 3 and 6. Article 16 1. The Protocol of Signature of this Agreement shall have the same force, effect and duration as the Agreement itself, of which it shall be C]Onsidered to be an integral part. 2. No reservation to this Agreement, other than those entered in the Protocol· of Signature and those made in accordance with article 12, shall be permitted. Article 17 After 15 December 195 7, the original of this Agreement shall be deposited with the Secretary-General of the United Nations, who shall transmit certified true copies thereof to each of the countries referred to in article 6, paragraph 1. IN WITNESS WHEREOF the undersigned, },,eing duly authorized thereto, have signed this Agreement. DONE at Geneva, this thirtieth day of September one thousand nine hundred and fifty-seven, in a single copy, in the English and French languages for the. text of ,the Agreement proper, and in the French language for the Annexes,. each text being equally authentic for the Agreement proper. The Secretary-General of the United Natio ns is requested to pre­ pare an authoritative translation of the Annexes in the English lan­ guage and attach it to the certified true copies referred to in article 1 7. ECE/TRANS/60 (Vol. 1)/Add.l page 1 PROTOCOL AMENDING ARTICLE 14 (3) OF THE EUROPEAN AGREEMENT OF 30 SEPTEMBER 1957 CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD (ADR) THE PARTIES TO THE PRESENT PROTOCOL, HAVING CONSIDERED the provisions of the European Agree­ ment concerning the International Carriage of Dangerous Goods by Road (ADR), done at Geneva on 30 September 1957 (hereafter re­ ferred to as "the Agreement"), in so far as concerns the amendment of the annexes to the said Agreement, and in particular article 14 (3) of the Agreement; NOTING that the Contracting Parties to the Agreement occa­ sionally experience difficulties in implementing, within the three­ month time limit provided for by article 14 (3) of the Agreement be­ tween the time when an amendment is deemed to have been accepted and the time when it is to enter into force, those internal measures that are required for the purpose of putting the amendments into effect; DESIROUS of modigying in this respect the provisions of article 14 (3) of the Agreement; AGREE as follows: Article 1 Modification of article 14 (3) of the Agreement Paragraph 3 of article 14 of the Agreement is modified to read as follows: "3. Any proposed amendment to the annexes shall be deemed to be accepted unless, within three months from the date on which the Secretary-General circulates it, at least one-third of the Contracting Parties, or five of them if one-third exceeds that figure, have given the Secretary-General written notification of their objection to the pro­ posed amendment. If the amendment is deemed to be accepted, it shall enter into force for all the Contracting Parties on the expiry of a further period of three months, except in the following cases: (a) In cases where similar amendments have been or are likely to be made to the other international agreements referred to in para graph 1 of this article, the amendment shall enter into force on the expiry of a period the duration of which shall be determined by the Secretary- General in such a way as to allow, wherever possible, the simultaneous entry into force of the amendment and those that have been made or are likely to be made to such other agreements; such period s hall not, however, be of less than one month's duration; (b) The Contracting Party submitting the proposed amendment may specify in its proposal, for the purpose of entry into force of the amendment, should it be accepted, a period of more than three months' duration". Article 2 Acceptance of the present Protocol The present Protocol shall be open for acceptance by the Contract­ ing Parties to the Agreement. Instruments of acceptance shall be de­ positP,d with the Secretary-General of the United Nations. Article 3 Entry into force of the present Protocol 1. The present Protocol and the amendments therein shall enter into force one month from the date on which the instruments of accep­ tance of all Contracting Parties have been deposited with the Secre­ tary-General of the United Nations. 2. Any State becoming a Contracting Party to the Agreement after the entry into force of the present Protocol shall be a Contracting Party to the Agreement as amended by the Protocol. Article 4 Miscellaneous provisions The original of the present Protocol, in English and French, shall be deposited with the Secretary-General of the United Nations, who shall transmit a certified true copy thereof to the Contracting Parties to the Agreement and to all States which may become Parties to the latter. • DRAWN UP by the Secretary-General of the United Nations, at New York, on 21 August 1975, the date of the completion of the pro­ cedure by which the Contracting Parties to the Agreement and other States concerned decided to open the present Protocol for accep­ tance. • • • All the Contracting Parties to the Agreement having deposited their instruments of acceptance with the Secretary-General, the conditions have now been fulfilled for the entry into force of the present Protocol in accordance with article 3, 1. The date of deposit of the last instru­ ment of acceptance was 19 March 1985, therefore the Protocol en­ tered into force one month later, i.e. 19 April 1985. As a result, arti­ cle 14 (3) of the Agreement has been modified in accordance with the text reproduced in article 1 of the present Protocol. The Agreement as it appears in ECE/TRANS/60 (Vol. I) should be amended accordingly. E<DHMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 901 PROTOCOL OF SIGNATURE TO THE EUROPEAN AGREEMENT ON THE NTERNATIONAL CARRIAGE OF DANGEROUS GOODS • BY ROAD (ADR) On proceeding to sign the European Agreement on the Inter­ national Carriage of Dangerous Goods by Road (ADR) the un­ dersigned, duly authorized, 1. CONSIDERING that the conditions governing the carriage of dangerous goods by sea to or from the United Kingdom differ basically from those set forth in Annex A to ADR and that it is impossible to modify them so as to conform to the latter in the near future; HAVING REGARD to the undertaking given by the United Kingdom to submit as an amendment to the said Annex A a special apfendix containing special provisions for road-sea carriage o dangerous goods between the Continent and the United Kingdom; HA VE AGREED that, until the entry into force of such spe­ cial appendix, dangerous goods carried under ADR to or from the United Kingdom shall comply with the provisiol}s of Annex A to ADR and also with the United Kingdom con­ ' ditions for the carriage of dangerous goods by sea; 2. TAKE NOTE OF a declaration by the representative of France to the effect that the Government of the French Re­ public reserves the right, notwithstanding th~ proyisions. of article 4, paragrafh 2, to refuse to allow vehicles m service on the territory o another Contracting Party, whatever the date on which they were put into service, to be used for the carriage of dangerous goods on French territory unless such vehicles comply either with the conditions laid dowi;i for such carriage in Annex B or with the conditions laid down for the carriage of the goods in question in the French regulations governing the carriage of dangerous goods by road; 3: RECOMMEND that, before submission in accordance with article 14, paragraph 1, or article 13, paragraph 2, pro­ posed amendments to this Agreement or its Annexes shall as far as possible first be discussed at meetings of experts of the Contracting Parties and, if necessary, of the other coun­ tries mentioned in article 6, paragraph l, of the Agreement and of the international organizations mentioned in article 14, paragraph 5, of the Agreement. EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD ANNEX A PROVISIONS CONCERNING DANGEROUS SUBSTANCES AND ARTICLES Table of Contents Part I - DEFINITIONS AND GENERAL PROVISIONS Marginals Definitions ............................. 2000 and 2001 General Provisions . . . . . . . . . . . . . . . . . . . . . . 2002 to 2099 Part II - LIST OF SUBSTANCES AND SPECIAL PROVISIONS Class la Class lb Class le Class 2 FOR THE VARIOUS CLASSES Explosive substances and articles 2100 et seq. Articles filled with explosive sub- . stances .................... 2130 et seq. Igniters, fireworks and siinilar goods ..................... 2170 et seq. Gases: compressed, liquefied or dissolved under pressure . . . . . . 2200 et seq. Class 3 Class 4.1 Class 4.2 Inflammable liquids .. • ........ 2300 et seq. Inflammable solids ........... 2400 et seq. Substances liable to spontaneous . combustion ................. 2430 et seq. Class 4.3 Substances which give off inflam h. Class 5.1 Class 5.2 Class 6.1 Class 6.2 mable gases on contact with water 24 70 et seq. Oxidizing substances . . . . . . . . . 2500 et seq. Organic peroxides ........... 2550 et seq. Toxic substances ............ 2600 et seq. Repugnant substances and sub Class 7 Class 8 stances liable to cause infection . 2650 et seq. Radioactive substances . . . . . . . . 2700 et seq. Corrosive substances ......... 2800 et seq. Part III - APPENDICES TO ANNEX A Appendix A. l Stability and safety conditions re­ lating to explosive substances, in­ flammable solids and organic per oxides .................... 3100 et seq. Appendix A.2 Provisions relating to the nature of aluminium-alloy receptacles for certain gases of Class 2; require­ ments concerning the materials and construction of receptacles in­ tended for the carriage of deeply­ refrigerated liquefied gases of Class 2; provisions relating to tests on aerosol dispensers and non­ refillable containers for gases un­ der pressure of Class 2, 10 ° and 11 ° ...................... 3200 et seq. Appendix A.3 Tests relating to inflamniable·liq~ uids of Classes 3, 6.1 and 8 .. ; 3300 et seq. Appendix A.4 Reserved .................. 3400 et seq. Appendix A.5 General packing conditions, types • ; • of packing, requirements applica- • ble to packagings, test require ments for packagings . ; .•... :. 3500 et seq. Appendix A.6 Regulations relating'to radioactive· substances of Class 7 ........ 3600 et seq. Appendix A.7 Reserved . .- .... -............ 3700 et seq. Appendix A.8 Reserved ........ : ... ~,~· . . ,::c .. 3800 et seq. Appendix A. 9 Provisions relating to danger la • bels; explanation of symbols . . . 3900 et seq. PART I. DEFINITIONS AND GENERAL PROVISIONS 1-1999 DEFINITIONS (1) For the purposes of this Annex: the term "competent authority" means the authority designated as such in each country and in each specific . case by the Government; . the term "fragile package" means a package contain­ ing a fragile receptacle, i.e. a receptacle mad~ of ~ass, por • celain • stoneware or similar materials, which IS not en­ closed in a packaging with complete sides protecting it ef­ fectively against shock (see also marginal 2001 (7)); the term "gas" means a gas or vapour; the term "dangerous substance~"• when yse~ alone, means the substances and articles designated as bemg sub­ stances and articles of ADR: the term "carriage in bulk" means the carriage of a solid substance without packaging; the term "RID" signifies Regulations concerning the international carriage of dangerous goods ~y r~, whic~ are Annex I of COTIF - Convention concernmg mternational carriage by rail, Appendi~ B - U~orm rules concernin~ the contract for internallonal carriage of goods by rail (CIM). 2000 902 t:tVHMt:PIL I HL KYBt:PNHLt:OL \ 11: VXOL aEYTEPO) (2l For the purposes of this Annex, tanks (see definitions in Annex B) are not placed on the same footing as recepta­ cles, the term "receptacle" being used in a restrictive sense. Provisions concerning receptacles are applicable to fixed tanks, batteries of receptacles, demountable tanks and tank-containers only if this is expressly stipulated. (3) The term "full load" means any load originating from one sender for which the use of a vehicle or of a large container is exclusively reserved and all operations for the loading and unloading of which are carried out in confor­ mity with the instructions of the sender or of the consignee. Definitions and General Provisions Units of measurement (1) The following units of measurement1/ are applicable in this Annex and in Annex B: Acceptable Measurement SI Unit2/ alternative Relationship of units between units Length m (metre) Area m2 (square metre) Voluine m3 (cubic metre) 13/ (litre) 11 = I0-3m3 Time s (second) min (minute) lmin=60s h (hour) lh=3600s d (day) ld=86400s Mass kg (kilogramme) g (gramme) 1 g = I0-3kg I (tonne) lt=l03kg Mass density . kg/m3 kg/I I kg/I = 103kg/m3 Temperature K (kelvin) •c (degree o·c = 213,15 K Celcius) Difference of temperature K (kelvin) °C (degree 1°C = I K Celsius) Force N (newton) 1 N = I kg.m/s2 Press.ore Pa (pascal) . bar (bar) I bar= 105Pa I Pa= 1 N/m2 Stress N/m2 N/mm2 I N/mm2 = I MPa Work J Goule) I J = I N.m = I W.s Energy J Goule) kWh (kilowatt I kWh= 3.6 MJ hour) Quantity e V (electron- . of heat J Goule) volt) I eV = 0.1602.I0-181 Power W(watt) lW=lJ/s=lN.m/s Kinematic viscosity • m2/s mm2/s I mm2/s = I0-6m2/s Dynamic viscosity Pa.s mPa.s 1 mPa.s = I0-3Pa.s Force Stress 1 kg = 9.807 N 1 kg/mm2 = 9.807 N/mm2 1 N = 0.102 kg 1 N/mm2 = 0.102 kg/mm2 Pressure I Pa l bar I kg/cm2 I torr = 1 N/m2 = I0-5bar= 1.02. I0-5kg/cm2 = 0.75. 10-21orr = 105Pa = 1.02 kg/cm2 = 750 torr = 9.807. 104Pa = 0.9807 bar = 736 torr = 1.33. 102Pa = 1.33. I0-3bar = 1.36. I0-3kg/cm2 2001 I/ The following round figures are applicable for the conversion of tht units hitherto used into SI Units. 2/ The International System of Units (SI) is the result of decisions taken at the General Conference on Weights and Measures (Address: Pavilion de Breteuil, Pare de St-Cloud, F-92 310 Sevres). 3/ The abbreviation "L" for litre may also be used in place of the abbrevia­ tion "I" when a typewriter cannot distinguish between figure "I" and letter "I". Energy, work, quantity of heat I J = I Nm = 0.278. I0--6kWh = 0.102 kgm = 0.239. I0-3kcaI I kWh = 3.6. I06J = 367. l03kgm = 860 kcal 1 kgm = 9.807 J = 2. 72 . I0-6kWh = 2.34. 10-3 kcal 1 kcal = 4.19 .103J = 1.16. I0-3kWh = 427 kgm Power I W = 0.102 kgm/s = 0.86 kcal/h I kgm/s = 9.807 W = 8.43 kcal/h 1 kcaljh = 1.16 W= 0.119 kgm/s Dynamic viscosity Kinematic viscosity Im2/s = 10451 (Stokes) l St = 10-4m2/s I Pa . s = I Ns/m2 = 10 P (poise) = 0.102 kgs/m2 I p = 0.1 Pa. s lkgs/m2 = 9.807 Pa. s = 0.1 Ns/m2 = 1.02. I0-2kgs/m2 = 9.807 Ns/m2= 98.07 P The decimal multiples and sub-multiples of a unit may be forme by prefixes, having the following meanings, placed before the name c the unit: Factor Prefix Symbol 1 000 000 000 000 000 000 = 1018 quintillion exa E 1 000 000 000 000 000 = 1015 quadrillion peta p 1 000 000 000 000 = 1012 trillion tera T 1000000 000 = 109 billion giga G I 000 000 = 106 million mega M 1 000 = 103 thousand kilo k 100 = 102 hundred hecto h 10 = 101 ten deca da 0.1 = 10-1 tenth deci d 0.01 = 10-2 hundredth centi C 0.001 = 10-3 thousandth milli m 0.000 001 = I0-6 millionth micro I' 0.000 000 001 = 10-9 billionth nano n 0.000 000 000 001 = 10-12 trillionth pico p 0.000 000 000 000 001 = 10-15quadrillionth femto f 0.000 000 000 000 000 001 = I0-18quintillionth atto a NOTE: 109= 1 billion is United Nations usage. By analogy, so is 10-9= I billionth. (2) Whenever the word "weight" is used in this Annex and in Annex B, it means "mass". (3) Whenever the weight of a pack\1ge is mentioned in this Ann.ex and in Annex B, the gross mass is meant unless otherwise stated. The mass of containers or tanks used for the carriage of goods is not included in the gross mass. (4) Unless expressly stated otherwise, the sign "%" in this Annex and in Annex B represents: (a) in the case of mixtures of solids or ofliquids, and also in the case of solutions and of solids wetted by a liquid: a percentage mass based on the total mass of the mixture, the solution or the wetted solid; (b) in the case of gaseous mixtures: a percentage by vol­ ume based on the total volume of the gaseous mixture. (5) Pressures of all kinds relating to receptacles (such as test pressure, internal pressure, safety-valve opening pressure) are always indicated in gauge pressure (pressure in excess of atmospheric pressure), however, the vapour pressure of substances is always expressed in absolute pressure. (6) Where this Annex or Annex B specifies a degree of filling for receptacles or tanks, that degree of filling is al­ ways referred to a temperature of the substances of 15°C unless some other temperature is indicated. (7) Fragile receptacles secured, either singly or in groups, by cushioning materials in a strong receptacle are not regarded as fragile receptacles if the strong receptacle is leakproof and so designed that in .the event of breakage or leakage of the fragile receptacles their contents cannot E<l>HMEPII THI KYBEPNHIEQI (TEYXOI·aEYTEPO) escape from the strong receptacle and the mechanical strength of the latter is not impaired by corrosion during carriage. (8) The following approximate conversion formula is au­ thorized until SI units have been incorporated throughout the texts of this Annex and Annex B. 1 kg/mm2 = 10. N/mm2 1 kg/cm2 = 1 bar GENERAL PROVISIONS (1) This Annex specifies the dangerous goods to be ex­ cluded from international carriage by road and the danger­ ous goods to be acGepted for such carriage under certain conditions. It groups the dangerous goods in restrictive and non-restrictive classes. Of the dangerous goods covered by the headings of the restrictive classes (Classes la, lb, le, 2, 4.2, 4.3, 5.2, 6.2 and 7), those which are listed in the clauses concerning these classes (marginals 2101, 2131, 2171, 2201, 2431, 2471, 2551, 2651 and 2701) are to be accepted for carriage only under the conditions speci­ fied in these clauses, and others are to be excluded from carriage. Some of the dangerous goods covered by the headings of the non-restrictive classes (Classes 3, 4.1, 5.1, 6.1 and 8) are, by notes inserted in the clauses concerning the various Classes, excluded from carriage; of the other goods covered by the headings of the non-restrictive classes, those which are mentioned in the clauses concern­ ing these classes (marginals 2301, 2401, 2501, 2601 and 280 I) are to be accepted for carriage only under the condi­ tions specified in these clauses; those which are not men­ tioned or covered by one of the collective headings are not deemed to be dangerous goods for the purposes of this Agreement and are to be accepted for carriage without any special conditions. (2) The classes of this Annex are as follows: Class la Explosive substances and arti cles Restrictive Class I b Articles filled with explosive substances Class le Igniters, fireworks and similar goods Class 2 Gases: compressed, liquefied Restrictive Restrictive or dissolved under pressure Restrictive . Class 3 Inflammable liquids Non-restrictive Class 4.1 Inflammable solids Non-restrictive Class 4.2 Substances liable to spontaneous combustion Restrictive Class 4.3 Substances which give off inflammable gases on contact with water Class 5. I Oxidizing substances Class 5.2 Organic peroxides Class 6.1 Toxic substances Class 6.2 Repugnant substances and substances liable to cause infection Class 7 Radioactive substances Class 8 Corrosive substances Restrictive Non-restrictive Restrictive Non-restrictive Restrictive Restrictive Non-restrictive (3) Any carriage of goods governed by this Annex shall be the subject of a transport document. The sender shall communicate in writing to the carrier the particulars to be included in the transport document as laid down for each class in Part II of this Annex in sections 2.B. The document may be that already required by other regulations in force. Any goods the carriage of which is so governed shall be de­ scribed in the transport document in conformity with the in­ dications in sections B of the special provisions for each class. The particulars to be entered in the transport docu­ ment shall be drafted in an official language of the forward­ ing country, and also, if that language is not English, or French, or German, in English, French or German, unless 2002 international road transport tariffs, if any, or agreements concluded between the countries concerned in the trans­ port operation, provide otherwise. The transport document shall be accompanied, if appropriate, by instructions to be implemented in the event of an accident (see Annex B, marginal 10385). The transport document shall accom­ pany the dangerous substances carried. ( 4) If by reason of th~ size of the load a consignment cannot be loaded in its entirety on a single transport unit, at least as many separate documents, or copies of the single document, shall be made out as transport units loaded. Furthermore, in all cases separate transport documents shall be made out for consignments or parts of consign . ments which may not be loaded together on the same vehi­ cle by reason of the prohibitions set forth in Annex B. (5) Outer packagings additional to those specified in this Annex may be used providing that they do not contra­ vene the spirit of the provisions of this Annex relating to outer packagings. If such additional packagings are used, the prescribed marking and labels shall be applied to them. (6) If the mixed packing of several dangerous sub­ stances with one another or with other goods is allowed by the provisions of section A.3 of the provisions applicable to ihe various classes, the inner packagings containing differ­ ent dangerous substances shall be carefully and effectively separated from one another in the collective packagings if dangerous reactions, such as the production of dangerous heat, combustion, the formation of mixtures sensitive to friction or shock, and the release of inflammable or toxic gases, are liable to occur as a result of damage to or de­ struction of the inner packagings. In particular, if fragile receptacles- are used, and especially if the said receptacles contain liquids, the danger of the formation of dangerous mixtures shall be avoided and to this end all appropriate measures shall be taken, such as the use of suitable cush­ ioning materials in sufficient quantity, securing of the re­ ceptacles in a second, strong packaging, and subdivision of the collective packaging into several compartments. (7) If mixed packing is used, the provisions of this Annex concerning the particulars in the transport docu­ ment shall apply in respect of each of the different kinds of dangerous substance contained in the collective package, and the collective package shall bear all the inscriptions and all the danger labels prescribed in this Annex for the dangerous substances the collective package contains. (8) If solutions of substances listed in this Annex are not expressly mentioned in the list of the class to which the dis­ solved substances belong, they shall nevertheless be con­ sidered as substances of ADR if their concentration is such that they retain the danger inherent in the substances them­ selves; their packaging shall in such event conform to the requirements of section A of the special provisions applica­ ble to the class to which the said substances belong, it being understood that packagings which would be unsuitable for the carriage of liquids may not be used. (9) Mixtures of substances of ADR with other sub­ stances shall be considered as substances of ADR if they retain the danger inherent in the substance which is a sub­ stance of ADR. (10) The sender, either in the transport document or in a separate declaration, shall certify that the substance pre­ sented may be carried by road in conformity with the provi­ sions of ADR, that its condition, treatment and, as appro­ priate its packaging and labelling comply with the provi­ sions of ADR. Furthermore, if several dangerous goods are packed together in a collective package or in a single con­ tainer, the sender is required to declare that this mixed packing is not prohibited. (11) A substance whose specific radioactivity does not exceed 74 kBq/kg (0.002 microcurie per gramme) and which is covered by a collective heading of any class shall be excluded from carriage if, in addition, it is covered by the heading of a restrictive class in which it is not listed. 903 904 ECl>HMEPII: THI: KYBEPNHI:EtU: {TEYXOI: aEYTEPO) (12) A substance whose specific radioactivity does not exceed 74 kBq/kg (0.002 microcurie per gramme) and which is not listed by name in a class, but is covered by two or more collective headings of different classes, shall be subject to the conditions of carriage laid down: (a) in the restrictive class, if one of the classes concerned is a restrictive class; (b) in the class corresponding to the predominant danger exhibited by the substance during carriage, if none of the classes concerned is a restrictive class. (1) This Annex contains for each class other than Class 7: (a) a list of the dangerous substances constituting the class and, where applicable, under a marginal ending with the letter "a", the exemptions allowed from the provisions of ADR for some of these substances if they comply with certain conditions; (b) provisions sub-divided as follows; A. Packages: 1. General conditions of packing; 2. Packing of a single substance or of articles of the same kind; 3. Mixed packing; 4. Marking and danger labels on packages. B. Particulars in the transport document. C. Empty packagings. D. (where appropriate) Other provisions. (2) Provisions concerning: consignment in bulk, in containers and in. tanks; method of despatch and restrictions on forwarding; prohibitions on mixed loading; and transport equipment. are to be found in Annex B and its appendices, which also contain all other pertinent provisions applying specifi cally to carriage by road. . (3) The appendices to this 'Annex contain: Appendix A. l: Stability and safety conditions relating to explosive substances, inflammable solids and organic per­ oxides, together with ru,les for tests; Appendix A.2: Provisions relating to the nature of aluminium-alloy receptacles for certain gases of Class 2; provisions relating to the materials and construction of re­ ceptacles, intended for the carriage of deeply-refrigerated liquefied gases of Class 2; and provisions relating to tests on aerosol dispensers and non-refillable containers for gases under pressure of Class 2, 10° and 11 °; Appendix A.3: Tests relatitig to inflammable liquids of classes 3, 6.1 and 8; Appendix A.5: General packing conditions, types of packaging, requirements applicable to packagings, test re­ quirements for packagings; . Appendix A.6: Regulations relating to radioactive sub stances of Class 7; • Appendix A. 9: Provisions relating to danger labels, and explanation of the symbols. Appendices A.4, A.7 and A.8 are reserved. (4) For Class 7, the details concerning conditions of packing, mixed packing, labelling and marking of pack­ ages as well as provisions governing storage, despatch and carriage, including in bulk, in containers and in tanks, are specified in the schedules of Annex A listed in marginal 2702. Some of the detailed and technical provisions affect­ ing this class are elaborated in Appendix A.6 which also in­ cludes the complete table of radionuclides and methods of testing packagings intended for substances of Class 7. Where the provisions relating to carriage as a "full load" are applied, the competent authorities may require the ve­ hicle or large container used for the transport operation concerned to be loaded at only one point and unloaded at only one point. 2003 2004 2005 (1) If the vehicle carrying out a transport operation sub­ ject to the provisions of ADR is conveyed over a section of the journey otherwise than by road haulage, then any na­ tional or international regulations which, on the said sec­ tion, govern the carriage of dangerous goods by the mode of transport used for conveying the road vehicle shall alone be applicable to . the said section of the journey. (2) In cases where a transport operation subject to the provisions of ADR is likewise subject over the whole or a part of its. road journey to the provisions of an international convention which regulates the carriage of dangerous goods by a mode of transport other than road carriage by virtue of clauses extending the applicability of the said con­ vention to certain motor-vehicle services, then the provi­ sions of that international convention shall apply, over the journey in question, concurrently with those of ADR which are not incompatible therewith; the other clauses of ADR shall not apply over the journey in question. For the purpose of carrying out the trials necessary with a view to amending the provisions of this Annex in order to adapt them to technological and industrial developments, the competent authorities of the Contracting Parties may agree directly among themselves to authorize certain trans­ port operations in their territories by temporary derogation from the provisions of this Annex. The authority which has taken the initiative with respect to the temporary deroga­ tion so granted shall notify the competent service of the United Nations Secretariat of the derogation, which service shall bring it to the attention of the Contracting Parties. PART II. LIST OF SUBSTANCES AND SPECIAL PROVISIONS FOR THE VARIOUS CLASSES CLASS la EXPLOSIVE SUBSTANCES AND ARTICLES NOTE: Substances and articles which cannot explode on contact with a flame and which are not more sensitive to shock or friction than dinitrobenzene are not subject to the provisions of Class la. 1. List of substances and articles (1) Among the substances and articles covered by the heading of Class la, only those listed in marginal 2101 are to be accepted for carriage, and then only subject to the provisions of this Annex and of Annex B. These substances and articles to be accepted for carriage under certain con­ ditions are to be considered as substances and articles of ADR. (2) In the explosives which are to be accepted for car riage, nitroglycerine may be replaced wholly or in part by: (a) nitroglycol, or (b) dinitrodiethyleneglycol, or (c) nitrated sugar (nitrated saccharose), or (d) a mixture of the above substances. 1 ° Highly nitrated nitrocellulose (such as guncotton), i.e. with a nitrogen content of more than 12.6 per cent, well stabilized and containing in addition: when the nitrocellulose is not compressed, not less than 25 per cent water or alcohol (methyl, ethyl, normal propyl or isopropyl, butyl, or amyl alcohol or mixtures thereof), including denatured alcohol; or mixtures of water and alco­ hol; when the nitrocellulose is compressed, 'not less than 15 per cent water, or not less than 12 per cent paraffin wax or other similar substances. See also Appendix A.I, marginal 3101. NOTES: 1. Nitrocellulose with a nitroiren content not 2006 2007 2009 2010 2011 2099 2100 2101 <I>EK 104 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI llEYTEPO) exceeding 12.6 per cent is a substance of Class 4.1 if it complies with the specifications set out in marginal 2401, 7 ° (a), (b) or (c). 2. Nitrocellulose in the form of nitrocellulose-film waste, free from gelatine, in reels, sheets or strips, is a sub­ stance of Class 4.2 (see marginal 2431, 4°). 2 ° Cordite paste, non-gelatinized ("powder calce"), for use in the making of smokeless powders and containing not more than 70 per cent anhydrous substance and not less than 30 per cent water; the anhydrous substance must not contain more than 50 per cent nitroglycerine or similar liq­ uid explosives. 3 ° Gelatinized nitrocellulose powders and gelatinized nitrocellulose powders containing nitroglycerine (nitrogly­ cerine powders): (a) non-porous and non-dusty; (b) porous or dusty. See also Appendix A.I, marginal 3102. 4 ° Plasticized nitrocellulose containing not less than 12 per cent but less than 18 per cent plasticizing substances (such as butyl phthalate or a plasticizer at least equal in ef­ fect to butyl phthalate), and whose nitrocellulose has a ni­ trogen content not exceeding 12.6 per cent, also in the form of chips. NOTE: Plasticized nitrocellulose containing not less than 18 per cent butyl phthalate or a plasticizer at least equal in effect is a substance of Class 4.1 [ see marginal 2401, 7° (b) and (c)J. See also Appendix A.I, marginal 3102, 1. 5 ° Non-gelatinized nitrocellulose powders. See also Ap- • pendix A.I, marginal 3102. 6° Trinitrotoluene (tolite), also when compressed or cast, trinitrotoluene mixed with aluminium, mixtures termed liquid trinitrotoluene, and trinitroanisole. See also Appendix A.l, marginal 3103. 7° (a) Hexyl (hexanitrodiphenylamine) and (picric acid; (b) pentolites (mixtures of pentaerythritol tetranitrate and trinitrotoluene) and hexolites (mixtures of trimethyle­ ne-trinitramine and trinitrotoluene) if their trinitrotoluene content is such that their sensitiveness to shock does not exceed that of tetryl; (c) phlegmatized penthrite (pentaerythritol tetranitrate) and phlegmatized hexogen (trimethylene-trinitramine), both phlegmatized by incorporation of wax, paraffin wax or other similarly effective substances in such quantity that the sensitiveness of these substances to shock does not ex ceed that of tetryl. . For (a), (b) and (c), see also Appendix A.I, marginal 3103. NOTE: Substances of 7 ° (b) and phlegmatized hexogen of 7 ° ( c) may· also contain aluminium. 8 ° Explosive organic nitro-compounds: (a) soluble in water, e.g. trinitroresorcinol; (b) insoluble in water, e.g. tetryl (trinitrophenylmethyl­ nitramine); (c) tetryl gaines without metal covering. For ( a) and (b ), see also Appendix A. l, marginal 3103. NOTE: Except for liquid trinitrotoluene of 6 °, explo­ sive organic nitro-compounds in the liquid state are not to be accepted for carriage. 9° (a) Moist penthrite (pentaerythritol tetranitrate) and moist hexogen (trimethylene-trinitramine) wetted tI!,rough­ out with not less than 20 per cent water in the case of the former and not less than 15 per cent in the case of the lat­ ter; (b) moist pentolites (mixtures of penthrite and trinitro­ toluene) and moist hexolites (mixtures of hexogen and tri­ nitrotoluene) whose sensitiveness to shock in the dry state exceeds that of tetryl and which are wetted throughout with not less than 15 per cent water; (c). moist mixtures of penthrite or of hexogen with wax, 2101 2101 paraffin wax or substances similar to wax or paraffin wax, whose sensitiveness to shock in the dry state exceeds that of tetryl and which are wetted throughout with not less than 15 per cent water; (d) compressed penthrite gains without 1netnl <·n1·Pri11.~. For (a), (b) and (c), see also Appendix A.l, marginal 3103. ' 10° (a) Benzoyl peroxide: 1. in the dry state or with less than 10 per cent water; 2. with less than 30 per cent phlegmatizer. NOTES: 1. Benzoyl peroxide with not less than 10 per cent water or with not less than 30 per cent phlegmatizer is a substance of Class 5.2 [see marginal 2551, 8° (a) and (b)]. 2. Benzoyl peroxide with not less than 70 per cent dry and inert solicls is not subject to the provisions of ADR. (b) cyclohexanone peroxides [l-hydroxy-1 '-hydropero­ xy-dicyclohexyl peroxide and bis-(1-hydroxycyclohexyl) peroxide and mixtures of these two compounds]: 1. in the dry state or with less than 5 per cent water; 2. with less than 30 per cent phlegmatizer. NOTES: 1. Cyclohexanone peroxides and their mix­ tures with not less than 5 per cent water or with not less than 30 per cent phlegmatizer are substances of Class 5.2 [see marginal 2551, 9° (a) and (b)]. 2.,Cyclohexanone peroxides and their mixtures with not less than 70 per cent dry and inert solids are not sub­ ject to the provisions of ADR. (c) parachlorobenzoyl peroxide: 1. in the dry state or with less than 10 per cent water; 2. with less than 30 per cent phlegmatizer. NOTES: 1. Parachlorobenzoyl peroxide with not less than 10 per cent water or with not less than. 30 per cent phlegmatizer is a substance of Class 5.2. [see marginal 2551, 17° (a) and (b)]. • 2. Parachlorobenzoyl peroxide· wiµi • not :less than 70 per cent dry and inert solid~ ~ µot subject to the provisions of ADR. • • 11 ° (a) Black powder (with a b~is of potassium nitrate) in corned or meal form; • •• • • • (b) slow mining powders simWl! t~ bla~'ic powder (com­ posed of sodium nitrate, sulphur and wood charcoal, coal or lignite, or composed of potassium nitrate with or without sodium nitrate, sulphur, coal or lignite); •• • (c) cartridges of compressed black powder· or powder similar to compressed black powder. . NOTE: The density of the compressed mass must not be less than 1.5 g per cm3• . • For (a) and (b), see alsoAppendixA.l, margin~3104. 12 ° (a) Nitrate explosives, in powder.form, not covered by 11 ° or 14° (a) or (c)11nd consisting es~enti~y ofam­ monium nitrate or of a mIXture of ammomum mtrate and alkali or alkaline-earth nitrates or .of a mixture of ammo­ nium nitrate and sodium chloride, or of a mixture of alkali or alkaline-earth nitrates and a~monium chloride, or of a mixture of ammonium nitrate With alkali or alkaline-earth nitrates and of sodium.chloride, or of a mixture of ammo­ nium nitrate with alkali or alkaline-earth nitrates and am­ monium chloride. They may contain, in addition, combus­ tible substances (such as wood flour, or other vegetable flour or hydrocarbons), sensitizers (for example, fine alu­ minium powder), aromatic nitro-compounds, nitroglyce­ rine or nitroglycol or a mixture of the two, and inert stabiliz­ ing or colouring substances (see also Appendix A.I, mar ginal 3105). • (b) explosives not containing inorganic nitrates, in pow­ der form, consisting essentially of a mixture of inert sub­ stances (such as alkali chlorides) with nitroglycerine or nitroglycol or a mixture of the two. They may contain, in addition, aromatic nitro-compounds and substances with a phlegmatizing, stabilizing or gelatinizing, or colouring ef fect. See also Appendix A.I, marginal 3105. • 905 906 E<DHMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 13 ° Chlorate ari.d perchlorate explosives, i.e. mixtures of chlorates or perchlorates of alkali or alkaline-earth met­ als with compounds rich in carbon. See also Appendix A.1, marginal 3106. 14 ° (a) Dynamites with an inert absorbent, and explo­ sives similar to dynamite with an inert absorbent; (b) blasting gelatine consisting of gun-cotton and not more than 93 per cent nitroglycerine, and gelatinized dy­ namites with a nitroglycerine content not exceeding 85 per cent; (c) gelatinous nitrate explosives, consisting essentially of ammonium nitrate or of a mixture of ammonium nitrate with nitrates of alkali or alkaline-earth metals containing not more than 40 per cent gelatinized nitroglycerine or gelatinized nitroglycol or a mixture of the two. They may contain, in addition, nitro-compounds or combustible sub­ stances (such as wood flour or other vegetable flour or hy­ drocarbons) and, in addition, other inert or colouring sub­ stances. For (a), (b) and (c), see also Appendix A.l, marginal 3107. 15 ° Empty packagings, uncleaned, which have con­ tained dangerous substances of Class la. 2. Provisions A. Packages 1. General conditions of packing. (1) Packagings shall be so closed and leak-proof as to prevent any loss of the contents. The use of metal bands or wires to ensure closure is forbidden unless this procedure is specifically authorized in the special provisions ralating to the packing of the substances or articles in question. (2) The materials of which the packagings and their clo­ sures are made must not be liable to attack by the contents or form harmful or dangerous compounds therewith. (3) Packagings, including their closures, must be suffi­ ciently rigid and strong in all their parts to prevent any loos­ ening during carriage and to meet the normal requirements of carriage. Solid substances shall be firmly secured in their packagings, and inner packagings shall be firmly se­ cured in outer packagings. Unless otherwise specified in the section entitled "Packing of a single substance or of ar­ ticles of the same kind", inner packagings mpy be enclosed in outer packagings, either singly or in groups. (4) Bottles and other glass receptacles must be free from faults liable to impair their strength; in particµlar, in­ ternal stresses must have been suitably relieved. The thick- • ness of the walls must not be less than 2 mm. (5) Cushioning matenals shall be suited to the nature of the contents; in particular, they must be absorbent if the contents are liquid or might exude liquid. 2. Packing of a single substance or of articles of the same kind • (1) Substances of 1 ° and 2° shall be packed: (a) in wooden receptacles or in drums made of imper­ meable fibreboard; these receptacles and drums shall in addition be fitted with a lining impermeable to the liquids they contain; their closure must be leak-proof; or (b) in impermeable bags (e.g. made of rubber or of a suitable plastics material not readily inflammable) placed in a wooden case; or (c) in iron drums coated inside with zinc or lead; or (d) in receptacles made of tin-plate, zinc sheet or alu­ minium sheet, which shall be secured by cushioning mate­ rials in wooden cases. (2)° Metal receptacles shall be fitted with closures or safety devices yielding when the internal pressure reaches a value not greater than 0.3 MPa (3 bar); the presence of these closures or safety devices must not impair the strength of the receptacles nor impair its closure. (3) Nitrocellulose of 1 °, if wetted exclusively with water, may be packed in fibre drums; the fibreboard must have 2102 2103 undergone a special treatment to render it completely im­ permeable; the closures of the drums must be water­ vapour proof. • (4) A package containing substances of 1 ° must not weigh more than 120 kg or, if it can be rolled, more than 300 kg; however, where fibre drums are used, a package must not weigh more than 7 5 kg. A package containing substances of 2 ° must not weigh more than 7 5 kg. (1) Substances of 3° (a) and 4° shall be packed: (a) if they are to be carried as a full load: 1. in drums made of impermeable fibreboard; or 2. in packagings made of wood or of metal other than black sheet-iron; (b) if they are not to be carried as a full load: 1. in boxes made of fibreboard, tin-plate, zinc sheet or aluminium sheet, or of a suitable plastics material not read­ ily inflammable, or in bags made of closely-woven textile or of stout paper of at least two plies or. of stout paper lined with aluminium foil or with a suitable plastics material. These packagings shall be placed in wooden case; or 2. without preliminary packing in boxes or bags: a. in drums made of impermeable fibreboard or in wooden casks; or b. in wooden packagings lined with zinc sheet or alu­ minium sheet; or c. in receptacles made of metal other than black sheet­ rron. (2) If the powder is in tubes, sticks, threads, bands or sheets it may also be enclosed, without preliminary packing in boxes or bags, in wooden cases. (3) Metal receptacles shall be fitted with closures or safety devices yielding when the internal pressure reaches a value not greater than 0.3 MPa (3 bar); the presence of these closures or safety devices must not .impair the strength of the receptacle nor impair its closure. ( 4) The closure of wooden cases may be ensured by means of bands' of wires made of a suitable metal fastened tightly round them. If the bands or wires are made of iron, they shall be covered with a material not liable to produce sparks when subjected to impact or friction. (5) A package must not weigh more than 120 kg; how­ ever, where fibreboard drums are used, a packag~ust not • weigh more than 7 5 kg. ( 1) Substances of 3 ° (b) and 5 ° shall be packed: (a) if they are to be carried as a full load: 1. in drums made of impermeable fibreboard; or 2. in packagings made.of wood or of metal other than black sheet-iron; (h) if they are not to be carried as a full load: 1. in boxes made of fibreboard, tin-plate or aluminium sheet. A box must not contain more than 1 kg of powder and must be wrapped in paper. These.packagings shall be placed in wooden packagings; or 2. in bags made of closely-woven textile or of stout paper of at least two plies or of stout paper lined with alu­ minium foil or with a suitable plastics material. These bags shall be placed in fibre drums or in wooden casks or in other wooden packagings lined ~th zinc sheet or alumin­ ium sheet, or in receptacles made of zinc sheet or alumin­ ium sheet. Receptacles made of zinc sheet or aluminium sheet shall be completely lined with wood or fibreboard. (2) Metal receptacles shall be fitted with closures or safety devices yielding when the internal pressure reaches a value not greater than 0.3 Mpa (3 bar); the presence of these closures or safety devices must not impair the strength of the receptacle nor impair its closure. (3) The closure of wooden cases may be ensured by means of bands or wires made of a suitable metal fastened tightly round them. If the bands or wires are made of iron, they shall be covered with a material not liable to produce sparks when subjected to impact or friction. 2104 2105 E<DHMEPlr THr KYBEPNHrEQr (TEYXOr .dEVTEPO) (4) A package under (1) (a) must not weigh more than 100 kg; however, where fibre drums are used, a package must not weigh more than 75 kg. A package under (1) (b) must not weigh more than 7 5 kg. It must not contain more than 30 kg of nitrocellulose powder. ( 1) Substances of 6 ° shall be packed in wooden recep- tl 06 tacles. Drums made of impermeable fibreboard are like wise to be accepted for solid trinitrotoluene and for trinitroanisole, and iron receptacles for mixtures termed liquid trinitrotoluene. . (2) Metal receptacles shall be fitted with closures or safety devices yielding when the internal pressure reaches a value not greater than 0.3 MPa (3 bar); the presence of these closures or safety devices must not impair the strength of the receptacles nor impair it closure. (3) A package must not weigh more than 120 kg or, if it can be rolled. more 1li;111 30U kg: however. \d1t·n· !1l>n· drums are used, a package must not weigh more than 75 kg. • (1) Substances of 7° shall be packed: 2107 (a) substances of 7° (a): in wooden receptacles or in tlrums made of impermeable fibreboard. Lead and materi­ als containing lead (alloys or compounds) must not be used in the packaging of hexyl (hexanitrodiphenylamine) and picric acid. Picric acid may also be packed, not more than 500 g per receptacle, in receptacles made of glass, porcelain, stone­ ware or similar materials or of a suitable plastics material, secured in a wooden case by cuchioning material (e.g. cor­ rugated fibreboard). The receptacles shall be closed by means of a stopper,made of cork or rubber or a suitable plastics material, which shall be held in position by an addi­ tional device (such as a cap, crown, seal or binding) capa­ ble of preventing any loosening of the closure system dur­ ing carriage; (b) substances of 7° (b) and (c): not more than 30 kg per bag, in cloth bags which do not allow the contents to fil­ ter through, or in bags made of stout paper or a suitable plastics material, which shall be placed in leak-proof wooden receptacles or in drums made of hardened fibre­ board capable of being so closed as to be leak-proof and whose bottoms and lids shall be made of plywood. The lids of cases shall be secured by means of screws and those of drums by means of a collar. (2) A package containing substances of 7 ° (a) must not weigh more than 120 kg if it is a wooden receptacle; where fibre drums are used, a package must not weigh more than 75kg. Packages containing picric acid packed in fragile re­ ceptacles or in receptacles made of a plastics material must not weigh more than 15 kg. A package containing sub­ stances of 7° (b) or (c) must not weigh more than 75kg; cases which, with their contents, weigh more than 30 kg shall be fitted with means of handling. (1) Substances and articles of 8° shall be packed: • 2108 (a) substances of 8° (a): in receptacles made of steel not liable to rust, or of any other suitable material (which in particular excludes lead and its alloys). Nitro-compounds shall be uniformly wetted with sufficient water to ensure that they contain not less than 25 per cent water throughout the journey, at every point in the substance. Metal recepta cles shall be fitted with closures or safety devices yielding when the internal pressure reaches a value not greater than 0.3 MPa (3 bar); the presence of these closures or safety devices must not impair the strength of the receptacle nor impair its closure. Receptacles, except those made.of steel not liable to rust, shall be secured by cushioning materials in wooden packings; (b) subs lances of 8 ° (b): 1101 more 1ha11 I:; kg pn lia12-. . :2 I ()/1 in bags made of cloth or of a suitable plastics material, placed in wooden packagings; (c) substances of8° (a) and (b) may also be packed, not more than 500 g per receptacle, in receptacles made of glass, porcelain,. stoneware or similar materials, or of a suitable plastics material, secured by cushioning materials (e.g. corrugated fibreboard) in a wooden case. A package must not contain more than 5 kg of nitro-compounds. The receptacles shall be closed by means of a stopper, made of cork or rubber or a suitable plastics material, which shall be held in position by an additional device (such as a cap, crown, seal or binding) capable of preventing any loosen­ ing of the closure system during carriage; (d) articles of 8° (c): separately in stout paper and placed, not more than 100 per box, in sheet-metal boxes. Not more than 100 of these l,iy>xes shall be packed in a wooden packing case. (2) A package under paragraph (1) (a) or (b) must not weigh more than 75 kg; it must not contain more than 25 kg of substances of 8 ° (a) or more than 50 kg of substances of 8° (b). A package under paragraph (1) (c) must not weigh more than 15 kg, or a package under paragraph (1) (d) more than 40 kg. (1) Substances and articles of 9° shall be packed: (a) substances of 9° (a) to (c): 1. not more than 10 kg per bag, in bags made of cloth or of a suitable plastics material, placed in an impermeable fi­ breboard box or in a box made of tin-plate or aluminium sheet or zinc sheet; or 2. not more than 10 kg per receptacle, in receptacles made of fibreboard of adequate strength, impregnated with paraffin wax or rendered impermeable by some other means. Boxes made of tin-plate or aluminium sheet or zinc sheet and boxes or receptacles of other kinds shall be placed in a wooden case lined with corrugated fibreboard; metal boxes so placed shall be separated from one another by means of a corrugated-fibreboard wrapping. A case may not contain more than four boxes or receptacles of other kinds. The lids of cases shall be secured by means of screws. (b) penthrite of 9° (a) may also be packed either: 1. not more than 5 kg per receptacle, in receptacles made of glass, porcelain, stonewa1\tor similar materials, or of a suitable plastics material, closed by means of a stopper made of cork or rubber or a suitable plastics material; each receptacle shall be placed in a m~tal • ·r:eceptacle hermetically closed by welding or soldering and cushioned with resilient materials &ii as to wedge the inner receptacle securely without leaving any empty space. Not more than 4 metal receptacles shall be packed in a wooden case lined with corrugated fibreboard and shall be separated from one another by several thicknesses of corrugated fibreboard or of another material capable of perfonning the same func-­ tion; or 2. not more than 500 g dry mass per receptacle, in re­ c~ptacles made of glass, porcelain, stoneware or similar materials, or of a suitable plastics material, closed by means of a stopper made of cork or rubber or a suitable plastics material. These receptacles shall be placed in a wooden ca!Je. They shall be separated from one another by means of a corrugated fibreboard wrapping and from the sides of the case by a space of not less than 3 cm filled with cushioning materials; (c) hexogen of 9° (a) niay also be packed as provided under (b) 1. above for penthrite; ( d) articles of 9 ° ( d): first separately in stout paper and placed, not more than 3 kg per case, in fibreboard cases in which they shall be fixed in position by cushioning materi­ als; these cases, not more than 10 per wooden case, shall be so secured by cushioning materials in a wooden case closed by means of screws that there is a space of not less than 3 cm filled with cushioning materials at all points be­ tween the fibreboard cases and the packing case. (2) A package under (1) (a) or (1) (b) I. must not weigh more than 75 kg; a package under 1 (c) must not weigh more than 10 kg; a package under ( 1) (b) 2. or ( 1) ( d) must not weigh more than 35 kg. Packages which, with their 907 2109 908 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI 6EYTEPO) contents, weigh more than 30 kg shall be fitted with means of handling. (1) Substances of 10° shall be packed, not more than 2110 500 g per bag, i!'J firmly-tied bags made of a suitable pliant material; each bag shall be placed in a box made of metal, fibreboard or paperboard; these boxes, not more than 30 per packing case, shall be secured by cushioning materials in w wooden packing case with complete sides not less than 12 mm thick: (2) A package must not weigh more than 25 kg. (1) Substances and articles of 11 ° shall be packed: 2111 (a) substances of 11 ° (a) and (b): 1. not more than 2.5 kg per bag, in bags placed in boxes made of fibreboard, tin-plate or aluminium. The boxes shall be secured by cushioning materials in wooden packagings, or 2. in bags made of closely-woven fabric, placed in wooden casks or cases; (b) articles of 11 ° (c): rolled in stout paper; each roll must not weigh more than 300 g. The rolls shall be placed in a wooden case lined with stout paper. (2) The lids of the wooden cases shall be secured by means of screws; if the screws are made of iron, they shall be coated with a material not liable to produce sparks when subjected to shock or friction. (3) A package must not weigh more than 75 kg if it is carried as part of a full load, and not more than 35 kg if it is not carried as part of a full load. ( 1) Substances of 12 ° shall be cartridged in wrappings 2112 made of a suitable plastics material or of paper. The car tridges may be dipped in paraffin wax, ceresine or resin, or be wrapped in a suitable plastics material, so as to be pro tected from damp. Explosives containing more than 6 per cent liquid nitric esters shall be cartridged in paper coated with paraffin wax or ceresine or in an impermeable plastics material such·· as polyethylene. The cartridges shall be placed in wooden ·packagings. (2) Cartridges not coated. with paraffin wax or ceresine, or cartridges in permeable wrappings, shall be made up ' into packets weighing not more' than 2.5 kg each. Packets so made up, whose wrapping must consist at least of stout paper, shall be dipped in paraffin wax, ceresine or resin or wrapped in a suitable plastics material so as to be protected from damp. The packets shall be • placed in wooden packagings. • (3) The closure of wooden packagings may be ensured by means of metal bands· or wires fastened tightly round them. (4) A package must not weigh more than 75 kg. It must not contain more than 50 kg of explosives. (5) Instead of the wooden packagings prescribed in par­ agraph (1) and paragraph (2), it is also permissible to use suitable cases, made o( solid fibreboard or corrugated fi­ breboard, which are of.sufficient mechanical strength and whose lid flaps and bottom flaps must be closed by means of adhesive strips of sufficient strength. The design of cases made of solid fibreboard or corrugated fibreboard must be approved by the competent authority of the country of de­ parture. Such a package must not weigh more than 30 kg; it must not contain more than 25 kg of explosives. (1) Substances of 13 ° shall be cartridged in paper wrap- 2113 pings. Cartridges not coated with paraffin wax or ceresine shall first be rolled in paper that has been rendered imper meable. They shall be made up by means of a paper wrap ping into packets weighing not more than 2.5 kg each, which shall be secured by cushioning materials in wooden packagings whose closure may be ensured by means of metal bands or wires fastened tightly round them. (2) A package must not weigh more than 35 kg. (1) Substances of 14° shall be packed: 2114 (a) substances of 14 ° (a): cartridged in wrappings made of paper that has been rendered impermeable or in a suita­ ble plastics material. The cartridges shall be made up into packets by means of a paper wrapping or, if without a paper wrapping, secured by cushioning materials in fibre­ board cases. The packets or fibreboard cases shall be se­ cured by inert cushioning materials in wooden packagings whose closure may be ensured by means of metal bands or wires fastened tightly round them; (b) substances of 14° (b): cartridged in wrappings made of paper that has been rendered impermeable or in a suitable plastics material. The cartridges shall be placed in a fibreboard box. The fibreboard boxes, wrapped in paper that has been rendered impermeable, shall be secured, leaving no empty spaces, in wooden packaging whose clo­ sure may be ensured by means of metal bands or wires fas tened tightly round them; • (c) substances of 14° (c): . 1. cartridged in wrappings made of a suitable plastics material or of paper. The cartridges may be dipped in par­ affin wax, ceresine or resin or be wrapped in a suitable plastics material, so as to be protected from damp. Explo­ sives containing more than 6 per cent liquid nitric esters shall be cartridged in paper coated with paraffm wax or ceresine or in an impermeable plastics material such as polyethylene. The cartridges shall be placed in wooden packagings; . 2. cartridges not coated with paraffin wax or ceresine, or cartridges in permeable wrappings, shall be made up into packets weighing not more than 2.5 kg each. Packets so made up, whose wrapping must consist at least of stout paper, shall be dipped in paraffin wax, ceresine or resin or be wrapped in a suitable plastics material, so as to be pro­ tected from damp. The packets shall be placed in wooden packagings; 3. the closure of wooden packagings may be ensured by means of metal bands or wires fastened tightly round them; 4. instead of the wooden packagings prescribed under 1. and 2. above, it is also permissible to use suitable cases, made of solid fibreboard or corrugated fibreboard, which are of sufficient mechanical strength and whose lid flaps and bottom flaps must be closed by means of adhesive strips of sufficient strength. The design of cases made of solid fibreboard or corrugated fibreboard must be ap­ proved by the competent authority of the country of depar­ ture. (2) A package containing substances of 14° (a) or (b) must not weigh more than 35 kg. A package containing substances of 14 ° (c) must not weigh more than 75 kg; it must not contain more than 50 kg of explosives; in the case of a packing conforming to paragraph 1 (c) 4., the package rnust not weigh more than 30 kg nor contain more than 25 kg of explosives. 3. Mixed packing Substances listed under an item number of marginal 2101 may not be included in the same package either with substances grouped under the same or another item num­ ber of that marginal, or with substances or articles of other classes, or with other goods. NOTE: Packages as referred to in marginal 2108 (1) (c) may contain organic nitro-compounds having different compositions and names. 4. Marking and danger labels on packages (s~e Appen­ dix A.9) Packages containing picric acid of 7 ° (a) shall be marked with the name of the substance in clearly legible and indelible red characters. This marking shall be in an official language of the country of departure and also, if that language is not English, or French, or German, in Eng­ lish, French or German, unless international road transport tarrifs, if any, of agreements concluded between the coun­ tries concerned in the transport operation, provide other­ wise. (1) Packages containing substances and articles of .Class la shall bear a label conforming to model No. 1. (2) Packages c~ntaining fragile receptacles not visible 2115 2116 2117 EG>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) from the outside shall bear a label conforming to model No. 12. If the fragile receptacles contain liquids, the packages shall, in addition, except in the case of sealed ampoules, bear labels conforming to model No. 11; these labels shall be affixed high up on two opposite sides of cases or in an equivalent manner when other packagings are used. B. Particulars in the transport document -· (1) The description of the goods in the transport docu­ ment must conform to one of the names underlined in mar­ ginal 2101. Where the name of the substance is not indi­ cated in the case of 8 ° (a) and (b ), the trade name must be used. The description of the goods must be underlined and followed by particulars of the class, the item number (to­ gether with the letter, if any), and the initials «ADR» or "RID" [e.g., la, 3° (a), ADR]. (2) The following must be certified in the transport doc­ ument: "The nature of the goods, and the packaging, are in conformity with the provisions of ADR". (3) For consignments which, under marginal 11105 of Annex B, are to be accepted for carriage as a full load only, the transport document shall also show the mass of each package and the number and nature of the packagings. C. Empty packagings ( 1) Packagings of 15 ° shall be securely closed and be leak-proof to the same degree as though they were full. (2) Empty packagings, uncleaned, of 15 ° shall bear the same danger labels as if they were full. • (3) The description in the transport document shall be: "Empty packaging, la, 15°, ADR (or RID)". This text shall be underlined CLASS lb ARTICLES FILLED ·WITH EXPLOSIVE SUBSTANCES 1. List of articles (1) Among the articles covered by the heading of Class lb, only those listed in marginal 2131 are to be accepted for carriage, and then only subject to the provisions of this Annex and of Annex B. These articles to be accepted for carriage under certain conditions are to be considered as articles of ADR. (2) If the articles listed under 7 °, 10 ° or 11 ° of marginal 2131 are composed of, or filled with, explosive substances listed in marginal 2101, those substances must satisfy the stability and safety conditions laid down concerning them in Appendix A. l. 1 ° Fuses, not primed: (a) rapid combustion fuses (fuses consisting of a thick tube with a core of black powder, or with a core of threads impregnated with black powder, or with a core of nitrated cotton threads); (b) detonating fuses in the form of small-section metal tubes with thin walls and a core filled with an explosive sub­ stance; see also Appendix A.l, marginal 3108; ( c) flexible detonating fuses wrapped in textile or a plas­ tics material, of small section and with a core filled with an explosive substance; see also Appendix A. l, marginal 3109; {d) instantaneous detonating fuses (small-section woven fuses with a core filled with an explosive substance more dangerous than penthrite). • (For other fuses, see Class le, 3 ° (marginal 2171). 2 ° Non-detonating primers (primers which do not pro­ duce a disruptive effect either with the aid of detonators or by other means): {a) percussion caps; (b) 1. primed cases of central-percussion cartridge~, not filled with propellent powder, for firearms of all cali­ bres; 2118 2119 2120 2125 2127 2129 2130 2131 2. primed cases of rim-fire cartridges, not filled with propellent powder, for Flobert weapons and firearms of similar calibres; (c) quick-matches, screw-primers and other similar primers containing a small charge (black powder or other explosives), set in action by friction, percussion or electric­ ity; (d) fuses without any device, e.g. detonator, producing a disruptive effect and withoµt a transmission charge. 3 ° Railway for signals 4 ° Small-arms cartridges, with the exception of those containing a bursting charge (see under 11 °): (a) sporting cartridges; (b) Flobert cartridges; (c) tracer cartridges; (d) incendiary cartridges; (e) other central-percussion cartridges. NOTE: .{\part from sporting cartridges with lead pellets, only cartridges whose calibre does not exceed 13.2 mm are to be considered as articles of 4 °. 5 ° Detonating fuses: . (a) detonators with or without a delayed-action device; delayed-action connecting pieces for detonating fuses; (b) electric detonators fitted with fuses with or without a delayed-action device; (c) detonators connected firmly to a black-powder fuse; (d) detonators with gaines (detonators combined with a transmission charge composed of a compressed explosive); see also Appendix A.I, marginal 3110; (e) fuses with detonators (fused detonators) with or without a transmission charge; (f) detonators with percussion cap ("bouchons allu­ meurs") with or without a delayed action device, with or without a mechanical device for firing, and without a trans mission charge. • . , . .' •• - ' • •. • • 6° Sounding caps (detonators, with or without primers, contained in sheet-metal tubes). • 7 ° Articles with a propellent charge, otl,u;r. than those listed under 8 °; articles with a bursting, charge; articles with a propellent and a bursting charge, provided that they contain only explosive substances of Class la all without a device producing a disruptive effect (e.g. detonator). The charge in these articles may comprise a tracer substance (see also under 8° and 11 °). • NOTE: Non-detonating primers (2°) are allowed in these articles. 8 ° Articles filled with tracer substances or substances intended for signalling, with or without a propellent charge, with or without an ejection charge, and without a bursting charge, in which the propellent or tracer substance is com­ pressed in such a way that the articles cannot explode when ignited. 9° Smoke-producing devices containing chlorates or carrying an explosive charge or an explosive ignition charge. For smoke-producing substances for agricultural and forestry purposes, see Class le, marginal 2171, 2 7 °. 1 O O Boring devices containing a charge of dynamite or of an explosive similar to dynamite, without fuses and with­ out any device producing a disruptive effect (e.g. detona­ tor), hollow-charge devices for industrial purposes, con­ taining not more than 1 kg of explosive secured within the casing, and without a detonator. 11 ° Articles with a bursting charge, articles with a propellent and a bursting charge, all fitted with a device producing a disruptive effect (e.g. detonator), the whole well secured. The mass of each article must not exceed 25 kg. 909 2131 2131 910 E<J>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 2. Provisions A. Packages 1. General condition·s of packing (1) Packagings shall be so closed and leak-proof as to prevent any loss of the contents. The use of metal bands or wires fastened round the packages to ensure their closure is allowed; their use is compulsory with cases having hinged lids if the lids are not fitted with an effective device to obviate any loosening of the closure. (2) The materials of which the packagings and their clo­ sures are made must not be liable to attack by the contents or form harmful or dangerous compounds therewith. (3) Packagins, including their closures, must be suffi­ ciently rigid and strong in all their parts to prevent any loos­ ening during carriage and to meet tl1e normal requirements of carriage. Articles shall be firmly secured in their packagings, and inner packagings shall be firmly secured in outer packagings. Unless otherwise specified in the sec­ tion entitled "Packing of articles of the same kind", inner packagings may be enclosed in outer packagings, either singly or in groups. (4) Cushioning materials shall be suited to the nature of the contents. 2. Packing of articles of the same kind Articles of 1 ° shall be packed as follows: (a) articles of 1 ° (a) and (b): in wooden packagings or in drums made of impermeable fibre. A package must not weigh more than 120 kg; however, a fibre drum must not weigh more than 75 kg; (b) articles ofl 0 ( c ): rolled in lengths or up to 250 m on reels made of wood or fibreboard. The reels shall be placed in wooden cases in such a manner that they cannot come into contact either with one another or with the sides of the cases. A case must not contain more than 1 000 m of fuse; (c) articles of 1 ° (d): rolled in lengths of up to 125 m on reels made of wood or fibreboard which shall be packed in a wooden case, closed by means of screws and with sides not less than 18 mm thick, in such a manner that the reels. cannot come into contact either with one another or with the sides of the case. A case must not contain more than 1 000 m of instantaneous detonating fuse. (1) Articles of 2° shall be packed as follows: (a) articles of 2°(a): caps with an uncovered explosive charge, not more than 500 per box or small case, and caps with a covered explosive charge, not more than 5,000 per box or small case, in sheet-metal boxes, fibreboard boxes or small wooden cases. These packagings shall be placed in a packing case made of wood or sheet-metal; (b) article.s of 2°(b)l.: primed cases of central percus­ sion cartridges, not filled with propellent powder, for fire­ arms of all calibres, cases made of wood or fibreboard or in textile bags; (c) articles of 2 °(b)2.: primed cases of rim-fire car­ tridges, not filled with propellent powder, for Flobert weap­ ons and firearms of similar calibres, not more than 5,000 per box, in boxes made of sheet-metal or fibreboard which shall be placed in a packing case made of wood or sheet­ metal; however, these primed cases for rim-fire cartridges may also be packed, not more than 25,000 per bag, in a bag which must be secured by means of corrugated fibre­ board in a packing case made of wood or iron; (d) articles of 2° (c) and (d): in boxes made of fibre­ board, wood or sheet-metal which shall be placed in packagings made of wood or metal. (2) A package containing articles of 2 ° (a), (c) or (d) must not weigh more than 100 kg. • ( 1) Articles of 3 ° shall be packed in cases made of boards not less than 18 mm thick, tongued and grooved and assembled by means of wood screws. For signals shall be secured in cases by cushioning materials in such a man 2132 2133 2134 2135 ner that they cannot come into contact either with one an­ other or with the sides of the case. (2) A package must not weigh more than 50 kg. (1) Articles of 4 ° (a), (b) and (e) shall be placed tightly in firmly-closing boxes made of sheet metal, wood or fibre­ board; these boxes shall be housed, leaving no empty spaces, in packing cases made of metal, wood, hardboard, solid fibreboard or corrugated fibreboard; the fibreboard must have been rendered impermeable by impregnation and be of sufficient mechanical strength. • Fibreboard cases shall be closed by means of adhesive strips of sufficient strength or in an equivalent manner. The production model of cases made of solid fibreboard or cor­ rugated fibreboard must be approved by the competent au­ thority of the country of departure. (2) Articles of 4° (c) and (d) shall be placed, not more than 400 per box, in boxes made of sheet-metal, wood or fibreboard; these boxes shall be packed securely in pack­ ing cases made of metal or wood. (3) A package must not weigh more than 100 kg; how­ ever, where hardboard or fibreboard cases are used, a package containing articles of 4 ° (a), (b) or (e) must not weigh more than 40 kg. ( 1) Articles of 5 ° shall be packed as follows: (a) articles of 5 ° (a): not more than 100 per receptacle in the case of detonators and not more than 50 per recepta­ cle in the case of connecting pieces, in receptacles, made of sheet-metal or impermeable fibreboard, in which they shall be well protected against ignition and secured by cushion­ ing materials. Sheet-metal receptacles shall be lined with a resilient material. The lids shall be secured all round by ad­ hesive strips. Receptacles shall, not more than 5 per packet or box in the case of detonators and not more than 10 per packet or box in the case of connecting pieces, be enclosed in a packet or placed in a fibreboard box. The packets or boxes shall be packed in a wooden case closed by means of screws and with sides not less than 18 mm thick, or in a sheet-metal packaging, the case or packaging being se­ cured by cushioning materials in a packing case with sides not less than 18 mm thick in such a manner that there is a space of not less than 3 cm filled with cushioning materials at all points between the wooden case or sheet-metal pack­ aging and the packing case; (b) articles of 5 ° (b ): not more than 100 per packet, in packets with alternate detonators lying towards opposite ends of the packet. Not more than 10 of these packets shall be tied together to form a collective packet. Not more than 5 of these collective packets shall be secured by cushioning materials in a wooden packing case with sides not less than 18 mm thick, or in a sheet metal packaging, in such a man­ ner that there is a space of not less than 3 cm filled with cushioning materials at all points between the collective packets and the packing case or sheet-metal packaging; ( c) articles of 5 ° ( c ): fuses fitted with detonators, rolled into coils; not more than 10 coils shall be made into a roll which shall be wrapped in paper. Not more than 10 rolls shall be secured by cushioning materials in a small wooden case closed by means of screws and with sides not less than 12 mm thick. Not more than 10 small cases shall be se­ cured by cushioning materials in a packing case with sides not less than 18 mm thick in such a manner that there is a space of not less than 3 cm filled with cushioning materials at all points between the small cases and the packing case; ( d) articles of 5 ° ( d): 1. not more than 100 detonators per case, in wooden cases with sides not less than 18 mm thick, in such a man­ ner that the detonators are spaced not less than 1 cm from one another and from the sides of the case. The said sides shall be mortised and the bottom and lid shall be secured by screws. If the case is lined with zinc sheet of aluminium sheet, a side thickness of 16 mm is sufficient. The case shall be secured by cushioning materials in a packing case with sides not less than 18 mm thick in such a manner that 2136 2137 E<l>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: 6EYTEPO) there is a space of not less than 3 cm filled with cushioning materials at all points between it and the packing case; or 2. not more than 5 detonators per box, in sheet~metal boxes, the detonators being placed therein in slatted wooden frames or in holed pieces of wood. The lid shall be secured all round by adhesive strips. Not more than 20 sheet-metal boxes shall be placed in a packing case with sides not less than 18 mm thick; (e) articles of 5 ° (e): not more than 50 per case, in wooden cases with sides not less than 18 nim thick. The ar­ ticles shall be secured within the cases by a wooden struc­ ture in such a manner that they are spaced not less than 1 cm from one another and from the sides of the case. The sides of the case shall be mortised and the bottom and lid shall be secured by screws. Not more than 6 cases shall be secured by cushioning materials in a packing case with sides not less than 18 nim thick in such a manner that there is a space of not less than 3 cm filled with cushioning mate­ rials at all points between the cases and the -packing case. The space may be reduced to not less than 1 cm if it is filled with porous wood-fibreboard slabs. If the articles are indi­ vidually packed and firmly secured in hermetically-closing boxes made of sheet-metal or a plastics material, they may be placed in a wooden packing case with sides not less than 18 mm thick. The articles must be separated from one an­ other and firmly secured by fibreboard or by wood­ fibreboard slabs; (f) articles of 5 ° (f): 1; not more than 50 per case, in wooden or metal cases; in these cases each detonating part of the "bouchon allumeur" shall be so accommodated in a slotted wooden support that the distance between adjacent detonators and between the detonators of the outermost "bouchons allumeurs" and the side of th~ case is not less than 2 cm; closing the lid of the case shall ensure complete immobility of the whole; not more than 3 cases shall be placed, leaving no empty spaces, in a wooden packing case with sides not less than 18 mm thick; or 2. in boxes made of wood or metal; in these boxes each "bouchon allumeur" shall be so supported by a frame that the distance between t"'o "bouchons allumeurs" and be­ tween a "bouchon allumeur" and the side of the box is not less than 2 cm and that the immobility of the whole is en­ sured; these boxes shall be placed in a packing case with sides not less than 18 mm thick in such a manner that there is a space of not less than 3 cm filled with cushioning mate­ rials at all points between the boxes and between the boxes and the packing case; a package must not contain more than 150 "bouchons allumeurs". (2) The lid of the packing case shall be closed by means of screws or of hinges and folding bars. (3) Each package containing articles of 5 ° shllil be pro­ vided with a closure protected either by lead or other seals (stamp or mark) applied to two screw-heads at the ends of the major axis of the lid or of the folding bars, or by a strip, bearing the trade mark, gummed on to the lid and on two opposite sides of the case. (4) A package must not weigh more than 75 kg; pack­ ages weighing more than 30 kg must be fitted with means of handling. • ( 1) Articles of 6 ° shall be rolled separately i11 paper and placed in corrugated fibreboard wrappings. They shall be packed, not more than 25 per box, in boxes made of fibre­ board or sheet-metal. The lids shall be secured all round by adhesive strips. Not more than 20 boxes shall be placed in a wooden packing case. (2) A package must not weigh more than 50 kg. Pack­ ages weighing more than 30 kg shall be fitted with means of handling. (1) Articles of 7 ° shall be packed in wooden cases closed by means of screws or of hinges and folding bars and with sides not less than 16 mm thick, or in receptacles made of metal or a suitable plastics material of adequate 2138 2138 2139 strength. The lids and bottoms of the wooden cases may also be made of highly - compressed hardboard equalling the sides in strength. Articles weighing more than 20 kg may also be despatched in crates or without packing. (2) A package must not weigh more than 100 kg if it contains articles each of which weighs not more than 1 kg. Cases which, with their contents, weigh more than 30 kg shall be fitted with means of handling. (1) Articles of 8° shall be packed in wooden cases, in drums made of fibreboard which has been rendered imper­ meable, or in receptacles made of metal or of a suitable plastics material of adequate strength. The ignition head shall be protected in such a manner as to prevent any scat­ tering of the charge from the article. (2) A package must not weigh more than 100 kg; how­ ever, where fibre drums are used, a package shall not weigh more than 7 5 kg. Cases which, with their contents, weigh more than 30 kg shall be fitted with means of han­ dling. Articles of 9 ° shall be enclosed in wooden packagings. A package must not weigh more than 7 5 kg; packages weighing more than 30 kg shall be fitted with means of han­ dling. Articles of 10° shall be packed in wooden cases. Pa~k­ ages weighing more than 30 kg shall be fitted with means of handling. Articles of 11 ° shall be packed as follows: (a) articles less than 13.2 mm in diameter: not more than 25 per box, packed tightly in firmly - closing fibre­ board boxes or in receptacles made of a suitable plastics material of adequate strength; these boxes or receptacles shall be placed, leaving no empty spaces, in a wooden case, with sides not less than 18 mm thick, which may be lined with tin-plate, zinc or aluminium sheet, or a suitable plas­ tics or similar material of adequate strength. A package must not weigh more than 60 kg. Packages weighing more than 30 kg shall be fitted with means of han dling; ' . '. (b) articles from 13.2 mm to'57 mm in diameter: 1. separately in a tube made of fibreboard or of a suita­ ble plastics material, strong, close-fitting and clostng firmly at both ends; or .. . • strong, close-fitting, closed at ~ne end and open at the other; or • open at both.ends but with an inner projection or other suitable internal device to prevent the article from moving. Packed in this manner, not more than: 300 articles not less than 13.2 mm and not more than 21 mm in diameter; or 60 articles more than 21 mm but not more than 3 7 mm in diameter; or 25 articles more than 37 mm but not more than 57 mm in diameter shall be placed in layers in a wooden case with sides not less than 18 mm thick, the wooden case being lined with tin-plate, zinc sheet, or aluminium sheet. In the case of articles packed in tubes open at both ends or at one end, the packing case shall be lined on the side or sides adjacent to the open ends of the tubes either with a felt pad not less than 7 mm thick or with a sheet of the same thickness of double - faced corrugated fibreboard or simi­ lar material. A package must not weigh more than 100 kg. Packages weighing more than 30 kg shall be fitted with means of han­ dling; 2. articles 20 mm in diameter may also be packed, not more than 10 per box, in strong, closely-fitting fibreboard boxes coated with paraffin wax and equipped with a honey­ combed bottom insert and with partitions made of fibre­ board coated with paraffin wax. The boxes shall be closed by a gummed flap. Not more than 30 boxes shall be tightly packed in a wooden case with sides not less than 18 mm thick, the wooden case being lined with zinc sheet, tin-plate or aluminium sheet. 911 2140 2141 2142 2143 912 EG>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: llEYTEPO) A package must not weigh more than 100 kg. Packages weighing more than 30 kg shall be fitted with means of han­ dling; 3. articles not more than 30 mm in diameter may, in a number not exceeding that indicated under 1., also be put on lo strips and packed in a strong steel receptacle. This re­ ceptacle may be cylindrical. , These articles put on to strips shall be surrounded by a suitable device so as to constitute a compact unit and as to prevent individual articles from becoming detached. One or more units shall be so fixed in the receptacle that they cannot be displaced. The ends of articles put on to strips shall rest on shock­ absorbing non-metallic supports. The lid of the receptacle must be so closed as to be leak­ proof and be so secured by a locking device capable of be­ ing sealed that the articles cannot fall out. A package must not weigh more than 100 kg. Packages weighing more than 30 kg shall be fitted with means of.han­ dling. Receptacles capable of being rolled shall have their lids fitted with a strong handle enabling them to be carried; 4. articles not less than 30 mm and not more than 57 mm in diameter may also be packed separately in a strong, closely-fitting, hermetically-closed cylindrical box made of fibreboard, fibreboard or a suitable plastics material. Not more than 40 of these boxes shall be placed in layers in a wooden case- with sides not less than 18 mm thick. A package must not weigh more than 100 kg. Packages weighing more than 30 kg shall be fitted with means of han dling; . ;· . (c) other articles of 11 °: in conformity with the provi­ sions of marginal 2139 (1). A package must not weigh more than 100 kg. Packages weighing more. than 30 kg shall be fitted with means of handling. NOTE: In the case of articles containing both propellent and bursting charges, the diameter referred to is that of the cylindrical portion containing fue . bursting charge. 3. Mixed packing . . (I) Articles listed under an item number of marginal 2131 may not be included in: the same package either with articles of a different kind put of the same item number, or with articles of-another item number of that marginal, or with substances or articles belonging to other classes, or with other goods. • (2) The following may, however, be included in the same package: (a) articles of 1 ° with one another: When articles of I O (a) and (b) are included in the same package, they shall be packed in conformity with marginal 2133 (a). When articles of 1 ° (c) are ii.eluded in the same package with articles of I O (a) or (b) or both, those of I O (c) shall be made up into packages in conformity with the provisions applicable to them and the outer packaging shall be that prescribed for articles of 1 ° (a) or (b).A package must not weigh more than 120 kg; • (b) articles of 2° (a) with those of 2° (b), provided that both are contained in inner packagings consisting of boxes placed in wooden cases. A package must not weigh more than 100 kg; (c) articles of 4 ° with one another, taking into account the provisions for inner packaging, in a wooden outer pack­ aging. A package must not weigh more than I 00 kg; (d) articles of 7° with those of 5 ° (a), (d), (e) and (f), on condition that the packaging of these latter prevents the transmission of a possible detonation to the articles of 7 °. In one package the number of articles of 5 ° (a), (d), (e) and ( f) must be the same as that of the articles of 7 °. A package must not weigh more than 100 kg. 4. Marking and danger labels on packages (see Appen dix A.9) • Packages containing articles of Class lb shall bear a label conforming to model No 1. However, packages containing 2144 2145 articles of 1 ° ( d), 5 ° and 6 ° shall bear two labels conform­ ing to model No. 1. B. Particulars in the transport document (I) The description of the goods in the transport docu­ ment must conform to one of the names underlined in mar­ ginal 2131; it must be underlined and followed by particu­ lars of the class, the item number (together with the letter, if any), and the initials «ADR» or «RID» (e.g., lb, 2° (a) ADR). • . ' (2) The following must be certified in the transport docu­ ment: « The nature of the goods, and the packaging, are in con­ formity with the provisions of ADR». C. Empty packagings No provisions. CLASS le IGNITERS, FIREWORKS AND SIMILAR GOODS 1. List of goods (1) Among the substances and articles covered by the heading of Class I c, only those listed in marginal 21 71 are to be accepted for carriage, and then only subject to the provisions of this Annex and of Annex B. These substances and articles to be accepted for carriage under certain con­ ditions are to be considered as substances and articles of ADR. (2) Articles to be accepted must fulfill the following con­ ditions: (a) The explosive charge shall be constituted, arranged and distributed in such a manner that neither friction, shaking, shock nor ignition of the packed articles can lead to an explosion of the whole contents of the package; (b) white or yellow phosphorus may not be used except in articles of 2° and 20°; (c) the detonating compound of fireworks (21 ° - 24 °), flash-powders (26°), and the smoke-producing com­ pounds of pesticides (27°), must not contain chlorates; (d) the explosive charge must satisfy the stability condi­ tions of Appendix A. I, marginal 3111. A. lgniters: 1 ° (a) Safety matches (with· a potassium chlorate and sulphur base); (b) matches with a base of potassium chlorate and of phosphorus sesquisulphide, also friction igniters. 2 ° Strips of amorces for safety lamps and strips of paraffin-waxed amorces for safety lamps. 1,000 amorces must not contain more than 7 .5 g explosive. For strips of caps, see under 15°. 3 ° Slow-combustion fuses (fuses consisting of a thin im­ permeable tube with a narrow - section core of black pow­ der). For other fuses, see Class lb, I O (marginal 2131). 4 ° Pyroxylin thread (nitrated cotton thread). See also Appendix A.l, marginal 3101. 5 ° Tubular igniters ("lances d' allumage") (tubes, made of paper or fibreboard, containing a small quantity of a fuse composition of oxygenated substances and organic sub­ stances and, possibly, of nitrated aromatic compounds) and thermite caps with pellet igniters. 6 ° Safety igniters for fuses (paper cartridges containing a primer pierced by a thread intended to cause friction or tearing, or similar devices). . . 7 ° (a) Electric primers without detonator; (b) pellets for electric primers. • 8° Electric igniters (e.g. igniters intended for igniting photographic magnesium powders). The charge of each 2146 2147 2148 2162 2163 2164 2169 2170 2171 2171 <I>EK 104 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) must not exceed 30 mg nor contain more than 1 O per cent fulminate of mercury. ·. NOTE: Appliances of the electric bulb type producing a sudden light and containing an ignition charge similar to that of electric igniters are not subject to the provisions of ADR. B. Pyrotechni~ articl~s and toys: caps and strips (strings) of caps; detonabng articles: 9° !ndoor pyrot~chnic articles (e.g. Bosco cylinders, confettI bombs, cotillon fruits). Articles with a nitrated­ cotton (collodion-cotton) base must not contain more than l g per article. l O ° Fulminating bonbons, flower crackers, strips of ni trated paper (collodion paper). • 11 °. (a) Fulminating peas, fulminating grenades and other similar pyrotechnic toys containing fulminate of sil­ ver; (b) fulminating matches; (c) accessories with fulminate of silver. For (a), (b) and (c): 1 000 articles must not contain more than 2.5 g fulminate of silver. 12° Detonating pebbles, each carrying on the outside a c~arge of not more than 3 g of an explosive other than ful­ minate. 13 ° Pyrotechnic matches (e.g. Bengal matches, golden­ ram matches or cascade-of-flowers matches). 14 ° Miracle candles without ignition heads. . 15 ° Caps for children's toys, strips (strings) of caps and nngs of caps. 1 000 caps must not contain more than 7.5 g of an explosive free from fulminate. For strips of caps for safety lamps, see under 2 °. . 16 ° Explosive corks with an explosive charge having a phospho;11-1~ and chlorate base or with a charge of fulminate or a similar compound compressed into cardboard cartidges. 1 000 corks must not contain more than 60 g chlorate explosive nor more than 10 g of fulminate or of a compound with a fulminate base. 1 7 ° Round petards with an explosive charge having a phosphorus and chlorate base. 1000 petards must not con­ tain more than 45 g explosive. 18° Cardboar<i caps (toy ammunition) with an explosive charge having a phosphorus and chlorate base or with a charge of fulminate or a similar compound. 1 000 caps must not contain more than 25 g explosive. 19° Cardboard caps exploding under foot, with a pro­ tected charge having a phosphorus and chlorate base. 1 000 caps must not contain more than 30 g explosive. 20° (a) Detonating sheets; (b) martinikas (so-called Spanish fireworks). Both comprise a mixture of white (yellow) and red phos­ phorus with potassium chlorate and not less than 50 per cent inert substances not taking part in the decomposition of the mixture of phosphorus and chlorate. A sheet must not weigh more than 2.5 g and a martinika not more than 0.1 g. C. Fireworks. 21 ° Anti-hail rockets not fitted with a detonator, bombs and firepots. The charge, including the propellent charge, must not weigh more than 14 kg per article, the bomb or firepot not more than 18 kg in all. 22 ° Incendiary bombs, rockets, Roman candles. foun­ tains, wheels and similar fireworks, with a charge not weighing more than 1,200 g per article. 23 ° Cannon shots each containing not more than 600 g granulated black powder or 220 g of an explosive not more dangerous than aluminium powder with potassium perchlorate, rifle shots (crackers) each containing not more than 20 g granulated black powder, all provided with fuses with covered ends; and similar articles for producing a loud detonation. For railway fog-signals, see Class lb, 3 ° ( marginal 2131). 2171 24 ° Small fireworks (e.g. jumping - crackers, serpents, golden rain, silver rain, if they contain not more than 1,000 g granulated black powder per 144 articles; volca­ noes and hand comets, if they contain not more than 30 g each of granulated black powder). 25 ° Bengal fires without ignition heads ( e.g. Bengal torches, lights, flames). 26 ° Magnesium flash - powders, not more than 5 g per bag or 'tube, in paper bags or in small glass tubes. D. Pesticides (substances and articles): 27° Smoke - producing substances for agricultural and forestry purposes, and smoke - producing cartridges for use as pesticides. For smoke-producing devices containing chlorates or carrying an explosive charge or an explosive ignition charge, see Class lb, 9° (marginal 2131). 2. Provisions A. Packages 1. General conditions of packing. (1) Packagings shall be so closed and leak - proof as to prevent any loss of the contents. (2) Packagings, including their closures, must be suffi­ ciently rigid and strong in all their parts to prevent any loos­ ening during carriage and to meet the normal requirements of carriage. Articles shall be firmly secured in their packagings, and inner packagings shall be firmly secured in outer packagings. Unless otherwise specified in the sec­ tion entitled "Packing of a single substance or of articles of the same kind", inner packagings may be enclosed in outer packagings, either singly or in groups. (3) Cushioning materials shall be suited to the nature of the contents. 2. Packing of a single substance or of articles of the same kind. • • (1) Articles of l O (a) shall be packed,in,boxes-cir in books. These boxes or books shall be wrapped in stout paper to · form a collective packet ,all the· folds of which shall be glued. The books may also be placed in boxes made of thin fibreboard or of a material not readily inflamfuable-'(e.g. cellulose acetate). The fibreboard boxes or- the collective packets shall be placed in a·strong case made of wood, metal, compressed - wood hardboard, strong solid fibre­ board or double - faced corrugated fibreboard. All joints of metal cases shall be closed by soft soldering or by double - seaming. Fibreboard cases shall be closed my mearis of joined flaps. The edges of the outer flaps, and all joints,· must be either glued or firmly closed by some other suitable means. If the fibreboard boxes or collective packets are-packed in fibreboard cases, the mass of a package may not exceed. 20 kg. (2) Articles og l O (b) shall be so packed in boxes as lo prevent any movement. Not more than 12 of these boxes shall be enclosed in a packet all the folds of which shall be glued.· Not more than 12 of these packets shall be wrapped in stout paper to form a collective packet all the folds of which shall be glued. The collective packets shall be placed in a strong case made of wood, metal, compressed - wood hard­ board, strong solid fibreboard or double faced corrugated fibreboard. All joints of metal cases shall be secured-by soft solder ing .. or double seaming. "' Fibreboard cases shall be closed by means of joined flaps. The edges of the outer flaps, and all joints, must be either glued or firlllly closed by some other suitable means. If the collective packets are packed in fibreboard cases, the mass of a package must not exceed 20 kg. ( 1) Articles of 2 ° shall be packed in boxes made of sheet­ metal or fibreboard. Not more than than 30 sheet-metal or 913 ,2172 2173 2174 914 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) 144 fibreboard boxes shall be enclosed in a packet which must not contain more than 90 g explosive. These packets shall be placed in a packing case, with well-jointed sides not less than 18 mm thick, lined with stout paper or with thin zinc or aluminium sheet or with a sheet of a plastics material not readily inflammable. A side thickness of 11 mm is sufficient for a package weighing not more than 35 kg if the case is encircled with an iron band. , (2) A package must not weigh more than 100 kg. (1) Articles of 3° shall be packed in wooden cases lined with shout paper or thin zinc or aluminium sheet, or in drums of impe'rmeable fibreboard. Small consignments weighing not more than 20 kg, wrapped in corrugated fibreboard, may also be made up into packets in stout two-ply packing paper securely tied with string. (2) Where fibre drums are used, a package must not weigh more than 75 kg. (1) Pyroxylin thread of 4 ° shall be rolled, in lengths not ex­ ceeding 30 m per strip, on fibreboard strips. Each roll shall be wrapped in pape·r. Not more than 10 of these rolls shall be wrapped in packing paper to form packets which shall be secured by cushioning materials in small wooden cases. The cases shall be placed in a wooden packing case. (2) A package must not contain more than 6 000 m of pyroxylin thread. (1) Articles of 5 ° shall be packed, not more than 25 per box, in boxes made of tin-plate or fibreboard; however, thermite caps may be packed, not more than 100 per box, in fibreboard boxes. Not more than 40 of these boxes shall be secured by cushioning materials in a wooden case in such a manner that they connot come into contact either with one another or with the sides of the case. (2) A package must not weigh more than 100 kg. (1) Articles of 6 ° - 8 ° shall be packed: (a) articles of 6 °: in wooden cases; (b) articles of 7 ° (a); in wooden cases or in wooden casks or in drums made of impermeable fibreboard; (c) articles of 7° (b): not more than 1 000 per box, se­ cured by sawdust cushioning in fibreboard boxes divided into not less than three compartments each containing ap­ proximately the same number of articles and separated by interposed fibreboard sheets. The lids of boxes shall be se­ cured by gummed strips applied all round. Not more than 100 of these fibreboard boxes shall be placed in a perfo­ rated sheet-iron receptacle. This receptacle shall be se­ cured by cushioning materials in a wooden packing case closed by means of screws and with sides not less than 18 mm thick, in such a manner that there is a space of not less than 3 cm filled with cushioning materials at all points be­ tween the sheet-iron receptacle and the packing case; (d) articles of 8°: in fibreboard boxes. The boxes shall be made up into a packet containing not more than 1 000 electric igniters. The packets shall be placed in a wooden packing case. (2) In the case of fibre drums, a package containing arti­ cles of 7° (a) must weigh more than 75 kg. A package con­ taining articles of 7 ° (b) must not weigh more than 50 kg; if it weighs more than 30 kg, it shall be filled with means of handling. (1) Articles of9° - 26° shall be enclosed (inner packag­ ing): (a) articles of 9° and 10°: in paper packagings or in boxes; (b) articles of 11 ° (a): not more than 500 per fibreboard box or per small wooden case, secured by sawdust cushion­ ing: 1. in fibreboard boxes which shall be wrapped in paper; or 2. in small wooden cases; (c) articles of 11 ° (b): not m«;>re than 10 per book, in books; not more than 100 books together shall be packed in a fibreboard box or wrapped in stout paper: 2175 2176 2177 2178 2179 (d) articles of 11 ° (c): not more than 10 per bag, in bags made of paper or of a suitable plastics material; not more than 100 bags together shall be packed in a fibreboard box; (e) articles of 12 °: not more than 25 per box, in fibre­ board boxes; (f) articles of 13°: in boxes wrapped in paper to form packets each containing not more than 12 .boxes; (g) articles of 14 °: in boxes or in bags made of paper or of a suitable plastics material. These packagings shall be wrapped in paper to form packets each containing not more than 144 of these articles; (h) articles of 15 °: in fibreboard boxes each containing: not more than 100 caps each charged with not more than 5 mg explosive; or not more than 50 caps each charged with not more than 7.5 mg explosive. Not more than 12 of these boxes shall be made up in paper into a roll and not more than 12 of these rolls shall be wrapped in packing paper to form a packet. Strips (strings) of 50 caps, each cap being charg~d with not more than 5 mg explosive, may be packed in the follow­ ing manner: 5 strips (strings) per box, in fibreboard boxes wrapped 6 together in paper equivalent in strength \o Kraft paper of a minimum mass of 40 g/m2; 12 small packets so made up shall be wrapped together in paper of the same quality to form a large packet; (i) articles.of 16°: secured by cushioning materials, not more than 50 per box, in fibreboard boxes. The corks shall be glued to the bottom of the boxes or fixed in position there by some equivalent method. Each box shall be wrapped in paper and not more than 10 of these boxes shall be wrapped in packing paper to form a packet; (k) articles of 17 °: not more than 5 per box, in fibre­ board boxes. Not more than 200 boxes, arranged in rolls, shall be placed together in a collective fibreboard box: (I) articles of 18 °: secured by cushioning materials, not more than 10 per box, in fibreboard boxes. Not more than 100 boxes, arranged in rolls, shall be wrapped in paper to form a packet; (m) articles of 19 °: secured by cushioning materials, not more than 15 per box, in fibreboard boxes. Not more than 144 boxes, arranged in rolls, shall be packed in a second fibreboard box; (n) articles of 2'0° (a): secured by cushioning riiaterials, not more than 144 per case, in fibreboard cases; (o) articles of 20° (b): not more than 75 per box, in fi­ breboard boxes; not more than 72 boxes shall be wrapped •. in fibreboard to form a packet; (p) articles of 21 °: in fibreboard boxes or in stout paper. If the ignition point of the articles is not covered by a pro­ tective cap, each article must first be wrapped separately in paper. The propellent charge of bombs weighing more than 5 kg shall be protected by a paper case covering the lower part of the bomb; (q) articles of 22 °: in fibreboard boxes or in stout paper. However, large fireworks need not have an inner packag­ ing if their ignition point is covered by a protective cap: (r) articles of 23 °: secured by cushioning materials in boxes made of wood or fibreboard. The ignition heads shall be protected by a protective cap; (s) articles of 24 °: in fibreboard boxes or in stout paper; (t) articles of 25 °: in fibreboard boxes or in stout paper. However, large fireworks need not have an inner packag­ ing if their ignition point is covered by a protective cap: (u) articles of 26 °: in fibreboard boxes. A box must not contain more than 3 glass tubes. (2) The inner packagings mentioned under (1) shall be placed: (a) packagings containing articles of 10 °, 13 ° and 14 °., in wooden packing cases; (b) packagings containing substances or articles of 9°, 11 °, 12 ° and 15 ° - 26°, in wooden packing cases with E<DHMEPII THI KYBEPNHIEQI (TEYXOI LlEYTEPO) well - jointed sides not less than 18 mm thick, lined with stout paper or. thin zinc or aluminium sheet. A side thick­ ness of 11 mm is sufficient for a package weighing not more than 35 kg if the case is encircled with an iron band. The contents of a packing case are to be limited as fol lows: for articles of 1 7 °, to 50 outer fibreboard boxes; for articles of 18 °, to 25 packets; for articles of 20° (a), to 50 fibreboard cases; for articles of 20° (b), to 50 packets, each of 72 fibre­ board boxes; and for articles of 21 °, lo a number of articles such that the mass of their total charge does not exceed 56 kg: (c) packaging containing magnesium flash powders (26°), either in conformity with (b) above, or in wooden packing cases each weighing not more than 5 kg, or, in the case of packagings in the form of paper bags, in strong fi­ breboard cases each weighing not more than 5 kg. (3) Wooden cases containing articles with an explosive charge with a phosphorus and chlorate base must be closed by means of screws. (4)Apackagecontainingarticlesof9°, 11 °, }2°.15° 22 ° or 24 ° - 26 ° must not weigh more than 100 kg; it must not weigh more than 50 kg if it contains articles of 23 ° or more than 35 kg if the sides of the case are only 11 mm thick and the case is encircled with an iron bai;d. (1) Substances or articles of 27° shall be packed in wooden cases lined with packing paper, oiled paper or cor­ rugated fibreboard. No lining is necessary if these sub­ stances and articles are wrapped in paper or fibreboard. (2) A package must not weigh more than 100 kg. (3) Smoke-producing cartidges for use as pesticidf's Special conditions: Description Item No. • of substance 10 Matches 2° and 3~ Strips of amorces and slow-combustion fuses 40 Pyroxylin thread 5° - 8° All articles 9° - 20° All articles 21°-25° All articles 26° and 27° All articles and substances 2180 may, if wrapped in paper or fibreboard, likewise be packed: (a) in corrugated-fibreboard boxes or in strong fibre­ board cases; such a package must not weigh more than 20 kg; or (b) in ordinary-fibreboard cases; such a package must not weigh more than 5 kg. 3. Mixed packing (1) Substances and articles grouped under the same item number may be included in the same package. The inner packagings shall conform to what is laid dawn for each dangerous substance, and the outer packaging shall be that laid down for the dangerous substances of the item number in question. In this connection a fibreboard case containing articles of 20 ° (a) shall be deemed equivalent to a packet containing articles of 20° (b). (2) If smaller quantities are not prescribed in the section entitled "Packing of a single substance or of articles of the s ame kind'.', dangerous substances of this class. in quanti­ ties not exceeding 6 kg for all of the dangerous substances listed under the same item number or the same letter. mav be enclosed in the same package either with dangerou~ substances of another item number or of another letter of the same class, or with dangerous substances belonging to other classes (if mixed packing is likewise permitted in the case of such substances), or with other goods, subject to the following special conditions. The inner packagings must satisfy the general and spe­ cial conditions of packing. In addition, the general provi­ sions contained in marginals 2001 (7) and 2002 (6) and (7) must be observed. A package must not weigh more than 100 kg. or riwre than 50 kg if it contains articles of 23 ° Maximum quantity •. ~; . per per Speci~I receptacle package provisions 5 kg 5 kg Must not be packed together with substances of Classes 3, 4.1 and 4.2 Mixed packing not allowed 1 500 m of pyroxylin thread Mixed packing not allowed Mixed packing allowed only ,rith small wares or non pyrotechnic toys, from which they must be kept separate. The collective case must meet the requirements laid down for those articles con tained therein in respect of which marginal 21 79 (2) and (3) imposes the most strin gent conditions Mixed packing allowed only with one another. The collec live case must meet the re quirements laid down for those articles contained therein in respect of which marginal 2179 (2) and (3) imposes the most stringent conditions Mixed packing 1101 allowed 915 2181 916 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) 4. Marking and danger labels on packages (see Appen­ dix A.9) . (1) Packages containing articles of Class le. 16° or 21 ° to 23 ° shall bear a label conforming to model No. I. (2) Packages containing fragile receptacles not 1isible from the outside shall bear a label conforming to model !'lo. 12. B. Particulars in the transport document (1) The description of the goods in the transport docu­ ment must conform to one of the names underlined in mar­ ginal 2171; it must be underlined and followed by particu­ lars of the class. the item number (together with the let1er. if any), and the initials "ADR"' or ''RID"" [e.g. le. 1 ° (a). ADR]. The wording ''Fireworks of ADR. le. item number ...... ", with particulars of the item numbers under which the substances or articles to be carried are listed. is also al­ lowed in the transport document. (2) In the case of substances- or articles of 2 °. 4 °. 5 °. 8°, 9°, 11 °, 12° and 15° - 27°, the follo11ing must be certified in the transport document: .. The nature of the goods, and the packaging. are in conformity with the pro1·i • sions of ADR". C. Empty packagings No provisions. CLASS 2 GASES: COMPRESSED, LIQUEFIED OR DISSOLVED UNDER PRESSURE . 1. List of substances (1) Among the substances and articles covered by the heading of Class 2, only those listed in marginal 2201 are to be accepted for carriage, and then only subject to the re­ quirements of this Annex and to the provisions of Annex B. These substances· and'atticles to be accepted for carriage under certain ·. conditions • are ·to·. be considered as sub­ stances and articles of ADR. . (2) Substances .having a critical ·temperature lower than 50°C or, at 50°C, a vapour pressure greater than 300 kPa(3 bar-) are deemed to be substances of Class 2. (3) The substances and articles of Class 2 are classified as ·follows:· • A: Compressed gases having a critical temperature below - l0°C; B: Liquefied gases ·having a critical temperature of l0°C or above: a. Liquefied gases having a critical temperature of 70°C or above; b. Liquefied gases having a critical temperature of l0°C or above, but below 10°C; C: Deeply-refrigerated liquefied gases; D: Gases dissolved under pressure; E: Aerosol dispensers and non-refillable containers of gas urider pressure; F: Gases subje~t to special requirements; and G: Empty receptacles and empty tanks. The substances and articles of Class 2 are subdivided according to their chemical properties, as follows: (a) non-inflammable; (a t) non-inflammable, toxic; (b) inflammable; (b t) inflammable, toxic; (c) chemically unstable; (c t) chemically unstable, toxic;:. Unless otherwise specified, chemically unstable sub­ stances shall be considered to be inflammable. The names of corrosive gases and of articles containing such gases shall be followed by the word "corrosive" in brackets. 2182 2183 2184 2185 2189 2190 2191 2199 2200 ( 4) Substances of Class 2 which are listed among the chemically unstable gases are to be accepted for carriage only if the necessary steps have been taken to prevent their dangerous decomposition, dismutation or polymerization during carriage. To this end, care should in particular be taken to ensure that receptacles and tanks do not contain any substances Ii­ . able to promote these reactions. A. Compressed gases [see also marginal 2201a under (a)]. For gases of 1 ° (a) and (b) and 2° (a) in aerosol dis­ pensers or in non-refillable containers for gases under pressure, see under 10 ° and 11 °. Gases having a critical temperature below -l0°C are considered to be com­ pressed gases for the purposes of ADR. 1 ° Pure gases and technically-pure gases (a) Non-inflammable Argon; helium; krypton; neon; nitrogen; oxygen; tetrafluo­ romethane (R 14 ). (a t) Non-inflammable, toxic Boron trifluoride; fluorine (corrosive); silicon tetrafluoride (corrosive). (b) Inflammable Deuterium; hydrogen; methane. (b t) Inflammable, toxic Carbon monoxide. (c t) Chemically unstable, toxic Nitric oxide (nitrogen monoxide) NO (non-inflammable). • 2 ° Mixture of gases (a) Non-inflammable Mixtures of two or more of the following gases: rare gases (containing not more than 10 per cent xenon by vol­ ume), nitrogen, oxygen, carbon dioxide (not more than 30 per cent by volume); non-inflammable mixtures of two or more of the following gases: hydrogen, methane, nitrogen, rare gases ( containing not more than 10 per cent xenon by volume), not more than 30 per cent carbon dioxide by vol­ ume; nitrogen containing not more than 6 per cent ethylene by volume; air. (b) Inflammable Mixtures of not less than 90 per cent methane by volume with hydrocarbons of 3 ° (b) and 5 ° (b); inflammable mix­ tures of two or more of the following gases: hydrogen, methane, nitrogen, rare gases (containing not more than 10 per cent xenon by volume), not more than 30 per cent carbon dioxide by volume; natural gas. (b t) Inflammable, toxic Town gas; mixtures of hydrogen with not more than 10 per cent hydrogen selenide or phosphine or silane or germane by volume or with not more than 15 per cent arsine by vol­ ume; mixtures of nitrogen or rare gases (containing not more than • 10 per cent xenon by volume) with not more than 10 per cent hydrogen selenide or phosphine or silane oi: germane by volume or with not more than 15 per cent arsine by volume; water gas; synthesis gas (e.g. from the Fischer-Tropsch process); mixtures of carbon monoxide with hydrogen or with methane. (c t) Chemically unstable, toxic· Mixtures of hydrogen with not more than 10 per cent dibo­ rane by volume; mixtures of nitrogen or rare gases (con­ taining not more than 10 per cent xenon by volume) with not more than 10 per cent diborane by volume. B. Liquefied gases [see also marginal 2201a under (b) and ( e )]. For gases of 3 ° to 6 ° in aerosol dispensers or in non-refillable containers for gases under pressure, see under 10° and 11 °. Gases having a critical temperature of 10 ° C or above are considered to be liquefied gases for the purposes of ADR. a. Liquefied gases having a critical temperature of70°C or above: 3 ° Pure gases and technically-pure gases (a) Non-inflammable 2201 EG>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: ~EYTEPO) 917 Bromochlorodifluoromethane (R 12 B l); chlorodifluoro­ methane (R 22); chloropentafluoroethane (R 115); l-chloro-2,2,2-trifluoroethane (R 133a); dichlorodifluo­ romethane (R 12); dichlorofluoromethane (R 21); 1,2 dichloro-l, 1,2,2,-tetrafluoroethane (R 114); octafluorocyclobutane (RC 318). (a t) Non-inflammable, toxic Ammonia; boron chloride (corrosive); chlorine (corrosive); chlorine trifluoride (corrosive); hexafluoropropylene (R 1216); hydrogen bromide (corrosive); methyl bromide; nitrosyl chloride (corrosive); nitrogen dioxide NO~ (nitro­ gen peroxide, nitrogen tetroxide N 2 0,) (corrosive}; phos­ gene (corrosive); sulphur dioxide; sulphuryl fluoride; tung­ sten hexafluoride. (b) Inflammable Butane; 1-butylene (I-butene); l-chloro-1, 1-difluoroe­ thane (R 142b); cis-2-butylene (cis-2-butene); cyclopro­ pane; 1,1-difluoroethane (R 152a); dimethyl ether; isobu­ tane; isobutylene (isobutene); methylsilane; propane; pro­ pylene; trans-2-butylene (trans-2-butene ); 1, 1, 1-tri­ fluoroethane. (b t) Inflammable, toxic Arsine; dichlorosilane; dimethylamine; dimethylsilane; ethylamine; ethyl chloride; hydrogen selenide; hydrogen sulphide; methylamine; methyl chloride; methyl mercap­ tan; trimethylamine; trimethylsilane. (c) Chemically unstable 1.2-butadiene; 1,3-butadiene; vinyl chloride. NOTE: In receptacles containing 1,2-butadiene, the ox­ ygen concentration in the gaseous phase shall not exceed 50 mJ/m3. • (c t) Chemically unstable, toxic Cyanogen; cyanogen chloride (non-inflammable) (corro­ sive); ethylene oxide; methyl vinyl ether; trifluorochloroe­ thylene (R 1113); vinyl bromide. NOTE: In the case of halogenated hydrocarbons, the use of names customary in the trade, such as the following, is also permitted: Algofrene, Arcton, Edifren, Flugene, Forane, Freon, Fresane, Frigen, lsceon, Kaltron, followed by the substance identification number without the letter R. 4 ° Mixtures of gases (a) Non-inflammable Mixtures of substances listed under· 3 ° (a) with or without hexafluoropropylene of 3 ° (a t), which as: mixture F 1, have a vapour pressure at 70 ° C not exceeding , 1.3 MPa(l3 bar) and a density at 50°C not lower than that of dichlorofluoromethane (1.30); mixture F 2, have a vapour pressure at 70°C not exceeding 1.9 MPa(l 9 bar) and a density at 50°C not lower than that of dichlorodifluor.oinethane (1.21 ); mixture F 3, have a vapour pressure at 70 °C not exceeding 3 MPa(30 bar) and a density at 50°C not lower than that of chlorodifluoromethane (1.09); • NOTES: 1. Trichlorofluoromethane (R 11), trichloro­ trifluoroethane (R 113) and chlorotrifluoroethane (R 133) are not liquefied gases within the meaning of ADR and thus are not subject to the requirements of ADR. They may, however, enter into the composition of mixtures F 1 to F 3. 2. See NOTE under 3 °. The azeotropic mixture of dichlorodifluoromethane (R 12) and 1, 1-difluoroethane (R 152a), known as R 500; The azeotropic mixture of chloropentafluoroethane (R 115) and chlorodifluoromethane (R 22), known as R 502; The mixture of 19 to 21 per cent by m~s dichlorodifluoro­ methane (R 12) and 79 to 81 per cent by mass bromochlorodifluoromethane (R 12 BI). (a t) Non-inflammable, toxic Mixtures of methyl bromide and chloropicrin having a vapour pressure above 300 kPa(3 bar) at 50°C. (b) lrtflammable Mixtures of hydrocarbons listed under 3 ° (b) and of eth­ ane and ethylene of 5 ° (b ), which as: mixture A, have a vapour pressure at 70°C not exceed­ ing 1.1 MPa(ll bar) and a density at 50°C not lower than 0.525; mixture A 0, have a vapour pressure at 70°C not ex­ ceeding 1.6 MPa(l6 bar) and a density at 50°C not lower than 0.495; mixture A 1, have a vapour pressure at 70°C not ex­ ceeding 2.1 MPa(21 bar) and a density at 50°C not lower than 0.485; mixture B, have a vapour pressure at 70°C not exceed­ ing 2.6 MPa(26 bar) and a density at 50°C not lower than 0.450; mixture C, have a vapour pressure at 70°C not exceed­ ing 3 .1 MPa(3 l bar) and a density at 50 ° C not lower than 0.440; NOTE: In the case of the foregoing mixtures, the use of the following names customary in the trade is permitted for describing these substances: Name given under 4 ° (b) Mixture A, mixture A 0 Mixture C Mixtures of hydrocarbons of 3 ° (b) and 5 ° (b) containing meJhane. (b t) Inflammable, toxic Name customary in the· trade butane propane Mixtures of two or more of the following gases: methylsi­ lane, dimethylsilane, trimethylsilane; methyl:~hloride and methylene chloride in mixtures having a vapour pressure above 300 kPa(3bar) at 50 °C; mixtures of methyl chloride and chloropicrin and mixtures of m{\thy\ bromide and eth­ ylene bromide having in either case a •.vapour. pressu re above 300 kPa(3 bar) at 50°C. (c) Chemically unstable . .• . Mixtures of 1,3-butadiene and h39rocarbons of3 ° (b) hav.: ing a vapour pressure at 70°C not exceeding,1.1 MPa(ll bar) and a density at 50°C not lower than 0.525; Mixtures of methylacetylene and. propadiene. with the hydrocarbons of 3 ° (b), which as: . , .'."v· .''-: ':. • mixture P 1, contain not.!,more than, 63. ·per cent: methylacetylene and propadi~ne by volume and not.more than 24 per cent propane and propylene by volume;-the percentage of C 4 saturated hydrocarbons being. not less than 14 per cent by volume; and as . mixture P 2, contain not more than 48 per, cent methylacetylene and propadiene by volume an\! not more than 50 per cent propane a~d propylene by volume, the percentage of Cfsaturated hydrocarbons being not less than 5 per cent by volume. • (c t) Ch~mically unstable, toxic • Ethylene oxide containing not more than 10 per cent car­ bon dioxide by mass; ethylene oxide containing not more than 50 per cent methyl formate by mass, with i:i,itrogen up to a total pressure not exceeding 1 MPa(lO b~r) at 50°C; ethylene oxide with nitrogen up to a total pressure of 1 MPa(lO bar) at 50°C; dichlorodifluoromethane containing 12 per cent ethylene oxide by mass. b. Liquefied gases having a critical temperature of l0°C or above, but below 70°C: 5 ° Pure gases and technically-pure gases (a) Non-inflammable Bromotrifluoromethane (R 13 B l); carbon dioxide; chlorotrifluoromethane (R 13); hexafluoroethane (R 116); nitrous oxide N 2 0; sulphur hexafluoride; trifluoromethane (R 23); xenon. • With regard to carbon dioxide, see also marginal 2201a under (c). NOTES: 1. Nitrous oxide is to be accepted for carriage only if it is not less than ·99 per cent pure. 918 E<DHMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) 2. See NOTE under 3 °. (a t) Non-inflammable, toxic Hydrogen chloride (corrosive). (b) Inflammable Ethane; ethylene; silane. (b t) Inflammable, toxic Germane; phosphine. (c) Chemically unstable 1, 1-difluoroethylene; vinyl fluoride. (c t) Chemically unstable, toxic Diborane. 6 ° Mixtures of gases (a) Non-inflammable Carbon dioxide containing not less than 1 per cent and not more than 10 per cent nitrogen, oxygen, air or rare gases by mass; the azeotropic mixture of chlorotrifluoromethane (R 13) and trifluoromethane (R 23) known as R 503. NOTE: Carbon dioxide containing less than 1 per cent nitrogen, oxygen, air or rare gases by mass in a substance of 5° (a). (c) Chemically unstable Carbon dioxide containing not more than 35 per cent ethylene oxide by mass. (c t) Chemically unstable, toxic Ethylene oxide containing more than 10 per cent but not more than 50 per cent carbon dioxide by mass. C. Deeply-refrigerated liquefied gases 7 ° Pure gases and technically-pure gases (a) Non-inflammable Argon; carbon dioxide; helium; krypton; neon; nitrogen; • nitrous oxide N 2 0; oxygen; xenon. (b) Inflammable Ethane; ethylene; hydrogen; methane. 8 ° Mixtures of gases (a) Non-inflammable Air; mixtures of substances of 7 ° (a) (b) Inflammable Mixtures of substances of 7° (b); natural gas. D. Gases dissolved under pressure 9° Pure gases and technically-pure gases (a t) Non-inflammable, toxic Ammonia dissolved in water with more than 35 per cent but not more than 40 per cent ammonia by mass; ammonia dissolved in water with more than 40 per cent but not more than 50 per cent ammonia by mass. NOTE: Ammonia solution containing not less than 10 per cent but not more tha:1 35 per cent ammonia is a sub­ stance of Class 8. (c) Chemically unstable Acetylene (dissolved in a solvent (e.g. acetone) absorbed by porous substances. E. Aerosol dispensers and non-refillable containers of gas under pressure [see also marginal 2201a under (d)]: NOTES: 1. Aerosol dispensers are receptacles which can be used only once, are equipped with a release valve or dispersal device, and contain, under pressure, a gas or mixture of gases listed in marginal 2208 (2) or contain an active sub­ stance (insecticide, cosmetic, etc.) together with such a gas or mixture of gases as a propellent. 2. Non-refillable containers of gas under pressure are receptacles which can be used only once and contain a gas or a mixture of gases listed in marginal 2208 (2) and (3) (e.g. butane for camp-cookers, refrigerant gases, etc.), but are not equipped with a release valve. 3. The term "inflammable substances" means: (i) gases (propellent in aerosol dispensers; contents of non-refillable containers of gas under pressure) whose mixtures with air can be ignited and have a lower and an upper inflammability limit; (ii) liquids (active substances in aerosol dispensers) of Class 3. • 4. The term "chemically unstable" is applied to:!;ontents which in the absence of special precautions undergo dan­ gerous decomposition or self-polymerization at a tempera­ ture of not more than 70°C. 10 ° Aerosol dispensers (a) Non-inflammable With non-inflammable contents. (a t) Non-inflammable, toxic With non-inflammable toxic contents. (b) Inflammable 1. With not more than 45 per cent of inflammable con­ tents by mass. 2. With more than 45 per cent of inflammable contents by mass. (b t) Inflammable, toxic 1. With toxic contents and not more than 45 per cent of inflammable contents by mass. 2. With toxic contents and more than 45 per cent of in flammable contents by mass. (c) Chemically unstable With chemically-unstable contents. (c t) Chemically un1,table, toxic With chemically-unstable toxic contents. 1 i O Non-refillable containers of gas under pressure (a) Non-inflammable With non-inflammable contents. (a t) Non-inflammable, toxic With non-inflammable toxic contents. (b) Inflammable With inflammabl~ contents. (b t) Inflammable, toxic With inflammable toxic contents. (c) Chemically unstable With chemically-unstable contents. (c t) Chemically unstable, toxic With chemically-unstable toxic contents. F. Gases subject to special requirements 12 ° Various mixtures of gases Mixtures containing gases listed under other item num­ bers of this Class, and mixtures of one or more gases listed under other item numbers of this Class with one or more vapours of substances not excluded from carriage under ADR, on condition that during carriage: 1. the mixture remains entirely gaseous; and 2. all possibility of a dangerous reaction is excluded. 13° Test gases Gases and mixtures of gases not listed under other item numbers of this Class and used only in laboratory tests, on condition that during carriage: (a) the gas or mixture of gases remains entirely gaseous; and (b) all possibility of a dangerous reaction is excluded. G. Empty receptacles and empty tanks 14 ° Empty receptacles and empty tanks, uncleaned, which have contained tetrafluoromethane of 1 ° (a), sub­ stances of 1 °,(at)- (c t); 2°, (b)-(c t); 3° - 6°; carbon dioxide and nitrous oxide of 7 ° (a); or substances of 7 ° (b), 8 ° (b ), 9 °, 12 ° or 13 °. NOTES: 1. Receptacles and tanks which after being emptied of substances listed under 14 ° still contain small residual amounts are regarded as empty receptacles or empty tanks, uncleaned .. 2. Empty receptacle or empty tanks, uncleaned, which have contained gases of 1 ° (a) other than tetrafluorome­ thane (R 14), or gases of 2 ° (a), 7° (a) other than carbon dioxide and nitrous oxide, or 8 ° (a), are not subject to the requirements of ADR. E<J>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) Gases and articles handed over for carriage in confor­ mity with the following provisions are not subject to the re­ quirements or provisions relating to this Class set out else­ where in this Annex or in Annex B: (a) compressed gases which are neither inflammable nor toxic nor corrosive and whose pressure in the receptacle, referred to a temperature of 15 ° C, does not exceed 200 kPa(2 bar); the same rule applies to mixtures of gases con­ taining not more than 2 per cent inflammable components; (b) liquefied gases contained, in quantities not exceed­ ing 60 1, or in quantities of less than 5 l with not more than 25 g hydrogen, in freezing appliances (refrigerators, ice machines, etc.) and necessary for their operation; (c) carbon dioxide of 5 ° (a) in metal capsules (sodors, sparklets) if the carbon dioxide in the gaseous state does not contain more than 0.5 per cent air and the capsules contain not more than 25 g carbon dioxide and not more than 0. 75 g per cm3 of capacity; ( d) articles of 10 ° and 11 ° of a capacity not exceeding 50 cm3• A package of such articles shall not weigh more than 10 kg; (e) liquefied petroleum gases contained in motor-vehicle tanks firmly secured to the vehicles; the fuel cock between tank and engine must be closed and the electrical contact open. 2. Provisions A. Packages 1. General conditions of packing (1) The materials of which the receptacles and their clo­ sures are made must not be liable to attack by the contents or from harmful or dangerous compounds therewith. NOTE: Care must be taken not to allow any moisture to enter receptacles when they are being filled, and to dry re­ ceptacles completely after hydraulic pressure tests (see marginal 2216) carried out with water or with aqueous so­ lutions. (2) Packagings, including their closures, shall be suffi­ ciently rigid and strong in all their parts to prevent any loos­ ening during carriage and to meet the normal requirements of carriage. When outer packagings are prescribed, the re­ ceptacles shall be firmly secured therein. Unless otherwise specified in the section entitled "Packing of a single sub­ stance or of articles of the same kind", inner packagings may be enclosed in outer packagings either singly or in groups. (3) Metal receptacles intended for the carriage of gases of 1 ° to 6 ° and 9 ° shall contain only the gas for which they have been tested and whose name is inscribed on the re­ ceptacle [see marginal 2218 (1) (a)]. Derogations are allowed: 1. for metal receptacles tested for one of the substances of 3 ° (a) or 4 ° (a) or for bromotrifluoromethane, chlorotrifluoromethane or trifluoromethane of 5 ° (a). These receptacles may also be filled with some other sub­ stance of the aforesaid items on condition that the mini­ mum test pressure prescribed for that substance does not exceed· the test pressure of the receptacle and that the name of the substance and its permissible maximum filling mass are inscribed on the receptacle; 2. for metal receptacles tested for hydrocarbons of 3 ° (b) or 4 ° (b ). These receptacles may also be filled with some other hydrocarbon on condition that the minimum test pressure prescribed for that substance does not exceed the test pressure of the receptacle and that the name of the substance and its permissible maximum filling mass are in­ scribed on the receptacle. For 1 and 2, see also marginals 2215, 2218 (1) (a) and 2220, (1) lo (3). (4) A change in the use to which a receptacle is assigned is allowed in principle if it does not conflict with national regulations; it requires, however, the approval of the corn 2201a 2202 petent authority and replacement of the former markings by markings relating to the new use. 2. Packing of a single substance or of articles of the same kind NOTE: For carbon dioxide and nitrous oxide of 7° (a), mixtures containing carbon dioxide and nitrous oxide of 8 ° • (a) and the gases of 7° (b) and 8° (b), see Annex B, mar­ ginal 21 105. a. Nature of receptacles . (1) Receptacles intended for the carriage of gases of 1 ° to 6 °, 9°, 12 ° and 13 ° shall be so closed and leak-proof as to prevent any escape of the gases. (2) These receptacles shall be made of carbon steel or of alloy steel (special steels). • The following may, however, be used: (a) copper receptacles for: 1. compressed gases of 1 °, (a), (b) and (b t), and 2 °, (a) and (b), whose filling pressure referred to a temperature of 15 °C does not exceed 2 MPa (20 bar); and 2. liquefied gases of 3 ° (a); sulphur dioxide of 3 ° (at); dimethyl ether of 3 ° (b ); ethyl cloride and methyl cloride of 3 ° (b t); vinyl chloride of 3 ° (c); vinyl bromide of 3 ° (c t); mixtures F 1, F 2 and F 3 of 4 ° (a); and ethylene oxide containing not more than 10 per cent carbon dioxide by mass of 4 ° (c t); (b) aluminium-alloy receptacles (see Appendix A.2) for: 1. compressed gases of 1 °, (a), (b) and (b t); nitric oxide (nitrogen monoxide) NO of 1 ° (c t); and compressed gases of 2 °, (a), (b) and (b t); 2. liquefied gases of 3 ° (a); sulphur dioxide of 3 ° (at); liquefied gases of 3 ° (b) other than methylsilane; hydrogen selenide, and methyl mercaptan of 3 ° (b t); ethylene oxide of 3 ° (c t); liquefied gases of 4 °, (a) and (b); ethylene oxide containing not more than 10 per cent carbon dioxide by weight, of 4 ° (c t); and liquefied gases of 5 °, (a} and (b), and 6 °, (a) and (c). Sulphur dioxide of 3 ° (a t) and sub­ stances of 3 ° (a) and 4 ° (a) shall be dry; and 3.· dissolved acetylene of 9° (c). ',:J All gases which are to be carried in aluminium-alloy re­ ceptacles shall be free from alkaline impurities. . . . (1) Receptacles for dissolved acetylene of 9° (c) shall. be entirely filled with a porous material, uniformly distrib­ uted, of a type approved by the competent authority and which (a) does not attack the receptacles or form harmful or dangerous compounds either with acetylene or with the sol­ . vent; (b) does not shake down, even after prolonged use or through jolting, at temperatures up to 60°C; (c) is capable of preventing the spread of decomposition of the acetylene in the mass. (2) The solvent must not attack the receptacles. . (1) The following liquefied gases may, in addition, be carried in thick-walled glass tubes on condition that the quantity of substance in each tube and the degree of filling of the tubes do not exceed the figures indicated below: Quantity Degree of Names of gases of substance filling of tube Carbon dioxide, 3g one-half of nitrous oxide N20 of 5 ° 3(a), ethane, ethylene of 5 ° (b) capacity Ammonia, chlorine, methyl 20g two-thirds of bromide of 3 ° (a t), cyclopropane of 3 ° (b), capacity ethyl chloride of 3 ° (b t) Phosgene, sulphur dioxide 100g three-quarters of 3° (at), of capacity ,(2) The glass tubes shall be flame-sealed and secured separately by infusorial-earth cushioning in closed sheet­ metal capsules which shall be placed in a wooden case or in 919 2203 2204 2205 920 EG>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) some other outer packaging of sufficient strength (see also marginal 2222). (3) For sulphur dioxide of 3 ° (a t) stout glass siphons containing-not more than 1.5 kg of substance and filled to not more than 88 per cent of their capacity are also al­ lowed. The siphons shall be secured by infusorial earth, sawdust or powdered carbonate of lime, or by a mixture of the two latter, in strong wooden cases or in some other outer packaging of sufficient strength. A package shall not weigh more than 100 kg. If it weighs more than 30 kg, it shall be fitted with means of handling. (1) Gases of 3 ° (a); 3 ° (b) other than methylsilane; 3 ° (b t) other than arsine, dichlorosilane, dimethylsilane, hydro­ gen selenide and trimethylsilane; 3 ° (c); 3 ° (c t) other than cyanogen chloride; and mixtures of 4 ° (a) and 4 ° (b), may also, on condition that the mass ofliquid per litre of capac­ ity does not exceed either the maximum mass of contents indicated in marginal 2220 or 150 g per tube, be con­ tained in thick-walled glass tubes, or in thick-walled metal tubes made of a metal allowed by marginal 2203 (2). The tubes shall be free • from faults liable to impair their strength; in particular, internal stresses in glass tubes shall have been suitably relieved and the thickness of the tube walls shall not be less than 2 mm. The leakproofness of the closure system shall be ensured by an additional device (cap, crown, seal, binding, etc.) capable of preventing any loosening of the closure system during carriage. The tubes shall be secured by cushioning material in small boxes made of wood or fibreboard, the number of tubes per box being such that the mass of the liquid contained in a box does not exceed, 600 g. These small boxes shall be placed in wooden cases or in some other outer packaging of suffi­ cient strength; if the liquid contents of a case weigh more than 5 kg, the case shall be lined with soft-soldered sheet­ metal. (2) A package shall not weigh more than 75 kg. (1) Gases of 7 ° (a) other than carbon dioxide and nitrous· oxide, and of 8 ° (a) other than mixtures containing carbon dioxide and nitrous oxide, shall··be enclosed in closed, double-walled metal receptacles which are so insulated that they cannot become coated with dew or hoar-frost and which are-fitted· with safety valves .. (2) Gases of 7 ° (a) other than carbon dioxide and nitrous oxide, and of 8 ° (a) other than mixtures containing carbon dioxide and nitrous ocide, may also be enclosed in recepta­ cles which are not hermetically closed and which are: (a) double-walled vacuum-jacketed glass receptacles surrounded by an absorbent insulating material; these re­ ceptacles shall be protected by iron-wire baskets and placed in metal cases; or (b) metal receptacles protected against heat transmis­ sion in such a way that they cannot become coated with dew or hoar-frost; the capacity of these receptacles shall not ex ceed 100 litres. • (3) Th metal cases referred to in subparagraph (2)(a) and the receptacles referred to in subparagraph (2)(b) above shall be fitted with means of handling. The openings of the receptacles referred to in subparagraphs (2)(a) and (b) shall be fitted with devices allowing gases to escape, preventing any splashing out of the liquid, and so fixed that they cannot fall out. In the case of oxygen of 7° (a) and mixtures containing oxygen of 8 ° (a), the devices referred to above and the absorbent insulating material surrounding the receptacles referred to in subparagraph (2)(a) shall be made of incombustible materials. (1) Aerosol dispensers (10°) and non-refillable contain­ ers for gas under pressure (11 °) shall satisfy the following requirements; (a) aerosol dispensers containing only a gas or a mixture of gases, and non-refillable containers for gas under pres­ sure, shall be made of metal. This requirement shall not apply to non-refillable containers for gas under pressure with a maximum capacity of 100 ml for butane. Other aer­ osol dispensers shall be made of metal, a plastics material 2206 2207 2208 or glass. Receptacles made of metal and having an outside diameter of not less than 40 mm shall have a concave bot­ tom; (b) receptacles made of materials liable to shatter, s~ch as glass or certain plastics materials, shall be enclosed m a device ( close-mesh wire netting, flexible cover made of a plastics material, etc.) affording protection against fr~g­ ments and their dispersal. Receptacles whose capacity does not exceed 150 cm3 and whose internal pressure at 20°C is below 0,15 M Pa (1.5 bar) are exempted from this requirement; • (c) the capacity of receptacles made of metal shall not exceed 1,000 cm3; that of receptacles made of a plastics material or of glass shall not exceed 50Q cm3; ( d) each model of receptacle shall, before being put into service, satisfy a hydraulic pressure test carried ou~ in con • formity with Appendix A.2, marginal 3291. The mternal pressure to be applied (test pressure) shall be 1.5 limes the internal pressure at 50° C, with a minimum pressure of 1 MPa (10 bar); (e) the release valves of aerosol dispensers, and their dispersal devices, shall ensure that the dispensers are so closed as to be leak-proof and shall be protected against accidental opening. Valves and dispersal devices which close only by the action of the internal pressure are not to be accepted. (2) The following gases shall be accepted as propellants, or as constituents of propellants, or as filler gases, for aeros sol dispensers: gases of 1 °, (a) and (b); 2 °, (a) and (b); 3 °, (a) and (b) other than methylsilane; ethyl chloride of 3 ° (b t); 1,3-butadiene of 3 ° (c); trifluorochloroethylene of 3 ° (c t); gases of 4 °, (a) and (b); gases of 5 °, (a) and (b) other than silane; gases of 5° (c) and 6° (a) and (c). (3) All the gases listed under (2) and, in addition, the fol­ lowing gases shall be accepted as filling gases for non­ refillable containers for gas under pressure; methyl bro­ mide of 3 ° (at); dimethylamine, ethylamine, methylamine, methyl mercaptan and trimethylamine of 3 ° (b t); ethylene oxide, methyl vinyl ether and vinyl bromide of 3 ° ( c t); eth­ ylene oxide containing not more than 10 ::ier cent carbon dioxide by mass, of 4 ° (c t). (1) The internal pressure at 50°C of aerosol dispensers and of non-refillable containers of gas under pressure shall exceed neither two-thirds of the test pressure of the recep­ tacle nor 1.2 MPa (12 bar). (2) Aerosol dispensers and non-refillable containers of gas under pressure shall be so filled that at 50°C the liquid phase does not exceed 95 per cent of their capacity. The capacity of aerosol dispensers is the available volume in a • closed dispenser fitted with the valve support, the valve and the dip tube. (3) All aerosol dispensers and non-refillable containers for gas under pressure shall satisfy a tightness (leakproofness) test in conformity with Appendix A.2, ma r ginal 3292. . (1) Aerosol dispensers and non-refillable con tamers of gas under pressure shall be placed in wooden cases or strong fibreboard or metal boxes; aerosol dispensers made of glass or a plastics material and liable to shatter shall be separated from one another by interposed sheets of fibre­ board or of another suitable material. (2) A package shall not weigh more than 50 kg if fibre­ board boxes are used or more than 7 5 kg if other • packagings are used. (3) Where carriage is by full load, each load comprising only aerosol dispensers made of metal, the dispensers may be grouped together and secured on trays with the aid of an appropriate plastics material, by means of a shrinkage a?d heat-sealing process, on condition that the groups of dis­ pensers are then stacked and suitably secured on pallets. b. Conditions governing metal receptacles (These conditions are not applicable to the metal tubes • referred to in marginal 2206, to the receptacles referred to 2209 2210 ll>EK 104 EG>HMEPlr THr KYBEPNHrEor (TEYXOr aEYTEPO) 921 in marginal 2207 (2)(b), cir to the aerosol- dispensers or non-refillable metal containers for gas under pressure re­ ferred to in marginal 2208). 1. Construction and fittings (see also marginal 2238). ( 1) At the test pressure, the stress in the metal at the most severely stressed point of the receptacle (marginals 2215, 2219 and 2220) shall not exceed three-quarters of the guaranteed' minimum yield stress (Re). By "yield stress" is meant the stress at which a permanent elongation of 2 ° /oo (i.e. 0.2 per thousand) or, for austenitic steels, 1 per cent of the gauge length on the test-piece, has been produced, NOTE: In the case of sheet-metal the axis of the tensile test-piece shall be at right angles to the direction of rolling. The permanent elongation at fracture (1 = 5 d) shall be measured on a test-piece of circular cross-section in which the gauge length 1 is equal to five times the diameter d; if test-pieces of rectangular cross-section are used, the gauge length shall be calculated by the formula 1 = 5.65 F0, where F O indicates the initial cross-sectional area of the test-piece. (2) (a) Steel receptacles whose test pressure exceeds 6 MPa (60 bar) shall be of seamless construction or welded. For welded receptacles, steels ( carbon or alloy) of fully sat­ isfactory weldability shall be used. (b) Receptacles whose test pressure does not exceed 6 MPa (60 bar) shall either conform to the provisions of sub­ paragraph (a) above, or be riveted or hard-soldered on con­ dition that the manufacturer guarantees the workmanship of the riveting and hard-soldering and that the competent authorities of the country of origin have given their ap­ proval. (3) Aluminium-alloy receptacles shall be seamless or welded. (4) Welded receptacles are to be accepted only on con­ dition that the manufacturer guarantees the workmanship of the welding and that the competent authorities of the country of origin have given their approval. ( 1) A distinction is made between the following types of receptacles; (a) cylinders of a capacity not exceeding 150 litres; (b) receptacles of a capacity of not less than 100 litres [ with the exception of cylinders in conformity with subpara­ graph (a)] and not more than 1 000 litres (e.g. cylindrical receptacles equipped with rolling hoops, and receptacles on skids); (c) tanks (see Annex B); (d) assemblies, known as "frames", of cylinders in con­ formity with subparagraph (1 )(a), the cylinders being inter­ connected by a manifold and held firmly together by a metal fitting. (2) (a) If under the regulations of the country of depar­ ture the cylinders referred io in subparagraph (l)(a) are re­ quired to be fitted with a device to prevent rolling, this de­ vice shall not be integral with the valve cap (marginal 2213 (2)). (b) Receptacles in conformity with subparagraph (1) (b) which are capable of being rolled shall be equipped with rolling hoops or be otherwise protected against damage due to rolling (e.g. by corrosion-resistant metal sprayed on to the receptacle's outer surface). Recept~cles in co~formity with subparagraphs (1) (b) and (1) (c) which are not capable of being rolled shall be fitted with devices (skids, rings, straps) ensuring that they can be safely handled by mechanical means and so ar­ ranged as not to impair the strength of, nor cause undue stresses in, the wall of the receptacle. (c) Frames of cylinders in conformity with subparagraph (1) (d) shall be fitted with devices ensuring that they can be handled safely. The manifold and the master cock shall be situated within the frame and be so mounted as lo be pro­ tected against any damage. • (3) (a) With the exceptions of gases of 7° and 8°, gases 2211 2212 r of Class 2 may be carried in cylinders in conformity with subparagraph (1) (a). • NOTE: For possible limitations on the capacity of cylin­ ders for certain gases, see marginal 2219. (b) With the exception of fluorine and silicon tetrafluoride of 1 ° (at); nitric oxide (NO) of 1 ° (c t); mix­ tures of hydrogen with not more than 10 per cent hydrogen selenide or phosphine or silane or germane by volume or with not more than 15 per cent arsine by volume; mixtures of nitrogen or rare gases (containing not more than 10 per cent xenon by volume) with not more than 10 per cent hy­ drogen selenide or phosphine or silane or germane by vol­ ume or with not more than 15 per cei:it arsine by volume of 2 ° (b t); mixtures of hydrogen w1th not more than 10 per cent diborane by volume; mixtures of nitrogen or rare gases (containing not more than 10 per cent xenon by vol­ ume) with not more than 10 per cent diborane by volume of 2 ° (c t); boron chloride, chlorine trifluoride, nitrosyl chlo­ ride, sulphuryl fluoride and tungsten hexafluoride of 3 ° (a t); methylsilane of 3 ° (b); arsine, dichlorosilane, dimethylsilane, hydrogen selenide and trimethylsilane of 3 ° (b t); cyanogen chloride, cyanogen and ethylene oxide of 3 ° (c t); mixtures of methylsilanes cif 4 ° (b t); ethylene oxide containing not more than 50 per cent metliylformate by mass, of 4 ° (c t); nitrous oxide of 5 ° (a); silane of 5 ° (b); and substances of 5 ° (b t), 5 ° (c t), 7°, 8°, 12 ° and 13 °, gases of Class 2 may be carried in receptacles in confor- . mity with subparagraph (1) (b). (c) With the exception of silicon tetrafluoride of 1 ° (at); nitric oxide of 1 ° (c t); mixtures of hydrogen with not more than 10 per cent hydrogen selenide or phosphine-or:silane or germane by volume or with not more than 15 per cent arsine by volume; mixtures of nitrogen or rare gases (con­ taining not more than 10 per cent xenon by volume) with not more than 10 per cent hydrogen selenide or phosphine or-silane or germane by volume or with not more.than 15 per cent arsine by volume of 2 ° (b t); mixtures of hydrogen with not more than 10 per cent dibor;~ne by volume; mix­ tures of nitrogen or rare gases -(c6ntaining not m ore than 10 per cent xenon by volume) with not more than 10 per cent diborane by volume of 2° (c t); boron chlqride, chlo­ rine trifluoride, nitrosyl chloride, sulphuryl {luo ride and tungsten hexafluoride of 3 ° (a t); .methylsilane of 3 ° (b); arsine, dichlorosilane, dimethylsilane, hydrogen selenide and trimethylsilane oL3 ° (b t); cyanogen chloride, cyano­ gen and ethylene oxide of 3 ° (c t); mixtures of~ methylsilanes of 4 ° (b t); substances of 4 ° (c) and 4 ° (c t) other than dichlorodifluoromethane containing 12 per cent ethylene oxide by mass; nitrous oxide of.5° (a); silane of 5 ° (b); and substances of 5 ° (b t), 5 ° (c t), 7°, 8°, 12 ° and 13 °, gases of Class 2 may be carried in frames of cylinders in conformity with subparagraph (l)(d). The individual cyl­ inders in a frame of cylinders shall contain only one and the same compressed gas, liquefied gas or gas dissolved under pressure. Each cylinder in a frame of cylinders for fluorine of 1 ° (at) or dissolved acetylene of 9° (c) shall, however, be fitted with a cock. The cylinders in a frame of cylinders for acetylene shall all contain the same porous material (marginal 2204). (1) Openings for filling and emptying receptacles shall 2213 be fitted with flap valves or needle-valves. Valves of other types may, however, be allowed if they present equivalent guarantees of safety and have been approved in the country of origin. Nevertheless, whatever the type of valve adopted; its system of attachment shall be strong and such that its satisfactory condition can be verified easily before each fill ing. Apart -from a manhole, which if provided shall be closed by an effective closure, and from the necessary· orifice for the removal of deposits, receptacles and tanks in confor­ mity with marginal 2212 (1) (b) and (c) shall not be equipped with more than two openings, for filling and dis­ charge respectively. Nevertheless, receptacles of a capac­ ity of not less than 100 1 intended for the carriage of dis 922 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI .dEYTEPO) solved acetylene of 9° (c) may have more than two open­ ings for. filling and discharge. Similarly, receptacles and tanks in conformity with mar­ ginal 2212 (1), (b) and (c), intended for the carriage of substances of 3 ° (b) and 4 ° (b) may be provided with other openings intended in particular for verifying the level of the liquid and the gauge pressure. (2) Valves (cocks) shall be effectively protected by caps or fixed flanges. Caps shall possess vent-holes of sufficient cross-sectional area to evacuate gases if leakage occurs at the valves. The caps or flanges shall adequately protect the valve if the cylinder falls and during carriage and stacking. Valves place1 inside· the neck of the receptacles and pro­ tected by a screw-threaded plug, and receptacles carried packed in protective cases, shall not require a cap. Like­ wise, no protective cap shall be required for valves (cocks)on frames of cylinders. (3) Receptacles containing fluorine of 1 ° (a t); clorine trifluoride of 3 ° (at); or cyanogen cloride of 3 ° (c t) shall, whether or not they are carried packed in protective cases, be fitted with steel caps. These caps shall have no openings and shall, throughout carriage, be fitted with a gasket en­ suring gas-tightness and made of a material not liable to at­ tack by the contents of the receptacle. (1) In the case of receptacles containing boron trifluoride or fluorine of 1 ° (at); chlorine trifluoride or liq­ uefied ammonia of 3 ° (at); ammonia dissolved in water of 9 ° ( a t); nitrosyl .chloride of 3 ° ( a t ); or dimethylamine, ethylamine, methylamine or trimethylamine of 3 ° (b t), valves made of copper or of any other metal liable io be at­ tacked by these gases are not to be accepted. (2) The use of substances containing grease or oil for en­ suring the leakproofness of joints (seams) or for maintain­ ing the closure devices of receptacles used for oxygen of 1 ° (a); fluorine of 1 ° (at); mixtures with oxygen of 2 ° (a); ni­ trogen dioxide, chlorine trifluoride of 3 ° (a t); nitrous oxide of 5 ° (a); or mixtures of 12 ° containing more than 10 per cent oxygen by volume is prohibited. (3) The following requirements shall apply to the con­ struction of the receptacles referred lo in marginal 2207 (1): (a) The materials a,nd construction of the receptacles shall be in conformity with th~ requirements of Appendix A.2, B, marginals 3250 to 3254. All the mechanical and technological characteristics of the material used shall be established for each receptacle al the first lest; with regard to the impact strength and the bending coefficient, see Ap­ pendix A.2, B, marginals 3265 to 3285. (b) Receptacles shall be fitted with a safety valve which shall be capable of opening at the working pressure shown on the receptacle. The valves shall be so .constructed as to work perfectly even at their lowest working temperature. Their reliability of functioning at that temperature shall be established and checked by testing each valve or a sample of valves of the same type of construction. (c) The vents and safety valves of receptacles shall be so designed as to prevent the liquid from splashing out. ( d) The closing devices shall be so arranged that they cannot be opened by unqualified persons. (e) Receptacles whose filling is measured by volume shall be provided with a level indicator. (f) The receptacles shall be thermally insulated. The thermal insulation shall be protected against impact by means of continuous metal sheathing. If the space between the receptacle and the metal sheathing is. airless (vacuum insulation), the protective sheathing shall be designed to withstand without deformation an external pressure of at least 100 kPa (1 bar). If the sheathing is so closed as to be gas-tight (e.g. in the case of vacuum insulation), a device shall be provided to prevent any dangerous pressure from developing in the insulating layer in the event of inadequate gas-tightness of the receptacle or its fittings. The device shall prevent moisture from penetrating into the insulation. 2214 (4) In the case of receptacles containing mixtures Pl or P2 of 4° (c) or<dissolved acetylene of9° (c), metal parts of closing devices in contact with the contents shall not con­ tain more than 70 per cent copper. Receptacles for dis­ solved acetylene of 9 ° (c) may also have stop-valves taking yoke connectors. (5) Receptacles containing oxygen of 1 ° (a) or 7 ° (a) and fitted in fish-tanks are likewise to be accepted if they . are provided with appliances enabling the oxygen to escape gradually. 2. Official test of receptacles (for aluminium-alloy re­ ceptacles, see also Appendix A.2). ( 1) Metal receptacles shall be subjected to initial and pe­ riodic tests under the supervision of an expert approved by the competent authority. The nature of these tests is speci­ fied in marginals 2216 and 2217. (2) In order to ensure compliance with the requirements of marginals 2204 and 2221 (2), tests of receptacles in­ tended to contain dissolved acetylene of 9° (c) shall in­ ·clude, in addition, examination of the nature of the porous material and of the quantity of solvent. (1) The initial test of new or unused receptacles shall • comprise: A. On an adequate sample of receptacles: (a) testing or' the material of construction in respect at least of yield stress, tensile strength, and permanent elon­ gation at fracture; the values yielded by these tests shall comply with national regulations; (b) measurement of wall thickness al the thinnest point, and calculation of the stress; (c) checking the homogeneity of the material for each manufacturing batch, and inspection of the external and in­ ternal condition of the receptacles; B. For all receptacles: (d) a hydraulic pressure test in conformity with the pro­ visions of marginals 2219 to 2221; ( e) an inspection of the markings on the receptacles ( see marginal 2218). C. In addition, for receptacles intended for the carriage of dissolved acetylene of 9° (c): (f) an inspection as required by national regulations. (2) Receptacles shall withstand the test pressure without undergoing permanent deformation or exhibiting cracks. (3) At the periodic inspections the following shall be re­ peated: the hydraulic pressure test; check of the external and internal condition of the receptacle (e.g. by weighing, internal inspection, checks of wall thickness); verification of the equipment and markings and, if necessary, verifica­ tion of the characteristics of the material by suitable tests. Periodic inspections shall be carried out: (a) every 2 years in the case of receptacles intended for the carriage of gases of 1 ° (at) and 1 ° (c t); town gas of 2 ° (b t); gases of 3 ° (a t) other than ammonia. hexafluoropropylene and methyl bromide; cyanogen chlo­ ride of 3 ° (c t); and substances of 5 ° (at); (b) every 5 years in the case of receptacles intended for the carriage of other compressed and liquified gases (sub­ ject to the provisions of subparagraph (c) below) and of re­ ceptacles for the carriage of ammonia dissolved under pressure of 9° (a t); (c) every 10 years in the case of receptacles intended for the carriage of gases of 1 ° (a) other than oxygen; of mix­ tures of nitrogen with rare gases, of 2 ° (a); of gases of 3 ° (a) and 3 ° (b) other than l-chloro-1,1-difluoroethane. 1,1 difluoroethane, dimethyl ether, methylsi\ane and 1,1.1 trifluoroethane, and of mixtures of gases of 4 ° (a) and 4 ° (b), if the receptacles have a capacity of not more than 150 litres and the country of origin does not prescribe a shorter interval; ( d) in the case of receptacles intended for the carriage of dissolved acetylene of 9° (c), marginal 2217 (1) shall apply, and in that of receptacles conforming to marginal 2215 2216 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) 2207 (1), marginal 2217 (2) shall apply. (1) The external condition (corrosion, deformation) of. and the condition (loosening, selllemenl) of the porous ma­ terial in, receptacles intended for the carriage of dissolved acetylene of 9° (c) shall be examined every 5 years. Sam­ pling shall be. performed by culling up, if considered neces­ sary, a suitable number of receptacles and inspecting them internally for corrosion and for any changes that may have occurred in the constituent materials and in the porous ma­ terial. (2) Receptacles conforming Lo marginal 2207 (1) shall be subjected every 5 years lo external inspection and lo a tightness (leakproofness) Lest. The tightness (leakproofness) test shall be carried out with the gas con­ tained in the receptacle or with an inert gas al a pressure of 0.2 MPa (2 bar). Checking shall be performed by means of a pressure gauge or by vacuum measurement. The thermal insulation shall not be removed. The pressure shall not de­ cline during the 8-hour Lest period. Changes resulting from the nature of the test gas or from variations in temperature shall be taken into account. 3. Marks on receptacles (1) Metal receptacle1, shall bear the following particulars in clearly legible and durable characters: (a) one of the names of the gas or of the mixture of gases in full, as given in marginal 2201, 1 ° to 9 °: the names or mark of the maker or owner; and the number of the recep­ tacle [see also marginal 2202 (3)1. In the case of halogenated hydrocarbons of 1 ° (a), 3 ° (a). 3 ° (a 1). 3 ° (b), 3 ° (c t), 4 ° (a), 5 ° (a) and 6 ° (a). the use of the letter R followed by the substance identification number is also pn­ mitted; (b) the tare of the receptacle without fittings and acces­ sories; (c) in addition, in the case of receptacles intended for liquefied gases, the tare of the receptacle including such fittings and accessories as valves. metal plugs, etc .. bul ex­ cluding the protective cap; NOTE lo (b) and (c): Those particulars of the mass. in so far as they are not already marked on the receptacle. shall be so marked at the next periodic test. (d) the test pressure (see marginals 2219 to 2221) and the date (month, year) of the last test undergone (see marginals 2216 and 2217): (e) the stamp of the expert who carried out the tesls and inspections; and, in addition: (f) in the case of compressed gases or mixtures of com­ pressed gases of 1 °, 2°, 12° and 13°: the maximum fill­ ing pressure at 15 ° C allowed for the receptacle in ques­ tion (see marginal 2219); (g) in the case of boron fluoride of·l O (at). liquefied gases of 3° to 6° and ammonia dissolved in water of 9° (at): the maximum filling allowed, and the capacily. In the case of deeply-refrigerated gases of 7 ° and 8 °: the ea pace ity; (h) in the case of acetylene dissolved in a solvent of 9 ° (c): the permilled filling pressure [see marginal 2221 (2)]. and the mass of the empty receptacle. including the mass of the fillings and accessories, of the porous material. and of the solvent: (i) in the case of mixtures of gases of 12 ° and tesl gases of 13 °, the words '"mixtures of gases'' or "Lest gases". as the case may he, shall be engraved on the receptacle as a general indication of the contents. An exact description of the contents shall be shown in a durable form 1hroughoul carriage; (k) in. the case of metal receptacles which. under mar­ ginal 2202 (3), are accepted for the carriage of a number of different gases (multi-purpose receptacles). an exacl de­ scription of the contents shall be shown in a durable form during carriage. (2) The marks shall be engraved either on a reinforced part of the receptacle, or on a ring, or on a data plale. irn movably affixed to the receptacle. In addition, the nam~ of 221 7 the substance may be indicated on the receptacle by an ad­ herent and clearly-visible inscription applied by painting or by any other, equivalent process. c. Test pressure, degree of filling. and limitation of ca­ pacity, of receptacles (see also marginals 2238, 211 180. 211 184 and 212 180). (1) In the case of receptacles intended for the carriage of compressed gases of 1 °, 2 ° and 12 °, the internal pressure (test pressure) to be applied in the hydraulic pressure lest shall be at least one and one-half times the filling pressure at l5°C indicated on the receptacle: but shall not be less than 1 MPa (10 bar). (2) In the case of receptacles used for the carriage of substances of 1 ° (a) other than letrafluoromelhane: of deu­ terium and hydrogen of 1 ° (b); or of gases of2 °(a).the fill­ ing pressure shall not exceed 30 MPa (300 bar) referred to a temperature of 15°C. In the case of tanks. the filling pressure shall not exceed 25 MPa (250 bar) referred to .1 temperature of 15 ° C. In the case of receptacles and tanks intended for the car­ riage of other gases of 1 ° and 2 °, the filling pressure shall 2218 not exceed 20 MPa (200 bar) referred to a lemperature of l5°C. (3) In the case of receptacles intended for the carriage of fluorine of 1 ° (at), the internal pressure (test pressure) Lo be applied in the hydraulic pressure Lest shall be 20 MPa (200 bar) and the filling pressure shall not exceed 2.8 MPa (28 bar) at a temperature of 15 °C; in addition. no recepta­ cle may contain more than 5 kg fluorine. In the case of receptacles intended for the carriage of boron trifluoride of 1 ° (a t), the hydraulic pressure to be applied in the test (test pressure) shall be either 30 MPa (300 bar), in which case the maximum mass of the con ten ls per litre of capacity shall not exceed 0.86 kg, or 22.5 MPa (225 bar), in which case the maximum mass of the conlents per litre of capacity shall not exceed 0. 715 kg.. • (4) In the case of receptacles intended for'the c~rriage of nitric oxide NO of 1 ° (c t). the car,icity shall be limited to 50 I; the hydraulic pressure to be applied in the test (test pressure) shall be 20 MPa (200 bar): and the Iii.ling p res­ sure shall not exceed 5 MPa (50 bar) at a.temperature of 15°C. • • (5) In the case of receptacles intended for the carriage of mixtures of hydrogen with not more than 10 per cent hy­ drogen selenide or phosphine or silane or germane by rnl­ ume or with not more than 15 per cent arsine by volume: of mixtures of nitrogen or rare gases (containing not more than 10 per cent xenon by volume) with nol more than 10 per cent hydrogen selenide or phosphine or silane or ger­ mane by volume or with n·ol more than 15 per cent arsine by volume, of 2 ° (b t); of mixtures of hydrogen with not more than 10 per cent diborane by volume: or of mixtures of nitrogen or rare gases (containing not more than 10 per cent xenon by volume) with not more than 10 per cent diborane by volume, of 2 ° (c t), the capacity shall be lim­ ited to 50 I; the hydraulic pressure lo be applied in the lest (test pressure) shall be not less than 20 MPa (200 bar): and the filling pressure shall not exceed 5 MPa (50 bar) al a temperature of l5°C. (6) Receptacles in conformity with marginal 2207 (l) shall not, at the filling temperature and at a pressure of 0.1 MPa (1 bar), be filled beyond 98 per cent of their capacitv. Where oxygen of 7 ° (a) if carried, steps shall be taken to prevent any spillage of the liquid phase. (7) Where dissolved acetylene of 9° (c) is carried in re­ ceptacles in conformity with marginal 2212 ( 1) (b ). the ca­ pacity of the receptacles shall nol exceed 150 I. (8) The capacity of receptacles intended for the carriage of mixtures of gases cif 12 ° shall not exceed 50 I. The pres­ sure of the mixture shall not exceed 15 MPa ( 150 bar) al a temperature of 15 ° C. • (9) The capacity of receptacles inlended for the carriage' 923 2219 924 E<DHMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) of test gases of 13 ° shall not exceed 50 I. The filling pres­ sure at a temperature of 15 °C shall not exceed 7 per cent of the test pressure of the receptacle. (10) In.the case of tungsten hexafluoride of 3 ° (a t), the capacity of the receptacles shall be limited to 60 I. The capacity of receptacles for silicon tetrafluoride of 1 ° (at); boron chloride, nitrosyl chloride and sulphuryl flu­ oride of 3 ° (at); methylsilane of 3 ° (b); arsine, dichlorosilane, dimethylsilane, hydrogen selenide and trimethylsilane, of 3 ° (b t); cyanogen chloride and cyano­ gen of 3 ° (c t); mixtures of methylsilanes of 4 ° (b 1); ethyl­ ene oxide containing not more than 50 per cent methyl formate by mass, of 4 ° (c t); silane, of 5 ° (b); and sub­ stances of 5° (b t) and (c t), shall be limited lo 50 I. ,' (11) In the case of receptacles intended for chlorine trifluoride of 3 ° (at), the capacilv shall bf' limit«>rl to 40 I. Description of substance Bromochlorodifluoromethane (R 12 B 1) Chlorodifluoromethane (R 22) Chloropentafluoroethane (R 115) l-chloro-2,2,2-trifluoroethane (R 133a) Dichlorodifluoromethane (R 12) Dichlorofluoromethane (R 21) 1,2-Dichloro-l, l,2,2-letrafluoroethane (R 114) Octafluorocyclobutane (RC 318) Ammonia Boron chloride Chlorine Chlorine :trifluoride Hexafluoropropy lene (R 1216) Hydrogen bromide Methyl bromide Nitrogen dioxide Nitrosyl chloride Phosgene Sulphur dioxide Sulphuryl • fluoride Tungsten hexafluoride Butane I-Butene • l-Chloro-1,1-difluoroethane (R 1426) Cis-2-6utene Cyclopropane 1,1-Difluoroethane (R 152a) Dimethyl ether Isobutane lsobutene Methylsilane Propane Propylene Trans-2-butene 1, 1, 1-Trifluoroethane Arsine Dichlorosilane Dimethylamine Dimethvlsilane Ethyla~ine Ethyl chloride Hydrogen selenide Hydrogen sulphide Methylamine Methyl chloride Methyl mercaplan Trimethylamine Trimethvlsilane 1,2-But~diene 1,3-Butadiene ' After filling, a receptacle containing chlorine trifltJoride of 3 ° (a t) shall, before being handed over for carriage, be held back for not less than seven days in order to verify that it is leak-proof. ( 1) In the case of receptacles intended for the carriage of liquefied gases of 3'0 to 6 °, and of receptacles intended for the carriage of gases dissolved under pressure of 9°. the hydraulic pressure to be applied in the test (lest pressure) shall be not less than 1 MPa (10 bar). (2) In the case of liquified gases of 3 ° and 4 °. the fol­ lowing values shall be complied with for the hydraulic pres­ sure to be applied to the receptacles in the lest (test pres­ sure) and for the maximum degree of filling allowed:* * See the end of the table. 2220 Minimum Maximum mass test of contents Item pressure per litre of No. MPa capacity (kg) 3 °(a) 1 1.61 3 °(a) 2.9 1.03 3 °(a) 2.5 1.06 3 °(a) 1 1.18 3 °(a) 1.8 1.15 3 °(a) 1 1.23 3 °(a) 1 1.30 3 °(a) 1.1 1.34 3 °(a t) 3.3 1.53 3 ° (a t) 1 1.19 3 °(a t) 2.2 1.25 3°(a L) 3 1.40 3°(a t) 2.2 1.11 3 °(a t) 6 1.54 3 °(a t) 1 1.51 3°(a t) 1 1.30 3°(a 1) 1.3 1.10 3°(a t) 2 1.23 3 ° (a t) 1.4 1.23 3 °(a 1) 5 1.10 3°(a 1) 1 2.70 3 °(6) 1 0.51 3 °(6) 1 0.53 3 °(6) 1 0.99 3 °(6) 1 0.55 3 °(h) 2 0.53 3 °(b) 1.8 0.79 3 °(6) 1.8 0.58 3 °(6) 1 0.49 3 °(6) 1 0.52 3°(6) 22.S 0.39 3 °(b) 2.5 0.42 3 °(6) 3 0.43 3 °(h) 1 0.54 3 °(6) 3.5 0.75 3 °(6 1) 4.2 1.10 3 °(b 1) 1 0.90 3 ° (b I) 1 0.59 3 ° (b 1) 22.5 0.39 3 ° (b 1) 1 0.61 3 ° (6 1) 1 0.80 3°(b L) 3.1 1.60 3 °(b 1) 5.5 0.67 3 °(6 1) 1.3 0.58 3°(b t) 1. 7 0.81 3 °(b 1) 1 0.78 3 °(6 1) 1 0.56 3 ° (b 1) 22.5 0.39 3°(c) I 0 . .59 3 °(c) l 0.55 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) 925 ,linimum Maximum mass test of contents Item pressure per litre of Description of substance No. MPa capacity (kg) Vinyl chloride 3 °(c) 1.2 0.81 Cyanogen 3 °(c t) 10 0.70 Cyanogen chloride 3°(c t) 2 1.03 Ethylene oxide 3°(c t) 1 0.78 Methyl vinyl ether 3 "(c t) 1 0.67 Trifluorochloroethylene (R 1113) 3°(c t) 1.9 1.13 Vinyl bromide 3 ° (c t) 1 .. 1.37 Mixture F 1 4 °(a) J.2 1.23 Mixture F 2 4 °(a) 1.8 1.15 Mixture F 3 4°(a) 2.9 1.03 Mixture of gases R 500 4 °(a) 2.2 1.01 Mixture of gases R 502 4°(a) 3.1 1.05 Mixture of 19 to 21 per cent by mass dichlorodifluoromethane (R 12) and 79 to 81 per cent by mass bromochlorodifluoromethane (R 12 B 1) 4 °(a) 1.2 1.50 Mixtures of methyl bromide and chloropicrin 4 ° (a t) 1 1.51 Mixture A (trade name: butane) 4 °(b) 1 0.50 Mixture A 0 (trade name: butane) 4 °(b) 1.5 0.47 Mixture A 1 4°(b) 2 0.46· Mixture B 4°(b) 2.5 0.43 Mixture C (trade name: propane) 4°(b) 3 0.42 Mixtures of hydrocarbons containing methane 4°(b) 22.5 0.187 30 0.244 Mixtures of methylsilanes 4 ° (b t) 22.5 0.39 Mixtures of methyl chloride and methylene chloride 4 °(b t) 1.7 , . 0.81 . . . Mixtures of methyl chloride and chloropicrin 4 ° (b 1) 1.7 0.81 Mixtures of methyl bromide and ethylene bromide 4 ° (b t) 1 1.51. Mixtures of 1,3-butadiene and hydrocarbons of 3 ° (b) 4°(c) 1 0.50 Mixtures of methylacetylene/propadiene and hydrocarbons -. Mixture P 1 4 °(c) 3 .. 0.49 Mixture P 2 4°(c) 2.4 - 0.47 Ethylene oxide containing not more than 10 per .·• cent carbon dioxide by mass 4°(c t) 2.8 0.73 Ethylene oxide containing not more than 50 per cent methyl formate by mass with nitrogen up ; to a maximum total pressure of 1 MPa (10 bar) al 50°C 4°(c t) 2.5 0.80 · Ethylene oxide with nitrogen up to a total pressure of 1 MPa (10 bar) at 50°C 4 °(c 1) 1.5 Q.78 Dichlorodifluoromethane containing 12 per cent ethylene oxide by mass 4°(c t) 1.8 1.09 1. The test pressures prescrihed are al leasl equal lo the rnpour pressures of the liquids al 70°C, reduced by O. l MPa (l bar), the rni1ii111Um tesl pressure required being, however. l MPa (10 bar). 2. In view of the high degree of lox icily of phosge11e (carho11yl chloridt'\ of 3 ° (al) and of cyanogen chloride of 3 ° (cl), the minimum test pressure for these gases has heen fixed al 2 MPa (20 bar). • • • 3. The maximum val ues prescribed for the degree of filling in kg/litre ha1e been determined as follows: maximum mass of contents per litre of capacity= 0.95 times the density of the liquid phase at 50°C: in addition. the vapour phase must not disappear below 60°C. (3) In the case of receptacles intended to contain lique­ fied gases of 5 ° and 6°, the degree of filling shall be such that the internal pressure at 65 ° C does not exceed the Lest pressure of the receptacles. The following values shall be complied with, see also paragraph (4): Description of substance . Bromotrifluoromethane (R 13 B 1) Carbon dioxide Chlorotrifluoromelhane (R 13) Item No. S "(a) 5 °(a) 5 °(a) Minimum Maximum mass test of contents pressure per litre of MPa capacity (kg) 4.2 1.13 12 1.44 25 1.60 19 0.66 25 0.7S JO 0.83 926 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) Description of substance Hexafluoroethane (R 116) Nitrous oxide N 2 0 Sulphur hexafluoride Trifluoromethane (R 23) Xenon Hydrogen chloride Ethane Ethylene Silane Germane Phosphine 1.1-Difluoroethvlene Vinyl fluoride· , Diborane Carbon dioxide containing 1~10 per cent nitrogen. oxygen. air or rare gases by mass Mixture of gases R 503 Carbon dioxide containing not more than 35 per cent ethylene oxide by mass Ethylene oxide containing more 10 per cent but not more than 50 per cent carbon dioxide by mass (4) For substances of 5 ° other than hydrogen chloride of 5 ° (at); germane and phosphine of 5 ° (b t): and diborane of 5 ° (c t), and for substances of 6°, the use of receptacles tested at a lower pressure thanthat indicated in paragraph (3) for the substance in question is allowed. but the quan­ tity of substance per receptacle shall not exceed that which at 65°C would produce inside the receptacle a pressure ' Item Description of substance No. Ammonia dissolv ed under pressure in water with more than 35. per cent but not more than 40 per cent ammonia by mass 9°(a t) with more than 40 per cent but not more than 50 per cent ammonia by mass 9°(a t) Dissolved acetylene 9°(c) Minimum Maximum mass Item No. 5 ° (a) 5 °(a) 5 °(a) 5°(a) 5 °(a t) S 0 (6) 5 °(6) S 0 (6 l) 5°(6 t) 5 o(c-) S 0 (c) 5°(c t) 6°(a) 6°(a) 6°(c) 6°(c t) test pressure MPa 12 19 25 20 18 22.5 25 7 14 16 19 25 13 10 "12 15 20 9.S 12 30 22.5 30 22.5 25 25 22.S 25 25 25 25 19 19 25 25 3.1 4.2 10 19 25 19 25 of contents per litre of capaci1, (kg) 0.90 1.04 1.10 1.10 0.68 0.74 0.75 1.04 1.33 1.37 0.87 0.95 1.24 0.30 0.56 0.67 0.74 0.25 0.29 o.~9 0.34 0.37 0.32 0.41 1.02 0,30 0.51 0.77 0.64 0.072 Constituents (mass per cent) 1 1-10 1 1-10 0.64 0.48 0.73 0.59 0.11 0.20 0.66 0.66 0.75 0.66 0.75 equal to the test pressure. In such a case the permissible maximum load shall be prescribed by the expert appro1·ed by the competent authority. (1) In the case of gases dissolved under pressure. of9°. the following values shall be complied with for the hydraulic pressure to be applied to the receptacles in the test (test pressure), and for the maximum degree of filling allowed: Minimum Maximum mass test of contents pressure per litre of MPa capacity (kg) 1 0.80 1.2 0.77 6 see under (2) 2221 ECl>HMEPII THI: KYBEPNHIEQI: (TEYXOI: ~EYTEPO) 927 (2) In the case of dissolved acetylene of 9°(c). once equilibrium has been achieved at 15 ° C the cylinder-filling pressure shall not exceed the value prescribed by the com­ petent authority for the porous mass, which value shall be engraved on the cylinder. The quantity of solvent and the quantity of acetylene shall likewise correspond to the fig­ ures specified in the approval. 3. Mixed packing ( 1) Substances of this Class other than substances of 7 ° and 8° may be enclosed in the same package with one an­ other if they are contained: (a) in metal pressure-receptacles of a volume not ex­ ceeding 10 litres: (b) in thick-walled glass tubes or glass syphons in accor­ dance with marginals 2205 and 2206. on condition that Special conditions: Item No. Description or of letter substance Gases packed in accordance with mar ginal 2205 All gases listed in this marginal (a) Non-inflammable gases (a t) Non-inflammable toxic gases (b) Inflammable gases Gases packed in accordance with 111ar ginal 2206 All gases listed in the marginal except ammonia and cyclopropane (a) Non-inflammable gases (a t) Non-inflammable toxic gases (b) Inflammable gases (b t) Inflammable toxic gases (c) Chemically unstable gases (c t) Chemically unstable toxic gases 3 ° (a t) Ammonia 3 °(6) Cyclopropane "" 4. Markings and labels on packages (see Appendix A. 9) (1) Every package containing receptacles holding gases of 1 ° to 9°, 12° or 13 ° or non-refillable containers of gas under pressure of 11 ° shall be marked legibly and indeli­ bly with an indication of its contents. with the addition: "Class 2". This marking shall be in an official language of the country of departure, and also, if that language is 1101 English, French or German, in English, French or Ger­ man, unless any agreements concluded between the coun­ tries concerned in the transport operation provide other­ wise. This provision need not be complied with if the recepta­ cles and their markings are clearly visible. (2) Packages containing aerosol dispensers of l 0° shall be marked with the word "AEROSOL'' in clearl~ IPgiblc and indelible characters. (3) Where a consignment constitutes a· full load. thP markings referred to in paragraph ( 1) are 1101 ma11dator1·. In these fragile receptacles are secured in accordance with the provisions of marginal 2001 (7). The cushioning mate­ rials shall be suited to the properties of the contents. Inner packagings shall be placed in an outer packaging in which they shall be effectively kept apart from one another. (2) Articles of 10° and 11 ° may be enclosed in the same package with one another under the conditions prescribed in marginal 2210. 2222 (3) In addition, substances packed in accordance with marginal 2205 and 2206 may be enclosed in the same package with one another subject to the following special conditions. • (4) A package which meets the requirements of (1) and (3) shall not weigh more than 100 kg. or more than 75 kg if it contains fragile recPplaclPs. Maximum quantity per per Special receptacle package Provisions the quantities pre 6 kg Chlorine of 3 ° (a t) shall not 6€ scribed Ill marginal packed together with sulphur d iox 2205 ide of 3° (at) Shall not be packed together with substances of Classes la. lb, le, 3, 4.2, 5.2 or 7 Shall not be packed together wit~ substances of Classes la, 1 b, le, 3, 4.1, 4.2, 4.3. 5.1, 5.2, 7 or 8 ., .. ' 150 g 6 kg Shall 1101 be packed together with substances of Classes la, lb, le, 3, 4.2. 5.2 or 7 Shall not be packed together with substances of Classes la, lb, le, 3. 4.1, 4.2, 4.3. 5.1, 5.2 ur 7 20 g 6 kg (1) Packages which contain receptacles made of rnatcri- 2224 2223 als liable to shatter, such as glass or certain plastics malPri­ als, shall bear a label conforming to model No. I 2. (2) Every package containing gases of 7 ° (a) or 8 ° (a) shall bear, on two opposite sides, labels conforming to model No. 11, and if the substances ii contains arc en­ closed in g]af.S receptacles [rnarginal 2207 (2)(a)]. il shall. in addition. hear a lahel <'onforming to model No. 12. Every package containing aerosol dispensers of I 0o (b) 2., 10° (b t) 2., 10° (c) or 10° (c 1). or non-refillable con­ tainers of gas under pressure of 11 ° (b). ] 1 ° (b 1). 11 ° (c) or 11 ° (c t), shall bear a label conforming lo model No. 3. B. Particulars in the transport document (1) The description of the goods in the transport docu­ ment must be: (a) in the case of pure and technically-pure gas<'s of I 0 • 3°, 5°, 7° or 9°, of aerosol dispensers of 10°. of 11011 refillable con tainers of gas under prPssu r{' of I I O :· 01w of 2225 2226 928 E<J>HMEPII THI KYBEPNHIEOI (TEYXOI LlEYTEPO) the names underlined in marginal 2201; (b) in the case of mixtures of gases of 2 °, 4 °, 6 °, 8 °, 12° or 13°: "mixture of gases". This description must be supplemented by an indication of the composition of the mixture of gases in volume per cent or mass per cent. Con­ stituents below one per cent need not be indicated. In the case of mixtures of gases of 2° (a), 2° (b), 2 ° (bt), 4 ° (a), 4° (b), 4° (c), 6° (a), 8° (a) or 8° (b), the descriptions or names customary in the trade which are underlined in mar­ ginal 2201 may likewise be used, without indication of the composition. These descriptions must be underlined and followed by particulars of the class, the item number (together with the letter, if any), and the initials "ADR" or "RID" [e.g .. 2, 5 ° (at), ADR]. (2) In the case of consignments of gases which are listed among the chemically unstable gases, the sender shall cer­ tify as follows in the transport document: "The necessary steps have been taken to satisfy the requirements of ADR marginal 2200 (4)". In the case of consignments of mix­ tures of gases of 12° or test gases of 13 °, the sender shall certify as follows in the transport document: "The condi­ tions laid down in ADR marginal 2201, 12° or 13 °. have been complied with". (3) In the case of consignments of chlorine trifluoride of 3 ° (at), the sender.shall certify as follows in the transport document: "After filling with chlorine trifluoride, the re­ ceptacle has been kept under observation for not less than seven days and its leakproofness has been verified". ( 4) In the cll§e of tanks containing gases of 7 ° (a) or 8 ° (a), other than carbon dioxide and nitrous oxide, the trans­ port documerit shall bear the following entry: "The tank is in permanent communication with the atmosphere» C. Empty packagings --~ ·- • • • (1) Receptacles and tanks ofl 4 ° shall be closed in the same manner as ifthey were (ull. (2) The descriptio,1 1,Jn the transport document shall con­ form to one of the names given in 14 °, (e.g. "Empty recep­ tacle, uncleaned, 2, 14 °, ADR"). T.his text shall be under­ lined. The description shall be completed by adding the words "Last load", together with the name and item num­ ber of the goods last loaded, e.g., Last load: argon, 1 ° (a). (3) The receptacles of 14 ° referred to in marginal 2212 (1) (a), (b) and (d) may be transported after the expiry of the time-limit set for the periodic test prescribed in mar­ ginal 2215, for the purpose of undergoing the tests. D. Transitional provisions The foilowing transitional provisions shall apply Lo re­ ceptacles for compressed or liquefied gases or gases dis­ solved under pressure: (a) receptacles already in service shall, subject Lo the fol­ lowing exceptions, be accepted in international traffic so long as the requirements of the contracting country in which the tests in accordance with marginal 2216 were carried out so permit and as the intervals prescribed in marginals 2216 (3) and 2217 for the periodic inspections are observed; (b) in the case of receptacles manufactured under the previous system (permissible stress two-thirds, instead of three quarters, of the yield stress), no increase in either the test pressure or the filling pressure shall be permitted [ see marginal 2211 (l)]; (c) transitional measures for tanks: see marginals 211 180 and 211 184. (d) transitional ml;)asures for tank-containers: see mar­ ginal 212 180 2227 2236 2237 2238 2239 2299 CLASS 3 INFLAMMABLE LIQUIDS 1. List of substances (1) Among the inflammable substances and mixtur~s whic~ are liquid or viscous at a temperature ~10t exceedmg 35 C 1/ those listed in marginal 2301 or which fall under a col­ le,ctive heading of that marginal are subject to the condi­ tions prescribed in marginals 2300 (2) to 2322 and the provisions of this Annex and of Annex B. They are then considered as substances of ADR.21 (2) Inflammable liquids, within the meaning of ADR, have a vapour pressure not exceeding 3~0 kPa (3 bar) ~ta temperature of 50 ° C and a flash - pomt not exceedmg 100° C, except those infammable liquids which, because of supplementary dangerous properties, ~re listed in, or as­ signed to, other classes. The flash - pomt shall be deter­ mined as indicated in Appendix A.3, marginals 3300 to 3302. (3) Substances of Class 3, other than those of 12° ~nd 13 °, classified under the various item numbers of margmal 2301 shall be assigned to one of the following groups des­ ignated by the letter (a), (b) or (c) according to their degree of danger: letter (a): Very dangerous substances: inflammable liq­ uids having a boiling point or initial boiling point not ex­ ceeding 3 5 ° C, and inflammable liquids having a flas~ point below 21 ° C, which are either highly toxic accordmg to the criteria of marginal 2600 or highly corrosive accord­ ing to the criteria of marginal 2800; letter (b): Dangerous substances: inflammable liquids having a flash - point be.low 21 ° C which are not classified under letter (a), with the exception of substances of mar­ ginal 2301, 5° (c); letter ( c ): Substances presenting a minor danger: inflam­ mable liquids having a flash - point of 21 ° C to 100 ° C and substances of marginal 2301, 5° (c). (4) When, as a result of additions, the flash-point, boil­ ing point, initial boiling point or vapour pressure of a sub­ stance of Class 3 is not within the limits prescribed for the various items of marginal 2301, such a mixture shall be classified under the item number to which it belongs on the basis of its flash - point, boiling point, initial boiling point or vapour pressure as actually determined. (5) Substances of Class 3 which are liable to f?rm pero~­ ides easily (as happens with ethers or with certam heterocyclic oxygenated substances) are not to be handed over for carriage unless their peroxide content, calculated as hydrogen peroxide (H20 2), does not ex~eed 0.3 p~r cent. The peroxide content shall be determmed as md1 cated in Appendix A.3, marginal 3303. (6) Chemica:lly unstable substances of Class 3 are not to be handed over for carriage unless the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end, care should in particular be taken to ensure that receptacles do not con­ tain any substance liable to promote these reactions. NOTE: Even where no substance is listed under letters (a), (b) or (c) of the various items of th!s margina:l, sub­ stances solutions, mixtures and preparat10ns may be clas­ sified u~der these letters in accordance with the criteria set out in marginal 2300. A. Substances having a flash-point below 21 ° C, not toxic and not corrosive. I/ Determination of the viscous state at 35 °C sha:ll be based on the penetrometer test criteria, see Appendix A.3, marginals 3310 and 3311. , 21 For the quantities of substahces of marginal 2301 which are not subject to the provisions for this Class, either in this Annex or in Annex B, see marginal 2301a. 2300 2301 <l>EK 104 ECl>HMEPlr THr KYBEPNHreor (TEYXOr AEYTEPO) 1 ° Substances having a vapour pressure at 50°C of more than 175 kPa (1.75 bar) such as: (a) acetaldehyde (aldehyde), 2-chloropropene, vinylidene chloride, crotonylene (2-butyne), methyl iso­ propyl ether, methyl formate, isopentane, 2-methyl-1 butene, 3-methyl-1-butene (isopropylethylene), 1,4-pentadiene, normal amylene (1-pentene). 2 ° Substances having a vapour pressure at 50 ° C of more than 110 kPa (1.10 bar) but not more than 175 kPa (1. 75 bar), such as: (a) ethyl ether, isoprene, propylene oxide; (b) 1-chloropropane (propyl chloride),. 2-chloropropane (isopropyl chloride), cyclopentene, dimethoxymethane (methylal), vinyl ethyl ether, methyl propyl ether, 2-methyl-2-butene, normal pentane, 2-pentene, dimethyl sulphide. 3 ° Substances having a vapour pressure at 50° C of not more than 110 kPa (l.lQ bar), such as: (b) certain crude petroleums and other crude oils, vola­ tile products from the distillation of petroleum and of other crude oils (of the tars of coal, lignite, shale, wood or peat), e.g. petrol (gasoline), petroleum ether, condensation prod­ ucts of natural gas. NOTE: While in some climatic conditions petrol (gaso­ line) may have a vapour pressure al 50°C of more than 110 kPa (1. 10 bar) but not more than 150 kPa (1.50 bar), it is to continue to be classified under this item number. Hydrocarbons, such as: benzene, cycloheptane, cyclohexane, cyclohexene, cyclopentane, ethylbenzene, technical, heptanes, heptenes, hexanes, octanes, octenes, toluene; Halogenated substances, such as: normal butyl bromide, amyl chloride, butyl chlorides (chlorobutanes), 1, 1-dichloroethane (ethylidene chloride), propylene dichloride; NOTE: Toxic halogenated substances are substances of 16 °; corrosive halogenated substances are substances of 21 ° or 25°, Alcohols, such as: tertiary amyl alcohol, tertiary butanol (tertiary butyl al­ cohol), technical diacetone alcohol, ethanol (ethyl alcohol) and its aqueous solutions containing more than 70 per cent alcohol, isopropanol (isopropyl alcohol): Ethers, such as: acetal (1,1-diethoxyethane), 1,2-dimethoxyethane, dio­ xane, dioxolane, ethyl butyl ether, vinyl isobutyl ether, diisopropyl ether, tetrahydroforan; Aldehydes, such as: butyraldehyde, propionaldehyde; Ketones, such as: acetone, ethyl methyl ketone, methyl isobutyl ketone, methyl propyl ketone, methyl vinyl ketone; Esters, such as: secondary butyl acetate, ethyl acetate, isobutyl acetate, isopropyl acetate, methyl acetate, normal propyl acetate, vinyl acetate, ethyl acrylate, methyl acrylate, triethyl bo­ rate, trimethyl borate, methyl butyrate, dimethyl carbon­ ate, ethyl formate, propyl formates, methyl methacrylate, ethyl propionate, methyl propionate; Substances containing sulphur, such as: amyl mercaptan, butyl mercaptan, propyl mercaptan, thiophene. NOTE: Toxic substances containing sulphur are sub­ stances of 18 °. 4 ° Mixtures of substances of 1 ° to 3 ° containing not more than 55 per cent nitrocellulose with a nitrogen con­ tent not exceeding 12.6 per cent (collodion solutions, semi-collodion solutions, other nitrocellulose solutions, and nitrocellulose paints, lacquers and varnishes). (a) having a boiling point or initial boiling point not ex­ ceeding 35°C; (b) having a boiling point or initial boiling p~int exceed ing350C. ' NOTE: Mixtures having a flash-point below 21 °C and containing more than 55 per cent nit~ocellulose, what­ ever its nitrogen content; or containing not more than 55 per cent nitrocellulose·with a nitrogen content above 12 .6 per cent, are substances of Class la, (see marginal 2101, 1 °), or of Class 4.1 (see marginal 2401, 7° (a)). • 5 ° Viscous substances such as: adhesives, enamels, • paints, polishes, varnishes, and certain colours for leathers and for rotogravures, with the exception of mixtures con­ taining nitrocellulose: (a) having a boiling point or initial boiling point not ex­ ceeding 35 °C, provided that they do not come under (c); (b) having a boiling point or initial boiling point exceed­ ing 35°C, provid!'!d that they do not come under (c); (c) if they meet the following requirements: 1. that less than 3 per cent of the clear solvent layer sep­ arates in the solvent - separation test; I/ and 2. that the viscosity 21 and flash - point are in accordance with the following table: • Kinematic visco- Flow time t in accor sity v (extrapola- dance with ISO 2431-1980 Flash-point ted) ( at near-zero shear rate) Jet diameter mm2/s at 23 °( ins in mm in °C C. 20<v~ 80 20 <t~ 60 4 above 17 80 < V ~ 135 60 < t ~ 100 4 above 10 135 < V ~ 220. 20<t~ 32 6 above 5 220 <v..;;300 32 < t~ 44 6 above -1 300 <v~ 700 44 < t ~ 100 6 above -5 700<v 100 < l~ 6 5 and belm• 6 ° Harmful substances and preparations used as ·pesti­ cides and having a flash - point below 21 °C:· (a) having a boiling point or initiai hoiliri'g-point not.ex~ ceeding 35°C; • (b) having a boiling point or initial boiling point exceed ing 35°C; • • • • NOTE: The classification of substances and prepara­ tions of this item is based on the criteria for harmful sub­ stances in footnote 11 to marginal 2600 (1 ), and the Notes to 71 ° to 88 ° of marginal 2601. · . B. Toxic substances having a flash-point below 21-°C NOTES: 1. Toxic substances having a flash-point of 21 ° C or above, hydrocyanic acid and solutions thereof, and metal carbonyls, are substances of Class 6.1 I/ Solvent - separation test: This test is carried out at 23 °C using a l 00 ml graduated measuring cylinder of the stoppered type of approximately 25 cm total height and of a uniform internal diameter of approximately 3 cm over the calibrated section. The substance should be stirred to obtain a uniform.consistency and poured into th~1measuring cylinder up to the 100-ml mark. The stopper sho~j2e inserted and the cylinder left standing undis­ turbed for 24'!:iours. After 24 hours the height of the upper sepa­ rated layer should be measured and the layer's height as a per­ centage of the total height of the sample should be calculated. 2/ Viscosity determination: Where the substance concerned is non-Newtonian, or where a flow cup method of viscosity determi­ nation is otherwise unsuitable, a variable shear-rate viscometer should be used to determine the coefficient of dynamic viscosity of the substance, at 23 ° C, at a number of shear rates, the values obtained are plotted against shear rate and then extrapolated to zero shear rate. The dynamic viscosity thus obtained, divided by the ·density, gives the apparent kinematic viscosity at near-zero shear rate. 929 930 . ECJ>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: aEYTEPO) 2. For toxicity criteria, see footnote 11 to marginal 2600 (1). . 3. Harmful substances having a flash-point below 21 °C are substances of 1 ° to 6 ° of this class. 11 ° Nitriles and isonitriles (isocyanides), such as: (a) acrylonitrile, tertiary butyl isocyanide; (b) acetonitrile, butyronitrile, 2-chloroacrylonitrile, isobutyronitrile, methacrylonitrile, pivalonitrile, propionitrile. 12 ° I mines, such as: ethyleneimine, propyleneimine NOTE: Special packing conditions are applicable for these substances (see marginal 2303). 13 ° Ethyl isocyanate, m~thyl isocyanate NOTE: Special packing conditions are applicable for these. substances (see marginal 2304). 14 ° Other isocyanates, such as: (a) tertiary butyl isocyanate, methoxymethyl isocyanate, propyl isocyanates; (b) normal, butyl isocyanate, isobutyl isocyanate, solu­ tions of isocyanates having a flash-point below 21 °C (cf. Class 6.1, marginal 2601, 18° and 19°). 15 ° Other substances containing nitrogen, such as: (a) allylamine, 1,2-dimethylhydrazine; (b) pyridine. 16 ° Halogenated organic substances, such as: (a) ally) bromide, ethyl chloroformate, methyl chloroformate, chloroprene, ally! chloride; (b) methyl chlorothioformate, 1,2-dichloroethane (eth ylene dichloride), methyl chloromethyl ether. 1 7 ° Oxygenated organic substances, such as: (a) acrolein, methyl orthosilicate (tetramethoxysilane); (b) allyl acetate, diallyl ether, methanol, (methyl alco hol), methacrylaldehyde. 18 ° Organic substances containing sulphur, such as: (a) isopropyl isothiocyanate, carbon disulphide; (b) ethyl mercaptan, diethyl sulphide, solutions of isothiocyanates having a flash-point below 21 ° C ( cf. Class 6.1, marginal 2601, 20° (b)). 19° Highly toxic. gr toxic substances and preparations used as pesticides having a flash-point below 21 °C: (a) with a boiling point or initial boiling point not exceed­ ing 35 °C and/or highly toxic; (b) with a boiling point or initial boiling point exceeding 35°C and toxic. NOTES: 1. The classification of substances and prepa­ rations under 19° (a) or"(b) shall be based on the criteria for highly toxic or toxic substances contained in footnote 11 to marginal 2600 ( 1) and in the Notes to 71 ° to 88 ° of marginal 2601. 2. Harmful substances and preparations used as pesti­ cides having a flash-point below 21 °Care substances of 6 ° (a) or (b). 20° Highly toxic or toxic substances, solutions, mix­ tures and preparations, having a flash-point below 21 °C which cannot be classified under other collective headings: (a) wllh a boiling point or initial boiling point not exceed­ ing 35°C and/or highly toxic; (b) with a boiling point or initial boiling point,r~)l'.ceeding 35°C, and toxic. ·,~~ NOTE: The classification of substances, solutid'ris, mix­ tures and preparations under 20° (a) or (b) shall be based on the criteria applicable to highly toxic or toxic substances contained in footnote1 to marginal 2600 (1). C. Corrosive substances having a flash-point below 21 °C NOTES: 1. Corrosive substances having a flash-point of 21 ° C or above and some acid halides having a flash-point below 21 ° C are substances of Class 8. 2. For corrnsivity criteria, see footnote 11 to marginal 2800 (1). • 21 ° Chlorosilanes, such as: (a) dimethyldichlorosilane, ethyltrichlorosilane, m~thyl trichlorosilane, trimethylchlorosilane, vinyltrichlorosilane. NOTE: Chlorosilanes which give off inflammable gases on contact with water or moist air are substances of Class 4.3 and are not to be accepted for carriage unless specifi­ cally listed thereunder. 22 ° Amines and their solutions, such as: (a) isopropylamine, aqueous s~lutions of d!methyla­ mine of ethylamine, of methylamme and of tnmethyla­ mine'. having a boiling point not exceeding 35 ° C; (b) n-amylamine, n-butylamine, diallylamin~, di~thyla­ mine, diisopropylamine, dimethyl-N-propylamme, 1sobu­ tylamine, n-propylamine, pyrrolidine, triethylamine, aque­ ous solutions of dimethylamine, of ethylamine, of methyla­ mine and of trimethylamine, having a boiling point exceed­ ing 35°C. NOTE: Anhydrous dimethylamine, ethylamine, methy­ lamine and trimethylamine are substances of Class 2 (see marginal 2201, 3° (b t). • 23 ° Alkylhydrazines, such as: (a) 1, 1-dimethylhydrazine, methylhydrazine. 24 ° Solutions of alcoholates, such as: (b) alcoholic solutions of sodium methylate. 25 ° Other halogenated corrosive substances, such as: (a) isopropyl chloroformate, ally! iodide; (b) acetyl chloride, propionyl chloride. 26° Highly corrosive or corrosive substances, solutions, mixtures or preparations having a flash-point below 21 ° C which cannot be classified under other collective headings: (a) with. a boiling point or initial boiling point not exceed ing 35°C and/or highly corrosive; (b) with a boiling point or initial boiling point exceeding 35 ° C and corrosive. NOTE: The classification of substances, solutions, mix­ tures or preparations under 26° (a) or (b) shall be based on the criteria applicable to highly corrosive and corrosive substances contained in footnote11 to marginal 2800 (1 ). D. Non-toxic and non-corrosive substances, having a flash-point between 21 °C and l00°C inclusive NOTE: Non-toxic and non-corrosive solutions and ho­ mogeneous mixtures having a flash-point of 21 °C or over (such as certain paints or varnishes, excluding substances containing nitrocellulose) shall not be subject to the re­ quirements of ADR if, in the solvent-separation test, as de­ scribed in footnote1/ to 5 °, the height of the separated layer of solvent is less than 3 per cent of the total height, and if the substances al 23 ° C have, in the flow cup conforming Lo ISO 2431 - 1980 having a jet 6 mm in diameter, a flow time of: • (a) not less than 60 seconds, or (b) not less than 40 seconds and contain not more than 60 per cent of substances of Class 3. 31 ° Substances having a flash-point between 21 ° C and 55 ° C inclusive. (c) certain· petroleums and other crude oils, semi-heavy products from the distillation of petroleum or other crude oils (of the tars of coal, lignite, shale, wood or peat), such as: kerosene, petroleum, solvent naphtha, white spirit (tur­ . pentine substitute): Hydrocarbons, such as: . cumene (isopropylbenzene), cymenes (methyl isopropyl . benzenes), n-decane, dicyclopentadiene, ethylbenzene, chemically pure, mesitylene (1, 3, 5-trimethylbenzene), nonane, pentamethylheptane (isododecane), sty~ene (vinylbenzene), turpentine, m-xylene (l,3-dime­ thylbenzene), o-xylene (1,2-dimethyl benzene), p-xylene ( 1,4-dimethylbenzene ); Halogenated substances, such as: E<J>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: aEYTEPO) 931 chlorobenzene (phenyl chloride), dichloropentanes, 1,3-dichloropropene; Alcohols, such as: N-amyl alcohol, sec-amyl alcohol, methyl amyl alcohol (methyl isobutyl carbinol), butanol (n-butyl alcohol), n-butanol-2 (sec-butyl alcohol), cyclopentanol, diacetone alcohol, chemically pure, 2-ethoxyethanol (ethylene glycol monoethyl ether), isobutanol (isobutyl alcohol), methoxy­ ethanol, n-propanol, aqueous solutions of ethyl alcohol in a concentration from 24 per cent up to and including 70 per cent. NOTE: Aqueous solutions of ethyl alcohol in a concen­ tration less than 24 per cent are not subject to the provi­ sions of ADR. Ethers, such as: 1,2-diethoxyethane (ethylene glycol diethyl ether), di-n­ butyl ether (n-butyl ether), diisoamyl ether, phenyl methyl ether (anisole). Aldehydes, such as: 2-ethyl hexaldehyde, hexaldehyde, paraldehyde; Ketones, such as: cyclohexanone, cyclopentanone, diisobutyl ketone, mesityl oxide; Esters, such as: amyl acetates, n-butyl acetate, ethylene glycol monomethyl ether acetate, 2~ethoxyethyl acetate (ethylene glycol monoethyl ether acetate), 2-ethylbutyl acetate, methyl amylacetate, n-butyl acrylate, ethyl butyrate, isoamyl formate, ethyl lactate, triethyl phosphite, trimethyl phosphite, tetraethyl silicate. Nitrogenous substances, such as: dimethyl ethanolamine (dimethylaminoethanol), mor­ pholine, amyl nitrate, nitromethane, nitropropanes, pico­ lines (methylpyridines). 32 ° Substances having a flash-point above 55 ° C, up to and including 100°C. (c) Certain petroleums and other crude oils, heavy prod­ ucts from the distillation of petroleum or other crude oils, certain gas oils, certain tars and their distillation products, heating oils, diesel oils; Hydrocarbons, such as: decahydronaphthalene (decalin), diethyl benzenes, tetrahydronaphthalene, undecane; • Oxygenated substances, such as: cyclohexyl acetate, di isobutyl carbinol (2,6-dimethyl heptanol) furfural (furfuraldehyde), hexanols; Halogenated substances, such as: 2-ethyl hexyl chloride; Nitrogenous substances, such as: N,N-dimethyl formamide; 3 3 ° ( c) Mixtures of substances of 31 ° ( c) containing not more than 55 per cent nitrocellulose with a nitrogen con­ tent not exceeding 12.6 per cent (solutions of collodions, of semi-collodions, other nitrocellulose solutions and nitrocellulose paints, varnishes and lacquers. NOTE: Mixtures containing more than 55 per cent nitrocellulose, whatever its nitrogen content, or containing not more than 55 per cent nitrocellulose with a nitrogen content above 12.6 per cent, are substances of Class la (see marginal 2101, 1 °) or of Class 4.1 (see marginal 2401, 7° (a)). 34 ° (c) Mixtures of substances of 32 ° (c) containing not more than 55 per cent nitrocellulose with a nitrogen con­ tent not exceeding 12.6 per cent (solutions of collodions, of semi-collodions, other nitrocellulose solutions and nitrocellulose paints, varnishes and lacquers). NOTE: Mixtures containing more than 55 per cent nitrocellulose, whatever its nitrogen content, or containing not more than 55 per cent nitrocellulose with a nitrogen content above 12.6 per cent, are substances of Class la (see marginal 2101, 1 °) or of Class 4.1 (see marginal 2401, 7° (a)). E. Empty packagings 41 ° Empty packagings, empty tank-vehicles, empty demountable tanks and empty tank-containers, uncleaned, which have contained substances of Class 3. Substancesofl O to6°, 21 ° to26° and 31 ° to34° car- 2301a ried in conformity with the following provisions are subject neither to the provisions for this Class contained in this Annex nor to those contained in Annex B. (1) (a) Substances classified under (a) of each item: Not more than 500 ml per inner packaging and not more than 1 litre per package; (b) Substances classified under (b) of each item: Not more than 3 ° litres per inner packaging and not more than 6 litres per package; (c) Substances classified under (c) of each item: Not more than 3 litres per inner packaging and not more than 45 litres per package. These quantities of substances shall be carried in combi­ nation packaging which at least meet the conditions of mar­ ginal 3538. The "General conditions of packing" of Appendix A.5, marginal 3500, (1), (2) and (4) to (7) shall be observed. NOTE: In the case of homogeneous mixtures containing water, the quantities specified relate only to the substances of this Class contained in those mixtures. (2) The motor-fuel contained in the tanks of transport vehicles for their propulsion or the operation of their spe­ cialized equipment (refrigerators, for example). The fuel cocks between the engine and the fuel tank of motorcycles and motor-assisted pedal cycles whose tanks contain fuel, must be closed during transport; in addition; these motorcycles and motor-assisted pedal cycles must be loaded upright and secured against falling. 2. Provisions A. Packages 1. General conditions of packing (1) Packagings shall satisfy the conditions of Appendix 2302 A.5, unless special conditions 'for the packing of certain substances are prescribed in marginals 2303-2310. (2) I n accordance with the provisions of marginals 2300 (3) and 3511 (2), the following shall be used: Packagings of packing group I, marked with the letter "X", for the very dangerous substances classified under the letter (a) of each item; , Packagings of packing group II or I, marked with the let­ ter "Y", or "X", for the dangerous substances classified under the letter (b) of each item; Packagings of packing group III, II or I, marked with the letter "Z", "Y" or "X", for the less dangerous substances classified under the letter (c) of each item. NOTE: For the carriage of substances of Class 3 in tank­ vehicles, demountable tanks or tank containers, see Annex B. 2. Special conditions of packing (a) Imines of 12 ° shall be packed in steel receptacles of 2303 sufficient thickness, which shall be closed by a screw threaded bung or plug rendered leakproof both to liquid and to vapour by means of a suitable gasket. The recepta cles shall initially and periodically, at least every five years, be tested at a pressure of not less than 0.3 MPa (3 bar) gauge pressure in accordance with marginal 2216. Each receptacle shall be secured by absorbent cushioning mate rials in a strong leakproof protective metal packaging. The protective packaging shall be hermetically closed and its clos\lre shall be secured against any inadvertent opening. The ·mass of the contents shall not exceed 0.6 7 kg per litre of capacity. A package shall not weigh more than 75 kg. Packages weighing m ore than 30 kg, other than those for warded as a full load, shall be fitted with means of han dling. (b) Imines of 12 ° may also be packed in steel recepta 932 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO). cles of sufficient thickness, which shall be closed by a screw-threaded bung and a screw-threaded protective cap or equivalent device leakproof both to liquid and to vapour. The receptacles shall initially and periodically, at least every five years, be tested at a pressure of at least 1 MPa (10 bar) gauge pressure in accordance with marginal 2216. The mass of the contents shall not exceed 0.67 kg per litre of capacity. A package shall not weigh more than 75 kg. Methyl isocyanate and ethyl isocyanate of 13 ° shall be packed: (a) in hermetically closed receptacles made of pure alu­ minium and having a capacity not exceeding one litre, which shall not be filled beyond 90 per cent of their capac­ ity. The receptacles shall be secured, not more than 10 to a box, with appropriate cushioning material in a wooden box. Packages of this kind shall satisfy the test requirements for combination packagings conforming to marginal 3538 for packing group I, and shall not weigh more than 30 kg; or (b) in receptacles made of pure aluminium having a wall thickness of not less than 5 mm or in receptacles of stain­ less steel. The receptacles shall be fully welded and shall initially and periodically, at least every five years, be tested at a pressure of at least 0.5 MPa (5 bar) gauge pressure in accordance with marginal 2216. They shall be so closed as to be leakproof by means of two closures one above the other, one of which shall be screw-threaded or secured in an equally effective manner. The degree of filling shall be not more than 90 per cent. Drums weighing more than 100 kg shall be fitted with ex­ panded (pressed1o'ut)rolling hoops or separate (fitted) roll ing hoops. • Substances classified iinder (a) of the various items of marginal 2301 shall be ·packed: (a) in non-removable head steel drums conforming to marginal 3520, or (b) in non:remoyable head aluminium drums conform­ ing to marginal 3521, or • •• : (c) in steelJerricans conforming to margi~al 3522, or (d) in non- removable head plastics drums of a capacity not exceeding 60 litres or plastics jerricans conforming to marginal 3526, or . (e) in composite packagings (plastics material) conform­ ing to marginal 3537, or • (f) in combination packagings with inner packagings of glass, plastics material or metal conforming to marginal 3538. (1) Substances classified under (b) of the various items of marginal 2301 shall be packed: (a) in steel drums conforming to marginal 3520, or (b) in aluminium drums conforming to marginal 3521, or (c) in steeljerricans conforming to marginal 3522, or (d) in plastics drums or jerricans conforming to marginal 3526, or . (e) in composite packagings (plastics material) conform­ ing to marginal 3537, or (f) in combination packagings conforming to marginal 3538. NOTE to (a), (b) and (d): Removable-head drums are only permitted for viscous substances having a viscosity above 200 mm2/s at 23°C. (2) Substances classified under (b) of 3 °, 6 °, 15 °, 1 7 °, 22 °, 24 ° and 25 ° may also be packed in composite packagings (glass, porcelain or stoneware) conforming to marginal 3539. Substances classified under (c) of the various items of marginal 2301 shall be packed: (a) i.n steel drums conforming to marginal 3520, or (b) in aluminium drums conforming to marginal 3521, or (c) in steeljerricans conforming to marginal 3522, or 2304 2305 2306 2307 ( d) in plastics drums or jerricans conforming to marginal 3526, or (e) in composite packagings (plastics material) conform­ ing to marginal 353 7, or • (f) in combination packagings conforming to marginal 3538, or (g) in composite packagings (glass, porcelain or stone­ ware) conforming to marginal 3539. NOTES: 1. To (a), (b) and (d): Removable-head drums are only permitted for viscous substances having a viscosity above 200 mm2 /s at 23 °C. 2.,Packagings conforming to marginal 2307 containing substances of 32 ° ( c) and 34 ° ( c) need only meet the re­ quirements of marginal 3500 (1), (2) and (4) to (7). (1) Ethyl alcoholand its aqueous solutions of 3 ° (b) and 31° (c) may also be packed in bung-type wooden barrels conforming to marginal 3524. (2) Substances of 3 ° (b), 4 ° (b), 5 ° (b) and (c), 6° (b), 31 ° (c), 32 ° (c), 33 ° (c) ~nd 34 ° (c) may also be packed in light gauge metal packagings conforming to marginal 3540. Removable-head light gauge metal packagings are permitted only for viscous substances having a viscosity above 200 mm2 /sat 23 °C, and for substances of 5 ° (c). NOTE: Packagings conforming to marginal 2308 (2) containing substances of 32° (c) and 34° (c) need only meet the requirements of marginal 3500 (1 ), (2) and ( 4) to (7). The openings of packagings for substances of 6 ° (a) and (b), 11 ° (a) and (b), 14° (a) and (b), 15° (a) and (b), 16° (a) and (b), 17° (a) and();,), 18.0 (a) and (b), 19° (a) and (b), 20° (a) and (b), shall be so closed as to be leakproofby means of two closures in series, one of which must be screw-threaded or secured in an equally effective manner. Packagings containing preparations of 31° (c) or 32° (c) which give off small quantities of carbon dioxide and/or nitrogen, shall be vented, in accordance with marginal 3500 (8). 3. Mixed packing (1) Substances covered by the same item number may be packed together in a combination packaging conforming to marginal 3538. (2) Substances of different items of Class 3 in quantities not exceeding five lit res per packaging may be packed to­ gether and/or with goods not subject to the provision~ of ADR, in a combination packaging conforming to margmal 3538, provided they do not react dangerously with one an­ other. (3) Except as otherwise specially provided below, ~ub­ stances of Class 3, in quantities not exceeding five htres per packaging, may be packed together in a combination packaging conforming to marginal 3538 with substances or articles of other classes, provided that mixed packing is also permitted for substances or articles of these classes, and/ or with goods which are not subject to the provisions of ADR, provided they do not react dangerously with one an­ other. (4) The following are considered dangerous reac tions: (a) combustion and/or giving off considerable heat; (b) emission of inflammable and/ or toxic gases; (c) formation of corrosive liquids; (d) formation of unstable substances. . (5) The mixed packing of acid substances with basic substances in a package shall not be permitted if the two substances are packed in fragile packagings. (6) The provisions of marginals 2001 (7), 2002 (6) and (7) and 2302 shall be complied with. (7) If wooden or fibreboard boxes are used, a package shall not weigh more than 100 kg. 2308 2309 2310 2311 EG>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) Special conditions: Maximum quantity per per Item Description recep- pack- Special No. of substance tacle age provisions 12° lmines 13° Methyl and Mixed packing not per ethyl mitted isocyanate Substances 0.5 1 Shall not be tlassified under litre litre packed to a) in each item ~ether with substances pr articles of (:lasses la, lb, le, 5.2 other than hardeners and corn pound sys ems) and 17. 4. Marking and danger labels on packages (see Appen- •• dix A.9) ( l) Packages containing substances of 1 ° to 6 °, 11 ° to 26 °, 31 ° and 33 ° shall bear a label conforming to model No.3. However, if substances are packed in composite packagings (glass, porcelain or stoneware) conforming to marginal 3539 of a capacity exceeding five litres, the pack­ ages shall bear two labels conforming to model No.3 (see marginal 3901 (2)). (2) Packages containing substances of 6 ° shall in addi­ tion bear a label conforming to model No.6. lA; those con­ taining substances of 11 ° to 20 °, a label conforming to model No.6.1, and those containing substances of 21 ° to 26 °, a label conforming to model No.8. (3) Packages containing fragile packagings not visible from the outside shall bear on two opposite sides a label conforming to model No.12. (4) Packages containing packagings the closures of which are not visible from the o'utside and packages con­ taining vented packagings or vented packagings without outer packaging shall bear on two opposite sides a label conforming to model No.11. B. Particulars in the transport document (1) The description of the goods in the transport docu­ ment must conform to one of the names underlined in mar­ ginal 2301. If the substance is not mentioned by name, the chemical name must be entered. For substances and prep­ arations of 6 ° and 19 °, this name shall be entered for the most dangerous component, both of the pesticide element I/ and of the inflammable element (e.g. parathion in hex­ ane). The description of the goods must be underlined and followed by particulars of the class, the item number (to­ gether with the letter, if any), and the initials «ADR» (or «RID») e.g., 3, 14° (a), ADR. (2) For consignments of chemically unstable sub­ stances, the sender shall certify in the transport document: «Measures taken in accordance with marginal 2300 (6)». I/ For the description of the pesticide element, the name accord­ ing to ISO Standard R.1/50-1981 (see also marginal 2601, 71 ° to 88°) should be used, if it appears therein. 2312 2314 2315 2321 C. Emp'ty packagings ( 1) Empty packagings, uncleaned, of 41 °, shall be closed in the same way and with the same degree· of leakproofness as if they were full. • (2) Empty packagings, uncleaned, of 41 °, shall bear th~ same danger labels as if they were full. • (3) The description in.the transport document shall con­ form to one of the names underlined in 41 °, e.g.: Empty packaging 3, 41 °, ADR. This description shall be under­ lined. In the case of empty tank - vehicles, empty demountable tanks and empty tank - containers, uncleaned, this description shall be completed by adding the words «Last load», together with the name and item number of the goods last loaded, e.g. Last load: Petrol, 3 ° (b). CLASS 4.1. INFLAMMABLE SOLIDS 1. List of substances Among the substances covered by the heading of Class 4.1, those listed in marginal 2401 are subject to the provi­ sions of this Annex and of Annex B. These substances to be accepted for carriage under certain conditions are to be considered as substances of ADR. 1 ° Substances which can easily be ignited by sparks, such as wood flour, sawdust, wood shavings, wood fibre, wood charcoal, wood parings and wood cellulose, old paper and waste paper, paper fibres, cane (except Spanish broom), reeds, hay, straw, also when damp (including maize, rice and flax straw), vegetable textile substance s and waste of vegetable textile substances, cork in powder or granular form, expanded or not, with or without an ad- mixture of tar or of other substances not subject to sp o~ta; • neous oxidation, and cork waste in smali-Iumps. ·See· also· Class 4.2, marginal 2431, 8°-10°, and marginai 2431a, under (b). NOTES: 1. These substances are included in the list only for the purposes of the prohibitions on niixed:•loading. • For this purpose the provisions of marginal 2416 (1) apply. No other clause, either of this Annex or of Annex B, is applicable to them. • • 2. Hay still having a degree of humidity which might lead to fermentation is not to be accepted for carriage. . • 3. Wrappings and slabs of expanded cork, manufac­ tured under pressure, with or without an admixture of tar or of other substances not subject to spontaneous oxida­ tion, are not subject to any. of the provisions of ADR. 4. Cork impregnated with substances still subject to· spontaneous oxidation is a substance of Class 4.2 (see mar­ ginal 2431, 9°). 2° (a) Sulphur (including flowers of sulphur); (b) sulphur in the melted state. 3 ° Cello id in, produced by incomplete evaporation of the alcohol contained in collodion and consisting mainly of col­ lodion coiion: 4 ° Celluloid in slabs, sheets, rods or tubes, and fabrics coated with nitrocellulose. 5 ° Film celluloid, i.e. the raw material for films, without emulsion, in rolls and developed celluloid films. 6 ° Celluloid waste and celluloid - film waste. NOTE: Nitrocellulose-film waste, free from gelatine, in reels, sheets or strips, is a substance of Class 4.2 (see mar­ ginal 2431, 4°). 7° (a) Weakly nitrated nitrocellulose (such as collodion cotton), i.e. with a nitrogen content not exceeding 12.6 per cent, well stabilized and containing in addition- not less than 25 per cent, water or alcohol (methyl, ethyl, normal propyl or isopropyl, butyl or amyl alcohol, or mixtures thereof), also if denatured, solvent naphtha, benzene, toluene, 933 2322 2323 2399 2400 2401 934 ECJ>HM EPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) xylene, mixtures of denatured alcohol and xylene, mixtures of water and alcohol, or alcohol containing camphor in so­ lution; NOTES: 1. Nitrocellulose with a nitrogen content ex­ ceeding 12.6 per cent is a substance of Class la (see mar­ ginal 2101, 1 °). 2. When the nitrocellulose is wetted with denatured al­ cohol, the denaturing substance must not have a detrimen­ tal effect on the stability of the ~itrocellulose. (b) plasticized nitrocellulose, non - pigmented, contain­ ing not less than 18 per cent plasticizer (butyl phthalate or a plasticizer at least equivalent in effect) and in which the nitrocellulose has a nitrogen content not exceeding 12.6 per cent; the nitrocellulose may be in the form of chips; NOTE: Plasticized nitrocellulose, non-pigmented, con­ taining not less than 12 per cent and less than 18 per cent butyl phthalate or a plasticizer at least equivalent in effect is a substance of Class la (see marginal 2101, 4°). (c) plasticized nitrocellulose, pigmented, containing not less than 18 per cent plasticizer (butyl phthalate or a plasticizer at least equivalent in effect), in which the nitrocellulose has a nitrogen content not exceeding 12.6 per cent and which contains not less than 40 per cent nitrocellulose; the nitrocellulose may be in the form of chips. NOTE: Plasticized nitrocellulose, pigmented, containing less than 40 per cent nitrocellulose is not subject to the provisions of ADR. For (a), (b) ~nd (c): weakly - nitrated nitrocellulose and plasticized nitrncellulose, pigmented or not, are not to be accepted for carriage unless they satisfy the stability and safety conditions of Appendix A. l or the conditions set forth above regarding the nature and quantity of the addi­ tional substances. For (a), see also Appendix A.I," marginal 3101; for (b) and (c), see also Appendix A.l, marginal 3102, 1. 8° Red phosphorus (amorphous), phosphorus sesquisulphide and phosphorus pentasulphide. NOTE: Phosphorus pentasulphide not free from white or yellow phosphorus is not to be accepted for carriage. 9° Ground rubber, rubber dust. 10 ° Dust of coal; lignite, lignite coke ~n-d peat, artifi­ cially prepared (e.g. by pulverization or other processes), and coke from carbonized lignite rendered inert (i.e. not li­ able to spontaneous ignition). NOTES: 1. Natural dusts obtained as residues in the production of coal, coke, lignite or peat are not subject to the provisions of ADR. 2. Coke from carbonized lignite not rendered com­ pletely inert is not to be accepted for carriage. 11 ° (a) Crude naphthalene with a melting point below 75°C; . (b) pure naphthalene and crude naphthalene with a melting point of 7 5 ° C or over; (c) naphthalene in the melted state. For (a) and (b) see also marginal 2401 a. 12 ° Expandable polystyrenes, giving off inflammable vapour having a flash - point no.t above 55 ° C. Naphthalene in balls or flakes of 11 ° (a) and (b) is sub­ ject neither to the provisions for this Class contained in this Annex nor to those contained in Annex B if it is packed, not more than 1 kg per box, in tightly closed fibreboard or wooden boxes and these boxes are enclosed, not more than 10 per case, in wooden cases. 2. Provisions A. Packages 1. General conditions of packing (1) Packagings shall be so closed and arranged as to pre­ vent any loss of the contents. (2) The materials of which the packagings and their clo 2401a 2402 sures are made must not be liable to attack by the contents or form harmful or dangerous compounds therewith. (3) Packagings, including their closures, must be suffi­ ciently rigid and strong in all their parts to prevent any loos­ ening during carriage and to meet the normal requirement of carriage. Solid substances shall be firmly secured in their packagings, and inner packagings shall be firmly se­ cured in outer packagings. Unless otherwise specified in the section entitled «Packing of a single substance», inner packagings may be enclosed in outer packagings either sin­ gly or in groups. 2. Packing of a single substance (1) Sulphur of 2 ° (a) shall be packed in stout bags made of paper or of closely woven jute. (2) Sulphur in the melted state, of 2 ° (b ), may not be carried otherwise than in tanks. Celloidin of 3 ° shall be so packed as to prevent its desicca­ tion. (1) Celluloid in slabs, sheets, rods or tubes, and fabrics coated with nitrocellulose, of 4 °, shall be enclosed: (a) in firmly closed wooden packagings, or . (b) in strong paper wrappings which shall be placed. 1. in crates; or 2. between frames made of boards, the edges of the frames extending beyond the paper wrapping and the frames being bound together with iron bands; or 3. in wrappings of closely woven fabric. (2) A package must not weigh more than: 75 kg in the case of celluloid in slabs, sheets or tubes and of fabrics coated with nitrocellulose, if the outer pack­ aging is made of fabric in conformity with (1) (b) 3; 120 kg in all other cases. Film celluloid in rolls and developed celluloid films of 5 ° shall be enclosed in wooden packagings or in fibreboard boxes. ( 1) Celluloid waste and celluloid - film waste of 6 ° shall be enclosed in wooden packagings or in two strong bags made of coarse, closely woven jute canvas, the bags being fireproofed so as not to ignite even on contact with a flame and having strong and continuous seams. These bags shall be placed one inside the other; after filling, their openings shall be separately and several times folded over and closely stitched so as to prevent any escape of the contents. However, celluloid waste may be packed in a single bag if the celluloid waste is first packed in strong packing paper or in a suitable plastics material and it is certified in the transport document that the celluloid waste does not con­ tain any waste in the form of dust. (2) Packages having a raw - canvas or jute packaging must not weigh more than 40 kg in single packaging nor more than 80 kg in double packaging. (3) For the particulars in the transport document, see marginal 2416 (2). (1) Substances of 7° (a) shall be packed: (a) in wooden receptacles or in drums made of imperme­ able fibreboard; these receptacles and drums shall have a lining impermeable to the liquids they contain; their clo­ sures must be leakproof; or (b) in bags impermeable to the vapours from the liquids they contain ( e.g. bags made of rubber or of a suitable plas­ tics material not readily inflammable), placed in a wooden box or in a metal receptacle; or ( c) in zinc - lined or lead - lined iron drums; or ( d) in receptacles made of tin - plate, zinc sheet or alu­ minium sheet and secured by cushioning materials in wooden boxes. (2) Nitrocellulose of 7° (a), if wetted exclusively with water, may be packed in fibre drums which have under­ gone special treatment to render them completely imper­ meable; the closures of the drums shall be water - vapour proof. 2403 2404 2405 2406 2407 2408 E<DHMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) (3) Nitrocellulose of 7° (a), with added xylene, may 110I be packed otherwise than in metal receptacles. ( 4) Substances of 7 ° (b) and ( c) shall be packed: . (a) in wooden packagings lined with stout paper or zinc sheet or aluminium sheet; or (b) in strong fibre drums or, provided that the sub­ stances are dust - free and that this is certified in the trans­ port document, in fibreboard boxes which have been ren­ dered impermeable; or (c) in sheet - metal packagings. (5) For substances of 7°, metal receptacles must be so constructed that, by reason of the method of assembly of their walls, of their mode of closure, or of the presence of a safety device, they yield when the internal pressure reaches a value not greater than 0.3 MPa (3 bar); the presence of these closures or safety devices must nor impair the strength of the receptacle not impair its closure. (6) A package must not weigh more than 75 kg or, if it can be rolled, not more than 300 kg; however, a fibre drum must not weigh more than 75 kg and a fibreboard box not more than 35 kg. (7) For the particulars in the transport document, see marginal 2416 (3). (1) Red phosphorus and phosphorus pentast.ilphide (8°) shall be packed: (a) in receptacles made of sheet iron or tin - plate, which shall be placed in a strong wooden case; a package must not weigh more than 100 kg; or (b) in receptacles made of glass or stoneware not less than 3 mm thick, or of a suitable plastics material, each containing not more than 12.5 kg of substance. These re­ ceptacles shall be secured with cushioning materials in a strong wooden box; a package must not weigh more than 100 kg; or ( c) in metal receptacles which, if with their contents they weigh more than 200 kg, shall be fitted with reinforcing hoops at their ends, and with rolling hoops. (2) Phosphorus sesquisulphide (8 °) shall be packed in leakrroof metal receptacles, which shall be secured by cushioning 111aleri,ils in wooden boxes \\ilh clost:>h·-ri11i11g sides. A package must not weigh more than 75 kg. Substances of 9 ° shall be packed in metal or wooden re­ ceptacles or in strong bags. (2) Wooden receptacles and bags are not, however, to be accepted for coal dust, lignite dust or peat dust artificially prepared unless the dust has been completely cooled after drying by heat. (3) For the particulars in the transport document, see marginal 2416 (4). (1) Naphthalene of 11 ° (a) shall be packed in firmly closed wooden or metal receptacles. (2) Naphthalene of 11 ° (b) shall be packed in wooden or metal receptacles, or in stout fibreboard boxes or in strong bags made of textile or of four - ply paper or of a suitable plastics material. Where fibreboard boxes are used, a package must .not weigh more than 30 kg. (3) Naphthalene in the melted state of 11 ° (c) must not be carried otherwise than in tanks. ' ( 4) Expandable polystyrenes of 12 ° shall be packed in securely closed leakproof packagings. 3. Mixed packing (1) Substances grouped under the same item number may be included in the same package. The inner packagings shall conform to what is prescribed for each substance, and the outer packaging shall be that laid down for the substances of the item number in question. A pack­ age containing celluloid rods and tubes packed together in a textile wrapping must not weigh more than 75 kg. (2) If smaller quantities are not prescribed in the section entitled «Packing of a single substance», substances of this Class, in quantities not exceeding 6 kg for all of the sub­ stances listed under the same item number or the same let 2409 2410 2412 2413 . ter, may be enclosed in the same package, either with sub­ stances of another item number or of another letter of the same class, or with dangerous substances belonging to other classes (if mixed packing is likewise allowed in the case of such substances), or with other goods, subject to the following special conditions: ' The inner packagings must satisfy the general and spe­ cial conditions of packing. In addition, the general provi­ sions contained in marginals 2001 (7) and 2002 (6) and (7) must be observed. A package must not weigh more than 150 kg, or more than 75 kg if it contains fragile receptacles. Special conditions Maximum quantity Description per re- per Special Item no of substance ceptacle package provisions 2°(a) Sulphur 5kg 5kg Must not be packed together with chlorates, permanganates, • perchlorates, or peroxides ( other than solutions of hydrogen perox W~akly nitrated ide) 7°(a) 100 g 1 kg Musi not be nitrocellulose packed toget~er (such as collodion with substances of cotton) Classes 4.2 and 5.1 30 Red (amorphous) 5kg 5kg phosphorus 8° Phosphorus Mixed packing .~, ~·-· sesquisulphide not allowed " • 4. Marking and danger labels on packages (see Appen dix A.9) . . ... (1) Packages containing substances of 4° to.13'0 .,.shall bear a label conforming to model No 4.1. However, if substances of 4 ° to 7 ° are packed in wrap­ pings made of closely woven fabric in accordance with marginal 2405 (1) (b) 3., in fibreboard boxes in accor­ dance with marginals 2406 and 2408 (4) (b), in jute bags in accordance with marginal 2407 (1) or in fibre drums in accordance with marginal 2408 (1) (a), (2) an 4 (b), the packages shall bear two labels conforming to model No 4.1. Packages containing e·xpandable polystyrenes of 12 ° shall bear the following marking: «Keep away from any source of ignition». This marking shall be in an official lan­ guage of the country of departure, and also, if that lan­ guage is riot English, French, or German, in English, French or German, unless any agreements concluded be­ tween the countries concerned in the transport operation provide otherwise. (2) Packages containing fragile receptacles not visible from the outside shall bear a label conforming to model No. 12. If the fragile receptacles contain liquids, the packages shall, in addition, except in the case of sealed ampoules, bear labels conforming to model No 11; these labels shall be affixed high up on two opposite sides of cases or in an equivalent manner when other packagings are used .. B. Particulars in the transport document (1) The description of the goods in the transport docu­ ment must conform to one of the names underlined in mar­ ginal 2401. Where the na.me of the substance is not indi­ cated in tJ.ie case of 1 °, the trade name must be used. The 935 2414 2415 2416 936 ECJ>HMEPII THI KYBEPNHIEOI (TEYXOI aEYTEPO) . description olthe· goods must be underlined and followed : by particulars of the Class, ~e item number (together with • the letter;~, and the initials «ADRi. or «RID» (e.g. 4.1, 7 ° (a), ADR). • • (2) In the case of celluloid waste of 6 ° packed in stout packing paper or in a suitable plastics material and placed, so packed, in bags made of closely - woven raw canvas or jute, the following must be certified in the transport docu­ ment: «Contains no waste in dust form». (3) In the case of substances of 7° (b) and (c) packed in fibreboard boxes, the following must be certified in the transport document: «Substances free from dust». (4) In the case of coal dust, lignite dust or peat dust (10°) artificially prepared and packed in wooden recepta­ cles or in bags (see marginal 2411 (2)), the following must be certified in the transport document: «Substances com­ pletely cooled after drying by heat». C. Empty packagings No provisions CLAS/, 4.2 SUBSTANCES LIABLE TO SPONTANEOUS COMBUSTION 1. List of substances Among the substances and articles covered by the head­ ing of Class 4.2, only those listed in marginal 2431 are Lo be accept1d for carriage, and then only subject to the provi­ sions of this Annex and of Annex B. These substances and articles to be accepted for carriage under certain condi­ tions are to he considered as substances and articles of ADR. 1 ° • White· or yellow phosphorus. 2 ° Compounds of phosphorus with alkali metals or alkaline-earth ·metals; :c·.g.~ sodium phosphide, calcium phosphide, strontium phosphide. NOTES: 1. Phosphides of aluminium, magnesium and zinc a~e:substances of Class 6.1 (see marginal 2601. 43 ° , (a) or (b)): • '' ~ 2. Other compounds of phosphorus with heavy metals such as iron, copper, tin, etc. are not subject to the provi­ sions of ADR. 3 ° Organo-metallic compounds liable to spontan·eous combustion, such as: aluminium alkyls, aluminium alkyl halides, aluminium alkyl hydrides, lithium alkyls, magne­ sium alkyls, zinc alkyls. gallium alkyls and boron alkyls: and their solutions liable to spontaneous combustion. NOTES: 1. Organo-metallic compounds and their so­ lutions which are not liable to spontaneous combustion but which on contact with water give off inOammable gases are substances of Class 4.3 (see marginal 2471, 2° (e)). 2. Inflammable solutions of substances of 3 ° in con­ centrations which are not liable to spontaneous combustion and which on contact with water do not give off inOamma­ ble gases are substances of Class 3. The sender shall enter in the transport document the words: ''Substance not liable to spontaneous combustion». (See also Class 4.3. marginal 2471, 2° (d), NOTE 2.). 4 ° Nitroc~llulose-film waste, free from gelatine. in reels, sheets or strips. NOTE: Nitrocellulose-film waste free from gelatine is not to be accepted for carriage if it is dusty or includes dusty portions. 5 ° (a) Used rags and waste: (b) greasy or oily fabrics, wicks. cord or thread: (c) the following greasy or oily substances: wool. hair (and horsehair), artificial wool, reclaimed wool (also called wool shoddy), .cotton, recarded collon, artificial fibres (rayon, etc.), silk. flax, hemp and jute, also in the form of spinning or weaving waste. 2417 2423 2424 2425 2429 2430 2431 For (a), (b) and (c), see also marginal 243 la under (a). NOTE: Wetted substances of 5° (b) and (c) are not lo be accepted for carriage. 6° (a) Metals in pyrophoric form, such as: dust and powder of aluminium, magnesium, nickel. tita­ nium, zinc or zirconium, also mixtures of powders and powders of alloys; dust from blast-furnace filters; NOTE: Dust and powder of metals in a non-pyrophoric form which, on contact with water, give off inOammable gases, are substances of Class 4.3 (see marginal 24 71, l 0 (d)). (b) salts of dithionous (hydrosulphurous) acid (H 2 Sp 4 ) such as: dithionites (hydrosulphites of sodium, potassium, calcium and zinc; (c) anhydrous potassium sulphide and anhydrous so­ dium sulphide, and their hydrates containing less than 30 per cent water of crystallization; sodium hydrosulphide containing less than 25 per cent water of crystallization. NOTE: Potassium sulphide and sodium sulphide con­ taining not less than 30 per cent water of crystallization. and sodium hydrosulphide containing not less than 25 per cent water of crystallization are substances of Class 8 (see marginal 2801, 45° (h)). For (a), see also marginal 2431a under (b): for (b).see also marginal 243 la under (a). 7 ° Freshly calcined soot. See also marginal 2431 a under (a). 8° Newly-quenched charcoal, powdered, granulated or in lumps. See also marginal 243 la under (a) and Class 4. l. mar­ ginal 2401, 1 °. NOTE: By "newly-quenched charcoal" is meant: in the case of charcoal in lumps, charcoal which has been quenched less than four days previously: in the case of powdered charcoal and of granulated char­ coal in a granule size of less than 8 111111, charcoal which has been quenched less than eight days previously and has been\air-cooled in thin layers or by a process ensuring an equivalent degree of cooling. 9° 1 Mixtures of granulated or porous combustible sub­ stances with constituents still liable lo spontaneous oxida­ tion, such as linseed oil or other natural drying oils. boiled or with added drying compounds, resin, resin oil. petro­ leum residues, etc. (e.g. the substance known as cork waste, lupuline), and oily residues from the bleaching of soya oil. See also marginal 243 la under (a) and Class 4. l. mar­ ginal 2401, l O • 10° Paper, cardboard and products made of paper or cardboard (e.g., cardboard wrappings and cardboard rings), wood-fibre sheets, skeins of thread, fabrics. string. thread, spinning or weaving wastes, all impregnated with oils, greases, natural drying oils, boiled or with added dry­ ing compounds or other impregnating substances liable lo spontaneous oxidation. See also marginal 243 la under (a) and Class 4.1, marginal 2401, 1 °. NOTE: Substances of 10° are 1101 lo be accepted for carriage if their humidity exceeds the hygroscopic humid­ ity. 11 ° The substance with an iron oxide hase having been used for purifying lighting gas (spent oxide of iron). NOTE: If the substance which has been used for purify­ ing lighting gas (spent oxide of iron) is, after storage and aeration, no longer liable to spontaneous ignition. and if this is certified in the transport document by the entry: "Substance not liable to spontaneous ignition". ii is not subject to the provisions of ADR. 12° Used yeast bags, uncleaned. See also marginal 243 la under (a). 13 ° Empty sodium nitrate bags made of a textile fahric. NOTE: Textile bags from which all the nitrate impreg­ nating them has been completely removed by washing are <I>EK 104 E<DHMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 937 not subject to the provisions of ADR. 14 ° Empty packagings, empty tank-vehicles, empty demountable tanks and empty tank-containers, uncleaned, having contained phosphorus of 1 °. 15 ° Empty packagings, empty tank-vehicles, empty· demountable tanks and empty tank-containers, uncleaned, having contained substances of 3 °. NOTE: With reference to 14 ° and 15 °: empty packagings which have contained other substances of Class 4.2 are not subject to the provisions of ADR. Dangerous substances handed over for carriage in con­ formity with the following provisions are subject neither to the provisions for this Class contained in this Annex nor to those contained in Annex B: (a) Substances of 5 °, 6 ° (b), 7 ° to 10° and 12 °, if their condition· is such as to exclude any danger of spontaneous ignition and if this is certified by the sender in the transport document by the entry: "Substances not liable to spontane­ ous ignition"; for substances of 8° and certain substances of 9° and 10°, see, however, Class 4.1, marginal 2401. 1 o. , (b) Dust and powder of aluminium or zinc of 6 ° (a), e.g. packed together with varnish for use in the manufacture of colours, if packed with care in quantities not exceeding 1 kg. 2. Provisions A. Packages 1. General conditions of packi,~g (1) Packagings shall be so closed and arranged as to prevent any loss of the contents. (2) The materials of which the packagings and their clo­ sures are made must not be liable to attack by the contents nor form harmful or dangerous compounds therewith. (3) Packagings, including their closures, must be suffi­ ciently rigid and strong in all their parts to prevent any loos­ ening during carriage and to meet the normal requirements of carriage. In particular, in the case of substances in the liquid slate or immersed in a liquid or in solution. recepta­ cles and their closures must, unless the section headed "Packing of a single substance or of articles of the same kind" provides otherwise, be able to withstand any pres­ sure which, the pressure of air also being taken into ac­ count, may arise inside the receptacles in normal carriage. For this purpose a free space must be left, account being taken of the difference between the temperature of the sub­ stances at the time of filling and the highest mean tempera­ ture which they are likely to reach during carriage. Solid substances shall be firmly secured in their packagings. and inner packagings shall be firmly secured ill outer packagings. Unless otherwise specified in the section enti­ tled "Packing of a single substance or of articles of the same kind", inner packagings may be enclosed ill outer packagings either singly or in groups. (4) Bottles and other glass receptacles must be free from faults liable to impair their strength, in particular. in­ ternal stresses must have been suitably relieved. The thick­ ness of the walls must be not less than 3 mm in the case of receptacles which, with their contents, weigh more than 35 kg, and not less than 2 mm in the case of other receptacles. The tightness of the closure system must be ensured by an additional device (cap, crown, seal, binding. etc.) capa­ ble of preventing any loosening of the closure system dur­ ing carriage. (5) When receptacles made of glass, porcelain. stone­ ware or similar materials are prescribed or allowed. they must be secured by cushioning materials in protective packagings. Cushioning materials shall be suited lo the nature of the contents; in particular, they shall be dry and absorbent when the contents are liquid or might exude liquid. 2431a 2432 2. Packing of a single substance or of articles of the same kind • (1) Phosphorus of 1 ° shall be packed: 2433 (a) in leakproof tin-plate receptacles heimetic~lly closed and placed in wooden cases; or (b) in sheet-iron drums closing hermetically. Press-on lids shall not be allowed. The sheet-iron constituting the • body, bottom and lid shall not be less than 1.5 mm thick. A package must not weigh more than 500 kg. If it weighs more than 100 kg, it shall be fitted with rolling hoops or strengthening ribs, and shall be welded; or (c) not more than 250 g per'receptacle, in hermetically closed glass receptacles secured by cushioning materials in leakproof tin-plate receptacles closed by soldering and se­ cured, likewise by cushioning materials, in wooden cases. (2) Receptacles and drums containing phosphorus shall be filled with water. • (1) Substances of 2 ° shall be packed in leak proof tin- 2434 plate receptacles hermetically closed and placed in wooden cases. (2) Substances of 2 ° may also be packed, not more than 2 kg per receptacle, in receptacles made of glass, percelain, stoneware or similar materials, secured by cush­ ioning materials in wooden cases. (1) Substances of 3 ° shall be packed in hermetically 2435 closed metal receptacles not liable to be attacked by the contents, of a capacity not exceeding 450 litres. The receptacles shall either: be seC'url'd in outer packagings of fire-resistant materials; or ha, ea wall thickness of not less than 3 mm, with the.clo­ sure of the fillings and discharge device secured by a ·pro tective cap. • Receptacles shall be subjected to the initial test and to periodical tests every five years with an inert test substance. at a test pressure of not less than 1 MPa (10 bar) (gauge pressure). , . , . The receptacles shall not be filleg,to more than '90 per. cent of their capacity; a space of 5 per cent shall remain. empty for safety when the liquid is at a temperature of ~Q.0 , C. When handed over for carriage, the liquid shall !>~.under . a layer of inert gas, the pressure of which shall not exceed . 50 kPa (0.5 bar) gauge pressure. • The following particulars shall be stamped on the data· plate of the receptacle: • (a) "Organo0metallic compounds. Class 4.2"; (b) the tare of the receptacle, including fillings and ac-. cessories; (c) the test pressure and date (month, year) of the last test undergone; (d) the stamp of the expert who carried out the tests; (e) the capacity of the receptacle and the maximum de­ gree of filling allowed. The exact designation of the contents and the words: "Do not open during carriage: liable to spontaneous igni­ tion" shall he durably mafked in an official language of the country of departure, and also, if that language is not Eng­ lish, French or German, in English, French or German. un­ less any agreements concluded between the countries con­ cerned in the transport operation provide otherwise. A package shall not weigh more than 1000 kg. (2) Substances of 3 ° may also be packed in hermetically closed glass receptacles of not more than 5 li­ tres' capacity, which shall be secured with cushioning ma­ terials in sheet-metal receptacles. The glass receptacles shall not be filled to more than 90 per cent of their capac­ ity. (1) Substances of 4° shall be packed in bags placed in 2436 drums made of impermeable fibreboard or in receptacles made of zinc sheet or aluminium sheet. The sides of metal receptacles shall be lined with fibreboard. The bottoms and lids of fibre drums and metal receptacles shall be lined with wood. 938 E<DHMEPII: THI: KYBEPNHI:EQI: (TEYXOI: ~EYTEPO) (2) Metal receptacles shall be fitted with closures or safety ctevices yielding when the internal pressure reaches a value not greater than 0.3 MPa (3 bar); the presence of these closures or safety devices must not impair the strength of the receptacle nor impair its closure. (3) A package must not weigh more than 75 kg. (1) Substances of 5° (a) shall be tightly compressed and be placed in leakproof metal receptacles. (2) Substances of 5 ° (b) and (c) shall be tightly com­ pressed and be packed either in wooden or fibreboard cases or in paper or textile wrappings firmly secured. (1) Substances of 6 ° (a) shall be packed in hermetically closed receptacles made of metal, glass or a suitable plas­ tics material. The substances shall be dispatched under a protective liquid or gas. The receptacle shall if necessary be fitted with a suitable pressure-compensating device. Glass receptacles shall be secured with cushioning ma­ terials in fibreboard or metal packagings; cushioning mate­ rials shall be incombustible. Receptacles made of a plastics material shall be placed in fibreboard or metal packagings. Packagings containing receptacles made of glass or a plas­ tics material shall be placed in a wooden packing case. A package shall not weigh more than 75 kg. (2) Substances of 6 ° (b) and (c) shall be packed in hermetically closed sheet-metal receptacles or steel drums. In the case of sheet-metal receptacles, a package shall not weigh more than 50 kg. • Substances of 7 ° - 10 ° and 12 ° shall be enclosed in tightly-closing packages. Wooden packagings used for substances of 7 ° and 8 ° shall be provided with a leakproof lining. Special conditions ''· Item No. Description of substance 1 0. - • White or yellow phosphorus 2" Phosphides 30 Zinc alkyls. etc. 6° (a) Metals in pyrophoric form 40' 50 All substances 6° (b) 7° - 12° 4. Marking and danger labels on packages (See Appen­ dix A.9) (1) Packages containing substances of 1 ° to 4 ° and 6 ° shall bear a label conforming to model No. 4.2. Packages containing substances of 3 ° shall in addition bear a label conforming to model No. 4.3. When substances of 4 ° are packed in waterproof fibre drums. conforming to marginal 2436 (1). the packages shall nevertheless bear two labels conforming Lo model No. 4.2 (see marginal 3901). (2) Drums containing phosphorus of 1 ° and having a screw-cap lid shall, unless they are filled with a device maintaining them upright, bear, in addition, high up in two diametrically opposite places, two labels conforming to model No. 11. (3) Packages contai;1ing receptacles filled with vents. and receptacles fitted with vents without outside packaging, containing substances of 6 ° (a), shall bear on two opposite 2437 2438 2439 The substance having been used for purifying lighting gas (spent oxide of iron) of 11 ° shall be packed in tightly closing sheet-metal receptacles. Empty sodium nitrate bags of 13 ° shall be made up into tightly packed bundles securely fastened with string and placed either in a wooden case or in a wrapping consisting either of several thicknesses of stout paper or of water­ proofed fabric. 3. Mixed packing (1) Substances grouped under the same item number may be included in the same package. The inner packagings shall conform to what is prescribed for each substance, and the outer packaging shall be that laid down for the substances of the item number in question. (2) If smaller quantities are not prescribed in the sec­ tion entitled "Packing of a single substance or of articles of the same kind", substances of this Class, in quantities 1101 exceeding 6 kg in the case of solids or 3 litres in the case of liquids for all of the substances listed under the same item number or the same letter, may be enclosed in the same package either with substances of another item number or of another letter of the same class, or with dangerous sub­ stances belonging to other classes (if mixed packing is like­ wise allowed in the case of such substance·s), or with other goods, subject to the following special conditions. The inner packagings must satisfy the general and spe­ cial conditions of packing. In addition, the general provi­ sions of marginals 2001 (7) and 2002 (6) and (7) must be observed. A package must not weigh more than 150 kg. or mon-' than 75 kg if it contains fragile receptacles. Maximum quantity per per Special provisions receptacle package Mixed packing not allowed 3 kg 3 kg Shall not be packed together with weakly nitrated nitrocellulose and red phosphorus of Class 4.1, nor with bifluorides 2443 sides a label conforming to model No. 11. Packages con­ taining fragile receptacles not visible from outside shall bear labels conforming to model No. 12. ff fragile recepta­ cles contain liquids, the packages shall in addition. except in the case of sealed ampoules, bear labels conforming Lo model No. 11; the labels shall be placed on the upper part of the two opposite sides of a case, or in an equivalent man­ ner for other types of packaging. B. Particulars in the transport document The description of the goods in the transport document shall conform to one of the names underlined in marginal 2431. Where the name of the substance is 1101 indicated. for 2 °, 3 °, 9° or 10°, the trade name shall be given. The description of the goods shall be underlined and followed by particulars of the class, the item number (together with the letter, if any), and the initials ""ADR'' (or ""RID"). e.g. 4.2, 5 ° (a), ADR. 2440 2441 2442 2,1-44 2445 2446 2452 E<DHMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) 939 C. Empty packagings (1) Empty packagings, uncleaned, of 14° mid 15°, 2453 shall be closed in the same manner and be leak proof lo the same degree as if they were full. (2) Empty-packagings, uncleaned, of 14° and 15°, shall bear the same danger labels as if they were full. (3) The description in the transport document shall conform to one of the names underlined in 14 ° and 15 °. • e.g. Empty packaging, 4.2, 14 °. ADR. This text shall be underlined. In the case of empty tank-vehicles, empty demountable tanks and empty tank-containers. uncleaned. this description shall be completed by adding the words "Last load", together with the name and item number of the goods last carried, e.g. Last load: white phosphorus. 1 0. CLASS 4.3. SUBSTANCES WHICH GIVE OFF IN­ FLAMMABLE GASES ON CONT ACT WITH WATER 1. List of substances 2454 2469 Among the substances and articles covered by the head- 24 70 ing of Class 4.3, only those listed in marginal 24 71 are lo be accepted for carriage, and then only subject lo the provi sions of this Annex and of Annex B. These substances and articles to be accepted for carriage under certain condi tions are to he considered as substances and articles of ADR. 1 ° (a) Alkali and alkaline-earth metals. e.g. sodium. 24 71 potassium, calcium, as well as alkali metal alloys. alkaline earth metal alloys and alloys of alkali and alkaline-earth metals; (b) alkali metal amalgams and alkaline-earth metal amalgams; (c) alkali metal dispersions. (d) other metals and alloys of metals which give off in­ flammable gases 011 contact with water. such as: dust, powder and fine shavi~gs of aluminium. zinc. mag­ nesium and magnesium alloys containing more than 50 per cent magnesium, all being free from particles likely lo pro­ mote ignition, magnesium granules. coated. of a particle size not less than 149 µm. NOTE: Dusi and powder of metals in pyrophoric form are substances of Class 4.2 (see marginal 2431. 6 ° (a)). For (d) see also marginal 2471a under (b). 2 ° (a) Calsium carbide and aluminium carbide: (b) alkali metal and alkaline-earth metal hydrides (e.g. lithium hydride, calcium hydride), mixed hydrides. and boron hydrides and aluminium hydrides of alkali metals and alkaline-earth metals; (c) alkali silicides: (d) calcium silicide, in powder, grains or lumps. con­ taining more than 5 per cent silicon, manganese calcium silicide (silico- manganese - calcium); (e) organo-metallic compounds which give off innarn­ mable gases on contact with water, such as: aluminium al­ kyls, aluminium alkyl halides, aluminium alkyl hydrides. lithium alkyls, magnesium alkyls, zinc alkyls. gallium al­ kyls, boron alkyls and solutions of these substances which give off inflammable gases on contact with water. NOTES: 1. Organo-metallic compounds and their so­ lutions which are liable lo spontaneous ignition are sub­ stances of Class 4.2 (see marginal 2431. 3 °) 2. Inflammable solutions of substances of 2 ° (e) in con­ centrations which are not liable lo spontaneous ignition and which do not give off inflammable gases on contact with water are substances of Class· 3. The sender shall enter in the transport document the words: "Substances not giving off inflammable vapour when in con lac I with water". (See also Class 4.2, marginal 2431. 3°, NOTE 2). 3 ° Amides of alkali metals and alkaline-earth nwtals. e.g. sodamide (sodium amide). See also marginal 24 7 la under (a). NOTE: Calcium cyanamide is not subject to the provi­ sions of ADR. 4 ° (a) Trichlorosilane (silicochloroform). (b) methyldichlorosilane and ethyldichlorosilane 5 ° Boron trifluoride dimethyletherate 6 ° Empty packagings, empty tank-vehicles, -empty demountable tanks, empty lank-containers and empty small bulk containers, uncleaned, having contained sub­ stances of Class 4.3. Substances carried in conformity with the followin·g pro- 24 71a visions are subject neither 10 the provision for this Class contained in this Annex nor~ those contained in Annex B: (a) Sodamide of 3 ° in quantities not exceeding 200 g per package, packed in receptacles which are so closed as to be leakproof and which cannot be allacked by the con­ tents, if these receptacles are packed with care in a strong, leakproof wooden packaging with a leakproof closure; (b) Dust and powder of aluminium or zinc of 1 ° ( d), e.g. packed together with varnish for use in the manufacture of colours, if packed with care in quantities not exceeding 1 kg. 2. Provisions A. Packages 1. General conditions of packing (1) Packagings shall be so closed and leakproof as lo 2472 prevent the ingress of moisture and any loss of the con tents. (2) The·materials of which the receptacles and their clo­ sures are made must not be liable to allack by the contents or form harmful or dangerous compounds therewith. Ree ceptacles must in all cases be free from moisture. (3) Packagings, including their closures, must-be suffi­ ciently rigid and strong in all their parts lo prevent any loos­ ening during carriage and lo meet the normal requirements of carriage. In particular, in the case of solids immersed in a liquid, receptacles and their closures must, unless the section headed "Packing of a single substance" provides otherwise, be able lo withstand any pressure which. the. presence of air also being taken into account, may arise in­ side the receptacles in normal carriage. For this purpose a free space must be left, account being taken of the differ­ ence between the temperature of the substances at the time of filling and the highest mean temperature which they are likely to reach during carriage. Solid substances shall be firmly secured in their packagings, and inner packagings shall be firmly secured in outer packagings. Unless otherwise specified in the section entitled "•Pack­ ing of a single substance", inner packagings may be ·en­ closed in outer packagings either singly or in groups. (4) Bollles and other glass receptacles must be free from faults liable to impair their strength; in particular. in­ ternal stresses must have been suitably relieved. The thick­ ness of the walls must. in no case be less than 2 mm. The tightness of the closure system must be ensured by an additional device (cap, crown, seal. binding, etc.) capa­ ble of preventing any loosening of the closure system dur­ ing carriage. (5) Cushioning materials shall be suited 0 l0 the nature of the contents. • 2. Packing of a single substance (1) Substances of 1 ° (a) lo (c) shall be packed: 2473 (a) in receptacles made of sheet-iron, lead-lined sheet iron or tin-plate. For substances of 1 ° (b), however. recep tacles made of lead-lined sheet-iron or of tin-plate are not to be accepted. These receptacles, with the exception of iron drums, must be placed in wooden packing cases or in protective iron hampers; or (b) not more than l kg per receptacle, in recep tacles made of glass or stoneware. Not more than 5 of these re­ ceptacles shall he packed in a wooden packing case having • 940 E<DHMEPII: THI: KYBEPNHI:EQI: (TEYXOI: AEYTEPO) a leakproof lining of ordinary sheet-iron. lead-lined sheet­ iron, or tin-plate, assembled by soldering. For glass recep­ tacles containing quantities not exceeding 250 g. the lined wooden case may be replaced by an outer receptacle made of ordinary sheet-iron, lead-lined sheet-iron. or tin-plate. Glass receptacles shall be secured in the outer packagings by incombustible cushioning materials. (2) If a substance of 1 ° (a) is not packed in a welded metal receptacle with a lid hermetically closed by solder­ ing, then: (a) it must be completely covered by mineral oil whose flash-point is above 50°C, or be sufficiently sprinkled lo ensure that the lumps are coated with this oil, or (b) the air in the receptacle must be completely re­ placed by a protective gas (e.g. nitrogen) and the receptacle so closed as to be gas-tight; or (c) the substance must be poured into the receptacle. which must be filled lo the brim and so closed. after cool­ ing, as lo be gas-tight. (3) Iron receptacles must have sides not less than l .25 mm thick. If, with their contents, they weigh more than 75 kg, they must be hard-soldered or welded. If they weigh more than 125 kg, they must in addition be fitted with end and rolling hoops or with rolling flanges. (4) Substances of 1 ° (d) shall be packed in hermetically closed receptacles of.metal, glass or a suitable plastics ma­ terial or in waterproof bags. Glass receptacles and bags shall be secured with cushioning materials in an outer packaging of wood, metal or fibreboard. A package shall not weigh more than 115 kg. (1) Substances of 2° (a) to (d) shall be packed: (a) in receptacles made of sheet-iron, lead-lined sheet­ iron or tin-plate. For substances of 2 ° (b) and (c).a recep­ tacle must not contain more than 10 kg. Those receptacles. with the exception of iron drums, must be placed in wooden packing cases or in protective iron hampers; or (b) not more than l kg per receptacle. in receptacles made of glass or stoneware or of a suitable plastics mate­ rial. Not more than 5 of these receptacles shall be packed in a wooden packing case with a leakproof lining of ordi­ nary sheet-iron, lead-lined sheet-iron or tin-plate. assem­ bled by soldering. For glass receptacles containing quanti­ ties not exceeding 250 g, the lined wooden case may be re­ placed by an outer receptacle made of ordinary sheet-iron. • lead-lined sheet-iron or tin-plate. Glass receptacles shall be secured in the packing cases by incombustible cushion­ ing materials. (2) A package shall not weigh more than 75 kg if it con­ tains substances of 2 ° (b) or (c) and not more than 125 kg if it contains substances of 2 ° (d). (3) Substances of2 ° (e) shall be packed in hermetical!~( closed metal receptacles not liable to be allacked by the contents, of a capacity not exceeding 450 litres. The receptacles shall either: be secured in outer packagings of lire-resistant materials: or have a wall thickness of not lcss than 3 mm. with the clo­ sure of the fillings and discharge device secured by a pro­ tective cap. Receptacles shall be subjected to the initial test and to periodical tests every five years with an inert test substance at a test pressure of not less than 1 MPa (10 bar) (gauge pressure). The receptacles shall not be filled lo more than 90 per cent of their capacity; a space of 5 per cent shall remain empty for safety when the liquid is at a temperature of 50°C. When handed over for carriage, the liquid shall be under a layer of inert gas, the pressure of which shall not exceed 50 kPa (0.5 bar) (gauge presure). The following particulars shall be stamped on the data plate of the receptacle: (a) "Organo-metallic compounds. Class 4.3": 2474 (b) the tare of the receptacle, including fillings and ac­ cessories; (c) the test pressure an<l date (month. year) of the last test undergone; (d) the stamp of the expert who carried out the tests; (e) the capacity of the receptacle and the maximum de­ gree of filling allowed. The exact designation of the contents and the words: "Do not open during carriage. Gives off inflammable gases on contact with water" shall be durably marked in an ofti­ cial language of the country of depart~re, and, also. if that language is not English, French or German, in English. French or German, unless any agreement concluded be­ tween the countries concerned in the transport operation provides otherwise. A package shall not weigh more than 1,000 kg. (4) Substances of 2 ° (e) may also be packed in hermetically closed glass receptacles of not more than 5 l capacity, which shall be secured with cushioning materials in sheet-metal receptacles. The glass receptacles shall not be filled to more than 90 per cent of their capacity. Amides of 3 ° shall be packed. not more than 10 kg per box or drum, in hermetically closed metal boxes or drums. which shall be placed in wooden cases. A package must not weigh more than 75 kg. (1) Trichlorosilane (silicochloroform) of 4° (a), methyldichlorosilane and ethyldichlorosilane of 4 ° (b) shall be packed in receptacles made of corrosion-resistant steel and having a capacity not exceeding 500 litres. The receptacles must be hermetically closed; the closing device must be specially protected by a cap. The receptacles must be constructed as pressure vessels for a working pressure of0.4 MPa (4 bar) and be tested in conformity with the reg­ ulations governing pressure vessels in force in the country of departure. Receptacles with a dpacity not exceeding 250 litres must have a wall thicknes~ of not less than 2.5 mm, and those with a higher capacity 1a wall thickness of not less than 3 mm. / (2) If filling is based on mass, thl degree of filling shall not exceed: 1.14 kg/1 for trichlorosilanc; 0.95 kg/1 for methyldichlorosil1ne; 0.93 kg/1 for ethyldichlorosilane. If carried out by visual check, the/1 degree of filling shall not exceed 85 per cent. Boron trifluoride dimethyl eth~rate of 5 ° shall be packed: (a) in amounts of not more than ] litre per receptacle in hermetically sealed receptacles ma~e of glass, stoneware or a suitable plastics material placed in wood or fibreboard packing cases. Glass or stoneware rbceptacles shall be se­ cured in the packing cases with dppropriate absorbent. inert and non-combustible cushioni11g materials or placed in closely filling packagings made of preformed inert plas­ tics materials. A package shall not w~igh more than 55 kg if the packing case is of fibreboard and not more than 12 5 kg if the packing case is of wood; (b) in hermetically sealed receptacles made of a suita­ ble plastics material and having a ~apacity not exceeding 250 litres, each receptacle placed in a fitted steel protec tive packaging with complete walld; • (c) in hermetically sealed cJrosion-resistant steel drums of a capacity not exceeding 450 litres. 3. Mixed packing '. (1) The substances grouped under the same item num­ ber may be included in the sam1e package. The inner packagings shall conform to what/ is prescribed for each substance, and the outer packaging shall be that laid down for the substances of the item nui'nber in question. (2) If smaller quantities are no\ prescribed in the sec­ tion entitled "Packing of a single substance", substances of this Class; in quantities not excee8ing 6kg in the case of solids or 3 litres in the case of litjuids for all of the sub 2475 2476 2477 2478 E<DHMEPII: THI: KYBEPNHI:EQI: (TEYXOI: .dEYTEPO) 941 stances listed under the same item number or the same let­ ter, may be enclosed in the same package either with sub­ stances of another item number or of another letter of the same class, or with dangerous substances belonging lo other classes (if mixed packing is likewise permilled in the case of such substances), or with other goods. subject lo the following special conditions. Special conditions: Item No. 1 ° (a) 2° (a) 2° (b) Description of substance Alkali and alkaline-earth metals (e.g. sodium. potassium. calcium. barium) in fragile receptalc-es in other receptacles Calcium carbide Alkali metal and alkaline-earth metal hvdrides (e.g. litl;ium hydride. calcium hydride). mixed lwdrides. boroi1 hydrides and aiuminium hydrides in fragile receptacles in other receptacles All substances Boron triOuoride dimethvl elhernle 4. Marking and danger labels on packages (see Appen­ dix A.9): (1) Packages containing substances of Class 4.3 shall bear a label of model No. 4.3 and a label conforming to model No.10. (2) Packages containing substances of 4° and 5° shall bear, in addition, labels conforming lo model Ni:Js. 3 aiif!-3. (3) Packages containing fragile receptaclt's not visible from the outside shall bear a label conformini to n10lkl No.12 . .I~ the fragile receptacles contain liquids. the pack­ ages shall in addition, except in the case of sealed am­ poules, bear labels conforming lo model No. I I: these la­ bels shall be affixed high up on two oposile sides of cases or in an equivalent manner when other paf'kagings are usf'fl. B. Particulars in the transport docume1tl The description of the goods in the transport document shall conform to one of the names underlined in marginal 24 71. If the name of substan·ce is 1101 gi1 en. for substanC"es of 1 °; the trade name shall be entert>d. Tlwdescriptio11 of The inner packagings must satisfy the general and spe­ cial conditions of packing. In addition, the general pro\'i­ sions contained in marginals 2001 (7) and 2002 (6) and (7) must be observed. • • A package must not weigh more than 150 kg. ·or more than 75 kg if it contains fragile receptacles. Maximum quantity per receptacle per package 500 g l kg 500 g 1 kg Mixed packing not allowed 500 g 500g 1 kg I kg 2479 Mixed packing not allowed Mixed packing not allowed Special provisions The limits of 500 g or 1 kg apply lo alkali metals and alkaline­ earth metals of 1 ° (a), and to al­ kali metal and alkaline-earth metal hydrides of 2 ° (b), in re spect of the aggregate mass o these substances. Alkali metals and alkaline-earth metals, and substances of 2 ° (b ). may not be packed together with acids; nor with liquids conlainin~ water. the goods shall be u1tderlined and followed by particulars of class, item number and leller if any. and the initials "ADR" or "RID". e.g. 4.3. 2° (a). ADR. 2482 2497 2480 2481 C. Empty packagings U) Empty packagings, uncleaned. of·6 ° shall be closed in the same manner and be leak proof lo the same degree as if they were full. (2) Empty packagings, uncleaned, of 6 ° shall lwar the same danger labels as if they were full. (3) The description in the transport document shall conform to one of the names underlined i1t 6 ° (e.g .. "Empty packaging, 4.3, 6°. ADR''). This text shall be un­ derlined. In the case of empty lank-vehicles. empty demountable tanks, empty tank-containers and emptv small bulk containers, uncleaned, this description shall be completed by adrling the words "Last load'' together with the name and item number of the goods last loaded. e.g. Last load: trichlorosilane, 4 ° (a). 2498 2499 942 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) CLASS 5.1 OXIDIZING SUBSTANCES 1. List of substances Among the substances and articles covered bv the head­ ing of Class 5.1, those listed in marginal 2501 ;re subject to the provisions of this Annex and of Annex B. These sub­ stances and articles to be accepted for carriage U1 1der cer­ tain conditions are to be considered as substances and arti­ cles of ADR. NOTE: Unless specifically listed in Class la or Class le. mixtures of oxidizing substances with combustible sub­ stances are not to be accepted for carriage if they are capa­ ble of exploding on contact with a flame or are more sensi­ tive to shock and to friction than dinitrobenzene. 1 ° Aqueous solutions of hydrogen peroxide containing more than 60 per cent hydrogen peroxide, s.tabilized. and hydrogen peroxide, stabilized. NOTES: 1. For aqueous solutions of hydrogen perox­ ide containing not more than 60 per cent hydrogen perox­ ide, see marginal 2801, 62°. 2. Aqueous solutions of hydrogen peroxide containing more than 60 per cent hydrogen peroxide, not stabilized. and hydrogen peroxide, not stabilized, are not to be ac­ cepted for carriage. 2 ° Tetranitromethane. free from combustible impuri­ ties. NOTE: Tetranitromethane not free from cornbustible impurities. is not to be accepted for carriage. 3 ° Perchlorie acid in aqueous solutions containing more than 50 per cent but not more than 72.5 per cent perchloric acid (HCl0.J See also marginal 2501a, under (a). NOTE: Perchloric acid in aqueous solutions containing not more than 50 per cent perchloric acid (HC l 0 ) is a substance of Class 8 (see marginal 2801, 4 °). Aque~ 1 us so­ lutions of perchloric acid •containing more than 72.5 per cent perchloric acid are not to be accepted for carriage: the same applies lo mixtures of perchloric acid with anv liquid other than ~iJtrr. • 4 ° (a) Chlorates; inorganic chlorate weed-killers con­ sisting of mixtures of sodium chlorate. potassium chlonlle or calcium chlorate with a hygroscopic chloride (such as magnesium chloride or calcium chloride): NOTE: Ammonium chlorate is not lo be accepted for carriage. (b) perchlorates (with the exception of a1111noniu111 perchlorate, see 5 ° ): (c) sodium and potassium chlorites: (d) mixtures of chlorates, perchlorates and chloril«:>s of (a), (b) and (c) with one another. For (a), (b). (c) and (d), see also marginal 250 la. under (b). 5 ° Ammonium perchlorate. See also marginal 250 la. under (b). 6° (a) Ammo1iium nitrat«:> containing nol more than 0.2 per cent combustible substances (including any organic substance calculated as carbon) lo the exclusion of nnv other added substance. • NOTES: 1. Ammonium nitrate containing 111orc than 0.2 per cent combustible substances (including nm· or­ ganic substance calculated as carbon) is not Lo be acc~pted for carriage unless it is a constituent of an explosi1·e of Class la (see marginal 2101, 12° or 14°). 2. Aqueous solutions of ammonium nitrate. in a conccn­ lration not exceeding 80 per cent. are 1101 subject to the re­ quirements of ADR. (b) Ammonium nitrate fertilizers. type A 1: uniform non-segregating mixtures containing 90 per cent or more ammonium nitrate with added matter 1d1ich is inorganic and chemically inert towards ammonium nitrate. and not more than 0.2 per cent of combustibl«:> malerinl (incl11dinf! organic material calcula\ed as carbon), or mixtures con­ taining less than 90 per cent but more than 70 per cent am­ monium nitrate and not more than 0.4 per cent of combus­ tible material. 2500 (c) Ammonium nitrate fertilizers, type A2: uniform non-segregating mixtures of ammonium nitrate with cal­ cium carbonate and/or dolomite, containing more than 80 per cent but less than 90 per cent ammonium nitrate and not more than 0.4 per cent total combustible material. (d) Ammonium nitrate fertilizers, type A3: uniform non-segregating mixtures of ammonium nitrate/ammonium sulphate containing more than 45 per cent but hot more than 70 per cent ammonium nitrate and not more than 0.4 per cent of total combustible material. (e) Ammonium nitrate fertilizers. type A4: uniform 2501 non-segregating mixtures (compound fertilizers) of nitrogen/phosphate or nitrogen/potash types. or complete fertilizers of nitrogen/phosphate/potash type, containing more than 70 per cent but less than 90 per cent ammonium nitrate and not more than 0.4 per cent total combustible material. NOTES: 1. In determining the ammonium nitrate con­ tent, all nitrate ions for which a molecular-equivalent of am­ monium ions is present in the mixture shall be calculated as ammonium nitrate. 2. Fertilizers having ai1 ammonium nitrate content or a content in combustible substances exceeding the values shown i~ 6° (b) to 6 (e) respectively are not to be accepted for carnage except under the conditions applicable to Class la (see marginal 2101, 12° (a)). See also NOTE 4. 3. Fertilizers having an ammonium nitrate content below the limit values indicated in 6° (c) to 6° (e) respectivelv are not subject Lo the requirements of ADR. • 4. Fertilizers having an ammonium nitrate content of not more than 45 per cent and whose content of combustible substances is more than 0.4 per cent, are 1101 subject to the provisions of ADR provided that the molecular excess of nitrate over ammonium ions (calculated as potassium ni­ trate) is not more than 10 per cent by mass. For (a) to (e), see also marginal 2501a under (b). 7° (a) Sodium nitrate; (b) mixtures of ammonium nitrate with nitrates of so dium, potassium, calcium or magnesium; (c) barium nitrate, lead nitrate. For (a), (b) and (c), see also marginal 2501a. under (b). NOTES: 1. If they do not contain more than 10 per cent ammonium nitrate, mixtures of ammonium nitrate with calcium nitrate or with magnesium nitrate or with both are not subject to the provisions of ADR. 2. Empty textile bags which have contained sodium ni- • trate and have not been entirely freed from the nitrate im­ pregnating them are articles of Class 4.2 (see marcrinal 2431, 13°). " (b). 8 ° Inorgan.ic nitrites. See also marginal 2501 a. under NOTE: Ammonium nitrite and mixtures of an inor(Yanic nitri!e with an ammonium salt are not to be accepted for carnage. . 9° (a) Peroxides of alkali metals and mixtures con­ taining peroxides of alkali metals which are not more dan­ gerous than sodium peroxide; (b) peroxides of alkaline-earth metals. e.g. barium di­ oxide; (c) permanganales of sodium, potassium. calciurn and barium. For (a), (b) and (c).see also marginal 2.30 la. undn (Ii). NOTES: 1. Ammonium permanganate. and mixtures of a permanganate with an ammoniu111 salt, are not to b«:> ac­ cepted for carriage. 2. Solutions of chromic acid are substances or Class 8 (see marginal 2801, 11° (b)). E<DHMEPII: THI: KYBEPNHI:EQI: (TEYXOI: AEYTEPO) 10° Chromium trioxide (chromic anhydride: also called • chromic acid). See also marginal 2501a, under (b). 11 ° Empty packagini:;s, empty tank-vehicles. empty demountable tanks, empty tank-containers and empty small bulk containers, uncleaned, having rn11tai11ed sub­ stances of Class 5.1. NOTE: Empty packagings and empty tanks "hich have contained a chlorate, a perchlorate, a chlorile of 4 ° and 5 °, an inorganic nitrite of 8 ° or substances ol' 9° and I O O , with residues from their previous contents adhering lo tlw outside, are not to be accepted for carriage. Substances handed over for carriage in conformity with thP following provisions are subject neither lo the prol'isions for this Class contained in this Annex nor lo !host' con­ tained in Annex B: (a) substances of 3 °, in quantities not exceeding 200 g per receptacle, on condition that they are packed in rPcep­ tacles so closed as to be leakproof and not capable of being attacked by the contents, and that receptacles are packed. not more ihan I O per case. in a wooden case with inert ab­ sorbent cushioning materials; (b) substances of 4 °-] 0°, in quantities 1101 exccPding 10 kg, packed not more than 2 kg per receptacle in recep­ tacles so closed as to be leak proof and 1101 capable of being attacked by the contents, these receptacles being enclosed in strong, leakproof packagings made of slwcl-melal and having leakproof closures. 2. Provisions A. Packages 1. General conditions of pa<:king (1) Receptacles shall be so closed and arranged as lo 2502 prevent any loss of the contents. (2) The materials of which the packagings and their clo­ sures are made must not be liable lo allack bv the contents. or cause the contents to decompose. of foim harmful or dangerous compounds therewith. (3) Packagings, including their c.losures. must be sulli­ ciently rigid and strong in all their parts to prevent am loos­ ening during carriage and to meet the normal requirements of carriage. In particular, where substances are i11 the liq­ uid state, receptacles and their closures must. unless the section headed "Packing of a single substance" provides otherwise, be .able to withstand any pressure which. the presence of air also being taken into account. mav arise in­ side the receptacles in normal carriage. For this purpose a free space must be left, account being taken of the differ­ ence between the temperature of the substances at the time of filling and the highest mean temperature which they are likely lo reach during carriage. Unless othernise specifiPd in the section e1ititled "Packing of a single substancP"'. inner packagings may be enclosed in outer packagings ei­ ther singly or in groups. (4) Bottles and other glass receptacles must be free from faults liable to impair their strength: in particular. in­ ternal stresses must have been suitablv relieved. The walls must be not less than 3 mm thick in th~ case or receptac-les weighing, with their contents, more than 35 kg and 1101 less than 2 mm in the case of other receptacles. The tightness of the closure system musl be ensured bv an additional'device (cap. crown. seal. binding. elc.) cap,;­ ble of preventing any loosening of the closure svslem dur ing carriage. • • (5) When receptacles made of glass. porcelain. stone­ ware or similar materials are prescribed or allowed. the,· must be securer! by cushioning materials in protectiv~ packagings. Cushioning materials must be incombustible (glass wool, absorbent earth, infusorial earth, etc.) and in­ capable of forming dangerous compounds with the con­ tents of the receptacles. If the contents are liquid. the cush­ ioning materials shall also be absorbent and proportionate in quantity to the volume of the liquid: this interior absorb­ ent layer must not, however. be less than 4 cm thick al am point. • • Packing of a single substance (1) Aqueous solutions of hydrogen peroxide. and hv­ drogen peroxide of 1 °, shall be packed in drums or other receptacles marle of aluminium of at least 99.5 per cei1l purity or of special steel not liable to cause the hydrogen peroxide to decompose. These receptacles shall be filled with means of handling; they must be able lo remain up­ right in a stable fashion and must: (a) be fitter! in their upper part with a closing de\'ic:e en­ suring equality of the internal and the atmospheric pres­ sure; this closing device must in all circumstances prevent any escape of the liquid and any entry of foreign matter into the receptacle and must be protected by a vented cap: or (b) be able to withstand an internal pressi ire of 0.25 MPa (2.5 bar) and be fitted in the upper part with a sal'etv device yielding when the excess of internal pressure is 0.1 MPa (1 bar) at most. (2) Receptacles shall not be filled beyond 90 per cent of their capacity. (3) A package must not weigh more than 90 kg. Tetranitromethane (2 °) shall be contained in bot1les made of glass, porcelain, stoneware of similar materials or of a suitable plastics material. with incombustible stoppers. placed inside a wooden case with complete sides: fragile re­ ceptacles shall be secured therein by absorbent - earth cushioning. Receptacles shall nol be filled bevond 93 per cent of their capacity. Perchloric acid in aqueous solutions (3 °) shall be con­ tained in glass receptacles, which shall be filled to 1101 more than 93 per cent of their capacity. The receptacles shall be secured by absorbent and incombustible cushioning mate­ rials in incombustible protective packagings impermPable to liquids and capable of retaining the contents of the re­ ceptacles. The closure of the receptacles shall be protected by caps if the protective packagings are 1101 completelv closed. Glass bottles closed by glass stoppers may also·be se­ cured by absorbent and incombustible ;cushioning maleri- • als in wooden cases with complete sides. Packages containing fragile receptacles and carried·oth­ erwise than as a full load must not weigh more than -75 kg and shall be fitted with means of handling. - • (1) Substances of 4 ° and 5 ° and solutions of sub­ stances of 4 ° shall be packed in receptacles made of glass. of a suitable plastics material, or of metal: solid substances of 4 ° (b) may also be enclosed in hardwood casks. (2) Fragile receptacles and receptacles made of a plas­ tics material must be secured by cushioning materials in wooden or metal protective packagings. They may also be secured separately by incombustible cushioning materials in non-fragile intermediate receptacles which must in turn be firmly placed or secured by cushioning materials in pro­ tective packagings. Each receptacle must contain not more than 5 kg of substance. In the case of receptacles whose contents are liquid, the cushioning materials must be ab­ sorbent. (3) In the case of receptacles made of a plastics mate­ rial and containing solutions of substances of 4 °. the pro­ tective packagings may be dispensed with if the walls are not less than 4 mm thick at every point, the walls are strengthened by strong reinforcing rims, the ends are strengthened, the upper part is provided with two strong handholds, and the opening is filled with a screw-threaded closure. (4) Receptacles for liquids shall not be filled beyond 95 per cent of their capacity. (5) Packages containing fragile receptacles or recepta­ cles made of a plastics material [see (2) and (3)]. if they contain liquids, and packages containing fragile recepta­ cles or receptacles made of a plastics material [see (2)]. if they contain only solid substances and are carried other­ wise than as a full load, must not weigh more than 75 kg. Packages carried otherwise than as a full load shall be fit­ ted with means of handling. 943 2503 2504 2505 2506 ECJ>HMEPiI THI KYBEPNHIEOI (TEYXOI .6EYTEPO) · (6) Packages which can be rolled must not weigh more than 400 kg; if they weigh more than 2 7 5 kg, they shall be fitted with rolling hoops. (7) Receptacles containing solid chlorates other than those referred to under (8) must not contain any combusti­ ble material other than a small pad of waxed paper. (8) If the chlorate is in the form of tablets, with or with­ out a suitable binder, and is packed in boules containing not more than 200 g, a suffici~nt quantity of cotton-wool may be used to prevent excessive movement of the tablets in the bottle. The bottles shall be packed in fibreboard boxes placed in an intermediate packaging separate from the outer packaging. An intermediate packaging may not contain more than 1 kg or a package more than 6 kg of chlorate. (1) Substances of 6°, 7° and 8° shall be packed. (a) in drums or cases; or (b) in strong bags made of closely woven fabric or of stout paper of at least five plies or, in quantities not exceed­ ing 50 kg, in bags made of a suitable plastics material suffi­ ciently thick and strong to prevent any loss of the contents. If the substance is more hygroscopic than sodium ni­ trate, bags made of closely woven fabric or of stout paper of five plies must be lined with a suitable plastics material or be rendered impermeable by suitable means. Packages which can be rolled must not weigh more than 400 kg; if they weigh more than 275 kg, they shall be fitted with rolling hoops.· (1) Substances of 9° (a) shall be packed: (a) in steer drums:· or (b), in receptacles made of sheet-metal, lead-lined sheet-iron, or tin-plate, secured in wooden packing cases having a metal lining rendered leakproof, e.g. by soldering. Whe.n carried as a fuU load, substances of 9° (a) may be packed in tin-plate receptacles placed solely in protective iron hampers. (2) Receptacles containi~tL~ubstances of 9° (a) must be so closed and leakproof as to prevent moisture from en tering. • (3) SubstaQCfS of 9° (b) and (c) shall be packed: (a) in incombtisiible receptacles fitted with an incom­ bustible hermetic closure. If the incombustible receptacles are fragile, each shall be secured separately by cushioning materials in a wooden case lined with stout paper: or Special conditions: Item No. 4 ° (a) Description of substance Hydrogen peroxide anrl aqueous solutions of hydrogen peroxide containing more than 60% hydrogen peroxide Tetranitrometha ne Perchloric acid Solutions of substances of 4 ° Chlorates in fragile receptacles in other receptacles 2507 2508 (b) in hardwood casks with closely fitting staves. lined with stout paper. (4) Packages containing fragile receptacles and carried otherwise than as a full load must not weigh more than 7 5 kg and shall be fitted with 1-neans of handling. Packages capable of rolling must not weigh more than 400 kg; they mus;t be fitted-with rolling hoops if they weigh more than 275 kg. (1) Chromium trioxide (10°) shall be packed: (a) in receptacles made of glass, porcelain. stoneware or similar materials, tightly stoppered, and secured in a wooden case by inert and absorbent cushioning materials; or (b) in metal drums. (2) Packages containing fragile receptacles carried oth­ erwise than as a full load must not weigh more than 7 5 kg and shall be fitted with means of handling. Packages capable of rolling must not weigh more than 400 kg; they must be fitted with rolling hoops if they weigh more than· 275 kg. 3. Mixed packing (1) Substances groups under the same letter may be in­ cluded in the same package. The inner packagings shall conform to what is prescribed for each substance. and the outer packaging shall be that laid down for the substances of the item number in question. (2) If smaller quantities are not prescribed in the sec­ tion entitled "Packing of a single substance", substances of this Class, in quantities not exceeding 6 kg in the case of solids or 3 litres in the case of liquids for all of the sub­ stances listed under the same item number or the same let­ ter, may be enclosed in the same package either with sub­ stances of another item number or of another leller of the same class, or with dangerous substances beionging to other classes (if mixed .packing, is likewise allowed in the case of :;uch substances), or with other goods, subject to tlie following special co11ditions. The inner packagings must satisfy the general and spe­ cial conditions of packing. In addition, the general provi­ sions of marginals 2001 (7) and 2002 (6) and (7) must be observed. A package must not weigh more than 150 kg. or more than 75 kg if it contains fragile receptacles. Maximum quantity per receptacle per package Special provisions Mixed packing not allowed l kg 5 kg 2.75 kg 5 kg Must not be packed together with weakly - nitrated nitrocellulose, red phosphorus, bifluorides, liq­ uid halogenated irritants, hydro­ chloric acid, sulphuric acid. chlorosulphonic acid, acetic acid, benzoic acid, salicylic acid. formic acid, nitric acid. free sulphonic acids. mixed nitrating 2509 2510 ll>EK 104 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI 6EYTEPO) Item No. 4° (b) and 5 ° 4° (c) an (d) 60,70,80 Description of substance Perchlorates xrAII substances 9° (a) and (b) Peroxide In fragile receptacles In other receptacles 9° (c) Permanganates rno Chromic anhydri<lP (chromic aci<l) B. Particul!lrs in the transport document The description of the goods in the transport document must conform to one of the names underlined in marginal 2501; it must be underlined and followed by particulars of the class, the itr.m number (together with the letter. iLany). and the initials "ADR" or '"RID'' [e.g. 5.1. 4 ° (a). ADR J. C. Empty packagings (1) Empty packagings, unclea11ed, of l l O shall be closed in the. same manner and be leakprool lo the same degree as if they were full. (2) Empty packagings, uncleaned. of 11 ° shall bear the same danger labels as if they were full. Maximum quantity per receptacle per package Special provisions 5 kg 5kg acids, sulphur, hydrazine. Must be separated from uncombined carbon (in any form), hypopho­ sphites, ammonia and its com­ pounds, triethanolamine, aniline, xylidine, toluidine, or inflamma­ ble liquids having a flashpoint below 21 °C. Must not be packed together with weakly nitrated nitrocellulose, red phosphorus, bifluorides, liq­ uid halogenated irritants, hydro­ chloric acid, chlorosulphonic acid, nitric acid, mixed nitrating acids, aniline, pyridine, xylidine, toluidine, sulphur, hydrazine Must not be packed together with • weakly nitrated nitrocellulose or red p~osphorus. 500 g 5 kg 2.5 kg 5 kg Same substances prohibited as in the case of perchlorates, and also: aluminium dust, powder or granules, acetic acid; aqueous liquids, inflammable liquids of Classes 3 and 6.1 ;· substances of Class 4.1; 5 kg 5 kg metallit:'·: peroxides must not be packed in the same ·package with solutions of hydrogen peroxide. The limitation of, 2.5,kg applies to peroxides of-9 9 ·(a) and (b) for all of these substances. The use . of sawdust or other organic filling materials is prohibited. Same substances prohibited as in the case of chlorates, and also: solutions of hydrogen peroxide, glycerine, glycols. Must br. sepa­ rated from the same substances as indicated in the case of chlo­ rates. 4.5 kg 4.5 kg The use of sawdust or other or­ ganic filling materials is prohib­ ited. 2513 2514 2520 2521 (3) The description in the transport document shall conform to one of the names underlined in 11 °. e.g. Empty packaging, 5.1. 11 °, ADR. This text shall be underlined. In the case of empty tank-vehicles, empty demountable tanks, empty tank-containers and empty small bulk con­ tainers, uncleaned, this description shall be completed by adding the words "Last load'' together with the name and item number of the goods last loaded, e.g. Last load: hy­ drogen peroxide, 1 °. (4) Empty textile bags, uncleaned. which hav<' con­ tained sodium nitrate of 7 ° (a) are subject to the provisions • of Class 4.2 (see marginal 2441). 945 2522 2549 946 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) CLASS 5.2 ORGANIC PEROXIDES 1. List of substances Among the subs.lances and articles covered by the head­ ing of Class 5.2, only those listed in marginal 2551 are Lo be accepted for carriage, and then only subject to the provi­ sions of this Annex and of Annex B. These substances and articles to be accepted for carriage under certain condi­ tions are to be considered as substances and articles of ADR. NOTE: Organic peroxides which may explode on con­ tact with a flame or which are more sensitive lo shock and to friction than dinitrobenzene are not to be accepted for carriage unless they are specifically listed in Class la (see marginal 2101, 10° and Appendix A.l, marginal 3112: also marginal 2551, Group E, below). Group A 1 ° Ditertiary butyl peroxide. 2° Tertiary butyl hydroperoxide with not less than 20 per cent ditertiary butyl peroxide and not less than 20 per cent phlegmatizer. NOTE: Tertiary butyl hydroperoxide with 1101 less than 20 per cent ditertiary butyl peroxide but without phlegmatizer is listed under 31 °. 3 ° Tertiary butyl peracetate with not less than 30 per cent phlegmatizer. 4 ° Tertiary butyl perbenzoate. 5 ° Tertiary butyl permaleate with not less than 50 per cent phlegmatizer. 6° Ditertiary butyl diperphthalate with not less than 50 per cent phlegmatizer. 7° 2,2-bis (tertiary butyl peroxy) butane with not less than 50 per cent phlegmatizer. 8 ° Benzoyl peroxide: (a) with not less than l O per cent water; (b) with -not less than 30 per «;:ent phlegmatizer. NOTES: l .Benzoyl peroxide in the dry state or with less than 10 per cent water or less than 30 per cent phlegmatizer is a substance of Class la [see marginal 2101, 10° (a)). 2. Benzoyl peroxide containing not less than 70 per cent dry and inert solids is not subject to the provisions of ADK. 9° Cyclohexanone peroxides (l-hydroxy-1 • -hydrope­ roxydicyclohexyl peroxide and bis (1-hydroxycyclohexyl) peroxide and mixtures of these two compounds]: (a) with not less than 5 per cent water: (b) with not less than 30 per cent phlegmatizer. NOTES: 1. Cyclohexanone peroxides and their mixtures in the dry state or with less than 5 per cent water or less than 30 per cent phlegmatizer are substances of Class la [ see marginal 2101, JO O (b )]. 2. Cyclohexanone peroxides and their mixtures contain­ ing not less than 70 per cent dry and inert solids ar~ not subject to the provisions of ADR. 10° a,a-Dimethylbenzyl hydroperoxide (curnyl l11dro­ peroxide) with a peroxide content not exceeding 95 per cent. 11 ° Dilauroyl peroxide. 12° 1,2,3,4-Tetrahydro-l-naphthyl hydroperoxide. 13 ° 2,4-Dichlorobenzoyl peroxide: (a) with not less thf!n 10 per cent water: (b) with not less than 30 per cent phlegmatizer. 14 ° p-Menthanyl hydroperoxide with a peroxide con­ tent not exceeding 95 per cent (remainder: alcohols and ketones). 15 ° 2,6,6-Trimethyl noq.iinanyl hydroperoxide (pi­ nanyl hydroperoxide; pinane hydroperoxide) with a perox­ ide content not exceeding 95 per cent (remainder: alcohols and ketones). 2550 2551 16° Di (a,a-dimethylbenzyl) peroxide (dicumyl perox­ ide) with a peroxide content not exceeding 95 per cent. NOTE: Dicumyl peroxide containing 60 per cent or more dry and inert solids is not subject to the provisions of ADR. 17° Parachlorobenzoyl peroxide; (a) with not less than 10 per cent water; (b) with not less than 30 per cent phlegmatizer. NOTE: 1. Parachlorobenzoyl peroxide in the dry state or with less than 10 per cent water or less than 30 per cent phlegmatizer is a substance of Class la [see marginal 2101, 10° (c)]. 2. Parachlorobenzoyl peroxide containing 70 per ceiit or more dry and inert solids is not subject to the provisions of ADR. 18 ° Di-isopropylbenzene hydroperoxide (isopropy­ lcumyl hydroperoxide) with 45 per cent of a mixture of al­ cohol and ketone. 19° 4-Methylpentan-2-one peroxide (isobutylmethyl­ ketone peroxide) with not less than 40 per cent phlegmatizer. 20° Tertiary-butyl (cumyl) peroxide with ncit more than 95 per cent peroxide. 21 ° Diat:etyl peroxide with not less than 75 per cent phlegmatizer. 22 ° Acetyl benzoyl peroxide with not less than 60 per cent phlegmatizer. NOTE For 1 ° to 22 °: substances which are inert to or­ ganic peroxides and have a flash-point not lower than 100°C and a boiling-point not lower than 150°C are deemed to be phlegmatizing substances: substances of Group A may also be diluted with solvents which are inert to these substances. Group B 30° Butanone peroxide (ethyl methyl keto11e perox­ ide): (a) with not less than 50 per cent phlegmatizer: (b) in solution::; containing not more than 12 per ce111 of this peroxide in solvents which are inert to it. 31 ° Tertiary butyl hydroperoxide: (a) with not less.than 20 per cent ditertiary butyl perox­ ide, without phlegmatizer; (b) in solutions co"ntaining not more than 12 per cent of this hydroperoxide in solvents which are inert to it. NOTE: For 30° and 31 ° substances which are inert to organic peroxides and have a flash-point not lower than l00°C and a boiling-point not lower than l50°C are deemed to be phlegmatizing substances. Group C 35 ° Peracetic acid containing not more than 40 per cent peracetic acid and not less than 45 per cent acetic acid and not less than l O per cent water. NOTE: re Groups A, B and C. Mixtures of products listed in Groups A, Band Care to be accepted for carriage subject to the conditions laid down for Group C if they co11 tain peracetic acid, a11d in other cases subject to the condi­ tions laid down for Group B. Group D 40° Samples of phlegmatized organic peroxides not listed in Groups A, B or C, or of their solutions. arc to be accepted in quantities not exceeding 1 kg per package on condition that their stability in storage is at least equal to that of the substances listed in Groups A. and l:l. Group E NOTE: Group E comprises organic peroxides which de­ compose easily at normal temperatures and must therefore be carried only under conditions of adequate refrigeration. Although of an explosive nature as defined bv tlw Note on E<J>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) Class 5.2, a few organic peroxides are included in Group E because they can be safely carried in a refrigerated state and in order to avoid any confusion regarding their han­ dling. 45 ° Dioctanoyl peroxide (dicaprylyl peroxide) of t<='chni cal purity. 46 ° Acetyl cyclohexane su lphonyl peroxide: (a) containing not less than 30 per cent water: (b) in solution with not less than 80 per cent sol1ent: (c) in solution with not less than 70 per cent phlegmatizer. 4 7 ° Diisopropyl peroxyrlicarbonate: (a) of technical purity; (b) in solution with not less than 50 pn C<"nt phlegmatizer or solvent. 48 ° Dipropionyl peroxide in solution with 1101 less than 7 5 per cent solvent. 49° Tertiary butyl p<"rpivalate: . (a) of technical purity: (b) in solution with not less than 25 per C<"11t phlegmatizer or solvent. 50° Bis-(3,5,5-trimethylhexanoyl) peroxide in solution with not less than 20 per cent phlegmatizer. 51 ° Dipelargonyl peroxide of technical purity. 52 ° Tertiary butyl per-2-ethylhexanoate of technical purity. 53 ° Di-2-ethylhexyl-peroxydicarbonate in solution 1\ ith not less than 55 per cent phlegmatizer or solvent. 54° Didecanoyl peroxide of technical purity. 55° Tertiary butyl perisobutyrate in solution with not less than 25 per cent solvent. NOTES: 1. Substances which are inert to organic perox­ ides and have a flash-point not lower than l00°C and a boiling point not lower than l50°C are deem<='d to be phlegmatizing substances. 2. The solvents referred to are substances which are inert to organic peroxides and which also satisfy one of the following conditions: (a) they are not inflammable and have a boiling point of not less than 85 ° C: or (b) they are not inflammable and have a boiling point of less than 85°C hut not less than 60°C. in which case hermetically-closed containers must be used: or (c) they have a flash-point of not less than 21 °C and a boiling point of not less than 85 °C: or • (d) they have a flash-point of less than 21 °C but not less than 5 ° C and a boiling point of not less than 60 ° C. 111 which case hermetically closed containers must be userl. Group F 99° Empty packagings, empty tank-vehicles. emptv demountable tanks and empty lank-containers. unclcaned. having contained substances of Class 5.2. 2. Provisions A. Packages 1. General conditions of packinp; (1) The materials of which the packagings and their clo­ sures arc made must not be liable to allack by the contents or form harmful or dangerous compounds therewith. (2) Packagings, including their closures. must be suffi­ ciently rigid anrl strong in all their parts to prevent any loos­ ening during carriage and to meet the normal requirements of carriage. Inner packagings ~hall be firmly secured in outer packagings. Unless otherwise specified in the section entitled "Packing of a single substance". inner packagings may be enclosed in outer packagings, either singly or in ,groups. (3) Cushioning materials must not be readily inflamma- • ble; in addition, they shall be suited to the nature of the contents and must not cause the peroxides to decompose. 2552 2. Packing of a single substance , a. Packing of substances of Group A Receptacles shall be so closed and leakproof as to pre­ vent any loss of the contents. (1) Substances of 1 ° to 7°, 8 ° (b). 9° (b). 10° to 12 °. 13° (b), 14° to 16°, 17° (b)and 18° 1022° and their so­ lutions must be packed: (a) in hot-dipped tinned receptacles or in receptacles made of aluminium not less than 99.5 per cent pure: or (b) in receptacles, made of suitable plastics material. which shall be placed in protective packagings: or (c) not more than 2 litres per boule, in tightly closing glass bollles which shall be secured by cushioning materi­ als in a protective packaging so as to be protected against breakage. (2) Substances of 1 ° to 3 °. 5 ° to 7 °. 8 ° (b). 9° (b). l0° to 12°, 13° (b). 16°, 18° and 20° may also be packed in hot-dipped galvanized receptacles. (3) Substances of 8° (a). 9° (a), 13° (a) and 17° (a) shall be contained, not more than 5 kg per packaging. in water-tight packagings placed in a wooden case. (4) Pasty and solid peroxides may also be packed in bags, made of a suitable plastics material, placerl in suita­ ble protective packagings. The thickness of the packing material shall be sufficient to prevent any loss of the con­ tents from the hags in normal carriage. Solid peroxides may be packed, not more than 1 kg per receptacle. in paraffin-waxed fibreboard receptacles placed in a wooden case; however, in the case of cyclohexanone peroxides of 9° (a) the contents of a receptacle shall be limited to 500 g. (5) Substances of 10 ° and of 14 ° to 18 ° may also be packed in receptacles made of sheet-steel. (6) With the exception of bags made of a suitable plas­ tics material, receptacles containing liquid or pasty org~nic pr¥0xides must not be filled beyond 93 per cent of their ca­ pacity. (7) A package must not weigh:rr1o'i~ than 50 kg. Pack~, ages weighing more than 15 kg shall be filled with means of handling. , b. Packing of substances of Group B (1) Receptacles filled with substances of 30° ·(a) anrl 31 ° (a) shall be fitted with a venting device allowing corn- • pensation between the internal pressure and the atmos­ pheric pressure and in all circumstances - even in the e1·ent of expansion of the liquid through heating~ preventing the liquid from splashing out and impurities from entering the receptacle. For substances of 30° (b) and 31 ° (b).only re­ ceptacles so closed and leakproof as to prevent any loss of the contents shall be accepted. (2) Packages shall be fitted with a base which keeps them securely upright without danger of falling. (1) Substances of 30 ° (a) and 31 ° (a) shall be packed: (a) in hot-dipped tinned or hot-dipped galvanized recep­ tacles or in receptacles made of aluminium not less than 99.5 per cent pure; or (b) in receptacles, made of a suitable plastics material. placed in protective packagings. The strength of these re­ ceptacles shall be sufficient to prevent any loss of the con­ tents in normal carriage; or (c) not more than 2 litres per bollle, in glass bollles. which shall be secured by cushioning materials in protec­ tive packagings so as to be protected against breakage. (2) Receptacles containing liquid or pasty organic per­ oxides must not be filled beyond 90 per cent of their capac­ ity. (3) A package must not weigh more than 40 kg. Pack­ ages weighing more than 15 kg shall be filled with means of handling. (4) Substances of 30° (b) and 31 ° (b) may be forwarded only in quantities not exceeding 5 kg in receptacles as specified in (l) but not equipped with a venting device (in glass bottles, only in quantities not exceeding 1.5 litre). 947 2553 2554 2555 2556 948 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) The receptacles must not be filled beyond 75 per cent of their capacity. c. Packing of substances of Group C (1) Substances.of 35 ° and mixtures containing peracetic acid shall be packed, not more than 25 kg per receptacle, in thick-walled glass receptacles, or in receptacles made of a suitable plastics material, fitted with a special closure made of a suitable plastics material, capable of being sealed, in communication with the atmosphere through an opening situated above the level of the liquid, and in all cir­ cumstances - even in the event of expansion of the liquid through heating - preventing the liquid from splashing out and impurities from entering the receptacle. (2) Glass receptacles shall be firmly secured, by clean mica powder or glass wool used as cushioning materials, in protective packagings made of sheet steel or of aluminium, capable of being closed, and fitted with means of handling and with a base which keeps them securely upright without risk of falling; the receptacles shall be secured even if the walls of the protective packagings are not complete. Re­ ceptacles made of a suitable plastics material must be placed in close-fitting protective packagings made of sheet­ steel and capable of being closed. d. Packing of substances of Group D Substances of Group D shall be packed, in quantities not exceeding 1 kg per package, in hot-dipped tinned recepta­ cles, or in receptacles made of aluminium not less tha1i 99.5 per cent pure, or in bottles made of a suitable plastics material injection moulded or blown and having a sufficient wall thickness, or in glass bottles placed in protective packagings made of sheet steel, aluminium or wood. The glass bottles shall be firmly secured in the protective packagings by clean mica powder or glass wool used as cushioning materials. Solid compounds may also be packed in bags, made of a suitable plastics material of suf­ ficient thickness, likewise placed in protective packagings made of sheel0steel, aluminium-,-or wood. If the peroxides give off gases al a temperature lower than 40°C, the recep­ tacles must satisfy the conditions of marginal 2555. e. Packing of subst:1-11!:es of Group E (1) Packages containing substances of Group E shall be fitted with a venting device allowing compensation between the internal pressure and the atmospheric pressure and in all circumstances - even in the event of expansion of the liquid .through.heating - preventing the liquid from splash­ ing out and impurities from entering the receptacle. (2) Receptacles containing liquid organic peroxides must not be filled beyond 95 per cent of their capacity. ( 1) Substances of 45 °, 51 ° and 54 ° shall pe packed. not more than 50 kg per receptacle or bag, in receptacles or bags, made of a suitable plastics material, which shall be placed in suitable protective packagings in quantities not exceeding 50 kg per packaging. (2) Substances of 46° (a) shall be packed, not more than 5 kg per bag, in bags made of a suitable plastics material. which shall be placed, not more than 20 kg per packaging and either singly or in. groups, in suitable protective packagings. (3) Substances of 4 7 ° (a)shall be packed: (a) not more .than 1 kg per receptacle, in receptacles made of a suitable plastics material; (b) not more than 3 kg per bowl, in bowls made of alu­ minium not less than 99.5 per cent pure, with plastics lids. The protective packaging must not contain more than 1 0 kg of the substance. (4) Substances of 46° (b) and (c), 4 7 ° (b), 48°. 49° (b). 50°, 52 °, 53 ° and 55 ° shall be packed, not more than 25 kg per receptacle, in rec.eptacles made of a suitable plastics material, which shall be placed, not more than 50 kg· per packaging (but not more than 25 kg per packaging in the case of substances of 52 °), in protective packagings. (5) Substances of 49° (a) shali be packed. not more than 2557 2558 2559 2560 10 kg per receptacle, in receptacles made of a suitable plastics material, which shall be placed, not more than 40 kg per packaging, in protective packagings. (6) Packages weighing more than 35 kg which contain substances of Group E shall be fitted with means of han­ dling. f. Packing of substances in small quantities Substances of 1 °. lo 22 °, 30° and 31 °, forwarded in small quantities, may also be packed as follows: (a) liquids not more than 1 kg per package, in bottles, made of alu­ minium, a suitable plastics material, or glass, with stop­ pers, made of a suitable plastics material or with yoke or screw closures having, in either case, an elastic gasket. The bottles shall be secured, by clean mica powder or glass wool used as cushioning materials, in fibreboard or wooden boxes. The filling material must be sufficient in quantity to absorb the whole of the liquid. The bottles must not be filled beyond 75 per cent of their capacity; (b) pasty or powdered substances not more than 1 kg per package, in aluminium boxes or in fibreboard or wooden boxes (the two latter being lined with aluminium or with a suitable plastics material) with a strong closure. A free space of 10 per cent shall be left in the packagings. 3. Mixed packing Substances of Class 5.2 may not be included in the same package either with other substances or articles of ADR or with other goods. Substances of Group C must not be in­ cluded in the same package with substances of Groups A, B or E. 4. Marking and danger labels on packages (see Appen­ dix A.9) (1) Every package containing substances of Class 5.2 shall bear two labels conforming lo model No.5. Packages containing substances of 46 ° (a), 4 7 ° (a) and 49° (a) shall ~lso bear a label conforming to model No. l. (2) Packages containing fragile receptacles not visible from the outside shall bear a label conforming lo model No.12. If the fragile receptacles contain liquids, the pack­ ages shall in addition, except in the case of sealed am­ poules, bear labels conforming lo model No.11; packages containing substances of 30 °, 31 °, 35 °, 40 ° and 45 ° to 55 ° shall also bear labels conforming to model No.11: these labels shall be affixed high up on two opposite sides of cases or in an equivalent manner when other packagings are used. B. Particulars in the transport document The description of the goods in the transport document must conform to one of the names underlined in marginal 2551; it must be underlined and followed by particulars of the class, the item number (together with the letter, if any). and the.initials "ADR" or "RID" [e.g. 5.2, 8° (a), ADRJ. C. Empty packagings (1) Empty packagings of 99°, uncleaned, shall be closed in the same manner and be leakproof to the same degree as if they were full. (2) Empty packagings of 99 °, uncleaned, shall bear the same danger labels as if they were full. (3) The description in the transport document shall con­ form l~ one of the names underlined in 11 °, e.g. Empty packagmg, 5.2, 99°, ADR. This text shall be underlined. In the case of empty lank-vehicles, empty demountable t~nks and empty tank-containers, uncleaned, this descrip­ tion shall be completed by adding the words "'Last load" to­ gether with the name and item number of the goods last loaded, e.g .. Last load: 2,6,6-trimethyl norpinanyl hydroperoxide, 5.2, ] 5 °. 2561 2562. 2563 2564 2565 2566 2569 2570 2571 2599 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) CLASS 6.1 TOXIC SUBSTANCES 1. List of substances (1) Among the substances and articles covered by the heading of Class 6.1, 11 those which are listed in marginal 2601 or are covered by a collective heading of that mar­ ginal are subject to the conditions set out in marginals 2600(2) to 2622 and the provisions of this Annex and of Annex B. They are then considered as substances and arti­ cles of ADR;21 Substances of Class 6.1 (other than the substances of 1 ° to 3 °) which are classified under the various items of mar­ ginal 2601 shall be assigned to one of the following groups designated by the letter (a), (b) or (c) according to their de­ gree of toxicity: letter (a): Highly toxic substances letter (b): toxic substances letter (c): Harmful substances Subdi\·isio11 . i11lo groups \\ilhi11 all ilclll Highly toxic (a) Toxic (b) Harmful (d .,;;;: > solids: > When, as a result of additions, substances of Class 6.1 pass into categories of toxicity or boiling point other than those to which the substances specified in marginal 2601 2600 belong, such mixtures or solutions shall be classified under the items or letters to which they belong on the basis of their actual degree of toxicity or their boiling point. Oral toxic-ity I.D50 When, as a result of additions, substances of Class 6.1 pass into the category having a flash-point below 21 °C. such mixtures and solutions shall be classified under the corresponding items and letters of Class 3, taking into ac­ count their toxicity. When, as a result of additio~s of substances of Class 8. substances of Class 6.1 acquire a preponderance of corro­ sive properties, such mixtures or solutions shall be classi­ fied under the corresponding items and letters of Class 8. NOTE: Toxic inflammable liquids having a flash-point below 21 °C, other than hydrocyanic acid and its solutions and metal carbonyls, are substances of Class 3, marginal 2301, 11 ° lo 20°. Toxicity on Dermal inhalation lox icily LCso LDso Dusts and mists (111g/kg) (mg/kg) (mg/I) 5 .,;;;: 40 .,;;;: 0.5 5-50 > 40-200 > 0.5-2 > 200-1000 > 2-10 S0-200 .,, liqtiids: ;·t > Where a substance exhibits different degrees of toxicity for two or more kinds of exposure. it should be classilied under the high­ est such degree of toxicity. Substances, which bv reason of their loxicitv criteria would normally fall within the ~lassilication "'harmful". ·arP classified as toxic if their vapour pressure at 20°C is sufficient lo crea!P an at­ mosphere producing 011 the eyes an irritant lachry111alorv effpct comparable to that of tear gases. LD50 value for acute oral toxicity That dose of the substance administered which is most likl'h lo cause death within 14 <lavs in nnP half of hoth malP and fpn;ale l/ See page 140 lhroui:h pagr 142. 21 For the quantities of subs!anres of 111argi11al 260 I whi<"h a,·p no! subject to the provisions for this Class eilhPr in this Anne, or i11 A11m•x B. see marginal 260 I a. l/ The heading of Class 6.1 · covers the loxir substances of which ii is known by experience or regarding which ii is prrsu111ed frolll exp,•ri111e11ls on animals Iha! in relalivdy small quantity thev are able by.a single action or by action of short duration lo cause damage to human health. or death. by inhalation, by cutaneous absorption or bv ingeslion, Substances, including pesticides of 71 ° lo 88°. 1101 exprPssly tnt'n­ tioned should be classified under the appropriale ilc•m ami leller areurd­ ing lo the following provisions: To assess the toxic hazard, account should lw 1aken of human experi­ ence in instances of accidental poisoning, and of special properties pos­ sessed by any individual substances. such asl iquid stale. high V<ilatilitv. any special likelihood of cutaneous absorption. and special biological e 0 f­ fecls. In the absence of observations on man. the loxic hazard should be as­ sessed using the available data from animal experiments in accordance with the table below: ;j0-500 •,• ;. ,. '· ~· ..,, . young adult albino rats. The number of animals testPd ·,mtifi be sufficien t to give a statistically significant result ai1Wshall br in conformity with good pharmacological practices. The result is·ex­ pressed in milligrams per kg body mass. LD50 value for acute dermal toxicit, That dose of the substance which. adn1inislt'red hv rnntinuous contact for 24 hours with the bare skin of albino· rabbits -is ,1110s1 likely to cause death within 14 days in one half of tlw animals tested. The number of animals tested shall be sufficient to give a. statistically significant result and shall be in conforn1ity with good pharmacological practices. The rPsult is expressed in n1illigrmns per kg body mass. • LC50 value for acute toxicity 011 i11hala1ion That concentration of vapour. mist or dust which. a<lministered by continuous inhalation for one hour to both male and fe111ale young sdult albino rats, is most likely to cause death within 14 days in one half of the animals tested. If the substance is a<lrnini­ stered to the animals as dust or mist. more than 90 per cent of the particles available for inhalation in the Lest must have a diameter of 10 µm or less, provided that it is reasonably foreseeable thal such concentrations could be encountered by man during trans­ port. The result is expressed in 111illigra111s per litre of air for dusts and mists an<l in millilitres per cubic metre of air (parts per mil­ lion) for vapours. The criteria for'inhalation toxicity of dusts and 111ists arf' based on LC50 data relating to 1-hour exposures. and where such infor­ mation is available it should be used. However. where onlv LC. 0 data relating to 4-hour exposures to dusts and 111ists are 1\\'~ilabl;, such figures can be multiplied by four and the product substituted in the above criteria, i.e. LC50 (4 hour) X 4 is considered the equivalent of I.C50 (1 hour). Inhalation toxicity of vapours The following criteria shall 'be used for the classification in groups (a) to (c) of liquids giving off toxic vapours, where ·•V" is the saturated vapour concentration in ml/1113 air at 20°C and standard atmospheric pressure: 949 950 E<l>HMEPiI THI KYBEPNHIEQI (TEYXOI aEYTEPO) Subdivision into groups within an item Highly toxic {a) Where V ~ 10LC50 and LC50 ~ 1000 ml/m3 Toxic {b) Where V ~ LC O and LC O ~ 3000 ml/m3 and ~e criteria for (a) are not met Harmful {c) Where V ~ 1/5 LC50 and LC50 ~ 5000 ml/m3 and the criteria for {a) 4 or {b) are not met • .• These criteria for inhalation toxicity of vapours are based on LC 50 data relating to 1-hour exposures, and where such informa­ tion is available, it should be used. However, where only LC50 data relating to 4-hour exposures to the vapours are available. such figures can be multiplied by two and the product substituted in the above criteria, i.e. LC50(4 hour) X 2 is considered the equivalent of LC50{1 hour). INHALATION TOXICITY: PACKING GROUP BOROERLINES 10 100 1.000 10.000 100.000 VOLAllLITY ml/m' In this figure the criteria are expressed in graphical form. as an aid to easy classification. However. due to approximations inher­ ent in the use of graphs. substances falling on or near packing group borderlines shottld be checked using numerical criteria. (2) For the packaging requirements of marginals 2605(2), 2606(3) and 2607(2), substances or mixtures of substances having a melting point above 45 °C, are consid­ ered solids. (3) The chemically unstable substances of Class 6.1 are to be accepted for carriage only if the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end, care should in particular be taken to ensure that packagings do not con­ tain any substance liable to promote these reactions. (4) The flash-point referred to below shall be deter­ mined in the manner described in Appendix A.3. NOTE: Even where no substance is listed under letters (a), (b) or (c) of the various items, substances, solutions, mixtures and preparations may be classified under these letters in accordance with the criteria set out in marginal 2600. A. Highly toxic substances which )lave a flash-point below 21 °C and a boiling point below 200°C and are not substances of Class 3. 1 ° Hydrocyanic acid containing not more than 3 per cent water (completely absorbed by an inert porous sub­ stance or in the liquid state), on condition that the filling of 2601 the receptacles was carried out less than one year previ­ ously; NOTES: 1. Special conditions of packing are applicable to this substance (see marginal 2603(1)). 2. Hydrocyanic acid not satisfying these conditions is not to be accepted for carriage. 2 ° The following solutions of hydrocyanic acid: Aqueous solutions of hydrocyanic acid containing not more than 20 per cent pure acid; Alcoholic solutions of hydrocyanic acid containing not more than 45 per cent pure acid in methanol; ( Alcoholic solutions of hydrocyanic acid containig not more than 40 per cent acid in ethanol. NOTES: 1. Special conditions of packing are applicable to these substances (see marginal 260.3(2)). 2. Aqueous solutions of hydrocyanic acid containing more than 20 per cent pure acid, alcoholic solutions of hydrocyanic acid containing more than 45 per cent pure acid in methanol, and alcoholic solutions of hydrocyanic acid containing-more than 40 per cent pure acid in ethanol are not to be accepted for carriage. 3 ° The following metal carbonyls: Iron pentacarbonyl, nickel tetracarbonyl NOTES: 1. Special conditions of packing are applicable to these substances (see marginal 2604). 2. For metal carbonyls having a flash-point of 21 °C or over, see 36 °. Other metal carbonyls having a flash-point below 21 ° C are not to be accepted for carriage. B. Organic substances which have a flash-point of21 °C or over or are non-inflammable NOTE: Organic substances and preparations used as pesticides are substances of71 ° to 77° and 81 ° to 83 °. 11 ° Nitrogenous substances having a boiling point below 200°C, such as: (a) acetone cyanohydrin; (b) aniline, benzonitrile, diamethylaminoacetonitrile, N, N-dimethyl-aniline, dimethylpyridine, lactonitrile, metho­ xypropionitrile, ( mono )chloroacetonitrile, trichloroacetoni­ trile; ( c) diethylaminoacetonitrile, N-methylaniline. NOTE: Isocyanates having a boiling point below 200°C are substances of 18 °. 12 ° Nitrogenous substances having a boiling point of 200°C or over, such as: (a) ... (b) 2-aminobenzonitrile, aminonitrobenzonitrile, benzi­ dine, bromoanilines, N-butylanilines, chloronitrobenzenes, dichloroanilines, benzidine dihydrochloride, dimethylami­ noborane, dinitroanilines, dinitrobenzenes, dinitrotolue­ nes, ethyltoluidines, nitrobenzotrifluorides, 3-nitro-4-chlo­ robenzotrifluoride, monochloroanilines, mononitroanili­ nes, mononitrotoluenes, beta-naphthylamine, nitroben­ zene, nitroxylenes, phenylhydrazine, benzidine sulphate, toluidines, xylidines. (c) acrylamide, adiponitrile, aminophenols, anisidines, benzylcyanide (phenylacetonitrile ), diaminodiphenylme­ thane, N,N-diethylaniline, ethylanilines, N-ethyl-N-bezyla­ nimine, alphanaphthylamine, nitrocresols, nitrophenols, phenetidines, phenylenediamines, 2,4-toluylenediamine. NOTE: Isocyanates having a boiling point of 200°C or over are substances of 19 °. 13 ° Oxygenated substances having a boiling point below 200°C, such as: (a) ally! alcohol, dimethyl sulphate; (b) aldol (beta hydroxybutyraldehyde), phenol, chlorodi­ methyl sulphate; (c) furfuryl alcohol, triallyl borate, ethylene glycol monobutyl ether, ethyl oxalate. 14 ° Oxygenated substances having a boiling point of 200°C or civer, such as: (a) ... E<l>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: ~EYTEPO) (b) benzoquinone, chlorocresols, cresols, diethyl sul­ phate, xylenols: (c) alkyloxyphenols, alkylphenols (with C 2 to C 8 chains), hydroquinone, pyrocatechol, quinhydrone, resorcinol. 15 ° Halogenated hydrocarbons having a boiling point below 200°C, such as: (a) ... (b) benzyl bromide, ethyl bromide, chloroform, benzyl chloride, ethylene dibromide (sym.-dibromoethane), methyl iodide, pentachloroethane, 1, 1, 1,2-tetrachlo­ roethane, 1, 1,2,2,-tetrachloroethane (acetylene tetrachlo­ ride), carbon tetrachloride. NOTE: Mixtures of ethylene dibromide (sym. dibromoethane) with methyl bromide having, at 50°C, a vapour pressure greater than 300 kPa (3 bar) are sub­ stances of Class·2 (see marginal 2201, 4° (b t)). (c) bromoform; methylene chloride (dichloromethane), 1,2-dichlorobenzene, carbon tetrabromide, tetrachloro­ ethylene (perchloroethylene ), trichloroethylene, 1, 1, 1 trichloroethane, trichloropropane. NOTE: Mixtures of methylene· chloride with methyl chloride having, at 50°C, a vapour pressure greater than 300 kPa (3 bar) are substances of Class 2 (see marginal 2201, 4° (b t)). 16 ° Other halogenated substances having a boiling point below 200°C, such as: (a) chloropicrin, chlorotrifluoropyrimidine, epibromo­ hydrin, perchloromethylmercaptan; NOTES: 1. Mixtures of chloropicrin with methyl bro­ mide or methyl chloride, having, at 50°C, a vapour pres­ sure greater than 300 kPa (3 bar) are substances of Class 2 (see marginal 2201 4 ° (a t) or 4 ° (b t)). 2. Symmetrical dichlorodimethyl ether is not to be ac­ cepted for carriage. (b) chloroacetaldehyde, ethylbromoacetate, methylbro­ moacetate, bromoacetone, ethylchloroacetate, methylchlo­ roacetate, chloroacetone, cyclohexyl chloroformate, 2-ethylhexyl chloroformate, phenyl chloroformate, 1-chlo­ ro-l-nitropropane, l-chloro-2-propanol, 1,2-dibromo-3 butanone, sym.-dichloroacetone, 1,3-dichlorohydrin (l,3 dichloro-2-propanol), 1, l-dichloro-1-nitroethane, epi­ chlorohydrin, 2,2-dichloroethyl ether, dichloroisopropyl ether, 3-aminobenzotrifluoride, ethylene chlorohydrin (2 chloroethanol), pentafluorobenzaldehyde, trichloroacetal­ dehyde (chloral), trichloronitroethane. NOTE: Chloroformates having predominantly corrosive properties are substances of Class 8 (see marginal 2801, 64°). (c) 2-chlorophenol, 3-chloro-l-propanol, methyl dichlo­ roacetate, methyl trichloroacetate. 17° Halogenated substances having a boiling point of 200°C or over, such as: • (a) phenylcarbylamine chloride, alpha-bromobenzyl cy­ anide; (b) phenacyl bromide ( omega-bromoacetophenone ), nitrobenzyl bromide, xylyl bromide, phenacyl chloride (omega-chloroacetophenone), benzylidene chloride, hexa­ fluoroacetone hydrate, benzyl idodide, sodium pentachlo­ rophenate, trichlorobutene. (c) chloroanisidines, chlorobenzaldehyde, tert-butylcy­ clohexylchlorof9rmate, chloronitroanilines, chloronitroto­ luenes, 3-chlorophenol, 4-chlorophenol, chlorotoluidines, bromobenzyl chloride, chlorobenzyl chlorides, dichloro­ phenols, dichlorotoluidines, hexachloroacetone, hexachlo­ robenzene, hexachlorobutadiene, hexachloroethane, so­ dium monochloroacetate, 1,1,2,2-tetrabromoethane (ace­ tylene tetrabromide), tetrachlorobenzenes, tetrachlorophe­ nols, trichlorobenzenes, trichlorophenols. NOTES: 1. Chloroformates having predominantly cor­ rosive properties are substances of Class 8 (see marginal 2801, 64°). 2. 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) in con centrations considered highly toxic according to the criteria in marginal 2600 (1), footnote 1 is not to be accepted for carnage. 18 ° Isocyanates having a boiling point below 200 ° C, such as:. (a) ... (b) chloroethyl isocyanate, cyclohexyl isocyanate, phenyl isocyanate, tolyl isocyanate; solutions of iso­ cyanates of 18 ° (b) and 19 ° (b) having a flash-point of 21 °C or over. NOTE: Solutions of these isocyanates having a flash­ point below 21 ° C are substances of Class 3 [ see marginal 2301, 14° (b)]. (c) ... 19° Isocyanates having a boiling point of 200°C or over, such as: (a) ... (b) hexamethylene di-isocyanate, 2,4-toluylene di-iso­ cyanate and isomeric mixtures, 3-chloro-4-methylphenyl isocyanate, 3-chlorophenyl isocyanate, 4-chlorophenyl isocyanate, 3, 4-dichlorophenyl isocyanate, alpha­ naphthyl isocyanate, tosyl isocyanate; NOTES: 1. Solutions of these isocyanates having a flash-point below 21 °Care substances of Class 3 [ see mar • ginal 2301, 14° (b)]. 2. Solutions of these isocyanates having a flash-point of 21 °C or over are substances of 18 ° (b). • (c) 4,4'-diphenylmethane di-isocyanate, isophorone di­ isocyanate (3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate), 1,5-naphthylene di-isocyanate, trimethylhe­ xamethylene di-isocyanate and isomeric mixtures, stearyl isocyanate, solutions of isocyanates of 19 ° C having a flash-point of 21 °C or over. 20 ° Substances containing sulphur and having a boiling point below 20 0°C, such as: (a) thiophenol; . (b) 2-ethylthiophene, furfurylmercaptan, ·allyf. isothio­ cyanate, ethyl isothiocyanate, mercaptoethanol (thiogly­ col), thiophosgene, solutions of isothiocyanates of 20° (b) having a flash-point of 21 °C or over; . NOTE: Solutions of these isothiocyanates having"a fla~h­ point below 21 ° C are substances of Class 3. [ see marginal 2301, 18° (b)]. • (c) methyl isothiocyanate, 4-thiapentanal. 21 ° Substances containing sulphur and having a boiling point of 200°C or over, such as: (a) ... (b) 2-acetylthiophene, aminothiophenol; (c) ... 22 ° Substances containing phosphorus and having a boiling point below 200°C, such as: {a) ... (b) triethyl phosphine; (c) ... 23 ° Substances containing phosphorus and having a boiling point of 200°C or over, such as: (a) ... {b) ethyldiphenylphosphine, triphenylphosphine oxide, tricresyl phosphate with more than 3 per cent ortho isomer, triethylene-phosphoramide; (c) ... • 24 ° Organic compounds which cannot be classified under other collective headings, such as: (a) ... (b) benzoyl cyanide; (c) 1,5,9-cyclododecatriene C. Organometallic compounds and carbonyls NOTES: 1. Toxic organometallic compounds"used as pesticides are substances of 7 8 ° to, 80 °. 2. Spontaneously inflammable organometallic com­ pQunds are substances of Class 4.2 (see marginal 243). 951 952 E<J>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: ~EYTEPO) 3 °). Organometallic compounds which, in contact with water, release inflammable gases are substances of Class 4.3 [see marginal 2471, 2° (e)]. 31 ° Organic lead compounds such as: (a) tetraethyl lead, tetramethyl lead, mixtures oflead al­ kyls with halogenated organic compounds, e.g. ethyl fluid (anti-knock additive for motor fuels). 32 ° Organic tin compounds, iwch as: (a) ... (b) dibutyl tin chloride, dimethyl tin chloride; (c) monoalkyl tin chloride,. other dibutyl tin com­ pounds. NOTE: Butyl tin trichloride is a substance of Class 8 [ see marginal 2801, 21 ° (b)]. 33 ° Organic mercury compounds, such as: (a) .. . (b) .. . (c) .. . 34 ° Organic arsenic compounds, such as: (a) .. . (b) .. . (c) .. . 35 ° Other organometallic compounds, such as: Organic compounds of antimony, cadmium, chromium, cohalt and thallium. (a) ... . (b) .. . (c) .. . 36° Carbonyls, such as: (a) .. . (b) .. . {c) chromium carbonyl, cobalt carbonyl. NOTE: Iron pentacarbonyl and nickel tetracarbonyl are substances of 3 ° . D. l11qrgaqic:s.1:11?.stances which may release toxic gases on contact with water,(or atmospheric humidity), aqueous solutions .or acids 41 ° Inorganic cyanide;, such as: (a) solid~cyanides, such as: barium cyanide, calcium cya­ nide; potassium cyanide, sodium cyanide, solutions of inor­ ganic cyanides, preparations of inorganic cyanides; complex cyanides in solid form, such as: sodium cuprocyanide, mercuric potassium cyanide, solutions of complex cyanides. (b) solid cyanides, such as: mercury cyanide; complex cyanides in scilid form, such as: potassium cuprocyanide. (c) ... NOTE: Ferricyanides, ferrocyanides, alkaline thiocya­ nates and ammonium thiocyanate are not subject to the provisions of ADR. 42 ° Azides, such as: (a) barium azide with not less than 50 per cent water or alcohols; (b) aqueous solutions of barium azide, sodium azide; (c) ... NO'I;ES: 1. Azides which may explode on contact with a flame or which are more sensitive to shock or to friction than dinitrobenzene are not to be accepted for carriage un­ less they are specifically listed in Class la. 2. Barium azide in the dry state or with less than 50 per cent water or alcohols is not to be accepted for carriage. 43 ° Preparations of phosphides containing additives in hibiting spontaneous ignition, such as: (a) aluminium phosphide, magnesium phosphide; (b) zinc phosphide; (c) ... • NOTES: 1. These preparations are not to be accepted for carriage unless they contain additives inhibiting sponta­ neous ignition. 2. Preparations of sodium phosphide, calcium phosphide and strontium phosphide are substances of Class 4.2 (see marginal 2431 2°). 44 ° (b) Ferro-silicon and mangano-silicon with more than 30 per cent and less than 70 per cent silicon, ferro­ silicon alloys with aluminium, manganese, calcium or more than one of these metals, with a total content of silicon and of elements other than iron and manganese greater than 30 per cent but less than 70 per cent; (c) ... Substances of 44 ° shall be accepted for carriage only if they have been stored for not less than three days in a dry • place open to the air. NOTES: 1. Ferro-silicon and mangano-silicon bri-· queues, whatever their silicon content, are not subject to the provisions of ADR; 2. Substances of 44 ° are not subject to the provisions of ADR if they are not liable to release dangerous gases under the effect of moisture during carriage and the sender so certifies in the transport document. E. Other inorganic substances 51 ° Arsenical compounds, such as: (a) arsenic acid (liquid), liquid arsenical compounds, ar­ senic trichloride; (b) arsenic acid (solid), arsenic tr.ioxide (white arsenic), arsenic pentoxide, calcium arsenate, magnesium arsenate, potassium arsenate, sodium arsenate, potassium arsenite, sodium arsenite, arsenic bromide; • (c) ... NOTE: Substances and preparations containing arsenic and used as pesticides are substances of 84 °. 52 ° Mercury compounds, such as: (b) mercuric acetate, mercuric chloride; (c) ... NOTES: 1. Substances and preparations contammg mercury and used as pesticides are substances of 86 °. . 2. Cinnabar and mercurous chloride (calomel) are not subject to the provisions of ADR. 3: Fulminates of mercury are not to be accepted for car­ riage. 4. Mercuric potassium cyanide and mercury cyanide are substances of 41 °. 53 ° Thallium compounds, such as: (b) .. . (c) .. . NOTE: Substances and preparations containing thal lium and used as pesticides are substances of 88 °. 54 ° Beryllium and beryllium compounds, such as: (b) beryllium in powder form; (c) ... 55 ° Selenium and selenium compounds, such as: (a) selenates, selenites; (b) selenium disulphide, selenium dioxide; (c) selenium metal. NOTE: Selenic acid is a substance of Class 8 (see mar ginal 2801, 11 ° (a)). 56 ° Osmium compounds such as: (a) osmium tetroxide; (b) .. . (c) .. . 5 7 ° Tellurium compounds, such as: (b) tellurum dioxide, aluminium telluride, cadmium tel luride, zinc telluride; (c) ... 58 ° Vanadium compounds, such as: (b) vanadium pentoxide, vanadates; ,(c) ... NOTES: 1. Vanadium oxytrichloride, vanadium tetra­ chloride and vanadium trichloride are substances of Class 8 (see marginal 2801, 21 ° and 22°). <I>EK 104 E<DHMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) 2. Vanadium chlorate and perchlorate are substances of Class 5.1 (see marginal 2501, 4°). 59° Antimony compounds, such as: • (c) antimony oxides, antimony salts NOTES: 1. Antimony pentachloride, antimony trichloride and antimony pentafluoride are substances of Class 8 (see marginal 2801, 21 °, 22° and 26°). 2. Antimony chlorate and antimony perchlorate are sub­ stances of Class 5.1 (see marginal 2501, 4 °). 3. Antimony oxides with an arsenic content not exceed­ ing 0.5 per cent of the total mass, and stibnite, are not sub­ ject to the provisions of ADR. 60° Barium compounds, such as: (c) barium carbonate, barium chloride, barium fluoride, barium hydroxide, barium oxide, barium sulphide. NOTES: 1. Barium chlorate, barium nitrate, barium ni­ trite, barium perchlorate, barium permanganate and bar­ ium peroxide are substances of Class 5.1 (see marginal 2501, 4°, 7°, 8° and 9°). 2. Barium azide is a substance of 42°. 3. Barium stearate, barium sulphate and barium titanate are not subject to the provisions of ADR. 61 ° Cadmium compounds, such as: ( c) cadmium acetate, cadmium carbonate, cadmium ni­ trate, cadmium sulphate. NOTE: Cadmium pigments, such as cadmium sul­ phides, cadmium sulphoselenides and cadmium salts of higher fatty acids (e.g. cadmium stearate), are not subject to the provisions of ADR. 1. 62 ° Lead compounds, such as: (c) lead oxides, lead pigments, such as white lead and lead chromate, lead salts including lead acetate; NOTES: 1. Lead chlorate, lead nitrate and lead perchlorate are substances of Class 5.1 (see marginal 2501, 4° and 7°). 2. Lead salts and lead pigments which are not soluble in 0.1 N. hydrochloric acid are not subject to the provisions of ADR. 63 ° Residues and wastes containing compounds of anti­ mony or of lead or of both, such as: (c) lead sludges containing less than 3 per cent free sul­ phuric acid, ashes of antimony or of lead or of antimony and lead. NOTE: Lead sludge containing 3 per.cent or more free sulphuric acid is a substance of Class 8 (see marginal 2801, 1 ° (b)). 64 ° Hydrazine salts, such as: (c) hydrazine dihydrobromide, hydrazine dihydrochloride, hydrazine monohydrobromide, hydrazine monohydrochloride, hydrazine sulphate. 65 ° Fluorides soluble in water, such as: (c) ammonium fluoride, potassium fluoride, sodium flu­ oride. NOTE: Corrosive fluorides are substances of Class 8 (see marginal 2801, 25° and 26°). 66 ° Silicofluorides. such as: 71 ° Organophosphorus compound,;. such as: Acephate Amidithion Azinphos-ethyl Azinphos-methyl Bromophos-ethyl Carbophenothion . Chlorfenvinphos Chlormephos 71 ° (n) <'I, (c) ammonium silicofluoride. 67° (c) Oxalates soluble in water. 68 ° Inorganic compounds which cannot be classified under other collective headings, such as: • • (a) .. . (b) ... . (c) cobalt chloride, cupric chloride, molybdenum triox ide. • NOTE: Substances and preparations containing copper and used as pesticides are substances of 87°. • F. Substances and preparations used as pesticides NOTES: 1. Inflammable liquid substances and prepara­ tions, used as pesticides, which are highly toxic, toxic or harmful and have a flash-point below 21 °Care substances of Class 3 (see marginal 2301, 6° or 19°). 2. Articles impregnatel with substances and prepara­ tions used as pesticides of 71 ° to 88 °, such as fibreboard plates, paper strips, cotton-wool balls, sheets of plastics material, etc., in airtight, hermetically closed envelopes are not subject to the provisions of AOR. 71 ° to 88 °: These items are tabulated under • letter (a): Highly toxic substances and preparations. letter (b): Toxic substances and preparations. letter (c): Harmful substances and preparations. NOTES: 1. All active substances and their preparations used as pesticides shall be classified under 71 ° to 88 ° (a), (b) and (c) in accordance with footnote1/ to marginal 2600 (1). 2. If only the L050 value of the active substan.ce is known and not that of the preparations of the active substance, the preparations may be classified urider 71 ° to 88° (a), (b) and·( c) using the following tables, where the figures shown in columns (a), (b) and (c) of 71 ° to 88° represent the per­ centage of active pesticide substance in the prepara tions. • • 3. For-substances which are not named in the.list, and for which only the LO O value of the .. active substance is known and not the Los: values of the various preparations, the classification of a preparation may be determined from th table in footnote 11 to marginal 2600 (1), usi11g.anLOso value obtained by multiplying the LOso value of.the active substance by 100 /X, X being the percentage of active sub­ stance by mass according to the following formula: D f th . LD 50 value of the active substance X 100 • L s0value o e preparabon percentage of active substance by mass 4. The classification according to notes 2 and 3 above shall not be used the preparations contain additives which affect the toxicity of the active substance or when a prepa­ ration. contains more than one active substance. In such cases the classification shall be based on the L050 value of the preparation in question according to the criteria in footnote 11 to marginal 2600 (1). If the L050 v~ue is :iot known, the substance shall be classified under (a) of 71 to 88°. • 71 ° (h) 71 ° (c) . % solid% liquid% - 100 - 40 - 100 - 30 100 ->25 25 - 2 25 - 0.5 100 ->20 20 - 2 • 20 - 0.5 100 - 10 100- 3 100->20 20- 2 20 - 0.5 100 ->20 20- 2 20 - 0.5 100 -> lS 15 - 1 15 ->0 953 I 954 EG>HMEPII THI KYBEPNHIEQI (TEYXOI LlEYTEPO) 71 ° Organophosphorus compounds, such as (contd): Chloropyrithos Chlorthiophos Crotoxyphos. Crufomate Demephion (Demephion-0 and Dcmephion-S) Demeton Demeton-O-methvl Thiolo Isomer • Thiono Isomer Demeton-S-melhvl Dialifos • Diazinon Dichlofenthion Dichlorvos Dicrotophos Dimefox Dimethoate Dioxathion Disulfoton Dithianon Endothion EPN Ethion Ethoate-methyl Ethoprophos Fenitrothion Fensulfothion Fenthion Fonofos Formothion Malathion Mecarb~ni Mephosfolan Methidathion Methyltrithion Mevinphos Monocrotophos Naled Omethoate Oxydemeton-melhyl Oxydisulfoton Parathion Parathion-methyl Phenkapton Phorate Phosalon~ Phosfolan Phosmet (Phthalophos) Phosphamidon Pirimiphos-ethyl Prothoate Pyrazophos Pyrazoxon Sulfotep Temephos TEPP Terbufos Thiometon Thionazin Triamiphon Trichlorfon Trichloronat Vamidothion 71 ° (a) % 100->40 100->0 100 ->30 100->20 ~ 100 ->75 100 ->65 100->40 100 ->60 100 ->25 100 ->60 ~ 100 ->70 100->40 100 ->20 IOU ->80 100 -> 10 100 -> 15 100 ->70 71 ° (b) % solid% 100 - 15 40->5 5->0 100 - 15 100 - 90 30->3 3->0 100 - 10 100 - 35 100 - 10 100 - 10 100 - 15 100 - 50 100 ->35 35 - 5 100 ->25 25 - 3 20->2 2->0 100 - 30 100->40 40- 4 100 -> 15 15 - 2 100->45 45 - 5 75 ->15 15 - 3 100 ->25 25 - 2 100 - 25 65 -> 10 10 - 3 100 - 45 40->4 4->0 100- 60 60->6 6->0 100 - 65 100 ->30 30 - 3 25 ->5 .5->0 100 ->40 40 - 4 100 - 15 60->5 5->0 100 ->25 25 - 3 100 - 50 100 - 10 100 ->90 90- 9 70->5 5->0 40-'->4 4->0 100 -> 15 15 - 1 100 - 10 20->2 2->0 100 - 20 100 :> 15 15 - 2 100 - 15 100 ->30 30->3 100 - 30 100 -> 15 15 - 1 100 - 55 80->5 5->0 100 -> 10 10->0 10->0 15 ->3 3->0 JOO ->50 50- 5 70->5 • 5->0 100 ->20 20- 2 100 - 80 100 ->30 30 - 3 100 -.10 71 ° (c) liquid% 100 - 4 5->0 100 - 3 100 - 20 3->0 100 - 3 100- 5 100- 3 100- 2 100- 4 100 - 10 35 - 5 25 - 0.5 2->0 100 - 10 40- 1 15 ->0 100 - 50 45 - 1 15 - 3 25 - 0.5 100- 5 10 - 3 1-00 - 10 4->0 100 - 15 6->0 100 - 15 100 - 30 30 - 0.5 5->0 40 - 1 100- 4 5->0 25 - 0.5 100 - 10 100 - 3 90- 2 5->0 4->0 15 ->0 100 -2 2->0 100-5 15 - 0.5 100 -4 30 - 0.5 100 - 5 15 ->0 100 - 15 5->0 10->0 100 - 50 3->0 50- 1 5->0 20 - 0.5 100 - 20 30 - 0.5 100 - 3 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) 72 ° Chlorinated hydrocarbons, such as: Aldrin Camphechlor (Toxaphene) Chlordane Chlordimeform DDT 1,2-dibromo-3-chloropropane Dieldrin Endosulfan Endrin Heptachlor Isodrin Lindane Pentachlorophenol 73 ° Chloro-phenoxyacelic derivatives, such as: 2,4-D 2,4-DB Dichlorprop Fenoprop Formetanate MCPA MCPB Mecoprop 2,4,5-T 7 4 ° Halogenated organic compounds not classified under 72 ° or 73 °, such as: Allidochlor Benzoylprop-ethyl Bromoxynil Chlordecone Chlormequat Chlorobenzilate Dicamba Dichlone Dicofol loxynil Isobenzan Mirex Propachlor Propanil Tetradifon 72 ° (a) % 100 ->60 73° (a) % 74° (a) r,1tc, 100 - > 5 72 ° (b) % solid% 100->75 75 - 7 100 - 10 100 - 55 100 - 50 100 - 20 100 - 30 100 ->90 90-10 100 ->80 80- 8 60->5 " 5->0 100 ->80 80- 8 100 -> 10 10 - 1 100 - 20 100 ->50 50 - 5 73 ° (b) % solid% 100 - 75 100 - >40 40 - 4 100 - 60 7 4 ° (b) % solid% 100 - 35 100 - 35 100 - 15 . 100-20 5 - > l 1 - > 0 100 - 60 955 72 ° (c) liquid% 75 - 2 100- 3 100 - 10 100 - 10 100 - 5 100 - 5 90- 2 80 - 2 5->0 80- 2 10->0 100 - 5 50 - 1 73 ° (c) ·liquid% 100 - 15 100 - 35 100 - 40 100 - 30 40- 1 . 100 - 35 106 - 30 too - 30 ··100 - 15 74° (c) liquid% 100 - 35 100 - 75 100 - 10 100- 4 100 - 30 100 - 35 100 - 50 100 - 80 100 - 25 100 - 5. 1- > 0 100 - 15 100 - 35 100 - 25 100 - 25 956 7 5 ° Nitrogenated organic compounds not classified under other item numbers, such as: Benquinox Binapacryl Butocarboxim Chinomethionate Cyanazine Cycloheximide Dinobuton Dinoseb Dinoseb acetate Dinoterb Dinoterb acetate Diphenamid DNOC Dodine Drazoxolon Medinoterb Methyl isothiocyanate Nitrofen Terbumeton Tridemorph i6 ° Carbamates and thiocarbamates, such as: Aldicarb Aminocarh Barban Bendiocarb Carbary! - --· Carbofuran Di-allate Dimetilan Dioxacarb EPTC Isolan Mercapto-d imeth u r Metam-sodium • Methomvl Mexaca~hate Molinate Nabam Oxamyl Pendimethalin Pirimicarb Promecarb Propoxur Sulfallate Thiram Tri-allate 77° Alcaloids, such us: Nicotine Strychnine ECDHMEPII THI KVBEPNHIEQI (TEVXOI aEVTEPO) 75° (a) 75 ° (b) % % solid % - 100 - 20 - ~ 100 - 25 - 100 - 30 - - 100 - 35 - 100 - 10 - 100 - 10 100->40 40- 5 - 100 - 10 100 ->50 50- 5 - 100 - 10 - 100 - 55 100 ::..>50 50- 5. - - 100 - 25 100 ->80 80 - 8 - 100 - 35 - - ..: 76 ° (a) 76° (b) % % solid% . 100 -> 15 15 -> l l->O 100 ->60 60-6 - 100 ->65 65-5 - 100-80 100 ->10 10-l - 100-80 100 ->50 50-5 - 100-10 - 100 ->20 20-2 - ]00-10 - 100-50 100 ->30 30-3 100 ->25 25-2 - - 100-80 100 -> 10 10-1 - - 100-75 - 100-15 - 100-15 - -. - - - 77 ° (a) 77° (b) % % solid% - 100-10 100->20 20->0 75 ° (c) liquid % 100 - 5 100 - 5 100 - 5 100-55 100-10 100 - 3 100- 2 40- 5 100 - 3 50 - 1 100- 3 100-10 50 - 1 100-25 100- 5 80 - 2 100 - 8 100-30 100-20 100-30 76 ° (c) liquid% 1->0 60-1 100-30 65-1 100-20 10->0 100-20 50-1 100-3 100-80 20-0.5 100-3 100-10 30-0.5 25->0 100-25 100-20 10->0 100-50 100-20 100-3 100-4 100-40 100-25 100-30 77 ° (c) liquid% 100-2 EG>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) 78 ° Organic compound; of mercury, such as: Phenylmercuric acetate (PMA) Chloro-methoxyethyl mercury Phenylmercury pyrocatechin (PMB) 79° Organic compounds of tin, such as: F entin acetate Cyhexatin Tricyclohexyl-tin hydroxide) Fentin hydroxide 80° Other organo-metallic compounds which cannot be classified under 78 ° and 79°, such as: 81 ° Rodenticides, such as: Chlorophacinone Coumachlor Coumafuryl Coumaphos Crimidine Dicoumarol Diphacinone Warfarin 82 ° Derivatives of bipyridyl, such as: Diquat Morfamqual Paraquat 78 ° (a) % 79° (a) % 80° (a) % ... 81 ° (a) % 100 ->40 100 ->25 100 ->25 100 ->20 82 ° (a) % 78 ° (b) % solid % 100->60 60-6 100 ->40 40-4 100->60 60.6 79° (b) % solid% 100-25 100-55 100-20 80° (b) % solid% ,., ... 81 ° (b) % solid% 40->4 4->0 100-10 100-80 100->30 30-3 25->2 2->0 100-10 25 ->2 2->0 20->2 2->0 82 ° (b) % solid% 100-45 100-65 100 ->40 40-4 957 78 ° (c) liquid% 60-1.5 40-2 60-1.5 79° (c) liquid% 100-5 100-10 100-5 80° (c) ' ,liqyid % .. . ,-.., 81 ° (c) liquid% 4->0 100-2 100-20 30-0.5 2->0 100-2 2->0 2->0 82 ° (c) liquid% 100-10 100-15 40-4 958 EG>HMEPII THI KYBEPNHIEQI (TEYXOI 6EYTEPO) 83 ° Organic compounds which cannot be classified under a collective heading of 71 ° to 81 °, suc;h as: Allethrin Bentazone Dazomet Desmetrvn Difenzoquat Dimexano Endothal-sodium Fluoracetamide Pindone Pyrethrin Rotenone 84 ° Inorganic compounds of arsenic, such as: Arsenic trioxide Calcium arsenate Sodium arsenite 85 ° Inorganic compou11ds of fluorine, such as: • • · • ·, · Barium silicofluoride Sodium silicofluqride 86° Inorganic compounds of mercury, such as: Mercuric chloride Mercury oxide 87° Inorganic compou11ds of copper, such as: Copper oxychloride Copper sulphate 88 ° Inorganic compounds of thallium, such as: Thallium sulphate 83 ° (a) ':4· 84° (a) <:,;., 85 ° (a) % 86° (a) r;,, 87° (a) ':4· 88° (a) % 83 ° (b) '7r solid% ]00-90 100-45 100 ->75 7.5-5 100 -> 10 10-1 100-55 100-25 84° (b) % solid% 100 ->40 40-4 100->40 40-4 100 ->20 20-2 85 ° (b) % solid% 100-35 ]00-25 86° (b) % solid% 100 ->70 70-7 100 ->35 3.5-5 87° (b) '7,-, solid% 100 - 20 88 ° (b) % solid% 100 - > 30 30 - 3 83 ° (c) liquid% 100-30 100-50 100-25 100-65 100-20 100-10 75-2 10->0 100-10 100-30 100-6 84 ° (c) liquid% 40-l 40-1 20-0.5 85 ° (c) liquid% 100-8 100-5 86 ° (c) liquid% 70-1.5 35-0.5 87° (c) liquid% 100 - 35 100 - 10 88 ° (c) liquid%. 30 - 0.5 EO>HMEPII THI KVBEPNHIEQI (TEVXOI .dEVTEPO) 89° (c) Cereal grains, dressed seed and other sub­ stances of vegetable origin, impregnated with one or more of the pesticides or other substances of Class 6.1. G. Active substances intended for laboratories and ex­ periments and for the manufacture of pharmaceutical products, if not listed in other items of this Class. 90 ° Active substances, such as: (a) colchicine, digitoxin. (b) adrenalin. (c) phenobarbital. NOTES: l. The active substances and triturations or mixtures of these substances of 90° with ~ther substances are to be classified according lo their toxicity (see footnole 11 to marginal 2600(1 )). 2. Pharmaceutical products ready for use (tablets. pills. ampoules, etc.) containing substances of 90° are not sub­ ject to the provisions of ADR. H. Empty packagings. NOTE: Empty packagings with residues from their pre­ vious contents adhering to the outside are not lo be ac­ cepted for carriage. 91 ° Empty packagings, empty tank - vehicles. empty demountable tanks, erripty tank-containers and empty small bulk containers, uncleaned, which have contained • substances of Class 6.1. Substances of 11 ° to 24 °, 32 ° to 36 °, 41 ° to 44 °. 51 ° to 68°, 71 ° Lo 88° and 90° carried in conformity with the following provisions are subject neither° to the provisions for this Class contained in this Annex nor to those con­ tained in Annex B: (a) Substances classified under (a) of each item are not covered by this marginal. (b) Substances classified under (b) of each item: Liquids: not more than 500 ml per inner packaging and not more than 2 litres per package: Solids: not more than 1 kg per inner packaging and not more than 4 kg per package. (c) Substances classified under (c) of each item: Liquids: not more than 3 litres per inner packaging and not more than 12 litres per package. Solids: not more than 6 kg per inner packaging and not more than 24 kg per package. These quantities of substances shall be carried in combi­ nation packagings which at least meet the conditions of marginal 3538. •• The "General conditions of packing" of marginal 3500 (1), (2) and (4) to (7) shall be obsen:ed. 2. Provisions A. Packages. 1. General conditions of packing. (1) Packagings shall satisfy the conditions of App!'ndix A.5, unless special conditions for the packing of cc>rtain substances are prescribed in marginals 2603-2609. (2) In accordance with the provisions of marginal 2600 (1) and of marginal 3511 (2), the following shall be uscd: Packagings of packing group I. marked with the letter "X", for the highly toxie substances classified under lctter (a) of each item: Packagings of packing groups II or I. marked with the letter "Y" or "X", for the toxic substances classified under letter (b) of each item; Packagings of packing group III. II ~r I. marked with the letter "Z", "Y" or "X", for the harmful substances classi­ fied under letter (c) of each item. NOTE: For the carriage of substances of Class 6.1 in tank - vehicles, demountable tanks or tank containers. and for the carriage in bulk of solids of this Class. see Annex B. 2. Special conditions for packing of certain sub­ stances. (1) Hy<lrocyanic acid of 1 ° shall be packed: (a) when completely absorbf'rl lw an i,wrt poro11s 111.tl<' 2601a 2602 2603 rial: in strong metal receptacles of a capacity of not more than 7 .5 litres, placed in wooden cases in such a manner that they cannot come into contact with one another. Such a combination packaging shall comply with the following conditions: 1. The receptacles shall be tested al a pressure of not Jess than 0.6 MPa (6 bar) gauge pressure; 2. The receptacles shall be entirely filled with the porous material. The porous material shall not shake down or form dangerous spaces even after prolonged use or under im­ pact, even at temperatures of up to 50° C. The date of fill­ ing shall be durably marked on the lid of each receptacle: 3. The combination packaging shall be tested and ap­ proved, in accordance with Appendix A.5, for packing group I. The package shall not weigh more than 120 kg. (b) when liquid, but not absorbed by a porous material: in carbon-steel pressure-resistant cylinders which shall sat­ isfy the following conditions: 1. Before being used for the first time. the pressure­ resistant cylinders shall undergo a hydraulic pressure test at a pressure of not less than 10 MPA (100 bar) gauge pressure. The pressure test shall be repeated every two years and shall include a meticulous inspection of the in­ side of the receptacle and a check of the tare. 2. The cylinders must comply with the relevant provi­ sions of Class 2 (see marginals 2211. 2212 (l)(a). 2213. 2215 and 2218); 3. In addition lo the markings prescribed in marginal 2218 (l')(a), (b), (d), (e) and (g), the date of the most recent filling (month/year) shall be shown; 4. Maximum permissible mass of the contents: 0.55 kg per litre of capacity. (2) Solutions of hydrocyanic acid of 2 ° shall be packed in flame-sealed glass ampoules, containing not more than 50g, or in glass bottles so closed as to be leakproof·and containing not more than 250g. The ampoules or bottles shall be carried in combin~tion packagings which meet the following conditions: (a) The ampoules and bottles shall be secured by ab­ sorbent cushioning materials in leakproof steel or alumin­ ium outer packagings; a package shall not weigh more than 15 kg; or (b) The ampoules and bottles shall be secured by ab­ sorbent cushioning materials in wooden cases with a leakproof tin-plate lining; a package shall not weigh more than 75 kg. • The combination packagings referred to in (a) and (b) shall be tested and approved, in accordance with Appendix A.5, for packing group I. Metal carbonyls of 3 ° shall be packed as follows: (1) In seamless moulded bottles made of pure alumin­ ium of a capacity not exceeding 1 litre and a wall thickness not less than J mm, which shall be tested at a pressure of not less than l MPa (10 bar) gauge pressure. The bottles shall be closed by means of a metal screw-threaded plug with an inert gasket, the screw-threaded· plug being screwed firmly into the neck of the bottle and so secured that it cannot work loose under normal conditions of car­ riage. • A maximum of our aluminium bottles of this type may be secured in outer packagings of wood or fibreboard by non­ inflammable absorbent cushioning material. Such a combi­ nation packaging shall conform to a design type which has been tested and approved for packing group I in accor­ dance with Appendix A.5. A package shall not weigh more than 10 kg. (2) In metal receptacles fitted with completely leak proof closing· devices which shall, if necessary. be secured against mechanical damage hy-.protective -caps. Steel re­ ce ptacles of a capacity notexceeding-150 ltres shall hal'e a 7miiiimurn wall thickness of 3 mm. and larger steel receptacles and receptacles made of other materials sliall have walls at least thick enough to guaranlf'P equivalPnl 959 2604 960 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) mechanical strength. The maximum capacity of recepta­ cles permitted shall be 250 litres. The mass of the contents shall be not more than 1 kg of liquid per litre of capacil y. Before being used for the firts time, the receptacles shall undergo a hydraulic pressure test at a pressure of not less than 1 MPa (10 bar) gauge pressure. The presure lest shall be repeated every five years an·d shall include a meticulous inspection of the inside of the receptacle and a check of the tare. Metal receptacles shall bear the following particulars in clearly legibl~ and durable characters: (a) the name of the substance in full (the names of both substances may also be shown side by side in the event of alternative use); (b) the name of the owner of the receptacle; . (c) the tare of the receptacle including such fittings and accessories as va]bes, protective caps, etc.; (d) the date (month, year) of the initial test and of the most recent test, and the stamp of the stamp of the expect carrying out the test; (e) the maximum permissible mass of the contents of the receptacle in kg; (() the internal pressure (test pressure) lo be applied in the hydraulic pressure test. (1) Substances classified under (a) of the various items of marginal 2601 shall be .packed. (a) in non-removable head stell drums conformig Lo mar­ ginal 3520, or (b) in non-removable head aluminium drums conform­ ing to marginal 3521, or (c) in steeljerricans conforming to marginal 3522. or (d) in non-removable head plastics drums of a capacity not exceeding 60 litres or plastics jerricans conforming to marginal 3526, or (e) in composite packagings (plastics material) conform­ ing to marginal 353 7, or (() in combination packagings of glass, plastics or metal conforming to marginal 3533. • (2) Solid substances within the meaning of marginal 2600 (2) may also be packed: (a) in removable-head drums conforming Lo marginals 3520 for steel, 3521 'for aluminium, 3523 for plywood. 3525 for fibreaboard, or 3526 for plastics material. if nec­ essary with one or more sift-proof inner bags: or (b) in combination packagings conforming Lo marginal 3538, with one or more sift-proof inner bags. (1) Substances classified under (b) of the various items of marginal 2601 shall be packed: (a) in steel drums conforming to marginal 3520. or (b) in aluminium drums conforming Lo marginal 3521. or (c) in steeljerricans conforming lo marginal 3522. or (d) in plastics drums or plastics jerricans conforming Lo marginal 3526, or (e) in composit~ packagings (plastics material) conform­ ing to marginal 353 7, or (() in combination packagings conforming Lo marginal 3538. NOTE to (a), (b) and (d): Removable-head drums are permitted only for viscous substances having a viscosity above 200 mm2/s at 23°C and for solids. (2) Substances classified under 15° (b) may also be· packed in composite packagings (glass, porcelain or stone­ ware) conforming to marginal 3539. (3) Solid substances within the meaning of marginal 2600 (2) may also be packed: (a) in remobable head drums conforming Lo marginal 3523 for plywoo<l or 3525 for fibreaboard. if necessar~· with one or more sift-proof inner bags; or (b) in water-resistant bags conforming to marginals 3533 for textile material, 3534 for woven plastics mate­ rial, 3535 for plastics film or 3536 for water-ressis1,111L paper, provide<l the goods are <lispatched as a full load or 2605 2606 the bags secured on pallets. (1) Substances classified under (c) of the various items of marginal 2601 shall be packed: (a) in steel drums conforming to marginal 3520. or (b) in aluminium drums conforming Lo marginal 3521, or (c) in steeljerricans conforming to marginal 3522. or (d) in plastics drums or plastics jerricans conforming to marginal 3526, or (e) in composite packagings (plastics material) conform­ ing to marginal 3537, or (() in combination packagings conforming lo marginal 3538, or (g) in composite packagings (glass, porcelain or stone­ ware) conforming to marginal 3539, or (h) in light gauge metal packagings conforming lo mar­ ginal 3540. • NOTE to (a), (b), (d) and (h): Remobable head drums conforming to (a), (b) and (d), and removable head light gauge metal packagings conforming lo (h) are permitted only for viscous substances having a viscosity above 200 mm2/s at 23° C and for solids. (2) Solid substances within the mea,\ing of marginal 2600 (2) may also be packed: (a) in removable head drums conforming to marginal 3523 for plywood, or 3525 for fibreboard, if necessary with one or more sift-proof inner bags; or (b) in water-resistant· bags conforming lo marginals 3533 for textile material, 3534 for woven plastics mate­ rial, 3535 for plastics film or 3536 for water-resistant paper. . The openings of packagings, other than glass ampoules and cylinders under pressure, for the carriage of liquids having a viscosity below 200 mm2 /sat 23 ° C shall be capa­ ble of being so closed as to be leakproof by means of two devices placed in series, one of which shall be screw­ threaded or secured in an equivalent manner. Packagings containing dimethylaminoborane of 12 ° (b) shall be fitted with a vent in accordance with marginal 3500 (8). 3. Mixed packing (1) Substances covered by the same item number may be packed together in a combination packaging conforming to marginal 3538. (2) Substances of different items of Class 6.1 in quanti­ ties not exceeding, per packaging, 3 litres for liquids and/or 5 kg for solids, may be packed together and/or with goods not subject to the provisions of ADR. in a com­ bination packaging conforming lo marginal 3538. pro­ vided they do not react dangerously with one another. (3) Except as otherwise specially provided below. sub­ stances of Class 6.1, in quantities not exceeding. per re­ ceptacle, 3 litres for liquids and/or 5 kg for solids. may be packed together in a combination packaging conforming Lo marginal 3538, with substances or articles of other classes. provided that mixed packing is also permitted for the sub­ stances and articles of these classes, and/or with goods which are not subject to the provisions of ADR. provided they do not react dangerously with one another. (4) The following are considered dangerous reac tions: (a) combustion and/or giving off consideiable heat: (b) emission of inflammable and/or toxic gases: (c) formation of corrosive liquids; (d) formation of unstable substances. (5) The mixed packing of acid substances with basic substances in a package shall not be permilled if the L\\O substances are packed in fragile receptacles. (6) The provisions of marginals 200 l (7). 2002 (6) and (7) and 2602 shall be complied with. (7) If wooden or fibreboard boxes are used. a package shall not weigh more than 100 kg. 2607 2608 2609 2610 2611 <l>EK 104 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) 961 Maxi111um quantity Description of per Item No. substances receptacle 10 Hydrocyanic acid 30 Iron pentacarbonyl and nickel tetracarbonyl 20 Hydrocyanic acid in solutions Liquids classified 0.5 litre under (a) of each item 4. Marking and danger labels on packages (See AppP11 dix A.9) (1) Packages containing substances of 1 ° to 3 ° or sub­ stances classified under (a) or (b) of other items shall bear a label conforming lo ·model No.6.1. • If substances of 15°(6) are packed in composite packagings (glass, porcelain or stoneware) co11formi11g to marginal 3539, of a capacity exceeding 5 litres, the pack­ ages shall nevertheless bear two labels conforming to model No. 6.1 (see marginal 3901 (2)). (2) Packages containing substances classified under (c) of each item shall bear a label conforming to model No. 6. lA. However, if liquids are packed in composite packagings (glass, porcelain or stoneware) conformi11g to marginal 3539 of a capacity exceeding 5 litres. the pack­ ages shall bear two labels conforming to model No. 6.1 A (see marginal 3901 (2)). (3) Packages containing substances having a Oash-point of 55 °C or below shall, in addition, bear a label conform­ ing to model No.3, and packages conta111111g chloroformates of 16 ° or 17 ° shall, in addition. bear a label conforming to model No. 8. (4) Packages containing fragile packagings 11ot \'isible from the outside shall bear on two opposite sides a label conforming to model No. 12. (5) Packages containing liquids in packagi1igs the clo­ sures of which are not visible from the outside. packages containing packagings with vents and packagings with vents but without outer packaging shall bear on two oppo­ site sides a label conforming to model No. l]. B. Particulars in the transport document (1) The description of the goods in the transport docu­ ment shall conform to one of the names underlined in mar­ ginal 2601. If the substance is not mentioned by name. the chemical name 11 shall be entered. The description of the goods shall be underlined and followed by particulars of the class, the item number (together with the leller. if any). and the initials "ADR" (or "RID"). e;g. 6.1. 11 °(a).AUK. (2) For hydrocyanic acid of 1 °. the sender shall certify in the transport document: "The nature of the goods. anrl the packaging, are in conformity with the provisions of ADR". (3) For substances of 44 °, the sender shall certifv in the transport document: "Stored in an open and dry pi'ace for not less than three days". I/ In the case of pesticides. the name lo lw <'llll'r<'d shol!ld ht' that given in ISO Standard R. l 7!}0-1981 if lislC'd. 2612 2613 2614 per Special provisions package Mixed packing not permitted Shall not be packed together with substances of articles of Classes la. lb. ] c, 5.2 or 7 1 litre (4) For consignments of chemically unstable sub­ stances, the sender shall certify in the transport document: "Measures taken in accordance with marginal 2600 (3)'". C. Empty packagings 2615 2621 (1) If the empty packagings. uncleaned. of 91 ° are bags. 2622 these shall be placed in boxes or waterproof bags to pre vent any leakage of substance. (2) Other uncleaned empty packagings of 91'0 sh~II be closed in the same manner and with the same degree of leakproofness as if they were full. (3) Empty packagings, uncleaned. of 91 ° shall bear Hi'e same danger labels as if they were full. (4) The description in the transport document shall con-. form to one of the names underlined jn 9.1 ° .·e·:g.: Empt, packaging, 6.1, 91 ° ADR. This desir1p~o11 shall be unde(­ lined. In the case of empty tank-vehicles. empty demountable tanks, empty tank-containers and empt)' small bulk containers, uncleaned, this description shall be completed by adding the words "last load'\ .together. with the na me and item number of the goods last loaded. e.g.: Last load: Phenol, 13 ° (b). CLASS 6.2 REPUGNANT SUBSTANCES AND SUB­ STANCES LIABLE TO CAUSE INFECTION 1. List of substances . 2623 2649 Among the subswices and articles coveted by the heading 2650 of Class 6.2, only those listed in marginal 2651 are to be accepted for carriage, and then only subject to the provi sions of this Annex and of Annex B. These substances and articles to be accepted for carriage under certain condi tions are to be considered as substances and articles of ADR. 1 ° (a) Fresh tendons, clippings of fresh skins not limed 2651 or salted, trimmings from fresh tendons or from clippings of fresh skins; NOTE: Clippings of wet fresh skins, limed or salted, are not subject to the provisions of ADR. (b) fresh horns, claws or hoofs not cleansed of bone and soft adhering parts, fresh bones not cleansed of flesh or other soft adhering parts; (c) undressed pig's bristles and hair. 2 ° Fresh skins, unsalted or salted, from which offensive quantities of blood or hrine drip. 962 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) NOTE: Properly salted skins containing only a small quantity of moisture are not subject to the provisions of ADR. 3 ° Cleaned or dried bones, cleaned or dried horns, claws or hoofs. NOTE: Dry bones divested of fat, not giving off any pu­ trid odour, are not subject to the provisions of ADR. 4 ° Fresh calf rennets, cleansed of all traces of edible matter. NOTE: Dried calf rennets not giving off an offensive odour are not subject to the provisions of ADR. 5 ° Compressed residues arising from the manufacture of skin glue (calcareous residues, residues from the liming of skin clippings, or residues used as fertilizers). 6 ° Non - compressed residues arising from the manu­ facture of skin glue. 7 ° Non - infected urine protected against decomposi tion. 8° Anatomical pieces, entrails and glands. (a) non - infected (b) infected 9° Manure 10 ° Excrement 11 ° Other animal subst.ances, repugnant or liable to cause infection, not already specifically mentioned in 1 ° to 10°. 12 ° Empty packagings and empty bags which have con­ tained substances of 1 ° to 8 °, 10 ° and 11 °, and sheets which have been used to cover substances of Class 6.2. NOTE: If ~ncleaned, these packagings, bags and sheets are not to be accepted for carriage. 2. Provisions A. Packages . 1: General conditions of packing ( 1) Packagings shall be so closed and leakproof as to pre­ vent any loss of the contents. (2) Packagings, including their closures, must be suffi­ ciently rigid and strong in all their parts to prevent any loos­ ening during carriage and to meet the normal requirements of carriage. In particular, where substances are in the liq­ uid state or are liab]e·to ferment, receptacles and their clo­ sures must, unless the section headed "Packing of a single substance" provides otherwise, be able to withstand any pressure which, the presence of air also being taken into account, may arise inside the receptacles in normal car­ riage. For this purpose a free space must be left, account being taken of the difference between the temperature of the substances at the time of filling and the highest mean temperature which they are likely to reach during carriage. (3) No trace of the contents must adhere to the outside of packages. 2. Packing of a single substance Substances of 1 ° shall be packed: (a) if forwarded otherwise than as a full load: 1. in metal receptacles fitted with a safety closure capa­ ble of yielding to internal pressure, or in casks, small vats or cases; or 2. in the case of substances of 1 ° (c) in the dry state, also in bags, on condition that the bad odour can be removed by disinfection. In the case of substances not in the dry state, packing in bags is allowed only from 1 November to 15 April; (b) if forwarded as a full load: 1. in the packagings specified in (a) 1. above; or 2. on condition that the bad odour can be removed by disinfection, in bags impregnated with suitable disinfec ~n~. • Substances of 2 ° shall be packed: (a) if forwarded otherwise than as a full load: 1. i;1 casks, small vats or cases; or 2652 2653 2654 2. during the months from November to February inclu­ sive, in bags impregnated with suitable disinfectants, on condition that the bad odour can be removed by disinfection; (b) if forwarded as a full load: 1. in the packagings specified in (a) 1. above; or 2. on condition that the bad odour can be removed by disinfection, in bags impregnated with suitable disinfec­ tants. Substances of 3 ° shall be packed in casks, small vats, cases, metal receptacles or bags. Substances of 4 ° shall be packed: (a) if forwarded otherwise than as a full load: in casks, small vats, cases, meta] receptacles or bags; (b) if forwarded as a full load: in any suitable packagings. Substances of 5" and 6 ° shall be packed in casks, small vats, cases or metal receptacles. Substances of 7 ° shall be packed in hermetically closed receptacles made of galvanized sheet-steel. • ( 1) Substances of 8 ° shall be packed in metal recepta­ cles fitted with a safety closure capable of yielding to inter­ nal pressure, in casks or small vats; substances of 8 ° (a) may also be packed in cases. (2) Substances of 8 ° may also be packed as follows: (a) substances of 8° (a),'in receptacles made of glass, porcelain, stoneware, metal or a suitable plastics material. .These r~ceptacles shall be placed, either singly or in groups, in a strong wooden case, with absorbent cushioning materials if the receptacles are fragile. If the substances to be carried are immersed in a preserving fluid, the absorb­ ent materials shall be sufficient in quantity to absorb all the fluid. The- preserving fluid must not be inflammable. Pack­ ages weighing more than 30 kg shall be fitted with means of handling; (b) substances of 8 ° (b ), in suitable receptacles placed with cushioning materials in a strong wooden case having a metal liriing rendered leakproof, e.g. by soldering. Pack­ ages weighing more than 30 kg shall be fitted with means of handling; Substances of 9° shall be forwarded only in bulk. Substances of 10 ° shall be packed in receptacles made of sheet-metal. Substances of 11 ° shall be packed in metal receptacles fitted with a safety closure capable of yielding to internal pressure, or in casks, small vats or cases. 3. Mixed packing Substances listed under an item number of marginal 2651 may be included in the same package only with sub­ stances listed under the same item number,and then only on condition that the packagings prescribed in sections A. l and 2 above are used. 4. Marking and danger labels on packages (see Appen­ dix A.9) Packages containing fragile receptacles not visible from the outside shall bear a label conforming to model No.12 ° If the fragile receptacles contain liquids, the packages shall, in addition, except in the case of sealed ampoules, bear labels conforming to model No.11; these labels shall be affixed high up on two opposite sides of cases or in an equivalent manner when other packagings are used. B. Particulars in the transport document The description of the goods in the transport document must conform to one of the names underlined in marginal 2651. Where the name of the substance is not indicated, the trade name must be used. The description of the goods must be underlined and followed by particulars of the Class, the item number (together with the letter, if any), and the initials "ADR" or "RID" [e.g. 6.2, 1 ° (a), ADR]. 2655 2656 2657 2658 2659 2660 2661 2662 2663 2664 2665 2666 2667 2672 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI .6EYTEPO) C. Empty packagings (1) Articles of 12 ° shall be cleaned and treated with suitable disinfectants. (2) The description in the transport document must be: "Empty packaging (or empty bag, or sheet), 6.2, 12 °, ADR (or RID)". This description must be underlined. Class 7 RADIOACTIVE SUBSTANCES Introduction (1) Scope (a) Among the substances with a specific activity of more than 7 4 kBq/kg (0.002 microcurie per gramme) and arti­ cles containing such substances, onlv those indicated in the schedules of marginal 2703 are to b~ accepted for carriage and then only under the conditions set out in the appropri­ ate schedules of the said marginal and in Appendix A.6 (marginals 3600 to 3699). (b) The substances and articles referred to in (a) are sub stances and articles of ADR . NOTE: Cardiac pacemakers containing radioactive sub­ stances, when they have been surgically implanted in medi­ cal patients, or radiopharmaceuticals being carried inside patients in the course of medical treatment, are not subject to ADR. (2) Definitions and explanations A1 and A2 . "A1" means the maximum activity of special form radio­ active substances permitted in a Type A package. "A" means the maximum activity of radioactive substancls, ?ther than special form radioactive substances, permitted m a Type A package. These values either are listed in Ap­ pendix A.6 Table XX or may be derived in accordance with the procedure described in marginals 3690 and 3691 of Appendix A.6. Allowable number of packages "Allowable number11 of packages" means the maximum nui:nber of Fissile Class II or Fissile Class III packages which may be grouped together in one place during car­ riage or during transit storage. Containment system "Containment system" means the components of the packaging specified by the designer as intended to retain the radioactive substance during carriage. Design "Design" means the description of a special form sub­ stance, or of a package or a packaging of a particular kind, which enables it to be fully identified. The description may include specifications, engineering drawings, reports dem­ onstrating compliance with regulatory requirements, and other relevant documentation. Fissile substances "Fissile substance" means plutonium-238, plutoniurn 239, plutonium-241, uranium-233, uranium-235, and all substances containing any of these radionuclides. Unirradiated natural and depleted uranium do not c.ome under this definition. Low-level solid radioactive substances "Low-level solid radioactive substance" (LLS) means any of the following: (a) Solids (e.g. consolidated wastes, activated sub­ stances) in which: I/ Wh~n the group is made up of packages of different designs, the maximum number of packages shall be such that the following formula is satisfied: ~ + ~ + ~ + .... shall not exceed 1. In this formula, nl' Nl N2 N3 nl(, n3 ... are the numbers of package; for which the corresponding allowable numbers are Ni' N2, N3 ... respectively. 2673 2674 2699 2700 (i) the ~ctivity in normal carriage is and remains distrib­ uted throughout the solid or the collection of solids or is and remains uniformly distributed in a solid compact bind­ ing agent (such as concrete, bitumen, ceramic); (ii) the activity is and remains insoluble so that even under loss of packaging the loss of radioactive substance per package resulting from the effects of wind, rain, etc., of from total immersion in water is limited to less than 0.1 ~ in a period of one week; and (iii) the activity averaged throughout the radioactive sub­ stance does not exceed 2x10-3 A/g. (b) Articles of non-radioactive substance which are con­ taminated with a radioac tive substance, provided that the radioactive contamination is in a non-readily0dispersible form and· that the level of contamination averaged over 1 m2 ( or over the area of the surface if that area is less than 1 m2) does not exceed: 740 kBq/cm2 (20µCi/cm 2 ) for beta and gamma emit­ ters and the low-toxicity alpha emitters indicated in Table XIX of Appendix A.6; and· 74 k Bq/cm2 (2 µCi/cm2) for other alpha emitters. Low specific activity substances. (I) "Low specific activity substances (I)" (LSA) means any of the following: • (a) Uranium or thorium ores and physical or chemical concentrates of those ores: (b) Unirradiated natural or depleted uraniu!]1. or unirradiated natural thorium; (c) Tritium oxide in aqueous solutions, provided that the concentration does not exceed 0.37 TBq/1.(10 Cijlitre); (cl) Substances in which the activity is uniformly distrib­ uted and which if they were reduced to their minimum vol­ ume in conditions likely to be encountered in carriage, such as dissolution in water with subsequent n•rrystallizati"on; precipitation; evaporation; combustion; abrasion; etc., would have an average specific· activity of not more than 10-4 A/ g; . : (e) Articles on non-radioactive substance which are con­ taminated with a radioactive substance, provided that the non-fixed surface contamination does not exceed 10 times • the values in Table XIX of Appendix A.6 and that the con­ taminated article or the contamination on the article, if it was reduced.to its minimum volume in conditions likely to be encountered in carriage, such as dissolution in water with subsequent recrystallization; precipitation; evapora­ tion; combustion; abrasion; etc., would have an average specific activity of not more than 10-4 A/g. Low specific activity substances {II) "Low specific activity substances (II)" (LSA) means any of the following: (a) Substances in which the activity in normal carriage is and remains uniformly distributed and in which the aver­ age specific activity does not exceed 10-4 A/ g; (b) Articles of non-radioactive substance which are con­ taminated with a radioactive substance, provided that. the radioactive contamination is in a non-readily-dispersible form and that the level of contamination averaged over 1 m2 ( or over the area of the surface if that area is less than 1 m2) does not exceed • 37 kBq/cm2 (1 µCi/cm2) for beta and gamma emitters and the low-toxicity alpha emitters indicated in Table XIX of Appendix A.6; and 3. 7 kBq/cm2 (0.1 µCijcm2) for other alpha emitters. Maximum normal operating pressure "Maximum normal operating pressure" means the max­ imum pressure above atmospheric pressure at mean sea­ level that would develop in the containment system in ape­ riod of one year in conditions of temperature and solar ra­ diation corresponding to environmental conditions of transport in the absence of venting, external cooling by an ancillary system, or operational controls during car­ riage. 963 964 ECJ>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: .6EYTEPO) Multilateral approval "Multilateral approval" means approval by the compe-.. tent authority of the country of origin and by the competent authority of each country in whose territory the consign­ ment is to be carried. Package "Type A package" means a type A packaging together with its limited radioactive contents. As the contents of a Type A package are limited to A 1 or A 2 , such a package does not require approval by the competent authority. "Type B(U) package'1 means a Type B packaging, to­ gether with its radioactive ~ontents, which since it is de­ signed in accordance with specified design and contain­ ment criteria requ'ires unilateral approval only of the pack­ age design and of any stowage provisions that may be nec­ essary for heat dissipation. "Type B(M) package" means a Type B packaging, to­ gether with.its radioactive contents, which since its design fails to meet one or more of the specific additional design criteria for Type B(U) packages (see marginal 3603 of Ap­ pendix A.6) requires multilateral approval of the package design and, in.certain circumstances, of the conditions of despatch. • Packaging "Packaging" means the assembly of components neces­ sary to ensure compliance with the packaging require­ ments of this Class. It may, in particular, consist of one or more receptacles, absorbent materials, spacing structures, radiation shielding, and devices for cooling, for absorbing mechanical shocks and for thermal insulation. These de­ vices may include the vehicle with the tie-down system when these are intended to form an integral part of the packaging. "Type A packaging" means a packaging which in nor­ mal carriage is able to prevent any loss or dispersal of the radioactive content and to retain its shielding function. The conditions of normal carriage shall be reproduced by the tests prescribed in marginal 3635 and 3636 of Appendix A.6, which tests the packaging shall be shown to have passed. "Type B packaging" means a packaging which is able to withstand not only the conditions of normal carriage, as a Type A packaging does, but also a transport accident. The conditions of such an accident shall be reproduced by the tests prescribed in marginals 3635 to 3637 of Appendix A.6, which tests the packaging shall be shown to have passed in the conditions likewise prescribed. • Radiation level "Radiation level" means the corresponding radiation dose equivalent rate expressed in millirem per hour. Radi­ ation levels may be determined by instruments, combined with the use of conversion tables where necessary or by cal­ culation. Measured or calculated neutron flux densities may be converted into radiation levels by using the date given in the following table. Neutron flux densities to be regarded as equivalent to a radiation level of 10 µSv/h (1 mrem/h) Energy of neutron Thermal 5 keV 20 keV 100 keV 500 keV 1 MeV 5 MeV 10 MeV Flux density equivalent to 10 µSv/h (l mrem/h) (neutrons/cm2•s) . 268 228 112 32 12 7.2 7.2 6.8 Note: Equivalent flux densities for energies between those listed above should be obtained by linear interpola­ tion. Radioactive contents "Radioactive contents" means the radioactive substance together with any contaminated solids, liquids or gases in the package. Special form radioactive substance "Special form radioactive substance" means either a non-dispersible solid radioactive substance or a sealed capsule containing a radioactive substance. The sealed capsule shall be so constructed that it can be opened only by destroying it. The special form radioactive substance shall meet the following requirements: (a) It shall have at least one dimension of not less than 5 mm; and (b) It shall comply with the relevant test requirements specified in marginals 3640 to 3642 of Appendix A.6. In general, the "special form" concept enables sub­ stances exhibiting a higher activity level to be included in a Type A package. Speci.fic activity The "specific activity" of a radionuclide means that radionuclide's activity per unit mass. The specific activity of a substance in which the radionuclides are essentially uniformly distributed is that substance's activity per unit mass. Transport index The "transport index" of a package means: (a) The number expressing the maximum radiation level in millirem per hour at 1 m from the external surface of the package; or (b) In the case of packages of Fissile Class II or Fissile Class III, the higher of the following numbers: the number expressing the maximum radiation level as under (a) above; and the number obtained by dividing 50 by the allowable number of such packages. The "transport index" of a container means either; the sum of the transport indices of all packages within the container, except that for containers carrying Fissile Class III packages, the transport index shall be 50 unless the sum of the transport indices of the packages necessi­ tates a higher figure. or for containers not carrying Fissile Class II or III pack­ ages and under full load, the number expressing the maxi­ mum radiation level in millisievert per hour (mSv /h) multi­ plied by 100 or in mrem/h at 1 m from the external sur­ face of the container multiplied by the value in the follow­ ing table appropriate to the maximum cross-sectional area of the container. Multiplication factors Size of load Measurement • Multiplication factor (cross-sectional area measurements of the load perpendic­ ular to the direction of interest). 1 m2 and less 1 > 1 m2 to 5 m2 3 > 5 m2 to 20 m2 6 > 20 m2 to 100 m2 19 (c) The figure expressing the transport index shall be rounded upwards to the first decimal place. Uncompressed gas "Uncompressed gas" means a gas at a pressure not ex­ ceeding the ambient atmospheric pressure at the time when the containment sytem is closed. E<DHMEPII THI KYBEPNHIEQI (TEYXOI 6EYTEPO) Unilateral approval "Unilateral approval" means approval by the competent authority of.the country of origin only. If the country of ori­ gin is not a party to ADR, the approval shall require valida­ tion by the competent authority of the first ADR country reached by the consignment. 'Unirradiated uranium "Unirradiated uranium" means uranium containing not more than 10-6 g plutonium per g uranium-235 and a fis­ sion product activity of not more than 9.3 MBq (0.25 mCi) per g uranium -235. Unirradiated thorium "Unirradiated thorium" means thorium containing not more than 10·7 g of uranium -233 per g of thorium-232. Uranium; natural, depleted, enriched "Natural uranium" means chemically - separated ura­ nium with the naturally - occurring distribution of uranium isotopes (approximately 99.28 per cent uranium - 238 and 0. 72 per cent uranium - 235). "Depleted uranium" means uranium containing less than 0. 72 per cent uranium - 235, the remainder being uranium - 238. "Enriched uranium" means uranium containing more than 0. 72 per cent ura­ nium - 235, the remainder being uranium - 238. In all cases a very small amount of uranium - 234 is present. (3) Prohibitions on mixed loading Substances of Class 7 contained in packages bearing a label conforming with models Nos. 7 A, 7B or 7C shall not be loaded in the same vehicle together with substances and articles of Classes la ( marginal 2101 ), 1 b ( marginal 2131) or le (marginal 2171) contained in packages bearing one or two labels conforming with model No. 1. The substances and articles of this Class contain one or more of the radionuclides referred to in section VI of Ap­ pendix A.6 (marginals 3690 and 3691). The list hereunder specifies the different types of con­ signment: 1. Empty packages which have contained radioactive substances; 2. Articles manufactured from natural or depleted ura nium or natural thorium; 3. Small quantities of radioactive substances; 4. Instruments and manufactured articles; 5. Low specific activity substances LSA (I); 6. Low specific activity substances LSA (II); 7. Low - level solid radioactive substances; 8. Radioactive substances in Type A packages; 9. Radioactive substances in Type B(U) packages; 10. Radioactive substances in Type B(M) packages; 11. Fissile substances; 12. Radioactive substances carried under special ar­ rangement. Schedule 1 Danger labels on packages. None NOTE: Any label indicating a danger shall be covered or removed. 1. Substances Empty packages: which have contained radioactive sub­ stances. 2. Packaging/Package (a) Packaging shall be in accordance with the require­ ments given in marginal 3600 of Appendix A.6, and shall be securely closed and in good condition. (b) Permitted internal contamination levels: not more than 100 times those levels set out in paragraph 5. (c) Where an empty packaging includes natural or de­ pleted uranium or natural thorium in its structure, its sur­ face shall be covered with a substantial, inactive sheath made of metal or some other resistant material. • 3. Package maximum radiation level ' 5µ::3v/h (0.5 mrem/h) al the surface or the packni!<'. • 2701 2702 2703 4. Mixed packing No provisions. 5. Contamination on packages Non - fixed external contamination limits: Beta/gamma/low - toxicity alpha emitters 3. 7Bq/ cm2 (10·4 µCi/ cm2) Natural/depleted uranium/ natural thorium 37 Bq/cm2 (10·3 µCijcm 2) Other alpha emitters 0.37 Bq/cm2 (10·5 µCijcm2 ) For full details, see marginal-3651 of Appendix A.6. 6. Marking on packages . (a) Packages shall be plainly and durably marked with the mass if over 50 kg. (b) Any marking indicating a radioactive danger shall not be visible. 7. Transport documents The transport document shall include the description "Radioactive substances (Empty packages), 7, schedule 1, ADR", with the name underlined. 8. Storage and despatch No provisions. 9. Carriage of packages in vehicles and containers No provisions. 10. Carriage in bulk in vehicles and containers Not app-i.icable. 11. Carriage in tank vehicles and tank containers Not applicable. 12. Placards and labels on vehicles, tank vehicles, tank' containers and containers None. 13. Prohibitions on mixed loading No provisions. 14. Decontamination of vehicles, tank vehicles, ·tank containers and containers No provisions. 15. Other provisions None. Schedule 2 Danger labels on packages. None. 1. Substances • Articles manufactured from natural or depleted uranium or natural thorium. The outer surface of. the uranium or thorium shall be covered by a substantial, inactive sheath made of metal or some other resistant material. NOTE: Such articles may, for example, be unused packagings intended for the transport of radioactive substances. 2. Packaging/Package Packaging shall be in accordance with the requirements given in marginal 3600 of Appendix A.6. 3. Package maximum radiation level 5 µSv /h (0,5 mrem/h) at the surface of the package. 4. Mixed packing • No provisions. 5. Contamination on packages Non - fixed external contamination limits: Beta/ gamma/lo\\'. - toxicity alpha emitters 3.7 Bq/cm2 (104 µCijcm2) Natural/depleted uranium/ natural thorium 37 Bq/cm2 (10·3 µCi/cm 2) Other alpha emitters 0.3.7 Bq/cm2 (10·5 µCijcm 2) For full details see marginal 3651 of Appendix A.6. 6. Marking on packages None. 7. Transport documents The transport document shall include the description 965 966 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) "Radioactive substances (Manufactured articles), 7, schedule 2, ADR", with the name underlined. 8. Storage and despatch No provisions. 9. Carriage of packages in vehicles and containers No provisions. 10 .. Carriage in bulk in vehicles and containers Not applicable. 11. Carriage in tank vehicles and tank containers Not applicable. 12. Placards and labels on vehicles, tank vehicles, tank a containers and containers None. 13. Prohibitions on mixed loading No provisions. 14. Decontamination of vehicles, tank - vehicle&, tank containers and containers No provisions. 15. Other provisions None. Schedule 3 Danger labels on packages. None (but see paragraph 15). 1. Substances Small quantities of radioactive substances in amounts which do not exceed those given in the table below and which do riot contain more than 15 g of uranium - 235. Nature of Package substances limits Solids and gases Special form Other forms Tritium Liquids Tritium oxide in aqueous solutions less than 3.7 GBq/1 10·3 A lQ•3 I 0.74 TBq (20 C~ (0.1 Cijl) 37 TBq (1000 Ci) between 3. 7 GBq/1 and 37 GBq/1 (0.1 Cijl and 1.0 Ci/1) 3.7 TBq (100 Ci) greater than 3 7 GBq/1 (1.0 Ci/1) 37 GBq (1 Ci) Other liquids 10·4 A For mixtures of radionuclides, see marginal 3691 oT Appendix A.6. 2. Packaging/Package (a) Packaging shall be in accordance with the requirements given in marginal 3600 of Appendix A.6. (b) During transport there shall be no leakage of radioactive substance. 3. Package maximum radiation level 5 µSv /h (0.5 mrem/h) at the surface of the package. 4. Mixed packing No provisions. 5. Contamination on packages Non - fixed external contamination limits: Beta/ gamma/low - toxicity alpha emitters 3.7 Bq/cm2 (10·4 µCi/cm2) Natural/depleted uranium/ natural thorium 37 Bq/cm2 (10·3 µCi/cm 2) • The values for tritium also apply to tritium in activated luminous paint and tritium absorbed on solid carriers. Other alpha emitters 0.37 Bq/cm2 (10·5 µCi/cm2) For full details, see marginal 3651 of Appendix A.6. 6. Marking on packages The outermost surface of the containment system shall be marked "RADIOACTIVE" as a warning on opening the package. 7. Transport documents The transport document shall include the description "Radioactive substances (Small quantities), 7, schedule 3, ADR", with the name underlined. 8. Storage and despatch No provisions. 9. Carriage of packages in vehicles an? containers No provisions. 10. Carriage in bulk in vehicles and containers Not permitted. 11. Carriage in tank - vehicles and tank - containers Not permitted. 12. Placards and labels on vehicles, tank - vehicles, tank containers and containers None. 13. Prohibitions on mixed loading No provisions. 14. Decontamination of vehicles, tank - vehicles, tank containers and containers See marginal 3695 (3) of Appendix A.6. 15. Other provisions (a) Accident provisions - see marginal 3695 (1) of Appendix A.6. (b) Decontamination in storage - see marginal 3695 (2) of Appendix A.6. (c) Radioactive substances which possess other hazardous properties shall also comply with the provisions of the appropriate class. Schedule 4 Danger labels on packages None 1. Substances Instruments and manufactured articles such as clocks, electronic tubes or apparatus, having radioactive substances as a component part, whose activity does not exceed the amounts given in the table below and which do not contain more than 15 g. of uranium - 235. Nature of Item Package substances limits limits Solids Special form 10-2 Al Al Other forms 10·2 A2 A2 Liquids 10-3 A2 10·1 ~ Gases Tritium 0.74 TBq 7.4 TBq (20 Ci)* (200 Ci)* Special form 10·3 Al 10-2·Al Other forms 1Q·3 A2 10·2 A 2 For mixtures of radionuclides, see marginal 3691 of Appendix A.6. 2. Packaging/Package (a) Packaging shall be in accordance with the requirements given in marginal 3600 of Appendix A.6. • The values, for tritium also apply to tritium in activated luminous oaint and tritium absorbed on solid carriers. E<l>HMEPII THI KYBEPNHIEQI (TEYXOI L.\EYTEPO) (b) The instruments and articles shall be securely packed. 3. Package maximum radiation level 5 µSv /h (0.5 mrem/h) at the surface of the package and 100 µSv/h (10 mrem/h) at 10 cm from any point on the external surface of any unpacked instrument or article. 4. Mixed packing No provisions. 5. Contamination on packages Non - fixed external contamination .limits: Beta/ gamma/ low - toxicity alpha emitters 3. 7 Bq/ cm2 (10·4 µCi/ cm2) Natural/depleted uranium/ natural thorium 37 Bq/cm2 (10·3 µCi/cm 2) Other alpha emitters 0.37 Bq/cm2 (10·5 µCijcm 2) For full details, see marginal 3651 of Appendix A.6. 6. Marking on packages Each instrument or article (except radioluminescent timepieces or devices) shall bear the marking "RADIOACTIVE". • 7. Transport Documents The transport document shall include the description "Radioactive substances (Instruments) or (Manufactured articles),?, schedule 4, ADR", with the name underlined. 8. Storage and despatch No provisions. 9. Carriage of packages in vehicles and containers No provisions. 10. Carriage in bulk in vehicles and containers Not applicable. 11. Carriage in tank - vehicles and tank - containers Not applicable. 12. Placards and labels on vehicles, lank - vehicles, tank c-ontainers and containers None. 13. Prohibitions on mixed loading No provisions. 14. Decontamination of vehicles, tank vehicles, tank containers and containers • See marginal 3695 (3) of Appendix A.6. 15. Other provisions (a) Accident provisions.- see marginal 3695 (1) of Appendix A.6. (b) Decontamination in storage - see marginal 3695 (2) of Appendix A.6. Schedule 5. Danger labels on packages (see Appendix A. 9). 1. Substances Low specific activity substances LSA(l), belonging to one of the following groups as defined fully in marginal 2700(2): (i) uranium or thorium ores or c6ncentrates (sub-para. (a) of definition) (ii) unirtadiated natural or depleted uranium or unirradiated natural thorium (sub-para. (b) of definition) (iii) tritium oxide in aqueou·s solutions - concentration 0.3 7 TBq/1 (10 Ci/1) or less. (sub-para (c) of definition) (iv) substances with uniform activity under minimum volume conditions of not more .than 10·4 A/g (sub-para. (cl) of definition). (v) Non - radioactive articles contaminated to not more than 10 times the package limits set in para 5 below and so that the specific activity under minimum volume conditions never exceeds 10·4 A/g (sub-para. (e) of definition). Unless transported as a full load, labels to models 7 A, 7B or 7C shall be affixed externally to two opposite sides, see marginals 3653 to 3655 of Appendix A.6 for package category. The contents shall be described on the labels as "Radioactive LSA". Subsidiary labelling: (i) for thorium nitrate, solid, and uranium nitrate, solid model No.5 labels are required. (ii) for uranium hexafluoride and uranyl nitrate hexahydrate in solution: model No.8 labels are required. If fissile substances are present the requirements of schedule II shall be met in addition to the requirements of this schedule. 2. Packaging/Package Packages transported other than as full load: packaging shall be in accordance with the requirements of marginal 3600, marginal 3650 to 3655 and marginal 3656(1) to (4) of Appendix A.6. Substances of paragraph l(ii) above in massive solid form shall be packed so as to prevent abrasion, and in other solid forms shall be contained in a substantial sheath. 3. Package maximum radiation level 2 mSv /h (200 mrem/h) at the surface of the package and 0.1 mSv/h (10 mrem/h) at 1 metre from that surface (see marginals 3653 lo 3655 of Appendix A.6). Except in the case of a full load when the limit is 10 mSv /h (1,000 mrem/h) at the surface of the package and may exceed 0.1 mSv/h (10 mrem/h) at 1 metre from that surface (see marginal 3659(7) of Appendix A.6). 4. Mixed packing • See marginal 3650 of Appendix A.6. 5. Contamination on packages (a) Non-fixed external contamination limits for packages carried other than as full load. Beta/ gamma/low-toxicity alpha emmiters 3.7 Bq/cm2 (10 •4 µCi/cm2) Natural/depleted uranium/ natural thorium 3 7 Bq/cm2 (10·3 µCijcm 2) Other alpha emitters 0.37 Bq/cm2 (10·5 µCi/cm 2 For full details, see marginal 3651 of Appendix A.6. (b) For packages carried in a full load - No provisions. 6. Marking on packages .Packages transported as full load - stencilled or otherwise marked "RADIOACTIVE LSA". Packages transported other than full load - plainly and durably marked with the mass if over 50 kg. • 7. Transport documents The transport document shall include the description "Radioactive substances (Low specific activity LSA (I)), 7, schedule 5, ADR", with the name underlined and the details specified in marginals 3680 and 3681 of Appendix A.6. 8. Storage and despatch (a) Storage and segregation from other dangerous goods see marginal 365.8 (1) of Appendix A.6. (b) Storage and segregation from packages labelled "FOTO" - see marginal 240001 of Appendix B.4 for segregation table. • (c) Total tra~sport index limitation for storage, no limit except in the case of Fissile Class II or III packages, see marginal 3658 (2) tp (5) of Appendix A.6.). 9. Carriage of packages in vehicles and containers (a) Segregation from packages labelled "FOTO" - see marginal 240001 of Appendix B.4 for segregation table. (b) Total transport index limitation - 50. This limit does not apply to a full load, provided that if Fissile Class II or III packages are present the allowable number is not exceeded, (see marginal 3659(5) of Appendix A.6). (c) Maximum radiat10n levels for vehicles and large containers in the case of a full load 2 mSv /h (200 mrem/h) al surface 0.1 mSv/h (10 mrem/h) at 2 metres from surface (see marginal 3659(7) of Appendix A.6) Also, for vehicles - 20 µSv /h (2 mrem/h) in any normally occupied position. (see marginal 3659(8) of Appendix A.6.). 967 2703 ECDHMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) (d) Packages not in conformity with the requirements of marginal 3600 shall be transported as full load, and the limits in the following table shall not be exceeded: Nature of substances Solids Tritium oxide in aqueous solutions Other liquids and gases Vehicle or large container activity limit No limit 1 850 TBq (50,000 Ci) 100 X A2 10. Carriage in bulk in vehicles and containers Permitted under full load provided that, after loading, external surfaces of vehicles are carefully cleaned by the consignor and provided that no leakage can occur under normal transport. Quantity limits as in the t~ble in paragraph 9 above. 11. Carriage in tank-vehicles and tank-containers (a) Carriage in tank-vehicles: permitted for liquids or solids other than uranium hexafluoride and substances liable to spontaneous ignition (see Appendix A.6, marginal 3660); • (b) Carriage in tank-containers: permitted for liquids or solids, including natural or depleted uranium hexafluoride (see Appendix A.6, marginal 3661). 12. Placards and labels on vehicles, tank vehicles, tank containers and containers (see Appendices A. 9 and B.4). Containers - labels to models 7 A, 7B or 7C on all four sides. Vehicles and large containers - placards to model 7D in Appendix B.4 marginal 240 010 on each lateral side and on rear wall of vehicle (see marginals 3659(6) and 71 500). Subsidiary labelling (i) for thorium nitrate, solid and uranyl nitrate, solid model No. 5 labels are required. (ii) for ·uranium hexafluoride and uranyl nitrate hexahydrate in solution - model No. 8 labels are required. (iii) for substances· exhibiting an additional dangerous property and carried as a complete load - appropriate danger label required. 13. Prohibitions on mixed loading See marginal 2700(3). • 14,. Decontamination vehicles, tank vehicles, tank containers and containers (a) For full load consignments, after unloading, vehicles to be decontaminated by the consignee to the levels in Table XIX of Appendix A.6 unless to be used for carrying the same substances. See also marginal 3695(4) of Appendix A.6. (b) For non-full load consignments, see marginal 3695(3) of Appendix A.6. 15. Other provisions (a) Accident provisions - see marginal 3695(1) of Appendix A.6. • (b) Decontamination in storage - see marginal 3695(2) of Appendix A.6. Scheldule 6 Danger labels on packages None required unless fissile substances are present. (see Schedule 11). 1. Substances Low specific activity substances LSA(II) belonging to either of the following groups as defined fully in marginal 2700(2): (i) substances with uniform activity of not more than 104 A/g. (sub-para (a) of definition). (ii) non-radioactive articles contaminated non-dispersibly to a level not exceeding 37 kBq/cm2 (1 µCi/cm 2) for beta and gamma emitters and low toxicity alpha emitters, or 3. 7 kBq/cm2 (0.1 µCijcm 2) for other alpha emitters (sub-para (b) of definition). If fissile substances are present the requirements of schedule 11 shall be met in addition to the requirements of this schedule. 2. Packaging/Package Packaging shall be in accordance with the requirements of marginal 3600, marginal 3650 and marginal 3651 of Appendix A.6. 3. Package maximum radiation level Closed vehicles under conditions of marginal 3659(7) (a) of Appendix A.6 - 10 mSv/h (1000 mrem/h) at the surface of the package and may exceed 0.1 mSv/h (10 mrem/h) at one metre from that surface. All other vehicles not under the conditions of marginal 3659 (7)(a) of Appendix A.6 - 2 mSv /h (200 mrem/h) at the surface of the package and 0.1 mSv/h (10 mrem/h) at one metre from that surface. 4. Mixed packing See marginal 3650 of Appendix A.6. 5. Contamination on packages Non-fixed external contamination limits: Beta/gamma/low toxicity alpha emitters Natural/ depleted uranium/natural thorium Other alpha emitters 3.7 Bq/cm2 37 Bq/cm2 0.37 Bq/cm2 10·4 µCi/cm 2 10·3 µCi/ cm2 10·5 µCi/cm2 For full details, see marginal 3651 of Appendix A.6 Danger labels on packages None required unless fissile substances are present (see Schedule 11 ). 6. Marking packages Packages shall be stencilled or otherwise marked "RADIOACTIVE LSA". 7. Transport documents The transport document shall include the description "Radioactive substances (Low specific activity LSA (II)), 7, schedule 6, ADR", ~ith the name underlined, and the details specified in marginals 3680 and 3681 of Appendix A.6. • 8. Storage and despatch Only under full load 9. Carriage of packages in vehicles and containers (a) Carriage only by full load (b) If the consignment includes Fissile Class II or III packages the allowable number shall not be exceeded. (see Schedule 11 ). (c) Maximum radiation levels for vehicles and large containers 2 mSv/h (200 mrem/h) at surface, 0.1 mSv/h (10 mrem/h) at 2 metres from surface (see marginal 3659(7) of Appendix A.6) Also, for vehicles - 20 iiSv /h (2 mrem/h) in any normally occupied position - (see marginal 3659(8) of Appendix A.6) (d) The limits in the following table shall not be exceeded: Nature of substances Solids Tritium oxide in aqueous solutions Other liquids and gases Vehicle or large container activity limit No limit 1850 TBq (50000 Ci) 100 X A2 10. Carriage in bulk in vehicles and containers Not permitted. 11. Carriage in tank vehicles and tank containers Not permitted. 12. Placards and labels on vehicles, tank vehicles, tank containers and containers (see Appendices A.9 and B.4) Cl>EK 104 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) Containers - labels to 7 A, 7B or 7C on all four sides: Vehicles and large containers - placards to model in Appendix B.4, marginal 240 010 on each lateral side and on rear wall of vehicle (see marginals 3659(6) and 71 500). 13. Prohibitions on mixed loading See marginal 2700(3). 14. Decontamination of vehicles, tank vehicles, tank containers and containers See marginal 3695(3) and (4) or Appendix A.6. 15. Other provisions Accident provisions - see marginal 3695 (1) of Appendix A.6. Schedule 7 Danger labels on packages. None required unless fissile substances are present (see Schedule 11 ). 1. Substances Low level solid radioactive substances LLS belonging to either of the following groups as defined fully in marginal 2700(2): (i) substances with uniform activity of not more than 2 X 10·3 A/g. (sub para (a) of definition). (ii) non-radioactive articles contaminated to a level not exceeding 740 kBq/cm2 (20 µCi/cm 2 ) for beta and gamma emitters and low toxicity alpha emitters or 7 4 kBq/ cm2 (2 µCi/cm 2 for other alpha emitters. (sub-para (b) of definition). If fissile substances are present, the requirements of schedule 11 shall be met in addition to the requirements of this schedule. 2. Packaging/Package (a) Packaging shall be in accordance with the requirements of marginals 3600 and 3650 of Appendix A.6 and shall be capable of withstanding the tests set out in marginal 3635(4) and (5) of Appendix A.6. (b) Under the conditions of the tests set out in (a), there shall be • (i) no loss or dispersal of the radioactive contents (ii) no increase of the maximum radiation level recorded or calculated at the external surface for the condition before the test. 3. Package maximum radiation level Closed vehicles under conditions of marginal 3659(7) (a) of Appendix A.6 - 10 mSv/h (1000 mrem/h) at the surface of the package and may exceed 0.1 mSv/h (10 mrem/h) at one metre from that surface. All other vehicles not under the conditions of marginal 3659(7) (a) of Appendix A.6 - 2 mSv /h· (200 mrem/h) at the surface of the package and 0.1 mS\//h (10 mrem/h) at one metre from that surface. 4. Mixed packing See marginal 3650 of Appendix A.6. 5. Contamination on packages No provisions. 6. Marking on packages Packages shall . be stencilled or otherwise marked "RADIOACTIVE LLS". 7. Transport documents The transport document shall include the description "Radioactive substances (Low - level solid (LLS), 7, schedule 7, ADR", with the name underlined, and the details specified in marginals 3680 and 3681 of Appendix A.6. 8. Storage and despatch Only under full load. 9. Carriage of packages in vehicles and containers (a) Carriage only by full load (b) If the consignment contains Fissile Cla'l!'I II or rn packages the allowable number shall not be exceeded (see schedule 11 ). (c) Maximum radiation levels for vehicles and large containers. 2 mSv /h (200 mrem/h) at surface 0.1 mSv /h (10 mrem/h) at 2 metres from surface see marginal 3659(7) of Appendix A.6. Also, for vehicles 20µSv /h (2 mrem/h) in any normally occupied position - see marginal 3659(8) of Appendix A.6. 10. Carriage in bulk in vehicles and containers Not permitted. 11. Carriage in tank vehicles and tank containers Not applicable. ,., 12. Placards and labels on vehicles, tank vehicles, tank containers and containers (see Appendices A.9 and B.4) Containers - labels to model 7 A, 7B or 7C on all four sides. Vehicles and large containers - placards to model 7D in Appendix B.4, marginal 240 010 on each lateral side and on rear wall of vehicle (see marginals 3659(6) and 71 500). 13. Prohibitions on mixed loading . See marginal 2 700(3). 14. Decontamination of vehicles, tank vehicles, tank containers and containers After unloading, vehicles to be contaminated by the consignee to the level set in Tal:1le XIX of Appendix A.6 unless to be used for carrying the same substances. See also marginal 3695(3) and (4) of Appendix A.6. 15. Other provisions Accident provisions - see marginal 3695 (1) of Appendix A.6. Schedule 8 Danger labels on packages (see Appendix .A.9.) Labels to models 7 A, 7B or 7C shall be affixed externally to two opposite sides, see marginalst 3653 to :3655 of Appendix A. 6 for package category. 1. Substances Radioactive substances in Type A packages··up.to· an activity per package of A 2 or A 1 if in special form. If fissile substances are present the requirements of schedule 11 shall be met in addition to the requirements of this schedule. 2. Packaging/Package Type A, in accordance with the design .requirements given in marginals 3600 and 3601 of Appendix A.6. 3. Package maximum radiation level 2 mSv/h (200 mrem/h) at the surface of the package and 0.1 mSv/h (10 mrem/h) at 1 metre from that surface (see marginals 3653 to 3655 of Appendix A.6). Except in the case of a full load, when the limit is 10 mSv/h (1000 mrem/h) at the surface of the package and may exceed 0.1 mSv/h (10 mrem/h) at 1 metre from that surface (see marginal 3659 (7) of Appendix A.6). 4. Mixed packing See Marginal 3650 of Appendix A.6. 5. Contamination on packages Non - fixed extremal contamination limits: Beta/gamma/ low - toxicity alpha emitters 3.7 Bq/cmi (10·4 µCi/cm 2 ) Natural/depleted uranium/natural thorium 37 Bq/cm2 (l 0·3 µCi/ cm2) Other alpha emitters 0.37 Bq/cm2 (10·5 µCijcm 2) For full details, see marginal 3651 of Appendix A.6 6. Marking on packages Packages shall be plainly and durably marked externally with • (i) "Type A" . (ii) the mass of the packag~, if over 50 kg. 969 970 Ed>HMEPII THI KYBEPNHIEQI (TEYXOI 4EYTEPO) 7. Transport Document (a) For a summary of the approval and notification requirements, see marginal 2704. (b) The transport document should include the description "Radioactive substances in Type A packages, 7, schedule 8, ADR", with the name underlined, and the details specified in marginals 3680 and 3681 of Appendix A.6. • (c) Whe re advantage is taken· of the increased activity per package permitted if the subtstance is in special form, the unilateral special form design approval certicate shall be in the co n signor's possesion befor the first shipment (see margina'i-"3671 of Appendix A.6.). "8. Storage and despatch (a) Storage and segregation from other dangerous goods see marginal 3658 (1) of Appendix A.6. (b) Storage and segregation from package labelled "FOTO" - see marginal 240 001 Appendix B.4 for segregation table. (c) Total transport index limitation for storage - 50 per group with 6 metres between groups - see marginal 3658 (2) to (5) of Appendix A.6. 9. Carriage of packages in vehicles and containers (a) Segregation from packages labelled "FOTO" - see marginal 240001 of Appendix B.4 for segregation tables. (b) Total transport index limitation - 50. This limitation does not apply to a full load, provided that if fissile class II or III packages are present the allowable number is not exceeded - see marginal :3659 (5) of Appendix A.6. (c) Maximum radiation level for vehicles and large containers in tht; case of a full load. 2 mSv /h (200 mrem/h) at surface 0.1 mSv/h (10 mrem/h) at 2 metres from surface See marginal 3659 (7) of Appendix A.6. Also, for vehicles - 20ii.Sv /h (2 mrem/h) in any normally occupied. position - see marginal 3659 (8) of Appendix A.6. 10. Carriage in bulk in vehicles and containers. Not applicable. 11. Carri.age in. tank vehicles and tank containers. Not applicable. 12. Placards and labels on vehicles, tank vehicles, tank containers and containeIB (see Appendices A. 9 and B.4) Containers - labels to model 7 A, 7B or 7C on all four sides. Vehicles and large containers - placards to model 7D in Appendix B.4 marginal 240 010 on each lateral side and on rear wall of vehicle (see marginals 3659(6) and 71 500). 13. Prohibition on mixed loading See marginal 2700 (3). 14. Decontamination of vehicles, tank vehicles, tank containers and containers. See marginal 3695(3) of Appendix A.6. 15. Other provisions (a) Accident provisions - see marginal 3695 (1) of Appendix A.6. (b) Decontamination in storage - see marginal 3695(2) of Appendix A.6. Schedule 9 Danger labels on packages (see Appendix A.9) Labels to models 7 A, 7B or 7C shall be affixed externally to two opposite sides. See marginals 3653 to 3655 of Appendix A.6 for package category. 1. Substances Radioactive substances in Type B (U) packages No limit on the quantity per package except as prescribed in the approval certificates. If fissile substances are present, the requirements of Schedule 11 shall be met in addition to the requirements of this Schedule. 2. Packaging/Package Type B(U), in accordance with the design requirements given in marginals 3600 to 3603 of Appendix A.6 requiring competent authority unilateral approval, see marginal 36 72 of Appendix A.6. 3. Package maximum radiation level 2 mSv /h (200 mrem/h) at the surface of the package and 0.1 mSv/h (10 mrem/h) at 1 metre from that surface. See marginals 3653 to 3655 of Appendix A.6. Except in the case of a full load, when the limit is 10 mSv/h (1000 mrem/h) of the surface of the package and may exceed 0.1 mSv/h (l0mrem/h) at 1 metre from that surface. See marginal 3659 (7) of Appendix A.6. 4. Mixed packing See marginal 3650 of Appendix A6 5. Contamination on packages· Non - fixed external contamination limits: Beta/gamma/low-toxicity alpha emitters 3.7 Bq/cm2 (104 ii.Ci/cm2 ). . Natural/depleted uranium/natural thorium 37 Bq/cm2 (10·3 ii.Ci/cm2). Other alpha emitters 0.37 Bq/cm2 (10-5 ii.Ci/cm2). For full details, see marginal 3651 of Appendix A.6. 6. Marking on packages Packages shall be plainly and durably marked externally with: (i) "TYPE B(U)". (ii) competent authority identification mark. (iii) the mass if over 50 kg. (iv) the trefoil symbol embossed or stamped on the outermost fire - and - water - resistant receptacle. 7. Transport documents (a) For a summary of the approval and notification requirements - see marginal 2704. (b) The transport document shall include the description "Radioactive substances in Type B(U) packages, 7, Schedule 9, ADR", with the name underlined, and the details specified in marginals 3680 and 3681 of Appendix A.6. (c) Unilateral package design approval certificate is required, see marginal 3672 of Appendix A.6. (d) Before the shipment of any package the consignor shall be in possession of all relevant approval certificates. (e) Before the first shipment of a particular design of package, if the activity is greater than 3 X 103A 2 or 3 X 103 A as appropriate, or 3 X 104Ci, whichever is tfie lower, the c~nsignor shall ensure that copies of the competent authority approval certificates have been supplied to the competent authorities of countries affected by the movement, see marginal 3682 (1) of Appendix A.6. (f) Prior to each shipment where the activity is greater than 3 X 103A2 or 3 X 103A1 as appropriate, or 3 X 104Ci, whichever is the lower, the consignor shall notify the competent authorities of all countries affected by the movement, preferably 15 days in advance as detailed in marginal 3682 of Appendix A.6. . (g) Where advantage is taken of the increased activity per package permitted because the substance is in special form (see paras. (e) and (f) above) a unilateral special form design approval certificate is required (see marginal 3671 of Appendix A.6). 8. Storage and despatch (a) Any instructions in the competent authority approval certificates must be observed (b) Storage and segragation from other dangerous goods see marginal 3658 (1) of Appendix A.6. (c) Storage and segregation from packages labelled "FOTO" - see marginal 240 001 Appendix B.4 for segregation table. (d) Total transport index limitation for storage - 50 per E<DHMEPII THI KYBEPNHIECI (TEYXOI aEYTEPO) group with 6 metres between groups - see marginal 3658 (2) to (5) of Appendix A.6. (e) The consignor shall have complied with the pre - use and pre - shipment requirements of marginal 3643 and 3644 of Appendix A.6. (f) The temperature of the accessible surfaces of the package shall not exceed 50° C in the shade unless transport is under full load conditions, in which case the limit is 82°C (see marginals 3602 (3) (b) and 3603 (8) of Appendix A.6). (g) If the average surface heat flux from a package exceeds 15 W /m2 then the package shall be transported as a full load. 9. Carriage of packages in vehicles and containers • (a) Segregation from packages labelled "FOTO" - see 240 001 of Appendix 8.4 for segregation table. (b) Total transport index limitation - 50. This limitation does not apply to a full load, provided that if Fissile Class II or III packages are present the allowable number is not exceeded. See marginal 3659(5) of Appendix A.6. (c) Maximum radiation levels for vehicles and large containers in the case of a full load. 2 mSv/h (200 mrem/h) at surface. 0.2 mSv/h (10 mrem/h) at 2 metres from surface. See marginal 3659 (7) of Appendix A.6. Also for vehicle - 20 µSv /h (2 mrem/h) in any normally occupied position - see marginal 3659 (8) of Appendix A.6. 10. Cariage in bulk in vehicles and containers (a) No applicable. 11. Carriage in tank vehicles and tank containers Not applicable. 12. Placards and labels on vehicles, tank vehicles, tank containers and containers (see Appendices A.9 and 8.4) Containers - labels to models 7 A, 78 or 7C on all four sides. Vehicles and large containers - placards to model in Appendix 84 marginal 240 010 on each lateral side and on rear wall of vehicle (see marginals 3659 (6) and 71 500). 13. Prohibition on mixed loading See marginal 2700 (3) 14. Decontamination of vehicles, tank vehicles, tank containers and containers See marginal 3695 (3) of Appendix A.6. 15. Other provisions (a) Accident provisions - see marginal 3695 (1) of Appendix A.6. (b) Decontamination in storage - see marginal 3695 (2) of Appendix A.6. Schedule 10 Danger labels on packages • (see Appendix A.9) Labels to models 7 A, 78 or 7C shall be affixed externally to two opposite sides. (See marginals 3653 to 3655 of Appendix A.6 for package category). 1. Substances Radioactive substances i~ Type B(M) packages. That is a Type B package design which fails to meet one or more of the specific additional requirements for Type B(U) packages (see marginal 3603 of Appendix A.6). No limit on the quantity per package except as prescribed in the approval certificate. If fissile substances are present the requirements of Schedule 11 shall be met in addition to the requirements of this schedule. 2. Packaging/Package Type B(M), in accordance with the design requirements given in marginal 3604 of Appendix A.6, requiring competent authority multilateral approval (see marginal 3673 of Appendix A.6). 3. Package maximum radiation level 2 mSv /h (200 mrem/h) at the surface of the package and 0.1 mSv /h .(10 mrem/h) at 1 metre from that surface. (See marginals 3653 to 3655 of Appendix A.6), except in the case of a full load, with the limit is 10 mSv/h (1000 mrem/h) at the surface of the package and may exceed 0.1 mSv /h (10 mrem/h) at 1 metre from that surface. See marginal 3659 (7) of Appendix A.6. 4. Mixed packing See marginal 3650 of Appendix A.6. 5. Contamination on packages Non - fixed external contamination limits: Beta/ gamma/low - toxicity alpha emitters 3. 7 Bq/ cm2 (10-4 µCi/ cm2). Natural/depleted uranium/natural thorium 37 Bq/cm2 (10·3 µCi/cm 2). • Other alpha emitters 0:37 Bq/cm2 (10·5 µCi/cm2 ). For full details, see marginal 3651 of Appendix A.6. 6. Marking on packages Packages shall be plainly and durably marked externally with: (i) "TYPE B(M)". (ii) competent authority identification mark. (iii) the mass of the package if over 50 kg. (iv) the trefoil symbol embossed or stamped on the outermost fire - and - water - resistant receptacle. 7. Transport documents (a) For a summary of the approval and notification requirements - see marginal 2704. (b) The transport document shall include the description "Radioactive substances in Type B(M) packages, 7, Schedule 10, ADR", with the name underlined, and the details specified in marginals 3680 and 3681 of Appendix A.6. (c) Multilateral package design approval certificates are required, (see marginal 3672 of Appendix A.6.). (d) If the package is designed to allow for continous venting or if the total activity of the contents exceed 3 X 103 A 2 or 3 X 103 A1 Aas appropriate, or 3 X 104Ci, whicnever is the lower, multilateral shipment certificates are required unless a competent authority • authorizes transport by a specific provision in its package design certificate (see marginal 3675 of Appendix A.6). (e) Where advantage is taken of the increased activity per package permitted if the substance is in special form (see par. (d) above (a unilateral special form design approval certificate is required (see marginal 3671 of Appendix A.6). (f) Prior to each shipment the consignor shall notify the competent authorities of all countries affected by the movement preferably fifteen days in advance as detailed in marginal 3682 (2) to (4) of Appendix A.6. (g) Before the shipment of any package, the consignor shall be in possession of all relevant approval certificates. 8. Storage ·and despatch (a) Any instructions in the competent authority approval certificates must be observed. (b) Storage and segragation from other dangerous goods see marginal 3658 (1) of Appendix A.6. ( c) Storage and segregation ffrom packages labelled "FOTO" - see marginal 240 001 Appendix B.4 for segregation table. . (d) Total transport index limitation for storage - 50 per group with 6 metres between groups - see marginal 3658 (2) to (5) of Appendix A.6. (e) The consignor shall have complied with the pre-use and pre-shipment requirements of marginal 3643 and 3644 of Appendix .A.6. • f) If the surface temperature· of the package exceeds 50°C in the shade the package shall be transported as a 971 2703 972 ECl>HMEPII THI KYBEPNHIEDI (TEYXOI 4EYTEPO) full load - see marginal 3602 (4) (b) of Appendix A.6. g) If the average surface heat flux from a package ex­ ceeds 15W /m2, then the package shall be transported as a full load. h) Packages specially designed to allow continuous ve­ nting - see marginal 3604 (2) of Appendix A.6 - shall· only be transported under full load. 9. Carriage of packages in vehicles and containers (a) Segregation from packages labelled "FOTO" - see marginal 240001 Qf 1ppendix B.4 for segregation table. (b) Total transport index limitation· 50; This-limitation does not apply to a full load, provided that if Fissile Class II or III packages are present the allowable number is not ex­ ceeded - see marginal 3659 (5) of Appendix A.6. c) Maximum radiation levels for vehicles and large co ntainers in the case of a full load: 2 mSv/h (200 mrem/h) at surface 0.1 mSv/h (10 mrem/h) at 2 metres from surface. See marginal 3659 (7) of Appendix A.6. Also for vehicles - 20 1-1Sv /h (2 mrem/h) in any nor­ mally occupied position - see marginal 3659 (8) of Ap­ pendix A.6. 10. Carriage in bulk in vehicles and containers Not applicable. 11. Carriage in tank-vehicles and tank-containers Not applicable. 12. Placards and labels on vehicles. tank-vehicles. lank­ containers and containers (See Appendix A. 9 and 8.4.) Containers - labels to model 7 A, 7B or 7C on all four si­ des. Vehicles and large containers - placards to model 4D in Appendix 8.4, marginal 240010, on each lateral side and on rear wall of vehicle (see marginals 3659 (6) and 71 500). 13. Prohibition on mixed loading See marginal 2700 (3). 14. Decontamination of vehicles, tank vehicles. tank co ntainers and containers See marginal 3695 (3) of Appendix A.6. 15. Other provisions (a) Accident provisions - see marginal 3695 (1) of Ap pendix A.6. • (b) Decontamination in storage - see marginal 3695 (2) of Appendix A.6. Schedule 11 Danger labels on packages (See Appendix A. 9). Fissile Class I - labels to models 7 A, 7B or 7C. Fissile Class II - labels to models 7B or 7C. Fissile Class III - labels to model 7C only. Labels to be affixed externally to two opposite sides, see marginals 3653 to 3655 of Appendix A.6 for package category. 1. Substances Fissile substances, that is, uranium-233, uranium-235. plutonium-238, plutonium-239, plutonium-241, or any substance containing any of the foregoing. except unirra­ diated natural and depleted uranium. Fissile substances shall also be consigned in full com­ pliance with the requirements of one of the other sched­ ules, as appropriate to the radioactivity. 2. Packaging/Package The following substances specified fully in marginal 3610 of Appendix A.6 are exempt from the special packa­ ging requirements of this Schedule: (i) fissile substances in quantity nol exceeding 15 g. (ii) natural or depleted uranium irradiated in a thermal reactor (iii) dilute hydrogenous solutions in limited concentra­ tions and quantities. (iv) enriched uranium with not more than 1 per cent of uranium-235, which should not form a lattice arrangement if metal or oxide. (v) substances distributed at not more than 5 g per 10 litre volume. (vi) plutonium where less than 1 kg per package and where not more than 20 per cent by mass consists of pluto­ nium-239 or 24]. (vii) enriched uranyl nitrate solution containing uranium with not more than 2 per cent uranium-235. (b) Otherwise, packages shall be in accordance with the design requirements of Fissile Class I, II or III given in marginals 3611 to 3624 of Appendix A.6 and have com­ petent authority approval, where necessary, as detailed in marginal 3674 of Appendix A.6. 3. Package maximum radiation level. See appropriate schedule. 4. Mixed packing See marginal 3650 of Appendix A.6. 5. Contamination on packages See appropriate schedule. 6. Marking on packages See appropriate schedule. 7. Transport documents (a) For a summary of the approval and notification req­ uirements, see marginal 2704. (b) The transport document shall include the details spe­ cified in the schedule appropriate to the nature of the co­ ntents with the word "Fissile" prefixed to the description and underlined. (c) Unilateral or multilateral package design approval certificates may be required. see marginal 36 7 4 of Appen­ dix A.6. (d) Fissile Class II package designs complying with mar­ ginal 3620 of Appendix A.6 shall have multilateral ship­ ment approval certificates. Such a package design requires no prior notification unless specified in the competent au­ thority's shipment approval. (e) Fissile Class III package designs shall have multilate­ ral shipment approval certificates unless a competent au­ thority authorizes transport by a specific provision in its package design certificate, see marginal 36 75 of Appendix A.6. (I) Prior to each shipment of a Fissile Class III package which requires multilateral package design approval. see marginal 3674 of Appendix A.6 the consignor shall notify the competent authorities of all countries affected bv the movement preferably fifteen days in advance as detaifed in marginal 3682 (2) to (4) of Appendix A.6. (g) Before the shipment of any package the consignor shall be in possession of any relevant approval certificates. . 8. Storage an despatch (a) Any instructions in the competent authority approval certificates must be observed. (b) Total transport index limitation for storage - 50 per . group with 6 metres between groups - see marginal 3658 (2) to (5) of Appendix A.6. (c) The consignor shall have complied with the pre-use requirements of marginal 3643 of Appendix A.6. 9. Carriage of packages in vehicles and containers (a) Any instructions in the competent authority approval certificates shall be observed. (b) Total transport index limitation - 50. This limitation does not apply to a full load, provided that if fissile Class II or III packages are present the allowable number is not ex­ ceeded - see marginal 3659 (5) of Appendix A.6. 11. Carriage in bulk in vehicles and containers (a) No restrictions for fissile material up to 15 g total or for solutions within certain concentration and quantitv li­ mits, see paragraph 2 (a) (i), (iii) and (vii) and marginal 3610 of Appendix A.6. (b) Not applicable for Fissile Class I or II packages. ECDHMEPII THI KYBEPNHIEQI (TEYXOI 4EYTEPO) (c) Permitted under Fissile Class Ill only if so specified in the competent authority certificate. 11. Carriage in tank-vehicles and tank-containers Not applicable. 12. Placards and labels on vehicles. tank-vehicles. Lank­ containers and containers (see Appendices A.9 and B.4.) Containers - labels to models 7 A. 7B or 7C on all four si­ des. Vehicles and large containers - placards to model 7D in Appendix B.4 marginal 240 010 on each lateral side and on rear wall of vehicle (see marginals 3659 (6) and 71 500). 13. Prohibitions on mixed loading See marginal 2700 (3) 14. Decontamination of vehicles. tank-vt'hicles. Lank coniainers and containers See appropriate schedule. 15. Other provisions Accident provisions - see marginal 3695 ( l) of Appen­ dix A.6. Schedule 12 Danger labels on packages (see Appendix A.9) Labels in conformity with model no. 7C shall be affixerl externally to two opposite sides unless otherwise prescri­ bed in the competent authority certificate. See marginal 3655(1) of Appendix A.6. 1. Substances Radioactive substances carried under special arrange~ ment If it is not possible to comply with the package design or shipment requirements, consignments sJrnll be transported under a special arrangement which will 'ensure that Lhe over-all safety level is no less than it would have been had all the applicable requirements been met. See marginal 3676 of Appendix A.6. NOTE: For a summary of the approval and notification requirements, see marginal 2704. Summary of approvals and prior notification require­ ments (a) Approval of special form substances. and package designs . Subject of approval 1 Special form substance excepting those items specified in Schedules 3 and 4 2 Type A, LSA ans LLS 4 Type B(M) ~ Fissile packages Package designs complying with marginal 3620. 3623 or 3624 of Appendix A.6 Package designs complying with marginal 36 i 6 or 3622 of Appendix A.6 All other package designs Competent authority whose. approval is required Country of origin None unless contents are fissile and not exempted from the fissile requirements under marginal ~,6~.0 of Ap pendix A.6: f ": • • c Countru of origin Country of origin and all countries en route None Country of origin Country of. origin and all countries en route NOTE: "Country of origin'" refers lo the country where the design originated. Packages in the fissile classes also fall into one or other of package design categories 2. 3 or 4 abol'e a1id the relevant provisions also apply to them. (b) Approval of shipments and prior notification Competent authority Prior notification Package whose approval is required of each shipment for each shipment 1 Type A, LSA None None and LLS 2 Type B(U) None Country of origin and all countries en rmite when contents exceed 3 X l03A 1 or 3 X 103A 2 as appropriate or 3 X 104Ci, whichever is lower 973 2704 974 E<DHMEPII THI KYBEPNHIEQI (TEYXOI 4EYTEPO) Competent authority Prior notification Package whose approval is required of each shipment for each shipment 3 Type B(M)- Country of origin and all countries en Country of origin and all countries en Continuously venting route route 4 Type B(M) - Not Country of origin and all countries e11 Country of origin and all countries en continuously venting route when contents exceed route 3 X 10:1A 1 or 3 X 103A 2 as appropriate or 11.1 x 102TBq (3 x 104Ci), · whichever is lower 5 Fissile packages Class I None None Class II Packages complying with marginal 3620 None unless specified in the competent of Appendix A.6 only: authority shipment approval Country of origin and all countries en route Class III Country of origin and all countries en Country of origin and all countries en route route 6 Packages subject to Country of origin and all countries en Country of origin and all countries en transport under special route route arrangements NOTE: Before shipping a Type B(U) package the contents of which exceed 3 X 103A or 3 X 103 A2, as appropriate, or 11.1 X 102Tbq (3 X 104Ci), whichever is lower. for the first time, the consignor shalf ensure that copies of each appli cable competent authority certificate applying to the design have been submitted to the competent authority of those coun tries in whose terriotory it is to be transported. Country of origin refers to the country where the shipment originated. ·1., ~ Packages in the fissile classes also fall .into one or other of the other headings of this Table and the relevant provisions also apply to them. 2705 2799 CLASS 8·CORROSIVE SUBSTANCES 1. List of substances (1) Among the substances and articles covered by the 2800 heading of Class 8 11, those which are listed in marginal 2791 or are delivered by a collective heading of that l/ The heading of Class 8 covers substances which by chemical action attack epithelial tissue - of skin, mucous membranes or eyes - with which they are in contact, and substances which in the event of leakage are capable of damaging or destroying other goods, or means of transport, and may also cause other hazards. The heading of this Class also covers substances which form a corrosive liquid only in the presence of water, or which produce corrosive vapour or mist in the presence of the natural moisture of the air. In the absence of other tests, corrosive action may be deter­ mined by experiments on animals. Substances that cause visible necrosis of the skin tissue at the site of contact when tested on the intact skin of an animal for a pe­ riod of up to four hours are substances of group (c). Substances which, while not dangerous to epithelial tissue, cor­ rode steel or aluminium are likewise substances of group (c). Substances that cause visible necrosis of the skin tissue at the site of contact when tested on the intact skin of an animal for a pe­ riod of more than three minutes and up to 60 minutes are sub­ stances of group (b ). Other substances covered by the he~ding of Class 8 which are more corrosive than the substances of grciup (b) are substances of group (a). marginal are subject to the conditions set up in marginals 2800 (2) to 2822 and to the provisions of this Annex and of Annex B. These are then considered as substances and articles of ADR21 Substances of Glass 8 ( other than the substances of 6 °, 24 ° and 25 °) which are classified under the various items of marginal 2801 shall be assigned to one of the following groups designated by the letter (a), (b) or (c) according to their degree of corrosiveness: letter (a): Highly corrosive; letter (b): Corrosive; letter (c): Slightly corrosive. When, as a result of additions, substances of Class 8 pass into categories of corrosiveness other than those to which the substances specified in marginal 2801 belong, such mixtures or solutions shall be classified under the items and letters to which they belong on the basis of thek actual degree .of corrosiveness. When, as a result of additions, substances o{ Class 8 pass into the category having a flash-point below 21 °C, such mixtures or solutions shall be classified under the cor­ responding items or letters of Class 3, taking into account . their corrosiveness. When, as a result of additions of substances of Class 6.1, substances of Class 8 acquire a preponderance of toxic properties, such mixtures or solution shall be classi­ fied under the corresponding items and letters of Class 6.1. 21 For the quantities of substances listed in marginal 2801 which are not subject lo the provisions for this Class, either in this Annex or in Annex B, see marginal 2801a. EG>HMEPII THI KVBEPNHIEQI (TEVXOI aEVTEPO) (1) For the packaging requirements of marginals 2805 (2), 2806 (2) and 2807 (2), substances or mixtures of sub­ stances having a melting point above 45 ° C are considered to be solids. (3) Corrosive inflammable liquids having a flash-point below 21 ° C, other than certain acid halides of 3 6 ° (b ), are substances of Class 3 (see marginal 2301, 21 ° to 26 °). (4) Corrosive substances which have a very high inhala­ tion toxicity, as defined in footnote11 to marginal 2600 (1), are substances of Class 6.1 (see marginal 2601 ). (5) The chemically unstiible substances of Class 8 are to be accepted for carriage only if the necessary steps have been taken to prevent their dangerous decomposition or polymerization during carriage. To this end it should in particular be ensured that receptacles do not contain any substance liable to promote these reactions. (6). The flash-point referred to below shall be deter­ mined in the manner described in Appendix A.3. NOTE: Even where no substance is listed under letters 2801 (a), (b) or (c) of the various items, substances, ·solutions, mixtures and preparations may be classified under these letters in accordance with the criteria set out in marginal 2800. A. Acid substances Inorganic acids 1 ° Sulphuric acid and similar substances, such as: (a) chromosulphuric acid, sulphur trioxide, oleum (fum­ ing sulphuric acid); (b) alkyl sulphonic and aryl sulphonic acids containing more than 5 per cent free sulphuric acid, sulphuric acid, waste sulphuric acid, aqueous solutions of bisulphates, ni­ trosulphuric acid, lead sludge containing sulphuric acid; (c) ... NOTES: 1. Lead sludge containing sulphuric acid with less than 3 per cent free acid is a substance of Class 6.1 (see marginal 2601, 63° (c)). 2. Alkyl sulphonic and aryl sulphonic acids, containing not more than 5 per cent free sulphuric acid, are sub­ stances of 34 °; 2 ° Nitric acids, such as: (~) nitric acid containing more than 70 per cent pure acid, red fuming nitric acid; (b) nitric acid containing not more than 70 per cent pure acid; (c) ... 3 ° Mixtures of inorganic acids, with the exception of hy­ drofluoric acid, such as: (a) mixtures of sulphuric acid with more than 30 per cent nitric acid; (b) mixtures of sulphuric acid with not mor e th~n 30 per cent pure nitric acid, mixtures of sulphuric acid with hydro­ chloric acid mixtures of nitric acid (containing not more than 30 pe; cent HNO3) with acetic acid and phosphoric adid; (c) ... . . NOTES: 1. Mixtures of nitric acid with hydrochlonc acid are not to be accepted for carriage. 2. Mixtures of residual sulphuric and nitric acids, not denitrated, are not to be accepted for carriage. 4 ° Solutions of perchloric acid: (b) Aqueous solutions of perchloric acid containing not Jl\Ore than 50 per cent pure acid; • (c) ... NOTE: Aqueous solutions of perchloric acid containing more than 50 per cent but not more !han 72.5 per cent pure acid are substances of Class 5.1. (see parginal 2510, 3 o). . . Solutions containing more than 72.5 per cent pure acid are not to be accepted for carriage; the same applies to mixtures of perchloric acid with any liquid other than water. 5 ° Solutions-of hydrogen halid~s (with the exception of hydrofluoric acid), such as: (b) solutions of hydrobromic acid, solutions of hydro­ chloric acid, solutions of hydriodic acid, aqueous solutions of substances of 21 ° and 22 ° (b ); with the exception of aqueous solutions of aluminium chloride and of aqueous solutions of aluminium bromide; ( c) aqueous solutions of substances of 22 ° ( c ), aqueous solutions of aluminium bromide, aqueous solutions of alu­ minium chloride. NOTE: Hydrogen bromide and hydrogen chloride are substances of Class 2 (see marginal 2201, 3° (at) and 5° (at)). 6 ° Anhydrous hydrofluoric acid (hydrogen fluoride), aqueous solutions of hydrofluoric acid containing more than 85 per cent anhydrous hydrofluoric acid. NOTE: Special packing conditions are applicable to these substances (see marginal 2803). 7° (a) Aqueous solutions of hydrofluoric acid containing more than 60 per cent but not more than 85 per cent anhy­ drous hydrofluoric acid, mixtures of inorganic aciqs with aqueous solutions of hydrogluoric acid; (b) aqueous solutions of hydrofluoric acid containing not more than 60 per cent anhydrous hydrofluoric acid; (c) ... 8 ° Solutions of fluoboric acid: (b) Aqueous solutions of fluoboric acid containing not more than 78 per cent pure acid; • (c) .... NOTE: Solutions of fluoboric acid containing more than 78 per cent pure acid are not to be accepted for carriage. • 9° (b) Fluosilicic acid (hydrofluosilicic acid) H2SiF 6 ); (c) ... 10° Other fluoro-acids, such as: (a) fluorosulphonic acid; . (b) difluorophosphoric acid (anhydrous), . fluo~opho sphoric acid (anhydrous), hexafluorophosphonc acid; {c) ... • • 11 ° Other inorganic acids, such as: (a) selenic acid; (b) solutions of chromic acid; NOTE: Chromium trioxide, anhydrous, is a substance of Class 5.1 (see marginal 2501, 10°). (c) chloroplatinic acid, phosphoric acid. Inorganic halides, acid salts and other halogenated sub­ stances 21 ° Liquid halides and other liquid halogenated sub­ stances (except fluorine compounds) which, in contact with moist air or water, give off acid fumes, such as: (a) chlorosulphonic acid (SOi(OH)Cl), chromyl chloride (chromium oxychloride) {CrOh--Cl2), disulphur dichloride (S Cl ), sulphuryl chloride l;-,O2Cl2), thionyl chlor!de (SOd ), sulphur dichloride (SCl2), vanadium tetrachlonde (VCl )! boron tribromide (boron bromide) (BBr3); . (b) pyrosulphuryl chloride (S 2 0 5 CL 2 ), anhydrous stanmc chloride (SnCl ), thiophosphoryl chloride (PSCl ), phos­ phorus oxychliride (phosphoryl ch~oride) (POd:J v~na­ dium oxytrichloride (VOCL3), anllmony pentachlonde, (SbCl ), and non aqueous solutions of antimony penta~hloride, iodine monochloride (IC!), silicon tetrachlo­ ride (SiCl ), titanium tetrachloride (TiCl ), phosphorus tribromidc/ (PBr~), butyltin trichloride (C 4 H 9 SnC1 3 ), phos­ phorus trichloricte (PC13); (c) ............ . NOTES: 1. Stannic chloride pentahydrate is a substance of 22° (c). 2. Aqueous solutio~s of substances of 21 ° are sub­ stances of 5 ° (b ). 22 ° Solid halides and other solid halogenated sub­ stances (except fluorine compounds), which, in contact with moist air or water, give off acid fumes, such as: 975 976 ECDHMEPlr THr KYBEPNHrEor (TEYXOr aEYTEPO) (b) aluminium bromide (anhydrous) (A!Br 3 ), aluminium chloride (anhydrous) (AICl3), phosphorus oxybromide (POBr3) phosphorus pentachloride (PC! ), antimony trichloride (SbCl3) mixtures of titanium trichforide (TiCl3), non-pyrophoric; NOTE:' Aluminium bromide hexahydrate, aluminium chloride hexahydrate and aluminium chloride monoby­ drate are· not subject to the provisions of ADR. (c) ferric chloride (iron trichloride) (anhydrous) (FeClJ, stannic chloride pentahydrate (SnC14.5J!.iO), zinc chloride (ZnCl ), molybdenum pentachloride (MoCl ), zirconium tetrachloride (ZrC14), vanadium trichloride (\TCl3). NOTES: 1. Ferric chloride hexahydrate is not subject to the provisions of ADR. 2. Aqueous solutions of substances of 22 ° are sub­ stances of 5 ° . 23 ° Sulphates containing sulphuric acid and bisulpha­ tes, such as: (b) ammonium bisulphate, potassium bisulphate, so­ dium bisulphate and lead sulphate containing 3 per cent or more sulehuric acid; (c) ammonium bisulphate, potasium bisulphate, and so­ dium bisulphate containing less than 3 per cent free sul­ phuric acid. NOTES: 1. Aqueous solutions of bisulphates are sub­ stances of 1 ° (b ). 2. Lead sulphate containing less than 3 per cent free sul­ phuric acid is a substance of Class 6.1 (see marginal 2601, 63 °(c)). 24° Bromine NOTE: Special packing conditions are applicable to this substance (see marginal 2804). 25 ° Molybdenum hexafluoride NOTE: Special packing conditions are applicable to this substance (see marginal 2803). 26° Other compounds of flourine, such as: (a) bromine pentafluoride, bromine trifluoride: (b) ammonium bifluoride, potassium bifluoride, sodium bifluoride, chroJ11ic. fluoride, antimony pentafluoride; (c) ............ . NOTE: Ammonium fluorie, potassium fluoride, sodium fluoride and the silicofluorides are substances of Class 6.1 (see marginal 2601, 65° (c) and 66° (c)). 27 ° Inorganic acid substances which cannot be classi­ fied under other collective headings, such as: (a) ............ . (b) phosphorus pentoxide (phosphoric acid, anhy drous); (c) cyanuric chloride, hydroxylamine sulphate. Organic substances 31 ° Solid carboxylic and dicarboxylic acids and solid halogenated carboxylic • acids and their solid anhydrides, sues as: (b) bromoacetic acid, chloroacetic acid (mon9chloro­ acetic acid) trichloroacetic acid, trichloroacetic anhy­ dride; (c) maleic anhydride, phthalic anhydride, tetrahydro­ phthalic anhydride. 32° Liquid carboxylic acids and liquid halogenated car­ boxylic acids and their liquid anhydrides, such as: (a) trifluoroacetic acid; (b) glacial acetic acid and· aqueous solutions of acetic acid containing more than 80 per cent pure acid, acrylic acid, solutions of bromoacetic acid, solutions of chloroacetic acid (monochloroacetic acid), mixtures of chloroacetic acids, dichloroacetic acid, formic acid con­ taining more than 70 per cent pure acid, thioglycolic acid, solutions of trichloroacetic acid, acetic anhydride; (c) acetic acid containing from 50 to 80 per cent pure acid, 2-chloropropionic acid, 5-chlorovaleric acid, formic acid containing from 50 toy 70 per cent pure acid, heptafluorobutyric acid, methacrylic acid, propionic acid containing not less than 50 per cent pure acid, butyric an­ hydride, propionic andhydride. NOTE: Formic acid, acetic acid and propionic acid con­ taining less than 50 per cent pure acid are not subject to the provisions of ADR. 33 ° Complex compounds of boron trifluoride, such as: (a) ............ . (b) boron trifluoride acetic acid complex, boron trifluoride propionic acid complex, boron trifluoride ether · complex, boron trifluoride phenol complex; (c) ............ . 34 ° Alkyl sulphonic and aryl sulphonic acids, such as: (b) nitrobenzenesulphonic acid, phenolsulphonic acid; (c) 3-benzidinesulphonic acid, methanesulphonic acid, toluene sulphonic acids and their solutions. NOTE: Alkyl sulphonic and aryl sulphonic acids con­ taining more than 5 per cent free sulphuric acid are sub­ stances of 1 ° (b ). 35 ° Solid organic acid halides, such as: (b) dichloroquinoxaline-carbonyl chloride, anisoyl chlo­ ride, 2, 4-dichlorobenzoyl chloride, nitrobenzenesulphonyl chloride, p-nitrobenzoyl chloride, isophthaloyl chloride: (c) ............ . 36 ° Liquid organic acid halides, such as: (a) ............ . (b) acetyl bromide bromoacetyl bromide, benzoyl chlo­ ride, chloroacetyl chloride, diethyl thiophosphoryl chlo­ ride, fumaryl chloride, pivaloyl chloride, (trimethyl acetyl chloride), trichloroacetyl chloride, valeryl chloride, acetyl iodide; (c) benzenesulphonyl chloride, o-chlorobenzoyl chlo­ ride, p-chlorobenzoyl chloride, dimethyl thiophosphoryl chloride. 3 7 ° Alkyl chlorosilanes and aryl chlorosilanes having a flash-point of 21 °C or above, such as: (a) ............ . (b) allyltrichlorosilane, amyltrichlorosilane, butyltrichlo­ rosilane, chlorophenyltrichlorosilane, cyclohexenyltrichlo­ rosilane, cyclohexyltrichlorosilane, dichlorophenyltrichlo-. rosilane, diethyldichlorosilane, diphenyldichlorosilane, do­ decyltrichlorosilane, ethylphenyldichlorosilane, hexade­ cyltrichlorosilane, hexyltrichlorosilane, methylphenyldi­ chlorosilane, nonyltrichlorosilane, octadecyltrichlorosi­ lane, phenyltrichlorosilane, propyltrichlorosilane; (c) ............ . NOTE: Chlorosilanes which give off inflammable gases on contact with water or moist air are substances of Class 4.3 and are not to be accepted for carriage unless specifi­ cally listed thereunder. 38° Acid phoshoric esters, such as: (b) ........... . (c) dibutyl acid phosphate, dipropyl acid phosphate, butyl acid phosphate, isooctyl acid phosphate, isopropyl acid phosphate. 39° Organic acid substances which cannot be classified under other collective headings, such as: (b) acetopolysilanes, acetoxysilanes, ethyltriacetoxysi­ lane; (c) ............ . B. Basic substances Inorganic substances 41 ° Basic solid compounds of alkali metals, such as: (b) caesium hydroxide, litliium hydroxide, potassium hy droxide (caustic potash), sodium hydroxide (caustic soda), potassium oxide, sodium oxide; (c) soda lime (mixtures of caustic soda and quicklime). 42 ° Solutions of alkaline substances, such as: (b) solutions of sodium aluminate, solutions of potas <I>EK 104 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) 977 sium hydroxide (potash lye) and of sodium hydro~ide (soda lye), alkaline solutions of cresols, of phenol and of xylenols, alkaline residues (e.g. from oil refining); (c) ............ . 43 ° Ammonia solutions; (c) ammonia solutions containing not less than 10 per cent and not more than 35 per cent ammonia. . NOTES: 1. Ammonia solutions containing more than 35 per cent ammonia are substances of Class 2 (see marginal 2201, 9° (at)). • 2. Ammonia solutio~s containing less than 10 per cent ammonia are not subject to the provisions of ADR. 44 ° Hydrazine and its aqueous solutions: (a) anhydrous hydrazine, aqueous solutions of hydrazine containing more than 64 per cent hydrazine; (b) aqueous solutions of hydrazine containing not more than 64 per cent hydrazine; (c) ............ . 45 ° Sulphides and hydrogensulphides, such as: (b) solutions of ammonium sulphide and solutions of ammonium polysulphide; potassium sulphide and sodium sulphide containing not less than 30 per cent water of crys­ tallization and sodium hydrogensulphide containing not less than 25 per cent water of crystallization; • NOTE: Anhydrous potassium. sulphide and anhydrous sodium sulphide and their hydrates containing less than 30 per cent water of crystallization, and sodium hydrogensul­ phide containing less than 25 per cent water of crystalliza­ tion .are substances of Class 4.2 (see marginal 2431 6 ° (c)). (c) aqueous solutions of sulphides and of hydrogensul­ phides, with the exception of ammmonium sulphide in so­ lution and ammonium polysulphide in solution. Organic substances 51 ° Tetra-alkylammonium hydroxides, such as: (b) tetramethylammonium hydroxide; (c) ............ . 52 ° Solid alkylamines, arylamines and polyamines, such as: (c) diethylenediamine (piperazine), hexamethylenedia­ mine. 53 ° Liquid alkylamines, arylamines and polyamines, such as: (b) benzyldimethylamine, cyclohexylamine, solutions of cupriethylenediamine, di-n-butylamine, diethylenetria­ mine, N,N-di-ethylethylenediamine, N,N dimethylchyclo­ hexylamine, ethylenediamine, solutions ofhexamethylene diamine, triethylenetetramine; • (c) benzylamine, bisaminopropylamine (dipropylene­ triamine, 3,3-iminobispropylamine), dicyclohexylamine, ' diethylaminopropylamine, 2-ethylhexylamine, isoprhoro­ nediamine, pentaethylenehexamine, tetraethylenepenta­ mine, tributylamine, trimethylcyclohexylamine, trimethyl­ hexamethylenediamines. 54 ° Amino-alcohols, such as: ( c) ethanolamine and its solutions. C. Other corrosive substances 61 ° Hypochlorite solutions, sucha as: (b) solutions of potassium hypochlorite and solutions of sodium hypochlorite containing not less than 16 per cent available chlorine; (c) solutions of potassium hypochlorite and solutions of sodium hypochlorite containing more than 5 per cent but less than 16 per cent available chlorine. NOTE: Solutions of hypochlorite containing not more than 5 per cent available chlorine are not subject to the provisions of ADR. 62 ° Solutions of hydrogen peroxide (b) aqueous solutions of hydrogen peroxide containing not less than 20 per cent and not more than 60 per cent hy­ drogen peroxide; ( c) aqueous solutions of hydrogen peroxide. containing 8 per cent or more but less than 20 per cent hydrogen perox­ ide. NOTES: 1. Solutions containing more than 60 per cent hydrogen peroxide are substances of Class 5.1 (see mar ginal 2501, 1 °); • 2. Solutions containing less than 8 per cent hydrogen peroxide are not subject to the provisions of'ADR; 63 ° Formaldehyde solutions: (c) Aqueous solutions ~f formaldehyde e.g. formalin with not less than 5 per cent formaldehyde; also. with not more than 35 per cent methanol. • NOTE: Aqueous solutions of formaldehyde with less than 5 per cent formaldehyde are not subject to the provi­ sions of ADR. 64 ° Esters of organic and inorganic acids whose proper­ ties are predominantly corrosive, such as: (a) chloroformic esters, such as: ally! chloroformate, benzyl chloroformate; (b) ........... . (c) ............ . NOTE: Esters of organic and inorganic acids whose properties are predominantly toxic are substances of Class 6.1 (see marginal 2601 16° and 17°). 65 ° Solid corrosive substances and preparations which cannot be classified under othe~ collective headings, such as: (a) .................. . (b) diphenylmethyl bromide; (c) .................. . 66 ° Liquid corrosive substances, solutions and prepara­ tions, which cannot be classified under other collective headings, such as: (a) ........... ' ...... . (b) benzotrichloride (trichloromethylbenzen~): l-pe1i1ol (3-methyl-2-pentene-4-yne-l-ol): , • (c) .................. . D. Empty packagings •• .,, ,~ 71 ° Empty packagings, empty lank-vehicles: empty de­ mountable tanks, empty tank- containers and empty small bulk containers, uncleaned, which have contained substan­ ces of Class 8. Substances of 1 ° to 5°, 7° to 11 °, 21 ° to 23°. 26°, 2801a 2 7 °, 31 ° to 3 9 °, 41 ° to 45 °, 51 ° to 5 4 ° and 61 ° I~ 66 °. carried in conformity with the following provisions are subject neither to the provisions for this Class contained in this Annex nor to those contained in Annex B: • (1) (a) Substances classified under (a) of each item: Liquids: not more than 100 ml per inner packaging and not more than 400·ml per package: • Solids: not more than 500 g per inner packaging and not more than 2 kg per package. (b) Substances classified under (b) of each item: Liquids: not more than 1 litre per inner packaging and not ,more than 4 litres per package: Solids: not more than 3 kg per inner packaging and not more than 12 litres per package: . (c) Substances classified under (c) of each item: Liquids: not more than 3 litres per inner packaging and not more than 12 litres per package: Solidl>: not more than 6 kg per inner packaging and not more than 24 kg per package. . These quantities of substances shall be carried in combi­ nation packagings which at least meet the conditions of marginal 3538 (b) and (d). The «General conditions of packing» of marginal 3500 (1), (2) and (4) to (7) shall be observed. (2) Alkaline solutions or acids in storage batteries with metal or plastics casings. Batteries shall be so secured as to prevent short circuiting, sliding, falling or damage: they shall be fitted with means of handling. Means of handling 978 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) are not, however, necessary, if the batteries are stacked and adequately secured, for example, on pallets. No dan­ gerous trace of alkali or acid shall appear outside the pac­ kage. 2. Provisions A. Packages 1. General conditions or packing (1) Packagings shall satisfy the conditions of Appendix A.5, unless special conditions for the packing of certain substances are prescribed in margi11als 2803 - 2808. (2) In accordance with the provisions of marginals 2800 (1) and 3511 (2) the following shall be used: Packagings of packing group I, marked with the letter «X», for the highly corrosive substances classified under the letter (a) of each item; Packagings of packing groups II or I. marked with the letter «Y» or «X» for the corrosive substances classified under the letter (b) of each item; Packagings or packing groups III. II or I marked with the letter·«z», «Y» or «X», for the slightly corrosive substan­ ces classified under the leller (c) of each item. NOTE: For the carriage of substances of Class 8 in lank vehicles, demountable tanks or tank - containers. and for the carriage in bulk of solids of this Class, see Annex B. 2. Special conditions for packing of certain substan­ ces Anydrous hydroflouric acid and aqueous solutions of hydrofluoric.acid containing more than 85 per cent anhyd­ rous hydrofluoric acid of 6 ° or molybdenum hexafluoride of 25 ° shall be packed in pressure receptacles made of carbon steel or suitable alloy steel. The following pressure receptacles shall be permitted: (a) Cylinders having a capacity not exceeding 150 litres: (b) Receptacles having a capacity of not less than 100 litres and not more than 1000 litres (for example, cylindri­ cal receptacles fitted .with rolling hoops or receptacles mounted on skids). The pressure receptacles shall satisfy the relevant requi­ rements of Class 2 (see marginals 2211. 2213 ( l) and (2). • 2215, 2216 and 2218). • The wall thickness of the pressure recep.tacles shall not be less than 3 mm. Before being used for the first time. pressure receptacles shall be subjected to a hydraulic pressure test at a pressure of not less than l 1v!Pa (] 0 bar) gauge pressure. The pressure test shall be repeated every eight years and shall be accompanied by an internal! ispec­ tion of the pressure receptacles and a check of their equip­ ment. In addition, the resistance of the pr'e!;sure receptac­ les to corrosion shall be checked by means of suitaple instr­ uments (e.g. by ultrasound), and the condition of the equip­ ment verified, every two years. The tests and inspectio'ns shall be carried out under the supervision of an expert approved by the competent autho­ rity. The maximum mass of the contents per litre of capacit\' shall be: • 0.84 for anhydrous hydrofluoric acid and aqueous sol­ utions of hydrofluoric acid: 1.93 kg for molybdenum hexafluoride. (1) Bromine of24 ° shall be packed in glass inner packa­ gings containing not more than 2.5 litres each which shall • be placed in combirration packagings conforming Lo niargi­ nal 3538. The combination packagings shall be Lesled and approved in accordance with Appendix A.5 for packing group I. (2) Bromine containing less than 0.005 per cenl waler. or between 0.005 per cent and 0.2 per cent water. prol'i­ ded that in the letter case measures are taken to prevent corrosion of the lining of the receptacles. mav also be car­ ried in receptacles satisfying the following conditions: (a) The receptades shall be made of steel and be equip­ ped with a leakproof lining made of lead or of some mate 2802 2803 2804 rial affording equivalent protection and with a hermetic closure; receptacles made of monel metal or nickel, or with a nickel lining, shall also be permitted; (b) The capacity of the receptacle shall nol exceed 450 litres; (c) The receptacles shall 1101 be filled to more than 92 per cent of capacity or more than 2.86 kg per litre of capa­ city; (d) The receptacles shall be welded and disgned for a calcualation pressure of not less than 2.1 MPa (21 bar) gauge pressure. The materials and workmanship shall i11 other respects meet the relevant requirements of Class 2 (see marginal 2211 (1)). The initial test of unlined steel re­ ceptacles shall be subject to the provisions of Class 2 (see marginals 2215 (1) and 2216 (1)). (e) The closures shall project as little as possible from the receptacle and be fitted with protective caps. The clos­ ures and caps shall be fitted with gaskets made of a mate­ rial not capable of being attacked by bromine. The closures shall be in the upper part of the receptacles in such a man­ ner that they can in no case be in permanent contact with the liquid phase; (t) The receptacles shall be provided with fittings enab­ ling them to stand stably upright, and with lifting attach-· ments (rings, flanges etc) at the top, whi ch shall be tested al twice the working load. (3) Before being put into service, receptacles in confor­ mity with (2) above shall be subjected to a leakproofness test at a pressure of at least 0.2 MPa (2 bar) gauge press­ ure. The leakproofness test shall be repeated every two ye­ ars and shall be accompanied by an internal inspection of the receptacle and a check of its tare. The test and the in­ spection shall he carried out under the superivision of an expert approved by the competent authority. (4) Receptacles in conformity with (2) shall bear. in cle­ arly legible and rlurable characters: • (a) the name or mark of the maker and the number of the receptacle; (b) the word «Bromine»; (c) the tare of the receptacle and its maximum permitted ma~s when filled: (d) the date (month and year) of the initial test and of the most recent undergone; (e) the stamp of the expert who carried out the test. (1) Substances classified under (a) of tlie various items of marginal 2801 shall be packed: (a) in non-removable head steel drums conforming to marginal 3520 or (b) in non-removable head steel aluminiun1 drums con forming to marginal 3251; or • (c) in steeljerricans conforming to marginal 3522: or (d) in non-removable head plastics drums of a capacity not exceeding 60 litres or plastics jerricans conforming to . marginal 3526; or (e) in composite packagings (plastics material) co.nfor­ ming to marginal 353 7; or (t) in combination packagings with inner packagings of glass, plastics or metal conforming to marginal 3538: or (g) in composite packagings (glass. porcelain or slone­ ware) conforming to marginal 3539. NOTES 1 to (d): The permissible period of use for pac­ kagings intended for the carriage of nitric acid of 2 ° (a) and aqueous solutions of hydrofluoric acid of 7° (a) shall be two years from the date of their manufacture. 2 to (t) and (g): Inner packagings or receptacles of glass shall not be permitted for fluorides of 7 ° (a). 10 ° (a). 26 ° (a) or 33 ° (a). (2) Solid substances within the meaning of marginal 2800 (2) may also be packed: (a) in removable head drums conforming to marginals 3520 for steel, 3521 for aluminium, 3523 for plywood. 3525 for fibreboard, or 3526 for plastics material. if ne 2805 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) cessarv with one or more sift-proof inner bags: or (b) in combination packagings conforming lo marginal 3538, with one or more sift-proof inner bags. (1) Substances classified under (b) of the ,arious itP111s of marginal 2801 shall be packed: • (a) in steel drums conforming to marginal 3520: or (b) in aluminium drums confonning lo marginal :-352 l: or (c) in steeljerricans conformi1ig to marginal 3522: or (d) in plastics drums or plastics jerricans conforming lo marginal 3526; or (e) in composite pachagings (plastics malPrial) confor­ ming to marginal 3537: or (f) in combination paC'hagings conforming to marginal 3538; or (g) in composite packagings (glass. porcelain or ;stone­ ware) conforming to marginal 3539. NOTES 1 to (a). (b) and (cl): Removable head rlru111s are. permitted only for viscous substances hal'ing a ,·iscositl' above 200 mm2/s at 23°C and for solids. 2 to (cl): The permissible period of use for packagings intended for the carriage of nitric acid containing more than 55 per cent pure acid of 2 ° (b) and aqueous s olutions of hydrofluoric acid of 7° (b) shall be two years lrom the date of their manufacture. 3 to (f) and (g): Inner packagings or receptacles of glass shall not be permitted for fluorides of 7° (b). 8 ° (h). 9° (b). 10° (b), 26°(b) or 33° (b). (2) Solid substances within the meaning of marginal 2800 (2) may also Le packed: (a) in removable head drums cqnfonning ( o margi11,1ls 3523 for plywood or 3525 for fibreboard. 1f necessan with one or more sift-proof inner bags: or (b) in water-resistant bags conforming lo •~iarginals 3533 for textile material, 3534. for woven plastics mate­ rial, 3535 for plastics film of 3536 for water resistant pa­ per, provided the goods are carried as a full load or the bags secured on pallets. . . (1) Substances classified under (c) of the rnrious 1tt'ms of marginal 2801 shall be pached: Or (a) in steel rlrums conforming to marginal 3520: or (b) in aluminium drums conforming to marginal J52 l: (c) in steeljerricans conforming lo marginal 3522: or (d) in plastics drums or plastics jerricans conforming to marginal 3526; or (e) in composite packagings (plastics material) confor­ ming to marginal 3537; or (f) in combination packagings conforming to marginal 3.538: or • (gl 111 ,·omposite packagings (glass. porcelain or ston,·­ ware) confonuing tu- marginal 3539: or 2806 2807 (h in light gauge metal packagings conforming to margi­ nal 3540. NOTE to (a), (b), (d) and (h): Removable head rlrums conforming to (a), (b) and (d) and removable head light gauge metal packagings conforming to (h) are permitted only for viscous substances having a viscosity abo,·e 200 • mm2 /s at 23 ° C and for solids. (2) Solid substances within the ,neaning of marginal 2800 (2) may also Le packed: (a) in removable head drums conforming to marginals 3523 for plywood, or 3525 for fibreboard. if necessary with one or more sift-proof inner bags: or (b) in water-resistant bags conforming to marginals 3533 for textile material. 3534 for woven plastics mate­ rial, 3535 for plastics film or 3536 for water-resistant pa­ per. Packagings containing substances of 61 ° or 62 ° shall he fitted with a vent confom1ing to marginal .3500 (8). 3. Mixed packing (1) Substances covered by the same item number n.1ay be packed together in a combination packaging confonrnng to marginal 3538 .. (2) Substances of different items of Class 8 in quanlitit's not exceeding, per packaging, 3 litres for liquids and/or 5 kg for solids, may be packed together and/or with goods not subject to the provisions of ADR. in a combination pac­ kaging conforming to marginal 3538 provided they rlo not react dangerously with one another. (3) Except as otherwise specially provided • below. substances of Class 8, in-quantities not exceeding. per pac­ kaging, 3 litres for liquids and/or 5 kg for solids. mav he packed together in,a combination packaging conforming lo nwr2;inal 3538 with substances or articles of other'classes. provided that mixed packing is also permitted for the substances and articles of these classes. and/or with goods which are not subject to the provisions of ADR, provided they do not react dangerously with one another. (4) The following are considered dangerous ·reac tions: (a) combustion and/or giving off considerable heat: (6) emission of inflammable and/or toxic gases: (c) formation of corrosive liquids; (d) formation of unstable substances. (5) The mixer! packing of acid substances with basic substances in a package shall not be permitted if the two substances are packed in fragile packagings. (6) The provisions of marginals 2001 (7). 2002 (6) and (7) and 2802 shall be complied with. (7) If woorlen or fibreboard boxes are user!, a package may not weigh more than 100 kg. 979 2808 2809 2810 2811 980 ECJ>HMEPII THI KYBEPNHIECI (TEYXOI .dEYTEPO) Special conditions: Description Item of substance 40 Perchloric acid containing not more than 50 per cent pure acid 60 Anhydrous hydrofluoric acid, aqueous solutions of hydrofluoric acid containing · more than 85 per cent anhydrous hydrofluoric acid 24° Bromine 25° Molybdenum hexafluoride Substances classified under (a) t>f each item 4. Marking and danger labels on packages (see Appen dix A.9) • (1) Packages containing substances of this Class shall bear a label conforming io moaefNo: 8. (2) tf liquids are packed in composite packagings (glass. poreelain or stoneware) conforming to marginal 3539 of a capacity exceeding ·5 litres, the packages shall, however. bear two labesl coriforming to model No 8 (see Appendix A.9, marginal 3901 (2)). (3) Packages containing substances having a flash-point up to 55 °C inclusive shall in addition bear a label confor­ ming to model No 3, those containing oleUJn (fuming sulphuric acid) of 1 ° (a) or substances of 6 °. 7 °. 24 ° to 26 ° or 44 ° a label conforming to model No 6.1 and those containing substances of 62 ° a label conforming to model No 5. (4) Packages containing fragile packagings 1101 visible from the outside shall bear on two opposite sides a label. conforming to model No. 12. • (5) Packages containing liquids in packagings the clos­ ures of which are not visible from the outside and packages containing vented packagings or vented packagings wi­ thout outside packaging shall bear on two opposite sides a label conforming to model No.11. B. Particulars in the transport document (1) The description of the goods in the transport doc­ ument must conform to one the names underlided in mar­ ginal 2801. If the substance is not mentioned by name, the chemical name must be entered. The description of the go Maximum quantity per per Special receptacle package provisions Mixed packing not allowed except with perchloric acid of Class 5.1 (see marginal 2501, 3 °) Mixer! packing not allowed 0.5 litre 1 litre Shall not be packed 2812 2813 2814 together with substances or articles of Classes la, lb, le, 5.2 or 7 ods must be underlined and followed by particulars of the class, the item number (together with the latter, if any), and the initials ·«ADR» (or «RID»), e.g. 8,1 °(a), ADR. (2) In the case of bromine containing 0.005 per cent to 0.2 per cent water and carried in receptacles in conformity with marginal 2804 (2), the sender must certify in the tran­ sport document: «Measures taken to prevent corrosion of the lining of the receptacles». (3) For consignments of chemically unstable substan­ ces, the sender shall certify in the transport document: «Measures taken in accordance with marginal 2800 (5).» C. Empty packagings . ( 1) Empty packagings, uncleaned, of 71 ° shall be clo­ sed in the same manner and with the same degree of lea­ kproofness as if they were full. (2) Empty packagings, uncleaned, of 71 ° shall bear the same danger lahels as if they were full. (3) The description in the transport document shall con­ form to one of the descriptions underlined in 71 °. e.g.: Empty packaging, 8, 71 ° ADR. This text shall be underli­ ned. In the case of empty lank-vehicles, empty demou­ ntable tanks, empty tank-containers and empty small bulk containers, uncleaned, this description shall be completed by adding the words «last load» together with the name and item number of the goods last loaded, e.g. Last load: sulphuric acid, l O (b). 2815 2821 2822 2823 2899 2900 2999 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI .dEYTEPO) 981 ECONOMIC COMMISSION FOR EUROPE I\LJ\~D TH:\ \~l'OHT 10\1\I ITH:I-: European Agreement concerning the international carriage of dangerous goods by road {ADR) and protocol of signature· done at Geneva on 30 September 1957 VOLUME II (Appendices to Annex A} UNITED NATIONS New York, 1985 EUROPEAN AGREEMENT CONCEIF'.JI\C TIii·: INTERNATIONAL C:AHHIAGE OF l);\I\Cl·:Bot:s (;(l()()S BY HOAD (AllH) PROVISIO\S CO\CEH\I\C 11\\U:l{(ll S SU3ST:\i\CES .\~ll .\IHICl.l·:S PART Ill. .\l'l'E\DIU:S TO ·\\ \I-:\ \ Appendix A. l Appendix A.2 i\ppendix A.3 Contents Part III. APPENDICES TO ANNEX A Stability and safety conditions relating to explosive sub­ stances, inflammable solids and organic peroxides; Rules for tests ................ . Provisions relating to the na­ ture of aluminium-alloy recep­ tacles for certain gases of Class 2; provisions relating to the materials and construction of receptacles, intended for the carriage of deeply-refrigerated liquefied gases of Class 2; and provisions relating to tests on aerosol dispensers and non­ refillable containers for gases under pressure of Class 2, 10° and 11 ° .............. . Tests relating. to inflammable liquids of Classes 3, 6.1 and 8 Marginals 3100 et seq. 3200 3300 Appendix A.4 Appendix A.5 Appendix A.6 Appendix A. 7 Appendix A.8 Appendix A. 9 Reserved ............... · General packing conditions, types of packagings, require­ ments applicable to . packa­ gings, test requirements for packagings ............. . Regulations relating to radio­ active substances of Class 7 . Reserved .............. . Reserved .............. . Provisions relating to danger labels; Explanation of symbols, and model labels ........ . 3400 3500 3600 3700 3800 3900 .trinitroresorcinol, if they are soluble in water; tetryl (trinitrophenylmethylnitramine), if they are insoluble in • water.· • •• ' See marginals 3150, 3152, 3154, 3155 and 3156. Re marginal 2101, 11 °(a) and (b): 3104 1. Black powder of 11 °]a) must not be more sensitive lo flame-ignition, impact or friction than the finest sproting powder having the following composition: 75 per cent po­ tassium nitrate 10 per cent sulphur and 15 per cent black alder charcoal. See marginals 3150, 3154, 3155 and 3156. 2. Slow mining powders similar to black powder of 11 °(b) must not be more sensitive to flame-ignition, impact or friction than the standard explosive having the following composition: 7 5 per cent potassium nitrate, 10 per cent sulphur and 15 per cent lignite. See marginals 3150, 3154, 3155 and 3156. Re marginal 2101, 12°: Nitrate explosives in powder .. 31Q5 form of l2°(a), and explosive not containing inorganic ni . trates, in powder form of 12 ° (b ); must be caP,ab!f of b.eing .. stored for 48 hours at 75°C without. gi.v.ing·off'visible, yellowish-brown nitrous fumes. B~fore and after storing they must not be more sensitive to flame-ignition, impact or. friction than the standard explosive having the followi,nK. composition: 80 per cent ammonium nitrate, 12. per cent trinitrotoluene, 6 per cent nitroglycerine and 2 per cent wood flour. See marginals 3150, 3152(b), 3154(a) (lnd . (b), 3155 and 3156. A sample of the standard explosive referred to abov~ is held at the disposal of the Conttracting States by Laboratoire du Centre d'etudes et recherches des charbonnages de France (CERCHAR), Boite postale No.2, 60550 Verneuil-en-Halatte, France. Re marginal 2101, 13°: Chlorate and perchlorate ex- 3106 plosives must not contain any ammonium salt. The must not be more sensitiveTo flame ignition, impact or friction · than a chlorate explosive having the following composition: 80 per cent potassium chlorate, 10 per cent dinitrotoluebe, 5 per cent trinitrotolu'ene, 4 per cent castor oil and 1 per cent wood flour. See marginals 3150, 3154, 3155 and 3156. Re marginal 2101, 14 °(a) and (b): Explosives of 14 °(a) 3107 and (b) must not be more sensitive to flame-ignition, impact or friction than blasting gelatine containing 93 per cent nitroglycerine or guhr dynamite containing not more than 75 per cent nitroglycerine. They must satisfy the exudation test of marginal 3158. See marginals 3150, 3154(b), 3155 and 3156. Re marginal 2101, l4°(c): Explosives of l4°(c) must be capable of being stored for 48 hours at 7 5 ° C without giving off visible yellowish-brown nitrous fumes. Before and after storing they must not be more sensitive to flame­ ignition, impact or friction than the standard explosive hav­ ing the following composition: 3 7. 7 per cent nitroglycol or nitroglycerine or a mixture of the two, 1.8 per cent guncot­ ton, 4 per cent trinitrotoluene, 52.5 per cent ammonium nitrate and 4 per cent wood flour. See marginals 3150, 3152(b), 3154(a), (b), (c) and (d), 3155 and 3156. 982 ECl>HMEPII THI KYBEPNHIEDI (TEYXOI .6EYTEPO) Re marginal 2131, 1 °(6): The explosive substance 3108 must not be more sensitive lo flame-ignition, impact or fric tion than tetryl. See marginals 3150, 3154, 3155 and 3156. Re marginal 2131, 1 °(c): The explosive substance must 3109 not be more sensitive to flame-ignition impact or friction than penthrite. See marginals 3150, 3154, 3155 and 3156. Re marginal 2131, 5°(d): The transmission charge 3110 must not be more sensitive to flame-ignition, impact or fric tion than tetryl. See marginals 3150, 3154, 3155 and 3156. PART III - APPENDICES TO ANNEX A ~PPENDIX A. l 3000 3099 A. Stability and safety conditions ralating to explosive substances, inflammable solids and organic peroxides The conditions of stability set out below are the standard 3100 minima defining the stability required of substances to be accepted for carriage. These substances may be handed over for carriage only if they fully conform to the following requirements. Re marginal 2101, 1 °, marginal 2171, 4° and mar- 3101 ginal 2401, 7° (a): Nitrocellulose healed for half an hour at 132°C must not give off visible yellowish-brown nitrous fumes. The ig­ nition Lemperalure must be above 180°C. Pyroxylin thread musl satisfy the same conditions of stability as nitrocellulose: See marginals 3150, 3151 (a) and 3153. Re marginal 2101, 3 °, 4 °, and 5 °, and marginal 2401, 3102 7°(6) and (cJ: 1. NitrocellLilose po~ders not containing nitroglycerine; plasticized nitrocellulose: 3 g of powder or of. plasticized nitrocellulose, heated for one hour at 132 °C, must not give off visible yellowish­ brown nitrous fumes. The ignition temperature must be above l 70°C. 2. Nitrocellulose powders containing nitroglycerine: 1 g of powder heated for one hour al l l0°C must not give off visible yellowish-brown nitrous fumes. The ignition temperature must be above 160 ° C. with regard to 1. and 2., see marginals 3150, 3151 (b) and 3153. Re marginal 2101, 6°, 7°, 8°(a) and (b) and 9°(a), (b) 3103 and (c): 1. Trinitrotoluene (tolite), mixtures termed ·liquid trini­ trotoluene and lrinitroanisole of 6 °, hexyl (hexanitrodiphe­ nylamine) and picric acid of 7°(a), pentolites (mixtures of pentaerythritol telranitrate and trinitrotoluene) and hexolites (mixtures of Lrimethylene - trinitramine and trini­ trotoluene) of 7°(b), phlegmalized penthrile and phlegmalized hexogen of 7°(c), Lrinilroresorcinol of 8 ° (a), telryl (trinilrophenylmelhyl-nitramine) of 8 °(6), penlhrite (penlaerythritol letranilrale) and hexogen (trimethylene­ Lrinitramine) of 9°(a), penLoliLes (mixtures of penlhrite and trinitrotoluene) and hexoliLes (mixtures of hexogen and tri­ nitrotoluene) of 9 ° (b) and mixtures of penthrile or hexogen with wax, paraffin wax or substances similar to wax or par­ affin wax of 9°(c); heated for three hours at a temperature of 90°C, musl not give off visible yellowish-brown nitrous fumes. See marginals 3150 and 3 l 52(a). • 2. Organic nilro-compounds of 8 ° other than trinitroresorcinol and Letryl (Lrinilrophenylmethylnilrai'ni­ ne), heated for 48 hours al a temperature of 75°C, must not give off visible yellowish-brown nitrous fumes. See marginals 3150 and 3152(b). 3. Organic nilro-compo\lnds of 8° must nol be more sensitive to ignition, shock or friction than: Re marginal 2170, (2)(d): The explosive charge, after having been stored for four weeks at 50°C, must show no signs of deterioration due to insufficient stability. See marginals 3150 and 3157. Re marginal 2551; 1 ° to 50°: The substances shall be subjected to the tests described in marginals 3154, 3155 and 3156. B. Rules for tests (1) The test procedures set out below are lo be applied when diferrences of opinion arise as lo the acceptability of substances for carriage by road. (2) If other methods or test procedures are used to verify the conditions of stability prescribed above in this Appen­ dix, those methods must lead to the same findings as could be reached by the methods specified below. (3) In carrying out the stability tests by healing de­ sci-ibed below, the temperature of the oven containing the sample under lesl musl nol deviate by more than 2 °C from the prescribed temperature; the prescribed duration of a 30-minule or 60-minule Lest must be observed Lo within two minutes, that of a 48-hour Lest Lo within one hour, and Lhal of a 4-week Lest lo within 24 hours. The oven must be such that the required temperature is restored not more than five minutes after insertion of the sample. (4) Before undergoing the tests prescribed in marginals 3151, 3152, 31~3, 3154, 3155 and 3156, the samples must be dried for not less than 15 hours at the ambi~nt temperature in a vacuum desiccator containing fused and granulated calcium chloride, the sample substance being spread in a thin layer; for this purpose, substances which are neither in powder form nor fibrous shall be ground, or grated, or cul into small pie ces. The pressure in the desiccator must be brought below 6.6 kPa (0.066 bar). (5) (a) Before being dried as prescribed in paragraph (4) above, substances of marginal 2101, 1 ° ( except those con­ taining paraffin wax or a similar substance), 2 °, 9° (a) and (b), and those of marginal 2401, 7°(6), shall undergo pre­ liminary drying in a well-ventilated drying oven, with its temperature set al 70 ° C, until the loss of mass per quarter­ hour in less than 0.3 per cent of the original mass. (5) (b) For substances of marginal 2101, 1 ° (when they contain paraffin wax or a similar substance), 7°(c) and 9°(c), the preliminary drying must be carried out as pre­ scribed. in subparagraph (a) above, except that the temper­ ature of the oven shall be sel al between 40° and 45 °C, (6) Nitrocellulose of marginal 2401, 7 °(a) shall first un­ dergo preliminary drying as prescribed in paragraph (5) (a) above; drying shall then be completed by keeping the nitrocellulose for al least 15 hours over concentrated sul­ .phuric acid in a desiccator. Test of chemical stability under heat Re marginals 3101· and 3102 • (a) Tesl of substances listed in marginal 3101. (1) In each of two glass Lest tubes having the following dimensions: length .................... 350 mm internal diameter . . . . . . . . . . . 16 mm thickness of wall ........ , ... 1,5 mm is placed 1 g of substance dried over calcium chloride (if necessary the drying must be carried out after reducing the substance lo pieces weighing not more than 0.05 g each). Both test tubes, completely covered with loose-filling clo­ sures, are then so placed in an oven that at least four-fifths of their length is visible, and are kept at a constant temper­ ature of 132 °C for 30 minutes. It is observed whether ni­ trous gases in the form of yellowish-brown fumes clearly visible against a while background are given off during this time. (2) In the absence of such fumes the substance is deemed to be stable. 3111 3112 3113 3149 3150 3151 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) 983 (b) Test of powders listed in marginal 3102. (1) Nitrocellulose powders not contammg nitroglycerine, whether gelatinized or not, the plasticized nitrocellulose: 3 g of powder are placed in glass test tubes, similar to those referred to in (a),'which are then placed in an <;>ven kept at a constant temperature of 132°C. (2) Nitrocellulose powders containing nitroglycerine: 1 g of powder is placed in glass test tubes, similar to those re­ ferred to in (a), which are then placed in an oven kept at a constant temperature of ll0°C. • ·(3) The Lest tubes containing the powders referred- to in (l) and .(2) are kept in the oven for one hour. During this time no nitrous gases must be visible. Observation and ap­ praisal as in (a). Re marginals 3103 and 3105 (a) Test of substances listed in marginal 3103, 1. (1) Two samples of explosive each weighing 10 g are placed in cylindrical glass bottles having an internal diame­ ter of 3 cm and a height of 5 cm to the underside of the cover; the bottles are then firmly closed with their covers and heated for three hours at a constant temperature of 90°C in an oven in which they are clearly visible. (2) During this time no nitrous gases must be visible. Observation and appraisal, as under marginal 3151.(a). (b) Test of substances listed in marginals 3103, 2. and 3105. (1) Two samples of explosive each weighing 10 g are placed in cylindrical weighing hollies having an internal di­ ameter of 3 cm and a height of 5 cm Lo the underside of the cover; the bottles are then firmly closed with their covers and heated for 48 hours at a constant temperature of 75 °C in an oven in which they are clearly visible. (2) During this time no nitrous gases must be visible. Observation and appraisal as under marginal 315l(a). Ignition temperature (see marginals 3101 and 3102) (1) The ignition temperature is determined by heating 0.2 g of substance enclosed in a glass test tube immersed in a Wood's alloy bath. The Lest is placed in the bath when the !alter has reached 100 ° C. The temperature of the bath is then progressively increased by 5 ° C per minute. (2) The test tubes must have the following dimensions: length .................... 125 mm internal diameter ........... 15 mm thickness of wall ............ 0.5mm and must be immersed Lo a depth of 20 mm. (3) The Lest must be repealed three times, the tempera­ ture at which ignition of the substance occurs, i.e., slow or rapid combustion, deflagration or detonation, being noted each time. (4) The lowest temperature recorded in the three tests is the ignition temperature. , Test of sensitivity Lo red heat and to flame-ignition (see marginals 3103 Lo 3110) (a) Test in red-hot hemispherical iron crucible (see marginals 3103 to 3106 and 3108 Lo 3110). (1) Quan Li Lies of the explosive Lo be examined increasing from 0.5 g to 10 g are thrown into a red-hot hemispherical iron crucible 1 mm thick and 120 mm in diameter. The results of the test are to be classified as follows: (i) ignition with slow combustion (explosives with an am­ monium nitrate base); (ii) ignition with rapid combustion ( chlorate explo­ sives); (iii) ignition with violent combustion and deflagratiori (black powder); (iv) detonation (fulminate of mercury). (2) The effect on the sequence of events of the amount of explosive used should be taken into account. (3) The explosive to be examined must not show any fundamental difference from the standard explosive. (4) The iron crucibles must be carefully cleaned before each test and replaced at frequent intervals. 3152 3153 3154 (b) Test of ease of ignition (see marginals 3103 to 3110). (1) The explosive to be examined is placed in a small heap on an iron plate in quantities increasing - in the light of the results of the test under (a) - from 0.5 g to a maxi­ mum of 100 g. (2) A burning match is applied to the apex of the small heap and note is taken whether the explosive ignites and burns slowly, deflagrates, or detonates, and whether, once : ignition has occurred, combustion continues even after the match has be'en removed. If no ignition takes place a simi­ lar test is made by bringing the explosive into contact with a gas Oame and noting the same pojnts. (3) The results of the test are compared with those ob­ tained with the standard explosive. (c) Combustion test in conditions of enclosure in a sheet­ steel box (see marginal 3107). (1) The combustion Lest is carried out in a cubical box, made of sheet steel. with edges 8 cm long and a wall thick­ ness of 1 mm. The box is made of annealed mild steel sheet and closed in as tight a manner as possible by folding the edge of the lid over (fig. l ). (2) In the case of explosives sensitive to friction, the top surface should. be covered with a sheet of paper to prevent particles of explosive from finding their way between the edges and remaining trapped there when the edge of the lid is being bent over. The box is completely filled with the ex­ plosive so that the latter has as nearly as possible the same density as when in cartridges. The box is placed in the fire with care; it shall first be wrapped in, for example, several layers of packing paper to avoid immediate ignition of the explosive. A pile of wood 0.8 m high is prepared for the fire by first placing on the ground a thin layer of wood-wool and then on top of it, lying flat, three billets about 0.5 m long and 0.25 m in diameter. Across these are laid three more .bil­ lets of similar size. On top of all are placed three layers of small sticks cut about 0.2 m long, with wo()d-wo()I between the lavers. On each side, threee or four pieces of wood about ·o.5 m long are leant against the pile to prevent it from collapsing while it burns. The pile is set alight with a lighted fuse of wood-wool. • • (3) Observations are made lo see whether the explosive flares or explodes; how long it burns and what phenomena accompany combustion; and what changes the box has un dergone. • (4) The test is carried out four times. A photograph is taken of the steel boxes after they have been used. (d) Test by heating in a confined space in a steel tube with a calibrated orifice plate (steel tube test) (see marginals 3103 to 3110 and 3112). •(l) The tests in (a) to (c) may be supplemented by the following test. COMBUSTION TEST (Re marginal 3154 (c)) Fig. 1: Steel box thickness of wall 1 mm dimensions in mm (1) general view (2) vertical section (3) section A-B (4) fabrication of wall 3154 (5) fabrication of base and cover, (6) edges to be folded in 984 E<DHMEPII THI KVBEPNHIEQI (TEVXOI dEYTEPO) (2) Description of the steel tube (fig. 2): The tube is made by pressing from sheet steel suitable for deep drawing. 11 The dimensions .are: inner diameter 24 mm; wall thickness 0.5 mm; length 75 mm. The open end is fit­ ted with an outer flange. The tube is closed with a pressure­ resistant central-orifice plate fixed tightly on the flange by an externa!Jy-threaded collar slipped over the tube and by a box nut screwed on to this collar. The plate is made from heat resisting chrome stell2/ 6 mm thick. To allow the es­ cape of gases of decomposition, plates are used having cy­ lindrical central orifices (a) with the following diameters: ,../1.0-l.5-2.0-2.5-3-4-5-6-8-10-12-14-16-18-20 mm; a diameter of 24 mm is added when the tube is used without orifice plate and closing device. The threaded collar and nut are made of manganese-chrome steel non-scaling up to 800°C.31 With orifice plates of from 1 to 8 mm diameter, nuts with a perforation (b) 10 mm in diameter must be used; if the diameter of the orifice is above 8 mm, that of the nut perfonation must be 20 mm. Each tubt;: is used for one test only. On the other hand, the orifice plates, threaded collars and nuts may be used again provided they are undamaged. As a check the orifice must be measured after each test. (3) Heating and protective device (fig.3): Heating is pro­ vided by town gas with a net calorific value of 16, 7 5 MJ / m3, from four burners producing about 10 W for a con- . sumption of 0.6 1/s. As destruction of the tube is-possible, heating is done in a splinter-proof welded box, made of steel 10 mm thick, open on one side and at the top. The tube is suspended be­ tween two rods 4 mm in diameter inserted through holes drilled in opposite walls of the box, and is then heated by four Teclu burners (external tube diameter 19 mm), the lowest heating the bottom of the tube, those at the right and left the walls, and that at the rear the closure. The burner tubes are inserted and secured in holes 20 mm in diameter drilled in the walls of the splinter-proof box. The burners are lit simultaneously by~- r.ilot jet and regulated to a plen- . tiful supply of air so that the tips of the blue inner cones of the flames are almost touching the tube. The whole installation is contained in a test stand sepa­ rated from the observation area by a strong wall in which sight holes protected by armoured glass and slatted steel plates are arranged. The splinter-proof box is placed with its open side towards the observation area, care being taken that the flames are not affected by draughts. Equip­ ment for exfracting gases of decomposition and smoke from the explosi.on is installed in the test room. If town gas is not availble, propane can be used for heat­ ing. In such a case the propane is taken from an industrial cylinder fitted with a pressure regulator [4.9 kPa (0.049 bar) (gauge)], through a meter (bellows-type meter with a capacity of 2 litres·at 4.9 kPa (0.049) bar gauge and dis­ tributed by a manifold to the four burners, whose jets have a diameter of 0.8 mm. Each burner consumes not more than about 1. 7 litre of propane a minute. The gas cylinders and the meter are placed outside the test stand. (4) Test procedure: The tube is filled with the explosive substance to within 15 mm of the top, i.e. to a height of 60 mm. If the substance is in powdered form it is compressed by cautiously and gently tapping the tube and then pressing lightly with a small wooden rod. If the substance is gelati­ nous it is put into the tube with the aid of a spatula; after each addition the substance is lightly pressed down with a I/ e.g. Material Specification No. 1.0336.505 g, in accor­ dance with DIN 1623 Sheet 1. 21 e.g. Material Specification No. 1.4873, in accordance with Sheet "Stahl-Eisen-Werkstoff' 490-52. 3/ e.g. Material Specification No. 1.3817, in accordance with Sheet "Stahl-Eisen-Werkstoff' 490-52; ·smMl wooden rod to eliminate occlusions of air. When the quantity of substance inserted has been weighted, the threaded collar is slipped on to the tube, the required ori­ fice plate is put in placr, and the nut is tightened by hand. It is essential to· make sure that norie of the substance is trapped between the flange and the plate, or in the threads. The tube is then put in a rigidly mounted vice with shielding against inadvertent explosion, and the nut is fully tightened with a spanner. The tube, now ready for the test, is sus­ pended between the two rods in the splinter-proof box; the pilot jet is lighted, and when the test stand has been closed the gas supply to the four burners is turned on. At the same TEST BY HEATING IN A STEEL TUBE WITH A CALIBRATED ORIFICE PLATE Re marginal 3154(d) 'r.~ ~ 7-L,0 .. ---111•--® ® Lr ::'.;::7 r 'f'.;~:r--=:,--Q) (I) Fig. 2: Steel tube and accescories Fig. 3: Heating ancJ protective device dimensions in mm; for con struction materials see marginal 3154(d) (2) and (3) (1 } tube V" (la) outer flange (2 ) threaded collar; low-friction thread (3 ) orifice plate a = 1.0 ... 20.0 diameter (4 ) nut b = 10 or 20 diameter (5 ) chamfered surface (6 } 2 flats for spanner size 41 (7 ) 2 flats for spanner size 36 (8 ) splinter-proof box (9 ) 2 supporting rods for the tube (10) assembled tube (11) position of rear burner; the other burners are visible ( 12) pilot jet time a stop-watch is started to measure the time t1 elapsing between the lighting of the burners arid the ignition of the substance, as shown by the escape of a flame from the ori­ fice in the plate, ani:I the time t2 between lighting and explo­ sion. On completion of the test the gas supply is shut off and the exhaust system in the test stand is started up; no one muste enter the starid until a sufficient period of tirrie has elapsed. To make sure that the heating device is working satisfac­ torily, the tests must be preceded by a "dummy run". (5) Interpretation of results: The relative degree of sen­ sitivity of a substance to heating in the steel tube is ex­ pressed by the limiting diameter, this being the orifice with • the largest diameter in millimetres with which, in three tests, at least one tube explodes, that is to say breaks up into at least three pieces. The thermal sensitivity increases with increasing limiting diameter and with decreasing times t 1 and t 2 . Organic peroxides (except those wetted or diluted with volatile substances, e.g. water)'for which the limiting diam I ll>EK 104 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) eter is not less than 2.00 mm should be considered as ex­ plosive substances of Class la (see also note to marginal 2550). (e) Heating test in a·pressure vessel with an orifice plate and bursting disc (pressure vessel test) (see marginal 3112). • (lfFor organic peroxides, the tests shown under (a), (b) and (d) may be supplemented by the following test. HEATING TEST IN A PRESSURE VESSEL WITH AN ORIFICE -PLATE AND BURSTING DISC Re marginal 3154(e) Fig. 4: Assembled pressure vessel; vertical section and plan Fig. 5: Pressure vessel dimensions in mm (1 ) pressure vessel (stainless steel) (la) welded joint (2 ) box nut (fully-killed weldable steel) (3 ) central-orifice plate (stainless steel) (4 ) inert retaining ring, 0.5 thick (5 ) pressure ring (stainless steel) (6 ) brass handle (7 ) bursting disc [for material see marginal 4154 (e) (2)] (8 ) wing nuts (brass M6 DIN 315) (9 ) eye-bolt (stainless steel) (10) pivot for wing nuts (stainless steel) Note: Stainless steel having the following average composition is considered suitable: Cr 18%, Ni 9%, Mn ,;;;; ·2%, Si ,;;;; 1 %, C ,;;;; 0.12%. (2) Description of the pressure ve!?sel: figures 4 to 6 and the appropriate captions give the details of the apparatus used and the dimensions and materials of the constituent parts. It sould be noted that the use of 24 plates is provided for, the diameters of the orifices being: 1.0 - 1.2 - 1.5 • 2.0 2.5,- 3.0 - 3.5 - 4.0 - 4.5 - 5.0 - 5.5 - 6.0 - 7 .0 - 8.0 • 9.0 10.0 - 11.0 - 12.0 - 14.0 - 16.0 • 18.0 • 20.0 • 22.0 and· 24.0 mm. These plates have a thickness of 2.0 mm ± 0.2 mm. The bursting disc is cut by a punch from a sheet of brass 0,05 mm thick withstanding a bursting pressure of 0.53 MPa ± 0.05 MPa (5.3 bar ± 0.5 bar) at normal tempera­ ture. Unannealed rolled brass containing 67 per cent cop­ per is suitable. (3) Heating device: The pressure vessel is heated by technical grade but~ne taken from a cylinder fitted with a pressure regulator. The heat outp4t must be about 3.1 KW. With a net calorific value of 113 MJ/,3 (at 100 kPa (1 bar) and 20°C), the rate of gas supply must be about 0.1 m3/h. A Teclu butane burner is used. The amount of gas used is measured by a rotameter or other meter and regu• lated by the burner valve. Instead of butane, town gas or propane may be used with· a suitable burner, provided that the heat output of the gas is likewise about 3.1 kW (for example, in the case of town gas with a net calorific value of 17 Mj/m3 it would be necessary to supply about 0.67 m3 /h). The gas cylinder and the rotameter or other meter must be situated outside the test area. Appendix 1\.1 !!EATING Tl::.S7 Ji: A PHES~;Uf1E VESSEL IHTll I\N ORif!CE PL/\TE AND UUri~TitlG DISC ~ margtnal 315'1 ( e) ~: . ;; .;. :··'\ · Pressure ring of the vessel; • details .in vertical section· and plan viP.W • dimensions in mm (4) Test procedure: For a normal test, 10 grammes of the substance are placed in the vessel. In the case of a sub~ stance the sensitivity of which is unknown a start is made with smaller quantities: 1 gramme to begin with, then {if possible), 5· grammes, and finally 10 grammes.' The bot­ tom of the vessel must be evenly covered with the sub­ stance. The bursting disc, central orifice plate and retain­ ing ring are then put in place. The wing nuts are tightened by hand and the box nut with a spanner. The bursting disc is covered with enough water to keep it at a low tempera­ ture. The pressure vessel is placed on a tripod (with an inside ring diameter of 6 7 mm) which is inside a protective cylin­ der. The ring at the bottom of the vessel rests on the tripod. • . The burner is lit, the flow of gas set at the required rate, and the flow of air so adjusted that the colour of the flame is blue and the inner cone of the flame light blue. The tripod must be of such a height that the inner cone almost touches the bottom of the vessel. Then the burner is placed under the vessel through a hole in the protective cylinder. The test area must be very well v,ntila.ted and admission to it prohibited during the test. The vessel is observed from outside either by mirrors or through a sight hole in the wall, fitted with armoured glass. The time 1 1 between the beginning of heating and the be­ ginning of reaction (flame, production of smoke, hissing) and the time 12, until the end of the·reaction (detonation, end of hissing and production of smoke, or extinction of the flame) are measured. Th e vessel is then cooled with water and cleaned. 985 986 ECl)HMEPII THI KYBEPNHIEDI (TEYXOI aEYTEPO) (5) Interpretation of results: The relative degree of sen­ sitivity of a substance to heating in the pressure vessel is expressed by the limiting diameter, this being the largest orifice diameter in millimetres with which the bursting disc is broken at least once in three tests. while having remained intact during threee tests with the next larger diameter. The thermal sensitivity increases with increasing limit­ ing diameter and with decreasing times t 1 and t 2 . Organic peroxides (except those wetted or diluted with volatile substances, e.g. water) for which the limiting diam­ eter is not less than 9 mm should be considered as explo­ sive substances of Class la (see also note to marginal 2550). Test of sensitivity to impact (see marginals 3103 to 3110 and 3112) (a) Fall-hammer test I (figs. 7 and 8) against a standard (control) explosive (1) The explosive, after drying as described in marginal 3150, is put into the following form: a. Compact exp losives are rasped fine enough to pass without residue through a sieve of 1 mm mesh; only the residue remaining on a sieve of 0.5 mm mesh is kept for the following test; FALL-HAMMER TEST I Re marginal 3155 (a) ITT ' ' 3155 Fig. 7: Impact device, vertical sec'tion dimensions in mm Fig. 8: Base for impact device. vertical section dimensions m mm A. cement concrete block B. steel block C. protective cylinder D. striker E. anvil F. guide ring b . Explosives in powdered form are passed through a sieve of 1 mm mesh; all that passes through this sieve is kept for the impact test; c. Plastic and gelatinous explosives are formed into small, roughly spherical pills weighing between 25 and 35 mg. (2) The apparatus for carrying out the test consists of a mass which, sliding between two bars, is capable of being set to fall from a prearranged height and of being readily released for the fall. The mass does not fall directly onto the explosive, but falls onto a striker D resting on an anvil E, both in very hard steel and sliding easily in the guide ring F (fig. 7). The sample of explosive is placed between the striker and the anvil. The striker, anvil and guide ring are in a protective cylinder C made of hardened steel and placed on a steel block B embedded in a cement block A (fig. 8). The dimensions of the various parts are given in the fig­ ures. (3) The tests are carried out in turn on the explosive to be tested and on the standard (control) explosive as fol­ lows: ·.• .. FALL-HAMMER TEST II Re marginal 3155 (b) ;;,..--@ @) ~;;. (!) ® Cl) (l) ··1@ @ J ;r ! ; Fig. 9: Fall-hammer II, front and side, general view dimensions in mm Fig. 10: Fall-hammer II, lower part dimensions in mm (1) base, 450 X 450 X 60 (2) steel block, 230 x 250 x 200 (3) anvil, 100 diameter X 70 (4) column (5) median cross-member (6) 2 guides (7) toothed rack (8) graduated scale (9) fall-hammer (drop mass) (10) holding and releasing device (11) locating plate (12) intermediate anvil (interchangeable), 26 diameter x 26 (13) locating ring with orifices (14), impact device a. The explosive, in the form of spherical pill (if it is plas­ tic) or measured with a measuring spoon of 0.05 cm3 ca­ pacity (if it is in-the form of a powder or of raspings), is ar­ ranged with care between the striker and the anvil, whose contact surfa':es must not be moist. The ambient tempera-· lure must not exceed 3 0 ° C nor be less than 15 °C. Each sample of the explosive must be subjected to one impact only. After each test the striker, the anvil and the guide ring must be carefully cleaned, any residue of explosive being removed. b. The tests must begin at heights of fall likely to cause complete explosion of the explosives under test. The height of fall is reduced gradually until the resulting explosion is incomplete or no explosion results. At this height four im­ pact tests are carried out, and if at least one produces a def­ inite explosion, four further fall tests from a slightly lower height are carried out, and so on. c. the lowest height of fall causing a definite explosion in a series of at least four tests at that height is taken as the limit of sensitivity. d. The impact test is normally carried out with a drop mass of 2 kg; however, if the sensitivity to impact with this mass requires a height offal) greater than 60 to 70 cm, the impact test must be carried out with a mass of 5 kg. (b) Fall-hammer test II (gis. 9 to 13) with numerical ex­ pression of impact sensitivity (impact energy in joules). (1) The test described in (a) may be replaced by the fol­ lowing test. ECl>HMEPII THI KYBEPNHIEOI (TEYXOI AEYTEPO) (2) Description of the apparatus: The essential parts of the apparatus are the impact device [see under (4)], the cast steel block with base, the anvil, the column, the guides and the hammer with release device (fig. 9). A steel anvil (100 mm in diameter, 70 mm high) is screwed on the steel block (230 X 250 X 200 mm) cast integral with the base (450 X 450 X 60 mm). Bolted to the back of the steel block is the support into which the column formed from a seamless-drawn steel tube (90 mm outside diameter, 75 mm inside diameter) is fixed. The two guides are fixed to the column by means of threee cross-members and are fit­ ted with a toothed rack to limit the rebound of the hammer and with a movable graduated scale for setting the height of fall. The hammer.,holding and releasing device is adjusta­ ble between the guides and is clamped to them by the oper­ ation of a levyr-nut on two jaws. The apparatus is so fixed on a concrete block (600 600 mm) by means 't>f four an- • choring screws sealed in the concrete that the base is in contact with the concrete over its whole area and the guides are exactly vertical. A wooden splinter-proof box which has a lead lining 2 mm thick and opens easily surrounds the ap­ paratus up to the level of the bottom crossmember. An exhauster enables the explosion gases and dust from the substance to be removed. Appendix A. l FALL-HAMMER TEST II Re Marginal 3155 (b) Fig. 11: Hammer (drop mass) of 5 kg (1) suspension spigot (2) height marker (3) posotioning groove (4) cylindrical striking head (5) rebound catch (3) Description of ihe fall-hammers: Each hammer is provided with two posiiioning grooves holding it between the guides as it drops and with a suspension spigot, a re­ movable cylindrical striking head and a rebound catch which are screwed on to the hammer (fig. 11). The striking head is of hardened steel (HRC 60 to 63); its minimum di­ ameter is 25 mm; it has a shoulder preventing it from being forced into the hammer by the impact. There are three hammers of different weights. The 1-kg hammer is used for highly sensitive substances, the 5-kg hammer for substances of medium sensitivity and the 10-kg hammer for substances of low sensitivity. The 5-kg and 10-kg hammers are of massive and compact steel.* The 1-kg hammer must have a heavy steel centre carrying the striking head and forming with it the main mass of the hammer. The 1-kg hammer is used for drop heights of 10 to 50 cm (impact energy 0.98 to 4,9J), the 5-kg hammer for drop heights of 15 to 60 cm (impact energy 7 .4 to 29.4J), and the 10-kg hammer for drop heights of 35 to 50 cm (im­ pact energy 34.3 to 58.9J). (4) Description of the impact device: The sample to be examined is enclosed in an impact device (fig. 11) consist­ ing of two solid steel cylinders coaxially placed one above the other in a cylindrical guide ring likewise made of steel. The cylinders are steel rollers for anti-friction bearings and are 10 mm in diameter (type with a mean deviation of -4 microns for a tolerance of -2 microns, i.e. a diameter of 10 ~g:gg: mm, 10 mm high, with polished surfaces and rounded edges (radius of curvature o.5 mm) and an HRC hardness between 58 and 65. The guide ring has an outer diameter of 16 mm, a lapped bore of 10 :g:g~~ mm and a height of 13 mm. A cylindrical plug gauge may"be used to chek that the bore diameter is within the prescribed toler­ ances. The cylinders and the guide ring shall be degreased with acetone before use. The impact device is placed on an intermediate anvil 26 mm in diameter and 26 mm high and centred by a locating ring provided with a ring of vent-holes to permit the escape of the gases (figs. 11 and 12). Each striking surface of the cylinders shall be used only once. If an explosion occurs, the guide ring shall not be used again. . •• (5) Preparation of the samples: The·explosive·substance are tested in the dry state. Substances of marginal 2101, 11 0 to 14 °, are tested as delivered provided that their water content agrees with the value indicated by the manu­ facturer. If the water content is higher, the mixtures must be dried before the lest untiltheir moistur content is that in­ dicated. In addition, in the case of solid substances other than those in paste-like form the following points should be ob­ served: a. substances in powdered form are sieved (sieve mesh 0.5 mm); everything that passes through the sieve is used for the test; b. substances which have been con'ipressed, cast or oth­ erwise consolidated are broken into small pieces and sieved; the siftings from 0.5 mm to 1.0 mm in diameter are used for the test. • (6) Test procedure: In the case of substances in pow­ dered form, a sample is taken with a cylindrical measure of 40 mm3 capacity (3.7 mm diameter 3.7 mm). For sub­ stances in paste-like form, a cylindrical tube of the same capacity is used, which is plunged into the mass. After lev­ elling off the excess extending beyond the measure, the sample is taken out by means of a wooden rod. For explo­ sive liquids a fine-drawn pipette of 40 mm3 is used. The sample is placed on the open impact device, which is already in the locating ring on the. intermediate anvil, and in the case of substances in powdered or paste-like form the upper steel cylinder is lightly and carefully pressed with the forefinger until it touches the sample without flattening it. In the case of liquid substances the upper steel cylinder is pressed down with the aid of the depth scale of a vernier • At least St 37-1, in accordance with DIN 17000. 987 988 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI 4EYTEPO) ' gauge until it is 1 mm from the lower cylinder, and held in this position by a rubber ring previously slipped on to it (fig. · 13). The device is plac.ed centrally on the anvil, the protective wooden box is.closed, the hammer suspended at the re­ quired height. is released, and the exhauster is then started up. The test is performed six times at each height of fall. (7) Interpretation of resuits: In interpreting the results of •. the test of sensitivity to impact a distinction is made be­ tween "no reaction", "decomposition" (without flame or detonation; recognizable by colour-change or odour) and "explosion" [with weak to strong detonation*]. The degree of sensitivity to impact of substance is measured by deter­ mining the mass of the hammer in kg and the lowest geight of drop in cm with which an explosion occurs in at least one out of six tests, and the resultant impact energy in joules. The sensitivity of' the substance to impact is greater the lower the impact energy in joules. Appendix A. l FALL-HAMMER TEST II Re marginal 3155 (b) ,0 11 :i:; rffi ~~. 1--,.•---l ® Fig. 12: Impact de~i.ce for substances in powdered or paste-like form dimensions in mm .. Fig. 13: Impact device for liquid substances dimensions iri mm (1 )steel cylinders* (2) guide ring for steel cylinders* (3) locating ring with orifices (a) vertical section (b) plan ( 4) rubber ring (5) liquid substance (40 mm3) (6) space free from liquid * Steel can have the following composition: Cr ± 1.55%, C ± 1 %, Si max 0.25% Mn± 0.35/, HRC 58 .. ,65 (heat-treated steel) * For some substances there is "ignition without detonation". This reaction is, however, regarded as an explosion (and desig­ nated by the terms in inverted commas) because it involves the entire sample and an explosion can also occur under identical conditions. Test of sensitivity to friction (see marginals 3103 to 3110 and 3112). (a) Friction test in a porcelain mortar (1) The explosive is dried over calcium chloride. Asam­ ple of the explosive is compressed and ground in an un­ glazed porcelain mortar by means of a pestle, also un­ glazed. The mortar and pestle must have a temperature about 10 degrees higher than the ambient temperature (15° to 30°C). (2) The results of the test are compared with those ob­ tained with the standard (control) explosive, and are classi­ fied as follows: (i) no effect; • (ii) faint occasional crackling; (iii) frequent crackling or very pronounced occasional crackling. Appendix A. l 3156 TEST WITH FRICTION APPARATUS Re marginal 3156 (b) • Fig. 14: Friction apparatus; elevation and plan view (1) steel base (2) movable carriage Fig. 15: Starting position of peg on sample (3) porcelain plate, 25X25x5 mm, held on the carriage (4) fixed porcelain peg, 10 diameter X 15 mm (5) sample under test, approximately 10" mm3 (6) peg-holder (7) loading arm (8) counterweight (9) switch (lOf wheel for setting carriage at starting position (11) direction to electric drive motor (3) Explosives which, under test, give the result set out in 1. are to be considered as practically insensitive to fric­ tion; if they give the result set out in 2. they are to be con­ sidered as moderately sensitive to friction; if they give the result set out in 3. they are lo be considered as very sensi­ tive to friction. (b) Test with the friction apparatus (figs. 14 and 15) (1) The test described in (a) may be replaced by the fol­ lowing test. (2) Description of the apparatus: The friction apparatus is made up of a cast-steel base on which the friction device proper, comprising a fixed porcelain peg and a movable porcelain plate (fig. 14), is mounted. The porcelain plate is held in a carriage which runs in two guides: On operation of a push-button switch the carriage is moved by an electric motor through a connecting-rod, an eccentric disc and suit EG>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) 989 able gearing in such a way that the porcelain plate moves back and forth once only beneath the porcelain peg. the distance of travel being 10 mm. The peg-holder pivots on an axis so that the porcelain peg can be changed; it is ex­ tended by a loading arm with six notches for hanging a mass. Balance in the '"zero" position (without masses) is achieved by adjusting a counter-weight. When the peg­ holder is lowered on Lo the porcelain plate the longitudinal axis of the porcelain peg is perpendicular to the upper surcace of the plate. One of the masses is hung by means of a ring and hook in the appropriate notch; the load on the peg can be varied from 0.5 lo 36 kg. (3) Description of the porcelain plate and peg: The flat porcelain plastes are made of pure technical white porce­ lain and have the following dimensions: 25 mm X "2'5 mm X 5 mm. Before being fired, their two rubbing surfaces are thoroughly roughened by being rubbed with a sponge. The sponge-marks are clearly visible. The cylindrical porcelain pegs are also.made of techni­ cal white porcelain; they are 15 mm long and 10 mm in di­ ameter and their roughened ends are rounded, with a ra­ dius of curvature of 10 mm. Samples of porcelain pegs and plates of the quality de­ scribed above are deposited with the Bundesantalt for Materialpriifung. Berlin-Dahlem, which can supply the ad­ dresses of manufacturers. As the natural undamaged roughness of the plates and pegs is an essential condition for the reaction of the explo­ sive substance, each part of the surface must be used only once. In consequence, the two end surfaces of each peg are sufficient for two tests, and the two friction surfaces of a plate will each serve for about three to six tests. (4) Preparation of samples: The explosive substances are tested in the dry state. Substances of marginal 2101, 11 ° to 14 ° are tested as delivered, provided that their water content agrees with the value indicated by the manu­ facturer. If the water content is higher, the mixtures must be dried before the test until their moisture content is that indicated. In addition, for solid substances, except those in paste­ like form, the following points should be observed: a. substances in powdered form are sieved (sieve mesh 0.5 mm); everything that passes through the sieve is used for the Lest; b. substances which have been compressed, cast or oth­ erwise consolidated are broken into small pieces and sieved; everything that passes through a sieve mesh of 0.5 mm is used for the test. (5) Test procedure: A porcelain plate is fixed on the car­ riage of the friction apparatus so that the grooves of the sponge - marks on it run transversely to the direction of movement. The quantity lo be tested, about -10 mm3, is taken from substances in powdered form by means of a cy­ lindrical measure (2.3 mm diameter X 2.4 mm); in the case of substances in paste-like form .the sample is meas­ ured by a cylindrical tube which is plunged into the mass. After levelling off the excess extending beyond the meas­ ure, the sample is taken out by means of a wooden rod and placed on the porcelain plate. The firmly - clamped porce­ lain peg is set on the heaped-up quantity as shown in figure l~; the loading arm is loaded with the required mass and the push-bulton switch is operated. Care must be taken that the peg rests on the sample and that there is enough of the substance in front of it lo come under the peg as the plate moves. (6)1nlerprelalion of results: In interpreting the results of the test a distinction is made between "no reaction", "de­ composition" (change.of colour, smell), «ignition", "crack­ ling" a11d "explosion". The relative deg~ee of sensitivity of a substance to fric­ tion in the friction apparatus as described is indicated (without taking the coefficient of friction into account) by the smallest load on the peg in kg, with which ignition, crackling or an explosion occurs iq at least one· out of six test. In this connection, even ignitiQll\and crackling are deemed to be dangerous reactions. The sensitivity of an ex­ plosive substance to friction is greater the lower the ascer­ tained load on the peg (loading weight in relation to length of loading peg). • Explosive liquids and substances in paste-like form are ~ not in general sensitive to friction under the conditions of this test, since because of the lubricating effect the slight frictional heat produced is insufficient to induce ignition. With such subtances the absence of any reaction is no indi­ cation that the substance is not dangerous. The stability of the products referred to in marginal 3111 is to be checked by ordinary laboratory methods. Test of dynamite for exudation (see marginal 3107) (1) T he apparatus for testing dynamite for exudation (figs. 16 to 18) consists of a hollow bronze cylinder. This cylinder which is closed at one end by a plate of the same metal, has an internal diameter of 15:7 mm and a depth of . 40 mm. It is pierced by 20 holes 0.5 mm in diameter (4 sets of 5 holes) on the circumference. A bronze piston, cy­ lindrical over 48 mm of its total length of 52 mm, can slide in the vertical cylinder; this piston, whose diameter is 15.6 mm, is loaded with a mass of 2 220 g so as to produce a pressure of 118 kPa (1.18 bar). (2) A small plug of dynamite weighing 5 to 8 g, 30 mm long and 15 mm in diameter, is wrapped in very fine gauze and placed in the cylinder; the piston and its loading mass are then placed on it so that the dynamite is subjected to a pressure of 118 kPa (1.18 bar). • The time taken for the·appearance of the first signs of oily droplets (nitroglycerine) at the outer orifices of the cyl­ inder holes is noted. (3) The dynamit is considered satisfactory if the time elapsing before the appearance of the liquid exudations is more than five minutes, the test having been carried out at a temperature of 15° to 25° C. •t' 3157 3158 3159 3199 TEST OF DYNAMINE FOR EXUDATJON Re marginal-3158 II ;,u• ~QJ-o: (!) -~ • '-----~==z~l : Fig. 17: Bell-shaped mass of 2 220 g capable of being suspended on the bronze piston Fig. 16: Hollow bronze cylinder, Fig. 18: Cylindrical closed al one end; plan and vertical bronze piston section { dimensions in mm ) (1) 4 sets of 5 holes of 0.5 diameter (2) copper (3) lead plate with central taptjred recess on undersirle (4) 4 openings, about 46 X 56, evenly spaced round periphery 990 E<l>HMEP.lr THI KYBEPNHrEcr (TEYXOr AEYTEPO) A. Provisions relating to the nature of aluminium-alloy receptacles for certain gases of Class 2 I. Quality of the material (1) The materials of aluminium-alloy receptacles which are to be accepted for the gases referred to in marginal 2203 (2) (b) shall satisfy the following requirements: 3200 A B C D Tensile strength, Rm, in MPa ( = N/mm2) 49 lo 186 196 lo 372 196 lo 372 343 lo 490 Yield scress, Re, in MPa ( = N/mm2) (permanent set = 0.2%) 10 lo 167 59 to 314 137 lo 334 206 lo 412 Permanent elongation al fracture (l = 5d) in per cent 12 lo 40 12 to 30 12 to 30 11 to 16 Bend test n = 5 (Rm< 98) 11 = 6 (Rm :S 325) n = 6 (Rm < 325) n = 7 (Rm < 392) (diameter of former d = n.e .. where e is the thicknees of the test piece) 11 = 6 (Rm> 98) 11 = 7 (Rm > 325) 11 = 7 (Rm > 325) n = 8 (Rm > 392) Aluminium Association Series Numher* 1000 5000 6000 2000 * See «Aluminium Standards and Data». fifth edition. January 1976. published by the Aluminium Association, 750 Third Avenue, New York. The actual properties will depend on the composition of the alloy concerned and on the final treatment of the recep­ tacle, but whatever alloy is used the thickness of the recep­ tacle shall be calculated by the following formulae: pMPa X D Pl,u· X D e= or e= 2 X Re + P~m, 20 X Re X Pl,u 1,30 1.30 where e = minimum thickness of receptacle wall. in 111111: P MPa = test pressure, in MPa (Phar = test pressure. in bar) D = nominal external diameter ·or the receptacle. in mm:· and Re = guaranteed minimum 0.2 - per cent proof stress. in MPa ( = N/mm2). • In addition, the value of the minimum guaranteed proof stress (Re) introduced into the formula is 110 case to be greater than 0.85 times the guaranteed minimum tensile strength (Rm), whatever the type of alloy used. Notes: 1. The above characteristics are based on previ­ ous experience with the following materials used for recep­ tacles: Column A: Aluminium, unalloyed, 99.5 per cent pure; Column B: Alloys of aluminium and mag11esiu1i1: Column C: Alloys of aluminium, silicon and magnesium. such as ISO/R209-Al-Si-Mg (Aluminium Association 6351); Column D: Alloys of aluminium. copper and magne­ sium. 2. The permanent elongation at fracture (l =5d) is measured by means of test-pieces of circular section in which the gauge length 1 is equal to five times the dirneter d; if test-pieces of rectangular section are used the gauge length must be calculated by the formula 1 =5.65 ifF:.. () where F O is the initial cross-sectional area of the test-piece. 3. (a) The bend test (see diagram) shall be carried out 011 speciml.'ns obtained by cutting into two equal parts of width 3e, but in no case less than 25 mm, an annular section of a cylinder. The specimens shall not be machined elsewhere than on the edges. (b) The bend test shall be carried out between a mandrel of dia!lleter (d) and two circular supports separated by a distance of (d + 3e). During the test the inner faces shall be separated by a distance not greater than the diameter of the mandrel. (c) The specimen shall not exhibit cracks when it has been bent inwards around the mandrel until the inner faces are separated by a distance not greater than the diameter of the mandrel. (d) The ratio (n) between the diameter of the mandrel and the J hickness of the specimen shall conform to the val­ ues given in the table. Diagram of bend test (2) A lower minimum elongation value is accept~ble on condition that an additional test approved by the competent authority of the country in which the receptacles are 111ade proves that safety of carriage is ensured to the same extent as in the case of receptacles constructed to comply with the rcharacteristics given in the table in para~raph (1 ). (3) The wall thickness of the receptacles al the thinnest point shall be the following: where the diameter of the receptacle is less than 50 mm: not less than 1.5 mm; where the diameter of the receptacle is from 50 to 150 mm: not less than 2 mm; and where the diameter of the receptacle is more than 150 mm: not less than 3 111111. (4) The ends of the receptacles shall have a semicircu­ lar, elliptical or •basket-handle• section; they shall afford the same degree of safety as the body of the receptacle. EG>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) II. Additional official test for aluminium alloys (1) In additional to the tests required by marginals ~215, 2216 and 2217, it is necessary to test for possible mtercrystalline corrosion of the inside wall of the recepta­ cle where use is made of an aluminium alloy containing copper, or where use is made of an aluminium alloy con­ taining magnesium and manganese and the magnesium content is greater than 3.5 per cent or the manganese con­ tent lower than 0.5 per cent. (2) In the case of an aluminium/copper alloy the test shall be carried out by the manufacturer at the time of ap­ proval of a new alloy by the competent authority; it shall thereafter be repeated, in the course of production, for each pour of the alloy. (3) In the case of an aluminium/magnesium alloy the test shall be carried out by the manufacturer at the time of approval of a new alloy and of the manufacturing process by the competent authority. The test shall be repeated whenever a change is made in the composition of the alloy or in the manufacturing process. (4) (a) Preparation of aluminium/copper alloys Before the aluminium/copper alloy is subjected to the corrosion test, the samples shall be cleansed of grease by means of a suitable solvent, and dried. (b) Preparation of aluminium/magnesium alloys Before the aluminium/magnesium alloy is subjected to the corrosion test, the samples shall be heated for seven days at l00°C; they shall then be cleansed of grease by means of a suitable solvent, and dried. (c) Performance of test The inner side of a specime~t measuring 1 000 mm2 (33.3 X 30 mm) of the material containing copper shall be treated at ambient temperature, for 24 hours, with 1 000 ml of an aqueous solution containing 3 per cent NaCl and 0.5 per cent HCI. , (d} Examination After being washed and dried, a section of the specimen 2~ m~ long shall be examined micrographically at a mag­ mficat10n of 100 to 500 x , preferablv after electropolishing. , The depth of attack shall not go beyond the second !aver of grains from the surface subjected to the corrosion tesi· in principle, if the entire first layer of grains is attacked, o~lv part of the second row should be. , In the case of sections, examination shall be performed at right angles to the surface. Where after electropolishing it is found necessary to render the grain boundaries particularly visible for subse­ quent examination, this shall be done by a method accepta­ ble to the competent authority. III. Protection of the inner surface The inner surface of aluminium-alloy receptacles shall be provided with a suitable anti-corrosion coating if the competent testing stations so consider necessary. 3201 3202 3203 3249 B. Requirements concerning the materials and construc­ tion of receptacles intended for the carriage of deeply­ refrigerated liquefied gases of Class 2 (1) Receptacles shall be made of steel, aluminium. alu­ minium alloy, copper, or copper alloy, e.g. brass. How­ ever, receptacles, tanks and shells made of copper or cop­ per alloy shall be accepted only for gases containing no . acetylene; ethylene may however contain not more than 0.005 per cent acetylene. (2) Only materials appropriate to the lowest working temperature of the receptacles, and of their fittings and ac­ cessories, may be used. The following materials shall be accepted for the manu­ facture of receptacles: (a) steels not subject lo brittle fracture at the lowest working temperature (see marginal 3265); 1. fine-grained unalloyed steels, down to a temperature of -60°C; 2. nickel steels (with a nickel content of 0.5 to 9 per cent), down to a temperature of -196 ° C, depending on the nickel content; 3. austenitic chrome-nickel steels, down to a tempera­ ture of -270°C. (b) aluminium not less than 99.5 per cent pure. or alu­ minium alloys (see marginal 3266): (c) deoxidized copper not ness than 99.9 per cent pure. or copper alloys having a copper content of over 56 per cent (see marginal 3267). (1) Receptacles shall be either seamless or welded. (2) Receptacles unrler marginal 2207 made • or austenitic steel, of copper or of copper alloy may alterna­ tively be hard-soldered. The fittings and accessores may either be screwed to the receptacles, or be affixed thereto as follows: (a) aluminium alloy: by welding; . (b) receptacles made of austenitic steel. of copper or of copper alloy: by welding or hand-soldering. The construction of receptacles and their mode or arfix­ ing to the vehicle, Lo the underframe or in the container frame shall be such as to preclude with certainty any such reduction in the temperature of the load-bearing compo­ nents as would be likely to render them brittle. The fasten­ ings of the receptacles, tanks and shells shall themselves be so sesigned that even when the receptacle, tank or shell is at its lowest working temperature they still possess the nec- • essary mechanical properties. 1. Materials, receptacles (a) Steel receptacles The materials used for the manufacture of receptacles. and the weld beads, shall at their lowest working tempera­ tures meet at least the following requirements as to impact strength. . . The tests may be conducted with test-pieces having ei ther a Ushaped or a V-shaped notch. 991 3250 3251 3252 3253 3254 3255 3264 3265 Impact strength•/ of theet metal and weld beads at lowest 1-or~41g temperatures (--:--------M:.:a.::te:.:r.::ia7l --1r------- :!JL/::.c''..::n'......2 1 J cm Unalloyed killed steel F erritic alloy steel Ni<5% Ferritic alloy steel 5%~Ni~9% Austenitic Cr-Ni steel 34.3 34.3 44.1 39.2 27.4 21.6 34.3 31,4 •I Impact strengths deter111ined with differf'nl lf'St-pif'Cl'S nre not rnulunlly cornparablf', Sef' also niarginals 3275 to 3277. b/ The values relate to Lest-pieces with 11 U-shapf'd notch ,1s illuslrnled hPlow, c/ The values relate to test-pieces 1<ilh a V-shapf'd notch l'onfonning Lo ISO R. 1-i8, 992 EG>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) ), . t> I ~ ---------,, I r-' 0 7 ± 0,1 J -L----------~ I I IE 1 55 I ~ I In the case of austenitic steels, only the weld bead need be subjected to an impact-strength test. For working temperatures below -196 ° C, the impact­ strength test is not performed at the lowest working tem­ perature, but at -196 ° C. (b) Receptacles made of aluminium or aluminium alloy The seams of receptacles shall at ambient temperature meet the following requirements as to bending coefficient: Bending coefficient k•/ for the seam Thickness of sheet e in nun Root in compression zone Root in tension zone ~12 >12 lo 20 >20 •I See marginal 3285. c) Receptacles, lank and shells made of copper or cop­ per alloy It is not necessary to carry out tests to determine whether the impact strength is adequate. 2. Tests (a) Impact-strength tests 3267 3268 3274 The impact strength shown in marginal 3265 relate to 3275 test-pieces measuring lOx 10 mm and having a U-shaped or a V-shaped notch. Notes: 1. With regard to the shape of the lest piece. see marginal 3265 (table), foot-notes"! "'"1 •/. 2. For sheets less than 10 mm but not less than 5 mm thick, test0 pieces having a cross-section of l Oxe mm. where «e» represents the thickness of the sheet. shall be used. Such impact-strength tests generally yield higher val­ ues than do such tests on standard lest-pieces. 3. No impact-strength test shall be carried out on sheets less than 5 mm thick, or on their seams. (1) For testing sheet metal the impact strength shall be 3276 determined on three test-pieces. The test-pieces shall be removed at right angles to the direction of rolling in the case of test-pieces with a U-shaped notch and in the direc tion of rolling in the case of test-pieces with a V-shaped notch. (2) For testing seams-the test-pieces shall be takP11 as follows: e~lO:: ,three test-pieces from the centre of the weld: three-test-pieces from the zone of deformation created by the weld (the notch shall be completely outside the melted ' area but as near to it as possible): ~15 ~12 ~12 ~10 ~ 9 ~ 8 Centre of weld . 2 ~e. ,) Zone of deformation i.e. twelve test-pieces in all. e< 20: two sets of three test-pieces (one set 011 the upper face, one set on the lower face) at each of the points indi­ cated below: Centre of weld Zone of deformation i.e. six test-pieces in all. i 3266 (1) For sheet m~tal the average of three tests shall meet 3277 the minimum values given in marginal 3265: none of the centre of weld Zone of deformation The test-pieces shall be so machinecl as fo havp the max imum possible thickness. ·, 10< e ~ 20: three test-pieces from the cPnlrt· of th:· weld;' three test-pieces from the zone of cleformation: values may be more than 30 per cent below the minimum specified. (2) For welds the average values obtained from three of the test-pieces taken at the different points. centre of weld and zone of deformation, shall correspond lo the minimum values shown. None of the values may be more than 30 per · cent below the mii1imum specified. 3278 3284 Cl>EK 104 E(l)HMEPII THI KYBEPNHIEQI (TEVXOI aEYTEPO) 993 (b) Determination of bending coefficienl (1) The bending coerficienl k rer('ITPd lo i11 111argi11al 3266 is defi11ed as follows: • where , 4 K = 50 e = thickness of sheet i11 111111: and r = mean radius of curvature in 111111 ol' lh(' lesl-pit>('(' 1111<'11 the first crack appears in the h·11sio11 w,w, (2) The bending coefficient k shall be determined for the seam. The width of the test piece shall be equal to 3 e. (3) Four tests shall be performed on the seam, two with the root in the compression zone (fig. 1) and two with the root in the tension zone (fig. 2); all values obtained-shall meet the minium value requirements of marginal 3266. Fig. 1 Fig. 2 C. Provisions relating to tests on aerosol dispensers and nonrefillable containers for 0 gases under pressure of Class 2, 10° and 11 °. 1. Pressure and 'bursting tests on receptacle model Hydraulic pressure tests shall be carried out on at least five empty receptacles of each model; (a) until the prescribed test pressure is reached, by which time no leakage or visible permanent deformation shall have occured; and (b) until leakag~ or bursting occurs; the dished end, if any, should yield first and the receptacle not leak or burst until a pressure 1.2 times the test pressure has been reached or passed. 2. Tightness (leakproofness) tests on all receptacles (1) For the test on aerosol dispensers (10°) and non­ refillable containers for gas under pressure (11 °) in a hot­ water bath, the temperature of the bath and the duration of the test shall be such that the internal pressure of each re­ ceptacle reaches al least 90 per cent of the internal pres­ sure that would be reached at 55 ° C. However, if the contents are sensitive to heat or if the re­ ceptacles. are made of a plastics material which softens at this test temperature, the temperature of the bath shall be from 20° to 30°C; in addition, one dispenser out of every 2,000 shall be tested at the temperature prescribed in the foregoing paragraph. (2) No leakage or permanent deformation of receptacles shall occur. The provision concerning permanent deforma­ tion is not applicable to receptacles which, being made of a plastics material, soften. Tests relating to inflammable liquids of classes 3, 6.1 and 8 Test for determining flash-point (1) The flash-point is determined by means of one of the following types of apparatus: (a) for use at temperatures not exceeding 50°C: Abel, Abel-Pensky, Luchaire-Finances, Tag; (b) for use at temperatures above 50°C: Pensky­ Martens, Luchaire-Finances; (c) failing these, any other closed-cup apparatus capable of giving results within 2 °C of those which an apparatus listed above would give at the same place. (2) To dermine the flash-point of paints, gums and simi­ lar viscous products containing solvents, only apparatus 3286 3290 3291 3292 3293 3299 3300 and test methods suitable for determining the flash-point of viscous liquids may be used, such as method A of IP stan­ dard 170/59 or more recent IP standards, German stan­ dards DIN 53 213 and TGL 14 301, leaflet 2. • The test procedure shall be: (a) for the Ab\e apparatus, that ofIP* standard·33/44; this standard may also be used for the Able-Pensky appa ratus; (b) for the Pensky-Martens apparatus, that of IP* stan­ dard 34/47, or that of ASTM** standard D.93/46; (c) for the Tag apparatus, that of ASTM** standard' D.53/46; ( d) for the Luchaire apparatus, that of the Instruction an­ nexed to the ministerial order (arrete ministeriel) (France) of 26 October 1925 issued by the Ministere du Commerce et de l'lndustrie and published in the Journal Officiel of 29 October 1925. If any other apparatus is used, the following precautions must be taken: 1. The test must be performed in a place free from. draughts. 2. The rate of temperature increase of the liquid being tested must never exceed 5 ° C per minute. 3. The pilot-flame must be 5 mm ( ± 0.5 mm) long. 4. The pilot-flame must be applied to the opening of the receptacle after each rise of 1 ° C in the temperature of the liquid. 3301 In the event of a dispute as to the classification of an in- 3302 flammable liquid, the item number proposed by the sender shall be accepted if a check-test of the flash-point, carried out on the liquid in question, yields a result not differing by more than 2 ° from the limits (21 °, 55 ° and 100° respec- •• tively) stated in marginal 2301. If a check-test yields a re sult differing by more than 2 ° C from these limits, a secopd check-test must be carried out, and the highest figure ob---,. , tained shall be adopted. Test for determining peroxide contexitt-,;~c;, '., The peroxide content of a liquid shall be determined as : 3303 follows: a quantity p (about 5 g, weighed .to the nearest ~g) of the liquid to be titrated is placed in an Erlenmeyer flas~; 20 cm3 of acetic anhydride and about 1 g of powdered.solid potassium iodide are added; the flask is shaken.and,"after 10 minutes, heated for 3 minutes to about 60°C; it is then allowed lo cool for 5 minutes, after which 25 cm3 of water are added. After being left standing for half an hour, the io-. dine liberated is titrated with a decinormal solution of so dium thiosulphate, no indicator being added. Complete decolorization indicates the end of the reaction·. If n is the number of cm3 of thiosulphate solution required, the per centage of peroxide (calculated as H..i?OJ) present in the sample is obtained by the formula l in lO0p. Test for determining fluidity To determine the fluidity of liquid or viscous substances and mixtures of Class 3, the following test method should be used. (a) test apparatus Commercial penetrometer conforming to ISO Standard 2137 /1972, with a guide rod of 47.5 ± 0.05 g; sieve disc of duralumin with conical bores and a mass of 102.5 ± 0.05 g (see figure); penetration vessel with an inside diam­ eter of 72 mm to 80-mm for reception of the sample.· (b) Test procedure The sample is poured into the penetration vessel not less than half an hour before th e measurement. The vessel, * The Institute of Petroleum, 61, New Cavendish Street, L.wn­ don, W.L ** American Society for Testing and Materials, 1916 Rae~ Street, Philadelphia 3, (pa.). 3304 3309 994 ECJ>HMEPII THI KYBEPNHIEtU: (TEYXOI dEYTEPO) which is hermetically closed, is kept immobile until the measurement. The sample is heated in the hermetically closed penetration vessel to 35 °C ± 0.5 Kand is placed on the penetrometer table only directly before the meas­ urement (not more than two minutes). The centre S of the sieve disc is then brought into contact with the surface of the liquid and the penetration depth measured in relation to time. PENETROMETER adjust mass to 1 02,5 g ± 0,05 g J S press fit = ci en Ln en c.D Tolerances not specified are.± 0.1 mm Evaluation of tesi results A substance shall not be subject to the conditions of class 3 of ADR if, after the centre S has been brought into contact with the surface of the sample, the penetration indi­ cated by the dial gauge (a) after a loading time of 5 s ± 0.1 s, is less than 15.0 mm ± 0.3 mm, or (b) after a loading time of 5 s ± 0.1 s, is less than 15.0 mm ± 0.3 mm, but the additional penetration after an­ other 55 s ± 0.5 sis smaller than 5.0 mm ± 0.5 mm. Note: In the case of samples having a flow point, it is often impossible to produce a plane surface in the penetra­ tion vessel and, hence, to fix clear initial measuring condi­ tions for the contact of the centre S. Furthermore, with some samples, the impact of the sieve disc can cause an elastic deformation of the surface and in the first few sec­ onds simulate a deeper penetration. In all these cases it may be useful to make the evaluation mentioned in (b) above. Appendix A.4 Reserved 3311 3312 3399 3400 3499 Appendix A.5 GENERAL PACKING CONDITIONS: TYPES OF PACKAGING: REQUIREMENTS APPLICABLE TO PACKAGINGS: TEST.REQUIREMENTS FOR PACKAGINGS Note: These requirements apply to packagings contain­ ing substances of classes 3, 6.1 or 8. Section I General packing conditions (1) Packagings shall be so manufactured and closed as 3500 to prevent any leakage of contents from a package pre pared for dispatch such as might be caused in normal con ditions of carriage particularly by changes in temperature, humidity or pressure. No dangerous substance shall ad here to the outside of packages. These provisions apply both to new and to reused packagings. (2) Parts of packagings which are in direct contact with dangerous substances shall not be affected by chemical or other action of those substances; where necessary, they shall be provided with a suitable inner coatinp; or treatment. Such parts of packagings shall not incorporate constituents liable to react dangerously with the contents, lo form haz­ ardous produts, or significantly to weaken them. (3) Each packaging except inner packagings of combi­ nation packagings shall conform to a design type tested and . approved in accordance with the requirements laid down in section IV. Mass-produced packagings shall conform to the approved design type. (4) Where packagings are filled with liquid substances, sufficient ullage shall be left to ensure that no leakage or liquid substance and no permanent distortion of the pack­ aging occurs as a result of expansion of the liquid sub­ stance, due to temperatures which may be attained during carriage. For a filling temperature which may be attained • during carriage. For a filling temperature of 15 ° C, the de­ gree of filling shall be determined as follows, unless other­ wise provided under a particular class, either: (a) • boiling point ~ 60 ~ 100 ~ 200 (initial boiling point) < 60 of the Substance in °C < 100 < 200 < 300 Degree of filling as a percentage of the capacity of the packaging 90 92 94 96 98 or (b) Degree .of filli1ig = per cent of the capacity of the packaging. In this formula a represents the mean coefficient of cubic expansion of the liquid substance between 15 ° and 50 °; that is to say, for a maximum rise in temperature of 35 ° C a is calculated according to the formula: CJ; = du; and d~0 being the relative densities * / of the liquid at 1 ::i ° C and 50 ° C and tF the mean temperature of the liquid at the time of filling. . * Relat ive density (d) is considered to be synonymous with spe­ cific gravity (SG) and will be used throughout this appendi". ~ 300 98 ECl>HMEPII: THI KYBEPNHIEQI (TEYXOI · AEYTEPO) .(5) Inner packagings shall be packed in an outer pack­ aging in such a way that, under normal conditions of car­ riage, they cannot break, be punctured or leak their con­ tents into the outer packaging. Inner packagings which are liable to break or be punctured easily, such as those made of glass, porc,elain or stoneware or of certain plastics mate~ rials, etc., shall be secured in outer packagings with suita­ ble cushioning material. Any leakage of the contents shall not substantially impair the protective properties of the cushioning material or of the outer packaging. • (6) Inner packagings containing different substances which may react dangerously with one anotehr shall not be placed in the same outer packaging (see also the mixed packing provisions under the various classes). (7) The closure of packagings containing wetted or di­ luted substances shall be such that the percentage ofliquid (water, solvent or phlegmatizer) does not fall below the pre­ scribed limits during carriage. (8) Where oyerpressure may develop i~ a package through the emission of gas from the contents (as a result of temperature increase or other causes), the packaging may be fitted with a vent provided that "the gas emitted will not cause any danger on account of its toxicity, its inflammability, the quantity released, etc. The vent shall be so designed that, when the packaging is in the attitude in which it is intended to be transported, leakages of liquid and the penetration of foreign matter are prevented under normal conditions of carriage. However, a substance may be carried in such a packaging only where a vent is ex­ pressly prescribed for that substance in the conditions of carriage of the relevant class. (9) New, reused or reconditioned packagings shall be capable of passing the tests prescribed in section IV. Be­ fore being filled and handed over for carriage, every pack­ aging shall be inspected and its freedom from corrosion, contamination or other damage, verified. Any packaging which shows signs of reduced strenght in comparison with the approved design type shall no longer be used or shall be so reconditioned that it is able to withstand the design­ type tests. (10) Packagings used for liquids shall undergo a leakproofness test if so required by and under the condi­ tions prescribed in marginal 3560. (11) Liquids shall be filled only into packagings which have an appropriate resistance to the internal pressure that may be developed under normal conditions of carriage. Packagings marked with the hydraulic test pressure as pre­ scribed in marginal 3512 (1) (d) shall be filled only with a liquid having a vapour pressure: (a) such that the total gauge pressure in the packaging (i.e. the vapour pressure of the filling substance plus the partial pressure of air or other inert gases, less 100 kPa) at 55 °C determined on the basis of a maximum degree of fill­ ing in accordance with (4) above and a filling temperature of 15 ° C, will not exceed two-thirds of the marked test pres­ sure; or (b) at 50°C less than ·four-sevenths of the sum of the marked test pressure plus 100 kPa; or (c) at 55°C less than two-thirds of sum of the marked test pressure plus 100 kPa. Section II Types of packaging Definitions (1) Subject to the special provisions for each class, the packagings listed below may be used: Drums: flat-ended or convex-ended cylindrical packa­ gings made of metal, fibre, plastics, plywood or other suita­ ble materials. This definition also includes packagings of other ·shapes made of metal or plastics, e.g. round taper­ necked packagin•gs, or pail, shaped packagings. Wooden barrels and jerricans are not covered by this definition. Wooden barrels: packagings made of natural wood, of round cross-section, having convex walls, constisting of staves and heads and fitted with hoops. 3501 3509 3510 Jerricans: metal or plastics packagings of re~tangular or polygonal cross-section with one or more orifices. . Boxes: packagings with full rectangular or polygonal sides, made of metal, wood, plywood, reconstituted wood, fibreboard, plastics or other suitable metarial, without ori­ fices. Bags: flexible packagings made of paper, plastics film, textiles, woven material or other suitable·materials. • Composite packagings (plastics material): packagings consisting of an inner plastics receptacle and an outer packaging (made of metal, fibreboard, plywood; etc.). Once assembled, such a packaging remains thereafter an inseparable unit; it is filled, stored, despatched and emp­ tied as such. Composite packagings (glass, porcelain or stoneware): packagings consisting of an inner glass, porcelain or stone­ ware receptacle and an outer packaging (made of metal, wood, fibreboard, plastics material, expanded plastics ma­ terial, etc.). Once assembled, such a packaging remains thereafter an inseparable unit; it is . filled, stored, despatched and emptied as such. It shall be tested in accor­ dance with marginals 3552 (1) (a) or (b), 3553 and 3554. Compination packagings: a combination of packagings for transport purposes, consisting of one or more inner packagings secured in an outer packaging in accordance with marginal 3500 (5). (2) Subject to the special provisions for each class, the following packagings may also be used: Composite packagings (glass, porcelain or stoneware): if tested in accordance with marginal (3552 (1) (e). Light gauge metal packagings: packagings of circular, elliptical, rectangular or polygonal cross-section, (also con­ ical) and tapernecked and pail-shaped packagings made of tinplate or light metal, having a wall thickness of less than 0.5 ·nm, flat or convex bottoned and with one or more ori­ fices which are not covered in marginal 3510 (1) as drums or jerricans. (3) The following definitions are applicable to packagings in (1) and (2) above: Closures: devices shich close an opening in a receptacle; Inner packagings: packagings for which an outer pack­ aging is required ·for carriage. Inner receptacles: receptacles which require an outer packaging in order to perform their containment function. • Maximum capacity (as used in Section III): the maxi­ mum inner volume receptacles or packagings expressed in litres. Maximum net mass: the maximum net mass of contents in a single packaging or maximum conbined mass of inner packagings and the contents thereof expressed in kilo­ grams. Outer packaging: the outer protection of a composite or combination packaging together with any absorbent mate­ rials, cushioning and any other components necessary to contain and protect inner receptacles or inner packa­ gings. Packages: the complete product of the packing opera­ tion, consisting of the packaging and its contents prepared for dispatch. Packagings: receptacles and any other components or materials necessary for the receptale to perform its con­ tainment function. Receptacles: containment vessels for receiving and holding substances of articles, including any means of clos ing. ' Note: the "inners" of "combination packagings" are al­ ways termed "inner packagings" not "inner receptacles" A gl~ss bottle is an example of such an "inner packaging". The "inners" of "composite packagings" are normally termed "inner receptacles". For example, the "inner" of a • 6HA1 composite packaging (plastics material) is such an "inner receptacle" since it is normally not designed to per 995 996 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) forrri a containment function without its "outer packaging" and is not therefore an "inner packaging". Coding of design types for packagings conforming to marginal 3510 (1) and (2) (1) The code number consists of an Arabic numeral indicating the ty;:ie of packaging, e.g. drum, jerrican etc.; a capital letter or letters (latin characters) indicating the nature of the-material, e.g. steel, wood, etc.; where necessary, an Arabic nu~eral indicating the cate­ gory of packaging within the type to which the packaging belongs. • In the case of composite packagings, two capital letters (Latin characters) shall be used. The first shall indicate the material d the inner receptacle and the second that of the outer packaging. In the r;ase of combination packagings, only the code number for the outer packaging shall be used. The following numerals shall be used for the type of packaging: 1. Drum 4. Box 2. Wooden barrel· 5. Bag 3. Jerrican 6. Composite packaging 0. Light gauge metal packagings The following capital letters shall be used for the types of material: A. Steel (all types and surface treatments) B. Aluminium C. Natural wood D. Plywood . F. Reconstituted wood G. Fibreboard H. Plastics material, including expanded plastics mate rial L. Textile M. Paper, niuitiwall N. Metal (other than steel or aluminium) P. Glass, porcelain or stoneware (2) Three packi11g groups are provided for in the special requirements for each class, according to the degree of danger presented by the substances to be carried: Packing Group I: for substances of group (a); Packing Group. II: for substances of group (b); . Packing Group III: for substances of group (c) of the items in the. list of substances. The code number of the packaging shall be followed in the marking by a letter indicating the groups of substances for wich the design type is approved as follows: X for packagings for substances in packing groups I to III; • Y for packagings for substances in packing groups II and III; and Z for packagings for substances in packing group Ill. Marking (1) Each packaging shall bear durable and clearly visible marking. The marking for new packagings manufactured in con formity with the approved type consists of: • I a) Ii) the sym~ol for packagings conform ing to marginal 3·510 (1). For metal packagings on whi'ch the marking is stamped. the leiters UN may be applied in stead of the symbol (ID (ii) the symbol "ADR" (or "RID/ ADR" for packagings approved for rail transport as well as road transport) in 3511 3512 stead of the symbol ®Un for packagings conforming lo marginal 3 510 (2) (b) the packaging code number in accordance with mar­ ginal 3511 (l); (c) a code in two parts; (i) a letter (X, Y or Z) designating the packing group (s) for which the design type has been approved; (ii) for packagings without inner packagings, intended to contain liquids having a viscosity at 23 °C of200 mm2/s or less,· the relative density (rounded off to the first decimal), to which the design type has been tested if more than 1.2. For packagings intended to contain liquids having vis­ cosity at 23 °C of more than 200 mm2/s solids or inner packagings, the maximum gross mass in kilograms; (d) either a letter "S" denoting that the packaging is in­ tended to contain liquids having a viscosity at 23 ° C of more than 200 mm2/s solids or inner packagings, or, where a hydraulic pressure test has been successfully passed, the test pressure in Kpa rounded off to the nearest 10 Kpa. • (e) the year of manufacture (last two digits); in addition for packagings of types lH and 3H, the month of manufacture; this part of the marking may be affixed in a different place from other particulars. A suita­ ble method is; tQ'' 12 1 ', 1 8 ◄ 4 7 6 5 (f) the mark* of the State in which the approval was is­ sued; (g) either a registration number and the name of mark of the manufacturer or some other pakaging identification mark specified by the competent authorities. (2) Every re-usable packaging liable to undergo recon­ ditioning which might obliterate the packaging markings shall bear the marks specified in (a), (b), (c), (cl) and (e) in a parmanent form (e.g. by stamping) so as to withstand the reconditioning process. (3) The registration number is valid for only one design type or series of design types. Different surface treatmens may fall within the same design type. A ··series of design types" means packagings of the same structural design, wall thickness, material and cross­ section, which differ only in their lesser design heights from the design type approved. The closures of receptacles shall be identifiable as those referred to in the test report. (4) After reconditioning a packaging the reconditioner shall affix to it, near the durable marks required by (a) to (e) the following sequence of marks: (h) the mark* of the State in whose territory the recondi­ tioning was carried out; (i) the name or authorized of the reconditioner; G) the year of reconditioning, the letter "R" and, for every packaging which has successfully undergone the leakproofness test in accordance with marginal 3500 (10), the additional letter "L". '(5) Packagings marked in accordance with this para­ graph but which were approved in a State which is not a contracting party to the ADR may nevertheless be used for carriage under ADR. * Distinguishing sign for motor vehicles in international trafic prescribed in the Vienna Convention on Road Traffic (1968). ' ECl>HMEPII THI KYBEPNHIEQI (TEVXOI AEYTEPO) 997 (6) Examples of the markings for a new steel drum: lAl/Yl .4/150/83 NL/VL123 (a) (i), (b), (c), (d) and (e) (f) and (g) For a reconditioned steel drum: lAl/Yl.4/150/83 (a) (i), (b), (c), (d) and (e) NL/RB/84/RL (h), (i) and (j) For new light gauge metal packagings: RID/ ADR/OAl/Y /75/83 (a) (ii), (b), (c), (d) and (e) Non-removable NL/VL 123 (f) and (g) RID/ADR/OA2/Y/83 Type head Material A. Conforming lo marginal 3510 (1) and marked "UN" 1. Drums A. Steel B. Aluminium D. Plywood G. Fibre H. Plastics 2. Barrels C. Wood 3. Jerricans A. Steel H. Plastics 4. Boxes A. Steel B. Aluminium C. Natural wood D. Plvwood F. R~constituted wood G. Fibreboard H. Plastics . * Under 3538 these packagings may be ust>d as !he ouh·r pa<'kagi11gof <'ornl•i1wlio11 packaging. " (a) (ii), (b), (c) and (e) NL/V!-, 124 (f) and (g) Removable head, inte nded for liquids with a viscosity al 23 °C esxeeding 200 mm2/s Certification 3513 The manufacturer certifies, ·by affixing marking in ac­ cordance with marginal 3512 (1) that mass-produced packagings correspond to the approved design type and that the requirements referred to in the approval have been met. Index of packagings :~.i 1-1 The follm,ing t,-pes and cod<'s or p,u-kaµ:i11µ:,; ar(' ,. , signed: Category Code Marginal non-removable head lAl 3520 removable head 1A2 non-removable head 181 3521 removable head 182 1D 3523 :: lG 3525 non-removable head lHl .. 3526 removable head·' 1H2 bung type 2Cl 3524 removable head non-removable head 3Al 3522 removable head 3A2 non-removable head 3Hl 3626 removable head 4Al 3532* with liner 4A2 4Bl 3532* with liner 482 ordinary 4Cl 3-527* with sift-proof walls 4C2 4D 3528* 4F 3529* 4G 3530* expanded 4Hl 3531* solid 4H2 998 ECl>HMEPII · THI KYBEPNHIEQI (TEYXOI dEYTEPO) Type Material Category Code Marginal A. Conforming to marginal 3510 (1) and marked "UN"" ·-- .. ···--- -···-----·--·-- ·--·--·•-•' ·---- - - . -...... -. - -~~ 5. Bags H. Woven plastics without inner lining or coating 5Hl sift-proof 5H2. 3534 water resistant 5H3 H. Plas,ics film - 5H4 3535 L. Textile without inner lining or coating SU 3533 sift-proof 5L2 water resistant 5L3 M. Paper multiwall 5Ml 3536 multiwall, water resistant 5M2 6. Composite packagings H. Plastics receptacle in steel drum 6HA1 in steel crate or box 6HA2 in al~minium drum 61-1B1 in aluminium crate or box 6HB2 in wooden box - 6HC 3537 in plywood drum 6HD1 in plywood box 6HD2 in fibre drum 6HG1 in fibreboard box 6HG2 in plastics drum 6HH B. Packagings which may conform to marginal 3510 (1) or (2) 6. Composite packagings P. Class porcelain or stoneware in steel drum 6PA1 receptacle in steel crate or box 6PA2 in aluminium drum 6PB1 in aluminium crate or box 6PB2 in wooden box 6PC in plywood .drum 6PD1 in wickerwork hamper 6PD2 3539 in fibre drum 6PG1 in fibreboard box 6PG2 in expanded plastics packaging 6PH1 in solid plastics packaging 6PH2 ECl>HMEPII THI KYBEPNHIEDI (TEYXOI AEYTEPO) Type Material Category Code Marginal C. Conforming only to marginal 3510°(2) and marked "ADR" (or "RID/ADR") .. 0. Light gauge metal A. Steel packaginp .. Section UI. Requirements for packagings A. Packagings conforming to marginal 3510 (1) Steel drums lAl non-removable head 1A2 removable head (a) The sheet metal for the body and ends shall be of suitable steel and of a gauge appropriate to the drum's ca pacity and intended use. • (b) Body seams shall be welded on drums intended to contain more than 40 litres of liquid. Body seams shall be mechanically seamed or welded on drums intended lo con­ tain solids or 40 litres or less of liquids. (c) Head and chime seams shall be mechanically seamed or welded. (d) If there are built-on rolling hoops they shall be fitted tightly on the body and so secured that they cannont shift. Rolling hoops shall not be spot-welded. (e) Internal coatings of lead, zinc, tin, lacquer and the like shall be tough and resilient and shall adhere lo the steel al every point, including the closures. (f) Openings for filling, emptying and venting in the bod­ ies or heads of non-removable head (lAl) drums shall not exceed 7 cm in diameter. Drums with larger openings are considered to be of the removable head type (1A2). • (g) Closures shall incorporate a leakproof gasket except where a taper thread ensures comparable leakprofness. (h) Closures of non-removable-head drums shall either be of the screw-threaded type or be capable of being se­ cured by a screw-threaded device or at least equally effec tive device. • (i) Closure devices for removable head drums shall be so designed and applied that they will remain secure and drums will remain Jeakproof under normal conditions of carriage. Caskets or other sealing elements shall be used with all removable heads. 0) Maximum capacity of drum: 450 litres. (k) Maximum net mass: 400 kg. Aluminium drums lBl non-remo'vable head 1 B2 removable head (a) The body and heads shall be of aluminium at least 99 per cent pure, or of an aluminium-base alloy having corro­ sion resistance and mechanical properties appropriate to the capacity of the drum and its intended use. (b) Openings for fillings, emptying and venting in the bodies or heads of non-removable head ( 1B 1) drums shall not exceed 7 cm in diameter. Drums with larger openings are considered to be of the removable head type (182). (c) Aluminium drums 181. End seams, if any, shall be adequately reinforced for their protection. If there are any body and end seams they shall be welded. The closure shall either be of the screw­ threaded type or be capable of being secured by a screw­ threaded device or a device at least equally effective. Clo­ sures shall incorporate a leakproof gasket except where a taper thread ensures comparable leakproofness. (d) Aluminium drums 1B2. The body of the drum shall either be seamless or have a welded seam. The closures shall be so designed and fitted 3515 3519 3520 3521 .. !)On-removable head OAl ' 354() removable· head OA2 that they will remain secure and the drums will remain leakproof under normal conditions of carriage. Caskets or other sealing elements shall be used with all removable heads. (e) Maximum capacity of drum: 450 litres. (f) Maximum net mass: 400 kg. Steel jerricans 3Al non-removable head 3A2 removable head (a) Body and heads shall be constructed of steel sheet of a suitable type and of adequate thickness in relation to the capacity of the jerrican and its intended use. (b) Chimes of all jerricans shall be mechanically seamed or welded. Body seams of jerricans intended to contain more than 40 litres of liquid shall be welded. Body seams of jerricahs intended to carry 40 litres or less shall be me­ chanically seamed or welded. (c) Openings injerricans (3Al) shall not exceed 7 cm in diameter. Jerricans with larger openings are considered to be of the removable head type (3A2). (d) The closure shall either be of the screw-threaded type or be capable of being secured by a screw-threaded device or a device at least equally effective. (e) Maximum capacity of jerrican: 60 litres. (f) Maximum net mass: 120 kg. Plywood drums lD (a) The wood used shall be well seasoned, commercially dry and free from any defect likely to lessen the effective­ ness of the drum for the purpose intended. If a material other than plywood is used for the manufacture of the ends, it shall be of a quality equivalent to the plywood. (b) At least ·two-ply .plywood shall be used for the body and al least three-ply plywood for the ends; the plies shall be firmly glued together, with their grain crosswise, by a water-resistant adhesive. (c) The body and ends shall be of a design appropriate to the capacity of the drum and its intended tise. (d) In order to prevent sifting of the contents, lids shall be lined with kraft paper or same other equivalent material which shall be securely fastened to the lid and extend lo the outside along its full circumference. v•, (e) Maximum capacity of drum: 250 litres. (f) Maximum net mass: 400 kg. Wooden barrels 2Cl bung type 2C2 removable head (a) The wood used shall be of good quality, straight­ grained, well-seasoned and free from knots, bark, rotten wood, sapwood or other defects likely ·10 lessen the effec­ tiveness of the barrel for the purpose intended. (b) The body and ends shall be of a design appropriate to. the capacity of the barrel and its intended use. (c) Staves and ends shall be sawn or cleft with the grain so,that no annual ring shall extend over more than half the thickness of a stave or head. (d) Barrel hoops shall be of steel or iron and good qual­ ity. The hoops of2C2 barrels with removable heads may be of a suitable hardwood. (e) Wooden barrels 2Cl: The diameter of the bung-hole shall not exceed half the width of the stave in which it is placed. 999 3522 3523 3524 1000 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) (t) Wooden barrels 2C2: Heads shall fit tightly into the orozes. (g) Maximum capacity of barrel: 250 litres. (h) Maximum net mass: 400 kg. Fibre drums lG (a) The body of the drum shall consist of multiple plies of heavy paper or fibreaboard (without corrugations) firmly glued or laminated together and may include one or more protective layers of bitumen, waxed kraft paper, metal foil, plastics material, etc. (b) Heads shall be of natural wood, fibreboard, metal, plywood or plastics material and may include one or more protective layers of bitumen, waxed kraft paper, metal foil, plastics material, etc. (c) The body and heads of the drum and their joins shall be of a design appropriate to the capacity of the drum and its intended use. (d) The assembled packaging shall be sufficiently water­ resistant so as not to delaminate under normal conditions of carriage. (e) Maximum capacity of drum: 450 litres. (t) Maximum net mass: 400 kg. Plastics drums and jerricans 1 Hl drums, non-removable head 1 H2 drums, removable head 3 Hl jerricans, non-removable head 3 H2 jerricans, removable head (a) The packagings shall be capable of withstanding the physical (in particular mechanical and thermal) and chemi­ cal stresses to be expected in carriage and of remaining leakproof. They shall be capable of withstanding danger­ ous substances and their vapours. They shall also have the necessary degree of resistance to ageing and ultra-violet radiation. Packagings shall be safe to handle. (b) The. pern:1itted period of use of the packagings for the carriage of dargerous goods shall be five years from the date of their manufacture except where the conditions for carriage of the various Classes prescribe a shorter period of use. (c) If prote-:;;tion against ultra-violet radiation is required, it shall be provided by the addition of carbon black or other suitable pigments or inhibitors. These additives shall be compatible with the contents and remain effective through­ out the life of the packaging. Where use is made of carbon black, pigments or inhibitors other than those used in the manufacture of the tested design type, retesting may be . waived if the carbon black content does not exceed 2 per cent by mass or if the pigment content does not exceed 3 · per cent by. mass; the content of inhibitors of ulstra-violet radiation is not limited. (cl) Additives serving purposes other than protection against ultra violet radiation may be included in the compo­ sition of the plastics material provided that they do not ad­ versely affect the chemical and physical properties of the material of the packaging. In such circumstances, retesting may be waived. (e) Appropriate steps shall be taken to ensl!re that the plastics material to be used in the manufacture of the pack­ aging is chemically compatible with the goods which the packaging is intended to contain, see marginal 3551 (5). (t) Packagings shall be manufactured from suitable plas­ tics material of known origin and specifications; their con­ struction shall be fully appropriate to plastics materials and in accordance with technological developments. For new packagings, no used material other than production resi­ dues or regrind from the same manufacturing process may be used. (g) The wall thickness at every point of the packaging shall be appropriate to its capacity and intended use, taking into account however the stresses to which each point is lia­ ble to be exposed. 3525 3526 (h) Openings for filling, rmptying and venting in the bodies or heads of non-removable head drums (lHl) and jerricans (3Hl) shall not exceed 7 cm in diameter. Drums and jerricans with larger openings are considered to be of the removable head type (1H2, 3H2). (i) Removable head drums (1H2) and jerricans (3112) used for solid substances shall rem!lin leakproof at every point with respect to the filling substance. Closure devices for removable head drums andjerricans shall be so designed and applied that they will remain se­ cure and- leakproof under normal conditions of carriage. Gaskets shall be used with all removable heads unless the drum or jerricari design is such that, where the removable head is properly secured, the drum or jerrican is inherently leakproof. G) The maximum permissible permeation for inflamma­ ble liquids shall be 0.008g/l.h at 23 °C (see marginal 3556). (k) Maximum capacity of drum!! and jerricans: lHl, 1H2: 450 litres 3Hl, 3H2: 60 litres (1) Maximum net mass: lHl, 1H2: 400 kg 3Hl, 3H2: 120 kg. Boxes of natural wood 4C 1 ordinary 4C2 with sift-proof walls Note: For plywood boxes, see marginal 3528: for recon­ stituted wood boxes, see marginal 3529. (a) The wood used shall be well seasoned, commercially dry and free from defects that would materially lessen the strength of any part of the box. The strength of the material used and the method of construction shall be appropriate to· the capacity of the box and its intended use. The tops and bottoms mav be made of water-resistant reconstituted wood such a"s hardboard, particle board or other suitable type. (b) Boxes with sift-proof walls 4C2: Each part of the box shall be in one piece or equivalent thereto. A part shall be deemed equivalent to a part in one piece if it is glued together by one of the following methods: Lindermann (dovetail) jointing, tongue-and~groove foi­ nting, ship-lap or rabbet jointing, or butt-jointing with at least two corrugated metal fasteners at each joint. (c) Maximum net mass: 400 kg. Plywood boxes 4D (a) The plywood used shall have at least threee plies. It shall be made of well-seasoned rotary-cut, sliced or sawn veneer commercially dry and free from defects likely to lessen the strenght of the box. All plies shall be glued by means of a water-resistant adhesive. Other suitable materi­ als may be used together with plywood in the manufacture of boxes. Boxes shall be firmly nailed or secured to corner , posts or ends or be assembled by other equally suitable de­ vices. (b) Maximum net mass: 400 kg. Reconstituted wood boxes 4F (a) The walls of boxes shall be made of water-resistant reconstituted wood such as hardboard, particle board or other suitable type. the strength of the material used and the method of construction shall be appropriate to the ca­ pacity of the box and its intended use. (b) Other parts of the boxes may be made of other suita­ ble material. (c) Boxes shall be securely assembled by means of suita­ ble devices (d) Maximum net mass: 400 kg. 3527 3528 3529 11>EK 104 ECDHMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) Fibreboard boxes 4G (a) Good quality solid or double-faced (single-wall or multiwall) corrugated fibreboard app.ropriate to the capac­ ity and intended use of the boxes shall be used. The water­ resistance of the outer surface shall be such that the in­ crease in mass, as measured in a test carried out over ape­ riod of 30 minutes by the Cobb method of water-absorption determination, is not greater than 155 g/m2 (in accordance with ISO International Standard 535 - 1976). The fibre­ board shall be capable of bending sufficiently without breaking. It shall be cut, creased without scoring and slot­ ted so as to permit assembly without cracking and without its surfaces tearing or bulging unduly. The fluting of corru­ gated fibreboard shall be firmly glued to the facing. (b) Ends of boxes may have a wooden frame or be en­ tirely of wood. Reinforcements of wooden battens may be . used. (c) Joins of boxes shall be taped with adhesive tape, be lapped and glued, or be lapped.and metal-stapled. Lapped joins shall have a suitable overlap. Where closure is ef­ fected by gluing or by applying adhesive tape, the adhesive shall be water-resistant. The dimensions of the box shall be appropriate for the contents. (d) Maximum net mass: 400 kg. Plastics boxes 4Hl expanded plastics boxes 4H2 solid plastics boxes (a) The box shall be manufactured from suitable plastics material and be of adequate strength in relation to its ca­ pacity and intended use. The box shall be adequately resis­ tant to ageing and to degradation caused either by the sub­ stance contained or by ultra-violet radiation. (b) An expanded plastics box shall comprise two parts made of a moulded expanded plastics material, a bottom section containing cavities for the inner packagings and a top section covering and interlocking with the bottom sec­ tion. The top and bottom sections shall be designed so that the inner packagings fit snugly. The closure cap for any inner packaging shall not be in contact with the inside of the top section of this box. (c) For dispatch, an expanded plastics box shall be closed with a self-adhesive tape having sufficient tensile strength to prevent the box from opening. The adhesive tape shall be weather-resistant and its adhesive compatible with the expanded plastics material of the box. Other clos­ ing devices at least equally effective may be used. (d) For solid plastics boxes, protextion againts ultra­ violet radiation, if required, shall. be provided by the addi­ tion of carbon black or other suitable pigments or inhibi­ tors. These additives shall be compatible with the contents and remain effective throughout the life of the box. Where use is made of carbon black, pigments or inhibitors other than those used in the manufacture of the tested design type, retesting may be waived if the carbon black content does not exceed 2 per cent by mass or if the pigment con­ tent does not exceed 3 per cent by mass; the content or in­ hibitors ·of ultra-violet radiation' is not limited. (e) Solid plastics boxes shall have closure devices made of a suitable material of adequate strenght and so designed as to prevent the box from unintentional opening. (f) Additives serving purposes other than protection against ultra - violet radiation may be included in the com­ position of the plastics material of boxes 4Hl and 4H2 provided that they do not adversely affect the chemical and physical properties of the material. In such circumstances, retesting may be waived. (g) Maximum net mass 4Hl: 60 kg 4H2: 400 kg. 3530 Steel or aluminium boxes 4Al steel 4A2 steel, with liner 4Bl aluminium 4B2 aluminium, with liner (a) The strength of the metal and the construction of the box shall I;,e appropriate to the capacity of the box and to its intended tlse. (b) Boxes 4A2 and 4B2 shall be lined with fibreboard or felt packing pieces as required or shall have an inner liner or coating of suitable material. If a double seamed metal liner is used, steps shall be taken to prevent the ingress of substances into the recesses of the seams. (c) Closures may be of any suitable type, they shall re main secured under normal conditions of carriage. (d) Maximum net mass: 400 kg. Textile bags 5Ll without inner lining or coating 5L2 sift-proof 5L3 water-resistant (a) The textiles used shall be of good quality. The strength of the fabric and the construction of the bag shall be appropriate to the capacity of the bag and its intended use. (b) Bags, sift-proof, 5L2. The bag shall be made sift-proof, for example by the use of: 3 531 paper bonded to the inner surface of the bag by a water resistant adhesive such as bitumen; or plastics film bonded to the inner surface of the bag; or one or more inner liners made of paper or plastics mate~ rial. (c) Bags, water-resistant, 5L3 To prevent any entry of moisture the bag shall be made waterproof, for example by the use of: separate inner liners of water-resistant ,,,p11pe~ (ii:g. waxed kraft paper, tapped paper or ptas·t1cs-coated kraft paper); or plastics film bonded to the inner surface of tne bag; or • one or more inner liners made of plastics mat'1ri!!l (d) Maximum net mass: 50 kg. • Woven plastics bags 5Hl without inner lining or coaling 5H2 sift-proof • 5H3 water-resistant (a) Bags shall be made from stretched tapes or stretched monofilaments of a suitable plastics material. The strength of the material used and the construction of the bag shall be appropriate to the capacity of the bag and its intended use. (b) Bags may be fitted with an inner liner of plastics film or given a thin inner coating of plastics material (c) If the fabric is woven flat, the bags shall be formed by sewing or some other method ensuring closure of the bot­ tom and one side. If the fabric is tubular, the bottom of the bag shall be closed by sewing, Weaving or some other equally strong method of closure. (d) Bags, sift-proof, 5H2: The bag shall be made sift-proof, for example by means by: paper or a plastics film bonded to the inner surface of the bag; or one or more separate inner liners made of paper or plas­ tics material. (e) Bags, water-resistant, 5H3 To prevent any entry of moisture, the bag shall be made waterproof, e.g. by means of: separate inner liners of water-resistant paper (e.g. waxed kraft paper, double-tarred kraft paper or plastics coated kraft paper); plastics film bonded to the inner or outer surface of the bag; 1001 3532 3533 3534 1002 ECJ>HMEPII THI KYBEPNHIEOI (TEYXOI 4EYTEPO) or one or more inner plastics liners. (f) Maximum net mass: 50 kg. Plastics film bags • 5H4 3535 (a) Bags shall be made of suitable plastics material. The strength of the material used and the construction of the bag shall be appropriate to the capacity of the bag and its intended use. Seams shall withstand pressures an d impacts liable to occur in normal conditions of carriage. (b) Maximym net mass: 50 kg. Paper bags 5Ml, multiwall 3536 5M2, multiwall, water-resistant (a) Bags shall be made of a suitable kraft paper or of an equivalent paper with at least three plies. The strength of the paper and the construction of the bags shall be apporopriate to the capacity of the bag and its intended use. Joins and closures shall be sift-proof. (b) Paper bags 5M2: Water-resistant paper shall be used for the outermost ply or for the one in contact with it. Where there is a danger of the intended contents reacting to moisture, or where they are packed damp, the innermost ply also shall be water­ resistant. The side seams and top and bottom closures shall be sift-proof and water-resistant. (c) Maximum net mass: 50 kg. Composite packagings (plastics material) 6HA1 plastics receptacle with outer steel drum 353 7 6HA2 plastics receptacle with outer steel crate* or box 6HB1 plastics receptacle with outer aluminium drum 6HB2 plastics receptacle with outer aluminium crate* or box • 6HC plastics receptacle with outer wooden box 6HD 1 plastics receptacle with outer plywood drum 6HD2 plastics receptacle with outer plywood box 6HG1 plastics· receptacle with outer fibre drum 6HG2 plastics receptacle with outer fibreboard box 6HH plastics receptacle with outer plastics drum (a) Inner re«;:~ptacle . (1) The provisions of marginal 3526 (a) and (c) - (h) shall apply to plastics inner receptacles. (2) The plastics inner receptacle shall fit snugly inside • the outer packaging, which shall be free of any projection that might abrade the plastics material. (3) Maximum capacity of inner receptacly: 6HA1, 6HB1, 6DH1, 6HH: 250 litres 6HA2, 6HB2, 6HD2, 6HG2: 60 litres. (4) Maximum net mass: 6HA1, 6HB1, 6HD1, 6HG1, 6HH: 400 kg 6HA2, 6HB2, 6HC, (,HD2, 6HG2: 75 kg. (b) Outer packaging (l)' Plastics receptacle with outer steel or aluminium drum 6HA1 or 6HB1; the provisions or marginal 3520 (a) (i) or 3521 (a) - (d); as appropriate, shall apply to the con­ struction of the outer.packaging. (2) Plastics receptacle with outer steel or aluminium crate or box 6HA2 or 6HB2; the provisions of marginal 3532 shall apply to the construction of the outer packag­ ing. (3) Plastics receptacle with outer wooden box 6HC; the provisions of marginal 352 7 shall apply to the construction of the outer packaging. (4) Plastics receptacle with outer plywood drum 6HD1; the provisions of marginal 3523 shall aply to the construc­ tion of the outer packaging. * Crates are outer packagings with incomplete surfaces. (5) Plastics receptacle with outer plywood box 6HD2; the provisions of marginal 3528 shall apply to the con­ struction of the outer packaging. (6) Plastic's receptacle with outer fibre drum 6HG1; the provisions of marginal 352.5 (a) - (d) shall apply to the con­ struction of the outer packaging. (7) Plastics receptacle with outer fibreboard box 6HG2; the provisions of marginal 3530 (a) - (c) shall apply to the construction of the outer packaging. (8) Plastics receptacle with outer plastics drum 6HH; the provisions of marginal 3526 (a) and (c) - (h) shall apply to the construction on the outer packaging. Combination packagings (a) Inner packagings The following may be used: glass, porcelain or stoneware packagings with a maxi­ mum permissible capacity of 5 litres for liquids or 5 kg for solids; • plastics packagings with a maximum permissible capac­ ity of 30 litres for liquids or 30 kg for solids; metal packagings with a maximum permissible capacity of 40 litres for liquids or 40 kg for solids; paper, textile, woven plastics or plastics-film sachets and bags with a maximum permissible capacity of 5 kg for solids in sachets and 50 kg in bags; cans, folding cartons and boxes made of fibreboard or plastics with a maximum permissible capacity of 10 kg for solids; other types of small packagings such a tubes with a max­ imum permissible capacity of 1 litre or liquids or 1 kg for solids. (b) Outer packaging The following may be used: outer packagings made of steel or aluminium (marginal 3532), plywood (marginal 3528), natural wood (marginal 3527), fibreboard (marginal 3530), reconstituted wood (marginal 3529) or plastics material (marginal 3531). B. Packagings which may conform to marginal 3510 (1) or (2) Composite packagings (glass, porcelain or stoneware) 6PA1 receptacle with outer steel drum 6PA2 receptacle with outer steel crate* or box 6PB1 receptacle with outer aluminium drum· 6PB2 receptacle with outer aluminium crate* or box 6PC receptacle with outer -wooden box 6PD1 receptacle with outer plywood drum 6PD2 receptacle with outer wickerwork hamper 6PG 1 receptacle with outer fibre drum 6PG2 receptacle with outer fibreboard box 6PH1 receptacle with outer expanded plastics packag ing 6PH2 receptacle with outer solid plastics packaging (a) Inner receptacle (1) The receptacle shall be suitably moulded (cylindrical. or pear-shaped) and be made of good quality material free from any defect that could impair its strength. The walls shall be sufficiently thick at every point and free from inter­ nal stresses. (2) Screw-threaded plastics closures, ground glass stop­ pers or closures at least equally effective shall be us ed as closures for receptacles. Any part of the closure likely to come into contact with the contents of the receptacle shall be resistant to those contents. Care should be taken to ensure that the closures are so fitted as to be leakproof and are suitably secured to prevent any loosening during carriage. If vented closures are necessary, they shall be leak proof. • (3) The receptacle shall be firmly secured in the outer packagings by means of cushioning and/or absorbent ma terials. • 3538 3539 ECl>HMEPl:E THI: KVBEPNH:EEQ:E (TEYXO:E dEVTEPO) (4) Maximum capacity of receptacle: 60 litres (5) Maximum net mass: 75 kg. (b) Outer packaging (1) Receptacle with outer steel drum 6PA1. The provisions of marginal 3520 (a) - (i) shall apply to the construction of the outer packaging. The removable lid required for this type of packaging may however be in the form of a cap. • (2) Receptacle with outer steel crate or box 6PA2. The provisions of marginal 3532 (a) - (c) shall apply to the construction of the outer packaging. For cylindrical re­ ceptacles the outer packaging should, when upright, rise above the receptacle and its closure. If the protective crate surrounds a pear-shaped receptacle and is of matching shape, the outer packaging shall be fitted with a protective cover (cap). (3) Receptacle with outer aluminium drµm 6PB1. The provisions of marginal 3521 (a) - (d) shall apply to the construction of the outer packaging. ( 4) Receptacle with outer aluminium crate or box 6PB2. The provisions of marginal 3532 shall apply to the con­ struction of the outer packaging. (5) Receptacle with outer wooden box 6PC. The provisions of marginal 3527 shall apply to the con­ struction of the outer packaging. (6) Receptacle with outer plywood drum 6PD1. The provisions of marginal 3523 shall apply to the con­ struction of the outer packaging. (7) Receptacle with outer- wickerwork hamper 6PD2. The wickerwork hamper shall be properly made with material of good quality. It shall be fitted with a protective cover (cap) so as to prevent damage to the receptacle. (8) Receptacle with outer fibre drum 6PG1. The provisions of marginal 3525 (a) - (d) shall apply to the construction of the outer packaging. • (9) Receptacle with outer fibreboard box 6PG2: The provisions of marginal 3530 (a) - (c) shall apply to the construction of the outer packaging. (10) Receptacle with outer expanded plastics or solid plastics -packaging (6PH1 or 6PH2). The materials of both outer packagings shall meet the provisions of marginal 3531 (a) - (f).Solid plastics packag­ ing shall be made of high density polyethylene or other comparable plastics material. The removable lid for this type of packaging may however be in the form of a cap. C. Packagings conforming only to marginal 3510 (2) Light gauge metal packagings OA 1 non-removable-head OA2 removable-head. (a) The sheet metal for the body and ends shall be of suitable steel, and of a gauge appropriate to the capacity and intended use of the packaging. (b) The joints shall be welded, at least double-seamed by welting or produced by a method ensuring a similar degree of strength and leakproofness. (c) Inner co'atings of zinc, tin, lacquer, etc., shall be tough and shall adhere to the steel al every point, including the closures. (d) Openings for filling, emptying and venting in the bodies or heads of non-removable head (OAl) packagings shall not exceed 7 cm in diameter. Packagings with larger openings shall be considered to be of the removable-head type (OA2). (e) The closures of non-removable-head packagings shall either be of the screw-threaded type or be capable of being secured by a screwable device or a device al least equally effective. (Q Maximum capacity of packagings: 40 litres. (g) Maximum net mass: 50 kg. 3540 Section IV Test requirements for packagings A. Design-type tests Performance and frequency of tests ( 1) The design type of each packaging shall be tested and approved by the competent authority or by a body des­ ignated by that authority. (2) Tests in accordance with (1) shall be carried out again after any modification of the design type unless the· authorized testing body has agreed to the modification of the design type. In the latter event a new approval of the de­ sign type is not required. (3) The competent authority may at any time require proof, through tests in accordance with this section, that mass-produced packagings meet the requirements of the design-type tests. (4) For verification purposes the authorized testing body shall keep a record of the materials used, through materials testing or by retaining samples or pieces of the materials. (5) If an inner coating is required for safety reasons, it shall retain its protective properties even after the tests. Preparation of packagings and packages for testing (1) Tests shall be carried out on packagings and pack­ ages prepared as for despatch, including inner packagings of combination packagings. Inner or single receptacles or packagings shall be filled to not less than 95 P,er cent of their capacity for solids or 98 per cent for liquids. The sub­ stances lo be carried in the packages may be replaced by other substances except where this would invalidate the re­ sults of the tests. For solids, when another substance is used it shall have the same physical characteristics (mass, grain size, etc.) as the substance lo be carried. It is permis­ sible to use additives, such as bags of lead shot, to achieve the requisite total package mass, so long as they are placed so that the test results are not affected. St1itable mixtures of powdery solids, such as polyethylene or PVC, po'Yder with sawdust, fine sand etc., may be used as a· s'til'>stitu.te filling substance for substances having a viscosity in excess of 2680 mm2/s at 23°C. (2) In the drop tests for liquids, when another substance ' is used its relative density and viscosity shall be .similar to those of the substance lo be carried. Water may also be . used for the liquid drop test under the conditions in mar­ ginal 3552 (4). (3) Paper or fibreboard packagings shall be conditioned for al least 24 hours in an atmosphere having a controlled temperature and relative humidity (r.h.). There are three options, one of which shall be chosen. The preferred at­ mosphere is 23 ° ± 2 °C and 50 per ~nt ± 2 per r.h. The two other options are 20° ± 2°C"'and 65 per cent ± 2 per cent r.h. or 27 ± 2 °C and 65 per cent ± 2 per cent r.h. (4) Bung-type barrels made of natural wood shall be left filled with water for at least 24 hours before the tests. (5) To check that their chemical co'mpatibility with the liquids is sufficient, plastics drums and jerricans in accor­ dance with marginal 3526 and if necessary cqmposite packagings (plastics material) in accordance with marginal 353 7 shall be subjected to storage at ambient temperature for six months, during which time the test samples shall be kept filled with the goods they are intended to carry. For the first and last 24 hours of storage, the test sam­ ples shall be placed with the closure downwards. However, packagings fitted with a vent shall be so placed on each oc­ casion for five minutes only. After this storage the Lest sam­ ples shall undergo the tests prescribed in marginals 3552 lo 3556. When it is known that the strength properties of the plas­ tics material of the inner receptacles of composite packagings (plastics material) are not significantly altered by the action of the filling substance, it shall not be neces­ sary to check that the chemical compatibility is sufficient. 1003 3550 3551 1004 E<DHMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) A significant alieration in strength properties -means: (a) disti!lct embrittlement; or (b) a.considerable decrease in elasticity, unless related to a not less than proportionate increase in the elongation under load. • Note: Fore plastics drums and jerricans and composite packagings (plastics material) made of high molecular mass polyethylene, see also (6) below. (6) For high molecular mass polyethylene drums and jerricans in accordance with marginal 3526 and if neces­ sary composite packagings of high molecular mass poly­ ethylene in accordance with marginal 3537, conforming to the following specifications: relative density at 23 °C after thermal conditioning for one hour at 100°C ;;:a,, 0.940, in accordance with ISO Standard 1183, melt flow rate at l 90°C/ . 21.6 kg load < 12 g/10 min. in accordance with ISO Standard 1133, chemical compatibility with the liquids listed in section II of the annex to this appendix may be verified as follows with standard liquids (see section I ,of the annex to this ap­ pendix). The sufficient chemical compatibility of these packagings may be verified by storage for three weeks at 40 ° C with the appropriate standard liquid; where this stan­ dard liquid is water, proof ofchemical compatibility is not required. ' For the first and last 24 hours of storage, the test sam­ ples shall be placed with the closure downwards. However, packagings fitted with a vent shall be so placed on each oc­ casion for fiv•e minutes only. After this storage, the test Packaging (a) Steei dru~~ Aluminium dru'"ins- • • Steel jerricans Plywood drums .. Wooden barrels •• Fibre·drums · Plastics ·drums and jerricans Composite packagings (plastics material) which are in the shape of a drum Composite packagings (glass, stone ware or porcelain) comforming to marginal 3510 (1) arid which are in the shape of a drum Light' gauge metal packagings (b) Boxes of natural wood ·Plywood boxes Reconstituted wood boxes Fibreboard boxes Plastics boxes Steel or aluminium boxes Composite packagings (plastics mate rial) which are in the shape of a box Composite packagings (glass, stone ware or porcelain) conforming to mar ginal 3510 (l) and which are in the shape of a box (c) Textile bags Paper bags (d) Woven plastics bags Plastics film bags (e) Composite packagings (glass, stone ware of porcelain) conforming to mar ginal 3510 (2) and which are in the shape of a drum or box • See ISO Standard 2248 samples shall undergo the tests prescribed in marginals 3552 to 3556. When a packaging design-type has satisfied the approval tests with a standard liquid, the comparable filling substances listed in section II of the annex to this ap­ pendix may be accepted for carriage without further test­ ing, subject to the following conditions: the relative densities of the filling substances shall 1101 exceed that used to determine the height for the drop te:,;t and the mass for the stacking lest: • the vapour pressures of the filling substances al 50°C or 55 °C shall not exceed that used to determine the pressure for the internal pressure test. (7) For drums and jerricans conforming lo marginal 3526, and where necessary composite packagings con­ forming to marginal 3537, made of high molecular mass polyethylene, which have passed the lest in paragraph (6) of this marginal. filling substances other than those listed in section II of the annex may also be approved. Such ap­ proval shall be based on laboratory tests proving that the effect of such filling substances on the lest specimens is less than that of the standard liquids. The processes of de­ terioration to lie taken into account shall be the following: softening through swelling, cracking under stress and mo­ lecular degradation. The same conditions as those set out in (6) above shall apply with respect lo relative density and vapour pressure. Drop test* (1) Number of test samplt>s (per design type and rnanu­ facturer) and drop orientation. For other than flat drops the centre of gr.wit, shall be vertically over the point of impact. No. of test samples Drop orientation Six First drop (using three samples). (three for each drop) the packaging shall strike the target diag onally on the chime or, if the packaging has no chime, on a circumferential seam or an edge. Second drop (using the other three sam pies): the p;i.ckaging shall strike the target on the weakest part not tested by the first drop, for example a closure or, for some cylindrical drums, the welded longitudi nal seam of the drum body. Five First drop: flat on the bouom Second drop: flat on the thop ( one for each drop) Third drop: flat on the long side Fourth drop: flat on the short side Fifth drop: on a corner Three First drop: flat on a face of the bag (two drops per bag) Second drop: on the end of the bag Three- First drop: flat on a wide face (three drops Second drop: flat on a narrow face per bag) Third drop: on the end of the bag Three Diagonally on the botto,m chime, or. if there is no chime, on a circumferential (one for each drop) seam or the bottom edge 3552 E<DHMEPII THI KYBEPNHIEOI (TEYXOI AEYTEPO) (2) Special preparation of test samples for the drop test: Testing of plastics drums, jerricans and boxes in accor­ dance with marginals 3526 and 3531, of composite packagings (plastics material) in accordance with marginal 3537 and of combination packagings with plastics inner packagings- with the exception of bags and plastics boxes in accordance with marginal 3538 shall be carried out when the temperature of the test sample and its contents has been reduced to -l8°C or lower; where test samples Packing group I 1.8m For liquids: If the test is performed with water: (a) where the substances to be carried have a relative density not exceeding 1.2 Packing group I 1.8 m (b) where the substances lo be carried have a relative density exceeding 1.2, the drop height shall be calculated on the basis of the relative density of the substance to be carried, rounded up to the first decimal, as follows: Packing group I relative density X 1.5 (m) (c) for light-gauge metal packagings intended for the carriage of substances having a viscosity al 23 °C greater than 200 mm2 /s (corresponding lo a flow time of 30 sec­ onds with an ISO flow cup having a jet orifice of 6 mm di­ ameter in accordance with ISO Standard 2431-1980): (i) if the relative density does not exceed 1.2: Packing group II Packing group III 0.6 m . 0.4 m If the test is performed with the substance to be carried or with a liquid of at least equal relative density: Packing group I 1.8 m (5) Criteria for passing the test: (a) Every packaging containing liquid shall be leakproof when equilibrium has been reached between the internal and external pressues, except for inner packagings of com­ bination packagings or composite packagings (glass, por­ celain or stoneware) whenit is not necessary that the-rires­ sures be equalized. (b) Where removable-head drums for solids undergo a drop test and their upper faces strike the target, the test sample passes the test if the entire contents are retained by with an outer packaging of fibreboard a:re prepared in this way the conditioning specified in marginal 3551 (3) may be waived. Test liquids shall be kept in the liquid state, if necessary by the addition of anti-freeze. (3) Target The target shall be a rigid, non-resilient, flat and· hori­ zontal surface. (4) Drop height For solids: Packing group II 1.2 m Packing group II 1.2 m Packing group II relative density X 1.0 (m) Packing group III 0.8 m Packing group· III 0.8 m Packing group III relative density X 0.67 (rri) • J!::.:...-. .. ·.: .. . .. (ii) where the substances to be carried h~·ve. a,,,relative density exceeding 1.2 the drop height shall be calcul ated on the basis of the relative density of the substanc~. t9 be carried, rounded up lo the first decimal place, as follows: ,. ' . Packing group II . Packing group III relative density relative density X 0.5 (m) x·o.33 (m) Packing group II Packing group III 1.2 m 0.8 m an inner packaging (e.g. a plastics bag) even if the cl()Sure on the top face of the drum is no longer sift-proof. (c) The outermost ply of a bag shall not exhibit any dam age liable to effect safety, in carriage. • (d) The outer packaging of a composite or combi!'lation"' packaging shall not exhibit any damage liable to affect·• safety in carriage. There shall be no leakage of the filling substance from the inner packaging. (e) A slight discharge from the closure (s) upon impact shall not be considered to be a failure of the packaging pro­ vided that no further. leakage occurs. 1005 1006 E<DHMEPII THI KYBEPNHIEQI (TEYXOI .dEYTEPO) Leakproofness test (1) The leakproofness test shall be perfornwd on all types of packagings intended to contain liquids: ho11<'rer. this test is not required for: foner packagings of combination packagings: inner receptacles of composile packagings (glass. porce­ lain or stoneware) conforming lo marginal 3510 (2): removable head packagings intended for subs1a11C't' 11 ith a viscosity at 23 °C exceeding 200 1rn112/s. (2) Number of lest samples: Three test samples per design type and rnanufaC'­ turer. Packing group I 3553 (3) Special preparation of te.,1 samples for the test: Test samples shall be pierced for entry of lhC' c·om­ pressed air at a neutral point. so as also to test the tightness of the closure. Vented closures of packagings shall be re­ placed by non-vented closures. (4) Test method: The test samples shall be immersC'd in 11aler: lhev shall be kept under water in such a way as not to distort the rC'sult of the test. The packaging may al~o be covered 11ith soap solution, heavy oil or other suitable liquid mi the seams or at any other place where leakage lllight occur. Otlwr nwth­ ods at least equally effective may also be used. (5) Air pressure lo be applied: Packing group II Packing group III Not less than 30 kPa \01 less than 20 KPa Not less than 20 kPa (6) Criterion for passi1\g the test: There shall be no leakage. Internal pressure (hydraulic) lesl: (1) The hydraulic pressure test shall be carried out on all types of steel, aluminium and plastics packagings. and 011 all composite packagings intended to contain liquids. How­ ever,. this test is not required for: inner packagings of combination packagings: inner receptacles of composite packagings (glass. porc·e­ lain or stoneware) conforming to marginal 3510 (2): remobable head packagings intended for subslanc·es with a viscosity at 23 ° C exceeding 200 1111112/,;. (2) Number of te~l samples: Three test samples per design type and nH11111fa!'­ turer. (3) Special preparation of packagings for the lest. Te>st samples shall be pierced for entr,y of the prC'ssure at IIC'Ulral point, so as also to lest the tightness of the closure. Vented closures of packagings shall be replaced bv 11011-vcnted closures. • (4) Test method and r·ressure to be applied: The packagings shall be subjected for li1·e minutes ('."rn minutes in the case of plastics packagings) to a In draulic gauge pressure not lower than: (a) the total gauge pressure measured in the packaging (i.e. the vapour pressure of the filling substance and the partial pressure of the air or other inert gases. less I 00 kPa) at 55 °C, multiplied by a safety factor of] .5: this total gauge pressure shall be determined on the basis of a nraxi-. nium degree of filling in accordance 11itl1-111argi11al 3500 ( 4) and a filling temperature of 15 ° C. or (b) 1. 75 times the vapour pressure of th~· filli11g sub­ stance at !J0°C, less] 00 kPa. but a gauge pressure of 1101 less than 100 kPa, or (c) 1.5 times the vapour pressure of the filling substance at 55 °C, less 100 kPa. but at a gauge pressure of not less than 100 kPa. The manner in which the packagings are maintained in place shall not distort the results of tlie lest. Pressure shali be applied continuously and evenly. The test pressure shall be kept constant throughout the lest period. The minimum test pressure for packagings for Packing Group I shall be 250 kPa. (5) Criterion for passing the test: No packaging shall leak. Stacking test. ( 1) All packagings other than bags and 11011-stackable composite packagings (glass, porcelain or stoneware) con 3554 3555 forming to marginal 3510 (2). shall be subjC'clC'd lo a stacking test. (2) Number of test samples: Three test samples rer design l\'pe and 111a11ufnc­ turer. (3) Test method: The test samples shall be capable of 11i1hslandi11g an ad­ ditional mass placed on a flat surface resting on thf' IPst sample and equivalent lo the total mass of identical pack­ ages which might be stacked on it during carriage. The duration of the test shall be 24 hours. except for plastics drums and jerricans in accordance with marginal 3526, or plastics composite packagings 6HH. intended for liquids. The slacking height to be allowed for shall he at least 3 m. In the stacking test act:ount shall be taken of the higll('st relative density of filling substance Lo be approved. Plastics drums and jerricans in accordance with mar­ ginal 3526, or plastics composite packagins (6HH). in­ tended for liquids shall be subjected to the stacking test for a period of 28 days, with the original filling substance. at a temperature of 40°C. A slacking height of al least 3111 shall be allowed for. For the test in accordance with marginal 3551 (6), a stacking test shall also be carried out 11ith a standard liquid. The mass of the stacking load shall he dC'­ termined on the basis of the highest relatil'e density or fill­ ing substance to be approved. (4) Criteria for passing the lest: No test sample shall leak. In composite packaging~r combination packagings, there shall be no leakage of the filling substance from the inner receptacle or inner packag­ ing. No test sample shall show any deterioration which could adversely affect transport safety or any distortion liable lo reduce its strength or cause instability in stacks of pack­ ages*. Supplementary permeability tesl for plastics drums and jerricans in accordance with marginal 3526 and for com­ posite packagings (plastics material) in accordance with marginal 353 7 intended for the carriage of liquids having a . flash - point < 55 ° C. other than 6HA 1 packagings. (1) Polyethylene packagings need be subjected to this test only if they are lo be approved for the carriage of ben­ zene, toluene, xylene or mixtures and preparations con­ taining those substances. (2) Number of test samples: three packagings. (3) Special preparation of the test sample for the test: the test samples are to be pre-stored with the original filling substance in accordance with marginal 3551 (5), or. for 3556 E<DHMEPII THI KYBEPNHIECI (TEYXOI dEYTEPO) high molecular mass polyethylene packagings, -with the standard liquid mixture of hydrocarbons (white spirit) in accordance with marginal 3551 (6). (4) Test method: • The test samples filled with the substance for which the packaging is to be approved shall be weighed before and after storage for 28 days at 23 °C and 50 per cent relative atmospheric humidity. For high molecular mass polyethyl­ ene packagings, the test may be carried out with the stan­ dard liquid mixture of hydrocarbons (white spirit) in place of benzene, toluene or xylene. · (5) Criterion for passing the test: Permeability shall not exceed 0.008 l.h Supplementary test for natural wood bung type barrels. 3557 (1) Number of test samples: One barrel. (2) Test method: Remove all hoops above the bilge of an empty barrel which has previously stood assembled for at least two davs. (3) Criterion for passing test: • The diameter of the upper part of the barrel shall not in­ crease by more than 10 per cent. 1. Testing body; 2. Applicant; 3. Manufacturer of packaging; 4. Description of packaging (e.g. distinctive features such as material, inner lining, dimensions, wall thickness, mass, closures, colouring of plastics materials); 5. Design drawing of packaging and closures (if neces sary, photographs); 6. Method of manufacture; 7. Actual capacity; 8. Permissible filling substances (in particular details of realtive densities and vapour pressures at 50°C or 55 °C): 9. Drop height; 10. Test pressure in leakproofness test in accordance with marginal 3553; 11. Test pressure in internal pressure test in accordance' with marginal 3554; 12. Stacking height; 13. Test results; 14. Marking of packaging and details lo identify clo­ sures. A copy of the test report shall be retained by the compe­ tent authority. B. Leakfproofness test for all new or reconditioned packagings intended to contain liquids. 1007 Approval of combination packagings. 3558 Note: Combination packagings shall be tested in accor- (1) Application of the test. •• 3560 dance with the provisions applicable to the outer packag ing. (1) During design-type tests of combination packagings. approval may at the same time be given for packagings: (a) containing inner packagings of less volume: (b) having a lower net mass than that of the design type tested. (2) Where several types of combination packaging hav­ ing different types of inner packaging have been approved, the various inner packagings may also be assembled in a single outer packaging if the sender certifies that this pack­ age meets the test requirements. (3) Provided that the strength properties of the plastics inner packagings of a combination packaging are 1101 sig­ nificantly altered by the action of the fillii1g substance. proof of chemical compatibility is not necessary. A signili­ cant alteration in strength properties means: (a) distinct embrittlement, (b) a considerable decrease in elasticilv. unless related to a not less than proportionate increase in elastic elonga­ tion. Test report. 3559 A test report giving at least the following particula1's shall be drawn up: Every packaging intended to contain liquids shall un dergo the leakproofness test: before it is firts used· for carriage: after reconditioning, befor it is re-used for carriage. This test is not required for: inner packagings of combination packagings: inner receptacles of composite packagings (glass. porce­ lain or stoneware) conforming lo marginal 3510 (2): removable head packagings intended· for substances with a viscosity at 23 °C exceeding 200 mm2/s: light gauge metal packagings conforming lo marginal 3510 (2). (2) Test method. • ' •• Compressed air shall be introduced through the filling orifice of each packaging. The packaging shall .be im­ mersed in water; it shall be kept under water in such a w:ay as not to distort the result of the test. The packaging may also be covered with soap solution, heavy oil or other.suita­ ble liquid on its seams or at any other plaee where leakage might occur. Other methods at least equally cffccti,e may also be used. Packagings need not be equipped with their 01\11 ·clo­ sures. (3) Air pressure to be applied: Packing group I Packing group II Packing group Ill Not less than 30 kPa Not less than 20 KPa Not less than 20 kPa (4) Criterion for passing the tesl: There shall be no leakage. 3561 3569 Section V Transitional period Packagings not conforming to the provisions of this ap- 35 70 pendix but which nevertheless could be used in accordance with the provisions of ADR applicable on 30 April 1985 for the corresponding substances of Classes 3. (i. I and 8 may still be used for a transitional period of five years until 30 April 1990 for the carriage of these substances. Packagings not conforming lo the provisions of this ap­ pendix, but which were used fo r substances not regulated by ADR on 30 April 1985 but falling under the provisions of Classes 3, 6.1 and 8 applicable from 1 Mav 1985. niav continue to be used for a transitional period "or li1·e ,ear~ until 30 April 1990 for the carriage of those substa.nces. provided that the provisions of marginal 3500. paragraphs (1), (2), (4), (.5), (6) and (7) of this appemlix are complied with. ANNEX TO APPEl\'DIX A.5 Section I Standard liquids for verifying the chemical com1~a1ibility 3571 3599 1008 E<DHMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) of high molecular mass polyethylene packagings in accor­ dance with marginal 3551 (6). The following standard liquids shall be used for this plastics material. (a) Wetting Solution for substances causing severe cracking in polyethylene under stress. in particular for all solutions and preparations containing welling agents. • An aqueous solution of 1-10 per cent of a welling agent shall be used. The surface tension of this solution shall be 31 to 35 mN/m at 23°C. The stacking test shall be carried out on the basis of a relative density of not less than 1.20. • A compatibility test with acetic acid is not required if ad­ equate chemical compatibility is proved with a welling so­ lution. (b) Acetic acid for substances and preparations causing cracking in polyethylene under stress, in particular for monocarboxylic acids and monovalent alcohols. Acetic acid in 98-100 per cent concentration shall be used. Relative density= 1.05. The stacking test shlc\ll be carried out on the basis of a relative density not less than 1.1. In the case of filling substances causing polyethylene to swell more than actic acid and lo such an extent that the polyethylene mass is increased by up to 4 per cent. ade­ quate chemical compatibility may be proved after prelimi­ nary storing for three weeks al 40°C, in accordance with marginal 3551 (6) but with the original filling mailer.• (c) Normal butyl acetate/normal butyl acetate - satu­ rated wetting solution for substances and preparations causing polyethylene to swell to such an extent that the pol­ yethylene mass in increased by up to about 4 per cent and at the same time causing cracking under stress, in particu­ lar for phyto-sanitary products. liquid paints and esters. Normal butyl acetate in 98-100 per cent concentration shall be used for preliminary storage in accordance 11ith marginal 3551 (6). • For the stacking test in accordance with marginal 3555. a test liquid consisting of a 1 lo 10 per cent aqurous wel­ ting solution mixed with 2 per cent normal butyl acetate conforming to (a) above shall be used. The stacking test shall be carried out on the basi~ of a relative density not less than 1.0. Class 3 Item Substance In the case of filling substances causing polyethylene to swell more than normal cutyl acetate and to such an extent that the polyethylene mass is increased by up to 75 per cent, adequate chemical compatibility may be proved after preliminary storing for three weeks at 40°C, in accordance with marginal 3551 (6) but with the original filling mailer. (cl) Mixture of hydrocarbons (white spirit) for substances and preparations causing polyethylene to swell, in' particu lar for hydrocarbons, esters and ketones. • A mixture of hydrocarbons having a boiling zone of 180°C-200°C, a relative density of 0. 79, a flash-point above 61 °C and an aromatics content of 16 to 18 per cent (C9 and higher aromatics only) shall be used. The stacking test shall be carried out ·on the basis of a relative density not less than 1.0. In the case of filling substances causing polyethylene to swell to such an extent that the polyethylene mass is in­ creased by more than 7 .5 per cent, adequate chemical compatibility may be proved after preliminary storing for three weeks at 40°C, in accordance with marginal 3551 (6) but with the original filling mailer. (e) Nitric adic for all substances and preparations having an oxidizing effect on polyehtylene and causing molecular degradation identical to or less than 55 per cent nitric acid Nitric acid in 55 per cent concentration shall be used. The stacking test shall be carried out on the basis' of a relative density of not less than 1.4. In the case of filling substances more strongly oxidizing than 55. per cent nitric acid or causing degradation of the molecular mess proceed in accordance with marginal 3551 (5). (f) Water for substances which do not allack polyethyl­ ene in any of the cases referred lo under (a) to (e), in partic­ ular for inorganic acids and lyes, aqueous saline solutions, polyvalent alcohols and organic substances in aqueous so­ lution. The stacking test shall be Cllrried out on the basis of a relative density of not less than 1.2. Section II List of substances lo whit'h the standard liquids may be regarded as equivalents in accordance with marginal 3551 (6). • Standard Liquid A. Substances, not toxic and not corrosive, having a nash-point below 21 °C 3 ° (b) Substances having a vapour pressure at SO° C of not more than 110 kPa (1.1 bar) Crude petroleums and other crude oils Hydrocarbons Halogenated substances Alcohols Ethers Aldehydes Ketones Esters 5 ° Viscous substances: Certain colours for rotogravures and for leathers B. Toxic subsiances having a flash-point below 21 °C 17° • (b) Methanol (methyl alcohol) D. Substances, not toxic and not corrosive, having a nash-point between 2 loC and 100 ° C inclusive 31 ° (c) Substances having a nash-point between 21 °C and 55 °C inclusive: . Petroleum, solvent naptha White spirit (turpentine substitute) Hydrocarbons Halogenated substances Alcohols Ethers Aldehydes Ketones Esters Mixture of hvdrocarbons Miture of hydrocarbons Acetic acid Mixture of hydrocarbons Normal butyl acetate where the swelling effect is up to 4 per cent (mass): other cases, mixture of hydro­ carbons Mixture of hydrocarbons Acetic acid Mixiure of hydrocarbons Acetic acid Mixture of hydrocarbons Normal butyl acetate where the swelling effect is up to 4 per cent (mass): other cases, mixture of hydro­ carbons <I>EK 104 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI .dEYTEPO) 32° Class 6.1. Nitrogenous substances (c) Substances having a flash-point above 55 °C, but not exceeding 100°C Heavy, products from distillation of petroleum Heating oils, diesel oils Hydrocarbons Oxygenated substances Halogenated substances Nitrogenous substances B. Organic substances ,.;hich have a flash-point of 2 loC or above or are non-inflammable 11 ° Nitogenous substances having a boiling point below 200°C (b) Aniline 13 ° Oxygenated substances having a boiling point below 200°C (b) Phenol (c) Ethylene glycol monobutyl ether Furfun-l alcohol 14° Oxygenated substances having a boiling point of 200°C or above (b) Cresols (c) Alkyl phenols Class 8 A. Acid substances Inorganic acids 1 ° (b) Sulphuric acid • 70 (b) (b) Waste sulphuric acid Nitric acid containing not more than 55 per cent pure acid (HN0 3 ) Aqueous solutions of perchloric acid containing not more than 50 per cent pure acid (HC!0 4 ) (b) Solutions of hydrochloric acid containing not more than 36 per cent pure acid, solutions of hydrobromic acid, solutions of hydriodic acid (b) Aqueous solutions of hydrofluoric acid containing not more than 60 per cent anhydrous hydrofluoric acid1I 8 ° (b) Fluoboric acid containing not more than 50 per cent pure acid (HBF 4 ) • 9° (b) Fluosilicic acid (hydrofluosilicic acid) 10° (b) Solutions of chromic acid containing not more than 30 per cent pure acid 11 ° (c) Phosphoric acid Organic substances 32 ° Liquid carboxylic acids and liquid halogenated carboxylic acids and their liquid anhydrides (b) Acrylic acid, formic acid, acetic acid, thioglycolic acid (c) Methacrylic acid, propionic acid l/ Maximum 60 litres; pei-missible period of use two years Item Substance B. Basic substances Inorganic substances 42° 43° 44° Solutions of alkaline substances (b) Soda lye, potash lye, caustic lyes (c) Ammonia solutions Hydrazine and its aqueous solutions (b) Aqueous solutions of hydrazine containing not more than 64 per cent hydrazine (N 2 H 4 ) C. Other corrosive substances 61 ° 62° 63° Hypochlorite solutions21 Solutions of hydrogen peroxide3I (b), (c) Aqueous solutions containing not less than 8 per cent and not more than 60 per cent hydrogen peroxide Formaldehyde solutions: (c) Aqueous solutions containig not less than 5 per cent formaldehyde, even with not more than 35 per cent methanol • Mixture of hydrocarbons Mixture of hydrocarbons Acetic acid Acetic acid Water Mixture of hydrocarbons Nitric acid Nitric acid Water \'i'ater Water Water Nitric acid 'Water Acetic acid Standard Liquid Water Mixture of hydrocarbons \ . Nitric acid Water Water 21 Test to be carried out only with vent. If the test is carried out with nitric acid as the standard liquid, an acid-resistant vent shall be used. For hypochtorite solutions themselves, vents of the same design type. resistant to hypochlorile (e.g. of silicone rubber) but not resistant to nitric acid, are also permitted. 31 Test to be carried out only with vent. APPENDIX A.6 REGULATIONS RELATING TO RADIOACTIVE SUBSTANCES OF CLASS 7 (3) A package of gross mass in excess of 50 kg shall be so designed as to enable safe handling Lo be done by me­ chanical means. (4) The design shall be such lhat any lifting attachments on the package, when used in the intended manner. do not impose unsafe stresses on the structure of the package: as­ sessment shall take account of appropriate safety factors Lo cover "snatch" lifting. SECTION I - PACKAGING AND PACKAGI:: DESIGN REQUIREML\TS A. General Design Requirements for Packaging and Packages (1) The packaging shall be so designed that the package can be easily handl~d and can be properly secured d11rii1g transport. (2) A package of gross mass l O kg or more and up lo 50 kg shall be prnvided with means for manual handling. 3600 (5) Attachments and any other features on the outer sur­ face of the packaging which could be used lo lift the pack­ ages shall be removable or otherwise rendered inoperable for transport or shall be designed to support the weight of the package in accordance with the requirements of (4) above. 1009 1010 E<DHMEPII THI KYBEPNHIEQI (TEYXOI .6EYTEPO) ... (6) The outer layer of packaging shall be so designed as to avoid; as far as practicable, the collection and the reten­ tion of water. (7) The external surfaces of packaging shall, as far as practicable, be so designed-and finished that they may be easily decontaninated. (8) Any features added to the package at the time of transpor t which are not part of the package shall not reduce the safety of the package. (9) The.smallest over-all external dimension of the pack­ aging shall not be less thaQ 10 cm. (10) Substances which have a critical temperature below 50°C or, at this temperature, a vapour pressure above 300 kPa (3 bar) shall be contained in receptacles which also comply with the regulations of marginals 2202 and 2211 to 2218. B. Additional Requirements for Type A Packages (1) The outside of every package shall incorporate a fea­ ture such as a seal, which is 1101 readily breakable and which, while intact, will be evidence that the package has not been opened. • (2) As far as practicable. packaging shall be designed so that the external surfaces are free from protruding fea­ tures. (3) The design of the packaging shall take into account the variations in temperature to which the packaging may be subjected rluring transport and storage. In this respect. 40°C and 70°C shall be considered as satisfactory limits to be used in the selection of the materials; special allen­ tion, however, shall be given to brittle fracture over tl)is temperature range. (4) The design, fabrication and manufacturing tech­ niques for welded, brazed, or other fusion joints shall be in accordance with national or international standards or with standards acceptable to the competent authority. (5) The package shall be capable of withstanding the ef­ fects of any acceleration, ·vibration or vibration resonance which may arise during normal transport without any dete­ rioration in the effectiveness of the closing devices on the various receptacles or in the integrity of the pack~ge as a whole. In particular; nuts, bolts and other securing devices shall be so designed as to prevent them from becoming loose or being released unintentionally, even after repeated use. (6) Special form radioactive substances may be consid­ ered as a component of the containment system. (7) The design shall include a containment system closed by a positive fastening device, that is a device which cannot open by itself, can only be opened intentionally and will resist the effect of a possible increase in pressure in side the vessel. • (8) If a containment system forms a separate unit of the packaging, it shall be capable of being securely closed by a positive fastening device which is independent of any other part of the packaging. , (9) The materials of the packaging and any components or structures shall be physically and chemically compatible with each other and with the package contents; account shall be taken of their behaviour under· irradiation. (10) The design of any component of the containment system shall take into account, where applicable. the radiolytic decomposition of liquids and other vulnerable materials and the generation of gas by chemical reaction and radiolysis. (11) The containment system shall retain its radioact1ve contents under the reduction of ambient pressure to 25 kPa (0.25 bar). (12) All valves, other than pressure relief valves. through which the radioactive contents could otherwise es­ cape shall be protected against unauthorized operation and shall be provided with an enclosure to retain any leakage from the valve. (13) A radiation-shield. which e·ncl~sis a component of the packaging specified as a part of the containment system shall be so designed as to prevent the unintentional release of thet component from the shield. Where the radiation shield and such component within it form a separate unit, the radiation shield shall be capable of being securely closed by a positive fastening device which is independent of any other packaging structure. (14) Any ite-down attachments on the package shall be so designed that, under both normal and accident condi­ tions, the forces in those attachments shall not impair the ability of the package to meet the requirements of this Ap­ pendix. (15) Type A packaging shall be so designed that, if ii were subjected to the tests specified in marginal 3635 ii would prevent: (a) loss or dispersal of the radioactive contents~ and (b) any increase of the maximum radiation level re 3601 corded or calculated al the external surface for the condi­ tion before the test. (16) Type A packaging designed for liquids shall, in ad­ dition, be adequate to meet the conditions prescribed in (15) above if the package is subjected lo the tests specified in marginal 3636. However, these tests are not required when enough ab­ sorbent material lo absorb twice the volume of the liquid contents is within the containment system and: (a) the absorbent material is within the radiation shield; or (b) the absorbent material is outside the radiation shield. provided that it can be shown that if the liquid contents were taken up by the absorbent material the resultant radi­ ation level at the surface of the package would not exceed 2 mSv/h (200 mrem/h). (1 7) Type A packaging designed for compressed or uncompressed gases shall, in addition, prevent loss or dis­ persal of the radioactive contents if the package is sub­ jected to the .tests specified in marginal 3636. Packaging designed for tritium and argon-37, in gaseous form and in activities up to 7.4 TBq (200 Ci), shall be exempted from this requirement. C. Basic Additional Requirements for Type B/U) and Type B(M) Packages (1) Except as provided in marginal 3603 (1) (a) and 3604 (2) respectively, Type B(U) and Type B(M) packages shall be designed to meet the additional requirements specified for Type A packages in marginal 3601 (1) to (15) inclusive. (2) The packaging shall be so designed that if it were subjected to the tests in marginal 363 7 it would retain sufficient radiation shielding to ensure that the radiation le­ vel at 1 m from the surface o f the package would not ex­ ceed 10 mSv /h (1 rem/h) had the package contained suffi­ cient iridium-192 to produce a radiationlevel of 100 µ Sv /h (10 mrem/h) at 1 m from the surface before the tests. Where the use of the packaging is to be restricted to partic­ ular radionuclides, those radionuclides may be used as the reference source in place of iridium-192. In addition, if the packaging is to be used for meutron emitters, an approp­ riate neutron reference source shouid also be used. It is not ri;quired that a measurement necessarily be made with a test radiation source but only that calculations be made with respect to the particular reference radiation source considered. (3) Type B(U) and Type B(M) packages shall be so de­ signed, constructed and prepared for shipment that, under the ambient conditions specified in (4), they shall satisfy the conditions in (a) and (b) below: (a) Heat generated within the package by the radioactive contents will not, under normal conditions of transport (as demonstrated by the tests in marginal 3635) adversely af­ fect the package in such a way that it will fail to meet the 3602 ECl>HMEPII THI KYBEPNHIEOI (TEYXOI AEYTEPO) 1011 applicable requirements for containment and shielding if left unallended for a period o.f one week. Particular alle­ ntion shall be paid to the effects of heat which may: (i) alter the arrangement, the geometrical forrri or the physical state of the radioactive contents or, if the material is enclosed in a can or receptacle (for example, clad fuel elements), cause the can, receptacle or material to melt; (ii) lessen the efficiency of the packaging through diffe­ rential thermal expansion or cracking or melting of the ra­ diation shielding material; (iii) in combination with moisture, accelerate corro­ s10n. (b) The temperature of the accessible surfaces of a Type B(U) or Type B(M) package shall not exceed 50°C in the shade unless the package is transported as a full load. (4) In applying paragraph (3) (a), the following condi tions shall be assumed: (a) Ambient teperature 38 °C. (b) lnsolation data according to Table I below. In applying paragraph (3) (b), the following condition shall be assumed: Ambient temperature 38 ° C. In the case of Type B(M) packages to be transported exclusively between specified countries, alternative condi­ tions may be assumed with the agreement of the competent authorities of these countries. TABLE I - INSOLATION DATA Form and location lnsolation W /m2 of surface (caljcm2 for 12 hours per hour) Flat surfaces transported horizontally: ..:. base other surfaces none Flat surfaces not transported 800 horizontally: each surface 200•1 Curved surfaces 400•/ •/ Alternatively, a sine function may be used, adopting an ab­ sorption coefficient and neglecting the effects of possible reflec­ tion from neighbouring objects. (5) Packaging which includes thermal protection for the purpose of satisfying the requirements of the thermal test specified in marginal 3637 (3) shall be so designed that such protection will remain effective if the packaging is subjected to the tests specified in marginal 3635 and mar­ ginal 363 7 (2). Any such protection on the exterior of the package shall not be rendered ineffective by conditions commonly encountered in normal handling or in accidents and not simulated in the tests referred to above, e.g. by rip­ ping, cutting, skidding, abrasion or rough handling. D. Specific Additional Requirements for Type B(U) Pac­ • kages ( 1) The package shall be so designed that, if it were subjected to the tests referred to below, it would: (a) with regard to the tests specified in marginal 3635 restrict the loss of radioactive contents· to not more than A 2 X 10·6 per hour. .(b) with regard to the tests in marginal 3637, restrict the accumulated loss of radioactive contents to not more than A 2 X. 10·3 in a period of one week. Where mixtures of different radionuclides are present, the provisions of marginal 3691 shall apply. For (a) above, the evaluation shall take into account the external contamination limitations of marginal 3651. For both (a) and (b) above, the A2 values for noble gases shall be those for the uncompressed state. (2) Compliance with the permitted acitivty release limits 3603 shall depend neither upon filters nor upon a mechanical co­ oling system. (3) A package shall not incorporate a feature which is intended to allow continuous venting during transport. (4) The package shall not include a pressure relief sys­ tem from the containment system which would allow the re­ lease of radioactive substances to the environment under the conditions of the tests specified in marginals 3635 and 3637. (5) Where the maximum normal operating pressure (see marginal 2700 (2)) of the containment system added to any differential pressure below mean sea-level atmosphe­ ric pressure to which any component of the packaging spe­ cified as part of the containment system may be subjected exceeds 35 kPa (0.35 bar), that component shall be ca­ pable of withstanding a pressure of not less than one and a half times the' sum of those pressures; the stress at this lat­ ter pressure shall not be more than 75 per cent of the mi­ nimum yield strength and not more than 40 per cent of the ultimate strength. of that component at the maximum expected operating temperature. (6) With the package at the maximum normal operating pressure (see marginal 2700 (2) subjected to the thermal test specified in marginal 363 7 (3), the pressme in any component of the packaging specified as a part of the co­ ntainment system shall be demonstrated not to exceed the pressure which corresponds to the minimum yield strength of that component at the maximum temperature which it . would be expected to reach in the test. (7) The package shall not have a maximum normal ope­ rating pressure (see marginal 2700 (2)) in excess of 0. 7 MPa (7 bar) (gauge). (8) The maximum temperature of any surface readily accessible during transport of the package shall not exceed 82 ° C in the shade under normal conditions of transport . (see also marginal 3602 (3) (b) above) . (9) The containment system of a package ·c~ntaining liq­ uid shall not be impaired if the package is subjected. to a temperature of -40°C under normal conditions of trana sport. . E. Additional Requirements for Type B(M) Packages (1) In addition to the requirements of marginal 3602, 3604 Type B(M) packages shall, as far practicable, meet the ad ditional specific requirements for Type B(U) packages gi ven in marginal 3603. (2) A Type B(M) package shall be so designed that, if it were subjected to the tests referred to in Table II it would restrict the loss of radioactive contents to not more than the activity limits specified in Table II. The evaluation with res­ pect to the tests specified in marginal 3635 shall take into account the external contamination limitations of marginal 3651. TABLE II - ACTIVITY LIMITS FOR LOSS OF RADIO ACTIVE CONTENTS FROM TYPE B(M) PACKAGES Type B(M) packages Type B(M) packages specially designed Conditions not designed for to allow continuous continuous venting venting After the tests in A2 X 10·6 per hour A2 X 5 X 10·5 pe nour marginal 3635 After the tests in Krypton-85: Krypton-85: marginal 363 7 370 TBq (10 000 Ci) 370 TBq (10 000 Ci) in 1 week in 1 week Other Other radionuclides: radionuclides: A2 in 1 week A2 in 1 week 1012 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) The A 2 values .used for noble gases shall be for the uncompressed state. Where mixtures of radionuclides are present the provisions of marginal 3691 shall apply. (3) If the pressure in the containment system of a Type B(M) package could result in stress exceeding, under the conditions of the tests in marginals 3635 and 3637, the minimum yield strength of any structural material of the containment system at the temperature which it would be expected to reach in the tests, the packaging shall be equip­ ped with a presure relief system to ensure that that mi­ nimum yield ~trength is not exceeded. SECTION II - FISSILE SUBSTANCES A. Exemptions of Fi&sile Substances from Fissile Class Package Prescriptions Packages containing radioactive substances which are also fissile substances except for the cases specified in (a) to (g) below, shall be designed to comply with the require­ ments of this· section. (a) Packages containing individually not more than 15 g of uranium-233, uranium-235, plutonium-238, pluto­ nium-239, plutonium-241, or 15 g of any combination of these radionuclides, provided that the smallest external di­ mension of the package is not less than 10 cm. When mate­ rial is transported in bulk, the quantity limitations shall ap­ ply to the vehicle. (b) Packages containing only natural or depleted ura­ nium which has been irradiated in thermal reactors only. (c) Packages containing homogeneous hydrogenous sol­ utions or mixtures satisfying the conditions listed in Table III. Whe\'l material is transported in bulk, the quantity limi­ tations shall apply to the vehicle. TABLE III - LIMITATIONS ON HOMOGENEOUS HYDROGENOUS -,S OLUTIONS OR MIXTURES Any other fissile 235u only Parameters substances (including mixtures). Minimum H/X•I 5200 5200 Maximum concentration of • fissile nuclide in g/1 5 5 Maximum mass of fissile nuclide in g/package 500 800b/ •I Where H/X is the ration of the number of hydrogen atoms· to the number of atoms of fissile nuclide. b/ With a tolerance for Pu and 233u of not more than l per cent of the mass of 235u· (d) Packages containing uranium encrkhed in uranium 235 .to a maximum of 1 per cent by mass, and with a total . plutonium and uranium-233 content of up to 1 per cent of the mass uranium-235, provided, that the fissile substan­ ces are distributed homogeneously throughout the mate­ rial. In addition, if uranium-235 is present in metallic or oxide forms, it shall not form a lattice arrangement within the package. (e) Packages containing any fissile substances provided that they do not contain more than 5 g of fissile substances in any 10-litre volume. The substances shall be packed in packages which will maintain the limitations on fissile substances distribution during normal transport. 3605 3609 3610 (£) Packages containing individually not more than 1 kg of total plutonium, of which not more than 20 per cent by mass may consist of plutonium-239, plutonium-241,. or any combination of those radionuclides. (g) Packages containing liquid solutions of uranyl nitrate enriched in uranuim-235 to a maximum of 2 per cent by mass, with a tolerance for plutonium and uranium-233 of up to '0.1 per cent of the mass or uranium-235. The packages shall also comply with the other relevant parts of this Appendix. B. General Provisions for Nuclear Safety (l) All fissile substances shall be packed and shipped in such a: manner that criticality!! cannot be reached under any foreseeable circumstances of transport. In particular, the following contingencies shall be considered: (a) water leaking into or out of packages; (b) the loss of efficiency of built-in neutron abosrbers or moderators; (c) possible rearrangement of contents into more reac­ tive arrays, either within the package or as a result of loss from the package; (d) reduction of spaces between packages or contents; (e) packages becoming immersed in water or buried in snow; (£) possible increase of reactivity due to temperature changes; (2) In addition, for irradiated nuclear fuel or unspecified fissile substances the following assumptions shall be made: (a) Irradiated nuclear fuel for which the degree of irra­ diation is not known and whose reactivity decreases with burn-up shall be regarded as unirradiated for criticality co­ ntrol. If its reacrtivity increases with burn-up, it shall be re­ garded as irradiated to the point of maximum reactivity. The reactivity of nuclear fuel for which the degree of irra­ diation is known may be assessed accordingly. (b) For unspecified fissile substances such as residues or scrap whose inrichment, mass, concentration, moderation ratio or density is not known or cannot be identified, the assumption. shall be that each parameter that is not known has the value which gives the maximum reactivity under credible conditions. (3) Packages of fissile substances, except as provided in marginal 3610, shall be classified as follows: (a) Fissile Class I: packages which are nuclearly safe in any number and in any arrangement under all foreseeable circumstances of transport: (b) Fissile Class II: packages which, in limited number, are nuclearly safe in any arrangement under all foresee­ able circumstances of transport; (c) Fissile Class III: packages which are nuclearly safe under all foreseeable circumstances of transport by reason cif special precautions, or special administrative or opera­ tional controls imposed upon the transport of the consig­ nment. C. Provisions Specific to Fissile Class I Packages 3611 (1) Each Fissile Class I package shall be so designed 3612 that, if it were subjected to the tests specified in marginal 3635: (a) water would not leak into or out of any part of the package unless water inleakage to, or outleakage from, that part, to the optimum foreseeable extent, has been assumed for the purposes of marginal 3614 (l); and (b) the configuration of the contents and the geometry of the containment system would no·t be altered so as to incre­ ase the reactivity significantly. l/ Jn applying criticality data, obtaned by either calculation or experiment, to the critacility clearance of transport packages, al- • lowance shall be made separately for any inaccuracy in the data or uncertainty concerning their validity. E<DHMEPII THI KYBEPNHIEQI (TEYXOI .6EYTEPO) (2) Fissile Class I packages shall satisfy the nuclear sa fety criteria specified in marginals 3613 and 3614. 1. For the individual package considered in isolation (1) The following conditions shall be assumed: (a) the package is "damaged" (for this purpose "dama­ ged" shall mean the evaluated or demonstrated condition of the package if it had been subjected either to the tests specified in marginals 3635 and 3637 (1) to (3), followed by that in marginal 3638 or to the tests specified in margi­ nals 3635 and 3637 (4), whichever·combination is the more limiting); and (b) water can leak into or out of all v.oid spaces of the package including those within the containment system, except that, where the package design incorporates special features to prevent the leakage of water into or out of cer­ tain void spaces even as a result of human error, absence of leakage may be assumed in respect of those void spaces. Such special features may include either: • (i) multiple high standard water barriers, each of which would remain leak tight if the package were subjected to the combinations of test~ specified in paragraph (l)(a); or (ii) high degree of quality control in the production and maintenace of packaging, ·coupled with special tests to de­ monstrate closure of each package before shipment. (2) The package shall be sub-critical by an adequate margin21 under the conditions specified in paragrafph (1), the physical and chemical characteristics being taken-into account, including any change in those characteristics wh­ ich could occur under the conditions of paragraph (1), and with the conditions of moderation and reflection as speci­ fied below: (a) with the substances within the containment system; (i) the most reactive configuration and moderation fore­ seeable under the conditions of paragraph (l); (ii) close full water reflection of the containment system or such greater reflection of the containment system as may additionally be provided by the surrounding material of the packaging, and, in addition, (b) if any part of the substances escapes from the co­ ntainment system under the conditions of paragraph ( 1 ): (i) the most reactive configuration and moderation consi dered credible; (ii) close full water reflection of the substances. 2. For consignments,of one or more packages (1) Any number of undamaged packages of one design in any arrangement shall be sub-critical; for this purpose "undamaged" shall mean the condition in which the packa­ ges are designed to be presented for transport. (2) Two hundred any fifty such packages when "dema­ ged" shall be sub-critical if stacked together in any arran­ gement and closely reflected on all sides of the stack by the equivalent of water (for this purpose "damaged" shall mean the evaluated or demonstrated condition of the pac­ kage if it had been subjected either to the tests specified in marginals 3635 and 3637 (1) to (3), followed by that in marg(nal 3638, or to the tests specified in marginals 3635 and 363 7 ( 4 ), whichever combination is the more limiting). Hydrogenous moderation31 between packages, and water leakage into or out of the packages consistent with the test results shall be.assumed to the extent which results in the greatest reac.tivity. 2/ For example, if.mass of fissile substance is an appropriate parameter for control. an adequate margin would be represented by limiting the mass to 80 per cent of that mass which would be critical in a similar system. 3/ The hydrogenous moderation may be considered to consist of either a uniform laver of full density water surrounding each package of water at ai; appropriate density homogeneously inter­ spersed between packages. 3. Examples of package designs requiring multilateral approval • Example I 3613 (The calculation shall be based on the following require ♦ 3614 ments: (a) Each individual package shall comply with the crite­ ria under marginals 3612 and 3613. (b) The package, whether damaged or undamaged, shall be such as to shiHd the fissile contents from thermal neu­ trons. (c) When a parallel beam of neutrons having an energy spectrum as specified in Table IV is incident at any angle 011 an undamaged package, the surface multiplication fac­ tor for epithermal neutrons, i.e. the ratio of the number of epithermal neutrons leaving the package to the number of epithermal neutrons entering the package, shall be less than one, and the energy spectrum of the neutrons that are emitted by the package in an infinite array shall be no har­ der than that of the incident neutron. (d) The package design shall comply with the criteria in marginal 3614 (2). TABLE IV - NEUTRON ENERGY SPECTRUM"1 Neutron energy Fractions of neutrons E with energy less than E 11.0 MeV 1.000 2.4 MeV 0.802 1.1 MeV 0.590 0.55 MeV 0.460 0.26 MeV 0.373 .. ., 0.13 MeV 0.319.-;:,;;;,-, . 43 keV 0.263 10 keV - 0.210 1.6 keV 0.156 0.26 keV 0.111 ;"1.;~ .. ~ 42 eV 0.072 5.5 eV 0.036 - ·- ~ 0.4 eV 0 •/ The spectrum is the epithermal portion of the equilibrium spectrum emergent from packages incorporating 5 cm thickness of wood in a critical array of such packages. • 4. Examples of package designs requiring uni.lateral ape proval Example I . • (1) The packaging shall be constructed so that the fissile contents are surrounded by a layer of material capable of absorbing all thermal neutrons incident on it41 and this neutron absorbent layer is then surrounded by a thickness of at least 10.2 cm of wood having a.minimum hydrogen content of 6.5 per cent by mass, so that the minimum external dimensio1i over the wood is 30.5 cm. (2) The packaging shall be so constructed that when "damaged" (for this purpose "damaged" shall have the meaning assigned in marginal 3613 (1)) the fissile co~ ntents will remain surrounded by the neutron absorbent layer, the neutron absorbent layer will remain surrounded by the wood, and wood will not be lost to an extent which . would reduce the thickness 9f the remaining wood to less than 9.2 cm or reduce the minimum external dimension over the remaining wood to less than 28.5 cm. 4/ This layer ·may consist of cadmium· at least 0.38 mm thick equivalent to 0.325 g cadmium per cm2. 1013 3615 3616 1014 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI 4EYTEPO) ned in marginal 3613 (1)). (3) The contents shall not exceed that permissible mass of fissile substances shown in Tables V to XIII which is consistent with: (a) the nature of the substances; (b) the ma­ ximum moderation; and (c) the maximum diameter (or vol­ ume) which ceuld occur if the package were "damaged" (for this purpose "damaged" shall have the meaning assig Note: A detailed calculation for a given package design in accordance with the method set out in marginal 3615 can give less restrictive values than those in Tables V to XIII. Appendix A.6 TABLE V AQUEOUS SOLUTIONS OF URANYL"1 FLUORIDE OR URANYL81 NITRATE Permissible mass of uranium per package as a function of the packaging wood density 1. Limited bv maximum i11tenrnl diarneler of inner rt'replade Inner \'food densi11 1101 t'\Ct'rding l.2;j g/cn13 and 1101 less lhan (g/cm3) receptacle ~. 0.6 ·. 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1.0 I.OS 1.1 diameter not exceeding (cm) kg uranium prr packagr 10.16 No limit No limit ' 0.084 0.120 0.157 0.193 0.231 0.267 0.301 0.335 0.370 0.400 0.429 2. Limited by maximum intenrnl rnlun1e of inner rereplarle Inner Wood densitr not exceeding 1.25 g/rni1 and not less 1han (g/cm3) receptacle 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1.0 1.05 1.1 volume not exceeding (1) kg uranium per package 2 0.152 0.380 0.66 l.01 l.4i 2.00 2.66 3.50 4.64 6.64 7.62 3 0.084 0.223 0.416 0.65 0.93 1.25 1.58 1.96 2.34 2.74 3.16 4 0.084 0.120 0.157 0.193 0.231 0.274 0.356 0.498 0.73 1.05 1.47 5 ' 0.084 0.120 0.157 0.193 0.23] 0.267 0.301 0.495 0.57 0.66 0.74 7 0.084 0.120 0.157 0.19:3 0.231 0.267 0.301 0.347 0.406 0.467 0.53 No limit 0.084 0.120 0.157 0.19:1 0.231 0.267 0301 0.335 0.370 0.400 0.429 •/ Uranium which indudps 110 L: 2:l:l a11d 11<1 ,;,on· 1ha11 1):3.;i pl'r 1·,'111 C235 bv mass 1.15 1.2 0.456 0.478 1.15 1.2 9.39 11.3 3.57 3.99 2.02 2.70 0.84 0.92 0.60 0.66 .0.456 0.478 1.25 • 0.498 1.25 13.3 4.42 3.55 1.02 0.73 0.498 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) Appendix A.6 TABLE VI NON-HYDROGENOUS UR.\NIUM·'1 COMPOUNDS OR MIXTURES IN WHICH THE URANIUM-235 CONCENTRATION.DOES NOT • • EXCEED 4.8 g/cm3 b/ (Including u1imoderated uramium metal of uraniurn-235 enrichment not exceeding 25 per cent by weight) Permissible mass of uranium per package as a function of the packaging-wood density 1. Limited by maximum internal diameter of inner receptacle Inner Wood densilv nol exceeding 1.25 g/rm3 and not less tban 0.6 g/crn3 receptacle diameter not exceeding (cm) kg uranium per package 10.16 No limit No limit 0.69 2. Limited by maximum internal volume of iuner receptacle • Inner Wood density 1101 exceeding 1.25 g/cm3 and 1101 less than g/cm3 receptacle 0.65 0.7 0.75 0.8 0.85 volume not exceeding (1) kg uranium per package 3 7.0 10.0 12.2 14.5 14.5 4 4,8 7.8 7.8 7.8 7.8 5 3.63 3.63 3.63 3.63 3.63 7 1.41 1.41 l.41 1.41 1.41 No limit U.69 U.69 0.69 0.69 0.69 0.9 14.5 7.8 3.63 1.41 0.69 u/ Uramium which includes 110 U:.?:i:i and no more llurn 93.5 per cent U235 by nrnss L/ Mixtures containing bt'rylliu111 or deulerium .an• t•xdudC'd and rnuss of C'arhou shall 1101 exrPr.d fin• times lhP allowed mass of uranium TABLE VII NON-HYDROGENOUS URANIUM"1 COMPOUNDS OR MIXTURES JN WHICH THE URANIUM-235 CONCENTRATION DOES NOT EXCEED 9.6 g/cm3 b/ (Including unmoderated uranium metal of uranium-235 enrichment not exceeding 50% by weight) Permissible mass of uranium per package as a function of the packaging wood density 1. Limited by maximum internal diameter of inner receptacle Inner Wood density 1101 exceeding 1.25 g/c1113 nnd not less than (g/c111") receptacle 0.6 0.()5 0.7 0.75 0.8 0.85 0.9 0.95 1.0 1.05 1.1 1.15 diameter not exceeding (cm) kg uranium per package 7.5 No limit 8 6 No limit 8.5 6 7 8 No limit 9 6 7 ,8 9.2 10 11 No limit 9.5 6 7 8 9.2 JO 11 12 14 15 No limit 10 6 7 8 9.2 10 11 12 14 15 16 17, 17 No limit 0.69 0.69 069 0.69 0.69 0.69 0.69 0.69 0.69 O.fi9 0.6<l 0.69 2. Limited by maximum internal volume of inner receptacle •. Inner Wood de~sity 1101 exceeding 1.25 g/cm" and not less than (g/cm3) receptacle 0.65 0.7 0.75 0.8 0.85 0.9 0.95 volume not exceeding (1) 3 7 8 9.2 10 11 12 14 4 4.8 7.8 7.8 7.8 . 7.8 7.8 7.8 5 3.63 3.63 3.63 3.63 3.63 3.63 3.63 7 1.41 1.41 1.41 1.41 1.41 1.41 1.41 No limit 0.69 0.69 0.69 0.69 0.69 0.69 0.69 1.2 1:23 17 19 0.69 0.69 1.0 14.5 7.8 3.63 1.41 0.69 a/ Uranium· which includes no U233 and no more than 93.5 pn ce11l u2:15 by mass b/ Mixlures-conlaining beryllium or deuterium arc> excludt-'rl nnd the niass or C'arhon shall nol excees five timrs thP allowP'1 rna!:is of uranium. 1015 1016 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) TABLE VIII UNMODERATED URANIUM'/ METAL Permissible mass of uranium per packnge as a function.of the packaging wood density l. Limited by maximum iuterna l dia111eter of inner receptacle Inner receptacle diameter not Wood density not exceeding l.25 g/cm3 and not less than (g/cm3) 0,6 0.65 0,7 0,75 0,8 0,85 0,9 0,95 1.0 1.0.5 LI exceeding (cm) kg uranium per package 6 No limit 6,5 6 7 No limit 7 6 7 8 9,2 JO • No limit 7,5 6 7 8 9,2 10 11 12 14 15 16 17 10 6 7 8 9,2 10 II 12 14 15 16 17 No limit 0,69 0,69 0,69 0,69 0.69 0,69 0.69 0,69 0,69 0,69 0,69 No limit' 6 7 8 9,2 10 11 12 14 15 16 17 2, Limited by maximum internal volume of inner receptacle Inner Wood density not exceeding L25 g/cm3 and not less than (g/cm3) receptacle 0,6 0,65 0,7 0,75 0,8 0,85 0,9 LO l.05 Ll LIS volume not exceeding (l) kg ura11ium per package 2 6 7 8 9,2 JO 11 12 14 15 16 17 3 6 7 8 9,2 10 II 12 14 14,5 14,5 14,5 4 6 7 7,8 7,8 7,8 7,8 7,8 7,8 7,8 7,8 7,8 5 3,63 3,63 3,63 3,63 3,63 3,63 3,63 3,63 3,63 3,63 3.63 7 1.41 1.41 L41 1.41 l.41 1.41 l.41 1.41 1.41 1.41 l.41 No limit 0.69 0,69 0,69 0,69 0.69 0,69 0,69 0.69 0.69 0,69 0,69 No limit"/ 6 7 8 9,2 JO II 12 14 15 16 17 us 1.2 us 17 17 19 17 17 19 0,69 0,69 0,69 17 17 19 L2 L25 17 17 19 14,5 14,5 14,5 7,8 7,8 7.8 3,63 3.63 3.63 l.41 1.41 l.41 0.69 0.69 0,69 l 7 17 19 •/ Uranium which includes no u23:i and no more than 93.5 per cent U235 by mass b/ These enhanced masses upply where lhe fissile.subsLances are i11 the form of massive metal pieces weighing not less than 2 kg each and free from re• entrant surfaces. Appendix A,6 TABLE IX 26.44 URANIUM"1 COMPOUNflS OR MIXTURES IN WHICH TME UHANIUM CONCENTRATION DOES NOT EXCEED g/crn3 11/U + 1.41 Permissible mass of uranium per package as a funclion of the packaging \\oud density I. Limited by maximum internal dinnu-•ter of i1111rl' rc-c·<·ptllclr Inner Woo<l density nol exceeding 1.25 g/cm3 .ind nol less than (g/cm3) receptacle O,li 0,65 0,7 0,75 0,8 ,0,85 0,9 0,95 LO LOS LI LIS L2 1.25 diameter nol exceeding (cm) kg uranium per package 6 No limil 6.5 2,80 6,0 No limi1 7 2,80 6,0 6,0 6,0 6,0 No limit 7,5 2,80 6,0 6,0 6,0 6,0 6,0 6,0 14 15 15,2 15,2 15,2 15,2 15,2 10 0,330 0,87 LIO L80 2,50 3.50 4,6 7,1 i, 7 9,6 IL6 13.8 16,I 18,3 No"limil 0,084 0,120 0,157 0,193 0,231 0,267 0,301 0,335 0,370 0.400 0.429 0.456 0.478 0.498 2. Limited Uy maximum internal \'Olume of inner receptacle ' .Inner Wood density Doi exa:cding J.25 g/cm3 and DOI leN than (g/cm3J receptacle 0,6 0,65 0,7 0,75 0,85 0,85 0,9 0,95 LO LOS LI Ll5 L2 J,25 volume 1101 exceeding (I) kg uranium 1u•r packag<' 2 0,152 0,380 0.66 LOI L47 2,00 2,66 3.50 4,64 6,04 7,62 9,39 IL3 13,3 3 0,08-1 0.223 0.416 0,65 ,0,93 L25 L58 L96 2,34 2,74 3,16 3,.57 3,99 4.42 4 0.084 0,120 0,157 0,193 0,231 0,274 0,356 0.498 0,73 LOS L47 2,02 2,70 3,55 5 0,084 0,120 0,157 0,193 0.231 0,267 0,301 0,495 0,57 0,66 0,74 0.84 0,92 L02 7 0,084 0,120· 0,157 0,193 0,231 0,267 0,301 0,347 0.406 0,467 0,53 0,60 0,66 0,73 No limit 0,084 0,120 0,157 0,193 0,231 0,267 0,301 0,335 0.370 0.400 0,429 0,456 0.478 0,498 a; Uranium which includes 110 U233 and no more lhan 93.5 per cenl U235 by rnAss (l>EK 104 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) TABLE X NON-HYDROGENOUS PLUTONIUM COMPOUNDS OR MIXTURES IN WHl~H THE PLUTON!lJj'\1-239 CONCENTRATION DOS NOT EXCEED 10 g/cm3 ' Permiuible lll9MI of p1ulonium per pack11~ H II function of the packagin~ wood density 1. Limiled by nrnximurn internal diameter of inner reccplaC'lc Jnner wood <lcnsity 1101 ('xeecding 1.25 g/(•m3 .and not less than (g/cm3) ., rP.ceptade 0.6 0.6,; 0.7 0.75 0.8 0.95 dinmctcr 110i exceeding (cm) kg pluloniurn per pnrkagc 6 No limit 6.5 1.(,0 •l.2 7 :l.60 4.2 1.7 5.3 7.5 :J.60 4.2 ,u 5.3 5.9 7.1 JO :u,o 4.2 ,u 5,3 5.9 7.1 No·limil o.,w;, 0,4ll'i 0.405 0.405 0.405 0.405 2. 1.imitt:d by mall.i111u111 i11t,·rnal voh1mt• •>f i11ner rccrplndt Inner n·ct'plaelc volumt-. ·not t'xcceding (I) 3 4 5 ~o limit Wood de11si1~· 1101 ('Xl·t•t·ding 1.25 g/cm3 ntul not less thnn (g/C'm3) O.h O.hS 0.7 kg plutonium per pac·kngc 3.60 4.2 4.7 :1.60 3.8,( 3.84 2.H Vl-1- 2.44 1.20 1.20 1.20 0.'10:'l O.•I05 0.405 1.05 1.1 No limit No limit 8.\ 8.3 0.405 0.405 0.7S 5.3 3.84 2.44 1.20 0.405 1.15 No limit 8.6 0.405 0.8 5.9 3.84 2.4•l. 1.20 0.405 1.25 8.9 0.405 t1./ Mixlures containinµ: herylliun1 and dculPriu111 an• t·;\dudcd and tlw mnss of carlion ~hall nol exceed 1/10 of the allowed mass of plutonium. Appendix A.6 TABLE XI UNMODERATED PLUTONIUM METAL Permissible mass of plutonium per package as a function of the packaging wood density I. Limited by maximum internal d 0 iameler of inner receptacle Inner Wood density no\ exceeding 1.25 g/em3 and not less than (g/cm3) receptacle 0.6 0.65 0.7 0,75 0.8 diameter not exceeding (cm) kg plutonium per package 4 3.20 No limit 10 3.20 3,60 3.90 4.2 4.4 No limit 0.405 0,405 Q.405 Q.405 0.405 No limit•/ 3.20 3.60 3.90 4.2 4.4 2. Limited by maximum internal volume of inner receptacle Inner Wood density no\ exceeding 1.25 g/cm3 and no\ less than (g/cm3) receptacle 0.6 0.65 0,7 0.75 . 0.8 volume not exceeding (I) kg plutonium per package 3 3.20 3.60 3.90 4.2 4.4 4 3.20 3.60 3.84 3.84 3.84 5 2,44 2.44 2.44 2.44 2.44 7 1.20 1.20 1.20 1.20 1.20 No limit 0.405 0.405 Q.405 Q.405 0.405 No limit"/ 3.20 i..i. 3.90 4.2 4.4 0,85 4,5 0.405 4.5 0.85 4.5 3.84 2.44 1.20 0,405 4.5 11 / These enhanced masses apply wll<.'re lhl' fissile substa11res are. 111 the form of ma~sive metal pieces weighing not less than 2 kg each and free from re­ enlranl surfaces. 1017 1018 ECDHMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) Appendix A.6 . TABLE XII PLUTONIUM COMPOUNDS OR MIXTURES IN WHICH THE PLUTONIUM CONCENTRATION 26.56 DOES NOT EXCEED g/cm3 H/Pu+l.35 Permissible mass of plutonium per package as a function of the packaging wood density 1. Limited by maximum internal diameter of inner receptacle Inner Wood density nol exceeding 1.25 g/cm3 and 1101 less than (g/cm3) receptacle 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1.0 1.05 I.I I.IS diameter not exceeding (cm) kg uranium per package 4 No limit 5 3.2 3.60 3.90 4.2 4.4 No limit 6 2.80 3.60 3.90 4.2 4.4 4.5 4.5 4.5 4.5 4.5 4.5 4.5 6.5 2.50 3.40 3.80 4.2 4.4. 4.5 4.5 4.5 4.5 4.5 4.5 4.5 7 2.20 3.10 3.70 4.2 4.4. 4.5 4.5 4.5 4.5 4.5 4.5 4,5 7.5 1.90 2.70 3.40 4.1 4.4. 4.5 4.5 4.5 4.5 4.5 4.5 4.5 8 1.60 2.30 3.0 3.80 4.4. 4.5 4.5 4.5 4.5 4.5 4.5 4.5 8.5 1.30 1.80 2.40 3.20 3,80 4.3 4.5 4.5 4.5 4.5 4.5 . 4.5 9 0.97 1.30 1.80 2.40 3.00 3.40 3.60 3.80 4.0 4.2 4.4 4.4 9.5 0.65 0.88 1.20 1.50 l.90 2.20 2.40 2.60 2.80 3.10 3.60 4.4 10 0.330 0.42 0.50 0.58 0.70 0.83 0.99 1.20 1.50 1.90 2.70 3.90 No limit 0.022 0.053 0.084 0.114 0.143 0.171 0.199 0.226 0.250 0.274 0.294 0.311 2. Limited by maximum internal volume of inner receptacle Inner Wood density not e,reeding 1.25 g/cm3 and not less than (g/cm3) receptacle 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1.0 1.05 1.1 1.15 volume not exceeding (l) kg uranium per package 2 0.152 0.309 0.52 0.80 1.16 1.59 4.5 4.5 4.5 4.5 4.5 4.5 .3 O.M7 0.13:l 0.247 OJ80 0.700 0.76 4.:i 4.5 4.5 4.5 4.5 4.5 4 0,022 0.076 0.095 0.133 0.700 0.700 0.700 0.700 0.700 0.89 1.19 1.55 5 0.022 0.053 0.085 0.118 0.700 0.700 0.700 0.700 0.700 0.700 0.700 0.700 7 0.022 0.053 0.084 0.114 0.700 0.700 0.700 0.700 0.700 0.700 0.700 0.700 No limit 0.022 0.053 0.084 0.114 0.143 0.171 0.199 0.226 0.250 0.274 0.294 0.311 TABLE XIII AQUEOUS SOLUTIONS OF URANIUM-233 NITRATE OR URANIVM-233 FLUORIDE Permissible mass of uranium per package as a function of the packaging wood density 1. Limited by maximum iutrrnal diamelC'r uf i1111cr n:'ceplaclc Inner Wood density not e.,reeding 1.25 g/nn" and not lrss than (g/cm3) receptacle 0.(, 0.65 O.i 0,7:i ·0.11 (1.115 O.<J 0.95 1.0 I.OS I.I l.15 diameter not exceeding (cm) • kg· uranium per package 9 No limit 9.5 0.035 0.067 No limit 10 0.035 0.067 0.100 No limit No limit 0.035 0.067 0.100 0.134 0.169 0.200 0.231 0.261 0.289 0.316 0.340 0.361 2. Limited by maximum internal volume ·or inner receptacle Inner Wood density not exceeding l.25 g/cm" and 1101 less than (g/cm3) receptacle 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1.0 l.05 I.I 1.15 volume not exceeding (I) kg uranium per package 2 0.152 0.309 0.475 0.71 0.99 1.33 1.71 2.l l 2.54 2.99 3.44 3.94 3 0.085 0.133 0.180 0.228 0.285 0.332 0.389 0.446 0.50 0.56 0.60 0.67 4 0.085 0.109 0.133 0.175 0.213 0.256 0.304 0.356 0.408 0.460 0.51 0.57 5 0.035 0.076 0.114 0.152 0.190 0.223 0.256 0.292 0.323 0.356 0.389 0.422 . 7 0.035 0.073 0.109 0.142 0.175 0.204 0.235 0.263 0.289 0.318 0.342 0.368 No limit 0.035 0.067 0.100 0.134 0.169 0.200 0.231 0.261 0.289 0.316 0.340 0.361 1.2 1.25 4.5 4.5 4.5 4.5 4.5 4,5 4.5 4.5 4.5 4.5 4.5 4.5 4.4 4.4 4.4 4.4 4.5 4.5 0.327 0.339 l.2 1.25 4.5 4.5 4.5 4.5 1.98 2.47 0.700 0.700 0.700 0.700 0.327 0.339 1.2 1.2:; 0.371 0.391 1.2 1.25 4.41 4.8 0.73 0.78 0.63 0.69 0.451 0.484 0.394 0.420 0.377 0.391 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) D. Pr9visions Specific to Fissile Class II Packages (1) Each Fissile Class II package shall be designed s~ that if it were subjected to the tests specified in marginal 3635: (a) Neither the volume nor any spacing on the basis of which nuclear safety for the purpose of marginal 3619 (a) has been assessed would suffer more than 5 per cent re­ duction, and the construction of the package would not per­ mit the entry of a 10 cm. cube. (b) Water would not leak into or out of any parl of the package unless water inleakage lo, or oulleakage from. that part, to the optimum foreseeable extent had been assumed in assessing the allowable number for the purpose of mar ginal 3619 (a). • (c) The configuration of the contents and the geometry of the containment system would not be altered so as to in­ crease the reactivity significantly: (2) Fissile Class II packages shall satisfy the nucler safety criteria described in ma.rgirlals 3618 and 3619. 1. The individual package considered in isolation, (1) The following conditions shall be assumed: (a) the package is damaged (for this purpose "damaged" shall mean the evaluated or demonstrated condition of the package if it has been subjected either Lo the tests specified in marginals 3635 and 3637 (1) Lo (3), followed by that in marginal 3638 or to the Lesls specified in marginals 3635 and 3637 (4), whichever combination is the more limiting): and (b) water can leak into or out of all void spaces of the package, including those within the containment svstem, except that, where the package design incorporates special features to preverit the leakage of water into or out of cer­ tain void·spaces even as a result of human error, absence of leakage may be assumed in respect of those void spaces. Such special features may include either: (i) multiple high-standard water barriers, each of which would remain leaktight if the package were subjected to the co.mbinations of tests specified in paragraph (1) (a): or (ii) a high degree of quality control in the production and maintenance of packaging, coupled with special tests Lo demonstrate closure of each package before shiplment. (2) The package shall be sub-critical by an adequate margin (see fott-note 2) under the conditions specified in paragraph (1), the physical and chemical characteristics being taken into account, including any change in those characteristics which could oecur under the conditions or paragraph (1 ), and with the. conditions of moderation and reflection as specified below: (a) with the substances within the containment system: (i) the most reactive configuration and moderation foresseable under the conditions of paragraph ( 1 ): (ii) close full water reflection of the containment s,stem • or such greater reflection of the containment system a·s mm· additionally be provided by the surrounding n;aterial or th~ packaging and, in addition. (b) if any part of the substances escapes from Lll(' con­ tainment system under the conditions of paragraph (I): (i) the most reactive configuration and moderation con sidered creadihle: (ii) close full water reflection of the substanct's. 2. Consignments of one or more packages An "allowable number" shall.be derived for each Fi~sile Class II package design. such that: (a) five limes the allowable number of undamaged jiack­ ages shall be sub-critical if slacked together i11 a11y arrange­ ment without anything between the packages. close rellec­ Lion on all sides of the stack by the equirnlenl of 1H1ter being assumed: for this purpose "undamaged .. shall 111ea11 the condition in which the packages are designed to be pre­ sented for transport; and • (b) twice the allowahle of such packages when damagt>d shall be sub-critical if stacked together in any arrangement 3617 3618 and closely reflected on all sides of the stack by the equiva­ lent of water (for this purpose "damaged" shall mean the evaluated or demonstrated condition of each package if it had been subjected either to the tests specified in marginals 3635 and 3637 (1) to (3) followed by that in marginal-3638, or to the tests specified in marginals 3635 and 363 7 (4), whicheve'i,combination is the more limiting); hydrogenous moderations3 between packages and water leakage into or out of the packages consistent with test re • suits shall be assumed to the extent which results in the • greatest reactivity. 3. Examples of package designs requiring no competent . authority approval Example I (requiring multilateral approval of shipment) Packages for Fissile Class II require to competent authority approval of package design provided that the following conditions are met: . (a) Packaging: the criticality safety of these consign­ ments does not depend upon the integrity of the packaging. Any packaging which complies with the other relevant re­ quirements of Class 7 with respect to the non-fissile radio­ active characteristics may, therefore, be used. (b) Contents - uranium metal, compounds and/or mix­ tures: the contents of any consignment consisting of the "allowable number" of packages shall not exceed the per­ missible mass of uranium-235 given in Table XIV per con ' signment as a function of enrichment for substances satis­ fying the following cpnditions: (i) Uranium-233 shall not be present. (ii) Beryllium and hydrogenous material eririched in deuterium shall not be present. (iii) The total mass of graphite present shall not exceed 150 times the total mass of uranium-235. (iv) Mixtures of fissile substances with substances having a higher hydrogen density than water, e.g., some hydrocar­ bon oils, shall not be present. This does not preclude the use of polyethylene for packing of wrapping. (c) Contents - uranium metal, compounds and/or mix­ tures not forming a lattice: the contents of any consignment consisting of the allowable number of packages shall not exceed the permissible mass of uranium-235 given in Table XV per consignment as a function of enrichment for substances satisfying the following conditions: (i) Uranium-233 shall not be present., (ii) Beryllium and hydrogenous material emiched in deuterium shall not be present. (iii) The total mass of graphite present shall not exceed 150 times the total mass of uranium-235. (iv) Mixtures of fissile substances with substances having a higher hydrogen density than water. e.g., some hydrocar­ bon oils, shall not be present. This does not preclude the use of polyethylene for packing or wrapping. TABLE XIV - PERMISSIBLE MASS OF URANIUM-235 PER CONSIGNMENT Uranium enrichment in mass Permissible mass per per cent of uranium-235 consignment grams of not exceeding uranium-235 93 160 75 168 80 176 40 184 30 192 20 .203 15 224 11 240 10 256 9.5 262 a ')7() 1019 3620 1020 • ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) TABLE XIV - PERMISSIBLE MASS OF URANIUM-235 PER CONSIGNMENT Uranium enrichment in mass Permissible mass per per cent of uranium-235 consignment grams of not exceeding uranium-235 8.5 276 8 284 7.5 294 7 300 6.5 312 6 324 5.5 340 5 360 4.5 380 4 400 3.5 440 3 500 2.5 600 2 820 1.5 1.360 1.35 1.600 1 3.400 0.92 6.000 (v) The fissible substances shall be distributed homoge­ neously throughout the contents. In addition, the sub­ stances shall not form a lattice arrangement within the package. TABLE XV - PERMISSIBLE MASS OF URANIUM-235 PER CONSIGNMENT ' - ' Uranium enrichment in mass Permissible mass per per cent of uranium-235 consignment grams of not exceeding uranium-235 4. 420 3.5 460 3 560 2.5 740 2 1.200 1.5. 2.800 1.35 4.000 (d) Contents - uranium and/or plutonium metal, com­ pounds and/or mixtures: the substances shall satisfy the following conditions: • (i) Beryllium and hydrogenous material enriched in deu­ terium shall· not be present. (ii) The total mass of graphite present shall not exceed 150 times the total mass of uranium and plutonium. (iii) Mixtures ·of fissile substances with substances hav­ ing a higher hydrogen density than water, e.g., some hy­ drocarbon oils, etc., shall not be present. This does not preclud,e the use of polyethylene for packing or wrapping. The total mass of fissile substances per consignment shall be such that: 235u w•msl Pu<sr•m•> 233u (sram•> ·---- + + ---- is not greater than 1 160 90 100 (e) Allowable number: the allowable number for a par­ ticular package to this specification will depend on the ac­ tual contents and is equal to the fissile mass limit per con­ signment divided by the actual fissile mass present in the package. In the case of the mixed nuclides in (d) above, the allowable number is: 160 235u + 1.6 X 233u + 1. 778 X Pu where 235u, 233U. and Pu are the numbers of grams of 235u, 233u and Yu present in the package. Where the package forms part of a mixed consignment the require­ ments of foot-note 1 to marginal 2700 (2) be met. (f) Shipment shall be subject to multilateral approval. E. Provisions Specific to Fissile Class III Packages Fissile Class III packages shall meet the general re quirements of marginal 3611 and shall be approved in ac­ cordance with marginals 3674 and 3675. 1. Examples of package designs requiring unilateral ap­ proval Example I (requiring multilateral approval of ship­ ment) Packages to the following specification require only uni­ lateral approval of the package design provided that the fol­ . lowing conditions are fulfilled: (a) The number of packages in any one consignment shall be so limited that: (i) twice this number of undamaged packages shall be sub-critical if stacked together in any arrangement without anything between the packages, assuming close reflection on all sides of the stack by the equivalent of water; for this purpose "undamaged" shall mean the condition in which the packages are designed to be presented for transport; and (ii) this number of packages when "damaged" shall be sub-critical if stacked together in any arrangement and closely reflected on all sides of the stack by the equivalent of water ( or this purpose "damaged" shall mean the evalu­ ated or demonstrated condition of each package if it had been subjected either to the tests specified in marginals 3635 and 3637 (1) to (3) followed by that in marginals 3638 or the tests specified in marginals 3635 and 3637 ( 4 ), whichever combination is the more limiting). Hydroge­ nous moderation 3/ between the packages and water leak­ age into or out of the packages consistent with test results shall be assumed to the extent which results in the greatest reactivity. (b) Shipment of these packages shall be made only under arrangements approved by the competent authori­ ties in conformity with marginal 3675, so as to prevent loading, transport of storage of these packages with other labelled packages of radioactive material. 2. Examples of fissile package design requiring no com­ petent authority approval Example I (requiring multilateral approval of ship­ ment). Packages to the following specification for fissile Class III re.quire no competent authority approval of package de­ sign provided the follo{ving conditions are met: (a) The package is currently approved as a Fissile Class II package and the number in any one consignment does not exceed twice the allowable number associated with the Fissile Class II approval. (b) Shipment of these packages shall be made only under arrangements approved by the competent authori­ ties in conformity with marginal 3675, so as to prevent loading, transport or storage of these packages with otehr Fissile Class II or Class III packages. Examples of such ar­ rangements are: (i) no other labelled packages of radioactive substances may be carried with the consignment in the same vehicle, and (ii) either transport shall be direct to the consignee with­ out any intermediate transit storage; or 3621 3622 3623 ECl>HMEPII THI KYBEPNHIECI (TEYXOI dEYTEPO) controls shall be imposed, by the provision of an escort, to prevent the packages of the consignment from being stacked with or allognside any other packages of radioac­ tive substances after an accident, or at any other time. The escort shall travel in a separate vehicle. Example II (requiring multilateral approval of shipment) Packages for Fissile Class III require no competent au­ thority approval of package design provided that the fol lowing conditions are met: • (a) Packaging: the criticality safety of these consign­ ments dnes not depend upon the integrity of the packaging. Any packaging which complies with the other relevant re­ quirements of this Appendix may therefore be used, pro­ vided it does not incorporate lead exceeding 5 cm in thick­ ness, tungsten or uranium shielding. (b) Contents - uranium metal, compounds and/or mix­ tures: the contents of any consignment shall not exceed the permissible mass of uranium-235 given in Table XVI per consignment as a function ·of enrichment fo'r substances satisfying the following conditions: (i) Uranium-233 shall not be present. (ii) Beryllium and hydrogenous material enriched in deuterium shall not be ·present. (iii) The total mass of graphite present shall not exceed 150 times the total mas of uranium-235. (iv) Mixtures of fissile substances with substances having a higher hydrogen density than water, e.g., some hydrocar­ bon oils, shall not be present. This does not preclude the use of polyehtylene for packing or wrapping. Appendix A.6 TABLE XVI ..:. PERMISSIBLE MASS OF URANIUM-235 PER CONSIGNMENT Uranium enrichment in Permissible mass per mass per cent of consignment grams of turanium-235 not exceeding uranium -235 93 400 75 420 60 440 40 460 30 480 20 520 15 560 11 600 10 640 9.5 655 9 675 8.5 690 8 710 7.5 730 7 750 6.5 780 6 810 5.5 850 5 900 4.5 950 4. 1.000 3.5 1.100 3 1.250 2.5 1.500 2 2.050 I, 1.5 3.400 1.35 4.000 1 8.500 0.92 15.000 (c) Contents - uranium metal, compounds and/or mix­ tures not forming a lauice: Table XVII ginves the permissi 3624 ble mass of uranium-235 per consignment as a function of enrichment, for substances satisfying the following condi­ tions: (i) Uranium -233 shall not be present. (ii) Berullium and hydrogenous meteral enriched in deu­ terium shall not be present. (iii) The total mass of graphite present shall not exceed 150 times the total mass of uranium-235. (iv) Mixtures of fissile substances with substances having a higher hydrogen density than water, e.g., some hydrocar­ bon oils, shall not be present. This does not preclude the use of polyethylene for packing or wrapping. Appendix A.6 (v) The fissile substances shall be distributed homogene­ ously throughout the contens. In addition, the sub-. stances shall not form a lattice arrangement within the package. • TABLE XVII - PERMISSIBLE° MASS OF URANIUM-235 PER CONSIGNMENT Uranium enrichment in Permissible mass per mass per cent of consignment kilograms of turanium-235 not exceeding uranium -235 4 1.05 1.15 3.5 1.4 3 1.8 2.5 3 2 7 1.5 10 1.35 (d) Conteilts - uranium and/or plutonium metal,. com­ pounds and/or mixtures: the substances shall satisfy the following conditions: • • •• -· • (i) Beryllium and hydrogenous material enriched in deu terium shall not be present. • (ii) The total mass of graphite present shall not exceed 150 times the total mass of uranium and plutonium. • (iii) Mixtures of fissile substances with substances. h~v­ ing a higher hydrogen density than water, e.g., some hydro­ carbon oils, shall not be present. This does not preclude the use of polyethylene for packing or wrapping. The total mass of fissile substances per consignment shall be such that: 235U (grams) Pu (grams) 233u (grams) , . + -- + ---- 1s not greater than 1 400 225 250 ( e) Conditions of transport:· the following .administrative controls shall be applied throughout the transport of the consignment: (i) The quantity of substances in a consignment shall not exceed that defined in (b ), ( c) or ( d) above; (ii) transport shall be direct to the consignee, without any intermediate transit storage. (I) Shipment shall be subject to multilateral approval. SECTION III - TEST AND INSPECTION PROCE­ DURES A. Demonstration of compliance with the test require­ ments (1) Demonstration of compliance with the test require­ ments of this chapter may be accomplished by any of the methods listed below or by a combination thereof. 1021 3625. 3629 3630 1022 ECJ>HMEPII THI KYBEPNHIEDI (TEYXOI 4EYTEPO) (a) Performance of tests with prototypes or samples of the packaging as normally presented for transport, in which case the contents of the packaging for the test shall simulate as closely as practicable the expected normal ra dioactive contents. • (b) Reference to previous satisfactory demonstrations of suffidently similar nature. (c) Performance of tests with models of appropriate seal~ incorporating those features which are significant with respect to the item under investigation, when enginnering experience has shown results of such tests to be suitable for design purposes. When a scale model is used, the need for adjusting certain test parameters, such as the penetrator diameter or the compressive load, shall be taken into account. (d) Calculation, or reasoned argument, when the calculative procedures and parameters are generally agreed to be reliable or conservativ e. (2) With respect to the initial con1itions for the tests of this chapter. except those in marginals 3637(4) to 3639, the demonstration of compliance shall be based on the as­ sumption that the package is in equilibrium at an ambient temperature of 38 ° C. With respect to the thermal test the effects of solar radiation can be neglected prior to and dur­ ing that test but shall be taken into account in the subse0 quent evaluation of the test results. B. Tests for packaging 1. Number of speciments to be tested The number of specimens actually subjected to the tests should be related to the number of packagings of that type which are to be produced, the frequency of use and the cost. The results of the tests may necessitate an increase in the number of specimens to meet the requirements of the test procedures .in respect of maximum damage. 2. Preparation of a specimen· for testing . (1) All specimen1! shall be examined before testing to indentify and record faults or damage including the follow­ ing: (a) divergence from the specifications or the drawings; (b) defects in construction; (c) corrosion or other deterioration; and ( d) distortion of features. • , (2) The containment system of the packaging shall be clearly specified. (3) The external features of the specimen shall be clearly indentified so that reference may be made simply and clearly to any part of such specimen. 3. Testing the integrity of containment and shielding After any of the applicable tests specified in marginals 3635 to 3637, it shall be further demonstrated that the in­ tegrity of the containment, or of the containment and shielding, has been retained to the extent required in marginals 3601 (15) to (17), 3602(2), 3603(1) and 3604(2) for the packaging under test. 4. Target for the drop tests specified in narginals 3635(4), 3636(2), 3637(2) and 3641(1) The target shall be a flat, horizontal surface of such a character that any increase. in its resistance to displace­ ment or deformation upon impact by the specimen would not significantly increase the damage to the specimen. 5. Tests for demonstrating ability to withstand normal conditions of transport (1) The tests are: the water spray test, the free drop test, the compression test and the penetratiQn test. Prototypes of the package shall be subjected to the free drop test, the compression test and the penetration test, preceded in each case by the water spray test. 'One prototype may be used for all the tests, provided that the requirements of para­ graph (2) are complied with. (2) The tirrie interval between the conclusion of the water spray test and the succeeding test shall be such that the water has soaked in to the maximum extent, without ap preciable drying of the exterior of the specimen. In the ab­ sence of any evidence to the contrary, this interval shall be taken to be about two hours if the water spray is applied from four directions simultaneously. No time interval should elapse, however, if the water spray is applied from each of the four directions consecutively. (3) Water spray test: Any water spray test shall be con­ sidered as satisfactory provided that: (a) the amount of water per unit of ground area is ap- proximately equivalent to a rainfall rate of 5 cm per hour; (b) the water impinges upon the specimen at an angle of approximately 45 ° from the horizontal; (c) the water is approximately uniformly distributed, as in a rainfall, over the entire surface of the specimen in the direction of the spray; (d) the duration of the spray is at least one hour; (e) the orientation of the packaging is such that the ef­ fects are expected to be the most severe for the features under investigation, and the specimen is supported so that it does not sit a pool of water. (4) Free drop test: The specimen shall fall onto the tar­ get so as to suffer maximum damage in respect of the safety features to be tested. • (a) The height of fall measured from the lowest point of the package to the upper surface of the target shall be as specified in Table XVIII. 3631 TABLE XVIII. FREE-FALL DISTANCE 3632 3633 3634 3635 FOR PACKAGES Packages mass Free-fall distance (kg) (m) less than 5000 1.2 5000 to < 10000 0.9 10000 to < 15000 0.6 15000 and greater 0.3 (b) For Fissile Class II packages, the free drop specified above shall be preceded by a free drop from a height of0.3 m on each corner or, in the case .of a cylindrical package, onto each of the quarters of each rim. (c) For fibreboard or wood rectangular packages not ex­ ceeding 50 kg in mass, a separate specimen shall be sub­ jected tffa free drop onto each corner from a height of 0.3 m. (d) For fibreboard cylindrical packages not exceeding 100 kg in mass, a separate specimen shall be subjected to a free drop onto each of the quarters of each rim from a height of 0.3 m. (5) Compression test: the specimen shall be subjected, for a period of 24 hours, to a compressive load exerted by a mass equal to the greater of the following: (a) the equivalent of 5 times the mass of the actual pack­ .. age; (b) the equivalent of 1 300 kg/m2 multiplied by the ver-. tically projected area of the package. The load shall be applied uniformly to two opposite sides of the specimen, one of which shall be the base on which the package would normally stand. (6) Penetration test: the specimen shall be placed on a rigid, flat, horizontal surface which will not move signifi­ cantly while the test is being carried out. (a) A bar of 3.2 cm diameter with a hemispherical end and weighing 6 kg shall be dropped and directed to fall, with its longitudinal axis vertical, onto the centre of the weakest part of the specimen, so that, if it penetrates suffi­ ciently far, it will hit the containment vessel. The bar shall not be significantly deformed by the test performance. E<DHMEPII THI KYBEPNHIEQI (TEYXOI 4EYTEPO) 1023 (b) The height of fall of the bar measured from its lower end to the upper surface of the specimen shall be 1 m. 6. Additional tests for Type A packaging designed for liquids and gases ( 1) Separate specimens shall be subjected to each of the following tests unless it can be demonstrated that one test is more severe for the specimen in question than the other, in which case one specimen shall be subjected to the more se­ vere test. (2) Free drop test: the specimen shall fall onto the target so as to suffer the maximum damage in respect of contain­ ment. The height of the fall measured from the lowest part of the specimen to the upper surface of the target shall be 9 m. (3) Penetration test: the specimen shall be subjected to the test specified in marginal 3635 (6) except that the height of fall shall be increased to 1. 7 m from the 1 m spec­ ified in marginal 3635 (6) (b). 7. Tests for demonstrating ability to withstand accident conditions in transport (1) The specimen shall be subjected to the cumulative effects of the mechanical tests specified in paragraph (2) and the thermal test specified in paragraph (3) in that order. A separate specimen shall be subjected to the effect of the water immersion test in paragraph (4). (2) Mechanical test: the test shall consist of two drops onto a target. The order in which the specimen is subjected to the two drops shall be such that, on completion of the mechanical test, the specimen will have suffered such dam, age as will lead to the maximum damage in the thermal test which follows. (a) For drop I, the specimen shall fall onto the target so as to suffer the maximum damage, and the height of fall measured from the lowest point of the specimen to the upper surface of the target shall be 9 m. (b) For drop II, the specimen shall fall onto the target so as to suffer the maximum damage, and the height of fall measured from the intended point of impact of the speci- • men to the upper surface of the target shall be 1 m. The tar­ get in this case shall be the upper end of a solid mild steel bar of circular section, 15 cm ± 0.5 cm in diameter. The target surface shall be flat and horizontal with its edges rounded off to a radius of not more than 6 mm. The bar shall be rigidly mounted perpedicularly on the foundation target described in marginal 3634 and shall be 20 cm long unless· a longer bar would cause greater damage; in that case, a bar of sufficient length to cause maximum damage shall be used. (3) Thermal test: any thermal test shall be considered as satisfactory provided that the heat flux incident on the specimen is not less than that which would result from ex­ posure for 30 minutes of the whole specimen to a radiation environment of 800°C with an emissivity coefficient of at least 0. 9. For purpose of calculation, the surface absorptivity shall be either that value which the package may be expected to possess if exposed to a fire or 0.8 , whichever is greater. In addition, when significant, convective heat input shall be included on the basis of still ambient air at 800°C during the thirty-minute period. After cessation of the external heat input to the specimen: (a) the specimen shall not be cooled artificially until an­ other three hours have elapsed or until it has been demon­ strated that all internal temperatures have begun to fall, whichever is the earlier; and (b) any combustion of materials of the specimen shall be allowed to proceed for three hours after the cessation of ex­ ternal heating to the specimen unless it terminates earlier naturally. • (4) Water immersion test: the specimen shall be im­ mersed under a head of water of at least 15 m for a period of not less than eight hours. For test purposes, an external pressure of water of 0.15 MPa (1.5. bar) (gauge) will be considered to meet these conditions. 8. Water in-leakage test for packages containing fissile substances (1) Packages other than Fissile Class I or Fissile Class II 3638 packages and any packages for which water in-leakage or 3636 out-leakage to the extent which results in greatest reactivity has been assumed for purposes of assessment under marginals 3614(2) and 3619(b) shall be exempted from the test. ' • (2) Before the specimen is subjected to the water in­ leakage test specified below, it shall be subjected to the tests in marginals 3637(2) and (3). (3) The speci~en shall be immersed under a head of water of at least 0.9 m for a period of not less than eight hours and in the attitude for which maximum leakage is ex­ pected. For this test an·ambient temperature of 38 °C is not required. 9. Tests for integrity of containment and shielding Any test or inspection method may be employed to de- 3639 termine whether the requirements of this section have been met after the specimen has been subjected to th~· tests in 3637 marginals 3635 to 3637, provided that the method can be demonstrated to meet the relevant requirements of marginals 3601 to 3604. C. Tests for special form radioactive substances 1. General (1) The tests are: the impact test, the percussion test, the 3640 bending test and the heat test. (2) Specimens (solid radioactive substances or capsules) to be tested shall be prepared as normally presented for transport. The radioactive substance shall be duplicated as closely as practicable. (3) A different specimen may be used for each of the tests. (4) The specimen shall not break or shatter when sub­ jected to the impact, percussion or bending tests. (5) The specimen shall not melt or disperse when-sub jected to the heat test. • ,.., • ·' • (6) After each test, a leaching assessment shall be per­ formed on the specimen by a method no less sensitive than· the methods given in marginal 3642. • <·' 2. Test methods (1) Impact test: the specimen shall {all onto the target 3641 from a height of 9 m. The target shall be as defined in mar ginal 3634. (2) Percussion test: the specimen shall be placed on a sheet of lead which is supported by a smooth solid surface and struck by the flat face of a steel billet so as to produce an impact equivalent to that resulting from a free fall of 1.4 kg through 1 m. The flat face of the billet shall be 25 mm in diameter with the edges rounded off to a radius of 3 mm ± 0.3 mm. The lead, of hardness number 3.5 to 4.5 on the Vickers scale and not more than 25 mm thick, shall cover and area greater than that covered by the speci­ men. A fresh surface of lead shall be used for each impact. The billet shall strike the specimen so as to cause maxi-· mum damage. (3) Bending test: the test is applicable only to long, slen­ der sources with both a minimum length of 10 cm and a length to minimum width ration of not less than 10. The specimen shall be rigidly clamped· in a horizontal position so that one half of its length protrudes from the face of the clamp. The orientation of the specimen shall be such that the specimen will suffer maximum damage when its free and is struck by the flat face of a steel billet. The billet shall strike the specimen so as to produce an impact equivalent to that resulting from a free vertical fall of 1.4 kg through 1 m. The flat face of the billet shall be 25 mm in diameter with the edges rounded off to a radius of 3 mm to ± 0.3 mm. (4) Heat test: the specimen shall be heated in air to a temperature of 800°C and held at that temperature for a period of 10 min and shall then be allowed to cool. 1024 E<DHMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) 3. Leaching assesment methods (1) For indispersible,solid substances: (a) The speciipen shall be immersed for seven days in water at ambient temperature. The water shall have a pH of 6 to 8 and a maximum conductivity of lOµS/cm at 20°C. (b) The water with specimen shall then be heated to a temperature of 50° ± 5 °C and maintained at this temper­ ature for four hours. (c) The activity of the water shall then be determined. ( d) The specimen shall then be stored for at least seven days in still air of humidity not less than 90 per cent at 30°c. • ( e) The specimen shall then be immersed in water of the same specification as in (a) above and the water with speci­ men heated ar 50 ° C ± 5 ° C and maintained at this tem­ perature for four hours. (f) The activity of the water shall then be determined. The activities determined in (c) and (f) above shall not exceed 1.85 kBq (0.05 µ Ci). (2) For encapsulated substances: (a) The specimen shall be immersed in water at ambient temperature. The water shall have a pH of 6-8 with a maxi­ mum conductivity of lOµS/cm. The water and specimen shall be heated to a temperature of 50 ° C ± 5 ° C and maintained at this temperature for four hours. (b) The activity of the water shall then be determined. (c) The specimen shall then be stored for at least seven days in still air at a temperature not less than 30°C. (d) Repeat (a). • (e) The activity of the water shall then be determined. The activities determined in (b) and (e) above shall not exceed 1.85 kBq (0.05 µ Ci). D. Inspection requirements to be fulfilled before first use and before each shipment of certain types of packages 1. Before first use Before first use of any package, the following require­ ments shall be complied with by the consignor: (a) For each Type B(U) and Type B(M) package, it'shall be ensured that the effectiveness of its shielding and con­ tainment, and, where necessary, the heat transfer charac­ teristics, are within the limits applicable to or specified for the approved design. (b) If the design pressure of the containment system ex­ ceeds 35 kPa (0.35 bar) (gauge), it shall be ensured that the containment system of each package conforms with the approved design requirements relating to the capability of that system to maintain its integrity under pressure. (c) Where, in order to comply with the unclear safety cri­ teria, neutron poisons are specifically included as compo­ nents of the packaging primarily for this purpose, tests shall be performed to confirm the presence and distribu­ tion of that poisoning. 2. Before each shipment Before each shipment of any package, the following re­ quirements shall be complied with by the consignor: (a) Type B(U) and Type B(M) packages shall be held until equilibrium conditions have been closely enough ap­ proached to demonstrate complian~e with the shipment re­ quirements for temperature and pressure unless an ex­ emption from these requirements has received unilateral approval. (b) It shall be ensured that all the requirements specified in the approval certificates have been satisfied. (c) It shall be ensured by examination and/or appropri­ ate tests that all closures, valves and other openings of the containment system through which the radioactive contents might escape are properly closed and, where appropriate, sealed in the manner for which the demonstrations of marginals 3603(1) and 3604(2) were made. 3642 3643 3644 (d) It shall be ensured that the provisions of marginal 3600(5 ), with regard to lifting attachments have been com­ plied with. SECTION IV. -CONTROLS FOR TRA\ISPOHT AND STORAGF. IN TRANSIT A. Mixed packing A package containing radioaclire substances shall not contain any other items except such articles and dol'u111c11Ls as are necessary for the use of the radioactive suhstanc·es. Such items may be included. provided that Llwre is 110 i11 teraction betwee11 them and the packaging or c·o11tP11ts that would reduce the safety of the package. B. Non-fixed radioactive conlami11atio11 The non-fixed radioactive co11tami11atio11 or1 am exter­ nal surface of the package shall be kept as low as 1;rncticn­ ble and shall al no time during normal Lrn11sporl exceed tlw levels laid down in Table XIX. The lel'el of 11011-fixed radio­ active contamination may be determined by wiping a11 area of 300 cm2 of the surface concerned by hand 1, ith a filter paper, or a wad of colton wool or any other material of this nature. TABLE XIX. MAXIMUM PERMISSIBLE LEVELS OF NON-FIXED RADIOACTIVE CO!\TAMI\ATIO:\ Maximum pern1issihle le1·el (st><' .Notenf) Contaminant Bq/em~ (µCi/mi2) Natural and depleted ura11iu111 and natural thorium only 37 10-:1 Beta and gamma emitters and the low-toxicity alpha emillers specified in Note"1 belo11 3.7 ]()·' All other alpha emitters 0.37 I o·,; a/ The above levels are Jll'rll1issihl,· 1d11·11 ,i1 t'r,ig<'d owr all\ area of 300 cm2 or llll\' part or tll<' s11rf'11<·<'. b/ Low toxicilY alpha ('111ill<'rs: lJraniurn-235 or ura11iu111-2:l8: thori,1111-2:12: rliori11111-221\ a11d thoriurn-230 when diluiPd lo a sp<'<'ific· :wli, ii\ oi' tlw .,a1111· onl,·r as that of natural uranium a11d naluntl rlioriu,11: radio1111C'lid,·s "irl, ,1 half-life of less tha11 l () da, s. Packages used for the transport of 'radioadi1e substanc~s such as irradiated fuel. shall be assessed to determine whether activitv is likelv to be leached to the surface e.g. by rain. The· frequen~y of such nssessment shall be related to the likelihood of radioacti,e contamination having been absorbed into the surface coating, particularly paint. When activity is likel, to he leached to the surface of the package. the continued use of such a package shall be conditional upon a radiation safct, assessment by a qualified person. C. Categories Packages and containers (both large a11a small) shall bP in one of the following three categories: 1. Category I-WHITE (1) Paekages: When the radia.tion level originating from the package al any time during normal transport does 1101 exceed 5 µSv /h (0.5 mrem/h) at any locatio11 011 the external surface of the package. and the package does not belong to Fissile Class II or III. (2) Containers: When the container contains packages of radioactive substances none of which is in a category higher than Category I-WHITE. 3645 3649 36Sl :1652 3653 Cl>EK 104 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI 4EYTEPO) 2. Category II-YELLOW (1) Packages: When the radiation level limit in marginal 3654 3653(1) is exceeded, or the package belongs to Fissile Class II, provided that: . . (a) the radiation level originating .from the package al any time during normal transport does not exceed 0.5 mSv/h (50 mrem/h) at any location on the external surface of the package: and (b) the lranspprt index at any time during normal transport does not exceed 1.0. (2) Containers: When the transport . index of the container at any time during normal transport does not exceed 1.0, and when it contains no packages of Fissile Class III. 3. Category III-YELLOW (1) Packages:· When either of the two limits in inarginal · 3655 3654(1) is exceeded, or when the package belongs to Fissile Class II or Class· III, or when the package .is beipg transported under special arrangemeni. provided that: (a) the radiation level originating· from the pa~kage al any time during normal transport does not exceed 2 mSv/h (200 mrem/h) at any location on the external surface of the package, except that, for full load shipments u1ider the conditions specified in marginal 3659(7). the··maxim~m allowable level shall be 10 mSv/h (1.000 mrem/h): and (b) the transport index at any time during i1ormai transport does not exceed 10 unless the package is being transported as full load. ' (2) Containers:. when the transport index of the container, at any time· during normal tra1isporl. exceeds 1.0, or when the container carries packages belonging to Fissile Class III, or when it is bei11g transported, under special arrangement. • •• • • • D. Labelling and marking (see Appendix A.9) (1) Each package and container (both large and small) 3656 shall bear at least two labels which conform to the models 7 A, 7B or 7C in Appendix· A.9 according lo the category (see marginals 3652 to 3655) of that package or container. • (2) The labels shall be affixed to two opposite sides of the outside of the package, or on the outside of all fot1r sides of the container. • (3) The labels shall be completed as follows in a clear and indelible manner: ' • (a) next to the word "contents'" shall be indicated the radionuclide or the substance whose presence constitutes the principal danger in the event of damage lo the package (for example: strontium -90: irradiated uranium. radioactive LSA); . (b) next to the word "activity" shall be wrillen the activity in curies; • • . Note: This activity may also be expressed in micro. milli . or kilocuries on condition that the ·prefixed micro. milli and kilo are written in full; . (c) on the label to Model Nos. 7B and 7C shiill be written, in addition, the transport index in the largest possible figures in the frame intended for that purpose. (4) Each package of gross mass exceeding 50 kg shall have its gross mass plainly and durably marked on the outside of the package. (5) Each package which conforms lo a Type A packaging design shall be plainly and durably marked on the outside of the package with "Type A". (6) Each package which conforms to a design approved under marginals 3672 to 367 4 shall be plainly and durably marked on the outside of the package with the identification mark allocated to that. design by the competent authority and, in the case of a Type B(U) or type B(M) package deisign, with "Type B(U)" or "Type B(M)". (7) Each package which conforms to a Type B(U) or Type • B(M) package design shall have the outside of the .. outermost receptacle which is resistant to the effects of fire and water plainly marked by embossing, stamping or other means resistant to the effects of fire and water with tlw trefoil symbol shown in the labels to models 7 A to 7C. E. Segregation of radioactive substances Packages of Category II-YELLOW or III-YELLOW shall be separated in carriage and in storage from packages which bear a label with the word "FOTO" by the safety distances given in the table in marginal 240 001 of Appendix B.4. F. Storage in transit (1) Packages of radioactive substances shall not be stored near dangerous goods with which mixed loading is prohibited (see marginal 2700(3)). (2) The number of Category II-YELLOW and Category III-YELLOW packages and containers stored in any one storage area, such as a transit area, terminal building. store-room or assembly yard, shall be so limited that the total sum of.the t ransport indices in any individual group of such packages or containers does not exceed 50. Groups of such packages and containers shall be stored so. as to maintain a spacing of at least 6 metres from other groups of such packages or containers. (3) Where control of package accumulations is effected by .-eference to the red bands marked on the labels there shall not be more than 50 Category II-YELLOW or 5 Category III-YELLOW packages in any one group of packages. Where packages of both categories are present. one Category IH-YELLOW package shall be taken as equivalent lo ten Category II-YELLOW packages. . (4) Except in the case of Fissile Class II or Class III packages, the limitations in marginal 3658(2) do not apply to packages marked "RADIOACTIVE • LSA" and containing low specific activity substance or those marked "RADIOACTIVE LLS" and containing low level solid radioactive substance when they are maintained in a compact stack or iri containers. • · • '· - • • r . , • (5) Mixing of different kinds of pYtk'irg~;· including Fissile Class I packages with Fissile Class II packages. 'is permitted. • G. Transport 1. Packages (1) Packages shall be so loaded in vehicles that· they cannot shift dangerously, upset or fall. (2) Provided that its average surface heal flux does no.t exceed 15W /m2, and that the surrounding cargo is not in· sacks or bags, a package may be carried among packaged general cargo without any special stowage provisions except as may be specially required by the competent authority in an appropriate certificate. If the heal flux , exceeds 15W /m2 the.package shall be carried as full load. (3) Categories I-WHITE, II, or III-YELLOW packages shall not be carried in cimpartmenls occupied by passengers, except those exclusively reserved for couriers specially authorized lo accompany such packages. (4) Mixing of different kinds of packages, including Fissile Class I packages with Fissile Class II packages. is permitted. (5) Accumulation of packages and containers shall be controlled as follows: (a) For both packages and containers, the number of packages and containers shall be so limited that the total sum of the transport indices in any vehicle does not exceed 50. Where this control of packages is effected by reference to the red bands marked on the packages see marginal 3658(3). (b) In the case of full loads the limits under paragraph (5)(a) shall not apply, provided that the radiation level under normal conditions of transport does not exceed 2 mSv/h (200 mrem/h) at any point on, and 0.1 mSv/h (10 mrem/h) at 2 m from the outside surface of a freight container or vehicle. For Fissile . Class II or III 1025 3657 3658 3659 1026 EG>HIViEPlr THI: KYBEPNHI:EOr (TEYXOr 4EYTEPO) consignments, or mixtures thereof. the full load shall not include more than the allowable number of packages (see foot-note to marginal 2700). (6) Vehicles and large containers carryi11g packages or containers labelled with any of the labels to Models 7A. 78 or 7C, or carrying full load consignments of any n1dioactive substances shall display the placard model No. 7 D prescribed in marginal 240 010 of Appendix 8.4 on the outside of ear.h of'the two lateral sides and the rear wall in the case of a vehicle. (7) In the case of full loads the radial ion level shall 1101 exceed: (a) 10 mSv/h (1000 rnrem/h). al any point 011 the external surface of any package. provided that: (i) the vehicle is equipped with an enclosure which. during normal lransporl. prevents the access of unauthorized persons lo the interior of the enclosurC': (ii) provisions are made to secure .the packages so that their ·position within the vehicle n'111ai11s 'f'ix<'d during normal • transport: (iii) thre are no loading or unloading operations lwl1H•t•11 the beginning and end of the lra11sport. Undenither conditions, the radiation 'le1:cl al any point <in the exleriial surfacP. of the package sluill 1101 excc·c•d 2 mSv/h (200 rnrem/h). (b) 2 mSv /h (200 mrPm/h) al any point 011 tlw outer surface of lhe v~hicle oi· large container. including th<' upper and lowP.r surfaces. and. in the cas<' of' an open vehicle at an y poihton the vertical planes projected from the outer edges·of ihe vehicle. on the upper surl'acc or the itoad, ahd oh the lowe1 .. exler11al surf,ice of tlie IPhicle and (c) 0.1 mSvih (10 rnrem/h) al any point 2 111 from the \'ertical planes represented by the outer lateral slirfacr·s of lfhe vehicle or 'large container. allff. if the load. is 'fraiisportei:I iii ail open vehicle'al any Ifoi11l 2 111 fro111 the vertical planf'S projected from ihe outer cdgt•s of the vehicle. • • (8) (a) The radiation level i11 any nonnalll' ocrnpiPd position of a vehicle slwll iiol exceed 20 µSv/h (2'111i·e111/h) during transpor!, 'U1idP.r such circu111slai1ces ilw carrin shall ensure'ihat'lhe i.lriver or any acco(npa11l'i11g pcrso11cll. shall not receive rnore ra<liatio11 'th,i11 5 ·111S1 (0.5 rc111) i11 aily 12 month period. Mai111aii1i11g the 111i11ii1iu111 di,;la11ces listed in fhe'table in•111argi11al 240.000 of A1jpe11ilix B.-1-. even in the absence of a protective shield. shall lw considered as keeping within the 20 µSl'/h (2 111n•1i1/h) limit.· (b) As ·ah alternative 10 '(a) abov(•. the cnrriPr 111m operate by a stlieme of work approl'ed 1hl' the co11IpclC'III at.iiliority \vllf'reby'records lllUS l be'kqll by. hi,11 or llie limes speiit'by persons travclli11g·i11 his 1ehielcs a1id the rndia1io11 levels 1ihose ·persons are subjected lo. in order Ih,11 110 person ·receives a greater dose than 3. 75 1i1SI' (:3 7S 111n'r11) in ·aily calendar qua,wr. 2. Tank Vehicles Low-specific-activity substances. LSA (1). or 111hrgi11al 2703. ·schedule ·5. other Ih,i11 ura11iu111 ht>xafluiiridt• and suostances liable to·spoiitaneous ig11iIio11. 111ay lw carried in tank-vehicles in accordance with lh(• 1'·pq11ir('IIH'llls of Appendix B.la. 3. Ta1ik°Coi1tai11ers •l'.ow 'specific-activity suhsla11ccs. I.SA (I). of 111argi11al 2703, ·schedule 5. i11cludi11g natural or deplc·lt•d ura11iu111 hexafluoride, may be carried i11 1a11k-c·tHllai11t•r,; in accoraance with ti1e requirements <if .'\ppc·11ilix B. I b. SEC°TION V - ADMINISTRATIVE HEQLIIU:msrs A:ppro,;al by co111pete1il authorili~s is ·1101 requin·d fnr package designs for substanct·s ('Ollsigi1ed under Schedules 1 '10 4 and, provided the c·o11te11Is are 1101 li,;,;il<' sbhstances requiring apf?roval under 111argi11al ,3iJ 71L for ,3()62 :3669 package designs for substances consigned under schedules 5 to 8. A. Approval of Special Form Radioactive Substances (1) Any design for special form radioactive substances. 3671 with the exception of the substances specif'ied in Schedules 3 and 4, shall require unilateral approval. An application for approval shall include: (a) a detailed description of the substances or. if a capsule, the contents; particular reference shall be made lo both physical and chemical states; (b) a detailed statements of the design or any capsule lo be used, including complete engineering drawings and schedules of materials and methods of eo11slruclio11 to be used; (c) a statement of the lesls which have been doue and their results, or evidence based 011 calculative methods lo show that the substances are capable of meeting·the tests. or other evidence that the special· form radioactive substances mf'et the requirements of this Appendix. (2) The competent authority shall establish a certif'icale '• stating that the approved design meets the definition of special form radioactive substances as defined in marginal 2700 (2) and shall·attribute lo that design an identification mark. The ~ertificale shall specify the details of the radioactive substances. 8. Approval of Package Designs 1. Approval of Type B(U) package designs (including those for Fissile Class I. Class II and Class III packages which are also subject lo marginal 3674) (1) Any design of Tyr,~ 8(U) package originating in a 3672 country party to ADR shall be approverl by the co111pele1il authority of this i;ouiitry: if the couulry where the paekage has been designerl is not parly·to ADR. carriage is possible on cohdition that: (a) a certificate has been supplied by this country. proviiig that the package sriiisf'ies 1he'Ieel111ical regulations of ADR, and that this r.ertif'icale is cou11ler-sigi1e<l by the competent authority of the f'irsl ADR cou11In· reached b, the consignment: (b) if no certif'icale has been supplied. the package design is approved by the co111pele11l authority of the first ADR country reached by the eo11sig11me11I: (2) An application for approval shall include: (a) a detailed description of the proposed contents with particular refereuee lo their physieal and ~he111ical slates and the ·nature of the radiation emilled: (b) a detailerl slalemenl of the design. i11cluding complete engineering drawings and schedules of nialcrials and methods of constructiou lo be used: • (e) a stalemenl of-the 'tests whi;·h 'have been done and their results. or evideuce based oil cidculati1 e 111etli'ods or other evidence that the package design is arlN1ualf' to meet the requirements of marginals :3602 and 3603: (d) the proposed operating and 1nai11le11a11ce instructions for the use of the package. in particular. in the case 'of packages likely to be immersed in- coi11a111i11a1ed ponds. ·the provisions incoi·poi'ated lo ensure that the surface of thP package is 1101 -co111ami11aIed tibo\'(' the permitled levf>ls: (e) if the package is designed to have a maximu111 iionnal operating'pressure in excess of'O. I MPa ( 1 bar) (gau~e). the application for approval shall. in particular. stale. in respect·of the'malerials of co11slruclion of the cod1ai11111P11t system, the spPcif'ications. the samplt>s lo br Iakr11 1111d the tests to be nrni-Je: (f) where ihe proposed eo11te11Ls areirra<fiated ftH:i. lht' applicant shall slate aud justify an\' assumptiou in tlw safety analysis relating to 'the characleristics of the i'uel: (g) any special stowage provisions nec'esshr~· 10 Pnstll'<' the safe dissipation of heal from the package: r·cinsiderlllion shall be given to the type of '1·t'l1ir-le or c·o1itairwr (see marginal 3681 (1) (a)): ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) ('1) a reproducible illustration. not larger than 21 cm X 30; cm, showing the make-up of the package. (3) The competent authority shall establish a certificate stating that the approved design rneets, the requirements for Ty,pe B(U) packages (see marginals 36 77 and 36 78). 2·. Approval of Type B(M) package design (including those for Fissile Class I, Class II and Class III packages which are also subject to marginal 3674) (1) Each type B(M) package design shall require multilateral approval. (2) An application for approval of,a Type B(M) package design shall include, in addition to the information required in marginal 367.~ (2) for Type B(U) p\lc~ages: (a) a list of t~ose specific additional requirements for. Type B(U) packages specified in marginal 3603 with which the package does not conform; (b) any proposed supplementary operational controls"/ lo compensate for the Q!, ficiencies listed in (a) above: and (c) a sla!e ment relative to any special.loading. carriage. unloading, Cff handling procedures; (d) the maximum and minimum ambient conditions • (temperature, solar radiation) expected to be encountered during tr.ansporl (Ind which haye been taken into.acc;ount in the design. ' (~) The competent authority shall.establish a certificqle stating that the (lpproved package · design meets the requirements for Type B(M) packages (see marginals 3677 lo 3679). 3 . Approval of Fissile Class I. Class II and Class Ill package design (1) Package designs complying with the examples in marginal 3620, 3623, or 3624 shall· require 110 further competent authority approvals. (2) Package designs. complying with the examples in marginals 3616 and 3622 shqll require unilateral approval. (3) All other package designs shall require multilateral approval. (4) An application for apprornl shall include all information necessary to satisfy the competent authority that the design meets the requiremtnls of marginals 3610 to 3624. (5) T he co111petent authority sh!lll establish a certificate (see marginals 36 77. to 36 79) stating that. the approved package design meets the requirements of marginals 3610 to 3624. • C. Approval of Shipments. (l) Multilateral shipment approvals shall be required for: the following packages: (a) Type B(M) packages specially designed lo allow co11dinuous venting. (b) Typj:! B(M) packages containi11g radioactive materials with an aqtivity greater than 3 X 103 Al or 3 X 103 A21 as appropriate, or 1110 TBq, (3 X. 104 Ci),"-' whichever is the lower; (c) Fissile Class II packages complying with marginal 3620. (d) Fissile Class III, packages. H qwev er, a competent auth9rity can1author.ize transport into ,Qr through it!> country, without shipment approval, by a specific; pr<>vision in i~ design a.pproval. :,; That. is. operalio11al c·o11lrols duri11)-': 1n11isporl 11111 rou1i11c•h provided for in this Appendi, hut" hid1 ,11·1· co11sid,·r,·d ll!'c·,•ssan lo ensure the s~fely of tlw pn<'kag{' durin~ lransporl. ~Lwli a,..; hu1nan intervention for ternperalutT or pn•,..;:-.11n· rnt:a:,;1ir('llH'lll:-. or for periorlical 1·rnti11p:. Tlws,· r·onlrols shall .il-.11 lak,· i11111 account tl]~ possibili11 or u1H'\p1·r·icd. dnlm. 3673 3674 3675 : (2) An application for shipment approval shall i11~lud~: (a) the·period of time, related to the shipment,for which the approval is sought; (b) the actual contents, the type of vehicle and the probable or prop<>sed route; and • (c) how the special- precautions and special administrative. and operational controls referred to in the package design certificates issued under m!lfginals 3673 and 36 7 4, are to be put into effect. (3) Upon approval of the shipment,. the competent authority shall issue a certificate (see marginals 367,7 to 367.9). ( 4) The package and shipment, certificates may be combined into a single certificate. , D. Approval of Transport by Special' Arrangement (1) A consignment ofradioactive'substances which does ot satisfy all the applicable requirements of this Appendix shall be transported only by special arrangement, which always requires multilateral approval. The special arrangements shall be adequate to ensure that the-over-all level of safety in transport is at least equivalent to that which would be provided if all the applicable requirements of this Appendix had been met. (2) An application for approval shall include the information required under marginals 3672 to 3675 and also: (a) a statement of the respects in which, and of the reas<>ns why, the consignment cannot be made in full accordance with the applicable requirements of this Appendix; and (b) a statement of any special precautions or special administrative or operational controls which shall be taken during transport to compensate for the failure to meet the applicaple requirements of this Appendix. f3) Upon approval of the special ar-rangment, the competent authority shall issue a certificate (see marginals 3677 to 3679). E. Competent Authority Certificates of Approval 1 .. Competent authority identification marks : .... (l) E!lch approval certificate issued by a comp~te·nt . authority shall·be iden~ified by an identification mark. The mark sha!] be ofthe following generalized type: Syr11bol of nationality of country6I Number /Type Code (a) The number shall be assigned by the competent authority, and shiµl be unique and specific with regard to the partic,4l~r design or shipment. The shipment approval identificatio'! mark shall. be clearly identified wjth the packa.ge design approval identification m!)rk. (b) The following type codes shall be used in the order listed to indicate the types of approval certificates issued: A Type A package design (when also a fissile class package) B(U) Type B(U)' package design B(M) Type B(M) package design F Fissile class package design S Special form material approval T Shipment X Special arrangement. {2) These type codes shall be applied as follows: (a) Each certificate and each package shall hear the appropriate identification mark composed of the symbols prescribed in paragraph,(!) except that for packages, only the applicable package design type codes shall appear following the second stroke, i.e. the "S", "T" and "X" shall not appear in the indentific:ation 111arking on the package. Where the package design approval and shipment approval are combined, the applicable Type Codes do not need to b~ repeated. For example: 6/ The signs referred to are the n!ltional distinguishing signs for motor vehicles in international traffic. 1027 3676 3677 1028 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) A/132/B(M)F: A Type B(M) Fissile Class package approved by Austria for package design number 132 (to be marked on both the package itself and on the package design approval certificate). • A/132/B(M)FT: The shipment approval certificate identification mark issued for that package design (to be marked on the certificate only). A/ 13 7 /X: The shipment approval certificate identification mark issued for Austrian design 137 under a special arrangements shipment (to be marked on the certificate only). (b) Where multilateral approval is effected by validation, only the identification marks issued by the country of origin of the design or shipment would be used. Where multilateral approval is effeted by .issue of certificates by successive countries, each certificate would bear the llppropriate mark and the package whose design was so approved would bear all appropriate identification marks. For example, (A/132/B(M)F) (CH/28/B(M)F) would be the identification marks of a package which was originally approved by Austria a!')d was subsequently approved, by separate certificate, by Switzerland. Additional indentification marks would be tabulated in a similar m.anner on the package. (c) The revision of cerificate numbers sha ll be indicated by a parenthetical expression following the indentification mark on the certificate. For example, A/132/B(U)F. (Rev .2) would indicate revision 2 of the Austrian-approved package design certificate; or A/132/B(U)F. (Rev.0) would indicate the original issue of the Austrian-approved package design certificate. For· original issue the parenthetical expression is optional and other words such as "(original issue)?' m~y also be used in lieu of"Rev.0)". Certificate revision .nuin~s.may only be issued by the country issuing the original certificate number. Revision by other than the issuing country shall require a new certificate and identification number .. (d) Additional symbols (as may be necessitated· by national requirements) may be added in brackets to the end of - the identification mark. For example, A/132/B(U)F (SP503). (e) It is not necessary to alter the identification mark on the package each time that a revision to the package certificate is made. Such alteration shall be made only in those cases where the revision of the package design certificate involves a change in the letter codes for the package design, following the second stroke. 2. Information required in certificates. Each approval certificate issued by a competent authority shall include the relevant information from the following: (a) The competent authority identification mark. (b) A brief description of the packaging, including materials of construction, gross mass, general outside dimensions, and appearance. This shall include a reproducible illustration not larger than 21 cm by 30 cm, showing the make-yp of the package. (c) A brief specification of the permitted contents, including any restrictions on contents ·which might not be obvious from the nature of the packaging. This should include the physical and chemical forms, the activities in curies (including those of the various isotopes, if appropriate), amounts in grams for fissile substances, and whether in special form. (d) Additionally, for fissile class packages: (i) Fissile Class I: a detailed description of the permissible contents and any special features, on the basis of which the leakage of water in respect of certain void 3678 spaces has been assumed in the-criticality assessment (see marginal 3613 (b)). • (ii) Fissile Class II: a detailed description of the permissible contents, the corresponding . allowable numbers (or transport index) and any special features, on the basis of which the leakage of water in respect of certain • void spaces has been assumed in the criticality assessment (see marginal 3618 (b)). (iii) Fissile Class III: a detailed description of the individual consignments including the permissible contents and the corresponding allowable numbers (or transport indices) together with any special precautions to be taken during transport. (e) A , statemen t regarding the ambient co~ditions assumed for purpose of design (see marginal 3602 (4)). (f) For Type B(M) packages, a statement specifying those prescriptions of marginal 3603 with which the package does not conform ~nd any amplifying information which niay be useful to other competent authorities. (g) A reference to the'following information provided by the applicant: (i) instructions on the use and maintenance of the packaging; ' (ii) the actions to be taken by the c~~signor prior to the . shipment, e.g. any special decontamination procedures. (h) A detailed listing of any supplementary operational requirements (see foot-note 5) for package preparation, loading transport, storage, unloading, and handling, including any special stowage provisions for the safe dissipation of heat from the package, or a statement that no such controls are required. {j) A statement authorizing shipment where shipment approval is required under marginal 3675 .. (k) Any restrictions on the types of vehicle containers, and any necessary routing instructions. (I) Emergency arrangements ~pecific to the approved design. . . (m) The following statement: "This certificate does not relieve the consignor from compliance with any requirement of the government of any country through or into which the package will be transported". (n) An issue date, and, if appropriate, an expiry date. ( o) Signature and identification of the certifying official. (p) Appendices containing certificates for alternative package contents, other competent authority validations, or additional technical data or information. 3. Validation of certificates. Multilateral approvals may be by validation of the 36 79 original certificate issued by the competent authority of the country of origin of the design or shipm ent. F. Consignor's. Responsibilities. 1. Particulars of consignments. The consignor shall. include in the transport document for each consignment or radioactive substances, as well as the description given in the appropriate schedule,: the following details: (a) The statement "The nature of the goods and the packaging are in conformity with the provisions of ADR". (~) The identi~cation mark for each competent authority cerl!ficate (special form, p~ckage design, and shipment) applicable to the consignment. ( c) The name of the radioactive substances, or nuclide. (d) A description of the physical and chemical form of the substance, or whether it is in special form. (e) The activity of the radioactive substances in appropriate curie units. (f) The category of the package, i.e. I-WHITE, II-YELLOW, III-YELLOW. (g) The transport index (Categories II - and III-YELLOW only). (h) For a consignment of fissile subst~nces: 3680 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) 1029 (i) If exempted under marginal 3610, the words "FISSILE EXEMPT"; or (ii) if not so exempted, the fissile class of the package(s). 2. Information and notification for carriers. (1) The consignor shall provide in the transport document a statement regar ding actions, if any, that must be taken by the carrier. The statement shall be in the languages deemed necessary by -the carrier or the authorities concerned, and shall include at least the following points: (a) supplementary operational requirements for loading, transport, storage, unloading, handling, and stowage for safe dissipation of heat, or a statement that no supplementary operational requirements are necessary (see marginal 3678 (h)); (b) any necessary routing instructions (see marginal 3678 (k)). (c) emergency arrangements specific to the approved design (see marginal 3678 (1)). (2) In all cases where approval of the shipment or prior notification to the competent authority is required, all the carriers shall be informed of the requirements in advance, . in order that they may take in good time any measures required for the transport. 3. Notification to competent authorities. (1) Before the first shipment of a Type B(U) package containing radioactive substances with an activity greater than 3 Cl 103 A or 3 X 103 A , as appropriate, or 1110 TBq (3 X 10 Ci), wbichever is the lower, the consignor shall ensure that copies of each applicable competent authority certificate applying to that package design have been submitted to the competent authority of each country in whose territory the consignment is to be transported. The consignor is not required to await an acknowledgement from the competent authority, nor is the competent" authority required to make such acknowledgement of receipt of the certificate. : (2) For each shipment listed in (a) to (d) below inclusive, I the consignor shall notify the competent authorities of each country in whose territory the consignment is to be 3681 3682 transported. This notification shall be in the hands of each competent authority prior to the commencement of the shipment, and preferably at least 15 days in advan9e. (a) Type B(U) packages containing radioactive3 substances with an ac~ivity greater than 3 X 103Ai' ?r 3 X 103 A2, as appropnate, or 1110 TBq (3 x 10 C1), whichever is the lower." ' (bf Type B(M) packages. (c) Fissile Class III packages under marginal 367 4 (3). (d) Transport by special arrangement. (3) The consignment notification shall include: (a) sufficient information to enable the identification of the package, including all applicable certificate numbers and identification marks; :and (b) infoi:m~t~Qn on the date ~f shipment, the·-expected date of arrival and proposed routing. ( 4) The consignor is not required to send a separate notification if the required information has been .included in the application for shipment approval (see marginal 3675 (2)). 4. Possession of certificates. The consignor shall have in his possession a copy of 3683 each certificate required under this Appendix and a copy of the instructions with regard to the proper closing of the package and other preparation for shipment before making any shipment under the terms of the certificates. G. Quality Control in Fabrication and Maintenance of Packaging. • The manufacturer, consignor, or user of an approved 3684 package design shall be prepared to demonstrate to any cognizant competent authority that: (a) the constructional methods and materials used for the construction of the packaging are in accci;dance with:· the approved design requirements; the competent-· • authority may carry out inspection of the packaging ·during construction; (b) all packagings built to an approved design shall be maintained -in good condition so that they continue to'' comply with all relevant regulatory criteria, even after!,, repeated use. • 3685 :3689 '- .... 0 c.,., 0 I SECTION VI - ACTIVITY LIMITS DETERMINATION OF A 1 AND A2 1. Single radionuclides (1) For single radionuclides of known identity, the values of A1 and A 2 , are given in Table XX. The values of A 1 and A2 are also appicable for radionuclides contained in (ot, n) or (y, n) neutron sources. TABLE XX, A 1 AND A2 VALUES FOR RADIONUCLIDES Symbol of Element and Al A2 Specific activity Ii radionuclide atomic number TB (Ci) TB (Ci) TB/g (Ci/g) q q l.ll x 104 2.7 X 10-1 s: 227 Ac Actinium (89) 37 1000 0.003 7.2 X 10 m 228 Ac 0.37· 10 0.15 4 8.1 X 104 2.2 X 106 :2 105 Ag Silver (47) 1.48 40 1.48 40 8.1 X 103 3.1 X 104 M t ll0m Ag 0.26 7 0.26 7 1.7 X 102 4.7 X 103 J: lll Ag 3.7 100 3.7 100 5.9 X 103 1.6 X 105 M 241 Am Americium (95) 0.3 8 3 X 10-4 0.008 1.2 X 10-2 3.2 ;i. < 243 Am 0.3 8 3 x 104 0.008 7.0 X 10-3 1.9 X 10-1 m 37 Ar (compressed or m "tl uncompressed) Argon (18) 37 1000 37 1000 3.7xl03 1.0 X 105 2 41 Ar (uncompressed) 0.74 20 074 20 1.6 X 106 4.3 X 107 J: M 41 Ar (compressed) 0.74 1 0.04 1 1.6 X 106 4.3 X 107 m 73 As Arsenic (33) 37 1000 14.8 400 8.9 X 102 2.4 X 104 IO M 74 As 0.74 20 0.74 20. 3.7 X 103 1.0 X 105 '=i 76 ·As 0.37 10 0.37 10 5.9 X 104 1.6 X 106 m 71 As 11.1 300 11.1 300 4.1 X 104 1.1 X 106 < X 2ll At Astatine (85) 7.4 200 0.26 7 7.8 X 104 2:1 X 106 0 193 Au Cold (79) 7.4 200 7.4 200 3.4 X 104 9.3 X 105 M 196 Au l.ll 30 1.11 30 4.4 X 103 1.2 X 105 t> m 198 Au 1.48 40 1.48 40 9.3 X 103 2.5 X 105 ~ 199 Au 7.4 200 7.4 200 7.8 X 103 2.1 X 105 m 131 Ba Barium (56) 1.48 40 1.48 40 3.2 X 103 8.7 X 104 "tl 133 Ba 1.48 4.0 0.37 10 1.5 X 10 4.0 X 102 ,g 140 Ba 0.74 20 0.74 20 2.7 X 103 7.3 X 104 7 Be Beryllium (4) 11.1 300 11.1 300 1.3 X 104 3.5 X 105 206 Bi Bismuth (83) 0.19 5 0.19 5 3.7xl03 9.9 X 104 207 Bi 0.37 10 0.37 10 8.1 2.2 X 102 Symbol of Element and Al radionuclide atomic number TB (Ci) q 210 Bi (RaE) Bismuth (83) 3.7 100 212 Bi 0.22 6 249 Bk Barkelium (97) 37 1000 82 Br Bromine (35) 0.22 6 14 C Carbon (6) 37 1000 45 Ca Calcium (20) 37 1·000 47 Ca 0.74 20 109 Cd Cadmium ( 48) 37 1000 115m Cd l.l'l 3·0 115 Cd 2.96 80 139 Ce Cerium (58) 3.7' 100 141 Ce 11.l 300 143 Ce 2.22 60 144 Ce 0.37 10 249 Cf Californium (98) 0.08 2 250 Cf 0.26 7 252 Cf 0.08 2' 36 Cl Chlorine (17) 11.i: 300 38 Cl 0.37 10 242 Cm Curium (96), 7.4 200 243 Cm 0.33 9 244 Cm 0.37 10 245 Cm 0.2·2 6 246 Cm 0.22 6 56 Co Cobak (27) 0.19 5 57 Co 3.3°3 90 58m Co 37 1000 58 Co 0.74 20 60 Co 0.27 7 51 Cr Chromium (24) 22.2 600 131 Cs Caesium (55) 37 1000 134m Cs 37 1000 134 Cs 0.3·7 10 ,ll A2 TB (Ci) q 0.15 4 0.22 6 0.04 1 0.22 6 3.7 100 1.48 40 0.74 20 2.59 70 1.11 30 2.96 80 3.7 100 7.4 200 2.22 60 0.26 7 7.4 1 l0-5 0.002 2.59 x 10-4 0.007 7.4 X 10-5 0.002 1.11 30 0.37 10 7.4 X l0-3 0.2 3.33 X 10-4 0.009 3.7 x;l0-4 0.01 2.22 X 10-4 0.006 2.22 X 10-4 0.006 0.19 5 3.33' 90 37 1000 0.74 20 0.26- 7 22.2 600 37 1000 37 1000 0.26 7 TB/g 4.4 X 103 5.6 X 105 6.7 X 10. 4.1 X 104 1.7 X 10-1 7.0 X 102 2.2 X 104 9.6 X 10 9.6 X 102 1.9 X 104 2.4 X 102 1.0 X 103 2.4 X 104 1.2 X 102 1.2 X 10-1 4.8 2.4 X 10 1.2 X 1()-3 4.8 X 106 1.2 x: 102 1.6 3.0 3.7 x10-3 1.3 X 10-2 1.1 X 103 3.1 X 102 2.2 X 105 1.2 X 103 4.1 X 10 3.4 X 103 3.7 X 103 2.7 X 105 4.4 X 10 Specific activity (Ci/g) 1.2 X 105 1.5 X 107 1.8 X 103 1.1 X 106 4.6 1.9 X 104 5.9 X 105 2.6 X 103 2.6 X 104 5.1 X 105 6.5 X 103 2.8 X 104 6.6 X 105 3.2 X 103 3.1 1.3 X 102 6.5 X 102 3.2 X 10-2 1.3 X 108 3.3 X 103 4.2 X 10 8.2 X 10 1.0 X 10-1 3.6 X 10-1 3.0 X 104 8.5 X 103 5.9 X 106 3.1 X 104 1.1 X 103 9.2 X 104 1.0 X f05 7.4 X 106 1.2 X 103 m e :I: s:: m :!! M I :I: M ,.. < m m ,, 2 :I: M m IO M "::j m < X 0 M t> m ~ m ,, .9 , . 0 i:,y , . ..... 0 ~ N Symbol of Element and Al A2 Specific activity . radionuclide atomic number TB . (Ci) TB (Ci) TB /g (Ci/g) q q q ' 135 Cs Caesium (55) . 37 ,1000 2.22 60 3:3 X 10·5 8.8 X 10·4 136 Cs 0.26 7 0.26 7 2.-7 X 103 7.4 X 104 137 Cs 1.11 30 · 0.34 9 3.6 9.8 X 10 m 64 Cu Copper (29) 2.96 80 2.96 80 1.4 X 105 3.8 X 106 e 165 Dy Dysprosium (66) 3.7 100 3.7 100 3.0 X 105 8.2 X 106 ::c 166 Dy 37 1000 7.4 200 8.5 X 103 2.3 X 105 s: m 169 Er Erbium (68) 37 1000 11.1 300 3.0 X 103 8.2 X 104 .,, 171 Er 1.85 50 1.85 50 8.9 X 104 2.4 X 106 M 152m Eu Europium (63) 1.11 30 1.11 30 8.1 X 104 2.2 X 106 -4 ::c 152 Eu 0.74 20 0.74 20 7.0 1.9 X 102 M 154 Eu 0.37 10 0.19 5 5.6 1.5 X 102 " 155 Eu 14.8 ·400 3.33 90 5.2 X 10 1.4 X 103 -< m 18 F Fluorine (9) 0.74 . 20 0.74 20 3.4 X 106 9.3 X 107 m 52 Fe Iron (26) 0.22 6 0.22 6 2.7 X 105 7.3 X 106 .,, 2 55 Fe 37 1000 37. • 1000 8.1 X 10 . 2.2 X 103 ::c 59 Fe 0.37 10 · 0.37 10 1.5 X 103 4.9 X 104 M .. m 72 Ga Gallium (31) 0.26 7 0.26 7 1.1 X 105 3.1 X 106 IO 153 Gd Gadolinium (64) 7.4 200 3.7 100 1.3 X 102 • 3.6 X 103 M 159 Gd 11.1 ,,300 11.1 300 4.1 X 104 1.1 X 106 '=i m 71 Ge Germanium (32) 37 1000 37 1000 5.9 X 103 1.6 X 105 -< 3 H Hydrogen (1) X 0 see T-tritium M 181 Hf Hafnium (72) 1.11 30 1.11 ,30 5.9X 102 1.6 X 104 I> 197m Hg Mercury (80) 7.4 200 7.4 200 2.4 X 104 6.6 X 105 m 197 Hg 7.4 200 7.4 200 9.3 X 103 2.5 X 105 :!i 203 Hg 2.96 80 2.96 80 5.2 X 102 1.4 X 104 m .,, 166 Ho Holmium (67) 1.11 30 1.11 30 2.6 X 103 6.9 X 105 .Q 125 I Iodine (53) 37 1000 2.59 70 6.3 X 102 1.7 X 104 126 I 1.48 40 0.37 10 2.9 X 103 7.8 X 104 129 I 37 1000 7.4 X 10·2 2 5.9 X 10-6 1.6 X 104 131 I 1.48 40 0.37 10 4.4 X 103 • 1.2 X 105 132 I 0.26 7 0.26 7 4.1 X 105 1.1 X 107 133 I 1.11 30 1.11 30 4.1 X 104 1.1 X 106 134 I 0.3 8 0.3 8 1.0 X 106 2.7 X 107 e t'1 ::,,:: ..... 0 .... I Symbol of Element and Al A2 Specific activity " radionuclide atomic number TB (Ci) TB (Ci) TB/g (Cijg) q q 135 I Iodine (53) 0.37 10 0.37 10 1.3 X 105 3.5 X 106 113m In Indium (49) 2.22 60 2.22 60 5.9 X 105 1.6 X 107 114m In 1.11 30 0.74 20 8.5 X 102 2.3 X 104 115 In 3.7 100 3.7 100 2.3 X 105 6.1 X 106 m e 190 lr Iridium (77) 0.37 10 0.37 10 2.3 X 103 6.2 X 104 :::c 192 lr 0.74 20 0.74 20 3.4 X 102 9.1 X 103 s: 194 lr 0.37 10 0.37 10 3.2 X 104 8.5 X 105: m g 42 K Potassium (19) . 0.37 10 0.37 10 2.2 X 105 6.0 X 106 M 85m Kr (uncompressed) Krypton (36) 3.7 100 3.7 100 3.1 X 105 8.4 X 106 -t 85m Kr (compressed) 0.11 3 0.11 3 3.1 X 105 8.4 X 106 :::c M 85 Kr (uncompressed) 37 1000 37 1000 1.5 X 10 4.0 X 102 ~ 85 Kr (compressed) 0.19 5 0.19 5 1.5 X 10 4.0 X 102 l:D 87 Kr (uncompressed) 0.74 20 0.74 20 1.0 X 106 2.8 X 107 m 87 Kr (compressed) 0.02 0.6 0.02 0.6 1.0 X 106 2.8 X 107 -g 2 140 La Lanthanum (5 7) 1.11 30 · 1.11 30 2.1 X 104 5.6 X 105 :::c LLS Low-level solid radioac- M m tive material 0 See Marginal 2700 (2) M LSA Low specific activity '=i material m < See Marginal 2700 (2) X 177 Lu Luterium (71) 11.1 300 lLl 300 4.1 X 103 1.1 X 105 0 MFP Mixed fission 0.37 10 0.015 0.4 M products t> m 28 Mg Magnesium (12) 0.22 6 0.22 6· 1.9 X 105 5.2 X 106 ~ 52 Mn Manganese (25) 0.19 5 0.19 5 1.6 X 104 4.4 X 105 m 54 Mn 0.74 20 0.74 20 3.1 X 102 8.3 X 103 -g 56 Mn 0.19 5 0.19 5 8.1 X 105 2.2 X 107 .9 99 Mo Molybdenum (42) 3.7 100 3.7 100 1.7 X 104 4.7 X 105 22 Na Sodium ~11) 0.3 8 0.3 8 2.3 X 102 . 6.3 X 103 24 Na • 0.19 5 0.19 5 3.2 X 105 8.7 X 106 93m Nb Niobium (41) 37 1000,1 37 1000 4.1 X 10 1.1 X 103 95 Nb 0.74 20 0.74 20 1.4 X 103 3.9 X 104 97 Nb 0.74 20 ~- · • 0.74 20 9.6 X 105 2.6 X 107 . 147 Nd. Neodymium (60) 3.7 100 3.7 100 3.0 X 103 8.0 X 104 149 Nd 1.11 30 1.11 30 4.1 X 105 1.1 X 107 I ..... 0 c.,;, c.,;, Symbol of Element and Al radionuclide atomic number TB (Ci) q 59 Ni Nickel (28) 37 1000 63 Ni 37 1000 65 Ni 0.37 10 237 Np Neptunium (93) 0.19 5 239 Np 7.4 200 185 Os Osmium (76) 0.74 20 191 Os 22.2 600 191m Os 7.4 200 193 Os 3.7 100 32 p Phosphorous (15) 1.11 30 230 Pa Proctactinium (91) 0.74 20 231 Pa 0.07 -2 233 Pa 3.7 100 210 Pb Lead (82) 3.7 100 212 Pb 0.22 6 103 Pd Palladium (46) 37 1000 109 Pb 3.7 100 147 Pm Promethium (61) 37 1000 149 Pm 3.7 100 210 Po Polonium (84) 7.4 200 142 Pr Praseodymium (59) 0.37 10 143 Pr 11.1 300 191 Pt Platinum (78) 3.7 100 193 Pt 7.4 200 197m Pt 11.1 300 197 Pt 11.1 300 238 Pu Plutonium (94) 0.11 3 239 Pu 0.07 2 240 Pu 0.07 2 241 Pu 37 1000 242 Pu 0.11 3 233 Ra Radium (88) 1.85 50 ,\ TB (Ci) q 33.3 900 3.7 100 0.37 10 1.85 X 10·4 0.005 7.4 200 0.74 20 14.8 400 7.4 200 3.7 100 1.11 30 0.03 0.8 7.4 X 10·5 0.002 3.7 100 0.007 0.2 0.22 6 25.9 700 3.7 100 2.96 80 3.7 100 0.007 0.2 0.37 10 7.4 200 3.7 100 7.4 200 11.1 300 11.1 300 1.11 X 10·4 0.003 7.4 X 10·5 0.002 7.4 X 10-5 0.002 0.004 0.1 1.11 X 104 0.003 0.007 0.2 Specific activity TB/g (Ci/g) 2.3 X 10-3 8.1 X 10·2 1.7 0.46 X 102 7.0 X 105 1.9 X 107 2.6 X 10·5 6.9 X 104 8.5 X 103 2.3 X 105 2.7 X 102 7.3 X 103 • 1.7 X 103 4.6 X 104 4.4 X 104 1.2 X 106 2.0 X 104 5.3 X 105 1.1 X 104 2.9 X 105 1.2 X 103 3.2 X 104 1.7 X 10·3 4.5 X 10·2 7.8 X 102 2.1 X 104 3.3 8.8 X 10 5.2 X 104 1.4 X 106 2.8·x 103 7.5 X 104. 7.8 X 104 2.1 X 106 3.5 X 10 9.4 X 102 1.6 X 104. 4.2 X 105 1.7 X 102 4.5 X 103 4.4 X 104 1.2 X 106 2.4 X 103 6.6 X 104 8.5 X 103 2.3 X 105 7.4 X 103 2.0 X 105 4.4 X 105 1.2 X 107 3.3 X 104 8:8 X 105 6.6 X 10·1 1.7 X 10 2.3 X 10·3 6.2 X 10·2 8.5 X 10-3 2.3 X 10·1 4.1 1.1 X 102 1.4 X 10·4 3.9 X 10·3 1.9 X 103 5.0 X 104 ..... 0 c., ,j:>. m e :::c 3: m :2 M I :::c M ~ < m m "'tl 2 :::c M m IO M '=i m < >< 0 M t> m ~ m "'tl .9 Symbol of Element and Al radionuclide atomic number TB (Ci) q 224 Ra Radium (88) 0.22 6 226 Ra 0.37 10 228 Ra 0.37 10 86 Rb Rubidium (3 7) l.ll 30 87 Rb Unlimited Unlimited Rb (natural) Unlimited Unlimited 186 Re Rhenium (75) 3.7 100 187 Re Unlimited Unlimited 188 Re 0.37 10 Re (natural) Unlimited Unl.imited 103m Rh Rhodium (45) 37 1000 105 Rh 7.4 200 • 222 Rn Radon (86) 0.37 10 97 Ru Ruthenium (44) 2.96 80 103 Ru l.ll 30 105 Ru 0.74 20 106 Ru 0.37 10 35 s Sulphur (16) 37 1000 122 Sb Antimony (51) l.ll 30 124 Sb 0.19 5 125 Sb 1.48 40 46 Sc Scandium (21) 0.3 8 47 Sc 7.4 200 48 Sc 0.19 5 75 Se Selenium (34) 1.48 40 31 Si Silicon ( 14) 3.7 100 147 Sm Samarium (62) Unlimited Unlimited 151 Sm 37 1000 153 Sm 11.1 ·300 113 Sn Tin (50) 2.22 60 125 Sn • 0.37 10 85m Sr Strontium (38) 2.96 80 85 Sr l.ll 30 87m Sr 1.85 50 A2 TB (Ci) q 0.02 0.5 0.002 0.05 0.002 0.05 1.11 30 Unlimited Unlimited Unlimited Unlimited 3.7 100 Unlimited Unlimited 0.37 10 Unlimited Unlimited 37 1000 7.4 200 0.07 2 2.96 80 l.ll 30 0.74 20 0.26 7 11.1 300 1.11 30 0.19 5 l.ll 30 0.3 8 7.4 200 0.19 5 1.48 40 3.7 100 Unlimited Unlimited 3.33 90 11.l 300 2.22 60 0.37 10 2.96 80 1.11 30 1.85 50 Specific activity TB/g (Ci/g) 5.9 X 103 1.6 X 105 3.7 X 10-2 1.0 8.5 2.3 X 102 · 2.3 X 103 8.1 X 104 2.4 X 10-9 6.6 X 10-8 6.7 X 10-10 1.8 X 10-8 7.0 X 103 1.9 X 105 1.4 X 10-9 3.8 X 10-8 3.7 X 104 1.0 X 106 8.9 X 10-10 2.4 X 10-8 1.2 X 105 3.2 X 107 3.0 X 104 8.2 X 105 5.6 X 103 1.5 X 105 2.0 X 104 5.5 X 105 1.2 X 103 3.2 X 104 2.4 X 105 6.6 X 106 1.3 X 102 3.4 X 103 1.6 X 103 4.3 X 104 1.4 X 104 3.9 X 105 6.7 X 102 1.8 X 104 5.2 X 10 1.4 X 103 1.3 X 103 3.4 X 104 3.0 X 104 8.2 X 105 5.6 X 104 1.5 X 106 5.2 X 102 1.4 X 104 1.4 X 106 3.9 X 107 7.4 X 10-io 2.0 X 10-8 9.6 X 10-1 2.6 X 10 1.6 X 104 4.4 X 105 3.7 X 102 1.0 X 104 4.1 X 103 l.lxl05 1.2 X 106 3.2 X 101 8.9 X 102 2.4 X 104 4.4 X 105 1.2 X 107 m e ::c 3: m "'U ;:; f ::c M ~ m m "'U 2 ::c M m IO M ~ m < X 0 M I:> m ~ m "'U .9 0 C;) C/l Symbol of Element and Al radionuclide atomic number TB (Ci) q I 89 Sr Strontium (38) 3.7 100 90 Sr 0.37 10 91 Sr 0.37 10 92 Sr 0.37 10 T (uncompressed) Tritium (1) 37 1000 T ( compressed) 37 1000 T (activated luminous) 37 1000 paint) T (absorbed on solid) 37 1000 carrier) T (tritiated water) 37 1000 T (other forms) 0.74 20 182 T Tantalum (73) 0.74 20 160 Tb Terbium (65) 0.74 20 96m Tc Technetium (43) 37 1000 96 Tc 0.22 6 97m Tc 37 1000 97 Tc 37 1000 99m Tc 3.7 • 100 99 Tc 37 1000 125m Te Tellurium (52) 37 1000 127m Te Tellurium (52) 11.1 300 127 Te 11.1 300 129m Te 1.11 30 129 Te • 3.7 100 131m Te 0.37 10 132 Te 0.26 7 227 Th Thorium (90) 7.4 200 228 Th 0.22 6 230 Th 0.11 3 231 Th 37 1000 232 Th Unlimited Unlimited 234 Th 0.37 10 Th (natural) Unlimited Unlimited A2 TB • (Ci) q 1.48 40 1.5 X 10-2 0.4 0.37 10 0.37 10 37 1000 37 1000 37 1000 37 1000 37 1000 0.74 20 0.74 20 0.74 20 37 1000 0.22 6 7.4 200 14.8 400 100 2.96 80 3.7 100 1.48 40 11.1 300 1.11 30 3.7 100 0.37 10 0.26 7 7.4 X 10-3 0.2 2.96 X 10-5 0.0008 1.11 X 1Q-4 0.0003 37 1000 Unlimited Unlimited o:37 10 Unlimited Unlimited Specific activity TB/g (Ci/g) · 1.1 X 103 2.9 X 104 5.6 1.5 X 102 1.3 X 105 3.6 x.106 4.8 X 105 1.3 X 107 3.6 X 102 9.7 X 103 2.3 X 102 6.2 X 103 4.1 X 102 1.1 X 104 1.4 X 106. 3.8 X 107 1.2 X 104 3.2 X 105 5.6 X 102 1.5 X 104 5.2 X 10-5 1.4 X 10-3 1.9 X 105 5.2 X 106 6.3 X 10-4 1.7 X 10-2 6.7 X 102 1.8 X 10 4 1.5 X 103 4.0 X 10 4 9.6 X 104 2.6 X 10 6 9.3 X 102 2.5 X 10 4 7.4 X 105 2.0 X 10 7 3.0 X 104 8.0 X 10 5 1.1 X 104 3.1 X 10 5 1.2 X 103 3.2 X 10 4 3.1 X 10 8.3 X 10 2 7.0 X 10-4 1.9 X 10-2 2.0 X 104 5.3 X 10 5 4.1 X 10-9 1.1 X 10-7 8.5 X 102 2.3 X 10 4 (See Table XXI) I-' 0 1:1,) °' m e ::c s: m .,, ;::; t ::c M ,-:: < m m .,, z ::c M m 0 M ":::j m < X 0 M r.:> m ~ m .,, .9 .. ./\' TABLE XX. (cont'd) Symbol of Element and Al ,\ Specific activity radionuclide atomic number TB (Ci) TB (Ci) TB/g (Cijg) q q Th (irradiated) Thorium (90) a/ a/ a/ a/ (cont'd) 200 TI Thallium (81) 0.74 20 0.74 20 2.2 X 104 5.8 X 105 201 TI 7.4 200 7.4 200 8.1 X 103 2.2 X 105 202 TI 1.48 40 1.48 40 2.0 X 103 5.4 X 104 204 TI 11.1 300 1.11 30 1.6 X 10 4.3 X 102 . 170 Tm Thulium (69) 11.1 300 1.48 40 2.2 X 102 6.0 X 103 171 Tm 37 1000 3.7 100 4.1 X 10 1.1 X 104 230 u Uranium (92) 3.7 100 3.7 X lQ-3 0.1, 1 X 103 2.7Xl04 232 u 1.11 30 1.11 X 10-3 0.03 7.8 X 10-1 2.1 X 10 233 u 3.7 100 3.7 X 10-3 0.1 3.5 X 104 9.5 X 10-3 234 u 3.7 100 3.7x10-3 0.1 2.3 X 104 6.2 X 10-3 235 u 3.7 100 3.7 X 10-3 0.2 7.8 X 10-8 2.1 X lQ-6 236 u 7.4 200 7.4 X 10-3 0.2 2.3 X 10-6 6.3 X 10-5 238 u Unlimited Unlimited Unlimited Unlimited 1.2 X 10-8 3.3 X lQ-7 U (natural) Unlimited Unlimited Unlimited Unlimited (See Table XXI) 20% Unlimited Unlimited Unlimited Unlimited (See Table XXI) U (enriched 20% 3.7 100 3.7 X 10-3 0.1 U (depleted) Unlimited Unlimited Unlimited Unlimited (See Table XXI) U (irradiated) b/ b/ b/ b/ V-48 Vanadium (23) 0.22 6 0.22 6 6.3 X 103 1.7 X 105 W-181 Tungsten (7 4) 7.4 200 3.7 100 1.9 X 102 5.0 X 103 W-185 37 1000 3.7 100 3.6 X 104 9.7xl0-3 W-187 1.48 40 1.48 40 2.6 X 104 7.0 X 105 131m Xe (compressed) Xenon (54) 0.37 10 0.37 10 3.7 X 103 1.0 X 105 •/ The values for A 1 and A 2 shall be calculated in accordance with marginal 3691 (3) taking into account the activity of the fission products and uranium-233 in addition to that of thorium. b/ The values for A 1 and A 2 shall be calculated in accordance with marginal 3691 (3) taking into account the activity of the fission products and plutoniuµi isotopes to that of the uranium. m e :::c s: m J! M I :::c M " -< m m "'tl z :::c M m :0 M ~ m < X 0 M r:> m ~ m "'tl .Q ...... 0 w .J Symbol of Element and radionuclii;le atomic number TB q 131m Xe (uncompressed) Xenon (54) 3.7 (cont'd) 133 Xe (uncompressed) 37 133 Xe (compressed) 0.19 135 Xe (uncompressed) 2.59 135 Xe (compressed) 0.07 90 y Yttrium (39) 0.37 91 Ym 1.11 91 y 1.11 92 y 0.37 93 y 0.37 175 Yb Ytterbium (70) 14.8 65 Zn Zinc (30) 1.11 69m Zn 1.48 69 Zn 11.1 93 Zr Zirconium (40) 37 95 Zr 0.74 97 Zr 0.74 • TABLE ~ (cont'd) Al A2 (Ci) TB q 100 3.7 1000 37 5 0.19 70 2.59 2 0.07 10 0.37" 30 1.11 30 1.11 10 0.37 10 0.37 400 14.8 30 1.11 40 1.48 300 11.1 1000 7.4 20 0.74 20 0.74 (Ci) 100 1000 5 70 2 10 30 30 10 10 400 30 40 300 20(} 20 20 Specific activity • TB/g (Ci/g) 3.7 X 103 1.0 X 105 7.0 X 103 1.9 X 105 7.0 X 103 1.9 X 105 9.3 X 103 2.5 X 105 9.3 X 103 2.5 X 105 9.3 X 103 2.5 X 105 1.5 X 106 4.1 X 101 9.3 X 102 2.5 X 104 3.5 X 105 9.5 X 106 1.2 X 105 3.2 X 106 6.7 X 103 1.8 X 105 3.0 X 102 8.0 X 103 1.2 X 105 3.3 X 106 2.0 X 106 5.3 X 107 1.3 X 104 3.5 X 10-3 7.8 X 102 2.1 X 104 7.4 X 104 2.0 X 106 ..... 0 t,IJ CX) 1; ::c s: m ,, M I ::c M :;ill. < m m ,, 2 ::c M m IO M "=i m < X 0 M t> m ~ m ,, .Q ECl>HMEPII THI KYBEPNHIEQI (TEYXOI L\EYTEPO) 1039 TABLE XXI. ACTIVITY-MASS RELATIONSHIPS FOR· URANIUM AND NATURAL THORIUM•/ (This table is referred to in Table XX). Radioactive material TBq/g (Ci/g) g/TBq (g/Ci) Uranium (wt/235L, present) 0.45 J.9 X JO• 5.0 X lQ·7 5.4 X }07 2.0 X 106 0. 72 (natural) 2.6 X JO' 7.06 X 10·7 3.8 X }07 1.42 X 106 1.0 2.8x 10• 7.6 X 10·7 3.5 X }07 1.3 1.5 3.7 X JQ• 1.0 X }Q-6 2.7 X }07 1.0 5.0 1.ox ]0·7 2.7 X JO·<> J.Ox JO' 3.7 10.0 l.8 X JO·' 4.ll X lQ•il 5.7 X 10' 2.1 20.0 :u X JO·' 1.0 X IQ·~ 2.7 X ]O' 1.0 :1s.o 7A X 10·7 2.0 X JO·' l.4X 10' 5.0 50.0 9.3X JO·' 2.5 X 10 .. ~ l.l X 106 4.0 90.0 2.1 X 10• 5.8 X JO·' 4.6 X 10' 1.7 93.0 2.6 X JO< 7.0 X 10.$ 3.8x 105 1.4 95.0 3.4 X J0·6 9.1 X 10' 3.0x 105 1.1 Natural thorium 8.J X J0·9 2.2 X 10·7 1.2 X )08 4.6 •/ The figures for uranium include the activity of uranium-234 which is concentrated during the enrichment process. The activity for thorium includes the equilibrium concentration of thorium 228. • (2) For any single radionuclide whose identity is known, but which is not listed in Table XX, the values of A 1 and A shall be determined according to the procedure give~ below: (a) If the radionuclide emits only one type of radiation, A1 shall be determined according to the rules in (i), (ii), (iii) and (iv) below. For radionuclides emitting different kinds of radiation, A1 shall be the most restrictive value of those determined for each individual radiation. However, in both cases A1 shall be restricted to a maximum of 3 7 TBq ( 1000 Ci). If a parent nuclide decays into a shorter lived daughter, of a half-life not greater than 10 days, A I shall be calcu­ lated for both the parent and the daughter, and the more limiting of the two values should be assigned to the parent nuclide. . (i) For gamma emitters, A 1 is determined by the expres­ swn: 4.65 X 106 9 A= l (in TBq) or A I (in Ci) Va where ( is the gamma-ray constant (in C.m.2.kg-1 ), corre­ sponding to the dose in C.kg. - 1s-1 at 1 m per Bq; the num­ ber 4.65x 106 results from the choice of 1 Orn Sv /hat a dis­ tance of 3m as the reference dose"-equivalent rate. where ( is the gamma-ray constant, corresponding tci the . dose in R,lh at 1 m per Ci; the number 9 results from the choice of 1 rem/h at a distance of 3 m as the reference dose equivalent rate. (ii) For X-ray emitters, A1 = is determined by the atomic number of the nuclide: . for Z .,.;; 55; A I = 37 TBq (1000 Ci) for Z > 55; AI = 7 .4 TBq (200 Ci) (iii) For beta emitters, A1 is determined by the maximum beta energy (Ema.) according to Table XXII. . (iv) For alpha emitters A 1 is determined by the expres­ swn: Al= 1000 A3 where A 3 is the value listed in Table XXIII. (b) A 2 shall be the more restrictive of the following two values: (i) the corresponding AI and (ii) the value A3 obtained from Table XXIII. X 106 X 106 X 105 X 105 X \Q!. X )04 X )04 X 104 X 10" X }04 X 106 TABLE XXII RELATIONSHIP BETWEEN A 1 AND E FOR BETA EMITTERS maa Em•• (MeV) TBq Al (Ci) < 0.5 37 1000 0.5 - < 1.0 11.1 300 1.0 - < 1.5 3.7 100 1.5 - < 2.0 1.11 30 > 2.0 0.37 10 TABLE XXIII RELATIONSHIP BETWEEN A AND THE ATOMIC NUMBER OF THE RADIONutLIDE Atomic number A3 Half-life less Half-life 1000 Half-life greater .. than 1000 days days to 106 years than 106 years 1 to 81 0.11 TBq (3 Ci) l.85GBq (50 mCi) 0.11 TBq (3 Ci) 82 and above 7 4 MBq (2 mCi) 74 MBq (2 mCi) 0.11 TBq (3 Ci) (3) For any single radionuclide whose identity is un­ known, the value of A shall be taken to be 74 GBq (2G) and the value of A2 shall be taken to be 7 4 MBq (0.002 Ci). However, if the atomic number of the radionuclide is known to be less than 82, the value of A 1 shall be taken to be 3 7 0 G Bq ( 10 Ci) and the value of A 2 shall be taken to be 14.8 GBq (0.4 Ci). 2. Mixtures of radionuclides, including radioactive decay chains (1) For mixed fission products the following activity lim­ its may be assumed, if a detailed analysis of the mixture is not carried out: Al = 370 GBq (10 Ci) A2 = 14.8 GBq (0.4 Ci) (2) A single radioactive decay chain in which the radionuclides are present in their naturally occurring pro­ portions and in which no daughter nuclide has·a half-life ei­ ther longer than 10 days or longer than that of the parent nuclide shall be considered as a single radionuclide. The activity to be taken into account and the A 1 or A2 value to be applied shall be those corresponding to tlie parent nuclide of that chain. However, in the case of radioacrtive decay chains in which any daughter nuclide has a half-life either longer than 10 days or greater than that of the parent nuclide, the parent and such daughter nuclides shall be considered as mixtures of different nuclides. • (3) In the case of a mixture of different radionuclides, where the identity and activity of each radionuclide are known, the permissible activity of each radionuclide. R1, R 2 ... R., shall be such that F I + F 2 + ... F. is not greater than unity, .where Total activity of R1 FI= Total acrtivity of R 2 F2 = Total acrtivity of R. F = " Ai (R1), Ai (R2), ... A (R ) is the value of A1 or A2 as appro­ priate for the nuclide R' I , R2 ... R •. 3691 . 1040 E(l)HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) 't ( 4) When the identity of each radionuclide is known but the individual activities of some of the radionuclides are not known, the formula given in paragraph (3) shall be applied to establish the values of A or A 2 as appropriate. All the radionuclides whose indiviclual activities are not known (their total a~tivity will, however, be known) shall be classed in a single group and the most restrictive value of Al. or A~ applicable to any one of them shall be used as the value ot A1 or A2 in the denominator of the fraction. (5) Where the identity of each radionuclide is known but the individual activity of none of the radionuclides is known, the most restrictive value of A1 or ~ applicable to any of the radionuclides present shall be adopted as the ap­ plicable value. (6) When the identity of none or only some of the nuclides is known, the value of A~ shall be taken to be 74 GBq (2 Ci) and the value of A 2 shall be taken to be 7 4 MBq (0.002 Ci). However, if alpha emitters are known to ,., be absent, the value of A 2 shall be taken to be 14.8 GBq •• (0.4 Ci). . SECTION VII. DECONTAMINATION, LEAKING PACKAGES AND ACCIDENTS (1) If a package containing radioactive substances is broken or is visibly leaking or is involved in an accident during carriage, the vehicle or affected area shall be iso­ lated so as to prevent all contact of persons with radioactive substances and, when possible, shall be duly marked off or surrounded by barriers. No-one shall be authorized to stay within the isolated area until qualified persons arrive to su­ pervise the handling and salvage work. The sender and au­ thorities concerned shall be notified immediately. Notwith­ standing these provisions, the presence of radioactive sub­ stances shall not be considered as a bar to operations for the rescue of people or fire-fighting. (2) If radioactive substances have leaked, have been spilled or have been ·scattered in any way whatever in a place, area or on to goods or equipment used in storage, qualified persons shall be called in as soon as possible to direct decontamination operations. The place, area or equipment thus contaminated shall only be put back into service when its use has been declared free from danger by qualified persons. (3) Except as provided for in paragraph (4) any vehicles, equipment or part thereof, which have been contaminated in the course of carriage of radioactive substances shall be decontaminated as soon as possible by a qualified person and shall not be reused unless the non-fixed radioactive contamination is below the levels specified in Table XIX and the vehicles, equipment or part thereof have be~n de­ clared safe in respect of residual radiation levels by a quali fied person. • (4) Vehicles or compartments used for the bulk trans­ port or tank transport of low specific activity substances, or for the transport of packages of low specific activity sub­ stances carried as a full load or for the transport of low level solid radioactive substances as a full load shall not be used for other goods until decontaminated as specified. in paragraph (3) Appendix A. 7 Appendix A.8 Appendix A. 9 1. Provisions relating to danger labels t., (1) Labels Nos. 1, 3, 4.1, 4.2, 4.3, 5, 6.1, 6.lA, 7A, 7B, 7C and 8 shall be in the form of a square of 10 cm side standing on a corner. They have a black line of 5 mm in the edge and running parallel to it. Labels to be affixed to vehi 3692 3694 3695 3696 3699 3700 3799 3800 3899 3900 cles with fixed or demountable tanks shall be of not less than 30 cm side. (2) Labels Nos. 10, 11 and 12 shall be rectangular, of standard formatA5 (148X210 mm). For packages, these dimensions may be reduced to a format not less than A 7 (74xl05 mm). (3) An inscription, in figures or letters, concerning the nature of the danger may be placed on the lower part of the labels. (1) Danger labels, where they are required under the provisions of this Annex, must be stuck on packages and fixed tanks or affixed in some other suitable manner. Only where the state of the outside of a package does not permit this should labels be stuck on cards or tablets securely at­ tached to the package. On outer packagings and fixed tanks, indelible danger markings corresponding exactly to the prescribed models may be used instead of labels. (2) Where a package is required to bear two labels of the same model, the labels shall be affixed in the manner indi­ cated hereafter: (3) It is the sender's duty to affix the labels to packages, and, where appropriate, to fixed tanks and containers. (4) In addidition to the danger labels prscribed under ADR, danger labels conforming to the requirements of other modes of transport may be affixed to packages, con­ tainers, tank-containers and batteries of receptacles con­ taining dangerous goods which are transported for part of a journey by road and which must be labelled in accordance with the provisions of those requirements. 2. Explanation of symbols • 3901 The danger labels prescribed for substances and articles 3902 of Classes 1 to 8 (see annexed plate) have the following meanings: No. 1 No. 2 No. 3 No.4.1 No. 4.2 (black bomb on orange ground): prescribed in marginals 2117 (1), 2145 and 2563; liable to explosion; This number is reserved foi: possible future use of the internationally accepted gas cylinder symbol on a green background. No label embodying this symbol is at pre­ sent prescribed for class 2 substances of ADR. (black flame on danger of fire (iriflam red ground): mable liquids); prescribed in marginals 2225, 2312 (1), 2479 (2), 2612 (3) and 2812 (3) (black flame on ground of equidistant alternate red and white vertical stripes): prescribed in marginal 2414 (l); (black flame on white ground, lower triangle of label red): prescribed in marginal 2443 (l); danger of fire inflammable solids); substance liable to spontaneous ignition; cJ>EK 104 ECDHMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) 1041 No. 4.3 (black flame on blue ground): prescribed in marginal 2479 (1) No. 5 (flame over a circle, black on yellow ground): prescribed in marginals 2511 (1), 2563 (1), 2703 (Schedule 5) and 2812 (3) No. 6.1 (death's head on· cross-bones, black on white ground): prescribed in marginals 2312 (2) and 2612 (2) and 2812 (3) No. 6.lA (St. Andrew's Cross on ear of corn, black on white background): prescribed in marginals 2312 (2) and 2612 (2) danger of emission of inflammable gases on contact with water; oxidizing substance or oganic peroxide; toxic substance: to be kept apart in vehicles and at loading, unloading or transloading points from foodstuffs and other articles for consumption; harmful substances: to be kept apart from foodstuffs in vehicles arid at loading, unloading or transloading points; No. 6.2 This number is reserved for possible use of the inter­ nationally accepted symbol of three crescents superim­ posed on a circle. No label embodying this symbol is at present prescribed for class 6.2 substances of ADR. No. 7A No. 7B (stylized trefoil, inscription RADIOAC­ TIVE, a vertical stripe in the lower half, with following text: Contents .. . Activity .. . Symbol and inscriptions black on white ground, vertical stripe red): prescribed in Schedules 5 to 12 of marginal 2703 as appropriate and in marginal 3656 (1 ), (2) and (3); (like the foregoing, but with two vertical stripes in the lower half and the following text: Contents.,. Activity ... Transport index. Symbol and inscriptions black; upper half of ground yellow; lower half of ground white; vertical stripes red): radioactive substance in packages of Category I WHITE; in the event of damage to the packages, danger to health by ingestion or inhalation of, or contact with, spilled contents; radioactive substance in packages of Category 11 YELLOW; packages to be kept away from packages containing undeveloped radi­ ographic or photographic plates or films; in the event of damage to packages, • danger to health by ingestion or inhalation of, or contact with, spilled contents, and risk of external irradiation at a distance; No. 7C No. 7D No. 8 No. 9 No. 10 No. 11 No. 12 No. 13 prescribed in Schedules 5 to 12 of marginal 2703 as appropriate and in marginal 3656 (1), (2) and (3); (like the foregoing, but with three vertical stripes in the lower half): prescribed in Schedules 5 to 12 of marginal 2703 as appropriate and in marginal 3656 (1), (2) and (3); radioactive substance in packages of Category III­ YELLOW; packages to be kept away from packages containing undeveloped radiographic or photographic plates or films; in the event of damage to packages, danger to health by ingestion or inhalation of, or contact with, spilled contents, and risk of external irradiafion at a dis­ tance; This number refers to the placard prescribed in mar­ ginal 240 010 of Appendix B.4. (liquid dripping from corrosive substance;· a test-tube on to a plate and from another test tube on to a hand; black on white ground, lower triangle of label black with a white border): prescribed in marginals 2312 (2), 24 79 (2), 2511 (1), 2612 (3), 2703 (Schedule 5) and 2812 (1). This number is reserved for possible future introduc­ tion of a Class 9 in ADR. •• • • • • •• r- • •. (open black umbrella on white ground): prescribed in marginal 2479 (l); (two· black arrows on white ground): prescribed in marginals 211 7 (2), 2224 (2), 2312 (4), 2414 (2), 2443 (2) and (3), 2479 (3), 2511 (2), 2563 (2), 2612 (5), 2664 and 2812 (5) (red wineglass on white ground): prescribed in marginals 2117 (2), 2182 (2), 2224 (1) and (2), 2414 (2), 2443 (3), 2479 (3), 2511 (2), 2562 (2), 2612 (4), 2664 and 2812 (4). keep dry . this side up: label to be affixed, with arrows pointing upwards, on two opposite sides • of the package; handle, with care, or: do not drop. This number is used in the international carriage of dangerous goods by rail only. 3903 3999 1042 No. 1 / :~'. . •,, ~~ No. 4.2 No. 6.1 No. 10 ECl>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: 4EYTEPO) APPENDICE A.9 DANGER LABELS (See margmal 39021 Reproduction on reduced scale No. 3 No. 4.3 No. 6.1A No. 78 No.11 ... ' ' ' ' ' ' ' No. 4.1 ' No.5 No. 8 ' ' / V No. 12 ' ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) 1043 ECONOMIC COMMISSION FOR EUROPE INLAND TRANSPORT COMMITTEE " European Agreement concerning the international carriage of dangerous goods by road (ADR) and protocol of signature done at Geneva on 30 September 1957 VOLUME Ill (Annex 8) UNITED NATIONS New York, 1985 ANNEX B: PROVISIONS CONCERNING TRANSPORT EQUIP­ MENT AND TRANSPORT OPERATIONS CONTENTS Plan of the Annex Applicability of other regulations, national or interna­ tional Applicability of the provisions of Part I PART I. Section 1 Section 2 Section 3 GENERAL PROVISIONS APPLICA­ BLE TO THE CARRIAGE OF DAN­ GEROUS SUBSTANCES OF ALL CLASSES General Scope of this Annex (including limited quantities) Definitions Mode of carriage Method of dispatch, restrictions on forwarding Full load Carriage in bulk Carriage in containers Carriage in tanks Labelling of tank-containers and bat­ teries of receptacles Special requirements to be fulfilled by the means of transport" and its equip­ ment Types of vehicle Vehicles with fixed or demountable tanks or batteries of receptacles Fire-fighting appliances Electrical equipment Miscellaneous equipment Approval of vehicles General service requirements Vehicle crews Special training of drivers Supervision of vehicles Carriage of passengers Use of fire-fighting appliances Marginal 10000 10 001 10002 10 010 et seq. 10 010 et seq. 10 014 10 100 et seq. 10105 10108 10111 10 118 10 121 10130 10 200 et seq. 10204 10 220 10 240 10 251 10 260 10 282 and 10283 10 300 et seq. 10 311 10 315 10 321 10 325 10340 Section 4 Section 5 Section 6 PART II Classes la, lb and le Class 2 Class 3 Class 4.1 Class 4.2 Class 4.3 Class 5.1 Class 5.2 Class 6.1 Class 6.2 Class 7 Class 8 Appendix B.la Appendix B.lb Appendix B. le Portable lighting apparatus Prohibition of smoking Empty tanks • Documents to be carried on the trans­ port unit Instructions in writing Special provisions concerning loading, 10 353 10374 10 378 10 381 10 385 unloading and handling 10 400 et seq. Limitation of the quantities carried 10 401 Prohibition of mixed loading on one vehicle 10 403 Prohibition of mixed loading in one container 10 404 Prohibition of mixed loading with goods contained in a container 10 405 Cleaning before loading 10 413 Handling and stowage 10 414 Cleaning after unloading 10 415 Precautions against electrostatic charges 10 417 Loading and unloading of dangerous substances in .containers 10 419 Running the engine during loading or unloading 10 431 Special provisions concerning the op eration of vehicles • Marking and labelling of vehicles Parking in general Parking at night or in poor visibility Parking of a vehicle constituting a spe­ cial danger Other provisions Transitional provisions, derogations and provisions peculiar to certain countries Rapid procedure for authorizing dero­ gations for the purpose of trials • SPECIAL PROVISIONS APPLICA­ BLE TO THE CARRIAGE OF DAN­ GEROUS SUBSTANCES OF CLASSES 1 TO 8 Explosive substances and articles; Ar­ ticles filled with explosive substances; 10 500 et seq. 10 500 10503 10 505 10507 10599 10 600 et seq. Hi602 Igniters, fireworks and similar goods 11 00 et seq. Gases: Compressed, liquefied or dis solved under pressure 21 000 et seq. Inflammable liquids 31 000 et seq. Inflammable solids 41 Odo et seq. Substances liable to spontaneous com bustion 42 000 et seq. Substances which give off inflamma ble gases on contact with water 43 000 et seq. Oxidizing substances 51 000 et seq. Organic peroxides 52 000 et seq. Toxic substances 61 000 et seq. Repugnant substances and substances liable to cause infection 62 000 et seq. Radioactive substances 71 000 et seq. Corrosive substances 81 000 et seq. APPENDICES Marginals Provisions common to the B. l Appen dices 200000-210999 Provisions concerning fixed tanks {tank-vehicles), demountable tanks and batteries of receptacles 211 000-i211999 Provisions concerning tank-containers 212000-212999 Provisions concerning fixed tanks and demountable tanks made of reinforced plastics 213000-213999 1044 ECl>HMEPII THI KYBEPNHIECI (TEYXOI 4EYTEPO) Appendix B.ld Requirements concerning the materi­ als and construction of fixed tanks, of demountable tanks and of shells of tank-containers, intended for the car­ riage of deeply-refrigerated liquefied Appendix B.2 Appendix B.3 Appendix B.4 Appendix B.5 Appendix B.6 gases of Class 2 214000-219999 Provisions concerning electrical equipment 220000-229999 Certificate of approval for vehicles carrying certain dangerous goods 230000-239999 Tables concerning the carriage of dan gerous substances of Class 7; Label to be placed on vehicles carrying these subsiances 240000-249999 List of substances covered by mar ginal I O 500(2) 250000-259999 Certificate of driver's training in ac cordance with marginal 10 315(1) 260000-269999 ANNEX 8: PROVISIONS CONCERNING TRANSPOHT EQUIPMENT AND TRANSPORT OPERATIONS Plan of the Annex (1) This Annex comprises: JO 000 (a) General provisions applicable lo the carriagc of dan gerous substances of all Classes (Part I): (b) General provisions applicable lo the carriage of dan­ gerous substances of Classes I lo 8 (Part II): (c) Appendices as follows: Appendix B. la concerning fixed tanks (tank-vehicles). demountable tanks and batteries of receptacles: App~ndix B. lb concerning tank-containers: Appendix B.lc concerning fixed tanks and demountable tanks made of reinforced plastics;. Appendix 0 8.ld relating to requirements concerning the materials and contruction of fixed tanks. of demountable tanks, and of shells of tank-containers. intended for the carriage ofdeeply-refrigerated liquefied gases of Class 2: Appendix 8.2 .concerning electrical equipment: Appendix B:3 containing a model certificate of apprornl for vehicles;- •· Appendix 8.4 containing tables concerning the carriage of substances of Class 7 and a model label lo be affixed to vehicles carrying these substances: Appendix 8.5 containing the list of substances covered by marginal 10 500(2): Appendix 8.6 contai11ing a model driver·s training certif­ icate. (2) The general provisions of Part I and the special pro­ visions of Part II are divided into sections with the following headings: General Section 1 Section 2 Section 3 Section 4 Section 5 Section 6 This section describes the scope of this Annex and includes the provisions concern­ ing permitted exemptions anq definitions: Mode of carriage of goods (this section con­ tains the provisions concerning method of dispatch, restrictions on forwarding. full loads and the possibility of carriage of goods in bulk. in· containers or in tanks): Speciaf requirements to be fulfilled by the means of transport and its equipment: Genaral service provisions: Special provisiirns concerning loading. un­ loading and handling (this section. contains also ihe. prohibitions on mixed loading): Special provisions concerning the operation of vehicles; Transitional provisions, derogations and pro­ visions peculiar to certain countries. Applicability of other regulations. ·national or interna­ tional. (1) If the vehicle carrying out a transport operation sub- 10 001 ject to the provisions of ADR is conveyed over a se~tion of the journey otherwise than by road haulage, any nallonal or international ·regulations which govern the carriage of dan gerous goods on that section by the mode of transport used for conveying the road vehicle shall alone be applicabl~ to that section of the journey. (2) In cases where a transport operation subject to the provisions of ADR is likewise subject over the whole or a part of the road journey to the provisions of an international convention which regulates the carriage of dangerous goods by a mode of transport other than road carriage by virtue of clauses extending the applicability of that conven­ tion to certain motor-vehicle services, then the provisions of that international convention shall apply over the jour­ ney in question concurrently with those of AOR which are 1101 incompatible with them: the other clauses of AOR shall not apply over the journey in question. Applicability of the provisions of Part I of this Annex Where provisions of Part II or of the Appendices to this 10 002 Annex conflict with provisions of Part I. those pr01·isions of Part I shall not apply. Nevertheless (a) the provisions of marginal l O O 10-10 013 shall take precedence over those of Part II: (b) the provisions of marginal 10 403 shall take prece­ dence over the prohibitions on mixed loading prescribed in the sections 4 of Part II. PART I - GENERAL PROVISIONS APPLICABLE TO THE CARRIAGE OF DANGEROUS SUBSTANCES OF . ALL <..:LASSES (See, however, marginal 10 002) General Scope of this Annex 10 003 10 009 Annex A exempts, from the prol'isions of the present 10 010 Annex, carriage performed under the conditions (of pack aging, mass, etc.) laid down in marginals 2201a. 2301a. 2401a, 2431a,. 2471a. 2501a, 2601a and 2801a. Table specifying the limited quantities of dangerous sub- 10 011 stances in packages which may be carried in one transport unit without application of the provisions of this Annex re lating to: Types of vehicles (marginals XX 204 of Parts I and II and marginals 11 205 and 11 206 of Part II concerning Classes la, ] h and lr:): Vehicle crews (marginals XX 311 of Parts I and II): Supervision of vehicles (marginals XX 321 of Parts I and II); The carriage of passengers (marginal 10 325 ): Instructions in writing (marginals 10 381(1 )(b). 10 385 and 61 385): The special certificate of approval for ,ehicles (marginals 10 282 and 11 282); The special training for drivers (marginal 10 315): The special requirements to be fulfilled by the means of transport and its equipment (all sections 2 of Parts I and II), subject, however, to-compliance with the prol'isions of marginal 21 212; Places of loading and unloading (marginals 11 407. 21·407 and 61 407); and The operation of vehicles (all sections 5 of Parts I and II), subject, however, to compliance with the pro, isions of marginal 61 515. ECJ>HMEPII THI KYBEPNHIEQI (TEVXOI ~EYTEPO) 1045 SUBSTANCES Maximum total quantity per transport unit (gross mass) • ~..::,<,. ,- Multipliers for calculating total quantities. A B C D E F G , . exempted for a load which includes several substances Classes,' • e11ch of which is affected by different mass li111ils 200 50 20 10 3 2 1 Unlimited (see note ] below) .,. 5 20 50 100 333 500 1000 kg kg kg kg kg kg kg la, 2 (only the gases classified under (a) and (b)), 3, 4.1.2, 4.3, 5.1, 5.2. 6.1 and 8 1 Empty packagings (including' receptacles. excluding tanks) X 1° - 14° X lb 2° (b), 4° X Other articles X 1 ° (a) X ------- ------- ------- ------- ------- -------- .,. le 30 X Other alicles X Cyanogen chlori<le of 3 ° (cl) • X ------- 2 Phosgenc of 3 ° (al), nuorine of 1 ° (at) X l O (a) anrl (b), 2° (a) et (b) X • Other substances and empty packagings having contained a gas classified under (al), (bi), (c) or (cl) X 12°, 13° and substances of "(a)" of 11 ° and. 14° lo 26° X Substances of "(b)" of 11 ° and 14° lo 26° X ------- -------- ------- ------- ------- ------- ------- 3 1 ° (a), 2 ° (a) and (b). 3 ° (b). 4 ° (a) and (b). 5 ° (a). 6 ° (a) ,:.r::.1:. :, and (b) X ------- -------- ------- ------- ------- -------- ------- 32 ° ·(a) and 34 ° (c) X ------- -------- ------- ------- ------- ------- ------- Other substances X 9°. 10° X 4.1 2° (a), 11 ° (b) X 4.2 • 4.3 5.1 5.2 6.1 8 ------- -------- ------- ------- ------- -------- ------- Other substances 5° - 13° Calcium carbide of 2 ° (a). calcium silicide or manganese calcium silicide of 2 ° ( d) Other substances 1 °. 3 ° and 10 ° Other suhslances 45 ° (b), 46 ° (a). 4 7 ° (a) and (b) packed in accordance with marginal 2559 1 ° - 22 °, 30°. 31 ° packed in accordance with marginal 2561 1 ° - 22 °, 30 °. 31 °, 40° packed in accordance wi lh marginals 2553 lo 2556 and· 2558 . X X* X Substances classified under ( c) Substances classified under (b) • Other substances (except 1 ° and 2°) X X X X X X X X X X Sodium sulphide of 45 ° (b) X ------- ------- ------- ------- ------- ------- ------- 1 ° (a), 2° (a). 6°, 8° (b). 21 ° (a). 22° (b). 24°. 25°. 26° (a), 36° (a), 37° (a). 44° (a). 53° (b)· X ------- ------- ------- ------- ------- -------- ------- 21 ° (b), 26° (b). 33° (6), 36° (b). 37° (b). 44° (b), 52° (c), 53° (c), other substances under (a) anti (b) X Other substances 'X I • Excluding the mass of 1he refrigeraling applianf'e if all\'. 1046 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI 4EYTEPO) General Provisions Applicable lo the Carriage' of Dangerous SubslancPs of All Classes NOTE: 1. The maximum quantities shown in lhP abm·e table represent a degree of danger which lllay. fro!ll a highly simplified standpoint . be considered as equival(•nl for each of the substances listed. This danger level shall not be exceeded even where a load not affected by any prohibi­ tion on mixed loading includes more than one dangerous substance. Where the same exemption limit applies lo the sub­ stances concerned, their respective masses are added and the total must not exceed that limit. Where. however. dif Cl. Substance ;"j 20 k'"' t, k'"' t'> 2 2° (a) 3 31° 4.1 7° (a) 6.1 60 (b) 6.1 6° (c) Total of quJntities carried Multiplier factor 200 50 Product (factor x quantity) Total of products 10011 50 kg 2 3 5 20 100 100 ferenl exemption limits apply to the substances. the maxi­ mum quantities allowed for each shall be calculated as fol­ lows: (a) The total actual mass of each substance referred lo in any one column of the table shall be multiplied by the fac tor shown at the head of the column: • (b) The products so obtained are added together and their total shall 1101 exceed 1.000. Up Lo that figure, the difference divided bv the !'actor corresponding to some other substance gil·es the exelllp­ Lion limit still not taken up. Example of these calculations Maximum quantity 100 333 500 1000 kg kg kg . kg 100 50 / 25 25 50 100 10 3 2 1 250 100 100 + 250 + 100 + 100 Since the total of the products is less than 1.000. the case set out above leaves available within the exemption limit 1,000 - 550 = 450, which could be ust>d Lo make up the load with. for t>xarnple. gas cylinders of Class 2. 11 ° (a) (limit 333 kg) up to a value of 450: 3 = 150 kg. These multiplications or divisions can be nrnidf'd In using the rnass tables below. = 500 I Maximum mass of each of two different substa1wes shown in columns A lo G of the above table which may be loaded (contd) 10011 together on a transport unit without exceerling tlw exemption limits (in kg): Columns A et seq. A A A and B A anrl C A and D A and E A andF A and G 1 4 1 16 l 40 1 80 1 266 1 400 1 800 2 3 2 12 2 30 2 60 2 200 2 300 2 600 3 2 3 8 3 20 3 40 3 133 3 200 3 400 4 1 4 4 4 10 4 20 4 66 4 100 4 200 5 0 5 0 5 0 5 0 5 0 5 0 5 0 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) 1047 Columns B et seq. B B Band C 2 18 2 45 4 16 4 40 6 14 6 35 8 12 8 30 10 10 10 25 12 8 12 20 14 6 14 15 16 4 16 10 18 2 18 5 20 0 20 0 Columns C et seq. C C C and D 5 45 5 90 10 40 10 80 15 35 15 70 20 30 20 60 25 25 25 50 30 20 30 40 35 15 35 30 40 10 40 20 45 5 45 10 50 0 50 0 Columns D et seq. D D D and E 10 90 10 300 20 80 20 266 30 70 30 233 40 60 40 200 50 50 50 166 60 40 60 133 70 30 70 100 80 20 80 66 90 10 90 33 100 0 100 0 Columns E et seq. E E E and F 25 308 25 462 50 283 50 425 75 258 75 387 100 233 100 350 125 208 125 312 150 183 150 271 175 158 175 237 200 133 200 200 • 225 108 225 "162 250 83 250 125 275 58 275 . 87 300 33 300 50 325 8 325 12 333 0 333 0 Band D 2 90 4 80 6 70 8 60 10 50 12 40 14 30 16 20 18 10 20 0 C and E 5 300 10 266 15 233 20 200 25 166 30 133 35 100 40 66 45 33 50 0 D and F 10 450 20 400 30 350 40 300 50 250 60 200 70 150 80 • 100 90 50 100 0 E and G 25 925 50 850 75 775 100 700 125 ,. 625 150 550 175 475 200 400 225 325 250 250 275 175 300 100 325 25 333 0 Band E Band F Band G 2 300 2 450 2 900 4 266 4 400 4 800 6 233 6 350 6 700 8 200 8 300 8 600 10 166 10 250 10 500 12 133 12 200 12 40(1 14 100 14 150 • 14 300 16 66 16 100 16 200 18 33 18 50 18 100 20 0 20 0 20 0 C and F C and G 5 450 5 900 10 400 10 800 15 350 15 700 20 300 20 600 25 250 25 500 30 200 30 400 35 150 35 300 40 100 40 200 45 50 45 100 50 0 50 0 D and G 10 900 20 800 30 700 40 600 50 500 60 400 70 300 80 200 90 100 100 0 IL on taking into account the mass of the first substance to be loaded (as shown in one of the columns.of a quick-reference table) the maximum quantity for the sernnd substance is not reached (in the other column of the same table) the mass remaining available may be used for a third sub­ stance. To ascertain the permissible mass of that substance, teference should be made to the quick-reference table which is headed by the col­ umn leuers corresponding lo the second and third substances. if the max­ imum quantity for the third substance is not used up either, the same pro­ cedure may be followed in regard lo loading one or more other sub­ stances. In the left-hand column of each table, an intermediate higher value for a quantity actually loaded (e.g. in the Band D table, 9 between 8 and 10) may be rounded down to the lower value shown (in this case 8). In the ' right-hand column. on the other hand, an intermediate value for a quan­ tity actually loaded (e.g., in the same table, 55 instead of 60) must be ·rounded up lo the higher value shown (in this case 60). 1048 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI 4EYTEPO) Columns E et seq. F F F and G 50 450 50 900 100 400 100 800 150 350 150 700 200 300 200 600 250 250 250 500 300 200 300 400 350 150 350 300 400 100 400 200 450 50 450 100 500 0 500 0 NOTE: 2. For the purposes of this marginal and its table, the masses of liquids or gases contained in the ordi­ nary fixed tanks of means of transport for their propulsion or for operation of their specialized equipment (refrigerat­ ing appliances, for example) 'or for ensuring their safety shall not be taken into account. In the case of exemptions provided for in marginal 10011 the transport document prescribed by marginal 2002 (3) shaJI bear the following inscription after the par­ ticulars specified in chapter B of the special requireme11ls for each class of Annex A: '"load 1101 exceeding the exemption limits prescribed in marginal 10011". (l) The only provisions of this Annex applicable to the carriage of dangerous substances of Class 6.2 shall be those of Part II which relate lo this Class and those of the marginals of this Part I which are expressly made applica­ ble by those provisions of Part II. (2) Derogations from the provisions of this Annex may be made in the case of emergency transport lo save human life. Definitions (1) For the purposes of this Annex: The term "competent authority .. mea,is the authority desig11ated as su<:h in each country and in each specific case by the Government: The term "fragile package·· 1i1eans a package containing a fragile receptade (i.e. a receptacle made of glass. porce­ lain, stoneware or similar materials) which is not enclosed in a packaging with complete sides protecting it effectively against shock (see also Annex A. marginal 2001 (7)): The term "glls" means a gas or vapour: The term "dangerous substances ... when used alo11e, means the substances and articles designated as being sub­ stances and articles of ADR: The term ''RID" signifies Regulations concerning the international carriage of da11gerous goods by rail. which are Annex I of COTIF - Convention cencerning •international carriage by rail, Appendix B - Uniform rules concerning the contract for international carriage of gooJs by rail (CIM); The term "carriage in bulk .. means the carriage of a solid suhstance without packaging: The term "container" means an article of transport equipment (lift van. demouiltable lank or other similar structure): • Of a permanent character and accordingly strong enough lo he suitable for repeated use: Specially designed to facilitate the carriage of goods, by one or more means of \ransport. without breflkage of load: Fitted with devices permilli11g its ready handling, partic­ ularly when being lransloaded from one means of transport lo another: 10011 10012 10013 10014 So designed as to be easy to fill and empty, and having an internal volume of not less than lm3 • The term "container" does not cover conventional packagings, or vehicles, or lank-containers: The term "large container'' means a <:ontainer having an internal volume of more than 3 111 3 : The term "small container" means a container having an internal volume of not less than 1 m:i and not more than 3 m:1; The term "tank-container" means an article of transport equipment conforming lo the definition of the term "con­ tainer" given above and built to contain liquid, gaseous, powdery or granular substances but having a capacity of more than 0.45 m:1; The term "battery of receptacles" means an assembly comprising a number of receptacles (called "elements") whose individual or average capacity is over 150 litres and which are interconnected by a manifold and permanently mounted on a frame (for frames of gas cylinders, see A11nex A. margi11al 2212 (1) (d)); The term "demountable lank" means a tank, other than a fixed tank, a tank-container or a battery of receptacles, which has a capacity of over LOOO litres, is not designed for the carriage of goods without breakage of load, and nor­ mally can only be handled when it is empty; The term "fixed tank'' means a tank which is structurally attached to a vehicle (which then becomes a tank-vehicle) or is an integral part of the frame of such vehicle; The term "tanks'' when alone, means a lank-container or a tank of a capacity exceeding 1 m3 which may be a fixed tank, a demountable tank or a battery of receptacles. (See, however, a limitation of the meaning of the word "tank" in the provisions common to the B. l Appendices, margi11al 200 000 (2); The term "transport unit" means a motor vehicle with­ out an allached trailer, or a combination consisting of a motor vehicle and an attached trailer; The term "closed vehicle" means a vehicle having a body capable of being closed: • The term ''open vehicle" means a vehicle the platform of which has not superstructure or is merely provided with side boards and a tailboard; The· term "sheeted vehicle .. ,~eans an open vehicle pro­ vided with a sheet lo protect the load: The term "'tank-vehicle" means a vehicle built to carry liquids. gases, or powdery or granular substances and con{­ prising one or more fixed tanks: The term "batlerv,vehicle" means a lank-vehicle com­ prising a number or' fixed tanks (called "'elements") inter­ connected by a manifold. (2) For the purposes of this Annex. tanks (see definition in (1) above) are 1101 placed 011 the same footing as recepta­ cles, the term "'receptacle" being used in a restrictive sense. Provisions concerning receptacles apply to fixed tanks, balleries of receptacles, demountable tanks and ta11k-co11tainers only if this is expressly stipulated. (3) The term "full load'" means any load originating from one sender. for which the use of a vehicle or a large container is exclusively reserved and all operations for loading and unloading are carried out in conformity with the instructions of the sender or consignee (see marginal 10108). • (1) Unless expressly slated otherwise. the sign ''%" in this Annex represents: (a) In the case of mixtures of solids or of liquids, and also in the case of solutions and of solids welled by a liquid: a percentage by mass based 011 the total mass of the mixture. the solution or the wetted solid: (b) In the case of gaseous mixtures: a percentage by vol­ ume based on the total volume. of the gaseous mixture. (2) Whenever the mass of a package is mentioned in this Annex, the gross mass is mea11t unless otherwise stated. 10015 ECl>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: AEYTEPO) 1049 The mass of containers or tanks used for the carriage of goods is not included in the gross mass. (3) Pressures of all kinds relating to tanks (such.as test pressure, working pressure, safety-valve opening pressure) are always indicated in gauge pressure (pressure in excess of atmospheric pressure); however, the vapour pressure of substances is always expressed in absolute pressure. (4) Where this Annex specifies a degree of filling for. tanks, the degree of filling is always given .for a temperatur, of the substances of 15 °C unless some other temperature is indicated. Section 1: Mode of carriage of goods 10016 10099 10100 10104 Method of dispatch, restrictions on forwarding The carriage of certain dangerous goods is subject to t he 10105 mandatory uses of a particular type of transport or equip ment. These special conditions are set out in this Annex, Part II, marginals XX 105. Full load 10106 10107 Where the provisions relating 10· carriage as a "full load" 10108 are applied, the competent authorities may require the ve hicle or large container used for such carriage to be loaded at only one point and unloaded at only one point. Carriage in bulk 10109 10110 (1) Solid dangerous substances m\!y not be carried in 10111 bulk unless this mode of carriage is expressly authorized for such substances by the provisions of Part II of this Annex, and then only under the conditions stipulated by those prov1s10ns. Nevertheless, empty packagings, uncleaned, may be carried in bulk if this mode of carriage is not explicitly prohibited by the requirements of Annex A, Part II. (2) For carriage in bulk in containers, see marginal 10118 (2) and (5). Carriage in containers NOTE:The ·provisions concerning carriage in tank­ containers are set out in the marginals headed "Carriage in tanks". • 10112 10117 (1) The carriage of packages in containers is authorized. 10118 (2) Substances may not be carried in bulk in containers unless their carriage in bulk is expressly authorized (see marginal 10211 ); small containers shall be of the closed type and have cot'nplete walls. • (3) Large containers shall meet the requirements con­ cerning the body of the vehicle laid down in this Annex for the load in question; the body of the vehicle need no l then satisfy those provisions. (4) Subject to the provisions of the last phrase in (3) above, the fact that dangerous substances are contained in .one or more containers shall 1101 affect the conditions Lo be met.by the vehicle by reason of the naiure and quantities of the dangerous substances carried. (5) If the dangerous substances carried in a container are such that, under Annex A, one or more danger labels have to be affixed to the packages containing them, the same label or labels shall be affixed lo the outside of the container containing those substances in packages or in bulk. However, label No. 11 need not be affixed if the con­ tainer comprises a device or inscription clearly show.ing which way up ii should be kept. 10119 10120 ·carriage in tanks ( 1) Dangerous substances may be carried in tanks only if this mode of carriage is expressly authorized for those sub­ stances by the provisions on the use of fixed tanks, demountable tanks and batteries of receptacles set out in each section 1 of Appendix B.la, Part II, and those on the use of tank-containers set out in each section 1 of Appen­ dix B.lb, Part II. (2) Reinforced-plastics tanks may be used only if their use is expressly authorized in Appendix B. le, marginal 213010 (Use). The temperature of the substance car~ied shall not exceed 50°C at the Lime offilling. NOTE: See marginal '!0500 for the marking and label­ ling of vehicles with fixed or demountable tanks. · Labelling of Lank-containers and batteries of recepta­ cles 10121 101122 10129 (1) Tank-containers and balleries of receptacles shall 10130 bear on both sides .the labels J>rescribed in the XX 130 marginals of each Class. If these labels are not visible from outside the vehicle, the same labels shall be affixed to the. vehicle's side and rear walls. (2) The above requirements apply equally to empty tank-containers and batteries of receptacles, unclean.ed and not degassed. NOTE: See marginal 10500 for the marking of vehicles carrying tank-containers or batteries of receptacles. Section 2: Special requirements lo be fulfilled by the means of transport and its equipment • 10131 10199 .. • 10200 Types of vehicle • · -10203 (1) A transport unit loaded with da1;gerous substances 10204 may in no case include more than one trailer or semi trailcr. (2) Special provisions concerning the types.of vehicle to be used for the carriage of certain dangerous substances will, where appropriate, be found in Part IJ of this Annex (see also the marginals dealing with carriage in containers, the carriage of solid substances in bulk. carriage in tanks. and tanks). (3) Packages comprising packagings made of materials se11sitive to moisture shall be loaded on lo closed or on lo sheeted vehicles. Vehicles with fixed or demountable tanks or balleries of receptacles NOTES: (a) The p'rovisions concerning the design, inspection, filling and use of fixed tanks, demountable tanks and bat­ teries of receptacles, and various provisions concerning la11k-.vehicles and their use, will be found in Appendix B. la and, so far as the design of fixed tanks, demountable tanks and balteries of receptacles intended 'for the carriage of ,deeply refrigerated liquefied gases of Cl.ass 2 is concerned, in Appendix B. ld (for the approval of lank-vehicles. see marginal 10282). (b) The provisions concerning the construction, items of equipment, type approval. tests, marking, etc. of tank­ containers are lo be found in Appendix 8.1 band, so far as the construction of tank-containers intended for the car­ riage of deeply refrigerated liquefied gases of Class 2 is concerned, in Appendix B.ld. (c) The provisions concerning the construction of fixed tanks and demountable tanks of reinforced plastics are Lo be found in Appendix B.lc. 10205 10219 1050 ECl>HMEPII THI KYBEPNHIEQI (TEVXOI AEYTEPO) (d) The provisions common to the 8.1 Appendices are Lo be found in marginaf 200000. (e) Fur receptacles, see Annex A. (1) Rear protection of vehicles: A bumper sufficiently resistant to rear impact shall be filled over the full width of the tan(;. at the rear of the vehicle. There shall be a clear • ance of at least 100 mm between the rear wall of the tank and the rear of the bumper. this clearance being measured from the rearmost point of Lhe tank wall or from projecting fillings or accessories in contact with the substance being carried. NOTE: For the protection of tanks against damage by lateral impact or overturning. see marginal 211127 (4) and its Note. (2) Vehicles transporting liquids having a flash-point of .SS °C or below or the inflammable gases listed i11 marginal 220002 shall in addition rnmply with the following further requirements: (a) Engines and exhaust systems The engine propelling the vehicle and where applicable. the discharge pump. shall be so equippeJ and situated and the exhaust pipes so directed or protected as to avoid any danger lo the load through healing or ignition. (b) Fuel tanks The fuel tanks for supplying the engine, shall be so placed as Lo be protected so far as possible against any rol­ lisio11. and so that in the event of a11y leakage the fuel may drain directly lo the ground. Fuel tanks shall in no case be placed immediately above the exhaust pipe and tanks con­ taining petrol shall be equipped with an effective flame­ trap. filling the filler opening or with a closure with which the opening can be kepr hermetically closed. Fire-fighting appliances (1) Every transport unit carrying dangerous substances , shall be equipped with: (a) At least one portable fire extinguisher of adequate • total capaciiy, suitable for fighlinga fire in the e11gine or in any other part of the transport unit. and such that. if it is used to fight a fire in the load. ii does not aggravate the fire and. if possible. controls it: however. if the vehicle is equipped with a fixed fire extinguisher. automatic or easilv brought into action. . for fighting a fire in the engine, the portable extinguisher need not be suitable for fighting a fire in the engine; (b) In addition to the equipment prescribed under (a) above, at least one portable fire extinguisher of adequate total capacity, suitable for fighting a fire in the load, and such that, if it •is used to fight a fire in the engine or in any other part of the tranpsort unit, it does not aggravate the fire .and, if possible, controls it; (2) The extinguishing agents contained in the fire extin­ guisher with which a transport unit is equipped shall be such that they are not liable to release toxic gases into the driver's cab or under the influence of the heat of the fire. (3) Where a transport unit comprises a trailer and the laden trailer is uncoupled and left on the public highway, at a distance from the drawing vehicle, the trailer shall be equipped with at least one fire extinguisher conforming to the provisions of subparagraph (1) (b) of this-marginal. Electrical equipment The requirements concerning the electrical equipment of vehicles set out in Appendix B.2 shall apply only to the fol­ lowing vehicles: (a) Vehicles with fixed tanks, vehicles carrying demountable tanks or batteries of receptacles transporting either liquids having a flash-point of 55 °C or below, or the inflammable gases listed in marginal 220 002; 10220 10221 10239 10240 10241 10250 10251 (b) Vehicles intended for the carriage of explosives and having to comply with the requirements set out in marginal 11 205 (2) (c) for transport units of categocy B.111. Miscellaneous equipment Every transport unit carrying dangerous goods shall be equipped with: . (a) a tool kit for emergency repairs to the vehicle; (b) for each vehicle, at least one scotch of a size suited to the weight of the vehicle and to the diameter of the wheels; (c) two amber lights. These lights shall be independent of the electrical equipment of the vehicle and be so de­ signed that their use cannot cause the goods being carried • to ignite; they shall be steady or flashing. " Approval of vehicles (1) Thank-vehicles, vehicles carrying demountable tanks or batteries. of receptacles and, where so required under the provisions of Part II of this Annex, other vehicles shall be subject to technical inspection in their country of registration to make sure that they conform to the provi­ sions of this Annex, including those of its appendices, and to the general safety of registration; if these vehicles are trailers or semi-trailers coupled behind a drawing vehicle, the drawing vehicle shall be subject to technical inspection for the same purposes. (2) A certificate of approval shall be issued by the co111 petent authority of the country of registration for each yehi­ cle whose inspection yields satisfactory results. It shall be drawn up in the language or one of the languages of the country issuing it, and also, if that language is not English, French, or German, in English, French or German, unless agreements councluded between the countries concerned in the transport operation provide otherwise. It shall con­ form to the model shown in Appendix B.3 (3) A special certificate of approval issued by the compe­ tent authorities of one Contracting Party for a vehicle regis­ tered in the territory of that Contracting Party shall be ac­ cepted, so long as its validity continues, by the competent authorities of the other Contracting Parties. ( 4) The validity of a special certificate of approval shall expire not later than one year after the date of the technical inspection of the vehicle preceding the issue of the certifi­ cate. However, in the case of tanks subject to compulsory periodic inspection this provision shall not mean that tightness (leakproofness) test, hydraulic pressure tests or internal inspections of tanks have to be carried out at inter­ vals shorter than those laid down in Appendices B. la and B.lc. Transport units intended for the carriage of tank­ containers exceeding 3000 1 capacity shall be subject to an annual technical inspection in their country of registra­ tion to ensure that they conform to the general safety regu­ lations concerning brakes, lighting, etc. in force in their country. A certificate of approval shall be issued by the competent authority of the country of registration for each element of the transport unit whose inspection yields satis­ factory results. The date of the last inspection should be specified. The model shown in Appendix B.3 may be used for this certificate • -Section 3: General service provisions Vehicle crews Where the relevant provisions of Part II of this Annex require the presence in the vehicle of an assist~nt, the as­ sistant must be able to take over from the dnver. 10252 10259 10260 10261 10281 10282 10283 10284 10299 10300 10310 10311 10312 10314 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) 1051 Special ti"aining of drivers (1) Drivers of tank vehicles or transport units carrying 10315 tanks or tank containers with a total capacity of more than 3,000 1 shall hold a certificate issued by the competent au thority or by an organization recognized by that authority stating that they have successfully participated in a training course on the particular requirements that have to be met during the carriage of dangerous goods. (2) By means of appropriate endorsements on his certifi­ cate made every five years by the competent authority or by any organization recognizea by that authority, a vehicle driver must be able to show that he has successfully partici­ pated in refresher training courses. However, the compe­ tent authority or any organization recognized by that au­ thority to which an application has been made for an exten­ sion of the period of validity of the certificate may exempt the applicant from undertaking a refresher course provided that he can prove- he has continued in his occupation with­ out a break since his certificate was issued or last revalidated. (3) Training shall take place at courses approved by tbe competent authority. Its main objectives are to make driv­ ers aware of hazards arising in the carriage of dangerous goods and to give them basic information indispensable for minimizing the likelihood of an incident taking place and, if it does, to enable them to take measures which may prove necessary for their own safety and that of the environment and for limiting the effects of the incident. This training, which should include individual practical exercises where appropriate, should cover: (a) The general requirements govering the transport of dangerous goods; (b) The main types of hazard; (c) Preventive and safety measures appropriate to the various types of hazard; (d) What to do after an accident (first aid, road safety, basic knowledge about the use of protective equipment . etc.); (e) Labelling and marking to indicate danger; (f) What a vehicle driver should and should not do dur- • ing the carriage of dangerous goods; (g) The purpose and the method of operation of techni cal equipment on vehicles; • (h) The behaviour of vehicles carrying tanks or tank­ containers on the road, including movements of the load. (4) All certificates of training conforming with para­ graphs ( 1 ), (2) and (3) of this marginal and issued in accor­ dance with the model shown in Appendix B.6 by the com­ petent authorities of a Contracting Party or by any organi­ zation recognized by those authorities shall be accepted during their period of validity by the competent authorities of other Contracting Parties. Supervision of vehicles 10316 10320 Transport units carrying dangerous goods in the quanti- 10321 ties shown in the relevant marginals of Part II shall be su pervised or alternatively may be parked, unsupervised, in an isolated position in the open in a secure depot or secure factory premises. If such facilities are not available, the transport un,it, after having been properly secured, may be parked in an· isolated position meeting the requirements of paragraphs (i), (ii) or {iii) below. The parking facilities per mitted in paragraph (ii) shall be used only if those de scribed in paragraph (i) are not available, and· those de scribed in paragraph (iii) may be used only if facilities de scribed in paragraphs (i) and (ii) are not available. (i) A vehicle park supervised by an attendant who has been notified of the nature of the load and the whereabouts of the driver; (ii) A public or private vehicle park where the transport unit is not likely to suffer damage from other vehicles; or (iii) A suitable open space separated from the public highway and from dwellings, where the public does not normally pass or assemble. Carriage of passengers 10322 10324 Apart from members of the vehicle's crew, no passen- 10325 gers may be carried in transport units carrying dangerous substances. Use of fire-fighting appliances 10326 10339 The crew of the vehicle must know how to use the fire- 10340 fighting appliances. Portable lighting apparatus 10341 10352 A vehicle may not be entered by persons carrying light- 10353 ing apparatus comprising a flame. I~ addition, the lighting apparatus used shall not exhibit any metal surface liable to· produce sparks. • Prohibition of smoking 10354 10373 Smoking shall be prohibited during handling operations, 103 7 4 in the vicinity of packages awaiting handling, near station- . ary vehicles, and inside the vehicles. Empty tanks 10375 10377 (1) For fixed tanks (tank vehicles), demountable tanks 10378 and batteries of receptacles, see marginal" 211 177. (2) For tank-containers, see marginal 212 177. Documents to be carried on the transport unit 10379 10380 (1) In addition to the documents required under other 1038( regulations, the following documents shall be carried on the transport unit: (a) The transport documents prescribed in Annex A, marginal 2002(3) and (4), covering all the dangerous sub- • stances carried; and {b) The instructions prescribed in marginal 10 385, re­ lating to all the dangerous substances carried. (2) Where the provisions of this Annex require the fol­ lowing documents to be drawn up, they shall likewise be carried on the transport unit: (a) The special certificate of approval referred to in mar­ ginal 10 282 or 10 283 for each transport unit or element thereof; (b) The driver's training certificate prescribed in mar­ ginal 10 315 and reproduced in Appendix B.6; and {c) The permit authorizing the transport operation. Instructions in writing 10382 10384 (1) As a precaution against any accident or emergency 10385 that may occur or arise during carriage, the driver shall be given instructions in writing specifying concisely: • (a) The nature of the danger inherent in the dangerous substances carried, and the safety measures that need to be taken to avert it; (b) The action to be taken and treatment to be given in the event of persons coming into contact with the goods carried or with any substances which might escape 'there­ from; { c) The measures to be taken in case of fire and, in par­ ticular, the fire-fighting appliances or equipment not to be used; 1052 ECl>HMEPII THI KYBEPNHIEOI (TEYXOI 4EYTEPO) (d) The measures.to be taken in c~se of breakage or de­ terioration of packagings or of the dangerous substances carried, particularly where such dangerous substances have ·spilled over the road; (e) In the case of transport units with tanks of a capacity exceeding 3 000 1 carrying one or more of the substances referred to in Appendix B.5, the name of the substance(s), the Class, item number and letter, and the substance iden­ tification and hazard identification numbers in accordance with Appendix 8.5. (2) These instructions shall be prepared for each dan­ gerous substance or Class of dangerous substances by the manufacturer or the sender, in a language of the country of origin; where that language is not the same as those of the countries of transit or destination, the instructions shall also be drawn up in the language of those countries. A set of these instructions shall be kept in the driver's cab. (3) These instructions shall be supplied to the carrier at the latest when the iransport order is given, so as to enable him to take all necessary steps to ensure that the employees concerned are aware of these instructions and are capable of carrying them out properly. Section 4: Special provisions concerning loading, unc loading and handling Limitation of the quantities carried The fact that dangerous substances are contained in one or more containers shall not affect the weight limitations laid down by this Annex regarding carriage in a single vehi­ cle or in a single transport unit. Prohibition of mixed loading on one vehicle Unless the contrary is explicitly prescribed by the provi­ sions of the Sections 4 of Part II of this Annex, the prohibi­ tions of mixed loading on one vehicle shall not apply to con­ signments of goods packed together in the manner permit­ ted by the.provisions on mixed packing contained in Annex A. Compliance with the prohibitions on mixed loading shall be based on the danger labels of Appendix A. 9, which shali be affixed to packages in accordance with the requirements laid down for the various Classes in Annex A. NOTE: As prescribed in marginal 2002 (4), separate transport documents shall be prepared for consignments which may not be loaded together on the same vehicle. Prohibition of mixed loading in one container The prohibitions of mixed loading on one vehicle shall also be observed within each container. , Prohibition of mixed loading with goods contained in a container For the purpose of the application of the prohibitions of mixed loading on one vehicle, no account shall be taken of substances contained in closed containers with complete sides. General Provisions Applicable to the Carriage of Dangerous Substances of All Classes Cleaning before loading All the provisions in this Annex which relate to the clean­ ing of vehicles before loading shall also apply to the clean­ ing of containers. Handling and stowage 10386 10399· 10400 10401 10402 10403 10404 10405 10406 10412 10413 (1) The various components of a load comprising danger- 10414 ous substances shall be properly stowed on the vehicle and wedged by appropriate means to prevent them from being displaced in any way in relation to each other and to the walls of the vehicle. (2) If the load comprises goods of different categories the packages of dangerous substances shall be separated from the other packages. (3) All the provisions in this Annex which relate to the loading and unloading of vehicles and to the stowage and hadling of substances shall also apply lo the loading, stow­ age and unloading of containers on to and from vehicles. ( 4) Nothing whatsoever may be loaded on top of a fragile package. (5) A driver or a driver's assistant may not open a pack­ age containing dangerous substances. Cleaning after unloading (1) If, when a vehicle which has been loaded with packaged dangerous substances is unloaded, some of the contents are found to have escaped, the vehicle shall be cleaned as soon as possible and in any case before reloading. (2) Vehicles which have been loaded with dangerous substances in bulk shall be properly cleaned before reloading unless the new load consists of the same danger­ ous substance as the preceding load. (3) All the provisions of this Annex which relate to the cleaning or decontamination of vehicles shall also apply to the cleaning or decontamination of containers. Precautions against electrostatic charges In the case of substances with a flash-point of 55 ° C or below, a good electrical connection from the vehicle chas­ sis to earth shall be established before tanks are filled or emptied. In addition, the rate of filling shall be limited. Loading and unloading of dangerous substances in con­ tainers The provisions o(this Annex which relate lo the loading and unloading of vehicles and the stowage and handling of dangerous substances shall also apply to the loading and unloading of dangerous substances in containers. Running the engine during loading or unloading Except where the engine has to be used lo drive the pumps or other appliances for loading or unloading the vehicle and the laws of the country in which the vehicle is operating permit such use, the engine shall be shut off during loading and unloading op"rations. Section 5: Special provisions concerning the operation of vehicles Marking and labelling of vehicles (1) Transport units carrying dangerous substances shall display two rectangular reflectorized orange-coloured plates of 40 cm base and not less than 30 cm high, set in a vertical. plane. The plates shall have a black border not more than 15 mm wide. They shall be affixed one at the front and the other at the re~r of the transport unit, both perpendicular lo the longitudinal axis of transport unit. They shall be clearly visible. NOTE: The colour of the orange plates in conditions of normal use should have chromaticity co-ordinates lying within the area on the chromaticity diagram formed by join­ ing the following co-ordinates: Chromaticity co-ordinates of points at the corners . of the area on the chromaticity diagram X . 0.52 0.52 0.578 0.618 y 0.38 0.40 0.422 0.38 10415 10416 10417 10418 10419 10420 10430 10431 10432 10499 10500 EG>HMEPl:t: THI: KYBEPNH:t:EC:t: (TEYXO:t: AEYTEPO) 1053 Luminance factor of reflectorized colour: B~0.12. Reference centre E, standard illuminant C, normal incidence 45 °, viewed at O O • Co-efficient of reflex luminous intensity at an angle of illimination of 5 °, viewed at 0.2 °: not less than 20 can­ delas per lux per m2. (2) Transport units with tanks of a capacity greater than 3,000 1 carrying substances listed in Appendix B.5 shall, in addition, display on the sides of each tan~ or tank com­ partment, clearly visible and parallel to the longitudinal axis of the vehicle, orange-coloured plates identical with those prescribed in paragraph (1). These orange-coloured plates shall bear the identification numbers prescribed in Appendix B.5 for each of the substances carried in the tank or in a compartment of the tank. (3) Where such tanks are containers (tank-containers), the plates prescribed in paragraph (2) may be replaced by a self-adhesive sheet, by paint or by any other equivalent process, provided the material used for this purpose is weather-resistant and ensures durable marking. In this case, the provisions of the last sentence of paragraph (5), concerning resistance to fire, shall not apply. (4) For transport units with fixed or demountable tanks carrying only one of the substances listed in Appendix B.5, the orange-coloured plates prescribed in paragraph (2) shall not be necessary provided that those displayed at the front and rear in accordance with paragraph (1) bear the identification numbers prescribed in Appendix B.5. (5) The identification numbers shall consist of black dig~· its 100 mm high and of 15 mm stroke thickness. The hazard-identification number shall be inscribed in the upper part of the plate and the substance-identification number in the lower part; they shall be separated by a hori- • zontal black line, 15 mm in stroke width, extending from side to side of the plate at mid-height (see Appendix B.5). The identification numbers shall be indelible and shall re­ main legible after 15 minutes engulfment in fire. (6) Vehicles with fixed or demountable tanks shall also bear on both sides and at the rear the labels prescribed in marginals XX 500 of each class. NOTE: See marginal 10 130 for the labelling of tank­ containers and batteries of receptacles. (7) The above requirements are also applicable to empty tanks, uncleaned and not degassed. (8) After the dangerous substances have been unloaded and the tanks have been cleaned and degassed, the orange coloured plates and danger labels shall no longer be visi ~- . Parking in general 10501 10502 No transport unit carrying dangerous substances may be 10503 parked without the parking brakes being applied. Parking at night or in poor visibility ( 1) If a vehicle is parked at night or in poor visibility and its lights are not working, the amber lights referred to in mar­ ginal 10 260 (c) shall be placed on the road. One about 10 m ahead of the vehicle; and The other about 10 m to the rear of the vehicle. (2) The provisions of this marginal shall not apply in the territory of the United Kingdom. Parking of a vehicle constituting a special danger Without prejudice to the measures prescribed in mar­ ginal 10 505 above, if the nature of the dangerous sub­ stances carried in the parked vehicle constitutes a source of special danger to road-users (e.g. in the event of sub­ stances dangerous to pedestrians, animals or vehicles spill­ ing over the road) and the crew of the vehicle is unable to 10504 10505 10506 10507 eliminate the danger quickly, the driver shall alert the near­ est competent authorities, or cause them to be alerted, im­ mediately. He shall also, where necessary, take the meas­ ures prescribed in the instructions provided for in marginal 10 385. • Other provisions In so far as provisions not included in this part or in Part II of this Annex which concern the operation of vehicles carrying dangerous goods are concerned, the relevant measures adopted in this sphere by each Contracti~g Party on the basis of its domestic legislation and relating to do­ m estic carriage shall apply to international carriage using its territory. Section 6 : Transitional provisions, derogations, and pro­ visions peculiar to certain countries Rapid procedure for authorizing derogations for the pur­ pose of trials 10508 i0598 10599 10600 10601 For the purpose of carrying out the trials necessary with 10602 a view to amending the provisions of this Annex in order to adapt them to technological and industrial developments, the competent authorities of the Contracting Parties may agree directly among themselves to authorize certain trans port operations in their territories by temporary derogation from the provisions of this Annex. The authority which has taken the initiative with respect to the temporary deroga tions so granted shall notify the competent service of the United Nations Secretariat of the derogation, which service shall bring it to the attention of the Contracting Parties. 10603 10999 Part II - SPECIAL PROVISIONS APPLICABLE TO THE CARRIAGE OF DANGEROUS SUBSTANCES OF CLASSES i' TO 8 SUPPLEMENTING OR AMENDING THE REQUIREMENTS OF PART 1 Classes la· Explosive substances and art icles lb Articles filled with explosive substances le Igniters, fireworks and similar goods General (Only the general provisions of Part 1 apply) Section 1: Mode of carriage • · Method of dispatch and restrictions on forwarding 11000 11099 11100 11104 Substances of Class la, 13° and 14° (a) and (b), may 11105 be carried only as a full load. However, packages weighing not more than 10 kg and handed over for carriage iri a quantity not exceeding 100 kg may be carried otherwise than as a complete load. 11106 11117 Carriage in containers Small containers shall satisfy the requirements pre- 11118 scribed in respect of the body of the vehicle for the trans port operation concerned; it will then not be necessary for the body of the vehicle to satisfy those requirements. Section 2: Special requirements to be fulfilled by the means of transport and its equipment • 11119 11199 11200 11203 1054 E<DHMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) Types of vehicle (See also marginals 11205 and 11206) Dangerous substances or articles of Classes la, lb and 11204 le may be carried only in closed vehicles or in sheeted ve hicles fitted with side boards and a tailboard. The sheet of a sheeted vehicle must be of impermeable material not read ily inflammable. It must be tautened so as to cover the vehi cle on all sides, with an overlap of not less than 20 cm down the walls of the vehicle, and be kept in position by lockable metal bars or chains. Categories of vehicles For the purposes of this Annex, transport units author­ ized to carry dangerous substances or articles of Classes la, lb and le are classified as follows: (1) «A» transport units: Transport units whose engines use a liquid fuel with a flash-point below 55 ° C. (2) «B» transport units: Transport units whose engines use a liquid fuel with a flash-point of 55 ° C or avobe; this category B comprises the following subcategories: (a) «B.I» transport units: These have either no trailer or a trailer meeting the fol­ lowing conditions: Its coupling device is quickly detachable and is robust; and It is fitted with an effective braking device acting on all the wheels, actuated by the service-brake control of the drawing vehicle and automatically stopping the trailer in the event of breakage of the coupling. (b) «B.11» transport units: These have the following characteristics in addition to those of subcategory B.I: (i) Engine and ·exhaust system The engine and· the exhaust system are placed forward of the front wall of the body. The esxhaust-pipe outlet is di­ rected outwards from the vehicle. (ii) Fuel tank The fuel tank is placed well away from the engine, the electric wiring and the exhaust-gas piping, and in such a manner that in the event of leakage from the tank the fuel drains directly on to the ground and cannot reach the load of explosives. The fuel tank is well away from the storage battery, or is at least separated from it by a leak-proof par­ tition. It is so placed as to be so far as possible protected in a "collision. The engine is not gravity-fed. (iii) Driver,s cab No inflammable material has been used in the construc­ tion of the driver's cab, except in the seating equipment. (c) «B.III» transport units: These have all the characteristics of subcategory B.11 and, in addition, their body exhibits the following features: (i) It is closed and has a continuous surface; it is sepa­ rated from the driver's cab by a space of not less than 15 ° cm; it is robustly constructed in such a manner and of such materials that ·it adequately protects the goods carried; the materials used for the lining are incapable of producing sparks; the insulating and heat-resisting properties of the body are at all points at least equivalent to those of a parti­ tion consisting of a layer of asbestos board 5 mm thick be­ tween two metal walls or to those of a partition consisting of an outer metal wall lined with a layer of fire-proofed wood 10 mm thick. (ii) The door or doors are pr9vided with a lock and key; all joints and closures are of the overlapping type. The door or doors must be so constructed as to reduce the strength of the body as little as possible. Restrictions on the use of vehicles of certain categories (1) «A» transport units may carry only articles of Class lb, 2 ° (b), 4 ° (a), (b) and (e), and of Class le, 1 ° (a) and 30. 11205 11205 11206 No special limitation of mass is prescribed for such car­ riage. (2) «B.I» transport units may carry (a) Without special mass limitations, articles of Class lb, 2° (b) and 4°, and of Class le, 1 ° (a) and 3°; (b) Subject to the mass limitations prescribed in mar­ ginal 11401, the dangerous substances referred to in that marginal. (3) The provisions relating to restrictions, in the light of the mass and nature of the load, on the use of «B.11» and «B.III» transport units are set out in marginal 11401. Materials to be used in the construction of vehicle bodies In the construction of the body, no materials shall be used which are likely to form dangerous compounds with the explosives carried (e.g. lead in the case of the carriage of hexyl, picric acid, picrates, explosive . organic nitro­ compounds soluble in water, or explosives of an acid na­ ture (see also marginal 11?05 (2) (c). Driver's cab (See margin~! 11205 (2) (b), (iii).) Combination of drawing vehicle and trailer (See marginal 11205 (2) (a).) Engine and exhaust system (See marginal 11205 (2) (b), (i).) Fire-fighting appliances The provisions of marginal 10240 (1) (b) and (3) shall not apply to the carriage of dangerous substances of Class le, 1 ° to 3°, 5° to 20°, 24°, 25° and 27°. Electrical equipment ( 1) The rated voltage of the electric lighting system shall not exceed 24 V. (2) No circuit shall be installed inside the bodies of «B.11» and «B.111» transport units. Approval of vehicles The requirements of marginal 10282 shall be applica­ ble to «B.111» transport units. Section 3: General service provisions Vehicle crews A driver's assistant shall be carried on every transport unit. If the national regulatioris so provide, the competent auihority of a contracting country may require an approved official to be carried in the vehicle at the carrier's expense. Supervision of vehicles The provisions of marginal 10321 shall apply to the dangerous goods listed below in quantities exceeding those specified: Class la: Substances and articles of 1 ° to 14° : 5 kg; Class 1 b: Articles of 1 ° (b ), ( c) and ( cl), 5 ° to 7° and 9 ° to 11 ° Class le: Articles of 21 ° to 23 ° : 50 kg; and : 50 kg. 11207 11209 11210 11211 11215 11216 11217 11224 11225 11226 11230 11231 11232 11239 11240 11241 11250 11251 11252 11281 11282 11283 11299 11300 11310 11311 11312 11320 11321 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI 4EYTEPO) 1055 In addition, these goods shall be supervised at all times in order to prevent any malicious act and to alert the driver and the competent authorities in the event ofloss or fire. Section 4: Special provisions concerning loading, un­ loading and handling Limitation of the quantities carried The quantity of dangerous substances or articles of Classes la, lb and le which may be carried on one trans­ port unit shall be limited as follows (see also marginal 11403 as regards the prohibition of mixed loading). (1) A "B.1" transport unit may carry only (a) One of the loads authorized by marginals 11206 (1) and (2) (a); or (b) Not more than 500 kg of articles of Class le, 1 ° (b); or (c) Not more than 300 kg of substances of Class la, 12°; or (d) Not more than 100 kg of substances of Class la, 11°, 13° and 14°. (2) A "B.Il" transport unit may carry only (a) One of the loads authorized in (1) above for "B.l" transport units; or (b) Not more than 500 kg of substances of Class la, 1 ° to 10° and 12 °, as well as articles of Class lb, 1 °, 2 ° (a), ( c) and ( d), 3 ° and 6 ° to 11 °, or dangerous goods of Class le. However, substances of Class la, 3 °, 4 ° and 5 °, must be packed in accordance with the requirements for con­ signments carried otherwise than as a complete load. (3) A "B.III" transport unit may carry only (a) One of the loads authorized in (2) above for "B.II" transport units; or (b) Provided that the mass of the load of dangerous sub­ stances does not exceed 90 per cent of the mass of the load of ordinary goods declared permissible for the vehicle by the competent authority of the country of registration of the vehicle, not more than 9000 kg of the dangerous sub­ stances or articles of Classes la, lb or le per articulated vehicle or vehicle without trailer, or not more than 15000 kg of those dangerous substances per transport unit of an­ other kind. However, if the load includes one or more sub­ stances of Class 1 a, 11 °, 13 ° or 14 °, or one or more arti­ cles of Class 1 b, 5 \ 6 ° or 11 °, these limits shall be re­ duced to 6000 kg and 10000 kg respectively. • Prohibition of mixed loading on one vehicle (1) Substances and articles of Class la shall not be loaded together on one vehicle with: (a) Articles of Class lb contained in packages bearing two labels conforming to model No. l; (b) Packages bearing a label conforming to any of the models Nos. 4.3, 7 A, 7B or 7C; (c) Packages bearing a label or two labels conforming to any of the models Nos. 3, 4.1, 4.2, 5, 6.1, 6.lA, or 8. (2) Articles of Class 1 b contained in packages bearing a label conforming to model No. 1 shall not be loaded to­ gether on one vehicle with: (a) Articles-of Class lb contained in packages bearing two labels conforming to model No. l; (b) Packages bearing a label conforming to any of the models Nos. 4.3, 7 A, 7B or 7C; (c) Packages bearing a label or two labels conforming to any of the models Nos. 3, 4.1, 4.2, 5, 6.1, 6.lA or 8. (3) Articles of Class lb contained in packages bearing two labels conforming to model No. 1 shall not be loaded together on one vehicle with: • (a) Substances or articles of Classes la, lb or le con­ tained in packages bearing a label conforming to model No. l; or • 11322 11399 11400 11401 11402 11403 (b) The packages indicated under (2) (b) and (c) above. (4) Articles of Class le contained in packages bearing a label conforming to model No. 1 shall not be loaded to­ gether in one vehicle with: (a) Articles of Class lb contained in packages bearing two labels conforming to model No. l; (b) Packages bearing a label comforming to any of the models Nos. 4.3, 7 A, 7B • or 7C; (c) Packages bearing a label or two labels conforming to any of the models Nos. 3: 4.1, 4.2, 5, 6.1, 6.lA, or 8. Prohibition of mixed loading in one container , The prohibition of mixed loading of goods laid down in 11404 marginal 11403 shall apply within each container. Prohibition of mixed loading with go!)ds contained in a container The provisions of marginal 11403 shall apply as be- 11405 tween the dangerous goods contained in a container and the other dangerous goods load.ed on the same vehicle, whether or not the latter.are contained in one or more other containers. Places of ioading and unloading 11406 (1) The following operations are prohibited: 11407 (a) Loading or unloading dangerous substances or arti cles of Classes la, lb and le in a public place in a built-up area without special permission from the competent au­ thorities; (b) Loading or unloading dangerous substances or arti­ cles of these Classes in a public place elsewhere than in a built-up area without prior notice having been given to the competent authorities, unless these operations are justified for serious reasons cif safety. (2) If, for any reason, handling operations have to be carried out in a public place, then: • • • Substances and articles of different kinds shall be sepa­ rated according to the labels; and Packages fitted with means of handling shall be kept flat while being handled. Cleaning before loading 11408 11412 Before d.angerous substances or articles of Classes la, 11413 lb or le are loaded, all remnants of straw, rags, paper and similar materials, and all iron objects (nails, screws, etc.) that are not an integral part of the body of the vehicle shall be removed. • Handling and stowage (1) The use of readily inflammable materials for stowing 11414 packages in vehicles is prohibited. (2) Packages containing dangerous substances or arti­ cles of Classes la, lb and le shall be loaded in such a manner that they can be unloaded one by one al the point of destination without it being necessary to rearrange the load. (3) Packages shall be so stowed in the vehicle that they cannot be displaced therein. They shall be protected against any friction or impact. If casks are carried lying on their sides, they shall be so arranged that their' longitudinal axis lies parallel to that of the vehicle, and wooden wedges shall be applied to prevent any lateral movement. Section 5: Special provisions concerning the operation of vehicles Halts for passage through Customs 11415 11499 11500 11507 When a transport unit or convoy of vehicles carrying 11508 1056 E(J)HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) dangerous substances or articles of Classes la, lb and le is to pass a frontier Customs post, the transport unit (or convoy) shall stop at least 50 m from the Customs post. The driver's assistant shall proceed to the Customs post to inform the authorities of the arrival of the transport unit ( or convoy) carrying dangerous goods. Halts of limited duration for service requirements So far as is possible, halts for service requirements shall 11509 not be made near inhabited places or places of resort. A halt near such a place may not be prolonged except with the agreement of the competent authorities. Convoys 11510 11519 (1) When vehicles carrying dangerous substances or ar- 11520 tides.of Classes la, lb and le travel in convoy, a distance of not less than 80 m shall be maintained between each transport unit and the next. (2) If, for any reason, the convoy is obliged to stop and if, in particuiar, loading or unloading operations have to be carried out in a public place, a distance of not less than 50 m shall be maintained between the stationary vehicles. (3) The competent authorities may lay down rules for the order or composition of convoys. Section 6: Transitional provisions, derogations, and pro­ visions peculiar to certain countries Provisions peculiar to certain countries ' fhe carriage of dangerous substances or articles of Classes -1 a, 1 b and 1 c shall be subject in the territory of the United Kingdom to the regulations in force in that country at the time of carriage. Class 2: Gases: Compressed, liquefied or dissolved under pressure General (Only the genaral provisions of Part I apply) Section 1: Mode of carriage Method of dispatch and restrictions on forwarding Carbon dioxide and nitrous oxide of 7 ° (a), mixtures containing carbon dioxide and nitrous oxide of 8° (a), and the gases of 7 ° (b) and 8 ° (b) may be carried only in fixed tanks, in demountable tanks, in batteries of receptacles or in tank-containers. Carriage in containers The carriage in small containers of packages containing gases of 7 ° (a) and 8 ° (a) is prohibited. Labelling of tank-containers and batteries of recepta­ cles (1) Tank-containers and batteries of receptacles con­ taining substances of 1 ° (b ); 2 ° (b ); 3 ° (b ); chloroethane (ethyl chloride) of 3 ° (b t); substances of 3 ° (c); or sub­ stances of 4 ° (b), 4 ° (c), 5 ° (b), 6° f c), 7° (b) or 8° (b) shall bear on both sides a label conforming to model No. 3. 11521 11599 · 11600 11609 11610 11611 20999 21000 21099 21100 21104 21105 21106 21117 21118 21119 21129 21130 (2) Tank-containers and batteries of receptacles con­ taining oxygen of 1 ° (a); mixtures containing more than 20 per cent oxygen by volume, of 2 ° (a); nitrous oxide of 5 ° (a); nitrous oxide or oxygen of 7 ° (a); or liquid air or mix­ tures containing more than 20 per cent oxygen by weight, of 8 ° (a), shall bear on both sides a label conforming to· model No. 5. (3) Tank containers and batteries of receptacles contain­ ing boron trifluoride of 1 ° (at), ammonia, bromomethane, chlorine or sulphur dioxide of 3 ° (a t) shall bear on both sides a label conforming to model No. 6.1. (4) Tank-containers and batteries of receptacles con­ taining gases of 1 ° (b t) or 2 ° (b t), or dimethylamine, ethylamine, hydrogen sulphide; methylamine, methyl chlo­ ride, methyl mercaptan or trimethylamine of 3 ° (b t), vinyl bromide or methyl vinyl ether of 3 ° (c t) or substances of 4 ° ( c t), shall bear on both sides labels conforrning to mod­ els Nos. 3 and 6.1. (5) Ta11k-c·o11lai11f'rs and ballerit>s of rPCepiades <·011- :2 I I :{O taining nitrogen dioxide or phosgene of 3 ° (a t) shall bear on both sides labels conforming to models Nos. 5 and 6.1. (6) Tank-containers and batteries of receptacles con­ taining hydrogen bromide of 3 ° (a t) or hydrog~n chloride of 5 ° (a t) shall bear on both sides labels conforming to models Nos. 6.1 and 8. Section 2: Special requirements to be fulfilled by the means of transport and its equipment Ventilation If packages containing gases of 1 ° to 6 ° and 9 ° ( c) are carried in a closed vehicle, the vehicle shall be provided with adequate ventilation. Fire-fighting appliances The provisions of marginal 10240 (]) (b) and (3) shall not apply to carriage other than that of inflammable gases or articles listed in marginal 220002, or of empty packagings of 14 ° which have contained such gases. Special equipment When compressed gases or liquefied gases harmful to the respiratory organs or entailing a risk of poisoning and identified by the letter "t" in the list of substances are being carried, the crew of the vehicle shall be provided with gas masks (respirators) of a type appropriate to the gases being carried. Section 3: General service provisions Supervision of vehicles The provisions of marginal 10321 shall apply to the dangerous goods listed below in quantities exceeding those specified: Boron trifluoride and fluorine of 1 ° (at); the substances of 3 ° (at), of 3 ° (b t) other than ethyl chloride and of 3 ° (c t); hydrogen chloride of 5 ° (a t); and the deeply­ refrigerated liquefied gases of 7 ° (a) and 8 ° (a): 1000 kg; The substances of 3 ° (b); ethyl chloride of 3 ° (b t); vinyl chloride of 3 ° (c); the substances of 4 ° (b); and the deeply­ refrigerated liquefied gases of 7° (b) and 8° (b): 10000 kg. • 21131 21199 21200 21211 21212 21213 21239 21240 21241 21259 21260 21261 21299 21300 21320 21321 21322 21352 <l>EK 104 E(J)HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) 1057 Portable lighting apparatus When inflammable gases or articles listed in marginal 220 002 are being carried, a closed vehicle may not be en­ tered by persons carrying lighting apparatus other than portable lamps so designed and constructed that they can­ not ignite any gases which may have penetrated into the in­ terior of the vehicle. Empty tanks . For fixed tanks (tank-vehicles), demountable tanks, bat­ teries of receptacles and tank containers, see also Annex A, marginal.2201, 14°, Note 1. Section 4: Special provisions concerning loading, un­ loading and handling Prohibition of mixed loading on • one vehicle Articles of Class 2 enclosed in packages bearing a label conforming to model No. 3 shall not be loaded together on one vehicle with substances or articles of Classes la, lb or 1 c enclosed in packages bearing one or two labels con­ forming to model No. 1. Places of loading and unloading ( 1) The following operations !ire prohibited: (a) Loading or unloading the following substances in a public place in a built-up area without special permission from the competent authorities: hydrogen bromide, chlo­ rine, nitrogen dioxide, sulphur dioxide o r phosgene (3 ° (a t)); hydrogen sulphide (3 ° (b t)); and hydrogen chloride (5 ° (a t)); (b) Loading or unloading the substances liste~ u!1der (a) above in a public place elsewhere than in a bmlt-up area without prior notice having been given to the competent au­ thorities, unless the said operations are justified for serious reasons of safety. (2) If for any reason handling operations have to be car­ ried out in a public place, then: Substances and articles of different kinds shall be sepa­ rated according to the labels; and Packages fitted with means of handling shall be kept flat while being handled. Handling and stowage (1) Packages shall not be thrown or subjected to impact. (2) Receptacles shall be so stowed in the vehicle that they cannot overturn or fall and that the following require­ ments are met: (a) The cylinders referred to in marginal 2212 (1) (a) shall be laid parallel to or at right angles to the longitudinal axis of the· vehicle; however, those situated near the for­ ward transverse wall shall be laid at right angles to the said axis. Short cylinders of large diameter (about 30 cm and over) may be stowed longitudinally with their valve­ protecting devices directed towards the middle of the vehi-1 de. Cylinders which are sufficiently stable or are carried in suitable devices effectively preventing them from overturn­ ing may be placed upright. Cylinders which are laid flat shall be so wedged or at­ tached that they cannot shift; 21353 21354 21377 21378 21379 21399 21400 21402 21403 21404 21406 21407 21408 21413 21414 (b) Receptacles containing gases of 7 ° (a) or 8° (a) shall always be placed in the position for which they were de­ signed and be protected against any possibility of being damaged by other packages. 21415 21499 Section 5: Special provisions concerning the operation of vehicles • Marking and labelling of vehicles Vehicles with fixed or demountable tanks containing or having contained (empty tanks, uncleaned) substances listed in Appendix B.5 shall bear the following labels on 21500 both sides and at the rear: Air, liquid, deeply-refrigerated Ammonia Ammonia, dissolved in water Butadienes Butane 1-Butylene (I-Butene) cis-2-Butylene (cis-2-Butene) trans-2-Butylene (trans-2-Butene) Carbon dioxide containing ethylene oxide Clhorine l-Chloro-1, 1-difluoroethane (R 142b) Cyclopropane Dichlorodifluoromethane containing 12 per cent by mass of ethylene oxide 1,1-Difluoroethane (R 152a) 1, 1-Difluoroethylene (Vinylidene fluoride) Dimethylamine Dimethyl ether Ethane Ethane, liquid, deeply-refrigetared Ethylamine, anhydrous Ethyl chloride Ethylene Ethylene, liquid, deeply-refrigerated Ethylene oxide containing carbon dioxide Ethylene oxide with nitrogen Hexafluoropropylene (R 1216) Hydrogen, liquid, deeply-refrigerated Hydrogen bromide Hydrogen chloride Hydrogen sulphide Isobutane Isobutylene (Isobutene) Methane, liquid, deeply-refrigerated Methylamine, anhydrous Methyl bromide. Methyl chloride Methyl mercaptan Methyl vinyl ether . Mixtures of 1, 3-butadiene and hydrocarbons Mixtures of hydrocarbons (Mixtures A, AO, Al, Band C) Mixtures of methylacetylene and propadiene with hydrocarbons (Mixtures Pl and P2) Mixtures of methyl bromide and chloropicrin Mixtures· of methyl chloride and chloropicrin Mixtures of methyl chloride and methylene chloride Natural gas, liquid, deeply-refrigerated Nitrogen dioxide NOiNitrogen peroxide, Nitrogen tetroxide Nitrous oxide N 2 0 Nitrous oxide N20, liquid, deeply-refrigerates Oxygen, liquid, deeply-refrigerated Phosgene Propane Propylene Sulphur dioxide Trifluorochloroethylene (R 1113) 1, 1, 1,-Trifluoroethane 5 6.1+8 6.1+8 3 3 3 3 3 3 6.1+8 3 3 3+6.1 3 3 3+6.1 3 3 3 3+p.l 3+6.1 3 3. 3+6.1 3+6.1 6.1 3 6.1+8 6.1+8 3+6.1 3 3 3 3+6.1 6.1 3+6.1 3+6.1 3+6.1 3 3 3 6.1 3+6.1 3+6.1 3 5+6.1 5 5 5 5+6.1 3 3 6.1+8 3+6.1 3 1058 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) Trimethylamine, anhydrous Vinyl bromide Vinyl chloride 3+6.1 3+6.1 3 Vinyl fluoride Halts of limited duration for service requirements. 3 21501 21508 In the carriage of dangerous substances of Class 2 other 21509 than those of 1 °(a) ans (at), 2°(a), 7°(a), 8°(a), and 10°, halts for service requirements shall so far as possible not be made near inhabited places or places of resort. A halt near such a place may not be prolonged except with the agree ment of the competent authorities. Section 6: Transitional provisions, derogations and pro­ visions peculiar to certain countries (Only the general provisions of Part I apply) ~lass 3: Inflammable liquids General (Only the general provisions of Part I apply) Section 1: Mode of carriage Labelling of tank-containers Tank-containers containing or having contained sub­ stances of 1 ° to 6 °, 11 ° to 26 °, 31 ° or 33 ° shall bear on both sides a label conforming to model No.3. Those containing or having contained substances of 6 ° shall in addition bear labels conforming to model No. 6. lA. Those containing or having contained substances of 11 ° to 20° shall in addition bear labels conforming to model No. 6.1 Those containing or having contained substances of 21 ° to 26 ° shall in addition bear labels conforming to model No.8 .. Section 2: Special requirements to be fulfilled by the means of transport and its equipment (Only the general provisions of Part I apply). Section 3: General service provisions 21510 21599 21600 30999 31000 31099 31100 31129 31130 31131 31199 31200 31299 31300 31320 Supervision of vehicles The provisions of marginal 10321 shall apply to the 31321 dangerous goods listed below in quantities exceeding those specified: Substances of 1 ° to 5° (a) and (b), 6° (a) and (b) and 21 ° to 26°: •., 10000 kg Substances of 11 ° to 20 °: 5.000 kg 31322 31352 Portable lighting apparatus A closed vehicle may not be entered by persons carrying 31353 lighting apparatus other than portable lamps so designed and constructed that they cannot ignite any gases which may have penetrated into the interior of the vehicle. 31354 31399 Section 4: Special provisions concerning loading, unloading and handling 31400 31402 Prohibition of mixed loading on one vehicle ( 1) Substances of Class 3 contained in packages bearing 31403 one or two labels conforming to model No. 3 shall not be loaded on one vehicle together with substances or articles of Classes la, lb or le contained in packages bearing one or two labels conforming to model No. l (2) Substances of Class 3 contained in packages b~aring two labels conforming to model No. 3 shall not be loaded on one vehicle together with: (a) Substances of Class 5.1 or Class 5.2 contained in packages bearing two labels conforming to model No. 5; (b) Substances of Class 6.1 or Class 8 contained in packages bearing two labels conforming to model No. 6.1, 6.lA or 8. 31404 31409 Precautions with respect to articles of consumption (1) Packages bearing labels conforming to models No. 31410 6.1 or 6. lA shall be kept apart from foodstuffs, other arti cles of consumption and animal feeds in vehicles and at places of loading, unloading and transloading. (2) Empty receptacles, uncleaned, bearing labels con­ forming to models No. 6.1 or 6.lA shall be kept apart from foodstuffs, other articles of consumption and animal feeds in vehicles and at places· of loading, unloading and transloading. (2) Empty receptacles, uncleaned, bearing labels con­ forming to models No. 6.1 or 6. lA shall be kept apart from foodstuffs, other articles of consumption and animal feeds in vehicles and at places of loading, unloading and lransloading. Handling and stowage 31411 31413 The use of readily inflammable materials for stowing 31414 packages in vehicles is prohibited. Cleaning after unloading If any substances of 6° or 11 ° to 20° have leaked and 31415 been spilled in a vehicle, it may not be re-used until after it has been thoroughly cleaned and, if necessary, decontami nated. Any other goods and articles carried in the same ve hicle shall be examined for possible contamination. Section 5: Special provisions concerning the operation of vehicles Marking and labelling of vehicles 31416 31499 Vehicles with fixed or demountable tanks containing or ·31500 having contained substances of 1 ° to 6 °, 11 ° to 26 °, 31 ° or 33 ° shall bear on both sides and at the rear a label con forming lo model No. 3. Those containing or having contained substances of 6 ° shall in addition bear labels conforming lo model No. 6.1 A. Those containing or having contained substances of 11 ° to 20 ° shall in addition bear labels conforming to model No. 6.1 Those containing or having contained substances of 21 ° to 26 ° shall in addition bear labels conforming to model No. 8. 31501 31599 E<DHMEPlr THI: KYBEPNHIEQI: (TEYXOr aEYTEPO) 1059 Section 6: Transitional provisions, derogations, and provisions peculiar to certain countries (Only the general provisions of Part I apply) • Class 4.1: Inflammable solids General (Only the general provisions of Part I apply) Section 1: Mode of carriage Method of dispatch and restrictions on forwarding Sulphur in the melted state, 2 ° (b ), and naphthalene in the melted state, 11 ° (c), may be carried only in tank­ vehicles and tank-containers. Carriage in bulk (1) Sulphur of 2° (a) may be carried in bulk. (2) Naphthalene of 11 ° (a) and (b) may be carried in bulk; in that case it shall be carried in closed vehicles with a metal body or in sheeted vehicles with a non-inflammable sheet and either having a metal body ~r having a sheet of closely-woven material spread on the floor. For the car­ riage of naphthalene of 11 ° (a), the floors of vehicles shall be protected by an oil-proof lining. (3) Expandable polystyrenes of 12 ° may be carried in bulk in open but sheeted vehicles with adequate ventila­ tion. Car~iage in containers (1) For the carriage of naphthalene of 11 ° (a) and (b), small wooden containers shall be fitted with an oil-proof lining. (2) Expandable polystyrenes of 12 ° may also be packed without internal packaging in small containers of the closed type with complete walls. Small containers containing ex­ pandable polystyrenes shall bear the marking: "Keep away any source of ignition". This marking shall be in an official language of the country of departure, and also, if that lan­ guage is English, French or German, in English, French or German, unless any agreements concluded between the countries concerned in the transport operation provide oth­ erwise. Labelling of tank-containers 31600 40999 41000 41099 41100 41104 41105 41106 41110 41111 41112 41117 41118 41119 • -41129 Tank containers containing or having contained sulphur 41130 of2° (a) or 2 ° (b), phosphorus sesquisulphide or phospho rus pentasulphide of8°, nephthalene of 11 ° (c), shall bear on both sides a label ccnforming to model No. 4.1 Section 2: Special requirements to be fulfilled by the means of transport and its equipment 41131 41199 41200 41203 Types of vehicle Packages containing substances of 4 ° to 8 ° shall be car- 41204 ried in closed or sheeted vehicles. 41205 41299 Section 3: General service privisions Supervision of vehicles The provisions of marginal 10321 shall apply to the dangerous goods listed below in quantities exceeding those specified: Substances of 7° (a), (b) and (c): 1000 kg, Section 4: Special provisions concerning loading,· unloading and handling • Prohibition of mixed· loading on one vehicle (1) Substances of Class 4.1 contained in packages bear­ ing a label or two labels conforming to model No. 4.1 shall not be loaded iogether on one vehicle with substances or articles of Classes la, lb or le contained in packages bear­ ing one or two labels conforming to model No. 1. . (2) Substances of Class 4.1 contained in packages bear­ ing two labels conforming to model No. 4.1 shall not be loaded together on one vehicle with: (a) Substances of Classes 5.1 or 5.2 contained in pack­ ages bearing two labels conforming to model No. 5; (b) Substances of Class 6.1 contained in packages bear­ ing two labels conforming to models Nos. 6.1 or 6.lA; ( c) Substances of Class 8 contained in packages bearing two labels conforming to model No. 8. Section 5: '.::i3ecial provisions concerning the operation of vehicles Marking and labelling of vehicles .·c• :,--, (1) The provisions of margiJ!al 10500, (1), (7) a:nd-(8) shall apply only to the carriage of substances of 2 °, .4 ° to 8° and 11 ° (c). • (2) Vehicles with fixed or demountable tanks containing or having contained (empty tanks, uncleaned) substances listed in Appendix B.5 shall bear on both sides and at the rear labels conforming to model No. 4.1. Section 6: Transitional provisions, derogations, and provisions peculiar to certain countries (Only the general provisions of Part I apply) 41300 41320 41321 41322 41399 41400 41402 41403 41404 Al499 41500 41501 41599 41600 41999 Class 4.2: Substances liable to spontaneous combustion (Only the general provisions of Part I apply) Section 1: Mode of carriage Carriage in bulk 4200( 4209~ 4110( 4211( Substances of 5 °, dust from blast-furnace filters of 6 ° 4211. (a) substances of 10° may be carried in bulk. In that case, substances of 5 ° and 10 ° shall be carried in 'closed vehi cles with a metal body, and dust from blast-furnace filters in closed vehicles with a metal body or in sheeted vehicles with a metal body. 4111 4112 1060 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) Labelling of tank-containers· Tank-containers containing or having contained sub- 42130 stances of 1 ° or 3 ~ shall bear on both sides a label con forming to model No. 4.2. • Those containing or having contained substances of 3 ° shall bear in addition labels conforming to model No. 4.3. Section 2: Special requirements to be fulfilled by the means of transport and its equipment Types of vehicle 42131 42199 42200 42203 Packages containing substances of 4 ° and 10 ° shall be 42204 carried in closed or sheeted vehicles. Section 3: General service provisions Supervision of vehicles 42205 42299 42300 42320 The provisions of marginal 10321 shall apply to the 42321 dangerous goods listed below in quantities exceeding those specified: Substances of 1 ° to 3° and 6° (a): 10000 kg. 42322 42377 Empty tanks For empty tanks which have contained phosphorus ofl O 423 78 see also marginals 211474 and 212474. Section 4: Special provisions concerning loading, unloading and hadling Prohibition of mixed loading on one vehicle 42379 42399 42400 42402 (1) Substances of Class 4.2 contained in packages bear- 42403 ing a label or two labels conforming to model No. 4.2 shall not be loaded together on one vehicle with substances or articles of Classes 1 a, 1 b or 1 c contained i n packages bear ing one or two labels conforming to model No. 1. (2) Substances of 4 ° contained in packages bearing two labels conforming to model No. 4.2 shall not be loaded to­ gether on one vehicle with: (a) Substances of Classes 5.1 or 5.2 contained in pack­ ages bearing two labels conforming to model No. 5; (b) Substances of Class 6.1 contained in packages bear­ ing two labels conforming to models 6.1 or 6.lA; (c) Substances of Class 8 contained in packages bearing two labels conforming to model No. 8. Handling and stowage 42404 42413 (1) Receptacles and packages containing substances of 42414 1 ° and 3 ° shall not be subjected to impact. They shall be so placed in the vahicle that they cannot overturn or fall or be displaced in any way. • (2) The use of readily inflammable materials for stowing packages in vehicles is prohibited. 42415 42499 Section 5: Special provisions concerning the operation of vehicles Marking and labelling of vehicles (1) The provisions of marginal 10500, paragraphs (1), 42500 (7) and (8), shall apply only to the carriage of substances of 1 ° to 4 ° and 6 °. (2) Vehicles with fixed or demountable t~nks containing or having contained (empty tanks, uncleaned) substances listed in Appendix B.5 shall bear on both sides and at the rear labels conforming to model No. 4.2. Those containing or having contained substances of 3 ° shall bear, in addition, labels conforming to model No. 4.3. Section 6: Transitional provisions, derogations, and provisions peculiar to certain countries (Only the general provisions of Part I apply) Class 4.3.: 42401 42599 42600 42999 Substances which give off inflammable gases on contact with water General (Only the general provisions of Part I apply) Section 1: Mode of carriage Carriage in bulk 43000 43099 43100 43110 Magnesium granules, coated, of 1 ° ( d), calcium carbide 43111 of 2 ° (a)ond calcium silicide in lumps of2 ° (d) may be car ried in bulk in specially-equipped vehicles. The openings used for loading or unloading shall be capable of being closed hermetically .• Carriage in containers 43112 43117 Small containers used for the carriage in bulk of the sub- 43118 stances referred to in marginal 43111 shall conform to the provisions of that marginal concerning vehicles and the re ceptacles of vehicles. Labelling of tank-containers 43119 43129 Tank cont~iners containing or having contained sub- 43130 stances of this Class shall bear on both sides a label con forming to model No. 4.3. Those containing, or having contained substances of 4 ° shall in addition bear labels conforming to model Nos. 3 and 8 Section 2: Special requirements to be fulfilled by the means of transport and its equipment Types of vehicle 43131 43199 43200 43203 Dangerous substances of Class 4.3 in packages shall be 43204 carried in closed or sheeted vehicles. However, receptacles containing calcium carbide of 2 ° (a) may also be carried in open vehicles. 43205 43299 ECJ>HMEPII THI KVBEPNHIEQI (TEVXOI .dEVTEPO) Section 3: General service provisions Sypervision of vehicles 43300 43320 The provisions of marginal 10321 shall apply to the 43321 dangerous goods listed below in quantities exceeding those specified: Alkali metals and substances containing alkali metals of 1 °, alkali metal hydrides of 2 ° (b ), and substances of 4 °: 10000 kg. Section 4: Special provisioris concerning loading, unloading and handling Prohibition of mixed l9ading on one vehicle 43322 43399 43400 43402 Substances of Class 4.3 shall not be loaded together on 43403 one vehicle with substances or articles of Classes la, lb or le contained in packages bearing one or two labels con forming to model No. 1. Handling and stowage 43404 43413 Packages shall be so stowed in the vehicle that they can- 43414 not be displaced therein. They shall be protected against any friction or impact. While packages are being handled, special measures shall be taken prevent them from coming into contact with water. Section 5: Special provisions concerning the operation of vehicles Marking and labelling of vehicles 43415 43499 Vehicles with fixed or demountable tanks containing or 43500 having contained (empty tanks, uncleaned) substances of this Class listed in Appendix B.5 shall bear on both sides and at the rear a label conforming to model No. 4.3. Those containing or having contained substances of 4 ° shall in addition bear labels conforming to models Nos. 3 and 8. Section 6: Transitional provisions, derogations, and provisions pecu­ liar to certain countries (Only the general provisions of Part I apply) Class 5 .1: oxidizing substances General (Only the general provisions of Part I apply) Section 1: Mode of carriage Carriage in bulk 43501 43599 43600 50999 51000 51099 51100 <51110 (1) Substances of 4 ° to 6 ° and 7 o (a) and (b) may be 51111 carried in bulk as a full load. (2) Substances of 4 ° and 5 ° shall be carried in open • metal "vat vehicles" (vehicules cuves) covered with an im­ permeable non-inflammable sheet, or the metal containers (see marginal 51118(2)). (3} Substances of 6° and 7°(a) and (b) shall be carried in closed vehicles or in vehicles covered with an impermea­ ble non-inflammable sheet, the vehicles being so con­ structed either that the substance cannot come into contact with wood or any other combustible ~aterial .or that the en­ tire surface of the floor and walls, if combustible, has been provided with an impermeable and incombustible surfac­ ing or treated with substances rendering the wood incom­ bustible. • Carriage in containers (1) Fragile packages within the meaning of marginal 10014(1) and those containing hydrogen peroxide or solu­ tions of hydrogen peroxide of 1 ° or tetranitromethane of 2 ° may not be carried in small containers. (2) Containers intended for the carriage of substances of 4 ° and 5 ° shall be made of metal, be leak proof, be covered with a lid or an impermeable sheet resistant to combustion, and be so constructed that the substances in the containers cannot come into contact with wood or any other combusti­ ble material. (3) Containers intended for the carriage of substances of 6 °, 7 ° (a) and (b) shall be covered with a lid or an imperme­ able sheet resistant to combustion and be so constructed ei­ ther that the substance in the containers cannot come into contact with wood or any other combustible material or that the entire surface of the floor and walls, if made of wood, has been provided with an impermeable sufracing resistant to combustion or has been coated with sodium silicate or a similar substance. Labelling of tank-containers Tank-containers containing or having contained sub­ stances of this Class shall bear on both ·sides labels con­ forming to model No.5. Those containing or having con­ tained perchloric acid (in solution) of 3 ° shall, in addition, bear labels conforming to model No. 8. Section 2: Special requirements to be fulfilled by the means of trans­ port and its equipment Vehicles with fixed or demountable tanks The following provisions shall apply to the carriage of liquids of 1 °: (1) Cad (a) Unless the driver's cab is made of fireproof materi­ als, a metal shield of the same width-as the tank shall be fit­ ted at the back of the cab; (b) Any windows in the back of the driver's cab or in the metal shield shall be hermetically closed. They shall be made of fire-resistant safety glass and have fireproof frames; (c) There shall be a clear space of not less than 15 cm between the tank and the driver's cab or the shield. (2) Vehicle body No wood (unless covered with metal or a suitable syn­ thetic material) shall be used in the construction of any part of the vehicle situated to the rear of the shield prescribed in paragraph (1) above. (3) Engine The engine and (except where the vehicle is driven by a diesel engine) the fuel tank shall be placed forward of the rear wall of the driver's cab or of the shield, or if placed othewise shall be specially protected. 1061 51112 51117 51118 51119. 5l-129 51130 51131 51199 51200 51219 51220 1062 ECJ>HMEPII THI KYBEPNHIECI (TEYXOI AEYTEPO) (4) Special equipment Vehicles shall carry on board a tank having a capacity of about 30 litres of water. The water tank shall be placed as securely as possible, and there shall be admixed to the water it contains an anti-freeze preparation which does not attack the skin or the mucous membranes and does not react chemically with the load. Section 3: General service provisions Supervision of vehicles • The provisions of marginal 10321 shall apply to the dangerous goods listed below in quantities exceeding those specified: Substances of 1 ° to 3° and 9°(a): 10000 kg. Section 4: Special provisions concerning loading, unloading and han­ dling Prohibition of mixed loading on one vehicle (1) Substances of Class 5.1 contained in packages bear­ ing a label or two labels conforming to model No.5 shall not be loaded together on one vehicle with substances or arti­ cles of Classes la, 1 b or le contained in packages bearing one ·or two labels conforming to model No. l (2) Substances of Class 5.1. contained in packages bearing two labels conforming to model No.5 shall not be loaded together on one vehicle with: (a) Substances of Classes 3, 4.1 or 4.2 contained in packages bearing two labels conforming to models Nos. 3, 4.1 or 4.2; (b) Substances of Class 6.1 contained in packages bear­ ing two labels conforming to models Nos. 6.1 or 6. lA; (c) Substances of Class 8 contained in packages bearing two labels conforming to model No. 8. Precautions with respect to articles of consumption In vehicles and at places of loading, unloading or transloading, tetranitromethane of 2 °, barium chlorate of 4°(a), barium perchlorate of 4° (b), barium nitrate and lead nitrate of 7 ° ( c ), inorganic nitrites of 8 °, barium diox­ ide of 9° (b) and barium permanganate of 9° (c) shall be kept away from foodstuffs, other articles of consumption and animal feeds. Handling and stowage (1) Packages containing substances of Class 5.1 shall be placed flat on their bottoms. In addition, receptacles con­ taining liquids of Class 5.1 shal be so wedged that they can­ not overturn. (2) The use of readily inflammable materials for stowing packages in vehicles is prohibited. Cleaning after unloading After unloading, vehicles whi~h have been carrying sub­ stances of 4 ° to 6 ° and 7 ° ( a) and (b) in bulk shall be copi­ ously swilled. 51221 51299 51300 51320 51321 51322 51399 51400 51402 51403 51404 51409 51410 51411 51413 51414 51414 51415 51416 51499 Section 5: Special provisions concerning the operation of vehicles Marking and labelling of vehicles (1) The provisions of marginal 10500, paragr~phs (1), (7) and (8), shall apply only to the carriage of substances of 1 °, 2 °, 3 °, chlorates and inorganic chlorate weedkillers of 4 ° (a), barium perchlorate of 4 ° (b ), substances of 8 ° and 9° (b), and barium permanganate of 9° (c). (2) Vehicles with fixed or demountable tanks containing or having contained (empty tanks, uncleaned) substances listed in Appendix B:5 shall bear on both sides and at the rear a label conforming to model No. 5. Those containing or having contained perchloric acid (in solution) of 3 ° or ammonium nitrate (hot concentrated aqueous solutions) of 6 ° shall in addition bear labels conforming to model No. 8. Section 6: Transitional provisions, derogations, and provisions pecu­ liar to certain countries (Only the general provisions of Part 1 apply) Class 5.2: Organic peroxides General (Only the general provisions of Part I apply) Section 1: Mode of carriage Method of dispatch and restrictions of forwarding. (1) Substances of Group E shall be forwarded in such manner that the ambient temperatures indicated below are not exceeded: Substances of 45 ° • 46(a) » 46°(b) and (c) » 47°(a) » 47°(b) • 48° • 49°(a) • 49°(b) with phlegmatizer with solvent • 50° • 51 ° • 52° » 53° • 54° » 55° maximum temperature :+ 10° C :-10° C :-10° C :- 10° C :-10° C :+ 2° C :-10° C :+ 2° C 5° C : 0° C : 0° C :+ 20° C :- 10° C :+ 200 C :+ 10° C (2) Where substances of Group E are not carried in mechanically-refrigerated vehicles, the quantity of refrig­ erant in the protective packaging shall be so proportioned that the temperatures specified in paragraph (1) above are not exceeded at any time during carriage, including loading and unloading. (3) The use ofliquid air or liquid oxygen as a refrigerant is prohibited. ( 4) The temperature of refrigeration shall be so selected as to avoid any danger which might arise from the· separa­ tion of phases. Carriage in containers Fragile packages within the meaning of marginal 10014 (1) shall not be carried in small containers. 51500 51501 51599 51600 51999 52000 52099 52100 52104 52105 52106 52117 52118 52119 52129 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) Labelling of tank-containers Tank-containers containing or having contained sub­ stances of 10 °, 14 °, or 15 ° shall bear on both sides a label conforming to model No.5. Section 2: Special requirements to be fulfilled by the means of trans­ port and its equipment Types of vehicle ( 1) Substances of 1 ° to 22 °, 30 ° and 31 ° shall be car­ ried in closed or sheeted vehicles. Substances of 45 ° to 55 ° contained in protective packagings filled with a refrig­ erant shall be carried in closed or sheeted vehicles. If the vehicles used are closed they shall be adequately venti­ lated. Sheeted vehicles shall be fitted with side boards and a tail board. The sheets of these vehicles shall be of an im­ permeable material not readily inflammable. (2) Where, under the provisions of marginal 52 105, substances are required to be carried in insulated, refriger­ ated or mechanically-refrigerated vehicles, those vehicles shall satisfy the requirements of marginal 52248. Insulated, refrigerated and mechanically-refrigerated vehicles Insulated, refrigerated and mechanically-refrigerated vehicles used by reason of the requirements of marginal 52105 shall conform to the following provisions: (a) The vehicle used shall be such and be so equipped as regards its insulation and source of cold that the maximum temperature prescribed in marginal 52105 is not ex­ ceeded whatever the atmospheric conditions may be; (b) The vehicle shall be so equipped that vapours from the substances carried cannot penetrate into the cab; (c) A suitable device shall be provided enabling the tem­ perature prevailing in the loading space to be determined at any time from the driver's cab; (d) The loading space shall be provided with vents or ventilating valves if there is any risk of a dangerous excess pressure arising therein. Care shall be taken where neces­ sary to ensure that refrigeration is not impaired by the vents or ventilating valves; • (e) The refrigerant used shall not be inflammable; (f) The refrigerating appliance of a mechanically­ refrigerated vehicle shall be capable of operating inde­ pendently of the engine used to propel the vehicle. Section 3 General service provisions ~upervision of vehicles The provisions of marginal 10321 shall apply to the dangerous goods listed below in quantities exceeding those specified: Group A. Substances of 4°, 8°(a), 9°(a), 13°(a) and l 7°(a):l.OOO kg • Group C. Substances of 35 °: 1.000 kg Group E. Substances of 46 °(a), 4 7°(a) and 49°(a): 100 kg Substances of 45°, 46°(b) and (c), 47°(b), 48°, 49°(b), 50° to 55°: 2.000 kg In addition, vehicles carrying substances of 46 ° (a), 4 7 ° (a) or 49° (a) shall be subject at all times to supervision to prevent any malicious act and to alert the driver and the competent authorities in the event of loss or fire. 52130 52131 52199 52200 52203 52204 52205 52247 52248 52248 52249 52299 52300 52320 52321 52322 52399 Section 4: Special provisions concerning loading, unloading and han­ dling Limitation of the quantities carried A transport unit shall not carry more than 7 SO kg of sub­ stances of 46°(a), 47°(a) and 49°(a), not more than 5,000 kg of substances of 45 °, '46°(b) and (c), 47 °{b), 48°, 49°(b), 50° to 53 ° and 55 °, not more than 10,000 kg of substances of 54 °. • Prohibition of mixed loading on one vehicle Substances of Class 5.2 shall not be loaded together on one vehicle with: (a) Substances or articles of Classes la, lb or le con­ tained in packages bearing one or two labels conforming to model No. l; (b) Substances of Classes 3, '4.1 or 4.2 contained in packages bearing two labels conforming to models Nos. 3, 4.1 or 4.2; (c) Substances of Class 6.1 contained in packages bearing two labels conforming to models Nos. 6.1 or 6. lA; (d) Substances of Class 6.2, 9° or 10°; (e) Substances of Class 8 contained in packages bearing two labels conforming to model No.8. Cleaning before loading Vehicles- for the carriage of packages containing sub­ stances of Class 5.2 shall be carefully cleaned. Handling and stowage (1) Packages containing substances of Class 5.2 shall be • loaded in such a manner that they can be unloaded one by one at the point of destination without it being necessary to • rearrange the load. '•·'• ··' (2) Packages containing substances of Class 5 .2 shall be· kept upright and be so secured and fixed that they cannot·· overturn or fall. They shall be protected against any dam- • age which might be caused by other packages. (3) The use of readily inflammable materials for stowing packages in vehicles is prohibited. ( 4) Packages containing substances of Group E shall not be placed on top of other goods; in addition, they shall be so stowed as to be readily accessible. (5) Substances of Group E shall be loaded and unloaded without intermediate storage, and shall in the event of transloading be transferred directly from one vehicle to an­ other. The prescribed maximum temperatures shall not be exceeded during such handling (see marginal 52105(1)). Section 5: • Special provisions concerning the operation of v~hicles Marking and labelling of vehicles Vehicles with fixed or demountable tanks containing or having contained (empry tanks, uncleaned) substances listed in Appendix B.5 shall in addition bear on both sides arid at the rear labels conforming to model No.5. Halts of limited duration for service requirements During the carriage of substances of 46°(a), 47(a) and 49°(a), halts for service requirements shall so far as possi­ ble not be made near inhabited places or places of resort. A halt near such a place may not be prolonged except with the agreement of the competent authorities. The same rule shall apply where one transport unit is loaded with more than 2000 kg of substances of 45 °, 46 ° (b) and ( c ), 48 °, 49°(b) and 50° to 55°. 1063 52400 52401 52402 52403 52404 52412 52413 52414 52415 • 52499 52500 52501 52508 52509 52510 52599 1064 E<DHMEPII THI KYBEPNHIEOI (TEYXOI aEYTEPO) Section 6: Transitional provisions, derogations and provisions pecu­ . liar to certain countries. (Only the general provisions of Part I apply) Class 6.1.: Toxic substances General (Only the general provisions of Part I apply) Section 1 : Mode of carriage Carriage in bulk (1) Substances of 44°(b), 60°(c) and 63°(c) may be carried in bulk as a full load. (2)Subsrances of 44 ° (b) shall in such case be carried in closed or sheeted vehicles; those of 60°(c) or 63°(c) in sheeted, open vehicles. Labelling of tank-containers Tank-containers containing or having contained sub­ stances of 2 ° or 3 ° or substances of other items classified under (a) or (b) shall bear on both sides a label conforming to model No. 6.1. Those containing or having contained substances of any other item classified under (c) shall bear labels conforming to moded No. 6. lA. Those containing or having contained substances having a flash-point of 55 ° C or lower shall in addition bear labels conforming tq '!lode! No.3. Those containing or- having· contained chloroformates of 16 ° or 1 7 ° shall in addition bear labels conforming to model No.8. Section 2: Special requirements to be fulfilled by the means of trans­ port and its equipment Fire-fighting appliances The provisions of marginal 10240 (l)(b) and (3) shall apply only to the carriage of liquids having a flash-point of 55 ° C or below. Special equipment Whenever lead alkyls of 31 °(a) or receptacles having contained them are carried, the driver shall, when he is given the transport document, at the same time be given a , portable equipment box fitted with a handle and contain­ ing: Three copies of the written instructions specifying the action to be taken in the event of an accident or incident oc­ curring during carriage (see marginal 61385); Two pairs of gloves and two· pairs of boots made of rub­ ber or some suitable plastics material; Two respirators with an activated-charcoal cartridge of .500 cm3 capacity; • A bottle ( made of bakelite, for example) containing 2 kg for potassium permanganate and bearing the inscription "dissolve in water before use"; Six fibreboard notices bearing the inscription "DAN­ GER - volatile poison spilled. Do not approach without res­ pirator" in the language or languages of each of the coun­ tries in whose territory carriage takes place. 52600 60999 61000 61099 61100 61110 61111 61112 61129 61130 61131 .61199 61200 61239 61240 61241 61259 61260 This equipment box shall be kept in the driver's cab in a place where it can easily be found by the decontamination team . Section 3: General service provisions Action to be taken in the event of accident (See marginal 61385). Precautions with respect to articles of consumption (See marginal 61410) Supervision of vehicles The provisions of paragraph 10321 shall apply to the dangerous goods listed below in quantities exceeding those specified: Substances of 1 ° to 3 ° and substances classified under (a) of all items : 1000 kg Substances classified under (b) of all items :5000 kg. Portable lighting apparatus The provisions of marginal 10353 shall not apply. Prohibition of smoking The provisions of marginal 103 7 4 shall not apply. Instructions in writing Where lead alkyls of 31 °(a), or receptacles which have contained them, are carried, the text of the written instruc­ tions shall specify, inter alia, the following: (A) Precautions to be observed The substance being carried is highly toxic. In the event of leakage from one of the receptacles the following pre­ cautions should be taken: 1. Avoid: (a) Contact with the skin; (b) Inhalation of vapours; (c) Introduction of the liquid into the mouth. 2. When drums which are torn open or damaged or wet­ ted with liquid are being handled, the use of the following is compulsory: (a) Respirators; (b) Gloves made of rubber or some suitable plastics ma­ terial; ( c) Boots made of rubber or some suitable plastics mate­ rial. In the event of a serious accident involving obstruction of the public highway, it is essential that persons arriving to clear the site should be warned of the danger incurred. (B) Action to be taken All practicable steps, including the use of the notices re­ ferred to in marginal 61260, shall be taken to keep per­ sons at a distance of not less than 15 metres from the site of the accident; the notices contained in the equipment box shall be set up round the enclosure and onlookers shall be kept away. • The respirators, gloves and boots will enable one person to approach the load and verify its condition. Should any of the drums be torn open, the following should be done: (a) Additional respirators, gloves and boots with which to equip the workmen should be procured urgently; 61261 61299 61300 61301 61302 61303 61304 61320 61321 61322 61352 61353 61354 61373 61374 61375 613~4 61385 <l>EK 104 E<l>HMEPtr THI KYBEPNHI:EQ:t (TEYXO:t AEYTEPO) 1065 (b) Drums still intact should be set aside; (c) The liquid spilled on the vehicle or on the ground should be neutralized by copious swilling with an aqueous solution of potassium permanganate (a neutralizing agent a bottle of which is kept in the equipment box); the solution is easily prepared by stirring 0.5Kg of permanganate with 15 litres of water in a bucket; swilling should be carried out several times, because it takes 2 kg of potassium perman­ ganate to neutralize completely 1 kg of the substance being carried. Where practicable, the best way .to decontaminate the area is to pour petrol over the spilled fluid and ignite it. (C) Important notice In case of accident, one of the first steps which must be taken is to notify by telegram or telephone ... (insert here the addresses and telephone numbers of the establish­ ments to be notified in each of the countries in whose terri­ tory carriage is to take place). A vehicle which has been contaminated with the sub­ stance carried shall not be put back into service until it has been decontaminated under the supervision of a competent person. Any wooden parts of the vehicle which have been attacked by the substance carried shall be removed and burnt». • Section 4: Special provisions concerning loading, unloading and han­ dling Prohibition of mixed loading on one vehicle (1 )Substances of Class 6.1 contained in packages bear­ ing a label or two labels conforming to model No. 6.1 or 6. lA shall not be loaded together on one vehicle with sub­ stances or articles of Classes la, lb or le contained in packages bearing one or two labels conforming to model No.I. (2) Substances of Class 6.1 contained in packages bear­ ing two labels conforming to model No.6.1 or 6. lA shall not be loaded together on one vehicle with: (a) Substances of Classes 3, 4.1 or 4.2 contained in packages bearing two labels conforming to model No.3, 4.1 or 4.2; (b) Substances of Classes 5.1 or 5.2 contained in pack­ ages bearing two labels conforming to model No.5; • ( c) Substances of Class 8 contained in packages bearing two labels conforming to model No. 8. Precautions with respect to articles of consumption. Substances of Class 6.1 shall be kept apart from food­ stuffs, other articles of consumption and animal feeds in vehicles and at places of loading, unloading or transloading. Places of loading and unloading. (1) The following operations are prohibited: (a) Loading or unloading substances of 1 ° to 3 ° and any substance classified under (a) of other items in ·a public place in a built-up area without special permission from the competent authorities; • 61386 61399 61400 61402 11403 61404 61409 61410 61411 61412 (b) Loading or unloading the said substances in a public • place elsewhere than in a built-up area without prior notice having been given to the competent authorities, unless the said operatins are justified for serious reasons of safety. (2) If, for any reason, handling operations have to be carried out in a public place, then substances and articles of different kinds shall be separated according to the la­ bels. • .. 6Ml3 61414 Cleaning after unloading. (1) After unloading, vehicles and containers which have 61415 been carrying substances of 44 ° (b), 60° (c) and 63 ° (c) in bulk shall be copiously swilled. (2) A vehicle which has been contaminated with sub­ stances of 31 ° (a) or with a mixture thereof shall not be put back into service until it has been decontaminated under the supervision of a competent person. Any wooden parts of the vehicle which have been attacked by substances of 31 ° ( a) shall be removed and burnt. (3) If substances in this Class have leaked and been spilled in a vehicle, it may not be re-used until after it has been thoroughly cleaned and, if necessary, decontami­ nated. All other goods and articles carried in the same vehi­ cle shall be examined for possible contamination. Section 5: Special provisions concerning the operation of vehicles. Marking and labelling of vehicles. 61416 61499 (1) Whenever substances of 31 ° (a) are carried, the ve- 61500 hide shall display on each side a warning notir;e to the ef fect that, if any liquid escapes, the greatest caution must be exercised and that the vehicle must not be approached without respirator, gloves and boots of rubber or some suit able plastics material. (2) Vehicles with fixed or demountable tanks containing or having contained substances of 2 ° or 3 ° or substances classified under (a) or (b) of other items shall bear on both sides and at the rear labels conforming to model No.6.1. Those containing or having contained substances classi­ fied under (c) of each item shall bear labels conforming to model No. 6. lA. Those containing ~r having contained su~s.tances hin/J~g a flash point of up lo and including 55 °C shall in addition bear labels conforming to model No. 3. • Those contai~ing or having contained chloroformates ·of • 16 ° or 1 7 ° shall in addition bear labels conforming to model No. 8. Halts of limited duration for service requirements. 61501 61508 Halts for service requirements shall so far as possible 61509 not be made in residential or urban areas. A halt near such a place may not be prolonged except with the agreement of the competent authorities. 61510 61514 Protection against the action of the sun. During the period April to October inclusive, when ave- 61515 hide carrying hydrocyanic acid (1 °) is stationary the pack ages shall, if the legislation of the country in which the vehi cle is halted so requires, be effectively protected against the action of the sun, e.g. by means of sheets placed not less than 20 cm above the load. Section 6: Transitionat"provisions, derogations, and provisions pec~­ liar to certain countries. (Only the general provisions of Part I apply). Class 6.2: Repugnant substances and substances • liable to cause infection General. 61516 61599 61600 61699 62000 62009 1066 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI 4EYTEPO) Application of Part I of this Annex. The only provisions of this Annex other those of Sections 1 to 6 below which apply to the carriage of dangerous sub­ stances of Class 6.2 are those of marginals 10001, 10010 to 10014, 10111, 10118, 1038l(l)(a), 10404, 10405, 10413 to 10415 and 10419. Section 1: Mode of carriage Carriage in bulk. ( 1) Substances of 1 °, 2 °, 3 ° and 5 ° may be carried in bulk. Substances of 9 ° may not be carried otherwise than in bulk. (2) When they are in bulk (a) Substances of 1 ° (a) and (c) and 2° shall be carried in specially fitted covered vehicles equipped with ventilat­ ing installations. During the months from November to February these substances may also be carried in open ve­ hicles provided that they have been sprayed with suitable disinfectants to remove their bad odour; (b) The following shall be carried in open vehicles; Substances of 1 ° (b), after being sprayed with suitable disinfectants to remove their bad odour; Substances of 3 °; Substances of 5 °, after being sprayed with limewash so that no putrid odour is discernible; and Substances of 9 °. (3)"In addition, when they are carried in open vehicles, the follo¼'.ing shall be covered with: (a) A sheet:im.wegnated with suitable disinfectants and itself covered with.a second sheet: substances of 1 ° (a) and (c) and 2°; (b) A sheet of tarred or bituminized fibreboard .(and sprayed with suitable disinfectants): fresh horns, claws, hoofs or bones (1 °(b)); ( c )' A sheet: substances of 3 °, unless they are sprayed with suitable disinfectants to prevent any bad odour; and (d) A sheet: substances of 9° Carriage in containers The carriage of substances of 9 ° in small containers is prohibited. Section 2: Special requirements to be fulfilled by the means of trans­ port and its equipment. (No general or special requirements) Section 3: General service provisions. Precautions with respect to articles of consumption. 6201 0 62011 62099 62100 62110 62111 62112 62117 62118 62119 62199 62200 62299 62300 62302 (See marginal 62410) 62303 Section 4: Special provisions concerning loading, unloading and han­ dling. 62304 62399 62400 62402 Prohibition of mixed loading on one vehicle Substances of 9° and 10° shall not be loaded together on one vehicle with dangerous substances of Class 5.2. Precaution with respect to articles of consumption. In vehicles and at places of loading, unloading and transloading, dangerous substances of Class 6.2 other than substances of 7 ° or substances of 8 ° packed in conformity with the provisions of Annex A, marginal 2659 (2)(a) or (b), shall be kept away from foodstuffs, other articles of consumption and animal feeds. Cleaning after unloading. After unloading, vehicles which have been carrying sub­ stances of Class 6.2 in bulk shall be copiously swilled and treated with suitable disinfectants. Section 5: Special provisions concerning the operation of vehicles (No general or special provisions) Section 6: Transitional provisions, derogations and provisions pecu­ liar to certain countries. (No general or special provisions) Class 7: Radioactive substances. General Carriage For details see the relevant schedule in marginal 2703. Section 1: Mode of carriage Provisions For details see the relevant schedule in marginal 2703. Section 2: Special requirements to be fulfilled by the means of trans­ port and its equipment Provisions For details see the relevant schedule in marginal 2703 .. Section 3: General service provisions Provisions 62403 62404 62409 62410 62411 62414 62415 62416 62499 62500 62599. 62600 70999 71000 71001 71099 71100 71101 71199 71200 71201 71299 For details see the relevant schedule in marginal 2 703. 71300 See also below: 71301 71320 Supervision of vehicles The provisions of marginal 10321 shall apply to all sub- 71321 stances, in whatever quantity. However, the provisions of marginal 10321 need not be applied where: (a) The loaded compartment is locked and the packages carried are otherwise protected against any illicit unload­ ing; and (b) The dose rate does not exceed 0.5 mR/h at any ac­ cessible point on the surface of the vehicle. ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) In addition, these goods shall be subject at all times to supervision to prevenf any malicious act and to alert the driver and the competent authorities in the event of loss or fire. Prohibition of smoking The provisions of marginal 103 7 4 shall not apply. Section 4: Special provisions concerning loading, unloading and han­ dling Provisions For details see the relevant schedule in marginal 2703. Section 5: Special provisions concerning the operation of vehicles Marking and labelling of vehicles (1) Marginal 10500 shall not apply. (2) Every road vehicle carrying radioactive substances shall bear on the outside of each side wall and of the rear wall a label conforming to the model No. 7D shown in Ap­ pendix B.4, marginal 240 010. If loading is done by the sender, it shall be his duty to affix these labels to the vehi­ cles. However, this requirement shall not apply to vehicles carrying the packages referred to in marginal 2703, sched­ ules 1 to 4. Parking of a vehicle constaituting a special danger (In addition to marginal 10507, see AppendixA.6, mar­ ginal 3695). Section 6: Transitional provisions, derogations, and provisions pecu­ liar to certain countries (Only the general provisions of Part I appiy) Class 8: Corrosive substances General (Only the general provisions of Part I apply). Section l: Mode of carriage Carriage in bulk . Substances of 23 ° or lead sludge containing sulphuric acid of 1 ° (b), may be carried in bulk as a full load. The body of the vehicle shall be equipped with a suitable and sufficiently stout inner linig. If the vehicle is sheeted the sheet shall be so placed that it cannot touch the load. Carriage in containers Small containers used for the carriage of substances of • 23 ° or lead sludge containing sulphuric acid of 1 ° (b) in bulk, shall have complete walls and a suitable lining. while being handled. • 71322" 71373 71374 71375 71399 71400 71401 71499 71500 71501 71506 71507 71508 71599 71600 80999 81000 81099 8ll00 8lll0 8llll 81112 81117 81118 81119 81129 Labelling of tank-containers Tank-containers containing or having contained sub­ stances of this Class shall bear on both sides a label con­ forming to model No. 8. Those containing or having contained substances of this Class having a flashpoint of 55 ° C or lower shall in addition bear a label conforming to model No. 3. Those containing or havihg contained oleum (fuming sulphuric acid) of 1 ° (a) or substances of 6 °, 7 °, 24 °, 26 ° or 44 ° shall in addition bear labels conforming to model No. 6.1. Those containing or having contained substances of 62 ° shall in addition bear labels conforming to model No. 5. Section 2: Special requirements to be fulfilled by the means of trans­ port and its equipment Fire-fighting appliances The provisions of marginal 10240 (1) (b) and (3) shall apply only to the carriage of liquids having a flashpoint of 55°C or lower, or to substances of 2°(a) and 3°(a). Section 3: General service provisions Supervision of vehicles 'The provisions of marginal 10321 shall apply to the dangerous goods listed below in quantities exceeding those specified: Substances classified under (a) of all items: 10000 kg. Bromine of 24°: .: ·LO00'kg. Portable lighting apparatus The provisions of marginal 10353 shall not apply. Prohibition of smoking The provisions of marginal i'03 7 4 shall not apply. Section 4: • Special provisions concerning loading, unloading, and handling while being handled. Prohibition of mixed loading on one vehicle ( 1) Substances of Class 8 enclosed in packages bearing one or two labels conforming to model No. 8 shall not be loaded together on one vehicle with substances or articles of Classes 1 a, 1 b or le enclosed in packages bearing one or two labels conforming to model No. I. (2) Substances of Class 8 enclosed in packages bearing two labels conforming to model No. 8 shall not be loaded together on one vehicle with: (a) Substances of Class 3, Class 4.1 or Class 4.2 en­ closed in packages bearing two labels conforming to model No. 3, 4.1 or 4.2; (b) Substanceil of Class 5.1 or Class 5.2 enclosed in packages bearing two labels conforming to model No.5; ( c) Substances of Class 6.1 enclosed in packages bear­ ing two labels conforming to Models No. 6.1 or 6. lA. 1067 8ll30 81131 81199 81200 81239 81240 81241 81299 81300 81320 81321 81322 '-81352 81353 81354 81373 81374 81375 81399 81400 81402 81403 81404 81412 1068 EQ>t-lMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) Cleaning before loading Vehicles which are to carry packages containing sub­ stances of 2 ° (a) or 3 °(a) shall be carefully cleaned and in particular be free of all combustible waste (straw, hay, paper, etc.). Handling and stowage Packages containing substances of 2°(a), 3°(a), 61 ° or 62 ° shall rest on a stout floor and be placed with their openings at the top. The use of readily inflammable materi­ als such as straw for stowing such packages is prohibited. Section 5: Special provisions concerning the operation of vehicles Marking and labelling of vehicles • 81413 81414 81415 81499 Vehicles with fixed or demountable tanks containing or 81500 having contained substances of this Class shall bear on both sides and at the rear a label conforming to model No.8. Those containing or having contained substances of this class with a flashpoint of 55 ° C or lawer shall in addition bear labels conforming to model No. 3. Those containing or having contained oleum (fuming sulphuric acid) of 1 °(a) or substances of 6 °, 7 °, 24 °, 26 ° or 44 ° shall in addition bear iabels conforming to model No. 6.1. Those containing or having contained substances of 62 ° shall bear in addition labels conforming to model No. 5. Section 6: Transition~! provisions, derogations, and provisions pecu •• ' • t • liar to certain countries (Only tlie geri.~rai provisions of Part I apply) APPENDICES 81501 81599 81600 199999 APPENDICES B.l Provisions concerning tanks PROVISIONS COMMON TO, THE B.l APPENDICES ( 1) The scope of application of the various B. l Appendi- 200000 ces is as follows: (a) Appendix B. la applies to tanks other than tank­ containers; (b) Appendix B. lb applies to tank-containers; (c) Appendix B.lc applies to tanks, other than batteries of receptacles and tank-containers, made of reinforced plastics; (d) Appendix B.ld is concerned with the materials and construction of fixed tanks, of demountable tanks, and of shells of tank-containers, intended for the carriage of deeply-refrigerated liquefied gases of Class 2. NOTE: For receptacles, see the relevant requirements of Annex A (Packages). (2) By derogation from the definition given in marginal 10014, the term "tank" when used alone in Appendix B. la and Appendix B. le does not cover tank-containers. However, some of the requirements of Appendix B. la may be made applicable to tank-containers by the provisions of Annex B and Appendix B.lb. (3) It is recalled that marginal 10121 (1) prohibits the carriage of dangerous sustances in tanks except wh~re such carriage is expressly authorized under each Section 1 of Part II in Appendices B. la or B.lb and Section 1 of Ap­ pendix B. lc. 200001 210999 Appendix B. 1 a PROVISIONS CONCERNING FIXED TANKS (TANK-VEHICLES) DEMOUNTABLE TiNKS AND BATTERIES OF RECEPTACLES NOTE: Part I sets out the requirements applicable to fixed tanks (tank-vehides), demountable tanks and batter­ ies of receptacles intended for the carriage of substances of any Class. Part II contains special requirements supple­ menting or modifying the requirements of Part I. PART I: REQUIREMENTS APPLICABLE TO ALL CLASSES SECTION 1: General; scope (use of tanks); definitions NOTE: In accordance with the provisions of marginal 10121 (1 ), the carriage of dangerous substances in tanks (fixed or demountable tanks or batteries of receptacles) is permitted only where this mode of carriage is expressly au­ thorized for such subslu,ces in each Section 1 of Part II of this Appendix. These requirements shall apply to fixed tanks (tank­ vehicles), demountable tanks and batteries of receptacles used for the carriage of liquid, gaseous, powdery of granu­ lar substances. 200001 210999 211100 231101 (1) In addition to the vehicle proper, or the units of run- 211101 ning gear used in its stead, a tank-vehicle comprises one or more shells, their items of equipment and the fittings for~:•: taching them to the vehicle or to the running-gear units . (2) When attached to the carrier vehicle, the demountable tank or battery of receptacles shall meet the requirements pre&cfibed for tank-vehicles. In the following requirements: 211102 (1) (a) "shell" means the tank proper (including the openings and their closures); (b) "service equipment of the shell" means the filling, discharge, venting, safety, heating and heat-insulating de­ vices and the measuring instruments; (2) (a) "calculation pressure" means a notional pressure which is used to calculate the thickness of the walls of the shell. It is equal to the test pressure except in relation to certain dangerous gcods for which a special, higher calcu­ lation pressure is laid down. External or internal reinforc­ ing devices shall not be taken into account in this calcula­ tion; (b) "Maximum working pressure (gauge pressure)" means the highest of the following three pressures: (i) the highest effective pressure allowed in the shell dur­ ing filling ("rriaximum filling pressure allowed"); (ii) the highest effective pressure allowed in the shell during discharge ("maximum discharge pressure al­ lowed"); (iii) the effective gauge pressure to which the shell is subjected by its contents (including such extraneous gases as it may contain) at the maximum working tempera W~ •• Except where the special requirements for each Class provide otherwise, the numerical value of this working pressure (gauge pressure) shall not be-lower than the va­ pour pressure (absolute pressure) of the filling substance at 50°C. For shells equipped with safety valves (with or without bursting disc), the maximum working pressure (gauge pressure) shall however be equal to the prescribed opening pressure of such safety valves. • Fo'r shells equipped with venting systems and a safety device to prevent the contents spilling out if the shell over E<DHMEPII THI KYBEPNHIEQI (TEVXOI 4EYTEPO) 1069 turns, the maximum working pressure (gauge pressure) shall be equal to the static pressure of the filling sub­ stance). (c) "test pressure" means the highest effective pressure applied during the pressure test of the shell; (cl) "filling pressure" means the highest pressure actu­ ally built up in the shell when it is being filled under pres­ sure; (e) "discharge pressure" means the highest pressure ac­ tually built up in the shell when it is being discharged under pressure; (3) "Leakage test" or " leakproofness test" means the test which consists in subjecting the shell to an effective in­ ternal pressure equal to the maximum working pressure, but not less than 20 kPa (0.2 bar) (gauge pressure), by a procedure by the competent authority. Section 2: Construction 211103 211119 Shells shall be designed and constructed in accordance 211120 with the provisions of a technical code recognized by the compentent authority, but the following minimum require ments shall be met: (1) Shells shall be made of suitable metallic materials which unless other temperature ranges are prescribed in the various Classes, shall be resistant-to brittle fracture and to fissurizing corrosion under tensile stress between -20°C and +50°C. (2) For welded shells only materials of faultless weldability and whose adequate impact strengh at an ambi­ ent temperature of -20°C can be guaranteed, particularly in the welds and the zones adjacent thereto, shall be used. (3) Welds shall be skilfully made and shall afford the fullest safety. With regard to the execution and checking of weld beads, see also marginal 21112 7 (7). Shells whose minimum wall thicknesses have been de­ termined in accordance with marginal 211127 (3) to (6) shall be checked by the methods described in the definition of the weld coefficient 0.8. • ( 4) The materials of shells, or of their protective linings in contact with the contents, shall not contain substances li­ able to react dangerously with the contents, to form dan­ gerous compouds, or substantially to weaken the material. (5) The protective lining shall be so designed that its leakproofness remains unimpaired whatever the deforma­ tion liable to occur in normal carriage [211127 (l)]. (6) If contact between the substance carried and the ma­ terial used for the construction of the shell entails a pro­ gressive decrease in the thickness of the walls, this thick­ ness shall be increased at manufacture by an appropriate amount. This additional thickness to allow for corrosion shall not be taken into consideration in calculating the thickness of the shell walls. • ( 1) Shells, their attachments and their service and struc- 211121 tural equipment shall be designed to withstand without loss of contents (other than quantities of gas escaping through any degassing vents): • static and dynamic stresses in normal carriage; prescribed minimum stresses as defined in marginals 211125 and 211127. (2) In the case of vehicles in which the shell constitutes a stressed self-supporting member, the shell shall be de­ signed to withstand the stresses thus imposed in addition to stresses from other sources. The pressure on which the wall thickness of the shell is 211122 based shall not be less than the calculation pressure, but the stresses referred to in marginal 211121 shall also be taken into account. Unless specially prescribed otherwise in the various 211123 Classes, the following particulars shall be taken into ac count in the design of shells: (1) Gravity-discharge shells intended for the carriage of substances having a vapour pressure not exceeding 11 0 kPa (1. 1 bar) (absolute pressure) at 50°C shall be de­ signed for a calculation pressure .of twice the static pres­ sure of the substance to be carried but not less than twice the static pressure of water. (2) Pressure-filled or pressure-discharge shells in­ tended for the carriage of substances having a vapour pres­ sure not exceeding 110 kPa (1.1 bar) (absolute pressure) at 50 ° C shall be designed for a calculation pressure equal to 1.3 times the filling or discharge pressure. (3) Shells intended for the carriage of substances having a vapour pressure of more than 110 kPa (1.1 bar) but not more than 175 kPa (1. 75 bar) (absolute pressure) at 50°C shall, whatever their filling or discharge system, be de­ signed for a calculation pressure of not less than 0, 15 MPa (1,5 bar) gauge pressure or 1,3 times the filling or dis­ charge pressure, whichever is the higher. (4) Shells intended for the carriage of substances having a vapour pressure of more than 175 kPa (1. 75 bar) (abso­ lute pressure) at 50°C shall, whatever their filling or dis-. charge system, be designed for a calculation pressure equal to 1.3 times the filling or discharge pressure but not less than 0.4 MPa (4 bar) gauge pressure. Tanks intended to contain certain dangerous substances 211124 shall be provided with special protection which shall be de termined for the various Classes. At the test pressure, the stress o (sigma) at the most se- 211125 verely stressed point of the shell shall not exceed the material-dependent limits prescribed lmlow. Allowance shall be made for any weakening due to the welds. In addi tion, in choosing the material and determining wall thick ness, the maximum and minimum filling and working tem peratures should be taken into account. (l} For metals and alloys exhibiting a clearly-defined yield point or characterized by a guaranteed.convetional yield stress (Re) (generally 0.2 per cent of residii°'ai elonga­ tion and, in the case of austenitic steels, 1 per cent of inaxi~ mum elongation): (a) where the ratio Re/Rm is not more than 0.66: (Re = apparent yield stress, or 0.2 per cent proof stress or 1 per cent proof stress in the case of austenitic steels; Rm = guaranteed minimum tensile strength): a ~ 0.75 Re (b) where the ratio Re/Rm exceeds 0.66: a~ 0.5 Re (2) For metals and alloys exhibiting no clearly-defined apparent yield stress and characterized by a guaranteed minimum tensile strength Rm: a~ 0.43 Rm (3) For steel, the elongation at fracture shall be not less than 10000 determined tensile strength in N/mm2 but in any case it shall be not less than 16 per cent for fine-grained steels and not less than 20 per cent for other steels. For aluminium alloys the elongation at fracture shall be not less than 12 per cent. 11 Tanks intended for the carriage ofliquids having a flash- 211126 point of or below 55 ° C and for the carriage of inflammable gases shall be connected to all parts of the vehicle by e~uipotential connexion .and shall be capable of being elec tncally earthed. Any metal contact capable of causing elec­ trochemical corrosion shall be avoided. I/ In the case of sheet metal the axis of the tensile test-piece shall b~ at nght angles to the direction of rolling. The permanent e~ongallon at fract~re ~l =5~) shall be measured on a test-piece of <:1rcular cro~s-secllon m which t?e gauge length 1 is equal to five limes the diameter d; 1f test-pieces of rectangular section are use.cl, the gauge length shall be calculated by the formula 1 = 5.65 ~here F is the initial cross-sectional • area of the text-piece. 0 1070 ECDHMEPII THI KYBEPNHIEOI (TEYXOI aEYTEPO) Shells and their fastenings shall withstand the stresses specified in paragraph (1), and the wall thicknesses of shells shall be at least as determined in accordance with paragraphs (2) to (6) below. ( 1) The shells and their fastenings shall be capable of absorbing, under the maximum permissible load, the forces exerted by: in the direction of travel: twice the total mass; at right angles to the direction of travel: the total mass; vertically upwards: the total mass; vertically downwards: twice the total mass. Under the stresses defined above, the stress at the most severely stressed point of the shell and its fastenings shall • not exceed the value a defined in marginal 211125. (2) The thickness of the cylindrical wall of the shell and of the ends of cover plates shall be at least equal to that ob­ tained by the following formulae: PMPax D Pbarx D . e e = 2 x a x ).. 20 x a x ).. where ).. calculation pressure in MPa; calculation pressure in bar; internal diameter of shell in mm; permissible stress, as defined in marginal 211125 (1), (a) and (b), and (2), in N/mm2; and a coefficient, not exceeding 1, allowing for any weakening due to welds. The thickness shall in no case -be less than that defined in paragraphs (3) to (5) below. (3) The.walls, ends and cover plates of shells of circular cross-section not more than 1.80 m in diameter,21 other than those referred to in para~aph (5), shall not be less than 5 mm thick if of mild steel, I or of equivalent thickness if of another metal. If the diameter exceeds 1.80 m., 21 this thickness shall be increased to 6 mm if the shell is of mild steel, 3/ or to an equivalent thickness if the shell is of an­ other metal. "Equivalent thickness" means the thickness obtained by the following formula: e = I 21.4 X e 4/ (4) Where protection of the shell against damage through lateral impact or overturning is provided, the competent authority may allow the aforesaid minimum thicknesses to be reduced in proportion to the protection provided; however, the said thicknesses shall not be less than 3 mm in the case of mild stell31, or than an equivalent thickness in the case of other materials, for shells not more than 1.80 m in diameter.21 For shells with a diameter exceeding 1.80 m21 the aforesaid minimum thickness shall be increased to 4 mm in the case of mild steel31 an to an equivalent thickness in the case of other metal. "Equivalent thickness" means the thickness obtained by the following formula: • 21.4 X e el = -----"•-- 4/ 211127 NOTE: The following measures or equivalent measures may be adopted to protect the shell against damage: (a) The shell may be provided on both sides, at a hei~ht 211127 situated between its centreline and its lower half, with protection against lateral impact consisting of a rolled metal girder extending at least 25 mm beyond the extreme outer edge of the shell. This girder shall be of such c~os~ section that if it is of mild steel/ or a s1ro11~er matenal 11 has a section modulus of at least 5 cm31, the force being directed horizontally and at right angles to the direction of travel. If weaker materials are used, the section modulus shall be increased proportionately to the limits of elongation. Protection against overturning may take the form of strengthening rings, protective canopies, or transverse or longitudinal members so shaped that in the event of overturning no damage is caused to the fittings and accessories mounted on the upper part of the shell. (b) There is also protection: 1. Where shells are made with double walls, the space between the latter being evacuated of air. The aggregate thickness of the outer metal wall and the shell wall shall correspond to the minimum wall thickness prescribed in paragraph (3 ), and the minimum thickness of the wal of the shell itself shall not be less than the minimum thickness prescribed in paragraph (4); 2. Where the shells are made with double walls with an intermediate layer of solid materials at least 50 mm thick, the outer wall having a thickness of at least 0,5 mm if it is made of mild steel3/ and at least 2mm if it is made of a plastics materiai reinforced with glass fibre. Solid foam (with an impact-absorption capacity like that, for example, of polyurethane foam) may be used as the intermediate • layer of solid material. (c) For the rear protection of vehicles carrying fixed or demountable tanks or batteries of receptacles, see marginal 10220. (5) The thickness of tank shells designed in accordance with marginal 211123 (1) which either are of not more than 5,000 litres capacity or are divided into leak-proof compartments of not more than 5,000 litres unit capacity may be adjusted to a level which, unless prescribed otherwise in the various Classes, shall however not be less than the appropriate value shown in the following table: 2/ For shells not of circular cross-section, for example box­ shaped or elliptical shells, the indicated diameters shall correspond to those calculated on the basis of a circular cross­ section of the same area. For such shapes of cross-section the radius of convexity of the shell wall shall not exceed 2,000 mm at the sides or 3,000 mm at the top and bottom. 3/ "Mild steel" means a steel having a minimum breaking strength between 360 and 440 N/mm2• 4/ This formula is derived from the general formula e = e V I o where Rm A • R';nl Rm X A 0 0 360 27 for the mild steel of reference; minimum tensile strength of the metal chosen, in N/mm2; minimum elongation of the metal chosen on fracture undei tensile stress, in per cent. E<l>HMEPII THI KYBEPNHIEOI (TEYXOI aEYTEPO) 1071 Maximum radius Capacity of Minimum of curvature shell or shell thickness of shell (m) compartment (mm) (m) (m3) Mild steel ,;;;2 ,;;;5,0 3 2-3 ,;;;3 5 3 >3.5 but ,;;;5.0 4 Where a metal other than mild steel· is used,. the 211127 thickness shall be determined by the equivalence formula given in paragraph (3). The thickness of the partitions and surge-plates shall in no case be less than that of the shell. (6) Surge-plates and partitions shall be dished, with a depth of dish of not less than 10 cm; or shall be corrugated, profiled or otherwise reinforced to give equivalent strength. The area of the surge-plate shall be at least 70 per cent of the cross-sectional area of the tank in which the surge-plate is fitted. (7) The manufacturer's qualification for performing welding operations shall be one recognized by the competent authority. Welding shall be performed by skilled welders using . a welding process whose effectiveness (including any heat treatments required) has been demonstrated by test. Non-destructive tests shall be carried out by radiography or by ultrasound and must confirm that the quality of the welding is appropriate to the stresses. In determining the thichkness of the shell walls in accordance with paragraph (2), the following values of the coefficient lambda ()..) should be adopted for the welds: 0.8: where the weld beads are so far as possible inspected visually on both faces and are subjected to a non-destructive spot check with particular attention to connexions; 0. 9: where all longitudinal beads. throughout their length, all connexions, 25 per cent of circular beads, and welds for the assembly of large­ diameter items of equipment are subjected to non­ destructive checks. Beads shall be checked visually on both sides as far as possible; 1.0: Where all beads are subjected to non-destructive checks and are so far as possible inspected visually on both sides. kweld test-piece shall be removed. Where the competent authority has doubts regarding the quality of weld beads, it may require additional checks. (8) Measures shall be taken to protect shells against the risk of deformation as aresult of a negative internal pressure. (9) The thermal insulation shall be so designed as not to hinder access to, or the operation of, filling and discharge devices and safety valves. Stabilitv The ov~rall width of the ground-level bearing sufrace 211128 (distance between the outer points of contact with the ground of the right-hand tyre and the left-hand tyre of the same axle) shall be at least equal to 90 per cent of the height of the centre of gravity of the laden tank-vehicle. In ari articulatued vehicle the weight on the axles of the load carrying unit of the laden semi-trailer shall not exceed 60 per cent of the nominal total laden weight of the complete articulated vehicle. • Section 3: 211129 Items of equipment The items of equipment, wherever situated, shall be so 211130 arranged as to be protected against the risk of being wrenched off or damaged during carriage or handling. They shall possess a degree of safety adapted to and comparable to that of the shells themselves, and shall in particular: be compatible with the substances carried; and meet the requirements of marginal 211121. As many operating parts as possible shall be served by the smallest possible number of apertures in the shell walL The leakproofness of the items of equipment shall be ensured even in the event of overturning of the vehicle. Gaskets shall be made of a material compatible with the substance carried ans shall be replaced as soon as their effectiveness is impaired, for example as a result of ageing. Gaskets ensuring the leakproofness of operating parts needing to be manipulated during normal use of the vehicle shall be so designed and ananged that manipulation of the operating part in which they are incorporated does ~ot damage them. • • Every bottom-discharge shell, and in the case of 211131 compartmented bottom-discharge shells every compartment, shall be equipped with two mutually independent shut-off devices, the first being an internal stop-valve51 fixed directly to the tank and the second being a sluice-valve or other equivalent device, mounted in series, at each end of the discharge pipe-socket. In addition, the openings of the shells shall be capable of being closed by means of screw-threaded plugs, blank flanges or other equally effective devices. The internal stop-valve shall be operable from above or from below. if possible, the setting - open or closed - of the internal stop valve shall be capable of being verified from the ground in both cases. The controls of the internal stop-valve shall be so designed as to prevent any inadvertent opening through impact or unconsidered action. The internal shut-off device must continue to be effective in the event of damage to the . external control. The position and/or direction of closure of the sluice­ valves must be clearly apparent. In order to avoid any loss of contents in the event of damage to the external filling and discharge fittings (pipes, · lateral shut-off devices), the internal stop-valve and its seating shall be protected against the danger of being wrenched off by external stresses or shall be so designed as to withstand them. The filling and discharge devices (including flanges or threaded plugs) and protective caps (if any) shall be capable of being secured against any inadvertent opening. The shell or each of its compartments shall be provided with an opening large enough to permit inspection. Shells intended for the carriage of substances all the 21132 openings for which are above the surface level of the liquid may be equipped, in the lower part of the body, with a cleaning aperture (fist-hole). This aperture must be capable of being sealed by a flange so closed as to be leakproof and whose design must be approved by the competent authority or by a body designated by that authority. Shells intended for the carriage of liquids having a 21133 vapour pressure of n<it more than 110 kPa (1. 1 bar) (absolute) at 50°C shall have a venting system and a safety device to prevent the contents from spilling out if the shell overturns; otherwise they must conform to the requirements of marginals 211134 or 211135. Shells intended for. the carriage of liquids having a 21134 vapour pressure of not less than 110 kPa (1.1. bar) and not more than 175 kPa (1.75 bar) (absolute) at 50°C shall have a safety valve set at not less than 0.15 MPa (l.5 bar) gauge pressure and which must be fully open at a pressure not exceeding the test pressure; otherwise they must conform to the requirements of marginal 211135. 5/ Save as may be otherwise provided in the case of shells intended for the carriage of certain crystallizable or highly viscous substances, of deeply refrigerated liquiefied gases, or of powdery or granular substances. 1072 E<DHMEPII THI KYBEPNHIEOI (TEYXOI aEYTEPO) Shells intended for the carriage of liquids having a vapour pressure of not less than 175 kPa (1. 75 bar) and not more than 300 kPa (3 bar) (absolute) at 50°C shall have a safety valve set at not less than 0.3 MPa (3 bar) gauge gauge pressure and which must be fully open at a pressure not exceeding the test pressure; otherwise they must be hermetically closed6I, No movable parts such as covers, closures, etc., which are liable to come into frictional or percussive contact with aluminium shells intended for the carriage of inflammable liquids having a flash-point of or below 5~°C or for the carriage of inflammable gases may be made of unprotected corrodible steel. Section 4: Type approval The competent authority or a body designated by that authority shall issue in respect of each new type of tank a certificate attesting that the prototype tank, including the shell fastenings which it has surveyed, is suitable for the purpose for which it is intended and meets the construction requirements of Section 2, the equipment requirements of Section 3 and the conditions peculiar to the Classes of substances carried. The test results, the substances and/or the groups of substances for the carriage of which the tank is approved and its type approval number shall be entered in a test report. The substances of a group of substances shall be of similar • kind and equially compatible with the characterisi1cs of the shell. The substances or groups of substances pehnit~ed shall be specified in the test report, • ,"!'? .. -et . with their chemical names or the corresponding collective heading in the list of substances, and their Class and item number. This approval shall be valid for tank1, manufactured according to this prototype without modification. Section 5: Tests Shells and their equipment shall either together or separately undergo an initial inspction before being put into service. This inspection shall include a check of conformity to the approved prototype, a check of the design characteristics,71 an external and internal examination, a hydraulic pressure test8I at the test pressure indicated on the data plate and. a check of satisfactory operation of the equipment. The hydraulic pressure test shall be carried out before the installation of such thermal insulation as may be necessary. If the shells and their equipment are tested separately, they shall be jointly subjected to a leakproofness test after assembly. 6/ "Hermetically closed shells" means shells whose openings are hermetically closed and which are not equipped with safety valves, frangible disc or other similar safety devices. Shells having safety valves preceded by a frangible disc shall be deemed to be hermetically closed. 7 I The check of the design characteristics shall also include, for shells requiring a test pressure of 1 MPa (10 bar) or higher, a check of sample weld test-pieces and the tests prescribed in Appendix b.ld. 8/ In special cases and with the agreement of the expert approved.by the competent authority, the hydraulic pressure test may be replaced by a pressure test using another liquid or gas, where such an operation does not present any danger. 21135 211136 211137 211139 211140 211141 211149 211150 Shells and their equipment shall undergo periodic inspections at fixed intervals. The periodic inspections shall include: an external and internal examination and, as a general rule, a hydraulic pressure test8I. Sheathing for thermal or other insulation shall be removed only to the extent required for reliable appraisal of the characteristics of the shell. In the case of shells intended for the carriage of powdery or granular substances, and with the agreement of the expert approved by the competent authority, the periodic hydraulic pressure tests may be omitted and replaced by leakproofness tests in accordance with marginal 211102(3). The maximum intervals for inspections shall be six years. In addition, a leakproofness test of the shell with its equipment and a check of the satisfactory operation of all the equipment shall be carried out at least every three years. • When the safety of the shell or of its equipment may have been impaired as a result of repairs, alterations or accident, an exceptional check shall be carried out. The tests, inspections and checks in accordance with marginals 211150 to 211153 shall be carried out by the expert approved by the competent authority. Certificates shall be issued showing the results of these operations. 211151 211152 211153 211154 211155 211159 Section 6: Marking Every shell shall be fitted with a corrosion-resistant metal plate permanently attached to the shell in a place readily accessible for inspection. The following particulars at least shall be marked on the plate by stamping or by any other similar method. These particulars may be engraved directly on the walls of the shell itself, if the walls are so reinforced that the strength of the shell is not impaired: approval number; manufacturer's name or mark; manufacturer's serial number; year of manufactur~; test pressure in MPa or bar (gauge pressure); capacity in litres-in the case of multiple-element shells, the capacity of each element; design temperature (only if above +50°C or below 20°C); date (month and year) of initial test and most recent periodic test in accordance with marginals 211150 and 211151; and stamp of the expert who carried out the tests. In addition, the maximum working pressure allowed shall be inscribed on pressure-filled or pressure-discharge shells. The following particulars shall be inscribed on the tank­ vehicle itself or on a plate. These particulars shall not be required in the case of a vehicle carrying demountable tanks: name of operator; unladen weight; and permissible maximum weight. In addition, tank-vehicles shall bear the prescribed danger labels. Section 7: Operation 211160 211161 211162 211169 The thickness of the walls of the shell shall not, 211170 throughout its - use, fall below the minimum figure prescribed in marginal 21112 7 (2). <l>EK 104 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) 1073 Shells shall not be loaded with any dangerous substances other than those for whose carriage they have been approved. Foodstuffs may not be carried in these shells unless the necessary measures have been taken to prevent any danger to public health. ( 1) The following degrees of filling shall not be exceeded . in shells intended for the carriage of liquids at ambient te­ meratures: (a) for inflammable substances without additional risks (e.g. toxic or corrosive), in shells with a venting system and with or without safety valves where preceded by a bursting disc: 100 100 degree of filling = ----- or --- % of 1 + cx(50 - tF) 1 + 35a capacity; (b)for toxic or corrosive substances, whether inflammable or not, in shells with a venting system with or without safety valves even where preceded by a bursting disc: 98 98 degree of filling = ----- or --- % of 1 + cx(50 - tF) 1 + 35a capacity; • (c)for inflammable, harmful or slightly corrosive substances in hermetically closed shells61. 97 97 degree of filling = ----- or --- % of 1 + cx(50 - tF) 1 + 35a capacity; (d) for hightly toxic, toxic, highly corrosive or corrosive substances in hermetically closed shells:61 95 95 degree of filling = ------ or --- % of 1 + cx(50 - tF) 1 + 35a capacity; (2) In these formulae, a represents the mean coefficient of cubic expansion of the liquid between 15 ° and 50 ° C, . i.e. for a maximum variation in temperature of 35°C. dis- dso a is calculated by the formula: ex = 35 X d50 where d]S and diO are the relative densities of the liquid at 15 °C and 50 C reprectively and tF is the mean temperature of the liquid at the time of filling. (3) The prov1s1ons pf paragraph (1) above shall not apply to shells. whose contents are, by" means of a heating device, maintained at a temperature above 50°C during carriage. In such a case the degree of filling at the outset shall be such, and the temperature so regulated, that the shell is not full to more than 95 per cent of its capacity at any time during carriage, and that the filling temperature is not exceeded. ( 4) Where hot substances are loaded, the temperature of the outer surface of the shell or of the thermal insulation shall not exceed 70°C during carriage·. Where shells intended for the carriage of liquids91 are not divided by partitions or surge-plates into sections of not more than 7500 litres' capac-itv. thev shall be filled to not 91 Under this provision, substances whose kinematic viscosity at 20°C is below 25 cm2/s shall be deemed to be liquids. 211171 211172 211173 less than 80 per cent of their capacity unless, they are practically empty. Shells shall be closed in such a way that th~ contents cannot run out uncontrolled. The openings of bottom­ discharge shells shall be closed by means of screw­ threaded plugs, blank flanges or other equally effective devices. The leakproofness of the shell closures, particularly in . the upper part of the dip-tube, shall be verified by the sender after the shell has been filled. Where several closure systems are fitted in series, that nearest to the substance being carried shall be closed first. No dangerous residue shall adhere to the outside of shells during carriage, whether they are full or empty. To be accepted for carriage, empty shells, un~leaned, must be closed in the same manner and leakproof in the same degree as though they were full. The connecting pipes between independent but interconnected shells of a transport unit shall be empty during carriage. Flexible filling and discharge pipes which are not permanently connected to the shell shall be empty during . carriage. Section 8: Transitional measures 211174 211175 211176 211177 211178 211179 Fixed tanks (tank-vehicles), demountable tanks and 211180 batteries of receptacles built before 1 October 1978 and not conforming to the requirements of this Appendix may, if they were built in conformity with the requirements of. ADR, be used during a period of six years from 1 October 1978. Fixed tanks (tank-vehicles), demountable tanks and batteries of receptacles intended for the carriage of gas-::s of Class 2 may however be used for 12 years from the same date if the periodic-test requirement is complied with. On the expiry of this period the aforesaid units may be. 211181 kept in service if the equimpent of the shell meets the . present requirements. The thickness of the shell .~iill; except in the case of shells intended for the carriage" of gases of Class 2, 7 ° and 8 °, shall be appropriate to a calculation pressure of not less than 0.4 MPa (4· bar) (gauge pressure) in the case of mild steel and of not less than 0.2 MPa (2 bar) (gauge pressure) in the case of aluminium and aluminium alloys. For other than circular cross-sections of tanks, the diameter to be used as a basis for calculation shall be that of a circle whose area is equal to that of the real cross-section of the tank. The periodic tests for fixed tanks (tank-vehicles), 211182 demountable tanks and batteries of receptacles kept in service under these transitional provisions shall be conducted in accordance with the provisions of Section 5 and with the pertinent special provisions for the various Classes. Unless the earlier provisions prescribed a higher test pressure, a test pressure of 0.2 MPa (a bar) (gauge pressure) shall suffice for aluminium shells and aluminium-alloy shells. Fixed tanks (tank-vehicles), demountable tanks and 211183 batteries of receptacles which meet these transitional provisions may be used during a period of 15 years from 1 . October 1978 for the carriage of the dangerous goods for which they have been appproved. This transitional period shall not apply to fixed tanks (tank-vehicles), demountable tanks and batteries of receptacles intended for the carriage of substances of Class 2, or to fixed tanks (tank-vehicles), .. demountable tanks and batteries of receptacles whose wall thickness and items of equipment meet the requirements of this Appendix. Fixed tanks (tank-vehicles), demountable tanks and 211184 batteries of receptacles constructed before 1 May 1985 in accordance with the requirements of ADR in force between 1 October 1978 and 30 April 1985 but not conforming to the provisions applicable from 1 May 1985 may continue to be used after that date. 211185 211199 1074 ECl>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: AEYTEPO) PART II: SPECIAL REQUIREMENTS SUPPLEMENTING OR MODIFYING THE REQUIREMENTS OF PART I Class 2: Gases, compressed, liquefied or dissolved under pressure Section 1: General; scope (use of tanks); definitions Use Gases of Class 2 other than those listed below may be carried in fixed tanks, in demountable tanks, or in batteries of receptacles: fluorine and silicon tetrafluoride of 1 ° (at); nitric oxide of 1 ° (et); mixtures of hydrogen with not more .than 10 per cent hydrogen selenide or phosphine or silane or germane by volume or with not more than 15 per cent arsine by volume; mixtures of nitrogen or rare gases (containing not more than 10 per cent xenon by volume) with not more than 10 per cent hydrogen selenide or phosphine or silane or germane by volume or with not more than 15 per cent a·rsine by volume of 2 ° (bt); mixtures of hydrogen with not more than 10 per cent diborane by volyme; mixtures of nitrogen or rare gases (containing not more than 10 per cent xenon by volume) with not more than 10 per cent diborane by volume of 2 ° ( et), boron chloride, chlorine trifluoride, nitrosyl chloride, sulphuryl fluoride and tungsten hexafluoride of 3 ° (at); methylsilane of 3 ° (b); arsine, dichlorosilane, dimethylsifane, hydrogen selenide and trimethylsilane of 3 ° (bt); cyanogen, cyanogen chloride and ethylene oxide of 3 ° (et); mixtures of methylsilanes of 4 ° (bt); ethylene oxide containing not more than 50 per cent methyl formate by mass 4 ° (et); silane of 5 ° (b); substances of 5 ° (bt) and (et); dissolved acetylene of 9° (c); gases of 12 ° and 13 °. , Section 2: Construction Shells intended for the carriage of substances of 1 °· to 6 ° and 9 ° shall be made of steel. By derogation from marginal 211125 (3), a minimum elongation at fracture of 14 per ceni may be accepted in the case of weldless shells. The requirements of Appendix B.ld shall apply to the materials and construction of welded shells. Shells intended for the carriage of chlorine or phosgene of 3 ° (at) shall be designed for a pressure of at least 2.2 MPa (22 bar) (gauge pressure). Section 3: Items of equipment The discharge pipes of shells shall be capable of being closed not only by the devices prescribed in marginal 211131 but in addition by means of a blank flange or some. other equally reliable device. Shells .intended for the carriage of liquefied gases may be provided with, in addition to the openings prescribed in marginal 211131, openings for the fitting of gauges, including pressure gauges, and thermometers and with bleed holes, as required for their operation and safety. Safety devices shall meet the following requirements: ( 1) Filling and discharge openings of shells intended for the carriage of liquefied inflammable and/or toxic gases shall be equipped with an instant-closing internal safety device which closes automatically in the event of an inadvertent movement of the tank. It must also be possible to close the device by remote control. (2) All openings, other than those accommodating safety valves and than closed bleed holes, of shells intended for the carriage of liquified inflammable and/or toxic gases shall, if their nominal diameter is more than 1.5 mm, be equipped with an internal shut-off device. (3) By derogation from the provisions of paragraphs (1) and (2), shells intended for the carriage of deeply 211200 211209 2ll210 211211 211219 211220 211221 211222 211229 211230 211231 211232 refrigerated inflammable and/or toxic liquefied g~es may be equipred with external devices in place of mternal devices i the external devices afford protection at least equivalent to that afforded by the wall of the shell. ( 4) If the shells are equipped with gauges, the latter shall not be made of a transparent material in direct contact with the substance carried. If there are thermometers, they shall not project directly into the gas or liquid through the shell wall. (5) Shells intended for the carriage of chlorine or sulphur dioxide of 3 ° (at) or methyl mercaptan or hvdrogen sulphide of 3 ° (bt) shall not have any opening below the surface level of the liquid. In addition, cleaning apertures (first-holes) as referred to in marginal 211132 shall not be permitted. (6) Filling and discharge ~penings situated ii:' the upp~r part of shells shall be evmpped not only with what IS prescribed in paragraph (1 , but in addition with a second, external, closing device. his device shall be capable of being closed by a blank flange or some other equally reliable device. Safety valves shall meet the following requirements: (l) Shells intended for the carriage of gases of 1 ° to 6 ° and 9° may be provided with not more than two safety valves whose aggregate clear cross-sectional area of passage at the seating or seatings shall be not less than 20 cm2 per 30 m3 or.part thereof of the receptacle's capacity. These valves shall be capable of opening automatically at a pressure of between 0. 9 and 1.0 times the test pressure of the shell to which they are fitted. They shall be of such a type as to resist dynamic stresses, including liquid surge. The use of dead-weight or counter-weight valves is prohibited. Shells intended for the carriage of gases of 1 ° to 9 ° harmful to the respiratory organs or entailing a poison risk 10 shall not have safety valves unless the safety valves are preceded by a frangible disc. In the latter case the arrangement of the frangible disc and the safety valve shall be required to be satisfactory to the competent authority. Where tank-vehicles are intended for carriage by sea, the provisions of this paragraph shall not prophibit the fitting of safety valves conforming to the regulations governing that mode of transport. (2) Shells intended for the carriage of gases of 7 ° and 8 ° shall be equipped with two independed safety valves, each so designed as to allow the gases formed by evaporation during normal operation to escape from the shell in such a way that the pressure does not at any time exceed by more than 10 per cent the working pressure indicated on the shell. One of the two safety valves may be replaced by a frangible disc which shall be such as to burst at the test pressure. In the event of loss of the vacuum in a double-walled shell, or of destruc; tion of 20 per cent of tlw insulation of a single-walled shell, the safety valve and the frangible disc shall permit an outflow such that the pres­ sure in the shell cannot exceed the test pressurf'. (3) The safety valves of shells intended for the carriage of gases of 7 ° and 8 ° shall be capable of opening at the working pressure indicated on the shell. They shall be so designed as to function faultlessly even at their lowest working temperature. The reliability of their operation at that temperature shall be established and checked either by testing each valve or by testing a specimen valve of each design-type. Thermal insulation O) If shells intended for the carriage of liquefied gases of ;3 and 4 ° are equipped with thermal insulation, such insulation shall consist of either: a sun shield covering not less than the upper third but not more than the upper half of the shell surface and separated from the shell by an air space at least 4 cm across; or a complete cladding, of adequate thickness, of insulating materials. 211233 211234 10. Gases identified by the letter «t» in the list of substances are deemed to be gases harmful to the respiratory organs or entailing a poison risk. E<DHMEPII: THI: KYBEPNHI:EOI: (TEYXOI: AEYTEPO) 1075 (2) Shells intende<l°for the carriage of gases of 7° and 8 ° shall be thermally insulated. Thermal insulation shall be ensured by means of continuous sheathing. If the space between the shell and the sheathing is exhausted of air (vacuum insulation), the protective sheathing shall be so designed as to withstand without deformation an external pressure of at least 0,1 MPa (1 bar) (gauge pressure). By derogation from marginal 211102 (2), external and internal reinforcing devices may be taken into account in the calculations. If the sheathing is so closed as to be gas­ tigh t, a device shall be provided to prevent any dangerous pressure from developing in the insulating la"'' i,1 !he event of inadequate gas-tightness of the shell or of its items of equipment. The device shall prevent the ii§tltration of moisture into the heat-insulating sheath. (3) Shells intended for the carriage of liquefied gases having a boiling point below -182 ° C at atmospheric pressure shall not include any combustible material either in the thermal insulation or in the means of attachment to the frame. The means of attachment of shells intended for the carriage of argon, nitrogen, helium or neon of 7° (a) or hydrogen 7° (b) may, with the consent of the competent authority, contain plastics substances between the inner the inner and the outer sheath. For batteries of receptacles (see marginal 2212 (1) ·(c)) il the following conditions shall be complied with: (1) If one1of the elements of a multiple-element shell is equipped with a safety valve and shut-off devices are provided between the elements, every element shall be so equipped. (2) The filling and discharge devices may be affixed to a manifold. (3) Each element of a multiple-element shell intended for the carriage of compressed gases of 1 ° and 2 ° which are harmful to the respiratory organs or email a poison risk 10, or are inflammable, shall be capable of being isolated by a valve (cock). (4) The elements of a multiple-element shell intended for the carriage of liquefied gases of 3 ° to 6 ° shall be so designed that they can be filled separately and can be kept isolated by a valve capable of being sealed. · (5) The following requirements shall apply to demountable tanks: 211235 (a) they shall not be interconnected by a manifold; and (b) if the demountable tanks can be rolled, the valves shall be provided with protective caps. By derogation from the provisions of marginal 211131, 211236 shells intended for the carriage of deeply-refrigerated liquefied gases need not have an inspection aperture. 211237 Section 4: Type approval 211239 211240 (No special requirements) 211249 Section 5: Tests The ·materials of every welded shell shall be tested by 211250 the method-described in Appendix B.ld .. The test-pressure levels shall be as follows: 211251 ( 1) For shells intended for the carriage of gases of 1 ° and 2 °: the levels indicated in marginal 2219 (1) and (3). (2) For shells intended for the carriage of gases of 3 ° and 4°: (a) if the shells are not more than 1.5 m in diameter, the levels indicated in marginal 2220 (2); (b) if the shells are more than 1.5 m in ~iameter, the levels12 indicated below: 10, Gases identified by the letter «t» in t.he list of substances are deemed to be gases harmful to the respiratory organs or entailing a poison risk. 11. The provisions of this Appendix are not applicable to frames of cylinders. 12. 1. The prescribed test pressures are: (a) if the shell is equipped with thermal insulation, at least equal to the vapour pressure,reduced by 100 kPa (1 bar), of the liquid at 60°C, and not less than 1 MPa (10 bar); . • (b) if the shell is not equipped with thermal insulation, at least· equal to the vapour pressure, reduced by 100 kPa (l bar), of the liquid at 65 °C, and not less than 1 MPa (10 bar). • 2. In view of the high toxicity of phosgene of 3 ° (at), the minimum test pressure for this gas is fixed at 1.5 MPa (15 bar) if the ~hell is equipped with thermal insulation and at 1. 7 MPa ( 17 bar) if it is not so equipped. 3. The maximum values in kg/litre prescribed for the degree of filling are calculated as follows: maximum $ight of contents per litre of capacity = 0.95 X specific gravity of the liquid phase at 50°C. 1076 • ECl>HMEPII THI KYBEPNHIEOI (TEYXOI dEYTEPO) Appendix !J. la Minimum test pressure for Maximum Mass of Item shells contents per litre Description of substance number with without of capacity thermal insulation MPa MPa kg Bromochlorodifluoromethane (R 12 B 1) 3 ° (a) 1.0 1.0 1.61 Chlorodifluoromethane (R 22) 3 ° (a) 2.4 2.6 1.03 Chloropentafluoroethane (R 115) 3 ° (a) 2.0 2.3 1.08 l-Chloro-2,2,2-trifluoroethane (R 133a) 3 ° (a) 1.0 1.0 1.18 Dichlorodifluoromethane (R 12) 3 ° (a) 1.5 1.6 1.15 Dichlorofluoromethane (R 21) 3 ° (a) 1.0 1.0 1.23 1,2-Dichloro-1,1,2,2-tetrafluoroelhane (R 114) 3 ° (a) 1.0 1.0 1.30 Octafluorocyclobutane (RC 318) 3 ° (a) 1.0 1.0 1.34 Ammonia 3 ° (at) 2.6 2.9 0.53 Chlorine . 3 ° (at) 1.7 1.9 1.25 Hexafluoropropylepe (R 216) 3 ° (at) 1. 7 1.9 1.ll Hydrogen bromide 3 ° (at) 5.0 5.5 1.20 Methyl bromide 3 ° (at) 1.0 1.0 1.51 Nitrogen dioxide No 2 3 ° (at) 1.0 1.0 1.30 Phosgene 3 ° (at) 1.5 1.7 1.23 Sulphur dioxide 3 ° (at) 1.0 1.2 1.23 Butane 3° (b) 1.0 1.0 0.51 1-Butene 3 ° (b) 1.0 1.0 0.53 1-Chforo-Ll-difluoroethane (R 1426) 3 ° (b) 1.0 1.0 0.99 Cis-2-butene 3 ° (b) 1.0 1.0 0.55 Cyclopropane 3 ° (b) 1.6 . 1.8 0.53 1,1-Difluoroethane (R 152a) 3° (b) 1.4 1.6 0.79 Dimethyl ether 3° (b) 1.4 1.6 0.58 lsobutane 3 ° (b) 1.0 l.O 0.49 Isobutene 3 ° (b) 1.0 1.0 0.52 Propane 3 ° (b) 2.1 2.3 0.42 Propylene 3 ° (b) 2.5 2.7 0.43 Trans-2-butene 3 ° (b) 1.0 1.0 0.54 1, 1, 1-Trifluoroethane 3 ° (b) 2.8 3.2 0.79 Dimethylamine 3 ° (bt) 1.0 1.0 0.59 Ethylamine ... 3 ° (bt) 1.0 1.0 0.61 Ethyl chloride ' 3 ° (bt) 1.0 1.0 0.80 Hydrogen sulphide 3 ° (bt) 4.5 5.0 0.67 Methylamine 3° (bt) • 1.0 1.1 0.58 Methyl chloride 3 ° (bt) 1.3 1.5 0.81 Methyl mercaplan 3° (bt) 1.0 1.0 0.78 Trimethvlamine 3 ° (bt) 1.0 1.0 - 0.56 1,2-But~diene 3 ° (c) 1.0 1.0 ", ·• 0.59 1,3-Butadiene 3 ° (c) 1.0 1.0 '· 0.55 ·,, Vinyl chloride 3 ° (c) 1.0 1.1 ., 0.81 Methyl vinyl ether 3 ° (cl) 1.0 1.0 0.67 Trifluorochloroethylene (R 1113) 3 ° (et) 1.5 1. 7 1.13 Vinyl bromide 3 ° (et) 1.0 1.0 1.37 Mixture F 1 4 ° (a) 1.0 1.1 1.23 Mixture F 2 4 ° (a) l.5 1.6 1.15 Mixture F 3 4 ° (a) 2.4 2.7 1.03 Mixture of gases R 500 4 ° (a) 1.8 2.0 1.01 Mixture of gases R 502 4° (a) 2.5 2.8 1.05 Mixtures of 19 lo 21 per cent by mass dichlorodif luoromethane (Rl2) and 79 to 81 per cent by mass . bromochlorodifluoromethane (R 12 Bl) 4 ° (a) 1.0 1.1 1.50 Mixtures of methyl bromide and chloropicrin 4 ° (at) l.O 1.0 1.51 Mixture A (trade name: butane) 4 ° (b) 1.0 1.0 0.50 Mixture A O (trade name: butane) 4° (b) 1.2 1.4 0.47 Mixture A l 4° (b) 1.6 1.8 0.46 Mixture B 4 ° (b) 2,0 2.3 0.43 Mixture C (trade name: propane) 4° (b) 2.5 2.7 0.42 E<DHMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) Description of substance Mixtures o(hydrocarbons containing methane • Mixtures· of methyl chloride and methylene chloride Mixtures of methyl chloride and chloropicrin Mixtures of methyl bromide and ethylene bromide Methylacetylene/propadiene and hydrocarbon mixtures Mixture P 1 Mixture P 2 Mixtures of 1,3-butadiene and hydrocarbons of3 ° (b) Ethylene oxide containing not more than 10 per cent carbon dioxide by mass Ethylene oxide with nitrogen up Lo a tolal pressure of 1 MPa (10 bar) at 50°C Dichlorodifluoromethane containing 12 per cent ethylene oxide by mass (3) For shells intended for the carriage of gases of 5 ° and 6: (a) if the shells are not sheathed in thermal insulation: the levels indicated in marginal 2220 (3) and (4); (b) if the shells are sheathed in thermal insulation as de­ fined in marginal 211234 (1): the levels indicated below: Description of substance . Bromotrifluoromethane (R 13 B 1) Carbon dioxide Chlorolrifluoromelhane (R 13) Hexafluoroethane. (R 116) Nitrous oxide (N20) Sulphur hexafluoride Trifluorqmethane (R 23) ~ ... ~ Xenon Hydrogen chloride Ethane Ethylene >z 1, l-Difluoroelhyle11e Vinyl fluoride Mixture of gases R 503 Carbon dioxide containing i1ol more than 3;) per cent ethylei1e oxi<le by mass Ethylene oxide containing more than 10 per cent but not more than 50 per cenl carbon dioxide by mass . Appendix B.la Minimum test pressure for Item shells number with without thermal insulation MPa MPa 4 ° (b) -• 22.5 30.0 4 ° (bt) l'.3 1.5 4 ° (bt) 1.3 1.5 4 ° (bt) 1.0 1.0 4 ° (c) 2.5 2.8 4 ° (c) 2.2 2.3 4° (c) 1.0 1.0 4 ° (et) 2.4 2.6 1 ° (et) 1.5 1.5 4 ° (et) 1.5 1.6 Item Minimum test number pressure MPa 5 ° (a) 12.0 5 ° (a) 19.0 22.5 5 ° (a) 12.0 22.5 5° (a) 16.0 20.0 5 ° (a) . 22.5 5 ° (a) 12.0 5 ° (a) 19.0 25.0 5 ° (a) 12.0 5 ° (al) 12.0 5 ° (b) 12.0 5° (b) 12.0 22.5 5 ° (c) 12.0 22.5 5 ° (c) 12.0 22.5 0° (a) 3.1 4.2 10.0 6° (c) 19.0 22.5 6 ~ (cl) 19.0 25.0 1077 Maximum Mass of content~ per litre of capacity kg 0.187 0.244 0.81 0.81 1.51 0.49 0.47 0.50 0.73 0.78 1.09 '' · Maximum mass. of contents per litre .. of capacity kg 1.50 0.73 0.78. 0.96 1.12 1.28 1.34 0.78 1.34 0.92 0.99 L30 0.69 0.32 0.25 0.36 0.66 0.78 0.58 0.65 ' . 0.11 0.21 0.76 0.73 0.78 0.66 0.75 1078 ECJ>HMEPII THI KYBEPNHIEOI (TEYXOI aEYTEPO) Where shells sheathed in thermal insulation are used which have been subjected to a test pressure lower than that shown in the table, the maxium mass of the contents per litre of capacity shall be such that the pressure reached in the shell by the substance in question al 55 ° C does not Description of substance Ammonia dissolved under pressure in water with more than 35 per cent but not more than 40 per cent ammonia by mass with more than 40 per cent but not more than 50 per cent ammonia by mass (5) For shells intended for the carriage of gases of 7° and 8°: not less than 1.3 times the maximum permitted working pressure, as indicated on the shell, but not less than 0.3 MPa (3 bar) (gauge pressure); for shells with vac­ uum insulation the test pressure shall be not less than 1.3 times the maximum premitted working pressure increased by 0.1 MPa (l bar). Item number 90 (at) 90 (at) The first hydraulic pressure test shall be carried out be- 211252 fore the thermal insulation is placed in position. The capacity of each shell intended for the carriage of 211253 gases of 3° to 6° and 9° shall be determined. under the supervision of an expert approved by the competent au thority, by weighing or volumetric measurement of the quantity of water which fills the shell: any error in the measurement of shell-capacity shall be of less than one per cent. Determination bv a calculation based on the dimen sions of- the shell is n'ot permitted. The maximum filling masses allowed in accordance with marginals 2220 ( 4) and 211 251 (3) shall be prescribed by an approved expect. Checking of the welds shall be carried out in accordance 211254 with the lambda - coefficient 1.0 requirements of marginal 211127 (7). By derogation from the requirements of marginal 211255 211151, the periodic tests shall take place: (1) every three years. in the case of shells intended for the carriage of boron trifluoride of 1 ° (at). town gas of 2 ° (bt). hydrogen bro­ mide, chlorine, nitrogen dioxide. sulphur dioxide or pbos­ gene of 3 ° (at), hydrogen sulphide of 3 ° (bt). or hydrogen chloride of 5 ° (at); (2) every six years in the case of shells intended for the carriage of other compressed and liquefied gases or of ammonia dissolved under pressure (9° (at)); and (3) afer six years' service and thereafter every twelve vears in the case of shells intended for the carriage of gases of 7 ° or 8 °. A leakproofness check shall be performed by an approved expert six years after each periodic test. In the case of shells heat-insulated by vacuum, the 211256 hydraulic-pressure test and the check of the internal condi tion may, with the consent of the approved expt>rt. bt> rf' placed by a leakproofness lest and measurement of the vacuum. If apertures have been made, on the occasion of periodic 21125 7 inspections, in shells intended for the carriage of gases of 7 ° or 8 °, the method by which they are hermetically closed before the shells are replaced in service shall be approved by the approved expect and shall ensure the intergrity ·of the shell. exceed the test pressure stamped on the shell. In such a case the maximum load allowed shall be prescribed by the expert approved by the competent authority. (4) For shells intended for the carriage of ammonia dis­ solved under pressure of 9° (at): Maximum mass of Minimum lest contents per litre pressure of capacity MPa kg 1.0 . 0.80 1.0 0.77 Leakproofness tests of shells intended for the carriage of 211258 gases of 1 ° to 6 ° and 9 ° shall be performed at a pressure of not less than 0.4 MPa (4 bar) and not more than 0.8 MPa (8 bar) gauge pressure. 211259 Section 6: Marking. The following additional particulars shall be marked by 211260 stamping or by any other similar method on the plate pre scribed in marginal 211160, or directly on the walls of the shell itself if the walls are so reinforced that the strength of the shell is not impaired: (1) on shells intended for the carriage of only one sub­ stance: the name of.the gas in full. This indication shall be supplemented in the case of shells intended for the carriage of compressed gases of 1 ° and 2 ° by an indication of the maximum filling pressure at 15 ° C allowed for the shell, and in the case of shells in­ tended for the carriage of liquefied gases of 3 ° lo 8 ° or of ammonia dissolved under pressure of9° (at) by an indica­ tion of the permissible maximum load in kg and of the fill­ ing temperature if below -20°C. (2) on multi-purpose shells: the names, in full, of the gases for whose carriage the shell is approved. • These particulars shall be supplemented by an indica­ tion of the permissible maximum load in kg for each gas: (3) on shells intended for the carriage of gases of 7 ° or 80; the working pressure; and (4) on shells equipped with thermal insulatio;1: the inscription "thermally insulated" or «thermally in­ sulated-by vacuum". The frame of a multiple-element shell shall near the fill- 211261 ing point a plate specifying: the test pressure of elements; the maximum filling pressure at 15 ° C allowed for ele ments intended for compressed gases; the number of elements; the aggregate capacity of the elements in litres: the name of the gas in full; and, in the case of liquefied gases: the permissible maximum load per element. in kg. In addition lo the particulars prescribed in marginal 211262 211161, the following shall be inscribed either on the tank-vehicle itself or on a plate: (a) - either: "lowest permissible filling temperature 20°C", or: "lowest permissible filling temperature ......... ": ECl>HMEPII THI KYBEPNHIEQI (TEYXOI AEVTEPO) 1079 (b) where the shell is intended for the carriage of one substance only: the name of the gas in full; for liquefied gases of 3 ° to 8 ° and for ammonia dis solved under pressure in water of 9° (at), the permissible maximum load in kg; (c) where the shell is a multi-purpose shell: the name in full of all the gases to whose carriage the shell is assigned, with an indication of the permissible max­ imum load in kg. for each gas; (d) where the shell is equipped with thermal insulation: the inscription "thermally insulated" or "thermally in­ sulated by vacuum", in an official language of the forward • ing country and also in English, French or German. unless international road transport tariffs, in any, or agreements concluded between the countries concerned in the trans­ port operation provide otherwise. These particulars shall not be required in the case of a 211263 vehicle carrying demountable tanks. Section 7: Operation 211264 211269 A shell assigned at different times to the carriage of dif- 211270 ferent liquefied gases of 3° lo 8° (multi-purpose sh<'II) may not carry substances other than those listed in one. and one only, of the following groups: Group 1: halogenated hydrocarbons of 3° (a) and 4° (a); 1,3-butadiene of 3 °(c) and mixtures of 1,3-butadiene and hydrocarbons, of 4° (c); Group 2: hydrocarbons of 3 ° (b).and 4 ° (b): Group 3: ammonia of 3 ° (at); dimetnyl ether of 3 ° (b): dimethylamine, ethylamine, methylamine and trimethylamine of 3 ° (bt); and vinyl chloride of 3 ° (c): Group 4: methhyl bromide of 3 ° (at): ethyl chloride and methyl chloride of 3 ° (bt) Group 5: mixtures of ehtylene oxide with carbon dioxide and of ethylene oxide with nitrogen of 4 ° (cl): Group 6: nitrogen, carbon dioxide, ;-are gases. nitrous oxide N 2 0, and oxygen 7 ° (a); air, mixtures of nitrogen with rare gases, and mixtures of oxygen with nitrogell'. also when they contain rare gases of 8 ° (a); Group 7: ethane, ethylene, and methane of 7° (b): and mixtures of methane with ethane, also when they contain propane or butane of 8° (b). Shells wich hve been filled with a substance of group 1 or 21 1271 group 2 shall be emptied of liquefied gas before being loaded with another substance belonging to the same group. Shells which have been filled with a substance of groups 3 to 7 shalf be completely emptied of liquelied gas and then flown down before being loaded with another sub stance belonging to the same group. The multiple use of shells for the carriage of liquefied 211272 gases of the same group shali be allowed if aii the require ments prescribed for the gases to be carried in one and the same shell are observed. Such multiple use shall he subject to approval by an approved expert. The multiple use of shells for the carriage or gas!'s of dif- 2 I 1273 ferent groups shal be allowed if permi1ted by the apprmcd expert. .When shells are reassigned Lo gases of a different group. the shells shall be completely emptied of liquefied gases. then blown down and, lastly, degassed. The degassing of shells shall be verified and certified by the approH•d ex­ pert. When loaded tanks or empty but uncleaned tanks arc 211274 handed over for carrige, only Lh particulars specified in marginal 211262 applicable to the gas loaded or just dis charged shall be visible; all particulars concerning other gases shall be covered up. All the elements of a multiple-element shell shall con- 21 1275 lain only one and the same gas. In the case of a multiple element shell inteded for the carriage of liquefied gases. the elements shall be filled separately and be kept isolat<'d by a sealed valve. The maximum filling pressure for compressecj gases of 211276 1 ° and 2° other than boron fluoride shall 11ol exceed the values prescribed in marginal 2119 (2). For boron fluoride of 1 ° (at) the maximum filling mass per litre of capacity shall not exceed 0.86 kg. The maximum filling mass per litre of capacity accord­ ing to marginals 2220, (2); (3) and (4), and 21125 L (2). (3) and (4), shall be abided by. The degree of filling of shells inteded for the carriage of 211277 ga~es of 7 ° (b) and 8 ° (b) shall remain below the level al which, if the contents were raised Lo the temperature al which the vapour pressure equalled the valve-ope11ing pressure, the volume of the liquid would reach 95 per cent of the shell's capacity at that teperature. Shells intended for the carriage of gases of 7° (a) and 8 ° (a) may be filled to 98 per cent at the loading temperature a11d the. loading pressure. On shells intended for the carriage of nitrous oxide and 211278 oxygen of 7 ° (a), air or mixtures containi11g oxygen of 8 ° (a), substances containing grease or oil shall not be used to ensure leakproofness of the joints or for the maintenance of the closures. The requirement in marginal 211175 shall 1101 apply to 2 ll 279 gases of 7° and 8°. Class 3: lmflammable liquids Section 1: General; scope (use of tanks)? definitions Use 211280 211299 211:300 211309 The following substances of Class 3 may be carried in 211310 fixed or demountable tanks: (a) substances listed by name i11 12 °: (b) substances dassified under (a) of 11 °. 14 ° lo 23 ". 25 ° and 26° and comparable substances to be classified under (a) of those items, with the exception of isopropoyl chloroformate of 250 (a); (c) substances classified under (b) of 11 °. 14° lo 20°. 22 ° and 24 ° to 26 ° and comparable substances lo he classified under (b) of those items; (cl) substances of 1 ° to 6 ° and 31 ° to 340 and corn para­ . ble substances to he classified under these items. with the exception of nitromelhane of .31 ° (c). Section 2: Construction 21 I :3 I 1 211319 Shels intended for the carriage of substances of 1·2° 21] :~20 shall be designed for a calculation pressure 1:1 of 1101 less than 1.5 MPa (15 bar) gauge pressure. Shells intended for the carriage of the suhstanc<'s r<'- 21 1321 ferred lo in marginal 211 310 (b) shall be designed for a calculation pressure1:1 of not less 1ha11 1.0 MPa (10 bar) gauge pressure. Shells intended for the carriage of the substances re- 21 1322 ferred to in marginal 211 310 (c) shall be designed for a calculation pressure 1 :i of not less than 0.4 MPa (4 bar) gauge pressure. Shells intended for the carriage of the substances r<'- 211323 ferred to in marginal 211 31 (') (d) shall be designed in ac cordance with the requireme11ts of the ge11eral part of this Appendix. Section 3: Items of equipment All opening of shells intended for the earring or tlw sub- 21 I :3:rn stances referred to in margi11al 21 1310 (a) a11d (b) shall h<' above the surface level of the liquid. No pipers or pipe c·m1 nections shall pass through the walls of the shell below IIIP surface level of the liquid. Shells shall be capable of being i3 See marginal 211127 (2) 1080 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) hermetically closed6 and the closures shall be capable of being protected with lockable caps. Shells intended for the carriage of the substances re­ ferred to in marginal 311310 (c) and (d) may also be of the botom-discharge type. SheJls intended ior the carriage of the substances referred to in marginal 211310 ( c) shall be capable of being hermeticaly closed6• If shells intended for the carriag of the substances re­ ferred to in marginal 311310 (a) and (b) or 11 ° or 14° to 20° of marginal 211310 (c) are fitted with safety valves, a , bursting disc shall be placed before the valve. The arrange­ ment of the bursting disc and safety valve shall be such as to satisfy the competent authority. If shells intendef for the carriage of the substances referred to in marginal 311310 (d) are equipped with safety valves or a venting system, these shall satisfy the requirements of marginals 211133 to 211135. Shells intended for the carriage of the sub­ stances referred to in marginal 211310 (d) having a flash­ point not exceeding 55 °C and equipped with a venting sys­ tem which cannot be closed shall have a flame-trap in the venting system. Section 4: Type approval (No special requirements) Section 5: Tests Shells intended for the carriage of the substances re­ ferred to in marginal 211310 (a), (b) or (c) shall be sub­ jected to the initial and periodic tests al a gauge pressure of not less than 0.4 MPa (4 bar). Shells intended for the carriage of the substances re­ ferred to in marginal 211310 (d) shall be subjected to the initial and periodic-tests at their calculation pressure as de­ fined in marginal 211123. Section 6: Marking (No special requirements) Section 7: Operation The degree of filling of shells intended for the carriage of the substances referred to in marginal 211310 (a), (b) or (c) shall conform to marginal 211172 (1) (d). Shells shall be hermetically61 closed during carriage. The closures of shells intended for the carriage of the substances referred lo in marginal 211310 (a) and (b) shall be protected by lockable caps. Fixed tanks (lank-vehicles) and demountable tanks ap­ proved for the carriage of substances of 6 °, 11 °, 12 ° and 14 ° to 20° shall not be used for the carriage of foodstuffs. articles of consumption or animal feedstuffs. An aluminium-alloy shell shall not be used for the carriage of acetaldehyde of 1 ° (a) unless the shell is reserved solely for such carriage and the acetaldehyde is free from acid. From October to March, mixtures of hydrocarbons having a vapour pressure above 110 kPa (1.1 bar) but not exceed­ ing 150 kPa (1.5 bar) (absolute pressure) at 5D°C, such as certain light distillates for cracking, may be carried i11 shells of the type described in marginal 211133. 6/ "Hermetically closed shells" means shells whose openings are hermetically closed and which are not equipped with safety valves, frangible disc or other similar safety devices. Shells having safety valves preceded by a frangible disc shall be deemed to be hermetically closed. 211331 211332 211333 211339 211340 211349 211350 211351 211352 211359 211360 211369 211370 211371 211372 211373 211374 211399 Class 4.1: Inflammable solids Class 4.2: Substances liable to spontaneous combus­ tion Class 4.3: Substances which give off inflammable gases on contact with water Section 1: General; scope (use of tanks); definitions Use Substances of 2 °, 8 ° et 11 ° of Class 4.1 and 8 ° of Class 4.2 and sodium, potassium, alloys of sodium and po­ tassium (1 ° (a)), substances of2° (e) and 4° of Class 4.3 may be carried in fixed or demountable tanks. NOTE: For the carriage i~ bulk of sulphur of 2° (a), napthalene of 11 ° (a) and (b), expandable polystyrenes of 12 ° of Class 4. l , substances of 5 °, dust from blast­ furnace filters (6° (a)) and substances of 10° of Class 4.2, and magnesium granules, coated, of 1 ° (d), calcium car­ bide (2 ° (a)) and calcium silicide in lumps (2 ° (d)) of Class 4.3, see marginals 41-Ul, 42111 and 43111. Section 2: Construction Shells intended for the carriage of white or yellow phospho­ rus of marginal 2431, 1 ° orsubstancesof2° (e) and 4° of marginal 24 71 shall be designed for a calculation pressure of not less than 1 MPa (10 bar) gauge pressure. Shells intended for the carriage of substances of mar­ ginal 2431, 3 °, shall be designed for a calculation pres­ sure of not less than 2.1 MPa (21 bar) gauge pressure. Section 3: Items of equipment Shells intended for the carriage of sulphur of 2° (b) or naphthalene of 11 ° (c) of marginal 2401 shall be equipped with thermal insulation made of materials which are not readily inflammable. They may be equipped with valves opening automatically inwards or outwards under the effect of a difference of pressure of 20 kPa (0.2 bar) to 30 kPa (0.0.3 bar). The discharge devices shall be capable of being protected by a lockable metal cap. Shells intended for the carriage of white or yellow phos­ phorus of marginal 2431, 1 °, shall meet the following re­ quirements: (1) The heating device shall not penetrate into, but shall be exterior to, the body of the shell. However, a pipe used for extracting the phosphorus may be equipped with a heat­ ing jacket. The device heating the jacket shall be so regu­ lated as to prevent the temperature of the phosphorus from exceeding the filling temperature of the shell. Other piping shall enter the shell in its upper part; openings shall be situ­ ated above the highest permissible level of the phosphorus and be capable of being completely enclosed under lockable caps. In addition, the cleaning apertures (fist­ holes) referred to in marginal 211132 shall not be permit­ ted. (2) The shell shall be equipped with a gauging system for verifying the level of the phosphorus and, if water is used as the protective agent, with a fixed gauge mark showing the highest permisflible level of the water 211400 211409 211410 211411 211419 211420 211421 211422 211429 211430 211431 The openings and orifices (valves, sleeves. manholes, 211432 etc.) of shells intended for the carriage of substances of marginal 24 71, l O (a). shall be protected by leak proof lockable caps, and such shells shall be equipped with ther mal insulation made of materials which are not readily in­ flammable. Shells intended for the carriage of substances of mar- 211433 ginal 2431, 3°, or marginal 2471, 2° (e), shall no~ ha ve any openings or connections below the level of the hqu1d, even if such openings or connections are capable of being closed. In addition, the cleaning openings (fist-holes) pro \'ided for in marginal 211132 shall not be pennillcd. Openings in the upper part of the shell. including their fit <l>EK 104 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 1081 tings, shall be capable of being protected by a cap. Section 4: Type approval • (No special requirements) Section 5: Tests Shells intended for the carriage of sulphur in the molten state of marginal 2401, 2 ° (b), naphthalene in the molten state of marginal 2401, 11 ° (c), white or yellow phospho­ rus of marginal 2431,. 1 °, sodium, potassium or alloys of sodium or potassium of marginal 24 71, 1 ° (a), substances of marginal 2471, 2° (e), substances of marginal 3471, 4 °, shall be subjected to the .initial and periodic tests at a gauge pressure of at least 0.4 MPa (4 bar). Shells intended for the carriage o(substances of mar­ ginal 2431, 3 °, shall he subjected to the initial and peri­ odic tests with a liquid not reacting with the substance to he carried, al a test pressure of 1 MPa (10 bar) gauge pres­ sure. The materials of every shell intended for the carriage of substances of marginal 243 L 3 °, shall be tested by the method described in Appendix B.ld. Shells intended for the carriage of. sulphur (including flowers of sulphur) of 2 ° (a), phosphorus sesquisulphide and phosphorus penlasulphide of 8 °, crude or pure naph­ thalene of 11 ° (a) and (b) of marginal 240 Lor of fresh I,- . quenched charcoal of marginal 2431. 8°, shall be sub­ jected to the initial and periodic tests al their calculation pressure as defined in marginal 211123. Section 6: Marking 211434 211439 211440 211449 211450 211451 211452 211453 211459 Shells intended for the Cflrriage of substances of mar- 211460 ginal 2431, 3 °, shall bear in addition to the particu Jars prescribed in marginal 211161 the words: "Do nol open during carriage. Liable to spontaneous combustion". Shells intended for the carriage of substances of mar­ ginal 2471, 2° (e), shall bear in addition to the particulars prescribed in marginal 211161 the words: "Do not open during carriage. Gives off inflammable gases on contact with water". These particulars shall be in an official language of the country of approval, and also, if that language is not Eng­ lish, French or German, in English, French or German. un­ less any agreements concluded between the countries con-· cerned in the transport operation provide otherwise. Section 7: Operation 211461 211469 Shells intended for the carriage of sulphur of 2 ° (b) or 2114 70 naphthalene 11 (c) of marginal 2401 shall be filled lo not more than 98 per cent of their capacity. White or yellow phosphorus of marginal 2431, l O , 2114 71 shall, if water is used as the protective agenl, be covered with a depth of not less than 12 cm of water al the time of filling; the degree of filling at a temperature of 60°C shall not exceed 98 per cent. If nitrogen is used as the protective agent, the degreP- of filling at a temperature of 60°C shall not exceed 96 per cent. The remaining space shall be filled with nitrogen in such a way that even after cooling, the pressure al no time falls below atmospheric pressure. The shell shall be hermetically closed so that no leakage of gas occurs. Fotthe carriage of substances of marginal 24 7 L 1 ° (a), 2114 72 caps shall be locked in conformity with marginal 211432. For trichlorosilane (silicochloroform) of marginal 24 7 L 2114 73 4 ° (a), or for methyldichlorosilane or ethyldichlorosilane of 4 ° (b), the degree of filling shall not exceed 1.4 or 0.95 or 0.93 kg per litre of capacity respectively. if filling is by mass or 85 per cent if filling is by volume. Shells which have contained phosphorus of marginal 2431, 1 °, shall when handed over fQr carriage either: .,s . be filled with nitrogen; the sender shall certify in the transport document that the shell, after closure, is gas­ light; or be filled with water lo not less. than 96 per cent and not more than 98 per Cfnt of their capacity: between 1 Oc­ tober and 31 March this water shall contain one or more anti-freeze agents free from corrosive action. not liable lo react with phosphorus, and in such concentration as Lo make it impossible for the water to freeze during carriage. Tanks which have contained phosphorus of marginal 2431, 1 °, must be considered, as far as the application of the provisions of marginal 42500 (1) is concerned. as being ''empty tanks, uncleaned". The degree of filling for shells containing substances of marginal 2431, 3 °, or marginal 24 71. 2 ° (e), shall not ex­ ceed 90 per cent; a space of 5 per cent shall remain empty for safety when the liquid is al an average temperature of 50°C. During carriage, the substances shall be under a layer of inert gas, the gauge pressure of which shall not ex­ ceed 50 kPa (0.5 bar). The shells shall be hermetically closed61 and the protective caps conforming Lo marginal 211433 shall be locked. Empty shells, uncleaned. shall when handed over for carriage be filled with an inert gas al a gauge pressurP- of up Lo 50 kPa (0.5 bar). Class 5.1: Oxidizing substa11ces Class 5.2: Organic peroxides Section 1: General; scope (use of tanks); definitions Use The following substances of Class 5.1 may be carried in fixed or demountable tanks: substances of 1 ° Lo 3 °. solu­ tions of 4 ° (also powdery sodium chlorate:iiHlie·i11oist or the dry slate) and hot aqueous solutions of ammonium ni:: trate of 6 ° (a) in a concentration of more than 80 per cenl but not more than 93 per cent provided that: 211474 211475 211476 211499 211500 211509 2n510 (a) the pH value, measured in a 10 per cent aqueous so- • 1 ution of the substance carried, is between 5 and 7, and (b) solutions do not contain any combustible substance in a quantity greater than 0.2 per cent or any chlorine com 0 pound in such quantity that the chlorine content exce·eds 0.02 per cent. . Substancesof'l 0 , 10°, 14°, 15° and 18° ofClass5.2 may be carried in fixed or demountable tanks. NOTE: For the carriage in bulk of substances of 4 ° lo 6 ° and r (a) and (b) of Class 5.1 see marginal 51111. Section 2: Construction 211511 2115] 9 Shells intended for the carriage in the liquid slate of sub- 211520 stances referred to in marginal 211150 shall be designed for a pressure of at least 0.4 MPa (4 bar) (gauge pressure). Shells, and their items of equipment, intended for the 211521 carriage of hydrogen peroxide or of aqueous solutions of hydrogen peroxide of marginal 2501, 1 °, or of liquid or ganic peroxides of marginal 2551, 1 °, 10°, 14 °, 15 ° and 18°, shall be made of aluminium not less than 99.5 per cent pure or of suitable steel nol liable lo cause the hydro gen peroxide or the organic peroxides of marginal 255 L 1 °, 10°, 14°, ] 5 ° and 18°. shall be made of aluminium not'less than 99.5 per cent pure or of suitable steel not lia ble to cause thP- hydrogen peroxide or the organic perox ides to decompose. Shells intended for the carriage of concentrated and hot 211522 aqueous solutions of ammonium nitrate of marginal 250 L. 6° (a), shall be made of auslenitic steel. 211523 211529 1082 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI flEYTEPO) Section 3: Items of equipment Shells intended for the carriage of hydrogen peroxide and of aqueous solutions of hydrogen peroxide containing more than 70 per cent hydrogen peroxide, of marginal 2501, 1 °, shall have their openings above the surface level of the liquid. In addition, cleaning apertures (fist-holes) as referred lo iri marginal 211132 shall not be permitted. In the case of solutions containing more than 60 per cent but not more than 70 per cent hydrogen peroxide, openings below the surface level of the liquid shall be permissible. In this case the shell-discharge system shall be equipped with two mutually independent shut-off device mounted in se­ ries, the first taking the form of a quick-closing internal stop-value of an approved type and the second that of a sluice-valve, at each end of the discharge pipe-socket. A blank flange, or another device providing the same meas­ ure of security, shall also be fitted al the outlet of each ex­ ternal sluice-valve. The internal stop-valve shall be such that, if the pipe is wrenched off, the stop-valve will remain integral with the shell and in the closed position. The connexions to the external pipe-sockets of shells shall be made of materials not liable to cause decomposi­ tion of hydrogen peroxide. Shells intended for the carriage of hydrogen peroxide or of aqueous solutions of hydrogen peroxide of 1 °, or of con­ centrated and h ot aqueous solutions of ammonium nitrate of 6° (a), of marginal 2501 shall be fitted in their upper part with a shut-off device preventing any build-up of ex­ cess pressure inside the receptacle, any leakage of liquid, and any entry of foreign matter into the receptacle. The shut-off devices of shells intended for the carriage of con­ centrated and hot aqueous solutions of ammonium nitrate shall be so designed as to preclude obstruction of the de­ vices by solidified ammonium nitrate during carriage. Where shells intended for the carriage of concentrated and hot solutions of ammonium nitrate of marginal 2501, 6° (a), are sheathed in thermally-insulating material, the material shall he of an inorganic nature and entirely free from combustible matter. Shells intended for the carriage of liquid organic perox­ ides ofmarginal 2551, 1 °, 10°, 14°. 15° and 18°, shall be equipped with a venting device fitted with a flame-trap and followed in series by a safety valve opening al a gauge pressure of 0.18 to 0.22 MPa (1.8 to 2.2 bar). Shells intended for the carriage of liquid organic perox­ ides ·of marginal 2551, 1 °, 10°, 14 °, 15 ° and 18 °. shall be equipped with a sun shield complying with the require­ ments of marginal 211234 (1). The sun shield and any un­ covered part of the shell shall be painted white and the paint shall be cleaned before each transport journey and renewed in case of yellowii1g or deterioration. The sun shields shall be free from combustible mailer. Section ·4: Type approval (No special requirements) Section 5: Tests Shells intended for the carriage of hydrogen peroxide or of aqueous solutions of hydrogen peroxide of l O • or of con­ centrated and hot solutions of ammonium nitrate of 6 ° (a). of marginal 2501, or of liquid organic peroxides of mar ginal 2551, 1 °, 10°, 14°, 15 ° and 18°, shall be tested al a pressure of 0.4 MPa (4 bar). 211530 211531 211532 211533 211534 211535 211536 211539 211540 211549 211550 · 211551 211559 Section 6: Marking (No special requirements) 211560 211569 Section 7: Operation The inside of the shell, and all parts liable to come into contact with substances referred to in marginal 211510, shall be kept clean. No lubricant capable of combining dangerously with the substance carried shall be used for pumps, valves or other devices. Shells intended for the carriage of liquids of marginal 2501, 1 ° to 3 °, shall be filled to not more than 95 per cent of their capacity at a reference temperature of 15°C. Shells intended for the carriage of hot aqueous solutions of ammonium nitrate of marginal 2501, 6° (a), shall be filled to not more than 97 per cent of their capacity, and the maximum temperature after filling shall not exceed 140°c. Tanks used for the carriage of hot aqueous solutions of ammonium nitrate of marginal 2501, 6° (a), shall not be used for the carriage of other substances without being first carefully cleansed of any residues. Class 6.1: Toxic substances Section 1: General; scope (use of tanks); definitions Use The following substances of Class 6.1 may be carried in fixed or demountable tanks: (a) highly toxic substances listed by name in 2 ° and 3: (b) highly toxic substances classified under (a) of 11 ° Lo 24°, 31 °, 41 °, 51 °, 55° and 71 ° Lo 88°, carried in the liquid stale, and comparable substances or solutions lo be classified under (a) of those items; (c) toxic or harmful substances classified under (b) or (c) of 11 °, 24 °, 5] 0 to 55 °, 5 7 ° to 68 ° and 71 ° to 88 °. car­ ried in the liquid state, and comparable substances or solu­ tions to be.classified under (b) or (c) of those items; (d) toxic or harmful powdery or granular substances classified under (b) or (c) of 12°, 14°, 17°. 19°. 21 °. 23 °, 24 °, 51 ° to 55 °, 5 7 ° Lo 68 ° and 71 ° lo 88 °. and comparable powdery or granular substances lo be classi­ fied under (b) or (c) of those items. NOTE: For the carriage in bulk of buslances of 44 ° (b). 60° (c) and 63 ° (c) see marginal 61111. Section 2: Construction Shells intended for the carriage of substances listed by name under 2 ° and 3 ° shall be designed for a calculation pressure131 of not less than 1.5 MPa (15 bar) gauge pres­ sure. Shells intended for the carriage of the substances re­ ferred to in marginal 211610 (b) shall be designed for a calculation pressure 131 of not less than 1.0 MPa (10 bar) gauge pressure. Shells intended for the carriage of the substances re­ ferred lo in marginal 211610 (c) shall be designed for a calculation pressure131 of not less than 0.4 MPa (4 bar) gauge pressure. Shells intended for the carriage of the powdery of granu­ lar substances referred to in marginal 211610 (d) shall be designed in acc ordance with the requirements of the gen­ eral part of this Appendix. Section 3: Items of equipment 211570 211571 211572 211573 211599 211600 211609 211610 211611 211619 211620 211621 211622 211623 211624 2-11629 All openings of shells intended for the carriage of the 211630 substances referred to in marginal 211610 (a) and (b) shall be above the surface level of the liquid. No pipe or pipe connections shall pass through the walls of the shell 13 See marginal 21112 7 (2) E<l>HMEPII THI KYBEPNHIEQI (TEYXOI .6EYTEPO) 1083 below the surface level of the liquid. Shells shall be capable of being hermetically closed61 and the closures shall be ca­ pable of being protected with lockable caps. The cleaning openings provided for in marginal 211132 shall not how­ ever be permitted for shells intended for the carriage of so­ lutions of hydrocyanic acid of 2 °. Shells intended for the carriage of the substances re- 211631 ferred to in marginal 211610 (c) and (d) may also be of the bottom-discharge type. The shells shall be capable of being hermetically closed61. If shells are fitted with safety valves, a bursting disc shall 211632 be placed before the valve. The arrangement of the burst ing disc and safety valve shall be such as lo satisfy the com petent authority. • 211633 211639 Section 4: Type approval 211640 211649 (No special requirements) Section 5: Tests Shells intended for the carriage of the substances re- . 211650 ferred to in marginal 211610 (a), (b) and (c) shall be sub jected to the initial and periodic tests at a gauge pressure of not less than 0.4 MPa (4 bar). For shells intended intended for the carriage of substances of 31 ° (a), the periodic tests shall be carried out at intervals of not more than three years and shall include the hydraulic pressure test. Shells intended for the carriage of the substances re- 211651 ferred to in marginal 211610 (d) shall be subjected to the initial and periodic tests al their calculation pressure as de fined in marginal 211123. Section 6: Marking (No special requirements) Section 7: Operation . 211652 211659 211660 211669 The degree of filling of shells intended for the carriage of 2116 70 the substances referred to in marginal 211610 (a), (b) and (c) shall be in accordance with marginal 211172 (l)(d). Shells intended for the carriage of substances of 3 ° shall 2116 71 not be· filled to more than 1 kg per litre of capacity. Shells shall be hermetically closed61 during carriage. 211672 The closures of shells intended for the carriage of the sub stances referred to in marginal 211610 (a) and (b) shall be protected with lockable caps. Tank vehicles and demountable tanks approved for the 211673 carriage of the substances referred to in marginal 211610 shall not be used for the carriage of foodstuffs, articles of consumption or animal feedstuffs. 211674 211699 Class 7: Radioactive substances. Section 1: General; scope (use of tanks): definitions Use In accordance with the applicable schedule of marginal 2703. . NOTE: Liquid or solid low-specific-activity substances. LSA (I), of marginal 2703, schedule 5,'olher than uranium hexafluoride and substances liable to spontaneous ignition. may be carried in fixed or demountable tanks. 6/ "Hermetically closed shells" means shells whose openings are hermetically closed and which are not equipped with saf~ty valves, frangible disc or other similar safety devices. Shells havmg safety valves preceded by a frangible disc shall be deemed to be hermetically closed. 211700 211709 211710 211711 211719 Section 2: Construction Shells intended for the carriage of the substances re­ ferred to in marginal 2703, Schedule 5, paragraph 11, shall be designed for a pressure of at least 0.4 MPa (4 bar) (gauge pressure). Where the radioactive substances are in solution or sus­ pension in substances of other Classes and the calculation pressures prescribed for the shells of tanks intended for the carriage of the latter substances are greater, the latter pres­ sures shall be applied. Section 3: Items of equipment Shells intended for the carriage of liquid radioactive substances9/ shall have their openings above the surface level of the liquid. No piping or pipe connection shall pass through the walls of the shell below the surface level of the liquid. Section 4: Type approval Tanks approved for the carriage of radioactive sub­ stances shall not be approved for the carriage of foodstuffs, articles of consumption, animal feeding stuffs, cosmetics or medicaments, or of substances used in the manufacture of these products. Section 5: tests Shells intended for the carriage of the substances re­ ferred to in marginal 2703, Schedule 5, paragraph 11. shall be tested initially and periodically al a pressure of 0.4 Mpa (4 bar) (gauge pressure). By derogation from the requirements of marginal 211151, the periodic internal inspection may be replaced by a check of the wall thickness by u'hrasound, performed every three years. .,,. '-' ,,. Section 6: Marking (No special requirements) Section 7: Operation The degree of filling at the reference temperature of 15 ° C shall not exceed 93 per cent of the total capacity of the shell. Tanks which have been used for the carriage of radioac­ tive substances shall not be used for the carriage of food­ stuffs, articles of consumption, animal feeding stuffs, cos­ metics or medicaments, or of substances used in the manu­ facture of these products. • Class 8: Corrosive ~ubstances Section,!: General; scope (use of tanks): definitions Use 211720 211721 211730 211731 211739 211740 211741 21J 749 211750 211751 211752 211759 211760 211769 211770 211771 211772 211799 211800 211809 The following substances of Class 8 may be carried in fixed 211810 or demountable tanks: (a) substances listed by name in 6 °, 7 ° and 24 °. and substances comparable with those of 7 °; (b) highly corrosive substances classified under (a) of 1°, 2°, 3°, 10°, 11°, 21°. 26°, 27°. 32°, 33°, 36°, 37°, 64°, 65° and 66°, carried in the liquid slate, and comparable substances or solutions to be classified under (a) of those items; (c) corrosive or slightly corrosive substances classified under (b) or (c) of 1 ° to 5°, 8° to 11 °, 21 °, 26°. 27°, 31 ° to 39°, 42 ° to 45 °, 51 ° to 54 ° and 61 ° to 66 °, car­ ried in the liquid state, and comparable substances or solu­ tions to be classified under (b) or (c) of those items; 1084 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) (d) powdery or granular corrosive or slightly corrosive substances classified under (b) or (c) of 22 °, 23 °, 26 °, 27°, 31 °, 35°, 39°, 41 °, 45°, 52° and 65°,and compa­ rable powdery or granular substances to be classified under (b) or (c) of those items. NOTE: For the carriage in bulk of lead sludge contain­ ing sulphuric acid of 1 ° (b) and of substances of 23 °, see marginal 81 111. 211811 211819 Section 2: Construction Shells intended for the carriage of substances listed in 211820 · 6° and 24° shall be designed for a calculation pressure131 of not less than 2.1 MPa (21 bar) gauge pressure. SheJls intended for the carriage of bromine of 24 ° shall be pro vided with a lead lining not less than 5 mm thick or an equivalent lining. Shells intended for the carriage of substances of 7 ° (a) shall be designed for a calculation pressure 1:i; of not less than 1.0 MPa (10 bar) and shells for the carriage of sub­ stances of 7° (b) and (c) for a calculation pressure 131 of not less than 0.4 MPa (4 bar). The requirements of Appendix B.ld shall apply to the materials and construction of welded shells intended for the carriage of hydrogen fluoride and aqueous solutions of hydrofluoric acid of 6 °. Shells intended for the carriage of the substances re- 211821 ferred to in marginal 211810 (b) shall be designed for a calculation pressure13 / of not less than 1.0 MPa (10 bar) gauge pressure. Where the use of aluminium is necessary for shells in­ tended for the carriage of nitric acid of 2 ° (a), such shells shall be made of aluminium not less than 99.5 per cent pure, in which case, by derogation from the provisions of the paragraph above, the wall .thickness need not exceed 15 mm. • ••• • Shells intended for the carriage of the substance), re- 211822 ferred to in marginal 211810 (c) shall be designed for a calculati on pressure 13/ of not less than 0.4 MPa (4 bar) gauge pressure. Shells intended for the carriage of monochloroacetic acid of 31 ° (b) shall be equipped with an enamel or equiva­ lent lining if the material of the shell is attacked by that acid. Shells and their items of equipment intended for the car­ riage of aqueous solutions of hydrogen peroxide shall be made of aluminium not less than 99.5 per cent pure or of a suitable steel not causing hydrogen peroxide to decom­ pose. Notwithstanding the provisions of the first paragraph. the wall thickness need not be greater than 15 mm when the shells are made of pure aluminium. Shells intended for the carriage of the powdery or granu- 211823 lar substances referred to in margi!J,al 211810 ( d) shal I be designed in accordance with the requireri1ents of the gen eral part of this Appendix. 211824 2-11829 Section 3: Items of equipment All openings of shells intended for the carriage of sub- 211830 stances of 6°, 7° and 24° shall be above the surface level of the liquid. No pipes or pipe connections shall pass through the walls of the shell below the surface level of the liquid. Shells shall b~. capable of being hermetically closed61 and the closures shall be capable of being pro tected by lockable caps. In addition, the cleaning openings referred to in marginal 211132 shall not be permitted. Shells intended for the carriage of the substances re- 211831 ferred to in marginal 211810 (b), (c) and (d) may also be of 13 See marginal 211127 (2) the bottom-discharge type. The bottom-discharge fittings of shells intended for the carriage of the substances re­ ferred to in marginal 211810 (b) and (c) shall conform to the requirements of marginal 211131. If shells intended for the carriage of the substances re­ ferred to in marginal 211810 (b) are fitted with safety valves, a bursting disc shall be placed before the valve. The arrangement of the bursting disc and safety valve shall be such as to satisfy the competent authority. . Shells intended for the carriage of sulphur trioxide of 1 ° (a) shall be thermally insulated and fitted with a heating de­ vice on the outside. Shells and their service equipment intended for carriage of hypochlorite solutions of 61 ° and of aqueous solutipns of hydrogen peroxide of 62 ° shall be so designed as to pre­ vent the entry of foreign matter, leakage of liquid or any building up of dangerous excess pressure inside the shell. Section 4: Type approval. (No special requirements) Section 5: Tests. Shells intended for the carriage of anhydrous hydroflu­ oric acid or aqueous solutions of hydrofluoric acid of 6° shall be subjected to the initial and periodic tests at a gauge pressure of at least 1.0 MPa (10 bar) and those intended for the carriage of substances of 7 ° shall be subjected to in­ itial and periodic tests at a gauge pressure of not less than 0.4 MPa (1 bar). Shells intended for the carriage of substances of 6 ° and 7 ° shall be inspected every 3 years for resistance to corro­ sion, by means of suitable instruments (e.g. by ultrasound). The materials of everv welded shell intended for the car­ riage of hydrogen fluoride and aqueous solutions of hydro­ fluoric acid of 6° shall be tested by the method described in Appendix B.ld · Shells intended for the carriage of bromine of 24 ° or of the substances referred to in marginal 211810 (b) and (c) shall be subjected to the initial and preriodic tests at a gauge pressure of not less than 0.4 MPa (4 bar). The hy­ draulic pressure test for shells intended for the carriage of sulphur trioxide of 1 ° (a) shall be repeated every three years. Shells made of pure aluminium and intended for the carriage of nitric acid of 2 ° (a) and of aqueous solutions of hydrogen peroxide of 62 ° need be subjected to the initial and .periodic tests at a gauge pressure of only 0.25 MPa (2.5 bar). The condition of the lining of shells intended for the car­ riage of bromine of 24 ° shall be inspected every year by an expert approved by the competent authority, who sJiall in­ spect the inside of the shell. Shells intended for the carriage of the substances re­ ferred to in marginal 211810 (d) shall be sujected Lo the initial and periodic tests at their calculation pressure as de­ fined in marginal 211] 23. Section 6: Marking. Shells intended for the carriage of anhydrous hyrlroflu­ oric acid or aqueous solutions of hydrofluoric acid of 6 °. or bromine of 24 °, shall hear in addition to the particulars re­ ferred to in marginal 211160 an indication of the permissi­ ble maximum.net load in kg and the date (month. year) of the most recent internal inspection of the shell. Section 7: Operation. Shells intended for the carriage of sulphur trioxide of I 0 (a) shall not be filled to more than 88 per cent of their ca­ pacity; those intended for the carriage of bromine of 24 ° shall be filled to not. less than 88 per cent and not more 211832 211833 211834 211835 211839 211840 211849 21]850 211851 211852 211853 211859 21]860 211861 211869 211870 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 1085 than 92 per cent of their capacity or to 2.86 kg per litre of capacity. Shells intended for the carriage of anhydrous hydronu­ oric acid or aqueous solutions of hydrofluoric acid of 6 ° shall not be filled to more than 0.84 kg per litre of capacity. Shells intended for the carriage of substances of 6 °. 7° 211871 and 24 ° shall be hermetically closed<•/ during carriage and the closures shall be protected with lockable caps. Appendix B. lb PROVISIONS CONCERNING TANK-CONTAINERS NOTE: Part I sets out the re quiremcnts applicable to lank-containers intended for the carriage of substances of all Classes. Part II contains particular requirements sup­ plementing or modifying the requirements of Parl 1. PART I: REQUIREMENTS APPLCABLE TO ALL CLASSES 211872 211999 212000 212099 Section 1: General; scope (use of tank-containers): defi nitions. NOTE: In accordance with the provisions of marginal 10121 (1), the carriage of dangerous substances in tank­ containers is permitted only where expressly authorized for such substances in each of the Sections 1 of Part II of this Appendix. • These requirements shall apply to tank-containers. of a 212 l Off capacity of more than 0.45 cubic metre which are used for the carriage of liquid. gaseous. powdery or granular sub stances, and to their fillings and acc-essories. A tank-container shall comprise a shell and items of 212101 equipment, including equipment to facilitate mo,·ement without significant change of attitude. In the following requirements: 212102 (1) (a) "Shell" means the tank proper (including the openings and their closures): (b) "Service equipment" of the shell means filling am! emptying, venting, safety, heating and heat-insulating de­ \·ices and the measuring instruments: and (c) "Structural equipment'' means the reinforcing. fas­ tening, protective or stabilizing members external to the shell. (2) (a) "Calculated pressure·· means a theoretical pres­ sure al least equal lo the test pressure which according to the degree of danger exhibited by the substance heing car­ ried may exceed the working pressure more or less suh­ stanliallv. It is used solelv lo determine the thickness of the walls o(the shell, lo- the ~xclusion of any external or inter­ nal reinforcing rlevice: (b) "Maximum working pressure (gauge pressure)" means the highest of the following three pressures: (i) the highest effective pressure allowed in the shell dur­ ing filling ("maximum filling pressure allowed"): (ii) the highest effective pressure allowed in Lhe shell during discharge ("maximum discharge pressure al­ lowed"); and (iii) the effective gauge pressure lo• which the shell is subjected by its contents (including such extraneous gases as it may conl<1in) al the maximum working tempera­ ture. Except where the special requirements for each Class provide otherwise, the numerical value of this working pressure (gauge pressure) shall not be lower than the l'a­ pour pressure (absolute pressure) of the filling substance at 50°C. For shells equipped with safety valves (with or without bursting disc). the maximum working pressure (gauge pressure) shall however be equal to the prescribed opening pressure of such safety valves. For shells equipped with venting systems and a safetv device lo prevent the contents spilling out if the shell ovP,: turns, the maximum working pressure (gauge pressure) shall be equal to the static pressure of the filling substance. (c) "Test pressure" means the highest effective pressure which arises in the shell during the pressure test: (d) "Filling pressure" means the highest effective pres­ sure which arises in the shell during the pressure test: (d) "Filling pressure'' means the maximum pressure ac­ tually built up in the shell when it is being filled by pres­ sure; (e) "Discharge pressure .. rneans the maximum pressure actually built up in the shell when it is being discharged llY pressure; (3) "Leakage test" means the test which consists of sub­ jecting the shell to an effective internal pressure equal to the maximum working pressure, but 1101 less than 20 kPa (0.2 bar) (gauge pressure). by a procedure approved by the competent authority. Section 2: Construction. 212103 212119 Shells shall be desingned and constructed in accordance 212120 with the provisions of a technical code recognized by the competent authority, but the following minimum require ments shall be met: (1) Shells shall be made of ductile metallic materials. For welded shells only a material whose weldability has been fully demonstralerl shall be used. Welds shall be skil­ fully made and afford complete safety. The materials of shells and of their protective linings which are in contact with the contents carried shall not contain substances liable to react dangerously with the !alter to form dangerous corn­ pounds, or substantially to weaken the material. •· (1) Shells, their allachments and their service and struf~ •• 2-12121 tural equipment shall be designed to withstand at least the static and dynamic stresses in normal car'riage without loss of conlents 11. The pressureon which the dimensioning of the lank- ·212122 container shell is based shall not be less than the calculaied pressure, but the stresses referred lb in marginal 212121 shall also be taken into account. Unless specially prescribed otherwise in· the various 212123 Classes, the following particulars shall be taken into ac count in the design of shells: (1) Gravity-discharge shells intended for the carriage of substances having a vapour pressure not exceeding 110 kPa (1.1. bar) (absolute pressure) at 50°C shall be de­ signed for a c.alculation pressure of twice the static pres­ sure of the substance to be carried but 1101 less than twice the static pressure of water. (2) Pressure-filled ·or pressure-discharge shells in­ tended for the c.arriage of substances having a vapour pres­ sure not exceerling 110 kPa (1.1. bar) (absolute pressure) al 50°C shall be designed for a calculation pressure equal to 1.3 times the filling or discharge pressure. (3) Shells intended for the carriage of substances having a vapour pressure of more than 110 Kpa ( 1.1. bar) but not more than 175 kPa (1. 75 bar) (absolute pressure) at 50° C shall, whatever their filling or discharge system. be de­ signed for a calculation pressure of not less than 0.15 MPa (1.5 bar) gauge pressure or 1.3 times the filling or dis­ charge pressure, whichever is the higher. (4) Shells intended for the carriage of substances having a vapour pressure of more than 175 kPa (l. 75 bar) (abso­ lute pressure) at 50°C shall, whatever their filling or dis­ charge system, be designed for a calculation pressure equal lo 1.3 Limes the filling or discharge pressure but not l/ If there are degassing vents. this shall not appl,- tn qua11tili<'s of gas escaping through them. 1086 E<DHMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) less than 0.4 MPa (4 bar) gauge pressurf'. Tank-containers intended to contain certain <langerous 212124 substances shall be provided with additional protection, which may take the form of additional thickness <?f the shell At the.test pressure, the stress a (sigma) al the most se- 212125 verely stressed point of the shell shall conform the material-dependent limits prescribed below. In addition. in choosing the material and determining wall thickness, the maximum and minimum filling and working temperatures should be taken into account, with particular reference to the risk of brittle fracture. (such additional thickness being determined in the light of the dangers inherent in the substances concerned; see the relevant classes) or of a protective device. (1) For metals and allo}'.S exhibiting a clearly-defined yield point or characterized by a guaranteed conventional yield stress Re (generally 0.2 per cent of residual elonga­ tion). (a) where the ratio Re/Rm is not more than 0.66 (Re=apparent yield stress or 0.2 • per cen proof stress; Rm= guaranteed minimum tensile slrenght): a ,s:; 0.75 Re I (b) where the ratio Re/Rm exceeds 0.66: a ,s:; 0.5 Rm I (2) For metals and alloys exhibiting no apparent yield stress and.characterized bv a guaranteed minimum tensile strenghtRm: ·• ... •. • . a ,s:; 0.43 Re I (3) The elongation at fracture. 21 in per cent. shall be 1101 less than 10.000 (Rm (in N/mm2) but shall be not less than 20 per cent in the case of st('cl and not less than 12 per cent in the case of alirninium al­ loys. Tank-containers intended for the carriage of innamma­ ble liquids having a flashpoint of not mo~e than 50°C and for the carriage of inflammable gases sball be capable of being electrically earthed. Tank-containers shall be capable of absorbing the forces specified in paragraph (1) and the wall thickness of lire shells shall be as prescribed in paragraphs (2)-(4) below. (1) Tank-containers and their fastenings shall under the maximum permissible. load be capable of absorbing the forces exerted by: in the direction of travel: twice the total mass: horizontally at right angles lo the direction of lraw•I: the total mass; (where the direction of travel is nol clearly determined, the maximum permissible load shall be twice the total mass); 2/ The specimens used to dl"lennine Ill(' elongation al fradun· shall be taken trnnsve'rsely to the dir<'<'lion or l'Oliing and J,., so s,•­ cured that: Lo=5d where L o = lenght or the speciu111 liefnn· th,· 1,·sl: and d = diameter. 212126 212127 vertically upwards: the total mass; and vertically downwards: twice the total mass. Under each of these forces the safely factors to be ob­ served shall be the following: for metals having a clearly-defined yield point: a safety factor of 1.5 in relation to the apparent yield slres~; or for metals with no clearly-defined yeld point: a safety factor of 1.5 in relation to the guaranteed 0.2 per cent proof stress. (2) The thickness of the cylindrical wall of the shell and of the ends and cover plates shall be calculated by the fol­ lowing formulae: e pMPa D (in mm) 2 a e Pba,x D (in mm) 20 X a where PMI'· = calculated pressure or lest pressure. whichever is t11e higher, in MPa; PI>••= calculated pressure or test pressure. whichever is the higher, in bar; D = internal diameter of shell in mm: and a= permissible stress, as defined in marginal 212 125 paragraphs (1) (a), (1) (b), and (2). in N/mm2. The thickness shall in no case be less than that pre­ scribed in paragraphs (3) and (4) below. (3) The barrels, ends and cover plates of shells not more than 1.80 m in diameter, shall be nol less than 5 mrn thick if of mild steePI (as specified in marginal 212 125) or of equivalent thickness if of another metal. Where the diame­ ter exceeds 1.80 m this thickness shall be increased lo 6 mm if the tank is of mild steeP1 (as specified ·in marginal 212 125) or to an equivalent thickness if the lank is of an­ other metal. Whatever the metal used, the thickness of the shell wall shall in no case be less than 3 mm. ( 4) Where additional protection of the shell against dam­ age is provided, the competent authority may allow the aforesaid minimum thicknesses lo be reduced in propor­ tion to the protection provided: however, the said thick­ nesses shall be not less than 3 mm in the case of mild steel,31 or than an equivalent thickness in the case of other materials, for shells not more than 1.80 m in diameter. For shells with a diameter exceeding 1.80 hi the aforesaid min­ imum thickness shall be increased to 4 mm in the case of mild steel31 and to an equivalent thickness in the case of an­ other metal. Tank-containers shall be carried only on vehicles II hose fastenings are capable, under the maximum permissible load on the tank-containers, of absorbing the forces speci­ fied in marginal 212127 (1) above. S~ction 3: Items of equipment The items of equipment shall be so arranged as to be pro­ tected against the risk of being wrenched off or damaged during carriage or handling. If the connexion between the frame and the shell allows relative movement as between these sub-assemblies, the items of equipment shall be so fastened as lo permit such movement without risk of dam­ age to working parts. The items of equipment shall exhibit a suitable degree of safety comparable lo that of the shell. In addition, particular conditions applicable to bollom­ discharge lank-containers are prescribed in marginal 212131 below. 3/ ''Mild ~tee-I" means a st,·<'I hal'ing a l,1raki11g strPngh 1,., tween 360 and 440 N/111n12. 212128 212129 212130 E<l>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: 6EYTEPO) 1087 Every bottom-discharge tank-container, and in the case 212131 of compartmented bottom-discharge tank-containers every compartment, shall be equipped with two mutually inde pendent shut-off devices, the first being an internal stop valve4/ fixed directly to the shell and the second being a sluice-valve or other equivalent device51, mounted in se ries, one at each end of the discharge pipe. In addition, the openings of the shells shall be capable of being closed by means of screw-threaded plugs, blank flanges or other equally effective devices. The internal stop-valve shall be operable from above or from below. If possible, the setting open or closed - of the internal stop-valve shall be capa ble of being verified from the ground in both cases. Internal stop-valve control devices shall be so designed as t'o pre vent any unintended opening through impact or an inadver tent act. The internal shut-off device shall continue to be effective in the event of damage to the external control device. In order to avoid any loss of contents in the event of damage to the external discharge fittings (pipes, lateral shut-off de­ vices), the internal stop-valve and its seating shall be pro­ tected against the danger of being wrenched off by external stresses or shall be so designed as to resist them. The filling and discharge devices (including flanges or threaded plugs) and protective caps (if any) shall be capable of being se­ cured against any ·unintended opening. A tank-container or each of its compartments shall, save where it is intended for the carriage of deeply refrigerated gases, be provided with an opening large enough to enable the tank-container or compartment to be inspected. Tank-containers intended for the carriage of substances 212132 for which all the openings are above the surface level of the liquid may be equipped, in the lower part of the body, with a cleaning aperture (fist-hole). This aperture shan be capa ble of being sealed by a flange so closed as to be leakproof; the design of which shall be approved by the competent au thority or by a boqy designated by that authority. A tank-container intended for the carriage of liquids 212133 having a vapour pressure of not more than llO kPa (1.1 bar) (absolute) at 50°C shall have a venting system and a safety device to prevent the contents from spilling out of the shell if the tank-container overturns, or shall conform to the requirements of marginal 212134 or 212135 below. A tank-container intended for the carriage of liquids 212134 having a vapour pressure of not less than llO kPa (1.1 bar) and not more than 175 kPa ( 1. 7 5 bar) (absolute) at 50°C shall have a safety valve set at not less than 150 kPa ( 1. 5 bar) (gauge pressure) and such that it is fully open at a pressure not exceeding the test pressure; or shall conform to the requirements of marginal 212135. A tank-container intended for the carriage of liquids 212135 having a vapour pressure of not less than 175 kPa (1. 75 bar) and not more than 300 kPa (3 bar) (absolute) at 50°C shall be equipped with a safety valve set at a gauge pres sure not less than 300 kPa (3 bar) and such that it is fully open at a pressure not exceeding the test pressure; or shall be hermetically sealed61. 4/ Save as may be otherwise provided in the case of shells in­ tended for the carriage of certain crystallizable or highly viscous substances. 5/ In the case of tank-containers of less than l nil capacity, the sluice-valve or other equivalent device may be replaced by a blank flange. 6/ •Hermetically closed shells» means shells whose openings are hermetically closed and which are not equipped with safety valves, frangible discs or other similar safety devices. Shells having safety valves preceded by a frangible disc shall be deemed to be hermetically closed. Moving parts such as covers, closures, etc., which are li- 2121361 able to come into frictional or percussive contact with alu minium tank-containers intended for the carriage of in- • flammable liquids havjng a flashpoint of not more than 55 ° C or for the carriage of inflammable gases shall not be made of unprotected corrodible steel. Section 4: Type approval 212137 212139 The competent authority or a body designated by that 212140 authority shall issue in respect of each new type of tank container a certificate attesting that the prototype tank container, including fa stenings, which it has surveyed is suitable for the purpose for which it is intended and meets the construction requirements of Section 2 and the equip ment requirements of Section 3. If th~ tank-containers are serially manufactured without modification, this approval shall be valid for the entire series. The test results, the sub stances and/or groups of substances for the carriage of which the tank-container is approved and its type aproval number shall be entered in a test report. The substances of a group of substances shall be of a similar kind and equally compatible with the characteristics of the shell. The sub stances of groups of substances permitted shall be speci fied in the test report, with their chemical names or the cor­ responding collective heading in the list of substances, and their Class and item number. The approval number shall consist of the distinguishing sign 7 / of the State in whose ter ritory the approval was granted, and a registration nurriber. Section 5: Tests 212141 212149 Shells and their equipment shall either together or sepa- 212150 rately undergo an initial inspection before being put intQ service. This inspection shall include a check of conformity • to the approved prototype, a check of the design characteristics81, an external and internal examination, a hydraulic pressure test91 at the test pressure indicated on the data plate and a check of satisfactory operation of the equipment. The hydraulic pressure test shall be carried out before the installation of such thermal insulation as may be neces­ sary. If the shells and their equipment are tested sepa­ rately, they shall be jointly subjected to a leakproofness test after assembly. • Shells and their equipment shall undergo periodic in- 212151 spections at fixed intervals. The periodic inspections shall include: an external and internal examination and, as a general rule, a hydraulic press ure test91. Sheathing for thermal or other insulation shall be removed only to the ex tent required for reliable appraisal of the shell's character istics. In the case of shells intended for the carriage of powdery or granular substances, and with the agreement of the ex­ pert approved by the competent authority, the periodic hy­ draulic pressure tests may be omitted and replaced by leakproofness tests in accordance with marginal 212102(3). The maximum intervals for inspections shall lw five maximum years. 7 / Distinguishing sign for use in international traffic prscribed by -the Convention on Road Traffic (Vienna, 1968). 8/ The check of the design characteristics shall also include, for shells requiring a test pressure of 1 MPa (10 bar) or higher, a check of sample weld test-pieces and the tests prescribed in Appendix b.ld. 9/ In special cases and with the agreement of the expert approved by the competent authority, the hydraulic pressure test may be replaced by a pressure test using another liquid or gas, where such an operation does not present any danger. 1088 E<DHMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) In addition, a leakproofness test of the shell with its 212152 equipment and a check of the satisfactory operation of all the equipment shall be carried out at least every two and a half years: When the safety of the shell of of its equipment may have 212153 been impaired as a result of repairs, alterations or a~cident, an exceptional check shall be carried out. The tests, inspections and checks in accordance with 212154 marginals 212150 to 212153 shall be carried out by the expert approved by the competent authority. Certificates shall be issued showing the results of these operations: Section 6: Marking 212155 212159 Each tank-container shall be fitted with a corrosion- 212160 resistant metal plate permanently attached to the shell in a place readily accessible for inspection. The following par ticulars at least shall be marked on the plate by stamping or by any other similar method. These particulars may be en graved directly on the walls of the shell itself if the walls are so reinforced that the strength of the shell is not impaired: approval number; manufacturer's name or mark; manufacturer's serial number; year of manufacture; test pressure in MPa or bar (gauge pressure); capacity in litres - in the case of multiple-element tank-containers: capacity of each element; design temperature (only if above 50°C or below 20°C); date (month and year) of initial test and most recent periodic test in accordance with marginals 212150 and 212151; and stamp of 'the expert who carried out the tests. On pressure-filled or, pressure-discharge tank-containers the, maximum working pressure allowed shall be inscribed in addition. -. The following particulars shall be·irtscribed either on the 212161 tank-vehicle itself or on a board: the names of the owner and of the operator; the capacity of the shell; the unladen (tare) mass; the maximum permissible laden weight; and the· name ofsubstance being carried 101. In addition, tank-containers shall bear the prescribed danger labels. •• Section 7: Operation 212162 212169 During carriage, tank-containers shall be fixed on the 212170 carrying vehicle in such a way as to be adequately pro tected by the fittings of the carrying vehicle or of the tank container itself against lateral and longitudinal impact and against overturning111. If the shells and the service equip ment are so constructed as to withstand impact or overturn ing they need not be protected in this way. Tank-containers shall not be loaded with any dangerous 212171 substances other than those for whose carriage they have been approved. IO/ A collective description or an index number may be given instead of the name. 11/ Examples of protection of shells: 1. Protection against lateral impact may for example consist of longitudinal bars protecting the shell on both sides at the level of the median· line. 2. Protection against overturning may for example consist of reinforcing rings or bars fixed transversally in relation to the frame. 3. Protection ·against rear impact may for example consist of a bumper or frame. ( 1) The folloxing degrees of filling shall not be exceeded in tank-containers intended for the carriage of liquids at ambient temperatures: (a) for inflammable substances without additional risks (e.g. toxic or corrosive), in tank-containers with a venting system and with or without safety valves even where pre­ ceded by a bursting disc: 100 100 degree of filling = ------ or --- % of 1 + cx(50 - tF) 1 + 35a capacity; (b) for toxic or corrosive substances, whether inflamma­ ble or not, in tank-containers with a venting system with or without safety valves even where preceded by a bursting disc: 98 98 degree of filling = ----- or --- % of 1 + cx(50 - tr) 1 + 35a capacity; (c) for inflammable, harmful or slightly corrosive sub­ stances in hermetically closed shells61. 97 97 degree of filling = ------ or --- % of 1 + 1X(50 - IF) 1 + 35a capacity; . (d) for highly toxic, toxic, highly corrosive or corrosive highly substances in hermetically closed shells:6 95 95 degree of filling == ----- or --- % of 1 + 1X(50 - tr) 1 + 35a capacity; (2) In these formulae, IX is the mean coefficient of cubi­ cal expansion of the liquid between 15 ° and 50°C, i.e. for a maximum variation in temperature of 35 °C. dis - dso a is calculated by the formula: IX = 35 X d 50 where d 151 and d 501 are the relative density of the liquid at l5°C and 50°C reprectively. tF is the mean temperature of the liquid during filling. .(3) The provisions of marginal 212172 (1) above shall not apply to tank-containers whose contents are maintained by means of a heating device at a temperature above 50°C during carriage. In such a case the degree of filling at the outset shall be such and the temperature shall be so regulated that the tank-container is not full to more than 95 per cent of its capacity at any time during carriage. If the shells of tank-containers intended for the carriage of liquids12/ are not divided by partitions or surge plates into sections of not more than 5m3 capacity, th~ said shells shall be filled to not less than 80 per cent of their capacity unless they are practically empty. Tank-containers shall be closed so that the contents cannot run out uncontrolled. The openings of bottom­ discharge shells shall be closed by means of screw­ threaded plugs, blank flanges or other equally effective devices. 212172 212173 212174 6/ «Hermetically closed shells» means shells whose openings are hermetically closed and which are not equipped with safety valves, frangible discs or other similar safety devices. Shells having safety valves preceded by a frangible disc shall be deemed to be hermetically closed. 12/ Under this provision, substances whose kinematic viscosity at 20°C is below 25 cm2/s shall be deemed to be liquids. <I>EK 104 E<DHMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 1089 Where several closure systems are fitted in a series, that 212175 nearest to the substance being carried shall be closed first. No residue of the dangerous substance being carried 212176 shall adhere to the outside of a tank-container during carriage. To be accepted for carriage, empty tank-containers, 212177 uncleaned, shall be closed in the same manner and leakproof in the same degree as though they were full. Section 8: Transitional measures 212178 212179 Tank-containers constructed before 1 May -1985 in 212180 accordance with the requirements of ADR in force between 1 October 1978 and 30 April 1985 but not conform ing to the provisions applicable from 1 May 1985 may continue to be used after that date. • Section 9: Use of tank-containers approved for maritime transport 212181 212189 Tank-containers which do not fully meet the 212190 requirements of this appendix but which have been approved in accordance with the requirements concerning maritime transport13 / shall be accepted for carriage preceding or following maritime transport. In addition to the particulars already prescribed, the transport document shall bear the words: «Carriage in accordance with marginal 212190». Only substances authorized under marginal 10121(1) may be carried in tank-containers. PART 11:SPECIAL REQUIREMENTS SUPPLEMENTING OR MODIFYING THE REQUIREMENTS OF PART I Class 2: Gases, compressed, liquefied or dissolved under ·pressure Section 1: General, scope (use of tanks-containers), definitions Use 212191 212199 212200 212209 Gases of Class 2 other than those listed below may be 212210 carried in tank-containers: fluorine and • silicon tetrafluoride of 1 ° (at); nitric oxide of 1 ° (et); mixtures of hydrogen with not more than 10 per cent hydrogen selenide or phosphine or silane or germane by volume or with not more than 15 per cent arsine by volume; mixtures of nitrogen or rare gases ( containing not more than 10 per cent xenon by volume) with not more than 10 per cent hydrogen selenide or phosphine or silane or germane by volume or with not more than 15 per cent arsine by volume of 2 ° (bt); mixtures of hydrogen with not more than 10 per cent diborane by volume; mixtures of nitrogen or rare gases (containing not more than 10 per cent xenon by volume) with not more than 10 per cent diborane by •volume of 2 ° (et); boron chloride, chlorine trifluoride, nitrosyl chloride, sulphuryl fluoride and tungsten hexafluoride of 3 ° (at); methylsilane of 3 ° (b); arsine, dichlorosilane, dimethylsilane. hydrogen selenide and trimethylsilane of 3 ° (bt); cyanogen, cyanogen chloride and ethylene oxide of 3 ° (et); mixtures of methylsilanes of 4 ° (bt); ethylene oxide containing not more than 50 per cent methyl formate by mass of 4 ° (et); silane of 5 ° (b); substances of 5 ° (bt) and (et); dissolved acetylene of9° (c); and the gases of 12 ° and 13 °. 13/ These requirements are published in the IMDG Code. 212212 212219 Section 2: Construction The shells of tank-containers intended for the carriage 212220 of substances of 1 ° to 6 ° and 9 ° shall not be made of aluminium or aluminium alloy. The requirements of Appendix B.ld shall apply to the 212221 materials and construction of welded shells. 212222 212229 Section 3: Items of equipment In addition to being equipped with the devices 212230 prescribed in marginal 213131, the discharge pipes of tank-container shells shall be capable of being closed by blank flanges or some other equally reliable device. The shells of tank-containers intended for the carriage 212231 of liquefied gases may be equipped, in addition to the filling, discharge and gas - pressure - equalizing orifices, with openings in which gauges, thermometers and manometers can be fitted. Safety valves shall meet the conditions prescribed in 212232 paragraphs (1), (2) and (3) below. (1) The shells of tank-containers intended for the ~arriage of gases of 1 ° to 6 ° and 9 ° may be fitted with not more than two safety valves. The safety valves shall be • capable of opening automatically under a pressure of from 0.9 to 1.0'times the test pressure of the shell to which they are fitted. They shall in addition be constructed in such a way that in the event of to~al fire engulfment the pressure inside the shell does not exceed the test pressure. They shall be of such a type as to resist dynamic stresses, including liquid surge. The use of deadweight or counterweight valves is prohibited. • The shells of tank~containers intended for the carriage of gases of 1 ° to 9 ° harmful to the respiratory organs or entailing a poison risk141shall not have safety valves unless the safety valves are preceded by a bursting disc. In the : ' • latter case the arrangement of the bursting disc and the . safety valve shall be to the satisfaction of th1. c~~petent authority. • • (2) The shells of tank-containers intended for th e carriage of gases of 7° (a) and 8° (a) which are nqt in. constant communication with the outside air, and of those intended for the carriage of gases of 7 ° (b) and 8 ° (b) shall be fitted with two independent safety valves each so designed as to permit evacuation of the gases from the shell in such a way that the pressure does not at any time exceed the working pressure indicated on the tank-container by more than 10 per cent. In addition, the shells of such tank-containers may be fitted with bursting discs in series with and preceding the safety valves. In such a case the arrangement of the bursting disc and the safety valve shall be to the satisfaction of the competent authority. • (3) The safety valves of the shells of tank-containers intended for the carriage of gases of 7 ° and 8 ° shall be capable of opening at the working pressure indicated on the tank-container. They shall be so desingned as to function faultlessly even at the lowest working temperature. The reliability of their operation at that temperature shall be established and checked either· by testing each valve· or by testing a specimen valve of each type. An internal flow-restricting valve or equivalent device 212233 shall be fitted to every orifice more than 1. 5 mm in diameter provided in the shell for the passage of gases or liquids, other than orifices carrying safety valves. 14/ Gases identified by the letter "t" in the list of substances are deemed to be gases harmful to the respiratory organs or entailing a poison risk. 1090 E<l>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: AEYTEPO) Thermal insulation. ( 1) If the shells of tank-containers intended for the carriage of liquefied gases of 3 ° to 4 ° are equipped with thermal insulation, such insulation shall be subject to the special provisions under (2) below either: Consi?t of a sun shield covering not less than the upper third but not more than the upper half of the tank­ container's surface and separated from the shell by an air space at least 4 cm across; or Consist of a complete cladding, of adequate thickness, of insulating materials. The thermal insulation shall be so designed as not to hinder access to the filling and discharge devices. (2) The shells of tank-containers intended for the carriage of 1,3 - butadiene· of 3 ° (c), or of methyl vinyl ether, trifluorochloro - ethylene or vinyl bromide of 3 ° ( et), shall be protected by a sun-shield as defined above. (3) The shells of tank-containers intended for the carriage of gases of 7 ° and 8 ° shall be thermally insulated. The thermal insulation shall be protected against impact by means of continuous sheathing. If the space between the shell and the metal sheathing is under vacuum (vacuum insulation), the protective sheathing shall be so designed as to withstand without deformation an external pressure of at l!l,ast 0.1 MPa (1 bar) (gauge pressure). If the sheathing is so closed as to be gas-tight, a device shall be provided to prevent any dangerous pressure from ·developing in the insulating layer in the event of inadequate gas-tightness of the shell or of its items of equipment. The device shall prevent the infiltration of moisture into the heat-insulating sheath. (4) The shells of tank-containers intended for the carriage of oxygen of 7 ° (a), or of air or mixtures of oxygen with nitrogen of 8 ° (a), shall not include any combustible material either in the thermal insulation or in the means of attachment to the frame. In the ~ase of'multiple - element tank-containers, the following conditions shall be. met: (1) If one of the elements of a multiple - element tank­ container is fitted with a safety valve and shut~off devices are provided between the elements, every element shall be so fitted. (2) The filling and discharge devices may be fitted to a manifold. (3) Each element of a multiple - element tank-container intended for the carriage of compressed gases of 1 ° and 2 ° harmful to the respiratory organs or entailing a poison risk 15/ shall be capable of being isolated by a valve. (4) The elements of a multiple - element tank-container intended for the carriage of liquefied gases of 3 ° to 5 ° harmful to the respiratory organs or entailing a poison risk 15/ shall be so designed that they can be filled separately and be kept isolated by a valve capable of being sealed. Section 4: Type approval (No special requirements). 15/ The following are deeined to be liquefied gases harmful to the respiratory organs or entailing a poison risk: hydrogen bromide (anhydrous hydrobromic acid), hydrogen fluoride (anhydrous hydrofluoric acid), hydrogen sulphide (sulphuretted hydrogen), ammonia, chlorine, sulphur dioxide (anhydrous sulphurous acid), nitrogen dioxide (nitrogen peroxide; nitrogen tetroxide), T gas, methyl vinyl ether, chloromethane (methyl chloride), bromomethane (methyl bromide), phosgene (carbonyl chloride), vinyl bromide, methylamine (monomethylamine), dimethylamine, trimethylamine, ethylamine (monoethylamine), ethylene oxide, methanethiol (methyl mercaptan) mixtures of carbon dioxide with ethylene oxide and liquefied hydrogen chloride (anhydrous hydrochloric acid).· 212234 212235 212236 212239 212240 212249 Section 5: Tests The material s of every welded shell shall be tested by the method described in Appendix B.ld. The test pressure shall be as follows: (1) Tank-containers intended for the carriage of gases of 1 ° and 2 °, in conformity with marginal 2219 ( 1 ); (2) Tank-containers intended for the carriage of gases of 3 ° and 4 °, in conformity with marginal 2220 (2) if the shells are not more than 1.5 m in diameter, and in conformity with marginal 211 251 (2) (b) if the shells are more than 1.5 m in diameter; (3) Tank-containers intended for the carriage of gases of 5 ° and 6 °, in conformity with marginal 2220 (3) and (4), and in conformity with marginal 211 2 51 (3) (b) in the case of myltiple - element tank - containers whose elements are interconnected and form a battery, are not isolated from one another, and are encased in a thermal insulation; (4) Tank-containers intended for the carriage of ammonia dissolved under pressure of 9° (at), in conformity with marginal 211251 (4); (5) (a) Tank-containers fitted with safety valves and intended for the carriage of gases of 7 ° and 8 °: 1.5 times the working pressure indicated on the shells, but not less than 0.3 MPa (3 bar) (gauge pressure); for tank containers with vacuum insulation the test pressure shall be 1.5 times the working pressure increased by 0.1 MPa (1 bar). (b) Tu the case of tank-containers without safety valves and intended for the carriage of gases of 7° (a) and 8° (a), the first test shall be performed at 0.2 MPa (2 bar) (gauge pressure) and the periodic tests at 0.1 MPa (1 bar) (gauge pressure). The first hydraulic pressure test shall be carried out before thermal insulation is applied. The capacity of the shell of each tank-container intended for the carriage of gases of 3 °, 4 ° and 9 ° shall be determined, under the supervision of an expert approved by the competent authority, by weighing or volumetric measurement of the quantity of water required in order to fill the shell. The measurement of shell capacity shall be accurate to within 1 per cent. Determination by a calculation based on the dimensions of the shell is not permitted. The maximum permissible masses of filling according to marginals 2220 (4) and 211251 (3) shall be prescribed by an approved expert. All welds in the shell shall be non-destructively tested radiographically or ultrasonically. Notwithstanding the requirements of marginals 212150 and 212151, the periodic tests shall take•l)lace: (1) Every two and a half years in the case of tank­ containers intended for the carriage of boron trifluoride of 1 ° (at), town gas of 2 ° (bt), chlorine, hydrogen bromide, nitrogen dioxide, phosgene or sulphur dioxide of 3 ° (at), hydrogen sulphide of 3 ° (bt), or hydrogen chloride of 5 ° (at); (2) After six years' service in the case of tank­ containers, without safety valves, intended for carriage of gases of 7 ° (a) and 8 ° (a); (3) After eight years' service and thereafter every 12 years in the case of tank-containers fitted with safety valves and intended for the carriage of gases of 7 ° (a) and 8 ° (a) and of tank-containers intended for the carriage of gases of 7° (b) and 8° (b). A leakproofness check may be performed, at the request of the competent authority, between any two successive tests. At the periodic tests for tank-containers equipped with vacuum insulation and intended for the carriage of gases of 7 ° and 8 °, the hydraulic test may be replaced by a leakage test performed either with the gases which the tank­ containers are intended to contain or with an inert gas. If, at the time of periodic inspections, manholes are made in the shells of tank-containers intended for the 212250 212251 212252 212253 212254 212255 212256 212257 E<l>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: aEYTEPO) 1091 carriage of gases of 11 ° to 13 °, the method by which they are hermetically closed before the tank-containers are returned to service shall be one approved by the approved expert and shall ensure the intergrity of the shell. The leakproofness test of shells intended for the carriage of gases of 1 ° to 6° and 9° shall be carried out at a pressure of not less than 0.4 MPa (4 bar) and not inore than 0.8 MPa (8 bar) gauge pressure. Section 6: Marking In addition, the following particulars shall be marked by stamping or by any other equivalent method on the plate described in marginal 212160,or directly on the walls of the shell itself if the walls are so reinforced that the strength of the shell is not impaired: (1) On tank-containers intended for the carriage of only substance: the name of the gas in full. This shall be accompanied, in the case of tank­ contairiers intended for the carriage of compressed gases of 1 ° and 2 ° by the tank-containers's maximum permitted loading pressure and, in the case of tank - -containers intended for the carriage of liquefied gases of 3 ° to 8 ° and of ammonia dissolved under pressure of 9° (at), by the permissible maximum load in kg. (2) On multi-purpose tank-containers: the names, in full, of the gases for whose carriage the tank - container is approved followed by particulars of the permissible maximum load, in kg, for each of them. (3) On tank-containers equipped with safety valves and intended for the carriage of gases of 7° (a) and 8° (a), and on tank - containers intended for the carriage of gases of 7 ° (b) and 8 ° (b): the working pressure. • • . (4) On tank-containers equipped with thermal insulation the expression «thermally insulated» shall be inscribed in one of the official languages of ADR. • . The frame of a multiple - element tank-container shall be fitted near the filling point with a plate specifying: the test pressure of elements; the working pressure of elements intended for . compressed gases; . the number of elements; the aggregate capacity of the ·elements, in litres; the name of the gas in full; and, in the case of liquefied gases: the permissible maximum load per element. in kg. Section 7: Operation 212258 212259 212260 212261 212262 212269 A tank-container assigned at different times to the 212270 carriage of different liquefied gases of 3 ° to 8 ° (multi purpose tank - containers) may not carry substances other than those listed in one, and one only, of the following groups: Group 1: halogenated hydrocarbons of 3 ° (a) and 4 ° (a); Group 2: hydrocarbons of 3 ° (b) and 4 ° (b), 1,3-bytadiene of 3 ° (c) and mixtures of 1,3-butadiene and hydrocarbons of 4° (c); Group 3: ammonia of 3 ° (at); dimethyl ether of 3 ° (b); dimethylamine, ethylamine, methylamine and trimethylamine of 3 ° (bt); and vinyl chloride of 3 ° (c); Group 4: methyl bromide of 3 ° (at); ethyl chloride and methyl chloride of 3 ° (bt) Group 5: mixtures of ethylene oxide with carbon dioxide and of ethylene oxide with nitrogen of 4° (et); Group 6: gases of7 ° (a),and mixtures of gases of8 ° (a); Group 7: ethane, ethylene, and methane of 7° (b); and mixtures of ethane with methane, also when they contain propane or butane of 8° (b). Tank-containers which have been filled with a substance 212271 of group 1 or group 2 shall be emptied of liqu efied gas before being loaded with another substance belonging lo the same group. Tank-containers which have been filled with a substance of one of the groups 3 to 7 shall be completely emptied of liquefied gas and· blown down before being loaded with another substance belonging to the same group. • The multiple use of tank-containers for the carriage of 212272 liquefied gases of the same group shall be allowed-if all the requirements prescribed for the gases to be carried in one arid the same tank-container are observed. Such multiple u;e shall be subject to approval by an approval expert. The multiple use of tank-containers for the carriage of 212273 gases of different groups shall be allowed if permitted by . the approved experts. When loaded tank-containers or empty but uncleaned 212274 tank-containers are handed over for carriage, only the particulars applicable under marginal 212161 to the gas loaded or just discharged shall be visible; all particulars concerning other gases shall be covered up. All the elements of a multiple-element tank-container 212275 shall contain only one and the same gas. In the case of a multiple-element tank-container intented for the carriage of liquefied gases harmful to the respiratory organs or entailing a poison risk 141• 15/ the elements shall be filled separately and be kept isolated by a sealed valve. The maximum permissible degrees of filling in kg/litre 212276 prescribed in marginals 2219 (2), 2220 (2), (3) and (4) and 211251 (2), (3) and (4) shall be adhered to. The degree of filling of the shells of tank-containers 212277 fitted with safety valves and intended for the carriage of gases of 7 ° and 8 ° shall be such that at the «alerb• temperature, at which the vapour pressure is ~qual to the valve-opening pressure, the volume of the liquid does not exceed the permissible degree of filling of the shell at that temperature, i.e. 95 per cent in the case of inflammable gases and 98 per cent in the case of other gases. • On the shells of tank-containers intended for the 212278 carriage of oxygen of 7 ° (a), or of air or mixtures of oxygen . with nitrogen of 8 ° (a), substances containg grease or oil shall not be used to ensure leakproofness of the joints or for the maintenance of the closures. Class 3: Inflammable liquids 212279 212299 212300 Section 1: General; scope (use of tank-containers); -212309 definitions Use The following substances of Class 3 may be carried in tank-containers: 4 (a) substances listed by name in 12 °; (b) substances classified under (a) of 11 °, 14 ° to 23 °, 25 ° and 26 ° and comparable substances to be classified under (a) of those items, with the exception of isopropyl chloroformate of 25 ° (a); ( c) substances classified under (b) ~f 11 °, 14 ° to 20 °, 22° and 24° to 26° and comparable substances to be classified under (b) of those items; (d) substances of 1 ° to 6° and 31 ° to 34° and comparable substances to be classified under those items, with the exception of nitromethane of 31 ° (c). Section 2: Construction Shells intended for the carriage of substances of 12 ° shall be designed for a calculation pressure16/ of not less than 1.5 MPa (15 bar) gauge pressure. Shells intended for the carriage of the substances referred to in marginal 212310 (b) shall be designed for a 212310 212311 212319 212320 212321 1092 E<l>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: .dEYTEPO) calculation pressure16/ of not less than 1.0 MPa (10 bar) gauge pressure . Shells intended for the carriage of the substances referred to in marginal 212310 (c) shall be designed for a calculation pressure16/ of not less than 0.4 MPa (4 bar) gauge pressure. Shells intended ·for the carriage of the substances referred to in marginal 212310 ( d) shall be designed in accordance with the requirements of the general part of this Appendix. Section 3: Items of equipment 212322 212323 212324 212329 All openings of shells intended for the carriage of the 212330 substances referred to in marginal 212310 (a) and (b) shall be above the surface level of the liquid. No pipes or pipe connections 'shall pass through the walls of the shell below the surface level of the liquid. Shells shall be capable of being hermetically closed6/ and the closures shall be capable of being protected with lockable caps. Shells intended for the carriage of the substances 212331 referred to in marginal 212310 (c) and (d) may also be of the bottom-discharge type. Shells intended for the carriage of the substances referred to in marginal 212 310 ( c) shall be capable of being hermetically closed61. . If shells intended for the carriage of the substances 212332 referred to in marginal 212310 (a) and (b) or 11 ° or 14 ° to 20 ° of marginal 212310 (c) are fitted with safety valves, a bursting disc shall be placed before the valve. The arrangement of the bursting disc and safety valve shall be such as to satisfy the competent authority. If shells intended for the carriage of the substances referred to in marginal 212310 ( d) are equipped with safety valves or a venting system, these shall satisfy the requirements of marginals 212133 to 212135. Shells intended for the carriage of the substances referred to iri marginal 212310 (d) having a Hash-point not exceeding 55 °C and equipped with a venting system which cannot be closed shall have a flame-trap in the venting system. Section 4: Type approval (No special requirements). Section 5: Tests Shells intended for the carriage of the substances referred to in marginal 212310 (a), (b) or (c) shall be subjected to the initial and periodic tests at !1 gauge pressure of not less than 0.4 MPa (4 bar). • Shells intended for the carriage of the substances referred to in marginal 212310 (d) shall be subjected to the initial and periodic tests at their calculation pressure as defined in marginal 212123. Section 6: Marking (No special requirements) Section 7: Operation The degree of filling of shells intended for the carriage of the substances referred to in marginal 212310 (a) (b) or (c) shall conform to marginal 212172 (1) (d).Shells shall be hermetically61 closed during carriage. The closures of shells intended for the carriage of the substances referred to in marginal 212 310 (a) and (b) shall be protected by lockable caps. Tank-containers approved for the carriage of substances of 6°, 11 °, 12 ° and 14 ° to 20° shall not be used for the carriage of foodstuffs articles of consumption or animal feedstuffs. An aluminium-alloy shell shall not be used for the carriage of acetaldehyde of 1 ° (a) unless the shell is 16/ See marginal 212 127 (2) 212333 212339 212340 212349 212350 212351 212352 212359 212360 212369 212370 212371 212372 reserved solely for such carriage and the acetaldehyde is free from acid. From October to March, mixtures of hydrocarbons having a vapour pressure above 110 kPa (1. 1 bar) but not exceeding 150 kPa (1.5 bar) (absolute pressure) at 50°C, such as certain light distillates for cracking, may be carried in shells of the type described in marginal 212133. Class 4.1: Inflammable solids .. Class 4.2: Substances liable to spontaneous combustion Class 4.3: Substances which give off inflammable gases on contact with water. 212373 212374 212399 212400 Section 1: General; scope (use of tank-containers); -212409 definitions Use Sustances of 2 °, 8° and 11 ° of Class 4.1 and 1 °, 3 ° 212410 and 8 ° of Class 4.2, and sodium, potassium, alloys of sodium and potassium, of 1 ° (a), substances of 2 ° (e) and 4 ° Class 4.3 may be carried in tank-containers. NOTE: For the carriage in bulk of sulphur of 2° (a), naphthalene of 11 ° (a) and (b), expandable polystyrenes of 12 ° of Class 4.1, substances of 5 °, dust from blast­ furnace filters of 6° (a) and substances ofl0° of Class 4.2, and magnesium granules, coated of 1 ° (d), calcium carbide of 2° (a) and calcium silicide in lumps of 2° (d) of Class 4.3, see marginals 411, 42111 and 43111. 212411 ... 212419 Section 2: .Construction Shells intended for the carriage of white or yellow phosphorus of marginal 2 431, 1 ° or substances of 2 ° ( e) and 4 ° of marginal 24 71 shall be designed for a calculation pressure of not less than 1.0 MPa (10 bar) gauge pressure. Shells intended for the carriage of substances of marginal· 2431, 3 °, shall be designed for a calculation pressure of not less than 2.1 Mpa (21 bar) gauge pressure. Section 3: Items of equipment The shells of tank-containers intended for the carriage of sulphur of marginal 2401, 2 ° (b ), and of naphthalene of marginal 2401, 11 ° (c), shall be equipped with thermal insulation so made of materials which are not readily inflammable that the temperature on the outer surface cannot rise above 50 ° C during carriage. They may be equipped with valves opening automatically inwards or outwards under the effect of a difference of pressure of 20 kPa (0.2 bar) to 30 kPa (0.3 bar). The discharge devices shall be capable of being protected by .a lockable metal cap. The.shells of tank-containers intended for the carriage of white of yellow phosphorus of marginal 2431, 1 °, shall meet the following requirements: ( 1) The heating device shall not penetrate into the body of the shell but be fitted outside it. Other piping shall enter the shell in its upper part; openings shall be above the highest permissible level of the phosphorus and be capable of being completely enclosed under lockable caps. (2) The shell shall be equipped with a gauging system tor verigying the level of the phosphorus and, if water is used as the protective agent, with a fixed gauge mark showing the highest permissible level of the water. The openings and orifices (valves, ducts, manholes, etc.) in the shells of tank-containers intended for the carriage of substances of marginal 24 71, 1 ° (a), shall be equipped with leakproof lockable caps, and such shells shall be equipped with thermal insulation so made of materials which are not readily inflammable that the temperature on the outer surface cannot rise above 50 ° C during carriage. Shells intended for the carriage of substances of marginal 2431, 3°, or marginal 2471, 2° (e), shall not 212420 212421 212422 212429 212430 212431 212432 212433 E<J>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) 1093 have any openings or connections below the level of the liquid, even if such openings or connections are capable of being closed. In addition, the cleaning opt;nings (fistaholes) provided for in marginal 212132 shall not be permitted. Openings in the upper part of the shell, including their fittings, shall be capable of being protected .by a cap. Section 4: Type approval (No special requirements) Section 5: Tests Shells intended for the carriage of: sulphur in the molten state of marginal 2401, 2 ° (b) naphthalene in the molten state of.marginal 2401, 11 ° (c) . white or yellow phosphorus of margi~al 2431, 1 ° sodium, potassium or alloys of sodium or potassium of marginal 2471, 1 ° (a) substances of marginal 24 71, 2 ° ( e) substances of marginal 2471, 4° shall be subjected to the initial and periodic' tests at a gauge pressure of at least 0.4 MPa (4 bar) Shells intended for the carriage of substances of marginal 2431, 3 °, shall be subjected to the initial and periodic tests with a liquid not reacting with the substance to be carried, at a test pressure of 1.0 MPa (10 bar) gauge pressure. 212434 212439 212440 212449 212450 212451 The materials of every shell intended for the carriage of · substances of marginal 2431, 3 °, shall be tested by the· method described in Appendix B.ld. Shells intended for the carriage of sulphur (including 212452 flowers of sulphur) of 2 ° (a), phosphorus sesquisulphide and phosphorus pentasulphide of 8 °, crude or pure naphthalene of 11 ° (a) and (b) of marginal 2401, or of freshly-quenched charcoal of marginal 2431, 8 °, shall be subjected to the initial and periodic tests at their calculation pressure as difined in marginal 212123. Section 6: Marking 212453 212459 Shells intended for the carriage of substances of 212460 marginal 2431, 3 °, shall bear in addition to the particulars prescribed in marginal 212161 the words: "Do not open during carriage. Liable to spontaneous combustion". Shells intended for the carriage of substances of marginal 2471, 2° (e), shall bear in addition to the particulars prescribed in marginal 212161 the words: "Do not open during carriage. Gives off inflammable gases on contact with water". These partic~lars shall be in an official language of the country of approval, and also, if that language is not English, French or German, in English, French or German, unless any agreements concluded between the countries concerned in the transport operation provide otherwise. Section 7: Operation 212461 212469 The shells of tank-containers intended for the carriage .2124 70 of sulphur of marginal 2401, 2 °, shall be filled to not more than 98 per cent of their capacity. White or yellow phosphorus of marginal 2431, 1 °, 212471 shall, if water is used as the protective agent, be covered with a depth of not less than 12 cm of water at the time of filling; the degree of filling at a temperature of 60 ° C shall not exceed 98 per cent. If nitrogen is used as the protective agent, the degree of filling at -a temperature of 60 ° C shall not exceed 96per cent. The remaining space shall be filled with nitrogen in such a way that, even after cooling, the pressure at no time falls below atmospheric pressure. The shell shall be hermetically closed so that no leakage of gas occurs. ~or the carriage of substances of marginal 24 71, 1 ° (a), 212.4 72 caps shall be locked in conformity with marginal 212432 and the temperature of the outside surface of the shell shall not exceed 50°C. For trichlorosilane ( silicochloroform) of marginal 2 4 71, 2124 73 4 ° (a), or for methyldichlorosilane or ethyldichlorosilane of 4 ° (b), the degree of filling shall not exceed 1.14 or 0.95 or 0. 93 kg per litre of capacity respectively, if filling is by mass, or 85 per cent if filling is by volume. Tha. shells of tank-containers which have contained 212474 phosphorus of marginal 2431, 1 °, shall when handed over.· for carriage either: be filled with nitrogen; the sender must certify in the transport document that the tank, after closure, is gas0 tight; or be filled with water to not less than 96 per cent and not more than 98 per cent of their capacity; between 1 October and 31 March this water shall contain one or more anti-freeze agents free from corrosive action, not liable to react with phosphorus, and sufficiently· concentrated to prevent the water freezing during carriage. Tank-containers which have contained phosphorus of marginal 2431, 1 °, must be considered, as far as the • application of the provisions of marginal 42500 (1) is concerned·, as being "empty tank-containers, uncleaned". The degree of filling for shells containing substances of 2124 7 5 marginal 2431, 3 °, or marginal 24 71, 2 ° (e), shall not exceed 90 per cent; a space of 5 per cent shall remain empty for safety when the liquid is at an average • temperature of 50°C. During carriage, the substances shall be under a layer of inert gas, the gauge pressure of which shall not exceed 50 Kpa (0.5 bar). The shells shalJ be hermetically closed61 and the protective · caps conforming to marginal 212433 shall be locked. Empty. shells, uncleaned, shall when handed. over for carriige be • filled with an inert gas at a gauge pressure of up ,to 50 kPa (0.5 bar). • , Class 5 .1: Oxidizing substances Class 5.2: Organic peroxides Section 1: General; scope (use of tank-containers); definitions Use Substances of 1 ° to 3 ° and solutions of 4 °·(also moist s~dium chlorate) of Class 5 .1 and substances of 10 °, 14 ° and 15 ° of Class • 5.2 may be carried in tank­ containers. NOTE: For the carriage in bulk of substances of Class 5.1, 4 ° io 6° and 7 ° (a) and (b), see marginal 51 111. Section 2: Construction The shells of tank-containers, and their items of equipment, intended for the carriage of hydrogen peroxide or of aqueous solutions of hydrogen peroxide of marginal 2501, 1 °, or for the carriage ofliquid organic peroxides of marginal 2551, 10°, 14° and 15° shall be made of aluminium not less than 99.5 per cent pure or of suitable alloy steel not liable to cause the hydrogen peroxide or the organic peroxides to decompose. • 212476 212499 212500 212509 212510 212511 212519 212520 212521 212529 61 ~Hermetically closed shells• means shells whose openings are hermetically closed and which are not equipped with safety valves, frangible discs or other similar safety devices. Shells having safety valves preceded by a frangible disc shall be deemed to be hermetically closed. 1094 E<J>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) Section 3: Items of equipment The shells of tank-containers intended for the carriage 212530 of aqueous solutions of hydrogen peroxide containing more than 70 per cent hydrogen peroxide and of hydrogen peroxide of marginal 2501, 1 °, shall have their openings above the surface level of the liquid. In the case of solutions containing more than 60 per cent but not more than 70 per cent hydroge~ peroxide, openings below the surface level of the liquid shall be permissible. In this case the shell discharge system shall include two mutually independent shut-off devices, the first being a quick-closing internal stop-valve of an approved type and the second a sluice valve, mounted in series, one at each end of the discharge pipe. A blank flange or some other equally reliable device shall also be fitted at the outlet of each external sluice valve. The internal stop-valve shall be such that it remains . rigidly locked to the shell and in the closed position if the . pipe is wrenched off. In addition, the cleaning openings (fist-holes) referred to in marginal 212132 shall not be permitted. The connexion to the external pipe-outlets of tank- 212531 containers shall be coated with a suitable plastics material. The shells of tank-containers intended for the carriage 212532 of liquid organic peroxides of marginal 2551, 10°, 14° and 15 °, shall be equipped with a venting device fitted with a flame-trap and followed in series by a safety valve opening automatically at a pressure of 0.18 MPa (1.8 bar) to 0.22 MPa (2.2 bar) (gauge pressure). The materials of which closures liable to come into contanct with the liquid or its vapour are made shall not have a catalytic effect (spring-loaded safety valve made of aluminium-silicon alloy (silumin) or of V2A stainless steel or of a material of equivalent quality). The shells of tank-containers intended for the carriage 212533 of liquid organic peroxides of marginal 2551, 10°, 14° and 15 0, sh·au- be equipped with thermal insulation in accordance with the requirements of marginal 212234 (1). The covering and the uncovered part of the shell shall be painted white. 212534 . -212539 Section 4: Type approval (No special requirements) Section 5: Tests The shells of tank-containers intended for the carriage of hydrogen peroxide or of aqueous solutions of hydrogen peroxide, of marginal 2501, 1 °, or of liquid organic peroxides of marginal 2551, 10 °, 14 ° and 15 °, shall be tested at a pressure of 0.4 MPa (4 bar). Section 6: Marking (No special requirements) Section 7: Operation The inside of the shell of the tank-container, and all .metal parts liable to come into contact with hydrogen peroxides of marginal 2501, 1 °, shall be kept clean. No lubricant capable of combining dangerously with the substance carried shall be used for pumps, valves or other devices. The shells of tank-containers intended for the carriage of liquids of marginal 2501, 1 ° to 3 °, shall be filled to not more than 95 per cent of their capacity at a reference temperature of 15 °C. The shells of tank-containers intended for the carriage of liquid organic peroxides of marginal 2551, 10°, 14° and 15°, shall be filled to not more than 80 per cent of their capacity. Shells shall be free from impurities at the time of filling. 212540 212549 212550 212551 212559 212560 212569 212570 212571 212572 212599 Class 6.1: Toxic substances Section 1: General; scope (use of tank-containers); definitions Use The following substances of Class 6.1 may be carried in tank-containers: (a) highly toxic substances listed by name in 2° and 3; (b) highly toxic substances classified under (a) of 11 ° to 24°, 31 °, 41 °, 51 °, 55° and 71 ° to 88°, carried in the liquid state, and comparable substances or solutions to be classified under (a) of those items; (c) toxic or harmful substances classified under (b) or (c) of 11 ° to 24°, 51 ° to 55°, 57° to 68° and 71 ° to 88°, carried in the liquid state, and comparable substances or solutions to be classified under (b) or ( c) of those items; (d) toxic or harmful powdery or granular substances classified under (b) or ( c) of 12 °, 14 °, 1 7 °, 19 °, 21 °, 23 °, 24 °, 51 ° to 55 °, 5 7 ° to 68 ° and 71 ° to 88 °, and 51 ° comparable powdery or granular substances to be classified under (b) or ( c) of those items. NOTE: Fore the carriage in bulk of substances of 44° (b), 60° (c) and 63° (c) see marginal 61111. Section 2: Construction Shells intended for the carriage of substances listed by name under 2 ° and 3 ° shall be designed for a calculation pressure16/ of not less than 1.5 MPa (15 bar) gauge pressure. , Shells intended for the carriage of the substances referred to in marginal 212610 (b) shall be designed for a calculation pressure161 of not less than 1.0 MPa (10 bar) gauge pressure. . Shells intended for the carriage of the substances referred to in marginal 212610 (c) shall be designed for a calculation pressure161 of not less than 0.4 MPa (4 bar) gauge pressure. Shells intended for the carriage of the powdery or granular substances referred to in marginal 212610 (d) shall be designed in accordance with the requirements of the general part of thi~ Appendix. Section 3: Items of equipment All openings of shells intended for the carriage of the substances referred to in marginal 212610 (a) and (b) shall be above the surface level of the liquid. No pipe or pipe connections shall pass through the walls of the shell below the surface level of the liquid. Shells shall be capable of being hermetically closed61 and the closures shall be capable of being protected with lockable caps. The cleaning openings provided for in marginal 212132 shall not however be permitted for shells intended for the carriage of solutions of hydrocyanic acid of 2 °; Shells intended for the carriage of the substances referred to in marginal 212610 (c) and (d) may also be of the bottom-discharge type. The shells shall be capable of being hermetically closed6• If shells are fitted with safety valves, a bursting disc shall be placed before the valve. The arrangement of the bursting disc and safety valve shall be such as to satisfy the competent authority. Section 4: Type approval (No special requirements) 16/ See marginal 212 127 (2) 21260( 2126m 21261( 212611 21261~ 21262( 212621 212622 21623 212624 212629 212630 212631 212632 212633 212639 212640 212649 ECJ>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: ~EYTEPO) 1095 Section 5·: Tests Shells intended for the carriage of the substances referr~d to in marginal 212610 (a), (b) and (c) shall be subjected to the initial and periodic tests at a gauge • pressure of not less than 0.4 MPa (4 bar). Shells intended for the carriage of the substances referred to in marginal 212610 (d) shall be subjected to the initial and periodic tests at their calculation pressure as defined in marginal 212123. Section 6: Marking (No special requirements) Section 7: Operation The degree of filling of shells intended for the carriage of the substances referred to in marginal 212610 (a), (b) and (c) shall be in accordance with marginal 212172 (1) (d). Shells intended for the carriage of substances of 3 ° shall not be filled to more than 1 kg per litre· of capacity. Shells shall be hermetically closed6/ during carriage. The closures of shells intended for the carriage of the substances referred to in marginal 212610 (a) and (b) shall be protected with lockable caps. Tank-containers approved for the carriage of the substances referred to in marginal 212610 shall not be used for the carriage of foodstuffs, articles of consumption or animal feedstuffs. • Class 7: Radioactive substances Section 1: General; scope ( use of tank-containers); definitions Use In accordance with the applicable schedule of marginal 2703. NOTE: Only liquid or solid low-specific-activity substances, LSA (I), of marginal 2703, schedule 5, including, notwithstanding the provision in marginal 212100, natural or depleted uranium hexafluoride171 may be carried in tank-containers. Section 2: Construction Tank-containers intended for the transport of the substances reffered to in Schedule 5, with the exception of uranium hexafluoride, shall be designed for a calculation pressure of at least 04. MPa (4 bar). In the case of tank­ containers intended for the transport of uranium hexafluoride, the calculation pressure shall be fixed at 1 MPa (1 bar). When the radioactive substance is in solution or suspension in hazardous substances of other Classes and when the calculation pressures required for the tank­ containers intended for the transport of the latter substances are greater, these pressures shall be applied. Section 3: Equipment The openings of tank-containers intended for the transport of liquid radioactive substances121 shall be above the level of the liquid and no piping or pipe connection shall pass through the walls of the shell below the surface level of the liquid. • 212650 212651 212652 212659 212660 212669 212670 212671 212672 212673 212674 212699 211700 212709 212710 212711 212719 212720 212721 219729 212730 212731 212739 61 •Hermetically closed shells» means shells whose openings are hermetically closed and which are not equipped with safety valves, frangible discs or other similar safety devices. Shells having safety valves preceded by a frangibl~ disc shall be q!:!emed to be Jiermetically closed. Section 4: Type approval Tank-containers approved for the transport of 2127 40 radioactive substances shall not be approved for the transport of any other substance. Section 5: Tests• The tank-containers shall undergo, at least once every five years,· a hydraulic pressure test at a pressure of 0.4 MPa (1 bar). Notwithstanding marginal 212150, the periodic internal inspection may • be replaced by an ultrasonic test of the wall thickness conducted every two and a half years. Section 6: Marking (No special requirements) Section 7: Operation The degree of filling at the reference temperature of 15 ° C shall not exceed 93 per- cent of the total shell capac­ ity. Tank-containers which have been used for the trans­ port of radioactive substances shall not be used for the transport of other substances Class 8: Corrosive substances Section 1: General; scope (use of tank-containers); defi nitions Use The following substances of Class 8 may be carried in tank-containers: (a) substances listed by name in 6°, 7° and 24~.,land substances comparable with those of 7 °; - • (b) highly corrosive substances classified under (a) of 1 °, 2°, 3°, 10°, 11 °, 21 °, 26°, 27°, 32°, 33°, 36°, 3 7 °, 64 °, 65 ° and 66 °, carried in the liquid state, and comparable subslances or solutions to be classified under (a) of those items; . (c) corrosive or slightly corrosive substances classified under (b) or (c) of 1 ° to 5°, 8° to 11 °, 21 °, 26°, 27°, 31 ° to 39 ° , 42 ° to 45 °, 51 ° to 54 ° and 61 ° to 66 °, car­ ried in the liquid state, and comparable substances or solu­ tions to be classified under (b) or (c) of those items; 212741 212749 212750 212751 0 212759 212760 212769 212770 212771 212799 212800 212809 212810 ., (d) powdery or granular corrosive or slightly corrosive substances classified unser (b) or (c) of 22°, 23°, 26°, 27 °, 31 °, 35 °, 39°, 41 °, 45 °, 52 ° and 65 °, and compa- rable powdery or granular substances to be classified un­ der (b) or (c) of those items. NOTE: For the carriage in bulk of substances of 23 ° and lead sludge containing sulphuric acid of 1 ° (b), see marginal 81111. • Section 2: Construction 212811 212819 Shells intended for the carriage of substances listed in 212820 6 ° and 24 ° shall be designed for a calculation pressure161 of not less than 2.1 MPa (21 bar) gauge pressure. Shells intended for the carriage of bromine of 24 ° shall be pro vided with a lead lining not less than 5 mm thick or an equivalent lining. Shells intended for the carriage of substances of 7° (a) shall be designed for a calculation pressure16 pf not less • than 1.0 MPa (10 bar) and shells for the carriage of sub­ stances of 7 ° (b) and ( c) for a calculation pressure161 of not less than 0.4 MPa (4 bar). 121·under this provision, subst;n'i:es whose-kinematic viscosity at 20°C is below 25 crn2 / s shall be deemed to be liquids. 17/ For enriched uranium hexafluoride, see marginal 2703, Schedule 11. 16/ See marginal 2l 2 127 (2) 1096 ECI>HMEPlt THr KYBEPNHtEQt (TEYXOr dEYTEPO) The requirements of Appendix B. l d shall apply to the materials and construction of welded shells intended for the carriage of.hydrogen fluoride and aqueous solutions of hydrofluoric acid of 6 °. Shells intended for the carriage of the substances re­ ferred to in marginal 212810 (b) shall be designed for a calculation pressure161 of not less than 1.0 MPa (10 bar) gauge pressure. Where the use of aluminium is necessary for shells in­ tended for the carriage of nitric acid of 2 ° (a), such shells shall be made of aliminium not less than 99.5 per cent pure, in which. case, by derogation from the provisions of the paragraph above, the wall thickness need not exceed 15 mm.~ Shells intended for the carriage of the substances re­ ferred to in marginal 212810 (c) shall be designed for a calculation pressure16/ of not less than 0.4 MPa (4 bar) gauge pressure. Shells intended for the carriage of monochloroacetic acid of 31 ° (b) shall be equipped with an enamel or equiva­ lent lining if the material of the shell is attacked by that acid. Shells and their items of equipment intended for the car­ riage of aqueous solutions of hydrogen peroxide shall be made of aliminium not less than 99.5 per cent pure or of a suitable steel not causing hydrogen peroxide to decom­ pose. Notwithstanding the provisions of the first paragraph, the wall thickness need not be greater than 15 mm when the shells are made of pure aliminium. Shells intended for the carriage of the powdery or granu­ lar substances referred to in marginal 212810 (d) shall be designed in a-::cordance with the requirements of the gen­ eral part of this Appendix. Section 3: Items of equipment 212821 212822 212823 212824 212829 All openings of shells intended for the carriage of sub- 212830 stances of 6 °, 7 °, and 24 ° shall be above the surface level of the liquid. No pipes or pipe connections shall. pass thrqugh the walls of the shell below the surface level of the liquid. Tank-containers shall be capable of being hermetically closed6 and the closures shall be capable of being protected by lockable caps. In addition, the cleaning openings referred to in marginal 212132 shall not be per- • mitted. Shells intended for the carriage of the substances re- 212831 ferred to in marginal 212810 (b), (c), and (d) may also be of the bottom-discharge type. The bottom-discharge fit tings of shells intended for the carriage of the substances referred to in marginal 212810 (b) and (c) shall conform to the requirements of marginal 212131. If shells intended for the carriage of the substances re- 212832 fem:d to in marginal 212810 (b) are fitted with safety valves, a bursting disc shall be placed before the valve. The arrangement of the bursting disc and safety valve shall be such as to satisfy the competent authority. Shells intended for the carriage of sulphur trioxide of 1 ° 212833 (a) shall be thermally insulated and fitted with a heating de .vice on the outside. Shells and their service equipment intended for carriage 212834 of hypochlorite solutions of 61 ° and of aqueous solutions of hydrogen peroxide of 62 ° shall be so designed as to pre vent the entry of foreign matter, leakge of liquid or any building up of dangerous excess pressure inside the shell. 212835 212839 61 •Hermetically closed shells• . means shells whose openings are hermetically closed and which are not equipped with safety valves, frangible discs or other similar safety devices. Shells having safety valves preceded by a frangible disc shall be deemed to be hermetically closed. 16/ See marginal 212 127 (2) Section 4: Type approval (No special requirements) Section 5: Tests Shells intended for the carriage of anhydrous hydroflu­ oric acid or aqueous solutions of hydrofluoric acid of 6 ° shall be subjected to the initial and periodic tests at a gauge pressure of at least 1.0 MPa (10 bar) and those intended for the carriage of substances of 7 ° shall be subjected to in­ itial and periodic tests at a gauge pressure of not less than 0.4 MPa (4 bar). • Shells intended for the carriage of substances of 6 ° and 7 °·shall be inspected every two and a half years for resis­ tance to corrosion, by means of suitable instruments (e.g. by ultrasound). The materials of every welded shell intended for the car­ riage of hydrogen fluoride and aqueous solutions of hydro­ fluoric acid of 6 ° shall be tested by the method described in Appendix B.ld. Shells intended for the carriage of bromine of 24 ° or of the substances referred to in marginal 212810 (b) and (c) shall be subjected to the initial and periodic tests at a gauge pressure of not less than 0.4 MPa (4 bar). The hydraulic pressure test for shells intended for the carriage of sulphur trioxide of 1 ° (a) shall be repeated every two and a half years. Shells made of pure aluminium and intended for the carriage of nitric acid ~f 2 ° (a) and of aqueous solutions of hydrogen peroxide of 62 ° need be subjected to the initial and periodic tests at a gauge pressure of only-0.25 MPa (2.5 bar). The condition of the lining of shells intended for the car­ riage of bromine of 24 ° shall be inspected every year by an expert approved by the competent authority, who shall in­ spect the inside of the shell. Shells intended for the carriage of the substances re­ ferred to in marginal 212810 (d) shall be subjected to the initial and periodic tests at their calculation pressure as de­ fined in marginal 21212 3. Section 6: Marking Shells intended for the carriage of anhydrous hydroflu­ oric acid or aqueous solutions of hydrofluoric acid of 6 °, or bromine of 24 °, shall bear in addition to the particulars re­ ferred to in marginal 212160 an indication of the permissi­ ble maximum net load in kg and the date (month, year), of the most recen~ internal inspection of the shell. Section 7: Operation Shells intended for the carriage of sulphur trioxide of 1 ° (a) shall not be filled to more than 88 per cent of their ca­ pacity; those intended for the carriage of bromine of 24 ° shall be filled to not less than 88 per cent and not more than 92 per cent of their capacity or to 2.86 kg per litre of capacity. Shells intended for the carriage of anhydrous hydroflu­ oric acid or aqueous solution of hydrofluoric acid of 6 ° shall not be filled to more than 0.84 kg per litre of capacity. Shells intended for the carriage of substances of 6 °, 7 ° and 24 ° shall be hermetically closed 61 during carriage and the closures shall be protected with lockable caps. Appendix B.lc PROVISIONS CONCERNING FIXED TANKS AND DEMOUNTABLE TANKS MADE OF REINFORCED PLASTICS Notes: 1. This Appendix applies to fixed tanks and demountable tanks; it does not apply to batteries of recep­ tacles, to tank-containers, or to receptacles. 212840 212849 212850 212851 212852 212853 212859 212860 212861 212869 212870 212871 212872 212999 <l>EK 104 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) 1097 2. For receptacles, see the requirements concerning them in Ann~x A (packages). Section 1 : General provisions concerning the use and con­ struction of fixed and demountable tanks NOTE: In accordance with the provisions or marginal 10 121 (2) the carriage of dangerous substances in fixed or demountable tanks made of reinforced plastics complying with the requirements of this Appendix is permitted only where the use of such tanks for those substances is ex­ pressly authorized under marginal 213 010. Use 213000 213009 The following substances may be carried in reinforced - 213010 plastics tanks conforming to the provisions of this Appen dix: (a) Crude petroleum and other crude oils; volatile prod­ ucts from the distillation of crude petroleum and of other crude oils of 3 ° (b) of Class 3; (b) Semi-heavy products from the distillation of petro leum and of other crude oils of 31 ° (c) of Class 3; (c) Heating oils and diesel oils of 32° (c) of Class 3; (d) Solutions of 4° (a) of Class 5.1; (e) Substances of 1 ° (b) and (c), 2 ° (b) and (c), solutions of hydrochloric acid of 5 ° (b) and substances of 42 °, 61 ° and 62 ° of Class 8. Construction 213011 213099 The tanks shall comply with the following requirements 213100 of Appendix B.la: ( 1) General provisions applicable to tanks used for car­ riage of substances of all classes: Marginals211120(4),(5)and(6);211121;211122; 211 124; 211 126; 211 127 (6); 211 128; 211 130; 211 132; 211 140; 211 150 to 211 154; 211 160 and 211161;211171;211172(l)and(2);211173to2ll 178. (2) Provisions applicable to tanks used for carriage of substances of Class 3: Shells which are fitted with a vanting device not capable of being closed and which are intended for the carriage of inflammable liquids having a flash - point not exceeding 55 ° C shall have a flame - trap in the ·venting device. The leakproofness test and the internal inspection shall be performed every three years. (3) Provisions applicable to tanks used for carriage of substances of Class 8: marginal 211 834. The walls of the tank must present to material defect 213101 causing a reduction in safety. The walls of the tank must have a lasting resistance to 213102 the mechanical, thermal and chemical stresses to which they are subjected. Tank openings (1) Where the tank has one or more discharge openings 212103 below the level of the liquid, any pipe or valve fitted to such opening or openings shall be protected either by being re cessed into the tank shell or by any other means approved by the competent authority and providing equivalent pro tection. (2) The use of screwed plugs is strictly prohibited. Valves shall be of a model approved by the competent au­ thority. (3) Filling apertures shall be closed by a hermetic de­ vice. If the device projects outwards from the tank shell it shall be protected by a cap capable of withstanding wrenching stresses occurring through accidental overturn­ ing of the tank. 213104 213 119 Section 2: Materials used for the walls of the tank The walls of tanks may be made of the following materi- 213120 als: ( 1) Synthetic resin non -saturated polyester resins; epoxide resins; other resins with similar characteristics, provided that the safety of the wall is demonstrated. (2) Fibre reinforcements Glass fibres (glass of types E and C) I/ with an appropri­ ate coating, for example with a silane base or similar prod­ ucts. The glass fibres may be used in the form of cut or uncut ravings including prestressed continuous rovings or filaments, mats, surface mats or woven fabric. • (3) Additives (a) Additives necessary for the treatment of resins, for example, catalysts, accelerators, monomers, hardeners, thixotropic substances, in accordance with instructions by the manufacurer of the resin. • (b) Extenders, pigments, colorants and other products enabling the requireq properties to be obtained, for exam­ ple, the increase of fire - resistant properties, provided that . they cause no reduction in the safety of use of the walls of the tank. Section 3: Structure of the walls of the tank 213121 213 129 The external surface layer of the walls of the tan" must 213130 be resistant to atmospheric effects and also to brief contact with the substance to be ·carried. The walls of the tank and the sealed joints must satisfy 213131 the mechanical resistance requirements listed in section 4. The internal surface layer of the walls must be resistant 213132 to the lasting effects of the substance to be carried. This· • • layer must be made of reinforced resin having a minimum thickness of 1 mm. The fibres used must not reduce the chemical resistance of the layer. The inner part of the layer must be rich in resins and must have a minimum thickness of 0.2 m.m. ,. The requirements detailed in marginals 213 140 (6) and 213 1-42 (2) of section 4 must be satisfied. The finished walls must satisfy the requirements de-· 213133 tailed in marginal 213 140 (3) of section 4. The minimum thickness of the wall shall be . 213134 . 3. 5 mm if the capacity of the tank does not exceed 3 m3 5. 0 ml}I if the capacity of the tank is more than 3 m3• Section 4: Test methods and qualities required 213135 1-213 139 Tests and qualities.required for materials forthe proto- 213140 type tank (l) Taking of specimens The specimens required for the test must wherever pos­ sible be taken from the walls of the tank. For this purpose cut - out parts resulting from the making of apertures, etc. may be used. (2) Percentage of glass fibre. The test must be conducted in accordance with the methods prescribed in ISO Recommendation Rl 172 1970. The glass content of the specimen must be higher than 25 per cent and lower than 75 per cent by mass. (3) Degree of polymerization. (a) Wall in polvester resins • The residual styrene conte:-1t may not be higher than 2 per cent, calculated on the total quantity of resins. The test shall be conducted in accordance with a suitable method. 21 1/ Glass of types E and c; is defined in Table 1. 21 The method prescribed in standard DIN 16945 of June 1969, paragraph 6.4.3 is regarded as suitable. . 1098 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI .dEYTEPO) (b) Wall in epoxide resins The acetone extract may not be higher than 2 per cent calculated on the total quantity of resins. The test shall be conducted in' accordance with a suitable method. 3/ (4) Bending and tensile strength. The mechanical properties must be determined: for the shell, in the axial and circumferential directions; for the ends and walls of compartments, in any direction. If the principal directions of the reinforcement do not co­ incide with the axial and circumferential directions (for ex­ ample in the case of biaxial winding), the strength must be determined in the principal directions of the reinforcement and calculated for the axial and circumferential directions by applying the following formulae: Tensile· ··T,c T,a Bending ·-f,c ,,-f,a T = tensile 2 a T,H sin2,o( 2 a T,H cos2,/... 2 2 a F,H sin2 ~ a F,H cor<2.-/... c = circumferential a= axial H = helicoidal F = bending ex = preferential winding angle The tensile strength must be tested in accordance with the methods presC'ribed in do('ut11t•11t ISO/TC 61/WC 2/TG "Tests of glass reinforced plastics" No 4 of February ]971. • The bending strength mu~t be tested in accordance with the methods prescribed in Recommendation ISO /TC 61 No 1540 of April 1970. Requirements New tanks meet the following safety factors against rupture: Safety factor for static loading: 7.5 Safety factor for dynamic loading: 7.5 . The acceleration values to be applied in computing the dynamic load are as follows: 2 g in direction of travel; 1 g at right angles to direction of travel; 1 g vertically upwards; and 2 g vertically downwards. As the characteristics of a reinforced plastics laminate ·may vary according to its structure, minimum values are not prescribed for bending and tensile strength but for loads: A = e a T where a T is the tensile strength at break; B = e2 a F where a F is the bending strength at break; where e is the thickness of the wall The minimum values for forces A and B are: For bending: · Capacity of tank ~ 3 m3 circumferential direction axial direction Capacity of tank > 3 m3 circumferential direction axial direction For tensile: circumferential direction axial direction B B B B 600 daN 300 daN 600 daN 300 daN B = 100 daN/mm B = 70 daN/mm Module E on bending in measured at -40°C and at +60°C. The two values may not differ l:iy more than 30 per cent from the value obtained at 20 ° C. Behaviour of wall 3/ The method prescribed in standard DIN 16945 of June 1969, paragraph 6.4.2 is regarded as suitable. material during a tensile test lasting more than 1000 hours. The test tension is OT 7.5 During the test the factor K = be higher than 1.6. £1000 co may not ! 0 = elongation ofloaded specimen at begining of test ! 1000 = elongation of loaded specimen at end of test (5) Impact behaviour (a) Nature of test Impact behaviour is determined on a sample of lamimate corresponding to the structural material used for the construction of the tank. The test is carried out by drop­ ping a 5 kg steel mass onto the surface of the laminate cor­ responding to the external surface of the tank; (b) Apparatus The apparatus consists of a 5 kg steel mass, a guidance device for this mass and a specimen - bearing chassis. A general diagram of the apparatus is given in figure 1. The mass is in the form of a steel cylinder provided with two guide channels, the lower extremity being spherically shaped, 90 mm diameter The guidance device is fitted vertically to a wall. The specimen - bearer is composed of two angle - bars of 100 X 100 X 25 mm and 300 mm long, welded to a 400 X 400 mm metal support. The gap between the two bars is 175 mm. The specimen - bearer, fixed to the ground, is provided with a 50 mm cavity to allow flexion of the specimen. (c) Preparation of specimens. From the sample, three specimens are taken, each measuring 200 X 200 mm X thickness of the sample. ( d) Operating method The specimen is placed symmetrically on the specimen­ bearer; if possible it rests on the support following two ba­ sic straight lines of the surface, in such a way that the mass strikes the centre of the face of the specimen correspon­ ding to the external surface of the tank. The mass is allowed to fall from a determined height, care being taken to ensure that it does not rebound and strike the specimen a second time. The test must be conducterd at ambient temperature. The height to which the mass is raised in the guidance device is noted. The other two specimens are tested in the same way. ( e) Requirement The drop height for a 5 kg mass shall be 1 metre; the specimen must not allow leakage of more than 1 litre per 24 hours when subjected to a column of water of 1 m. (6) Resistance to chemical agents. Flat reinforced plastics test plates, prepared in the labo­ ratory, are subjected to attack by the dangerous substance at a temperature of 50°C for 30 days in accordance with the following procedure: (a) Description of the test apparatus (shown in figure 2). The test apparatus comprises a glass cylinder, diameter 140 X 150 mm, 150 mm high with two nozzles positioned at 135 ° one fitted with an NS 29 joint to take an intermedi­ ate pipe for a reflux condenser (1), the other nozzle fitted with an NS 14.5 joint to take a thermometer (2), an inter­ mediate pipe for a reflux condenser and a reflux condenser not shown in the diagram. The glassa part of the apparatus shall be in glass resistant to changes of temperature. The specimens taken from the test plates form the base and the top of the glass cylinder. They are sealed to the sides of the cylinder by a PTFE collar. The cylinder with the two specimens is clamped between two pressure plates E<l>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) 1099 in corrosion - resistant steel with six threaded bolts tight­ ened by means of wing nuts. An asbestos washer must be placed between the pressure plates and the specimens. These washers are not shown in figure 2. Heating is ef­ fected from outside by means of an automatically con­ trolled sleeve heater. The temperature is measured in the chamber containing the liquid. (b) Operation of the test apparatus. . The test apparatus allows only flat plates of uniform thickness to be tested. The test plates should, if possible, be 4 mm thick. Should these plates be covered With a gel coating, they must be tested in condition as for practical use. Six hexagonal specimens, each side measuring 100 mm, are cut from the test plate. For each test, three specimens are prepared per appara­ tus. One of these simples is used as a reference and the other two are used for checking in the liquid zone, and va­ pour zone of the device respectively. (c) Test procedure. The specimens to be tested are placed on the apparatus with the surface which may be gel- coated facing inwards. 1200 ml of test liquid is poured into the glass cylinder. The apparatus is then heated to the test temperature.· A con­ stant temperature is maintained during the test. After the test the apparatus is cooled to the ambient temperature and the test liquid removed. The specimens tested are immedi­ ately washed with distilled water. Liquids which are not sol­ uble in water are removed with a solvent which does not at­ tack the specimens. Mechanical cleaning of the plates can­ not be permormed because of the danger of damaging the surface of the specimens. (d) Evualtion A visual examination is made: if the visual examination reveals excessive attack (cracks, bubbles, pores, peeling off, swelling, or rough­ ness), the test is conclusive negatively; if the visual examination reveals no abnormality, bend­ ing tests are made by the methods specified in marginal 213 140 (4) on the two specimens subjected to chemical attack and on the reference specimen. In this case the bending strength shall not be more than 20 per cent lower than the value ascertained for the test plate not subjected to any stress. Test and quality required for the prototype unit. 213141 The prototype tank shall be subjected to a hydraulic pressure test conducted by an expert approved by the com petent authorities of a Contracting Party. . I(the prototype tank 1s divided into compartments either by bulkheads or by baffle plates, the test shall be con­ ducted on a unit made for this purpose with the same exter­ nal ends as the entire tank and which represents the part of the tank subjected, under normal conditions of use, to the greatest stresses. This test should not be conducted if there has already been a successful test on another prototype unit of the same section or a section with largher dimensions, geomet~ rically similar to that of the prototype unit in question, even if that unit has a different internal surface layer. This test must demonstrate that the prototype unit has, under normal conditions of use, a factor of not less than 7.5 so far as rupture is concerned. It must be proved, e.g. by calculation, that safety factors against fracture given in marginal2 l 3 l 40 ( 4) are complied with for each section of the tank. Rupture occurs when the test liquid escapes from the tank in the form of jets. Consequently, before this rupture, the presence of delaminations and losses ofliquid through these delaminations in the form of droplets is permitted. The prototype unit shall be submitted to a hydraulic pres­ sure. H = 7.5 x d X h where H is the height of the column of water h is the height of the tank d is the density of the substance to be carried. If a rupture occurs with a water - column height H1 less than H, there must still be HI ;;;,, 7 .5 ~ d X (h-h1) . . where h 1 is the height of the highest pomt where the first Jet of liquid appears. Should the flow of liquid at point h1 be too great, it is essential to make a temporary repair and temporary local strength~ning to enable the test to continue to height H. Conformity check on tanks produced in series. 213142 (1) The inspection of conformity on tanks produced in series shall be carried out by conducting one or more of the tests listed in marginal 213140. • However, the measurement of the degree of polymerization 1s replaced by Barcol hardness measurement. (2) Barco! hardness. The test must be conducted in accordance with suitable procedures 4/. Barcol hardness measured on the internal surface of the finished tank shall not be less than 7 5 per cent of the value obtained in the laboratory on pure hardened resin. (3) The percentage of glass fibre must be within the limits prescribed in marginal 213140 (2) and, in addition, must not deviate by more than 10 per cent of the figure for the prototype tank. Tests and qualities required for all tanks before being 213143 put into service. Leakproofness test The leakproofness test shall be conducted in accordance with the provisions of marginals 211150, 211151 and 211152 and the expert's stamp shall be applied to the . tank. 213144 213149 Section 5: Special prov1s1ons for tanks used for the carriage of substances with a flash - point of 55 ° C of lower ·. The tank must be constructed so as to ensure the 213150 elimination of static electricity from the various componenf parts so as to avoid the accumulation of dangerous electric. charges. All metal parts of the tank and the transport unit and also wall layers co~ducting electricity must be interconnected. The resistance between each conducting part and the chassis must not be higher than 106 ohms. Elimination of hazards due to charges generated by friction. The surface resistance and the discharge resistance to 213153 earth of the entire surface of the tank shall conform with the requirements of marginal 213154. The surface resistance and discharge resistance to earth 213154 measured in accordance with marginal 213155 must satisfy the following requirements. ( 1) Walls not equipped lith electrically conducting elements: (a) Surfaces upon which one can walk: The discharge resistance to earth shall not be higher than 108 ohms. (b) Other surfaces: The surface resistance shall not be higher than 109 ohms. (2) Walls equipped with electr1cally conducting elements: (a) Surfaces on which one can walk: The discharge resistance to earth shall not be higher than 108 ohms. 4/ The procedures prescribed in standard ASTM-D 2583-67 are regarded as suitable. ll00 E<DHMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) (b) Other surfaces: Conductance shall be considered as sufficient if the maximum thichkness of non-conducting layers on conducting elements, for example conducting sheets, metal netting or other appropriate material, connected to the ea11hing connexion, does not exceed 2 mm, and that in the case of a metal netting, the surface area of the mesh does not exceed 64 cm2. (3) Any measurement of surface resistance or discharge resistance to earth required to be carried out on the tank itself shall be replaced at intervals of not more than one year to ensure that the specified resistances are not exceeded. Test methods 213155 1. Surface resistance (RIO0) - (insulating resistance) in ohms, electrodes of conducting paint in accordance with figure 3 of Recommendation IEC 16 7 of 1964, measured in the standard 23/50 atmosphere according to Rec9mmendation ISO R 2 91, paragraph 3 .1 of 1963. Recommendation IEC 167 of 1964, measured in the standard 23/50 atmosphere according to Recommenda­ tion ISO R921, paragraph 3.1, of 1963. 2. The discharge resistance to earth in ohms is the ratio between the direct voltage measured between an electrode described below in contact with the surface of the lank of the vehicle and the earthed chassis of the vehicle. and the total current. • The conditioning of the specimens is the same as in par­ agraph 1. The electrode is a disc with a surface area of 20 cm2 and a diameter of 50 mm. Its close contact with the surface of the tank must be ensured, for example by using damp paper or a damp sponge or any other suitable sub­ stance. The earthed chassis of the vehicle is used as the other electrode. A direct voltage in the range of 100 volts 500 volts shall-be applied. The measurement shall be car­ ried out after the lest voltage has been applied for one min­ ute. The electrode may be placed on any point of the inter­ nal or external surface of the lank. If measuring is impossible on the lank. it may also be carried out, under the same conditions, in the laboralorv, on a specimen of the material. • Elimination of hazards due to charges generated during filling. Metallic components bon..-led lo earth shall be provided 213156 and so disposed that at any stage of the filling or emptying process there is an area of not less than 0.04 sq. metres.of earthed metal in contact with the product per cubic metre of product contained in the tank at that instant. and that no part of the product shall be more than 2.0 metres from the nearest earthed metal component. Such metallic compo nents may take the form of: (a) A metal foot valve, pipe outlet. or plate provided the total area of metal in contact with the liquid is not less than that specified, or (b) A metallic grill with wire thickness not less than l mm diameter and hole area not greater than 4 sq. centime­ tres, provided that the total area of the grill in contact with the liquid is not less than that specified. Marginal 213156 shall not apply to reinforced-plastics 213157 tanks equipped with any other system for eliminating \he hazard from charges generated during filling. provided it has been demonstrated by a practical comparative lest in accordance with marginal 213158 that the relaxation time of the charge generated within the tank during filling is equivalent to that obtained for a metal tank of comparable dimensions. • Comparative test 213158 (1) A comparative test of the electrostatic charge relaxa tion time in accordance with the conditions of test de scribed in paragraph (2) shall be carried out 011 a prototype· reinforced-plastics tank and steel lank in the following manner (see figure 3). (a) The reinforced-plastics tank shall be mounted in the same manner as it would be in use, for example, on a steel support simulating a vehicle's chassis, and shall be filled to not less than 75 per cent capacity with automotive diesel fuel, a proportion of which is passed through a suitable microfilter in such a manner that the charge density of the total flow is approximately 100 µC/m 3 • (b) The field strength in the tank vapour space shall be q1easured by a suitable continuous reading field meter mounted with its axis vertical and placed at least 20 cm from the vertical fill pipe. (c) A similar test shall be carried out on a steel lank whose width, length, breadth, and volume·are within 15 per cent of those of the reinforced-plastics tank, or on a reinforced-plastics tank of similar dimensions, coated internally with metal foil connected to earth'. (2) The following conditions of test shall be met: (a) The test shall be carried out in a covered area in conditions of relative humidity less than 80 per cent. (b) The automotive diesel fuel used in the test shall have a rest conductivity at the temperature of measurement between 3 and 5 pS/m. This shall be measured in a cell in which VT is less than or equal lo 2.5 X 106 d2 where V = applied voltage d = spacing between electrodes in metres T = duration of measurement in seconds. The rest conductivity measured on samples of the product taken from the lest tank afterf filling shall not differ in successive tests on plastics and metal tanks by more than 0.5 pS/m. (c) Filling shall be at a constant rate within the range 1 lo 2 m3 /min and shall be the same for the reinforced-plastics tank and for the steel tank. At the end of filling, the fiow should be stopped in a time which is short compared with the relaxation time for the charge in the steel lank. (cl) The charge density shall be measured by a suitable continuous reading meter (for example, a field mill type) immersed in the product and placed as close as possible to the filling pipe. (e) The supply pipes and the vertical filling pipe shall be of 10 cm internal diameter and shall terminate in a "T" type filling pipe outlet. (I) A suitable microfilter"( with an adjustable by-pass enabling the proportion of flow passing through it to be regulated, shall be fitted not more than 5 m from the filling pipe outlet. • (g) The liquid level shall not reach the bottom of the filling pipe or the field meter. Comparison of relaxation times (3) The initial value of the field strength shall be that recorded at the earliest point of time after the cessation of flow of the fuel when a smooth decay curve has been established. The relaxation time in both tests shall be expressed as the time taken for the field strength to decay from the initial value to 0.37 of the initial l'alue. (4) The relaxation time of the rei11forced-plastics tank shall not exceerl that of the steel tank. Table 1 COMPOSITION OF GLASS Glass E: Composition by mass: Silica (Si 0 2 Alumina (Alp) Lime (Ca 0) Magnesia (Mg 0) 52 lo 55 per cent 14 lo 15.5 per cent 16.5 lo 18 per cent 4 lo 5.5 per cent :,; A Rellumit 5 has bee11 found to he suitabl,·. 21315( 21399l E<l>HMEPII: THI: KYBEPNHI:EOI: (TEYXOI: aEYTEPO) 1101 Boric Oxide (B2O:1) 6.5 lo 21 per cent Fluorine (F) 0.2 lo 0.6 per cenl Ferric Oxide (Fep) < 1 per cent Titanium Oxide (Ti Oz) Alkaline Oxides (Nap+ K2O) < 1 per cent Glass C: Composition by mass: Silica (Si 0 2 63.5 lo 65 per cent Alumina (Alp) 4 lo 4.5 per cent Lime (Ca 0) 14 lo 14.5 per cent Magnesia • (Mg O} 2.5 lo 3 per cent Boric Oxidr. (B2 O:i) 5 lo 6.5 per cent Iron (Fep) 0.3 per cent Sodium Oxide (Nap) 7 to 9 per cenl Potassium Oxirle (K 2 O) 0. 7 lo 1 per cent Drvice for muturin11 impicl resistanc1 by mtans of I tphcdtally•endtd filling wei11hl i i - ------------+------------- Figure 2 Device to tffl 1tsist1nc1 td chemiul 1111nt1 STORAGE TANK , .....- F1.DW METER SCHDU.TIC LlYOUl' OF RIG FOR COll'ARJ.TIVE TEST SUPPLY PIPES "' CHARGE DENSIT'! / ME1'ER J' 1/, F!IJW BY PASS / FILLING PIPE PUMP TANK UNDER TEST REQUIREMENTS CONCERNING THE MATERIALS AND CONSTRUCTION OF FIXED WELDED TANKS, OF DEMOUNTABLE WELDED TANKS. AND OF WELDED SHELLS OF TANK-CONTAINERS FOR WHICH A TEST PRESSURE OF NOT LESS THAN 1 MPa (10 BAR) IS REQUIRED, AND OF WELDED FIXED TANKS, WELDED DEMOUNTABLE TANKS AND WELDED SHELLS OF TANK-CONTAINERS INTENDED FOR THE CARRIAGE OF DEEPLY­ REFRIGERATED LIQUEFIED GASES OF CLASS 2. ,j~-1'·...,.~ 214000 214249 (1) Shells intended for the carriage of substances of 214250 .Class 2, 1 ° lo 6° and 9°. Class 4.2. 3° or Class 8, 6°. lshall be rr.ade of steel. • (2) Shells intended for the carriage of deeply-, refrigerated liquefied gases of Class 2 shall be made of steel, aluminium, aluminium alloy. copper or copper allov. e.g., brass. However. shells made of copper or copper alloy shall be allowed only for gases containing no acetylene: ethylene, however, may contain not more than 0.005 per cent acetylene. (3) Only materials appropriate lo the lowesl and highest working temperature of the shells and of their fillings and accessories may be used. The following materials shall be allowed for Lhe 214251 manufacture of shells: (a) steels not subject lo brillle fracture al 1he lowcsl • working temperature (see marginal 214265). The following may be used: 1. mild steels (except for gases of Class 2. 7 ° and 8 °): 2. fine-grained unalloyed steels. down lo a lemperalurc of -60°C; 3. nickel steels (with a nickel content or 0.5 lo 9 per cent), down to a lempP.ralure of~ l 96 ° C. depending on the nickel content; 4. auste111l1c chrome-nickel sleels. down lo a temperature of -270°C: (b) aluminium nol less than 99.5 per c-enl pure. or aluminium alloys {see marginal 214266 ): (c) deoxidized copper nol less than 99.9 per cent pure;· or copper alloys having a copper content of over 56 per cent (see marginal 214267). (1) Shells made of steel. aluminium or alu111i11iu111 alloys 2] 4252 shall be either seamless or welded. (2) Shells made of auslenitic steel. copper or copper alloys may be hard-soldered. 1102 E<DHMEPII. THI KYBEPNHIEQI (TEYXOI dEYTEPO) The fittings and accessories may either be screwed to the 214253 shells or·be secured thereto as follows: (a) shells made of steel, aluminium or aluminium alloy: by welding; (b) shells made of austenitic steel, of copper or of copper alloy: by welding or hard-soldering. The construction of shells and their attachment to the 214254 vehicle, to the underframe or in the container frame shall be such as to preclude with certainty any such reduction in the temperature of the lo!1d-bearing components as would be likely to render them brittle. The means of attachment of shells shall themselves be so designed that even when the shell is at its lowest working temperature they still possess the necessary mechanical properties. 1. Materials and shells (a) Steel shells . 214255 214264 The materials need for the manufacture of shells and the 214265 weld beads shall, at their lowest working temperature, but at least at -20°C, meet at least the following requirements as to impact strength. • The tests may be conducted with test-pieces having either a U-shaped or a V-shaped notch. Impact strength 1L 2/ of sheet metal and Material weld beads at lowest working tem~erature J/cm2:1 J/cm2•t/ Mild steel and fine-grained 34.3 27.5 steel, killed Ferritic alloy steel Ni <5% 34.3 21.6 Ferriric alloy stell 44.1 34.3 5% ~Ni~ 9% Austenitic Cr-Ni steel 39.2 31.4 I/ Impact strengths de1enni11ed with diffen•111 1,·sl-pi,·,·,·s nre 1101 mutually comparable. 21 See.marginals 214275 lo 214277. 3 / The values •'elate lo test-pieces with " L-sl1'1p,·d 1101 .. 1, ns illustrated below. 4 / The values relate lo lesl-piec·,·s "ilh ,, \' -shapc·d 11111,·h conforming to ISO R 148. In the case of austenitic steels. only the weld bead need be subjected to an impact-strength test. For working lemperatures below -196 °C the impact­ strength test is not performed at the lowest working temperature, but at -196 ° C. (b) Shells made of aluminium ~r aluminium alloys The seams of shells shall meet the requirements lnid 214266 down by the competent authority. (c) Shells made of copper or copper allov It is not necessary to carry out tests lo determine 214267 whether the impact strength is adequate. 214268 214274 · 2. Tests (a) Impact-strength tests The impact strengths indicated in marginal 214265 214275 relate to test-pieces measuring 10 X 10 mm and having a U-shaped or a V-shaped notch. NOTES: 1. With regard to the shape of the test-piece. see marginal 214265 (table), footnotes :i; and 4/. 2. For sheets less than 10 mm but not less than 5 mm thick, test-pieces with a cross-section of 10 X e mm, where ·'e" represents the thickness of the sheet, shall be used. Such impact-strength tests generally yield higher ·values than do such tests on standard test-pieces. 3. No impact-strength test shall be carried out 011 sheets less than 5 mm thick, or on their seams. (1) For testing sheets the impact strength shall be 214276 determined on three test-pieces. Test-pieces with a U-shaped notch shall be taken at right angles to the direction of rolling and test-pieces with a V-shaped notch in the direction of rolling. (2) For testing seams the test-pieces shall be taken as follows: e ~ 10 three test-pieces from the centre of the weld: three test-pieces from the zone of deformation created by the weld (the notch shall be completely outside the melted area hut as i1ear Lo it as possible): ~XHMA i.e. six teat-pieces in all. Centt'e of weld zone of defonnatlon The test-pieces shall be so machined as lo have the maximum possible thickness. 10 < e ~20 three test-pieces from lhe centre of the weld: three test-pieces from the zcine of deformation: .g r::::s:t::::::=:,~) Centre of weld Zo~e of deformation i.e. six test-pieces in all. e > 20 Two sets of three test-pieces (one set 011 the upper face. one set on the lower face) at each of the points indicated below: u : ~ : ) Centt"e of weld I 11µ I i Zone 0€ deformation i.e. twelve ·test-pieces in all. E<DHMEPII THI KYBEPNHI:EQI (TEYXOI ~EYTEPO) 1103 (1) For sheets, the average of the three tests shall meet 214277 the minimum values indicated in marginal 214265; none of the values may be more than 30 per cent below the minimum shown. (2) For welds, the average values obtained from the test­ pieces taken at the different points, centre of weld and zone of deformation, shall correspond to the minimum values indicated. None of the values may be more than 30 per cent below the minimum indicated. (b) Determination of bending coefficient 2-14278 214284 (1) The bending coefficient k referred to in marginal 214285 214266 is defined as follo'Vs: k = 50 ~, r where e = thickness of the sheet in mm; and r = mean radius of curvature in mm of the test-piece when the first crack appears in the tension zone. (2) The bending coefficient k shall be determined for the seam. The width of the test piece shall be eaual. to 3 e. (3) Four tests shall be performed on the seam, two with the root in the compression zone (fig. 1) and two with the root in the tension zone (fig. 2); all individual values obtained shall meet the minimum-value requirements of marginal 214266. ~ ~ !J /r ~ !J /r "o lig. I fi;,2 Appendix B.2 ELECTRICAL EQUIPMENT 2U 286 219 999 The electrical equipment of vehicles shall meet the 220000 following requirements: • Requirements applicable to the electrical equipment as a whole (a) Wiring: Conduc tors shall be generously dimensioned to prevent overheating. They shall be appropriately insulated. Circuits shall be protected against excess current by fuses of automatic cut-outs. The wiring shall be firmly attached and so placed that the conductors are protected against impacts, projected stones and heat emitted by the exhaust system. • (b) 1. Battery master switch: In the case of vehicles used for the carriage of inflammable dangerous goods in tanks (fixed or demountable) or in batteries of receptacles. a switch for breaking all the electrical circuits shall be placed as close to the battery as possible. A direct or remote control system shall be installed in the driving cab and outside the vehicle. It shall be easily accessible and distinctively marked. The switch shall be openable while the engine is running without causing a dangerous surge. The electrical supply to the tachograph may, however. be provided by a circuit connected direct lo the battery. Except in the case of vehicles used for the carriage of hydrogen of Class 2, 1 °(6) and 7 °(b), or carbon disulphide of Class 3,1 °(()(), the battery master switch, the tachograph and their respective circuits shall be intrinsically safe category Ex ib for Group II B T4 (7 .8 per cent ethylene in air). In the case of hydrogen or carbon disulphide. this equipment and related circuits shall be intrinsically safe category Ex ib for Group II C (20 per cent hydrogen in air) 1/, 2. Storage batteries: If the batteries are situated elsewhere than under the engine bonnet, they shall be secured in a vented case of metal or another material of equivalent strength, with insulating inner walls. Requirements applicable to the part of the electrical equipment situated behind the driver's cab (c) The whole of this equipment shall be so designed, installed and protected as not to be able to cause ignition or short circuiting in normal conditions of use of the vehicles and as to reduce to a minimum the risk of either occurrence in the event of impact or distortion. In particular: 1. Wiring: Conductors (see (a)) shall consist of cables protected by seamless and rust-proof casings. 2. Lighting: Screw-cap bulbs shall not be used. If the lamps in the body of the vehicle are not fixed in parts of the walls or ceiling so strengthened as to protect them ag11insl any mechanical damage, they should be protected by a strong cage or grid. 220001 The inflammable gases and articles of Class 2 referred 220002 to in marginal 1025l(a) are the following: (a) Compressed gases Hydrogen of 1 °(b) Methane of 1 °(b) Carbon monoxide of l 0 (bt) Mixtures of gases of 2°(6) Synthetic gases of 2 ° (bt) Town gas of 2°(bt) Water gas of 2°(bt) (b) Liquefied gases Butane of 3 ° (b) 1-Butylene of 3 °(b) Cyclopropane of 3°(b) Dimethyl ether of 3 ° (b) Isobutane of 3°(b) Isobutylene of 3 ° (b) Propane of 3 ° (b) Propylene of 3°(b) Ethyl chloride of 3 ° (bt) . Methyl chloride of 3 ° (bt) Ethylamine of 3 ° (bt) Hydrogen sulpide of 3 ° (bt) Methylamine of 3 ° (bt) • Methyl mercaptan of 3 ° (bt) Trimethylamine of 3 ° (bt) Butadienes of 3°(c) Vinyl chloride of 3 ° ( c) Vinyl bromide of 3 ° ( c) Cyanogen chloride of 3°(ct) Ethylene oxide of 3 ° (et) Gaseous mixtures A, AO, AL B or C of 4 ° (b) Ethane of 5°(b) Ethylene ane of 5°(b) (c) Deeply-refrigerated liquefied gases The gases of 7° (b) and 8 ° (h) (d) Gases dissolved under pressure Acetylene of 9°(c) (e) Articles containing gas Aerosol dispensers of 10°(b) and (bt). I/ See European Standards EN SOO] ,I. and 50020. 220003 229999 1104 E<DHMEPII: THI: KYBEPNHIEQI (TEYXOI AEYTEPO) Appendix 8.3 (see marginal 10282) CERTIFICATE OF APPROVAL FOR VEHICLES CARRYING CERTAIN DANGEROlJS GOODS 1. CERTIFICATE NO. 230000 239999 2. testifying that the vehicle specified below fulfils the conditions prescribed by the European Agreement concerning the International Carriage of Dangerous Goods by Road (ADR) for its acceptance for the international carriage of dangerous goods by road. 3. Valid until ... : .. ......................... . 4. This certificate must l..,e returned to the issuing service when the. vehicle is taken out of service; if the vehicle is transferred to another owner; on expiry of the validity of the certificate; and if there is a material change in one or more essential characteristics of the vehicle. 5. Type of vehicle: chloseJ vehicle, open vehicle. Lank­ vehicle with/without closed/open trailer/semi-trailer (strike out words which do not apply) ......... . 6. Name and business address of carrier (owner) ... 7. Registration number (if none: chassis number) .. . 8. The vehicle descrihed abov~ has undergone at .. . the in~pe~l~n· presuibed by ADR. Annex B, marginal 10282 and fulfills the conditions required for its acceptance for the international carriage by road of dangerous goods of Classes ................. . item numbers 9. Remarks ............................... . 10. 19 .... 11. Signature and stamp of issuing service al .................. . 12. The validity of this certificate is extended until .. . 13. Signature and starnp of issuing service at ............. •· .... . 14. The validity of this certificate is extended until .. . 15. Signature and stamp. of issuing service at .................. . 16. The validity of this certificate is extended until .. . 17. Signature and stamp of issuing service al .................. . NOTES: 1. The dimensions of the certificate shall be 210 X297 mm (format A 4). Both front and back shall be used. The colour shall be white, with a pink diagonal stripe. 2. Every trailer shall be the subject of a separate certificate unless it is covered by the certificate of the vehicle lo which it is coupled. 3. Where a certificate is issued pursuant lo article 4. paragraph 2, of the Agreement to a vehicle whose construction does not entirely conform to the requirements laid down in Annex B, the certificate's validity shall not extend beyond the duration of the derogation granted by the said article 4, and the text of paragraph 8 of the certificate of approval shall be replaced by the following: "the vehicle described above does nto entirely conform Lo • the requirements laid riown in Annex B, but is entitled Lo the benefit of the provisions of article 4, paragraph 2. of the Agreement". Appendix 8.4 TABLES CONCERNING THE CARRIAGE OF DANGEROUS SUBSTANCES OF CLASS 7; LABEL TO BE PLACED ON VEHICLES CARRYING THESE SUBSTANCES The minumum distances indicated in the table below ·240000 between radioactive substances and areas on vehicles reserved for the .driving and accompanying personnel are compatible with the provisions of marginal 3659(8). Minimum distances in metres, 110 shielding material intervening, from living accommodations or regularly occupied working space Total sum of transport Applicable dat~ in the case of index exposure time nol exceeding 250 hours· per annum Less than 2 1.0 2 lo 4 1.5 4 lo 8 2.5 8 lo 12 3.0 12 lo 20 4.D 20 lo 30 5.0 30 to 40 5.5 40 lo 50 6.5 The minimum safety distances referred lo in marginal 240001 365 7 for the loading and storage of packages which bear a label "FOTO" together with packages ·of Category II YELLOW or Category III - YELLOW are given in the following table. Separation distances for the loading and the storage of packages which bear a label with the word FOTO together packages of Categories II - YELLOW or III - YELLOW. <l>EK 104 EG>HMEPII: THI: KYBEPNHI:EOI: (TEYXOI: ~EYTEPOf 1105 Total sum of the Total ·, packages of the sum of category the trans- • port YELLOW YELLOW index III II 1 2 0.2 0.5 0.5 0.5 0.5 0.5 1 1 0.5 0.5 2 2 0.5 1 4 4 1 1 8 8 1 1.5 1 10 10 ] 2 20 20 l.S 3 30 30 2 4 40 40 3 5 50 50 3 The label to be affixe<l Lo the walls of vehicles pursuant 240010 to the provisions of marginals 3659(6) and 71500(2) shall conform to the model No. 70 reproduced below: (Minimum length of side: 15 cm) Symbol and inscription black on white ground Appendix 8.5 240011 249999 List of substances and identification numbers 250000 (1) The hazard identification number consists of two or three figures. In general, the figures indicate the following hazards: 2 Emission of gas due lo pressure or to chemical reaction 3 Inflammability of liquids (vapours) and gases 4 Inflammability of solids 5 Oxidizing (fire-intensifying) effect 6 Toxicity 8 Corrosivity 9 Risk of spontaneous violent reaction Doubling of a figure indicates an intensification of that particular hazard. Where the hazard associated with a substance can be adequately indicated by a single figure, this is followed by a zero. The following combinations of figures, however, have a special meaning: 22, 333, 423, 44 and 539, see (2) below. 2 3 3 4 4 Journey or storage duration, in hours 4 10 24 48 120 Minimum distances in metres 0.5 0.5 1 1 2 0.5 1 1 2 3 1 1 2 3 5 1 1.5 3 4 7 1.5 3 4 6 9 2 4 6 8 13 3 4 7 9 14 4 6 9 13 20 5 7 11 16 25 5 8 13 18 30 6 9 14 20 32 If a hazard identification number is prefixed by the letter "X", this indicates that the substance will react dangerously with water. 20 • 22 223 225 23 (2) The hazard identification numbers listed in paragraph (3) have the following meanings: inert gas refrigerated gas refrigerated inflammable gas . refrigerated oxidizing (fire-intensifying) gas inflammable gas • inflammable gas, toxic 240 3 5 7 9 13 18 20 30 35 40 45 240002 240009 236 239 inflammable gas, whi ch can spontaneously· •• 25 26 265 266 268 286 30 33 X333 336 338 X338 339 39 40 X423 44 446 46 50 539 558 lead to violent reaction • oxidizing (fire-intensifying) gas ·toxic gas toxic gas, oxidizing (fire-intensifying) highly toxic gas toxic gas, corrosive corrosive gas, toxic inflammable liquid (flash-point between 21 °C and l00°C) highly inflammable liquid (flash-point below 21 °C) spontaneously inflammable liquid, which reacts dangerously with water highly inflammable liquid, toxic highly inflammable liquid, corrosive highly inflammable liquid, corrosive, which reacts dangerously with water highly inflammable liquid which can spontaneously lead to violent reaction inflammable liquid, which can spontaneously lead Lo violent reaction inflammable solid inflammable solid which reacts dangerously with water, emitting inflammable. gases inl1ammable sblid, in the molten slate at an elevated te~peratilre inflammable solid, toxic, in the molten state, at an elevated temperature . inflammable solid, toxic oxidizing (fire-intensifying) substance inflammable organic peroxide strongly oxidizing (fire-intensifying) substance, corrosive 1101> t:Cl>HMEPl:i THI: KYBEPNHI:EQI: (TEYXOI: ~EYTEPO) 559 589 60 63 638 66 663 68 69 80 X80 83 839 85 856 86 88 X88 883 885 strongly oxidizing (fire-intensifying) substance, which can spontaneously lead to violent reaction oxidizing (fire-intensifying) substance, corrosive, which can spontaileously lead to violent reaction toxic or harmful substance toxic or harmful substance, inflammable (flash-point between 21 °C and 55 °C) toxic or harmful substance, inflammable (flash-point between 21 °C and 55 °C), corrosive highly toxic substance highly toxic substance, inflammable .(flash-· p~int not above 55 °C) toxic or harmful substance, corrosive toxic or harmful substance, which can spontaneously lead to violent reaction corrosive or slightly corrosive substance corrosive or slightly corrosive substance, which reacts dangerously with water corrosive or slightly corrosive substance, inflammable (flash-point between 21 °C and 55 °C) • corrosive or slightly corrosive substance, inflammable (flash-point between 21 °C and 55 °C) which can spontaneously lead to violent reaction corrosive or slightly corrosive substance, oxidizing (fire-intensifying) corrosive or slightly corrosive substance, oxidizing (fire-intensifying) and toxic corrosive or slightly corrosive substance, toxic highly corrosive substance highly corrosive substance, which reacts danp;erously with water highly corrosive substance, inflammable (flash-point between 21 °C and 55°C) highly corrosive substance, oxidizing (fire­ intensifying) Name of substances (a) Acetal (l,1-Diethoxyethane) Acetaldehyde (Aldehyde) Acetic acid glacial and aqueous solutions of ace tic acid containing 'more than 80 per cent pure acid Acetic acid containing from 50 to 80 per cent pure acid Acetic anhydride Acetoin (Acetylmethylcarbinol) Acetone Acetone cyanohydrin Acetonitrile • Acetyl acetone: see Pantan -2, 4-dione Acetyl bromide Acetyl cloride Acetylene tetrabromide: see 1, 1,2.2-Tetrabrorn oethane Acetylene tetrachloride: see 1, 1.2.2-Tetrachlor oethane Acetylmethylcarbinol: see Acetoii1 Acrolein Acrylamide Acrylamide, solutions of Acrylic acid Acrylonitrile Adiponitrile Class and item number (b) 3, 3 °(b) 3. 1 °(a) 8. 32°(b) 8,32°(c) 8, 32°(6) 3,31°(c) 3, 3 °(6) 6.1, 11 °(a) 886 X886 89 highly corrosive substance, toxic highly corrosive substance, toxic, which reacts dangerously with water corrosive or slightly corrosive substance, which can spontaneously lead .to violent reaction .(3) The identification numbers referred to in marginal 10500 are listed in tables I and II below. NOTES 1. The identification numbers to be shown on the orange plates should be looked for first in table I. If in the case of substances of" Classes 3, 6.1 and 8 the name of the substance to be carried or the collective heading which covers it is not listed in table I, the identification numbers are to be taken from table II. 2. The danger labels prescribed under marginals 10130 and 10500 (6) take precedence over the labelling indicated in column (e) of tables I and II. Appendix B.5 Table I Substances listed under their chemical names or under collective headings which are given a specific «substances • identification number» (column (d)). For. solutions and mixtures of substances, see also marginal 2002 (8) and (9). This table also includes substances not shown in the class lists of substances, but which nevertheless fall within the classes and item numbers shown in column (b). For substances of Classes 3, 6.1 and 8 not included in this table, see table II. Substances are listed in alphabetical or-' der. The sign «++» in column (e) means: Labelling of tank containers and ba1teries of receptacles to be in accordance with the requirements in marginal 21130, labelling of veh­ icles with fixed or demountable tanks to be in accordance with the requirements of marginal 21500. The sign«-» in column (e) means: No label prescribed. Hazard ldentifi- Substance Identi cation No fication No Label (upper part) (lower part) (c) (d) (e) 33 1088 3 33 1089 3 83 2789 8+3 80 2790 8 83 1715 8+3 30 2621 3 33 1090 • 3 66 1541 6.1 3, ll 0 (6) . 336 1648 3 + 6.1 8. 36°(6) 80 1716 8 3. 25°(6) X338 1717 3+8 3,.] 7°(a) 336 1092 3 + 6.1 6.1.12°(c) 60 2074 6.lA 6.1, l2°(c) 60 2074 6.lA 8;32°(b) 89 2218 8+3 3.ll 0 (a) 336 1093 3 + 6.1 6.1, l2°(c) 60 2205 6.lA E<l>HMEPII: THI: KYBEPNHl:EQI: (TEYXOI: .dEYTEPO) 1107 Name of substances Class and Hazard' Identifi- Substance Identi item cation No fication No Label " number (upper part) (lower part) (a) (b) (c) (d) (e) Air, liquid, deeply-refrigerated 2. 8°(a) ·225 -1003 5 Alcohols, liquid, non-toxic, pure or in mixtures. not otherwise specified in this Appendix having a flash-point between 21 ° C and 55 ° C (limit values included) 3,31°(c) 30 1987 3 having a flash-point above 55 ° C 3. 32°(c) 30 1987 Aldehyde: see Acetaldehyde Aldehydes, not otherwise specified in this Appendix 1989 3 - having a flash-point below 21 ° C 3. 3 °(6) 33 having a flash-point between 21 ° C and 55 ° C (limit values included) 3.31°(c) 30 1989 3 having a flash-point above 55 ° C 3. 32°(c) 30 1989 Aldo\ (beta-Hydroxybutyraldehyde) 6.1. 13°(6) 60 2839 6.1 Alkaline inorganic substances, solutions of. not otherwise specified in this Appendix corrosive 8.42°(6) 80 1719 8 slightly corrosive 8.42°(6) 80 1719 8 Alkyl phenols, with C.,-C, 1 chains. not otherwise specified in this Appei1dix 6.1. l4°(c) 60 2430 6.lA Alkyl sulphonic acids, not otherwise specified in this Appendix containing more than 5 per cent free sulphuric· acid, 8. l 0(b) 80 2584 8 containing not more than 5 per cenl free sulphuric acid, corrosive 8. 34°(6) 80 2586 8 containing not more than 5 per cenl free sulphuric acid, slightly corrosil'e 8. 34°(6) 80 2586 8 Ally) acetate ~- 17°(6) 336 2333 ~ t 6.1 Ally! Alcohol 6.1. l3°(a) 663 1098 6.1 +3 Allylamine 3. l5°{a) 336 2334 3 + 6.1 Ally! bromide 3, l6°{a) 336 1099 3 + 6.1 Ally! chloride 3, l6°(a) 336 1100 3 + 6.1 Ally! chloroformate 8, 64°(a) 88 1722 8 Ally\ ethyl ether 3.17°(6) 336 2235 3 + 6.1 Ally! formate 3.17°(a) 336 2236 3 + 6.1 Ally! glycidyl ether {l-Allyloxy-2. 3-epoxv propane) 3.31°(c) 30 2219 3 Ally! isothiocyanale 6.1 20°{6) 69 1545 6.1 +3 · l-Allyloxy-2. 3-epoxypropane: see Ally! glycid ether Ally! trichlorosilane 8. 37°(6) 839 1724 4.2 + 4.3 Aluminium alkyl halides ,k2. 30 X333 2221 4.2 + 4.3 Aluminium alkyl halides solutions of 4.2. 30 X333 2220 4.2 + 4.3 Aluminium alkyls: Aluminium triethvl 4.2. 30 X333 1102 4.2 + 4.3 Aluminium triisobutyl 4.2, 30 X333 1930 4.2 + 4.3 Aluminium trirnethyl 4.2. 30 X333 1103 4.2 + 4.3 Aluminium bromide, anhydrous 8, 22°(6) 80 1725 8 Aluminium bromide, aqueous solutions of 8. 5 °(c)• 80 2580 8 Aluminium chloride, anhydrous 8. 22°(c) 80 1726 8 Aluminium chloride, aqueous solutions of 8. 5 °(c) 80 2581 8 N-Aminoethylpiperazine 8. 53°(c) 80 2815 8 Aminophenols 6.1. l2°(c) 60 2512 6.lA Ammonia 2. 3°(at) 268 1005 ++ Ammonia dissolved in water containing more than 40 per cent but not more than 50 per cent ammonia by mass 2. 9°(at) 268 2073 ++ Ammonia dissolved in water containing more than 35 per cent but. not more than 40 per cent ammonia (NH) by mass 2. 9°(at) 268 2073 ++ Ammonia solutions containing not less than JO per cent and not more than 35 per cent ammonia 8.43°(c) 80 2672 8 Ammonium bifluoride 8. 26°(b) 80 1727 8 + 6.1 Ammonium bifluoride. solutions of 8.26°(6) 80 2817 8 + 6.1 Ammonium bisulphate containing 3 per cent or more free sulphuric acid 8. 23°(6) 80 2506 8 lH,u 1,;\U, ,MEPIL I HL "Y81:t-'NH2.t:Ul. ( I t:YXUL ~EYTEPO) Name of substances Class and Hazard ldentifi- Substance Identi item cation No fication No Label number (upper part) (lower part) (a) (b) (c) (d) (e) Ammonium fluoride 6.1. 65°(c) 60 2505 6.lA Ammonium nitrate. hot concentrated aqueous solutions of 5.1. 6°(a) 589 2426 5+8 Ammonium polysulphide. solutions of 8.45°(6) 86 2818 8 Ammonium silicofluoride 6.1. 66°(c) 60 2854 6.lA Ammonium sulphide, solutions of 8. 45°(6) 86 2683 8 Amyl acetates 3,31°(c.) :rn 1104 3 n-Amyl alcohol 3.31°(c) 30 1105 3 sec-Amyl alcohol 3.31°(c) 30 1105 3 Amyl alcohol, tertiary 3. 3 °(6) 33 1105 3 n-Arnylamine 3. 22°(6) 338 1106 3+8 Amyl butyrates 3.31°(c) 30 2620 3 Amyl chloryde 3. 3 °(b) 33 1107 3 Amylene, normal (1-Pentene) 3. 1 °(a) 33 1108 3 Amyl mercaptan 3. 3 °(b) 33 1111 3 Amyl methyl ketone 3,31°(c) 30 1110 3 Amyl nitrate 3,31°(c) 30 1112 3 Amyltrichlorosilane 8. 37°(6) 80 1728 8 Aniline 6.1, 11 °(6) 60 1547 6.1 Anisidines 6.1, l2°(c) 60 2431 6.lA Anisole: see Phenyl methyl ether Anisoyl chloride 8. 35°(6) 80 1729 8 Antimony pentachloride (SbCI,) 8.21°(6) 80 1730 8 Antimony pentachloride. non aqueous solutions of 8. 21 ° (b) 80 1731 8 Antimony pentafluoride 8. 26°(6) 86 1732 8 + 6.1 Antimony trichloride (SbCI) 8.22°(6) 80 1733 8 Argon, liquid, deeply-refrigerated 2. 7°(a) 22 1951 Arsenic acid, liquid 6.l.51°(a) 66 1553 6.1 Arsenic acid. solid 6.1. 51 °(6) 60 1554 6.1 Arsenical compounds. liquid. inorganic. not otherwise specified in this Appendix 6.l.51°(a) 66 1556 6.1 Arsenic bromide 6.1. 51 °(6) 66 1555 6.1 Arsenic chloride 6.1. 51 °(a) 66 1560 6.1 Arsenic pentoxidc 6.1. 51 °(6) 60 1559 6.1 Arsenic trioxide (white arsenic) 6.1. 51 °(6) 60 1561 6.1 Aryl sulphonic acids, not otherwise specified in this Appendix containing more than 5 per cent free sulphuric acid 8. 1 °(b) 80 2584 8 containing not more than 5 per cent free sulphuric acid, corrosive 8. 34°(6) 80 2586 8 containing not more than 5 per cent free sulphuric acid, slightly corrosive 8. 34°(c) 80 2586 8 Barium carbonate 6.1. 60°(c) 60 1564 6.lA Barium· oxide 6.1. 60°(c) 60 1884 6.lA Benzene 3. 3 °(b) 33 1114 3 Benzene sulphonyl chloride 3. 36°(c) • 80 2225 8 .Benzonitrile 6.l. ll 0 (b) 60 2224 6.1 Benzoquinone 6. Ll4°(b} 60 2587 6.1 • Benzotrichloride (Trichloromethylbenzene) 8. 66°(6) 80 2226 8 Benzotrifluoride 3. 3 °(6) 33 2338 3 Benzoyl chloride 8. 36°(6) 80 1736 8 Benzyl bromide 6.1. 15°(6) 60 1737 6.1 Benzyl chloride 6.1. 15°(6) 68 1738 6.1 Benzyl chloroformate 8, 64°(a) 88 1739 8 ,,, .. Benzyl cyanide (Phenylacetonitrile) 6.1. l2°(c) 60 2470 ·6.lA Benzyl dimethylamine 8. 53°(6) 83 2619 8+3 Benzylidene chloride . 6.1, 17°(6) 68 1886 6.1 Bicycloheptadiene 3. 3 °(b) 33 2251 3 Bis-aminopropylamine (Dipropylenetriar;1ine. 3. 3-Iminobisporylamine) 8. 53°(c) 80 2269 8 1,2-Bis (dimethylamino)ethane (Tetramethylene diamine) 3, 31 °(c) 30 2372 3 Boron tribromide (Boron bromide) (BBr;i) 8.21°(a) X88 2692 ·8 BorQn trif11Joride acetic acid complex 8. 33 °(6) 80 1742 8 Boron trifluoride ether complex 8.33°(6) 83 2604 8+3 . ECJ>HMEPII THI KYBEPNHIEQr (TEYXOr ~EYTEPO) 1109 ~ Name of substances Class and Hazard ldentifi- Substance ldenti item cation No fication No Label number (upper part) (lower part) (a) (b) (c) (d) (e) Boron trifluoride propionic acid complex 8, 33 °(b) 80 1743 8 Boron trifluoride dihydrate 8, 33°(b) 80 2851 8 Bromine 8,24° 886 1744 8 + 6.1 Bromine pentafluoride 8, 26°(a) 856 J745 8 + 6.1 Bromine trifluoride 8, 26°(a) 856 1746 8 + 6.1 Bromoacetic acid 8. 31 °(b) 80 1938 8 Bromoacetone 6.L l6°(b) 60 1569 6.1 omega-Bromoacetophenone: see Pheiiacyl bromide • 8. 36°(b) X80 2513 8 Bromoacetyl bromide 8,36°(6) X80 2513 8 Bromobenzene 3,31°(6) 30 2514. 3 alpha-Bromo6enzyl cyanide 6.1, l7°(a) 66 1694 6.1 2-Bromobutane 3. 3 °(b) 33 2339 3 Bromochlorodifluoromethane (R 1281) 2. 3 °(6) 20 1974 Bromochloromethane 6.1, l5°(b) 60 1887 6.1 l-Bromo-3-chloropropane 6.1, l5°(c) 60 2688 6.lA 2-Bromoethyl ethyl ether 3, 3 °(6). 33 2340 3 Bromoform 6.1, l5°(c) 60 2515 6.lA l-Bromo-3-methylbutane 3, 3 °(6) ;33 2341 3 Bromomethylpropanes 3. 3 °(6) 33 2342 3 2-Bromopentane 3. 3 °(b) 33 2343 3. Hromopropanes 3. 3 °(6) 33 2344 3 Bromotrifluoromethane (R 13 B 1) 2. 5 °(a) 20 1009 Butadienes 2. 3 °(a) 239 1010 3 Butane 2, 3 °(6) 23 1011 3 Butanedione (Diacetyl) 3. 3 °(6) 33 2346 3 Butanol: see n-Butyl alcohol n-Butanol-2: see sec-Butyl alcohol Butanol, tertiary (tertiary Butyl alcohol) 3. 3 °(6) 33 1120 3 1-Butene: see 1-Butylelie -,1-.,~~ cis-2-Butene: see cis-2-Butylene trans-2-Butene: see trans-2-Butylene Butoxyl (Methoxy6utyl acetate) 3.31°(c) 30 2708 3 n-Butyl acetate 3.31°(c) 30 1123 3 Butyl acetate, secondary 3. 3 °(6) 33 1123 3 Butyl acid phosphate 8, 38°(c) 80 • 1718 8 n-Butyl acrylate 3.31°(c) 39 2348 .3 n-Butyl alcohol (Butanol) 3.31°(c) 30 1120 3 sec-Butyl alcohol (n-Butanol-2) 3. 31 °(c) 30 1120 3 Butyl alcohol, tertiary: see Bulanol, tertiary n-Butylamine 3,22°(b) 338 1125 3+8 N-Butyla11ilines 6.1. 12°(6) 60 2738. 6.1 Butyl • benzenes 3.31°(c) 30 2709 3 Butyl bromide, normal 3. 3 °(b) 33 1126 3 Butyl chlorides (Chloro6utanes) 3. 3°(6) 33 1127 3 n-Butylchloroformate 6.1, 16°(6) 638 2743 6.1 + 3 + 8 tert-Butylcyclohexylchloroformate 6.1. l 7°(c) 68 2747 6.lA + 8 i-Butylene (I-Butene) 2, 3°(6) 23 1012 3 cis-2-Butylene (cis-2-Butene) 2. 3 °(6) 23 1012 3 trans-2-Rutylene (trans-2-Butene) 2. 3 °(6) 23 1012 3 n-Butyl ether: see Di-n-6utyl ether n-Butyl formate 3. 3 °t6) 33 1128 3 N,n-Butyl imidazole 6.1. 12°(6) 60 2690 6.1 Butyl isocyanate, normal 3, 14°(6) 336 2485 3 + 6.1 Butyl isocyanate, tertiary 3, l4°(a) 336 2484 3 + 6.1 • Butyl mercaptan 3. 3 °(6) 33 2347 3 n-Butyl methacrylate 3.31°(c) 39 2227 3 Butyl methyl ether 3. 3 °(b) 33 2350 3 ~utylphenols, in the molten stale 6.1. l4°(c) 60 2229 6.lA Butylphenols, liquid 6.1. l4°(c) 60 2228 6.lA Butyl propionate 3.31°(c) 30 1914 3 Butyl toluenes 3. 32°(c) 30 2667 Butyltrichlorosilane 8. 37°(6) 83 1747 8+3 Butyl vinyl ether 3. 3°(6) 339 2352 3 2-Butyne: see Crotonylene Butyraldehyde 3. 3 °(b) 33 11-29 3 Butyraldoxime 3.32°(c) 30 2840 n-Butyric acid 8.32°(c) 80 2820 8 1110 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) Name of substances Class and Hazard Identifi- Substance Identi item cation No fication No Label number (upper part) (lower part) (a) (b) (c) (d) (e) Butyric anhydride 8. 32°(c) 80 2739 8 Butyronitrile 3.11°(6) 336 2411 3 + 6.1 Butyryl chloride 3.25°(6) 338 2353 3+8 Caesium hvdroxide 8. ,~1 °(b) 80 2682 8 Caesium hydroxide. aqueous solutions· or 8. 42°(b) 80 2681 8 Calcium arsenate 6.1. 51 °(6) 60 1573 6.1 Calcium chlorate, solutions of 5.1. 4°(a) 50 2429 5 Carbon dioxide 2. 5 °(a) 20 1013 Carbon dioxide. liquid. deeply-refrigerated 2. 7°(a) 22 2187 Carbon rlioxide containing not more than 6 per cent ethylene oxide by mass 2. 6°(c) 239 1952 ++ ·Carbon dioxide containing more than 6 per cent but not more than 35 per cent ethylene oxide by mass 2. 6°(c) 239 1041 ++ Carbon dioxide containing not less than l per cent and not more than 10 per cent oxygen by mass 2. 6°(a) 20 1014 Carbon disulphide 3. l8°(a) 336 1131 3 + 6.1 Carbon tetrabromide 6.1. l5°(c) 60 2516 6.lA Carbon tetrachloride 6.1. 15°(6) 60 1846 6.1 Caustic potash: see Potassium hydroxide Caustic soda: see Sodium hydroxide Chloral: see Trichloroacetaldehyde Chlorine 2. 3°(at) 266 1017 ++ Chloroacetaldehyde Cd. l6°(b) 60 2232 6.1 Chloroacetic acid (Monochloroacetic acid). solid 8. 31 °(b) 80 1751 8 Chloroacetic acid (Monochloroacetic acid). in tlw molten state 8.31°(6) 80 1750 8 Chloroacetic acids, mixtures of 8.32°(6) 80 1750 8 Chloroacetic acid. (Monochloroacetic acirl). sol utions of ,. 8. 32°(6) 80 1750 8 Chloroacetone 6.1. l6°(b) 60 16~5 6.1 omega-Chloroacetophenone: see Phenacyl chloride Chloroacetvl chloride • 8. 36°(6) X80 1752 8 Chloroanisidines • 6.l.17°(c) 60 2233 6.lA Chlorobenzene (Phenyl chloride) 3.31°(c) 30 1134 3 Chlorobenzotrifluorides 3.3l 0 (c) 30 2234 3 Chloro6enzvl chlorides 6.1. l 7°(c) 60 2235 6.lA Chloro6uta;1es: see Butyl chlorides Chlorocresols 6.1. 14°(6) 60 2669 6.1 l-Chloro-1. 1-difluoromethane (R 142b) 2. 3 °(6) 23 2517 ++ Chlorodifluoromethane (R 22) 2. 3 °(b) 20 1018 Chlorodinitrobenzene 6.1. 12°(6) 60 1577 6.1 2-Chloroethanol: see Ethylene chlorohydrin Chloroform 6.1. 15°(6) 60 1888 6.1 • Chloromethvlchloroformate 6.1. 16°(6) 638 2745 6.1 + 3 + 8 Chloromethyl ethyl ether 3. 16°(6) 336 2354 3 + 6.1 3-Chroro-4-methylphenyl isocyanate 6.1. 19°(6) 60 2236 6.1 Chloronitroanilines 6.1. l 7°(c) 60 2237 6.lA Chloronitrobenzenes 6.1. l2°(b) 60 1578 6.1 Chloronitrotoluenes 6.1. l7°(c) 60 2433 6.lA Chloropentafluoroethane (R 115) 2 .. 3 °(a) 20 1020 2-Chlorophenol 6.1, l6°(c) 68 2021 6.lA 3-Chlorophenol 6.1. l 7°(c) 60 2020 6.lA 4-Chlorophenol 6.1. l 7°(c) 60 2020 6.lA Chlorophenyl trichlorosilane 8. 37°(b) 80 1753 8 Chloropicrin 6.L l6°(a) 66 1580 6.1 Chloroprene 3. 16°(a) 336 1991 3 + 6.1 1-Chloropropane (Propyl chloride) 3 2 °(6) 33 1278 3 2-Chloropropane (lsopropyl chloride) 3. 2°(b) 33 2356 3 3-Chloropropane-1. 2-diol: see Glycerol alpha monochlorohydrin 3-Chloro-l-propanol 6.1. l6°(c) 60 2849 6.lA l-Chloro-2-propanol 6.1. l6°(b) 63 2611 6.1 + 3 2-Chloropropene 3. 1 °(a) 33 2456 3 .. 2-Chloropropionic acid 8.32°(c) 80 2511 8 2-Chloropyridine 6.1. 11 °(6) 60 2822 6.1 E<J>HMEPlr THI: KYBEPNHI:EQI: (TEVXOr ~EYTEPO) 1111 Name of substances Class and Hazard. ldentifi- Substance Identi item cation No fication No Label number ( upper part) (lower part) (;i) (b) (c) (d) (e) Chlorosilanes which do not give off innanunable gases on contact with water. not otherwise speci fied iri this Appendix 3.2l 0 (a) X338 2985 3+8 having a flash-point below 2] ° C 3.2l 0 (a) X338 2985 3+8 having a flash-point between 21 °C and 55°C (limit values included) 8. 37°(6) 83 2986 8+3 having a flash-point above 55 °C 8. 37°(b) 80 2987 8 Chlorosulphonic acid (SOz(OH)CI) 8.2l 0 (a) 88 1754 8 Chlorotoluenes 3.3] 0 (c) :rn 2238 3 Chlorotoluidines 6.1. l 7°(c) 60 2239 6.lA l-Chloro-2,2.2-trifluoroethane (R 133a) 2. 3 °(a) 20 1983 Chlorotrifluoroethane (R 13) 2, 5 °(a) 20 1022 Chromic acid, solutions of 8. ll 0 (b) 80 1755 8 Chromic fluoride 8. 26°(6) 80 1756 8 + 6.1 Chromic fluoride, sol~tions of 8. 26°(6) 80 1757 8 + 6.1 Chromium oxychloride: see Chromiyl chloridf' Chromosulphuric acid 8. l O (a) 88 2240 8 Chromyl chloride· (chromium oxychloride) . (CrOp2) 8.21°(a) 88 1758 8 Collodions. semi-collodions. solutions of. and other nitrocellulose solutions having a flash -point below 21 °C and a boi ling point not more than 35 ° C 3. 4°(a) 33 2059 3 having a flash -point below 21 ° C and a boi ling higher than 35 °C 3. 4 °(6) 33 2059 3 having a flash -point between 21 °C and 55 °C (limit values included) 3. 33°(c) 30 2060 3 having a flash -point above 55 °C 3. 34°(c) 30 2060 Cresols 6.1. 14°(6) 60 2076 6.1 Cresylic acid 6.1. 14°(6) 60 2022 6.1 Crotonic aldehyde (Crotonaldehyde) 3. 3 °(6) 33 1143 3 Crotonylene (2-Butyne) 3. 1 ° (a) 339 1144 3 Cumene (Isopropylbenene) 3.3l 0 (c) 30 1918 3 Cumyl hydroperoxide: see alpha. alpha Dimethylbenzyl hydroprepoxide Cupriethymediamine. solutions of 8.53°(6) 86 1761 8 Cyanides, inorganic solutions of (d. 41 °(a) 66 1935 6.1 Cvanuric chloride 8. 27°(c) 80 2670 8 Cyclobutyl chloroformate 6.1. 16°(6) 638 2744 6.1 + 3 + 8 1.5, 9-Cyclododecatriene 6.1. 24°(c) 60 2518 6.lA Cycloheptane 3, 3°(b) 33 2241 3 Cycloheptene 3 .• 3°(6) 33. 2242 3 Cyclohexane 3. 3 °(6) 33 1145 3 Cyclohexanone 3.3l 0 (c) 30 1915 3 Cyclohexene 3.3°(h) 33 2256 3 Cyclohexenyltrichlorosila1w 8. 37°(b) 80 1762 8 Cyclohexyl acetate 3. 32°(c) 30 2243 Cyclohexylamine 8. 53°(b) 83 2357 8+3 Cyclohexyl isocyanate 6.1. 18°(6) 63 2488 6.1+3 Cyclohexyltrichlorosilanc 8. 37°(b) 80 1763 8 Cyclooctadiene 3.3l 0 (c) 30 2520 3 Cyclooctatetraene 3.3l 0 (c) 30 2358 3 Cyclopentane 3. 3 °(b) 3;3 1146 3 Cyclopentanol 3.3] 0 (c) 30 2244 3 Cyclopentanone 3.31°(c) 30 224:;i 3 Cyclopentene 3. 2 °(b) 33 2246 3 Cyclopropane 2. 3 °(b) 23 1027 3 Cymenes (Methyl isopropyl benzenes) 3.31°(c) 30 2046 3 Decahydronaphthalene (Decal in) 3.32°(c) 30 1147 n-Decane 3.31°(<') 30 2247 3 Diaceton~ alcohol, technical 3. 3 °(b) 33 1148 3 Diacetyl: see Butanedione Diallylmnine 3.22°(b) 338 2359 3+8 Dialyl ether . 3, 17°(6) 336 2360 3+6.1 Diaminodiphenyl methane. in the molten stale (d. l2°(c) 60 2651 6.lA Di-n-amylamine 6.L ]2°(c) 60 2841 6.lA 1112 ECJ>HMEPII: THI KYBEPNHI:EQI: (TEYXOI: LlEYTEPO) Name of substances Class and Hazard ldentifi- Substance ldenti item cation No • fication No Label number (upper part) (lower part) (a) (b) (c) ,, (d) (e) Dibenzyldichlorosilane 8. 37°(6) 80 2434 8 Dibromobenzenes 3,32°(c) 30 2711 1,2-Dibromobutan-3-one 6.1. 16°(6) 60 2648 6.1 1,2-Dibromo-3-chloropropane 6.1. l5°(c) 60 2872 6.LA sym-Dibromoethane: see Ethylene dibromide Dibromomethane: see Methylene bromide Di-(n-butyl) amine 8, 53°(6) 83 2248 8+3 Dibutylaminoethanol 6.1. l2°(c) 60 2873 6.lA Di-n-butyl ether (n-Butyl ether) 3.31°(c) 30 1149 3 Dichloroacetic acid 8.32°(6) 80 1764 8 sym.-Dichloroacetone 6.1, 16°(6) 63 2649 6.1+3 Dichloroacetyl chloride 8, 36°(6) X80 1765 8 Dichloroanilines 6.1. 12°(6) 60 1590 6.1 1,2-Dichlorobenzcne 6.1. l5°(c) 60 1591 6.lA 1,2-Dichlorodiethyl ether 6.1, 16°(6) 63 1916 6.1+3 Dichlorodilluoromethane (R 12) 2. 3 °(a) 20 1028 Dichlorodilluoromethane containing 12 per cent of ethylene oxide by mass 2. 4 °(ct) 236 1028 ++ 1, 1-Dichloroethane (Ethylidene chloride) 3. 3 °(6) 33 2362 3 1,2-Dichloroethane (Ethylene dichloride) 3. 16°(6) 336 1184 3+6.1 1,2-Dichloroethylene 3. 3 °(6) 33 1150 3 Dichlorolluoromethane (R 21) 2, 3 °(a) 20 1029 1,3-Dichlorohydrin ( l ,3-Dichloro-2-propanol 6.1. 16°(6) 60 2750 6.1 Dichloroisopropyl ether 6.1, 16°(6) 60 2490 6.1 Dichloromethane: see Methylene chloride 1, 1-Dichloro-l-nitroethane 6.1. 16°(6) 60 2650 6.1 Dichloropentanes 3,31°(c) 30 1152 3 Dichlorophenols 6.l.17°(c) 60 2021 6.lA 3,4-Dichlorophenyl isocyanate 6.1. l 9°(c) 60 2250 6.1 Dichlorophenyltrichlorosilane 8,37°(6) 80 1766 8 l.3-Dichloro-2-propanol: see 1.3-Dichlorohydrin 1,3-Dichloropropene 3.31°(c) 30 2047 3 l,2-Dichloro-1,1,2,2,- letralluoioetl;,rne (R I J 4) 2. 3 °(a) 20 1958 • Dicychlohexylamine 8,53°(c) 80 2565 8 Dicyclopentadiene 3. 31 °(c) 30 2048 3 1, 1-Diethoxyethane: see Ace ta I 1,2-Diethoxyethane (Ethylene glycol diethyl ether) 3.31°(c) 30 1153 3 Diethoxymethante 3. 3 °(6) 33 2373 3 3,3,-Diethoxypropene 3, 3 °(6) 33 2374 3 Diethylamine 3. 22 °(6) 338 1154 3+8 Diethylaminoethanol (N, N-Diethylethanolamine) 3. 32 °(c) 30 2686 Diethylaminopropylamine 8, 53°(c) 80 2684 8 N,N-Diethylaniline 6.1. l2°(c) 60 2432 6.lA Diethyl benzenes 3.32°(c) 30 2049 Diethyl carbonate (Ethyl carbonate) 3.31°(c) 30 2366 3 Diethyldichlorosilane 8. 37°(6) 83 1767 8+3 Diethylenediamine (Piperazine) 8. 52°(c) 80 2579 8 Diethylenetriamine 8. 53 °(6) 80 2079 8 N, N-Diethylethanolamine: see Diethylaminoetha nol N,N-Diethylethylenediamine 8. 53 °(6) 83 2685 8+3 Diethyl ketone 3. 3 °(6) 33 1156 3 Diethyl sulphate 6.1. 14°(6) 60 1594 6.1 Diethylthiophosphoryl chloride 8, 36°(6) 80 2751 8 1,1-Dilluoroethane (R 152a) 2, 3 °(6) 23 1030 ++ 1, 1-Dilluoroaethylene (Vinylidene 11 uoride) 2. 5 °(c) 239 1959 3 Dilluorophosphoric acid, anhydrous 8. 10°(6) 80 1768 8 2,3-Dihydropyrau 3. 3 °(6) 33 2376 3 Diisobutylamine 3,31°(c) 30 2361 3 Diisobutylenes 3. 3 °(6) 33 2050 3 Diisobutyl ketone 3.31°(c) 30 1157 3 Diisooctyl acid phosphate 8. 38°(c) 80 · 1902 8 Diisopropylamine 3.22°(b) 338 1158 3+8 Siisopropylbenzene hydroperoxide (isopropyl cumyl hydroperoxide) with 45 per cent of a mixture of alcohol and ketone 5.2. 18° 539 2171 5 N,N-Diisopropylethanolamine 8.53°(c) 80 2825 8 «l>EK 104 E<J>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) 1113 Name of substances Class and Hazard· Identifi- Substance Identi item cation No fication No Label number (upper part) (lower part) (a) (b) (c) (cl) (e) Diisopropyl ether 3. 3 °(b) 33 1159 3 Iliketene 3. 31(0 (c) 39 2521 3 l, 1-Dimethoxyethane 3, 3 °(b) 33 2377 3 : .. 1 ,2-Dimethoxyethane 3. 3 °(b) 33 2252 3 ' Dimethoxymethane (Methylal) 3, 2 °(b) 33 1234 3 Dimethylamine, anhydrous 2, 3 °(bt) 236 1032 3+6.1 Dimethylamine, aqueous solutions of having a boiling point not more than 35 ° C 3. 22°(a) 338 1160 3+8 having a boiling point higher than 35°C 3. 22°(b) 338 1160 3+8 Dimethylaminoacctonitrile 6.1. 11 ° (b) 63 2378 6.1+3 Dimethylaminoethanol:see Dimethyletha11olami11e Dimethylaminoethyl methacrylate 6.l.ll 0 (b) 69 2522 6.1 N,N-Diethylanilinc 6.l. ll 0 (b) 60 2253 6.1 Dimethylbenzenes: see Xylenes alpha, alpha-dimethytbenzyl hydroperoxide (Cumyl hydroperoxide) with a peroxide content not exceeding 95 per cent 5.:Z, 10° 539 2116 5 1,3-Diemthylbutylamine 3. 3 °(b) 33 2379 3 N. N-Dimethylcarbamoyl chloride 8. 36°(b) 80 2262 8 Dimethyl carbonate 3. 3 °(b) 33 1161 3 Dimethylcyclohexanes 3. 3 °(b) 33 2263 3 N .N-Dimethylcylohexylamine 8, 33°(b) 83 2264 8+3 Dimcthvdichlorosilane 3, 21 °(a)· X338 1162 3+8 Dimethykliethoxysilane 3. 3 °(b) 33 2380 3 Dimethyldioxanes having a flash-point below 21 °C 3. 3 °(b) 33 2707 3 having a flash-point between 21 ° C and 55 °C (limit values included) 3. 31 °(c) 30 2707 3 having a flash-point above 55 ° C 3. 32°(c) 30 2707 -:-;-,: Dimethyl disulphide 3. 3 °(c) 33 2381 -..., ...... 3 .. . . Dimethylethanolamine (Dimethylami11oe1ha11ol) 3.31°(c) 30 2051 3 Dimethyl ether 2. 3 °(c) 23 1033 3 N,N-Dimethylforrnamide 3, 32°(c) 30 2265 1, 1-Dimet hylhydrazine 3. 23 °(a) 338 1163 .3+8. 1,2-Dimethylhydrazine 3. l5°(a) 336 2382 3+6.1 Dimethyl-N-propylamine 3. •22 ° (b) 338 2266 3+8 Dimethyl sulphate 6.1. l3°(a) 66 1595 6.1 Dimethyl sulphide 3. 2 °(b) 33 1164 3 Dimethyl thiophosphoryl chloride 8. 36°(c) 80 2267 8 Dinitroanilines 6.L 12°(b) 60 1596 6.1 Dinitrobenzenes 6.1. l2°(b) 60 1597 6.1 Dinitro-orthocresol 6.1. 75°(6) 60 1598 6.1 Dinitrotoluenes, solid 6.L 12°(b) 60 2038 6.1 Dinitrotoluenes, molten 6.1; 12°(b) 60 1600 6.1 Dioxane 3. 3 °(b) 33 1165 3 Dioxolane 3. 3 9 (b) 33 1166 3 Dipentene 3.31°(c) 30 2052 3 Diphenyldichlorosilane 8. 37°(b) 80 1769 8 4,4-Diphenylmethane diisocyanale 6.1. J9°(c) 60 2489 6.lA Diphenylmethyl bromide 8.65°(b) 80. 1770 8 Dipropylamine 3. 22°(b) 338 2383 3+8 Dipropylenetriamine: see Bis-an1inopopyla111i11e 2384 3 Dipropyl ether 3. 3°(6) 33 Dipropyl. ketone 3. 31 °(a) 30 2710 3 Disulphur dichlorirle (S.,CL.,) 8.21°(a) 88 1828 8 Ditertiary butyl peroxide - - •) 1 0 539 2102 5 ;:,, , Dodecyltrichlorosilane 8. 37°(b) 80 1771 8 Enamels having a flash-point below 21 °C 3. 50 33 1263 3 having a flash-point between 21 °C and 1263 3 55 ° C (limit values included) 3.31°(c)* 30 having a llash-poinl above 55 ° C 3. 32°(c)*. 30 1263 Epibromohydrin 6.1. l6°(a) 66 2558 6.1 Epichlorohydrin 6.1. l6°(b) 63 2023 6.1+3 1,2-Epoxy-3-ethoxypropane 3. 31 °(c) 30 2752 3 Ethane 2. 5 °(b) 23 1035 ++ 1114 1:CJ>HM1:PIL I HL KYBt:PNHLEQi ( i'EYXOI AEYTEPO) Name of substances Class and Hazard ldentifi- Substance ldenti item cation No fication No Label number (upper part) (lower part) · (a) (b) (c) (d) < (e) Ethane; liquid, deeply-refrigerated 2, 7°(b) 223 1961 ++ Ethanol (Ethyl alcohol) and its aqueous solutions . containing more than 70 per cent alcohol 3. 3 °(b) 33 1170 3 Et hanol (Ethyl alcohol), aqueous solutions of, in • concentration from 24 per cent up to and incl uding 70 per cent 3,31°(c) 30 1170 3 Ethanolamine and its solutions 8, 54°(c) 80 2491 8 2-Ethoxyethanol (Ethylene glycol monoethyl ether) 3,3l.0 (c)' 30 1171 3 (/ 2-Ethoxyethyl acetate (Ethylene glycol mono'ethyl ether acetate) 3,31°(c) 30 1172 3 Ethyl acetate 3, 3 °(b) 33 1173 3 Ethyl acrylate 3, 3 °(b) 339 1917 3 Ethyl acohol: see Ethanol Ethylamine, anhydrous 2, 3 °(bt) 236 1036 3+6.1 Ethylamine, aqueous solutions of having a boiling point not more thai1 35 ° C 3. 22°(a) 338 2270 3+8 having a boiling point higher than 35°C 3. 22 °(b) 338 2270 3+8 Ethyl amyl ketone 3, 31 °(c) 30 2271 3 2-Ethylaniline 6.1, l2°(c) 60 2273 6.lA N-Ethylaniline 6.1, l2°(c) 60 2272 6.lA Ethylbenzene, technical 3, 3 °(b) 33 1175 3 N-Ethyl-N-benzylaniline 6.1, l2°(c) 60 2274 6.lA Ethyl bromide 6.1, 15°(b) 60 1891 6.1 Ethyl bromoacetate 6.1. l6°(b) 63 1603 6.1 + 3 2-Ethylbutanol 3, 32°(c) 30 2275 2-Ethylbutyl acetate 3,31°(c) 30 1177 3 Ethyl butyl ether 3. 3 °(b) 33 1179 3 Ethyl butyrate 3, 31 °(c) 30 1180 3 Ethyl carbonate: see Diethyl carbonate Ethyl chloride 2. 3 °(bt) 236 1037 ++ Ethyl chloroa~etate 6.1, 16°(6) 63 1181 6.1 + 3 Ethyl chloroformate 3, l6°(a) 336 1182 3 + 6.1 Ethyl crotonate 3, 3 °(6) 33 1862 3 Ethyl cyanoacetate 6.1, l2°(c) 60 2666 6.lA Ethyl dichlorosilane 4.3. 4°(b) X338 1183 4.3 + 3 + 8 Ethylene 2, 5 °(b) 23 1962 3 Ethylene, liquid, deeply - refrigerated 2. 7°(6) 223 1038 3 Ethylene chlorohydrin (2-Chloroethanol) 6.1. 16°(b) 60 1135 6.1 Ethylenediamine 8. 53 °(b) 83 1604 8+3 Ethylene dibromide (sym.-Dibromoethane) 6.1. l5°(b) 60 1605 6.1 Ethylene dichloride: see 1,2-Dichloroethane Ethylene glycol diethyl ether: see 1, 2-Diethox yethane Ethylene glycol monobutyl ether 6.1, l3°(c) ,~. 60 2369 6.lA Ethylene glycol monoethyl ether: see 2-Ethoxyet hanol Ethylene glycol mo11oethyl ether acetate: see 2-Ethoxyethyl acetate Ethylene glycol monomethyl ether acelale 3. 31 °(c) 30 1189 3 . Ethyleneimine 3, 12° 336 ll85 3 + 6.1 Ethylene oxide containing nol more than I 0 per cent carbon dioxide by mass 2. 4 °(ct) 236 1041 3 + 6.1 Ethylene oxide containing more than 10 per cent but more than 50 per cent carbon dioxide by mass 2. 64 °(ct) 236 1041 3 + 6.1 Ethylene oxide containing carbon dioxide: see Carbon dioxide containing ethylene oxide Ethylene oxide with nitrogen 2. 4 °(ct) 236 1040 3 + 6.1 Ethyl ether 3, 2°(a) 33 1155 3 Ethyl fluid 6.1. 31 °(a) 66 1649 6.1 Ethyl formate 3. 3 °(b) 33 ll90 3 2-Ethyl hexaldehyde 3,31°(c) 30 1191 3 2-Ethylhexylamine 8,53°(c) 83 2276 8+3 2-Ethylhexyl chloroformate 6.L 16°(6) 68 2748 6.1 + 8 Ethylidene chloride: see 1. l-Did1loroelhane Ethyl isobutyrate 3. 3 °(6) 33 2385 3 Ethyl lactate 3, 31 °(cj>) 30 ) 1192 3 ' ' * See. howe,·er. NOTE 1111der ~,·1·1io11 I) of' 11iargi11al 2:~o I. E(l)HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) 1115 Name of substances Class and Hazard ldentifi- Substance ldenti item cation No fication No Label number ( upper part) . (lower part) (a) (b) (c) (d) (e) Ethyl mercaptan 3, 18°(~) 336 2363 3 + 6.1 Ethyl methacrylate 3, 3 o(~) 339 2277 3 Ethyl methyl ketone 3, 3 o(~) 33 1193 3 Ethyl orthoformate 3,31°(4) 30 2524 3 Ethyl oxalate 6.1, 13°(4) 60 2525 6.lA Ethyl phenyl dichlorosilane 8, 37°(~) 83 2435 8+3 1-Ethylpiperidine 3, 3 o(~) 33 2386 3 Ethyl propionate 3. 3 o(~) 33 1195 3 Ethyl propyl ether 3, 3 o(~) 33 2615 3 Ethyl sulphide 3. 18°(~) 336 2375 3 + 6.1 Ethylsulphuric acid 8, 34°(~) 80 2571 8 Ethyltoluidines 6.1. 12°(~) 60 2754 6.1 Ethyltrichlorosilane 3. 21 °(ix) X338 1196 3+8 Ferric chloride (Iron trichloride), anhydrous (FeCl3) 8. 22°(4) 80 1773 8 Ferric chloride (Iron trichloride), aqueous solu- • tions of 8, 5 °(4) 80 2582 8 Fluoboric acid, aqueous solutions of, containing not more than 78 per cent pure acid (HBF4) 8, 80(~) 80 1775 8 Fluorobenzene 3. 3°(~) 33 2387 3 Fluorophosphoric acide, anhydrous 8, 10°(~) 80 1776 8 Fluorosulphonic acid 8. 10°(ix) 88 1777 8 Fluorotoluenes 3. 3 o(~) 33 2388 3 Fluosilicic adic (Hydrofluosilicic acid) (H 2 SiF J 8, 90(~) 80 1778 8 Formaldehyde, aqueous solutions of (e.g. Formalin), containing not less than 5 per cent formaldehyde, also containing not more than 35 per cent methanol having a flash-point between 21 ~ C and 55 °C (limit values included) 8. 63°(4) 83 1198 ,,3 + 3 having a flash-point above 55 °C 8, 63 °(4) 80 2209 8 Formic acid containing more than 70 per cent pure adic 8, 32°(~) 80 1779 8 Forrriic -acid containing from 50 to 70 per cent pure acid 8. 32°(4) 80 1779 8 Fumaryl chloride 8. 36°(~) 80 1780 8 Furan 3. 1 °(ix) 33 2389 3 Furfural (Furfuraldehyde) 3. 32°(4) 30 1199 Furfurylamine 8,53°(4) 83 2526 8+3 Furfuryl alcohol 6.1. 13?(4) 60 2874 6.lA Gas mixture R 500 2. 4°(1X) 20 2602 Gas mixture R 502 2. 4°(ix) 20 1973 Gas mixture R 503 2. 60(1X) 20 2599 Glycerol alpha-monochlorohydrin (3 Chloropropane-1, 2-diol) 6.1. 17°(4) 60 2689 6.lA Glycidaldehyde 6.1. 13°(~) 63 2622 6.1 + 3 Helium, liquid, deeply-refrigerated 2. 7°(1X) 22 1963 Heptanes 3. 3 o(~) 33 1206 3 Heptanes 3. 3 o(~) 33 2278 3 Hexachloroacetone 6.1. 17°(4) 60 2661 6.lA • Hexachlorobenzene 6.1. 17°(4) 60 2729 6.lA Hexachlorobutadiene 6.1. 17°(4) 60 2279 6.lA Hexachlorocyclopentadiene 6.1. l 7°(ix) 66 2646 6.1 Hexadecyltrichlorosilane 8. 37°(~) 80 1781 8 Hexadienes 3. 3 o(~) 33 2458 3 Hexafluoroacetone hydrate 6.1. l 7°(b) 60 2552 6.1 Hexafluoroethane (R 116) 2. 5 °(a). 20 2193 Hexafluorophosphoric acid 8. l0°(b) 80 1782 8 Hexafluoropropylene (R 1216) 2. 3 ° (at) 26 1858 ++ Hexaldehyde 3. 31 °(c) 30 1207 3 Hexamethylenediamine 8.52°(c) 80 2280 8 Hexamethylenediamine. solutions of 8. 53 °(b) 80 1783 8 Hexamethylene diisocyanate 6.1. 19°(b) 60 2281 6.1 Hexamethyleneimine 3. 22°(b) 338 2493 3+8 Hexanes 3. 3 °(b) 33 1208 3 1-Hexene 3. 3 °(b) 33 2370 3 Hexyltrichlorosilane 8. 37°(b) 80 1784 8 1116 E<l>HMEPlt THr KYBEPNHtEQr (TEYXOr ~EYTEPO) Name of substances (a) Hydrazine. aqueous solutions of. co11tai11i11g nol more than 64 per cent hydrazim· Hydriodic acid, solutions of Hydrobromic acid. solu1io11s of Hydrocarbons. liquid. pure or in mixlun·s. 1101 otherwise specified in this Appendix having a nash-point belo" 2 l ° C having a nash-point below 21 °C and 55°C (limit values included) • - having a nash-poinl abol'e j5°C Hydrochloric acid, solutions of Hydrocyanic acid. aqueous solutions of. ('Onlain­ ing not mon~ than 20 per cent pure acid Hydrofluoric acid and sulphuric acid mixlurt's Hydrofluoric acid. a11hydrous (Hydrogen Ouoride) Hydrofluoric acid. aqueous solutions of. contain­ ing more than 85 per cent anhydrous hydroOu­ oric acid HydroOuoric acid. aqut'ous solutions of. contain-· ing more than 60 per cent but 1101 more than 8:-:; per cent anhydrous hydronuoric acid Hydrofluoric acid. aqueous solutions of. contain­ ing not more than 60 per cent anhydrous hydro­ fluoric acirl HydroOuosilicic acid: see Fluosilicic acid Hydrogen, liquid. deeply-refrigerated Hydrogen bromide Hydrogen chloride Hydrogen fluoride: see Hydronuoric a('irl. anhy­ drous Hydrogen peroxide. stal.iilizcd and aqueous solu­ tions containing more than 60 per cent hydrogen peroxide, stabilized Hydrogen peroxide, aqueous solutions of. con­ taining not less than 20 per cent but 1101 more than 60 per cent hydrogen peroxide Hydrogen peroxide, aqueous solutions of. con­ taining not less than 8 per cent but less than 20 per cent hydrogen peroxide Hydrogen sulphide Hydrogen sulphides, aqueous solutions of. not otherwise specified in this Appendix Hydroquinone beta-Hydroxybutyraldehyde: see Aldol Hydroxylamine sulphate Hypochlorite solutions containing not less than 16 per cent available chlorine Hypochlorite solutions containing more than 5 per cent but less than ] 6 per cent arnilahle chlori,w 3.3-Imino-bis-propylamine: see Bis-aminopropylamine Iroi1 pentacarbonyl Iron trichloride: see Ferric chloride lsoamyl formate Isobutane lsobutanol: see lsobutvl alcohol Isobutene: see lsobutylene lsobutyl acetate • • Isobutyl acrylate Isobutyl alcohol (Isobutanol) Isobutylamine Isobutylene (lsobutene) lsobutylene trimer: see Triisobutdent' lsobutyl formate • Isobutyl isobutyrate lsobtityl isocyanate Class and i1e111 m1111ber (b) 8. 44°(b) 8. -:; o(b) 8. 5 °(h) 3. ;3 °(1>) 3.]l 0 (c-) ;-3 ;-32o(c) 8. 50(1>) (,.I. 20 8. 7°(a) 8. 6°(a) 8. 60 8. 7°(a) 8. 7 °(a) 2. 7°(b) 2. 3 °(al) 2. 5 °(al) J. l. 1 0 8. 62°(b) 8. 62°(c) 2. 3°(bt) 8.45°(c) 6.l, l4°(c) 8. 27°(c) 8. 61 °(b) 8. 61 °(c) 6.1. 3 ° 3.31°(c) 2. 3°(b) 3. 3°(6) 3.31°(c) 3.31°(c) 3. 22°(b) 2. 3°(6) 3. 3°(6) 3,31°(c) 3. 14°(6) Hazard ldentifi- Substance ldenti cation No fication No (upper part) (lower part) (c) (d) 86 2030 80 1787 80 1788 33 1203 30 1223 30 1202 80 1789 633 1613 886 1786 886 1052 886 1790 886 1790 886 1790 223 1966 286 1048 286 1050 559 2015 85 2014 85 - 2984 236 1053 80 1719 60 2662 80 2865 85 1791 85 1791 663 1994 30 1109 23 1969 33 1213 39 2527 30 1212 338 1214 23 1055 33 2393 30 2528 336 2486 Label (e) 8 +.6.1 8 8 3 3 8 6.1 + 3 8 + 6.1 8 + 6.1 8 + 6.1 8 + 6.1 8 + 6.1 ++ 8 + 6.1 8 + 6.1 5 8+5 8+5 3 + 6,l 8 6.lA 8 8 8 6.1 + 3 .3 3 3 3 3 3+8 3 3 3 3 + 6.1 E<DHMEPII THI KYBEPNHIEQI (TEYXOI .l1EYTEPO) 1117 Name of substances - Class and Hazard Identifi- Substance Identi item cation No fication No Label number ( upper part) (lower part) (a) (6) (c) (d) (e) lsobutyl methacrylate 3. 31 °(c) 39 2283 3 lsobutyl propianate 3. 31 °(c) 30 2394 3 Isobutyraldehyde 3. 3 °(b) 33 2045 3 Isobutyric acid 8.32°(c) 80 2529 8 Isobutyric anhydride 8. 32°(c) 80 2530 8 Isobutyronitrile 3. 11 °(b) 336 2284 3 + 6.1 lsobutyryl chloride 3. 25 °(6) 338 2395 3+8 Isocyanates, solutions of. having a nash-point below 21 °C 3. 14°(6) 336 2478 . 3 + 6.1 lsocyanatobenzotrifluorides 6.1. l 8°(b) 60 2285 6.13 3-lsocyanatomethyl-3, 5. 5-trimethylcyclohexi I isocyanate: see lsophorone diisocyanate lsododecane: see Pentamethylheptam' lsopentane 3. l 0 (a) 33 1265 3 Isophoronediamine 8. 53 °(c) 80 2289 8 lsophorone diisocyanate (3-lsocyanatomethvl-3. 5, 5-trimethylcyclohexyl isocyanate) 6.1. l 9°(c) 60 2290 6.lA lsoprene 3. 2°(a) 339 1218 3 Isopropanol (lsopropyl alcohol) 3. 3 °(6) 33 1219 3. lsopropenyl acetate 3. 3 °(6) 33 2403 3 Isopropyl acetate :3. 3 °(6) 33 1220 3 Isopropyl acid phosphate 8. 38°(c) 80 1793 8 Isopropyl alcohol: see Isopropanol Isopropylamine 3. 22°(a) 338 1221 3+8 Isopropylbenzene: see Cumene Isopropyl butyrate 3. 3 °(h) 33 2405 3 Isopropylchloride: see 2-Chloropropane Isopropyl cumyl hydroperoxide: see '-4~~::··· Diisopropylbenze1ie hydroperoxide lsopropylethylene: see 3-Methyl-1-huten!' 3. -':~ 0 (6) lsopropyl isobutyrate 33 2406 3 Isopropyl isocyanate 3. l4°(a) 336 2483 3 + 6:1 .. Isopropyl nitrate 3. 3 °(6) 33 1222 3 Isopropyl propionate 3. ,3 °(b) 33 2409 3 Krypton, liquid, deeply-refrigerated 2. 7°(a) 22 1970 Lead acetate 6.1. 62°(c-) 60 1616 6.lA Lead alkyls with halogenated•organiC' C'Otll pounds,. mixtures of (>.i. :31 °(a) 66 1649 6.1 Lead compounds, not otherwise specilied in this Appendix 6.l.62°(e) 60 2291 6.lA Lead sulphate containing 3 per cent or 111ore free sulphuric acid 8. 23°(6) 80 1794 8 Lithium hydroxide 8. ,1,1 °(b) 80 2680 8 '1agnesium arsenate Cd. 51 °(b) 60 1622 6.1 Maleic anhvdride 8.:1] 0 (c) 80 2215 8 Malononitrile 6.1. 12°(b) 60 2647 6.1 p-Menthanyl hydroperoxide with a peroxide c·o11 tent not exceeding 95 per cei1t :i.2. 14 ° (a) 539 2125 5 Mercaptoethanol (Thioglycol) (i.L 20°(6) 60 2966 6,1 Mercuric chloride Ci.l. 52°(b) 60 1624 6.1 Mercury acetate Cd. :'i2°(6) 60 1629 6.1 Mesitylene (l ,3.5-Trimethyl6enze11c) 3,:3] 0 (<:) 30 2325 3 Mesityl oxide 3.31°(c) 30 1229 3 Methacrylaldehyde 3.17°(6) 336 2396 3 + 6.1 Methacrvlic acid 8.32°(c) 89 2531 8 Methallyl alcohol 3.3l 0 (c) 30 2614 3 Methane, liquid, deeply-refrigeratc·d 2. 7°(b) 223 1972 3 Methanol (Methyl alcohol) 3. l 7°(b) 336 1230 3 + 6.1 Methoxyhutyl acetate: see Butoxyl 4~Methoxy-4-methylpentan-2-ont:' 3. 31 °(c) 30 2293 3 Methoxyethanol 3. :31 °(c) 30 1188 3 Methoxymethyl isocyanate 3. l4°(a) 336 2605 3 + 6.1 Methyl acetate 3. 3 °(b) 3;3 1231 3 Methyl acrylate :3. 3 °(b) 339 1919 • 3 Methylal: see Dimethoxymethant:' Methyl alcohol: see Methanol lll8 EG>HMEPII: THI KYBEPNHIEOI (TEYXOI aEYTEPO) ,Name of substances Class and Hazard ldentifi- Subi.tance Identi item cation No fication No Label number (upper part) (lower part) (a) (b) (c) (d) (e) Methyl allyl chloride 3. 3 °(6) 33 2554 3 \1ethylamine, anhydrous 2, 3 ° (bt) 236 1061 ++ Methylamine, aqueous solutions of having a boiling point not more than 35 ° C 3. 22 °(a) 338 1235 3+8 having a boiling point higher than 35 °C 3. 22 °(6) 338 1235 3+8 Methyl amyl acetate 3.31°(c) 30 1233 3 Methyl amyl alcohol (Methyl isobutyl carbinol) 3.31°(c) 30 2053 3 N-Meth'ylaniline 6.1, 11 °(c) 60 2294 6.lA Methyl bromide 2. 3°(at) 26 1062 6.1 Methyl bromoacetate 6.1. l6°(b) 63 2643 6.1 + 3 3-Methyl butan-2-one 3. 3 °(6) 33 2397 3 2-Methyl-1-butene 3. • 1 °(a) 33 2459 3 3-Methyl-1-butene (isopropylethylene) 3. 1 °(a) 33 2561 3 2-Methyl-2-butenc 3. 2 °(b) 33 2460 3 Methyl tert-butyl ether 3, 3 °(b) 33 2398 3 • Methyl butyrate 3. 3 °(b) 33 1237 3 Methyl chloride 2. 3 ° (bt) 236 1063 3 + 6.1 Methyl chloroacetate 6.1. 16°(6) 63 2295 6.1 + 3 Methyl chloroforrnate 3. 16°(a) 336 1238 3 + 6.1 Methylchloromethyl ether 3, 16°(6) 336 1239 3 + 6.1 Methylcydohexane 3. 3 °(6) 33 2296 3 Methylcyclohexanone 3,31°(c) 30 2297 3 Methylcyclopentane 3. 3 °(6) 33 2298 3 Methyl dichloroacetate 6.1. l6°(c) 60 2299 6.lA Methyldichlorosilane 4.3. 4 °(b) X338 1242 4.3 + 3 + 8 Methylene bromide (Dibromornethane) 6.1. l5°(c) 60 2664 6.lA Methylene chloride (Dichlorornelhane) 6.1. l5°(c) 60 1593 6.lA 2-Methyl-5-ethyl pyridine 6.1, 11 °(c) 60 2300 6.lA Methyl formate 3, 1 °(a) 33 1243 3 2-Methylfuran 3, 3 °(6) 33· 2301 3 5-Methvlhexan-2-one 3;31 °(c) 33 2302 3 Methylhydrazine 3. 23 °(a) 338 1244 3+8 Methyl iodide 6.L 15°(b) 60 2644 6.1 Methyl isobutyl carbinol: see Methyl amyl alcolH?I Methyl isobutyl ketone 3. 3 °(6) 33 1245 3 Methyl isopropyl benzenes: see Cymenes Methyl isothiocyanate 6.1, 20°(c) 63 2477 6.lA + 3 Methyl isovalerate 3. 3 °(b) 33 2400 3 Methyl mercaptan 2. 3°(bt) 236 1064 6.1 + 3 Methyl methacrylate 3. 3 °(6) 339 1247 3 Methylmorpholines having a flash-point below 21 ° C 3. 22°(6) 338 2535 3+8 having a flash-point of 21 ° C or on.'r 8.53°(6) 83 2535 8+3 Methyl orthosilicate (Tetramethoxysilane) 3. l 7°(a) 336 2606 3 + 6.1 Methylpentadienes 3. 3 °(6) 33 2461 3 3-Methyl-2-pentene-4-yne-1-01: see 1-Penlol Methylphenyldichlorosilane 8. 37°(b) 83 2437 8+3 I-Methyl piperidine 3. 3 °(b) 33 2399 3 Methyl propionate 3. 3 °(b) 33 1248 3 Methyl propyl ether 3. 2°(b) 33 2612 3 Methyl propyl ketone 3. 3 °(6) 33 1249 3 Methylpyridines: see Picolines alpha-Methylstyrene 3. :31 °(c) 30 2303 3 Methyltetrahydrofuran 3. 3 °(6) 33 2536 3 Methyl trichloroacetate (>.l. l6°(c) 60 2533 6.lA Methyltrichlorosilane 3.21°(a) X338 1250 3+8 2-Methyl valeraldehyde 3. 3 °(b) 33 2367 3 Methyl vinyl ether 2. 3°(ct) 236 1087 ++ Methyl vinyl ketone 3. 3 °(b) 339 1251 3 Mixtures F 1. F 2 and F 3 2. 4 °(a) 20 1078 Mixtures of 1.3-butadiene and hvdrocarbons 2. 1 °(c) 239 1010 ++ Mixtures of caustic soda and qui~klimc: see Soda lime Mixtures of hydrocarbons (liquefied gas) (Mixtures A, A 0, A 1. B and C) 2. 4°(b) 23 1965 3 Mixtures of methylacetylene atul propadiene "ith hydrocarbons• ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 1119 Name of substances Class and Hazard Identifi- Substance Identi item cation No fication No Label number (upper part) (lower part) (a) (b) (c) (d) (e) (Mixtures P 1 and P 2) 2. 4°(c) 239 1060 3 Mixtures of methyl bromide and chloropicrin (liquefied gas) 2. 4 ° (at) 26 1581 ++ Mixtures of methyl chloride and chloropicrin (liquefied gas) 2. 4 ° (bt) 236 1582 ++ Mixtures of methyl chloride and methylene chloride (liquefied gas) 2. 4 °(b1) 236 1912 ++ Mixtures of sulphuric acid and more than 30 per cent pure nitric acid 8. 3 °(a) 885 1796 8 Mixtures of sulphuric acid and 1101 more than 30 per cent pure nitric acid 8. 3 °(6) 88 1796 8 Molybdenum pentachloride (MoCL,) 8. 22°(c) 80 2508 8 Monochloroacetic acid. solid: see Chloroacetic acid, solid Monochloroacetic acide. in the molten slate: see ChloroaCf~tic aGid, in the molten slate Monochloroacetic acid, solutions of: see Chloroacetic acid. solutions of Monochloroacelonitrile u.Lll"tb) 60 2668 6.1 Monochloroanilincs, liquid 6.L 12°(b) 60 2019 6.1 Monochloroanilines. solid 6.l. 12°(b) 60 2018 6.1 Mononitroanilines 6.L 12°(6) 60 1661 6.1 Mononitrotoluenes· 6.1. 12°(6) 60 1664 6.1 Morpholine 3.3] 0(c) 30 2054 3 Naphthalene in the molten slate 4.l.]l 0(c) 44 2304 4.1 beta-Naprhthylamine 6.L 12°(6) 60 1650 6.1 Natural gas. liquid, deeply'- refrigerated 2. 8°(6) 223 1972 3 Neon, liquid, deeply-refrigerated 2. 7 °(a) 22 1913 Nickel tetracarbonyl 6.1. 30 663 1259 f;i.J,.:t- 3 Nicotine sulphate 6.1. 77°(6) 60 1658 6.1 Nitrating acid mixtures. spent 8. 3° (6) 80 1826 8 Nitric acid, red fumig 8. 2 °(a) 856 2032 8 Nitric acid containing more than 70 per cent pure acid 8. 2 °(a) 885 2032 8 Nitric acid containing mot more thaii 70 per cent pure acid 8. 2°(6) 80 2031 8 Nitric acid. mixtures with sulphuric acid: see Mixtures of sulphuric acid and nitric acid Nitroanisoles 6.1. l'2°(c) 60 2730 6.lA Nitrobenzene. 6.l. 12°(6) 60 1662 .. 6.1 Nitrobenzenesulphonic acid 8. 34°(6) .80 2305 8 Nitrobenzotrifluorides 6.1. 12°(6) 60 2306 6.1 Nitrobromobenzenes 6.1. l2°(c) 60 2732 6.lA Nitrocellulose solutions: see Collodions. solutions of' 3-Nitro-4-chlorobenzotrifluoride 6.1. 12°(6) 60 2307 6.1 Nitrocrnsols 6.l. l2°(c) 60 2446 6.lA Nitroethane 3. 31 °(c) 30 2842 3 Nitrogen. liquid, deeply-refrigerated 2. 7°(a) 22 1977 Nitrogen dioxide N0 2 (Nitrogen peroxide. Nitro gen tctroxide Np) 2. 3 ° (at) 265 1067 5 + 6.1 Nitrophenols 6.1. l2°(c) 60 1663 6.lA Nitropropanes 3. 31 °(c) 30 2608 3 Nitrosylsulphuric acid 8. 1 °(6) 88 2308 8 Nitrous oxide Np 2. 5°(a) 25 1070 5 Nitrous oxid~ N.,O. deeply-refrigerated 2. 7 °(a) 225 2201 5 Nitroxylenes - 6.1. ]2°(6) 60 1665 6.1 Nonane 3.31°(c) 30 1920 3 Nonyltrichlorosilane 8. 37°(b) 80 1799 8 Octadexyltrichlorosilane 8. 37°(6) 80 1800 8 Octadienes having a flash-point below 21 ° C 3. 3 °(6) 33 2309 3 having a flash-point between 21 ° C and 55 °C (Limit values included) 3. 31 °(c) 30 2309 3 Octafluorocyclobutane (RC 318) 2. 3 °(a) 20 1976 Octanes 3. 3 °(6) 33 1262 3 Octyltrichlorosilane 8. 37°(b) 83 1801 8+3 Oleum (Sulphuric acid) fuming 8. 1 °(a) X886 1831 8 + 6.1 1120 ECl>HMEPII THI KYBEPNHIEOI. (TEYXOI ~EYTEPO) I Name of substances Class and Hazard Identifi- Substance Identi item cation No fication No Label number ( upper part) (lower part) (a) (b) (c) (cl) (e) Oxalates, soluble in water 6.1, 67°(c) 60 2449 6.lA Oxygen, liquid, deeply refrigerated 2. 7°(a) 225 1073 5 Paints having a flash-point below 21 ° C 3. 50 33 1263 ~ having a flash-point between 21 ° C and 55 ° C 1263 (limit values included) 3, 31 °(c)* 30 3 having a flash-point above 55 ° C 3. 32°(c)* 30 1263 •. Paraldehy<le 3,31°(c) 30 1264 3 Pentachloroethane 6.1, 15°(6) 60 1669 6.1 Pentamethylheptane (Isododecane). 3.31°(c) 30 2286 3 Pentan-2;4-dione (Acetyl acetone) 3.31°(c) 30 2310 3 Pentane, normal 3. 2 °(6) 33 1265 3 1-Pentene: see Amylene, normal 1-Pentol (3-Methyl-2-pentene-4-yne-1-01) 8.66°(6) 80 2705 8 Perchloric acid, aqueous solutions of, containig more than 50 per cent but not mon• than 72.5 per cent pure acid (HC10 1) 5.1. 30 558 1873 5+8 Perchloric acid, aqueous solutions of. containig more than 50 per cent pure acid (HClO,i) 8. 4 °(6) 85 1802 8 Perchloroethvlene: see Tetrachloroethvlene· Perchloromethylmercaptan • 6.1. l6°(a) 66 1670 6.1 Pesticides, organo-phosphorus compounds solid 6.l.71°(a) 66 2783 6.1 71 ° (b) 60 2783 6.1 71 °(c) 60 2783 6.lA liquid, having a flash-point below 21 ° C 3. 19° 336 2784 3 + 6.1 60 33 2784 3 + 6.lA liquid;'having a flash-point of 21 °C - 55°( 6.1. 7 l 0(a) 663 3017 6.1 + 3 71 °(6) 63 3017 6.1 + 3 71 °(c) 63 3017 6.lA + 3 liquid, not inflammable or having a flash-point above 55 ° C 6.1. 71 °(a) 66 3018 6.1 71 °(6) 60 3018 6.1 I 71 °(c) 60 3018 6.lA Pesticides. chlorinated hvdrocarbons solid (J.l, 72°(a) 66 2761 6.1 72 °(b) 60 2761 6.1 72 °(c) 60 2761 6.lA liquid. having a flash-point below 21 ° C 3. 19° 336 2762 3 + 6.1 60 33 2762 3 + 6.lA liquid. having a flash-point of 21 °C - 55°C 6.1, 72°(a) 663 2995 6.1 + 3 72°(6) 63 2995 6.1 + 3 72°(c) 63 2995 6.lA + 3 liquid. not i,iflammable or having a flash-point above 55 ° C 6.1. 72°(a) 66 2996 6.1 72°(b) 60 2996. 6.1 72 °(c) 60 2996 6.lA Pesticides. chloro-phenoxyilcetic derirntives solid 6.1. 73°(a) 66 2765 6.1 73°(6) 60 2765 6.1 73 ° (c) 60 2765 6.lA liquid. having a flash-point below 21 °C 3. 19° 336 2766 3 + 6.1 60 33 2766 3 + 6.lA liquid. having a flash-point belm, 21 °C - ;j5 °C (d. 73°(a) 663 2999 6.1 + 3 73 °(b) 63 2999 6.1 + 3 73°(c) 63 2999 6.lA + 3 liquid, not inflammable or having n flash-point above 55 °C 6.1. 73°(a) 66 3000 6.1 73 °(1.i). 60 3000 6.1 73°(c) 60 3000 6.lA Pesticides. carbamates solid 6.1. 76°(a) 66 2757 6.1 76°(6) 60 2757 6.1 76°(c) 60 2757 6.lA liquid. having a flash-point below 21 ° C :3. 19° 336 2758 3 + 6.1 60 33 2758 3 + 6.lA Cl>EK 104 EG>HMEPlr THI: KYBEPNHrEor (TEYXOr aEYTEPO) 1121 Name of substances Class and Hazard Identifi- Substance Identi item cation No fication No Label number (upper part) (lower part) (a) (b) (c) (d) (e) liquid, having a flash-point of 21 °C. 55°C 6.1. 76°(a) 663 2991 6.1 + 3 76°(6) 63 2991 6.1 + 3 76°(c) 63 2991 6.lA + 3 liquid, not inflammable or having a flash-point above 55 °C 6.1 6.1, 76°(a) 66 2992 76 °(6) 60 2992 6.1 76°(c) 60 2992 6.lA Pesticides, thiocarbamates solid 6.1, 76°(a) 66 2T71 6.1 76°)6) 60 277] 6.1 76°(c) 60 2771 6.lA liquid, having a flash-point below 21 ° C 3. 19° 336 2772 3 + 6.1 60 33 2772 3 + 6.lA liquid, having a flash-point of 21 ° C - 55 ° C 6.1. 76°(a) 663 3005 6.1. + 3 76°(6) 63 3005 6.1. + 3 76°(c) 63 3005 6.lA + 3 liquid, not inflammable or having a flash-point above 55 ° C • 6.1, 76°(a) 66 3006 6.1 76 °(6) 60 3006 6.1 76°(c) 60 3006 6.lA Pesticides, organotin compounds solid 6.1. 79°(a) 66 2786 6.1 79°(6) 60 2786 6.1 79° (c) 60 2786 6.lA liquid, havi1~g a flash-point below 21 ° C 3. 19° 336 2787 3 + 6.1 60 53 2787 3 + 6.lA liquid, having a flash-point of 21 °C - 55°C 6.1. 79°(a) 663 3019 6.1 + 3 79°(6) 63 3019 ,:; 6.1 :+ 3 79° (c) 63 3019 6.lA + 3 liquid, not)nflammable or having a flash-point above 55 ° C 6.1. 79°(a) 66 3020 6.1 79°(6) 60 3020 6.1. 79°(c) 60 3020 6.lA Pesticides, derivatives of bipyridyl solid (>.l. 82°(a) 66 2781 6.1 82°(6) 60 2781 6.1 • 82 °(c) 60 2781 6.lA liquid, having a flash-point below 21 ° C 3. 19° 336 2782 3 + 6.1 60 33 2782 3 + 6.lA liquid. having a flash-point of 21 °C - 55°C 6.1. 82°(a) 663 3015 6.1 + 3 82°(6) 63 3015 6.1 + 3 82°(c) 63 3015 6.lA + 3 liquid, not inflammable or having a flash-point above 55 °C . 6.1. 82°(a) 66 3016 6.1 82°(6) 60 3016 6,1 82 ° (c) 60 3016 6.lA Pesticides, inorganic compounds of ni:st'nil' solid 6.1. 84o(a) 66 2759 6.1 84 °(b) 60 2759 6.1 84 °(c) 60 2759 6.lA liquid. having a flash-point below 21 °C 3. 19° 336 2760 3 + 6.1 60 33 2760 3 + 6.lA liquid. having a flash-point of 21 ° C - ;j;j ° C 6.1. 84°(a) 663 2993 6.1 + 3 84 °(6) 63 2993 6.1 + 3 84 ° (c) 63 2993 6.lA + 3 liquid. not inflammable or having n flash-point above 55 ° C 6.1. 84°(a) 66 2994 6.1 84°(6) 60 2994 6.1 84 °(c) 60 2994 6.lA P·esticic.les. ·inorganic compounds of lllt'ITl&r, solid 6.1. 86 ° (a) 66 2777 6;1 86°(6) 60 2777 6.1 86°(c) 60 / 2777 6.lA liquid. having a flash-point below 21 °C 3. 19° 336 2778 3 + 6.1 60 33 2778. 3 + 6.lA liquid. having a flash-point of 21 ° C - .JS u (: 6.1. 86°(a) 663 3011 6.1 + 3 1122 ECl>HMEPII THI KYBEPNHiEQi ( 11:.YXOL dt.Y 11:.1-''l.JI) Name of substances Class and Hazard Indentifi- Substance Identi item cation No fication No Label number (upper part) (lower part) (a) (b) (c) (d) (e) 86 °(b) 63 3011 6.1 + 3 86 °(c) 63 3011 6.lA + 3 liquid, not inflammable or having a flash-point above 55 °C 6.1, 86°(a) 66 3012 6.1 86°(b) 60 3012 6.1 86 ° (c) 60 3012 6.lA Pesticides, inorganic compounds of copper 6.1, 87°(a) 66 2775 6.1 solid • 87°(b) 60 2775 "6.1 87°(c) 60 2775 6.lA liquid, having a flash-point below 21 ° C 3, 19° 336 2776 3 + 6.1 60 33 2776 3+6.lA liquid, having a flash-point of 21 ° C-55 ° C 6.1. 87°(a) 663 3009 6.1 + 3 87 °(b) 63 3009 6.1 + 3 87°(c) 63 3009 6.lA + 3 liquid, not inflammable or having a flash-point above 55°C 6.1. 87°(a) 66 3010 6.1 87 °(b) 60 3010 6.1 87°(c) 60 3010 6.lA Phenacyl bromide (omega-Bromoacetophenone) 6.1, l 7°(b) 60 2645 6.1 Phenacyl chloride (omega-Chloroacetophenone) 6.1. l 7°(b) 60 1697 6.1 Phenetidines 6.1, l2°(c) 60 2311 6.lA Phenol, in the molten state 6.1, 13°(b) 68 2312 6.1 Phenol, solutions of 6.1, 13°(b) 68 2821 6.1 Phenolsulphonic acid, liquid 8, 34°(b) 80 1803 8 Phenylacetonitride: see Benzyl cyanide Phenylacetyl chloride 8. 36°(b) 80 2577 8 Phenylcarbvlamine chloride 6.1, l 7°(a) 66 1672 6.1 Phenyl chl~ride: see Chlorobenzene Phenylchloroformate 6.1, 16°(6) 68 2746 6.1 + 8 Phenylenediamines 6.1. l2°(c) 60 1673 6.lA Phenylhydrazine • 6.1. 12°(6) 60 2572 6.1 Phenyl isocyanate 6.1. 18°(6) 63 2487 6.1 t J Phenyl methyl ether (Anisole) 3,31°(c) 30 2222 ~ Phenyl phosphorus dichloride 8, 36°(6) 80 2798 u Phenylthiophosphoryl dichloride 8. 3,6°(6) 80 ~7qq Phenyltrichlorosilane 8, 37°(b) g() 181)'1 8 Phosgene 2. 3 °(at) 26h ~ ' ,,,. ~ Phosphoric acid 8. 11 °/<') ,, 1 Of\ Phosphoric acid, anhydrous: see Phospl,oru,; pentoxide Phosphorus, white or yellow in the molten state I . ..'.. .L 1,..j.() ·-ii. I, . solid 4.'.? l " I:, 1381 I'.? Phosphorus oxybromide (POBr) o. :U 0 /h) 80 J'JJIJ 8 Phosphorus oxybromide (POBr;i) molten B. 22 l1..1J 80 2576 8 Phosphorus oxychloride (Phosphoryl chloride) (POCL) 8.21°(6) 80 1810 8 Phosphorus pentachloride (Pef:) 8.22°(6) 80 1806 8 Phosphorus pentasulphide ., 4.L go 40 1340 4.1 Phosphorus pentoxide (phosphoric acid, anhydrous) 8.27°(6) 80 1807 8 Phosphorus sesquisulphide 4.1, 30 40 1341 4.1 Phosphorus tribromide (PBr:)) 8, 21 °(6) 80 1808 8 Phosphorus trichloride (PCl:i 8.21°(6) 80 1809 8 Phosphoryl chloride: see Phosphorus oxychloride Phthalic anhvdride 8, 31 °(c) 80 2214 8 Picolines (M~thylpyridines) 3, :H 0(c) 30 2313 3 Pinane hydroperoxide (Pinanyl hydroperoxide): see 2,6,6-Trimethyl norpinanyl hydroperoxide alpha-Pinene 3.31°(c) 30 2368 3 Piperazine: see Diethylenediamine :>iperidine 3. 22°(6) 338 2401 3+8 Pivaloyl chloride (Trimethyl acetyl chloride) 8. 36°(6) 83 2438 8+3 Potash lye: see Potassiuni hydroxide. solutions of 423 2257 4.3 Potassium 4.3, 1 ° (a) E<1>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: AEYTEPO) 1123 Name of substances Class and Hazard lndentifi- Substance ldenti item cation No fication No Label number (upper part) (lower part) (a) (b) (c) (d) (e) Potassium arsenate 6.1, 51 °(6) 60 1677 6.1 Potassium arsenite 6.1, 51 °(6) 60 1678 6.1 Potassium bifluoride 8, 26 °(b) 80 1811 8 + 6.1 Potassium bisulphate containing 3 per cent or more 8,23°(b) free sulphuric acid 80 2509 8 Potassium chlorate, solutions of 5.1, 4°(a) 50 2427 5 Potassium fluoride 6.1. 65°(c) 60 1812 6.lA Potassium hydroxirk (Caustic potash). 8, 41 ° (b) 80 1813 8 Potassium hydroxide, solutions uf tl'otash lye) 8,42°(6) 80 1814 8 Potassium o-.:irk 8, 41 °(6) 80 2033 8 Putass1um sulphide contai11i11g not IPss tl1a11 30 per cent water of n1 sla!lization 8, 45°(b) 80 1847 8 Potassium sulph.idP. aqueous solutions of 8. 45°(c) 80 1847 8 Printers inks having a flash-point below 21 ° C 3, 50 33 1210 3 having a flash-point between 21 ° C and 55 ° C (limit values included) 3,31°(c)* 30 1210 3 having a flash-point above 55 ° C 3, 32°(c)* 30 1210 Propane 2, 3 °(b) 23 1973 3 n-Propanol, technical 3, 3 °(b) 33 1274 3 Propionalrlehyde 3. 3 °(b) 33 1275 3 Propionic acid containing not less than 50 per cent pure acid 8.32°(c) 80 1848 .8 Propionic anhydride 8,32°(c) 80 2496 8 Propionitrile 3, 11 °(b) 336 2404 3 + 6.1 Propionyl chloride 3, 25 °(6) 338 1815 3+8 Propyl acetate 3, 3 °(6) 33 1276 3 n-Propylamine 3,22°(6) 338 1277 3+8 n-Propylbenzene 3,31°(c) 30 2364 3 Propyl chloride: see l-Chloropropane ,tV:; Propylene 2, 3 °(6) 23 1077 3 Propy\enediamine 8, 53 ° (b) 83 2258 8+3 Propylene dichloride 3, 3 °(6) 33 1279 3 Propyleneimine . 3. 12° 336 1921 3 + 6.1 Propylene oxide 3, 2 °(a) 33 1280 3 Propylene tetramer: see Tetrapropylene Propylene trimer: see Tripropylene Propyl formates 3, 3 °(6) 33 1281 3 Propyl isocyanate, normal 3, l4°(a) 336 2482 3 + 6.1 Propyl mercaptan 3, 3 °(b) 33 2402 3 Propyltrichlorosilane 8, 37°(6) 83 1816 8+3 Pyridine 3, 15°(6) 336 1282 3 + 6.1 Pyrosulphuryl chloride (S.,O.Cl.,) 8,21°(b) 80 1817 8 Pyrrolidine - ' - 3,22°(6) 338 1922 3+8 Quinoline 6.1, l2°(c) 60 2656 6.lA R 12: see Dichlorodifluoromethane R 12B1: see Bromochlorodifluorornethane R 13: see Chlorotrifluoromethane R 13B1: see Brornotrifluoromethane R 21: see Di~hloroflubromethane R 22: see Chlorodifluoromethane R 23: see Trifluoromethane R 114: see 1.2-Dichloro-l, 1.2,2-tetrafluoro ethane R 115: see Chloropentafluoroethane R 116: see Hexafluoroethane R 133a: see l-Chloro-2,2,2-tri!luoroethane R 142b: see l-Chloro-1,1-difluoroethane R 152a: see 1,1-Difluoroethane R 500: see Gas mixture R 500 R 502: see Gas mixture R 502 R 503: see Gas mixture R 503 R 1113: see Trifluorochloroethylene R 1216: see Hexafli.Joropropylene RC 318: see oOctalluorocyclobutane * ..: linwt>n·r ~OTF 11111IPr SPC'lio11 I) of 111,11'),:i11al '.2:\0 I. 1124 t:\IJHMt:PIL I HL I\., Bt:PNHLt:iU. ( 11:YXOI AEYTEPO) Name of substances Class and Hazard Identifi- Substance Identi item cation No fication No Label number (upper part) (lower part) (,1) (b) (c) (d) (e) Resins in solution in inflammable liquids having a flash-point below 21 ° C 3. 50 33 1866 3 having a flash-point between 21 ° C and 55 ° C (limit values included) 3, 31 °(c)* 30 1866 3 having·a flash-point above 55°C 3. 32°(c)* 30 1866 Resorcinol 6.1. l4°(c) 60 2876 6.lA Selenales 6.1. 55°(a) 66 2630 6.1 Selenic acid 8. 11 °(a) 88 1905 8 Selenites 6.1. 55°(a) 66 2630 6.1 Selenium disulphide 6.1. 55°(6) 60 2657 6.1 Selenium metal 6. l. 55 °(c) 60 2658 6.lA Silicochloroform: see Trichlorosilane Silicon tetrachloride (SiCI) 8.21°(6) 80 1818 8 Soda lime (Mixtures of caustic soda and quicklime) 8. 41 °(c) 80 1907 ·8 Soda lye: see Sodium hydroxide. solutions of Sodium 4.3. 1 °(a) X423 1428 4.3 Sodium aluminate, solutions of 8. 42°(6) 80 1819 8 Sodium arsenate 6.1. 51 °(6) 60 1685 6.1 Sodium arsenite, solid 6.1, 51 °(6) 60 2027 6.1 Sodium arsenite, aqueous. solutions of toxic 6.1. 51 °(6) 60 1686 6.1 harmful 6.1. 51 °(c) 60 1686 6.lA Sodium bifluoride 8. 26°(6) 80 2439 8 + 6.1 Sodium bisulphate. aqueous solutions of 8. 1 ° (b) 80 2837 8 Sodium bisulphatc containing 3 per cent or more free sulphuric acid 8.23°(6) 80 1821 8 Sodium chlorate, solid 5.1. 4°(a) 50 1495 5 Sodium chlorate, solutions of 5.1. 4°(a) 50 2428 5 Sodium chlorite. solutions of 5.1. 4°(c) 50 1908 5 Sodium fluoride 6.L 65°(c) 60 1690 6.lA Sodium hydrogen sulphicle containing not less than 25 per cent water of crystallization 8.45°(6) 80 2949 8 Sodium hydroxide (Caustic soda) 8. 41 °(6) 80 1823 8 Sodium hydroxide, solutions of (Soda lye) 8. 42°(6) 80 1824 8 Sodium methylate, alcoholic solutions of 3. 24 °(6) 338 1289 3+8 Sodium oxide 8, 41 °(6) 80 1825 8 Sodium pentachlorophenate 6.1.17°(6) 60 2567 6.1 Sodium potassium alloys 4.3. 1 °(a) X423 1422 4.3 Sodium sulphide containing not less than 30 per \., cent water of crystallization 8.45°(6) 80 1849 8 Sodium sulphide, aqueous solutions of 8. 45°(c) 80 1849 8 Stannic chloride, anhydrous (SnCI.) 8.21°(6) 80 1827 8 Stannic chloride pentahydrate (Sn Cl 1'5Hp) 8. 22°(c) 80 2440 8 Styrene (Vinylbenzene) 3.31°(c) 39 2055 3 Sulphides, aqueous solutions of. not otherwise specified in this Appendix 8. 45°(c) 80 1719 8 Sulphur 4.L 2°(a) 40 1350 4.1 3ulphur in the molten stale 4.1. 2°(6) 44 2448 4.1 ,ulphur dichloride (SCI) 8,21°(a) X88 1828 8 ,ulphur dioxide 2. 3 ° (at) 26 1079 ++ 3ulphur hexafluoride 2. 5 °(a) 20 1080 3ulphuric acid 8, 1 °(6) 80 1830 8 3ulphuric acid, fuming: see Oleum 3ulphuric acid. mixtures with nitric acid: see Mixtures of sulphuric acid and nitric acid 3ulphuric acid, waste 8. 1 ° (b) 80 1832 8 Sulphur trioxide 8. 1 °(a) X88 1829 8 Sulphuryl chloride (SO.,Cl.,) 8.21°(a) X88 1834 8 'ars, liquid - - 3.32°(c) 30 1999 rerpene hydrocarbons. not otherwise specified in his Appendix having a flash-point between 21 °C and 55 °C (limit values included) 3,31°(c) 30 2319 3 having a flash-point above 55 °C 3.32°(c) 30 2319 erpinolene • 3.31°(c) 30 2541 3 See. however. NOTE u11d<'r se<'lio11 I) of' 111111·~i11al 2:10 I. EG>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) 1125 Name of substances Class and Hazard· Identifi- Substance Identi item cation No fication No Label number (upper part) (lower part) (a) (b) (c) (d) (e) 1,1,2,2-Tetrabromoethane (Acetylene tetrabromide) 6.1, l 7°(c) 60 • 2504 6.lA 1, 1,2 ,2-Tetrachloroethane (Acetylene tetrach lo ride) 6.1, 15°(b) 60 1702 6.1 ,. Tetrachloroethylene (Perchloroelhylene) 6.1, l5°(c) 60 1897 6.lA Tetrachlorophenols 6.1, l 7°(c) 60 2020 6.lA Tetraethylenepentamine 8, 53°(c) 80 2320 8 Tetraethyl lead 6.L 31 °(a) 66 1649 6.1 Tetraethyl silicate 3.31°(c) 30 1292 3 1,2,3,6-Tetrahydrobenzaldehyde 3. 32°(c) 30 2498 Tetrahydrofuran 3, 3°(b) 33 2056 3 Tetrahydrophthalic anhydride 8.31°(c) 80 2698 8 1,2,3,6-Tetrahydropyridine 3, 3 °(b) 33 2410 3 Tetrahydrothiophene 3. 3 °(b) 33 2412 3 Tetramethoxysilane: see Methyl orthosilicale Tetramethylammonium hydroxide 8. 51 °(6) 80 1835 8 Tetramethylethylenediamine: see 1,2-Bis (diamethylamino) ethane Tetramethyl lead 6.1. 31 °(a) 663 1649 6.1 + 3 Tetramethv lsilane Tetranitro~ethane, free from combustible impu 3. 1 ° (a) 33 2749 3 rities 5.1. 20 559 1510 5 Tetrapropylene (Propylene lelramer) 3.32°(c) 30 2850 Tetrapropylorthotitanate 3, 31 °(c) 30 2413 3 4-Triapentanal 6.L 20°(c) 60 2785 6.lA Thioacetic acid 3, 3 °(6) 33 2436 3 Thioglycol: see Mercaptoethanol Thioglycolic acid 8, 32°(b) 80 1940 • 8 ' , ,,·-l<'l'· ·; Thionyl chloride (SOCI) 8,21°(a) X88 1'836 • -s· Thiophene 3, 3 °(b) 33 2414 3 Thiophenol 6.1. 20°(a) 663 2337' 6.1 + 3, Thiophosgene • 6.l.20°(b) 60 247,4' 6.1 Thiophosphoryl chloride (PSCIJ 8. 21 °(b) 80 1837 8 Titanium tetrachloride (TiCl,i) 8.21°(b) 80 1838 8 Titanium trichloride, mixtures of. non-pyrophoric 8. 22°(6) 80 2869 8 Toluene 3. 3 °(b) 33 1294 3 Toluene sulphonic acids, solid 8. 34°(c) 80 2585 8 Toluene sulphonic acids, solutions of 8.34°(c) 80 2586 ·8 Toluidines 6.1. 12°(6) 60 1708 6.1 2,4-Toluylenediamine 6.1. l2°(c) 60 1709 6.lA 2,4-Toluylene diisocyanate and isomeric mixtures 6.1. 19°(6) 60 2078 6.1 Triallylamine 3. 31 °(a) :rn 2610 3 Triallyl borate 6.1. l3°(c) 60 2609 6.lA Tributylamine 8.53°(c) 80 2542 8 Trichloroacetaldehyde (Chloral) 6.1. 16°(6) 60 2075 6.1 Trichloroacetic acid 8.31°(6) 80 1839 8 Trichloroacetic acid, solutions of 8.32°(b) 80 2564 8 Trichloroacetyl chloride 8, 36°(6) X80 2442 8 Trichlorobenzenes 6.1.] 7°(c) 60 2321 6.lA Trichlorohutene 1 6.1. 17°(6) 60 2322 6.1 1, 1, I-Trichloroethane 6.1. l5°(c) 60 2831 6.lA Trichloroethvlene 6.1. 15°(c) 60 1710 6.lA Trichloromethylbenze1ie: see Be11zotrichloride Trichlorophenols 6.1. l 7°(c) 60 2020 6.lA Trichlorosilane (Silicochloroform) 4.3. 4°(a) X338 1295 4.3 + 3 + 8. Tricresylphosphate with more thai, 3 per ce111 ortho isomer 6.1. 23°(6) 60 2574 6.1 Triethylamine 3. 22°(b) 338 1296 3+8 Triethyl borate 3. 3 °(6) 33 1176 3 Triethylenetetramine 8, 53°(6) 80 2259 8 Triethyl phosphite 3.31°(c) 30 2323 3 Trifluoracetic acid 8. 32 °(a) 88 2699 8 Trifluorochloroethylene (R 1113) 2. 3 °(ct) 236 1082 ++ 1, 1, 1-Trifluoroethane 2. 3 °(b) 23 2035 ++ Trifluoromethane (R 23) 2. 5°(a) 20 19811 Triisobutylene (lsobutylene trimer) 3.31°(c) 30 2324 3 1126 E<DHMEPII: THI: KYBEPNHI:EOI: (TEYXOI: aEYTEPO) Name of substances (a) Trimethyl acetyl chloride: see Pirnloyl chloride Trimethylamine, anhydrous Trimethylamine, aqueous solutions of having a boiling point not more than 35 °C having a boiling point higher than 35°C 1.3.5-Trimethylbenzene: see Mesit\'lene Trimethyl borate T rimethylchlorosilane Trimethylcyclohexylarnine Trimethylhexamethylenediamines Trimethylhexamethylene diisocyanate and iso­ meric mixtures 2,6,.6-Trimethyl norpinanyl hydroperoxide (Pinanyl hydroperoxide: Pinane h\'droperoxide) with a peroxide content nol exceeding 95 per ce11l Trimethyl phosphite Tripropylamine · Tripropylene (Propylene trimer) Turpentine Undecane Valeraldehyde Valery! chloride Vanadium oxytrichloride (VOCI) Vanadium oxytrichloride (VOCL 1 ). aqueous solu­ tions of Vanadium pentoxide Vanadium tetrachloride (VCI) Vanadium trid1loride (VCL) Varnishes having a !lash-point below 2 I °C having a flash-point between 21 °C nnd 55 ° C (limit values induded) having a flash-point above 55°C Vinvl acetate Vinylbenzene: see Styrene Vinyl bromide Vinvl butvrate Vin~,I ehl~ride Vinyl c:hloroacetate Vinyl ethyl ether Vinyl fluoride Vinvlidene chloride Vinylidene fluoride: Sf'e 1.1-Dilluoroetln lene Vinyl isohutyl ether Vinyl toluene, mixed isomers Vinyltrichlorosilane White arsenic: see Arsenic trioxide Xenon Xenon, liquid. deeply refrigeral('O Xylenes (Dimethylbenzenes) Xylenols Xylidines Xylyl bromide Zinc chloride (ZnCI.,) Zinc chloride (ZnCI:). aqueous solutions of Zirconium tetrachloride (ZrCI I) Appendix B.5 Table II Class and item number (b) 2. 3°(bt) 3. 22°(a) 3.22°(b) 3. 3°(b) 3.21°(a) 8. 53°(c) 8. 53°(c) 6.]. l 9°(c) 5.2. 15°(a) 3. 31 °{c-) 8.53°(b) 3. 3] 00 (c) 3.3] 0 (c) :t 32°(c) :t 2°(b) H. 36°(b) 8. 21 °(b) 8. 5°(b) (d. 58°(b) 8. 21 °(a) 3.22°(c) 3. 5° 3. 31 °(c)* :). 32°(c)* 3. 3°(b) 2. 3°(ct). 3. :3 °(b) 2. 3°(ac (d. !6°(6) 3. 2°(b) 2. 5°(c) 3. ~ 0 (a) 3. 3°(b) 3. 31 °(c) 3.2] 0 (a) 2. 5°(a) 2. 7°(a) 3.3l 0 (c) (d. 14°(b) 6.1. 12°(b) (J.1. I 7°(b) 8. 22°(c) 8. 5°(c) 8. 22°(c) List of substances of Classes 3. 6.1 and 8 not listed b, name in Table 1 and not falling under a collective heading included in that table, but which nevertheless must he as­ signed to these Classes and to which no specifie «subs1,111c·e * See. howel'cr.· NOTE u11dt>r s,·,·Lion D of 111ar~i1wl :2:rn I. Hazard ldentifi cation No (upper part) (c) 236 338 338 33 X338 80 80 60 539 30 83 30 30 30 33 80 80 80 60 88 80 ;33 30 30 339 236 339 239 60 339 239 339 339 39 X338 20 22 30 60 60 60 80 80 80 Substance Identi­ fication No (lower part) (d) 1083 1297 1297 2416 1298 2326 2327 2328 2162 2329 2260 2057 1299 2330 2058 2502 2443 2443 2862 2444 2475 1263 1263 1263 1301 1085 2838 1086 2589 1302 1860 1303 1304 2618 1305 2036 2591 1307 2261 1711 1701 2331 1840 2503 Label (e) 3 + 6.1 3+8 3+8 3 3+8 8 8 6.lA 5 3 8+3 3 3 3 8 8 8 6.1 8 8 3 3 3 ++ 3 3 6.1 3 +·+ 3 3 3 3+8 3 6.1 6.1 6.1 8 8 8 identification number» is assigned. Substances arc grou­ ped according to Class and to the item number correspon­ ding to Lhe hazards pn~sented during carriage. NOTE This table applies only lo substances of Classes 3. 6.1 and 8 not included in table I. E<DHMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 1127 Name of substances Class and Hazard ldentifi- Substance ldenti item cation No fication No Label number (upper part) (lower part) (a) (b) (c) (d) (e) Inflammable liquids having a flash - point below 3. 1 °-5° 33 1993 3 21 ° C, not toxic and not corrosive Harmful substances and preparations used as 3. 6° 33 3021 3 ;t- 6.lA pesticides and having a flash - point below 2 l°C Toxic inflammable liquids having a flash-point 3. 11 °. 14°-18°. 336 1992 3 + 6.1 below 21°C 20° Highly toxic or toxic substances and preparations 3. 19° • 336 3021 3 + 6.1 used as pesticides, inflammable, having a flash point below 21 °C Corrosive inflammable liquids having a flash point below 21 °C • 3. 21 °-26° 338 .2924 3+8 Inflammable liquids, not toxic and not corrosive. 3. 31 ° 30 1993 3 having a flash-point between 21 °C and 100°C 3. 32° 30 1993 Highly toxic liquids, inflammable, having a flash- 6.1, letter (a) of 663 2929 6.1 + 3 point between 21 °C and 55 °C the items 11 °. 13°, 15°, 16°, 18°, 20°. 22°. 24° Toxic liquids, inflammable, having a flash-point 6.1. letter (b) of 63 2929 6.1 + 3 between 21 °C and 55°C the items 11 °, 13°, 15°, 16°, 18°, 20°, 22°, ) 24° Harmfull liquids, inflammable. having a flash- 6.1, letter (c) of 63 2929 6.lA + 3 point between 21 ° C and 55 ° C the items 11 °, 13°, lS 0 ,.l6°, 18°. 20°. 22°, 24° Highly toxic liquids, not inflammable or having a 6.1, leller (a) of 66 2810 6.1. flash-point above 55 °C the items 11 ° 24 °. 51 °. 55. 68° Toxic liquids, not inflammable or having a flash- 6.1. letler (b) of 60 2810 6.1 point above 55°C the items 11 ° 24°, 51-55°, 57-68° Harmful liquids, not. inflammable or having a fla- 6.1. leller (c) of 60 2810 6.lA sh-point above 55 ° C the items 11 ° 24°. 51-55°. 57-68° Highly toxic solids, combustible 6.1, letler (a) of 66 2930 6.1 the items 11°-24° Toxic solids, combustible 6.1. letter (b) of 60 2930 6.1 the items 11 °-21° Harmful solids, combustible 6.1. leller (c) of 60 2930 6.lA the items ,. 11 °-24° Highly toxic solids, not combustible 6.1. lelter (a) of 66 2811 6.1 the items 51 °. 55°, 68° Toxic solids, not combustible 6.1. letter (b) of 60 2811 6.1 the items 51 ° 55°. 57°-68° Harmful ~olids, not combustible 6.1, letter (c) of. 60 2811 6.lA the items 51 ° 55°, 57°-68° /2903 Highly toxic liquid substances and preparations 6.1, letter (a) of 663 6.1 + 3 used as pesticides, inflammable, having a flash- the items 74°, point between 21 ° C and 55 ° C 75°. 77°. 78°. 80 ° ' 81 ° . 83 °. 85°. 88° Toxic liquid substances and preparations used as 6. l. letter (b) of 63 2903 6.1 + 3 pesticides, inflammable, having a flash - point the items 74°. between 21 °C and 55°C 75°. 77°. 78°. 80 °' 81 °. 83 °. 85°' 88° 1128 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI .dEYTEPO) Name of substances Class and Hazard ldentifi- Substance Identi item cation No fication No Label number (upper part) (lower part) (a) (b) (c) (d) (e) Hl!:rmful liquid substances and preparations used 6.1, letter (c) of 63 2903 6.lA + 3 as pesticides, inflammable, having a flash - point the items 74°, between 21 °C ar:id 55°C 75°, 77°, 78°, 80 °' 81 °' 83 °' 85°, 88° Highly toxic liquid substances and preparations 6.1, letter (a) of 66 2902 6.1 used as pesticides; inflammable, having a flash - the items 74°, point above 55 °C 75°, 77°, 78°, 80 °' 81 °' 83 °. 85°' 88° Toxic liquid substances and preparations used as 6.1, letter (b) of 60 2902 6.1 pesticides, not inflammable or inflammable having a the items 7 4 °, flash - point above 55 ° C 75°, 77°, 78°, 80°' 81 °' 83 °' 85°, 88° Harmful liquid substances and preparations used 6.1, letter (c) of 60 2902 6.lA as pesticides, not inflammable or inflammable hav-. the items 7 4 °, ing a flash - point above 55 ° C 75°, 77°, 78°, 80°, 81 °, 83°, 85°, 88° Highly toxic solid substances or preparations 6.1, letter (a) of 66 2588 6.1 used as pesticides the items 74°, 75°, 77°, 78°, 80 °' 81 °' 83 °' 85°, 88° Toxic solid substances or preparations used as 6.1, letter (b) of 60 2588 6.1 pesticides the items 74°, 75°, 77°. 78°, 80°. 81 °, 83°·. 85 °, 88° Harmful solid substances or preparations used as 6.1, letier (c) of 60 2588 6.lA pesticides !;he items 7 4 °, "' 75°, 77°, 78°, 80 °' 81 °' 83 °' 85°, 88° Highly corrosive li~uids. inflammable. having a 8. letter (a) of the 883 2920 8+3 flash-point between 21 ° C and 55 ° C items 32°. 33°. •• 36°. 37°. 64°. 66° Corrosive or slightly corrosive liquids. inllarn- 8. letter (b) + (b) 83 2920 8+3 mable, having a flash-point between 21 ° C and and (c) of the. 55°c items 32 ° -34 °. 36°~39°. 51 °, 53°. 54°. 64°. 66° Highly corrosive liquids not inllammable or'· ha- 8. le11er (a) of the 88 1760 8 ving a flash - point above 55 °C items 1 °, 3 °. 10°, 11 °. 21 °. 27°. 32°, 33°. 36°, 37°. 64°. 66° Highly corrosive .liquids not inllammable or ha ving a flash - point above 55 ° C 8.26°(a) 88 1760 8 + 6.1 Corrosive or slightly corrosive liquids. not inflam- 8. letters (b) and 88 1760 8 mable or having a flash-point above 55 ° C (c) of the items l 0 • 3°. 5°. 10°. 11 °, 21 °, 23°, 27°. 32°-34°. 36°-39°, Sl 0 , 53°, 54°. 64°. 66° Corrosive or slightly corrosive liquids. 1101 inllam- 8, 26 ° (b) or (c) 80 1760 8 + 6.1 mable or having a flash-point above 55 ° C Highly corrosive solids. combustible 8. le11er (a) of the 88 2921 8 items 64 °, 65 ° <l>EK 104 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) Name or. st1bstanc·Ps Class and Hazard lndentifi- Substance Identi­ fication No (lower part) item catiou No 11u111ber (upper part) (a) (b) Corrosive or slightly corrosive solids. crnnbustible 8. letters (b) and (c) of the items 31 °. 33°-35°. Highly corrosive solids. 1101 co111bustihlP Highly corrosive solids. not co111hustible Corrosive or slightly corrosive solids. 1101 t'crn1hu­ stible Corrosive or slightly porrosi1e solid~. 1101 c-ombu­ stible 250 001 3 7 -3 9 °. 51 °. 52 °. 54 °. 64 °. 65° 8. letter (a) of the items 8 °. 11 °. • .27°. 65° 8. 26°(a) 8. lellcrs (b) a11d (c) of the items l l 0 • 22°. 26°. 2 7 °. 31 °. 33 ° 35°. 37°-39°. :I.] 0 • 0 i5 °. 65 ° 8. 26 (Ii) or (c) (c) 80 88 88 80 80 Identification numbers shall be shown on the plate as indicated below: § 0 "' c :1 j Background orange. Border, horizontal line and figures black, 15 mm thickness. 250 002 259 999 Appendix 8.6 (see marginal 10381) The certificate of competence for drivers of 1·ehicles car­ rying dangerous goods issued in co11fonnit1· with the pn's­ cription in marginal 10 315 shall hal'c the layout as rPp­ roduced in the model below. It is recommended tlrnt till' format shall be the same as the European national dri1 ing permit. namely A 7 (74 X 105 111111) or a double sheet whi('h can be folded to that formal. (for model eeriificate see m·er) • (d) 2921 1759 1759 1759 1759 Identification number of danger (2 ou 3 figures) Identification number of substance (4 figures) 260000 Label (e) 8 8 8 + 6.1 8 8 + 6.1 1129 1130 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) Appe11dix 8.6 1 ADR - TRAINING CERTIFICATE FOR DRIVERS OF VEHICLES CARRYING DANGEROUS GOODS Certificate No Distinguishing sign of issuing State ..... Valid for class( es) 1 / 2/ until ( date fl1 la, lb. le 2 3 4.1, 4.2. 4.3 5.1. 5.2 6.1, 6.2 7 8 I/ Delete those not applicable 21 For extension to other classes. see page 3 31 For renewal, see page 2 EXTENDED TO CLASS(ES)51 la, lb, le, 2 3, 4.1, 4.2, 4.32 5.1, 5.2, 6.1, 6.2 7, 8 la, lb, le, 2 3, 4.1, 4.2, 4.3, 5.1, 5.2, 6.1, 6.2, 7, 8 la, lb, le, 2, 3, 4.1, 4.2, 4.3, 5.1, 5.2, 6.1, 6.2, 7, 8 3 Date ................. . Signature and/or seal or stamp Date ................. . Signature anq/or seal or stam·p Date ................. . Signature and/or seal or stamp ....... .- ............ . 51 Delete those not applicable 2 Surname ....................................... . First name(s) .................................... . Date of birth • .............. Nationality .... , ....... : . Signature of holder ............................... . Issued by .................... : .................. . Dale ................... • •. •; • • • • • • • · · • • • • • • • · · · Signature4/ •........•......•.••...•.••.••..•.••••.• Renewed until By ............................................ . Date .......................................... . Signalure41 ............................•.......... 4/ and/or seal Jor stamp) of issuing authority 4 For national regulations only EQ>HMEPII THI KYBEPNHIEQI (TEYXOI AEVTEPO) 1131 OIKONOMIKH EilITPOilH fIA THN EYPOilH 'o , EilITPOTTH META<I>OPQN ELOTEPIKOY EYPOilAIKH LtM<l>ONIA fIA TH ME0NH OAIKH META<l>OPA ETTIKINIHNON EMilOPEYMATON (ADR) KAI TTPOTOKOAAO rnorPA<l>HL LUVE'tory71 xor:L' u1tqpci:cp71 O't'J) r EVEUTJ 't'J)V 30 LE1t'tEJ.Lf3plou 195 7 TOMOt I (tuµcpc,mci:, Ilpw-coxo)J.o Y 1to1pcxcp7Jc; xcxL Ilcxpci:p-c71µcx A) HNOMENA E0NH N. Y6px71, 1985 IlPOAOfOt To 1tcxpcxxci:-cw xEip.Evo 1tEpLAcxµf30:vaL, EX-coc; cx1t6 't1) tuµcpwvlcx Xotl Tipw1:oxoAAo Y 1toypcxcp7Jc;, -ccx Ticxpcxp"C7Jµcx-ccx fLE 't1J µopcp71 µa -c71v 01toicx cE071xcxv aE Lax,u -c71v 29 IouAiou 1968, xcxBwc; xcxL ,Le; 'tpo1to1tOL1JOELc; cxu cwv, µix.pL -c71c; l 71c; Mcxtou 1985. . H f p1XfLfLIX'tELIX 't'J)c; 0LXOIIOfLlXljc; Em-cpo1t7Jc; l'LIX -CT)\I Eupw1t71 Em0u­ µ.l VIX axcppiicrEl -c71v EX-ciµ71a71 't'J)c; XOtL 'tlc; auxcxpLa-ciEc; -CT)c; 1tpoc; 't'IJY ALE· Bv71 'Evwa71 Mrnxcpopwv (IRU) 1L0t 't'IJV f307JBELIX -c71c; O't'IJV OLEux6Auvcr11 c71c; auv-cci:~Ewc; XIXL 071p.oaLEua.wc; 't71c; 1t0tpoua"lc; cxvcxB.wp1Jµiv71c; .xM­ a.wc; Eupw1t0ti:x71c; Luµf3ci:a.wc; 1tou 0tcpopci: ,Le; ALaBv.ic; OoLxic; Ma'tcxcpo: pie; (ADR). • EYPOTTAIKH LYM<l>ONIA rIA TH AIE0NH OAIKH META<l>OPA EilIKINAYNON EMTIOPEYMATON (ADR) TA LYMBAAAOMENA MEPH, Eil!0YMOYNT A vex OtU~1JO'OUV 't'IJV cxacpo:AELOt 't'Tjc; OLEBvouc; OOlX7jc; fLE· ccxcpopo:c;, LYM<I>ONHLAN -ccx 1tcxp0txii-cw: 'ApBpo 1. r llX -c71v Ecpotpµo,71 't'J)c; 1t0tpouacxc; Luµcpwvi0tc;, (o:) µE 'tO\I opo «0)'.,'l](J-IX» VOOUV'tO:l -COt IX\l'tlXiv71't0t, 0tpBpw-cci: OX.TJfLOt'tOt, pup.ouAxoup..vcx OXTJfLOt'tot (TRAILERS) XOtl Tjf1-LpuµouAxoup..v0t (SEMI TRAILERS), 61twc; opi(E'tlXl O'tO ci:pBpo 4 -c71c; Luµf3cxo71c; TT.pt OoLXTjc; KuxAocpopi0tc; 'tTjc; 1971c; LE1t-cap.f3piou 1949, Ex-coc; 'twv ox.71µ0:'twv 1tou OtlllJXOUV T\ 'tEAouv \llt() ·nc; OlOt't0tyic; 'tWV EVOltAWV OUVO:fLEWY 'tO\l Lup.f3cxA­ AofLEVO\l Mipouc;· ({3) fLE 'tOY opo «EmxivouvOt EfL7t0pEUfl-Ot'tOt» \IOOUV-CIXl Ol UAEc; Xotl 't(X El01j cwv 011:oiwv 71 OLEBvljc; OOLXTJ µa1:0tcpopci: 0t1t0t1opEuE'tlXL 0t1t6, T\ Em'tpE1tE't0tl µovov \)lt(J WpLaµivouc; opouc; IXltO 't(X flcxpcxp'tTjfl-ot'tOt A XIXl B· (I) fLE 'tOV opo «OlEBVTjc; fLE'tOttpOp!X» VOEi-cCXL OltOL0t6Tj1tO-CE EltlX,ElpTJO'IJ µa-ccxcpopiic;, Ex-c.Aoup.Ev71 a-c71v E00tcpLX7J 1tEpLOX,1J (Emxpclt-cu0t) Mo 'touAii­ X,La-cov Lup.f30tAAOfLEVWV M.pwv fLE OX,Tj!'-Ot't(X 1t0\l opi(ov-tCXl 0-CTj mo ltO:YW 1t0tpci:1p0tcpo (cx). 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Mo111X6ei; µe-cp71oewc;;: (1) OL E~71,; µ0111X6ei; µ,e-cp71oew,; 1/ ecpapµo,ov-ccx1 o-co 1t0t- 2001 pov TTap1Xp-c71µ0t XCXL O"'CO TT0tp<Xp-c71µcx B: METPH.EH SI MONA.E 2/ aEKTE.E ENAA. .EEj.EH AAKT. MONME.E METASY MONAMlN M11xo,; fl· (fthpo) Emipiivucx l'-2 (ntp. flhpo) .'Oyxo,; l'-3 (xu~. flhpo) 1 Aitpo 3/ 10-3 l'-3 Xpovo,; s (lim•poA.) J\1IN. AElttO 1 ).,mo: 60 61. H wp0t 3600 Ii). D 7lf1ipcx 86400 Ii). Mix~cx KG Kv-o G yp0tflflixpw 10-3 XLAIX T 'tOVVO<; 103 XlAIX nuxVO'tT}<; fl/X~7l- XLAO/f'-3 xJ.o/).ltpo 10-3 XLA/f13 0Epf10Xp1XO<<X K KELVIN C ~0t8. K•).a[ou (273.15 K) a,cxipop,x 8Epf10Xp. K (KELVIN) C ' 1 C: lK. Iaxu, N NEWTON 1 N: 1 XLA. f1/S2 m.OT) PIX (PASCAL) BAR 105 P0t Tix01J N/1'-2 NiMM2 1 MP0t 'Epyo J (Zou>-) 1 J:l N,fl:l W.S Evipyi:,0t J (Zou).) 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OE\/ 1tpi1tEL VIX ,u,i~EL 7t0t\lW IX7t0 75 KG· XOAO\I t7Jc;; I (r) OE\/ 1tpE1tEt VIX ,u,i,Et 7t0t\lW IX7t0 10 KG. KoAO\I 'tTj<; (I) (~) 2, ri (I) (6) OE\/ 1tpi1tEL VIX ,u,i­ 'Et 1tti:vw cx1to 25 KG. Ko).cx .ex 01toicx, µe 'to 1teptexoµevo couc;, ,uri,ouv 1tti:vw cx1t6 30 KG 0cx ei11cxt erpootcxoµivcx µe xetpoAIX~Ec;;. ( 1) ·n~c;; 'tTJ<; 10 ° 0cx OUOXEUOt,0\l'tlXt: OXt Ot\lW "CW\/ 500 1p1XfLfL1XpLW\I IX\IOt OOtXXO\I, OE onpEOt OEfLE­ \IOU<; oti:xxouc; cx1t6 XIX'tW7JAO euxcxµ1to uAtxo· xti:0e oti:xxo.; e·cx -co1to8eni-ccxt oe xu-cio cx1t6 µi-cillo, tvw67] - ocxvi6cx ri X1Xp't0\IL (xcxp-C001X\li61X)' IXU't(X 'tlX XU'tLIX, O"/ L 7tEptOOO'tEp1X IX7t0 30 cxvdt xt~w-cto ouoxeucxoicxc;;, 0a oupewvov-ccxt µe cx1too~E­ cmxo UAtXO OE 1;uAt\lO Xt~W'tto OUOXEUIXOLIX<; fLE 7tAT)pEtc; 7tAEU­ pic; 1tdtxou.; oxt µ1xpo-cipou 'tW\I 12MM (xtAtoO'tWII). (2) To XOAO\I OE\/ 1tpi1tEt VIX ,url,Et 7t0t\lW IX7t0 25 KG. (J) •nee; XIXt Ei6TJ 'tTj<; 11 ° 0cx OUOXEUOt,O\l'tlXt: 2109 2110 (ex) uAec; •7J<; 11 ° (ex) xcxt (~ ): (1) oxt Ot\lW 'tW\I 2.5 KG CX\IOL odtxxov, OE odtxxouc; 't01t08E­ 'tTJfLE\IOUc;; OE xu,:icx xex-ccxoxwexoµivcx CX7t0 t\lWOTJ oexvioex, 7tAOt­ xec;; xexoo:ti:Epou T) cx1t6 CXAouµl11to. Tex xu-clex 0cx onpewvov-cext p.e. ex1too~eo-ctx6 uAtxo oe 1;uAtvex ei6TJ ouoxeucxo[cxc;· T) (2) OE odtxxouc; xex-cexOXEUCXOfJ-E\IOU<; ex1t6 UtpCXOfJ-CX fJ-E 7tUX\IT) uq,exvcrTJ, -co1to8E'tTJ(J.Evouc;; ae 1;uAt11cx xt~w-ctcx· (~) Ei67] "CTJ<; 11 ° (r): poUexptoµivex fLE repo xcxpfr xdt0e po­ AO<; 05\1 1tpi1tEt \/IX ~url,Et 7t0t\lW ex1t6 300 rpexµµdtpLex. Ot poA­ AOt 0ex 't01to8nouV'tCXt OE 1;uAt\lO XL~W'ttO E7tE\IOEOU(J.EVO (J.E 1epo xcxp-cL (2) Tex xexAufJ-µex-cex -cwv 1;uAivwv xL~w-clwv 0ex oupewvo­ v-ccxt fJ-5 ~loec;· EOL\I Ot ~ioEc; EL\ICXL xex-ccxoxwexoµEvec; CX7t0 oloepo 0cx emxpiov,:ext µe UAtxo 1tou 6e11 0cx 1tcxpdt1et omv0ripec; 6-ccxv U7tOO't5L xpouOTJ T) tpt~T)- • (3) To XOAO\I OE\/ 1tpfoet vex ,uri,Et TiEpLooonpo CX7t0 75KG EOt\l (J-E'tex<pEpE'tlXt we; 't(J-T)(-1-ex 7tAT)pouc; (j)Op'tLOU, xext OXt 7tEpto­ OO'tEpo cx1to 3 5 KG EOLV oev µe-ccxq,Epe-cext we; 'tfJ-T)(-1-CX 7tA ripouc; q,op-ciou. (I) 'YAEc; •7J<; 12 ° 0cx q,u0Lnto1t0Lou11-cext µioex oe 1tept-cu­ Ai1µcx-cex xcx,:exoxeucxoµi11ex: ex1t6 XCX'tOtAATJATj 1tAexO'ttXT) UATJ ri xcxp-cL Tex q,uolntcx 0cx ~u0l­ 'O\l't(Xt OE XTJPO 1texpcxq,l117Jc;;, X7Jpo,iv7Jc; ri p7J-clvTJ, ri 0ex wAl,o­ v-cext 05 xcx-caAA7JATJ 1tAexo-ctxri t>ATJ, wo-ce vex 1tpoo-cexnuov,:cxt ex1t6 'tTjll urpexolcx. Exp7JX'ttXOt • 7tEptixov-ccx 7t0t\lW ex1t6 6 o-cex Exex-c611 urpouc; Vttptxouc;; EO'tEpexc; 0ex rpuotnto7tOLOU\l't(XL fJ-E xexp-cl E7tEIIOEOU(J-EVO fLE X1jp611 1tcxpexq,iv7Jc;; T) X7Jpol;iv7J T) fJ-E cxotcx1tipcxo-c7J 7tAexonxri UA TJ 61twc; "CO 7t0AUCXL0UAE\lt0. Tex <pt>· ointex 0cx 't01to8E'tOUV'text OE 1;uAtllex ELOTJ ouoxeuexolexc;. (2) <l>uoi11tex fLTJ E7tE\1050UfLEIICX fLE X7Jp011 1tcxpex<piV7J<; T) X7J­ po/;i117JV, T) q,uol,,tcx OE exotex1tEpcxo-ccx 7tEpt-cuAl,µcx-cex, 0ex rlvo­ V'tCXt 7tCXXE'tCX 7t0U ~uri,ouv oxt Ot\lW 't'W\I 2.5 KG "CO xex0ivcx. 'E-cot xexi:cxoxwexoµivex 1totxii:cx, 'tex 7tEpt-cuAi1µcx-ccx -cwv 01toiw11 1tpi1tEL vex ex7tO'tEAOU\l'tott 'tOUAOLXtO'tO CX7t0 iEPO xcxp~i, 0cx ~uei,0111:ext OE X7jp6 1texpcxq,l117Jc;, X7Jp0,LVTJ T) PTJ'tLVTj T) 0cx 7tE­ pt'tUAi,ov-cott µe xcx-cdtAA7JA7J 1tAexo-ctXT) UA7J wou vex 1tpoo-ccx­ ceuo11-ccxt CX7t0 'tTj\l urpcxolex. ,:ex 1texxhcx 0cx 't01to8nouv-cext OE 1;uAt\lCX ELOTJ ouoxeucxolcxc;. (3) Tex xAEtoiµex,:cx -cwv 1;uAivwv Etow11 ouoxeuexolcxc; µ1to pouv vex exoq,cxAi,ov,:cxt: c • . fLE fLE't<XAAtxic; AwpioEc; T) oupfJ,ot'tex oeµivex O<ptX'tOt rupw -couc; .• ( 4) To xoAov oev 1tpi1tet vex ,u,i,EL 1tdtvw cx1t6 7 5 KG. l\ev 1tpi1tEL \lot 7tEptiXEL 7t0t\lW CX7t0 50KG EXpTj'ttXW\I, (5) A11-ci -cwv 1;uAi11w11 ouoxeucxotwv -cwv 1tpo~AE7tOfJ-EVWY oi:tc;; 1tcxpcxypti:rpouc; ( 1 )xext (2), em-cpi1te-ccxt E1tio7Jc; vex XP7JOt­ µ01totouvi:cxt xcxi:0tAA7JAot xt~w-ctcx, xex-cexoxeuotofJ,ivcx ex1t6 on­ peti: tvw67J ocxviocx ri xuµcx-coetori t11w67J .ocx11i6cx, 1tou eivext E1tcxpicouc; fL7JXCXVLXT)<; exv,:OXTJ<; XCXt 'tWII 07tOtW\I "CCX 7t'tEpt>1 tot (xAex1tii:cx) ,:wv x<XAuµµti:-cwv xcxt 1tu8µi11wv 0cx 1tpi1tet vex XAEi­ vov-cext µe XOAATj'ttxic; 'tottviec; rncxpxouc;; CXV'tOXTJ<;, To crxioto cwv xt~w-ciw11 i:w11 xexi:cxoxeuex,oµivwv cx1t6 onpedt 1vw67J oex­ vi6cx ri xuµcx-coetori LIIW07J oexvi6cx 1tpi1tet vex e1xpt0ei ex1t6 "CTJII expp.66tex cxpxri 'tTj<; xwpcxc; •Tj<; cxvcxxwprioewc;. 'Evcx 'tE"COto xo­ AO\I oe11 1tpi1tEL vex ,u,i,et 1tdtvw ex1t6 30 KG· oe11 1tpi1tet vex 7tE­ pLEXEt 7t0t\lW ot7t0 25 KG EXpTj'ttXOt. (I) OL 'nee; "CTJ<; 13 ° 0cx .q,uotnto7tOLOUV'tCXL xdtp-ctvot 7tEpt­ 'tUAi,µcx-ccx. <I>uointcx fLTj E7tLXPLOfLE11ot fLE X7jp611 1texpcxq,i117J.; T) X7Jpol;iv7JV 1tpi1tEL expxtxdt \lot rivou11 poUot fJ-E xcxp-ci "CO 01toiov EXEL xcx,:cxoni ex6tcx1tipcxoi:o. 0ot xcx-cexoxeudt,011,:cxt ot1t6 xdtp­ ctvo 1tEpL-cuAt1µcx oe 1texxi-ccx ,u,i,011'tex dtvw -cwv 2.5KG ,:o xex0Evot, XIXL 0cx O'tEpEW\10\l'text µe ex1too~EO'ttXO UALXO OE 1;uAtllot ELOTj ouaxeuexoiexc; 'tW\I 01toiwv "CO XAELOL(J-0 fJ-7t0pEi \lot e1;otorpci­ Ai,E'tott otot µe-ccxUtxwv 'tottvtwv T) oupµdt-cwv oi:epewµEvwv oq,txi:dt 1tEpt1; cxui:wv. ' (2)To XOAO\I OE\/ 1tpi1tEt \lot ,uri,Et 7t0t\lW ex1t6 35 -KG. (I)'nec; 'tTj<; 14 ° 0ot OUOXEUOL,0\l'tott: ( cx)uAEc; 'tTJ<; 14 ° ( ot): rpuotnto1tOt7Jµivec; OE 7tEpt-cuAi,µot-cot xot-cotoXEUotoµivot ot1t6 Xotp'ti -co 01toio EXEL xcx-coto-cei ototot1tEpcx­ oi:ot. Tot rpuoi,,tex 0ot 1texxE-c0tpov-cext µe xdtp-ctvo 7tEpt'tUALifLot T), EOL\I xwpic; xdtp-ct\10 7tEpt'tUALifLex, 0cx oi'epewvov'texL fLE exopcx­ vi.; ot1too~Eo-ctx6 uAtxo oe 1;uAtvex eio7J ouoxwexoiot.; -cwv 01toiwv 'tO xAEiotµo µ1topei 11ot e1;exorp<XAi,ov-cott oLcx fJ-E't<XAAt­ xwv 'textvtwv ri oupfJ-Ot'twil oeµivwv ( oupewµivwv) oq,tx-cdt ,upw -couc;. (/3) UAE<; 'tT]c;; 14 °(/3): qnioLnto7tOt'rJµEVE<; OE 7tEpt'tUAiyµcx-ccx 2111 2113 2114 E<DHMEPII: THI: KYBEPNHI:EQI: (TEYXOI: .dEYTEPO) Xot'totOX!Uotoµivot ot7t0 Xotp'ti 'tO 07t0LO ixet Xot'totoni ot6tot1tipot­ O'tO. Tot cpuointot 9ot 't07t09!'tOUV'tott O! XU'tio ot7to t11w671 Oot­ vi6ot. Tot XU'tlot ot7t0 tyw671 ootvi6ot, 7t!pt'tUAtrµivot µe Xotp'ti 'tO 07t010 exat Xot'totO't!L ot6tot7tEpotO'tO, 9ot O't!fl!W\10\l'tott, •xwpu; vot otcp7111ou11 xavcit 6toto't711,Lot'tot, oe ~uAtvot ei671 ouoxauotoiotc;; 'tWII 01toiw11 'tO XAELotµo µ1topei \lot e~otocpotAtO't!L µe µ~'totAAt­ x~ 'tottviec; 11 oupµot'tot 6eµivot (O't!pawµivot) ocptX'tlX rupw 'tOUt;. (r)u).ac;; 't7lt; 14°(1): 1. cpuotTTto1tot71µivec;; oa 1t!pt'tt.1Ai1µot'tot Xot'totoxauotoµivot ot7t0 Xot'till7JA7J 7tAotO'ttx71 UA7J TI Xotp'ti. Tot cpuointot µ1topou11 1101: eµ~u9i,ov'tott oa x71po 1totpotcpiv71c;, x71po0117111 71 PTJ'tLIITJII 71 vot 1t!pt'tt.1Ai1011'tott µe Xot'tillTJATJ 1tAoto'ttx71 iJ)..71, won vot 1tpo­ cpu1.citooov'tott ot1to 'tT)II u1potoiot. Exp71'ttxcit 1teptEXOV'tot citvw 'tOU 6 O'tot !Xot'tO\I u,pouc; Vt'tptxouc;; !O'tEpac; 9ot cpuotTTto7tOtoU\l'tott µa Xotp'ti !7ttXf)tOl,LEIIO µe x71po11 7totpotcpi117jc; TI x71po0117111 TI ot6tot1tipoto'tl'j 1tAotO'ttx7l UATJ 01twc; 'to 7tOAUott9uAivtov. Tot cpu­ OLTTtot Bot 't01to9a'tOUll'tott oa ~UAtllot ai671 ouoxauotoiotc;· 2. cpuointot µ71 !7ttXflLOl,LEllot µa x71po 1totpotcpi1171c;; TI x71poOv71c;;, 71 cpuointot oa ot6tot1tipoto'tot 1tapt'tt.1Ai1µot'tot, 9ot 1totpotoxaucit,o 11'tott O! 7totXE'tot ~u,i,Oll'tot oxt 7tot\lW ot7t0 2. 5. KG 'tO xot9ivot. Tot 7totXE'tot otu'tot, 'tWII 01toiw11 'tO 7t!pt'tUAt1µot 1tpi1tat \lot dvott 'tOUAotXtO'tO\I ot7t0 )"!po Xotp'tt, 9ot aµ~uBi~OV'tott O! x71po 1totpot­ cpi117jc;, x71pol;i117j 71 p71·ti1171 71 9ot 1tept'tUAt')"OV'tott µa xot'totAA7JA7J 7tAotO'ttx71 UAT), WO't! IIOl 7tfl00'tot't!UO\l'tott ot7t0 'tT)II urpotoiot. Tot 1totxi'tot 9ot 't01toBa'tou11'tott oa ~uAtllot d671 ouoxauotoiotc;. 3. To x1.dotµo 'tWV tu)..ivwv ouoxwototwv µ1topai vot atot­ ocpotAi~a'tott 6tot µnilltxwv 'tottvtwv 71 oupµcit'twv 6aµi11w11 ocptX'tot ')"UpW 'tOUt;' , 4. otll'tt 'tWII tu1.i11w11 ouoxwototwv 'tWII 1tapt1potcpoµi11w11 o'ttc;; otvw'tipw 7totpot1pcitcpouc; 1 xott 2, £1tt'tpi1tnott e1tio71c;; 71 XP7Jotµo1to!71071 Xot'till71)..w11 xt~w'tiwv, Xot'totoxauotoµivwv ot7t0 O't!p!ot t11w671 oot11i6ot TI xuµot'tO!t671 t11w671 ootvi6ot 7t0U ei­ \lott !7totpxouc;; µ71xot11tx71c;; ot\l'tOX'Tlc;; Xott 'tW\I 07t01Ca>\I 'tot mapu­ ')"Lot ( xAot7tE'tot) 'tWII xilluµµot'tWII Xott 1tuBµi11w11 9ot 1tpi1tet vot XA!l\10\l'tott µe XOAA7J'ttxic; 'tottviac;; !7totpxouc; ot\l'tOX7lc;;, To axi 6to 'tWII Xt~W'tlW\I 'tW\I Xot'totOX!UotOl,LEIIW\I ot7t0 O't!p!ot tllW67J ootvi6ot 71 xuµot'toat671 t11w671 ootvi6ot 1tpi1tat vot e1xpivnott ot1to 't1JII otpµo6tot otpx71 'tTJc;; xwpotc;; 't7Jc; otvotxwp71oewc;. (2) KoAO\I 7t!ptixov UA!c;; 'tl'jc;; 14°(ot) 71 (~) 6ev 1tpE1t!t \lot ,u,i~et 1tcit11w ot7t0 35KG. KoAO\I 7t!ptixov UA!c;; 'tl'jc;; 14° (r) oev 1tpi1tet vot ,u,i,at 1tdt11w ot7to 7 5 KG· oav 1tpi1tat vot 1tepti­ XEL axp7J'ttXot 1tdt11w ot7to 50 KG. L'tl'j 1tapi1t'two71 ouoxauotoiotc;; 'tT)c; 1totpot1pcitcpou 1(1) 4, 'to xoAov 6av 1tpi1tEt \lot ~u1i,at 1tdtvw <X7t0 30 KG OU't! \lot 7t!ptEXEt EXp7J'ttXot 7tot\lW ot7t0 25 KG .. 3. Mtx,71 auoxauotoiot •nac;; ot\lot')"potcpoµa11ac;; Xot'tW ot7t0 otptBµov !LOOUt; 'tOU 7tept­ Bwpiou 2101 6av 1tpi1tat vot ouµ1taptJ.otµ~citvov'tott O'tO otu'to xo)..011 du µa iJ)..ac;; 0µ01:601tot71µivac;; Xot'tW ot7to 'tOII otu'tov 71 illov otp19µov ai6ouc;; 'tou 1taptBwpiou otu,ou, du µa iJ)..ac;; 71 aµ1topatiµot'tot illwv KAcitoawv, dn µe illot aµ1topau µot'tot.- ' L71µaiwo71: KoAot otvotcpepoµavot O'tO 7teptBwpto 2108 (1) (,) µ1topouv \lot 7teptexouv op,otvtxcitc;; ot~Ca>'tOUXOUc;; ouv9ioetc;; !XOUOotc;; faotcpope'ttXEt; OUV9EO!tt; Xott ovoµotoiac;. 4. Ev6aitatc;; (µotpxdtptoµot) xott !'ttxinc;; xtv6uvou E1ti 'tWV xo)..wv (~AE7tE IlpooBiJx71v A. 9). KoAot 7teptEXOV'tot mxptxov otu (70° (ot)) Bot µotpxcitpov'tott µa 't1JV ovoµotoiot 'tT)t; u)..71c; µa ootcpaic;;, wotVot')"VWO'touc;; xott ot11a­ th71)..ouc; apuBpouc; xotpotX't7lpec;. To µotpxcitptoµot otU'tO Bot dv~t O't7JV !7tl01J!L1H AWOOot 't7lc; XWP9(.; 'tl'jc; otvotxwp71aawc; Xott E1tt 071c;;, acitv 71 1)..waoot otu,716av dvott 71A11AtxiJ,7171 filltx71, TI 71 fapµotvtXTj, O't7III An1.tx71, filltx71 TI fapµotvtx71, !X'toc;, !otll, 'tuxov, ootoµoM,tot 6ta9vouc;; o6txiJc; 1,LE'totcpopcitc;, 71 ouµ­ cpwviac; auvotcpBaioec; µa'tottu 'tWV av6totcpapoµivwv 1 tot ,7111 am­ xaip71071 't7lt; l,L!'totcpopcitc; xpot'tWV, 1tpo~AE7tOU)I otUtwc;;. ( 1) KoAot 7teptEXOV'tot UA!c; Xott !t671 'tl'jc;; K).dtoawc; 1 ot Bot cpi­ pouv ntxE'tot auµcpwvov 1tpoc; 'to µov'tEAO No 1. (2) KoAot 7t!ptEXOll'tot auBpotO'tot 6oxeiot µ71 opot'tot ot7t0 itw Bot cpipouv anxi'tot ouµcpwvov 1tpoc;; 'to µov'tiAo No 12. Ecitv 'tot auBpoto'tot ooxaiot 7teptixouv urpdt, 'tot XOAot ocpaiAouv !7tt7tpo­ o9i-cwc;, ax'toc; 1tpoxatµivou 1tapi oqipot1toµivwv otµ1touAwv, vot cpipouv !'ttxi'tac; ouµcpwvwc; 1tpoc; 'to µ011'tEAO No 11, ot !'tt­ xinc;; otu'tic; Bot 't01toBa'touv-cott tji71)..dt oa Mo otV'tilleuc;; 7tAEupic; 'tWV xt~w'tiwv iJ xot'tot taoMvotµov 'tpo1to11 oacitxtc;; xp71otµo 1totolinott citUot ai671 OUOX!UO(Oiotc;;. 21'15 2116 2117 B. Aamoµepmc; 'tOU !')"')"potcpou 'tl'jc;; IJ,!'totcpopcitc;. ( 1) H 1tept,potcp71 't(a)\I aµ1topauµot'tWV O'tO inpot<po (l!'tot­ <popcitc; 1tpi1tat vot aivott ouµcpwv71 1tpoc;;, µiot11 -cwv ovoµototwv 't(a)\I U7tO')"potµµtoµivwv O'tO 7tept9wpto 2101. 'O'totV 71 ovoµot­ oiot 't7lc;; iJ)..71c; 6av xotBopi~e'tott O'tTJ 1tapi1t'two71 'tT)c;; 8 ° (ot) xott (~ ), Bot 1tpi1tat vot xp71otµo1totahott 71 aµ1toptx71 ovoµotoiot. H 7t!pt,potcpT) 'tWV aµ1topauµot'tWV itpi1tEt \lot U7t0')"potµµi~!'tott µa xoxxtvo xott vot otxo)..ouBahott ot1to A!7t'toµipatac;; 'tT)t; KAcitoawc;;, 'tOU otptBµou 'tOU ai6ouc;; (oµou (lE, 'tO 'tUXOII, 1potµµot), Xott 'tot , otpxtxcit «ADR» 71 «RID» (1t,X, lot 3 ° (ot) ADR)). (2) Tot 7totpotXot't(a) 1tpE1tEt \lot ~!~otLOUll'tott O'tO inpotcpo 't7lc;; µa'tot<popcitc;;: •H cpliotc; 'tWV aµ1topauµcit'twv, xott 'tO ai6oc;; 'tT)c; OUOX!Uotoiotc;, !L\lott ouµcpwvot µa -ctc;; 6tot'tottatc; -c71c; ADR». (3) r tot ot7tOO'tOAEc;; Ot 01toiac;, U7t0 7teptBwpto II 105 'tOU Tiotpotp'tTJ(lot'toc; B, 1tpoxmott vot 1ivouv 6ax,ic;; 1tot (lE'tot<popcit we; 7tATjpec; cpop'ttO Xott µovov, 'tO inpotcpo 'tl'jc;; (lE'totcpopcitc; Bot Etxovi,at a1ti07Jc; 'tO ~citpoc;; xcitBa xo)..ou xott 'tOII otpt9µov xott 'tT)V <ptio71 'tWV atowv ouoxwotoiotc;;. r. Kavcit ai671 ouoxwotoiotc;; ( 1) Tot ai671 ouoxwotoiotc;; 'tT)c;; 15 ° 1tpimt vot aivott oto<potAwc;; XAEtaµivot Xott O't!')"otllot O'tO\I i6to ~otBµo, Oot\l \lot 71oot\l "J"!(lot'tot. (2) • Aomc; OUOXEUotOLEt;, otXotBotptO'tec;;, 'tl'jc;; 7totp. 15 ° Bot <pipouv 'ttc; i6tac; E'ttxhac; xtvMvou, ootv \lot iJoot11 1aµcituc;. (3) H 1tept1potcp71 o'to i11potcpo µa'totcpopcitc; 1tpi1tat vot aivott: «Kavov XOAO, lot, 15 °' ADR (iJ) RID». H 7tept,potcpT) 1tpE1t!t \lot U7t0')"potµµt,E'tott. • KAALH I~. - EI~H rEMILMENA ME EKPHKTIKEL YAEL 1. Kot'totAO')"Ot; EtOW\I, ( 1) Ma-cot;u 't(a)\I Et6wv 7t0U XotAU7t'tOV'tott ot7t0 'tOV 'tL'tAO\I c71c; K)..dtaewc; I~. µovov 'tot otvot,potcpoµavot O'tO 7teptBwpm 2131 Bot ')"IVOV'tott 6!X'tot ,tot µa-cotcpopcit, Xott 'tO't! µovov U7t0 c71v amcpliAot;71 -cwv 6tot'tot;awv 'tOU 1totpcivwc; Tiotpotpni~cuoc; Xott 'tou 1totpotp-ciJµot'toc; B. Tot ai671 otU'tot 'tot 01toiot 1ivov'tott 6a­ X'tot u1to wptoµivouc; cipouc; Bot Bawpounott we; ai671 't7lc; ADR. (2) Ecitv 'tot ai671 'tot ot\lot')"potcpoµavot ate; 7°' 10° TI 11 ° 'tOU 1tapt9wpiou 2131 ouv'ti9!V'tott ot1tci, 71 aivott 1aµtoµivot µe, axp71xnxic; UAec;; 7t0U otvot,pcitcpov'tott O'tO 7t!pt9wpto 2101, OL UAec; otU'tEc; 1tpE1t!L \lot 1tA71pouv 'tOuc; otcpopwnotc;; otU'tOUc;; opouc; O'totBapo't7l'totc; xott otacpotAaiotc; 'touc; otvot1pot<poµivouc; O'tTJ Ilpo­ oBiJx7I A. I. 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(2) To xoAov 6Ev 1tpE1tEt vot ~u1i~Et 1tdtvw ot1t6 50Kg. ( 1) Ei671 'tTjc; 4 ° ( ot ), (~) xott ( E) Bot 'to1toBEwu11'trJ.l acptX'tot aE 213 6 O'totBEpot XAELOfJ-Ellot XU'tLot Xot'totaxwotaµevot ot7t0 EAotaµot, ;u)..o 7] tvw671 aotvi6ot· 'tot XU'tLot otU'tot Bot 't01toBE'tO\lV't(Xt, xwpic; XE\10( 6tota't7](.J.ot'tot, aE xt~W'ttot auaxwotaiotc; Xot'totaxwotaµevot ot1t6 µiwMo, ;uAO, OXATJPTJ aotvi6ot, anpEot tvw671 aotvi6CX.7] xuµot 'tOEL67] tvw671 aotvi6ot· TJ Lvw671c; aotvi6ot 1tpE1tEL Vot EXEt "(LVEL ot6Lot1tEpotO'tTj 6L' EfJ-7tO'ttaµou XotL Vot ELVrJ.l E7totpxouc; fJ-TJXotllt XTjc; otV'tOX7Jc;. KL~W'ttot ot7t0 tvw671 aotvi6ot Bot XAELOV'tott [J.E XOAATj'tlXEc; 'tottviEc; rnotpxouc; otV'tOXTJc;. To fJ-OV'tEAO 1totpot-yw-y7Jc; XL~W- • 'tLWV Xot'totOXWot~OfJ-EVWV anpEot tvw671 aotvi6ot 7] xuµot't0Et67] tvw671 aotvi6ot 1tpE1tEt \lot qxpLBEi ot7t0 'tTJV otpµ66Lot otPXTJ 'tTjc; xwpotc; 'tTjc; otVotXWPTJOEwc;. (2) Eio71 'tTjc; 4 ° ( 'Y) Xott (6) Bot 't01tOBE'tOUV'tott, oxt dtvw 'tWV 400 otvdt xu'tio, aE xu'tiot xot'totaxwotaµivot ot1t6 fJ-E'totMtx6 cpuMo (EAotaµot), ;uAO 7J tvw671 aotvifo· 'tot XU'tLot otU'tot Bot au­ OXEUot~OV'tott otacpotAwc; aE x1~w'ttot auaxwotaiotc; Xot'totaxwot­ aµivot ot1t6 fJ-E'totMo TJ ;u1.o. (3) To x6Aov 6Ev 1tpEmt vot ~u1i~Et 1tdtvw ot1t6 100 Kg oµwc;, 07tOU XPTJOLfJ-07t0tO\l\l'totL Xt~W'ttot ot7t0 Xdtp11'tµ1t6pll't (HARDBOARD) 7] L\IOOotYi6ot, 'tO XOAOV 'tO 1tEp1ixov d671 'tTjc; 4(ot) (~) 7] (E) 6Ev 1tpEmt vot ~u1i~u 1tdtvw ot1t6 40Kg. ( 1) Ei671 'tTjc; 5 ° Bot auaxEuot~OV'tott we; xot'twBt: 213 7 {ot) EL6Tj 'tTjc; 5 ° {ot): OXt otVW 'tW\I 100 otVot 60XELO\I 1tpOXEt­ [J.EVOU 7tEpi 1tupoxpO'tTj'tWV XrJ.l oxt dtvw 'tWV 50 ot\lot 6oxEiov 1tpoxEtfJ-EIIOU 1tEpi auv6E'ttXWV nµotxiwv, OE 6oxEiot, Xot'tot­ OXEUotaµEvot ot1t6 EAotaµot 7] ot6tot1tEpota'tTj tvoaotvi6ot, 61tou Xott Bot 1tpoa'tot'tE\lO\l'trJ.l XotAwc; Xot'tot· 'tTjc; otllotq>AE;Ewc; X(J.l Bot otacpotAl~OV'tott (J.E ot7tOO~EO'tLXO UALXO. ~oxdot ot7t0 EAotaµot (cpuMo - fJ-E'totMou) Bot Emv6uoV'totL fJ-E Euxotµ1to UALXO. Tot Xot­ Atl(J.(J.ot'tot Bot rJ.alj)otAl~O\l'tott -yupw - -yupw [J.E XOAATj'ttXEc; 'tott­ viEc;. Tot 6oxdot, OXL ot\lW 'tW\I 5 ot\lot 7totXE'tO 7J XU'tLO 1tpoxuµi­ vou 7tEpi 1tupoxpO'tTj'tWV Xott OXt otVW 'tWV 10 otVot 7tlXXE'tO Tj · XU'tLO 1tpOXELfJ-EVOU 7tEpi auv6nLXW\I nµotxiwv, Bot XAELO\l'tott aE 1totXE'tO 7J w1toBE'tOUY'tott aE xu'tio ot1t6 tvoaotvi6ot. Tot 1tot­ xhot 7j XU'tlot Bot auaxwot~O\l'tott OE ;uAt\10 Xt~W'ttO XAELOfJ-E\10 fJ-E ~i6Ec; Xott fJ-E 7tAWpEc; 1tdtxouc; oxt µtxpo'tEpou 'tW\I 18 MM (XLA.). TJ aE Ei6oc; auaxEuotaiotc; ot1t6 cpuMo - µndtMou, 'tou Ei 6ouc; 'tOu'tou auaxEuotaiotc; 7] 'tOU xt~W'tiou otacprJ.At~oµivwv µE ot7tOO~EO'ttXO UAtXO OE Xt~W'ttO auaxwotaiotc; fJ-E 7tAWpEc; oxt µtxpO'tEpou 1tdtxouc; 'tW\I 18MM (xv...) Xot'tot 'tE'tOtO 'tp61to WO'tE Vot u1tdtpxu faota'tTjf)-ot oxt µtxpo'tEpo 'tWV 3CM "(E(J.t­ aµevo fJ-E ot7tOO~Ea'ttXO UAtXO OE OAot 'tot OTj(J.ELot fJ-E'tot;u 'tOU ;u­ AL\101) XL~w'tiou TJ 'tT)c; auaxwotaiotc; Ex cpuMou - fJ-E'totMou xm 'tOU xt~w'tiou auqxwotaiotc;· (~) Ei6Tj 'tTjc; 5 ° (~) oxt O(\IW 'tW\I 100 ot\llX 7totXE'tO, OE 7tot­ XE'tot µE EvotMdt; 1tupoxpo'tTJ'tEc; XEiµEvouc; 1tpoc; 'tot otv'tiBE'tot otXpot 'tOU 7totXE'tOU. '0XL 7tEpLaaonpqt 'tWII 10 'tO\l'tWV Bot 6i110 \l'trJ.L µot~i 1tot vot oXTJfJ-ot'ti~ouv ivot auMo1tx6 1totxho. 'Oxt 7tE­ pLaaO'tEpot 'tWY 1tEV'tE auMo1Lxwv 'tOU'tWV 1totxhw11 Bot otacpot­ )..[~ov'tott fJ-E ot7tOO~EO'ttXO UAtXO OE ;uAt\10 XL~W'ttO auaxwot­ aiotc; fJ-E 7tAwpic; 1tdtxouc; oxt µtxpo'tepou 'tW\I 18 MM {xtA.), 7J aE auaxwotaiot ot1t6 cpuM9 - (J.E'totMou xot'tot 'tE'tot0 'tp61to wa'tE \lot 7tEpLEXE'totL EVot 6tlXCl'tTj(J.ot oxt µtxponpo 'tWII 3 CM "(Eµt­ aµevo fJ-E ot7tOO~EO'ttXO UAtXO OE OAot 'tot a71µEiot fJ-E'tot;u 'tW\I auMo1Lxwv 1totxhwv xott wu xt~w'tiou auaxEuotaiotc; 7] 'tTjc; auaxwotaiotc; ot1t6 cpuMo - fJ-E'totMou· (r) d671 'tTjc; 5 ° (r): 1tupoaWATJYEc; Ecpo6totaµivoL (J.E 1tupo­ xpO'tTj't7]pEc;, poMotptaµEvot OE 1t7111iot· oxt ot\lW 'tWII 10 7tTJIILW\I Bot "(lVO\l'totL poMo 'tO 07t0LO Bot 'tUAL"(E'tott fJ-E xotp'ti. 'Oxt mpta­ OO'tEpot 'tWY 10 p6Mot Bot otacpotAi~oV'tott µE ot1toa~Ea'ttx6 UALXO E µtxp6 ;uAL\10 XL~W'ttO XAELO[J.E\10 fJ-E ~i6Ec; XotL fJ-E 7tAEU­ pec; 7totxouc; OXL (J.tXpO'tEpOU 'tWV 12 XO't. LE XL~W'tto auaxwotaiotc; fJ-E 7tAWpec; 1tdtxouc; 'tOUAotXtO'tO\I 18 xa't. 6Ev 1tpE1tEt Vot rJ.alj)otAL~O\l'totL fJ-E ot7tOO~EO'ttX(X UAtXot 7tEptaOO'tEpot ot7t0 10 (J.LXpot Xt~W'ttot Xot'tlX 'tp07t0 wan Bot fJ-EL­ \IEL 6tdta't71µot 'tou)..dtxta'tov 3 Ex. aE oAot 'tot 6tdtxEvot µE'tot;u 'tW\I µtxpwv Xt~W'tLWV, "(Eµtaµivot fJ-E ot7tOO~EO'ttXO UAtXO. (6) EL6Tj 'tTjc; 5 ° (6): 1. OXL dtvw 'tWV 100 1tupoxpO'tTj'tWV otV(X XL~W'ttO, OE ;u­ Atllot Xt~W'ttot fJ-E-7tAWpic; 1tdtxouc; oxt µtxpo'tipou 'tW\I 18 MM (xv..,). xiX'tot 'tE'tOtO 'tp07t0 wan Ot 1tupoxpO'tTj'tEc; \lot xwpi~o \l'tott µnot;u i:ouc; oxt At-ywnpo ot7t0 1 CM xotBwc; Xott ot7t0 i:tc; 7tAEt>pEc; ,;ou Xt~W'tLOU. Ot otllotcpEpoµEvEc; 7tAwpec; Bot EL\lotL µot­ 'ttaµevEc; Xott O 1tuBµi11otc; 'tO XotAuµµot Bet ctacpctAi~Oll'tctL fJ-E ~i 6Ec;. Edtv ,;o Xt~W,LO ELVott emv6E6uµivo fJ-E cpuMo <Jiw6otp-yu­ pou 7J cpuMo otAouµtviou, "1tAWptx6 7totxoc; 16MM (xv..,) aivott , E1totpxec;. To Xt~W'ttO Bot otacpotAi~E,ott [J.E ot7tOO~EO'ttXO UAtXO OE Xt~W,LO auaxwotaiotc; (J.E 7tAwpic; 1tdtxouc; oxt µtxpoi:ipou ,;wv 18 MM (XtA.) Xot'tot ,E'tOtO 1:p61to wan \lot U7totpXEt EVot 6tdtai:71µot oxt µtxpoi:Epo 'tWV 3 CM "(Eµtaµivo [J.E otTCOO~E­ ai:tx6 UALXO OE OAot ,;Qt OTjfJ-ELot µEi:ot;u otU'tO\l Xott ,;ou Xt~W'tLOU auaxwotaiotc;·Tj 2. oxt ot\lW 'tW\I 5 1tupoxpoi:71,;wv ctvdt XU'tlOV, OE xui:ict ct7t0 cpuMo - µEi:dtAou, ;twv 1tupoxpo'tTJ'tWV i:01toBE'tTJ[J.E11wv Etc; otU'tOC Enoc; ;uAivwv 1tAottaiw11 ot1t6 AE1ti:ec; Awpi6Ec; ;uAou 7] EV'toc; 6tot,p7],WII 'tE(J.otXLW\I ;uAOU. To XotAuµµot Bot otacprJ.Ai~E­ 'totL -yupw - -yupw fJ-E XOAATj'ttXEc; 'tottViEc;. 'Oxt 1tEp1aa6npot 'tWY 20 xui:iwv ot1t6 cpuMo µEi:otMou Bot w1toBEi:ouV'tott aE xt­ ~wi:to auaxEuctaiotc; (J.E 7tAEupic; 1tdtxouc; oxt µtxpo'tEpou 'tW\I 18~M (XLA.)· (3) Ei671 i:71c; 5 ° ( E ): oxt ,;wv 50 ct\lot Xt~wi:to, OE ;uAtllot Xt­ ~wi:tot fJ-E 7tAWpEc; 1tdtxouc; oxt ·µtxpoi:ipou ,;wv 18 MM (xv...)., Tot Ei671 Bot otacpotAi~onott Enoc; i:wv Xt~wi:iwv 6tot ;u)..[voµ xot­ 'totaxwdtaµotwc; Xot'tot ,E'tOLO i:p61to wan Vot xwpi~OV'totL OXL At-ywi:Epo i:ou 1 CM µEi:ot;u ,;wv Xott ot7t0 'ttc; 7tAwpec; 'tOU Xt­ ~W'tLOU. Ot 1tAwpic; i:ou xt~w'tiou Bot Eivott µoti:taµivEc; xott o 1tuBµ7J11otc; xott 'to xdtAuµµot Bot otacpotAi~OV'tott [J.E ~i6Ec; xctt µE ot1toa~Ea,tx6 uAtx6 aE xt~wi:t0 auaxEuotaiotc; µE 7tAEupic; 1tdt­ xouc; oxt µtxpoi:epou ,;wv 18MM (xv...) Xot'tot 'tE'tOto 'tp07t0 wa,E \lot U7totPXEt EVot 6tdtoi:71µot oxt µtxponpo ,;wv 3CM(Ex.) "(Eµtaµevo fJ-E ot7tOO~Eai:tx6 UAtXO OE OAct 'tot a71µEict fJ-E'tot;u i:wv XL~wi:iwv xott i:ou xt~W'tiou auaxEuotaiotc;. To 6tliai:71µct µ1topEi Vat [J.ELwBd oxt At-ywi:Epo 'tOU lCM(Ex) EotV "(EµtaBEi [J.E 7tAotXEc; ot7t0 1topw671 ;uAtvTj ivot. Edtv ~ot Ei671 auaxwotaBouv E7tL [J.Epouc; (oti:oµtxot) XotL EXOU\I ai:otBEpot anpEwBEi OE Ep[J.Tj,t­ ?tWc; XAELVO\l'tot xui:iot xoti:otaxwotaµevot ot7t0 cpuMo [J.Ei:illou 7J 7tAotai:tX7] UATj, µ1topouv Vot i:01toBE,71Bou11 OE ;uAL\10 Xt~W't LO ... auaxwotaiotc; [J.E 7tAWpic; 1tdtxouc; oxt µtxpoi:ipou ,;wv 18MM (XtA.). Tot Ei6711tpimt \lot xwpi~o\l'totL µEi:ot;u 'tW\I Xott \lot exouv O'totBEpot otacpotAtaBEi fJ-E 7tAotXEc; ot7t0 tvw671 aotvi6ot 7J ;uAtVTj ivot· (a,;) Ei671 i:71c; 5 ° (ai:): 1. OXL ot\lW ,;wv 50 ot\10( Xt~W'tto, OE ;uAtVot 7J µE,ctMtX(X XL­ ~W'ttot' ai:ot xt~W'ttot otui:dt xotBE Exp71xi:tx6 't(J.T]µot 'tOU «BOUCHON ALLUMEUR» (1tupoxpO'tTj'tO\l fJ-E xot<JiuMto xpouaEwc;) Bot exouv hat 'totX,07tOLTjBEi OE ;uAt\10 (J.E E"(X01tic; U7tOO'tTJPL"(fJ-ot wan Tj ot7tOO'totatc; fJ-E'tot;u ,;wv -ymvtct~Oll'tW\I 1tupoxpo't71,w11 xott µai:ot;u i:wv E;w1tupoxpo'tTJ'tWv «BOUCHONS ALLUMEURS» xott i:71c; 1tAwpdtc; i:ou xt~w­ i:iou 6Ev aivctt µtxp6np71 i:wv 2CM(Ex)· XAEivoV'totc; 'to xli­ Auµµot 'tOU XL~wi:iou Bot E;otacpotAi~E'totL 7tAT]pTjc; otxtv71aiot 'tOU auvoAou· OXL 1tEptaaO'tEpot 'tWV 3 xt~w'tiwv Bot 't01toBE'tOUV'tott, (J.Tj otcp7]110V'totc; XE\10( foota'tTjµoti:ot, OE ;uAtVO Xt~W'tto OUOXEUot­ aiotc; fJ-E 7tAEupec; 1tdtxouc; oxt µtxpo'tEpou ,;wv 18 MM (xv...) 7J 2. OE XU'tLot Xoti:otaxwotaµevot ot7t0 ;uAO 7J µhillo· ai:ot xu­ i:iot otu'tot xdtBE «BOUCHON ALLUMEUR» Bot u1toa't71pi~E'tot1 ot7t0 7t~otiato Xoti:dt i:p61to wa,E TJ ot1t6ai:ota71 [J.Ei:ot;u Mo «BOUCHON ALLUMEURS» xott µEi:ot;u Evoc; «BOUCHON ALLUMEUR» XotL i:71c; 1tAaupdtc; 'tOU xui:iou vot µ7111 Eivott µt­ xpoi:Ep; i:wv 2CM (Ex.) xott vot a;otacpotAi~nctt 71 ctXtVT)aiot i:ou auv6Aou· 'tot xui:iot otui:dt Bot i:01toBE'tOUV'tot1 aE xt~W'tto au­ axwotaiotc; fJ-E 7tAEupic; 1tdtxouc; oxt ·µtxpoi:ipou 'tWV 18 MM (xv...) xoti:dt 'tE'tOtO i:p61to wan Vat U7totPXEt 6tdtai:71µot ox1 µt- • xponpo ,;wv 3 CM (Ex.) "(Eµtaµevo fl.E ct7tOO~Eai:tx6 UAIXO OE OAot i:ot a71µdot fJ-E'tot;u 'tW\I xui:iwv XotL fJ-E'tot;u ,;wv xui:iwv Xott 'tOU xt~w'tiou auaxwotaiotc;· i:o x6Aov 6Ev 1tpE1tE1 vot 1tEpLEXEt mptaaonpot ot1t6 150 «BOUCHON ALLUMEURS». (2) To xliAuµµot i:ou xt~wi:iou auaxEuotaiotc; Bot XAELVEt µE ~i6Ec; 7J ~Evnai6Ec; xotL muaaoµavEc; pdt~6ouc;/µ1tdtpEc;. (3) KdtBa xoAov 1taptixo11 ai671 'tT)c; 5 ° Bot Eivott acpo61otaµivo µE XAEiatµo 1tpoai:ot'twoµavo dn ot1t6 µoAu~6ivtEc; Eii:E illEc;. acppot1i6Ec; mi Mo xEcprJ.Awv xox )..[ou Etc; 'tot dtxpot 'tou xupiou li;ovoc; ,;ou xrJ.Auµµotwc; TJ 'twv 1ti:uaaoµivw11 pdt~6wv, El'tE ot7t0 Awpi6ot, cpipouaot 'tO E[J.7t0ptx6 OTj(J.ot, XOAATj[J.EVTj [J.E -yoµot aw xdt1.uµµot xott ai:tc; 6uo otv'ti0anc; 1tAaupic; wu xt~w'tiou. (4) To xoAov 6av 1tpE1tE1 vot ~u1 i~Et 1tdtvw ot1t6 75 KG xoAot 1143 1144 t:wHMt:Plz. 1 Hz. k. vBt:PNHz.t:uz. ( 1 t:Y AUL ilt:Y I t:Pu) ,uri,ovw. 7tlXVW omo 30 KG 9ot EtVott E<pOOtotoµivot µE XEtpo­ Aot~ii;. ( 1) Ei671 't7I<; 6 ° 9ot poUotpto9ouv xwptO'tlX OE xotp'tl Xott 9ot 't01t08E't7l90UV OE 1tEpt'tUAirµot'tot xuµot'tOEtOOU<; tVOOotVlOot,;. 0ot OUOXE!)ot09ouv oxt nEptoooEpot 'tW\I 25 otVIX XU'tLO, OE XU'tLot ot7t0 LOOOIX\ltOot 71 q,uUo µE'tlXAAOU. Tot xotAuµµot'tot 9ot otocpotAi­ ,01/'tott rupw - -:yupw µE XOAA7l'ttXE<; 'tottVlE<;. 'Oxt ltlXVW ot7t0 20 XU'tLot 9ot· 't07t09E'tOUV'tott OE !;uAtVO XL~W'ttO ouoxwot­ o!oti;. (2) To XOAOV OEV 1tpE1tEt \lot ~uri~Et 7tlXVW ot7t0 50KG. KoAot ,ur!,OV'tot IXVW 'tW\I 30 KG 9ot Et\lott E<pOOtotoµivot µE XEtPOAot­ ~ii;. (1 )Eto71 't71i; 7 ° 9ot ouoxwix,ov'tott oE !;uAtvot xt~w'ttot XAEt­ oµavot µE ~ioE<; 71 flEV'tEOEOE<; Xott 7t'tUOOOflEIIE<; pix~ooui; (µnix­ pEi;) Xott µE ltAEUpei; nixxoui; oxt µtxpo'tEpou 'tWV 16 MM (XtA. ), 71 OE OOXELot Xot'totOXEUotoµivot ot7t0 µhotUo 71 Xot't1XA­ A7IOT) 1tAotO'ttX7I UA7I E1totpxoui; otV'tox71i;. Tot XotAuµµot'tot Xott Ot nu9µivEi; 'tWII !;u)..ivwv xt~w'tiwv µnopouv rni07Ji; 11ot xot'tot­ oxwix,011'tott ot7t0 7t0AU 1tE1ttEoµiv71 XotP'tOOotVioot µE ltAEUpei; io71i; ot\l'tOX7I<;, Eio71 ,uri,Oll'tott IXVW 'tWV 20 KG µnopouv rni 071.; Vot 1tpow8ou11'tott OE OXEAE'tOXt~W'ttot 71 xwp!i; ouoxwoto!ot. (2) To XOAO\I OE\/ 1tpE1tEt \lot ,uri,Et ltlXVW ot7t0 100 KG EIXV 1tEptEXEt Eio7J xot9Ellot 'tWV 01toiwv. 'tO 7tEptE,oµEvov ,uri,Et 1tix11w ot1to 30 KG 9ot Eivott Ecpoototoµivot µE XEtpoAot~k (1) Eto71 'tTJi; 8 ° 9ot ouoxEuix,oV'tott oE !;uAtVot xt~w'ttot, oE ~otpiAtot otno tvoootv!oot 71 ono!ot EXEL Xot'totoui ototot1tepoto't71, 71 OE OOXElot flE'totAAtXIX 71 ot7t0 Xot'tlXAA7IA7I 1tAotO'ttX7I UA7I E1totp­ xoui; otV'tox71i;. H XE<potA7I otvotcpAi!;Ewi; 9ot 1tpoo'tot'tEUE'tott Xot'tlX 'tE'tOLO 'tp07t0 WO'tE Vot ot7tO<pEUTE'tott 01tOLot07l1tO'tE OLot01topcx 'tOU TEµ[oµot'tO(, ot7t0 'tO Eiooi;. (2) To XOAOV OEV 1tpE1tEL Vot ,ur!'Et 7tCXVW ot7t0 100 KG· oµwi;, O'totll XP710Lfl01tOLOU\l'tott ~otpEAtot ot7t0 tvoootv!oot, 'tO xo­ AOV OE\/ 9ot ,urr,u 7tCXVW ot7t0 75 KG. KL~W'ttot 'tWV OltOLW\l 'tO 7tEpLEXOflEVOV ,uri,Et 7tlXVW ot7t0 30 KG 9ot ELVotL E<pOOLotoµivot µE xupoAot~ii;. Eio71 't7J<; 9° 9ot xAEivoV'tott oE !;uAtvot Eio71 ouoxEuotoioti;. To XOAOV OEV-7tpE7tEL Vot ,uri,Et 7tCX\IW ot7t0 75 KG. XOAot ,uri,o­ V'tot ltlXVW ot7t0 30 KG 9ot Et\lott E<pOOLotoµevot fJ.E XELpOAot~ii;. Ei671 't7Ji; 1 o O 9ot ouoxEucx,oV'totL oE !;uAtvot xL~w'tLot. KoAot ,uri,OV'totL 7tlXIIW ot7t0 30 KG 9ot EL\lotL E<pOOtotoµivot fJ.E XELpo­ Aot~ii;. Eio71 't7I<; 11 ° 9ot OUOXWCX,OV'totL wi; E!;71i;: (ot) EL07I Ototµhpou fJ.LXpO'tEpoti; 'tWV 13,2MM (XtA.): oxt 1tEptooO'tEpot 'twv 2 5 otvcx xu'tio, ouoxwotoµivot ocptx'tcx OE xu­ 'ttot ot7t0 LOOOIX\ltOot XAEtVOV'tot O'tot9Epcx OE OOXELot Xot'totOXWot­ oµivot ot7t0 Xot'tCXAA7JA7j 1tAotO'tLX7I UA7I E1totpxoui; otV'tox71i;· 'tot XU'tLot otU'tCX 71 OOXELot 9ot 't07t09E'tOUV'totL, xwpii; CXOEtot OtotO't7l­ µot'tot, OE !;VALVO XL~W'tLO, µE 7tAwpii; nixxoui; oxt µLxpoupou 'tWV 18 MM (XtA.), 'tO 01toio µnopEi vot EXEL E1tE11ou9Ei µE 1tACX­ XE<; - XotOOt'tepou, q,uUo 4EU0otprupou 71 cpuUo otAouµtviou, 71 fJ.E Xot'tlXAA7IA7l 1tAotO'tLX7I UA7I E1totpxoui; otV'tox71i;. To XOAOV OEV 1tpE1tEL Vot ,uri,Et ltCX\IW ot7t0 60 KG. KoAot ,uri,OV'tot ltlXVW otltO 30 KG 9ot ELVott E<pOOLotoµivot fJ.E XELpo­ Aot~ai;. (~) Eio71 oLotµhpou ot1to 13.2 MM (XLA.) µexpt 57 MM (XtA.): 1. XwpLo'tix OE OWA7IVot Xot'totOXEUotoµivo ot7t0 tvoootvioot 71 ot7t0 Xot't1XAA7IA7I 1tAotO'ttX7I UA'lj, TEPOV, E<potpµoo'tOV, XAEtVO\l'tot TEPIX Xott O'tot ouo ixxpot· 71 OE OWA7lllot Xot'totoxwotoµivov ot7t0 L\IOOotvioot 71 Xot'tCXAA7IA7I 1tAotO'tLX7I UA'lj, TEp0II, E<potpµoo'tOV, XAELOfJ.EVOV O'tO EVot cxxpo xotL otvotx'tov o'to illo· 71 OE OWA7IVot Xot'totOXWotoµivov ot7t0 LVOootvioot 71 Xot'tCXAA7IA7I 1tAoto,tx71 u)..71, otVOLX'tOII xott O'tot ouo ixxpot otUix µE EOW'tEptx71 1tpoE!;ox71 71 illov Xot'tCXAA7JAO\I EOW'tEpLXOV µ71xotvLoµov WO'tE Vot ot7tO<pEUTE'totL 71 flE'totx!v71071 'tOU Eiooui;. I:uoxwotoµivot Xot,ix 'tOV 'tpono otU'tOV, OXL 1tEptooo'tEpot ot1to: . 300 Eio7J Ototµhpou oxt µtxpoup71i; 'tWV 13.2 MM (XLA.) xott oxt fLETotAuup71i; 'tw11 21 MM (xtA.)· 71 60 Eio71 Ototµhpou IX\IW 'tWV 21 MM (xtA.), otAAIX oxt IXVW 'tWV 37 MM (XtA.)' 71 25 Eio71 Ototµhpou fJ.ETotAU'tEp7Ji; 'tWV 37MM (xtA.) Xott oxt µqotAuup71i; 'tWV 57 MM (xtA.) 9ot 't07t09E'tOUV'tott OE O'tpw µot'tot OE !;uAt\10 Xt~W'tto fJ.E 7tAWpii; ncxxoui; oxt µtxpO'tEpov 'tw11 18 MM (XtA.), 'to oE !;uAtvo xt~w'tto 9ot Eivott EnEvoEou 2138 µivo fJ.E ltACXXot XotOOt'tEpou, <pUAAO 4Euootprupou, 71 cpuUo otAouµtviou. IlpoxEtµivou 1tEpi Etowv ouoxEuotoµivwv oE owA71vE<; otvot- , X'tE<; Xott O'tot Mo cxxpot 71 O'tO EVot, 'tO Xt~W'ttO 't'T)<; OUOXEotuoioti; 9ot ElVott EltE\IOEOUµivo O't7I ltAEUpcx 71 O'tt<; 7tAWpii; 7tOU rmvtcx­ ,ouv fJ.E 'tot ot\lOtX'tCX cxxpot 'tW\I OWA7IVWV fJ.E q,uUot m)..71µot'tO<; ncxxoui; oxt µtxpo'tepou 'tWV 7 µµ (xv..,) 71 fJ.E cpuUo 'tOU otU'tOU ncxxoui; OL7tA7I<; o4Ewi; xuµot'tOEtOoui; tvoootviooi; 11 oµo!ou UAt­ xou. 'tO XOAO\I OEV 1tpE1tEt Vot ,uri,El ltCXVW ot7t0 100 KG. KoAot 2139 ,uri,OV'tot 7tCXVW ot7t0 30 KG 9ot Eivott E<pOOtotoµivot fJ.E XEtpo­ Aot~ii;. 2. Eio71 Ototµhpou .20 MM (xv..,) µ1topouv E7tl07)<; Vot ou­ OXWIX,01/'tott, OXL 1tEptoooupot 'tW\I 10 otVIX XU'ttOV, OE TEPIX xu­ 'ttot ot7t0 tllOOotlltOot EltEIIOEOuµivot fJ.E x71pov 1totpotq,iv71i; Xott E<pOOtotoµivot fJ.E xu4EAOEtOE<; XIX'tW 1totpiµ~)..71µot Xott fJ.E xwpi­ oµot,ot ot1to tvoootvioot Emxptoµav71v µ71 x71pov 1totpotcpiV7Ji;, Tot XU'ttot 9ot XAELVOV'tott fJ.E xoµµtwµa1171 OtXAEioot (xAot1tho). ·oxt mptOOO'tEpot 'tW\I 30 Ku'tLW\I 9ot OUOXEotU,OV'tott O<ptX'tlX OE !;u­ AtVO Xt~W'ttO fJ.E 7tAwpai; 1tcxxoui; oxt µtxpoupou 'tWV 18 MM (xv.,), 'tO OE !;uAtVO Xt~W'ttO 9ot EL\lott EltEVOEouµivo µE cpuUo 4wootprupou, ltACXXot XotOot'tipou T) cpuUo otAouµtviou. 2140 To XOAOV OEV 1tpE1tEt Vot ,uri,Et 7tCXVW ot7t0 100 KG· KoAot ,urt,Oll'tot 7tCXVW ot7t0 30 KG 9ot ELVott E<pOOtotoµivot µE XEtpoAot~ii;. 3. Eio71 Ototµhpou oxt µqotAu'tEpoti; 'tWV 30 MM (xv.,) µ1topouv, OE otpt9µo µ71 U7tEp~otLVOV'tot 'tOV otVot<pEpOfJ.EVOV U7t0 O'totxiov I, otVW'tEpw, Vot 't07t09E'tOUV'totL E1tio71i; OE 'totLVlE<; Xott OUOXEUCX,OV'tott OE TEPO XotAU~OtVO OOXELO. To OOXELO otU'tO µnopEi \lot ELVott XUAt110ptxo. Tot E!o71 otu'tix 'to1to8E'tOUV'tott oE 'tottviEi; 9ot 1tEpt~illoV'tott ot7t0 Xot't1XAA7JAO µ71xot11toµo WO'tE Vot otltO'tEAOUV ouµ1totT71 µo­ VIXOot XotL Vot ot7tO<pEUTE'tott 71 otltOO'totOT) 'tOU xot9Evoi; 'tWV Et 2141 owv. M!ot 71 1tEptooo'tEpEi; µovixoEi; 9ot oupEwvov'tott o'to oo­ XEio Xot'tCX 'tE'tOtO 'tp07t0 WO'tE Vot µ71 µE'tot't07tL,OV'tott. Tot cxxpot 'tW\I EtOWV 'tW\I 't01t08E't7lfJ.EVWV OE 'tott\lLE<; 9ot 2142 otxouµ1tou11 nixvw OE otV'ttxpotOot'ttxcx µ71 µE'totAAtxcx u1tOO't7I· pirµot'tot. To XIXAuµµot 'tOU OOXELOU 1tpE1tEt Vot XAELVEt Xot'tCX 'tp07t0\I 2143 O'tETotVOV Xott \lot otocpotAL,E'tott fJ.E µ71xotvtoµov otocpotAtaEW<; ou­ VCXfJ.EVOV Vot ocppotrto9Ei WO'tE 'tot El07I Vot µ71 µnopouv Vot 7tE­ oouv. To XOAOII OEV 1tpE1tEt \lot ,uri,Et 7tCXVW otltO 100 KG· KoAot ,ur!,ov,ot 7tCXVW ot7t0 30 KG 9ot E[Vott E<pOOtotoµivot fJ.E XEtpoAot~ii;. YitoooxEii; tXot\lOL Vot poUotpio9ouv 9ot exouv 'tot xotnixxtot 'toui; Ecpoototoµivot µE TEP71 XEtpoAot~71 i;iou vot fJ.7tOpOUV Vot fJ.E'tot<pEp9oUV' 4. EL07I Ototµhpou oxt µtxpo'tepoti; 'tWV 30 M (xv.,) Xott oxt µqotAU'tEpoti; ,wv 5 7 MM (XtA.) µ1topouv E1ti07Ji; vot ouoxwix­ ,011'tott xwptO'tlX OE TEPO, E<potpµoo'to, EpfJ.7l'ttXCX - XAEtOµE\10 XUAtvoptxo XU'tlO Xot'totOXEUotoµivo ot7t0 tVW07j ootvioot, ivot 71 Xot'tCXAA7JA7j 1tAotO'ttX7I UA7I, 'Oxt 1tEptoooupot 'tW\I 40 'tWV xu­ 'tlW\I otU'tWV 9ot 't07t09E'tOUV'tott OE O'tpwµot'tot OE !;uAt\10 Xt~W­ 'ttO µE 7tAWpii; 1tixxoui; OXL µtxpoupou 'tW\I 18 MM (xv.,). TO XOAO\I OEV 1tpE1tEt Vot ,uri,Et ltlXVW 07t0 100 kg, KoAot ,ur!,ov,ot 7tCXVW ot7t0 30 kg 9ot ELVott E<pOOtotoµivot µE XEtpoAot- • ~ii;. ( T) AOtltot El07I 't7I<; 11 ° : ouµcpwvot fJ.E 'tt<; Otot'tCX!;Eti; 'tOU 7tE­ pL9wpiou 2139(1). To XOAO\I OEV 1tpE1tEt Vot ,uri,Et 7tCXVW ot7t0 100 kg. KoAot ,ur!,OV'tot 7tCXVW ot7t0 30 kh 1tpE1tEt Vot ELVott Ecpoototoµivot µE XEtpoAot~ii;. • I:71µEiw07J: IlpoxEtµivou 1tEi Etowv 1tEptEXOV'tWV 'tOoov 1tpow871'ttXOII OOOV Xott EXp7jX'ttXOV TEfJ.LOµot, 71 OtCXfJ.E'tpoi; Et<; 't'T)II OltOLotV otvotcpEpoµE9ot EL\lott EXElV7J 'tOU XUAtVOtXOU 'tµ71µcx­ 't0(, 'tOU 7tEptEXOV'tO<; 'tO EXp7JX'ttXO reµtoµot. M tX't7I ouoxEuotoiot ( 1) E!o71 otVot<pEpoµEvot U7t0 otpt9µ011 Eiooui; 'tOU 7tEpt9wpiou • 2144 2131 µnopouv Vot µ 71 ouµnEptAotfJ.~IXVOV'tott O'tO otU'tO XOAOV El'tE fJ.E ELO'lj Otot<popou ElOoui; otAAIX 'tOU otU'tOU otpt9µou ElOoui;, EL'tE fJ.E El07j illou otpt9µou Eiooui; 'tOU (XVW'tEpw 7tEpL9wpiou, EL'tE µE u)..ai; 71 E!o71 ot1171xov'tot oE cxUEi; KAixoEti;, Eiu µE illot EfJ.1tOpEuµot,ot. <l>EK 104 E<DHMEPII: THI: KYBEPNHI:EQI: (TEYXOI: ~EYTEPO) (2) Tat 7tatpatXO:'t(I), oµwc; Eili71 µ1topou11 I/at ouµitEptAatµ~ii: 1101/'tatl O'tO atU'tO XOAOII: (at) EtOTj 't'Tj<; 1 °, µE'tat/;U 't(l)I/, 'O'tlXII Et671 'tTJ<; 1 ° (at) Xatl (~) ouµiuptA71cp8ou11 O'tO IXU'tO XOAOII, Oat ouoxwo:;011't1Xt ouµcpw11at µE 'tO 1tEpt8wpto 2 l 33(at). ·o'tlXII Ei671 'tTJ<; 1 ° (r) ouµ1tEpLA7jcp8ou11 O'tO OtU'tO XOAOII µE d671 't'Tjc; 1 ° (0t) 71 (~) 71 atµcpo'tEplX, 'tOt Ei671 'tTJ<; 1 ° (r) 80t ou­ OXEUO:;oll'tOtl ouµcpw110t µE 'tl<; 6t0t't0t/;Et<; 'tl<; tO)(UOUOE<; 1t' OtU'tOt XOtt 71 E!;wnp1x71 ouoxE1.!1XOi0t Oat Ei11ixt 1tpo/3AE1toµi1171 1t0t Ei671 't'Tj<; 1 ° (0t) TJ (/3). To x6Ao11 6E11 1tpa1tEt 110t ;u,i;Et 1tii:11w ix1t6 120 kg.· (/3) Ei6Tj 'tTJ<; 2 ° (0t) µE EXEtl/0( 't'Tjc; 2 ° (/3), U7t0 'tOII 6po11 O'tt ocµcpo'tEpOt 7tEptEXOll'tOC OE EOW'tEptXO: EioTJ OUOXEUOtOLOC<; OC1tO'tE· AouµE110t EX XU'tlWII 't01t08E'tTjµi11w11 OE !;uAtl/lX xt/3W'tl0t. To xo­ AO\I OEII 1tpE1tEL voc ~u,i;Et 1tii:p0t navw 0t1t6 100 kg? (r) Ei6Tj 'tTJ<; 4 °. µnoc!;u 'tW\I, Aatµ/3oc11oµi11w11 U1tocj>Et 'tWII OlOC'tlX!;EWV r10t EOW'tEptxii: E[6TJ OUOXEUOtoiocr:;, EV'tOr:; !;uAtl/OU Eownptx71c; ouoxEu0toiocc;. To xoA011 6Ev 1tpim1 110t ~u,i,Et 1t0:VW Ot'ltO 100 kg? · (6) Eio71 't'Tjt; 7° µE EXELIIIX 'tTJ<; 5° (oc), (6), (E) xatt (o't), u1t6 'tO\I 6po11 o'tt TJ ouoxEuixoioc 'tw11 'tEAEU't0tiw11 'tou'twv Eµito6i~Et 'tTJII µE,0:600111 m80t1171r:; EX1tupooxpo't7IOEW<; o'tOt Ei6Tj 'tTJ<; 7 °. ~E El/IX xoA011, ·o ocpt8µ6r:; ,w11 E1ow11 5 ° (oc), (6), (E) xOtt (o't) 1tpE1tEl 1/0t Eivext O OtU'tO<;; µ. EXEll/011 't(l)II Et6w11 7°. To XOAOV OE\/ 1tpE1tEt I/at ,u,i,Et 7tEptoocmpo OtltO 100 kg. 4. Mocpxii:ptoµix XIXl E'tlXE'tEr:; x1116uvou 7t0:VW O'tOt xoAex (/3AE1tE Ilpoo871x7111 A. 9). KoAOt ltepLEXOll'tOt ELOTJ 't"ljr:; KAO:OEW<;; l/3 Oat cpipow nLXE'tOt ouµcpw11011 µE 'tO µov'tEAO No I,7'0µwr:; XOAOt 7tEptEXOV'tex EioTJ 'tTJ<;; l O (6), 5 ° xocL 6 ° 80t cpipow 6uo E'ttXE'tE<; ouµcpwv.c; 1tpor:; 'tO µ011,iAo No 1. B. Arnwµapmc; (ow1xdoc) 'tOU •npo:cpou 'tTJ<;; µnixcpo­ pii:r:;. (1) H 1tEpt,pixcp71 'tW\I Eµitop.uµo:'tWV O'tO i,rpixcpo µo'tlX­ cpopii:c; 1tpi1m vat ouµcpw11d µE µiatv 'tWV 011op:ixo1w11 'tWII u1to­ ypixµµtoµi11w11 O'tO 7tEpt8WpLO 2131 • 1tpa1tEL \IOt E1tXEl U7t0· ypii:µµto"lj Xatl 1/0t OtXOAou8e['tatl Ot7t0 AE'lt'toµipuer:; (o'tOlXEiOt) 't"ljr:; KAo:oEwr:;, 'tOV 0tp18µ0 'tOU Eioour:;, µix~i µE 'tO ' .'tuxov, ypliµµoc, XOtt 'tOt ixpx1xii: «ADR» 71 «RID» (1t,x. l/3 2 ° (0t), ADR). (2) Tix it1Xp1XXO:'tW 1tpa1tEt \IIX /3E/30ttWIIO\l'tatl O'tO enpoccpo 't'Tj<;; µe,ixcpopii:c;: • «H cpuo71 ,wv eµ1topwµo:'tw11, xix1 'to ei6or:; ouoxwocoii:xc; ouµcpwvouv µe 'tl<;; 6tlX'tO:!;Etc; 't'Tj<; ADR». r. Keva ElOl'j OUOXEUOtoiexc; Kcxµµiex 61ii:-c0t!;71 KAALH 11. -ANA<l>AEKTHPEL, fffPOTEXNHMATA KAI TIAPOMOIA EMilOPEYMAT A 1. Kix't1Ho1or:; .µ1topwµii:,wv (1) ME't0t!;u 'tW\I UAW\/ Xatl 'tWV EL6wv 'tW\I XIXAUlt'toµavwv U'ltO -COIi 'ti'tAOV -c71r:; KAO:OEW<;; r,, µ011011 'tOt OtVIX'YPatcpoµEIIOt oto . 1tEp18wpto 21 71 0ix '(lVO\ltOtl 6.x-cii: ,tot µuoccpopii:, XOtt 'tO'tE µ611011 U7t0 EmcpuA0t!;71 'tW\I Olat't<X!;EW\I 'tOU 1t0tp611't0c; Ilexpixp-c71 µ0twc; XIXl 'tOU Ilatpatp-c71~oc; B. Au,ac; Ot UAE<;; XOtl d671 1COU 1tpoxEl'tlXL vex '(LIIOUI/ OEX'tO: ,10t µi.,ixcpopot UltO wptoµavouc; opour:; 8at 0i.wpouv-cm wr:; UAEr:; XOtl .[671 -c71r:; ADR. (2) Tex etOTj 7t0U 1tpoxm1Xt 1/0t '(l\lOUI/ OEX'tot 7tpE7tEt VIX 1tA71 pou11 ,our:; 1t0tp0txdt-cw opour:;: (at) To EXpTJx-c1xo 1aµ1oµix 0oc ou1xponi-c0tL, 't1XX'to1to1Ehat1 xexL OlOt\lEµE'tOtl XIX't!X 'tOlOU'tOII 'tpcmov WO'tE OU'tE TJ -cpt/371, -co XOU\ll']µOt 71 xpouo71, IXXOµTj xext 71 Otllot<pAE!;Tj 'tWII ouoxwexoµi­ \lW\I ElOW\I vex µrcopouv vex 0671,71oouv OE µ[ix axp71!;71 'tOU OAOU 1tEptqoµa11ou 'tOU xoAou· (/3) AEUxor:; 71 xi-cp111or:; cpwocpopor:; µ1topei I/IX µ71 xp7101µ0 7t0lEl't0tl EX'tor:; µE 0[671 't'Tjr:; 2 ° XOtl 20 °. (I) 71 EXPTJX'tlX7I ouv8.071 tWV 1tupo-cEXVl']µii:-cwv (21 ° 24 °), µ0t,VTJOLOU (26 °) XOtl OL XOt1CVO'Y011Er:; ow0foEtr:; 'tWll 'TCIX· p0to1-cox,011w11 (2 7 ° ), 0E11 1tpe1tEt 110t 1tep1exou11 X Awptxii: o:Acx-ccx· 2146 2147 2148 2162 2163 2164 2169 2170 (o) 'tO Exp71x-c1xo -yiµtoµot 1tpbm 1/0t 1tA71poi 'tour:; opou,; o-ccx0epo-cri'tcx,; -c71r:; Ilpoo871x71c; A.I. 1tEpt8wpto 3111, A. AvixcpAex-c71pEc;: • 1 ° (oc) Ilup.i0t ococp0tAEi0tr:; (µE /30:0111 x Awp1xou xixAiou x0t1 8eiou· (/3) 1tup.i0t µE /301otv x AWptxou XOtAiou XOtl U1to8Etouxou qiw­ ocpopou ( OEOXlOOUA<plOLO 'tOU cpwocpopou ), we; XOtl OtVOt<pAEX't'Tj· pee; ,pt~71c;. • 2 ° Ti:xtvi.c; eµ1tupiw11 -yt0t cp0t11our:; 0tocp1XAEi0tc; x0t1 'tOttvie,; Eµ1to,1oµivwv oE xripo 1tixpetcpivrir:; Eµ1tupiwv -ytoc cpocvou,; 0tocp1XAEi0tc;. 1. 000 Eµ1tupt0t OE.II 1tpE1tEl voc· ltEptEXOIJI/ Exp71'ttXO 1t0111w oc1to 7 .5 ypcxµµii:p10t. ftcx -coc1viEc; xixcjiuUiwv, /3AE1tE 15 °. 3 ° IlupooWATjVE<; /3poc6Eiou; - xocuoEwc; {1tupoowA.7111E,; 0t1to­ 'tEAouµevm Ot7t0 AE'lt'tO IXOllX7tEpOto,o OWATJIIOt µE O'tEVO 'tµTjµOt 1tup71vor:; µEA0t1171r:; 1tuph16or:;). f10t cxUouc; 1tupoOWATJVEr:;, /3AE1tE KA<XOtll l/3, 1 ° {1tEpt8w­ p10 2131). 4 ° N71µix 1tupoxuAiv71c; (PYROXILIN THREAD) ((3ocµ­ (30tx61171µ0t Eµ1tAou,1oµi110 µe 01,w,o ). BAi1tE E1tio71r:; Ilpoo811 x71v Al 7tEptllwpto 3101. 5 ° ~wA71vw-coi OtllOt(j)AEX't'fjpE,; («LANCES D' ALL­ UMAGE») (oWA7IVEr:; Ot'ltO l\lOOOt\ltOOt, 1tEp1axo11nr:; µtxp71 ltOOO­ 't'Tj'tOt ow8foEwr:; 1tupoowA7111oc; E!; o!;oyo1101tm71µivw11 UAWII XOtt op,0t111xwv UAWV XOtt, m80tv611, E!; 0tpwµ0t,lXWII ow8EOEWV Eµ1tAOU'ttoµavw11 µE dt,w,o) XIXt x0tcjiuU10t 8Epµi't'Tj i,tE Otoxi0t Ot\llX(j)AEX't'flPWII. . 6° A110tipAEX'tTJpEr:; 0tocp1XAEi0tr:; r10t 1tupoowA7111E,; (qiuoinux Ot7t0 xocp-ci 1tEptaxo11't0t Eµ1tup1011 Ot0t1tEp0toµi11011 µc 1171µ0t ( cpu­ 'tLAL) itpoo,1,oµEvov 1/(X 1tpox1XAfoa1 ,pt~7111, 71 ox ii:071, 711t0tpo­ µotour:; !lTJXOtlltOµour:;). 7° (ix) HAEX'tptXOl Eµ1tupt0t xwpir:; 1tupoxpo-C'Tj't'Tj' (~) 61ox[0t y10t TJAEX'tplX!X Eµ1tup10t. . 8 ° HAEX'tptxoi Otll0t<pAEX't7lpcc; (1t.x, OtVOt<pAEX'tTjpEr:; 1tpoop1 ;oµE11ot ,10t Otll!X<j)AE!;71 cpw-co,p0tip1xou µatyv71oiou) .. !,i;i, ;t,iµt­ oµoc ,ou xat8E116r:; 'tOU'tWII OEV 1tpi1tEL 110t u1tepf30ti11E1 'tOt 30 yp. OU'tE Vat 1tEp1axu 7t0tl/W Ot7t0 106 O'tOt EXat'tO ~pov-cw671 uopcxp­ yupo. L7lµEiwo71: LUOXEUE<; tUltOU TJAEX'tptxou A0tµ1t't71poc; 1t0tpdt­ youo0tt !;0tip111x6 cpwr:; XOtL 1tEptaxouo0t1 yiµ10µ0t Ot\lOtipAE!;Ewr:; 0µ010 µ. EXELl/0 'tWII TJAEX'tptXW\I OtllOtipAEX'tTJPWII 6E\I U7tOXEt· 1/'tatL O'tLr:; OLot'tot!;Etr:; ,71,; ADR. B. Ilupo'tEXIILXOt ELOTJ XCXl 1t0ttyvi61at: x0tcjiuU1ot XOtt (tOtl\lLE,;) xoccj,uUiwv: EXPTJX'ttXOt EioTJ • • 9° Ilupouxv1xcx Ei671 EOW'tEptxou (1t.x. KuAtv6pot BOSCO, ~oµ~Ec; XO<flE'tl, XO'tt-ytov). Ei671 µa /3dto111 Eµ1tAOU'tt· oµa110 µE cx;w-co /3cxµ/3otx0t ( x0Uoo10/3cxµ/30tx0t,;) OEV 1tpE1tEl 1/0t 7tEptEXOUV 7tEptOOO'tEpO ot'ltO 1 '(p0tµµ0tpto Otl/Ot Ei6oc;. 10° Exp7jyvu6µev0t xciucph0t (µ1toµ1t61110t), Aou).ou6o xpo,i6Ec;,,-cat111iEc; Eµ1tAOUttoµi11Er:; µE ot,w,ouxo xotp,i (xoUo­ OtO;(otpw). 11 ° ( Ot) ExpuyvuoµEvot µm~EALOt, ExpuyvuoµE11Ec; /30µ/3i6Ec; Xotl AOllt!X oµmot 7tUp0-CEX,VtXOl 7tatt-yvi6ux 1tEp1a;ov-cor. /3po11-cw671 ap,upo· • • (/3) Exp71,vuoµE110t 1tupei0t (orc[p-c0t)• {r) e/;0tp't~µ0t't0t µE /3pOll'tW6Tj 0tp-yupo·. 1tpoo'ti0E't0tt 6-ct: O'tot IXIIW'tEpW (ix), (/3) XIXt (r): 1. 000 ElOT) OE\I 7tpE1tEI vor. 1tEp1axow 7tOtVW OtltO 2, 5 yp0tµµii:­ p10t /3po11-cw6-q cxpyupo. 12 ° Exp71x,1xdt XIXAtXllX, • "CO xa:8a110t µnol(pipov, e!;WTE• ptxcx, ,eµtaµix Exp71x,1x71r:; u)..71.; 7tATJII xpo-ctxou <XAIX'tO<; oxt 7t0t\lW OtltO 3 -yp0tµµdtp10t. • 13 ° Ilupouxv1xdt 1tUpEi0t (1t.x. BETTIXALXIX 1tupEi0t, 1tUpEi0t XPua71r:; ~pox71,;, TJ 1tupei0t CASCADE - OF - FLO • WERS). 1+0 M0ty1x<i XEptdt x.wpic; XE<plXAac; otVOt<pAE!;Ewc;. 15 I' KcxcjiuUtor. r10t ltOtlOtXOt 1tot1yvi610t, 'tOttlltE<; xixcjiuUiwv XOtt EA0t't'fjpt0t xotcjiuUiwv. . 1.000 xixcjiuU10t OEII 1tpi1m VIX 1tep1axow 7t!X\IW IX1CO 7 .5 yp0tµµcxp10t exp71x'ttXTj<; uA71~ EAEu8ipcxr:; Ot7t0 xpo-ctxo <XAOt,;. r IIX 'totllltEr:; xotcjiuUiwv "(tOt cpatvour:; 0tacp1XAEi0tc;, (3AE7tE 2 °. 16 ° Exp71x'tlXOi cpEAAoi µE Exp71x,1x6 yaµ10µ0t EX,011 ~ci:071 cpwoq>opou X!Xl XAwptxou OlAOt'tO<; TJ µe yiµtaµat xpO'tlXOU <XAOt­ 'tOt; TJ oµoi0tc; OUll8EOEW<; 7tE7tlEOµEIIO OE cpuointlX XOtpV't µ1top11-c. 1.000 cpEAAOl Ell 1tpa1te.l VIX 7tEptEX,OU\I 7tEptoooupo • 1145 2171 1146 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) 0(7t() 60 yp0tµµcxpt0t Exp1pmx7Ji; uA71,; EX xAwptxou (X/..O('tO<; OU"CE 7tEptaaonpo 0(7t0 10 yp0tµµcxpL0t xpo'ttXOU (X/..O('tO<; auv0E­ OEW<; µE ~(XOtV xponxou (XAO('tO<;. 1 7 ° fapoTTUAO( ~OtpEAO't()( µE Exp71xnxo yiµtaµ0t txov ~&071 cpwacpopou XO(t XAWpLXOU (X/..O('tO<;. 1.000 ~cxpEAo't()( OEV 7tpE1tEL VO( 7tEptEXOUV 7t<XVW CX7t0 45 1p0tµµcxptcx EXp7IX'ttXTj<; uA71,;. 18 ° K0t4t1Mt()( 0(7t0 X<Xp'tV - µ1tcipn ( 1tupoµcxxLx<X 1tCXLyvL­ OLWV) fLE Exp71xnxo yiµtaµcx txov ~&071 cpwacpopou XO(t X Awpt­ xou cxAcnoc; T\ µa yiµtaµ0t xponxou <XA0t't0<; T\ oµoi0ti; auv0i­ aEwi;;. 1.000 x0t4t1MLO( OEV 1tpE1tEt VO( 7tEpLixouv 7t<XVW 0(7t0 25 1p0tµµcxpL0t Exp71x,tx7Jc; u).71,;. 10 ° K0t4t1Mt()( 0(7t() xcxpv't - µ1topV't Exp71yvuoµEVO( X<X'tW 0(7t() 'tO 7t00t, µa 1tpOO't()('tEU(lE(lO yiµtaµO( exov (1&071 cpwacpo­ pou XO(t XAWptxou CXAO('tO<;. 1.000 x0t4t1At()( OEV 1tpi1tEt VO( 7tE­ pLixouv 1tEptaacmp0t 0(7t() 30yp0tµµcitpL0t EXp7IX'ttXTj<; uA71.;;. 20° (0t) Exp71X'tLX(X cpuMOt (DETONATING SHEETS)· (/1) MARTINIKAS (hat x0tAoun0tt 'tOt la1t0tvtxcit 1tupo,E­ x~µ0t,0t. Aµcpo,Ep0t 1tEpLA0tµ(1citvouv ev0t µiyµ0t 0trco Awxo (xi,pwo) XO(L apu0po cpwacpopo fLE XAWptxo X<XALO XO(t oxt ALywnpo 'tOU 50 O't()(, EXCX'tOV 0top0tvw11 UAW\/ rcou OE\/ OUJ.LfLE'tEXOUV O't7IV 0(1COOt1V8Ea71 'tOU µiyµ0t,o~ cpwacpopou XO(t X Awptxou <XAOt'tO<;. "Evcx cpuMO OEV rcpircEL VO( ,uri,Et rccitvw 0(7t0 2,5 yp0tµµcxpt0t XOtL i110t MARTINIKA rccxvw 0t1to 0,1 ypcxµµcitptcx. r. n upo'tEXVTJµcx,cx 21 ° ITup0tUAOL (pouxin.;;) ANTI - HALL xwpii; rcupoxpo­ 'tTJ't'Tj, ~oµ{1E<;; XO(t EoX<XpE,; (oAµm) (FIREPOTS). To yiµtaµ0t, auµrcEpLA0tµ{10tvoµi11ou ,ou rcpow071,txou 1E­ µiaµ0t1:oi;, OE\/ rcpircEt VO( ,uri,Et TC(X\IW 0(7t() 14 KG ()(Vat aiooi;, T\ ~0µ~0t ri oAµoi; (FIREPOT) oxL rccxvw 0trco 18 KG auvo­ Atxcit. 22 ° Eµrcp7101:txi.;; {1oµ{1E,;, pouxhai;, Pwµ0ttX(X XEptcit, 1t71 yei; ( 7tLOO(XE<;;), ,:poxoi XO(t mxpoµOLO( 1tupo1:ax11TJµ0t,O(, µE yiµt­ aµ0t µ71 ~uyt,011 7t(XIIW 0(7t0 1.200 1p0tµµtxpt0t Ot\lCX ELOO<;. 23 ° CANNON SHOTS (B).71µ0t,cx ITupo~oAou), ~uyi,011 'tO x0tBEIIO( oxt 7t(XVW 0(7t() 600 ypµµcitpLOt xoxxwoou.;; (lEAOt~,; 1tupi1:t60ti; T\ 220 yp0tµµcxpLCX Exp71x,tx71,; uA71,; OXL 7tEptaOO'tE· pov Emxi116uv71,; ,71,; rcupi-tL00ti; 0tAouµwiou µa urcEpXAWpLxov xcitAmv, RIRIE SHOTS (BAT)µ0t,cx TucpExiou) (xpo,txcx) ,o x0t8iv0t 1tEpLEXOV OXL rccxvw cxrco 20 ypcxµµ. xoxxwo71 rcupi 1:t60t, cit1t0tn0t Ecpoot0taµe110t µE rcupoawAT)VE<;; µE xcxAuµµevot cxxpcx· Xotl 7totpoµmot Eio71 1t0tpcxyonot OUVot'tT\ EX1tupaoxpo­ 't7IOTJ (xpo,:o). fLot at671poopoµLX<X OTj(lCX't()( oµix A71,;, ~AE7tE KA&OTJ 1 /1, 3 ° ( 7tEpt0WpLO 2131 ). . 24 ° Mtxpcit 7tUpO,EXV7J(lCX'tot (rc,x, a1:p0tXO(O'tpOt1XE<;;, ocpEi­ OtOt, XPUOTJ (1poxT\, otpyup7j {1poxT\, E<XV 7tEpLEXOU\I OXL rccxpcx 7tCX\IW ot7t0 1.000 ypcxµµcxptot xoxxw671 J.LEACX\/Tj rcupt'tLOot otv<X 144 Eio71. ucpotiO'tEtot XO(t xoµ71ni; XEtpoi;, Eat\/ 7tEptexouv OXL rccxpcit 7tCX\IW ot7t0 30 ypcxµµcitpLCX xoxxwoou.;; (lEACXVT)<; rcupi,L­ ooi; 'tO XotBe110t). 25 ° BETTotAtXCX xwpii; xEcpotAii;; otVotcpAE;Ew,; (rc.x, BETTCX· ALxii; ocxoE,;, cpw,ot, cpAoyE,;). 26 ° MAGNESIUM FLASH - POWDERS (MotyvT)ato 1t0t cpAcit,; cpw'to1p0tcpLxw11 µ71xotvwv ), oxt rccitp0t rccitvw cxrco 5 ypotµµcitptot 0(\/(X OO(XXOUAot T\ OWATJVCX, OE xcxpnvE,; acxxxouAE<;; T) µtxpoui; yuCXALVoui; OWA7JIIE<;;. 4. rcotpcxaL'tOX't0\10( ( UAE<;; Xott Eio71): 2 7 ° KotrcvoyovE,; uAE,; ytot yEwpytxoui; Xott OO(OLXOU<; axo­ rcoui;, XO(t Xot1tvoyo110t cpuai TTtot rcpoi; XPTJOLV wi; rccxpotOL'tO­ X'tO\lot. r Lot Xotrcvoyovoui; µ71x0t11taµoui;; 7tEpLEXOV'tot<; X Awptxcit CXACX'tot T\ µE,otcpipov'tot Exp71xnxo yiµtaµot 71 EXpTJX'tLXo cxvcx­ cpAExnxo yiµLaµ0t, {1AE7tE KAcitat\l 1(1, 9° (rcEpLBwpm 2131 ). 2. l\tot'tot;EL<;; A. KoA0t 1. r E\ltXOl opOL auaxwotaicx.;; (1) Tot ELOTJ auaxEu0taioti; 00t EivotL hat xAELaµiv0t xotL a,cx­ yotvcx WO'tE \10( 0(1tOcpEt1YE't()(t 07tOLot07!7tO'tE<; 0(7tWAEtot 'tOU 7tEflLE· xoµivou.. •. (2) Tot EL07I auaxwotaioti;, auµ1tEpV:0tµ{1ot11oµi11w11 ,wv XAEtaLµcit,wv 'tWII, 1tpE1tEL Vat El\lotl E7tOtpxwi;; citxotµrc,ot XO(t • YEPCX OE OAot 't()( (lEPTJ 'tOU<; WO'tE Vat ot7tO(j)EUYE'totL 07tOLotOT)7tO'tE xcxAcxpwa71 otcxpxot107j<; ,71,; µE,otcpopcxi; Xotl Vat 1tA71pouv 'tOU<; 2172 xotvovLxoui; 6poui; µnotcpopciti;. Tot Eio71 !lot rcpircEt 110t 0tacpotAi­ ,0111:cxL O'tCX0Epcit, Xotl m EOW'tEpLxii; auaxwcxaiE,; O'tOtBEpcit 0tacp0tAtaµi11ai; a,ti; d;w,EpLxii;; OUOXEUotaiai;. Ex,oi;; ECXV <XMW,; ELOLxwi;; opi~E'totL a,o cxp0po urea ,ov ,i,Aov «Luaxwcxaiot µtoti; uA71c; TJ Eµrcopwµcit,wv 'tOU otU'tOU Etooui;», 't(l( EOW'tEptxCX-El07I auaxwotai0ti; µrcopouv \10( EOWXAELOV'totl OE E~W'tEptxcx Ei671 au-. axwotaioti;;, Et'tE ivot - E\lot Ei,E 0µ0totxcit. (3) To 0(7t00{1EO'tLXO UAtXO 0ot 'tOtlfll<X~EL µE 't7I cpi.1071 'tOU 7tE­ pLEXOµivou. 2. Luaxwotai0t µt0ti;; uA71,; 71 aµrcopwµcx,wv ,ou 0tu't0u Ei­ ooui;;. (1) Ei671 1:71,;; 1 ° (0t) 0ot OUOXEUCX,OV't(l(t OE XU'ttot T\ {1t- 217: • ~Al()(. Tex XU'ttot otU'tot 71 ~t~Aiex 00t 'ttJAiyonext µE xov'tpO xexp'ti WO'tE VO( 0(7tO'tEAOUV EVO( OUMOYLXO xoAov, OAE,; OL rc,uxii; 'tOU orcoiou 00t xoAAouncxL. T0t ~L~Ai0t µrcopouv rnia71,; vat 't0rco0E­ ,ouv'tott OE XU'ttot xex,exaxwexaµivot 0(7t() LVW07I aexvioot T\ exrco UALXO OXL wxEpwi; EticpAEX'tO (rc,x, O(XE'tUAOXU't't()(piv71). Tot 0trco tvw671 a0tvi60t xu,iot T\ ,Ot auAAo1Lxcit xoAOt 0cx ,01to 8E1:ouv,otL OE YEPO XL~W'tLO Xot'totOXEU0taµivo 0(7t() ;uAo, µi­ 'totMO, aexvioot 7tEmEaµivou ~UAOU, YEPT\ O'tEpECX LVW07I OO(VLOO( TJ OL7tA7J o4awi;; XUfLOt'tOEtOoui;; Lvwooui;; OO(VlOO(i;;. 'OAE<;; OL EVWOEt<;; ,wv µa1:0tAAtxw11 xt~w,iwv 00t xAEivov'tOtt fLE µ0tACXXTJ XOA0ta71 T\ µE omA T\ - p0tcp7J. Tex xL~w1:t0t 0trco tvw671 a0tvi60t 00t xAEivov,0tt µE avwµivcx rc,:apu1L0t (xA0trchex). T0t citxp0t ,wv E;wnptxwv mEpuyiwv, XO(L oAE,; OL EVWaw;, Et'tE 0cx XOMOUV't()(L El'tE 00t XAEtVOUV O't()( 0Ep<X 6L' cxAAou x0t,0tM7JAou µfoou. Ecitv 'tOt 0t1to ww671 a0tvi6ex xu,i0t T\ ,Ot auAAoytxcx rc0txhcx auaxEuoc~ov,cxL OE xt~C:nt0t 0trco Lvwo71 a0tvi60t, ,o ~0tpoi; ,ou xoAou OEV 00t ump~OttVEL 't()( 20 KG. (2) Ei671 ,71,; 1 ° (~) Bot Eiv0tt hat auaxEucxaµivot aE xu,icx wa,a VOt rcocpEu1E,OtL xcitBE p.E't0txiv71ati;. 'Oxt 1tEptaao,Ep0t 0t1to 12 0t1to 0tu1:cx 'tOt xu1:i0t B0t ayxAEtOV'tOtL OE rc0txho, oAEc; OL rc,u­ xec; 'tOU orcoiou 00t XCXMOTJV't()(l. ·oxt 1tEpLOOO'tEp0t 0(7t0 12 0(7t() O(l)'t(X 'tot 7t()(XE'tot 00t 'ttJAiyo­ V't()(L µE yapo x0tp1:i WO'tE V0( 0(7tO'tEAOU\I EVot OUMOYLXO TCO(Xho, oAE,; OL rc,uxii; 1:ou orcoiou 0ex xoAAoun0tt. Tex auUoytxcx 1t0t­ xhcx 80t 't01tOBE'tOUV'tott OE YEPO Xt~W'tLO XOt'totOXEUO(O(lEVO 0(7t() ~UAO, µh0tMO, XIXPV't - µrcopv, 7tEmEaµivou ~UAOU, YEPTJ O'tE­ pEOt ww671 OotVlOO( TJ OL7tA7J<:; o4Ew,; xuµ0t,OELOT) LVW07I OO(VLOO(. 'OAE<:; oL EvwaEtc; ,wv µE,OtMLxwv XL~w,iwv 00t 0tacpcxAi,o­ v,OtL fLE fLOtAOtXTj auyxoM 71071 T\ OL7tA T\ p0tcp7J. K t~W'tl()( 0(7t0 LVW07I aotviocx 0ot XAEtVO\l't()(t µE Evwµivex 7t'tE­ puytex (xAex1tE'tOt). Tex citxpex 'tW\I d;w,Eptxwv 7t,Epuyiwv xext OAE<;; OL EVWOEL<:;, 1tpE1tEL El'tE VO( XOAAOIJV'totL Et'tE VO( XAEtVOV'texL a,0tBEp0t 6t' ocAAou XO('tO()J-i\)-.ou µfoou. Eocv 't()( auAAoytxoc rcexxhcx OUOXEU<X~OV't(l(L OE XL~W'tLex exrco LVW07I aexvioex, 'tO ~0tpoc; 't:01) XOAOU OEV 1tpi1tEt Vat tJ1tEp~0tlVEt 't0t 20 KG. (1) Eio71 ,71,; 2 ° Oat OUOXEUOt,0\/'t()(t OE XU'tl()( xex,exaxEuex­ aµiv0t 0(7t() cpuMo (lE'tOtMOU T\ L\IW07I acxvioex. ·oxt 7tEpLOOO'tEpex 0(7t() 30 xt{1w,tex 0(7t() cpuMo (lE'tOtMOU T\ 144 Xt~W'tLex exrco wwo71 aotvioex Oex xAEivov,otL aE i110t mxxho ,:o orcoio oEv rcpi 7tEt vex 1tEptiXEL rcEptaa6,Epo 0t1to 90 ypexµµ0tptex Exp71x,tx71c; uA71c;. Tex rcexxh0t exu't0t Oex 't01toBE'tOUV'texL OE XL~W'tLO au­ axwcxaiexi;, fLE XOtAwi;; EVW(lEIIE<:; 7tAEUpii; 7t1Xxoui; oxt µtxpo,i­ pou 'tWV 18 MM (xLA.), E7tEVOEOUfLEVO µa yepo XOtp,i T\ µE AE 7t't0 cpuUo cpauoexpyupou 71 exAouµwiou T\ µa cpuUo 0t1to 1tA0t­ anxT\11 uA71v OXL EUXEpwc; Et1cpAEX't7I, ITAaupLXOV rccxxoi; 11 MM (xtA.) OtfJXEL yt()( xoAov 7tOU 'uri,EL OXL 7t0t\lW 0(7t() 35 KG e:&11 ,o xt~W'tLO 1tEpL~A71Bai µa at6Epivt0t ,0tLvi0t. (2) To xoAov OE\/ 1tpE1tEL \10( ,uri,Et rcocvw cxrco 100 KG. (1) Ei671 ,71,; 3 ° Bex auaxEucx,011,cxt aE ~uAwcx xt~w,L0t arcEv 6a6uµivcx fLE yapo xexp,i T\ AE7t't0 cpuMO 4w6expyupou T\ 0(/..0U­ µwiou, T\ OE ~OtpEAt()( O(Qt(l(~poxou wwooui; aexviooi;. MLxpii; exrcoa,oAi,; rcou ,uri,ouv OXL 7t0t\lW ot7t0 20 KG, 7tE­ pt'tUAtyµivai; µa xuµot,OELOTJ tVWOTj aotvioot, µrcopouv E1tia71c; v0t yivonotL 1t0txhex (lE yEpo Ot - cpuMo X0tp,i auaxEuexaiot.;; 0tacpotAW<;; oEµEVO( fLE arccitno, (2) Oacxxti; XP710L(l07t0LOUV'tott ~OtpEAtex 0(7t() LVW07I aotvi6ot, ,o xoAov OEV rcpircu vex ,uyi,Et rcocvw exrco 7 5 KG. (1) N7Jµex 1t~poxuAiv71,; (PYROXYLIN THREAD) (4°) 2176 Oex poAAotpE,ext, OE µ7JX7I o·y t U7tEp{1otivonex 'tot 30 µ. exvcit poA AOV, T) poAAoui; wwooui; acxviocx.;;. 0 xcitOE p6Uoi; Oot 'tUAlYE'tott OE xcxp,L ·oxl 7tEptaaonpOL otrco 10 0(7t0 CXU'tOU<; 'tOU<; poAAoui; ECl>HMEPII. THI. KYBEPNHIEQI (TEYXOI. 6EYTEPO) 0ex i:u)..l-1ovi:ext oE x expi:i ouoxEuexoiexc; wo,E vex ex1tonAouv 1tex­ xii:ex ,:ex 01toiex 0ex exocpexA[,ovi:ext fJ.E ex1too~Eo,txo uAtxo OE µt­ xpii ~UAL\lex Xt~w.:tex. Tex XL~W'tLex 0ex 't07t00E'tOUV'text 0~ ~UAt\10 xL~wi:to ouoxwexoiexc;. (2) To XOAO\I 6EV 1tpe1tEl vex 7tEpLE)(El ltlX\IW ex1to 6.000 µ. 1111µcxi:oc; 1tupoxuAivljc; (PYROXYLIN THREAD). ( 1) Ei6Tj 'tljc; 5 ° 0ex OUOXEUIX,OV'text, O)(t 7tEptooonpex 'tW\I 2 5 CXVIX xui:iov, OE XU'tt(X xcx,:exoxw0toµivex exltO ltAIXXex xexoot­ i:ipou 11 tvw6TJ ocxvioex Ev i:ou,oLc;, X0tq>UAAL0t 0Epµi,TJ µ1topouv 110t ouoxeudt,ovi:cxt, O)(l 1tepL006,Ep0t ex1t6 100 exvdt xui:iov, oE XU'ttex OtltO tvw6Tj oexvl6ex. ·0x.i 7tEpLOOO'tEpex exito 40 ex1to exui:ii ,Ot xui:i0t 0ex exoipexAi,ovi:0tL fJ.E ex1too~EO'tLx6 UALxo oE ~uAtvo xL­ ~W'tLO xex,:dt 'tE'tOto i:p61to WO'tE \l(X fJ.Tj µ1topouv \l(X el0ouv OE rnexiplj eii:e µE,0t~u i:wv ei'te µe i:tc; 7tAEupic; ,ou xt~wi:iou. (2) To x6).ov 6ev 1tpi1tEL vex ,u,i,EL 1tiivw ex1t6 100 KG. (1) Ei6Tj 'tW\I 6 ° - 8 ° 00t ouoxwdt,ovi:exL: (0t) Ei6Tj 'tT)c; 6°: oi ~UALvex xt~wi:tex· (~) d67J 'tT)c; 7 ° (ex): oE ~uAtvOt xt~wi:tex 11 oe ~uAtvex ~ui:iex ii oe ~expiAtex xexi:exoxwexoµivex ex1t6 0t6tex1tipcxo,1J t11w67J ocxvi6ex· (1) Ei6Tj 'tTjc; 7° (~): 6x t 1tEptoo6npex i:wv 1.000 exvdt xui:io, exoip0tAt,oµev0t fJ.E exitoo~Eo,txo UAtxo cxito 1tptov6oxo111j ( 1tpto­ vi6Lcx) OE xu,:iex ex1t6 LVW67J oexvi6ex 6L1jp1jµivex OE 6x t AL1wnpo ex1t6 i:picx 6LcxµEploµex,:ex 1tEpLix o11i:0t ,:o x0t8iv0t 1tepi1tou i:ov exu 1:611 1Xpt0µov EL6WV XIXl foexx wpt,oµEvex fJ.E 'tt6aµe110t µE't~U exu­ 'tW\I ipuAAOt 1X1t6 tvW67J oexvioex. Tex xexMµµex,:ex ,:wv xui:iwv 0ex exoq>0tAi~Oll'text µE xoµµtwµivec; ,upw - ,upw 'tlXtViEc;. 'Ox t 1tE­ ptoo6,ep0t 0t1t6 100 cx1t6 ,Ot xui:iex exui:ii ex1t6 tvw67J 00tvi6ex 0cx 't07t00E't01J\l't(Xl OE 6t1X'tpTj'tO 6ox Eio ex1t6 q>UAAO - OL6TjpOu. To 6ox eio 'tOU'tO 00t exoipexAi~E't(XL µE (XltOO~EO'tlXO UAlXO OE Xl~W­ 'tLO ouoxEuexoiexc; ~UALVO ,:o 01toio 00t XAEivet µE ~i6Ec; XOtl ,:ou 01toiou ot itAeupic; 6ex ix ouv 1tiix oc; 6x t µLxp6npo ,:wv 18 MM (x LA.) xexi:dt ,:otoui:o ,:p61to won vex U7t1Xp)(El 6Liio,7Jµex 6x t At 1onpo ,:wv 3 CM (ex.) 1Eµtoµivo µE cxitoo~eoi:txo UAtx6 OE 6).ex 't(X Ol]µEiex µe,Ot~U 'tOU 6ox Eiou exito (j)UAAO - ot6ljpou xext 'tOU Xl~W'tLOU OUOXEUOtoiexc;· (6) EioTj 'tTjc; 8 °: OE xui:icx 0t1to tvw67J ocxvi6ex. Tex xui:iex 0ex 1ivovi:0tt 1t0txii:o ,:o 01toio 00t mpti)(El 6x t 1tEptoo6npouc; ex1t6 1. 000 TJAExi:ptxouc; exvexqi).ax,7JpEc;. To 1tcxxho 0ex i:01to8ani­ i:0tL oE ~uAtvo xt~W'tto ouoxwexoi0tc;. (2) IlpoxEtµivou 1tEpl ~expeAlwv ex1to tvw67J ocxvi6ex, i:o xo­ Aov 1tou 1tEpti)(EL EioTj ,Tjc; 7 ° ( 0t) 6Ev 1tpi1tEt vex ~u1i~Et 1tEpto 06npo ex1t6 75 KG. KoAOV ltOU 7tEplE)(El EioTj 'tTjc; 7°(~) 6,EII 1tpa1tEl \l(X ~u,i,Et 7tEptooonpo otltO 50 KG EIXV ~u,i,El 7tEpto­ ocmpo OtltO 30KG 60t Et\lotl Eq>06Lexoµavo µE )(ElpOAot~ic;. (1) Ei6Tj ,:wv 9° - 26° 0ex EjXAEiovi:ext (EownptXTj ou oxEu0toi0t): · • (ex) EioTJ ,:wv 9 ° xm 10 °: oE x dtpi:tvot ei6Tj ouoxwotoioo; 7J OE· xui:iot· (~) Ei67J ,7Jc; 11 ° ( ot ): 6x t 1teptoo6-iepex ,:wv 5 00 otvcx xui:io ex1t6 tvw67J ootvioot 11 exvdt µtxpo ~UAL\10 XL~W'tlO, otOq>otAl~oµEvex µE 0t1too~eoi:tx6 UAtx6 cx1t6 1tpto11i6Lex: 1. oe xui:iot ot1t6 t11w67J oexvioex 'tOt 01toiex 0ex i:uAi1ovi:cxt µE x otpfr 7J 2. oE µtxpii ~uAtvot xt~wi:tot· ( 1) Ei6Tj 'tTjc; 11 ° (~) 6x t 1tEptoo6npot ,:wv 10 otvdt ~t~Aio, oE ~t~Alex· 6x t 1tEptoo6np0t i:wv 100 ~t~Aiwv µotl;i 0ot ou­ oxEudt~ov'tcxt OE xui:io ex1t6 tvw6Tj 00tvi6ot 1j 'tUALjO\l'totl fJ.E jEpo x expfr (6) ei6Tj 'tljc; 11 ° (j): O)(l 7tEpLOOO'tEp0t OtltO 10 ot\llX oexx­ XOUAOt, OE OOtXXOUAEc; x dtpi:t11Ec; 11 ex1t6 Xot't!XAATjATJ ltAotO'tlXTJ UATj • O)(l 7tEptoo6npa~ IXltO 100 OIXXXOUAEc; µot~i 0ot OUOXEUIX­ ,0\l'tcxt oE xui:io ot1to t11w67J 00t11i60t· (E) Ei6Tj ,7Jc; 12 °: 6x t 1tEptooo,Ep0t ex1to 25 exvdt xui:io, oE xui:lot 0t1t6 tvw67J oot11i60t • • ( o,:) Ei6Tj ,Tjc; 13 ° : xui:iot 'tUAtjµivot OE )( otpi:i won vex ex1to­ n).ou11 1texxi,:cx·1tEptax o11,ot i:o xex6i11ot 6x t 1tEptoo6npex ot1t6 12 xui:iot· (') Ei61J 'tTjc; 14 °: oE xui:iot 11 oexxxouAEc; cx1t6 x otp'ti 7J xot­ 'tCXAATjATj ltAOtO'tlXTj UATJ. Ot OUOXEUotoiEc; exui:ac; 0ot 'tUALjOll'tott oE x otpi:i won vex ot1tO'tEAou11 1totxii:ot 1tEptix o11,:ex ,:o xot0ivot O)(l 1tEptoo6npot ,wv 144 ,:wv Et6wv otui:wv· ( Tj) ei6Tj ,Tjc; 15 ° : oe xui:iot ex1t6 t11&61j ootvioex 1tEpti~o11,:ex i:o xex0avot: 6x t 1tEptooonpex ,:wv 100 x0tq>uAAiwv, i:o xex8i110t, . 1Eµt­ oµivo µE 6x t 1tEptoo6,Epot ,:wv 5 MGEXPTJX'ttx7Jc; UA'ljc;· 2178 2179 11 O)(t 7tEptoo6,Epex ,:wv 50 XOtq>UAAiwv ,:o xot0ivot jEµtoµivo µE O)(l 7tEptooonpot 'tW\I 7,5 MG EXPTJX'ttxric; UATjc;. 'Ox t 1tEptoo6npot ,wv 12 ot1to ,:ex xui:iot exui:dt 0ot 1 i11011i:0tt x dtpi:tvoc; poAAoc;, Xotl O)(l 1tEplOOO'tEpot otltO 12 poAAOl 60t 'tUAi­ jOll'tott oE x 0tpi:i ouoxwotoiexc; won vot ex1tonAou11 1totxi'to. • TottVLEc; 'tW\I 50 XIXq>UAALWV, 'tO xot6avex xot4uAAt0 jEµt­ oµivo µE O)(L 1tEptoo6,Epot i:wv 5MG EXpTJX'ttXljc; UAT)c; µ1to­ pouv \lot OUOXEUIX,OV'text Xot'tlX 'tO\I otXOAou0o ,:p61to: 5 'tCXt\ltEc; otvdt xu,:io, OE xui:iot ex1t6 tvW6Tj oexvioot 'tUAljfJ.Ellot 6 µotl;i OE )(otpi:l tooouv0tµo OE IX\l'tO)(TJ µE )(otpi:i KRAFT (x.0 11,:po x expi:i ouoxEuexoiotc;) xexi:w,:cx,:ou ~iipouc; 40 MG/µ2• 12 µtxpii 0ot ,:u).i1011i:0tt µotl;i OE x otpi:i ,Tjc; IXu'tTJc; 1tot6,1ji:oc; woi:E vot ot1to,EAioouv ivot µEjlXAO 1totxho· (0) ELOTj ,Tjc; 16°: otOq>CXAl~ov,:ott µE ot1too~Eo,txo UAtxo, O)(l 1tEptoo6,Epot i:wv 50 cxvcx xui:io,. OE xui:iot ot1to lllWOTj o001i6ex. Ot lj)EAAoi 0ot xexoAouv'tott 01:011 1tu0µi11ex ,:wv xui:iwv 11 0ot i:o 1to8e'touvi:0tt O'tTJ 6foTJ ,:ouc; µE xdt1totot toooii111Xµo µ!0060. To xii0E xui:lo 01X ,uAi1E,IXL µE )(Otp,i xcxt O)(t 1tEptooo,Epex 1X1to 10 xui:iex 01X ,u).i10111: 1XL oE x cxp,:i ouoxEuexoi0tc; wo,E \lot ot1tO'tEAoii11 ltOtXE'tO ,· (t) dOTj 'tTjc; 17 °: O)(l ltEptoOO'tEpot 'tW\I 5 exvdt xui:io, OE xu­ 'ttot otltO t11w61j ootvi6ot. 'Ox t 1tEptooo,Ep1X 'tW\I 200 XU'tLWV, i:otxi:01tot1jµivwv OE p6)..)..ouc; 01X i:01to8E'tOUV'tlXl µotl;i OE ouAAo 1tx6 xui:io 1X1t6 tvWOTj ·00tvi61X· (x) Et61j 'tTjc; 18 °: IXO(j)OtAt,oµEvlX fJ.E IXltOO~EO'ttXO UAtx6, O)(l mptoo6np0t ,:wv 10 cxvcx xui:io, oE XU'ttlX IXltO t\lWOTj o001i60t. 'Ox t 1tEptooonp0t 'tW\I 100 XU'ttWII, 'tlXX't01totouµivw11 OE poA­ Aouc;, 01X i:uAi1011,1Xt µE )(1Xp,i wo,E .vot ot1ton).foouv 1totxho· ().) Ei6Tj 'tTJ<; 19 °: cxotp0tAt,oµEvix fJ.E 1X1too~EO'ttxo uAtxO, 6x t 1tEptoo6,Ep1X ,:wv 15 exv<i xui:io, OE xu'tiex 1X1to tvWOTJ o001i61X. 'Ox t 1tEptoo6npex ,wv 144 xui:iwv, i:exxi:01tot'ljµi11wv oE poA­ Aouc;, 01X ouoxEu<i~ovi:ext oE OEunpo xui:io ex1t6 ww6'1j oot11i6ex· (µ) EL61J 'tTjc; 20° (ex): 1Xoq>CXA.t~6µE11ex µE ex1too~EO'ttx6 UAtx6, O)(l 1tEptoOO'tEp0t 'tW\I 144 exv<i Xl~W'ttO, OE Xl~W'tllX IXltO tvw6'1j OOtVi61X· • , ~ ' (v) Ei6'1j 't'ljc; 20~ (~) O)(l 7tEptoo6np1X 'tW\I 75 IX\l!X XU'ttO, OE xui:iex 1X1t6 tvw67J 01X11i60t· O)(l 1tEptoo6,Epex ,:wv 72 xui:iwv 0ex ,uAi1ovi:ott fJ.E tvw6'1j 01Xvi6ex won VIX ex1to,EAe.oou11 E\!.Ot 1tot- • xi'to· m EioTJ 't'ljc; 21 °: OE xui:iex IXltO L\IWOTJ 01X11i6ex 1j OE jEpo x 0t'p,:i. Edtv ,:o oTjµEio OtVotlj)AE~Ewc; ,:wv Et6wv OE\I XCXAUlt'tE'tlXl . 1X1to 1tpooi:0t'twnxo x<iAuµex, i:o xot0ivex Eiooc; 1tpi1tEt 1tpwi:ex VIX ,uAt)(0Ei x wptoi:dt µE x expi:i. To 1tpow8'1ji:txo 1iµtoµIX :wv ~oµ~wv ltOU ~u,i~OU\I ltlXV(a) exltO 5 KG 0ot 1tpooi:exnuo11'text ot1t6 x <ipi:tvo xt~wi:to x1XAii1ti:ou11 i:o x<i,:w µipoc; 'tTjc; ~oµ~IXc;· (o) Ei61j 'tTjc; 22 °: OE xu,:lex ex1to l\lWOTJ ootviolX 1l OE xo116po xexp,:i. 'Oµwc;, µEj!XAIX 7tUpO'tE)(111jfJ.1X'tlX OE\I )(PEl!X,E'texl \lot E)(OU\I EOW'tEptXlj OUOXEuexoilX E!X\I 'tO OTJfJ.EtO otllotq>AE~Ewc; ,:ouc; xa:Auitni:ext 1X1to 1tpooi:0tnui:txo x<iAuµµex· ( 7t) E/OTJ 'tTjc; 2 3 ° : 1Xoq>exAt,oµE11ot (J-E 0t1too~Eo,txo uAtxo oE xui:iex xex,1Xoxwexoµi11ot ex1t6 ~u).o 11 tvWOTJ 01X11i6ex. Ot xEtpCXAic; 1X11exrpAi~Ewc; 0ex 1tpooi:ex,Eiio11,:ext ot1t6 1tpoo,1Xi:wi:txo x<i­ Auµµ1X· (p) Eil'iTJ 'tTJc; 24 °: oE xu,i0t otlto tvw6TJ o001ioex -ri oE ,Epo )(1Xp,i· ( o) ELOTJ 'tTJ<; 2 5 °: OE xui:icx 1X1to tVWOTJ oot11i6ot 11 oE jEpo x expi:i. Ev i:oui:otc;, (J-Ej<XAIX 1tupo,EXV1)µoti:ex 6E11 )(PEtdt~next vot ix ouv Eow,EptXTj ouoxEuexoiot adtv ,:o O'ljµaio OOICXq>AE~Ewc; ,:ouc; E)(Et XIXAUq>0Ei (J-E 1tpoo,1X'tEU'ttXO x<iAuµµex· (t) EtOTJ ,7Jc; 26°: OE xu,:iex ex1t6 tvWOTJ 01Xvi6ot. To xui:io 6a11 1tpi1tEt 11ot 1taptE)(El 1tEptoooi:ipouc; 1X1to 3 .ru<iAtvouc; owA7111ac;. (2) Ot EOCa>'tEptxac; ouoxwotolEc; Ol ex111Xq>ipoµa11Ec; O'tO (1) 0ex OUOXEUIX,OV'text: (ex) OUOXEUotoiEc; ltEptix ouoac; EtOTj 't(a)V 10 ° . 13 ° xext 14 °' OE ~UAt\lex Xl~W'ttex OUOXEU0tOi1Xc;· (~) OUOXEUIXOiEc; 1taptax o1J0Ec; uAEc; 1l aiO'lj 't(a)\I 9 °. 11 °' 12 °. xext 15 ° - 26 °. oa ~UAtvex xt~wi:tex ouoxEuexoi~ µa xCXA<i Evwµivac; 1tAEupic; 1t<ix ouc; O)(t µtxpoi:ipou ,wv 18 MM (xLA. ), EltE116a6uµi11ex µa jEpo x exp,:i 1j AElt'tO q>UAAO <jiauoexp,upou 1j q>uAAo CXA.ouµtviou. 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(~) EucpAEx-cot • MiyµO(,O( OXl At,o'tEpo 'tOU 90% µE0otviou XO('t' oyxov fLE u6po1oviiv0potxEc; ,wv 3° (~) XIXl 5° (~)· Et>Cj)AEX'tO( µi1µot,O( 6uo 71 ltEplOOO'tEpwv 't(,)\I 1totp1XXIX't(,) otEplwv: u6poyovou, µE 00(\ltOU, O(,w,ou, OltO(Vtwv O(Epiwv (itEplEXov,wv oxt <ivw ,ou 10% :::evov Xot't' oyxov ), oxt IX\/(,) 'tOU 30% 6w;Et6iou 'tOU iiv 0potxoc; xot,' ciyxov) cpuotxov iiapwv. (~ T) EucpAax,O(, ,o~txii Aepto TToAEwc; (il~µou): µiyµot'tlX u6poyovou fLE OXL IX\IW 'tOU 10% OEATj\llOUXOV u6poyovov (HYDROGEN SELE­ NIDE) ~ cpwoq,iv71v ~ OlAIXVlOV ~ 1Epµiivw xot,' oyxov ~ fLE OXl IX\/(,) 'tOU 15% otpolVT)\I XO(,' oyxov· µiyµot,IX O('W'tOU 71 OltO(­ vlwv otEpiwv (itEptExonwv oxt iivw ,ou 10% '.::evov XO(,' oyxov) flE oxt 0.\1(,) 'tOU 10% OEATj\llOUXOU u6poyovou ~ cpw­ oq,lVT)\I ~ otAiivtov ~ 1Epµiivw xot,' oyxov ~ µa oxt iivw ,ou 15% otpolv71v Xot,' oyxov· u6pO(epto· otEpto XTJfLlXTjc; ouv0ioEwc; (it.X. Ex 'tT)c; µa066ou FISCHER-TROPSCH)· µiyµO('tlX µovo;Et6lou ,ou <iv0potxoc; µE u6po1ovo ~ µa µE0iivw. (r T) X71µtxwc; O(O'tot0~, -co;txii MiyµO(,O( u6po1ovou µa oxl iivw ,ou i 0% St~opiivw xot,' ciyxov· µiyµot,O( O('W'tOu ~ oitotviwv otEpiwv (itEplEXciv,wv OXl IX\/(,) 'tOU 10% '.::evov Xot,' oyxov) flE OXl IX\IW 'tOU 10% 6t~O piivto xot,' ciyxov. . B. YypoitOLTjflEVIX O(Eplot (~AEltE rnio-:iic; ltEpt0wpw 22of'd t)lt(l O'tOLXEtlX (~) XIXl (E). ftO( O(Eplot ,wv 3 ewe; 6° fl-EOIX OE 6tO(­ VEflT)'tEc; otEpO,OA ~ µEOO( OE µ71-;otVO(YEfll,OfLE\IO( 6oxEilX (CO­ NTAINERS) ytot IXEptot UltO lttEOTj, ~AEltE t)lt(l O'tOlXELIX 10° XIXl 11 °): • AiptlX sxo\l'tO( xpl'tLXTj\l 0EpµoxpO(OLIX\I -10° C ~ IX\/(,) 0Ew­ pou\l'tO(l O'tl Et\lO(l uypoitOLTjfLEVIX O(EptO( ytO( wuc; OXOltOUc;·'tT)c; ADR. (ot) Yypo1t0t71µev0( otEplot exonot xpt,tx~v 0EpµoxpO(OtO(V 70° ~ iivw: 3° K0(6otpii IXEplO( XO(l 'tEXVlxwc; - X0(0otpii O(EplO( ( 0() • AcpAEX'tlX • BpwµoxAwpw6tcp0opwµE0iivtov (R 12 B l)· XAwpto6t­ cp0optoµE0iivto (R 22)· XAwptoitEV'totcp0optom0iivw (R 115)· I-xAwpw-2,2,2-,ptcp0opl01Xt0iivlO (R 1330() 6lXAWpl06tEcp0o­ pwµa0iivlO (R 12)· 6txAwptocp0opwµa0iivto (R 21)· 1,2 Stx AWplo-1, 1, 2, 2 ,-'tE,pO(cp0oplOotl0iivw (R 114 )· ox,wq,0o­ ptOXUXAO~OU'tlX\llO (RC 318). ( 0( T) • Aq,AEX,O(, ,o;txii Aµµwviot: XAWpwuxo ~optov (6tot~pw,lXOV)· XAWplO\I (6lO(~pW'tlXOV)" ,ptcp0opwuxov XAWplO\I (Stot~pW'tlXOV)" E~Ot­ q,0opl01tpo1tUAEVlO\I (R 216)· u6po~pwµw (6tO(~pW'tlXOV)" µE 0uAo~pwµl6w· vt,po,uxAwpl6to (6tO(~pw,txciv)· 6w;d6wv ,ou O('W'tOU NOJ (u1tEpo;El6tov ot,wwu, 'tE,po;El6to ,ou O(,W­ ,ou N20~) (6tO(ppw,txov)· cpwoyivtov (6tO(~pw,txov)· 6to;ai 6tov 'tOU IJalou· cp0opwuxo SULPHURYL· E~O(cp0optouxo ~OA­ cppiiµw. (~) EucpAEx,ot Boui:O(VLO' 1-Bou'tUAE\llO (1-~0U'tE\llO)" l-xAwpto-l,l 6tq,0oplOO(L0iiVlO (R 142~)· CIS-2-~ou,uAivw (CIS-2 ~ou,evto )· XUXA01tp01tlX\ILO" 1, 1,- 6tq,8opt00(t0iivto (R l 52ot)· 6tµE0u).m0~p· too~ou,ii­ vto· too~ou,uAEVlO (too~ou,ivw)· µE0uAolA<Xvw· itpomivw· 1tpo1tuAEvto· TRANS-2-~ouwAEVlO (TRANS-2-~ou,evto)· 1, 1 l-,ptq,0optoO(t0iivto. • (~ T) EucpAEX'tO(, 'tO~LXIX Apoiv71· StxAwpootAiivto· 6tµa0uAotµivf· 6tµa0uAo~<ivto· otl0UA1XfLtVTj' O(l0UAOXAwpi6to· OEATj\llOUXO u6poyovo· u6pci 1149 1150 t:.tUHMt:.P12. I H2. kYBt:.PNH2.t:.U2. ( I t:.YXU2. ~t:.Y I t:.PU) 0Eto' µE8uAexµlv71· µE0uAoxAwpl6to· µE8uAtx71 µapxex1t'tdtv71· 'tptµE0uAexµlvTj • 'tpLµE0uAoLAotvto. (1) X71µtxwc:; exo'tex871 1,2-~ou'tex6tEVLO, 1,3-Bou'tex6tivto, XAwptouxo ~tVUAtO, Tiexpex't1jp71011: l:E 6oxdex 1tEptEXOV'tex 1,2-Bou'tex6tivto, 71 ouµ1tuxvwo71 o1;u1ovou o't71v exipto cpdto71 6Ev 0ex 1tpi1tEt vex U1tEp~exlvEt 'tex 50 xo'tA/µ3 • (, T) X71µtxwc:; exo'tex871, 'tO!;txdt Kuexvo,ovo· xAwpoxuexvi6to (dtcpAEX'tOV) (6tex~pwnxov)· o1;d6to exL0uAEvlou· µE0uAo~tvuAoexL0ipexc:;· 'tptcp0optoxAwpoexL 0uAivto (R 1113 )· ~tvuAo~pwµl6to. l:71µ.lwotc:;: l:'t71v 1tEpL1t'tWOT) 'tWV <XAo1ovwv u6po1ovexv 0pdtxwv, 71 XP7IOTJ ovoµexotwv ouv718wv o'to Eµm'>pto, 61twc:; ot 1texpexxdt'tw, Em'tpE1tE'tcxt: ALGOFRENE, ARCTON, EDIF­ REN, FLUGENE, FORANE, FREON, FRESANE, FRI­ GEN, ISCEON, KALTRON, exxoAou0ouµEvEc:; ex1to 'tOV expt0 µov exvexrvwploEwc:; 't'Tjc:; UA 71c:; xwplc; 'tO ,pdtµµex R. 4o. Ml1µex'tex exEplwv (ex) • AcpAEX'tex Ml1µex'tex uAwv 't7lc:; 3° (ex) µE'tot 71 dtvw E1;excp0opto1tpo1tuAE­ vlou 't7I<; 3° (ex T), 'tex 01tolex we;: µ[,µex FI ixouv 1tlE071 ex'tµou EL<; 70° µ71 U1tEp~exlvouoexv 'tex 1.3 MPex/13 BAR xext 1ttJXVO't7l'tex EL<; 50° C OXL µtxpo'tipexv 't7I<; 1tUXVO't7l'texc:; 'tot) 6tx Awpocp0optoµE0exvlou ( 1.30)· µl1µex F 2 ixouv 1tlE01J ex'tµou uc; 70° C µ71 ump~exlvouoexv 'tex 1.9 MPex/19 BAR xexL 1ttJXVO'tTJ'texc:; Etc; 50° C oxt µLxpo'tE pexv 'tTJ<; 1ttJXVO't7l'texc; 'tOU 6tx Awpo6tcp0optoµE0exvlou (1.21.)· • µl,µex F 3 ixouv 1tLE07I ex'tµou Etc:; 70° C f.71 U1tEp~exlvouoexv 'tex 3 MPex/30 BAR xext 1ttJXVO'tTj'tex Etc:; 50 C oxt µtxpo'tipexv 'tTJ<; 1tUXVO't7j'tex 'tOU XAwpo6Lcp0optoµE0exvlou (1.09)· l:71µ.lwotc:;: 1. TptxAwpocp0optoµE0<Xvtov (R 11), 'tptxAw­ po'tptcp0optoµE0otvtov (R 113) xex't xAwpo'tptcp0opLoµE0dtvto (R 133) 6Ev dvext u1po1tot71µivex exiptex EV'toc:; 'tTJ<; evvolexc:; 't7I<; ADR xexL rnoµivwc; 6EV U1tOXEtv'text O'tOuc:; opouc; 't7lc:; ADR. M1topouv EV 'tOU'tOtc; vex ouµ1tEptA71cp8ouv etc; 't7IV ouv0EOTJ 'tWV µtrµdt'tWv F 1-iwc:; F 3. 2. BAE1tE l:71µElwotv u1t6 O'tOLXElov 3°. To ex~EO'tpomxov µ[,µex 'tOU 6LxAwpo6t~0optoµE0exvlou (R 12) xext 1,l-6Lcp0optoext0exvlou (R 152ex), rvwo'tov we:; R 500· To ex~eo'tpomxov µl1 µex 'tOU XAwpo1tEV'texcp0opLoµE0exvlou (R 115) xext XAwpo6tcp0optoµe0exvlou (R 22), ')"VWO'tOV we; R 502. To µl,µex 'tOU 19 iwc:; 21 'tOL<; EXex'tOV Xex'tot ~dtpoc; 6tx AW­ po6Lcp0optoµE0exv[ou (R 12) xexL 79 iwc; 81 o'tex exex'tov xex'tdt ~dtpoc; ~pwµoxAwpo6tcp0optoµE0exvlou (R 12 BI). ( ex T) • Aq>AEX'tex, 'tO!;LX(X. Ml1µex'tex µe0uAo~pwµL6lou xexL xAwpomxplv71c; ixoV'tex 1tLEOT) ex'tµou <XVW 'tWV 300 KPex/3 (BAR) Etc; 50° c. (~) EucpAex'tex Ml1µex,ex u6po1ovexv0pdtxwv 't'Tj<; 3o (~) xext ext0exvlou xext cxt0uAev[ou ,71c; So (~), 'tex 01tolex we;: µ[,µex A ixouv 1tlE071 ex'tµou Etc; 70° C µ71 U1tEp~ex[vouoexv 'tex 1,1 MPex/(11 BAR) xext 1tuxvo't71,ex Etc; 50° C oxL xdt'tw 'tWV 0.525· µ[,µex AO ixouv 1tLE07I ex'tµou etc; 'tOU<; 70° C µ711.mEp~ex[­ vouoexv ,ex 1,6 MPex/(16 BAR) xext 1ttJXVO'tTj'tex Etc; 50° C oxt X<X,W 'tWV 0.495.· µl,µex A I ixouv 1tlEOTJ ex'tµou Et<; 70° C U1tEp~ex[vouoexv ,;ex 2, 1 MPex/(21 BAR) xext 1ttJXVO't7l'tex Etc; 50° C oxt XIX'tW 'tWV 0.485· µi,µex B ixouv 1tlE07I ex,µou Etc; 70° C µ71 U1tEp~exivouoexv 'tex 26 KG/CM2 xext 1tuxvo,71'tex uc:; so0 c oxt x<X,w 'twv 0.450· µl,µex r ixouv 1tlE07I ex,µou Etc; 70° C µ71 U1tEp~exlvouoexv 't(X 3,1 MPex/(31 BAR) xext 1ttJXVO't'Tj'tex etc; 50° C oxt XIX'tW 'tWV 0.440. l:71µeiw0Lc;: l:'t71v 1tEpl1t'two71 ,wv exvw,ipw µt1µdt'twv Em­ 'tpE1tE'text TJ xp71071 ,wv 1texpexxdt,w ouv718wv o'to Eµ1t6pto ovo­ µcxcrtwv ,tex ,71 1tEpL')"pexcp71 ,WV UAWV exu,wv: Ovoµexolex u1t6 o'totxelov 4° (~) Ovoµexolex ouv71871c; o,o eµ1t6 pto Ml1µex A, µl1µex A 0 Mi1µex r ~OU'totVLOV 1tpo1tdtvtov Mlrµex'tex u6po1ovexv0pdtxwv 'tWV 3o (~) xext 5o (~) 1tEpti­ XOV'tex µe0iivLov. (~ T) EucpAEX'tex, 't01;txdt Mi1µex,ex Mo 71 1tEpLooo'tipwv ,wv 1texpexxdt'tw exeplwv: µe 0uAotAexviou, 6tµe0uAotAexvlou, ,ptµe0uAotAexvlou· µe0uAo­ XAwpt6lou xexL µe0uAevoxAwpt6iou OE µl,µex,ex ixovi:ex 1tlE07I ex,µou <XVW ,wv 300 KPex/(3 BAR) Etc; 50° C • Mi1µex'tex µex0uAoxAwpt6lou xext XAwpomxplv71c; xext µ[1 µex,ex µe0uAo~pwµt6lou xext ext0uAEVLo~pwµt6iou ixov'tex oE xii.Se 1tEpl1t'tWOTJ 1tlE07I ex,µou <XVW 'tWV 300 KPA/(3 BAR). (,) X71µLxwc; exo,ex871 • Ml1µex'tex 1,3 ~ou'tex6tev[ou·xext u6po1ovexv0p(ixwv 't'T)c; 3° (~) µe 1tLE07I ex,µwv OE 70° C OXL 1t(XVW ex1t6 1, 1 MPex(ll BAR) xext 1tuxvo,71'tex oe so0 c oxt xdt'tw 'twv o,s2s. Ml1µex,ex µe8uAexxe'tuAlv71c; xexL 1tpo1tex6tevlou µE u6po1o­ vdtv0pexxec; 't'T)c; 3° (~), 'tex 01tolex we;: µi,µex P l 1tEptixouv oxt (XVW 'tOU 63% µE0uAexxe,UAEviou xext 1tpo1tex6tEvlou xex.' 61xov xext 'tO 1t0Au 24% 1tpo1texvlou xext 1tpo1tuAEvlou xex,;' 61xov, 'tOU 1toooo'tou 'tWV c 1 . xexope­ oµivwv u6po,ovexv0pdtxwv OV'tO<; oxt xdt,w 'tWV 4% xex't' O')"XOV' Xext we; , µ[,µex P 2 1tEptixouv oxt dtvw 'tOU 48% µe0uAexXE'ttlAEVLOU xexL 1tpo1tex6tEviou xex.' 61xov xext 'tO 1t0Au 50% 1tpo1texv[ou Xext 1tp01tUAEVlOU Xex,' O')"XOV, 'tOU 1tOOOO't01J 'tWV C 4 • XEXOpE· oµivwv u6po,ovexv0pdtxwv OV'toc; oxt XIX'tW 'tOU 5% xex.' 61xov. (, T) X71µtxwc; exo'tex071, ,o!;tX(X At0UAEvo1;d6to 1tEptixov oxt dtvw 'tOU 10% 6to1;EL6iou 'tOU <Xv0pexxoc; xix.' orxov· exL0uAevo1;ei6to 1tEptixov 'tO 1tOAU 50% µE0uALxou dtAex'tOc; µupµ71xtxou o!;foc; xex't' 61xov, µE dt~w'to ouv0Atx71c; mfoEwc; iwc; 1 MPex (10 BAR) OE 0epµoxpexoiex 50° C· 6txAwpo-6tcp0optoµe0<Xvto 1tEptixov 12% ext0UAEvo1;el 6to Xex't!X ~dtpoc;, (~) Y1po1tot71µivex exiptex ixov,ex xpt'tLx71v 0epµoxpexoiexv 10° C we; dtvw, exUdt X<X'tW 'tWV 70° C: 5° Kex0expdt exepLex xext ,exvtxwc; - xex0expdt exeptex (ex) 'AcpAex'tex Bpwµo'tpLcp0optoµe0iivLo (R 13 BI)· 6to1;ei6to 'tOU dtv0pex- 2.201 xoc; • X Awpo'tptcp0optoµE0<Xvto (R 13 )· e1;excp0optoext0dtvto (R 116)· Vt,pw6Ec; o!;u N20· E1;excp0optouxo 0Eiov· ,;'ptcp0optoµE 0iivLO (R 23)· !;ivov. Avexcpoptxdt µe 'tO 6to1;ei6to 'tOU dtv0pexxoc;, ~AE1tE E1titl'T)c; 1tE­ pt8wpto 220lex t)1t() O,OLXELOV (,). l:71µElw0Lc;: 1. To VL'tpwfac; o!;u 0ex ,lvE'text 6EX't0 ,tex µE'tex cpop<X µovov edtv 6ev Eivext xdt'tw ,ou 99% xex0exp6v. 2. BAi1tE l:71µElwotv U1t0 O'totxdov 3o. ( ex T) • AcpAex,ex, ,o!;txdt Y6poxAwpto (6tex~pW'tLXov). (~) EucpAEx,ex At0iivLo' ext0u)..ivto· OLAiivto. (~ T) EucpAEX'tex, 'tO~txdt fEpµdtvto, cpwocp[v71. . (1) X71µtxwc; cxcr,ex871 1, l-6tcp0optoexL0uAivto· cp0optouxo ~LVUAto. (1 T) X71µtxwc; cxcr,ex871, 't01;Lxdt dt~opdtvto. 6° Mi1µex,ex exEplwv (ex) 'AcpAEx,ex dto1;Ei6to 'tOU dtv0pexxoc; 1tEptEXOV OXt X<X'tW 'tOU 1 % Xext OXt otVW 'tOU 10% ot~W'tOV, o!;urovov, exipex 7I 01totVtex exipLex Xex'tot ~dtpoc;· 'tO ex~Eo,pomxov µl,µex 'tOU xAwpo,ptcp0optoµE0exviou (R 13) xext 'tptcp0optoµe0exviou (R 23), rvwo,ov we; R 503 .. l:71µEiwotc;: dto1;ei6to 'tOU dtv0pexxoc; 1tEpLEXOV oxt Xot'tW 'tOU 1 % <X~W'tOv, o1;u16vov, exipex 7101tdtvtex exiptex xex't<X ~dtpoc; elvext uA71 ,71c; 5° (ex). (,) X71µtxwc; ex1nex871 dto1;ei6to 'tOU <Xv0pexxoc:; 1tEptixov oxt dtvw 'tOU 35% ext0u­ AEVO~Et6iou xex'tdt ~expoc;. (r T) X71µLxwc:; exo'tex871, ,o!;txdt ' At0UAEvo1;ei6to 1tEpLEXOV dtvw 'tOU 10% exUdt oxt dtvw 'tOU 50% 6to1;Ei6to ,ou dtv0pexxoc:; xex'tdt ~dtpoc:;. f. Bex0etdt - xex,e~u1µevex (DEEPLY-REFRIGERATED) uwo1tot71µivex exipLex 7° Kex0exp(i exiptex xext ,Exvtxwc; - xex0expdt exiptex ECl>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: aEYTEPO) 1151 (ex) 'AcpAextcx Apyov· oto;Elliw tou dcv0pcxxoi;;· TjALov· xpu1ttov· veOV' ll~WTOV' Vttpw6Ei;; o~u Np· o~uyovOV' ~EVOV, (~) EucpAEx-rcx cxt0dcvw· ott0uAivto· u6po1ovo· µE0dcvw. 80. Miyµcxtcx otEpiwv. ( ex) • AcpAExtcx Aijp· µirµcxtcx uAwv t71i;; 7o (ex) (~) EucpAEx-rcx Miyµcx-rcx uAwv t'Tji;; 7 o (~)· cpuotxov dcEptov. 1:1. Aeptot OtlXAUOµEvlX !)7t0 7tlEOTj Kcx0cxpdc cxeptcx XIXL TEX,VLxwi;; - xcx0cxpdc cxaptcx ( IX T) • AcpAEXTIX, to;txcx ' Aµµwvicx Ol1XAU0µav71 OTO vepo µE cxvw TOU 35% IXAAIX OXL cxvw 'tOU 40% cxµµwvicx XIX'tCX ~cxpoi;;· .. cxµµwvicx Ot<XAuoµav11 O'tO vapo µe 6:vw TOU 40% illcx OX,t IXVW 'tOU 50% cxµµwvicx XIX'tCX ~cxpoc;. , L7lµEtWotc;: 8tCXAuµcx cxµµwvicxi;; µE 1ti!ptEXOµEvo OE cxµµw­ vicx wu)..cxx Lo-rov 10% illdc to 1t0Au 35% cxµµwvicx, eivm ou­ oiix 't'Jjc; K)..iioewc; 8. (r) XTjµtxwc; IXO'tot0ij AxE'tUAEVLO OLIXAUOµEvO OE OllXAU't7I (1t,X, IXXE'tOVTJ) IX1toppo­ cpouµevo IX7t0 1topw6Eti;; UAEc;. E. 8LIXVEfi71-rai;; IXEpO½OA XIXL µ71 - ;cxvcxyeµt½OµEVIX OOXELIX (CONTAINERS) IXEpiou U7t0 1tiE07I (~Aim EltLOTj<;; mpt8wpt0 220 lix UltO O'totXEio (6)): L71µdwotc;: 1. Ot OLIXVEµTjtEc; IXEPO½OA ElVIXL 6oxeiix ltOU µ1topouv VIX XPTJOLµ01tot718ouv µiix µcivo cpopdc, ELVIXL EcpOOllX­ oµavix µE ~IXA~l51X ixcpaoEwc; ij µ71xcxvtoµov OllXOltOpcxc;, XIXL 7tl!­ ptaxouv, UltO 7tlEOTj, cxapwv ij µiyµcx otEpiwv 'tOU 7tEpt0wpiou 2208 (2) ij 1tEptax ouv evep16v i,)..7111 (ev-roµox-rcivov, xooµTjtt­ xiJv (xilluv-rtx1111) xAit.)) µcx½i µE ixapto ij µi1µix otEpiwv oixv 1tpow871ttXTj 1oµwo71, 2.M71 - ;cxvix1Eµt½oµEvix 6ox eiix (ONTAINERS) ixepiwv UltO ltll!07I El\llXL OOX,ELIX ltOU µitopouv VIX x p71otµo1tOtTj80u\l µ0110 µtlX cpopdc XIXL 7tEptEX,OUV otapt0 Tj µi1µcx otap[wv 'tOU mpt 0wp[ou 2208 (2) XIXL (3) (1t,X,, ~OU'tCX\ILO ytix µcxyetpaiix - XIX­ 'tlXUAtoµwv, <Jiux-rtx dc ixaptlX' XA7t, ). IXAAOC OE\I ELVO(L acpoOLIX­ ofie.v~ µe ~IXA~iocx ixcpfoewc;. 3. 0 opoc; «EIJlj)AEXTEc; UAEc;>► 071µ.ixivEt: (I) ixaptlX (1tpow81jtlXTj yciµwo71 Ol1XVEµ71-rwv IXEPO½OA' ltE­ ptEX,oµEvO µTj - ;ixvix1Eµt½oµavwv 6oxEiwv (CONTAINERS) IXEpiou U7t0 1tiao71) 'tW\I OltOLW\I 'tlX µi1µ1XtlX µE 1XEp1X µitopouv VIX IXVIXcpAEYOIJ\I XIXL ax ouv XIX'twtepo XIXl IXVWtEpo cipw IXVIX­ cpW;awc;· (II) uypcx (mp1Eic; uAEc; otixvEµTj-cwv ixapo~ci)..) 't'Jjc; K)..dc­ aawc; 3. 4, 0 opoc; «X,7Jµtxwc; IXQ't1X0Tj» ecpixpµO½'E'tlXL OE itEptexoµEVO co oitoio aMEicj,Et ~totxwv itpocpu)..dc;ewv ucpio-rix-rcxt E1ttxivou­ vov IX1tOOUV8aa71 Tj IXU't0-7tOAuµeptoµciv Etc; 0epµoxpixaiixv oxt CX\IW 'tW\I 70° c. 10° 8LIXVEµ71-rac; Aapo,oA (IX) • AcpAEX'tot Ma oxt EU(j)AEX'tO\I itaptax oµevov. (ix T) 'Acphx-cot, -ro;txoi Me cxcpAEX'tO -ro;txci 7tEptax oµEvo. (~) EucpAax-rot 1. Me oxt dcvw 'tOU 45% aucpAEX'tO mptax ciµavo XIX'tCX ~cx poc;. 2. Me CX\IW 'tOU 45% aucpAEX'tO 1taptexoµEVO XIX'tlX ~dcpoc;. (~ T) E ucpAEXtEc;, 'tO~txac; 1. Ma 'tO~tXO 7tEptexoµevo XIXl OXL cxvw 'tOU 45% EU(j)AEX'tO 1taptExoµavo XIX'tCX ~ixpoc;. 2. Me 'tO~LXO 7tEptexoµevo XIXl CX\IW 'tOU 45% EU(j)AEXTO 7tE ptaxoµevo XIX'tlX ~cxpoc;. ( y) X 71µtxwc; IXOt1X8aic; Me X.TJ11LXwc; - IX(l't1X8ic; 7tEptexoµevo. (r T) X71µtxwc; IXOtlX0Eic;, -ro;txoi Ma x71µtxwc; - IXO:t1X8ac; 'tO~LXO 1taptex 6µevo. 11 °, M71-;ixvixyeµt½ciµav1X ooxaiix (CONTAINERS) IXEpiou UltO 7tLEOTj (IX) • AcpAEX'tlX (ix t) 'Acphx-rix -co~txdc: Me dccpAex-cix itEptex oµavix. (~) Eucp)..ax-rix Me EU(j)AEXto 1taptex oµavo. (~ T) EucpAEX'tlX, -ro;txix Ma aucpAEX'tO TO~LXO 1taptax ciµevo. ( r) X Tjµtxwc; IXOtlX0Tj Ma X,Tjµtxwc; - IXOtlX0ac; ltEptexoµevo (r T) XTjµtxwc; IXO't1X0Tj, -ro;txdc M a x11µtxwc; - IXO'CIX8ac; w;txci 7tEptaxoµevo. LT. AiptlX UltOXEtµEVIX aa ELOtxouc; opouc; 12° /:ltcxcpoplX µai1 fJ,IX'tlX IXEptW\I MiyµixtlX itEptEXOV'tlX 1XEpt1X IX111XcpapoµEvlX OE illouc; 1Xpt0 µouc; aioouc; t71c; 1t1Xpouo11i;; K)..iiaewc;, XIXL µiyµixtix avcic; ij 1ta­ ptaootipwv IXEpiwv IXVIX(j)Epoµavwv U7t0 cxUouc; otpt0µouc; Et­ oouc; -r71c; 1t1Xpoua11c; K)..cxaewc; µe EVIX\I 71 1tEptoo6tepouc; cx-rµouc; UAW\I 6ev e;cxtpouvtlXt t71c; µe-rcxcpopdcc; ouµcpwvwc; 1tpoc; t'Tjc; ADR, uit6 -rov cipov 6-rt xcx-rdc -r71v µe-rixcpopdc: 1. 'tO µiyµcx 7t1Xp1XµavEL e; oAoxAijpou cxaptw6ai;;· XIXL 2. IX7tOXAEtE'tlXt xdc0e OU\IIX'tO't7lc; amxtv6uvou IX\l'ttOpcx­ aewc;. 13° AeptlX 8oxtµwv AaptlX XIXL µiyµixtlX ixapiwv 11TJ IX111XcpapoµEVIX U7t0 cxUouc; ixpt0µouc; -r71c; 1t1Xpoua71c; K)..dcoewc; XIXL XP7JO tµo1tOt01Jµav1X µo­ \10\1 ytix Epyixa-r71ptixxac; ooxtµac;, UltO 'tO\I opov O'tl XIX'tlX 't'Tj µa­ tlXCpopix: (ix) 'tO ixapw Tj µiyµix cxapiwv itixpixµavEt e; OAOXAijpou 1XEpt­ w6ec;· XIXt (~) 1X1toxAEia-rixt xdc0e 6uvix-ro-r71c; emxtv6uvou ixnt6pdc­ oewc;. z. 'AoEtlX ooxeiix XIXt dcomc; oa~ixµavac; 14° Kevdc 6oxeiix x"ixt xavac; 6a;cxµevac;, ixxcx0dcptO'tlX, 7tOU 1tEptaixcxv -re-rpcxcp0opwµe0dcvto -r71c; 1 ° (ix), uAec; t'Tjc; 1 °, (ix T) (r T)· 2°, (~) (r T)· 3° - 6°· Olo~E[Olo 'tOU dcv0pixxoc; XIXL \lttpw­ oac; o~u -r71c; 7°(cx)· ij IJAEc;-rwv 7°(~), 8°@, 9°, l2°ij 13°. L'T]µEiwotc;: 1. l:lox aicx XIXL oe;ixµevac; ltOU µatdc tQ·IXOELIXOµIX 'tWV UAWV t71c; 14° a;ixxoAou0ouv VIX 1taptaxouv µtxpdc XIX'tlX­ Aot7tlX 0ewpou\l't1Xl we; xavdc o:xo:0cxptoto: oox aio: ij 6e;o:µavac;. 2. Axo:8dcpt0°'tlX XEVIX oox aio: 11 XEVE<;; 6.~o:µavac; 7tOU ltEptai­ xixv o:iptlX t'Tjc; 1 ° (o:) ltATjll 'tOU te-cpo:cp0optoµE0o:viou (R 14), Tj o:apto: t71c; 2° (o:), 7° (o:) ltATJV.'tOU 6to;at6iou 'tOU dcv0pixxoc; XIXL Vttpwoouc; o;foc;, Tj t'Tjc; 8° (ix), OE\I U7tOXELV'tlXL otouc; opouc; t71c; ADR. AaptlX xou ElOTj ito:po:otooµavo: yto: µe-ro:cpopix ouµcpwvix 2201 a itpoc; -rte; itixpcxxcx-rw oto:-rcx;ati;; oev u1t6x1uv-ro:t o-rouc; cipouc; 11 rte; OLIX'tll;Etc; nc; ox.mxac; µe 't7IV ito:pouoix KAllOTj 7tOU OllX- • Ao:µ~cxvov-ro:t CXAAou o-ro 1to:pciv Ilo:pdcp.-r71µix ij -r o Ilo:pdcpt'TjµIX B: (o:) ltEmEoµavo: ixaptot 'tlX 07tOLIX 6ev aivixt ou,;a aucpAEX'tlX outE -ro;txix outE oto:~pw-rtxix xo:t Tj lttEOTj -rwv 01toiwv o-ro oo­ xeio, IXIIIXCjiEpoµe.1171 OE 0apµoxpo:oio: 15° C, oav U7tEp~1XlVEL 'tlX 200 KPix (2 BAR)· 0 IXUtOc; xo:vovo:c; LoXUEL yto: µiyµo:-rcx <XE­ piwv 1taptaxovt<X OX,L IXVW 'tOU 2% EU(j)AEX'tlX ouotcmxdc µap11· (~) uypoitOt'Tjµivo: o:aptix 7tEptexoµavix OE ltOOO't'JjtEc; µ71 u1tEp~o:ivouoec; -cix 60 L, ij oa 1too6tTjtEc; µtxpcinpac; -rwv 5 L µe oxt iivw -rwv 25 1pixµµo:piwv u6po16vou, µaocx oa <Jiux-rt­ xac; ouoxauac; (<Jivyeio:, 11TJXIXVE<:; 1tciyou, XA7t.) X<Xl 1X1tlXp1Xi't7l'tlX 1 to: i:71 )..,moup1io: wuc;· (r) 0LO~Ei6w iiv0po:xoc; (5° "(o:)) OE µai:o:AALXCX xo:<jiuAALIX (SODORS, SPARKLETS) EIX\I 'tO oto;aioto 'tOU dcv0po:xoc; OE 1XEptwo71 XIX"tllO'tlX07I OE\l ltEptEXEL IX\IW i:ou 0.5% o:apo: XIXL "CIX xo:ylJAALIX mptaxouv OX,l IXVW i:wv 2 5 ypo:µµo:piwv OlO~Etoiou rou dcv0pixxoc; X<Xt OX,L dcvw ,;wv 0. 75 1po:µµo:piwv ixvcx CM 3 XWPTJ"tlXO"t'Tj"tOc;' • ( o) aio71 i:wv 10° XIXL 11 ° XWPTJ"tlXO't'Tj'tOc; µ~ 'u1tep~1Xl\lOIJ 071c; 'tlX 50 CM3. KoAO\I µa "tE"tOLIX Eio'Tj 6ev 0cx ½U1L~El CX\IW 'tWV 10 KG· ( E) uypoitot'TjµEVIX IXEpLIX 7tE"tpEAIXLOU mptaxoµev<X a·. oe;o:­ µevac; IXU"tOXLVTj"tWV Otot0EpCX Otapawµavac; O'tlX OXTj111X"t<X' Tj otpocptj'1 1X 'tOU XIXUo[µou µatcx;u 'tW\I OE;o:µev11c; XIXL t'Tjc; µ71 X,IXVTjc; 1tpE1tEl VIX El\llXL XAelO'tTj XIXL TJ 71Aax-cptxij E7t<XcpTj IXVOL­ xi:ij. 1152 ECJ>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: ~EYTEPO) A. Ko1.cx 1. r.11txo[ opot ouoxwexoicxc; (1) Tex UAlXCX CXltO ,:ex OltOtCX ,:ex OOXEtCX XCXL ,:ex XAELoiµcxi:cx i:ouc; xcx,:exoxwcx½Oll"tCXl o·EII 1tpE1tEl IICX XlllOUIIEUOUII IICX 1tpo 0W718ou11 CXltO ,:o 1tEpLEXOfLEIIO 7l IICX ox71µcxi:t½OUII EltL~Acx~dc; 7l amxt116u11ouc; ow8eoEic; (E11woatc;}. 171µEtw0Lc;: Meplf!\,ICX 1tpE1tEL IICX ACXfl~CXIIE,CXL WO"tE IICX µ7111 Em,pcxitat 01t0Lcxo711to,E uypcxo[cx 11cx EtoiA8Et o,:cx ooxElcx 01:cx11 1 Eµl~o111:cxt, xcxt 11cx l;71pcxl11oncxL ,ex ooxElcx 1tA71pwc; µE,cx nc; ooxtµec; uopcxuAtXTj<;; ltlEOEW<; (~AEltE 7tEpt8wpto 2216) ,Le; OlE· l;cxyoµE11Ec; f!E 11Epo 71 flE uocx,:wo71 OlCXAUfLCX"tCX. (2) OL ouoxwcxo[Ec;, ouµ1toptAcxµ~cx11oµe11w11 1:w11 XAEtotµcx 1:w11 'tWII, Sex EtllCXl Eitcxpxwc; cxxcxµiti:Ec; XCXl yapec; OE OACX ,:0( µip71 1:ouc; WO"tE IICX CX1tocpEuya,:OCL 07tOLCX07J7tO"tE XCXAcxpwo71 OLCXpxouo71c; 1:71<; f!E1:cxcpopcxc; XCXL IICX 1:71poU\l"tCXL Ol XCXIIOlllXOt opot 1:71c; µncxcpopcxc;. Oi:cx11 1tpo~AE1tO\l"tCXL El;w-cEptxec; OU· OXWCXOtEc;, ,:ex OOXEtCX Sex oupEWIIOll"CCXL 0-CEpEcx o' cxu-cic;. Ex-coc; ECXII illwc; opt½E"CCXl o:ro cxpSpo 1:0 "tl"tAocpopouµE110 «LUOXWCX· olcx fLLCXc; uA71c; 7j eµ1topEuµcx1:w11 "COU cxu-cou doouc;», Ol EOW"CE·. pLxec; ouoxwcxo[Ec; µ1topou11 IICX EYXAEtO\l"tCXl oi:tc; El;wuptxec; OUOXEUCXOtE<;;, Et-CE µ[cx-µ[cx El"tE Of!CXOLXCX. (3) ME,CXMLXCX OOXEtCX 1tpoopl½Of!EIICX ytcx ,:71 f!E"tcxcpopcx CXE· p[w11 'tWII 1 ° ewe;. 6° XCXL 9° Sex 7tEptEXOU\I µ011011 ,:o exepto ytcx "CO 07t0t0 ooxtµcxoS71xcx11 XCXl -cou OltOtOU 71 011oµcxo[cx EXEL ypcxcpE[ex ltCXIIW 01:0 ooxdo (~AEltE mptSwpLO 2218 (1) (ex)). A11exXA7lOEtc; Em1:pe1to111:CXL: ( 1) ytcx flE"texAAlXCX OOXEtex OOXLµex0Si111:ex ytex µiex 1:WII IJAWII 1:w11 3° (ex) 714° (ex) 1 Lcx ~pwµo1:ptcpSopLOµEScx11to, XAwpoi:pt - 71 i:ptcpSopLOµEScx11w 1:71c; 5° (ex). Tex ooxdex exu,cx µ1topouv E1tto71c; 11ex 1EfllOSou11 flE XCXltOlCX cxU71 UA71 1:WII 1tpocxvcxcpEpSenw11 El· OWII UltO "COIi opo11 01:l 71 1tpo~AE1toµiv71 ytcx 1:7111 UA71 CXU-CT) XCX· 1:w1:cx1:71 1t[Eo71 ooxtµ71c; OEV u1tEp~cxl11EL 1:7111 1ttE071 ooxLµT)c; ,ou ooxE[ou xcxt ·o:n 71 011oµcxoicx 1:71c; u)..71c; xcxL 1:0 • Em1:pE1t1:011 cxvw 1:cx1:0 ~cxpoc; yEµloµcx1:0c; cxwxypcxcponCXL Eltt 1:0U ooxElou· 2. ytcx flE"tCXAAlXCX OOXEtCX ooxtµcxoSev,:cx ytcx uopoyovcx11Spcx­ XE<;; "tWII 3° (~) 7l 4° (~). Tex OOXEtCX cxu-ccx µ1topou11 E1t[o71c; IICX 1EfllOSou11 fl-E XCXltOlOII CXAAOII uopo:yo11cx11Spcxxcx UltO "COIi opo11 01:L 71 1tpo~Arnoµi1171 1 tcx 1:7111 u)..71 cxui:71xcx-cwi:cxi:711tlE071 ooxt­ µ71c; OEII ump~cx[IIEl 1:71 7ttE071 ooxtµ71c; 1:01) OOXEtOU XCXL on 71 011oµcxolcx 1:71c; u)..71c; xcxt 1:0 Em,pE1ti:011 cx11wi:cx1:0 ~cxpoc; 1Eµ[­ oµcxi:oc; cx11cxypcxcpo11-ccxt Eltt 1:0IJ ooxdou. ftcx l xcxt 2, ~AE1tE E1tlo71c; 1topLSwptex 2215, 2218 (1) (ex) XCXL 2220, (1) ewe; (3). ( 4) Ancx,71 1:71c; optoSEto71c; ytcx EIICX ooxdo XP7JOEW<;; Eltl 1:pe1tE,exl xcx,:' expx7111 ECX\I OEII CXll"tl~CXlllEL oi:ouc; ES11Lxouc; XCXIIO· IILoµouc;· XPElCX~E"CCXL oµwc; 71 eyxpto71 1:71c; expµootcxc; expx71c; XCXL 71 CX\l"tlXCX1:CX01:0C071 1:WII cxpxLXWII EIIOEtl;EWII (µcxpxexptoµcx1:w11) f!E ,Le; E\IOEtl;EL<;; (µcxpxcxpioµcxw) ,Le; oxanxec; f!E 1:71 IIEex XP7l071· 2. 1uoxwcxo[ex µLcxc; u)..71.; 71 Eµ1topEuµcx1:w11 1:ou cxu-cou d­ oouc; 171µdwotc;: To Otol;EtOlO "tOIJ cx11Spexxoc; XCXL lll"tpWOEc; o!;u (7o (ex)) xCXL µ11µcxi:ex 1:w11 ouo cxui:w11cxEp[w111:71c; 80 (ex) xcx­ Swc; xexl ,ex cxeptex 7 (~) XCXL 8 (~) (apex ITcxpcxp1:71µcx B, 7tEpLSw­ pLO 21 105). • ex. <l>uoLc; ooxdw11 ( 1) Tex OOXEtex ,:ex 1tpoopL~OflEIICX ytcx 1:71 f!E,excpopcx CXEplwv "tWII 1 ° ewe; 6°, 9°, 12° XCXL 13° Sex EtllCXl E"l:OL XAEtoµe11ex XCXl . o-caycxvcx WO"tE IICX CX1tocpEuyE-cexL 07t0lCX07j1t01:E Otexppo71 "tWII CXE· plw11. (2) Tex ooxElcx cxu,cx Sex ElvexL xcxi:cxoxwexoµe11cx exito ex11Spcx­ xouxo XCXAU~CX 7l xpcxµcx xcxAu~oc; (ELOlXOt XCXAIJ~Ec;). Tex xcx,wi:epw µ1topou11 Ell "COU-COl<;; 11ex XP710lf!07t0l0U· \11:CXL: (ex) XCXAXlllCX ooxdcx ,Lex: 1. ltEltlEOfLE\ICX cxeptcx 1:7Jc; 1°, (ex), (~) xext (~ T), XCXl 2°, (ex) xcxt (~), -cwv 01tolw11711tlao711tA71pwoEwc; (1Eµ1oµcxi:oc;) 71 cx11ex­ cpEpoµi1171 OE SEpµoxpcxo[cx 15° C OEII u1tEp~ext11Et ,ex 20 bar (2Mpa) xcxL 2. ltEltlEOfLE\ICX exeptcx 1:71c; 3° (ex)· owl;doto "tOIJ Sa[ou 1:71c; 3° ( ex T)· 6LµESuAcxtSepcxc;, cxLSuAOX Awpioto xcxt µESu)..a11ox Awp[­ OLO 1:7Jc; 3° (~ T)· ~lllUXAWptoto 1:71c; 3° (r)· ~Lw~pwµ[oLO -c11c; 3° (r T)· µ[yµex,cx F 1, F2 XCXl F 3 -c71c; 4° (ex). xext cxLSUAEIIOl;El 2202 2203 OlO 7tEplE;(O\I OXl CXIIW "COIJ 10% OLOl;ELOLO "COU cxvSpO(XOc; xex,cx ~cxpoc;, -c71c; 4° (1 T)· (~) ooxdex exito xpcxµcx-ex)..ouµt11[ou (~AE1tE ITpooS71x71v A.2) 1 tcx: 1. ltEltLEOfLEIICX cxeptcx 1:71c; 1 °, (ex), (~) XCXL (~ T)· IILi:pwoEc; ol;u (µ011ol;EtOLO CX½W-COU) NO 1:71c; 1 ° (r T)· xext ltEltlEOf!Ellex CXE· ptcx 1:71<;'"'2°, (ex), (~) XOCL (~ T)· 2. urpo1toL71µevcx cxeptex 1:71c; 3° (ex)· otol;atoLO -cou SEtou -c71c; 3° (ex T)· uypo1tm71µi11cx exeptex 1:71c; 3° (~) 1tA7111 µEBuAOLAex11iou· OEA7111ouxo uopo,0110, xext µESUAlXT) f!Epxex1t1:cx11711:71c; 3° (~ T)· CXLSUAEVOl;EtOLO 1:71c; 3° (r T)· uypo1tm71µevex exeptex 1:71c; 4°, (ex) xext (~)· CXLSUAEVOl;EtOLO 1topLexo11 OXl CXIIW "COi) 10% OLOl;ElOlOIJ 1:01) cx11Spexxoc; XCXl ~cxpoc;, 1:71c; 4° (r T)· xext uypoitOL71f!E\ICX exE­ pLcx 1:71c; 5°, (ex) XCXt (~), XCXl 6°, (ex) XCXl (1). 8tol;Et0LO "COU SEtOIJ 1:71c; 3° (ex T) xext UAEc; 1:71c; 3° (ex) XexL 4° (ex) Sex dvext l;71pec;· xext 3. OLCXAUOfLE\10 CXXE1:IJAE\ll0 1:71c; 9° (,). "Q)..ex 1:CX CXEptex 'tCX 07tOLCX 1tp0XEL1:CXL IICX flE"tCXcpEpSoUV flEOCX OE OO;( EtCX CXltO xpcxµcx CXAOIJflllltOIJ Sex EtllCXL cx1texAAcxyµevcx CXltO CXA· xcxAtxec; cxxcx8expo1ac;. (1) Tex OO;(EtCX YLCX OlCXAIJOfLEIIO CXXE"tlJAEVLO (9o (r)) Sex 1tA71 poUV1:CXL El; OAOXATjpOu f!E 1toppw0Ec; UAlXO, oµmoµopcpcx xex1:cx 11Eµ71µevo, 1:UltOU EYXEXPLflEIIOU exito 1:7111 expµo6tcx cxpx71 xcxt 1:o OltOtO (ex) OEII 1tpoo~CXAAEL "CCX ooxaicx 71 ox71µcx1:t½El Eltl~ACX~Etc; 71 Emx[11ouvac; EVWOEtc; Et"tE µa "CO CXXE"tlJAE\llO El"tE f!E "COIi OlCXAU-c71. (~) OEII EX"tlllCXOOE"tCXl, cxxoµ71 xext µa,cx CXltO 1tcxpex1:E1:exµe11!l xp71071 71 cxito 1:pcxvi:cxyµcx, oE Sapµoxpexoiac; f!EXPL 60° C • (r) ElllCXl LXCXIIO 11ex EflltOOtOEL :r7111 El;cx1tAwo711:71c; omoou11SE­ OEwc; ,:ou cxxE,IJAEvtou 01:71 µcx½cx. (2) To OtexAIJ"tlXO OEII 1tpe1tEl IICX 1tpoo~CXAEl ,ex ooxdcx. (1) Tex 1tcxpcxxcx,:w uypo1tot71µe11cx exepLCX µ1topouv, E1tmpo 0Shwc;, IICX f!Ei:CXcpepo111:cxL µeoex OE yuiXALIIOUc; OWAT)IIE<;; µa xo11 opcx -COL;(Wf!CX1:CX IJltO 1:0\1 opo11 01:l 71 1tooo,:71c; 1:71c; uA71c; OE xcx8a OWAT)IIIX xexL O ~cxSµoc; 1tA71pwoawc; 1:WII OWAT)\IWII OEII IJ1tEp­ ~CXLIIOIJII 1:ouc; 1tcxpexxcx,:w 071µELOIJflEII01Jc; cxptSµouc;: 011oµcxo[ex AEptwll IToocii:71c; Bcx8µoc; 1tA71pw 8tol;doLO 1:01) cx11Spcxxoc;, U1tOl;EtOlO "COIJ CX½W"tOIJ N 2 0 (5° (ex)), CXLScx11LO, extSuAEIILO ·n71c; oawc; "tOIJ OWAT)· (5° (~)) 3 fpcxµµ. T)flLOU 1:71c; xwp71· 1:LX0,711:0<; Aµµw11[cx, XAWpL011, µaSu­ Ao~pwµtoLO (3° (ex T)), xuxA01tpo1tcx11Lo (3° (~)), ext­ SuAavoxAwploLO (3° (~ T) <l>woye11LO, OLOl;EtOLO 1:0U Sdou (3° (ex T) 20 fpexµµ. ouo-i:phex 1:71c; xwp711:LX01:711:exc; 100 r pexµµ. 1:plcx-1:hexp,cx -1:71c; xwp71nxo1:711:cxc; (2) Ot yucxAtllOl OWAT)VE<;; 01:Eycx110[ XCX'tCX 1:71c; cpA<iycxc; XCXl exocpexAlOflEIIOl xwpto,cx µa y71-otex1:ciµwv OE XAElOi:CX XCX~UMlex CXltO EAcxoµcx ,:ex OltOtCX Sex 1:01t0Sa1:ouvi:cxt OE l;uAt\10 Xl~W"tLO 7l OE XCXltOlCX CXAA71 El;W1:Eptx71 OIJOXEUCXOtCX xex1:cxAA71A71c; exv-cox71c; (~AEltE E1tto71c; 7tEptSwpto 2222). (3) fLcx OLol;ElOLo i:ou Sa[ou 1:71c; 3 ° (ex T) 1apcx 1uciALVCX ot­ cpovtcx 7tEplEXO\l'tCXL oxt CXIIW 1:WV 1.5 KG uA71c; XCXl yaµcx,ex OXl cxvw i:ou 88 01:cx axcx,011 1:71c; xwp71,Lxo-c711:oc; 1:w11 am1:pi1toncxt E1tto71c;. Tex otcpo11tcx Sex cxocpcx)..[~onext µa 171-otcx1:oµw11, 1tpw11[0 OLO 71 xo11Lo1tot71µe110 cx11Spcxxtxo cxo~foi:to, 71 µa µ[yµcx cxito ,:ex ouo 1:EAW,cxlcx, µfoex OE l;uAtllex Xl~Wi:lCX 7l OE XCXltOlCX cxn71 El;wuptXT) OIJOXWCXOlCX rncxpxouc; CX\l'tox71c;. To l(OAOII OEII Sex ½U1l½El CXIIW "tWII 100 KG. Ecx11 ½U1l½El CXIIW ,:wv 30 KG Sex Et\lexl EcpOOlCXOfLEIIO f!E XElpOACX~Ec;. (1) Aeptcx 1:71c; 3° (ex)· 3° (~) 1tA7111 µESuAootAexviou- 3° (~ T) 1tA7111 cxpol1171c;, OLXAwpootAcx11[ou, OLfLESu)..ootAcxviou, OEA7111ou­ xou uopoyci11ou XCXl ,ptµESUAOOlACXlllOIJ" 3° (r)· 3° (r T) 1tA7111 XAWpoxuexlllOLOU' xext µ[yµcx,:cx 1:71c; 4° (ex) xext 4° (~), µ1topou11 rn[o71c;, IJltO 1:011 opo11 01:l ,:o ~cxpoc; "COIJ 7tEplEXOflEIIOIJ CX\ICX ),,[. cpo11 urpou OEII U1tEp~extllEl El"tE 1:0 CXIIW"tCX"tO ~cxpoc; 1:0U 7tEplE· xoµe11ou 1:0U opl½OflEIIOU 0-CO 7tEptSwpLO 2220 El1:E 150 ypcxµµ. ex11cx OWAT)IICX, IICX 1tEptA71cpSouv OE yucxAt11ouc; OWA7JYE<;; f!E xo11opo i:olxwµex, 7l OE flE"tCXAALXOU<;; OWAT)IIEc; IJ •• YOIIOpo 2.204 2205 2206 <l>EK 104 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI .dEYTEPO) 1153 'totxwµex xex'texaxwexaµevouc; ex1to µitexllo E1tL'tpE1tOp.EVO U1t0 wu 1tEpLBwpiou 2203 (2). OL awA7111Ec; Bex EivexL ex1tcxllexrµe­ vm ex1to ~AIX~Ec; ouviiµEvEc; vex E;cx?BE1171aouv 't71\I exvwx71v 'touc;· ElOLxonpex, Ol EOW'tEplxec; 'tlXOEl<; 'tW\I 1uo:Al\lW\I awA71 vwv Bex EXOU\I Xex'tcxAA7IAWc; EAexnwBEi Xexl 'tO 1to:xoc; 'tW\I 'tOL­ xwp.iX'tul\l 'tOU awA71voc; OE Bex EL\lexl p.lXpO'tEpo 'tW\I 2 MM (XLA. ). H a'tE1exvo't71'tex 'tou aua't71µexwc; XAELatµexi:o~ Bex E;ex­ aqiCXAt,E'texl f!E 1tpoaBE'tO µ71xexvLaµo (xo:Auµµcx, xopwvex, aqipex,toex, OEalp.O, XA1t.) lXex\lO\I vex Ep.1toOL,El 01tOlex0711to'tE xexAo:pwa71 'tOu aua't71p.ex'toc; xAua[µex'toc; Olexpxou07Jc; 't71c; µE­ 'texqiopo:c;. OL awA7111Ec; Bex exaqiex).1,ov'texl µE ex1toa~Ea'tLXO uALxo OE p.lxpo: XU'tLex X:ex'texaxEuexaµevex ex1to ;uAo 71 l\lW071 aexvLOex, • 'tOU expL8µou 'tW\I OWA7I\IW\I exvo: XU'tLO\I O\l'toc; 'tOlOU'tOU WO'tE 'tO ~o:poc; 'tOU u,pou 'tOU 1tEplEXOP.E\IOU O'tO XU'tLO vex µ7111 U1tEp~exL­ \IEl 'tex 600 1pexµµo:plex. Tex µLxpo: exu'to: xu'tta Sex w1to8Ewu- • v'texL.aE ;uALvex Xl~W'tlex 71 aE xo:1tmex o:ll71 E;wnpLx71 auaxwex­ atex E1texpxouc; exvwx71c;· EIX\I 'tO El<; u,pov 1tEplEXOf!E\IO\I 'tOU Xl­ ~W'ttOU ,u,t,El 1tEplaaonpov 'tul\l 5 KG 'tO Xl~W'tlO Oex E1tE\I­ OUE'tCXl µE EAIXaµex µCXAexx71c; au1xoll71aEwc;. (2) To xoAov OE\I Oex ,u,r,u o:vw 'tW\I 75 KG . (1) Tex exeplex 't71c; 7 ° (ex) 1tA71v wu OLO;ELOLou 'tOU o:vOpexxoc; xexl 2207 'tou u1to;ELOLou 'tOu ex,w'tou, xexl 't71c; 8° (ex) 1tA71v 'tW\I µL1µo: 'tW\I 'tW\I 1tEpLEXO\l'tW\I BLo;EiOLo 'tOU o:vBpexxoc; xexL u1to;EiOLO ,ou ex,W'tOU, Oex E"'(XAELO\l'texl OE XAElO'tlX, f!E'texAAlXIX f!E omM wixwµex ooxElex 1tOU EL\ICXl EtOl µovwµe.vex wan vex µ71 µ1to pouy vex EmxexAuqiOouv ex1to opoaov 71 1tex"'(E'tO\I xext 'tex 01tolex Ei \lexl Ecpochexaµevex µE ~exA~LOEc; exaqiexAELexc;. • (2) Tex exiplex t71c; 7 ° (ex) 1tA71v tou oLO;ELoiou 'tou o:vOpexxoc; xm wu u1to;ELOtou 'tOU ex,w'tou, xexl 'tTjc; 8 ° (ex) 1tA71V 'tW\I p.l"'(­ µo:'twv twv 1tEpLEXO\l'tW\I OLO;EiOLO 'tou o:vOpexxoc; xexL u1to~EL 81ou 'tOtJ ex,W'tOtJ, µ1topouv E1tta71c; vex E"'(XAELO\l'texl OE OOXELex tex 01toiex EL\lexl EPf171'tlXW<; XAELaµevex Xexl 'tex 01toiex: (ex) Et\lexl "'(UIXAl\lex ooxdex Ol1tAOU ~oLxwµexwc; 1tepl~E~A71 µevex Olex XE\10\l (VACUUM - JACKETED) we; xexl Olex µLo:c; ex1toppoqi71'tlX7lc; µovW'tlX7lc; UA71c;· tex OOXEtex extJ'tlX Oex 1tpoa'tex­ tEUO\ltexl µE aupµo:nvouc; xo:AexOouc; xext Oex w1to8E'tOU\l'texl aE p.E'tWlXIX Xl~Wtlex' 71 (~) ELVexL µnexllLxo: OOXELex 1tpoa'tcx'twoµEvex xex'to: t71c; µE­ 'texooaEwc; t71c; 8Epµot71texc; xexto: tEtOlO 'tpo1to wan vex µ71 µ1topouv vex EmxexAtJ(jlOOU\I f!E opoaov 71 1tex"'(E'tOV' 71 xwp71'tlXO­ t71tex tul\l ooxEiwv extJ'tW\I OE Oex U1tEp~exL\IEl tex 100 Attpex. (3) Tex p.EtexAALXIX xL~W'tlex 'tex exvexqiEpoµEvex ai:o EOO:qno (2) (ex) xexl tex. ooxuo: tex exvexqiEpoµEvex O'tO EOIX(jllO (2) (~) exvw­ 'tEpw Oex Etvexl EcpooLexaµivex µE XELpoXex~ec;. Tex exvo11µex'tex twv ooxdwv tul\l exvexcpEpoµevwv atex EOIX(jllex (2) (ex) xexl (~) Oex EL­ \lexl E(jlOOlexaµeilex µE µ71xexvLaµouc; EmtpE1tO\ltexc; 'tex exiplex vex 6LexqiEu1ouv, Eµoo[,ovtexc; mtaLALaµex tou u1pou xexL E'tal an­ pEwµivouc; wan vex µ711tfoouv. L't71\I 1tEpi1ttwa71 'tOU o;u,o­ \10\J 7°(ex) xexl p.l"'(p.!XtW\I 1tEplEXO\ltW\I o;tJ"'(0\10\1 t71c; 8°(ex), OL ex\lul'tEpw exvexqiEpoµE\IOL µ71xix.vLaµol'xexL 71 ex1toppoqi71tlX7I µo­ Vul'tlX7I UA71 71 1tEpl~o:llouaex tex ooxEiex 71 exvexcpEpoµev71 ato. EO!Xcpto (2)(cx) Ocx Et\lCXl cx1to o:xexuato tJALxo. . (i) OL OLcxvEµ71tec; cxEpo~oA (lOo) xcx·l tcx µ71-;ava- 2208 "'(Ep.l~OµEvex ooxdcx (CONTAINERS) "'(Lex exeplO U1t0 1ttEa71 ( 11 °) Ocx 1tA71pouv touc; 1tapexxo:tw opouc;: ( ex) Ol OLexvEµ71tec; exEpo~OA 1t8pl9KO\J\I µovov exe.plO\I 71 µl,µcx exEpLW\I, xexl tex µ71-~cxvex,Ep.l,Op.Evex ooxElex (CONT AI­ NERS) "'(Lex cxeplO U1t0 1ttEa71, Oex EL\lexl ex1to µitexllo. 0 opoc; exutoc; OE Ocx lOXUEl "'(Lex µ71-;exvex,Ep.l,Op.E\l(l( ooxEiex (CONTAI­ NERS) "'(lCX cxeplO U1t0 1tiEa71 µE CX\IWtex'tTj xwp71tlXO't71'texlOO ML "'(lCX ~0\JtlX\llO, • Allol OLexvEµ71tec; CXEpO,OA Oex EL\lexl xextex­ axwcxaµevOL CX1t0 µitexllo, 1tAexa'tlX7I UA71 71 ,uexAL i\oxEkt xri­ 'tCXOXEUcxaµevex cx1to µhcxllo xcxL exo\l'tex E;wnpLx71 OLo:p.Etpo oxl p.lxpotEp71 'tc.JV 40 MM (XlA.) Oex EXOU\I XOLAO 1tuOµevex· (~) ooxEtex xextcxaxi:.uexaµevex ex1to uALxo: u1toxdµEvex aE OpuµµcxtLaµo, 01twc; to "'(tJCXAL 71 wpLaµenc; 1tAexatlXEc; UAEc;, Oex E"'(XAELO\ltCXl OE auaxw71 (anvo: - 1tAE"'(f!E\IO aupµo:'tl\10 oixtu, Euxexµ1t'to xo:Auµµex xextcxaxEucxaµevo ex1to 1tAexatLX7I uA71, XA1t.) 1tcxpexouacx 1tpoa'texaLCX\I "'(Lex Opcxuaµex'tcx XCXl ,0Lexa1topo:v exutw\l. i\oxEiex tul\l 01tOLW\I 71 xwp71nxo't71'tex OE\I U1tEp~ext\lEl 't(l( 150 CM3 xexl tul\l 01t0Lul\l 71 EawnplX7I 1tLEa71 O'tOtJc; 200 C EL\ICXl XIXtW tW\I 0, 15 MPex E;exlpOU\ltexl ex1to tO\I opov exu'tO\I. (,) H xwp71tlXO't71tex tW\I ooxdwv tW\I XCX'tCXOXEUCXaµevwv ex1to µitcxllo. OE Oex tJ1tEp~exLVEl tcx 1.000 CM3• twv OOXELW\I 'tW\I xex'tCXOXEtJexaµevwv ex1to 1tAexa'ttX7I\I UA71\I 71 uexAo\l OE Oex U1tEp~ext\lEl tex 500 CM3• . (8) xo:OE µov'tEAO ooxE1ou, 1tpowu 'tEBai aE u1t71pEaiex, Oex Lxcxvo1tmai ooxLp.7111 uopexuALx71c; mfoawc; 6ta;ex1opivTJV auµ­ qiwvwc; 1tpoc; 'tlj\l TipoaB71XTj\l A.2, 1taptOwplO 3291. H EOW­ 'tEplX7I 1ttaa711tou 1tpoxmcxl vex EqiexpµoaOEi (1tiEa71 ooxLµ71c;) Ocx EivexL 1.5 qiopo: 't71V EawnplX7I 1tLEOTJ awuc; 50° µE xex'tW'tlX't71 1tLEOTJ 1 MPex (10 bar). ( E) OL ~CXA~LOEc; exqifoawc; twv OLexvEp.TJ'tW\I exapo,o)., xat OL P.TJxexvLaµot OLexa1topo:c; (0Lexvoµ71c;) exu'twv, Oex a;cxaqiCXAt,OtJ\I ot OLcxvEp.TjtEc; vex dvexl etal xAuaµivoL wa'te:·va EL\lexl atE1exvoL xexL Oex 1tpoa'texnuov'tm cx1to 'ttJX~io cxvoL1µex. OL ~exA~ioac; xcxL Ol µ71xexvLaµot Olciai-topo:c; (6Lcxvoµ71c;) 1tou XAEivouv µovov OL' EawtEplx71c; mlaawc; OE Bex 1[vov'tcxl OExtoL (2) Tex 1tcxpcx~cx'tw exeplcx Ocx 11vovtexl oaxto: we; 1tpow871texi, 71 we; exeplex 1tA71pwaEwc;, "'(lCX OlEVEp.71tec; cxapo~oA: iXEplex t71c; 1 °, (ex) XCXl (~)· 2°, (ex) Xexl (~)· 3°, (ex) xexl (~) 1tA71v µEOuAoaLAexviou· exL0UAOXAwpiOLO xexL Olp.E0uAexL0ipexc; 't71c; 3~ (~ T)· 1,3 - ~OU'tCXOlE\llO 'tTJ<; 3° ("'()- tplqiBopLOXAwpocxLOuAE\llO 't71c; 3 (1 T)· exeplcx 't71c; 4, (ex) xexL (~)· cxeplex 't71c; 5°, (ex) xaL (~) 1tA71v tou aLAexviou· exepLcx t71c; 5° ("'() xexL 6 (ex) xexL ("'(). (3) "0).ex tex exeplex t71c; (2) xexL, rnmpoaOe'twc;, 'tCX 1tcxpcx­ XCX'tw· exEplex Oex "'(L\10\lt(l(l OEX'tlX we; exEplCX 1tA71pwaawc; (,Eµi­ aµextoc;) "'(Lex µ71-;exvex,EµL,oµavex ooxEiex (CONTAINERS) . 1Lex cxepLO u1to 1tiEa71 • µE0µAo~pwµt8LO 't71c; 3 ( ex T)· OLµa0uAex0 µ11171, exL8u).cxµiv71, µE8u).exµiv71, µE8UALX7I µEpxex1t't1X\171 xext tplp.E8u).cxµiv71 't71c; 3 ° (~ T)· aLOuAovo;EtOLO, µEOuAo~l\ltJAexl­ Oepcxc; XCXl ~l\lU~pwµiolO t71c; 3 ° (, T)· CXl0UAe\lO;Et0lO 1tEplE­ xov oxl cxvw tou 10% OLO~EtOLov 'tOU o:vOpexxoc; xato: ~o:poc;, 't71c; 4 ° (1 T). ( 1) H EawnpLx71 1tiEa71 atouc; 50 ° C 'tW\I Olex\lEf171'tW\I aEpo- 2209 ,oA xcxl twv µ 71 - ;exvex1Ef!l~oµevwv ooxEiwv exEpiou u1to 1tiEa71 OE\I Ocx u1tEp~ext\lEl outE 'tCX ouo - tpitex t71c; me:aEwc; ooxLµ71c; 'tOU ooxdou OU'tE tex 1.2 MPex (12 bar). (2) OL OLexvEµ71tec; cxEpiou xcxl tex µ71 - ;exvex1aµL~oµEvex oo­ XEiex (CONTAINERS) OCEpiou U1t0 1ttEa71 Ocx Et\lexl Etal "'(Ep.l-•: aµevcx watE atouc; 50°C 71 cpo:071 'tOU U"'(POU \l(X µ71v·u1tEp~at\lEl 'tO 95% 't71c; xwp71tlXO't71'tcxc; tW\I. H xwp71tlXO't7j'tex tW\I Olex­ \lEµ71twJ cxapo,oA EL\ICXL O OlexOfoLµoc; o,xoc; aa XAElO'tO Otex\lE­ µ71t71 E(jlOOlCXaµivo µE 'tO U1tOO't7lpl"'(l1-<X 't71c; ~(XA~ioexc;, 't71\I ~exA~iocx xexL to awA71vex Eµ~uOiaEwc;. (3) "0).m Ol Olex\lEP.71'tE<; exEpO,OA xexl 'tex µ71 - ;exvex,Eµt,o­ f!E\ICX ooxdex (CONTAINERS) "'(Lex exEplO U1t0 1tiEa71 Oex lXex\l0 1tOlOU\I OOXlp.7111 atqexvot71tcxc; auµqiwvex µa 't71\I Tipoa071x71 A.2, mplOwplO 3292. • ( 1) OL OlexVEP.71'tE<; exEpo,oA xexL tcx µ71 - ~exvex1Ep.l,Op.Evex oo- 2210 xdex (CONTAINERS) exEpiou u1to 1tiE07J Oex to1toOatouv'texl aE ;uALvex Xl~Wtlex 71 1Epo: ex1to Lvw871 aexviocx 71 µitcxllo xuticx· Ol foexvEµ71'tec; exEpo,o). m xextexaxwcxaµevm cx1to 1uexAi 71 1tAex atLX7I UA71 xexl u~oxdµE\IOL OE OpuµµextLaµo Oex Olexxwpi~O\l'texl 0 Evexc; ex1to 'tO\I cxllov Ol' E\IOlaµfoou 't01to8Et7IOEW<; cpullwv ex1to l\lW071 aexvioex 71 o:ll71 xcxtcxll71A71 UA71. (2) To XOAO\I OE Ocx ~u,i~El CX\IW tW\I 50 KG ECX\I xp71atµo 1tOlOU\l'texl xutiex 0(1t0 l\lW071 aexviocx 71 IX\IW tW\I 75 KG EIX\I xp71aLµo1toLOuvtexL o:llex µfoex auaxwcxaiexc;. (3) "Otexv 71 p.Etcxqiopo: dvexL p.E'texqiopcx 1tA7Jpouc; cpoptiou, Exo:a'tou qioptiou 1tEpLAexµ~o:110\l'to<; µovov OLexvEp. 71'tcxc; exapo­ ,oA xextexaxwexaµevouc; ex1to µitexllo, OL OLexvEµ71'tec; µ1topouv \ICX Of!CX001tOL718ouv xexl atEpEw0ou\l OE Otaxouc; p.E t71 ~0718Elex XCXtCXAA71A71c; 1tAexatlX7lc; uA71c;, µfow µEOooou aupplX\IWOEWc; XCXl 8Epµo-atE"'(CX\IOt71texc;, U1t0 'tO\I opov O'tl m oµo:6Ec; tW\I Olex­ \lEµ71tw\l Ocx OtOl~exxOou\l xexl xcxtexll71Awc; exacpexAlaOou\l 1tcxvw aE 1texllhEc;. ~- "Opm OlE1tO\lnc; 't(l( f!EtexAAlXCX ooxdex . . (Ol opm exU'tOL OE\I EXOU\I Ecpexpµo,71 "'(Lex p.E'texAALxouc; awA71 \IE<; exvexcpEpOf!E\IOU<; ato 1tEplOwplO 2206, "'(lCX ooxEiex exvexcpE­ poµE\10( ato 1tEplOwplO 2207 (2) (~). 71 "'(lCX Olex\lEf171'tE<; exEpo­ ,oA 71 µ71-~cx\lex"'(Ef!l~Of!E\lex p.EtexAAlXIX ooxdex (CONT AI­ NERS) "'(lCX exEplO U1t0 1ttEa71, exvexcpEpoµEvex ato 1tEplOwplO 2208). 1. - KcxtCXOXEU7I xexl Ecpexpµo,ec; (~AE1tE E1tia71c; 1tEplBwplO 2238). 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Toe 1twµoc,oe oeu,ii 6E 0oc e.xouv oevoi1µoe,oe xoet, xoc0' OATJ 'tTJ µE,oe­ cpop&., 0oc Etvoet Ecpo&toeaµivoe µE 1toepiµ~uaµoe E;oeacpoeA[,ov oeE­ pto - a,EyoevO'tTJ'tOC xoet xoe,ocaxEuoeaµe.vo ocito uAtito 1tou 1lEv xtv1luvEUEt voc 1tpoa~A7l0E[ oe1to 'tO 1tEptEXOV.EVO 'tOU 1loxe.iou. (1) IlpoxEtµivou 1tEp[ 1loxdwv ltEptEXOV'tWV ,ptcp0optouxo ~optov 7J cp0opwv (1 ° (oc T))· ,ptcp0opwuxo x1.wpto 7J uypo1tot 7Jµe.v7l oeµµwvioc (3° (oe T))· oeµµwvioc 1ltoeAuµiv7J a,o vEpo (9° (oc T)· x1.wptouxo NITROSUL (3° (oc T))· 7J 1ltµE0u>.oeµiv7J, oct 0u).oeµlv7J, µE0u).ocµlv7J 7J ,ptµE8u1.ocµlv7J (3° (~ T)), ~ocA~i5Ei;; XOC'toeaxEuoeaµe.vEi;; OC1t0 xocho 7] 01toto1l7J1tO'tE IXMO µhocMO xw1luvEuov voc 1tpoa~A7J0E[ oeito ,oc oee.ptoc ocu,ii 1le. 0oc y[vov,oct 1lEX'te.i;;. (2) H XP7JOTJ uAtxwv mptEXOV'tWV Aiitoi;; 7]. iAoetov 1tpoi;; E;oe­ acpiiAtaTj ,7Ji;; a,qocv6,7J,oci;; ,wv EvwaEwv (poecpwv) 7J 1tpoi;; au­ V't7JPTJOTJ 'tWV llTJXOCVtaµwv xAEtaiµoc,oi;; 'tWV 1loxEiwv 'tWV XPTJOLµo1tot7Jµivw\l ytoc o;uyovo (1 ° (oe))· cp0opto (l° (oc T))· µlyµoc,oe fl.E o;uyovo (2° (oc))· &to;E[Oto ,ou oe,w,ou, ,ptcp0o­ pwuxo XAWpto (3° (ocT))· u1to;d1lto 'tOU oc,w'tOU (5° (oe))· 7] µiyµoe,oc 'tTji;; 12° ltEpte.xov,oe IXVW 'tOU 10% o;urovov xoc't' oyxov oeitocyopEUE'tOCt. (3) Ot 1toepoeXIX'tW opot 0oe iaxuouv ytoe 'tTJV XOC'tOCOXEU7] 'tWV 1lOXELWV 'tWV OCVOC(flEpOfJ.EVWV O'tO 1tEpt0wpto 2207 (1): (oc) Toc UALXIX XOCL 7l xoe,oeaXEU7] 'tWV ooxEiwv 0oc ELVOCL auµ­ cpwvoc 1tpoi;; ,oui;; opoui;; 'tTji;; Ilpoa87]X7Ji;; A.2, B, 1tEpt8wptoe 3250 iwi;; 3254. '0).oc 'toe !lTJxoevtXIX xoet nxvoAoytXIX xocpoc­ X't7jpta'ttXIX ,ou XPTJOLµo1tot7J0e.v't0i;; uAtxou 8oe xoc0tEpouv,oct 1 toe xii0E 1loxEio xoe,ii ,7JV 1tpw,7J 1loxtµ'J]· oevoccpoptx&. µE 'tTJV oev,ox7Jv Eti;; xpouatv xoet ,o auvnAEO't7JV xiiµ4Ewi;;, ~Ae.m Ilpoa87]X7JV A.2, B, ltEpt0wptoe 3265 e.wi;; 3285. (~) Toe 1loxEioe 0oc Eivoet Ecpo1ltoeaµivoe fl.E ~ocA~i1loe oeacpocAEioei;; 7l 01toioc 0oc Eivoct tXCXV'J] voc oevol1Et O'tTJ xoc0wptaµiv7J 1tlEa7J 1tou EtXOVL,E'tOCt O'tO 1loxEio. Ot ~oeA~loEi;; 0oc ELVOCt E.'tOL xoc,oeaxwoc­ aµivEi;; WO'tE voc Aet,oupyouv iipta'tCX oeXOfl.Tj XOCl O'tTj mo xoc­ f1.TJA7] 1tlEa7J Amoupyloci;;. To ocacpocAe.i;; ,7Ji;; Amoupyioci;; ,wv O'tTJ 0Epp.oxpoca[oe ocu,7] 0cx xoe0te.pou,oct xoct EAEYX.E'tOCt fl.E 60 xtµ'J] xii0E ~oeA~i1loei;; 7J OEiyµoc,oi;; ~oeA~[1lwv ,ou oeu,ou ,u1tou Xoe'tOCOXEU7Ji;;, (y) Ot 01te.i;; OCEptap.ou XOCt ~oeA~[1lEi;; ocacpocAEioci;; 'tWV 1loxE[wv 0oc e.xouv E.'tOt axE1ltoca0E[ WO'tE voc Eµ1t61l[,ouv 'tO m,aiAtaµoe 'tOU uypou. (6) Ot fl.TJX.OCVtaµo[ xAEtalµoc'tOi;; 0oc Etvoet hat pu0µtaµlvot WO'tE voc {LT\ µitopouv voe oevoiyouv oeito oevocpµo&toc 1tpoaw1toc. ( E) ~ox.doc ,wv 01tolwv ,o ye.µtaµoe µE,pii,oct xoc,' oyxov 0oc 1ltoc0houv 6dx,7JV a,ii8µ7Ji;;. (a,) T oc 1lox.Eloc 8oc e.lvoct 8Epµtxwi;; µovwµe.voc. H 8Epf1.tX7] fJ.OVWOTJ 0oe 1tpOO'tOC'tEU'toet XOC'tlX ,7Ji;; xpouaEwi;; &toe OUVEX,Oui;; µnocMtX7Ji;; EltEV1luaEwi;;. Eiiv O xwpoi;; fLE'toc;u 'tOU OOXELOU XOCL 't7Ji;; fLE'tOCMLX7]i;; EltEV1luaEwi;; dvoct xwpti;; oee.poe (µovWOTj 1ltoc xEvou ), 7J 1tpoa,oe,Eu'ttX7] rne.v6ua7l 0oc axe.otix,E,oet voc OCV'tEXEL xwp[i;; 1tocpoeµopcpwa7J OE E;w,EptX'J] ltlEOTJ 'tOUAIXXL­ O'tOV 100 KPoc (1 bar}. Eiiv 7l rne.v1lua7J EXEL hat xfoa0Ei WO'tE voe Eivoet oeEpto - a,q7]i;; (1t,X, O'tTj 1tEpl1t'tW07l 'tlji;; µovw­ OEWi;; 1ltoe XEVOU ), 0oe Otoe,HlE'toct fl.TJxoevtap.oi;; Eµ1to1l[,wv 01tOtoe 2214 1l1j1tO'tE Emxiv1luVTJ ltlEOTJ voc oevot1t'tux0Ei O'tO fl.OVW'ttXO a,pwµcx O'tTJV 1tEpl1t'tWOTJ CXXCX'tCXM7JAOU CXEpto - anycxvO'tlj'toti;; 'tOU 1loxeiou 7] 'tWV E;otp'tTJfl.lX'tWV 'tOU. 0 \J.'T\XCXVtap.oi;; 0oe Ef1.1t0 6[,Et 'tTJV uypcxa[cx VCX EtoXWp7]0Et O'tTj fLOVWOTJ, ( 4) fa7Jv 1tEpL1t'tWOTJ 1loxe.lwv 1tEptEXOV'tWV µlyµoe,cx 't7ji;; 4o {r) 7] OtcxAuµe.vo CXXE'tUAEVLO (9° (y)), 'tot fLE'tocMtXIX 'tfl.'J](lCX'tCX 'tWV fl.TJXCXVLOfl.WV XAELaiµcx'tOi;; 'tot EPXOfl.EVoe OE EmXcp7] µa 'tO mptEXOfJ.EVO 1lEV 1tpe.1tEt vex 1tEptixouv xcx>-xov IXVW 'tOU 70 a,mi;; EXCX'tOV. ~OXELCX ytoe 1ltcxAuµe.vo CXXE'tUAEVLO (9° (y)) fl.1t0-· pouv rnia7Ji;; vex 6tcx0houv cx,µocppiix,Ei;;. (5) ~OXELCX ,teptE.XOV'tCX o;uyovo 'tlji;; 1 ° (ex) e.wi;; 7° (ex) XCXL e.cpcxpµoaµivcx aE tx0uo6E;otµEve.i;; ylvoll'toct oµolwi;; 1lEx,ii EIXV 1ltoc0houv auaxwe.i;; 1tcxpe.x.ouaEi;; 'tTJ 1luvcx,o't7J'tot a,o o;uyovo vex OtotcpEUYEL ~cx0µtcxlcx. 2. - E1tia7Jµoi;; e.AEncoi;; 1loxEiwv (rtoe OOX,ELCX CXltO xpiiµcx cxAouµtvlou, ~Ae.ltE E1tla7Ji;; Ilpoa07]X7JV A.2). (1) Tex fLE'tCXMLXIX oox.dcx 1tpe.1tEt voe U1tO~IXMOV't(XLOE oepxt­ xoui;; xoet ltEptoOtxoui;; EAincoui;; U1t0 'tTJV E1tL~AE47J EfL1tEtpo­ yvwµovcx oevoeyvwptaµe.vou UltO 'tTji;; cxpµo1l[oei;; cxpx7Ji;;. H cpuaTj 'tWV EAe.ncwv CXU'tWV xcx0opt,E'tCXt O'tCX 1tEpt8wptcx 2216 XCXt 2217. (2) ftcx vex E;cxacpcxAta0E[ o,t 'tTjpouv,cxt ot 1ltcx,ii;Eti;; ,wv 1tE­ pt0wpiwv 2204 xcxt 2221 (2), ot e.AEYX.Ot ,wv 1lox.Eiwv ,wv 1tpoopt,oµe.vwv vex 1tEptAii~ouv OtcxAuµe.vo cxxE,uAe.vw (9° (y)) 0cx 1tEptAcxµ~iivouv, rnmpoa0hwi;;, e.AEncov 'tTJi;; cpuaEwi;; ,ou 1toppw1loui;; uAtXOU XCXl 'tTji;; 1tOOO'tTJ'tOi;; 'tOU OtCXAU'tlXOU µe.aou. ( 1) 0 cxpxtxoi;; e.AEncoi;; xcxtvoupywv 7J µ7J-µE,CXXEtptaµe.vwv oox.Elwv Sex 1tEp1.Acxµ~cxvEt. A. - E1ti XCX'tCXM7JAOU 1le.iyµcnoi;; 1loXELWV: (ex) iAqxov 'tOU UAtXOU XCX'tCXOXEU7Ji;; ytoe 'tOUAIXX,tO'tOV 'tTJV 'tlXOTJ cx1to1loaEwi;;, 'tljV CXV'tOX7JV Eti;; EcpEAxuaµov, XCXt 'tTj µovtµTj E1ttfL7]XUVOTj 'tOU 0pcxuaµcx,oi;;· Ot EX 'tWV EAEYX.WV CXU'tWV 1tpo­ XU1t'tOUOEi;; ,tµe.i;; 1tpe.1tEl vex auµcpwvouv {LE ,oui;; E0vtxoui;; XCX­ vovtaµoui;;• (~) µhpTJOTJ ,ou 1tiix oui;; a,o AE1t,o,Epo aTjµEio ,ou ,otx w­ µcx,oi;; XCXl U1tOAoytaµoi;; 'tlji;; 'tlXOEwi;;· (y) e.AE'(XO 'tTji;; oµmoye.vEtoti;; 'tOU UAtXOU ytcx x&.0E mxp,i1lcx XCX'tCXOXEU7]<;, Xoct Eltt0Ewp7jOTJ 'tlji;; e;w,EptX'J]i;; XCXt EOW'tEplX7Ji;; XCX'tCXO'tlXOEW<; 'tWV 1lox.Eiwv· B. - ftcx OACX 'tot oox.e.[cx: (6) e.Ae.nco uopcxuAtx'J]i;; mfoe.wi;; auµcpwvwi;; 1tpoi;; ,ti;; &tcx,ii­ ;e.ti;; ,wv 1tEpt0wplwv 2219 e.wi;; 2221 • (e.) e.m8e.wp7JOTJ 'tWV e.v6El;e.wv Eltl 'tWV 1lox.Eiwv (~Ae.1tE ltE­ pt0wpto 2218). f. Emitpo60hwi;;, '(lot 1loxe.icx itpoopt,oµe.vcx ytcx 'tTJ fLE'tCX­ cpopii 1ltcxAuµe.vou CXXE'tUAEVLOU (9° (r)): (a,) E1tt8EWPTJ07l 01tw:; CXltOCl'tEL'tCXt EX 'tWV E0vtxwv xcxvovt­ aµwv. (2) Tex oox dcx 1tpe.1tEt vex cxv,e.xouv O'tTJ ltlEOTj 'tOU EAe.ncou xwp[i;; VCX ucp[a,CX'tCXl ·µovtµo 1totpotµopcpwa7J 7] VCX 1tcxpoua[CX,OUV pwyµe.i;;. (3) L,ti;; mpto1ltxe.i;;· e.m8Ewp~auc; Sex E1tcxvcxAcxµ~iivov,cxt ,ex 1tcxpcxxii,w: o e.AEncoi;; u6pcxuAtX7]<; mice.we;· EAEncoi;; 't7j<; e.;w,Eptx7Ji;; XCXt EOW'tEptx7Ji;; XCX'tCXO'tlXOEW<; 'tOU 1loxe.lou (1t,X,, Otex ,uyi­ ae.wi;;, EOW'tEptX7]<; Em0EWP7JOEWi;;, EAe.ncwv 'tOU 1tiixoui;; 'tOU ,mxwµcx,oi;;)· EltCXA7]8EUOTj 'tOU E;o1tAtaµou XCXt 'tWV Ev1ld;e.wv XCXt, EIXV XPEtcxa8a[, E1tOCA7]8EUOTJ 'tWV xcxpotX'tljpta'ttXWV 'tOU uAtXOU Otex XCX'tCXM7JAWV EAe.ncwv. • Ot 1tEpto6txe.i;; Em0e.wp7]aeti;; 0cx 1ltE;iiyov,oet: (cx) XIX8E 2 XPOVtoe 1tpOXElflE.VOU 1tEpt 1lOXELWV 1tpoopt,oµe.­ VWV ytoc 'tTJ µE,cxcpopii ,wv cxEpiwv 'tTJi;; 1 ° (ex T) xcxt -1 ° (y T). otEpiou 1tOAEwi;; (1l7]µou) ,lji;; 2° (~ T)· cxe.plwv 'tTJi;; 3° (ex T) 1tA7JV ,7Ji;; cxµµwvicx:;, E;cxcp8opto1tpo1tuAEviou )(ott µE8uAo~pw­ p.t6iou· x:i.wpoxucxvtoiou 'tlji;; 3° (y T)· XCXl uAwv 't7ji;; 5° (ex T)· . (~) XIX8E 5 XPOVlCX 1tpOXEtfLE.VOU ltEpi 1loXELWV 1tpoopt,oµe.­ VWV ytcx 'tTJ flE'tCXcpopii iiMwv 1te.me.aµe.vwv xcxt uypo1tot7Jµe.­ vwv cxapiwv ( U1t0 'tTJV EmcpuAot;Tj 'tWV OtCX'tlX;EWV 'tOU 1tcxpcx­ XIX'tW EOotcpiou (y)) xm 1loxEiwv ytcx 'tTJ µE,occpopii cxµµwvioei;; 1ltocAuµe.v7Ji;; u1to 1ttEOTJ (9° (oe T))· (y) xii8a 10 xpovtoc itpOXEtµe.vou mpi OOXELWV itpoopt,oµe.­ vwv ytcx 'tTj µE,cxcpopii cxEpiwv 'tTJi;; 1 ° (ex) 1tATJV ,ou o;uyovou· µtyµii,wv cx,w,ou fl.E aiccxvtcx cxe.ptcx, 'tTJ<; 2° (ex)· cxe.piwv ,7Ji;; 3° (ex) XCXL 3° (~) 1tATJV 1,1 - 1ltcp0optoµE0cxviou, 1 -xwpo - 1,1 1ltcp8opwµa8cxviou, µe.8uAoatAcxviou xcxt l,I,l - ,ptcp0optoµE8cx 1155 2215 2216 1156 E<DHMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) viou xcxt µryµ1hwv cxEpiwv TT)c:; 4° (ex) xcxt 4° (~), Eot\l ,ex OOXEicx exou11 XWPTJWCOTT)'tlX oxt IX\IW 'tW\I 150 At,pwv XIXl TJ xwpcx 1tpoEAEU0Ewc:; OE11 1tpo~Ai1tEt ~pcxxu1:Epo XPO\ltXO 6tcita,riµix. (6) 1tpoimµivou 1tEpi OOXELW\I 1tpoopt,oµivw11 jtlX 't'TJ µE,IX­ cpopcit OtlXAtJµivou IXXE'ttJAE\llOtJ (9° (r)), 'tO 1tEpt8wpt0 2217 (1) 9ix taxuEt, xcxt 1tpoxEtµivou 1tEpi ,wv auµcpwvwv 1tpoc:; ,o 7tEpt9wpto 2207(1) OOXELW\I, 'tO 1tEpt8wpt0 2217 (2) 9cx toXUEl. • 1) H El;wnptx71 xix,cita,ixari (6tcit~pwari, 1tixpixµopcpwari) XIXl TJ XIX'tlXO'tlXOTJ (xix).citpwari, xixet,11011) 'tOtJ 1topw6ouc:; tJAl­ xou OE OOXEllX itpoopt,oµE\IIX jllX 't'TJ µE,IX<popot OtlXAuµivou 1XXE,uAE11iou (9° ( 1)) 0cx ~Airxov,ixt xcit9E 5 XPOVLIX. H 6tqµix­ 'tOATJcj>iix 0ix EX'tEAEi,ixt OtlX TT)c:; xo1t71c:;, Eotv 0EwpTJ0Ei ix1tixpixi­ 'tTJ'tO, XIX'tlXAA7IAOtJ 1Xpt0µou 6oxdw11 XIXl Em8Ewp710Ewc:; IXtJ­ 'tW\I EOW'tEptxwc:; jllX OLot~pwari XIXl jllX 07t0tE007l7tO'tE OtAAIX­ ric:; ltOtJ E\IOEXE'tlXl \IIX 1tpoixucj>ix11 O'tlX OtJO'tlX'tlXIX tJALXIX XIXl 'tO 1topw6Ec:; tJAlXO. (2) Tix auµcpwvwc:; 1tpoc; 'tO 7tEpt0wpto 2207(1) OOXELIX 9ix u1to~otAO\l't1XL x<i0E 5 XPOVLIX OE E~W'tEptX7] Em0EWpTJOTJ XIXt aE EAl!jXO 'tTJc; O'tl!jlX\IO'tTJ'tlXc;. 0 EAEjXOc; 01:EjlXIIO'tTJ'tlXc; 9ix OtE­ i;iije'tlXL (LE 'tO cxipto 1tEpLA1Xf-l~IX\IO(-lE\IO O'tO ooxdo 7l µe ix6pcx­ \1Ec; cxipto OE 1tiEOTJ 0,2 MPix (2 bar). 0 EAEjXOc; 0ix eX,EAEL'tlXt OtlX mE,oµhpou 7j µe,p710Ewc:; 6lcx xevou. H 8epµt"x71 µovwari OE 0ix cxcpatpfricxt. H ltlEOTJ OE 0ix tJ7tOXWPEl 6tixpxouaric:; 'tTJc; 8-wpou 1tEpto6ou EAEjXOU. illcxric; 1X1toppfou0Ec:; EX ,ric; cpu­ OEWc; ,ou IXEpiou 6oxtµ71c:; ( EAEjXOU) 71 EX 61ixxuµ<i110Ew11 ,ric; 9Epµoxpixaicxc; 0ix AIX(-l~IX\10\l'tlXl uit' ocj>Et. • (3). - E116Eii;Etc; E7tl 'tW\I 6oxdw11. ' 1) Tix fLE'tlXAAtxot ooxEicx 0cx cpipouv ,ex 1t1Xp1XX(X'tW a,otXELIX (LE jpot(-l(-llX'tlX XIX91Xpwc; EtJIX\l<Xj\lWO'tlX XIXl Ot1XpXELIXc;: (1X) µicx ,wy ovoµixatw11 ,ou IXEpiou 71,ou µi1µcx,oc; ixepiw11, 7tATIPTJ, cmwc; OLOE'tlXl O'tO 1tept8wpt0 2201, 1 ° Ewe; 9°. 't'TJ\I EltW\ltJ(-lllX 7l 'tO a71µix 'tOtJ XIX'tlXOXEtJIXO't7j 7l t6totX't7j'tTJ' XIXl 'tO\I cxpt0µo 'tOtJ 6oxdou (~J..rne E1tia11c; 7tEpt9wpto 2202 (3)). IlpoxEtµ~vou itepi 1XA01011wv u6po1011cx119pcitxwv ,wv 1 ° (ix), 3° (ix), 3° (ix T), 3° (~), 3° (j T), 4° (ix), 5° (IX) XIXl 6° (ix), TJ x p71011 ,ou 1pcitµµix,oc; R o:xo).ou8ouµi11ou uito wu o:pt8µou IXYIXj\lWpiaewc; 'tTJc; UA ric; E1mpim,1Xt e1tia11c;· (~) ,o 1X1tO~IX'tO ,ou 6ox Eiou x wpic; Ei;ixptjµix,IX & auµ1tATJ­ pwµcx,1X. (j) rniaric;, IX\/ ,IX 6ox do: 1tpoopi,ov,1Xt jtlX u1po1tot11µivix ixiptix, ,o ixito~ixpo wu 6ox eiou, auµ1tAeptAIX(l~1X11oµivwv wptO(-lE\IW\I Ei;IXp'tTJfllX'tW\I XIXl OtJ(-l7tA TJPWf-l<X'tW oitwc; ~IXA~i­ OW\I, µnixUtxwv 1twµ<i,w11 XAit. o:Uii itATJV ,ou 1tpoa,ixu,w­ 'ttxou XIXAuµµo:,oc;. 1:HMEin:l:H a,tc:; (~) & (r)= Tix a,mx Eicx ixu,<i , 11c; µcit,11.;, 0ix itpEmt \/IX IX\11Xjp'o:cpouv XIX't(X 't'Yj\l EltO(-lE\ITJ 1tEpt00LX7I OOXt­ µo:aiix. (o) 't'TJ ltlEO'Yj ooxtµ71c; (~AEltE 7tEpt0wpt1X 2219 Ewe; 2221) xixt TT)\I 1jp.Epoµri11iix (µ71vix, hoe;) ,ric:; 1evoµiv71c; ,EAEU'tlltilltc; ooxtµ71c; (e).irxou) ~AE7tE 7tEpt9wpt1X 2216 XIXL 2217)· ( e) 't'TJ acpplltjlOIX ,ou Ef-lltEtporvwµovix itou OtEi;7jjlltjE ,ouc; e).irxouc:; XlltL Em8ewp710Etc:;· XIXL Em1tpoa9hwc;: ( O't) 1tpOXEtµi11ou mpi 1tEmeaµi11w11 IXEpiwv 7j (lLj(llX'tW\I mmEaµi11w11 IXEpiwv (1 °, 2 °, 12 ° xixt 13 °): 't'TJ\I IX\IW'tlX'tTJ itLEOTJ ltATJpWaEwc; awuc:; 15 ° C 't'TJV Em,prnoµivri jtlX ,o a,o eaµix oox Eio (~:i.aitE 7tEpt0wpw 2219)· (') itpowµivou 1tEpi cp0opwux ou ~~piou (1 ° ( o: T) ), u1po­ itotriµivwv lltEpiw11 (3 ° iwc; 6 °) XIXt ixµµwviixc; OtlXAuµivric:; no 11Epo (9 ° ( ix T)): ,o rnt,pEitoµEvo lltvw,o:,o 1iµtaµix, xixt 't'TJ x wprittXO'tTJ'tlX. IlpoxEtµivou jtlX ~ix9etcit XIXtEcj>u1µivix ixi­ JtlX (DEEPLY - REFRIGERATED GASES) ,w11 7 ° xlltt 8 °: r'Yj XWP7J'tlXO't'Yj'tlX • (11) itpoxEtµivou itEpi IXXE'ttJAEviou 6tixAuµivou ae 6ux).u,txo .J.EOO (9° (r)): 't'TJ\I Emtprnoµivri 7tLEOTJ ltATJpWaEwc; (~AEltE n:ept0wpto 2221 (2)), XIXl 'tO ~apoc:; 'tOtJ XE\IOU OOX,ELOU auµitE­ lAIXfl~IX\10(-lEIIOtJ ,ou ~citpouc; ,w11 Ei;o:p,11µ<it,w11 XIXt 1t1Xpixxo­ ,ou811µa,wv, 'tOtJ 1topwoouc; tJAtXOU, XIXl 'tOtJ OUXAtJ'ttXOU µi­ jQtJ' (9) itpOXElflE\IOtJ itEpi (llj(llX'tW\I IXEpiwv 'tTJc; 12 ° XIXt IXE­ lLW\I ooxtµwv ( eAirxwv) ,ric; 13 °, ot ).ii;Etc; «µi1µo:,ix ixe 1iw11» 7l «o:ipLIX EAEjXW\I», IX\IIXAOjWc; 'tTJc; mpt1t'tWOEWc; 0ix '1Xpotaao11't1Xl O'tO OOX,ELO OIX\I jE\llX7j E\IOeti;TJ 'tOtJ iteptexoµi­ OtJ. Axpt~71c; 1tept1pixcp71 ,ou iteptEXoµivou 9ix etxovt,E'tlXL :ix0' OATJ 't'Yj f-lE'tlXcpop<i· • 2217 2218 (t) 1tpoxEtµivou 1tEpi µE,IXAAtxwv 6ox Eiwv 1:0: 01toiix, auµ , cpwvwc; 1tpoc; 'tO 7tEpt0wpto 2202(3), il\10\l'tlXI OEX'tot jllX 't'TJ µno:cpopot evoc; 1Xpt0µou 6to:cpopE'ttXW\l 1XEpiwv (oox ELIX 7tOAAIX 7tA7jc; x p710Ewc;), ixxpt~7jc; 6tixpxdo:c; ( cmi;i1:11).oc;) 7tEpt1pixcp.7j ,:ou 1tepLEx oµi11ou 01lt Etxovi,e,ixt oto:pxouaric; 1:7Jc; µe,o:cpo­ pcitc;. (2) Ot E116di;Etc; 0o: x o:pcitaao\l'to:t EL'tE Eiti Evtaxuµivou 1:µ71 µo:1:oc; 'tOtJ ooxEiou, El'tE eiti OIXX'ttJALOtJ, EL'tE EltL 7tAIXXIXc; IX\IIX­ jp<Xcpouaixc:; 01:mx Eillt, 1:01to8n11µi1111c; x wpic; vex Xt\lEL,IXt 01:0 6ox Eio. Emitpoa0hwc;, TJ ovoµlltaiix ,ric:; UATJ<; µ1topEi 111X a11 p.Etou1:o:L O'tO 6oxEio ot' opo:1:71c; EUXptvouc:; emrpo:cp71c; OLIX ~llt­ cp71c; 71 otixa6711ton otAATJc; taoowcitµou µE9cioou. ( i) IliEOTJ 6oxtµ71c;, ~o:0µoc; 7tATJpWaEwc;, XIXl opto\l xwpri­ 'tlXO'tTJ'tlXc;, 'tW\I ooxeiwv (~AE7tE rniaric; 7tEpt0wpt1X 2238, 211 180 XIXl 212 180. (1) IlpoxEtfLE\IOtJ itepi ooxdwv itpoopt,OfLE\IW\I jllX 1:TJ µE­ 't1Xcpopa mmEOfLE\IW\I IXEplW\I 'tW\I 1 °, 2 ° XIXL 12 °, TJ EOW'tE­ ptX7j 7tLEOTJ (1tiEOTJ ooxtµ71c;) TJ Ecpo:pµoa1:iix 1to: EAl!jXO u6pixu­ Atx71c; miaEwc; 1tpi1tEL \IIX EL\IIXI 1:ouA1XXta1:ov fLtlXl J-LOtJ cpopii TJ 7tlEOTJ 7tA7jpwoEwc; 01:0uc; 15 ° C TJ OTJfLELOUfLE\ITj 01:0 OOX,ELO, IXAAIX OX,L µtxpo,epri 'tW\I 1 MPix (10 bar). (2) IlpoxELfLE\IOtJ 1tEpi 6ox eiwv itpoopt,oµivwv 1to: 1:71 µe­ 't1Xcpopii u).wv 1:ric; 1 ° (ix) 7tA riv wu 1:Etpo:cp8opt0µE9ixviou • 6w­ 'tEpiou XIXl UOpOj0\101> 1:TJ<; 1 °(~)• 7j lltEplW\I 'tTJc; 2°(0:), TJ ltLEOTJ itATJpwoewc; 6Ev 0o: uitEp~ixivEt ,IX 25 MPllt (250 bar) ,o: o:vo:­ cpEpoµEvo: 1tcx 9Epµoxpixoio: 15 ° C. :l:TTJV 1tEpi1t1:wari ,wv OE­ i;llt(LE\IW\I, TJ 7tLEO'Yj ltATJPWOEWc; OE\/ 0o: tJ7tEp~IXL\IEl 'tlX IX\IO:cpepo­ f-lE\IIX oe 9Epµoxpixoillt 15 ° C. Ilpoxetµivou itEpi ooxEiw11 XIXl oei;ixµevwv itpoopt,OfLE\IW\I 1tcx 't'TJ µE1:o:cpopii aUw11 o:Epiwv ,wv 1 ° Xlltl 2 ° TJ itieari 7tATJ- • pwaEwc; OE\/ 0ix ump~lltl\/El 'tilt 20 MPix (200 bar) 1:IX IX\IIX<pE­ poµE\IIX OE 0Epµoxp1XOtlX 15 ° C. (3) Ilpoxetµivou itEpi oox eiwv 1tpoopt,oµi11wv 1tix 't'TJ µE­ to:cpopii cp9opiou ( 1 ° ( IX T)) TJ Eow1:Eptx71 1tieo11 ( itLEOTJ EAEjXOtJ) TJ Ecpixpµoo,io: "(lilt 'tO\I EAEjXO 'tTJ<; uop1XUAtx71c; ltlEO'Yjc; 9o: El\llXL 20 MPcx (200 bar) xo:t TJ 7tLEOTJ ltATJpWoEwc; OE\I 0cx tJ1tEp~o:i­ \lEt 'tlX 2,8 MPix (28 bar) ae 9Epµoxpixoiix l5°C· E1tt1tpoo9i­ 'tWc;, XIX\IE\IIX OOX,ElO OE\I 0o: itEptiX,El 1tEptoao1:Ep1X 'tW\I 5 KG cp9opiou. flpoxEtµivou itEpi 6ox Eiwv itpoopt,oµivwv 1 tix TT) (lE'tlX­ cpopii 1:ptcp0optouxou ~opiou (1 °(0: T)) TJ u6p1XUAlX7j ltLEOTJ TJ Ecpo:pµoo,iix O't'TJ\I 7tLEOTJ 6oxtµ71c; (EAirxou) 0o: dvcxt EL'tE 30 MPcx (300 bar), OltO'tE 'tO IX\IW'tlX'tO ~apoc; 1:0tJ 7tEpLEX,O(lE\IOtJ ixvii ).[,:po x wp7J,LXO'tTJ'tlX<; 6ev 0o: uitep~o:[\IEL 1:0: 0.86 Kg. ( 4) flpoxuµivou itEpi oox eiwv 1tpoopt,oµivw11 1to: 't'TJ µE,IX­ cpopix· µ011oi;et6iou 1:ou llt,w1:ou NO ( 1 ° ( 1 T) ), TJ x wprinxo­ 't'Yj'ttX 0cx 1teptopi,et1XL O'tlX 50 L· TJ uopo:uAtX7j ltLEOTJ TJ Ecpo:pµo­ O'tEIX xo:,a 'tTJV ooxtµTj (1tiE0116oxtµ71c;) 9cx Eivo:t 20 MPix (200 bar)· xo:t 11 1tiE071 7tATJpWoEwc; OE\I 9cx uitEp~o:ivEL 'tlX 5 MPo: (50 bar) aE 0Epµoxpo:aillt 15 ° C. (5) flpo,mµivou itEpi 6ox Eiw11 1tpoopt,oµi11wv 1tix ,71 (LE­ 't1Xcpopii (-llj(-llX'tW\I uopo,ovou fLE OX,l IX\IW 'tOtJ 10 'tote; EXIX'tO\I OEA7I\IOUX,OtJ uopOjO\IOtJ 71 cpwocpiv11c; 71 OLAIX\ILOU 71 jEpµ~viou xo:,' 61xov 71 (LE OX,t avw 1:wv 15 o,cx Exo:,o o:poi1111c; xixt' OjXO\I' fLL j(llX'tW\I oc,w-rou 7j 07tlX\llW\I IXEplW\I ( 7tEptEX,O\l'tW\I OX,t IX\IW 'tOtJ 10 O'tlX EXIX'tO\I, OEA11\IOUX,OtJ uopOjO\IOtJ 71 cpwocpi­ \17lc; 71 aLAo:11iou 71 jEpµixviou xoct' 61xov 7j fLE ox t citvw ,ou 15 O'tlX l!XIX'tO\I ocpaiv71c; xoc-r' OjXO\I (2 ° (~ T))· fLljfLIX'tW\I uopo­ "(0\/0tJ fLE oxt IX\IW 'tOtJ 10 O'tlX EXIX'tO\I 6t~opix11iou xo:t' OjXO\I' 71 µt1µit,w11 o:,w1:0u 7j aitixviwv cxepiwv (1tEptEX,ci111:wv ox.t iivw ,ou 10 a,o: EXOC'tO\I O::ivov xo:t' o1xov) fLE ox t itvw ,ou o,oc 10% ot~opixviou xoct' o1xo11) (2o (j T)), ri x wpri,txci,711:0: 9ix 1tept0pl,E't1Xl OE 50 L • 71 uop lXtJAlX7I 7tLEO'Yj 71 Ei:po:pµoo,io: OTT) 6oxtµ71 (1tiE07I 6oxtµ71c;) OE\/ 9ix Et\llXl µtxpo,EpTJ 'tW\I 20 MPix (200 bar) XIXL 71 1tiea71 1t:l.71pw0Ewc; 6e11 0ix u1tEp~ixi11Et ,o: 5 MPo: (50 bar) OE 0Epµoxpo:oillt 15 °C.. (6) L\oxdix ouµi:pwvwc; (LE 'tO 1tEpt8wpt0 2207(1), O't7I 9Ep­ µoxpo:aiix 1tA71pwoewc; XIXl OE 7tlE07I 0,1 MPo: (1 bar), OE\I 0o: 1Eµi,ov,lltt 1tiplltv wu 98 a,ix EX1Xto11 ,71c; x wp71,txo,711:oc; 'tWV, Oocit,uc; µEtiXcpipE'tlXl oi;u-yovov ,71c; 7°(ix), 9ix AIX(l~IX\10\l'tlXl fLE'tpiX IX1tO(j)Uj7jc; OtOtJ07jltO'tE X,tJOLfLIX'tO<; 't7lc:; Ujpctc; (j)<XOEW<; (LIQUID PHASE). (7) Oaiixtc; OtlXAtJfLE\10 IXXE'ttJAE\ILO (9°(1)) fLE'tlXi:pipetlXL OE oox Eiix ouµcpwvwc; itpoc:; 'to itEpt0wpto 2212(1) (~), 11 x wpri 2219 E<l>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: ~EYTEPO) 1157 'tLXO'tlJ'tCX 'tW\I Boxeiwv Bev 01X U1tep~llt\lEL 'tll 150 L. (8) I-I X~P'JJ'tLX~'t'JJ<; 'tW\I Boxeiwv 't~\I 1tpoopt~oµi~W\I rtll ltptjpocqi~ uATJ<; Apt8µoc; Koctwt<XtTj Avwtocto Biipoc; 't'JJ µetmpopll µt11lll'tW\I iXEpLW\I 't'JJ<; 12 6ev 01X U1tep~llt\1Et 'tll 50 L. H 1ttE07J 'tOU µirµllto,; 6ev 01X ti1tEp~llt\lEt 'tll 15 MP!X Eioouc; m,OTJ Titptaxoµivou ( 150 bar) oe 0epµoxp1Xoi1X 15 ° C. doxtµ~c;/ ocva ).[tpo xw- ' (9) H xwp7Jttx6t7J'tll twv 6oxeiwv twv 1tpoopt~oµivwv 1 Lll EAarxou pTjtLXO't'l)tOCc; 't'JJ fEtllrpopcx iXEptWV ~oxtµ71,; ( E~El'XOti) 't'JJ<; }3 0 6ev 01X U1tep MPoc KG ~mvet 'tll 50 L. H meo7J 1tA7Jpwoew,; oe 0epµoxp1Xotll 15 °C <!J8optouxo SULPHYRYL 3°(oc T) 5 1.10 6ev 01X u1tep~1X[vet to 7 O'tll EX!ltov t71,; mfoew,; 6oxtµiJ,; E~ixqi8optouxo Bo).ippiiµto 3°(oc T) 1 2.70 (EAEl'XOti) 'tOU 6oxe[ou. Bout&.vt0 30(~) 1 0.51 (10) ~'t7JV 1tepi1t'tW07l 'tOU E~1Xrp0opLoux ou ~0Arpp1Xµiou (3 ° 1-Boutivto 30(~) 1 0.53 (IX T)) 7l XWP7J'tLXO't7j'tll 'tWV 6oxeiwv 01X 1teptopi~E'tllt O'tll 60 1-XAwpo - l, l - 6tqi8opto L. p.t8&.vt0 (R 142~) 30(~) l 0.99 H xwp71ttXO't7l'tll 6oxeiwv l'tll 'tE'tp1Xrp0optouxo 1tupitto ( 1 ° CIS-2-~outivto 30(~) l 0.55 (ll !))· XAWptouxo ~opto, /Awptouxo NITROSYL Xllt rp0o- KY xA01tpo1tiivt0 30(~) 2 0.53 pt0~XO SULPHURYL (3 (IX T))· µe0u).06v..1Xviou (3 ° (~))· l,l-dtqi8optoµa8iivto (R 152oc) 30(~) 1,8 0.79 1XpotV7J<;, 6tx AwpootAIX\ILOU, 6tµe0UAOOtXIXVLOU, -OEA7l\lOuxou dtp.aBuAtxoc; ru8~p 30(~) 1,8 0,58 u6porovou Xllt tptµe0uAOOLAIXVl0t) (3 ° (~ T))· XAWpOXUIX\lt- lao~outivto 30(~) l 0.49 6iou )tilt l(t)IXVt6iou (3 ° (y T))· µtrµcxtW\I µeBuAOOtAIXVLOU ( 4 ° lao~otiivto 30(~) 1 0.52 (~ T))· UAWV 't7j<; 4 ° (r T) 7tA7JV 6txAwpo6trp0opt0µe81Xviou 1tE- Mt8u).o6v-avto 30(~) 22,5 0.39 pLexouowv 12 'tOL,; EXIX'tO\I m0UAEVO~Et6iou Xll'tCX ~expo,;. OtAIX- Tipo1t1XVLO 30(~) 2,5 0.42 viou ( 5 ° (~)) • XIXL uAwv 't'JJ<; 5 ° (~ T) xm ( 1 T), 81X 1tepLopi~e- TI po1tuAivto 30(~) 3 0.43 'tilt O'tll 5 0. • TRANS -2-~outivto • 30(~) l 0.54 (11 ~ TTpoxEt µavou 1t~p[ 6oxeiwv 1tpoopt~oµivwv YLll ,pt- l, l, l - T ptqi8optoµt9iivto 3 o(~) 3,5 0.75 rp0optouxov XAWpto\l (3 (IX T)) 71 xwp71ttXO't7l'tll Bll 1tept0pi- ApoLVTJ 3°(~ T) 4,2 l.10 ~E't~t O'tll 4? L. Met~ 'tO raµtoµll, 6oxeiov 1tEpLEXOV tptrp8o- dLXAWpOOLAIXVlO 3 o(~ T) l 0.90 pt0uxov X Awpt0v (3 ( IX T)), 1tpO'tOU 1tllp1X600ei l'tll µetll- dtp.t8u).ocµ[vTJ 3o(P) 1 0.59 rpopcx, 01X xpll'tEt'tllt mi oxt OALl'O'tEpwv 'tWV 7 7Jµepwv 1tpo,; dtp.t81lAOOlA(XVLO 3°(~ T) 22,5 0.39 E1t1XA7j0Wotv t71,; otqllVO't'JJ'tCX<; tou. At8u).ocµ[vTJ 3°$ T) l 0.61 (1) TTpoxetµivou 1tepi 6oxeiwv 1tpoopt~oµivwv 1 tll 'tTJ µe- 2220 At81lAOXAWpt6LO 3°(~ T) 1 0.80 't!Xrpopix urpo1tOt7JµE\IW\I iXEpiwv 'tWV 3 ° iw,; 6 °' Xllt 6oxeiwv l:tA TJVOUXO Y6porovo 3°(~ T) 3,1 1.60 1tpoopt~oµivwv 1 tll 't'JJ µe,!Xrpopix 1Xepiwv 6LMu0iV'twv u1to Y6pooou).qi[6w 3°(~ T) 5,5 0.67 1ttE07J 't7j,; 9 °, 7J erp1XpµootEIX u6p1Xt!Atx71 1tieo7J Xll'tcx 'tTJ" 6oxt Mt8u).ocµ[vTJ 3°(~ T) 1,3 0.58 µiJv (1ttE07J 6oxtµiJ,;) 6ev Bll Et\lllt µtxpotep!X tW\I 1 MPIX (10 Mt8u).ox Awp[6to 3 °(~ T) 1,7 0.81 bar). . Mt8UALX~ MtpXOClttllVTJ 3°(~ T) 1 0.78 (2) TTpoxetµivou 1tepi UrP01tot71µivwv !Xepiwv twv 3 ° Xllt T ptµt8u).ocµ[vTJ 3°$ T) l 0.56 4 ° 01X t7Jpou\l't1Xt !XL XIX'tWtipw ttµlli 1 tll 't'JJV u6p1XuALX7l 1tieo7J T ptp.t8UAOOLAIXVLO 3°(~ T) 22,5 0.39 ,71v erp1Xpf!OO'tEIX Xll,cx t71v 6oxtµiJv (1tieo7J 6oxtµiJ,;) Xllt 1 tll Boutixotivto 3o(r) l 0.55 'tOV e1tLtpe1toµevov IXVW'tll'tOV ~IX0µ6v 1tA71pwoew,;: 1,3 - Bout116tivw 3o(r) l 0.59 Btvux ).wpioto . 3 o(j) 1,2 0.81 BAi1te O'tO 'tEAo,; 'tOU 7tl\llXXIX 't'JJ<; 1tllp!Xrpcxrpou (2). Kuocvorovo 3o(r T) 10 0.70 XAwpoxuocv[6to 3°(r T) 2 1.03 At9uAtvo~t[6to 3°(r T) 1 0.78 Mt8u1-o~tvuA1Xt8ipocc; 3°(r T) 1 0.67 T ptqi8optox Awpooct8UAEVLO (R Titptjp11qi~ UATJ<; Apt9µo<; Kixtwtii't'I) Avwtocto Biipo, 113) 3°(r T) 1,9 l.13 E[6ouc; m,OTJ Titptaxoµivou Btvu~pwµ[6to 3°(j T) l 1.37 doxtµ~c;/ ocvii Attpo xw- M[jp.lX F l 4°(ix) 1,2 1.23 • E1-irxou pTjtLXOtTjtOC<; Mtjl-'-IX F 2 4°(oc) 1,8 I.IS MPoc KG M[jp.lX F 3 4°(ix) 2,9 1.03 M[rµix ixtplwv R 500 40(,x) 2,2 1.01 Bpwµox).wpootqi8optop.t9&.vto 3°(ix) l 1.61 Mlrµoc octp1wv R 502 4°(oc) 3,1 1.05 (R 12 B l) Mlj!-'-IX 19 awe; 21 OtlX EXIX XAwpo6tqi8optoµa8iivw (R 22) 3 °(oc) 2,9 1.03 tOV XIXtll ~iipqc; 6txAwpoot XAwpo1ttvt11qi8optop.t8iivt0 (R qi8optop.t8ixv[ou (R 12) xOCL 115) 30(,x) 2,5 1.06 79 iwc; 81 otoc txoctov xoctii l-x1-wpo-2,2,2 - tptqi8optoµt- ~apoc; ~pwµox 1-wpo6tqi8opo 8&.vto (R 133ix) 3°(oc) 1.18 µt8ocv[ou (R 12 BI) 4°(oc) 1,2 1.50 dLXAwpo6tqi8optop.t9iivto (R M[rµoctix µa8uAo~pwµt6[ou 12)· 3 °(oc) 1,8 1.15 )(O(l x1-wpomxplv1jc; 40(,x T) 1.51 dLX Awpoqi9optoµt8iivto (R 21) 30(,x) l 1.23 M[rµoc A ( tp.1toptx~ ovoµoc 1,2 - dLXAwpo - 1,1,2,2 - o[ix: ~outiivto) 40(~) 1 0.50 mpocqi8optop.t8&.vto (R 114) 3°(oc) 1.30 Mtyµix A O (tp.1toptx~ ovo Oxtwqi8optoxux).o~outiivto µoco[ix: ~01lt0:VLO) 40$) 1,5 0.47 (RC 318) 3°(ix) l,l 1.34 Mlrµoc A 1 40(~) 2 0.46 Aµµwvloc 3°(oc T) 3,3 0.53 Mljp.lX B 40(~) 2,5 0.43 XAwptouxo Bopto 3°(oc T) 1 1.19 M[jp.lX r (tp.1toptx~ ovoµoc XAwpto 3°(oc T) 2,2 1.25 olix: 1tpo1tiivt0) 40(~) 3 0.42 Tptqi8optouxo XAwpto 3°(ix T) 3 1.40 Mtjl-'-IXtO( u6porovocv8paxwv E~ocqi8opto1tpo1tuAivto (R 216) 3°(oc T) 2,2 l.ll 1ttptixovt0t µt8avto 40(~) 22,5 0.187 Y6po~pwµto 3°(oc T) 6 ·I.20 3 0.244 Mt9uAo~pwµ[6to 3°(oc T) l 1.51 . 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Ot 1tpo~AE1tOfLEVEc; mfom; BoxtµTjc;/ EAETI(OV dv0tt i:ov- 2220 AIX)(.l01:0II ia.c; 1tpoc; i:tc; 7ttEOEtc; Ot1:fLOU ,:wv vypwv ai:ovc; 70°C, LUC'tl1'tLXOt fLEtwµivEc; xa,:ix 0, 1 MP0t (1 bar), i:71c; 0t1t0tti:ovµi1171c; xai:w- (~dtpoi; ,ot,; Ex1116v) i:ixi:71c; 1ttfoiwc; BoxtµTjc;/ EAETI(OV ot107Jc;, • i;v i:oui:otc;, 1 MPa .1w~1d6to wu dtv8p11xoi; 6' 19 1 0.64 (10 bar). ittpLEXOV (11) 1-10 19 1-10 0.48 2. EvocJ,71 ,:ov vcJ,71:>.ou ~a!lµou ,:o~txo,:~,:oc; ,:ov q>wa,EVelOV 'tOL<; tXl1"tOV Ot~W'tOV, o~u-. 25 1 0.73 (x. Awptoux o x0tp~ovu:>.t0) (3 ° ( 0t T)) xat i:ov x. :>.wpoxv0tvt8iov -y6vov, 11ip11 ~ a1tdtvt11 11i- 25 1-10 0.59 (3 ° (1 T)),' 71xa,:w,:ix,:711tica718oxtp.1jc;/cAETI(OV 1t0t i:0t 0tEpt0t pt11 Xl1t0t ~Otpo,; av,:ix EX.Et opta!ld ai:ix 2 MP0t (20 bar). Mt"(fll1 11tpiwv R 503 6° (11) 3,1 0.11 3. Ot OtVW1:0ti:Ec; 1tpO~AE1tOfJ.EVEc; ,:tµic; ,ta ,:ov ~a!lµov 1tA71 4,2 0.20 10 0.66 pwa.wc; ai; KG/LITRE ix ovv xa!lopta!l.i wi;; xixi:w!lt: ixvw Llto~d6to wu dtv8paxoi; ittpti i:ai:o ~ixpoc; 1teptcx oµivov aliix Aii:po x wp71nxoi:71i:0tc; = 0. 95 xov DXL dtvw wu 3 5 wti; q>opic; 1:7JV 1tvxvoi:71i:0t v1pixi;; q>ixai;wc; a,:ovc; 50 ° C • rnmpoa!li- Ex11,6v 11t8uAtvo~ti6to x111dt i:wi;;, 71 q>ixa71 ai:µou 8.v 1tpE1tEt vix .~0tq>0tvi,.i:0tt xixi:w i:wv ~iipo,; 6° (r) 19 0.66 60°C. 25 0.75 (3) TTpoxctµivov 1tEpi Box .iwv 1tpoopt,oµivwv vat 1tepti- At8UAEVO~tloto 7tcptixov dtvw . x.ovv v,po1tot71µiv0t 0tEpt0t ,:wv 5 ° XOtt 6 ° 0 ~a!lµoc; 1tA71pw- ,ou 10 ,ot,; ,x11,ov 11Udt oxt a.we; 0a .ivat i:hotoc;, wa,:i; 71 .awnptXTJ 1ti.a71 ai:ovi;; 65 ° C OtVW "tOU 50 "tO~ EXl1"tOV Oto µ71v V1tep~0tivat i:71v 1tica718oxtµ1ji;;/EAETI(OV ,:wv 8ox dwv. 0a ~.t6iou 'tOU dtv8p1XX11 Xl1"t0t i:71pouv1:0tt ot 1t0tp0txixi:w i:tµic; (~AE1tE E1tia71c; 1t0tpix1p0tq>ov ~iipo,; 6° (-y T) 19 ·o.66 (4)): 25 . 0.75 (4) ft0t UAEc; 171c; 5 ° 7tA7JV v8pox Awpt8iov (5 °(0t T)· 1cpµa TTtpt-yp11qi~ u1.11,; Apt8ft6,; K0t,W'tOt'tTj Avw tl1"t0 Bdtpo,; voµE00tviov xat q>waq>iv71c; (5 ° (~ T)· XOtt 8t~op0tviov (5 ° (1 T), Eloou,; m.a11 TTtpLtXOf!EVOU x0tt 1t0t UAEc; i:71c; 6 °, 71 X.P1J071 EAEx lliv,:wv Box Eiwv ai; xai:w .10XLft~<;/ 11vdt Ai,po xw- i:cp71 1tiEa7J 171c; opt,oµi1171i;; 01:7] 1t0tpix,p0tq>O (3) 1t0t i:71v a,:o EAE"(XOU pTj'tLXO'tTj'tl1<; !liµa t1A71 E7tt'tpE7tE1:0tt, IXM(X 711toao,:71,:0t i:71c; t1A71c; OtV(X Box Eio MP11 KG oav !la v1tap~aivct .x.i117111 71 01tot0t a,:ov 65 ° C !la 1t0tp1j10t1E .awi:aptxwc; ,:ov Box Eiov 1tica7111 ia71 µ. i:7JV 1tiE07J 8oxtµ1jc;/ Bpwfto,ptq,8optoftt8dtvto 5° (11) 4,2 1.13 EAETI(OV. Li:7111 1tEpi1ti:wa71 avi:11 ,:o Em,pa1toµc110 avw,:a,:o (R 13 B l) 12 1.44 q>O?'tlO Ila x0t!lopi,ei:0tt V7t0 ,:ov EfL7tEtporvwµo110t ,:ov 0t110trvw 25 1.60 pt,oµi11ov v1to i:71c; 0tpµo8i0tc; ixpx Tjc;. • .1to~ti6to 'Av8p11x11 5° (11) 19 0.66 25 0.75 (1) TTpoxEtfLEIIOV 7tcpi Otcpiwv 8tOtAVOfJ.EIIWII V7t0 7tlE07], i:71i;; 22'. XAwpo1ptq,8optof!E80tvto 5 ° (11) 10 0.83 9 °, ot 1t0tp0txixi:w i:tµic; !la i:71pou11~0tt 1t0t 1:7111 vopixvAtXTJ (R 13) 12 0.90 1tiaa71 ,:7111 Eq>0tpµoa,:i0t a1ti ,:w11 8ox Eiw11 xa,:ix i:7111 Boxt(J-Tjll / 19 1.04 EAETI(OII ( 1tica71 8oxtµ11c;/ EAETI(OV ), XOtt ,ta ,:011 E1tt,pe1toµa11011 25 1.10 OtllW1:0t1:0II ~0t!lµo11 1tA71pwa.wc;: E<DHMEPII: THI: KYBEPNHI:EQI: (TEYXOI: LlEYTEPO) Ap.p.wv[a 6taAup.iVT) u1t6 1t[taT) a-ro vtpc\ p.• livw wu 35% aAAli OJ(,t livw -rou 40% ap.p.wv[a xa-rli Apt0p.c\.; E1oou, ~lipo, 9° (a T) 9° (a T) auxJ.up.ivo AxmAivto 9° (r) Ka-rw-rlini mtaT) aoxtp.~,/ E).irxou MPa 1 1,2 6. 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MLX't'Tj LUOXEUOtOtOt Ot UAEc:; 't'Tjc:; KAotoEwc:; OtU't'Tjc:; itAT)V 't'WV uAwv 't'WV 7 ° XOtL 8 ° µitopc.uv VOt EjXAELo0ouv O't'O tOLOV XOAOV µE't'0t;u 't'WV EotV itEpLEXOV'tOtl: (0t) oE µe't'OtMLXTjc:; mfoEwc:; ooxEi0t 61xou µ71 u1tEp~0tivo­ v.oc:; 't'0t 10 Ai,p0t· (~) OE jUotALVouc:; OWATjVEc:; xovopou - 't'OLxwµ0t,oc:; Tj jUot­ ALVOt OL(j)OVLOt ouµq,wvwc:; itpoc:; 'tOt 1tEpt8wpL0t 2205 XOtL 2206, UltO 'tOV opov O'tL 'tOt Eu8p0to't'Ot OtU't'ot OOXEtOt ( UltOOOXEic:;) 0toq,0t­ AL,Oll'tOtL (o,EpEWVOV'tOtL) ouµq,wvwc:; itpoc:; 't'Otc:; OLOt'tot;Etc:; 'tOU 1tEpt8wpiou 2201(7). To 0t1too~Eo,txo UALXO 80t ,0ttptdt,et o,tc; lOLO'tT)'tEc:; 'tOU 1tEpLExoµivou. Ot EOW'tEptxic; OUOXEUOtOtEc; 80t 't'Oit00E"COUV'tOtl OE E;w,EpLXTj OUOXEUOtOtOt O'tT)V OltOtOt 80t 't'Tj­ pOUV'tOtL OtltO'tEAEoµ0t't'LXO( xwpLO't'ot 7l µiat OtltO 'tT)V otMTj, (2) Eio71 'tWV 10° XOtl 11 ° µ1topouv VOt EjXAELOV'tOtL O'tO tOLO XOAOV 7l µi0t µE 'tT)V otMTj UltO 't'ouc; opouc:; 't'otic:; itpo~AEltO­ µivouc; O'tO 1tEpt8wpt0 2 210, (3) Em1tpoo8hwc;, UAEc; ouoxEu0toµivEc:; ouµq,wvwc:; itpoc:; 't'Ot 1tEpt8wpt0t 2205 XOtL 2206 µ1topouv VOt EjXAEtOV'tOtL O'tO LOLO XOAOV 71 µi0t µE 'tT)V otMTj U7t0 ,ouc:; 1t0tp0tXot't'W ELOtxouc:; opouc:;. (4) KoAOV 'tO OltOLOV 60t 1tA71poi -couc:; opouc:; 'tWV (1) XOtL (3) OEV 80t ,u,[oet itdtvw 0t1t6 100 KG, Tj itdtvw 0t1t6 7 5 KG EotV mpLEXEL Eu8p0tUO'tOt OOXEtOt .. E101xoi 'Opot: Ap. 11 rp<Xfli'a E18ouc; (a) (a T) fl•pt-ypaq,,; 'U71c; Avwt<X't'f} Aip,a ouox•ua­ ol'iva OUfl<j)WVW<; 1tpoc; to 1t,p,8wpm 2205 avcx 60l(E<O • 0).a ta aip,a ta otu; 1too6 . ava-ypaq,61-'•va Oto 't'f}tec; ttc; 1t•pt8wpm auto 1tpo~AE1t0 • Aq,A•xta Aip,a • Aq,>-•xta To~,xcx Aip,a 1-'•v•<; oto 1t•pt8wpm 2205 floo6't'f}ta Et6,xic; i:xvtx ·xoAov dtattx;•u; 6 KG XAwp,ov (3° (a T) 6,v 8a ou­ ox•ucx~tta, I'• 6,o;ti6to tou 8t(ou (3° (aT) d•v 8a ou­ ox•ucx~ovtat f,l• UA!<; tWV IO.txOEWV la, l~. 11, 3, 4.2, 5.2 ,; 7 2222 Ap. 11 rp<Xflfla Ei8ou<; (a) (a T) (~) (Pl (r) (r T) 3°(a T) 3" (~) Aipux ouox•ua­ oµiva ouµq,wvwc; itpoc; tO 1tEpt8wpt0 2206 • 0')..a ta aip,a t<X ava1paq,6f,l•va oto 1tEpt8wpm ltATjV aµµwv(a<; Xat XU· XA01tpo1tav,ou Avwt<X't'f} avcx 8ox.do floo6't'f}ta Et8txic; avcx XOAOV dt<Xt<X~EI<; dtv 6a ou­ oxtu<X~OV't<XL µ• u')..tc; tc,iv IO.txotwv la, l~, 11, • 3, 4.1, 4.2, 4.3, 5.1, 5.2, 7 ,; 8 'Aq,>-•xta Aip,a 150 G 6 KG d•v 8a ou- OXtUtx~ovtaL flt UAt<; twv IO.cxotwv • Aq,AExta To;,xcx Aip,a Euq,AEXta Aip,a Euq,AEXta To;LX<X Aip,a X71µ,xw, AotaO,; Aip,a X71µ,xwc; Aota8,; To;ixcx Aip,a Aµf,!WVLa KuxA01tpo1ttivm 20 G 6KG la, l~. 11, 3, 4.2, 5.2 ,; 7 dtv 8a ou­ oxtuti~ovtm - • µ• u)..c; twv IO.tiotwv la, l~, 11, 3, 4.1, 4.2, 4.3, 5.1, 5.2,; 7 4. EvoEi;Etc:; XOtL mxi-rec; O't'Ot XOAOt (~AEltE Ilpoo8rix71v A. 9) ( 1) Kdt0E XOAOV itEptixov OOXEtOV µE 0tipt0t 'tWV 1 ° iwc; 9 °' 12° Tj 13° Tj µ71-;EVOtjEµt,oµEvOt ooxEiOt (CONTAINERS) 0tEpiou uito 1tiE071 ,71c:; 11 ° 80t µ0tpxdtpov't'0tt w0tvdtrvwo't'0t xatL OtvE;i 'tT)AOt µE 't'T)V ivo.t;71 't'OU 1tEpLExoµivou, 1tpoo8i't'Ovt0tc:; «KAdto71 2». To µ0tpxdtptoµ0t 0tu,6 60t Eiv0tt O't'T)V a1ti07Jµ71 jAWOOOt ,71c:; xwp0tc; 't'Tjc:; OtVOtXWPTjOEW<;, XOtl E1tio71c:;, adtv 71 1Awoo0t OtU't'Tj OEV EtVOtt 71 A11ALX'Tj, Tj f0tMLXTj, Tj fapµatvLXTj, O'tT)V AjjALXTj,fOtMLXTj Tj fEpµatvLXTj, ax,oc:; adtv, 't'UXOV, ouµ­ q,wv[Ec:; OUVTjq,87100tv µa,0t;u 'tWV EVOL0tq,apoµivwv xwpwv 1tpo~AEltOU0Ec:; we; 0tv0tq,optxwc:; µe 'tT)V imxa[p71071 't'Tjc:; µnat­ q,opdtc:;. H 1t0tpouo0t Olot't0t;71 OEV XPELot,E't'OtL VOt 't'7lp7j8EL EotV 't'Ot ~o XEtOt XOtL OL EVOEi;Etc; -couc:; EtVOtL 00tq,wc:; op~'tot. • (2) KoAOt mpLEXOV'tOt OL0tvEµ71,ic:; OtEpo,oA 't'Tjc:; 10 ° Bat µ0tp­ xdtpoV'tOtl µE 't'Tj Ai;71 «AEPOZOA» µE ,pdtµµ0t,Ot Euatvdtrvw­ O'tOt XOtL 0tvE;l,71A0t. (3) Oodtxtc; 71 0t1too-coATj EtVOtL 0t1too,OATj itATjpouc:; q,op't'iou, OL EVOEt;Etc:; OL OtVOt(j)EpoµEvEc:; O'tT)V 1t0tpotjp0t(j)O (1) OEV EtVOtL U7tOXPEW'tLXic;. (1) KoAOt 'tOt OltOtOt mptexouv OOXELOt XOt'tOtOXEU0tOµev0t OtltO UALXot XLVOUVEUOV'tOt VOt 8puµµ0t,to8ouv, 61twc:; 71 UOtAoc:; Tj wpt­ oµivac:; 1tA0to,1xic:; UAEc:;, 80t q,ipouv n1xi,0t ouµq,wvwc; itpoc; ,o µov,iAo No.12. 1159 2223 2224 llou 1:w1HM1:t"l2. 1 H.t. KYB1:PNH.t.EOI (TEYXOI L1EYTEPO) (2) KixSE XOAOV 7tEptixov exiptOL 't7]<; 7° ( OL) 71 8 ° ( IX}" 0ex cpi­ pEt, OE ouo exv-ri0hEi; 7tAEUpii;, E'ttXE'tE<; ouµcpwvwi; 1tpoi; 'tO µov-riAo No.11, XIXl EO:V ot UAE<; ,ti; 01toiEi; 1tEptEXEt E1XAEio­ V'tOCt OE yuixALVOL ooxEiex (1tEptSwpto 2207(2) (OL)), 1tpE1tEL, E7tl 1tpo0Si-rwi;, • VIX (j>EpEt E'tlXE'tOL ouµcpwvwi; 1tpo<; 'tO µov'tEAO No.12. KixSE XOAOV 7tEptixov OLOLVEµ7J,E<; OLEpo,oA 'tWV 10°(~) 2., 10°(~ T) 2., 10°(-y) 71 10°(-y T), 71 µ7J­ !;0LvOLyEµt,OfJ-EVOL ooxEiOL (CONTAINERS) OLEpiou U7t0 7ttE07J 'tWV 11 °(~), 11 °(~ T), 11°(-y)7111 °(-y T), SOL cpipEt E'ttXE'tOL ouµcpwvwi; 1tpoi; 'tO fJ-OV'tEAO No. 2A. B. Arnwµipmi; (o-ro.txEiOL) ET(po:cpou fJ-E'tOLcpopixi; . ( 1) H 1tEpt1pOLcp71 'tWV Eµ1topwµix,wv O'tO e11pOLcpo µE,OL­ q,opo:i; 1tpi1tEL VIX u1to:pxEt: (OL) O'tTJV 1tEpt1t'tW07J 'tWV XOLSexpWV XOLt 'tEXVLXW<; - XOLSOL­ pwv OLEpiwv 'tWV 1 °, 3 °' 5 °, 7 ° 71 9 °' 'tWV OtOLVEµ7J'tWV OLEpo 1;6).. ,71,; 10°, -rwv µ7J-1;exvOL1Eµtl;oµivwv OOXEiwv {CONTAI­ NERS) OLEp[ou u1t6 1tiE07J •7]<; 11 °, XOLt vex EtVOLt: µiOL ,wv ovo­ µOLotwv 'tWV U1to1pOLµµt,oµevwv O'tO 7tEptSwpt0 220 l • (~) O't7JV 1tEpi1t'tW07J 'tW\! µtyµo:,wv 'tWV OLEpiwv 'tWV 2 °' 4 °, 6 °, 8 °, 12 ° 7113 °: «µ[1µ0L OLEpiwv». H 1tEpt1pOLcp71 exu,71 1tpi1tEt VIX ouµ1tA7Jpou-rOLL µE ,7JV ivOEL1;7J •7]<; ouvSfoEwi; -rou µ11µ0L-roi; OLe:plwv XOL,' 61xov o,ex EXOL,ov 71 ~o:poi; o,OL EXOL-r6v. LUO'tOL'ttXIX µip71 XO:'tW 'tOU avoi; o-rex EXOL'tOV OEV XPELIX,E'tOLt vex exvexcpipov'tOLt. L't7JV 1tEpt1t'tW07J 'tWV µtyµo:-rwv OLEpiwv 'tWV 2°{1X), 2°(~), 2°(~ T), 4°(ex), 4°(~), 4°{1), 6°{0L), 8°(0L) 71 8 ° (~) ot itEpt1pOLq,ii; 71 ot ovoµOLoiEi; ot ouv71Smi; o,o Eµitopto 7t0U U1to1pOLµµi/;OV'tOLt O'tO 7tEptSWptO 2201 µitopouv oµoiW<; VIX XPTJOtµo1tOLOIJV'tOLt, xwpli; 'tOV XOLSoptoµov 't7]<; ouvSi­ OEW<;. Ot 1tEpt1pOLcpii; OLu,ii; 1tpi1te:t VIX 1mo1pOLµµ[,ov,OLt f,1-E xox­ xtvo XOLt VIX OLXOAouSouV'tOLL ex1t6 O'tOLXEiOL. 't7]<; KAO:OEW<;, 'tOV exptSµo 'tOU ELOoui; (µex,[ µE 'tO, -ruxov, ypixµµOL) xext 'tOL IXPXLXO: «ADR» 71 «RID» (1t.X., 2, 5°(0L T), ADR). (2) TTpoxEtµivou mpi OL1toowAwv OLEpiwv exvOLcpEpoµivwv µe:,OL1;u 'tWV X7Jµtxwi; OLO'texSwv OLEpiwv, 0 ex1tOO'tOAEOL<; ocpe:iAEt VIX 7tlO't07tQ\Et ~OL-XO:'tW0t O'tO e11pexcpo µE,OLcpopo:i;: «TTo:pS7]­ xexv 'tOL OL1t0LpOLi't7J'tOL µhpex 1tpoi; EX1tA71pwo7J -rwv 6pwv -rou 7tE­ ptSwpiou 2200 (4) ,7Ji; ADR». L't7JV 1tEpi1t,W07J OL7tOO'tOAWV µtyµix-rwv OLEp[wv 't7]<; 12 ° 71 OLEp[wv ooxtµ71i;/ EAEYXOU 'tTj<; 13 °, o OL1toO'tOAEOL<; ocpEiAEt vex mo,01totEi ,OL 1t0Lpexxo:,w o,o ET(pOLcpo fJ-E'tOCcpopixi;: «· Exouv 't7]p7JSE[ Ot 6pot ot Ot0LAOLµ~exv6 µEvot o,OL 12° 71 13° -rou 1tEptSwpiou 2201 ,7Ji; ADR». (3) TTpoxe:tµivou 7tEp[ OL7tOO'tOAWV ,ptcpSoptouxou XAWp[ou (3 ° ( ex T)) o ex1too-r0Ai0Li; ocpEiAEt VIX mo-ro1totEL 'tOL xo:-rwSt o-ro ET(pOLcpo µE,OLcpopixi;: «ME,O: 'tO yiµtoµOL µ~ ,ptcp0optouxo X AWpto, 'tO ooxe:io E't7Jp71S7J U7t0 1t0Lpex,71p7J07j E7tl XPOVLXO OtlX­ O'tTjfJ-OL oxt µtxpo,Epo 'tWV E7t't0( 7JµEpwv XOLt 7J O'tEYOLVO't7J'tO: 'tOU E7tOLA7JSEUS7JXE». ( 4) TTpoxuµivou 7tEpi od;exµEvwv 7tEpte:xouowv OLEptex 'tTj<; 7°(1X) 71 8~(1X) 7tA7JV Oto1;EtO[ou 'tOU cxvOpexxoi; XOLt u1to1;e:toiou 'tOU fX,W,OU, O'tO ET(pOLcpo f,1-E'texcpopcxi; SOL OLvexypcxcpE'tOLt: «H 0E 1;0LµEv71 ELVOLL OE µ6vtµ7J E7tlXotYWVLOL µE 'tTJV ex,µoocpexipOL». r. KEvcx E'.ioTJ LuoxEuOLoiOLi; ( 1) Tex ooxEiOL xext Ot OE!;OLµEvii; 't7]<; 14 ° SOL XAELYOUV µE 'tOV ioto ,p61to oexv VIX rnpoxmo ytex 7tA71P7J ooxEiex XOLt OE!;OLµEvii;. (2) H mpt1pmp71 o-ro i 11pOLcpo µE-rOLcpopcxi; 1tpi1tEL vOL ouµ­ q,wvE[ µE evex OL7t0 'tOL ov6µex,OL 7tOU oi6ov't0Ll O'tTJV 7t0Lp. 14 7t,x,: «KEVO 6oxEio· 71 («KEv71 OE!;OLµEv71,,), OLXOLScxptO'tO, 2, 140, ADR (TJ Eiooi; 14, RID)». To XELfJ-EVO exu,6 1tpE1tEt VIX cpepEt u1toypo:µµto7J, H 1tEpt1pexcp7J 1tpE1tEt vex ouµ1tA7JpwvE,OLt µE 'tTJV 1tpooS71x7J -rwv AE1;Ewv: «TEAEU'tOLio cpop-rio» µE 't7}V ovo­ µexo[OL XOLl 'tOV exptS. ElOOU<; 'twV Eµ1topEUµCX'tWV 7tOU cpop,w67J­ xexv ,EAEU'tOLiOL: 1t. X· TEAEU'tOLLO cpop,[o: Apyov I0 (0L). (2) TIX 6oxEiex 'tTj<; 14° 7tOU OLvexcpepov'texlL O'tO 7tEptSwpto 2212 (I) (OL) (~) XOLt (6) µ1topouv VIX fJ-E'texcpipov-rexL fJ-E'tlX 'tTJY EX7tV071 'tOU XPOVtXOU opiou 7tOU ,i8E'text 1tOL 'tTJV 1tEpto6tXTj 60 XlfJ-OLO[ex 7tOU XOLSop[,E'tOLl O'tO 7tEptSWplO 2215, 1tpOXEtµEVOU vex U7t0~A7]Souv OE ooxtµOLoiEi;. /J.. ME'tOL~OL'tLXE<; 0LOL'tCX1;Eti;. Ot 7t0LpOLXCX'tW µE,ex~OL'ttxk OLex,cx1;Eti; Sex Eq>OLpµo,OV'tOLl ytOL 2225 2226 2227 2236 2237 2238 6oxEiOL 7tOU 1tpoopi,OV't0Ll 1tOL ouµmEoµevOL 71 uypo1tot7JµEVOL exeptOL Tj OLEptex 6texAuµevOL U1t0 7tLE07J: (OL) ooxEiOL Tj07J OE U7t7JpEoiOL, SOL 1tpE1tEt, µE 'tTJV EmcpuAex1;71 rwv 1t0Lpexxix,w E1;0LlpEOEWV, 00L yivov,OLt 6Ex,de 1LOL 6tESv71 µE­ 'tOLcpopo: Ecp' 6oov -ro Em,pe1touv ot 6tex,ix1;Eti; ,71,; ouµ~exUoµi­ v71i; xwpm; O'tTJV 01toiex OLE1;71xS7JOOLV ot 6oxtµOLoiEi; ouµcpwvOL JJ-E 'tO 1tEptSwpto 2216 XOLL Ecp' OOOV E't7Jp71671oexv OL 1tpo8E­ OfJ-LE<; ot 1tpo~AE1tOµEvEi; crn6 'tOL 7tEptSwptOL 2216 (3) XOLl 22.1 7 1 tOL ,ti; 1tEpto0txei; EmSEwp710Eti;· (~) 1tpOXELfJ-EVOU 7tEp[ OOXELWV XOL'tOLOXEUOLOSEV'tWV ouµ­ ({)WVOL f,1-E 'tO 1tpo71-youµEvo OUO't7Jfl-OL (Em'tpE1toµiv7J 'tCXOTJ Mo­ 'tp[,OL, OLv,l ,ptwv-,E-rixp,wv, ,7Ji; -rcxoEwi; OL1too60Ewi;), OEV Sex Em'tpE1tE'tOLL XOLµiOL OLU1;7J07J OU'tE O'tTJ 1tfao7J 6oxtµiji; OIJ'tE O'tTJ 1tiE07J 7tATJpwoEwi; (~AenE 7tEptSwpw 2211 (l))· (r) fJ-E'tOL~OL'tLXIX µhpex ytOL 6E1;0LµEvei;: ~AE7tE 7tEptSwpto 211 180 XOLl 211 184. (6) fl-E'tOC~OL'tLXIX µhpOL ytOL OE!;OLµEvei;-ooxE[OL: ~um nEptOwpw 212 180. KAALH 3. EY<DAEKTA rrPA 1. KOL,IXAOYO<; UALXWV. ( 1) ME-rOL1;u 'tWV EU({)AEX'tWV UAWV XOLt µtyµcx,wv 7tOU ElVOL! u1pde TJ t1;wo71 oE SEpµoxpOLoiti; iwi; 35° C I/ EXEivOL nou exvOL­ q,epov-rlXl O'tO mptSwpto 2301 7J 1tOU Eµ1tl1t'tOUV O't7JV OUMO­ ytxiJ E7tlXE({)OLAiOOL ,ou 1tEptSwpiou OLu,ou, u1tOXELV'tOCt o,ti; 6tOL­ rde1;Eti; 'tOU 7t0U 1tpo~AE7tOV'tOLl O'tOL 7tEptSwptOL 2300 (2) ewi; 2322 XOLL o,ti; OLOL,o:1;Eti; -rou 1t0Lp6vwi; TTOLpexp-rijµoc-roi; TJ -rou 1t0Lpexp,71µexwi; B. KOLt ,cm XIXPOLX't7]pil;ov,m XOLt SEwpouv,OLt oOLv ouoiEi; ADR. 2/ (2) EucpAEX'tOL uypix, xex,IX 'tTJV ivvotex •7]<; ADR, exouv 7tLE07J OL'tfl-WV 7t0U OEV U7tEp~exLVEt 'ttq 300 KPOL (3 BAR) OE SEpµoxpOLoiOL 50° C XOLt 07JµEio OLVOLcpAi1;Ewi; 1tou 6Ev U1tEp~ocl­ VEt wu:; 100° C Ex,6i; oc1t6 ExEiVOL ,OL ecpAEX'tOL u1po: -roc onoiOL, A61w ouµ1tA7JpwµOL-rtxwv Emxtvouvwv toto,71-rwv, exvOL1po:cpo­ V'tlXl TJ exvijxouv OE CXME<; xAixoEti;. To 07JµEio exvOLq>Ai1;Ewi; SOL XOL0opi~E't0Ll 61twi; q>OLLVE'tOLt O'tO TTOLp1Xp't7Jfl-OL A.3, 7tEpt9wptoc 3300 ewi; 3302. (3) OuoiE<; 'tTJ<; KAixoEwi; 3, 7tA7JV ExEivwv 'tTJ<; 12° xext 13°, 'tOL1;tvoµ71µivEi; µE -roui; 6tOLcp6poui; OLptSµoui; Et6wv 'tOU 7tEpt­ Swp[ou 2301, Sex XOL'tOL,cxooov,OLL OE µiOL OL1t6 ,ti; OLxoAouSEi; oµcx6Ei; 7tOU OLOLxpivoV'tOLt µE 'tO rpcxµµOL (OL), (~) xext (r) OLVCX­ AoyOL µE wv ~ocSµo xtvOUvou ,wv: fpixµµOL (OL): TToAu Emxiv6uvEi; ouoiEi;: Euq,AEx,ex u1pix µE 071µEio ,eoEwi; ij OLpxtx6 07JµEio ~foEwi; ewi; 35° C XOLt EUcpAEX'tOL uypde fl-E OTjfJ,Elo OLVOLcpAE1;Ewi; XCX'tW 'tWV 21 ° C, 'tex 07t0LOL EiVIXl Tj E1;octpE'tLXCX -ro;txix, ouµcpwvoc fl-E ,OL xpt,iJptex -rou 1tEptSwplou 2600, 71 E1;extpE-rtxix 6tex~pw,txcx, ouµcpwvOL µE ,OL xpt,iJptoc -rou mptSwplou 2800. fpixµµoc (~): Emxlv6uvE<; ouoiEi;: EucpAEX't(l( uypix µE 07Jf1-ELO OLVOCcpAE1;Ewi; XO:'tW 0(7t() 21 ° C, 'tOL 07tOLOL OEV XOL'tOL'tO:OOOV'tOLt O'tO ypixµµoc (IX), µe E1;0LipE07J 'tL<; ouolEi; wu mptSwplou 2301,5° (1). r pixµµOL (r): OuoiEi; µE µtxpo xiv6uvo: EucpAEX'tOL uypix µe 071µdo OLvexcpAe;awi; OL7t0 21 ° C iwi; • 100° C XOLL ouoiEi; ,ou 1tEpt6wpiou 2301, 5° {1). ( 4) ·o,exv, OOLV OL7tO'tEAEoµOL 1tpoo67JXWV, 'tO 07JµEio O(VOLcpAE­ ;awi;, 'tO 07JµEio ~pOLoµou, 'tO IXPXLXO, OTjfl-Elo ~pOLoµou TJ 7J 7tLE07J OL,µwv µtOL<; ouo[OL:; 'tTj<; KAIXOEW<; 3 6Ev ~pioXE'tOLl µeaOL o,OL optex 1tou 1tpo6tex1pixcpov-roct 1tOL ,OL 6to:cpopOL Ei67J -rou 1tEpt 6wpiou 2301 'to µiyµOL OLU'tO 00L XOL'tex'tlXOOE'tOLt O'tOV 1Xpt0µ6 Ei 6oui; O'tO 01toio OLV71XEt rni 'tTJ ~IXOEt 'tOU 07JµEiou OLVOLcpAE1;Ewi; 'tOU, 'tOU 07Jfl-ELOU ~pOLOµou 'tOU 71 'tOU OLPXLXOIJ 07JµEiou ~poc­ oµou 71 'tTj<; 7tlEOEW<; OL,µou 61twi; 1tpOL-yµex-rtXCX xexSopil;E­ 'tOLt. (5) OuoiEi; 't7]<; KAIXOEW<; 3 7tOU ELVOLt EV6Exoµavo VIX OXTJ-· fl-OL't:LOOUV EUXOAOL U1tEpo;EiotOL ( 61twi; ouµ~OLLVEt (J,E wui; cxtSa­ pEi; 71 oE wptoµevEi; E,EpoxuxAtxei; o1;u1ovwµevei; ouoiEi;), 6ev 1tpE1tEL VIX 7t0LpOLoi6ov'tOLt ytOL p.E'tOLcpopcx, EX'tO<; O(Y 'tO 7tEptEXO­ µEvo -rwv oE umpo1;Eiow, unoAo1t~6µEvo oexv u1tepo1;Ei6to uopoyovou (H202) OEV U7tEp~exiVEL 'tO 0.3 'tOti;· EXOL'tO, To 1tEptEXOfl-EVO u1tEpo1;ei6to 00L 1tpE1tEt VIX 1tpoo6topi~e,ext 61twi; U7t00EtXVUE'tOLl OTO TTOLpcxp't7Jfl-OC A.3 7tEptSwpto 3303. 1/ TTpoooioptoµo:; 'tTj<; t1;wooui; XOC't:OLO'tlXOEW<; OE 35° C SOL ~OLoi~E't:OLL oE xpt,7JpLOL 6oxtµexoiOLi; µe Eto6uotofiE-rpo (~AE7tE TTOLpdep,7]µ0L A.3 mptS. 3310 XOLt 3311). 2300 <l>EK 104 EG>HMEPlr THr KYBEPNHtEOr (TEYXOr AEYTEPO) 2/ ftot -rte; 7tOaO'tT)'tEc; ouatWV 'tO\J 1tapt!l. 2301 7t0\J oav u1t6xatV'tott a-rte; 6tot-r<i1;atc; -rric; 1totpouaric; KA<iaawc;, aha a-ro 7totp6v Ilotp<ip-rT)µot d,a a-ro Ilotp<ip't1]µot B, ~AE7ta 1tapt!lwpto 230lcx. (6) Xriµtxwc; ota,ot9dc; ouaiac; 't1j<; K)..<iaawc; 3 oav Sot 1tpi 1tat VIX OtlXXtVOUV'tott9 '(lot µa-rotcpop<i ax,oc; CXV exouv AT)cp!lai 'tot xot,<XMT)ACX µhpot 1tot 1tp6ATJ41J emxtvBuvou ot1toauv8eaawc; Tj 7tOAuµaptaµou 'tWV XIX't<X 'tT)V µawcpop<i. ftot 'tOV axo1t6 IX\J'tO, !lot 1tpE1tat VIX OLV€'t1Xt t0tlXL'top1j 1tpOaOX'YJ Xott cppOV'tLOIX Wa'tE VIX a1;otacpotAi,a'tott 'tO O'tl 'tot ooxdcx Bev 1taptexouv xixµµiot ouaiot 7t0\J Vilt aivotL m!lcxvo VIX 1tpoxotAeaat 'ttc; otV'ttop<iaatc; IX\J'tE<;, LHMEIOLH: Ax6µ7] Xott 07t0\J oev otvotcpapa-rott ouaiot 'tWV 7totpotyp<icpwv ( ot ), (~) 'YJ ( 1) 'tWV OLotcpopwv atowv 'tO\J 7totp6v-roc; 1tept!lwpiou, ouaiac;, OLotAuµcx,cx, µiyµcx,ot xott axeu<iaµcx-rot µ1topOUV Vilt XIX'tlX't<XaaOV'tlXt a'tot 1paµµot'tlX ot\J't(X auµcpwvot µe 'tot xpt't'Yjptot 7t0\J EX'tL!JEV'tlXt a'tO mpt!JwptO 2300. A. Ouaiec; µa aT)µdo cxvotq,Ai!;ewc; x<i,w -rwv 21 ° C, µTj -ro!;t­ xic; xott µTj OLot~pwnxe.c; 1. Ouaiac; µa 1tiaari cx-rµwv aa so° C 'tO 7tOA\l we; 175 KPot (l.75 BAR) 61twc; 1t.x,: . Qtl(€'tlXAOEiiOT) ( otAoaiiori), 2-x Awpo1tp01t<XVtO, X Awptouxo ~twAtoavto, xpo-rovuA.ivto (2-~ou-ruAe.vto ), µelluAo-tao1tpo1t­ uAtx6c; ott01jp, µe!lu)..oµupµ7Jxtx6 tao1tpo1t<ivto, 2-µa!luAo-I­ ~ou-re.vto, 3-µa!lu)..o-l-~ou-re.vto ( tao1tp01tuAtx6 ott!luAivto ), 1, 4-1tev-rot6te.vto, xcxvovtxo cxµuAivto (l-1tev-re.vto ). 2. Ouaiec; µe 1tiea7J ot,µwv µe 50° C 7tAEOV 'tWV 110 KPot (1.10 BAR) ill<i axt 7tAe.ov ,wv 175 KPcx (1.75 BAR), 61twc; lt,x,: ex) ottlluAtxoc; ott01jp, tao1t1tpe.vto, o!;ai6to 1tpo1tuAeviou ~) I-xAwpo1tpo1t<XVtO (xAwptouxo tao1tp01t\lAto) l(UXA07t•­ V'tE.Vto, Otµe!lo!;uµa!lcxvto (µa!luACXA1]), ~tVUAtxoc; ott!lUAtxoc; ott­ !li]p, µa0uAtx6c; 1tpo1tUAtx6c; cxt!l'Yjp, 2-µa!luAo2-~ou-re.vt0, xcx­ vovtxo 7tEV't<XVtO, 2-mv-ce.vto, !lewuxo BtµalluAtO. 3. Ouaiec; µa 1tieari cx-rµwv aa 50° C -ro 1to~u 110 KPot (1.10 BAR) 61twc; 1t.x.: ~) wptaµivot otx<i!lotp,ot m-rpiAottot xott <XMIX opux-r<i eAottot, 1t-rrinxcx 1tpo'i6v,ot otitoa-rcx!;ewc; 1te-rpaAcxiou xcxt illwv opu­ x,wv €AIXLWV ( itiaaotc; ycxt<iv!lpcxxoc;, At'(VL'tT), axta'tOAi!lou, !;u­ AO\J 'YJ ,upcpT)c;), 7t,X· ~ev,ivri, 7tE'tpEAot'ixoc; ott!l'Yjp, 1tpoi:6v-rcx au­ µituxywaewc; cpuatxou cxapiou. TIAPATHPHLH: Evw ae wptaµevac; xAtµot-roAofxe.c; auv­ llrixac; 7l ~av,iV7] µ1topei VIX e.xet 1tiea7J cx-rµwv ae 50 C 1tepta­ a6-rapo IXltO 110 KPcx (1.10 BAR) CXM<X oxt 7tAEOV 'tWV 150 KPot (1.50 KPot BAR). !lot 1tpe1tet vex e!;cxxoAou!lei vot -rot!;tvo­ µehott µe 'tOV otpt!lµo 'tO\J 1totp6v-roc; <ip!lpou. Yocx-rcxv!lpcxxec; 61twc;: , ~av,e.vto, xuxAorn,<ivto, xux)..oa!;<ivto, xuxAoe!;e.vto, xuxAo 1tav-r<ivto, cxt!lUAt~ev,evto, ,exvtxo, E7t't<XVllX, E7t'teVtCX, e!;livux, OX't<XVtlX, ox-revtot, 'tOAO\JE.Vto. AAo1ovwµevac; ouaiec; 61twc;: XotVOVt)tO ~pwµwuxo ~O\J't\lAto, XAWptouxo otµUAto, XAW­ ptouxcx ~O\J't\lAtlX (x)..wpo~O\J't<XVtcx), 1, 1-otxAwpoott!l<ivto (xAwptouxo ott0uAEVlO), OtXAWptouxo 1tp01t\JAevto. TIAPATHPHLH: To!;txe.c; otAo1ovwµavec; ouaiec; aivott ou­ aiac; ,ou 16°. ~tot~pw,txic; otAo1ovwµavec; ouaiec; -rou 21 ° ri 25°. AhooAac;, 61twc;: rpt~oyevric; cxµuAtX'Yj otAxooA'Jj, -rpt-ro,ot'('Yjc; ~ou-rotvOA'JJ (,pt­ 'to-rcxyric; ~ou-ruAtX'Yj cx)..xo6A7]), ,axv'JJXTJ Btotxa-iovtx'i] cx)..xo­ OA1], ott!lotv6A7] (ottlluAtXTj 1XAxo6A1j) Xott -rot uoot-rtx<i OtotMµoc-rot CX\J'tWV 7t0\J mpte.xouv 7tAEOV 'tO\J 70% CXAXOOA1j, tao1tpo1tot­ VOA'Jj ( tao1tp01t\JAtXTj IXAXOOAT)). At!le.pac;, 61twc;: IXXa't<XAT) (l ,-1-otott!lo!;uott!l<iv'Jj), 1,2-otµa!lo!;uott!l<ivri, Ot0 1;1ivri, oto!;OA<XV'Jj, ottlluAtXoc; ~0\J't\JAtxoc; ott!l7jp, ~tV\JAtxoc; tao­ ~O\J't\JAtXoc; ott!l7jp, 0LL007tp07t\JAtXOc; ott!l7jp, 'ta'tpotiiopocpou­ p<ivri, A)..6aii6ac;, 61twc;: ~ou-rupotAOaii67], 1tpo1totovcx)..6aii67), Ka,ovac;, 61twc;: cxxa-rovri, ott0uAtX'Yj µa0uAtX7j xa,ovri, µa0uAtX1j tao~ou,u­ AtXTj xa-rovri, µe9uAtX1j 1tpo1tuAtX7l xa-rovri, µa9uALXTJ ~tvuAtXTj X£'COV'1j, 2301 Ea-ce.pec;, 61twc;: oeu-rapo-coty'i]c; ~OU'tUAtxoc; o!;atxoc;, ott0uAix6c; o!;atxoc;, tao­ ~O\J't\JAtXO<; o!;atxoc;, tao1tp01tUAtXoc; o!;atxoc;, µa9uAtx6c; o!;at­ xoc;, xotvovtxoc; 1tpo1tUAtx6c; o!;at~oc;, ~t\l\JAlXO<; o!;uxoc;, ott!lu­ AtXoc; otxpuAtxoc;, µa0UAtx6c; otxpuAtxoc;, -rptott9uAo-~optx6c;, rptµalluAtxoc; ~optxoc;, µa9uAtxoc; ~ou-ruptxoc;, 6tµe9u)..txoc; cxv9pcxxtx6c;, ott8uAtx6c; µ7Jpµuxtxoc;, 1tpo1tuAtxoi µ7Jpµuxtxoi, µe8uAo-µa!lotxpuAtx6c;, ott0uAo-1tpomovtx6c;, µalluAo-1tpomov­ tx6c;. Ouaiac; itepte.xouaec; Baio, 61twc;: cxµuAo-µapxot1t-c<XVT), ~ou-ruAtX'Yj µepxot7t't!XVT), 1tpo1tuAtXTj µepxcx1t-c<iv7J, 8etocpotivto. TIAPATHPHLH :. To!;txe.c; ouaiac; itaptaxouaec; Salo eivott oua[ac; 'tO\J 18°. 4. Miyµot,IX ouatWV 'tO\J 1 ° ewe; 3° itepte.xouaac; 'tO ltOAU 55% Vt-rpoxunotpivri µa itaptexoµevo ae <X'W'tO 'tO ltOAU 12.6% (OLotAUfl-CX'tlX XOMooiou, OtlXAuµcx-rot T)fl-tXOMOOLOU, <XAAIX OLIXA\lfl-lX'tlX Vt'tpOXU't'totpivric; Xott xpwµcx-rot Vt-rpoxunotpi­ V1jc;, ~epvixtot xott A<ixxec;.) ex) µa ariµaio ,ea.we; Tj cxpxtxo ariµeio ,eaewc; 'tO 7t0AU 35° c . ~) µa ariµeio ,e.aewc; ri cxpxtxo ariµaio ,e.aewc; 1te.potv -rwv 35°. IlAPATHPHLH: Miyµcx-rot µe aweio IXVotcpH!;awc; X<X'tW ot7to 21 ° Cxcxt: itapte.xov-rot 1taptao6-repo ot1to 35% vt-rpoxuncxpiv71, cxva­ !;otp'tT)'tot fl-E 'tO 1taptaxoµavo 'tWV aa !X'W'tO, 'ij: Ilepte.xov'tot 'CO ltOA\l 35% Vt'tpOXU't'totptV'Jj µa itaptexo­ µavo cx,w,ou it<ivw ot1t6 12,6% !lawpouv-rott we; ouaiac; -rric; K)..<iaawc; lot ( optot 1tapt8wpto 2101, 1 °) ri -r7Jc; K)..<ioawc; 4.1 (opot 7tept9wpto 2401 7° (ex).) 5. I!;woetc; ouoiac; 61twc;, auyxoAA1j'ttXCX, aµotyte., xpwµcx-rot, jUIXAiaµot-cot, ~epvixtot XIXt wptaµivcx XPWfl-lX'tlX oapµli-rwv XIXt • At8o1potcptwv (ROTOGRAVURES) µa a!;cxipaa'JJ -rot µiyµot-rot 7t0\J itaptE.XOUV Vt'tpOXU't'totptVT): ot) exov'tot ariµeio ,ea.we; Tj cxpxtxo ariµeio ,ea.we; e.wc; 35°0 C XIXt acp' oaov oav Ult<X'(OV'tlXt a-ro (I), ~) e.xov-rot ariµaio ,e.aawc; Tj cxpxtxo a'Jjµeio ,e.oawc; u1tap~oti­ vov -rouc; 35° C xott ecp' oaov Bev uit<i1ov,cxt a-ro (1), y) ecp' ooov 7tA1jpouv 'ttc; IXXOAou0ac; IXltlXt't'Yjaatc;: 1. O'tt Atyw-rapo IXltO "CO 3% 't'Jjc; a'tt~!Xooc; xcx8otpou OtlXAU­ 'tO\J otltoxwpi,a'tott a-criv ooxtµotciiot otltoxwptaµou OtlXA\l'tOV, 1/ Xott: 2. O'tt 'tO t!;woac; 1/ XIXt "CO a'Jjµaio otvotcpM!;awc; auµcpwvouv µa -cov cxxoAou!lo itivcxxcx: KtvTj'tlXO I!;woa, •V• ( a!;w1t0Atxo) ( aa ~IX0f1-0 axixaaw, 7tATJ­ alov ,ou 0) aa 23° C Xpovo, Po~, , OUfl-'!)WVIX f'-• 'tlX ISO 2431 - 1980 xo, aa XO't, LTJfl-· AvlX'!)Ai.!;.wi; OE °C 20 < v < BO 20 < , < 60 4 ltlXVW IX1t0 1 7 80 < V < 135 60 < 't < 100 4 10 135 < V < 220 20 < 't < 32 6 5 220 < V < 300 32 < 't < 44 6 -1 300 < V < 700 44 < 't < 100 6 -5 700 < V 100 < 't 6 -5 XIXl XIX'tW 6. Em~Aot~aic; ouaiac; xcxt 1totpotaxeu<iaµcx-rcx XPT)atµo1totou­ µavcx aotv 7totpotat'tOX'tOVot XIXl exov'tot a'Jjµelo otvotcpAe!;awc; l(<X'tW "CWV 21 ° C: ot) E.XOV'tlX a71µatO 'EaoWc; Tj otpxtl(() a71µatO ,eaawc; E.Wc; 35 C C, ~) exov-rot a71µaio ,eaawc; ri cxpxtxo a'Jjµaio ,e.aawc; lt<XVW Mo 35° C. 1/ ~oxtµotaiot cmoxwptaµou OtotAU"COU: H av AO'(W ooxtµotaiot Otavapyai-rott aa 23 ° C xp71atµo1totw­ V'totc; ~ot0µ0-roµ71µe.vo µa-rptxo XUALVOpo 'tWV 100 xa'tA. µa itwµot, auvoAtxou u4ouc; 1tapi1tou 2 5 ex. xcxt evtotioti; eaw-rept­ X'T}c; 6tcxµhpou 1tepi1tou 3 ex. a-co ~ot8µ0-roµ71µe.vo 't(J-Tj(J.IX -rou. H ouaiot !lot 1tpe.1tet VIX CXVIXOEU'tei wau \ICX IXltOX't'Yjaat oµot0 rav'i] aua-rcxari XIXt VIX xu8ei av-roc; "COU µa-rptxou XUA[vopou ewe; 't1jV xcxpoty'Tj 'tWV 100 xa-rL 0ot 1tpi1tat VIX atocxx!lai 'tO itwµot 1161 1162 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) XO(L O XUAlllOpoc;; \/IX 0tcpE8ei OE 71pEµi0t E7ti 24 wpec;;. ME't<X 24 wpEc;; 80t 1tpE1t£t \/IX µE'tp718Ei 'tO u<jioc;; 't7lc;; IX\IW'tEp0tc;; O'tt~<iooc;; OIX\I 7tOOOO't0 % 'tOIJ OU\IOAtXOU u<jiouc;; 'tOIJ Od-(µ0twc;;. 2/ flpoaOLOptaµoc;; L!;woouc;;: '01tou 71 ouai0t 1tou µ0tc;; IX7tlXa;(OAd IXll~XEt O'tlX µ71 Neu'tw 11tx<i ~ ci1tou oe11 Ei110tt 8u110t'to11 110t Ecp0tpµoa'tei µiSoooc;; 1tpoa­ owptaµou t!;woouc;; µE pociµa'tpo, 80t 1tpi1t£t \/IX xp71atµo1tot718d t!;wMµE'tpo µE'tlX~A7l'tOU ~0t8µou axaaewc;; "(tilt \/IX 1tpoaOLOpl­ ani O OU\l'tEAEO't~c;; OU\/Otµtxou t!;woouc;; 'tTjc;; ouai0tc;;, OE 23 ° C, OE 1XpXE'tO 1Xpt0µci ~0t8µw11 a;(<XOEWc;;, Ot A0tµ~0t11ciµanc;; nµic;; \/IX OU\IOUIXO'tOU\I µE 'tO\I ~0t8µ0 a;(<XOEWc;; XIXt Ell OIJIIEXELIX \/IX E!;W1tOAw8ou11 O'tO\I ~0t8µci axaaewc;; µ71oi11. 'tO 6u110tµtxci L!;w­ oac;; 7tO!J A0tµ~a11oµE XIX't' OtlJ'tO\I 'tO\I 'tp07tO, Ot0ttpouµa110 µe 't7III 7tUXIIO't7l'tlX, µ0tc;; OillEl 'tO 1tpocp0t11ic;; Xtll7l'ttXO L!;WOEc;; OE ~0t8µ0 axaaewc;; 7tA7IOLO\I 'tOIJ µ71oa11cic;;. · TIAP ATHPHtH: H 't0t!;llloµ~a71 OIJOLW\I XIXl 1t0tp0taXEIJIX­ aµa'tW\I 'tOIJ 7t1Xp011'tOc;; ap0pou ~IXOL,E'tlXl O'tlX Xpt't~pliX jllX E7tt· ~AIX~ELc;; ouaiac;; 't7lc;; u1to07Jµuwaawc;; 1/ 'tou 1tept8wpiou 2600 ( 1) XIXl 'tW\I 1t1Xp1X't7lp~aaw11 O'tlX ap0p. 71 - 88 'tOIJ 7tEpt0w ptOIJ 2601. . B. To!;txic;; ouaiec;; µE 07JµEio 0t110tcpAi!;ewc;; xa'tw 'tWII 21 ° TIAP A THPHLEit 1. To!;txic;; ouaiEc;; 1tou ixou11 071µEio 0t110tcpAi!;Ewc;; 0t1to 21 ° x0tt a11w, 'tO uopoxu0tlitxci o!;u x0tt 'tilt 0t0tAuµ0t't<X 'tOU we;; x0tt 'tilt µH0tMLX<X x0tp[,011uAL0t, Ei110tL ouaiec;; 't7lc;; KA<iaawc;; 6.1. 2. LXE'ttxa µe 'tilt xpt't~pl0t 'to!;txci't7l'tOc;;, [,AE7tE u1to07JµEi­ WOTJ 1/ O'tO 7tEpt0WplO 2600 (1). 3. Em[,A0t[,eic;; ouaiEc;; 1tou ixou11 07JµEio 0t110tcpAi!;Ewc;; X<X'tW IX7t0 21 ° C Ell/Ott ouaiEc;; 'tW\I ap8pw11 1 - 6 't7lc;; XA<Xaawc;; IXU­ ri\c;;, II. Nt'tpLALIX XIXL LOOllt'tplAtlX (taoxu0t11toux0t) ci1twc;;: 0t) IXXpUAO\ll'tpLALO, 'tpl'tO'tiXiEc;; tOOXIJIX\ILOUXO ~OIJ'tUAlO. [,) IXXE'tO\lt'tpiAto, [,ouwpo11t'tptALO, 2-xAwpo0txpuA011t'tpiA­ w, tao[,ou'tupo11t'tpiALo, µE80txpuA011t'tpiALO, m[,0tAO\lt'tpiALo, 1tp01ttC! ll!c'tPLAlO, 12. lµi11Ec;;, ci1twc;;: 0tt8u).011otµi1171, 1tpo1tuA£11otµi1171. TIAPATHPHtH: ft0t 'tLc;; ouaiEc;; Ot!J'tEc;; 0t1t0tt'tOUll'tlXt XIXL Ecp0tp­ µo,011't0tl ElOLXEc;; aw0~xac;; OIJOXEIJIXOllXc;; ([,AE7tE 7tEpt0wpLO 2303). 13. laoxUIX\ltXO OtL0UALO, lOOXUIX\ltXO µe0uAtO. TIAPATHPHtH: ft0t 'ttc;; ouaiec;; Otu'tic;; 0t1t0tL'tOUll'tlXL XIXt Ecp0tpµo,o\l'tlXl ElOLxic;; au118~xac;; OIJOXEIJIXOLIXc;; ([,AE7tE 7tEpt0w­ plO 2304). 14. 'AAA0t taoxu0t11tx<i, ci1twc;;: 0t) Tpt'tO't0t1ic;; taoxu0t11txci [,ou'tUALO, taoxu0t11txo µE0o!;uµa 0u)..w, tOOXIJIXVtX<X 1tp01tUAllX. [,) x0t11011txo taoxu0tvtxci [,ou'tUALo, taoxu0tvtxci tao[,ou'tuAto, 0t1XAuµ0t't0t Laoxu0t11txwv µE 071µaio 0t110tcpAi!;awc;; x<i'tw 0t1tci 21 ° C ('t0tl;t110µ. KA<XOEWc;; 6.1 7tEpt0wpto 2601, 18 XIXt 19). 15. Aot1tic;; OIJOLEc;; 7tEplixouaac;; a,W'tO, ci1twc;;: IX) IXMUA0tµi1171, l ,2-6tµE01JAUOp0t,!1171, [,) 1tupt6i1171. 16. AAo1011wµi11ac;; op10t11txic;; ouaia~, 01twc;;: at) [,pwµwuxo OtMUALO, XAWpocpopµtxci Ott0UALO, XAWpo­ (jlOpµtxci µE0UALO, x)..wpo1tpivto, XAwpwuxo, IXMUALO. [,) XAWpo0ELOcpopµtxci µe0UALO, l,2-0LXAwpo0tt8<i11LO (ot­ x Awpwuxo 1Xt8UAE\ll0 ), X AwpoµE8u).oµE8UAtXcic;; Otl8~p. 1 7. 01;u1ovwµi11ac;; op10tvtxic;; ouaiac;;, ci1twc;;: 0t) 0txpoAE°L1171, op801tupmxci µE0UAto ('tE'tp0tµE8o!;uat A<i1171) . [,) o!;etxci IXAAUALO, OtlXMUAtxcic;; 0tt8~p, µa80t11ci)..71 (µE0uAt x~).. 0thoci).71), µe80txpua't0tAOEiio71. 18. Op10t11txic;; ouaiEc;; 1tEptixouaEc;; 0Eio, ci1twc;;: IX} l008ELOXIJIXVtXO tao1tpo1tUALO, 6t8£t0uxoc;; cx11op0tx0tc;;, ~) 0tt81JALµEpx0t1t't<Xll7I, Ot0tt81JALXO OOUAcpiow, OtlXAUµOt'tlX tao8uoxu0t11wuxw11 µe 071µEio 0t110tcpAi!;Ewc;; xa'tw 'tWII 21 ° C ('t0t1;. KA<ia. 6.1 1tEpt8wpLO 2601, 20 ([,)). 19. 'E11'to110t 'tol;txic;; ~ 't01;txic;; ouaiEc;; XIXt 1t0tp0taxw<iaµ0t't0t xp71atµo1t0touµa110t OIXV 1t0tp0tat'tOX'tO\IIX XIXt EXOY'tlX 071µEio 0t110(cpAi1;Ewc;; xa'tw 'tWII 21 ° C. IX) µE 071µeio ,foawc;; ~ 0tpxtxci 071µdo 'EOEWc;; iwc;; 35 ° C. Xatt/~ EV'tOVIX 'tO/;LXEc;;, [,) µa 071µEio 'EOEwc;; ~ 0tpxtxci 071µEio ,foawc;; 1tEp0t11 'tWV 35 ° C x0tt 'tO!;txic;;. TIAP A THPHLElt: 1. H 't0tl;t110µ71071 OUOtWV XIXt OXEIJIXOµ<X'tW\I 'tOIJ ap0pou 19 (0t} ~ ([,} 80t 1tpi1tEt 110t [,0tai,a't0ttO't0t xpt-ri\pt0t 1t0t Ell'tO\IIX w!;t­ xic;; ~ w1;txic;; ouaiec;; 1tou 1tEptEXOll't0tt O'tTJII u1toa71µEiw07J 1 / 'tOIJ 1t£pt8wpiou 2600 (1) XIXt O'ttc;; 1t0tp0t't7jp~O£tc;; 'tW\I ap8pw11 71 - 88 'tOU 1tEpt8wpiou 2601. ~ 2. Em[,A0t[,~ 1tO(p0taxw<iaµ0t't0t. XIXt ouaiEc;; XP71atµo1totou 11't0tt OIXV 1t0tp0tOl'tOX'tOVIX XIXl ixouv 071µEio IXIIIX(f)AE1;Ewc;; X<X'tW 'tWII 21 ° C, ei110tL oua[ec;; 'tOU 6 ° (IX) ~ ([, ). 20. 'Ev'to110t 'to!;txic;; ~ 'tol;txic;; ouaiec;;, OL0tAuµ0t't0t, µi1µ0t't0t XIXt 1t0tp0taxw<iaµ0t't0t µa 071µEio 0tv0tcpAi!;Ewc;; x<i'tw 'tWII 21 ° C 7t01J 0£11 µ1topou11 VIX 't0t!;l110µ718ou11 OE illouc;; OUMOilXOUc;; 'tL'tAouc;;: . IX) µa 071µaio 'foEwc;; ~ IXPXLXO. 071µEio ,iaewc;; iwc;; 35. 0 xlXl/~ i11'to110t 'tol;txic;;. [,) µa 071µEio ,foawc;; ~ IXPXLXO 07Jµeio ,foawc;; 1tip0t11 'tWII 35 ° C XIXL 't01;txic;;. TIAP A THPHtH: H 't0tl;lllciµ7107J ouatWII, OtOtAUµ<X'tWII, µtjµ<X'tW\I XO(l 7t1XpO(OXWIXOµ<X'tW\I 'tOIJ ap0pou 20 (0t} ~ ([,) 80t [,0tat,E'tlXl O'tlX xpt't~pliX 7tOIJ E(j)O(pµo,011't1Xl jllX E\l'tO\IIX -co1;LXEc;; ~ w1;txic;; ouaiEc;; 1tou 1tEptixo11't0tt O't7III u1toa71µaiwa71 1 / 'tOU mpt0wpiou 2600 (1). r. 6t0t@pw'ttXEc;; ouaiec;; µE OT]µEio IXIIIXcpAi!;Ewc;; X<X'tW 'tW\I 21 ° c. TIAP A THPHtEit: 1. 6t0t[,pw'ttxic;; ouaiEc;; µE 071µEio 0t110tcpAi1;Ewc;; 21 ° C XIXL <X\IW XIXt wptaµi110t o1;LIIIX IXAiotO( µE 071µeio IX111XcpAE!;Ewc;; X<X'tW 'tW\I 'tW\I 21 ° C EL\IIXl ouaiac;; 't7lc;; KAaaEwc;; 8. 2. txrnxa µa 'tilt xel't~pliX OL0t[,pw0Ewc;; [,AE7tE u1toa71µai­ wa71 1/a'tO 7tEpt0wplO 2800 (1). 21. XAwpoaLA<XIILIX, ci1twc;;: IX) 6tµa0uAo-6txAwpo-aLA<X\llO, 0tL81JAO·'tplxAwpoatA<X\llO, µa8uAo-'tptx AwpoatA<X\llO, 'tptµE0uAo-x AwpoaLA<XlllO, ~l\lUA­ 'tptx AwpoatA<X\llO. TIAPATHPHtf{: XAwpoatA<XlltlX 1tou exAilou11 EUAEX'tlX 0ti­ pt0t OE E7t1Xcp~ µa 'tO 11Ep0 ~ µa urpo 0tip0t ELI/Ott ouaiac;; 't7lc;; KA<i­ aewc;; 4.3 XIXl OE\/ 1tpE1tEl \/IX ,1110\l'tlXl OEX'tEc;; jtO( µe'tOtcpopa 1t0tpii µ611011 IXV ElOtX!X OtVIXCj)EpOll'tlXl O'tTj\l XA!XOTJ IXU't~. • 22. Aµivec;; XIXL 'tO( Ot0tAuµ0t't<X 'tWV, ci1twc;;: . 0() l001tp01tUA0tµi1171, UOIX'ttX<X OllXAUµOt'tlX OLµE81JA0tµi1171c;;, 0tt8uA0tµiv71c;; ~ µE8uA0tµi1171c;; xatt 'tptµE8uA0tµi1171c;;, µE 071µEio ,iaawc;; iwc;; 35° C. [,) v-0tµuA0tµiv71, 11-[,ou't1JA0tµiv71, OL1XAu0tµi1171, Ot0tt8uA0t­ µi1171, 6t·iao1tpo1tuA0tµiv71, otµE8uAo-N-1tpo1tuA0tµi1171, tao[,ou­ 't1JA0tµi1171, v-1tpo1tuA0tµi1171, 1tup0At6iv71, 'tpt0tt8uA0tµiv71, uo0t­ 'ttx<i OlOLAUµOt'tOt otµa8uA0tµi1171c;;, 0t(8uA0tµiv71c;;, µE81JA0tµi1171c;; XIXL 'tptµE8uA0tµi1171c;;, µE 071µEio ,eaEwc;; 1tip0t11 'tWII 35 ° C. TIAPATHPHtH: H <ivuop71 OLµE81JA0tµi1171, iitffuA0tµi1171, µElluA0tµiv71 x0tt 'tptµElluA0tµiv71 Ei110tL ouaiEc;; 't7lc;; KA<iaEwc;; 2 ([,AE7tE 7tEpt8wpw 2201, 3 ([, 't)). 23. AhuAuOp0t,ivEc;;, c'mwc;;: IX} 1 ,l-otµEllUAUOp0t01171, µElluAuop0t,i1171. 24. 6t0tAuµ0t'tlX IXAXOOALXW\I, ci1twc;;: 0t} XAwpoµupµ71xtxci Lao1tpo1tilALo, twowuxou IXMUAto. [,) XAWptouxo OtXE'tUALO, XAWpwuxo, 1tp01tUAlO ... 26. 'Ev'tOIIOt 6t0t[,pw'ttxic;; ~ Ot0t[,pwnxic;; ouaiec;;, 6t0tAi.i­ µ0t't0t, µi1µ0t't0t ~ 1t0tp0taxwiiaµ0t't0t µE 07JµEio 0t110tcpAi1;ewc;; X<X'tW 'tW\I 21 ° C ltOIJ OE\/ µ1topouv VIX 't0tl;llloµ718ouv 0£ ill71 OUAAOjlX~ XIX'tTjjOpi0t: 0t) µE 071µeio ,foEwc;; ~ 0tpxtxci 071µdo ,foawc;; iwc;; 35 ° C x0tt/~ Ell'tOIIIX 6t0t[,pw'ttxic;;. [,) µE 071µEio ,foawc;; ~ 0tpxtxci 071µEio ,foawc;; 1tip0t11 'tWV 3 5 ° C XIXL Ot0t[,pw-ctxic;;. TIAPATHPHtH: H 't0tl;tvciµ7107J ouatw11, OtOtAuµa'twv, µt,µ<X'tW\I ~ 1t0tp0taXW0taµ<X'tWV X<X'tW IX7t0 'tO <ip8po 26 ° (0t} ~ ([,) 80t ~0tai,E't0tl O'tlX xpt't~plat 1tou La;(i.iouv 1t0t i11'tov0t OtlX­ [,pw'ttxic;; XIXL OL0t~pW'tLxic;; ouaiac;; 1tou 1teptixo11't0tt O't7III u1to 07Jµaiwa71 1/ 'tou 1tapt8wpiou 2800 (1). 6. M 't01;txic;; x0tt OLIX W'ttxic;; ouaiEc;;, £ a !;awe;; µE'tOt/;U 2 XIXt 1 0 TIAPATHPHtH: M71 w1;txic;; XOtt µ71 Ot0t~pw'ttxic;; ouaiec;; OE Ot1XAuµ0t'tlX XIXt oµotOjEII~ µi,µ0t'tlX 7t01J EXOU\I 07Jµeio IX\/Ot• . cp)..i1;awc;; 21 ° C XOtt <X\IW (cmwc;; wptaµi110t xpwµ0t't1X ~ [,Epvi­ XtlX, 1tA7111 'tWII ouatwv 1tou 1tEptixou11 11t'tpoxun0tpi1171}, oa11 80t EQ>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) u1tOX!IV't0t1 cmc; 0t1t0tl't1Jcmc; 't'fjc; ADR 0t11, O'tTjV 6ox1µ0toi0t 0t1toxwp1oµou 6uxAU'tOU 7t0U 7tEp1jp1X(j)E'tlXI O'tTjll U7tOOTjµEiwOTj 1 / O'tO dtpllpo 5, 'tO 1tdtxoc; 'tTjc; 0t1toxwp1oµe.v'fjc; O'tl~dt6oc; 610t­ A1J'tOU Ei110t1 AljW'tEpo IX7t0 't6 3% 'tOU OUIIOAIXOU u4>ouc;, XIXl IXII Ol ouoiac; OE 23 ° C ixouv, (o'tO XU7t!AAO poTjc; 'tO ouµµopcpo 1tpoc; -.o ISO 2431 - 1980 µa 1ti60tx0t 610tµhpou 6 XO't.), "f.20110 poTjc;: 0t) 'tOUAIXXLO'tOV 60 6Eunp0Am't0t, T) ~) 'tOUAIXXIO'tOV 40 6).. XIXL µE 1tEp1ExoµEvo 'tO 7tOAU 60% OUOIWII 'tTjc; XAIXOEWc; 3. 31. OuoiEc; 7tOU e.xouv 07JµEio IXIIIX(j)AE!;ewc; !J-E't0t!;u 21 ° C XIXI 55 ° C. i) wp1oµi110t 1tE'tpEA0tl0t XIXL ill0t opux-.dt iA0tL0t, 'fj!J-l~0tpi0t 1tpo'ioll't0t IX7tOO'tlX!;Ewc; 7tE'tpEAIXtOU TJ IXMWII ~0tpiw11 EAIXLWII (1tioo0tc; jlXIIXVllp0txoc;, AljllL'tTj CJXIO'tOAillou, !;uAOU TJ 'tupcp'fjc;), 01twc;: X7Jpo0v'fjc;, 1tE'tpEA0tiou, 11iicpll0tc; 8LOtAu'tou, AEUXou 1t11Euµ0t­ 'toc; ( u1toX0t't0tO'tlX'tOU upE~1111li1111c;). Y6porovdtvllp0tXEc;, 01twc;: . CUMENE (1001tpo1tuAo~Ev~i1110), CYMENES (µElluAo'ioo 1tpo1tuA1x1X ~Ell~EIIIIX}, N-DECANE, 6txUXA0-1tEll't1X61i1110, Otl 8uAl~E\l~ElllO, x11µ1xwc; x0tll0tpo !J-EOl'tUAEVlO (1, 3, 5-'tp1µEll­ UAO~Ev~i1110), NONANE, 7tEll'tlX!J-ElluAoE7t'tlXIIIO (1006w6exii 11to), o'tupi1110 (~1wA-~Ev~i1110) npE~LVllillTJ, µ-!;u).i1110 (l,3 8LµEllu).o~E11~i1110), O-!;uAe.1110 (l,2-61µelluA-~Ev~e.1110), p-!;uA­ i1110 (l,4-01µElluAo~ev~i1110). AAoyovwµa11ec; ouoiec;, 01twc;: XAwpo~Ell~ElllO (x Awptouxo (j)OtLIIUAIO ), 61x AWp01tEll'tlXIIIIX, 1,3-oix ).wpo1tpo1tdt1110t. AAxooAec;, 01twc;: N-0tµu). 0tAxociA1J, SEC-0tµuA-0thooATJ, µelluA00tµu). wo­ OATJ (µelluAo 1oo~ou'tuA1XT) x0tp~111ciAlJ), ~ou't0t11ciAlJ (11-~0U'tUA IXAXOOATJ), \l~~OU't0t\lOATJ•2 (SEC-~OU'tUA IXAXOOA'IJ), XUXA07tE· 11't0t11ciA1J, 010tXE'tOVtXTJ OtAxociATJ, X'IJ!J-lxwc; x0tll0tpTJ, 2-0t11lo!; 00t11l0tvciATJ ( 0t11luAE110-r ).uxoA1xcic; µ01100t11luA1xcic;; 0t11l1jp ), 100 ~ou't0t110A'fj ( 1oo~ou'tuA1xij wociATJ), µEllo!;u-0t11l0t110A'fj 11-1tpo1t0t110A7J, uOOt'tLXIX 011XAuµ0t't0t 0t1lluALXTjc; IXAXOOA'fjc;; OE ou­ µ1tuxvw01j IX7t0 24% iwc; XIXI 70%. TIAP ATHPHiH: 1°8ix't1xdt 611XAuµ0t't0t 0t11luA1x1Jc;; OtAxoci­ ATJc; OE ouµ1tux11~011 µ1xpoup11 IX7tO, 24% OEII U7tOXEIV't0tl O'tlc; 8L0t'tlX!;ELc; 'tOU ADR. A11lipec;;, ciitwc;: 1,2 010t18o!;u0t11lii11LO ( 0t1llt>AEIIO-y AUXOALXoc; 8L0t18u).1xoc; Otl­ llijp ), 01-11-~ou-.uA1xcic; 0t11l1jp (11-~0U'tt.1A1xci<; 0tlll1jp ), Moo 0tµuA1xcic; 0tlll1jp, cp0t1wAµelluA1xoc; 0t11l1jp (0t11100A7J), AA6Eii6Ec;;, ci1twc;: 2-0tlllt>AIXTJ E!;0tA6Eii67J, E!;OtAOEii6'1j, 1t0tp0tA6Eii67J. KE'to11Ec;;, ci1tw<;: XUXAOE!;IXIIOIIT), XUXA07tEll'tlX\IOIIT), 01'ioo~OU'tUAO-XE'tOll'fj, o!;Eio10 (-LEOl'tuAiou. Eo'tipEc;, ci1twc;;: . O!;EIXO aµuAIO, o!;EIXO 11-~0U'tUAlO, OtlllUAEIIOjAUXOALXOc; µovoµellu).1xcic; 0t11lijp (o!;uxcic;;), o!;E1xcic; a.1lluAE110-1AuxoA1xcic; µ01100t11lu).1xo<; 0t11lijp, o!;uxci 2-0t1llo0t11luAIO (o!;EIXO<; Ottllt>AE 110-r AUXOAIXOc; µ01100t11lu).cxci<; 0t11lijp ), o!;e1xci 2-0t1lluAO~OU't 1JALO, aµ1:>.o!;e1xci µEllu:>.co, 0txpu:>.cxo 11-~ou'tuA10, ~ouwpcxci 0t11l1JALO, µupµT)XIXO 1000tµuALO, jlXAIXX'ttXO OttlluAtO, cpwocpo­ pouxo 'tp10ttlluALO, cpwocpopouxo 'tpLµellu).10, 1tupt'tlXO 'tE'tp0t 0t1lluALO, A,w'touxac; ouoiE<;, 01twc;: 01µellu:>.1xTJ 0t11l0t110A0tµi117J (01µelluAo-0tµ11100t11l0tvciATJ), µop­ cp0Ai1111, 111'tp1xci 0tµuALO, Vt'tpoµelliivto 111'tpo1tpo1tet1110t, PICO­ LINES (µellu:>.01tup16ivac;). 32. OuoiEc; µe O'fj!J-Eio 0t110tcp:>.i!;Ewc; 1tdtvw 0t1tci 55 ° C iwc; XIXI 100° C. r) Op1oµi110t 7tE'tpE~IXIIX XIXI IXMIX opUX'tlX EAIXlOt, ~0tpa0t 1tpo'io11't0t IX7tOO'tlX!;Ewc;; 7tE'tpEAIXtOU TJ illwv opt>X'tWII EAOttWII, wp1oµi110t 0tEp1e.A0tl0t, wp1oµi11Ec; 7ttOoEc; XIXI 'tlX 1tpo'io11't0t Ot7tO­ O'tlX!;twc;; 'tWII, EAIXIIX llapµetvoEwc;;, EAOtllX ll'tTj~EA. Y6poro111Xvllp0txEc;;, ci1twc;: • OEX0tiiopo110tcpll1XAi1111 (oEXOtAtllTj), 011XL1lUAO~E\1~£\IIOt, 'tE'tp0tii­ opo110tcpll1XAi117J, EIIOEXIXIIIO. O!;urovwµe.vEc; ouoiec;, OltW<;: o!;e1xci xuxAoE!;uALO, 8L-1oo~ou'tuA1xij x0tp~1110ATJ (2,6 61µe8u).o E1t't0t110A'fj), cpoupcpouµiiA (cpoupcpoup1XA6eiio11), e!;a.­ voAEc;. AAo1ovwµe.vEc;; ouoiEc;, ci1twc;: 2-0t11luA-E!;u:>.-x:>.wpi610. ACw'touxec; ouoiEc;;, ci1twc;: N,N-01µellu:>.o-cpopµ0tµio1j. . 33. r) Mij!J-Ot'tlX OUOIWII 'tOU 31 (r) 1tEp1e.xo11't0t 'tO ltOAU 55% lll'tpOXU't'tp[1111 !J-E 1tEp1exoµE110 IX~W'tO 'tO ltOAU iwc; 12.6% (8i1XAuµ0t't0t xoUo6iwv, 11µ1x0Uo6iw11, ill0t 011XAu­ µ0t't0t lll'tpoxU't't1Xpi1111c; XIXI ~a.cpic; lll'tpOXU't't0tpi117Jc;, ~Epvix10t XIXI AIXXXEc;. TIAP ATHPHiH: Miyµ0t't1X 1tEp1axo11't0t 7tEp1000'tEpo OtltO 55% lll'tpOXU't'tOtp[vTj, µE 07tOI06TjTCO'tE 7tEp1EX,oµevo Ot~W'tOU TJ 1tEp1e.xo11't0t rcep1oocinp11 OtltO 55% lll'tpOXU't't0tpi1111 µE 1tep1e­ xoµE110 IX~W'tO ltlXIIW OtltO 12,5 %, El\llXI ouoiec; 'tTjc; KAetoE-wc; let (~Ae.m 1tep1llwp10 2101, 1 °) TJ 'tTJc; K).dtoEwc; 4.1 (~Ai1te 1tEp11lwp10 2401, 7 (0t)). 34. r) Mt1µ0t'tlX 'twv ouo1w11 'tou 32 (r) 1tEp1e.xoll't0t 'to ltOA\J 55% 111'tpOXU't't1XplllTJ !J-E ltEplEXOfJ-EIIO IX~W'tO 'tO ltOA\J 12,6% (6uxMµ0t't0t xoUo6iwv, 11µ1x0Uo6iw11, ltATjV 'tWV 611XAuµct'tWII lll'tpOXIJ't'tOtpivTjc; XIXl 'tWII "f.2W!J-IX'tWII 111'tpOXU't­ 't1Xpt11Tjc;, ~E-plltXIIX XIXI AIXXXEc;.) • TIAPATHPHiH: Mi-yµ0t't0t 7tE-p1EX,Oll't0t TCAEOII 'tOU 55% lll'tpOXU't't0tpi111j, fJ-f- 07tOL06Tj7tO'tE 1CEp1E-XOfJ-EIIO Ot~W'tOIJ, Tj ltE­ p1e.xo11't0t 'tO ltOAU 55 % lll'tpOXU't't0tpi1111 µe 7tEp1EX,O!J-EIIO IX~W'tO rccivw ixrco 12.6%, ei110t1 ouoiec; 'tTj<; K:>.dtoewc; lix (~Ai1tE rcep1 llwp10 2101, 1) 1l 'tTjc; K).dtoawc; 4.1 (~Ai1te 1tE-p11lwp10 2401, 7 (ix)). • Keve.c; ouoxeuixoiec; 41. Kevic; ouoxeuaoiec;, XEVIX ~t>'t1ocpcip0t OX,TjfJ-Ot'tlX, xevic; IX7tOOUV6eciµEvEc; 6e!;ixµe:ve.c; XIXl XEIIIX eµ1topeuµ0t'tOXl~W'tllX 6e!;0tµEvw11, ixxixlldtpto'tOt, 1tou mp1Eixix11 ouoiEc; 'tTJ<; KAcioewc; 3. OuoiEc; 'tWV 1 - 6, 21 ::- 26, x0t1 31 - 3 4 fJ-E'tlX(j)EpciµevEc; ouµcpwvOt µE 'ttc; IXXOAOUllEc; OIIX'tct!;Et<; 6ev UltOXElll'tlXl OU'tE O'tl<; 610t'tct!;Et<; 'tTj<; 1t0tpouo11c; K:>.iioewc; ltOU mp1ixo11't0tl O'tO 1t0tpci11 : Tirtpdtpn1µ0t, ouu O'tl<; 610t't0t!;E1c; 1tou 1tEp1ix.011't1Xt o'to TI0tpdtp­ 'tTj!J-IX B: 1) ix) Ouoiec; 't0t!;111oµouµe11Ec; O'tTJV 1t0tpdtjp. a) xdtlle dtp llpou: . To 1t0Au 500 X,O'tA. OE xdtlle Eownp1xri ouoxEu0toiix XIXL 'to ltOAU 1 ).i'tpo XIX'tOt OUOXEUIXOllX (xoAOII ). . ~) Ouoiec; 't0t!;111oµouµEvac; O'tTJV ~) xdtlla iipllpou: . 'tO ltOA\J 3 Ahp0t XIX'tlX EOW'tEplXTj OUOXEIJIXOtlX XOtl 'tO ltOA\J 6 At'tplX XIX'tlX OUOXEUIXOllX (xoAov). r) OuoiEc; 't0t!;111oµouµevec; O'tTjll (r) xdtlle etpllpou: . 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Mtx't~ Luoxauexoiex 1) Ouoiac; XCXAU7t'tOf.lEVEc; ex1to 'tO ioto iXp0po f.l7tOpouv vex ou­ OXEU(X~O\l'text 1-1ex~i OE ou1101exo1-10 ouoxEuexoiexc;, ou1-1q:,w11ex f.lE 'tO 1tEpt8wpto. 3538. 2) Ouoiac; ◊tex<popwv iXp0pwv 't7lc; KAiioEwc; 3 OE 1tOOO't7j'tEc; 1-171 u1tEp~exivouoEc; 'tex 1tE\l'tE Ai'tpex xex'tii ouoxEuexoiex, 1-11topou11 vex ouoxwiX,011,ext 1-1ex,i xext/11 f.lE Ef.l7tOpEUf.lex'tex 1tou OE\I u1to­ XEtv'text O'ttc; ◊tex'tii!;atc; 'tOU AD R, OE ouvouexo1-1i1171 ouoxauexoiex OUf.l<pWvex f.lE 'tO 1tEpt8wpt0 3538, f.lE 't7I\I 1tpoii1to8E07I O'tt'OE\I 0'ex exvnopouv E7tLXL\10U\lex f.lE'tex!;u 'tW\I. 3) OuoiEc; 't7lc; KAiioawc; 3, OE 1tooo't7l'tEc; 1tou OEV U7tEp~exi­ vouv 'tex 1ti11n Ai'tpex xex'tii ouoxEuexoiex, f.l7tOpouv vex ouoxwiX­ ,ov'text oE ou11ouexo1-1i1171 ouoxEuexoiex, f.l1topou11 vex ouoxwiX,o­ \l'text OE OU\IOUexOf.lE\17I OUOXEUexoiex OUf.l<pWll7I f.lE 'tO 1tEpt0wpto 3538 f.lE ouoiEc; 11 1tpiX1 f.tex'tex iXUwv xAiioEwv, f.lE 't7IV 1tpoii 1to8Eo71 o'tt Em'tpe1tE'text a1ti07jc; 71 fLLX't11 ouoxEuexoiex 1 tex ouoiEc; 11 1tpiX,f.lex'tex 'tW\I XAiioEW\I, f.lE 't'1j\l 1tpoii1to8E07j O'tl E7tt'tpE7tE· 'text mio71c; 71 f.lLX't11 ouoxEuexoiex 1 tex ouoiac; 11 1tpiX11-1ex,ex 'tW\I xAiioEw\l exu'twv, xext/1) f.lE Ef.t1tOpEuf.tex'tex 1tou OE\I u1toxEtv'text O'ttc; Otex,ii!;Etc; 'tOU AD R, f.lE 't7I\I . 1tpoii1to8E07I O'tl OE\/ ex\l'tl· opouv Emxi116u11ex f.lE'tex!;u 'tW\I, EX'tO<; ex\l xex'tW'tEpw 1tpo~AE7tE· 'text X<X'tl Otex<popE'tlXO. 4) Eexv E7tLXLVOU\IEc; ex\l'ttOpiioEtc; 0Ewpou\l'text ot exxoAOU 0Ec;: ex) xexuo71 xext/11 iXAuo71 0711-1ex11'ttx11c; 8Epf.lO't7l'texc;, ~) ixAuo71 EU<pAEX'tW\I xext/11 'to!;txwv exEpiwv, r) ox.711-1ex'tlOfLOc; Otex~pW'tlXW\I uypwv, o) OX,7lf.lex'tlOfLOc; exo'texSwv OUOlW\I. 5) H f.llX'tT) ouoxwexoiex o!;ivwv ouotwv f.lE ~exotxic; ouoiEc; OE f.llex ouoxwexoiex OE\/ 1tpi1tEt vex Em'tpe1tE'text exv ot ouo exu,ic; ouoiac; El\lCXl OUOXEUexOfLEVEc; OE EuSpexuo'tex oox Eiex. 6) Ot otex'tii!;Etc; ,wv 1tEptSwpiwv 2001 (7) 2002 (6) xext 2302 Sex 1tpi1tEt vex 't7lpOU\l'tCXl. 7) Av X,P7IOlf.l07tOlOU\l'text Xl~W'ttex ex1t6 !;uAo 71 f.lOptooexvioex, xiXSE XOAO\I OE\I 1tpE1tEL vex ,uri'EL 7tAEO\I 'tW\I 100 XlAW\I. fao,xoi 'OpOL Ap. tip8p. 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TiiXv,wc;, exv wptOfLEVEc; ouoiac; Eivext ou­ oxEuexo1-1evEc; oa ouv0a,ac; ouoxaexoiac; (1 texAi, 1topoaAiX1171111tu­ pi1-1exx.o) OUf.t<pWVex f.lE 'tO 7tEptSwpto 3539 7tEptEX,Of.lE\IOU 7t(XVW ex1t6 7tEV'tE Ahpex, ot ouoxiuexoiac; Sex 1tpE1tEt vex <pipouv ouo E'tt· XE't'tEc; Otlf.l<pWVEc; f.lE 'tO U7t00El1f.lex No 3 (~AE7tE mptSwpto 3901 (2)). 2) Luoxwexoiac; 1tap1ex ouoac; ouoiac; 'tou iXp0p. 6 0ex 1tpE1tEt E1ti 1tAiov vex <pipouv E,txinex ou1-1q:,wv71 f.lE 'to U7tOOEt1 f.lex No 6. lA. "OoEc; 7tEptEX,OU\I ouoiac; 'tOU 11-20 fLLiX E'tlXE't'tex Otlf.l· <pwvex f.lE 'tO U7t00El1f.lex 6.1 xext ooac; 7tEptEX,OU\I ouoiac; 'tW\I iipSp. 21 -26 f.lLex E'tLXE"t'tex Otlf.l(()W\17I f.lE 'tO U7t00El1 f.lex No 8. 2310 2311 2312 3) KoAex 1tap1ex o11'tex ouoxEuexoiEc; Eu0pexua<tac; 1tou OEV q:,exi 11011'text ex1t' e!;w, 0ex 1tpe1tat vex <pipouv oa Mo ex1tevexv'tt 7tAEupic; am1pex<p11 ou1-1q:,w1171 f.lE 'tO u1t6oa11 1-1ex No 12. 4. KoAex 1tap1ex o11'tex ouoxwexoiac; 'tWV 01toiwv 'tex XAEtoi­ f.lex'tex OE\/ q:,exivov,ext ex1t' i!;w xext xoAex 7t0U 1tEptixouv exapt,6 f.lEVEc; ouoxwexoiac;, 11 exapt,Of.lEIIE<; ouoxauexoiac; x wpic; E!;wn­ ptxo 1tapi~A71f.lex, 0ex 1tpi1tEt vex q:,ipouv oa Mo ex1ti11ex11'tt 7tAEU· pie; E'ttxinex ou1-1q:,wv71 f.lE 'to u1t6oat1 f.tex No 11. B. L'tOl)(Eiex 'tOU anpiXcpou µnexcpopiXc; 1) H 7tEpt1pex<p11 'tW\I Ef.l1tOpEUf.l(X'tW\I O'tO enpex<po f.lE'tex<pO· pile; 1tpE1tEL vex OUf.t<pWIIEi f.lE E\lex ex1to 'tex O\IOf.lex'tex 1t0U EL\lext U1toypexf.tf.llOf.lE\lex O'tO mpt0wpto 2301. Av 71 ouoiex OE\/ exvex<pipnext f.lE ,o 61101-1iX 't7lc;, 0ex 1tpi1tat vex 1piX<pE'text 'to X.71f.llXO 't7lc; 6vo1-1ex, ftex ouoiEc; xext 1texpexoxauiX­ Of.lex'tex 'tW\I iXpSp. 6 xext 19, 'tO 0\/0f.lex exu'to 0ex exvexypiX<pE'text ' 1 tex 'tO 1tAfo11 Emxivouvo ouo'texnxo, 'tooo 1 tex 'to 1texpexot'tO· X't0\10 O'tOlX,ELO 1/ooo Xext 1 tex 'tO EU<pAEX'tO O'tOlX,ELO (1t.x . 1tex­ pex8Eio oE E!;iivto ). H 1tEpt1pex<p11 'tW\I Ef.l7tOpEUf.lli'tW\I 1tpi1tat vex u1toypexµµi,E,ext xext vex exxoAou0ai'text ex1to O'tOtX,Eiex 't'1jc; XAii­ oEwc;, 'tO\I expt0. iXp0pou (1-1ex,i f.lE -co wx ov 1 pilf.lf.lex) xext 'tex exp­ x.1xiX «ADR» (11· «RID», 1t.x .: 3, 14 (ex), ADR. • 2) ftex <pop,iex X.71f.llXWc; exo'tex0wv OUOLW\I, 0 ex7tOO't<.>Aicxc; 1tpE1tEL vex 7tLO't07tOtEi O'tO enpex<po f.lE'tex<popiXc;: «EA11<p871oex11 2313 2314 f.thpex Otlf.l(()W\lex f.lE 'tO 7tEptSwpto 2300(6)». r. KEvic; ouoxEuexoiEc; 2315 - 2321 1) Kavic; ouoxauexoiac;, exxex0iXpto'tEc;, 'tOU 41 0ex 1tpi1tat vex ai­ vext XAElOf.lE\IEc; f.lE 'tO\I ioto 'tp07t0 xext f.lE 'tO\I ioto ~ex81-10 onrex­ \lO't7l'tOc; oexv vex 11oexv ra1-1iXnc;. 2) Kavec; ouoxEuexoiEc;, exxex0iXpto'tEc;, 'tou 41 0ex <pipouv 'ttc; iotEc; E'ttXE't'tEc; xtvMvou, oexv vex 11oexv 1Ef.lli'tEc;. 3) H 1tEptypexq:,11 O'tO inpexq:,o f.lE'tex<popiXc; 0ex 1tpE1tEL vex 2322 OUf.l<pWVEi f.lE EVex ex1tO 'tex 0\/0f.lex'tex 1tOU EL\lext U7t01 pexf.tf.llOP,EVex o,o iXp0po 41, 1t.x .: KEv11 ouoxEuexo[ex, 3, 41 ADR. H 1taptypexcp~ exu't~ 0ex 1tpi 1tEL vex u1toypexµµl,E,ext. LE 1tEpt1t'tW07l XE\IW\I OE!;exf.lEIIO<popwv ox.711-1ii'tW\I, XE\IW\I ' 1 • ex1tOOU\IOEOfLEVW\I OE!;exf.lE\IW\I xext .XE\IW\I oa!;exf.lEVW\I/E'µ'1top- • EUf.lex'tOxt~w,iwv, exxex0explo,wv, 71 1tEpt1pexq:,11 exutj 0ex ou­ f.t1tA71pw11E,CXL f.lE 't'1jV 1tpoo811x71 'tW\I Ai!;Ewv: «TEAEU'texio q:,op'tio» 1-1ex,i f.lE 'to 6vo1-1ex xext ,011 expt0. iXp0pou 'tW\I Ef.l7t0pEUf.lli'tW\I 7tOU <pop'tw871xexv 'tEAEU'texiex, 7t.x . TeAEU­ 'tex[o cpop,lo: BEv,iv~ 3 ° (@) YTIOEHMEim; : 2323 - 2399 1/ ftex 't7IV mpt1pex<p11 'tOU 1texpexot'tOX'tovou O'tQtX,Eiou, 'tO 01101-1ex Ot>f.l<pwvex f.lE -co Tip6w1to ISO R.1/50-1981 (~AE1tE E1tio11c; 7tEptSwpto 2601, 71 ewe; 88) 0ex 1tpE1tEl vex X,P7IOlf.lO· 7t0t1jSEi, exv exvexq:,epE'tCXl o' exu,6. KAiX0071 4.1. - EY<l>AEKT A LTEPEA II. Kex,iXAoyoc; uAwv ME'tex!;u 'tW\I UAW\/ 'tW\I xexAU7t't0f.lE\IW\I U7t0 'tO\I 'tl'tAO\I KAIX071 4. l, Ol exvexypex<pOfLEVE<; O'tO 7tEptSwpto 2401 U7tOXEl· \/'text o,tc; otex,ii!;Etc; 'tOU ?texpov'tOc; Tiexpexptjf.lex'toc; xext 'tOU Tiex­ pexp't11f.lex,oc; B. O, t>AEc; 1tou 1 ivo\l'text OEX'tE<; 1 tex fLE,ex<popiX U7t0 wp,oµivou opouc; Sex Sawpou\l'text we; tlAEc; 't7lc; ADR. • 1.0 ·nEc; m · 01toiac; f.l7tOpouv EUXOAex vex exvex<pAqouv ex1t6 omvS11pac;, 61twc; !;uAiiAwpo, 1tpto11iot, poxexviotex, !;71p11 ivex ( o'to !;uAo ), !;uAiivSpexxexc;, 1tCXA716x exp'tex xext iXx p71o'tex x exp'ttii, !;uAoxunexpiv71, x exp,o-ivex, xexAiXf.ttex ( EX'toc; 01tiip'tou ), ex1pto­ xiXAexf.lO, oexvoc;, iix upo, xex0wc; xext O'tex\l uypic; ( OUf.t7tEptAex1-1 ~exvOf.lE\IW\I 'tOU xexAexf.t7t0XlOU, pu,,ou, xext Atvexptou ), <pU'ttxec; u<piXVatfLE<; UAEc; xext U7tOAELf.lf.lex'tex <punxwv uq:,exvoifLW\I UAW\/, <pEAAoc; OE ox.111-1ex x61171c; 11 xoxxwv, EX'tex0Elc; 11 OX,l, f.lE't(X 11 iXvw 1tpoo1-1i!;awc; 'tUp<p1jc; (1tiooexc;) 11 iXUwv uAwv f.l'YJ U7tOXEt­ f.lEVWV oa o,t1 f.ttexiexv o!;aiowo71, xext u1toAELf.lf.lex'tex <pEAAou OE f.lLXpouc; ~wAouc;. BAi1tE E1tio71c; KAiXot\l 4.2, 1tEpt8wpto11 2431, 8 ° - 10°' xext 7tEptSwpto 243 lex, U7t0 O'tOlX,ELO\I (~). L7lf1Elwotc;: 1. Ot UAEc; exu,ic; OUf.t1tEptAexf.t~iX110\l'text o,ov xex,iXAo1o 1-1ovo 1 tex A61ouc; ex1tex1opEuoEwc; f.lLX't11c; <pop'tw­ OEwc;. ftex ,ov oxo1t611 exu,ov ot otex'tii!;Etc; 'tou 1tEptSwpiou 2416(1) Lax uouv. Kexvivex illo apSpo, El'tE 'tOU 1texpov'toc; Tiexpexp't11f.lex'toc; El'tE 'tOU Tiexpexp't11f.lex'toc; B, EX,El rt' exu'tec; E<pexpf.l0i11· • 2. 0 oexvoc; o 01toioc; E!;exxoAou0Ei vex ix Et ~exS1-16v u1pexoiexc; 2400 2401 1166 ECl>HMEPlr THr KYBEPNHIEOr (TEYXOr aEYTEPO) 0 OltOtoc; ELV(Xl EV6EXOfl-EVO \l(X 0671yiJaEl OE ,u1-1-wa71 6ev TlllE'tOCl 6EX't0<; )'lOC fl-E'tOCcpopa.. 3. IIEpmiALTfl-OC'ta xal ltA<X.xEc; (cp~Ua) EX'ta8i11'toc; cpEMoti, ;c~-raaxw.a~l-'-i11a u1to.1tiEa71, fl-E't<X. T) a11w 1tpoa1-1-i~Ewc; 'ttipcp71c; (maaac;) 71 aUw11 uAw11 l-'-71 UltOXElfl-EIIW\I El<; a'tlTfl-lOCia11 o~Et 6wa71, ae ouoeµ1a 'tW\I 6lOC't<X.~EW\I 't71c; ADR UltOXEl\l't(Xl, 4. <l>EMoc; Efl-ltAOU'tlOfl-£110<; fl-E UAEc; ltOU E~OCXOAou8oti11 Y(X UltOXElll'tOCl aE a'tL)'fl-lOCta o~E16wa71 Et\lOCl ti).71 't71c; IO.dtaEwc; 4.2 (~AEltE 7tEpl8wpw 2431, 9 ° ). • 2 ° (a) 0Eio11 (aufl-1tEplAOCfl-~0tvo1-1-ivw11 'tw11 a118iw11 8e1ou)· (~) 0E1011 OE 'tE't71Tfl-E1171 XOC'tlXO'tOCa71. 3 ° KEMot611171, 1tapocro1-1-i1171 OC7t0 OC'tEAT) E~IX'tfl-l071 't71c; OCA­ XOOATjc; 't71c; mplE;(Ofl-EY71c; OE x0Uo6w11 XOCl OCltO'tEAOUfJ-!1171 xu p1wc; aito x0Uo6w~ii1-1-~axa. . 4 ° Ku't'tapl1101'o71 ( aoUouoi6) ae itAiixEc;, cptiUa, pii~6ouc; T) OWAT)IIE<;, XOCl ucpiia1-1-a'ta emxplOfl-E\l(X fl-E \IL'tpOXU't'tOCpt 117111. 5 ° KuHapwoT671 Tal111w11, 't.E. 71 1tpW't'1) ti).71 )'lOC 'tOCl\lt£c; (cplAfl-), xwp1~ Efl-OUAai1171 (raAOCX'tW6Ec; fl-LTfl-OC), O! poUouc;, XOCl Efl-cpOC11la8E11'ta cpLAfJ- EX XU't't0Cpl1101'o1jc;, 6 ° Y ltOAElfl-fl-OC'tOC Ku't'tapo1101'o71c; • XOCl • UltOA!Lfl-fl-OC'tOC cpLAfl xu't'tapwot671c;. . :E71fJ-ELWalc;: Ta UltOAELfl-fl-OC'tOC \ll'tpoxu't'tapi1171c;, a1t71Aay1-1-i11a Mo ,EAa,11171, ae 1t7111ia, cptiUa T) Awp16Ec;, et\lOCl ti).71 't71c; KAii­ aewc; 4.2 (~Aim 1tEpl8wpw 2431, 4°). 7o (a) Aa8E11wc; Efl-ltAOU'tlOfl-E\171 fl-! IX'W'tO \ll'tpOXU't'tOCpt1171 (01twc; o xoU06w~ii1-1-~a~), d. fl-E 1tEplE)(Ofl-E\IO a,w'tou 1-'-71 U1tEp~ai11011 'to 12.6 a'ta EXOC'to11, xaAwc; a'ta8Epo1tol71fJ-i1171 xal 1tEplixouaa E1tmpoa8i'twc; O)(l AlTO'tepo 'tOU 25 a'ta !XOC'tO\I 11Epo T) OCAX00A7111 (1-1-E8UAlXT), OCL8UAlXT), XOC\10\1\XT) 1tpo1tUAlXT) T) lao1tpo1tUAlXT), ~OU'tUAlXTJ TJ OCfl-UAlXTJ aAxooA71, TJ fl-l)'fl-OC'ta au­ 'tW\I ), E1tt07Jc; E<i11 fl-E'tOUalWfl-E1171, 6LOCAti't71c; 11<icp8a, ~,11,0).w, 'tOAOUoA71, ~UAE\llO, fl-lTfl-OC't(X fl-E'tOUOlWfl-Ell71c; OCAXOOA71c; X(Xl ~UAE\ltou, fl-lTfl-OC'ta 11Epoti xal ~AxooA71c;, TJ OCAXoo).71 1tEpli­ xouaa xa1-1-cpopii OE 6llXAUfl-OC • LTJfl-ELWalc;: 1. H \ll'tpoxu't'tap11171 fl-E 1tEplEXOfl-E11011 £le; a.,w­ 'tO\I u1tEp~a111011 'to 12.6 a'ta: EXOC'tO\I it\lOCl ti).71 't71c; IO.iiaewc; • la (BAiite. 7tEpl8wpw 2101, 1 °). 2. '0'tOCV 71 \IL'tpOXU't'tOCpt1171 u1po1tm718Et fl-E fl-E'tOUOlWfl-EV7111 OCAX00A7111, 71 fl-E'tOUalW'tl~TJ ti).71 O!\I 1tpi1tu va iXEl emf,Aa~T) E1ti6paa71 EltL 't71c; a'ta8Epo't71,oc; 't71c; 11t'tpoxu't'tapiv71c;. (~) ltAOCO'tlXOltOl71fl-E1171 Vl'tpOXU't'tOCpiv71, xwpic; xpwanxic; oua1Ec;, ltEplE)(OUQ(X OXl Alroupo 'tOU 18.'tolc; EXOC'tOV ltAOCan­ XOltOlTJ'tlXT)V ouaiav ( cp8aAlxov ~OU'tUAlov T) 7tAOCO'tlXOltOl71'tl· • XT)V oua1av 'tOUAIX)(lO'tO\I Lao6uv<i1-1-ou a1touAiafJ-OC'toc;) xal a't7111 01tota 71 VltpoxU't'tap11171 E)(El 1tEplEXOfl-EVov a,wwu l-'-71 uitEp~a111011 'to 12.6 a'ta EXOC'tov· 71 Yl'tpoxu't'tap11171 fl-7tOpt1 va etVOCl uito 1-1-opcp7J11 plVLOfl-lX'twv (CHIPS)? 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(1) H vcxcp0cxAiVTJ 1:Tj<; 11 ° ·{cx) 8ot ouoxwOL~E"CCXL OE O'tCX8EpOL XAELoµevcx ;uAL\ICX ii µE,CXMLXOL OO?(EtCX (2) H votcp8cxAi117l 'tTj<; 11 ° (~) 8cx ouoxwOL~E"CCXL oE ;uALllot ij µE'tCXMLXOL OO?(ELCX, TJ OE -YEPOL XL~W"CLCX CXltO LVWOTJ ocx11iocx, TJ OE . -ytpoui; OOLXXOU<; xcx-ccxxoaucxoµevouc; CX7t0 ucpcxoµcx TJ "CE"CpOL- • cpuMo xcxp"ti TJ otltO Xot"COLMTJATJ ltACXO"CLXTJ UATJ, OoOLXLc; XPTJOLµ01t0LO\l\l"CCXL XL~W'tlot CXltO LVWOTJ ootvioot, "CO XOAOII OEV 1tpE1tEL 1/CX ~uri,EL ltOLVW otltO 3 0 KG. (3) H 11cxcp0cx).[v71 OE "CE'tTJWEVTJ Xot'tOLO"CotOTj 11 ° ( r ), OEV 1tpE1tEL 1/CX µE-ccxcpipncxL OLMWc; ELµTj av,:oc; OE;cxµE11w11. 3. MLx-cii ouoxaucxoicx ( 1) 0 IlEi:; oµotOOltOLTjµEvEc; U1t0 ,:ov CXU'tOII otpL0µ6v Eioouc; µ1topou11 Vat ouµ1tEpLA7lcp0ouv 0,:0 CXU'tO XOAOII. OL EOW1:EpLxei; ouoxtucxoiac; 0cx ouµcpwvouv µE 6, 'tL 1tpo~AE1tE'totL 1 Lcx xOL0E u).7111, xcxL m E;W'tEpLxei; ouoxaucxoiac; 0cx EivotL OL xcx0opLo8EioEc; YLCX "CL<; UAE<; 'tOU Ell 8eµcx-cL otpL0µou Eioouc;. KoAO\I 7tEpLE?(OV pOL~Ooui; XCXL OWATJIIE<; XU't'tCXpo'ioi1171c; ( OEMOUAO'iO) oµou xcx . 'totoxwcxoµevoui; OE ltEpl"CUAL.rµcx CX7t0 ucpcxoµcx OEV 1tpE1tEL vex ,uri~EL 7t0L\IW CX7t0 75 KG. (2) Eav µLxpo,EpE<; 7tOOO't7J'tEi; OE\/ 1tpo~AEltOV'tCXL CXltO "CO OLp0po -co 'tL'tAocpopouµEvo ·«~uoxwoioiot µLex<; UATJ<;», oL UAE<; 'tTj<; 1tcxpoiio7l<; KAOLoEw<;, OE 1too6-c7J'tEc; µ7J u1tEp~cxi11ouoE<; 'tot 6 KG -YLot OAE<; "CL<; UAEi; "CL<; ot11otcpEp6µEV£<; UltO 'tOV otU"CO\I otpL0 µ611 Eiooui; 7l "CO CXU"CO -ypOLµµot, µ1topouv Vat E-YXAELO\l"Cotl otltO cxu,:6 XOAOV EL'tE µE UAEi; OLMOU cxpL8µou Eioouc; Eii:E OLMOU ypOLµµoti:oc; ,7J<; cxu-ciic; KAOLoawc;, 71 µE Emxi11ouvEc; UAEc; cx11ij­ xou0Ei:; oa OLM£<; K).OL'!mc; ( EOLV µLx't'Tj ouoxEucxoicx Em'tpE1tE'totL oµoiwi:; 1tpoxELµivou mpi -cmou"twv uAwv), ii µa OLMcx Eµ1to­ ptuµcxi:ot, UltO 'tTjV EmcpuACX;Tj "CWV 1totpotXOL'tW ELOLXWV 6pwv. OL EOW'tEpLxei; ouoxwcxoiEc; 1tpE1tEL \lot ltATJpouv wui; 1 £VL­ xoui:; xcxL ELOLxoui; 6poui;·ouoxwotoicxc;. Em'tpoo0hwi;, oL 1EVL­ xti; OLCX'tOL;ELi; OL 7tEpLE?(OµEVE<; O'tot mpL8wpLot 2001(5) Xotl 2002(6) XCXL (7) 1tpe1tEL vex -c71pouv-cCXL. To XOAOV OEV 1tpE1tEL Vat ,uri,EL 1tapLOOO'tEpO CXltO 150 KG 71 1tlpLOOO'tEp0 CXltO 75 KG EOLV ltEpLE?(EL au8potUO'tot OO?(ELot. 1167 2409 2410 2411 2412 2413 1168 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) EL6,xoi "Opm 2o(<X) 7o(<X) Bo 0tiov Aa9tvw, •l11tAou.taµiv11 11• a~ww v,tpo­ xun<Xp<YTj (61tw<; xoUo 6wf3a11f3~ 100 fp<X1111· KoxXLVO<; (avu 6po<;) q,waq,o ava OO;(E<O 5 KG 1 KG <XV<X 4l<XT~t~ XOAOV 5KG 4tv 1tpbm v<X au­ axtua~n<XL 11"'~' 11• x1.wp,xa &t<X, U7tEP11"'TT"'V'X<X, U7ttp;(Awp,xa <XA<Xt(l ~ u1ttpo~•'°'"' (1tA~v 61<XAu1111atwv u1ttpo­ ~t16iou tOU UOp<>jO­ VOU) 4tv 1tpi1ttL V<X au­ axtua~ovt<XL 11<X~< 11£ tiAE<; twv KA<iatwv. 4.2. ""'' 5.1. po<; 5 KG 5 KG Bo Y1to8twtixo, «I>waq,opo<; M,x~ Euaxtu<Xai<X OtV t7tLtp£7tat<XL 4. Ev6E[!;Etc;; xext E"t:LXEtE<; xtv6uvou a,:or. xolex (~AE7tE 1tpoa871x71v A. 9) ( 1) Kolci 7tEptixov,:ex UAE<; ,:wv 4 ° iwc;; 8 ° 0ex cpipouv E"t:L­ xhex auµcpwvwc;; 1tpoc;; i:o µovi:elo No. 4.1. Ev i:outotc;;, Eocv ot ulEc;; i:wv 4 ° iwc;; 7 ° Eivext auax.uexaµi­ vEc;; OE 7tEpttUAiyµexi:ex xexi:exaxEuexaµivex ex1to O"t:EVOC ucpdcvatµo ucpexaµex auµcpwvwc;; 1tpoc;; "t:0 7tEpt0wpto 2405(1) (~)3, OE XU­ ,:[ex ex1to tvw671 aexvt6ex TJ Xt~wttex auµcpwvwc;; 1tpoc;; ,:ex 7tEpt0w­ ptex 2406(1) xext 2408(4)(~), ae adcxxouc;; ex1to toii'TT] auµcpw­ vwc;; 1tpoc;; to 1tEpt8wpt0 2407(1) TJ OE ~expEALex ex1to tvw671 aex­ vi6ex auµcpwvwc;; 1tpoc;; to 1tept0wpto 2408(1) (ex), (2) xext 4(~), ,:ex xolex 0ex cpipouv Mo ettxhec;; auµcpwvwc;; 1tpoc;; ,:o µovi:elo No. 4.1. KoAex 1tEptixovi:ex 6toyxouµevex ltOAUatupivtex "t:Oll 12 ° 0ex 1tpi1tEL vex cpipouv t71v e!;71c;; emypexq:,71: «Mexxpudc ex1to xdc0e ltT)"'(TJ exvexcpli!;ewc;;». H emypexq:,71 exui:71 0ex 1tpi1tet vex exvex1pdc­ cpei:ext at71v E1tta71µ71 "'(AWaaex 'TT]<; xwpexc;; exvexxwp71aewc;;, exv 6e 71 ylwaaex exui:716ev EtVext AnltXTj, fciUtXTj TJ fepµexvtXTj, 0ex 1tpi1tet vex 1pdccpetext rnia71c;; xext atex A11ltxdc, fexMtxdc 71 fep­ µexvtxdc, exi:oc;; exv u1tdcpxouv ocMec;; auµcpwviec;; µetex!;u tWV EV 6texcpepoµivwv 1 tex t'T)V µetexcpopoc xwpwv. (2) Kolex 7tEptixov,:ex eu0pexua,:ex 6oxeiex µ71 opextdc ex1to i!;w 0ex cpipouv ettxhex auµcpwv711tpoc;; ,:o µo6iMo No. 12. Av tex eu0pexuatex 6oxeiex 7tEptixouv uypdc, tex XOAex E7ttitpoa0hwc;;, EXtoc;; exv 1tpoxettext ytex acppexytaµivec;; exµ1toulec;;, 0ex cpipouv mxhec;; auµcpwvex µe to µo6iMo No 11. Ot enxinc;; exutic;; 0ex to1to0etouvi:ext <ji71ldc OE 6uo ex1tivexvtt 7tAEUpec;; tWV Xt~W"tlWV 71 xextdc ,:po1to exvdcloyo, otexv xp71atµo1totouvi:ext ocMec;; au­ ax.uexaiec;;. (3) flpoxuµivou 1 tex ex1toat0Aic;; rcou µetexcpipovtexL aexv 1tA7Jp71 '6f)'tiex, 71 mxhi:ex No. 2B 6e xpetdc,ei:ext vex to1to0en1 i:ext atex xolex. B." .faotxeiex tOU enpoccpou µei:excpopdcc;;. 1) H 1toptypexcp71 tWV eµ1topeuµdctwv ato enpexcpo µetexcpo­ pdcc;; 1tpi1tot vex eivext auµµopq,71 µE µiex ex1to i:tc;; ovoµexatEc;; 1tou u1to1 pexµµ1,ovi:ext ai:o 1tept0wpto 2401. "01tou 71 ovoµexaiex c71c;; ouaiexc;; 6ev opi,etext at71v 1tepi1t-cwa'T) t'T)c;; 1 °, 0ex XPT)atµo 1tOLEttext 71 eµ1toptx71 ovoµexaiex. H 1topt1 pexcp71 twv eµ1top.uµdc­ ,:wv 1tpE1tEt vex U1toypexµµi,etexL xexL vex exxolou0eii:ext ex1to tex ai:otxeiex t71c;; KlocaEwc;;, -cov expt0µo i:ou e16ouc;; (µex,1 µe to -cu­ xov, ypdcµµex xext ,:ex expxtxdc ·ADR» TJ «RID» (1t.x, 4.1, 7o (ex), ADR). . 2) flpoxuµivou 1tepi xexi:exloi1twv 71 ex1to~A7Jtwv xuttexpi­ VT)<; ( 6 °) OUOXEUexaµevwv OE "'(EpO xexptt OUOXEUexatexc;; TJ OE xex­ "t:IX~ T)AT) 1tAexotLXTJ UAT) xext i:01to8n7lµivwv, hat auax.uex­ auiw w, ae adcxxou<; ex1to 1tuxvdc ucpr,au~vo r,,~r,,:ilriyexato 2414 2415 2416 xexµ~dc TJ "'(lOUtT), Oto-enpexcpo µnexcpopdcc;; 1tpbm vex ~.~exLw­ vovtexL ,:ex e!;71c;;: «~EV 7tEptEXEL xex1:ocAot1tex OE µopcpTJ axov71c;;» 3) flpoxetµivou 1 tex ulec;; ,T)c;; 7°(~) xext (1) auaxeuexaµi­ vwv ae xt~wttex ex1to µoptoaexv16ex, ai:o i11pexcpo µei:excpopdcc;; 1tpi1tEL vex ~.~extwvovtexL ,:ex e!;71c;;: «nee;; ex1t71Mexyµivec;; ex1to OXOVT)», 4) flpoxetµivou 1 tex 1extdcv0pexxex ae axOVT), 1 tex AL"'(Vt'TT] ae OXOVT) TJ 1todcv0pexxex OE axov71 ( 10 °) 7tOU exow 1texpexx0e[ "t:E • XVT)tOC xext auaxeudcatT)Xexv OE !;uAtvex 6oxe1,ex TJ OE adcxxouc;; (~AE7tE 7tEpt0wpto 2411(2)), ato inpexcpo µnexcpopdcc;; 1tpE1tEt vex exvex1pdccpovi:ext tex E!;71c;;:: «·nee;; EV"t:EAW<; <jiuyµivec;; excpou !;Tjpdcv0T)xexv µe 0epµo­ "t:Tjtex». f. KEVOC Ei67J LUOXEUexa[exc;; Kexµµiex 6tdci:ex!;T), KAAiH 4.2. YAH YITOKEIMENEi iE AYTOMATH KATIH 1. Kexi:dc).o1oc;; Ouatwv Metex!;u tWV OUOLWV xext tWV et6wv 7t0U xexAU7t"t:EL T) KAdcOT) 4.2., µovov tex exvexcpepoµevex a,:o 7tEpt0wpto 2431 0ex yiv'ovi:ext 6extdc 1 tex µEtexcpopdc, xext ,:o,:e µovov µE "t'T)V Emcpulex!;T) twv 6textdc!;ewv tou 1texpovi:oc;; flexpexp-c71µextoc;; xext i:ou flexpexpt71 µextoc;; B. Ot ouaiec;; xext tex Ei6T) exu,:dc 1tou 0ex 11vovi:ext oexi:dc 1 tex µetexcpopdc u1to optaµivouc;; opouc;; 0ex 0ewpouvi:ext we;; i,).ec;; xext EtOT) 1:T)<; AD R. 1 ° A.uxoc;; TJ xii:ptVoc;; cpwacpopoc;; 2 ° Evwaetc;; cpoacpwpou µe exAxexALXOC µhexMex TJ CXAXCXALXIX 1extwo71 auai:exnxdc, 7t-X· cpwacpioto vexi:piou, cpwacpioto exa~e­ atiou, q>wacpioto ai:povtiou. flexpextT)pTJOEL<;: 1. Tex cpwacptOLex expytMiou, µexyv71aiou xext <jieuoexpyupou eivext ouaiec;; 1:71,; Kldcaewc;; 6.1 (~AE7tE 1tEpt0. 2601,43°(ex) 71 (~. • 2. 'AMec;; evwaetc;; cpwacpopou µe ~expiex µhciUex 61twc;; ai­ OT)poc;;, xexlxoc;;, xexaahepoc;; XA7t. OE\/ U7tOXEtV"text ai:tc;; Otextdc­ !;uc;; t71c;; ADR. 3 ° Opyexvo-µetexAAtxic;; evwaetc;; UltOXEtfLEVEc;; OE exui:oµext71 xexiiaT), 01twc;;: exlxuAtex exp1tMtou, exlxultxdc dclexi:ex exp1 tA­ ).[ou, u6p16tex exAXuAtxou expytMiou, exlxuALex At01ou, exlxultex µexyv71aiou, exAxuAtex <ji.u6expyupou, exlxultex 1exMiou xext ciA­ xuAtex ~op[ou wc;; xext 6texluµextex exui:wv 1tou u1toxetvi:ext ae exu­ i:oµext'T) xexUOTJ. ITAPATHPHLEIL: 1. OpyexvoµetexMtxic;; evwaetc;; xext otexAuµextex exui:wv 1tou 6ev u1toxetvi:ext ae exui:oµext'T) xexiiaT) exMdc 1tou ae rnexq:,71 µe vepo exluouv exvexcpli!;tµex exiptex, eivext ouaiec;;- ,T)c;; Kldcaewc;; 4.3. (opex 1tEpt0wpto 2471, 2°(e)). 2. Avexcpli!;tµex 6tciAuµextex tWV ouatwv 3 ° OE OUfL7tUXVW­ aetc;; 7tOU OEV U7tOXELV"text OE exu-coµex'TT] XexUOT) xext 7tOU OE E1texcp71 µe vepo oev exAuouv exvexcpAi!;tµex exiptex, eivext ouaiec;; 'TT]c;; KAdc­ aewc;; 3. 0 ex1toato1Eexc;; 0ex 1tpi1tet vex 1tpoa0ii:et ato i11pexcpo µai:exq>opdcc;; t'Tj cppdca7J: «Oua[ec;; 1tou oev u1toxetvtext OE exui:o­ µext71 xexiiaT)» (BAE7tE EltLOT)c;;: KAIXOT) 4.3., 7tEpt0wpto 2471, 2 ° (6) flexpexi:71pT)OT) 2). 4. Kexi:dcAomex cp[).µ-vti:poxut-cexptv'T)c;;, exitT)Mex1µivex ex1to 'EAexttVT), OE poAouc;;, cpuMex TJ Awpi6ec;;. flexpexi:71p71a7J: Tex xextdcAot1tex q:,11µ-vttpoxuttexptv'T)c;; exitT)Mex1µivex ex1to ½EAexi:LVT) oe 0ex 11vovtexL 6extdc 1 tex µetexcpopdc exv eivext axovt­ aµivex 71 1teptlexµ~dcvouv axovtaµivex xoµµdcnex. 5 ° ex) Metexxetptaµivex p1XXT) xext xextOCAOt1tex, (~) Amexpdc TJ eAextWOT) ucpo:oµexi:ex, 0puexM[6Ec;;, axo,vi 71 xlw­ OtTJ (v71µex)· (1) O, e!;71c;; Amexpdc 71 elcxtw6T) EtOT): ipto (µexMi), tpixec;; (xex, exlo1otptxec;;), tEXVT)tO ipto, exvexµopcpwµivo ipto ( e1tta'T)c;; xex­ Aouµevo (WOOL SHODDY), ~exµ~dcxt, !;exvex!;exaµivo ~exµ­ ~dcxt, tEYVT)tic;; ivec;; (RA YON XA7t.) µetdc!;t, Atvdcpt, xexvvdc~t 2417 2423 2424 2425 2429 2430 2431 ll>EK 104 E<J>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) x0tt jtOU't0t, rnia71c;; u1to µopq,11 X0t't0tAoi1tw11 xAwa-c71piou 11 ucp0t11t0upyi;iou. ft0t 't0t (0t), (~) X0tt (j), ~AE7tl! 1!7tLOTjc;; 7ti!pt0wpto 24310t (0t1to a'tOt;(. 0t)). TI0tp0t~p71a71: Bpojf.LEVEc;; uAEc;; 'tOU 5 °(~) X0tt (r) 6Ev 00t 1tpE1tEt 110t yi110 ll't0tt 6Ex'tec;; jt0t f.lE't0tcpopdt. 6 ° (0t) Mh0tAA0t OE 1tupocpopo µopq,11, 01twc;;: axo1171 X0tt 7tl)­ pi'ttc;; (1tou6p0t) 0tpjt>Aiou, fL0tjllTJOLOU, 1/LXl!Aiou, 'tL't0tl/LOU, 4.u 60tpjupou 11 ,tpxoviou, rnia71c;; µiyµ0t't0t 1tupht6w11 x0tt 1tupht 6w11 xp0tfLIX'tw11, xovtc;; 0t1to cpiA'tp0t u4tx0tµi11ou· TI0tp0t't1IPTJ0 11: LXOYTJ XO(t 1tupi'ttc;; f.lE'tlXAAW\I al! fLTJ 1tupocpopo µopcp11, 7t0l) 01! 1!1t0tcp11 fLI! 11op6 l!XAUOUII 0t110tcpAel;tµ0t 0tipt0t, Ell/0tt ouaii;c;; 't'rjc;; KAdtai;wc;; 4.3. (~Ae1ti; 1topt0wpto 2471, 1 ° (6)). ~) .AA0tt0t 6t0i!tO\ltXOU (u6po0Etw6ouc;;) ol;foc;; (H2SP 4) 01twc;; 6t0EtovhEc;; ( u6poawAqii6t0t) 110ttpiou, x0tAiou 0ta~Eatiou X0tt 4w60tpjupou. y) ·Aw6po aouAcpi6to xOtAiou X0tt dtw6po aouAcpi6to 110t'tpiou we;; x0tt t0t u6pol;Ei6t0t 'tWII 1tou 1ti!ptexou11 AtjWtEpo 0t1to 30% vEpo xpua't0tAA01to111ai;wc;;, u6poaou)..cpi6t0t 110ttpiou 1tou 1tEpti­ X•t AljW'tEpo 0t7t0 25% 11Epo xpuat0tAA07tOlT)OEWc;;. TI0tp0t~p71a71: LouAcpi6to x0tAiou X0tt aouAcpi6to 110ttpiou f.LE 1tEptE;(OfLEIIO 'touAiixtatov 30% vEpo xpua't0tAA01totT)aEwc;; x0tt u6poaouAcpi 6to 110t'tpiou 1tou 1tEpti;(it touAdt;(tato 2 5 % xpua't0tAA01tot1I• aEwc;;, Ei110tt ouaii;c;; t71c;; KAdtai;wc;; 8 (~Ai1ti; 7topt0wpto 2801 45 ° (~)). ft0t 'tO 0t) ~AE7tl! E1tia71c;; 7tEpt0wpto 24310t O'tO (~). ft0t 'tO ~) ~AE7tE E1tia71c;; 7tEpt0wpto 24310t \J7t0 O'tOt;(. (0t). 7 ° Tipoacp0t't0t 0ta~l!O't07tOlTjf.lEIITJ 0tt8dtA71. BAE7tE rnia71c;; 7tl!­ pt0wpto 24310t l)7t() a'tOl;(i!lO (0t). 8 ° Cl>pi;axo - a~71aµi11oc;; 1;uAdtv0p0tl;, aE axo1171, ai; xoxxouc;; TJ OE ~wAouc;;. BAE7tE rnia71c;; 7tEpt0wpto 24310t \J7t0 O'tOl;(ElO (0t) XOtt KAdta71 4.1. 7tEpt0wpto 2401, 1 0 • TI0tp0ttT)p71a71: Mi; tov opov «cppEaxoa~uaµivoc;; l;uAdt118p0tl;» 110Eit0tt: L'tTJY mpi1t'twa71 l;uAdt118p0txoc;; ai; ~wAouc;;, o l;uA:dt118p0tl; 7t0l) E;(El a~TjO'tEl 'tO 7t0AU 1tpo 4 Tjf.lopwv. LE 1tEpimwa71 1;uAdtv0p0txoc;; OE axo1171 x0tt 1;uAdtv0p0txoc;; aE xoxxouc;; aE µi1i;0oc;; x6xxw11 At1wnpo 'tWY 8 xat. o 1;uAdtv 0p0tl; 7t0\J E;(l!l a~71ani 1tpo 8 'tO 7tOAU -Tjf.ll!PWII XO(t E;(l!l 4ux0Ei fLI! 0tep0t al! AE7t'tlX a'tpWf.l0t't0t T) fLE IXAATJ µi0o6o 7t0l) E1;0tacp0tAi­ 'El 0tll'tLO'tOl;(O ~0t0f.LO 4u1;Ewc;;. 9° Mijf.L0t't0t XOXX07tOlTjf.lEYWII T) 1topo6w11 x0tuaiµw11 O\J­ OlWII µi; auat0t'ttxdt 1tou 0txoµ71 u1toXEtll't0tt aE 0t\J'tOfL0t't'rj ol;Ei 6wa71, 01twc;; 7t,;(. to At11iA0tto xm dtll0t cpuatxdt 1;71p0tt11oµE110t EA0tt0t, ~p0taµi110t T) f.ll! 1tpoa0EtEc;; 1;71p0tll'tLXEc;; 1!1/WaEtc;;, p71ti11i;c;;, pTj'ttviAmo, X0t'tdtAom0t 1totpEA0tiou XA7t. (1t,;(. 71 ouai0t 71 jllW· at11 a0t\l X0t'tlXAOl7tO cpEAAou, AOU7tOUAi1171) X0tl EA0ttw671 X0t'tlX­ AOl7t0t 0t1to 'tTJII AEux0tat11 aoytoA0tlou. BAE7tE rnla71c;; 7tEpt8wpto 24310t U7t0 O'tOt;(ElO (0t) X0tl KAiia71 4 .1.' 7tEpt0wpto 2401, 1 °. . . 1 O O X0tp'tl, ;(0tpto11t xm 1tpoi:611't0t X0t't0taxEu0taµE110t 0t1to ;(0tptl x0tt/T) ;(0tpto11t (1t.;(. mpt't\JALjf.l0tt0t ;(0tpto11tou xm 60t­ X'tUAt0t ;(0tpt011tou), cpull0t 0t7t0 i110t l;uAou, 6foµEc;; (xouxAoc;;) IITjf.llX'tWY, ucp0taµdttw11, a1tdtnoc;;, xAwa~ X0t'tlXAOl7t0t XAW­ at71p[ou 11 ucp0t11toupjEiou, 0A0t Ef.L7tO'ttaµi110t fLE Aii6t0t, Al1t71, cpuatxdt 1;71p0ttl/Of.ll!\10t eAOtt0t, ~p0taµi110t 11 fLE 1tpoa0Enc;; 1;71p0t­ \l'ttxec;; Evwai;tc;; T) dtlli;c;; Ef.l7tO'ttaµivEc;; oua[Ec;; u1toxElfLEVEc;; OE 0tU'tOfL0t'tTJ ol;d6wa71. BAi1tE rnla71c;; mpt0wpto 24310t u1to atotxEto M x0tt KAdtOTJ 4.1., 7tEpt0wpw 2401, 1 °. TI0tp0t'tT)pTJa71: OuaiEc;; 'tO\J 10 ° BEY 00t jLYO\l't0tt 6Extec;; jt0t fLl!'t0tcpopdt 0tll Tj uyp0tal0t twv u1tEp~0t[11Et 'tTJII u1p0tai0t Myw u6poaxomx6'tTJ· 'toe;;. 11 ° H ouai0t f.LE ~dta71 o1;d6to wu at61jpou 1tou ;(p71atµo 1t0t1j871xE jt0t x0t80tptaµo cpwt0tEpiou (60t1t0t11718i11 o1;Ei6to 'tOU at6T)pou). TI0tp0t'tT)p71a71: Av 71 ouai0t 1tou XPTJOLf.l07t0tT)871xE jt0t xdt00tp07j cpwt0tEpiou (60t1t0t11718i11 o1;.i6to at61jpou ), f.lE'tlX 't'rjll Ell0t7t00T)XWOTJ XO(t E1;0tEptaµo, 6.11 l)7t0XEt'tO(t 7tAEO\I OE 0tU'tOf.l0t'tTj 0t\llX(j)AE1;Tj XO(t Ecp' oaov 'tOU'tO ma't07tOtEl't0tt a'tO enp0tcpo f.lE't0tcpopdtc;; f.LE 't'rjll e116Etl;71: «Ouai0t f.l'rj l)7t0XEtfLEYTJ aE 0tU'tOf.l0t't'rj 0t\llX(j)AE1;Tj», 6.11 U7tOXEt 't0tt O'ttc;; 6t0ttdtl;Et& 't'rjc;; AD R. 12 ° MEt0t;(Etptaµivm adtxxot f.l0tjtdtc;;, 0tx0t0iiptatot. BXi1tE E1tia71c;; 7tEpt0wpto 24310t U7t0 O'tOl;(ELOII (0t). 13 ° K.voi adtxxot vtxtptxou 110ttpiou X0t't0taxw0taµe11ot 0t7t0 ucp0taµ0t. TI0tp0tt1jp71a71: • • Y cp0taµ0ttevtot adtxxot 0t1t6 wuc;; 01toiouc;; 0tcp0ttpe871xE tE­ AEiwc;; fLE 7tAUOlfLO OAO 'tO \lt'tptxo iiA0tc;; 7t0\J touc;; 6tE7tO'tt,E, 6.11 u1tOXEtY't0tt attc;; 6t0t't0tl;Etc;; 't'rjc;; ADR. 14 ° K.vic;; auaxw0taiEc;;, XEIIIX ~l)'ttocpop0t O;(T)f.l0t't0t, XEvec;; 0t1toau116EOf.LEYEc;; 6E1;0tµE11ec;; X0tl XE\IIX 60;(El0t - 6E1;0tµE11ec;;, 0tX0t 0dtpta't0t, 7tOU 7tEptEL;(0tll cpwacpopo 'tOU 1 °. 15 ° K.vec;; auaxw0taiEc;;, x.vdt ~uttocp6p0t ox11µ0tt0t, xEvec;; 0t1toau116EOfLEYEc;; 6E1;0tµE11Ec;; X0tt XEIIIX 6oxEi0t . 6E1;0tµE11ec;;, 0tX0t 0dtpta't0t, miu 7tEptEl;(0tll ouaiEc;; 'tOU 3 ° . TI0tp0t'tTJpTJa71: L;(Ettxdt fLE t0t 14 ° X0tt 15 °, xEvic;; auaxw0taiEc;; 1tou 7tE· ptEL;(0tll ouaiEc;; IXAAEc;; EXtoc;; t71c;; KAdta.wc;; 4.2 6.11 l)7t0Xl!lll't0tt one;; 6t0t1"0tl;Etc;; 't'rjc;; ADR. • Emxi116u11.c;; ouai.c;; 1t0tp0t6t66µ'e.11Ec;; jt0t µe.t0t.:popdt auµ­ cpw110t f.LE ,tc;; 0tx0Aou0Ec;; 6t0t't0tl;Etc;; 6Ev u1tOXEtll't0tt oun a,tc;; 6t0t't0tl;Etc;; 't'rjc;; 1t0tpoua71c;; KAdtaEwc;; 7t0l) 7tEptE;(Oll'tOtt a'tO 1t0tpo11 TI0tp0tp'tTjfL0t ou,E a'ttc;; 1te.ptE;(OfLEYEc;; a'tq TI0tpdtp't. B: (0t) OuaiEc;; 'tWII 5 °' 6 ° (~), 7° ewe;; l0°'x0tt 12 °' 0tll Tj X0t­ 'tlXO't0tOT) twv Ei110tt th0t0t wa'tE 110t 0t1toxAEiEt xdt0E xiv6wo 0tu­ 'tOf.L0t,71c;; 0t11dtcpAEl;71c;; x0tt Ecp' oaov 'tOU'tO ma'to1t0tEl't0tt 0t1to 'tOY 0t7tOO'tOAE0t ato Ejjp0tcpo 't'rjc;; f.LE't0tcpopdtc;; fLE 't'rjll e116Etl;71: «Ouaii;c;; µ 71 u1toxEiµE11Ec;; aE 0tU'tOf.l0t't'rj 0t11dtcpAEl;Tj» 1tpoxEtµe11ou oµwc;; jL0t ouaiEc;; t71c;; 8 ° xm yt0t optaµivEc;; ouai.c;; twv 9 ° x0tt 10°, ~Aem K1.dta71 4.1 1tEpt0wpto 2401, 1 °. (~) Kovtc;; XO(t 1tupi,tc;; 0tp,uAiou T) 4.u60tpjupou 'tOU (6 ° (0t)), 1t.;(, auaxw0taµe1171 µ0t'i fLE ~Epvixt jt0t XPTJOTJ aE ~to­ fLTJX0t11i0t XPWf.llX'tWV, 0t11 Ei110tt auaxw0taµi1171 fLE 1tpoaoxTJ aE 1toa6t71tEc;; 1tou 6.11 ump~0ti11ou11 to 1 xtAo. A. KoA0t 1. fE11txoi ·opot Luaxw0tai0tc;;. ( l) H auaxw0tai0t 00t 1tpE1tEt 110t Ei110tt xAEtO'tT) x0tt cppo11tt­ aµe1171 hat WO'tE 110t 1tpOA0tf.L~IXIIEt xdt8E 'tll;(OII 0t7tWAEt0t 'tWII 7ti!ptE;(OfLEYW\I. 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L'tEpEec;; ouaiEc;; 00t 1tpE1tEt \10t anpEWIIOll't0tt O'tot0Epdt O'ttc;; auaxw0taiEc;; 'tWY, EIIW ot EawtEptxec;; auaxw0taiEc;; 00t 1tpe1tl!t I/IX anpEWl/0\l'tlXt a't0t0Epdt a'ttc;; El;wnptxec;; auaxi;u0taiEc;;. Av 8E11 xot0opi,Et0tt dtllwc;; 1twc;; ato xEcpdtAotto fLI! 'tl'tAO «Luaxw0t­ ai0t f.LL0tc;; f.LOIITJ ouaiotc;; T) 7tp0tjfL<X'tW\I 'tOU OlU'tOU Ei6ouc;;», Ol .aw'tEptxec;; auaxw0taiEc;; µ1topou11 vot EjXAEio11tott ai; El;wtEpt­ xic;; auaxw0taiEc;; EL'tE µi0t - µi0t T) X0ttdt oµdt8Ec;;. ( 4) Cl>tdtAEc;; X0tt IXAA0t UIXAt110t 60;(Eiot 1tpE1tEl \10( fLTJII 1totpou­ atdt,ou11 acp1XAfL0t't0t 7t0U m00t11011 \10t f.LElWIIOUII 't'rjll 0tll'tO;(T) 'tWII, Et6tXW'tEp0t, Ol EOW'tEptXEc;; 't<Xaw; 1tpemt 110t IX\lotXOU(j)l,Oll't0tt x0tt1XAATJA0t. To 1tdtxoc;; ,wv 'tOt;(WfLIX'tWII 6Ev 1tpE1tEt 110t Ei110tt µtxpotEpo 0t7t0 3 xa't. 1tpoxuµi11eu jt0t 6oxEiot 't0t 01toi0t, µ0tl;l f.LE 'tO 7tEptE;(Of.lEIIO 'tW\I ,uri,ow 1tAEO\l 'tW\I 35 XI.AWII XOlt 'tOU­ A<X;(tO'tOII 2 xa't. O't'rj\l mpi1ttwa71 IXAAWII 80;(ELWII. 1169 2431a 2432 1170 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI .dEYTEPO) H ai:e10tvoi:71i:71c; i:ou auai:71µ0ti:oc; XAELaiµ0ti:oc; 1tpi1m v0t e;0tacp0tAi~e:,:otL µe: EVOt 1tp6a8ei:o e.;ipi:71µ0t {1twµ0t, xopwvOt, acpp0tyio0t, ofotµo, X.A. 7t ), LXOtVO VOt 1tp0Ai~e:L OltOLOt07lltOU X0tAipwa71 i:ou auai:71µ0ti:oc; xAe:taiµ0ti:oc; x0ti:i i:7111 µe:i:0t­ cpopi. (5 )' Owv 1tpOOL0typicpovi:m 71 e:m,:pi1tovi:0tl ooxe:i0t x0ti:0t­ axe:u0taµev0t 0t1t6 yu0tAi, 1topae:Aiv71, 1te.i:pwo71u)..71711t0tpoµm0t UALXi 0tui:i 880t 1tpEmL v0t e.;0tacp0tAi~ovi:0tL µe: 0tvi:txpouanxi UAtxi ae: 1tpoai:0ti:wi:txec; auaxe:u0taie:c;. T 0t 0tvi:txpouai:txi UALxi 80t 1tpE1te:L v0t dv0tL 1tpoa0tpµo­ aµiv0t a,:o dooc; ,:wv 1te.pte.xoµivwv. EL6txw,:e.p0t, 80t 1tpE1tEL VOt EtVCXL a,:Eyvi XOtl 0t1toppocp711:tXi 01:0tV 1:0t mpte.xoµe.vOt ELVOtl pe.ua,:i 7I EVOEXE1:CXL VOt e;topwaouv. 2. Luaxw0tai0t µt0tc; µovov ouai0tc; 71 1tp0tyµii:wv i:ou LOiou e.i­ oouc;. (l) <l>wacpopoc; i:71c; 1 ° 80t auaxwi~e.i:0tt: 2433 0t) Le: a,:ey0tvi e.mx0taati:e.pwµiv0t ooxd0t e.pµ71i:txi XAELai:i XatL i:01to8e.i:71µiv0t e.vi:oc; ;u).ivwv xt~wi:iwv 71: ~) LE LLOEpEVLOt ~OtpEALOt ltOU XAELVOUV epµ71i:txi. I1wµ0ti:0t. • 7t0U XAELVOUV µa 1tiea71 oe.v 80t e.mi:pE1tQV'1:0tl. To Ol07jp6cpuUo ltOU Otlt01:EAEL ,:0 awµ0t, ,:ov 1tu8µev0t XOtl ,:o XOtltiXL Six 1tpi1te.L VOt exouv 1tixoc; ,:ouAiXL01:0V 1.5 xai:. Kille XOAOV OEV 1tpE1tEL VOt ~uri~e.L 7tAEOV ,:wv 500 XLAWV, Katt OtV ~uri~e.L ltAEOV ,:wv 100 XLAWV 1tpE1tEL VOt ELVOtl ecpwOL0taµevo µe. ai:ecpivLOt (,:aep­ XLOt) 71 e.vtaxunxi 1tAwpi XatL v0t dv0tL 71).exi:poauyxoU71µevo, 71: r) To ltOAU 250 XLAi OE xiBe ooxdo; ae. Epµ71i:txi XAEL­ O(J-EVOt ruiALVOt ooxdOt OtOCj)OtAL,OfJ-EVOt µa OtV1:LXpouai:txi UALXi, e.v,:oc; a,:e.yocvwv EltlXOtaati:eptwµevwv ooxe.iwv XAELaµivwv µe: µ0Au~6oxoAA71a71 XOtL e~ote1cp0tALaµevat 1t0tpoµoiwc; µa atvi:t­ xpouai:txi uAtxi e:vi:oc; ~uAivwv xt~wi:iwv. 2 . .1oxe:i0t XOtl ~OtpEALOt 7teplE)(OV1:0t cpwacpopo Sat 1tpE1te:L VOt ELVOtl re.µtaµiv0t µe ve.po . (1) Ouaie:c; i:71c; 2 ° 1tpE1tEL v0t auaxe.ui,ovi:0tL ae ai:ey0tvi 2434 e.mx0taati:e.ptwµev0t ooxe.iat e.pµ71i:txi xAe.taµiv0t XOtL i:01to8e. i:71µivat ae. ;oALVOt XL~W,LOt. (2)0uaie.c; 1:71c; 2 ° µ1topouv e1tia71c; VOt auaxe:ui~ovi:atL ae. 1to­ ao,:71,:e.c; OXL ltAEOV ,:wv 2 XLAWV XOti:i ooxe.io, ae. ooxd0t OtltO ruOtAi, 1topae:Aiv71, ltE~pw671 UATJ 71 1t0tpoµm0t UALxi, e.;0tacp0t­ AL,aµe.v0t µe. Ot\11:LXpouai:txi UALXi ae: ;uALVOt Xl~W1:l0t, (1) Ouaie:c; ,:ou 3 ° 80t 1tpi1tELV0t auaxe.ui~ovi:atL ae e.pµ71nxi 2435 XAELOf-lEVOt µe:i:OtAALXi OO)(ELOt ltOU OEV µ1topouv VOt 1tpoa~A7l 8ouv at1t6 i:0t 1te:ptexoµev0t, xwp71i:tx61:71i:oc; i:o i.oAu 450 Ai i:pwv. Tat OO)(ElOt Otui:i 80t 1tpi1te.L: e.ii:e. vat 1tpocpuAiaaov,:m atltO e~wi:eptxi 1tept~A71µ0ti:0t OtltO 0tv8e.xnxo a,:71 cpwi:Li UALXO, 71: VOt exouv 1tixoc; i:mxwµ0ti:oc; ,:ouAiXL01:0V 3 xai:. µe. xAe.iatµo i:wv 0tx.pocpuaiwv ye:µiaµ0ti:oc; XOtL e.xpo71c; e.~0tacpOtAL­ ,aµe:vo µe. 1tpoai:0t'tW'1:LXO 1twµat. T0t ooxe.iat 1tpE1tEL VOt UltO~iUovi:OtL ae. 0tp)(LX7I ooxtµ0tai0t XOtL ae. 1te.pLOOLxec; 6oxtµ0taiec; xi8e. 1tivi:e. xpovtat µe. µi0t 0tOp0tv71 ouai0t ooxtµatai0tc;, ae. 1tie.a71 ,:ouAiXL01:0V 1 MPS (10 BAR). • T0t ooxe.iOt oe.v 1tpE1tEL VOt re.µi,ovi:atL 7t£ptaaonpo atltO 90% i:71c; 7teplEX1:LX01:Tj1:0'i ,:wv. 'Ev0tc; xwpoc; 5% itpE7tEt VOt µeve.t xe.voc; ytat atacpiAe.tat 01:atV ,:o uypo e.ivatt ae. 8e.pµoxpataiat 50 ° c. 'Oi:atv 1tatp0toioe.i:0tl ytat µe.i:atcpopi, ,:o uypo 1tpe.1te.t VOt ~piaxe. 1:0tl xii:w atltO a,:pwµat 0tOpatvou,; ate.piou, 7l 1tie.a71 ,:OU 01toiou oe.v 1tpe.1te.L Vat Uite.p~atlve.L ,:o 50 KPS (0,5 BAfl). I1ivw 01:TJV mvatxioat µe. ,:at ai:mxe.iat i:ou OO)(ELOU 1tpi1te.L Vat Eivatt ivi:uitat i:at E~71c; )(0tp0txi:71ptai:txi: 0t) «'Opy0tvo - µi;i:illtxic; ouaiEc;, K).ia71 4.2» • ~) To atltO~atpo ,:ou ooxEiou, auµ1te.pLA0tµ~atvoµivwv ,:wv E~0tp,:71µii:wv xatt 1tpoaatp1:71µii:wv. r) H lttEOTJ Xatl 71µi;poµ71viat ooxtµatalatc; (µ71vatc; XatL ii:oc;) 1:"lj'i nAwi:0ti0tc; ooxtµataiatc; 1tou i1 LVE. 6) H acppatyioat ,:ou EµitpEtpoyvwµovat ltOU OLEV7lpr7lOE ,Le; oox1µ0taie.c;. i;) H xwp71i:txoi:71c; i:ou ooxeiou XatL o e.mi:pe1t6µe.voc; µiyt ai:oc; ~0t8µ6c; 1tA71pwae.wc;. . 0 0tXpl~7l'i 1tpooptaµoc; 1:WV 7tEpLEXOfLEVWV XOtl 7j cppia71: «Aitatrope.ue:'tOtL ,:o ivmyµ0t XOt,i 1:TJV µi:cxcpopi, 1Lat'ti UltOXEL 1:CXt OE cxu,:0µ0ti:71 cxvicpAE~TJ» Sat 1tpe.1te.t VOt EtVCXL ypcxµµe.v71 CXVE­ ~t't""ljAat, OLat,:UltWfLEVTJ ae. e1tia71µ71 yAwaacx 1:"lj'i xwpatc; CXVOtXW p71aEwc; Xatl e.1tia71c;, OtV atu,:71 7l y)..waaat oe.v e.lvatL 7l AyyALX7I f0tUtx71 71 fepµatvtx71, xatL ai:at AyrAtxi, fatAALxi 71 fepµat­ vtxi, exi:oc; CXV iUwc; 1tpo~AEmL xiitOLCX auµcpwvicx µe.i:0t;u ,:wv EVOL0tcpepoµe.vwv xwpwv 't"lj'i e.mxetp71aew,; µe,:cxcpopi,;. Kille auaxeu0taiat (xoAov) OEV 1tpi1te.t Vat ~uri,EL ltAEOV ,:wv 1.000 XLAWV. (2) Ouaiec; ,:ou 3 ° µ1topouv e1tia71c; vat auaxwi,ovi:att ae. ep­ µ711:txi XAELaµe.vat ruO(ALVat OO)(dat xwp71i:tx6,:71,:oc; 'tO ltOAU 5 )..[,:pwv 1tou 1tpe.1te.L v0t 0tacpatAi,ovi:cxL µe 0tvi:txpouai:tx6 uALXO EV'tO'i f-1-E'tOtAAtVWV ooxeiwv. T0t ruO(ALVat ooxe.i0t oe:v 1tpe.1te:L VOt ,e.µi~ovi:atL 1te.ptaaoi:e.po atltO 90% ,:71,; xwp71i:txo,:71,:oc; ,:wv. ( 1) Ouaie:c; ,:ou 4 ° 1tpe.1tEL vat auaxwi,ovi:att ae. aixxou,; ,:o 1to8e,:ouµevou,; ae. ~cxpe.Alat X0ti:ataxw0taµe.vat atltO atOti~pox71 Lvoaexvioat 71 ae: ooxeiat Xat'texaxwataµe.vat omo Awxoaio71po 71 cpuUat OtAouµLViou. Ot ltAe:upe.c; ,:wv µei:illtxwv ooxe:iwv 1tpe.­ mL vex e:iVatl e.1te.vouµe.vec; µe: Lvoaexvioat. 0 1tu8µe.vatc; xcxt i:at Xat1tixtex ,:wv aexvtoe.vtwv ~cxpe.ALWV xexL ,:wv µe:'texAALXWV ooxe:iwv 1tpE1tEl Vat E)(OUV ;UAlVTJ e1te.voua71. (2) Tat µE,iAALVat ooxeiex 1tpE1tEl VOt eivext ecpwOLataµe.vOt µe. XAEtaiµex,:at 71 auaxe:uec; exacpexAe:iatc; ltOU VOt Ultoxwpouv o,:exv 11 eaw,:eptx71 ltLEOTJ cp8iaEt ,:o 1tOAU ae 0.3 MPS (3 BAR). H 7tat­ pouaiex exu,:wv 'tWV XAEtaLµi,:wv 71 auaxwwv atacpatAe.iexc; oe.v 80t 1tpe.1tEl VOt 1texpex~Ai1ti:E~ 'tTJV at\11:0)(71 'tWV ooxeiwv OU'tE VOt 1texpe.µ1tooi~El 'tO XAe.iatµo ,:wv. (3) KixBE XOAOV OEV 1tpE1tEl vex ~uri,Et 1te:ptaao,:e.po atltO 7 5 XlAIX. (1) Ouaie.c; ,:ou 5 °(ex) 1tpE1tEt vat eivatt ai:Eycxvi auµme.­ aµe.ve.c; Xatl 't01t08E't7jfJ-EVE'i OE UOex'1:001:E17I µe.i:OtAAtXi OOXElOt, (2) Ouaiec; 'tOU 5 ° (~) XatL (r) 1tpE1tEl Vat eivexL ai:e.yatvcx au­ µme.aµe.vec; XatL auaxeuataµe.vec; eli:e. ae. ~UALVat ei,:e ae. XL~W,Lat OtltO µopLOaexvioat 71 OE xipi:tvat 71 ucpataµii:LVOt 1te.pt,:u)..l-yµati:at 1:EAELex a,:epewµevat. (1) Ouaiec; ,:ou 6° (at) 1tpi1te.L vat auaxe.ui,ovi:atL ae. e.pµ71 1:1xix XAELaµevex ooxe.i0t atltO µii:atAAO, ")'UOtAL 71 xex,:ill71Aat 1tAexa,:txi uAtxi. H ouaiex 80t 1tpe1te.t vat ex1toai:e.Ue.i:0tt µe. e.vex 1tpoa'tat'CEU'1:LXO uypo 71 ate.pLO. Tat ooxe.iat Bat 1tpe.1te.L e.v 0tvcxyx71 vex e:ivatt e.cpw6tataµe.vo µe xexi:i).).71)..71 auaxe.u71 atvi:tai:at8µ1 a,:1x71 ,:71c; mfoe.wc;. Tex ruO(AtVex ooxe.iOt 80t 1tpe.1te.L Vat exacpatAl,0111:0tl µe. at\11:l­ xpouai:txi uAtxi ae. auaxwataie.c; at1t6 tvoaexvioat 71 ex1t6 µe.­ cillo. Tat exv,:txpouanxi UALXi Sat 1tpe.1te.t vat e.iv0tt ixatuai:at. Tat ooxe.iex ltOU e.ivexL XOt'tataxe.uataµivex OtltO 7tAOt01:tXO UAtXO 1tp~1te.t Vat 't01toBe.-couv't0tl ev,:oc; auaxe.uataiatc; LVOaatvioatc; 71 µi;­ ciUou. Luaxe.uataie.c; ltOU 1te.pte.xouv ooxe.iat atltO -yuOtAi 7l ltAat­ ai:tx71 UATJ 1tpe.1te.L VOt ,:01to8e.i:ouv,:att e.vi:oc; ;uAivwv XL~w,:[wv. Kille. XOAOV OEV 1tpE1tEL Vat ,u,i~e.L 1te.ptaaoi:e.po atltO 75. XLACX, (2) Ouaie.c; 1:ou 6 ° (~) XOtt (r) Sex 1tpE1tEt vat auaxe.ui,ov-catt ae. e.pµ71-ctxix XAEta-ci ooxe.iat ex1t6 µe.-cOtAALXO EAataµex 71 OE xex­ AU~OlVOt ~expiAtOt. Li:71v mpi1ti:wa71 'tWV ooxe.iwv ex1t6 µe.-catA­ ALXi cpuUat, xcx8e. XO/,OV oe.v 1tpe.1te.L Vat ,url,e.L 1te.ptaaoi:e.po OtltO 50 XLAi. Ouaie.c; ,:wv 7 ° - 10 ° XOtt 12 ° 80t 1tpe.1te.L vat tle.ivov-ratL µfoat ae. ate.poa-ce.ye.ic; auaxwataie.c;. ::'.uAtve.c; auaxe.uatale.c; XPTJ­ atµoitotouµe.ve.c; 1tat ouaie.c; -cou 7 ° xatt 8 ° Sex 1tpi1te.t vex 1tpo­ ~Ae.1tov-catt µe. µtat e.1tivoua71 atVtLOL0tppo71c;. H ouaiex 1tou xp71a1µ01tot71871xe. 1 tex xi8atpa71 cpwi:exe.piou ( a~uaµe.vo O~e.[Oto Ol07lpOu) 'tOU 11 ° 8ex 1tpE1tEl Vat OUOXEUCX~E­ 'tatl OE ai:e.yatvi XAEta-ci ooxe:iat atltO cpuUo µei:illou. Ke.voi aixxot VL'tpLxou vex-cpiou ~ou 13 ° Sat 1tpe.1te.L vat au­ axwi,ovi:att µiaat ae. OCj)LX1:00Eµe.110t OEµattOt ai:e.pe.i OEflEVat µe. a1ti,ro Xatl i:01to8ei:71µe.vat e.i,:e. ae. ~UAlVO Xl~W'tLO e.ii:e. OE 1te.p1 ,:UAL,µex ltOU Sat atlt01:EAEL1:atl OtltO ltOAAatltAO xovopo Xatpi:i µe:­ yiA71c; exvi:ox71c; 71 atltO UOOti:oa,:e.,e.c; {0t6Li~poxo) ucpataµat . MIKTH LTIKEYALIA ( 1) Ouaie.c; ltOU atv71xouv a,:ov ioto atpt8µo oµi6atc;, µ1topouv vat auµ1teptA71cp8ouv a,:o i6LO xoAov. Ot e.awi:e.ptxe.c; auaxi;uat­ aiec; Sat 1tpe.1tEl Vat e.ivatl auµµopcpi;c; µe. oaat 1tpoOLat,picpovi:atL y10t xi8e: ouaiex, e.vw 71 e.~w-ce.ptx71 auaxe.uexaiat 80t e.lv0tL e.xtiV"lj ltOU xat8opi~e.'tatl ")'lOt 'tl'i ouaie.c; ltOU Otll7IXOUV (l'tOV i6to 0tpt8µ0 e.i6ouc;. (2) Av OEV 1tpo6L0t,picpovi:0tl µtxpo-cipec; 1toao,:71,:e.c; O'tO ip 8po u1to i:ov ,:i-c~o «Luaxe.u0tai0t µtatc; µov71c; ouai0t 71 1tp0t1µi­ i:wv ,:ou i6tou e.!oouc;», ouaie.c; i:71c; 1t0tpou071c; KAiae.wc;, ae. 1to­ ao-c71i:e.c; ltOU oe.v U1te.p~0tlvouv '1:\X 8 XlACX a,:7111 1te.pi1t'tWOTJ a-re. 2436 2437 2438 2439 2440 2441 • 2442 EO>HMEPl:r TH:r KYBEPNHtEQt (TEYXOI: ~EYTEPO) pe:qiv TJ 3 Ah:pwv O'tlj\l 7tepl7t'tWOTJ urpwv jUX oAe:,; i:t,; ouoie:,; 7t0U mptA<Xµ~ot\10\l't(Xt O'tO\I ioto <Xpt0µo e:ioou,; TJ O'tO ioto xoAO\I e;l,:e; µe: ouoie:,; otAAOU <Xpt0µou e:ioou,; TJ otAAOU o/l]Cj)LOU 'tljt; iot<X,; xAiitoe:w,;, TJ µa e:mxivou11e:,; ouoie:,; 1tou <X\IT]XOU\I oe: iitUe:,; xAot­ ow; ( <XII 1t<Xpoµoiw,; e:mi:pem,<Xt µtX'tTJ ouoxe:u<Xoi<X 0,1]\I 1te:pi 1t1:WOTJ 'tE'tOLW\I OUOlWV ), 7j µa otAA<X e:µ1tope:uµ<X,<X, ouµcpwv<X µe: ,:ou,; d;71,; ElOlXOIJt; opou,;. Ol e:owi:e:plxe,; OUOXEU<XOte:,; 1tpe1te:l \l(X lX<X\107tOlOIJ\I ,:ou,; re:­ \llXOIJt; X<Xl ElOlXOIJt; opou,; OUOXEU<XOt<X,;. E1ti 1tAfov, Ol jelllXEt; Ol<X't0ti;w; 'tW\I 1te:pt8wpiw11 2001 (7), 2002 (6) X(Xl (7) 1tpe 1tEl \l(X 'tl]pOU\l't<Xl, Kiit0e: xoAov oe:v 1tpbm ll<X ~u1i~u 1te:pLooo,:e:po <X1to 150 XlAot TJ mplOOO'te:po (X7t() 7 5 XtAot (XII mpteXEl e:u0p<XUO't(X oo­ xe:i<X. E,o,xoi 'Opot Ap. Eiooui; Oept1potq>Tj ouolo:c; Aeuxoi; ri xhptvoi; q,woq,opoi; Cl>woq,iotot AAxuAtot • 4'w Me1 i<>tTj OoobtTj<; xo:-cci dev emtpi1tetoti l'"''t7J ouoxeuotoiot ootp- Aev ~m,pi1tnot,. ,upou XAlt. µtXtTj ouoxeuotoiot 4°, 5° 6' (~) 7° - 12° MitotUotoe1tu poq,opo µopq,ii 3 xiA. dev Bot 1tpi1tot vot ou-· 3 XtA. oxeu0<~011tott . µ• eAot­ q,pix vitpc.iµiYTj vitpo­ xunotpiv11 xoti epu8po q,waq,opo <TJ<; KAix­ o•wi; 4.1, oun µ< 8,­ q,8opiouxot M<Xpxiitptoµ<X X<Xt m11<Xxioe:,; Xt\lOIJ\10\J rni 'tW\I XOAWII (BAem TI<Xp&.p,:. A.9) ( 1) KoA<X mp1exo11't<X ouoie:,; 'tW\I 1 ° ew,; 4 ° X<Xt 6 ° 0<X 1tpe 1tet \l(X qiepow 7tt\l(XXLO(X ouµqiw11<X µe: 'tO U1tOOE:Ljf,l<X <Xp: 4.2. KoA<X 1te:plexo\l't<X ouoie:,; 'tOU 3 ° 0<X 1tpe1te:t rni 1tAfo11 \l(X qie.­ pou11 7ttV<XXLO<X ouµqiw11<X µe: 'tO U7t00Eljf,l<X 4.3. 0 0't<X11 ouoie:,; ,:ou 4 ° ouoxe:u&.~oll't<Xl oe: UO<X'tOO'tei7J ~<XpE­ Al<X (X7t() t\lWOTJ UATJ ouµcpwv<X µe: 'tO mpL0wpto 2436(1), 'tO XOAO\I 0<X 1tpe1tEl µoA<X't<XIJ't(X \l(X qiepe:l OIJO 7ttll<XXioe:,; ouµqiw11<X µe: 'tO U7t00eljµ<X No 4.2 (op<X 7te:pt0wpto 3901). (2) B<XpEAl<X mplEXOll't<Xl cpwocpopo 'tOU 1 ° X<Xl exo11,:(X ~t­ OW'tO XotAuµµ<X/1twµ<X, 0<X 1tpe1tEl \l(X qiepou11 E7tl 1tAEOII O'tO E7t0t\lW µe.poi;; X<Xt oe: OIJO EX 0t<Xµhpou <Xll'ti0e:,:e:,; 0eae:L,;, OIJO 1tl\l<XXi6e:,; ouµcpwll<X µe: 'tO U7t00Eljf,l<X No 11, e:x,:o,; <XII EL\l<Xt E(j)WOL<XOfJ.Ell<X f,1.E OIJO'tljf,l<X 7tOU 't(X Xp<X'tEt op0l<X, (3) KoA<X 7tEplEXOll't0t ooxdat e:cpwOt<XOf,lEll(X µe: e:i;<Xe:plO't7jpE,; XOtl ooxe:lat e:cpwOllXOfJ.EIIIX µe: e:i;<Xe:plO'tTJpE,; xwpl,; e:!;w,:e:ptXTj ouoxeucxoicx, 1tou 1tapLexouv ouoie:i;; ,:ou 6 ° (<X), 0<X 1tpe1te:t ll<X cpepow oe: Buo IX7tE\IIX\l'tl 7tAe:upei;; m11cxxlocx ouµcpwvcx µe: 'tO U7t00Eljf,l<X No 11. KoA<X mplEXOll't(X au0p<XUO't(X ooxe:i<X 7tOU OE\/ cp<XL\10\l't<Xl <X7t' ei;w, 0<X 1tpe1tEt \l(X cpepow mvcxxioe:,; ouµ­ cpw11<X µe: 'tO U7t00Eljf,l<X No 12. Av 't(X e:u0p<XUO'tlX ooxe:i<X 1te:pte­ xou11 tljp&., 'tilt XOA<X 0<X 1tpe1tu rni 7tAEOII, - \l(X cpepou11 7ttll<XXL­ oe:,; ouµcpw11cx µe: 'tO tl7tOOEljf,llX NO 11. Ot 7tl\llXXLOE,; 0cx 1tpemt \l(X EL\l<Xl 't01to8E'tljf,lEIIEt; O'tO Ot.\lW µepo,; Mo Ot7tE\l<X\l'tl 1tAe:upw11 e:vo,; Xl~W'tLOtl, TJ X<X'tOt. (X\l'tLO'tOlXO ,:po1to oe: OtlOXW<XOie:,; Ot.A­ Aou 't1J1tou. B. Arn,:oµe:p'Tj O'tOlXe:i<X O'tO enpcxcpo f,lE'tlXcpopdt,;. H 1te:pljpcxcp71 'tW\I e:µ1topeuµ&.,w11 O'tO enpcxcpo µe:,:cxcpop&.i;; 1tpe1te:L \l<X ouµcpwve:l µe: e11cx <X7to 't<X 011oµ<X,0t 1tou u1to1p<Xµµl­ ~O\l't1Xt O'tO ltEpt0wpto 2431. 'Oitou 0£\1 (X111XcpEpE'tlXL 'tO 011oµcx 'tljt; ouolcx,;, jl<X 'tilt 2 °' 3 °, 9 °' TJ 10 °, ·e(X 1tpe.mt VIX <Xll<XcpEpE­ 'tlXl TJ e:µ1topLX7J 011oµ<Xoi<X. H 1topt1pcxcp71 ,:w11 e:µ1tope:uµ&.,:w11 0<X 1tpemt \l(X tl1to-ypcxµµl~e:'t1Xt XIXL \/IX cxx0Aou8ou11 't(X Arn'to­ µe:p'Tj O'tOlXEtlX 'tl]t; XAotoe:w,;, 0 cxpt0µo,; e:ioou,; (µ<Xl;i µa 'tO q>l]­ cp[o (XII u1t&.pxu) X<Xt 't<X <XPXLXOt. «ADR» (71 «RID»), n.x. 4.2,5 ° (<X) ADR. r. Kave,; ouoxe:u<Xoie:,; ( 1) Kave,; ouoxe:u<Xoie:,;, cxx<X0&.ptoi:e:,; ,:wv 14 ° xcxt 15 ° 2443 2444 2445 2446 2552 2453 1tpe1te:l \/IX xAe:i\lO\l't<Xl XIX'tOt. 'tO\I loto ,:po1to X<Xt \/IX EL\l(Xl cxocpcx­ Ae:[,; xcx,:dt Ol<XppoTJ,; o,:ov iow ~ixeµo o<X11 \l(X TJO<X11 1t:>.71pe:1,;. (2) Kave,; ouoxaucxoie:,;, <Xxcx80t.plo'tE<;, ,:ou 14 ° xcxL 15 °, 0<X 1tpe1te:l \l(X cpepou\l 'tlt; iote:,; 7tl\l<XXioe:,; Xl\lOIJ\/Otl OIX\11/(X TJO<X\I re:­ µdt,:e;,;, (3) H 7topljp<XcpTJ O'tlX Ejjp<Xcpo f,1.E't<Xcpopdt,; 0cx 1tpe1te:t \l(X ouµcpwvd µe: E\IIX (X7t() 'tilt tl7t0jp<Xµµtoµev<X 0\/0f,I.CX't<X O'tO 14 ° X(Xl 15°, 7t,x,: Ke:v~ OtlOXEtlOL<X, 4.2, 14°, ADR. 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Tot BoxEiot Sot otacpotAi,011-cott fLE ot1toppocp71-ctx6 Xott dtxotua-co ot1toa~Ea,tx6 uAtxo OE dtxotua-cot 1tpoa-cot-cw-ctxdt E1671 auaxwotaiotc; ot6tot7ti­ pota-cot ot1t6 uypdt txotvdt vet auyxpot-couv -co 1tEptEXOflE\IO -cwv BoxEtW\I, To XAEtOlflO "CW\/ BoxEiwv Sot 1tpoa-cot"CEUE'tott Ol7t0 7tWfLot'Cot, Eotv -cot 1tpoa-cot-cEU-ctxdt Ei671 auaxEuotaiotc; 6Ev XAEiouv 1tA71pwc;. f UotALVE<; cptotAE<; XAELOfLE\IE<; fLE yudtAtvouc; ot\lotO"COAEl<; fl1t0 pouv E1tia71c; vet otacpotA[,onott fLE ot1toppocp71-ctx6 xott dtxotua-co Ol7tOO~EO'ttXO UALXO OE l;uAtVot Xt~c;mot iiE 7tA7lpEt<; 7tAEUpic;. KoAot 1tEptixonot EuSpotua-cot 6oxEiot Xott flE'totcpEpofLE\lot oxt we; 1tA71p71 cpop-ciot 6Ev 1tpE1tEt Vet ,ur[,ouv 1tEptaaotEpo "CW\/ 75 KG xm Sot 6totShouv xup0Aot~71. 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(5) KoAot 7tEptEXO\l'tot EuSpotua-cot OOXElot 71 OOXEtot Xot'tot­ OXEUOlOflE\lot Ol7t0 1tAOlO"CLX7I UA7I (~AE7tE (2) Xott (3 )), EotV 7tEpti­ xouv uypdt, Xott XOAOl 7tEptixov-cot EuSpotua-cot OOXElot 71 ooxEiot xot-cota'xwotafLEVot ot1t6 1tAotanx71 u)..71 (~AE7tE (2)), Eotv 1tEpti­ xou11 fLOVOV O't'EpEic; UAE<; Xott flE'totcpiponott oxt we; 7tA7lpE<; cpoptio, 6Ev 1tpi1tEL Vet ,ur[,ouv 7totVW ot7:6 75 KG. KoAot flE­ cotcpEpofLEVot oxt we; 7tA1JpE<; cpop1:[o Sot 6totShouv XEtpOAot ~7111. • ( 6) KoAot 7tOU fl7tOpOU\I Vet XUAtSouv OEV 1tpE1tEL Vet ,ur[,ouv 1tEptaao1:Epo Ol7t0 400 KG· EotV ,ur[,ouv 7tEptaao-cEpo "CWV 275 KG 1tpimt vet 6totShouv xuAtOfLEVE<; 01:EcpotvEc; (Rolling Hoops). (7) Aoxeiot 1tEptEXOV'tot O't'EpEot X AWptxdt otAot'tot 7tA7IV '!:WV otvotcpEpOfLE\IWV u1to 1:0 a1:otxEio11 (8) OE\/ 1tpa1tEL vet 1tEptexou11 XotUOLfLO UALXO 7tA TJV fLLXpou 1totpEfL~UOfLOl'tO<; Ol7t0 x71p6 Xotp1:o. (8) Edtv -co X Awptxov otAotc; Eivott u1t6 fLOpcp71v 6tax[wv, fLE'tot TJ otVEU Xot'totM7IAOU OUVOE'ttXTj<; UA7J<;, Xott OUOXEUot,E'tott OE cptotAE<; 7tEptixouaEc; oxt dtvw '!:WV 200 ypotfL., E1totpx71c; 7t000 't7j't0l ~Otfl~Otxo-Ep[ou fL7tOpE[ vet XP7JOLfL07tOtEt'tott ytot vo: Efl7t0 6taSd 7J u1tEp~oAtXT] fJ.Etotxiv7Ja71 1:w11 6tax[wv O"CT)V cptdtA71. Ot cptotAE<; Sot auaxwdt,onott aE xu1:[o: o:1t6 tvoaotvi6ot -co1toSE1:ou­ fLEVot OE EVOL0tfLE07J OUOXEUotO[ot xwpta'tot ot7t0 't7IV E/;W't'EptX7I auaxwotaiot. H Ev6totfLE07J auaxwota[ot 6Ev Sot 1tEptEXEt dtvw -cou 1 KG 71 "CO XOAOV dtvw '!:WV 6 KG XAWptxou otAOt'tO<;. (1) Ot UAEc; '!:WV 6°, 7°, Xott 8° Sot OUOXEUot,O\l'tott: (et) OE ~ot­ piAtot TJ Xt~W'ttot' TJ (~) OE yEpouc; OotXXOU<; Xot'totOXWOlOfLE\IOU<; Ol7t0 O'tEVot ucpot­ OflE\10 ucpotOfLOl TJ Ol7t0 ycpo X0tp1:[ "COUAotXLO'tO 7tE\l'totcpuMo Tj, OE 1toao'tT)tE<; fl7J u1tEp~oti11ouaEc; -cot 50 KG, OE adtxxouc; xot-cot OXEUotOfLEVouc; ot7t0 Xot'totM7JA7I 7tAotO'tlXTJ UA7I E7totpxouc; 7tot­ xouc; Xott YEPTJ<; WO"CE Vot ot7tOCflEUYE'tott 07tOtot01j7tO't'E ot7tWAEtot '!:OU 7tEptEXOfLE\IOU, Edtv 71 UA7I El\lott 7tEptaao't'Ep0 uypoax07tLXTJ ot7t0 "CO \lt'tptxo 2505 vdt-cpto, ot adtxxot 0t xot-cotaxEuotafLEVOt ot1t6 a,E\lot ucpotOfLE\lo' • U(jlOlOflot 71 ot7t0 ycpo xotpt[ 7tEV'CotcpuUo· 1tpE1tEL Vot E7tEV6UOV'totL flE xot1:otM7JA7J 1tAota-ctXT] UA7J TJ \lot xot0ia-cot11-cott ot6tot1tipota1:0t Otot Xot'totM 7IAOU fLEOOU. KoAot 'tot 07t0lot fL7t0pOU\I Vilt XUALSouv OEV 1tpE1tEL Vot ~uyi­ ,ouv 7tEptaao't'Epo ot7t0 400 KG, EotV ,uri,ouv 7totVW ot7t0 275 KG 1tpE1tEL Vet ELVott ECflOOtotOfLEVot fLE XUALOflE\IE<; O'tE(flot\lE<; (Rolling Hoops). (1) OL UAE<; 't7J<; 9° (et) Sot OUOXEUot,O\l'tott: 2508 (Cl) OE ~otpEAtot Ol7tO xdtAu~ot. TJ (~) OE 6oxEiot Xot'totOXWotOfLEVot Ol7t0 cpuMO-fLE'totMou, cpuMo at671pou E7tE\IOEOUfLEVO fLE fLOAU~6o, TJ ot7to AEUXOOL07Jp0 otacpotAL,OflE\lot OE l;uAtVot Xt~W'ttot auaxwotaiotc; exov-cot fLE'totA­ ALXTJV E7tE\IOU07J Xot'totO"CotOot\l O'tE-yotVT]V, 1t-X· fLE fLOAU~O­ auyx6A7J07J. 2506 '0-co:v fLEtotcpipov-co:t, we; 1tA71pEc; cpop1:[o ot UAE<; t7J<; 9° (o:) 1tpi1tEt vet auaxwdt,ov1:o:t OE 6oxEiot o:1t6 1tAotxot xo:aaL'tipou 't01tOSE't7lflE\lot 0:7tOXAELO'ttXwc; OE 1tpoatot't'EU"CLXOU<; at67Jpouc; xo:AdtSouc; (Iron Hampers). 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(1) To -cptol;Et6to -cou XPWfLLOU (10°) Sot auaxwot,E'tott: 2509 (o:) OE 6oxEiot Xot'totOXWO:OfLE\lot 0:7tO UO:AO, 1topaEAotV7J, Ei67J XEpotfLELXTJ<; 71 7totp0fl0lot UAtXot, acptx-cdt otacpotALOfLE\lot OE l;uAt\10 xt~w1:t0 fLE ot6po:vi:; xott ot1toppocp7Jttx6 ot1toa~EO'ttx6 UAtxo· TJ (~) OE flE'totMLXot ~otpEAtot. (2) KoAot 1tEptixov1:ot EtiSpcxua'tot 6oxEiot flE'tCXCflEPOfLE\lot oxt wi; 1tA7lpEc; cpop1:io 6Ev 1tpi1tEt vet ,uri,ouv 1tEptaao't'Epo cx1t6 7 5 KG xcxL Sot Et\lott Ecpo6totafLEVot fLE XEtpoAcx~71. KoACX LXO:Vot Vot XUALOUV 6Ev 1tpi1tEL VO: ,uri,ouv 1tEpLaao't'Epo cx1t6 400 KG· 1tpimt vo: Eivo:t Ecpo6LotafLiVot fLE XUAtOfLEVE<; a't'E­ cpotvEc; (Rolling Hoops) EotV ,uri,ouv 7tEptaao't'Epo CX7t0 275 KG. 3. Mtx1:71 auaxwotaicx (1) ·nEc; Oflcxoo1tolTJfLE\IEc; u1to -co cxu1:o ypdtfLfLot fl1topou11 2510 \lot OUfl7tEptAotfL~dtvonott 01:0 [OLO xoAov. 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U.IIJ\l()O'(Ol 'UIIJ91'(n3 'U.IIJ'(ll\lO 'U.IIJTilO'( ·01\lO(lllO Xll ':,i}.1nl0 :i130(!)1\3 llOX lOJl\(l)TITilO 'XlllO'(~ u.g(!ldodio(l)dioitn '(i}.didorl noiti},gJ01oito c;iitn) lOXJOd911~ 0111rloJOng,g11no u.rl t;JltlO llOll\OAJd(l)X JOI\ 1,it1du "U.I\J~Xldgn '11op9 'Xl130 lOX!)Ol(l)A)O ~llC1TI 'Xl130 ~x111ocb'(noo Xld•(l')•'(• '()30 119x1d1111 '!)30 119x1xu.rldorl '!)30 119x1'(nX1'(lOO 'i;i30 c;ix1.0~11,9 'i;i30 9x130 'Xlf3o ~x111JOdi'(noood(I)'( X 'i;i30 c;ix11•0 '')30 c;ix1d(l)'(Xodgn ':i-.1ono :i1x11019,d, :,3111rlu.1ouo110.l •O'(Xl :i1dJ..o ':io130 i;iox1do9diodgn XlllO'(~ 'odc;idio (l)di 0111xxc;ix 'U.11Jdl0unxod1111 u.111rlo11no'(itrl, :i(!)M(lOXl -.rl 1J01110A~n.xono JOI\ 1,it1du MV ;1,3~1l01v :i1x1g13 :))I s·v :))I s·v :))I s :))I s :))I s :))I s :))I s·z ·dJ.. 00S :))I s :))I s :))Is :))I s :))I Sl"Z :))I 1 "1l0l3lt1dl1lt3 11,g lOJOl003XOno l}.1x1w I\O'(c;iX opXog lOl\lO Xll\lO ~1u.19oou Ul~l(l)~v ( ')30 <pcrrl(l)dX) ;u.11dgn11JO ;9x11JOTl(l)dX lOllO'(V. ~)(11\lOJ..J..JOTld,it.t XlJ,Xog Xl'('(~ 30 XlpXog l01onJOd9!)• ,o Xl19J•3od,it ,i ;•'(': ,o ;.•m. XlllO'(V. ~x1d(I)'( Xd,it .l lOJ,Xog lO'('(~ 30 JOJ,Xog J01onl0d(l!)• .o XlllO'(V. ~x1d(l)'(X oi, :iu.1 ll(!l'(n XlllOTI')'(XllV ')30 c;ix1d(I)'( Xd,it .l 0111~9.rlod1111JOd1,.r, ·no119J..odgn no1 no1g1,3odwn %09 l\(l)l (1)1\~ l0ll\OX11d ,lt no119.lodgn no1 no1g1,3 od,itn lOllOTI')'(Xllg J01111~gn 1JOx no119J..odgn 01gp3odw .l :iu.'(i;i l}.cblOdJ..,d,u ll 11 (Od3.LA3V lOXA3.L) l03lHNd38A>I lH.1 lld3lf\lH<D3 001 (J..)06 (8) llOX (X>)o6 08 'ol '.9 (g) ~ (.l)o'V os ~ (s)ov (lO)oV o'V 0£ oZ ol '.:inog13 ·dy :1odc;i 1ox1g13 f'0I )13<1> 1178 E<l>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: AEYTEPO) 4. Ev6d~etc; (µcxpxti.ptoµcx) xcxt E,txinc; xtv6uvou mi ,wv xoAwv (~AE1tE Tipoo0iJx71v A. 9) ( 1) KoAot 1tEptEXOV'tot UAE<; ,71<; KA<XOEW<; 5 .1 0cx cpipouv m­ XE'tot ,ou µoV'tiAou No. 5. Ev ,ou,otc;, xoAot 1teptix ov,cx uAec; ,71.; 1 ° ewe; 5° iJ ,71.; 8° - 1 o• 0cx cpipouv Mo mxinc; ouµcpwvcx 1tpoc; ,o µov,iAo No. 5. KoAcx 1tEpLixov,cx uAac; 'tTJ<; 3° 0cx cpipouv em1tpoo0i,wc; m­ xi'tcx ouµq,wvcx 1tpoc; 'tO µoV'tEAO No. 8. (2) KoAot 7tEpLEXOV'tot eu0potUO'tot Boxeicx µ71 opot't<X ot7to i~w 0cx cpipouv E,txi,cx ouµq,wvcx µe ,o µov,iAo No. 12. E<Xv ,ex Eu0potUO'tot Boxe[cx 1tEptixouv u,p<X, 'tot xoAot, E1tmpoo0i'twc;, ex,oc; 1tpoxetµivou 1tepi oq,pot1toµivwv otµ1touAwv, 0cx q,ipouv E,Lxi,ec; ouµcpwvcx 1tpoc; ,o µoV'tiAo No. 11 • ot E,Lxinc; otuhc; 0ot 't01to0E'tOU\l'tott 471A<X OE 6uo otv,t0anc; 7tAEupic; 'tW\I Xt~W­ 'tLW\I iJ xcx,<X ,p61tov too6uvotµov o,otv xp710Lµo1totouv,ott <XAAot ei671 OUOXEUotoicxc;. B. - L'tOtXElot 'tOU er,p<Xq,ou µE,otq,op<Xc; H 1tEpLrpcxcpiJ 'tW\I eµ1topwµ<X,W\I O'tO inpotcpo µnotcpop<X~ 1tpE1tEL \lot ouµcpWVEl µe µ[ot 'tW\I OVOµotOtW\I 'tW\I U7t01potµµL­ oµEVW\I O'tO 1tEpL8wpLO 2 50 l • 1tpE1tEt \lot u1torpotµµi,E'totL µe xoxxtvo xott otxoAou0ei,ott ot1to 'tot o,otXELot 't'Tj<; KA<XoEwc;, ,ov otpt0µov 'tOU Ei6ou<; {µot'[ µe 'tO, WXOV, "(p<Xµµot), Xott 'tot otp­ XLX<X «ADR» iJ «RID» (1t.X. 5.1 4° (ot), ADR). r. - Kevic; OUOXEUotOLE<; ( 1) Kevic; ouoxwotoiec;, otxot0<XpLonc; ,ou 11 ° 0ot 1tpi1tEt vot XAEl\10\l'totL Xot'tll 'tO\I t6to ,po1to Xott \lot ot7tOxAElE'tott Xll0E 6totp­ poij, O'tO\I i6to ~cx0µo, Oot\l \lot iJocxv 1tA71pui;. (2) KEYE<; OUOXEUotoiEc; 'tOU 11 °' otxot01XptO'tE<;, 0cx 1tpi1tEL Vot q,ipouv ,Le; i6tEc; 1tp0Et601tot71,txic; mvotxt6Ec; ootv vot 71ootv 7tA1JpEt<;. (3) H 1tEpL')'potq,71 O'tO inpotcpo µe,otcpopll<; 0ot 1tpi1tEt \lot El­ \lott ouµcpwv71 µe E\lot ot7t0 'tot ovoµot,ot 7t0U 1tpo,pcxµµot,i,ov'tott O'tO 11 °, 1t-X· Kav~ ouoxwotoicx, 5,1,11 ° ADR. To xdµEvo otu,o 1tpi1tEt vex u1to1potµµi,e,ott. LE 1tEpimw071 xEvwv ~u,Lo­ cpopwv 71 6e~otµEvocpopwv ox71µ1X'tW\I, XE\IW\I ot1toouv6eoµivwv 6e~otµE\IW\I - XO\l'tE7IVEp<; Xott XE\IW\I µtxpwv XO\l'tE7JVEp<; xuµot cpop,iou, otxot0otpio,wv, 71 1totpouoot 1tEpt1potcp71 0ot 1tpi1tEt vot ouµ1tA71pwVE'tott µa 't'l]\I 1tpoo8ijx71 ,71.; cpp!XOEW<;: «TEAEU'totlO cpop,io» µot'U µE i0 ovoµot XotL 'tO\I otpL0µo d6ouc; 'tW\I Eµ1to­ pEuµll,W\I 7t0U cpop,w071xotv "(Lot 'tEAEU'totlot cpopll, 1t-X· TEAEU­ 'totlO cpop,io: U1tE o~Ei6Lo u6 o ovou, 1 °. ( 4) KEvot ucpcxoµll,Lvot o<Xxxot, otxcx !Xpto,ot, 1tou 1tEptEixcxv \IL1:pLXO \lll'tpLo 'tOU 7 ° (ex) U7tOXEl\l'tott O'tt<; 6Lot'tll;EL<; ,71.; KAll­ OEW<; 4.2. (~AE7tE 7tEpt0wpto 2441). KAAl:H 5.2 OPfANIKA YTIEPOEEIMA . 1. Kot'tilO'totOTj UAW\/ ME,ot;u 'tW\I UAW\/ Xotl Et6wv 'tW\I XotAU1t'tOµivwv U7tO 'tO\I 'tl'tAO\I 't7I<; KA!XOEW<; 5.2, µovov 'tot ot\lot')'potcpoµEvot Et<; 7tEpt 0wptov 2551 El\lott 6ax't<X ')'tot µE,otcpopll, XotL 'tO'tE µovov U1CO 't7I\I EmcpuAot;71 'tW\I 6Lot't<X;EW\I 'tOU 7totpov,oc; Tiotpotp,iJµot'tO<; Xott 'tOU Tiotpotp,71µot,oc; B. Ot UAE<; otU'tE<; Xott Ei671 1COU rtvo­ \l'tott 6EX'tll "(tot µa,otcpopll U7t0 opLoµivouc; opouc; 0ix 0awpou­ \l'tott we; uAE<; Xott ei671 ,71.; ADR. LT)µELWOT): - Op,otvtXll U1tepo;d6tot 'tot 07t0lot µ1topouv \lot EXpot')'OU\I OE E1totcpiJ µe cpAo')'ot 1j 'tot 07t0lot Et\lott 7tEptooonpov Wotio071,ot O't7I\I xpouo71 Xott 't7I\I ,pt~iJ ot7t0 'tO 6tvt,po~EV,0At0 Be ')'l\10\l'tott 6EX'tll 1'Lot µE,otcpopll EX'toi; Ell\/ Et6txwi:; otvcx,pll­ cpov,ott O't'Tj KAtiOTj lot (~AE7tE 7tEpt0wpto 2101, 10° Xott Ilpo­ o071x71v A.l, 7tEpL0wpLo 3'112; E1tio71i; 7tEpt0wpto 2551, Oµlli:; E xot,w,ipw). Oµlli; A 1° Y1tepo;ei6to 6L,pL,oya11oui:; ~ou,uAiou (DITERTIARY BUTYL PEROXIDE). . 2° r6 ou1ta o;ai6Lo·, t,o avoui:; ou,uAiou (TERTIARY BUTY D O I ) µa oxt t"(O'tEpo 'tOU 20 O'tot EXot'tO\I U1tepo;at6tou 6t,pt'tO"(E\IOU<; ~OU'tUAlOU Xott oxt At')'O­ npo ,ou 20 o,cx Exot,ov cx6potvo1tot71nxiJi:; ouoioti:; (PHLEG­ MATIZER). L7JhEtwyi: - Y6pou1i:epo~d6to ,pt,o1Evoui:; ~ou,uAiou TERT AR BUTYL HYDROPEROXIDE) µa oxL At1onpo 2511 2512 2513 2514 2520 2521 2522 2549 2550 2551 ,ou 20 o,ot. Exot,ov u1tEpo;EL6iou 6t,po,L1Evoui:; ~ou,uA[ou otAAll xwpii:; ot6potvo1tot7]'tlXYJ ouoiot otVotjplltpE'tott u1t6,p,ot­ xdov 31 •. 3° Y1ta o~txov, t,o Evii:; ou,uAto (TERTIARY BUTYL PERA ET ATE) µa oxt At,wnpo 'tOU 30 O'tot EXot'tO\I ot6pot­ \107tOt7]'ttX1j<; ouoioti:;. 4° Y1tEp~Ev,oi:xo ,pt,oyevii:; ~OU'tUAto (TERTIARY BUTYL PERBENZOATE). 5° TERTIARY BUTYL PERMALEATE µa oxt At1w,epo ,ou 50 o,ot axot,ov ot6pocvo1tot71nxiJi; ouoioti:;. 6° ~Luna 0otALxov OL't L'to avii:; ou,uALo (DITERTIARY BUTYL IPERPHT A AT ) µa oxL At1w,apo ,ou 50 O'tot . EXot'tOV. ot6potV01tOL7l'tLX1J<; OUO[oti:;. 7° 2,2 - BIS (TERTIARY BUTYL PEROXY) BUTANE µa OXL AL')'W'tEpo 'tOU 50 O'tot EXot'tO\I cxopcxvo1tOL7l'tLxiJi:; ouoioti:;. 8° Y1tEpo;eioto BEv,ouAtou: (ex) µE OXL AL1'W'tEpo 'tOU 10 O'tot EXot'tO\I uowp· (~) µE oxt ALjW'tEpo 'tOU 30 O'tot EXot'tO\I ot6pcxvo1tot71nxiJi:; ouoicxi:;. LT)µELWOEL<;: - 1. - To u1tEpo;Ei6Lo ,ou ~Ev,ouAiou OE ;71ptiv Xot'tllO'tot07] iJ µE AljW'tEpo 'tOU 10 O'tot EXot'tO\I uowp iJ At')'W 1:EpO ,ou 30 o,ot EXot,ov ot6pcxvo1toL71,LxiJi:; ouoioti:; ELVotL uA71 ,71,; KA<XOEW<; lot (~AE1CE 1tEpL8wpto 2101 10· (ot). 2. - r 1tEpo;at6to 'tOU ~E\l,OUALOU 1tEptixov OXL AtjW'tEpo 'tOU 70 o,cx EXot,ov ;71p1X xotL otOpotviJ o,EpEll OEV U7tOXEt'tott O'tt<; otot,ti;Eti:; ,71,; ADR. . , 9• Y1tE o;Ei6tot xuxAoE;otvoA i:; (I - HYDROXY - I? HYDROPEROXY DI YCL HEXYL PEROXIDE AND BIS (1-HYDROXY CY CLOHEXYL) u1tepo;Ei0Lo xoct µtr­ µot,;ot 'tW\I ouo otU'tW\I E\IWOEW\I )): (ot) µa oxt Atrw,Epo 'tOU 5 O'tot EXot'tO\I uowp· (~) µE oxt At')'W'tEpo 'tOU 30 O'tot EXot'tO\I otOpcxvo1tOt7l'tlX1j<; ouoioti:;. LT)µELWOEti:;: - 1. - Y 1tEpo;Et6tot xuxAoE;otvoA71i:; xoti 'tot µtr­ µcx,ti 'tOU<; OE ;71pll Xot'tllO'totO'Tj iJ µE Atjwnpo 'tOU 5 O'tot EXot­ 'tO\I uowp 71 At')'W'tEpo 'tOU 30 O'tot ~Xot'tO\I otOpotvo1tot71,txiJi:; otioicxi:; El\lott UAE<; ,71,; KAlloEwi:; 1 oc (~AE7tE 7tEpt0wpto 2101, 10• (~)). 2. - r 7tEpo;ai6tot xuxAoE;otvoA71i:; Xotl 'tot µijµot'tti ,oui:; 7tE­ ptEXOV'tott oxt AtjW'tEpo 'tOU 70 O'tot EXot'tO\I ;71pll Xott ot6pocv71 o,EpEll OEV u1toxatv,ott o,ti:; Otot,ti~Eti:; ,71,; ADR. 10° cx.ot - DIMETHYLBENZYL HYDROPEROXIDE (uopou1tEpo;doto 6tµE0UAO~Ev,uXtou) (CUMYL HYDROPE­ ROXIDE) µE 7tEptExoµevo OE U1tEpo;ai6to µ71 U1tEp~IXL\IO\I 'tO 9 5 O'tot EXot'tO\I. 11 ° Y1tE~o;Et6to DILAUROYL. 12° 1,2,,4 - TETRANYDRO - 1 -.NAPHTYL HYD­ ROPEROXIDE. 13° 2,4 - DICHLOROBENZOYL PEROXIDE (u1tapo­ ;Et6to OtXAwpo~Ev,ouAiou ) . (ot) µE oxt AtjW'tEpo 'tOU 10 O'tot EXot'tO\I uowp· (~) µE oxt At,wnpo 'tOU 30 O'tot EXIX'tOV otOpotvo1tot711:txiJi:; ouoicxi:; (PHLEGMA TIZER). 14° P-MENTHANYL HYDROPEROXIDE µE 1taptEXo­ µevov ati:; u1tepo;Ei6to µ71 u1tEp~otivov ,o 95 o,ot exot,ov (u1to­ AoL1tov: otAXOOAott Xott XE'tO\lott). 15° 8,6,6 - TRIMETHYL NORPINANYLE HYDRO­ PEROXIDE (PINANYL HYDROPEROXIDE· PINANE HYDROPEROXIDE) µE 7tEptexoµEVO Eti:; U1tEpo;EiOtO µ71 u1tap~cx[vov ,o 95 o,ot exot,ov ( u1t0Aomov: otAXoAott xott XE'tO\lott ): C • 16° DI- a,a - DIMETHYLEBENZYL PEROXIDE µe 1tEpLEXoµEVO\I EL<; U1tepo;d LO µ7] U1tEp ot(\10\1 'tO O'tot EXIX'tO\I. LTJµEiwoti:;: - DI - (A, OC-DIMETHYLBENZYL). • . To U7tEpo;ei6to 'tOU DICUMYL 7tEptixov 60 O'tilt EXot'tO\I 71 Xott 7tEpLOOO'tEpov O'tEpEll Xott ot6pcxv71 O'tEpEll OE\I U7tOXEt'tlXt O'tL<; OLot'ttX~EL<; ,71,; ADR. 17° PARACHLOROBENZOYL RPEROXIDE Y1tepo;eioto (IlcxpocxXwpo~E\l,ouA[ou (: ( ot) µE OXL AL"(W'tEpo 'tOU 10 O'tot EXot'tO\I uowp· (~) µe OXL At1wnpo ,ou 30 o,cx exot,ov cx6potvo1tot71,txrii:; ouoicxi:; (PHLEGMATIZER). LT)µEiwaT): - 1. - To u1tepo;e!6to 1totpo;xAwpo~ev,ouAiou OE ;71pll Xot'tllO'tlX07I 71 µe AL')'W'tEpo 'tOU 10 O'tot EXot'tO\I uowp 71 E<DHMEPII: THI: KYBEPNHI:EQI: (TEYXOI: ~EYTEPO) AL1wupo ,ou 30 ow. Exot,ov ot6potvo1tot7J'tLX7ll; ouoioti; ELVotL uATJ ,7Ji; KAixocwi; lot (~AE7tE 1tEpL8wpw 2101, 10° ('()). 2. - To u1tEpo;d6w mxpot;,cAwpo~Ev~oi.iAiou 1tEpLE)(OV 70 't0LI; EXot't0V 7J 7tEplOO0'tEpov ;71pii Xotl ot6pexv7J oupEIX 6av U1t0XEL'totl o,ti; 6tot,ii;EL<; ,71.; ADR. 18° DI-ISOPROPYLBENZENE HYDROPEROXIDE (ISOPROPYLCUMYL HYDROPEROXIDE) µc 45 ,oti; EXex't0V µi'(µot otAXO0ATjl; Xexl otXE't0VTj<;, 19° 4-METHYLPENT AN - 2 - ONE PEROXIDE (ISOBUTYLMETHYLKETONE PEROXIDE) µE o;,ct AL1w,Epo ,ou 40 o,ex axex,ov ex6potvo1tOLTj'tLX7j<; ouoiotc;. 20° TERTIARY BUTYL (a,a 1 DIMETHYLBENZYL) PEROXIDE µa 0)(L 1tapL006,apo ot1t6 95 o,ot axex,ov u1tapo~ai6w. 21° "f1tapo~d6to DIACETYL (i\w:xa,uAiou) µE 0)(L AL1w,apo ,ou 7 5 o,ex Exex,ov ot6pexvo1tOL7l'tLX7lc; ouoioti; (PHLPGMA TIZER). 1 22° Ympo~d6w otxnuAo-~av~oi.iA.iou (ACETYL BENZOYL PEROXIDE) µE 0)(l ALyw,Epo 't0\l 60 O'tO( EXot't0V ot6potV07tOLTj'tlXTJI; ouoiati;. LTJµdwoLc;: - ITapi 1 ° e.wc; 22°. ·nai; 7t0\l ELVotl ot6potVEii; oa op1otvLxii tmEpo;ai6Lot XatL e.;,couv 071µdov otvexcpAE;Ewc; 0)(L • ;,cexµ7JA0,Epo 'tWV 100 ° C xexL 07jµdov ~potoµou 0)(l )(otµTjAO'tEpo 'tWV 150 ° C 8Ewpouv'texl 0'tl ELVotl ex6pot1107tOLTj'tlXE<; uAac;. Ot UAEc; 't'Tjl; Oµii6oc; A µ1topouv a1tio71c; vex expexLw8ouv µE 6iotAu,oti; 1tou dvexL ot6potvaic; oni; \JAE<; exu,Ei;. Oµiii; B 30° Ym o~Ei0Lo Bou,otvoviou exL8uA.o- E8uAO-XE'tOV U1tEpo;Ei6to) (BUTA NE PEROXIDE (ETHY METHYL KETONE PEROXIDE). (ex) µE 0'/..L AL1w,Epo ,ou 50 o,ex Exot,ov ot6pexvo1toLTj'tLX7lc; ouoiot~ (PHLPGMA TIZER)· (~) oE 6LotAuµot,ex 1tEpLl;,cov,ex oxl ixvw ,ou 12 o,ot Exot,ov ,ou U1tEpo;ELOiou exu,ou oE OLexAu,ac; 1tou ELVexL ot0potvaii; EL<; 'tOU'tO. 31° Yopoi.i1tEpo;Ei6LO Tpl'toyEvouc; Bou'tUAiou (TER­ TIARY BUTYL HYDROPEROXIDE): (ex) µE 0)(L AL1w,Epo ,ou 20 o,ot Exot,ov u1tapo;Et6iou ,pL,o 1Evouc; ~ou,uAiou, ;,cwpic; ex6potvo1tot7J'tLX1J ouoiex (PHLEG­ MA TIZER)· (~) OE 0texAuµex,ot 7tEplE)(OV'tot 0)(l 7tEplOO0'tEpo 't0U 12 O'tO( Exot,611 ,ou u1tEpo;u6iou atu,ou oE 6LexAuuc; 1tou Eivext ex6pexvEic; EL<; 'tO\l'tO. LTJµEiWOTJ: - ITEpi 30 ° xexL 31 °. ·nEc; 1t0U EiVotL ot0pexvEic; oE opyexvLxii U1tEpo~aiOLot xexL E)(OUV 071µdov exvotcpAe.~Ewc; 0)(L xexµTjAW'tEpo 'tW\I 10O°c Xotl 071µEiov ~potoµou 0)(l xexµ71Aw­ 'tEp0 'tW\I 15O°C 8Ewpouv'totl we; ex6pcxvo1tOLTj'tlXEc; UAEc;. Oµiic; f 35° 17tEpO;LX0 o;u 1tEplE)(OV 0)(l mptoooupo 't0U 40 O'tO( EXot't0V U7tEpo;tx6 o;u X(XL 0)(l ALywupo 't0\l 45 O't(X EXot't0\I O~LX0 o;u Xotl 0)(l ALywupo 't0\l 45 O'tot EXot't0\I O~LX0 0~\) Xotl O)(l Al'(W'tEpO 't0U 10 O'tot EXot't0V uowp. LTJµELWOTJ: - ITEpi Oµii6wv A, B XCXL r. Miyµot,cx 1tpo't6 V'tW\I cxvotcpEpoµlvwv O'tlt; Oµcit6Ec; A, B Xotl f yivov'totl 6EX'tlX ytcx µE,cxcpopii U7t0 'tTjll EmcpuAex~'Tj 'tWV opwv 'tTjt; Oµcitooc; f EIX\I 7tEplE)(OU\I U1tEpO~LX0 o~u, xexL OE IXAAEc; 7tEpm,woaLc; U7t0 't'Tj\l EmcpuA0t;71 'tW\I opwv 't'Tjc; Oµcitooc; B. Oµiii; I\ 40° . i\Ei1µcx,ex 0t6pexvo1tot716iV'twv opycxvLxwv U7tEpo~EL 6iwv µ'Tj cxvotrpotcpoµlvwv O'tlt; Oµii6Ec; A, B 7l f, 7J O'tot 6LotAU­ µot,ot otu,wv, yivoV'totL 6Ex,cit OE 1too6,71,Ec; µ'Tj u1tEp~cxivouoEc; ,o 1 KG otvcit xoAov u1t6 ,ov opov 6,L 71 o,cx8apo,ri,cx ,ouc; av ot1to871xE~OEL aivotL ,ouACX)(LO'tov io71 1tpoc; axdv71v ,wv uAwv ,wv otvexypotcpoµivwv o,tc; Oµcit6ac; A xcxL B. Oµcitc; E • LTJµEiwoTJ: - H Oµcitc; E mpLAotµ~cxVEL op1otVLXIX u1tapo~ai 6tot 'tot 07tOLex CX1tOOUV'ti8E'tCXL EU)(Epwc; OE OUV7J67J 8apµoxpoto[ot xcxL anoµivwc; ·1tpe.1taL vot µnotcpe.pov,otL µovov u1t6 ouv67Jxotc; Xot'tcxAATJAOU 4u~awc;. MoAO\I0'tl EXPTJX'tlXTJC, cpuoawc; we; opi­ ~OV'totl u1t6 ,7Jc; L7Jµuwoawc; ,7Jc; KAiioawc; 5.2, oAi1a op1ot­ inxii u1tapo~ai6Lot ouµ1tapiJ..otµ~citvov'totL O'tTJV Oµcit6ot E 0L0'tl µ1topouv VO( µa,cxcpap8ouv otocpCXAwc; OE Xot'tE4u,µiv7J Xot'tCX• O'totOTj XCXL 0Lot VO: 0:1tOcpEU1E'tO:L 07tOL0:07J7tO'tE OU'Y)(UOLI; otVotcpo­ plXCX µa ,ov )(ELpLoµo wuc;. 45° 11tEpo;ai6Lo DIOCTANOYL (u1tEpo~Ei6LO DICAP­ RYL YL) 'tE)(VLXTJ<; xot8otp6,7J,oc;. 46° Y1tepo;Ei6w ACETYL CYCLOHEXANE SULPHO­ NYL: ~ mpLE)(OV 0)(l ALYW'tEpO 't0U 30 O'tot EXex'toV u6wp· (~) OE 6LcxAuµex 0)(l ALYW'tEpo 't0U 80 O't(X EXCX't0\I OLCXA\l'tOU' (r) OE 6icxAuµcx 0)(l Al')'W'tEpo 't0U 70 O'tCX EXot't0V ot6potvo 1tOl'Tj'tlX7li; ouoiexc; (PHLEGMATIZER). 4 7° t1tEpo;u6totv8p0txtx6 Moo1tpo1tUALO (DIISOPROPYL PEROXYDICARBONATE): (ot) 'tE)(VLx71c; x0t8otp6,7J,oc;· (~) OE 6iotAuµot µe 0)(l ALyw,apo 't0\l 50 O'tCX EXot't0V ot6pot­ V01tOLTj'tlX7IV ouoiexv 7l OLexAU'tTJV 48° Y1tapo~d6w i\mpomovuAiou (DIPROPIONYL PE­ ROXIDE) OE 0LCXAuµot µa 0)(l AL,o'tEpo 't0U 75 O'tot EXot't0V 0lotA\l't'Tj\l, 49° TERTIARY BUTYL PERPIV ALA TE:­ ( o:) 'tE)(VLx71i; xex8exp6,7J,oc;· (~) OE 6iexAuµex fJ.E 0)(l ALyw,Epo 't0U 25 O'tex EXot't0V ot6pot­ V07t0l TJ'tLX7IV ouoi0tv 71 0LotAU'tTJV. 50° l"1tEpo~Ei6w BIS - (3,5,5 - TRIMETHYLHEXA­ NOYL) OE OlCXAuµex fJ.E 0)(l AL,w'tEpo 't0U 20 O'tot EXot't0V ot0pot­ V07tOLTJ'tlX7IV ouoiotv (PHLEGMA TIZER). 51 • t 1tEpo~ai6to i\mEAexpyovu)-.iou (DIPELARGONYL PEROXIDE), 'tE)(IILXTJI; xot6cxpo't'Tj'tOI;. 52• TERTIARY BUTYL PER - 2 • ETHYLHEXANO­ ATE 'tE)(IILX7JI; xot8otpo'tTj'tOc;. S3° DI-2-ETHYLHEXYL- PEROXYDI CARBONATE OE 6LcxAuµex fJ.E 0)(l Al'(W'tEpo 't0U 55 O'tO( EXot't0V ot6pot1107tOLTJ­ 'tlX7JV OUOL(XV (PHLEGMATIZER) 7J OlotAU'tTJV, 54° l"1tEpo~dOLo DIDECANOYL 'tE;(VLX7JI; xot8otpo't7J­ 'tOI;, 55° TERTIARY BUTYL PERISOBUTYRATE oE OLcit­ Auµcx µE 0)(l ALywupo 't0U 25 O'tot EXot't0\I OLCXAU't'Tj\l, L'TjµELWOEL<;: - 1. - 'UEc; 7t0U EL\lotl cx6potvaic; OE opyotVLXCX u1tEpo~d6Lex· xcxt e.xouv 07Jµdov - otv0tcpAE~Ewc; 0)(L XotfJ.TjAW'tE­ pov ,wv 100 ° C xext oTjµEiov ~potoµou 0)(L )(OtfJ.TJAW,Epov ,wv 150° C 8Ewpou\l'totl we; ot6p0tv01tOL7l'tlXEI; UAEc; (PHLEGMA­ TIZING SUBSTANCES). 2. - Ot otvcxcpEp8iV'tEI; 6totAu,Ec; dvotL uAEc; 0L 01toiEc; dvm exopexvdc; oE opyexvtxix u1tEpo~ai6tot xexL oL onoiac; rnio7Jc; 1tA7J­ pouv ivot 'tWV 1texp0tXIX'tW 6pwv : (ex) 0EV EivexL EucpAEX'tOL xexL E)(OUV OTJfJ.ELOV ~potoµou O)(l ;,cot­ µTjAO'tEpO 'tWV 85 ° C • 7J (~) 6Ev ELVCXL EucpAEX'tOl Xotl E)(OUV OTjfJ.ELOV ~potoµou XIX'tW 'tWV 85 ° C CXAAIX 0)(l XIX'tW 'tWV 60 ° C, 07t0'tE 1tpE1tEl VO( XPTJOl­ µ01tOLO\lV'totl U1to60;,cEic; (60;,cEiot) •PfJ.TJ'tLXwc; XAELOfJ.EVO( 71 (y) axouv 07Jµaiov - cxvotcpAi~awc; 0)(L xix,w ,wv 21 °C Xotl OTjµdov ~p0toµou 0)(l XIX'tW 'tWV 85 °C. 7l (6) e.xouv 07Jµdov - otvotcpAe.;aw;; XIX'tW 'tWV 21 ° C otAAIX 0)(l XIX'tW 'tWV 5 ° C XCXL O~fJ.ELO ~potoµou 0)(l XIX'tW 'tWV 60 ° C, .. 07t0'tE 1tpeml vex XPTJOlfJ.07tOLOUV'tCXL EpfJ.~'tlXWI; XAELOfJ.EVOl U7t000)(Etl; (0O)(ELot ). Oµiiocx I:T 99 ° Kavii d6TJ ouoxauotoiotc;, otxot8ixpto,ot, XotL xave.i; OE~ot­ µave.c;, 0txot8citpLo'tEc;, 1tou mptai;,ccxv uAE<; 'tTJI; KAcitoawc; 5.2. 2.1\Lot'tot~Ell; A. KoAcx 1. • f EVLXO[ opOL OUOXWotOiotc; (1) Tot uXtxcit cx1t6 'tot 01toiot ,ex ai67] ouoxaucxoiotc; xotL ,ex xAELoiµot,ot ,wv xcx,0toxwcit~ov,otL oav 1tpi1tEL vot xtv6uvauouv VO( 1tpoo~A.7J8ouv (X1t() 't0 7tEplE)(0fJ.EVO 71 VO( oXTJ!"X'ti~ouv fJ.E (XU't0 E1tl~otA~Eic; 7l E1tlXLVOUVO\ll; EVWOELI;, (2) Tot EL0TJ ouoxEucxoicxc;, ouµ1taptAotµ~otvoµe.vwv ,wv XAELOlfJ.ot'tWV 'tWV, 1tpE1tEl \lot EiVotl E7totpxwc; otxotµ1t,ot Xotl yapcit OE 0AO: 'tCX µipTJ 't0UI; WO'tE V(X ot1tOcpEu,a'totl 07tOL0:07J7tO'tE )(CXA.citpwo7J 0LcxpxouoTj<; 't'Tjt; µE,cxcpopcitc; Xotl vot 1tA7Jpouv ,ouc; ouv7J8eLc; opouc; µE,otcpopcitc;. OL EOW'tEpLxe.i; ouoxwo:oiac; 80: otocpcxAi~OV'totl O'tot8Epot O'tll; E~W'tEpLxe.i; 0\lOXEUotoiEc;. Ex,oc; acitv illwc; opi~E'tOtL o,o citp8po ,o ,L,Aocpopouµavo «1:uoxEuot-. 1179 2552 1180 E<l>HMEPlr THr KYBEPNHrEQr (TEYXOr dEYTEPO) oio: µuxc; UA7lc;», Ot, EOW'tEpticic; ouoxwo:o[Ec;, µ1topouv VO: E1XAEiov,o:t OE El;w,Eptxic; ouoxEuo:oiEc; EhE µ[o: - µ[o: Ein oµo:otxcx. (3) To 0:7tOO~EO'ttXO UAtXO OEV 1tpi1m VO: ELVO:t EUXEpwc; EU­ (j)AEX'tO' rnmpoa0hwc; 0o: 'tO:LptCX,Et a,71 q,uari 'tOU 1tEptExoµi­ . \IOU XO:t OEV 1tpE1tEL VO: 1tpOXO:AEL 'tTjV 0:1toauv8E07I 'tWV U1tEpo l;EtOLWV. 2. - Luaxwo:oio: tcxc; u). c;. 0:. - Luaxwo:a[o: u WV ,71c; Oµcxooc; A To: OOXEio: 0o: ElVO:L hat XAEtaµivo: XO:t anyo:vcx wan VO: O:ltO(j)EUYE'tO:L 07tOLO:OTJltO'tE 0:7tWAEtO: 'tOU ltEptExoµivou. (1) ·nEc; 'tWV 1° iwc; 7°, 8° (~), 9° (~), 10° iwc; 12°, 13° (~), 14° iwc; 16°, 17° (~) xo:t 18° iwc; 22° xo:t ,o: 6to:Mµo:,cx 'tOuc; 1tpi1tEt vo: auaxwcx,ovo:t: ( o:) OE xo:aampwµavo: 6L' ,Eµ~o:1t,iaEwc; EV 0Epµw OOXELO: ii OE OOXElO: XO:'tO:OXEUO:aµivo: 0:7t0 o:p,uALO (o:Aouµivw) oxt Atyo­ 'tEpo 'tOU 99. 5 O'tO: EXO:'tOV xo:0o:po· ii (~) OE ooxEio:, xo:,o:axwo:aµivo: o:ito xo:,ill71).71 1tAO:O'ttXTJ u).71, ,o: oitoio: 0o: ,01to0E,ouv,o:L aE itpoa,o:nu,txac; auaxEuo:­ oiEc;· TJ (r) oxt cxvw 'tWV 2 At,pwv o:vcx (j)LCXA7IV, OE aq,tx,cx - XAEta,ic; 1uCXAtvEc; q,tcxAEc; 1tou 0o: o:aq,o:Ai,ono:t fLE o:1toa~Eonxo UAtxo OE 1tpoa'tO:'tEU'ttXTJ OUOXEUO:OlO: Etc; ,p01tOV wan VO: 1tpOO'tO:'tEU­ OV'tO:L o:ito ,o -aitcxatµo. (2) •nEc; 'tWV 1 ° ewe; 3°, 5° Ewe; 7°, 8° (~), 9° (~), 10° EWc; 12°, 13° (~), 16°, }8° Xo:t 20° µ1topot1V E1tta71c; VO: OUOXWCX,0 V'tO:t aE 1o:A~o:vtaµivo: (HOT -TIPPED GAL(!ANIZED) 60 XE[o:. (3) Ot UAEc; 'tWV 8° (o:), 13° (o:) XO:t 17° (o:) 0o: 1tEptEXOV'tO:t, oxt mptaao,EpEc; 'tWV 5 KG O:\ICX Eiooc; OUOXEUO:o[o:c;, OE UOO:'tO­ a,Eyo:vcx d671 auaxwo:aio:c; 'tOlt00E'tOUµEvo: OE l;uAtVO XL~W'ttO. ( 4) nmwori ( ao:v ,uµcxpt) XO:L O'tEpECX U1tEpol;EiOtO: µitopouv rniaric; VO: auaxwcx,OY'to:t OE acxxxouc;, XO:'tO:axwo:aµevouc; O:ltO xo:,CXM7IATj 1tAo:a,txiJ t1A7I, ,oito0E,ouµivouc; aE xo:,CXMTjAO: 1tpOO'tO:'tEU'ttXCX EL07I OUOXEUO:OLO:c;. To ltcxxoc; 'tOU UALXOU au­ OXEUO:aio:c; 0o: ElV9(L rno:pxic; WO'tE VO: Eµ1tooi,E'tO:t 01tOLO:OTJ 1ton 0:1twXEtlX fou "1tEptExoµavou 0:7t0 'tOUc; acxxxouc; XO:'tCX 't7I auviJ0ri µEto:q,opcx. To: O'tEpEcx UltEpol;Eioto: µitopouv VO: au­ OXEUCX,OV'tO:L, OXL ltEptaao,Epo 'tOU 1 KG o:vcx OOXElOV, OE 60 xEio: 0:7t0 LVOOO:\ILOO: EmxptaµEV7I µE XTjpOV 1tO:pO:(jllV7lc; 'tOlt00E­ 'tOUµEVO: OE l;t1ALYO XL~W'tLO' EV 'tOU'tOLc;, 1tpoxEtµavou 1tEpi UltE­ pol;Etoiwv XUXAOEl;o:vov71c; ,71c; 9° (o:) 'tO ltEptEXOµEvO 'tOU 60 XELOU 0o: ltEpLOpL,E'to:t O'tO: 500 ,po:µµ. (5) Ot UAEc; ,71c; 10° XO:t 14° Ewe; 18° µitopouv E1tia71c; VO: ouaxwcx,OV'to:t OE ooxdo: XO:'tO:OXWO:OfJ-EVO: 0:ltO (j)UMO - fLE­ 'tCXAAOU. (6) ME El;o:ipEaTj acxxxouc; xo:,o:axwo:aµavouc; o:1to itAo:­ a,txiJ UA7I, to: OOXElO: 'tO: ltEptiXOV't~ uypcx TJ 1AOlW07I (ao:v ,u­ µcxpt) opyo:vLXCX UltEpol;EtOtO: OEV 1tpi1tEt VO: '1tA71pot1V'tO:t 1tipo:v ,ou 93 ,me; Exo:,ov ,71c; xwp71,txo,71,oc; ,wv. (7) To xoAov OEV 1tpi1tEL vo: ,u,i,Et 1tEptaao,Epo ,wv 50 KG. KoAO: ,u,i,ovto: ltCXVW 0:7t0 15 KG 0o: ElVO:t E(j)OOto:aµavo: µE XELpOAO:~TJY, • ~: LuaXEUO:aio: UAWV ,71c; Oµcxooc; B (1) tJ.oxEio: yEµtaµivo: µE UAEc; ,71c; 30° (o:) XO:t 31 °(0:) 0o: Et­ \10:t E(j)OCLO:aµivo: µE µ71xo:vtoµov E/;O:Eptaµou E1tt'tpE1tOV'tO: O:V'tLO'tcx0µta71 µEtO:/;U 't7lc; EOW'tEpLXTJc; ltLEOEWc; XO:t 't'Yjc; o:,µo­ Olj)O:LptXT)c; ltLEOEWc; Xo:t OE XCX0E 1tEpl1t'tW07I - o:xoµ71 XO:L O't7I 1tEpL1t'tW07I EX'tO\IWOEWc; 'tOU uypou OtO: 0EpµcxvaEwc;- Eµn:ooi­ 'OV'tO: 'tO uypo VO: EX'tLYO:X0Ei xo:0wc; XO:t o:xo:0o:pa[Ec; VO: ELOEA 0ouv O'tO OOXElO. fto: UAEc; ,71c; 30° (~) XO:t 31 ° (~), µovov 60 XEiO: E'tOL XAEtoµavo: XO:t anyo:vcx WO'tE VO: 0:7t01j)EUYE't0:t OltOtO:­ OTJltO'tE 0:1tWAELO: 'tOU ltEptExoµivou 0o: "(lVOV'tO:L OEX'tlX. (2) To: XOAO: 0o: ElVo:t E(j)OOLo:aµivo: µE ~cxari 71 OltOLO: VO: 'tO: xpO:'tCX op0to: xwpic; 'tOV x[vouvov \10: 1tEOOUV. (1) Ot UAEc; 'tWV 30° (o:) Xo:t 31 ° (o:) 0o: OUXEUIX,OV'tO:L:­ (o:) OE Eµ~O:lt'tLOµEVO: Ell 0Epµw XO:oampwµevo: TJ Eµ~O:lt'tL­ oµEVO: EV 0Epµw yo:A~O:VLaµivo: ooxEio: ii OE ooxEio: XO:'tO:­ oxwo:aµavo: 0:lt() o:pyuAtO (o:Aouµ[vw) OXL Atyonpo 'tOU 99.5 'tote; EXO:'tO\I xo:0o:po. ii (~) aE ooxE[o:, xo:,o:axwo:aµivo: o:ito xo:,cxM71Ao ltAOtO'ttXTJ UA7I, ,o;co0EtouµEvo: OE itpoa,o:,w,txic; auoxwo:a[Ec;. H o:v,oxiJ ,wv ooxEiwv o:u,wv 0o: Eivo:L E1to:pxiJc; wa,E vo: o:1to­ lj)EU"(E'tO:L 01tOLO:OTJltO'tE 0:7tWAELO: 'tOU 1tEpLExoµivou XO:'tCX 't7I OUVTJ07I µE'tO:lj)OpCXV' TJ 2553 2554 2555 2556 (r) OXL IXVW 'tW\I 2 At'tpwv o:vcx (j)LCXATjll, OE yuCXAtvEc; lj)LCXAEc;, 1tou 0o: o:aipo:Ai,ov,o:t µE o:1toa~EO'ttxo UAtxo aE 1tpoo,o:,w,t­ xic; auoxwo:a[Ec; wan vo: itpoo,o:,Euov,o:t o:ito ,o 01tcxatµo. (2) tJ.oxEio: mptixov,o: uypix TJ YAOLWOTj (00:11 ,uµcxpt) opyo:­ VtXCX u1tEpol;Ei6to: OEV 1tpi1tEL vo: 1Eµi,ov,o:t itipo:v ,ou 90 a,o: EXO:'tO\I ,71c; xwpri,txo,71,oc; 'tW\I, (3) To xoAov OEV 1tpE1tEL vo: ,u,i,EL itEptaoo,Epo o:1to 40. KG. KoAO: ,u,i,ono: 1tEptaoo,Epo 0:7t0 15 KG 0o: E}vo:t Elj)0 6to:aµivo: µE XEtpoAo:~iJv. ( 4) Ot UAEc; 't'Yjc; 3 0° (~) XO:t 31 ° (~) µ1topouv VO: O:ltOO'tEAO­ V'tO:t µovov OE 1toao,71nc; µ71 UltEp~o:[vouaEc; 'tO: 5 KG OE 60 XEiO: we; opi,E'tO:t Etc; (1) o:MCX xwpic; VO: Eivo:t Elj)OOto:aµavo: µE µ71xo:vtaµov El;o:Eptoµou ( OE yuCXALVEc; q,tCXAEc;, µ011011 OE 1toao­ 't7l'tEc; µ71 uitEp~o:[vouaEc; ,o 1.5 Ahpo). To: ooxE[o: OEV 1tpE1tEt vo: 1tA71pouno:L 1tepo:v ,ou 7 5 a,o: Exo:,ov ,ric; xwpri,txo,71,oc; 'tWV. ,. - Luaxwo:aio: UAW\/ 'tTjc; Oµcxooc; r (1) Ot UAEc; ,71c; 35° XO:t µiyµo:,o: ltEptEXOV'tO: U1tEpol;txo ol;u 2557 0o: OUOXEUIX,OV'tO:t, OXL ltEptaao,Epo 0:1t0 25 KG 0:\10: ooxEio, OE yulXAL\10: ooxEio: fLE xovopo 'tOLXWfLO:, TJ OE OOXEiO: XO:'tO:­ OXEUO:aµevo: 0:7t0 XO:'tlXM7IAO ltAO:O'ttXTJ UA7I, Elj)OOto:aµevo: fLE ELOLXO XAELatµo XO:'tO:OXEUO:aµavo O:ltO XO:'tCXMTjA7I 7tAO:O'tLXTj UATj txo:vo vo: aq,po:1 ta0E[ ( an10:1101tot710Ei), aE Emxotvwv[o: µE 't7IV o:,µoaipo:[po: Ot' O:\IOL1µ0:'t0c; XEtµEVOU CXVW0t 't7lc; O'tcx0µ71c; 'tOU u1pou, XO:L OE xcx0E 1tEpL1t'tWOTj - O:X0µ7I XO:L O't7I 1tEpi lt'tW07I EX'tO\IWO~Wc; 'tOU u1pou Ot0:0EpµcxvaEWc; - Eµitoo[,o V'tO:c; 'tO u1po \10: EX'ttVO:X0Ei XO:t O:X0:0o:paiEc; VO: ELOEA0ouv O'tO OOXELO. (2) To: yucxAt\10: OOXELO: 0o: 0:0lj)O:AL,O\l'tO:t a,0:0Epcx, µE XO\ltV ( CXAEUpo) xo:0o:pcxc; µ[xo:c; TJ UO:AO-Epto xp71atµo1totOUfLEVO: w~ o:1toa~EO'tLXO uAtxo, aE 1tpoa,o:,w,txcx Ei671 auaxEuo:aio:c; xo:­ ,o:axEuo:aµevo: O:ltO lj)UMO - XCXAU~oc; TJ o:p,uALO, LXO:\ICX \10: XAELVOUV, XO:t Elj)OOLo:aµevo: µE XEtpoAO:~TJV XO:t ~cxari OLO:'tTj­ pouao: O:U'tlX op0to: xwp[c; 'tO\I xivouvov VO: ltEOOUV" 'tO: OOXELO: 0o: o:aipo:Ai,ovto:t o:xoµri XO:t EIXV 'tO: 'tOtxwµo:,o: 'tWV 1tpoo,o:­ 'tEU'tLXWV OUOXEUO:OtWV OEV El\lo:t ltATJP71· tJ.oxEio: XO:'tO:OXEUO:­ aµavo: 0:7t0 XO:'tCXM7IAO ltAO:O'tlXTJ UA7I 1tpE1tEL VO: 't01t00E,OUV'tO:t aE XAELo,iJc; - Eq,o:pµoriJc; itpoo,o:,Eunxcx ELOTj auaxwo:a[o:c; XO:'tO:OXEUO:Oµevo: O:ltO lj)UMO - XIXAU~O: XO:t tXO:VIX VO: XAEL\IOU\I. 6. - Luoxwo:aio: UAW\/ 'tTjc; Oµixooc; tJ. Ot UAEc; ,ric; OµcxBoc; tJ. 0o: OUOXEUIX,OV'to:t, OE ltOOO'tTj'tEc; µ71 2558 UltEp~o:ivouoEc; 'tO 1 KG 0:\l(X XOAOV, OE xo:oot,Epwµevo: ot' Eµ­ ~0:7t'tLOEWc; Ell 0Epµw OOXELO:, TJ OE OOXELO: XO:'tO:OXEUO:aµevo: 0:lt() o:p,uALO (o:).ouµivto) oxt Atyonpo 'tOU 99.5 O'tO: EXO:'tOV xo:0o:po, ii OE q,tcxAEc; XO:'tO:OXEUO:aµevEc; O:ltO XO:'tCXM 7IAO 7tAO: O'ttXTJ UA7I XO:AOumo:aµevEc; OL' EYXUOEWc; TJ q,uo71µe11Ec; XO:t exouoo:t XO:'tCXMTjAOV 1tcxxoc; 'tOLXWfLO:'tOc;, TJ OE rucxAtVEc; (j)LCX AEc; t01to8Et7lµEvEc; OE 1tpoo,o:,Eu,txiit Ei671 auxwo:oio:c; xo:,o:­ oxEuo:aµEvo: 0:ltO lj)UAO - XCXAU~oc;, o:Aouµi11to TJ l;uAO. Ot yuCXAt VEc; lj)LIXAEc; 0o: 0:0lj)O:Al,OV'tO:t o,o:0Epcx O'tO: itpoo'tO:'tEU'tLXCX ELOTj ouoxwo:oio:c; µE xov71 ( cxAwpov) xo:0o:pixc; µixo:c; iJ uo:Ao-ipto xp71otµo1tOLOt1µEvO: we; O:ltOO~EO'ttXO UALXO. L,EpEEc; EVWOEtc; µ1topou11 rnio71c; VO: OUOXEUIX,O\l'tO:t OE oixxxouc;, XO:'tO:OXWO: oµi11ouc; O:ltO XO:'tCXM7IAO ltAO:O'tLXTJ UA7I E1to:pxouc; 1tcxxouc;, 't0 lt00E'tOUµEVOL oµoiwc; OE 1tpOO'tO:'tEU'tLXCX El07I ouaxwo:oio:c; xo:­ 'tO:OXEUO:oµivo: O:ltO lj)UMO-XCXAU~oc;, O:Aouµivto TJ l;uAO. Ecxv 'tO: UltEpol;EioLO: ~rcx~ouv 0:Epto: OE 0Epµoxpo:o[o: XCX'tW 'tW\I 40 ° C, 'tO( OOXELO: 1tpE1tEL VO: 1tA71pouv ,ouc; opouc; 'tOU 7tEpt0wpiou 2555. E. - LuoxEuo:oio: uAwv 'TT)c; Oµcxoo:c; E (1) KoAo: ltEptexouv,o: uAEc; , 71c; Oµcxoo:c; E eo: Eivo:t Eipooto:- 2559 oµivo: µE µ71xo:11toµov E~O:Eptoµou Em'tpEltOV'tO: 'tTjV O(\l'ttO'tCX0 µtoTj µE,o:~u ,71c; EOW'tEptxiJc; mfoEwc; xo:t ,71c; o:,µooq,o:tptxiJc; • ' ltLEOEW<; XO:L OE xcx0E ltEpllt'tWOTj - O:X0µ7I XO:t O'tTj 1tEpi1t'tWOTj EX'tO\IWCIEWc; 'tOU uypou OLO: 0EpµcxvoEwc; -\ Eµ1to6i~OV'tO: 't~ uypo \10: EX'tLIIO:X0Ei XO:L o:xo:0o:paiEc; \10: ELOEA0ouv O'tO OOXEio: (2) tJ.oxEio: ltEptEXOV'tO: uypix opyo:vtxcx UltEpo~ElOLO: OE\I 1tpi1tEt \10: 1tA71pot1V'tO:L ltEpo:v 'tOU 95 Cl'tO: EXO:'tOV ,71c; xwp71,t xo,71,oc; 'tWV. , (1) ·nEc; ,71c; 45°, 51 ° XO:t 54° 0o: OUOXEUCX,OV'tO:t, oxt 7tE- 2560 ptCICIO'tEpo O:ltO 50 KG o:vcx ooxEiov ii acxxxov, CIE OOXELO: ii aiitxxouc; xo:,o:axwo:aµevouc; o:ito xo:,ill71A71 1tAo:a,LXTJ u).71, ,o: oitoio: iJ oL oitoiot 0o: ,oito0E,ouv,o:t CJE xo:,ill71Ao: 1tpoa,o: 'tEU'tLXCX Ei671 auaxEuo:aio:c; OE 1toao,71nc; µTj u1tEp~o:ivouaEc; ,o: 50 KG O:\IIX eooc; CIUCIXEUO:aio:c;. E<l>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: dEYTEPO) (2) ·nee; 'tTjc; 46° (ex) Bex ClUC!XEUIX,O\l'tCXt, oxt 7tEpLaacmpo cxito 5 KG cxvix aixxxov, ae aixxxouc; xcx'tcxaxeucxaµevouc; cx1to XCX'tlXAA7lA7l ltACXCl'tLXTJ UATj, OL OltOtOL 0cx 't07tOBE'tOU\l'tCXt, oxt IX\IW 20 KG CX\IIX ei6oc; auaxeucxaicxc; XCXt El'tE evcxc; - evac; EL'tE oµcx6txix, aE XCX't!XAATjACX 1tpoa'tCX'tEU'ttXIX ei671 auaxeucxaicxc;. (3) ·nee; 't'Tjc; 4 7° (ex) Bex ClUC!XEUIX,O\l'tCXt: (cx) OXL 7tEptC!ClO'tEpov 'tOU 1 KG CX\IIX 6oxeiov, C!E 6oxeicx xcx­ 'tCXC!XEUCXaµavcx CXltO XCX'tlXAATjATj ltACXCl'ttXYj UATj' (~) oxt 7tEpLC!ClO'tEpov 'tW\I 3 KG CX\IIX µ1twA, C!E µ1twA XCX'tCX­ OXEUcxaµevcx CXltO cxpytiAto\l ( CXAouµ[vto\l) oxt At"(O'tEpo 'tW\I 99. 5 Cl'tCX EXCX'tO\I xcxBcxpov, µe ltACXCl'tLXIX 1twµcx'tCX. To 1tpo·a'tCX'tEU'tLxo ei6oc; auaxwocaicxc; 6ev 1tpe1tEt vex itEpta­ XEt 1tEpLaao'tepcx 'tW\I 10 KG 't7lc; u)..71c;. (4) OL ti)..ec; 'twv 46° (~) xcxL (r), 4 7° (~), 48a, 49° (~), 50a, 52°, 53° xcxt 55° Bex auaxwix~o\l'tCXL, oxL ixvw 'tWY 25 KG cxvix 6oxdo, C!E 6oxe[cx XCX'tCXC!XEUcxaµavcx CXltO XCX'tlXAA7JA1j ltAOtCl'tLXTJ UA7J, 'tCX 01toicx Bex 't01to8E'tOUY'tCXL, oxL ixvw 'tWY 50 KG cxvix au­ ·axwcxaicxv (cxllix oxL ixvw 'tWII 25 KG cxvix auaxeucxaicxv 1tpo­ XELµe11ou 1tepi UAWll 'tTjc; 52°), aE 1tpoa'tCX'tEU'tLxec; auaxwcxaiEc;. (5) Ot UAEc; 't7lc; 49° (ex) Bex ClUC!XEUCX~O\l'tCXL, oxt CX\IW 'tW\I 10 KG CX\IIX 6oxeio, C!E 6oxeicx XCX'tCXC!XEUcxaµa11cx CXltO XCX't!XAA7JA7J 1tAcxa'ttXTJ ti).71, 'tCX 01toicx Bex 't01toBnoti11'tcxt, oxL ci11w 'tWII 40 KG CX\ICX C!UC!XEUCXOLCXII, C!E 1tpoa'tCX'tEU'ttxac; ClUC!XEUCXC!LEc;. (6) KoACX ~uyi~O\l'tCX CX\IW 'tW\I 35 KG 'tCX OltOLCX 7tEptaxouv· tiAEc; 1:71c; Oµci6cxc; E, Bex dvcxt ecpo6tcxaµevcx µe XEtpoACX~TJII. a,:. - tuaxwcxaicx uAw11 aE LX ac; 1toao't uc; •nee; 'tW\I 0 awe; 22°, 30° XCXL 3 °, CXltOCl'tEAoµEYE<; OE µt­ xpec; 7tOC!O't1j'tE<;, µ1topOU\I EltLC17J<; \ICX ClUC!XEUCX~O\l'tCXL we; XCX­ 'tWBL: (ex) uypa. oxt CX\IW ,:ou 1 KG CX\ICX XOAOII, C!E cptCXAEc;, xcx,:cxaxwcxaµe11ec; CXltO cxpyuALO\I (cxAouµi11to11), XCX't!XAA7JA1j ltACXCl'ttXTJ UA1j, TJ UCXAO, µe CX\ICXCl'tOAEic;, XCX'tCXC!XEUCXaµavouc; CXltO XCX't1XAAT)A7J ltACXCl'ttXTJ UAT), TJ µE XAElC!LflCX'tCX µoxAoti TJ XOXAtW'tCX XAEta!­ µcx'tCX, axo111:cx, XCXt Cl't'Tj µicx XCXt Cl't7l\l cill 71 mpi1t1:wa71, EACX O'ttXO 1tcxpeµ~cxaµcx. Ot cptciAec; Bex cxacpCXAi~ov1:cxt µE cxAwpo11 2 561 xcxBcxpixc; µixcxi:; TJ ucxAoipto XPTJOLµo1tototiµe11cx we; cx1toa~E a1:txo UAtXO C!E XU'tLCX t\lOCJCXYi5oc; TJ ~UAt\lCX, To UAtXO 1tA71pw aEwc; 1tpi1tEL wx Eivcxt Eitcxpxec; aa 1toa61:71'tcx 1tcx vex cx1toppocpri aat OAOXAT)pO 'tO uypo. Ot (jltCXAE<; 6ev 1tpE1tEL \ICX yeµi~O\l'tCXL ltE pcxv 'tOU 7 5 a,:cx excx,:011 'tT)<; xwp1j1:txo1:71'tcic; 'tW\I' (~) C!E XCX'tCXCl'tCXCl'JJ ~tiµ'J]c; ~ XO\lt07tOt7J(J.EIIEc; UAEc; OXL ix11w 1:ou 1 KG cxvci xo)..011, aE xu'tlcx cxito cxAouµivto TJ CXltO t\lOC!CX\1[6cx TJ ~UAL\ICX (,:wv Mo 'tEAEU'tCXLW\I EltE\16E6uµe11w11 µa CXAOUfll\lLO\I TJ µe XCX'tCXAATJA'lj ltACXCl'ttXYj UA7J) µe yapo XAELC!t­ µ011. EAetiBapoc; xwpoc; EX 10 Cl't(X EXCX'tO\I Bex CX(jlTJYE'tCXL a,:cx ei671 auaxwcxaicxc;. 3. - Mtx,:~ auaxwcxaicx • YAac; 1:71c; KXciaawc; 5.2 µ1topoti11 vex qxAELOY'tCXL a,:o cxu,:o 2562 xoAov EL'tE µa cillac; tiAEc; TJ ei61] 1:11c; ADR EL'tE µe cillcx aµ1to peuµcx1:cx. ·nee; ''t'ljc; Oµci6cxc; r 6e11 1tpE1tEL \ICX auµ1tEpLAcxµ~ci \lO\l'tCXL a,:o cxu,:o x0Ao11 µe UAEc; 1:w11 Oµci6w11 A, B TJ. E. 4. E116d~atc; (Mcxpxciptaµcx) XCXL mxhac; xtvMvou E1ti 'tWY 2563 x0Aw11 (~AaltE ITpoaBrix1111 A. 9) n:TKcxBE XOAO\I 7tEptexov UAEc; 't'ljc; KACXC!EW<; 5.2 Bex cpipEt E'ttxhcx atiµcpc,wcx 1tpoc; ,:o µov'tEAO No. 5. . KoACX 7tEpLEXOll'tCX UAEc; 'tW\I 46° (ex), 4 7° (ex) XCXt 49° (ex) Bex cpipou11 E1tla71i:; mxhcx auµcpwv71 1tpoc; 'tO µ0111:iAo No. 1. (2) KoACX 1tEptaxo11,:cx EuBpcxua,:cx 6oxeicx cxopcx,:cx CXltO e~w 0cx cpepouv E,txhcx atiµcpw11ov 1tpoc; 'to µov'tEAO No. 9. 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TO.'.::IKOTHL EILITNOHL OPIAKEL fPAMMEL OMMOL L"fLKEYALIAL 10.000 Oµiioot (r) 1.000 100 / 10 ·10 100 1.000 10.000 100.000 f1 't7l'tlXO't7lt; xo,V µ 3 L,ov otvw,ipw liivotxot ,ot xpt1:71ptot Excppii;ov,otl µE 1pot­ cptx71 1totpiia,ota71 aotv ~071S71µex 1 tot Euxo).71 1:ot;t116µ71071. 001:600, Emto71 6,otv xp71atµo1totouv-cm 1potcptxii; 1totpoto1:a 0Etc; Eillotl ex\lot1t6cpEUX'tO vex U1t1Xpxou11 1tpOaE11LOEl<;, 1 tot OUOiE<; 1tou Eµ1timouv 1tiivw 71 xov,ot OE optotxi,; rPotf1-f1-E<; Ofl-lXOwv ouaxwotaiotc;, 1tpimt vot 1 ivE,otl EAE)'XOt; µE exptSµ71,txii xpt,71 ptot. 2) ftot ex1tott't7IOEL<; auaxwotaiotc; ,wv 1tEptSwpiwv 2605(2), 2606(3) Xott 2607(2), ouoiE<; Xotl f1-i1µot,ot ouatwv µE 071µEio ,71;Ewc; ltlX\IW ot1t6 45 ° C SEwpou111:ext anpEE<;. 3) Ot x71µtxii exa,otSEic; ouaiEc; 't'JJ<; K).iioEwc; 6.1 Sot 1 ivo­ ll'totl OEx,ic; 1 tot µE,otcpopii µ611011 otv EA 71cpS71ootv ,ex otvot1xotiot fl-hpex ,tot 1tp6A71(j>71 E1t.txivouv71,; exitoauvSfoEw<; 'tW\I 71 ltOAU­ fl-Eplaµou 'tWII xex,ii 1:7111 µE,otcpopii. ftot 'tO\I OXOltO otu,6, tOloti­ np71 cppov,:loot 1tpE1tEL vot 1texipvnott 1 tot vex E;otacpotAto,Ei 6,t ot auaxwotaiEi; OEV 1tEptixouv xexµµtii ouaiex 1tou µ1topEi vot u1to­ ~0718710Et n<; ot\l'tlOpiiaEt<; otu,ai;. 4) To 07lf1-Eio otvotcpAE;Ew<; 1tou otvexcpipE,otl xot,w,ipw Sot 1tpE1tEl \lot 1tpoa0topi;E,otl fl-E 'tOV ,p61to 1tOU 1tEpt,piicpE,ott O'tO ITexpiip,71µex A.3. 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YopoXUO(\ILXO o!;u 7t0U OE\/ tX0(\107t0tEi i:ti:; 1tpoii1to0aaeti:; O(Ui:ai:; OE\/ 1tpa1tet \10( jt\lE'tO(t oexi:o jLO( µe,:O(cpopix. 2. TO( e!;~i:; OtO(AUµO(,:O( uopoXUO(\ltXOU o!;foi:;: J50('ttXIX 5tO(AUµO(,:O( u&poXUO(\ltXOU o!;foi:; itEptaxo\l'tO( 'tO 7tOAU 20% X0(00(pou o!;foi:;. iUxooAtXIX OtO(AUµO(,:O( u&poXUO(\ltXOU o!;foi:; 1tEptaxo11,:0( 'tO 7t0AU 45% )(0(00(pou o!;foi; OE µe00(\10ATJ. . AAxooAtXIX OtO(AUµO(,:O( u&poXUO(\ltXOU o!;foi:; 7tEptaxo\l'tO( to 7tOAU 40% Cl!;foi:; OE O(t00(\10ATJ, l;HMEJQl;Ell;: 1) Etotxo[ opoL OUOXWO(OlO(<; EcpO(pµo,o­ \l'tO(L ,tO( ,ti:; oualei:; O(u,ai:; (f3Aa1te itEpt0wpLO 2603(2)). 2) J50('ttXIX 0tO(AUµO(,:O( uopoXUO(\ILXOU o!;foi:; mpta?(O\l'tO( 1tAfo11 'tOU 20% XO(OO(pou o!;foi:;, o:AxooAtXIX OtO(AUµO(,:ex uopo­ xuexvtxou o!;foi:; 1tEptaxo11,:0( 1tAfo11 'tOU 45 % xex0o:pou o!;aoi:; OE µe00:116A7l xext O()..xooAtxix oto:Auµo:i:o: u&poxuo:vtxou o!;foi:; 1tE­ ·ptaxono: 1tAfo11 'tOU 40% XO(Oexpou o!;foi; OE ott0ex110A7l Bev 00( itpamt \10( jL\10\l'texL OEX'tlX ytex µei:excpopix. 3. Tex e!;~i:; µei:o:MtXIX XO(pf3011uAtO(: IlE\l'tO(Xotpf3011UALO ato~pou, 'tEtpO(Xotpf3011UALO \ltXEAiou. l;HMEIQl;Ell;: 1) Et5txoi opot OUOXWO(OlO(<; ecpexpµo,o \l'text jtot tL<; ouaiei; O(U'ta<; (f3H1tE mpt0wpLO 2604). 2) ftot µE,otMtXIX xo:pf3011uAtex axov,:o: ariµEio 0(\/0(cpAa!;ewi:; 21 °C XO(t IX\IW, (3Aa1tE ixp0. 36. 'AMO( µE,O(MtXIX XO(pf3011uAtex µE OTjµEio 0(\/otcpAa!;Ew<; XIX'tW 0(7t() 21 ° C OE\/ 0ot 1tpa1tEt vex yi­ \10\l'tO(t 5Extix 1tot µEi:otcpopix. B. Opyot11Lxai:; ouaiE<; µE 07lµEio O(\lotq>Aa!;Ew<; 21 ° C Xott IX\IW ~ µ:r1 0:110:cpXa!;tµei:;. l;HMEIQl;H: Opyo:vtxai:; ouaiei:; xo:t 1totpotaxeuixaµo:tot 1tou XPT]otµo1t0Lou11i:ott 00:11 1totpot0Li:oxi:6110: EL\lotL ouaiEi:; i:wv 71 ° awe; 77° xott 81 ° awe; 83°, II. A,w,ouxEi:;, ouaiEi:; µE ariµEio (3po:aµou XIXtW tW\I 200 ° C 61twi:;: o:) xuo:vouopLx~ otXEt0\11], (3) ot11LAi117l, (3e11,011LtpiAto, 6to:µe0uAo - o:µtvo - o:xei:ovti:pi­ Ato, N, N-6tµE0uAo-o:11tAi111j, 6tµ.0uAo-itupt5ivri, Aotxi:ovti:pi­ ALO, µE6o!;u - 1tpo1tpto11t - tpiAto, (µovo)xAwpo - O(XE,011Li:piAto, i:ptxAwpo - otXE'tO\lt'tpiAto. 6) OtotL8uAo - o:µtvo - o:xei:011LtpiALo, N-µE8uAo:111.Ai117l, l;HMEIQl;H: Iaoxuot\ltXIX µe oriµEio ,aaEw<; XIX'tW tW\I 200°c EL\10:L ouaiei:; 'tOU 18 °. 12. A,wtOUXE<; oual.i:; µE OT]µEio ,aa.wi:; 0(7t() 200° Xott ixvw, 61twi:;: ot) - - - (3) 2-otµL110-(3E11,011ttpiAto, otµLvo - tpL11ttpo - (3e11,011ttpiAto, (3e11,Lfii11ri, (3pwµo-o:11tAi11Ec;, N-(3outuA-o:11tAi11ei:;, xAwpo -11Ltpo (3e11,a11to:, 5t;,cAwpo - ex11tAi11ei:;, (3e11,tol11TJ otuopoxAwpwuxoi:;, 6tµe6uAo - o:µtvo - (3opix11Lo, 5Lvttpo - o:11tAi11ei:;, 6t11ti:po - (3e11,a 11tot, OL\lttpo - toAoua\ltot, ott8uAo - Aoui:olni:;, \lttpo - (3.11,0 - tpL cp8opi5tot, 3 - vti:po - 4 - X Awpo - (3.11,oi:pt - cp8opl5to, µ0110 xAwpo - 0(\/tAivei:;, µ0110 - \lt'tpOot\ltAi11ei:;, µo\10\/Ltpo - 'tOAouavLot, (3~t0( - 110:cp8uAo:µi111j, \lttpo - /3E11,a11to, \IL'tpo!;uH11Lot, cpott\lUAU­ opot,l\11], 8EL"ix~ /3E11,tol111j, t0Aoui:6i11E<;, xuAtoivei:;. i). o:xpuAo:µ[oto, At7t0\lttpl5to, o:µtvocpott\lOAE<;, O(\ltat5ivei:;, (3e11,uA - xuo:vi5to (cpottvuAo:xeto11ttpiAto), 6totµt110 - 6tcpott11uAo µE81X11LO, N, N - 0tott8uAotµLAL\17l, otL0uAot\lLAivei:;, N - ott8u)..o - N (3e11,uAo:11tAi11ri, ixAcpot - vo:cp0u)..o:µivri 11ti:poxpeo,0AE<;, Vttpo­ cpott116Aec;, cpott11ett6[11ei:;, cpott\lUAO - E\IEOtotµivei;, 2,4 - i:0Aouu Ae11e5Lotµi111j, 1 l;HMEIQl;H: laotOXUot\lLXIX µe ariµeio ,aa.wi:; 200°c )(O(t. ixvw eivott ouaiei:; i:ou 19 °. 13. O!;uyo11wµi11ei:; ouaiei:; µE OT)µeio ,aa.wi:; 200°c xext XIXtW, oitwi:;: ot) AUuA-O(AXOOATJ, 6eti:xo 6tµe6uAto, • (3) 0()..66)..ri ((3~,:ex uopo~uf3oui:upex)..5eu5ri), qiext116A71, Oeti:xo x Awpo-0tµE8uALO, 1) cpoupcpoupuALX~ exAXOOATj, (3optx6 i:ptO(AUAto, µovof3outu­ Atexxoi; extO~p ext8UAE\ILX~i; jAUXOATj<;, o!;exAtXO O(t8UAto, 14. O!;uyo11wµa11ei:; OUOLE<; µe 071µ.io (3pexaµou 200°c xext IX\IW, oitwi:;: ex) ... (3) (3.v,OXt\lOVTj, XOATJO'tEpOAE<;, xpeo,OAE<;, Oeti:xo 5text8u At0, !;uAE110Aec;. • 1) exhu)..o!;u-cpext116)..ei:;, exAxuAocpextvoAE<; (µe exMaeti; C2 ewe; CB), uopoxt\10\/Tj, 1tupoxexnxoA1j, • XL\lu&povri, pe,opat­ \lOATJ, . 15. AAoyo1101tot7Jµa11ot u5po1011ix110pexxei:; µe oriµeio (3pex­ aµou XIXtW tW\I 200°c, 61twi:;: ex) ... (3) (3pwµwuxLO (3.11,UALO, (3pwµtouxo ext8UAtO, XAWpocpop­ µLO, XAWpLOuxo (3e11,UALO, 6tf3pwµtouxo ext8uAa\ltO (SYM. 6tf3pwµoo:"i8ix11to ), twoLOuxo µe8uAto, itE\ltO(X AwpO(t0ixvto, 1, 1, 1,2 - i:ei:pex;,c)..wpexL00t11to, 1, 1,2,2, - i:ei:pex;,cAwpo:t8ix11to ( 'te'tpex;,c AWptou;,coi:; exaetUALIITj), i:npexxAwptouxo IX\/0pex!;. l;HMEJQl;H: Miyµexi:ex 5t(3pwµLOuxou exL8UAE\ltOU (CYM. 6tf3pwµoext8ex11iou) µe (3pwµLOuxo µe8uALO, axov,:ex OE 50 ° C 7tLEOTj exi:µwv µeyexAU'tEpTj exito 300 KPex (3 BAR), EL\lext, ou­ aiai:; 'tTj<; KAIXOEW<; 2 ((3Aa1tE 7tEpL8wpto 2201, 4 ° ((3 ,:)). y) (3pwµocpopµLo, xAwptouxo µE8UAa\ltO (otxAwpo - µa8ix­ \lto), 1,2 - otxAwpo - (3av,a11to, 'te'tp0((3pwµwuxoi:; Ot\10pex!;, 'tE­ i:pexxAwpo - ott8uAa\ltO (umpxAwpo - exL8UAa\lLO), i:ptxAwpo ext6uH11to, 1, 1, 1 - i:ptxAwpoext6ix11to, i:ptx Awpo - 1tpo1t1X\ltO. TTAPATHPHl;H: Miyµexi:ex XAWpLOuxou µE6uAiou µE xAwpwuxo µE6UAE\lto axovtex OE 50°C 7tLEOTj O(,:µwv µe,exAU­ 'tEPTJ ex1t6 300 KPex (3 BARj Eivext ouaiei:; i:rii:; K)..ixaEwi:; 2 ((3Aa7tE 1tEpt6wpw 2201, 4 (/3, ,)). 16. 'AME<; exAOjOV07t0t7lµa11Ei; ouaiei:; µe OT]µEio (3pexaµou XIXtW 'tW\I 200°c, 61twi:;: • ex) XAwpomxpi111j, xpwpo - tpt6opo - 1tuptµt6i11ri Em(3pwµo u&pivri, umpxAwpo - µe6uAo - µepxex1t't1XIITJ, . • -~~ • l;HMEIQl;Ell;: 1. Miyµexi:ex xAwpomxpivrii:; µE (3pw­ µwuxo µE8UALO ~ XAWptouxo µE6UAto, axov,:ex OE 50°C 7ttEOTj extµwv µqO()..u,:epri exito 300 KPex (3 BAR), ELiiott OUOLE<; tTj<; KAixa. 2 (f3H1te 1tept6wpto 2201 4° (ex i:) ~ 4° ((3 t)). 2. l;uµµEi:ptxoi:; 5tx Awpo - 6tµe6uAexL6~p OE\/ 6ex jL\/Etext OE­ xtoi:; 1 tex µetexcpopix. (3) xAwpo - exxEtuA - exA5Eu571, o!;txo ext6u)..o(3pwµto o!;txo µe6uAof3pwµto, (3pwµLO - exxE'tO\/Tj, o!;txo ext6UAOXAWpto, o!;txo µe0uAoxAwpLo, XAWpoexXE't0\11], XAwpocpopµtxo XUXAO a!;uALO, XAWpocpopµLxo 2 - ext0UAE!;UAtO, XAWpocpopµtxo cpext\lU­ Ato, 1 - X Awpo - 1 - 11ti:po1tpo1tix11to, 1 - X Awpo - 2 - 1tpo1tex 116A7l, 1,2 - 6t(3pwµo - 3 - (3outex116117j, auµ. - OtXAwpo - exxe­ ,:ovri, 1,3 - otxAwpou&pi111j (1,3 - otxAwpo - 2 - 1tpo1tex\lOA1j), 1, 1 - 5tx Awpo - 1 - wtpoext0ixvto, emx Awpo • uopivri, 2 ,2 6txAwpext0uAtxoi:; ott0~p, 6tx)..wpofoo - 1tpo1tUAtxoi; ext0~p. 3 exµt110(3e11,oi:ptcp0optouxo, ext6UAE\ltX~ XAwpo - uopivri (2 XAwpo - ott0ex110A7l), 7tE\l'texcp0opto - (3.11,0(AOEUOTj, tptxAwpo exXE'tUA - exA5eu5ri (CHLORAL), i:ptxAwpo • \lttpo - ext6ix11to. l;HMEIOl;H: XAwpocpqpµLXIX ix)..ex,:ex 7t0U axou\l xupiwi:; 6tex(3pwi:txai; t5t6i:1J,E<; eivexL ouaiei:; 'tTJ<; KAixaewi:; 8 ((3Aa1te 1tE­ ptBwpto 2801, 64°), 1) 2 - xAwpocpext110ATJ, 3 - XAwpo - 1tpo1to:116A1J, otxAwpo o!;txo µe0uAto, tptxAwpo - o!;txo µe0uAto. 1 7. AAOj0\107totTjµa11E<; ouaiei:; 7t0U axou\l oriµeio ,aa.wi:; 200°c xext IX\IW, 61twi:;: !X) XAWptouxoi:; cpextvuA - xexpµ1touAexµi11ri, xuexvtouxo IXAcpex ► (3pwµof3e11,uAtO. (3) (3pwµLOuxo cpextvexxuAtO (wµayO( - (3pwµo - exxei:ocpext­ \10\11]), (3pwµtouxo \lttpof3e11,uAt0, (3pwµwuxo !;uMALO, XAW­ pwuxo cpott\lexXUAtO, ( wµirex - X Awpo - exxei:ocpext\10\/Tj), X AW­ pwuxo /3Ell,UAtOE\ltO, a11u&p1j e!;excp0optoexxE't0\/Tj, tw6touxo (3.11,uAtO, 7tE\l'texxAwpo - cpext\lLXO \IIX'tpto, i:ptxAwpof3oui:a­ \ltO. 1) x Awpo - ex11tat&i11ei:;, x Awpof3e11,0()..6aii&1], i:pti:oi:ex1ai:; (3oui:uA - xuxAo - e!;u).. - XAwpo - µupµT]xtxo, XAwpo - \lttpo ex11tAi11ei:;, X Awpo - vti:po - i:oAouoAtex, 3 - X Awpo - cpext\lOATJ, 4 ;,cAwpocpott\lOATj, xAwpo - tOAOui:5ivei:;, ?(AWptou;,co (3pwµof3e11 ,uAto,. XAWptouxex ;,cAwpof3e11~UAtex, otxAwpocpext\lOAE<;, 5t­ ;,cAwpo - 'tOAoui:5i11Ec;, e!;o:xAwpo - exXE't0\11], e!;exxAwpof3e11,a 1184 E<DHMEPII: THI: KYBEPNHI:EQI: (TEYXOI: 6EYTEPO) VLO, E!;exx).wpo - ~OU'texOLEVLO, E!;exxAwpo - ext0dcvto, fJ.OYO XAWpo - o!;txo Y<X'tpto, 1, 1, 2, 2 - 'tE'tpex~pWfJ.Oext0dcvto (n­ 'tpex~pWfJ.LOUXO exXE'tUAEVLO ), 'tE'tpexx Awpo~Ev,ivtex, 'tE'tpexxAw­ prn:pCXLVOAE<;, 'tPLXAwpo~Ev,ivtex, 'tptXX.wpocpextvOAEc;. iHMEiniEri: 1. XAwpo<pOpfJ.tX<X <XAexi:ex 7tOU ixouv xu­ p[wc; 6tex~pwi:txic; t6toi:7Ji:Ec; dvext ouo[.c; 1:7J<; IO.dco.wc; 8 (~Ai1t. 1tEpt0wpto 2801, 64°). 2. 7J 2, 3, 7, 8 - ni:pexxAwpo - 6t~Ev,o - p - 6w!;[v7J (TCDD) oE OUfJ.1tuxvwoEtc; 1tou 0Ewpouvi:ext .!;extprnxdc i:o!;t­ xic; ~IXOEL ,:wv xpt1:7Jp[wv i:ou 7tEpt0wp[ou 2600 (1) U7t007Jfl· 1. - OEV 0ex y[v.i:ext 6.xi:ij 1tex fJ.Ei:excpopix. 18. Iaoxuexvtxic; evwoEtc; fJ.E 07JfJ.&lo ~pCXOfJ.OIJ XIX'tW 'twv 200 ° C 01twc;: ex) ... ~) LOOXUexVLXO XAWpm0uALO, Looxuexvtxo XUXAO - ext0uALO, tooxuexvtxo cpmvuAto, LOOXUexVtXO 'tOAUALO, 6texAUfJ.ex'tex tooxuex­ VLXWV 'tOU 18°(~) xext 19°(~) axov,:ex 07JfJ.ELO exvexcpAE!;Ewc; 21 °C xext IXVW. LHMEIQiH: AtexAufJ.ex'tex 'tWV EV ).oyw tooxuexvLXWV EYW­ OEWV fJ.E 07JfLEio exvexcp).i!;ewc; xix'tw ,:wv 21 ° C e[vext ouo[.c; 1:7Jc; K)..ixo.wc; 3 (~Ai1t. 1tept0wpw 2301, 14 ° (~)). y) ... 19. Iaoxuexvtxic; EvwoELc; fJ.E 07JfJ.Elo ~pexOfJ.OU 200 ° C xext IXVW, cmwc;: ex) ... ~) OL-LooxuexvLXO e!;exfJ.E0UAEVLO, OL-tooxuexvtxo 2, 4 - 'tO­ AOUUAEVLO xext LOOfJ.E'tptxdc fJ.l1fJ.ex'tex, tooxuexvtxo 3 - X Aowpo 4 fJ.E0u)..ocpextvuAto, tooxuexvtxo i:ptX AwpocpextvuAto, tooxuexvtxo 4 - XAwpocpextvuAto, otoxuexvtxo 3, 4 - OLXAwpocpextvuAto, too­ xuexvtxo dc).cpex - vexcpuALO, tooxuexvtxo 'tOOIJALO. iHMEIOLEIL: 1. AtexAUfJ.ex'tex 'tWV exvw'tipw todxuexvtxwv EVWOEWV fJ.E 07JfJ.ELO exvexcpAi!;ewc; xdt,:w ,:wv 21 ° C e[vext ouo[ec; 1:7J<; K)..dcoewc; 3 (~Ai1te 1tept0wpto 2301, 14°(~)). 2. AtCXAufJ.exi:ex ,:wv exvw'tipw tooxuexvtxwv evwoEwv fJ.E 07J· fJ.ELO exvexcpH!;ewc; 21 °C xext dcvw, dvext ouo[Ec; 1:7Jc; 18 ° (~). y) taoxuexvtxo 4, 4 - 6texcptvuAOfLE0otvto, 6-aoxuexvtxo tao<po­ povto (taoxuexvtxo 3 - tooxuexvtXOfJ.E0UALXO - 3, 5, 5 - i:ptfLE· 0u)..o - xux).oe!;uAto ), 6t - taoxuexvtxo 1, 5 - vexcp0u).ivto, 6t taoxuexvtxo i:ptfJ.E0UAO - E!;exfJ.E0UAEVLO, xext LOOfJ.EpTj fJ.lyflex'tex exU'tWV, taoxuexvtxo anexpuALO, OLexAIJfl-ex'tex LClOXUexVLXWV ,:ou 19° (y) flE Cl7JfJ.ElO exvexq,Ai!;ewc; 21 °C xext dcvw. 20. Ouo[Ec; 7tEptixouaec; 0e[o xexL 7tOU sxouv 07JfLElo ,ea.we; X<X'tW 'tWV 200°C 07tW<;: ex) 0EtocpextvoA7J. . ~) 2 - ext0u)..o - 0etoq,exlvto, q,oupq,oupuAOfJ.Epxex1t'totV7J, tao 0ewxuexvtxo illuAto, tao0etoxuexvtxo ext0uAto, fJ.Epxex1t'tO - ext 0exvoA7J ('tpt-1AuxOA7J), 0Etocpwayivto, 6texAufJ.exi:ex i:wv tao 0ewxuexvtxwv 1:7Jc; 20 ° (~) fJ.E Cl7JfJ.Elo etvetq,Ai!;ewc; 21 ° C xett <XVW. LHMEmiH: AtetAUfi-et'tet 'tWV EV ).oyw tao0EtoXUexVLXWV sxov,:et Cl7JfJ.Elo etvetq,Ai!;ewc; X<X'tW 'tWV 21 ° C Elvqtt ouo[ec; 1:7Jc; KA<iaEwc; 3 (~AE7tE 7tEpt0wpto 2301, 18°(~)). r) tao0eto - XUetVtXO fJ.E0UALO, 4 - i:ptet7tEV'tetV<XA7J. 21. Oua[Ec; mptexouaec; 0E[o Xett sxouaec; 07JfJ.ELO ,ea.we; 200°C Xext <XVW, 07tW<;: ex) ... ~) 2 - etXE'tUAO - 0etoq,etlw:i, etfJ.tvo0EtocpettVOA7J, y) ... 2 2. Oua[Ec; 7tEptixoua&c; q,waq,opo Xetl sxouaEc; Cl7JfJ.EtO ,s OEWc; xdt,:w ,:wv 200°c 01twc;: et) ... ~) 'tptett0uAtxij q,waq,[v7J. y) ... 23. OuaiEc; 7tEptixouoEc; q,woq,opo Xett 7t0U sxouv 07JfJ.ElO ,a­ OEWc; 200°C Xetl <XVW, 07tW<;: et) ... ~) ett0UAO - 6tcpettvUAO - q,waq,[v7J, o!;Eioto i:pi<pettvUAO - q,w­ oq,[v7Jc;, q,wa<poptxo 'tptxpEalJAto fl-E 1tAfov 'tou 3% op0o - too­ fJ.Epij, i:ptett0uAEvo - q,wacpopetfJ.t07J. y) ... 24. Opyetvtxic; EVWC!EL<; 7t0U OEV fJ.7tOpouv Vet 'tet!;LVOfJ.7J0ouv OE illEc; auUo1 txic;. Xet1:7Jyop[Ec;, 01twc;: et) ... ~) xuetvtouxo ~Ev,oiiAto. y) 1, 5, 9 - xuXAo - 6w6exet - i:ptivto. r. OpyetVOfJ.EWAALXEc; EVWClEL<; xext xotp~OVIJAtet. iHMEmiEii: 1. To!;txic; opyotVOfl-E'tetAAtxic; EVWClEL<; XP7JCltfJ.07tOLOIJf1-EVEc; aotv 1totpotat'tox1:ovot elvett oua[Ec; 't7Jc; 78 ° iwc; 80°. 2. Au'tOfl-<X'tW<; etvetcpAEYOfJ.EVE<; opyetvofJ.E'tetAALx~c; evwaetc; ELV(l(L oua[ec; 't7J<; KA<iaewc; 4.2 (~AE7tE 7tEpt0wpto 2431 3 ° ). OpyetVOfJ.E'tO:AALXE<; EVWClELc; OL 07tO[Ec;, OE rnotcpij fJ.E VEpo EXAU­ ouv etvotq,Ai!;tfJ.ot otiptot eivott oua[ec; 't7J<; IO.dca.wc; 4.3 (~AE7tE 7tEpt0wpLO 2471, 2° (E)). 31. Opyo:vofJ.E'tetAAtxic; .vwa.tc; 01twc;: et) 'tE'tpO: - Ott0UALXO<; fJ.OAu~ooc;, 'tE'tpotfJ.E0UAtxoc; fJ.OAU~ooc;, fLLYfJ.ot'tOt O:AXUAlwv µoAu~oou µE otAoyovoµivec; opyetvtxic; EVWClEL<;, 7t.X, uypo Ott0uAto (otv'ttxpouai:txo 1tpoa0E't0 xetuoi­ µwv XLV7J'tTjpwv). 32. Opyotvtxic; xotaampo - evwaetc; 01twc;: ot) ... ~) XAWptouxoc; OL~OU'tUALXO<; xotaa[npoc;, XAWptouxoc; OL­ fJ.E0UALXOc; xexaainpoc;. y) XAWptouxEc; EVWClEL<; fJ.OVO - otAXUALXOIJ XotOClL'tEpou, <XA­ AEc; evwaEtc; 6t~OU'tUAtxou xotoot'tipou. LHMEmiH: 0 'tPLXAWptouxoc; ~01)1:UALXO<; xocaati:epoc; E[vott fJ.tet oua[oc 't7Jc; K)..dcaewc; 8 (~AE7tE 1tEpt0wpto 2801, 21(~)). 33. Opyotvtxic; uopetpyuptxic; EVWC!Etc; 01twc;: et) . . . ~) .. . y) .. . 34. Opyotvtxic; EvwaEtc; ixpaevtxou, 01twc;: et) ...• ~) .. . y) .. . 35. Aot1tic; opyocvoµ.i:illtxic; EVWO&tc; 01twc;: Opyetvtxic; evwaetc; otvi:tµoviou, xet6f1-iou, xpwµiou, xo~CXA 't[ou XOtL 0ocUiou: ex) .. . ~) .. . y) .. . 36. Ketp~ovuAtoc, 01twc;: ot) .. . ~) .. . y) xotp~ovuAto XPWfJ.iou, xotp~ovuAto xo~otA'tiou. LHMEiniH: To 1tEV'totXotp~ovuAto otoijpou xott ,:o 1tEV'tot xetp~ovuAto VtXEAiou Eivott ouaiec; ,:ou 3 °. A. Avo otvEc; ouaiec; 1tou 1to Et vot EAXuoouv i:o!;txdc eti ux OE E1totq,~ µE vEpo (:n ot'tµoaq,ottptx~ urpocoiot), 1) pot'tLX<X OtCXAIJ­ µot'tot ~ o!;ioc. 41. Avopyotvot XUOtVtoiJXOC, 01twc;: et) onpdt XUOCVLOUXet, 01twc; xuotvtouxo ~dcpuo, XUOCVtOIJXO ' ota~eai:to, xuocvtouxo X<XAto, XUOtVtouxo v<ii:pto, OtOtAUfJ.Ot'tet etvopydcvwv xuetvwuxwv, 1totpoca.xEU<XClflet'tot etvopydcvwv xuoc­ vtouxwv. iuµ1tAOXot xuotvtouxet aE ai:EpETj µopcpij, 01twc;: XCXA· xoxuocvtouxo vdci:pto, xuotvtouxo uopetpyuptxo X<XAtO, OtCXAU­ µoci:ot auµ1tAOXWV xuetvtouxwv. ~) Cl'tEpE<X XUetVtOUXet, OltWc; XUotVtOUX01o U0potp1upoc;. LUfJ.ltAOX(l( xuotvtouxoc ClE ai:EpETj fl-Opcpij, 01twc; XCXAXOXUOt­ YLOUXO X<XALO. y) ... iHMEIQLH: LL07JPL - XUOtYtouxet, ClL07JpO - XUOtVtoUXOt, OCAXetALX<X 0EtoXUotYtouxet XotL 0EtoXUOtYLXO etµµwvto, UltOXEt­ Y'tott an.; Otot'toc!;Et.; 't7J<; AD R. 42. A'ioto:, 01twc;: ot) ot,[oto ~expuou µE 'tOUAotXtO'tOY 50% YEpo ij CXAXOOAE.;. ~) UOOC'tLX<X OtotAUfl-ot'tex (l(,to[ou ~etpuou XOtt Ot~LOLOU Yeti:piou. y) ... LHMEIQLEii: 1. Al;totet 7t01) fl-XOpEt Vilt expocyouv OE E7totcpij fl-E q,Mret Tj ltOU Eivoct 7tEptaoonpo wocia07J,:ot OE xpoua7J ij i:pt~Tj etlto 'tO i:ptvti:po - ~Ev~ivto, OEV 1tpi1tEt vot yivo- • Y'tett OEX'tot ytet µe,:ocq,opdc, EX'to.; etY EtYett EtOtX<X Xoti:otxwpt­ OfJ.EVOt Cl't7JV KA<XCl7J 1 Ot, 2. Al;toto ~etpuou ClE !;7JpTj XOt't<XCl't0tCl7J ij fLE Atrwnpo OtltO 50% VEpo ij OtAXOOAE.; OEV 0et 1tpE1tEt YOt yivE'tOtt OEX'tO ytet fJ.E· 1:0tq,opdc. 43. IletpexoxwdtofJ.exi:et q,waq,toiwv 1tEptixov.0t 1tpoa0ijxE.; 1tou a'tOtfl-et'touv otu'toµ0t1:7J OtVotcpAe!;7j, 01tw.;: et) q,woq,opouxo etpriAtO, ipwoq,opouxo fJ.etrvijato. <l>EK 104 E<J>HMEPII: THI: KYBEPNHI:EOI: (TEYXOI: AEYTEPO) . 1185 ~) q,woq,opouxoc; ~eu6otp1upoc;. r) ... LHMEIOLEIL: 1. T llt 1tlltplltoxeuiioµllttllt lltU'tot Bev 1tpe1teL Vilt yivov'tlltL BeX'tlX 'YLllt µetlltq>opii lltV Bev 7tEpLexouv 1tpoo8iJxEc; 1tou 1tlltpeµ1t0Bi,ouv 'tTJV lltU'tO(J-llt'tTj lltvotcpAE;Tj, 2. TTlltplltoXWIXO(J-llt'tllt q,wocpopouxou Vllt'tpiou, cpwocpopou­ xou OtO~EO'tlou XlltL q,wocpopouxou otpovtiou ElVlltL ouoiEc; 'tTjc; KAixoewc; 4.2 (~AE7tE 1tepL8wpLO 2431 2 °). 44. (~) LLBTjpO-OlALXOVTj Xlltl (J-lltTTlltVO - OlAlXOVTj (J-E 7tAEOV 'tWV 30% Xlltl AtywtepTj 'tWV 70% OtAlXOVTj, xpot(J-llt'tllt otBTjpO OlALXOVTjc; (J-E OtAouµivLO, (J-llt'Y'YIXVLO, lltO~ECl'tLO TJ µe 7tEptooo­ 'tEpllt 'tOU evoc; llt7t0 'tilt (J-E'tlltMllt lltU'tlX, (J-E OUVOAtXTj 7tEpteX'tlXO­ 'tTj'tllt otALXOVTjc; Xlltl otOLXElwv iiUwv 7tA7JV otBiJpou Xlltl (J-llt1 11ltvlou 7tAEOV 'tOU 30% OtMIX AtywtepTj llt7t0 70%. r) . . . • OuoiEc; 'tTjc; 44 ° 81lt rivoV'tlltt BExtec; ytllt µetlltcpopii µovov lltV exouv llt1t087JXW'tEt ytllt XPOVtXO BtotO'tTj(J-llt µtxponppo 'tWV tptwv Tj(J-Epwv OE ;TjpO Xlltt lltEpt,oµevo µepoc;. . LHMEIOLEIL: 1. M1tptxettEc; otBTjpO - otAtxov7Jc; Xlltt (J-lltTTlltVO - otAlXOVTjc;, µe 07tOLOBTj7tO'te 7tEplEXO(J-EVO OtAtXOVTjc;, Bev Silt u1tOXELV'tlltt Otte; Btllttot;Etc;· tou ADR. 2. OuoiEc; tTjc; 44 °. BEv Silt U7tOXEtV'tlltt one; Btllttot;Etc;• tTjc; ADR lltV BEv ELVlltt u1toxElµEvec; oE EXAUOTJ emxtvBuvwv lltepiwv µe 'tTJV rnl6plltoTJ u1plltollltc; Xllt'tlX 'tTjV (J-Etlltcpopii Xlltt 'tOU'tO to 1ttO't07tOlEL O llt7tOO'tOAElltc; O'tO enplltcpo (J-E'tlltcpopiic;. ·E, 0 illEc; lltVOp11ltVEc; OUOLEc;. 51. EvwoEtc; lltpOEVtXOU, 01twc;: llt) lltpOEVlXO o;u (uypo), uypec; evwoEtc; lltpoevtxou, tptxAw pwuxo lltpOEVlXO. • ~) lltpOEVlXO o;u ( O'tEpEo ), tpLO;EiBw lltpOEVlXOU (AEUXO lltp­ OEVtXO ), 1tEvto;elBw lltpoEvtxou, lltpoevtxtxo llto~fotto, lltpoevt­ xtxo lltyYTJOLo, lltpoEvtxtxo xiiAto, lltpoevtxtxo vixtpto, lltpoevtw­ oec; XIXALO, lipoEVLWBEc; VIX'tpLO ~pwµwuxo lltpOEVtXO. r) ... LHMEIOLH: OuolEc; Xlltt 1tlltplltoxeuiioµllttllt 1teptexovtllt lltpoEvtxo Xlltl XPTJotµo1tmouµevllt OlltV 1tlltplltol'tOX'tOVllt, eivlltt ouoiEc; tTjc; 84 °. • 52. Evwoetc; uBplltp1upou, 01twc;: ~) o;et;oc; uBpdtp-rupoc;, XAWptouxoc; uBpiipyupoc;. r) ... LHMEIOLEIL: 1. Ouolec; Xlltt 1tlltplltoxeuiioµllttllt 1tou 1te­ ptexouv uBpixpyupo Xlltl XPTJOl(J-07tOLOUV'tlltl OlltV 7tlltpllt0t't0 X't0Vllt, dvlltt ouolec; tTjc; 86 ° . . 2. To XtVVIX~lltpt Xlltt O xAwpwuxoc; uBpixpyupoc; (xlltAoµe­ Alltc;) Bev u1toxetV'tlltl ottc; Btllttii;etc; tTjc; AD R. 3. 0 ~povtWBTjc; uBpixpyupoc; Bev Silt rlvE'tlltt Bextoc; 'Ytllt µe­ 'tlltcpopii. 4. To XUlltVLOUXO uBplltpyuptxo XIXALO Xlltl O XUlltVtouxoc; . uBpixp1upoc; Elvlltt ouolEc; 'tTjc; 41 ° . • 53. EvwaEtc; 01ltMiou, cmw;: ~) .. . r) .. . LHMEIOLH: Ouolec; Xlltt evwoEtc; TJ 1tlltplltOXEUIXO(J-llt'tllt 1tou 1tEplEX01JV 8otMlO Xlltt XPTJOt(J-07tOtOUV'tlltt OlltV 7tlltplltOl'tOX'tOVllt EtVlltt ouoiE; tTjc; 88 °. 54. B1jpUMlO Xlltt evwoEt; ~TjpUMiou, cmwc;: ~) ~TjpUMLO OE OXOVTJ. r) ... 55. LEATJVLO Xlltl Evwoetc; oEATJviou, 01twc;: llt} oeA71vtXIX Xlltt OEATJVLOUXllt IXAllt'tllt. ~) Ot8Ewuxo oeATjVto, Bto;elBto OEA71viou. r) (J-E'tlltMtXO oEATJVlO. LHMEIOLH: To OEATjVtXO o;u elvlltt OUOtllt 'tTjc; KAIXOEwc; 8 (~Ae1te 7tEpt0wpw 2so1, 11 ° (llt)}. 56. EvwoEtc; ooµiou, 01twc;: llt} 'tEtpo;eiBto ooµiou. ~) .. . r) .. . 5 7. Evwou; nUouplou, 01twc;: ~) Bto;doto 'teMoupiou, 'tEMOupwuxo lltAouµlvLO, 'teMOU- • pwux.o xixBµto, teAAouptoux.o; ~wMpyupo;. r) . . . • 58. Evwou; ~otvotBlou, cmw;: ~) 7tEvto;doto ~lltvotBiou, ~otVotOtXIX IXAot'tot r) ... LHMEIOLEIL: 1. O;u - tptX,Awptouxo ~lltvixBto, tnpllt" X Awpwux.o ~otVriBto Xlltt tptX, Awpwuxo ~otvixBto EtVlltt ouolEc; 'tTjc; KArioEwc; 8 (~AE7te 7tEpt8wpto 2801, 21 ° & 22°). 2. XAwptxo Xott U7tEPX. Awptxo ~lltVIXOtO EtVlltt ouolec; 'tTj; KArioEwc; 5.1 (~AE7tE 7tEpt0wpLO 2501, 4°). 5 9. • Evwoetc; lltV'tl(J-OVLOU, 01twc;: r) o;EiBlllt OtV'tl(J-OVtOU, IXAot'tot OtV'tt(J-OVLOU. LHMEIOLEIL: TTev'tlltX,AWpLOuxo OtV'tl(J-OVtO, tptX,AW­ pwuxo lltV'tt(J-OVLO Xlltt 7tEV'totcp8optouxo OtV'tt(J-OVLO ·dvott ouolec; 'tTj; KAixoewc; 8 (~AE7tE 1tept8wpto 2801, 21 °' 22°.& 26 °). 2. XAwptXO lltV'tt(J-OVLO Xlltl U7tEpX, Awptxo otV'tt(J-OVtO EtVlltt ouoiec; 'tTjc; KAixoew; 5.1 (~AE7tE 7tEpt8wpto 2501, 4°). 3. O;dBtllt lltvnµovlou µe 1tEptEX'tlXO'tTj'tllt lltpoEvtxou 1tou BEV U7tEp~lltLVEl 'tO 0.5% 'tTj; OUVOAtXTj; (J-IX,ot; Xlltt tpt0eLOUXOU otvnµovlou, Bev u1toXELV'tlltL ottc; Btottdt;etc; tTjc; ADR. 60. Evwoeu; ~lltpuou, 01twc;: 1) lltv0plltxtxo ~ripuo, x. Awpwux.o ~dtpuo, q,0optoux.o ~ixpuo, uBpo;eiBto ~lltpuou, o;ei6to ~otpuou, 8ewux.o ~ixpuo. . LHMEIOLEIL: 1. XAwptxo ~ripuo, vttptxo ~ixpuo, vttpw­ oe; ~iipuo, u1tepx. Awptxo ~ixpuo, u1tepµotnotvLXO ~ixpuo Xlltl , u1tepo;eiBto ~lltpuou elvlltt ouolec; 'tTj; KArioewc; 5.1 (~AE7tE 7tE­ pt0wpto 2501, 4°, 7°, 8° Xotl 9°), 2. To ot;i6to ~lltpuou dvlltt ouolot t71c; 42 ° . . 3. Ltelltptxo ~iipuo, 8et'ixo ~ripuo xott 'tt'totvtxo ~iipuo Bev u1toxetV'tlltt ott; Btllttri;et~ tTjc; AD R. 61, Evwoetc; xlltBµlou, 01twc;: I) o;etXO ~dtpuo, otv0potXtXO ~rxpuo, Vt'tptXO ~Otpuo, 0ettXO ~ixpuo. LHMEIOLH: Xpwo'ttxe; XlltOµlou, 01twc; 0etouxec; EVW­ OEL; ~lltpuou, oouAcpooEATJVLOuxe; evwoetc; xotBµiou xott dtAottot XlltBµlou 'otvwtepwv At7totpwv o;ewv (1t,X,. O'tEotptxo xdtBµw) Bev u1toxetv't0tl Ott; Btllttix;et; 'tTj; ADR. 62. Evwoetc; µoM~Bou, 01tw;: r) o;eiBtllt µoAu~Bou, 01twc; Aeuxoc; µoAu~Boc; Xott XPW(J-t• xo; µoAu~Boc;, ixAllttllt µoAu~oou, ouµ1teptAot(J-~lltvoµevou o;et xou µoAu~Bou. • • LHMEIOLEIL: 1. XAwptxoc; µoAu~Boc;, vttptxoc;· µoAu­ ~Boc; Xlltl U7tEPX. Awptxo; µoAu~oo; ELVlltt' ouoiec; 'tTj; KAdtoEw; 5.1 (~AE7tE 7tEpt0wpto 2501, 4° xott 7°}. • . 2. • AAllt'tot µoAu~Bou Xotl XPWO'ttxec; µoAu~Bou 7tOU BEV ei- • Vlltt 6tlltAU'tlX OE o. l N uopox.Awptxo o;u, Bev U7tOXEtV'totl O'tt; BtllttlX;Etc; 'tTj; AD R. 63. Kllt'tlXAOt7tllt Xlltt ot7tO~ATj'tllt 1tept EX,OV'tllt EVWOEtc; OtV'tt(J-0· viou iJ µoAu~Bou iJ Xlltt twv Mo, 01tw;: r) tAuc; µoAu~Bou 1tepLEXOUOllt Atj'W'tEpo llt7t0 3% EAEJJ8epo 8ettXO o;u, 'tEq>pEc; lltV'ttµoviou iJ µoAu~Bou TJ lltV'tt(J-OVLOU Xott µoAu~Bou. LHMEIOLH: IAu; µoM~Bou 7tEptEX,OUcillt 7tAEOV 'tOU 3% eAeu0epou 0Etixou o;foc; eivott ouoillt tTjc; KAixoEwc; 8 (~AE1tE 7tEpt0wpLO 2801, 1 ° (~)), 64. • AAllttllt u~pot,iv7Jc;, 01twc;: 1) BtiiBpo~pwµwux.o; uBpot1;lv71, BtiiBpox.Awpwux.oc; uBpllt­ 'lvTJ, µovo - uBpo~pwµwux.oc; uBpllt1;\VTJ, µovo - uBpox.Awpwu­ xoc; uopllt,LVTJ 0Et"ixiJ uBpot1;lVTj. • 65. <D0opLOUX,Ec; EVWOEtc; OtotAU'tEc; O'tO VEpo, 01tw;: ,) cp0opwux.o llt(J-(J-WVtO, cp0optoux.o XIXAto, cp0optouxo vri­ tpLO. LHMEIOLH: Atot~pwttxec; cp0opwuxE; EVWOEL; EtVlltt ou olEc; 'tTj; KAdtoEwc; 8 (~AE7tE 7tEpt0wpLO 2801, 25 ° & 26 °). 66. LLAtxocp0optoux.ot, 01tw;: r) ol.Atxocp0optoux.o llt(J-(J-W\llO. 6 7. r) O;lltAtxri IXAllt'tllt BtOtAU'tlX OE vepo. . 68. Avopj'llt\lE; E\IWOEL; 7tOU BEv µ1topouv Vet 'tot;tvoµ7J8ouv OE IXAAEc; OUMO'ytxec; XOt'tTJ'YOPlEc;, 07tW~: llt} ... ~) . . . . . ,) X,AWplOUX,O XO~IXA'tlO, X,Awpwux.oc; X,OtAxo;, tpto;EiBto µoAu~BEviou. • LHMEIOLH: OuoiE; Xotl 1tlltplltOXEUIXO(J-llt'tot 1teptEX,OV'tllt X,iltAXO Xlltt X.PTJOL(J-01totouµE11E; ootv 1tlltpotottoxto11ot, eivlltt ou­ oiec; tTjc; 87 °. Z. OuoiEc; Xlltt 1tlltplltoxwrioµottot 1to9 XPTJotµo1totouvtlltt olltv 1totplltOl'tOX'tOVllt • LHMEIOLEIL: 1. AvlltcpAe;tµEc; uype; ouoiE; Xott 7tlltpllt­ OXWIXO(J-llt'tllt 1tou X,p7Jotµo1tmou11tott ootv 1tlltplltot'tOX'tOVllt itlltt 1186 EG>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: AEYTEPO) 7t0U ELVOll d;ottpa-ttXIX ,o!;txer:;, ,o!;txer:; 7J Em~Aot~eir:; XOll exouv ETHOPROPHOS 100-65 65-10 10-3 10-3 OTjfJ.ELO OlVOlq>Ae!;ewr:; XIX'tW 'tWV 21 ° C, ELVOll ouaier:; 't'Tjr:; I().ix- FENITROTHION 100-45 100-10 FENSULFOTHION 100-40 40-4 4-0 4-0 aewr:; 3 (~Ae1te 1tEpt8wpto 2301, 6° 7J 19°). FENTHION 100-60 100-15 2. Ei67j otot7tO'ttaµevot p.e ouaier:; xott 1totpotaxeuixap.ot,ot XPTJ· FONOFOS 100-60 60-6 6-0 6-0 OL(J.07tOL7tOUfJ.EVOl aotv 1totpotaL'tOX'tOVOl 't'Tjr:; 71 ° ewe; 88 °' 01twr:; FORMOTHION 100-65 100-15 7tAIXXEr:; tvoaotviootr:;, Awpioer:; ,cotp,tou, (J.1tlXMEr:; ~Olf.l~OlXLOU, MALATHION 100-30 MECARBAM 100-30 30-3 30-0.5 q,uMot 7tAOlO'tlXWV XA7t., OE otEpoa,Eyeir:; XOlL EPf.lTJ'tlXIX XAEl- MEPHOSFOLAN 100-25 25-5 5-50 5-50 ap.evour:; q,otxeMour:;, OEV U1tOXEtv'tOll O'ttr:; OlOl'tlX!;Etr:; 't'Tjr:; AD R. METHIDATHION 100-40 40-4 40-1 71-88: Tot ELOTJ otu,ii xot,ot:tiiaaov,ott a~ot: METHYL TRITHION 100-15 100-4 4TJ,:pio (at): E!;ottpmxii ,o!;txer:; ouaiar:; xott mxpotaxEuii- MEVINPHOS 100-60 60-5 5-0 5-0 MONOCROTOPHOS 100-25 25-3 25-0.5 aµot,ot. NALED 100-50 100-10 4TJq,io (~): To!;txer:; ouaier:; xott 1totpotax. OMETHOATE 100-10 100-3 4TJq,io (y): B).ot~Eper:; ouaiec; & 1totpotaxeuiiap.. OXYDEMETON-METHYL - 100-90 90-9 90-2 LHMEIOLEIL: 1. '0).er:; Ol opota,txer:; ouaier:; XOll 'tot 1totpot- OXYDISULFOTON 100-70 70-5 5-0 5-0 PARATHION 100-40 40-4 4-0 4-0 axwiiap.ot,ii ,wv 1tou ,cp7latµo1totouv,ott aotv 1totpotat,OX'tOVot PARATHION-METHYL 100~15 15-1 15-0 0ot 1tpe1tEl VOl 'tot!;tVO(J.OUV'tOll O'tOl 71 ° ewe; 88 °(at),(~), XOlL ("() PHENKAPTON 100-10 100-2 OU(J.(f)WVOl fJ.E 't'TjV U7t007jfJ.ELWOTj 1. - O'tO 7tEpt0Wpto 2600 (1). PHORATE 100-20 20-2 2-0 2-0 ~- Av eiv otL "(VWO'tTj p.ovov 7l 'tL~7J 'tOU LDSQ 't'Tj~ op0ta'tt x1jr:; PHOSALON 100-20 100-5 PHOSFOLAN 100-15 15-2 15-0.5 ouatatr:; XOlL O,CL 'tWV 1totpotOXEUatO(J.Ol'tWV 't'Tjr:;, 'tO'tE 'tat 'tat 1totpot- PHOSMET (PHTHALO i00-15 OXEUIXO(J.Ol'tOl p.1topouv Vat 'tot!;LVO(J.OUV'tatL O'tOl 71 ° ewe; 88 ° PHOS) 100-4 (at), (~) xatt ( 1) ,cp7jatp.01totwv'tatr:; wur:; xot,w'tepw 1tivotxir:;, PHOSPHAMIDON 100-30 30-3 30-0.5 PIRIMIPHOS-ETHYL 100-30 100-5 awur:; 01toiour:; OL atpt0µoi 1tOU OlVot"(piX<:pOV'tatL O'ttr:; O'tTjAEr:; (at), PHOTHOATE 100-15 15-1 15-0 (~) XOlL (r) 'tWV 71 ° ewe; 88 ° 7totpta'tOUV 'tO 7tOOOO't0 o/o 't'Tj<:; PYRAZOPHOS 100-55 100-15 OpotO'tLXTj<:; 1totpotOL'tOX'tOVOU ouaiatr:; 7tOU 1tEpte,couv 'tot 1tatpot- PYRAZOLON 100-80 80-5 5-0 5-0 OXEUIXOf.lOl'tOl. • SULFOTEP 100-10 10-0 10.0 TEMEPHOS 100-50 3. r tot· ouaier:; 7tOU OEV atvotq,epov'tatl O'tOV Xat'tlXAoyo Xatl rux TEPP 100-10 10-0 'ttr:; 01tOLEr:; ELVatL "(VWO'tTj Tj 'tlf.l7J 'tOU LDSO 't'Tj<:; opotO'tlX7Jr:; OU- TERBUFOS 10-15 15s3 3-0 3-0 aiotEr:; XOlL O,CL 'tWV Otatq,opwv 1tatpataXEUotaµii,wv, 7l 'tot!;tvo- THIOMETON 100-50 50-5 50-1 fJ.TJOTJ Evor:; 1totpotaxEuiiaµot'tor:; µ1topEi vat 1tpoa6topta,Ei ot1to THIONAZIN 100-70 70-5 5-0 5-0 TRIAMIPHOS 100-20 20-2 20-0.5 'tOV 1tivotxot 't'Tjr:; U1t007jfJ.ElWOEWr:; 1. - 'tOU 7tEpt0wpiou 2600 TRICHLORFON 100-80 100-20 (1) XPTJOtµo1tmwv,otr:; 't'TjV 'tlf.l7J 'tOU LD5 1tou 1totipvoµe 1toA- TRICHLORNAT 100-30 30-3 30-0.5 Aat1tAotatix~ov,atr:; 'tTJV ,tµ7J ,ou LD50 't'Tjr:; ~pota'ttX7Jr:; ouaiotr:; mi VAMIDOTHION 100-10 100-3 100 /X 07tOU X 'tO 1tOOOO't0 % 't'Tjr:; opotO'tlX7Jr:; ouaiotr:; XCX'tlX 72°(a) 72°(~) 12°(,) µix~at, auµq>wvot µe 'tov atxoAou0o 'tt11to: 72. XAwp,xoi u6a,<iv- % % a-t•p•o % urpo Opax•i;, 01twi;: r LO . a~a LD50 6paa-t. ouata,; X 100 ALDRIN 100-75 75-7 75-2 CAMPHECHLOR(TOXA a '°' so itapaax•uaaµa.o,; = itoaodi:o % 6paa-t. oua. xa,<i µ<i~a PHENE) 100-10 100-3 4. H 'tCX!;LVOfJ.TjOTj auµq>wvat µe 'ttr:; OTjfLElWOEtr:; 2 & 3 cxvw CHLORDANE 100-55 100-10 CHLORDIMEFORM 100-50 100-10 ,epw oev 0cx ,cp7latµo1totEi'tcxt o,atv 'tCX 1totpcxaxeuiiap.cx,at 1tEpte- DDT 100-20 100-5 ,COUV 1tpoa87JXE<:; 7tOU Emopouv O't'TjV 'tO!;tXO't'Tj'tat 't'Tj<:; EVEp1ou 1,2-6,~pwµo-3 ouaicxr:; 7J O'tatV 'tO 1tcxpataxeuotaµcx 7tEpte,CEl7tAEOV 't'Tjr:; µtiir:; opat- XAWpo1tp01t<XVlO 100-30 100-5 DIELDRIN 100-90 90-10 90-2 anxrir:; ouaiatr:;. LE 'tE'tOLEr:; 1tEpt1t'tWOEtr:; TJ 'tat!;tVOfJ.TjO'Tj 0cx ~atai- ENDOSULFAN 100-80 80-8 80-2 ~E'tatl O't'TjV 'tlfL7J LD 50 'tOU EV Abyw 1tatpotaXEUIXOfLCX'tOr:;, auµ- ENDRIN 100-60 60-5 5-0 5-0 q,wvat µe 'tat xpt't7Jptcx 't'Tjr:; U1t007j(J.ElWOEWr:; 1. 'tOU 7tEpt0wpiou HEPTACHLOR 100-80 80-8 80-2 2600(1 ). Av 7l ,tµ7J 't'Tjr:; L0 58 OEV Eivatt "(VWO-'t7J, TJ ouaicx 0at ISODRIN 100-10 10-1 10-0 LINDANE 100-20 100-5 'tCX!;tVOfLEl'tOll OIXV (at) 'tWV 71 ewe; 88 o. PENTACHLOROPHENOL - 100-50 50-5 50-1 71 °(a) 71 °(~) 71°(r) 7 3. XAwpo-q,a,vo~u-ol;•1x<i 71 • Op1avoq,waq,opoox•, % % anp•o % urpo 1tap<irwra 01tw,;: •vwau,; 01twi;: 2,4-D 100-75 100-15 ACEPHATE 100-40 2,4-DB 100-35 AMICITHION 100-30 DICHLORPROP 100-40 AZINPHOS-ETHYL 100-25 25-2 25-0.5 FENOPROP 100-30 AZINPHOS-METHYL 100-20 20-2 20-0.5 FORMETANATE 100-40 40-4 40-1 BROMOPHOS-ETHYL 100-10 100~3 MCPA 100-35 CARBOPHENITHION 100-20 20-2 20-0.5 MCPB 100-30 CHLORFEVINPHOS 100-20 20-2 20-0.5 MECOPROP 100-30 CHLORMEPHOS 100-15 15-1 15-0 2,4,5-T 100-60 100-15 CHLORPYRIPHOS 100-15 100-4 7 4. Afo1ovo1to,11µiv•,; oPra CHLORTHIOPHOS . 100-40 40-5 5-0 5-0 v,xi,; •vwaoti; µT) .a~1voµ11µi CROTOXYPHOS 100-15 100-3 vo,; a,a 72 ° Tj 73 ° 01tw,;: CRUFOMATE 100-90 100-20 ALLIDOCHLOR 100-35 100-35 DEMEPHIO (O&S) 100-0 .;. BENZOYLPROP-ETHYL 100-75 DEMETON 100-30 30-3 3-0 3-0 BROMOXYNIL 100-35 100-10 DEMETON-0- CHLORDECONE 100-15 100-4 METHYL-LO- CHLORMEQUAT 100-30 THIO-ISOMER 100-10 100-3 CHLOROBENZILATE 100-35 THIONO-ISOMER 100-35 100-5 DICAMBA 100-50 DEMETON-5-METHYL 100-10 100-3 DICHLONE 100-80 DIALIFOS 100-10 100-2 DICOFOL . 100-25 DIAZINON 100-15 100-4 IOXYNIL 100-20 -100-5 DICHLOFENTHION 100-50 100-10 ISOBENZAN 100-5 5-1 1-0 1-0 DICHLORVOS 100-35 35-5 35-5 MIREX 100-60 100-15 DICROTOPHOS 100-25 25-3 25-0.5 PROPACHLOR 100-35 DIMEFOX 100-20 20-2 2-0 2-0 PROPANIL 100-25 DIMETHOATf. 100-30 100-10 TETRADIFON 100-25 DIOXATHION 100-40 40-4 40-1 .75. A~w.ouxo,; op1avLXi,; DISULPHOTON 100-15 15-2 15-0 ,vwaoti; µT) .~1voµ11µivo,; at DITHIANON 100-50 ilia <ipOpa 01tw,;: ENDOTHION 100-45 45-5 45-1 VENQUJNOL 100-25 100-5 ERYN 100-75 75-15 15-3 15-3 BINAPACRYZ 100-25 100-5 ETHION 100-25 25-2 25-0.5 BUTOCARBOXIN 100-30 100-5 ETHOATE-METHYL 100-25 100-5 CHINOMF,THIONATE 100-55 E<DHMEPII THI KYBEPNHIEQI (TEVXOI AEYTEPO) 1187 CYANAZINE 100-35 100-10 PYRETHRINE 100-30 CYCLOHEXIMIDE 100-10 100-3 ROTENONE 100-25 100-6 DINOBUTON 100-10 . 100-2 84. Av6py0tvt<; evwaw; expo•· DINOSEB 100-40 40-5 - 40-5 vtxoU, 61tw:;: DINOSEB ACETATE 100-10 100-3 TPIO:::EI<l!O APl:ENIKOY - 100-40 40-4 40-1 DINOTERB 100-50 50-5 50-1 APl:ENIKO ALBHTIO 100-40 40-4 40-1 DINOTERB ACETATE 100-10 100-3 APl:ENIKOYXO NATPIO - 100-20 20-2 20-0.5 DIPHENAMID 100-55 100-10 8 5. A~opr0tve,; EVWOEt<; cp6o-.. DNOC 100-50 50-5 50-1 DODINE 100-25 plOU, 07tWc;: l:,).,xo-cp0op,ouxo DRAZOXOLON 100-25 100-5 ~<ipuo 100-35 100-8 MEDJNOTERB 100-80 80-8 80-2 LLA<xo-cp8opt0u)(O METHYL ISOTHIOCYA- VcttplO 100-25 100-5 NATE 100-35 100-8 86. Avopy0tvE, EVWOE<<; NITROFEN 100-30 u1ip0tprupou, 61tw,;: TERBUMETON 100-20 XAwplOU)(O,; u1ipctprupo<; 100-70 70-7 70-1.5 TRIDEMORPH 100-30 O~ei1it0 u1ipexprupou, 100-35 35.5 35-0.5 76. K0tp~ovtx<X x0t, 0at0x0tp· 87. Avoprexve,; EV wau, xexA ~ov,x<i, 61tw<;: xoU, 61twc;: ALDICARB 100-15 15-1 1-0 1-0 O~u-xAwpLOU)(OC, )(OtAXOC, 100-35 AMINOCARB 100-60 60-6 60-1 0e,ixo,; )(0tAxo,; 100-20 100-10 BARBAN 100-30 88. Avoprave,; EVWOE<C, €)0().. BENDIOCARB 100-65 65-5 65-1 Aiou, 61tw,;: CARBARYL 100-80 100-20 0e'1xo 0ctMLO 100-30 30-3 30-0.5 CARBOFURAN • 100-10 10-1 10-0 DI-ALLATE 100-80 100-20 89. (r) Litcipot OTJ(J.TJ'tpllXXWV, Xot'tEpjotO(J.EVOl 01tcip0t Xotl DIMETILAN 100-50 50-5 50-1 " DIOXACARB 100-10 100-3 <XAAE<; 0\JOlE<; (j)\J'ttx71c; itpOEAEUOEWc;, OtotltO'tlO(J.EVEc; (J.E avot 71 EPTC 100-80 m:p1oocitEpot ltotpotol'tOX'tOVot 71 IXAAEc; O\JOtac; 'tTjc; KAiioEwc; &. l !SOLAN 100-20 20-2 20-0.5 f. l1eotO'tlXEc; OUOiE<; 1teooe1~0~EVEc; riot EerotonJelot Xotl MERCAPTO-DIMETHUR - 100-10 100-3 MET AM-SODIUM 100-50 100-10 ltEleii~ot'tot ~ lot ~lO~:!]:X,otVIX~ ltot~ywyiJ ~ote~otXE\J'tlXWV METHOMYL 100-30 30-3 30-0.5 lteOtOV'tWV, otV - EV otVot~eeoV'totl OE IX-CX ixe0eot 't:!]c; ltoteOUO:!Jc; MEXACARBATE 100-25 ,25-2 25-0 K).iioawc;. MOLINATE 100-25 NABAM 100-80 100-20 90. 6potO'tlXEc; O\JOlE<;, oitwc;: OXAMYL 100-10 10-1 10-0 ot) COLCHICINE, DIGITOXIN PENDIMETHALIN 100-50 ~) AopEvotAiv71 PIRIMICARB 100-75 100-20 1) PHENOBARBITAL 2601 PROMECARB 100-15 100-3 PROPOXUR 100-15 100-4 :EHMEm:EEI:E: 1. 01 opoto'ttxec; ouoiEc; xot11toA'to1to171oa1c; SULFALLATE 100-40 71 µi1µottot twv ouotwv otutwv tou 90 ° µa <iUac; ouoiac; 1tpi1ta1 THIRAM 100-25 \lot 'tot~lVOfl-OtlV'totL ouµq,wvot µa 't7l\/ 'tO;lXO'tTJ'tlX. 'tW\/ (~AEltE TRI-ALLA TE 100-30 77. Ahex).oe,8~, 61tw,;: UltOOTJfl-EtWOTJ 1 O'tO 1tept8wpt0 2600( 1 )). NIKOTINH 100-10 100-2 2. <l>otpµotXe\J'tlXIX itpo'tciv'tot E'tOlfi-ot jlot XPTJOTJ (oioxiix.; xix~ l:TPYXNINH 100-20 20-0 mot, otfi-ltOtlAec; XAlt.) ltO\J 1tep1exouv O\JOtec; 'tO\J 90 ° OeV \JltO 7 8. Opr0tv,xi.r, evwau,; xm'totl ot1c; Otottii;atc; t71c; ADR. u1ipexp1upou, 61tw,;: PHENYLMERCURIC ACE- H. Kavic; ouoxEuototEc; TATE (PMA) 10-60 60-6 60-1.5 1:HMEinl:H: KEvic; ouoxEUotoiac; µa Xot'tlXAOlltot otltO 1tpo71 CHLOROLMETHOXYE- 1ouµEvot 1tEptaxoµa11ii 'tWV XOAATJ(J.Ellot oto i;w µipoc; OEV 0ot THYL 100-40 40-4 40-2 1ivov'totl oaxtic; 1tot fi-E'totcpopot. PHENYLMERCURY PYRO CA TECHIN (PMB) 100-60 60-6 60-1,5 91. Ki::vac; 0\JOXEUotoiac;, XEV(X ~U'ttocpopot OX7Jfl-lX'tot, xavac; 79. Op1av,xi.,; ,vwae,,; <j,tu- OE;otµavic;, xavec; oa;otµavec; XOV'tETJVEpc; Xotl XEVIX XOV'tETJVepc; 1i0tprupou, 61tw,;: xuµot aµ1top. otxot0iipto'tot, ltOU lteptaixotv ouo[ac; 'tTJ<; KAiioawc; FENTIN ACETATE 100-25 100-5 6.1. CYHEXATIN (TRICYC Ouoiic; twv 11 ° - 2 4 °, 3 2 ° • 36 °, 41 ° - 44 °, 51 ° - 68 °, 260lot LOHEXYL • TIN HYDRO XIDE) 100-55 100-10 71 ° - 8B O Xotl 90 °, fi-E'tot(j)EpciµEvEc; ouµq,wvot fi-E 'tic; Xot'tW FENTIN HYDROXIDE 100-20 100-5 tepw Olot'tlX~elc;, OEV UltOXelV'totl Otl'te Otte; Olot't1X;e.1c; 'tTjc; ltotpou 80. • iller, oprexvoµetill,xi.r, • 071c; KAiioawc; ltOU 1tep1exoV'totl O'tO ltotpciv Tiotp!Xp'tTjµot, Otl'te evwau,; ltQ\) OEV µ1topouv vex tex~<VOfLlj00UV CltOt 78 & 79, Otte; Olottii;a1c; itou 1teptixovtot1 oto I1otp<ipt71µot B. 61twc;: ot) Ouoiac; i:ot;1voµouµavEc; oto (ot) xii0E <ip0pou - aioouc;, oav 81. novtLXOXtovex, 61tw,;: XotAtllt'tOV'totl otltci 'to ltotpov mp18wpt0. CHLOROPHACINONE 100-40 40-'.I- 4-0 4-0 ~)Ouo[ac; tot;tvoµouµavac; O'tO (~) xii0e EiOouc;: Yjpot: ox1 COUMACHLOR 100-10 100-2 ltAEOV 'tWV 500 XAO't. OE xii0a EOW'tEplXTJ OUOXE\JotOtot Xotl ox1 COUMAFLURYL 100-80 100-20 itAfov -cwv 2 Ai-cpwv Xot't!X ouoxauotoiot. COUMAPHOS 100-30 30-3 30-0.5 LtepEii: oxt itAfov tou 1 x1Aou OE xii0a aowtap1x71 ouoxEuot CRIMIDINE 100-25 25-2 2-0 2-0 aiot Xotl to 1t0Au 4 x1Aii xot't!X auoxauotaiot. DICOUMAROL 100-10 100-2 DIPHACINONE 100-25 25-2 2-0 2-0 r) Ouaiec; 'tot;1voµot1µEvEc; O'tO (r) xii0e aioouc;: Yrp<i: 'tO WARFARIN 100-20 20-2 2-0 2-0 1t0Au 3 ).hpot xot-cii aawup. auaxEUotaiot Xott to ltOAt> 12 Ahpot 82. I1exp<irw,0t tou 6mup,1iu- Xot't<X O\JOXEUotOtot. ).(ou, 01tw<;: L'tepE<i: To 1t0At1 6 XLAIX xottii aawtap1x71 auaxauotaiot Xotl to DIQUAT 100-45 100-10 MORFAMQUAT 100-65 100-15 ltOAt> 2 4 xl.Aii Xot'tlX ouaxEUotaiot. PARAQµAT 100-40 40-4 40-4 01 ltOOO't7j'tEc; otU'tE<; 0\JOLWV 1tpe1tEl Vot (J.E'totcpipOV'totl OE auv 83, Op1exv,xi.,; .avwau,; 1tou • ouotaµivac; O\JOXEUotOtec; ltOU 'tOUAIXXLO'tOV ltATJpOt>V touc; opouc; OEV µ1topouv VO( t0(~tVOfLlj60UV a• aullo1,x~ xextlj')'Opiex exito tou 1tEp10wpiou 3538. 71 ° i.w,; 81 °, 61tw,;: 0ot 1tpE1tEl VIX 'tTJpOt>V'totl 01 «fEVLXoi OpOl OUOXE\Jotaiotc;» 'tOU ALLETHRIN 100-30 1tap10wpiou 3500(1) (2) xott (4) ewe; (7). BENTAZONE 100-50 2. ~lott!X;et<; DAZOMET 100-25 DESMETRYN 100-65 1. feVlXOt OpOl OUOXE\JotOiotc; DIFENZOQUAT 100-90 100-20 1) Tot XOAot 0ot 1tpi1tEl Vot ltA7jpouv -couc; opouc; 'tOU Tipoaotp DIMEXANO 100-45 100-10 't'Tjfl-ot'tOc; AS EX'toc; otV O'tot 1tep10wptot 2603 - 2609 itpoOLot ENDOTHAL-SODIUM 100-75 75-5 75-2 jp<X(j)O\/'totl EIOLXOt opot jlot 'tTJ OUOXEUotaiot wp1aµa11wv OUOIW\/. FLUORACETAMIDE 100-10 10-1 10-0 PINDONE 100-55 100-10 2) 1:uµq,wvot µa 'tlc; Olot't<X~El<; 'tOU ltept0wp1pu 2600 ( 1) Xotl 1188 EcJ>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: aEYTEPO) ~ou 1tEpL0wplou 3511 (2), 00t 1tps1tEL YOt XP71CJLµo1toiouv't0tL 'tot e!;71c;: KoAOt T71c; oµdt60tc; CJUCJXW0tCJl0tc; 1, µ0tpx0tp1CJµsv0t µe 'tO 2602 rpdtµµot «X» r10t 'ttc; e!;ottpE'ttXOt 'tO/;Lxic; OUCJLEc; ltOU 't0t!;Lvoµou Y't0tt µe 't:O rpdtµµot ( 0t) xot0evoc; doouc;. KoAOt 't71' oµdtooc; CJUCJXWOtCJLOtc; II 7J I µ0tpx0tptCJµsv0t µe 'tO rpdtµµot (( y » 7j «X» jtOt 'ttc; 'tO/;txic; OUCJLEc; 7tOtjl'tOt!;tvoµoiiY'tOtL CJ'tO rpdtµµot (~) xdt0e Eloouc;. KoAOt T71c; oµiiooc; CJUCJXW0tol0tc; III, II 71 1 µ0tpx0tpLCJp.EYOt µe 'tO rpdtµµot «Z», «Y» 71 «X» rtot nc; Em~AOt~Elc; ouolec; 't0t/;L110 µouµevec; O'tO rpdtµµot (r) xii0e eloouc;. LHMEI01H: ft0t.'t71 fLE'totcpopii ouoLwv 'tTjc; KAotCJEwc; 6.1 (,LE ~Utt0cpop0t <?X7JP.Ot't0t, OtltOCJUYOEOµevec; 6e!;0tµevsc; 71 6e!;0tµe­ YEc; XOV't571YEP~ )(O(L 1LOt 't71 xuµot µE'totcpopdt urpwv T71c; K)..ii­ oewc; OtU't7lc;, ~AEltE TT0tpiipT71µ0t B. 2. EtoLxo[ opot jtOt CJUOXWOtCJLOt wptoµsvwv OUCJLWV 1) To uopoxuOtVLXO o!;u 'tOU 1 ° 1tpE1tEL VO( CJUOXW<X~E'tOtL: 2603 0t) O'totV ELYOtl 'tEAEtOt 0t1toppocp71µsvo OtltO 0tOp0tv71 1topw671 OU- • olot: OE OtY0exnxii p.E'totMtVOt 6oxel0t 1tEpLEX'tLXO't71'toc; 'tO ltOAU 7 .5 Ahpwv, 't01t08E't7JµEYOt OE !;uALVOt XL~W'tlOt XOt'tlX 'tE'tOLO 'tp07t0 WCJ'tE VOt µ71 µnopouv VO( EA0ouv CJE EltOtcpTj µe'tot!;u 'tWY. Au'toc; 0 OUYOU0toµoc; OUCJXEU0tol0tc; 1tpE1tEL VO( 1tA71pol 'touc; e!;71~ opouc;: . 1. Tot 6oxel0t 1tpE1tEL YOt 6oxLµot,OV'tOtL OE ltLEOTJ 'tOUA<XXLCJ'tOV 0.6 MP0t (6BAR). • . 2. Tot 6oxel0t 1tpE1tEt YOt ELVOtL EV'tEAwc; 1EfLOt'tOt µe 'tO 1topw 6ec; UALXO, 'tO onolo 6ev 1tpE1tEt vot xAuowvl,E'tOtt oun vot ax71 µ0t'tl,Et Emxlv6uv0t XEVOt, 0txoµ71 XOtL p.E'tlX 1t0tp0t'tE't0tµEv1) :x.P7JOTJ 7j [-1.E't<X xpoUOTJ, EO'tW ~OtL otv 71 0epµoxp0tCJl0t cp0iioet iwc; 50°C. 1'to XOtlt<XXL xii0E ooxelou 00t 1tpE1tEt VOt 0tv0typiiq>E't0tt 0tve!;h71A0t 1) 1)fLEpoµ71vl0t 7tA1JPWCJEWc;. 3. H ouv6u0toµiv1) OUCJXEUOtCJLOt 1tpE1tEt VOt EAerx0e[ XOtl e1xpt0el ouµcpwvot µe 't1)V TTpoCJ071x71 A.5 1tot 't71Y oµdt60t CJu­ CJXEU0tCJl0tc; 1. To xdt0e XOAOY OEV 1tpE1tEt VO( ,url,EL 1tEpLCJCJcmpo OtltO 12 0 XtA<X. ~) O'tOtV ELVOtL urpo, OtMOt OXL 0t1toppocp71µivo OtltO 1topw6ec; UALXO: CJE xuAlvopouc; 0tv8p0txouxou XOtAU~oc; OtV0EX'tLXOUc; OE· 7ttECJ1), ltOU 00t tXOtV OltOLOUV 'tOUc; E/;7lc; Opouc;: 1. TTpO'tOU XPTJOLfL01tOL1)00uY YLOt 1tpw't71 cpopdt, OL OtV0EX'tL­ xol CJE ltLECJ71 XUAtv6pm 00t 1tpE1tEL VOt UltO~OtMOV'totL OE oox1µ0t­ ol0t mfoewc; 'tOUAOtXLCJ'tOV 10 MPA (100 BAR). H ooxLµOtCJLOt mfoewc; 00t 1tpi1tEt vot rn0tv0tA0tµ~0tVE't0tt otvdt 6Le'tl0t XOtt 00t 1tpi 1tEL vot 1tEpLAOtfL~IXVEL AElt'tOfLEP711tpooEX'tLXO sAerxo 'tOU EOW'tE­ ptxou 'tOU 6oxeiou XOtt EAEUO 'tOU OtTCO~<XpOU. 2. OL XUAtv6poL 1tpE7tEL VO( ELI/Ott CJuµµopcpot 1tpoc;, 'ttc; CJXE'tLxsc; OLOt't<X/;ELc; 1:71c; KAIX'OEwc; 2 (~AEltE 7tEpt0wptOt 2211, 2212, (1) (ot), 2213, 2215 )(O(L 2218). 3. Ex1:oc; 'tWV EVOEt/;EWV ltOU 1tpo6t0typdtcpov't0tL O'tO 1tEp18w­ pt0 2218 (1) (ot), (~). (6), (e) XOtL (71), 00t 1tpE1tELVOt 0tv0trpdtcpe­ 'tOtL XOtL 71 71µepoµ71vl0t T71c; 1tAfov 1tpoCJcpii1:ou 1tA71pwCJewc; (µ71 v0tc;/hoc;). Meylon1 em1:prnoµsv71 µii~ot 1tepexoµivou: 0.55 xLAou XOt'tlX Ahpo 1tEpLEX't:tXO'tTjtoc;. 2) AtotAUfLOt't:Ot uopoxuotvtxou o!;foc; 't:OU 2 ° 1tpE1tEt VOt 01)~ OXEUOt,OV'totL CJE yuotALVEc; 0tµ1touAEc; XAEtoµivec; OE cpAbyot, ltOU VO( 1tEptsxouv 'tO ltOAU 50 rP· 71 CJE jUIXAtVEc; cpt!XAEc; E'tCJt xAEL­ CJµsvec; WCJ't:E VO( µ71v µ1topel VO( rivet 6L0tppo71 XOtL ltOU 7tEpt5)(0UV w ltOAU 250 rp. OL 0tµ1touAEc; 71 cpLotAEc; 1tpE1tEL vot µe,1:0:cpipov1:0tt CJE ouv6u0t­ aµsvec; CJUCJXEtJO(CJtEc; ltOU VO( 1tA71pouv· 'touc;··E!;71c; opouc;: ot) Ot 0tµ1touAEc; XOtL OL cptatAEc; 00t 1tpi1tEL vot CJnpewvov'tott µe OtYO(CJXEttXIX OtV'tL0AL7t'tLXIX UALXIX OE 0tAouµtvivL0t 71 XOtAU~OLVOt el;w'tEptxlX mpL~A71µ0t1:0t xwplc; Ototppoic;. Kix0e XOAOV 00t 1tps 1tEL VOt ,url,Et 't:O ltOAU 15 XtA<X, 71: ~) Ot 0tµ1touAEc; XOtL Ot Cj)LIXAEc; 00t 1tpE1tEL VO( 01:picpwvtOtL µe OtVOtCJXE'ttXIX otvn0AL7t'ttX<X UAtXIX OE !;uAtVOt Xt~W'ttOt µe EltEV 0UCJ71 cpuMOU em<J,w60tprupwµivou xwplc; Ototpposc;. Kdt0e xo­ AOV 6ev 00t 1tpE1tEL VOt ,url~Et ltA.EOV 'tWV 75 XtAWV. Ot ouv6u0tCJµivec; CJUCJXWOtCJLEc; 1tou 0tv0tcpipov,0tt 01:0 ( 0t) XOtt (~) 00t 1tpE1tEt VO( exouv OOXLfLOtCJ'tEL XOtt EjXpL0Ei, ouµcpwvot fLE 'tO ITpoCJ0tp,71µ0t A.5 1LOt 'tTjV oµdtoot OUOXEU0tCJl0tc; 1. Metilltxdt x0tp~ovt1AL0t ,71c; 3 ° 00t 1tpE1tEL vot ouoxeudt~ov,Ott 2604 we; e!;71c;: 1) LE xu,ic; cpt<XAEc; xwplc; p0tcp71 XOt'tOtCJXEU0tCJµivec; OtltO XOt 00tpo OtAouµlvw xwp71,tXO'tTJ'tOc; 'tO ltOAU 1 Ahpou XOtL ltcxxouc; 'tOtXWfLOt'tOc; 'tOUAIXXIO'tOY 1 xoi:., ltOU 00t 1tpE1tEI YOt OOXLµotO'tEL CJ£ lttEOTJ 'tOUA<XXLO'tOV 1 MP0t (10 BAR). 01 cptiiAEc; 00t 1tpE1tEt YOt xAeioV'tOtt µe µei:illtxo ~Low,o 1twµ0t µe 0tOpotV7I cpAotV't~Ot ltOU 00t 1tpE1tEt VO( ~tOWVEL ocptx,dt O'tO AOtLf.lO ,71c; cptiiA71c; rtot VO( OtltOxAEtO't:EL xii0e xot:>..dtpwo71 X<X'tW Ot,:tO XOtYOVLXEc; ouv071xAec; µe,otcpopiic;;. To no)..u ,foCJotpE~ 0tAouµ1vivtec; cpuilec; ,ou ,u1tou 0tu1:ou µ1topouv VOt OUCJXEUOt,OV'tOtt OE E/;W'tEptxec; OUCJXEUOto[ec; OtltO !;uAo, tVOCJOtVLOOt f.lE IXCj)AEX'tiX OtVOtCJXE'ttXIX OtV'tL0At7t'tLXOt UALXOt. Ml0t 'tE'tOtOt CJUYOUO(CJµev71 CJUOXEUOtOLOt 00t 1tpE1tEt VOt ELVOtL CJUµ­ µopcp71 f.lE CJXEOtOtO'tLXO 'tUltO ltOU EXEL OOXlf.lOtO'tEL XOtt erxpt0Et 1 Lot oµii60t ouCJXEU0tol0tc; I, CJuµcpwv0t µe 1:0 ITpoCJ<ip-c71µ0t A.5. Kii0E XOAOV 00t 1tpE1tEt VOt ,url,Et 'tO ltOAU 10 XLAOt. 2) 1E fLE'tOtMtXIX OOXELOt ecpwotOtCJf.tEVOt f.lE 'tEAElwc; OtV'tlOt0tp­ po"ix0t ouCJ1:71µ0t-c0t 'tot 01tol0t 00t 1tpi1tEt EV 0tvix1 x71 YOt ELVOtL 0tocp0t­ ALCJfLEV0t OtltO xii0e µ71x0tvtx71 '71µl0t fLE 1tpOO'tOt'tEU'ttXOt xotAuµ­ µ0t1:0t. XotAU~OtVOt 6oxelOt xwp71-cLXO't1)'tOc; 'tO ltOAU 150 Ahpwv 00t 1tpE1tEL VOt sxouv 1tocxoc; 'tOLXWf.lOt'toc;; 'tOUAOtXLO'tOY 3 xo't. EVW µerotAutEpOt XOtAU~OLVOt 6ox El0t XOtt 6ox ei0t XOt'tOtOXEUOt­ OfLEVOt OtltO OtMOt UALXOt 00t 1tpE1tEt VO( exouv 'tOLXWf.lOt'tOt otpXE'tOU 1t0txouc; WO'tE VO( E/;0tCJcp0tAt~OUV OtVIXAOr7l µ71x0tvLX7j OtV'tOX7l· Merlo-c71 E1tt'tpE1tofiiv71 xwp1j'tlXO't71c; ooxelwv: 250 Ahpot. H f.lOt~Ot 'tWV 1tEpLEXOfLEVWV 00t 1tpE1tEI VOt EtVOtt 'tO ltOA\I 1 XtAO x0t1:dt )..hpo nepmc,. ITpo,ou :x,p7101µ01tot710ouv 1LOt 1tpw,71 cpopii, 'tOt OOXELOt 00t 1tpi1tEL vet 6oxLµ0t,oV't0tL µe u6p0tuA1x71 1tleo71 ,ouAOtXLCJ'tOV 1 MP0t ( 10 BAR). H 6oxLµ0ta10t mfoewc; 00t 1tpi1tEL vot £1t0tv0t­ A0tµ~iivE,0tt xdt0e 1tiv1:e xpovL0t XOtt 00t 1tps1te1 vot 1tEpLA0tµ~dtvet XOtt AElt'tOf.tEp7j 1tpOOEX'tLX7I em0ewp71071 'tOU EOW'tEpLXOU 'tOU ooxeiou we; XOtt EAerxo 'tOU OtltO~Otpou. Me,OtMtXIX 6oxel0t 00t 1tpiitet VO( 0tv0trpixcpouv 'tOt e!;71c; O'tOtXELOt µe EUOtY<X1YWCJ'tOt XOtl 0tvel;h71A0t 1pixµµ0t,0t: Ot) 'tO ovoµot 'tTjc; OUCJLOtc;; oAorpdtcpwc;; ( ,Ot OYOf.lOt'tOt XOtL 'tWV ouo OUOLWV µnopouv EltLOT)c; YOt OtYotcpipov,otL OtltAOt - OLltAOt OE 1tEpl1t'tWCJ71 EVotMOtX'tLX7lc; XP7lCJEWc;;. ~) 'tO ovoµot 'tOU LOLOX't7j'tTJ 'tOU ooxelou. r) 'tO OtltO~Otpo 'tOU ooxelou, CJUf.lltEptA.0tµ~0tvoµivwv XOtL 'tWV OltOLWV el;0tp,71µii1:wv XOtt ouoxwwv, b1twc; ~otA~loec;, 1tpoo1:0t­ 'tEU'ttXIX XOtAUf.lf.lOt'tOt XAlt. 6) ,71v 71µepoµ T)VLOt (µ11v0tc;, hoe;) 1:71c; 0tpxtx71c;; OOXLf.llXCJLOtc; XOtL 1:71 ocpp0trl60t 'tOU Ef.lltEtporvwµovOt ltOU EXOtf.lE 1:71 6ox1µ0t­ CJLOt. e) 't71 fLEjLCJ'tTj Eltl'tpElt'tTj fL<X~Ot 'tOU 1tEpLEXOP.EYOU 'tOU 00 XELOU CJE XLA<X. ~) ,71v ECJW'tEptx71 ltLEOT) (1tLEOT) OOXLµ0tCJL0tc;) ltOU 00t OtCJXEL'tOtt xot,ci 1:0 ,fo, u6p0tuAtx71c; mfoewc;. 1) OuCJiEc; 'tllt!;tvoµouµEvec;; CJ,71v 7tlltp. ot) 'tWV OLlltcpopwv dtp- 2605 0pwv - Et6wv 'tOU 7tEpL0wplou 2601 00t 1tpE1tEt Vilt CJUCJXEUOt~O V'tOtt: llt) OE XllLAU~OtVllt ~lltpEAtllt µe µ71 lltcp0ttpouµevec; XECj)lltAEc;, CJUfL(!>WVllt fLE 'tO 7tEpt0wpLO 3520, 71: ~) CJE lltAOUfLtVEVtllt ~0tpfo0t µe µ 71 0tcp0ttpouµevec; XECj)lltAEc;, CJuµcpwvOt µe 'tO 7tept0wpto 3521, 71: y) CJE XOtAu~6LVllt fLltL'tOVtOt CJuµcpwvllt µe 'tO 7tEpL0wpto 3522, 71: 6) CJE ltAOtCJ'ttXIX ~OtpEAIOt µe µ71 lltcplltLpouµevec; XEcpotUc; 'tO ltOAU .60 Ahpwv, 7j CJE 7tAlltCJ'ttXOt µ1tt'tOVLllt, CJt1µcpwv0t µe 1:0 1tE­ pt0wpLo 3526 7j: E) CJE CJUV0E't:Ec; CJUCJXEUlltOLEc; (0t1tO ltAOtCJ'tLXO UAtxo) CJuµcpwvOt µe 'tO 7tEpt0wpLO 353 7, 71: ,) CJE CJuv6u0tCJµivec; CJUCJXEUotCJlec; µe ECJWtEptx7j CJUCJXEUlltCJtOt • lltltO rulltAt, ltAOtCJ'tLXO 71 µhillo, CJuµcpwvllt µe 'tO 7tepL0wpLO 3538. 2) Lnpeic; ouCJlec; Xllt'tlX ,71v ivvotot 'tou 1tEpt0wplou 2600 (2) µ1topOUV ElttCJ71c;; Vilt CJUCJXEUOt~Oll'tOtL: llt) CJE ~0tpsAtllt µe lltcpllttpouµiv71 xecpot:>..71 CJuµcpw110t µe ,o mpt 0wpw 3520 (XlltAU~OtVOt), 3521 (otAOUf.lLYEVLOt), 3523 (xo­ ll'tpllt-ltAlltXE), 3525 (LvoCJlltvlollt) 71 3526 1 tot ltAOtCJ'tLxix uAtxcx, ev lltvoc1 x71 µe EVllt 7j 1tEptCJCJO,ipouc; nuxvoiicpll(CJµevouc; ECJwnpt­ xouc; CJotxxouc;, 7j: ~) CJE CJUVOUlltCJµivec; CJUCJXEUlltCJLEc; CJuµcpwvot µe 'tO 7tEpL0wpto 3538, µe EYllt 7j 1tEpLCJCJo,ipouc; 1tuxvoiicp0tCJµivouc; ECJW'tEptxouc; odtxxouc;. ECJ>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: ~EYTEPO) 1) OuaiEi; ,0t!;t11oµouµE11Ei; a-co(~) -cwv 6t0tq>6pw11 dtp0pwv EL6W\I 'tOU 7tEpt0wpiou 2601 60t 1tpE1tEt \IIX OUOXEUOt~O\l'tlXl: IX) OE XIXAU~6t111X ~IXpEAtlX, auµq>WIIIX flE 'tO 7tEpt0wpto 3520, t . . ~) OE IXAOUfll\lE\lllX ~IXpEAtlX auµqiw110t flE 'tO 7tEpt0wpto .' 3521, t r) OE XIXAU~6t\llX µm,O\ltlX, Otlfl<f>W\IIX µ. 'tO 7tEpt0wpto 3522, ~: 6) OE 7tAIXO'tlXOt ~IXpEAtlX ~ 7tAIXO'ttXOt f1:1tt'tO\ltlX, auµq>WIIIX flE 'tO 7tEpt0wpto 3526, ~: E) OE au116u0taµe11Ei; auaxwaiEi; ( IX7t0 7tAIXCl'tlXO UAtXO ), auµ <f>W\IIX flE 'tO 7tEpt0wplO 3537, ~: . ~) OE ClU\16UIXOfLE\IE<; ClUOXWIXOiE<;, Otlfl(f>W\IIX flE 'tO 7tEpt0wpto 3538. I:HMEim:H Cl'tlX (0t), (~) XIXt (6): B0tpEAtlX flE 1Xq>0ttpouµE11TJ XE(f>IXA~. rnt,pE7tO\l'tlXl µ6110 jtlX t!;w6Eti; ouaiEi; 7t0U exouv ~0t6µ0 t!;w6ou,; 7t0t\lW IX7t0 200 xa,. 2 OE 23 °( XIXt jllX a-c.paat. 2) OuaiEi; ,0t!;tvoµouµa11ai; a-co 15 ° (~) µnopouv a1tia1Ji; 110t auaxaudt~o11,0tt aa au116u0taµi11Ei; auaxw0taiai; ( 1u0tAi 1topaa­ A0t\lT) ~ xap0tµtxdt), auµq>WIIIX flE 'tO 1tapt6wpto 3539. 3) :E,Epi;ii; ouai.i; x0t,dt 'tTJII EWOtlX -cou 1tEpt6. 2600(2) µ1to­ pou11 \IIX OUOXWIX~O\l'tlXL: IX) OE ~IXpEAtlX flE 1Xq>0ttpouµe111j XEq>IXA ~, auµq>WIIIX µ. 'tO 7tE­ pt0. 3523 (jtlX X011'tp1X-7tAIXXE) ~ 3525 (jtlX t\lOOIX\li60t), Ell 0t11dt1 xTJ XIXt µE i110t ~ 1taptaao-cepoui; 1tuxvoiiqi0taµi11oui; aawn­ ptxoui; acixxoui;, ~: ~) OE IX110EX'ttXOtl<; O'tO 11apo OIXXXOU<;, OUfl<f>W\IIX fl• 'tO 1tapt 6wpto 3533 (jtlX tl(f>IXOfllX), 3534 • (jtlX 7tAEX'tO 7tAIXCl'tlXO UAtxo), 3535 (jtlX 7tAIXO'ttXO qiuUo) ~ 3536 jllX IX\10ax-ctx6 OE \IEpO X1Xp,i; flE 'tTj\l 1tpoii1to6EOTJ nwi; 'tilt Efl7tOpEuµix,IX IX7t0- a-ciUov,Ott a0t11 1tA~pai; qiop-cio ~ a0txxot 0taq>0tAi~o11,0t OE 7tEACX­ 'tE<;. 1) OuaiEi; ,IX!;tvoµouµEvai; O'tO (r) 'tW\I 6t0tqiopw11 at6wv 'tOU 7tEpt0wpiou 2601 60t 1tpEmt \IIX ClUOXEUIX~O\l'tlXt: IX) aa X1XAU~6L\IIX ~IXpEALIX auµqiw111X flE 'tO 7tEpt0wpto 3520, ~: ~) aa IXAOUflL\IE\ILIX ~IXpEALIX auµqiwylX µa 'tO 1tEpt6wpt0 3521, ~: r) OE X,IXAU~6t\llX µm-co\ltlX, auµqiw110t flE 'tO 1tapt6wpto 3522, ~: 6) aE 1tA0ta,txci ~IXpEAtlX ~ 7tAIXO'ttxci µm,611t0t auµqiw110t µa 'tO 1tai;pt6wpto 3526, ~: E) aa au116u0taµi111j auaxau0tai0t auµqiw110t µa -co 1tapt6wpt0 3538, ~: ~) aa au116u0taµev.i; auaxw0taiai; (1 uOtA[, nopaEACXIITJ ~ xap0t­ µtxci) Otlfl(f>W\IIX flE 'tO 7topt0wpto 3539, ~: TJ) aa Aa1t-cei; µ.-c0tUtxei; auaxau0talai; auµqiw110t µa -co 1tapt 6wpto 3540. :EHMEIQI:H: O'tO (0t), (~), (6) XOCL (TJ): B0tpEAtlX µa 1Xq>0ttpou­ µa11ai; XEq>IXAE<; auµqiw111X flE (0t), (~) XIXt (4) XIXL AE7t'tE<; µa,IXA­ ALXE<; OUOXEUIXO[Ei; auµqiwvai; flE (TJ) am-cpe1tO\l'tlXl µ6110 jllX t!;w6ati; oua[ai; µa ~0t6µ6 t!;w6oui; 7tlX\IW IX7t0 200 XO't- 2 aa 23 °C XIXt jllX a-capaci. 2) :Enpaei; oua[ai; XIX'tlX 'tTj\l E\lotlX 'tOU 1tapt6. 2600(2) µrco­ pouv rnlaTji; \IIX OUOXWIXO'tOU\I: 0t) aa ~0tpeAt1X µE 0tq>0ttpouµi11TJ xtq>IXA~, auµqiw110t µa 1tapt6. 3523 1 t0t x611-cp0t-1tAIXXE ~ 3525 jtlX t11oa0tvl60t; a11 0t110t1 XTJ µa e110t ~ 1tEptaao-cipoui; 1tuxvoiiqi0taµi11oui; aaw-captxouc; adtx­ xoui;, ~: ~) OE IX\10EX'ttXOtl<; O'tO 11Ep0 OIXXXOU<; Otlfl(f>W\IIX fl• 'tilt 1tapt- . 0wpt1X 3533 jtlX ucpciaµ0t,IX, 3534 (yLIX 7tAIXO'tlXO ucp0taµ0t), 3535 YLIX 7tAIXO'ttXO q>UMO ~ 3536 yt0t IX\10ax,tx6 O'tO vapo x0tp,L TIX IX\IOLjfllX'tlX 'tW\I OUOXWIXOLW\I, ax-coi; IX7t0 'tti;jUOtAt\lEc; 0tµ1toUAE<; xdttv-coui; xuA[v6poui; • uno 1ttEOTJ, jtlX µn0tcpopci u-ypwv flE t!;w6Ei; XIX'tW IX7t0 200 xa,. 2 /S OE 23 ° 60t 1tpE1tEt \IIX µ1topou11 \IIX XA.i\lOU\I E'tClL wan \IIX IX7tOXAELO\l'tlXt 6t0tppoii;, µE Mo auaxEuii; -co1to6E'tT)flE\IE<; aE aEtpci, TJ µi0t 0t1t6 ,ti; onoiEi; 60t ~t6w,m ~ 60t 0tacp0tAi~E'tlXt XIX't!X IX\IIXAOjO ,p61to. :EuaxEu0talai; 1tEptixouaEc; 6tµE6uAo-0tµtvo-~opci11t0 -cou 12 ° (~) 60t 1tpE1tEl \IE EilllXl Ecpo6tlXOflE\IE<; flE E!;0tEpta,~p1X auµ- .. <f>W\IIX flE 'tO 7tEpt0wpto 3500(8). 3. MtX't • ClUOXEUIXOtlX: 1) OuaiEi; nou 1t un,011,0tt 0t1t6 ,011 i6to 0tpt6µ6 Ei6oui; 2606 • 2607 2607 2628 2609' 2610 2611 fl1tOpOU\I \IIX ClUOXWIXO'tOIJ\I fllX~U. OE au116u0tOflE\17J OUOXEUIXa[, OUfl(f>W\IIX flE 'tO 7tEpt0wpto 3538. . 2) Oua[Ei; 6t0tcpopmxw11 Et6w11 ,71,; KAcxaEwc; 6.1. OE 7tOOO­ 'tTJ'tE<; 7t0U 6E11 U1tEp~0tt\lOU\I, XIX'tOt ClUOXWIXOtlX; 'tOt -cpl0t Al'tp0t 1tpoxctµe11ou ytlX u-ypci XIXt/~ ~IX 5 XtAIX jllX a,Epaci, µnopouv \IIX OUClXWIX~O\l~IXt µix~u xg.t/~ µ. Efl7tOpEUflOt'tlX 7tOU 6Ev U7tO­ XEL\l'tlXL a,ti; 6t0t,dt!;Eti; 'tTJ<; ADR aE .qu116uixaµe11Ei; auaxEu0talEi; OUfl(f>W\IIX flE 'tO 7tEpt0. 3538, Ecp' 000\1 6E\I Ot\l'tt6poU\I EmXt\l 6u\llX µE-c0t!;u -cwv. 3) Ex-co,; 0t11 dtUwi; Et6txdt 1tpo~AE1tE,1Xt xix-cw-cipw, ouaiEi; ,TJi; KAciaEwi; 6.1 aE 1toa6,1j-ce:i; 1tou 6Ev u1tEp~0ti11ouv XIX'tcx 60 XElo 'tilt 3 AL'tpiX 1tpoxEtflE\IOU jllX-Ujpci XIXt/~ 'tilt 5 AL'tpiX 1tpo­ xatµe11ou jllX Cl'tEpEci, µ1topou11 \IIX OUOXWIX~O\l'tlXt µ0t~U OE OU\l 6u0taµi111j auaxw0tai auµcpw110t µE -co 1tEpt6. 3538, µE oua[Ei; ~ 0t11,txalµE110t dtUwv xAocaEwv, µE 'tTJII 1tpoii1t66EaTJ 1twi; Em,pi­ m-cixt ~ µtx,~ auaxw0talix XIXL jllX ,ti; oua[Ei; ~ Ei6TJ -cwv XAIX­ OEW\I OtU'tW\I, XIXL/~ flE Ef17tOpEUfllX'tlX 'tilt 07t0tlX 6E\I U7tOXEt\l'tlXt an,; 6t0t-coc!;Eti; 'tTj<; AD R, µE 'tT)\I 1tpoii1t66EaTj O'tt 6Ev 1X\l'tt 6pou11 E7ttXt\16U\10t flE'tlX!;u 'tWli. 4) Ot E1toµE11Ei; 6Ewpou11,0tt Emxi116u11Ei; 0t11,t6pdtaui;: IX) XIXUOTJ XIXt/~ IX\IOC60aTj OTJflCX\l'tLX~i; 0Epµ6,TJ't0<; ~) EXAUOTJ 0t110tq>AE!;iµw11 x0tt/~ ,t!;txwv 0tEplw11 r) oXTJflOt'tLOfLO<; 6t0t~pw-ctXW\I uypwv 6) oXTJfllX'tlaµoi; IXO'tlX0wv ouatwv. 5) H µtxtj auaxwixal0t o!;ewv ouatwv µE ~Otatxii; ouaiEi; aE µi0t auaxw0tal0t 6E11 60t Em,pem:a,Ott 0t11 ot Mo 0tu,ic; oua[Ei; Ei­ vixt OUOXWIXClflEIIE<; OE EU6p0tUO'tlX 6oxE[IX. 6) 0 1tpE1tEt IIEEq>Otpµo~O\l'tOtt XIXL \IIX 'tTJPOU\l'tOtt ot 6tlX'tCX!;Eti; 'tW\I 1tEpt6wplw11 2001(7), 2002(6) XIXt (7) XOtt 2602. 7) • Av XPTJOlfl07tOLOU\l'tlXt !;uAt\llX ~ t\lOOIX\IL6E\ILIX Xt~W'ttlX, xci0E xoAov 1tpE1tEt vix ~uyl~Et 7tAEO\I -cwv 100 xtAwv. Et6txo[ "Opot Ap. Ei6ou, • Il,pqpxq,11 "'l• ·ouoioc, Y6poxuocv,xo o~u 6oxdo XOAOY l" 30 IlEYTOCXocpovuA<O AEV EmTpEltETOC< 2" o,~pou xoc, n Tpocxocp~ouvuA<a Y<XEALOU Yllpoxuocv,xo o~u o• lluxMµµocToc Y1pot TOC~<YOfl-OU· fl-!YOC OTO (cc) xii8• ot!lou, 0,5 A<T. 1 A<Tp. EL!l,xi, AtocTdt~u, µ,x~ ouox,uaaioc A•v itpi.,m voc au­ ax,udt~ETOC< µ• oual•, 11 dllTJ T<uv IO.ota!Wv Ice, I~, 11, 5.2 11 7 4. M0tpxciptaµix XIXt mvixxl6Ei; xt11M11ou a,IX XOAIX. (BAi1tE Tipoacip,1jµ0t A. 9). 1) KoAIX 7tEpLEXOll'tlX ouaiEi; 'tW\I 1 ° ewi; 3 ° ~ ouai.i; ,IX!;t • \IOflOUfLE\IE(, O'tO (0t) ~ (~) IXMW\I Et6w11, 60t 1tpE1tEt \IIX cpipouv 7tt\llXXt61X auµcpwvix flE 'tO u1to6. No 6.1 'Av, ouaiEi; -cou 15 ° (~) Ei110tt auaxEu0taµe11.i; aE au116u0taµi~ 11Ei; auaxw0talEi; {0t1t6-1 u0tAi, 1topaEAIX\IT) ~ xEpixµEtxci) auµ­ cpw110t µE -co 1tEpt6. 3539, 1taptax,tX6'tTj,O<; -co 1t0Au 5).hpwv, 'tilt xoAIX 60t 1tpE1tEt 1tci11-cw11 110t cpipouv Mo m110txi6.i; auµcpwvix µE -co u1to6EtjµIX No 6.1. (~Aim 1tEpt6. 3901(2). • 2) KoAIX 7tEptEXO\l'tlX ouaiEc; ,0t!;t11oµouµE11Ei; O'tO (y) xci0E ai6oui; 60t 1tpi1tu \IIX cpepouv 7tt\llXXL61X auµcpwvix µ. 'tO U7t0 6ELjfllX No 6.IA. Oa-coao, ixv EL\IIXL auaxEu0taµi110t u1 pci aE au116u0taµevai; auaxw0taiEi; ( 1uOtAi, 1topaEACX\IT) xEp0tµEtxci) auµcpw110t µa 'tO 1tEpt6wpt0 3539, XWPTJ'tlXO'tTJ'tO(, 'tO 7tOAIJ 5 ).[,pwv, ,Ot xoAOt 1tpi1tEt vix cpipouv Mo m110txi6ai; auµcpw110t µ. co uno6Et1µix No 6.IA (~AE7tE 1tEpt6. 3901 (2). 3) KoAIX 1taptixo11,0t ouaiai; µa 07JµEio ixvixcp).i!;Ewc; xci-cw 'tW\I 5 5 °' 60t 1tpE1tEl E7tt7tAEO\I \IIX cpipouv 7tt\11XXi60t auµcpw110t flE 'tO U1to6EtjfllX No3, E\IW XOAIX 7tEptEXOll'tlX XAWpocpopµt0u­ xai; avwaati; 'tW\I 16 ° ~ 1 7 ° 60t 1tpE1tEl E7tt 7tAEO\I \IOt cpipouv 7tl\llXXi61X auµcpw110t µE 'tO u1t66. No 8. 4) KoAIX 7tEptEXO\l'tlX Eu0pixuani; OUOXEUOta[.i; 7t0U 6av 7t1Xt- • 11011,0tt 1X1t' i!;w, 0ix 1tpi1tEt VIX cpipouv aa 6uo ixv-ci0E,E<; 1tAwpii; 7tt\llXXi6ix auµcpw110t µa 'tO u1t66. 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LHMEIOLIL: Ka.p6La.xoi ~71µoc,06onc; • 1tEpLiXoll'tac; pa. 6Lavapydc; UAac;, O'tlX\I exouv xaLpoupyLxwi; aµcpu,au0ai o6a 1Xo8ava[c; Tj (,LE't:1Xq>Ep011't1Xl p1X6l0cp<Xpf11XXIX a\l'tO<; 'tW\I IX00a\lWII xoc,dt 't:T)II LIX,plXT)II ,wv 8apa.1taioc11, 6av 1J1toxEL\l't1XL O't'Tj\l ADR. • (2) OpLaµoi XIXl a1ta;rir~ow; A XIXt A2 «~( » OT)fLIXLllaL 't:T)V a.vw,dt,T) avip1aLIX aL6tx7Jc; µopcp7Jc; poc6ta­ vap1wv uAwv 7t0IJ am,pi1tn1Xt "(LIX XOAO\I Tu1tOU A. «A2» OT)· µa.ii/El. 'tT)\I Ol\lW't<X't'Tj avip)'EllX p0l6La11apywv UAWV, ltAT)II 'tW\I aL6Lx7Jc; µopcp71c; poc6Lavapywv uAwv, 1tou am,pi1ta,1XL 1La. xo­ Aciv T UltOU A. OL tLµic; aha IX7t1XpL0µou\l'tlXL O'tT) Ilpoo0i\XTJ A.6 mva.; XXI ai,a µ1topou11 VIX a;ocx0ouv auµcpwvoc µa 'tTJY OLoc6Lxa.oia. 't:T)V 1tapLypocq,oµiv7JY o,a. 1tapL8wpLoc 3690 XIXL 391 tT)c; Ilpoo871xT)c; A.6. Emtpa1t-rfoc; ocpL0µoc; XOAWV «E-imprn,foc; 1XpL0µoc; 1/xoAwv» OT)µIXiYal 'tO\I IX\IW'tlX'tO\I OlpL0µov XOAW\I ilLIXOltlXO'tT)<; KAdtoawi:; II 71 ilLIXOltlXO'tTj<; KAdt- • oawc; III ltOU µ1topou11 I/IX oµoc601tot7J8ouv oa E\IIX µipoc; ?!IX'tlX. , 'tT)II 6LdtpxaLocv 'tlj<; µa,a.cpopdtc; 71 OLocpxoiio7Jc; 'tlj<; 1X1to81jXE~­ oawc; xoc,dt 'tT)V 6Locµa,a.xoµLoLY (TRANSIT STORAGE). I/ 'O,ocv 1J oµcx6a. IXltO't:EAEL'tlXl IXltO XOAIX 0La.cpopw11 oX-€· 6iwv, 0 IX\IW'tlX'tO<; 1XpL0µoc; xoAwv 0oc aiYIXl 'tE'tOlO<; WO'tE \IIX txocvoitmaha.L o 1ta.pa.1tcxvw tu1toc;. N° + ~ + ~ + .... 6av 0oc u1tap~1XiYEl 'tT)\I I. A,o 'tUltO I 2 3 ocu,ov -roe v1, v2, 113, ...... aivocL ot ocpL0µoi ,wv xoAWII "(LIX ,IX 01toiix ot a.v,io,oLXOL am,pa1t,fot ocpt0µoi dvocL ,a. N 1, N2, N3, ....... IX\l'tlO'toix:wc;. LUO'tT)(,LIX LUO'tOATjc;: «LUO't:T)(,LIX LUO'tOATj<;» 071µa.iYal 'tlX OUO'tOl'tlXIX O'tOLxaia. 'tT)c; ouoxauocaia.c; 't:IX opt~oµava. UltO 't:OU axaotlXO'tOU XIXl itpoopt~O­ µavoc va. ouyxp0lt1joou11 ,TJY pa.6La11apyo UA1J 6ta.pxooo7Jc; 'tT)<; µatoccpopo:c; LXifao • «Lxi6LO» OTJ!llXL\laL 'tT)\I 1tapt"(p1Xq>Tj UAT)<; EL6tx7Jc; µopcp7J<;, 7J xoAou Tj ouoxeuocoiocc; ouyxaxpL(,LEIIOU ai6ouc;, T) 01toi1X 7t1Xpexat ,TJ 6uvoct6,7Jt1X ,7J<; 1tA71pouc; a.va.yvwptoawc; a.u,wv. H 1tept 1poccp71 µ1topai I/IX 7tEptAocµ~cx\lEt 1tpooOL1Xypa.cpic;, !lTJXIXYtXCX oxi6t1X, ax0fouc; 6wt11uouaac; 'tT) OU(,LfLOpcpwoT) 1tpo<; 'tOU<; XIX­ \10\ltO't:tXOUc; • (puElµto,txouc;) opouc;, XIXl AOLltO: oXE't:lXCX ir 1poccpoc. ilLoco1tocotic; 'Y)..ac; «ilLIXOltlXO'tTj 'YAT)» OT)f.llXiVEl ltAOU't:O\ltO - 238, 7tAOU'tOIILO 239, 1tAou-rovlO 241, oupdtvLo - 233, oupdtvlO 235 xa.L oAac; ot uAEc; 1tou itapLixouv moc6ii1tota ,wv poc6L01tUpT)vLxwv ocu,wv. MT)·IXX'tl\lO~OAO\I q>UOLXO\I XIXl a;a.a8a11T)µivov oupcxvlOV oav OIJ­ µmpLAIX(,L~IX\10\l'tlXl O't:0\1 opLoµov IXU'tO\I. Xa.µ:riA~c; - o,dt0µ:ric; o-rapaic; pa.6LaYEPJEic; uAac;. «XocµT)ATjt; - o,dt0µT)c; O'tEpEic; pOlOlEYaproc; UAT)» (LLS) OT)(,LOlivaL OLIXOTj7tO'tE ,wv xa.,w,ipw: (ix) L-rEpao: (1t,X- avo1tOLT)(,LE\IIX u1t0Aaiµoc,a., avapyaii:; u;\.ac;) O'tlX OltOiOl: (I) TJ avip1ua. xa.tcx 'tT)V ouv7J8TJ µE-roccpopcxv aiva.t xa.t 1tixpoc­ µi11aL xa.,ocvaµljµi11T) oa OAOXAT)po to o,apao 71 ,1J ouUoY7J onpawv Tj dVIXl XIXl lt1Xp1XfLEYEl oµmoµopcpa. XIX'tlXVE(,LT)fLEIIT) OE o,apao 0Uf17t1Xj'Tj CXj'Oll'tlX 01J116iaawc; ( 01twi:; oxupo6aµa., modt­ ocpocA -roe;, xapa.µLxov )· 1191 2674 2699 2700 1192 E<DHMEPII THI KYBEP~HIEQI (TEYXOI .dEYTEPO) • (II) 71 Eviprw~ EtVIXl XIXl 1t0tp0tµivEt 0t6tCXAU~7j OE 'tpimov pa 61evepyou UATJ<; cxv<i xolov 1tpoepxoµiv7J ex 'tWV em6p<iaEwv 'tOlJ Otveµou, ~PO,(TJ<;, XAlt., 71 XCXt IXltO OAlXTJ<; ~u0tatv a'tO vepo VIX 1tEptopi,e't0tt xoc'tw 'tWV 0.1. A2 ae XPOVlXTJ 1tepio60 µt0tc; e~6oµ<i60tc;· XIXt (III) 71 µfo71 evip1et0t o).oxl71pou 't7I<; pcx6tevep1ou UA7J<; 6ev u1tep~0tivet 2 X 10- 3 A/fpcxµµ. (~) Ei67j µ7J-pcx6tevep1oua7Jc; UATJ<; 'tCX 01toi0t µoluvov't0tt µE p0t6tEVEpjoV UAT)\I, umi 'tOV opov l'tt 71 pcx6tEVEp,oc; µoluva71 ei­ \llXl µopcp71i; µ7J 6uv0tµiv7J wxepwc; VIX 6tlXOltCXpEl XIXt O'tl 'tO µi­ aov EltlltEOOV µoAU\IOEW<; OE 1µ2 (iJ OE xwpo emcp0tvei0ti; EWV 0 xwpoi; ElVIXl X<X'tW 'tOU 1µ2 ) 6ev UltEp~IXLVEt 'tilt: 7 40KB9 /CM2 jllX 1toµ1toui; ~ XIXl i XIXl 'tOU<; ;(1Xµ7JATJ<; 'tO~txo't7J't0t<; 1toµ1touc; 0t 'touc; a7JµEtouµivouc; a'tov Ili110txa XIX 't7j<; Ilpoa871x7Jc; A.6- xat 't(l( 74KBC/CM2 1tlX <iMoui; 1t01,L1touc; ex. ·nee; Xaµ71).~c; Etotx~c; E11eprei0tc; (I) • «·nee; X0tµ71 ~c; Et6tx71c; Evep1eiac; (I)» (LSA) 07Jµaivet Otcx6711to'tE 'tWV X<X'tW0t: • (0t) ME't0tMeuµ0t't(l( oupcxviou 710opiou xat cpuatx<i TJ ;(T)µtXOC au1tuxvwµ0t't1X 'tW\I µe'tlXMWµ(X'tW\I O(U'tW\I" (~) M71-ax'ttvo~o).011 cpuatxov 71 e~0ta8e117Jµivo11 oup<ivtov 71 µ71-0tx'ttvo~6).oi; cpumxov 06ptov· (r) O!;eiow 'tou 'tpt'tiou aE uo0t'tw67J ot0tMµµ0t't1X, uito 'tov opov on .'to auµituxvwµ(X OE\I U1tep~0tivet 'tilt 0.37TBg/L. (6) ·nEc; O'tt<; OltOlE<; 71 evipjEt(X El\l(Xt oµot6µopcp0t XIX'tot\lE• µ71µi117J Xott ot OltOLE<; EIX\I eµetOU\l'tO O'tO\I XCX'tW'tot'tO OjXO otU· 'tWV uito au11871xcxi; 1tpocp0tvwc; 0t\l'ttµe'twm,oµiv0ti; xot't<X 't7IV µe't0tcpop<i, 61twc; 6t<XAU07I O'tO u6wp )(Ott µE'tEltEt'tot EltlX\l(XXpu­ O't<XMWOTj" XIX't1XXpT)µVt07j (xcxel,7Jµ(X)· )((Xt)Oti;· otltO~E07j (ex'tpt~71)· XA1t., 80t Eix0tv· µfo71 et6tx71v Evip1Et0t11 oxt µey0t­ Au'tip0tv 'tWV 10·4 A/G (1p0tµµ.)· (e) Ei67J µ71-p0t6tevepyou u)..71.; 'tilt 01toi0t µ0Mvov't0tt µe p0t 6tEvep1o UAYjV, UltO 'tO\I opov O'tt 7j µ71•x(X80ptoµiv71 µoAU\107j e1ttcp(X11ei0tc; oev 1J1tEp~(Xt\lEt OEX(X cpopic; 'tt<; 'ttµii; 'tOU Iliv0txoc; XIX 't!)i Ilp,00871x71c; A.6 XIXt O'tt 'tO µoAuv0iv ei6oc; TJ 71 eit' IXU'tOU µ0Auva71, ·eocv eµEtOU'tO O'tO\I X(X'tW'tlX'tO OjXO otU'tTJ<; lJltO OU\10TjX(X<; 1tt8(XVW<; (XV'ttµE'tW1tt,OµE110t<; XIX't<X 't'Yj\l µe't0tcpopcx, OltW<; 6tocAU01j O'tO u6wp XIXL µe-t:EltEl'tlXL Elt(X\11XXpUa't<XMW07j. xot't<iµvta71 (x0t8i,TJµ0t)· X(XUO'Yj' (X1to~ea71 (Expt~71)· XAlt. 0<i EL;(E µforiv u6tx71v EVEpjELIX\I O;(l µe,OtAU'tEP'YJ 'tW\I 10-4 A/G (jp0tµµ.). ·nee; xcxµ71).~i; EtOtx~c; mpJEiai; (II) ,,nei; ;(IXµTjA'fj<; Et6txijc; e11ep,ei0tc; (II)» 07Jµ(Xt\1Et Otov6iJ­ ltO'tE 'tWV )((X'tW'tEpW: ((X) ·nei; O'tt<; OltOLE<; 7j evipyetlX )((X'tOC 't71V auv7187j µE't(XcpO­ pdcv ELVIXl XIXL 1t0tp(Xµevet oµotoµopcp(X )(IX'tlXVEµT)µEv7J )((Xt O'tt<; 01toiec; 7l µfo7J et6tx71 evip1EtlX oev u1tep~0tivet ;t(X 10-4 A/G (yp0tµµ.)· (~) Ei67j (l1j-p(X0tmp-you UA1j<; ltOU (lOAU\10\l'tCXt (LE pcx6te­ vep-yov UATJV, UltO 'tO\I opov 0-tt 1J p0t6tevep,oc; µoAuvatc; El\llXt µopcp71c; (lTJ wxepwc; 6uv0tµiv1c; \l(X 6t(Xalt0tpei XIXL O'tl 'tO EltlltE 00\1 µforic; µoAuvaewc; OE I µ ( TJ OE xwpov emcp0t11E[(Xc; E<X\I 0 xwpoc; IXU'tO<; EL\l(Xt XOC'tW 'tOU I µ 2) 6ev U1tep~0tt\1El 't(X: 3 7KBg/CM2 "(lilt 1toµ1touc; ~ )(Ott I X(Xt x0tµ1jATJ<; 'tO!;tXO't7l'tO<; 1toµ1touc; IX (XIIIX<pepoµivouc; O'tO\I mv(XXIX XIX 't7j<; Ilpoa871xric; A.6- )((Xt 37KBg/CM2 jl(X O:Moui; 1toµ1tovc; IX, Avw'tOC't lttEatc; x0tvo11tx • c; AEt'tOU tilt<; «AVW't<X't7j 1t[eati; XIX\IOVlXTJ<; Et'tOupyicxi;» a7Jµ0tt\1El 't'Tj\l Ot\lW't<X'tTJ 1tieatv dcvw 't'Yj<; 0t'tµoacp(Xtptx71i; mfoewc; ae µfoov E1tl1te6011 0otAOC001j<; 1j OltOLIX e(X µ1topouae \l(X IX\l(Xlt'tUx0e( O'tO OUO't7lµot OUO'tOATJ<; OE xpovtx71 1tepio6011 E\10<; E'tOlJ<; umi OU\I• 871xec; 0epµoxpcxal(Xc; XIXl 7JAllXXTJ<; (X)('tl\lO~OAtlX<; IX\l'ttO'totxou­ aec; <me; 1tept~illov'ttxic; auv0ijxec; µe't(Xcpop<ic; EMei4'et e!;0te­ ptoµou, E~W'tEplXTJ<; 4't1~EW<; 6t' ElttXOUptXOU OlJO't7Jµ(X'tO<;, TJ µox AW\I Amoup-yi0ti; )(IX't(X 't'Tjll 6ta:pXEt(X 't7l<; µe't0tcpopdcc;. rioAUltAWpoc; 'Erxpta71. «IloluitAwpoc; i 1xpta71» a71µ(Xt11et i 1xpta1j 't'YJ<; cxpµootcxi; 0tpx71c; 't7l<; xwpcxc; 1tpOEAEt>OEW<; )((Xt 't71<; (Xpµo6tcx.:; 0tpx71c; xix0e xwp(Xc; O't'Yj\l Eltlcp0t11Et(l( 't7l<; OltOL(X<; 1tpoxmat VIX 6tE!;ax0ei 1j IXltOO'tOATJ, • Kolov «KoAO\I Tuitou A» a71µ0tiVEl OUOXEU(XOLIX Tt11tOU A µe 'tO ltE­ ptwptoµivo p0t6tevep-yo ltEptexoµEvo 'tOU. E1tEt07J 'tO ltEptEXO· µevo Ello<; XOAOU Tuitou A ltEptopi,E't(l(l OE A 1 TJ A 2, E\10( 'tE'tOto XOAO\I 6ev xpet<X,E't(Xt 't'Yj\l i-yxptOl\l 't'Tj<; (Xpµo6t0tc; 0tp;(71c; . «KoAO\I Tuitou BU)» a71µ0tL\IEl OUOXEU(XOL(X Tt11tOU B, µ0tl;i (LE 'tO pcxOLEVEp"(O ltEplEXO(lE\10 'tOU, 'tO OltOLO\I Ecp' 000\1 sxet O;(E6tota0E[ auµcpw110t µe X(X0optaµivo axi6LO XIXl 't(l( XpL'tT)pl(X aua'tOATJ<; otlt(XLtEi e'tepo1tAeupo11 (µ01101tAwpo11) i1xptatv (LO· \10\1 'tOU O;(E6[ou tOU XOAOU XIXl OLWV6TJ1tOtE opwv O'tOl~otat(X<; ltOU ev6ixe-cm VIX El\lCXL (X1t0tpotl't7j'tOt "(lilt Otixxua71 't'Yj<; 0ep(l0· 't7jtoc;. . «KOAO\I Tuitou B(M),, 07Jµ0tiVEl OUOXEUCXOtlX Tu1tou B, µ0t'i flE 'tO piXOtEIIEp"(O ltEptexoµevo 'tOU, ecp' 000\1 to axEBto 'tOU Bev ltA7jpOi E\l(X TJ 1tEptaao'tEp0t et6tx<i auµ1tA71pwµottt)((X axe6ta:­ aewc; 1tcx xoAOt Tuitou BU) ~Aiite 1tept8wpto 3605 't71<; Ilpo 0871x71c; A.6) CXltlXt'tEl ltOAUltAWpov i-yxpta71 tOU axe6iou 'tOU xoAou XOtt, u1t6 wptaµivcxc; auv0iJxec;, 'tWV opwv 1tpow871 oEw::;. Luaxw0tai(X «Luaxeu0tai0t» 01jµcxivet 't7I auvcxpµoM17101j aua'tlX'ttxwv µepwv IX1tCXp1XttT)'tW\I VIX E~Mcp(XAtCJOU\I 't'Yj OU(lµopcpWa'Yj 1tpoc; 'tOU<; opouc; CJUOXEUIXCJLIX<; 't7j<; 1t(Xpouacxc; KA<iaewc;. M1topei, Et" 6tXO'tEpcx, \IIX IXltO'tEAEttott (Xlt() ·ev(X 71 7tEptaCJO'tEp1X ·6oxEi(X, 1X1tOppo<p71ttic6 UAtXO, xwpiaµ(Xtot, 1tpootcxai0t (0wpdcxtati;) XIXtOC t7jc; IXXtt\lO~OAicxc;, XIXl .fl1JX1XVtaµouc; 4'u!;ewc;, "(lot t7j\l ot1toppocp71071 fl7j;((X\ILXW\I xpOUCJEW\I (aox) XIXtjtot 0EpfltXTJ µo . vwa71. Ot fl'Yj;(IXVtaµoi cxutol 1tEptAotµ~<i11ouv to 0;(1jµ0t µE to auat71µcx atepewaEwc; ((XXl\17jt07tOLTJOEW<;) (TIE-DOWN SYSTEM) 6t0tv 1tpoopi,ov't1Xt vcx 0t1to-ce).foouv 0t\11X1toa1t0toto11 'tflTJµOt t71c; auaxeuOtCJicxc;. «LuoxEu0tai0t T u1tou A» a71µ0ti11et auaxEu0tai0t 71 01toi0t x0ttcit t'Yj auviJ0ri µet0tcpop<i EL\IIXL tXIX\IT) VIX eµ1tooioet OLot\lOTjltO'tE otltWAEtCX\I TJ OtlX01tOp<i11 tOU p0t6tevEp-you 1tEptexoµivou XIXl au­ yxpiX'tTJOEL t'Yj\l 1tpoatottEUtlXTJ 'tOU AEttoup-yi0t. Ot opot t'Yj<; x0tvovtx71c; flE't0tcpop<ic; 00t 0t\lot'tU1tot111't0tt ~<iaEL 'tWV e).i-yxwv tWV 1tpO~AE1tOµEYW\I UltO tOU 7tEpt0wp[ou 3635 XIXl 3636 't7j<; Ilpoo871x71c; A.6, touc;.01toiouc; e)..i-yxouc; 1J auaxw0tai0t 80t etxov[,Et ott 6te~71)..8e. «Luaxw0tai0t Tuitou B» ariµ0tivet auaxEu0tai0t 1j 01toi0t ei110tt lXIXIITJ \ICX Ot\10E!;Et O;(t µovov CJ'tOU<; opouc; 't7j<; XIX\10\llXTJ<; µet0t­ (j)Op<X<;, OltW<; 7j OUOXEUIXOLIX 'ttlltOU A, woe XIXl CJE IX'tt1X7J(J-IX µE't0tcpop<ic;. Ot opot ( auv071xec;) evoc; tE'tOlOU IX'tUXTjfllX'tO<; 80t 0tV0ttu1touV't0tt ~<iaet twv eU-yxwv twv 1tpo~AE1toµivwv u1t6 'tW\l 1tEpt8wpiw11 3635 iwc; 3637 t71i; Ilpoa871x71c; A.6, wuc; 01toiouc; EAi -yxouc; 71 auaxw0tai0t, 0cx etxovi,etcxt O'tt 6te!;iJ).0e u116 tote; oµoiwc; 11po~AE1toµiv0ti; aw871x0tc; ( opouc;). E11i11aoov AxttVO~OALIX<; «E1tbte6ov Ax'ttvo~o).i0tc;» a71µcxi11et t71v 0tv,iawtxov taoou­ v0tµov 11poc; pcx6tevep16v Mari 'ttµT) excpp0t,oµiv71v eti; MILLI­ REM wpt0tiwc;. T0t rni1te60t IXXttvo~o).[cxc; µ1topouv 110t x0t80- • pi,oV'tOtt 6t' op-yocvwv, oe au116u0taµ6 µe 'tTJ XPTJOTJ 1tt11citxw11 µe­ 't1Xtpo1t71c; oa<ixt~ 0t1t0tttd'tcxt 71 µe u1tolo1taµ611. Metp1jµiw; 71 uitoAo1to0eiaec; 1ruxv6't1j'tE<; po71c; ouoetepoviou µ1topouv va µetatpiitovtott ae e1ti1te00t 0tX'ttvo~o)..i0ti; µe 't7j XPTJ011 tw11 awtxeiwv twv 6tooµivwv CJ'tO\I mxpotXOt'tW 1ti11ax0t. Iluxv6t1jtE<; po71c; ou6enpoviou 8ewpot1(lEIIE<; we; tao6uv0tµec; 1tpoc; rni1te60 0txtt110~0Ai0tc; 'tWV 10 USv/wp. (1 MREM/H) (wpt0tiwc;) Evip1et0t ou6e'tepoviou 0epµtx71 (THERMAL) 5 KEV 20 KEV 100 KEV 500 KEV 1 MEV 5 MEV 10 MEV Ilux116t7j't1X po71c; taoouv0tµ71 1tpoc; 10 Uv /h I MREM/H (N/CM2 • S). 268 228 112 32 12 7.2 7.2 6.8 Lriµeiw01j: lao6u110tµei; 1tuXVO't1j'tE<; po71c; "(Lilt evip1mc; µe­ t0t!;u 'tWV 0tvwtipw 0tvcxcpepoµivw11 0cx lcxµ~dtvovt0tt 6t0t 1pcxµ­ µtxTjc; mxpeµ~o).71.;. <l>EK 104 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 1193 Pot61.v.p10 1t.p1.xof.tE\lo «Poto1evepyo 1r.p1exof.tevo» CTrJf.totlvai ni pot61evenov uA:qv (.lot'i f.tE 07tOtot61)7tO'tE f.tOAUV0e.v'tot aupeii, Ujp!X TJ ote.ptot 'tO\J XOAO\J. Pot61mp1oc; uA.TJ .161x11c; f.topcpTJ<; «Pot6tE11Ep,o<; UATJ e18tx11c; f.tOpcpT)<;» O'lj(.lotL\IEI Et'tE J.t'lj 6uvot(.lEVTJ \lot 6tota7totpe.l aupe.ii pot61evep,o<; UA 'lj Et'tE acppot"'(l 0(.lEll'lj xiitj,ouA.ot 1tEp1e.xouaot pot61evep1ov u).. TJV. H acppot1t­ Of.tEVTJ xiitj,ouA.ot 0ot Et\lotl hat Xot'totOXE\JotO(.lEll'lj wan \lot f.t7t0 pei vot otvotx0.l f.tovov f.tE niv Xot'tota'tpocp1111 otU'tT)<;, H pot6te­ vep1oi; UA'lj u8tx11c; f.tOpcpTJi; 0ot 7tA 'ljpoi 'tO\J<; XIX'tW0t opoui;: (ot) Sot e.x.1 'touAcxx1a'tov f.tiot 01iia'totaTJ ox1 xii'tw 'twv s XIA,. Xott (f3) 0ot 7tA'ljpol 'tO\J<; axmxoui; opoui; EAEjXO\J 'tO\J<; opt~O­ f.lE\10\Ji; u1to 'tWV 1tep18wpiwv 3640 e.wc; 3642 nii; Ilpoa811 XTJ<; A.6. r E\llxwi;, 'lj E\l\lotot «Et6txiJi; f.tOpcpiJ·i;» 1totpe.xe1 't'I) 6uvot't0 't'T)'tot a'tti; UAE<; 1tou 1totpoua1ii,ouv utj,TJA.o'tepov E1ti1tE6011 Evap 1eioti; \lot O\Jf.t7tEplAotf.tf3iivov'totl ae XOAO\I Tu1tou A. E18tx11 ave.p1atot H «El0lX7J EVEpjEtot» potOI07tUp'1)11tXOU 0'1)(.lott\lEt 't'T)\I evap­ jELot\l pot0107tUp'lj111XOU ot\lCX µii,otv µoviiooi;. H EIOIX7J EVEpjElot UA'lji; O'tTJII 01toiot 't0t p0t61om,p'1)VIXCX axow f3ota1xwi; Of.tOIOf.tOp­ cpwi; X0t'tot\1Ef.t'lj0Ei Et\lotl '1) eve.pre1ot nii; UA'lj<; ot\J'tT)i; ot\llX f.tCX'ot µovcxooi;. lldx'ti)i; Me'tcxcpopcxc; 0 «OEtX't'l)i; f.tE'totcpopcxi;» E\10<; XOAO\J 0'1)(.lotL\IEL: ( 0t) Tov otpt0µov O 01toioi; axcppcx~Et -co rni1te6011 -C7Ji; ot\lW'tCX­ 't'l)i; otx't111of30A.ioti; aa MILLIREM wptotiwc; ae 1 µ. ex nii; e~w-ce.p1x71i; EmcpotvEioti; -cou xoA.ou· 71 • (f3) 1tpoxELf.tEVOu 1tEpl xoA.wv -c'lji; ll1ota1t0ta'tT)i; KA.iiaewi; II 71 610ta1tota-c11i; KA.iiaaw<; III, -cov otvwupov 'tWV itotpotxii-cw otpl0J.tWV: 0 0tpt8(.loi; 0 01toioi; Excppii,.1 -co E7ttltE6ov 't'lji; ot\lW'tlX't'l)i; otx-c111of30A.ioti;, wi; uito a-cotx dov (ot) Ot\lW-cipw, x.cx1 o otpt0J.to<; o Aotµf30t11oµE11oi; 61ot 61ot1pfoe.wi; 'tO\J 50 µe -COIi E1tt'tpE1toµevo11 otpt0(.lOII 'tOIOU'tW\I XOAW\I. . 0 «OEtX't'lj<; f.tE'tOLcpopcxi;» 6ox.iou CTrj(.l0tt\lEl Et'tE: 'tO cx0pota(.lot 'tW\I OEIX'tW\I µnotcpopcxi; OAW\I 'tW\I XOAW\I e.11-coi; 'tOU ooxdou, ltA'lj\l 'tW\I ooxdwv 'tW\I f.tE'totcpEpOV'tW\I XOAot tucxaitotO'tTj<; KA.cxae.w~ III, 0 6e.ix-c11i; f.tE-Cotcpopcx<; 80t Et\10tl 50 ex-coi; ECX\I 'to cx6pota(.l<X 'tW\I OEIX'tW\I µa-c0tcpopcx<; 'tW\I xo­ AW\I 0t110trx0t10l utj,'l)A.o'te.pov 0tpt6(.loll. EL'tE rux 6ox e.i0t f.t"l µe.-c0tcpapo11-c0t XOA(X 'tW\I ll10ta1t0ta-cw11 KA.cxaEW\I II 7J III )((XL U7t0 ltA 7JPE<; cpop'tiov, 0 0tpt8(.loi; 0 Oitoio<; Excppii~Et -co rnlitEOov otvw-ccx-c'lji; 0tx-c111of30A.l0ti; Eti; mSv /h E7tt 100 TJ aE mrem/h ae. 1 f.t· EX 't'l)i; E~w-cEptx7Ji; amcp0t11Ei0ti; -cou Boxaiou 7tOAA<XltA<Xal0t,Of.tE110i; E7tt -CTJi; 'tt(.l71i; 'tOU 7t<Xpcxxcx-cw 1ti110txoi; ,;'l)i; x0t-cill71A.ou .Ot<X -CTJII <XIIW'tCX't'l)II amcp<i:11e.10t11 arxcxpalcxi; 'toµ71i; 'tOU BoxEiou. LU\l'tEAe.a-cac; Tioll0t1tA0ta10taµou Me.1e.0oi; cpop-ciou MhpTJOTJ (µE-cp11oe.t<;; e.mcp0tvEi0t<; e.rxcxpaioti; coµT}<;; -cou cpop-ciou xcx0i-cwi; itpo<; 't'l)V e.11610tcpEpop.i11'1)v xor.-cEu6uvo1v) 1 µ 2 xor.1 xii-cw > 1 µ2 ewi; 5 µ2 ) 5 µ2 awe; 20 µ2 )20 µ2 iwi; 100 µ2 L\J\l'tEAEO'tTJi; TI0Mot1tA0ta1or.of.tOU 1 3 6 19 (r) 0 otp18µ6i; 0 01toloc; EXcppii,Et -co OELX'tTJV (.lE't0tcpopcx<;; 801. o'tpOjjUAEUE'tOI.I 1tpoi; -cot CX\IW f.tEXPL 'tO\J itpw-rou 6ax0t61xou tj,Tjcplou. MTj-ltE1ttEoµivo11 otiptov «M7J-ltE1ttEaµivo11 or.iptov» 07Jµ0tivu 0te.p1ov ae. 1tiaa71 µ'lj u1te.pf3or.ivouoot ,71v Ot-Cf.tOOcp0ttptx71 ltLECTrJ -cou 1tap1f3illov-coi; O'tot\l -co aua-c'l}µot auo-coA71i; EL\101.l XAEIO'tO. • EupoitAEUpo<; ((.lOV07tAEUpoc;) erxp1a1i; «E-capo1tAeupoi; (f.tO\IOltAEUpoi;) erxptati;» a11µ0tl11e.1 't'Tj\l e.rxptat\l -CTJ<; 0tpµo610ti; <XPXTJ<; -CTJ<; xwp0t<; itpoaA.auaawi; X<XI f.tOVO\I. Ecxv "l xwp<X itpoeA.e.uaewi; OEV Et\lOtl auµf3}:q0av f.tEpoi; TJJ<; AD R, TJ e.rxp1a1i; 0cx otitotml emxupwa1v -cric; 0tpf.to61oti; otpx71i; 'tTJ<; itpwnii; xwpoti; AD R Et<; 'tTj\l 07t0Lot\l 0cx cp0iiaat TJ ot1toa-coA.71. M'1)-0tX'tl\lOf30AO\I oupcxvtov «M '1)-otx-c1vof30J..011 oupcxvwv» CTr)µotlve.t oupcxv1ov 1te.p1axov ox1 cxvw -cwv 1 o-6 G ('ypcxµf.t.) 1tA.ou-coviou otvcx G ( rpcxf.tf.t·) ou­ potviou-235 Xotl E\IEpjEl<X\I itpoi'.ov-coc; Ol<XOltlXOEW<; 0)(,1 µe.,0t­ AU'tEp0tv 'tW\I 0.25 MCI Ot\lCX G (rp<Xf.tf.t·) oupcxviou-235. Mri (Xl('tl\lOf30AO\I 0optov «MTJ-<XX'ttVOf30AO\I 0optov» OTJf.t<XL\IEI 0optov itaptE)(,011 oxt <i:vw 'tW\I 10-1 G (rp0tµµ.) oupcxvlou-233 ot\llX G (rpotµµ.) 0o piou-232. .. • Oupcxvtov· E~0ta6av11µavov, .µitAO\J'ttaµavov, cpua1xov «<l>ua1xov oupiiv1ov» a11µ0tlvai X'IJ\J.IXWi;-610txwptaf.tEVO\I ou­ pcxv1011 f.tE 'tTJ cpua1xwi; - 7tp0X\17t't0U(J(X X0t't<XV0µ71v 'tW\I tao-co 7tW\I oupcxviou {1tapi1tou 99.28 -cote; axcx-cov oup<Xviou-238 x<Xt 0. 72 -cot<; EX<X'tov oupotviou-235). «E~0ta8aVTjµe.vov oupcxv1ov» a'1)µ0tiva1 oupiiv1ov 1tap1axov XCX'tW 'tW\I 0. 72 -cot<; EXot'tO\I ou­ por.viou-235, -cou u1toA.ol1tou oV'toi; oupcxviou-238. «Eµ1tA.ou-c1 aµivov oup<i:vtov» ariµor.lva1 oup <i:v1ov 1tep1ixov iivw -cwv 0. 72 co1i; axor.-cov oupcxviou-235, -cou u1toA.oi1to u 011-coi; oupcxviou 238. Le. OAE<; -cti; 7tEpm-cwaEti; uitcxpxu f.tL0t ltOAU µ1xp11 ltoao­ CTJ'tOI. oupcxviou-234. (3) Aitor.ropEUaati; mi fllX'tT)i; cpop-cwae.wc; • nei; 't'l)i; KA.cxaEW<; 7 itEpLEXOf.tEVEi; OE XOA0t cpipov-ccx m­ XE't0t auµcpWV'lj itpoi; 't0t fLO\l'tEA0t 7 A, 7B 71 7f OE 0cx cpop-cwvo­ \l't0tl a-co 0t\J't0 ox11µcx µcx,l flE uJ..e.i; X0tl ELO'I) 't'I)<; KA.iiaEW<; 1 or. ( 7tEpt0wpto 2101 ), 1 f3 ( 7tEpt0WpLO 2131) TJ 1 "( ( 7tEpt6wpt0 21 71) 1tEp1ExoµE110t OE XOA0t cpipov-ccx µlor.v TJ Mo mxau<; auµ­ cpwve.<; itpoi; 'to f.tOV'tEAO No 1. 01 UAE<; XOtl Ei8Tj -CTJ<; 7totpoua'1)<; KA.cxae.w<; 1te.p1axow E\10t 71 2701 7tEptaao-ce.pot 'tW\I p0tfit01tUpTJVIXW\I 'tW\I Ol.\10tCj)Epoµe.vW\I O'tO XE Cj)CXA0tl0\I VI -crii; Ilpoa871x11c; A.6 {1tEp18wp10t 3690 X0tt 3691). 0 xcx-cw-cipw xcx-ciiA.ojoi; xor.0opi,Et -coui; 6tcxcpopoui; -cu1toui; • 2 7 02 0tltOO'tOAT)i;: 1. Ke.vex XOA0t 7t0\J 7tEptEixixv p0tOIEVEPrEii; UAe.i;· 2. Ei67J xcx-ccxaxe.ucxaµivcx 0t1t6 cpuatxov TJ e.~cxa6Ev1jµivov ou-. pcxviov 7J cpua1xov 8opt0v· 3. Mtxpe.<; ltOOO'tTJ'tEi; por.6tEVEPrWV UAwv· 4. ·opj0tV0t X0tt f310µ'1)X0tVOltOl1j6iv-cor. e.1611· 5. ·ne.i; X0tfl'1)A.'l'Ji; Et61xrii; Eve.p,e.lor.c; LSA (I) 6. ·ne.i; xor.µ'l)ATJi; E161x11i; mp1e.ior.i; LSA (II) 7. X0t(.lTjA71<;; a-c<i:6µTji; ( e.miti6ou) a-cEpe.ic; p0t61Eve.p1e.l<;; UA.Ei;· 8. Por.61e.ve.pjai<;; UAE<;; OE XOA0t Tu1tou A· • 9. Pcx61e.vEp1El<;; uAu; aE xoA.cx Tuitou B(U)·· 10. P0t6m1EpjEii; UAe.i; OE XOAOI. Tuito\J B(M)· 11. ll1or.a1t0tO'tE<;; UAEi;· 12. Por.oie.vEpjEi<; UAe.i; µe.-cor.cpe.poµEve.c; UltO e.161x11v 6tau0ani­ OIV. KEVCX XOAot: ltOU icEptEixocv potOLE­ VEpjEii; UAE<;. 2. Luaxeuoco[or. / KoAO\I (ot) H OUOXE\Jotolot 6ot EL\101.1 ouµ­ cpwll'lj µe. -coui; opoui; 'tOU 7tEpt0w­ piou 3600 -crii; Ilpoo071x11c; A.6, Xott 6oc XAELVE'tott ococpotAwi; Xott aE XOI.A.71 Xot'tCXO'tOCOTJ, (f3) Em-cpE1toµEvor. e.1ti1tE6ot e.aw-cE­ p1xrii; µoAU\IOEwi;: ox1 7tEptooo-cE­ pov or.ito 100 cpopic; ,ot rniite.6oc 'tot otV0tjp0tcpof.tE\lot O't'lj itotpcxjpotcpo 5. (r) OO(XXti; XE\17] ouoxwcxoiot 1tEpt­ ).ocµf3cxn1 cpuotXO\I 7J E~oto0EVTjµi­ \lO\I oupiivtov iJ cpuotx<iv 86p1011 O'tTJ XOl.'tOI.OXEU71 't'lji;, TJ E7tt<:pCXVEllX Ilivocxoci; 1 E'ttXE'tE<; Xt\lOU\10\J E1ti 'tW\I XOAW\I Ouoe.µioc L'ljµe.[wo71: 01oc6711ton E'ttxhor. OT)µE1ouoot XiVOU\10\1 801. EL\lotl Xot­ AuµµEVTJ iJ 0oc occpor.1 pai-ci1. 2703 1194 cwHMt:Pl.i. 1 Hi. kYBt:PNHLH,!L (It: VXOI: aEYTEPO) 't1)<; 0ot XotAU1t't!'t1Xt ot1to ouatota'tL­ x71v, µ7J-EVEpyov 1tpoa'totOLotV 0t1t0 µi'tixllo 71 ot1to xii1tow iillo otv0e­ X'tLXO UAtXO. 3. Avw'tot'tOV E1tt1te6ov otX'tlVO· ~OAtot<; XOAOU 0,5 mrem/h (wptottw<;) a't1)V em­ cpiivuot 'tOU xo)..ou. 4. MtX'tT} auaxeuotalot Ouoeµiot 6tii'tot!;71. 5. M0Auv01J e1tl xoAwv • M71 - wptaµivot oplot e!;w'tep tx71.; µoAuvaew.;: ~/ 'Y / X,otµ71A7I<; - 'tO!;LXOTTj'tot<; ot, 1toµ1to[ <I>uatxov / e1;ota0ev71µivov oupiivtov / cpuatxov 8opt0v Allot ot 1toµ1tol ftot 1tA 71pet<; AE1t'toµipite<;, ~AE1tE 1tEpt8wpto 3651 't'Jj<; Ilpo­ a871x7J<; A.6. 6. Ev6el!;et<; (µotpxiiptaµot) xo­ AWV ( ot) Tot xoAot 0ot µotpxiipoll'tott xot0otpii XotL otVe!;l't7JAot µe 'tO ~ii­ po<; eiiv 'tOU'tO elvotL iivw 'tWV 50 KG. (~) ITiiaot iv6et!;71 otvotcpipouaot pot 6tevepyov x[v6uvov 6ev 0ot dvotL opot'tT}, 7. 'Enpotq,ot (J-E'totcpopii.; To inpotq,o µnotq,opii<; 0ot 1tE­ pv..otµ~iivet 't1)V 1teptypotcp71v «Pot­ otevepyd.; UAE<; (Kevii XOAot), 7, 1tlvotxot<; 1, ADR», µe 't'JJV ovoµot­ alotv u1toypotµµtaµiv71. 8. A1to871xeu07J Xotl 1tpow871a71 Ou6eµlot OLIX'tot!;71. 9. Me'totcpopii xoAwv µe ox.71 µot'tot Xott OOX,Etot (CONTAINERS) Ou6eµlot OLIX'tot!;71. 10. M E'totcpopii ae x.uµot µe OX,7j(J-0t'tot Xotl OOX,ELot (CONTAI­ NERS l\ev EX,EL ecpotpµo'Y7lv. 12. Emypotq,i.; XotL mxhe.; e1tl ox.71µ.ii'tWV, ~V'tlOcpopwv TANK CONTAINERS xott oox elwv (CO­ NTAINERS). Ovoeµlot 13. A1totyopeuaeL<; E1tL (J-LX'tTj<; cpop'twaew<; Ouoeµlot 6tii'tot1;1J, 14. A1t0Auµotva11 OX,T)(J-IX'tWV, ~u'tt0cpopwv, TANK CONTAI­ NERS xott oox elwv (CONT AI­ NERS) Ouoeµlot otii'tot!;ri 15. • ille.; OLot'tii!;et<; Ovoeµlot. 1. ·ne.; 3, 7Bq/cm2 (10-4 MCijcm2 37Bq/cm2 10-3 ~g1/if~:m2 1 o-s MCijcm2 mvotxot<; 2 E'ttXE'tE<; Xtv6uvou ml 'tWV XOAWV Elori Xot'totaxeuota0iv'tot 0t1t0 Ouoeµlot q,uatxo T) e!;ota8ev71µivo ovpiivto 71 cpvatXO 0opto. H e!;wnptx71 emcpiivetot 'tOV ov­ potvlou 71 0op[ou 0ot XotAU7t'tE'tott ot1to ouatota'ttx71v, otvevepyov 1tpo­ a'totalotv (0wpiixtatv) ot1to µhillo 71 xii1toto illo otv0EX'ttXO UALXO. . L7Jµelwa71: Thotot el671 µ1topd 1t.x . VIX e[vlXt 0tx.pT)atµo1tol71'te<; au­ axeu1Xale.; 1tpoopt~oµeve.; yt1X 't1j µe't1Xcpopii p1XOtEVEpywv UAWV. 2. LUaXEUIXaLIX / KoAOV H auaXEUIXaLIX 80t ELVIXt auµq,w­ vw.; 1tpo~ 'tOU<; Opou<; 'tOU 1tEpt8w­ p[ou 3600 't7j<; Ilpoa871x71<; A.6. 3. E1tl1te6ov IXVW'tlX'tT)<; IXX'ttvo­ ~OAtot<; KoAou o.5 MREM/H ( wptotlw.;) a'tT)V emcpiivetlX 'tOU xo­ Aou. 4. Mtx'tT} auaxEulXatot Ovoeµlot 6tii't0tl;71. 5. Mo)..uva71 E1tt 'tWV XOAWY Mri-wptaµivlX optlX e!;wnpLXTj<; µoAuYaEw<;: ~/r X,1XµT)A7l<;-'to!;txo't1)'tO<; IX 1to­ µ1tol cpuatxov / e!;ota0evriµivov oupiivwv / cpuaLXOV 0opLOV • Allot ot 1toµ1tol ftlX 1tA71pet<; Aemoµipete<; ~AE1tE 1tept8wpto 3651 't7J<; Ilpo­ a871x71<; A.6. 6. Evoel!;et<; (M0tpxiiptaµ1X) rnl 'tWY XOAWY .Ouoeµlot. 7. 'Enpotq,ot µe'totcpopcx.; To inpotq,o (J-E'tlXCj>Opii<; 80t 1tE· ptAIX(J-~IXVEt 'tTjV 1tEptypotq,71 «Potote­ vepyei.; 'Yh.; (Bt0µT)X,otvo1tot718i­ V't0t / Kot't0taxev0ta8EV'tot £1671), 7, 1tlv0tx0t<; 2, ADR», µe 'tT)V ovoµ1X­ al0t u1toyp1Xµµtaµiv71. 8. A1to871xeua71 xotL 1tpow871a71 Ouoeµlot 6tcx't0t!;71. 9. Me'totcpopii xoAwv µe ox 71 (J.Ot't0t XIXL OOX,Etot (CONTAINERS) Ouoeµlot 6t0t'tot!;71. 10. Me'totcpopii EL<; x.uµot µe OX,7l(J-ot'tlX XIXL OOX,ELIX (CONTAI­ NERS) l\ev EX,EL eq,otpµoy71v. . 11. Me'totcpopii µe ~U'tt0cpopot xott TANK CONTAINERS. l\ev ix et eq,otpµoy71v. 12. Emyp1Xq,i.; xou E'tLXE'tE<; ml OX,7J(J.IX'tWV, ~U'tt0cpopwv, TANK CONTAINERS x1Xt 6ox elwv (CO­ NTAINERS) Ouoeµl1X. 13. Amiyopeuau.; E1tt (J.lX'tTj<; cpop'twaew<; • Ouoeµl1X 6Lii'tot!;71. 14. A1toAU(J-IXV07J OX,T)µIX'tWV, ~ti'tt0cpopwv, TANK CONTAI­ NERS xott oox dwv (CONT AI­ NERS) Ouoeµ[IX OLIX'tlX!;7J, 15. • ille.; OLot'tii!;et<; Ouoeµlot. 1. ·ne.; Mtxpi<; 1toa<i"t7Jn<; pototevepywv UAWV ae 7tOOOTTj'tE<; 7tOU oev u1tep­ ~1XtVOUY 'tOU<; otpt0µou<; 'tOU<; OLOO· µivou.; a'tOV Xot'tW'tEpw 1tLYIXXot XIXL Ot 07tOLE<; oev 7tEpL~X,OUY IXYW 10-4 MCI/CM2 10-3 MCI/CM2 10-5 MCI/CM2 mvlXXIX<; 3 E'ttXhE<; xtvMvou rn[ 'tWV XOAWV ' Ou6eµ[ot ( IXA.Ati ~AE7tE 1t1Xp<iyp1Xcpov 15 ). 'tW\I 15 G (rpaµµap[wv) oupa­ viou-235. <l>uou; UAW\/ L,apa<i xat <iapta Et6txric; µopcpTjc; 'Allwv µopcpwv Tpl,tov Ywii Ol;aioto T pt,[ou oa uoa,wo71 6ta­ Mµµa,a X<X'tW 'tW\I 3, 7 GBq/1 (0.1 CijL) µa,al;u 3, 7 GBq X<Xt 37GBq/l (0.1 C1 & 1.0 Ci) (X\IW 'tW\I 3,7 GBq/1 (l.O CijL) 'Alla u1pix fLa µirµa,a pa0Lo1tup71vtxwv, ~Aim 1tept8wpt0 3691 ,71c; TTpo 0811x71c; .A. 6. Ot ,tµic; 1 La ,o ,p[,to tax,uouv E7ttOT)<:; 1la ,pt'tto\l a11ap1ou (f'W'tEl· \IOU x.pwµa,oc; xat ,p['tLO\I a1top­ pocpouµavov a1t[ oupawv µa,acpo­ piwv. 2. :Euoxwaoia / KoAO\I (a) H ouoxwaoia 8a aivat ouµ­ cpwvwc; 1tpoc; 't0U<:; opouc; 't0U 7tEpl· 8wpiou 3600 'tTj<:; TTpoo8rix71c; A.6. (~) Ka,<i ,71 µa,acpop<iv oa 8a U7t<XPXEL 0Lappori pa6ta11aprou u)..71c;. • 3. Avw,a,011 a1ti1ta6ov ax,tvo­ ~oAiac; xoAou 5 µSv /h 0,71v amcp<ivELa ,ou xoAou (0,5 mrem/h) 4. MtX'tTJ ouoxwao[a Ou6aµ[a 0L<i,a/;71. 5. MoAUVOTJ (m[) 'tW\I X0AW\I M71-wptoµiva opta al;wuptxric; µoAuvoawc;: ~h I xaµTjATjc; - 'tO/;LX0'tTJ'tO<:; a 1toµ1to[: 3, 7 Bq/4µ~ cpuoLxov / a1;ao9a1171µivov oupii vwv / (f'UOLX0\I 9opwv: 37Bq/cm2 'Allm a 1toµ1to[: 0,37Bq/cin2 . fta 1tA1jpatc; Am,oµipmc;, ~AE7tE 1tapt8wpw 3651 'tTJ<:; TTpo 08rix1Jc; A.6. 6. Ev6a11;atc; (µapxapLoµa) a1t[ 'tW\I X0AWII H al;w,aptXT} amcp<ivata ,ou ou­ o,riµa,oc; ouo,OAT}c; 8a cpipaL ,71v a116aLl;t11 «PAMENEPfON» we; 1tpOEL001t0[7lOlll 1ta 't0 <XIIOL1µa 't0U X0AOU. 7. 'E11p1Xcp1X µa,acpopixc; To enp1Xcpo µa,acpop<ic; 81X 7tE­ ptAaµ~<X\IEt 'tT)\I 7tEPL1'Pacpri11 «Pa­ Otavaprdc; UAac; (Mtxpic; 7tOO0'tTJ· uc;), 7, 1t[v1XI; 3, ADR», µa 'tTJII 011oµao[a11 u1toyp1Xµµ·taµiv7111. 8. A1to8rixauo1j XaL 1tpow81jOTJ Ou6a!J-ia 6t<i,1Xl;TJ, 9. Ma,acpop<i X0AWII µa oxri­ µa,IX X<Xt ooxa[IX (CONTAINERS) Ou6aµ[a 6i1X,al;1j, 10. Mn1Xcpop<i EL<:; xuµa µa oxriµIX'tlX xat ooxa[IX (CONT AI­ NERS) 6.a11 am,pi1ta't1XL. 11. Ma,1Xcpop<i µa ~u,wcpop1X XIXt TANK CONTAINERS 6.av am,piita,at. 12. Emwacpic; xat mxhac; a1ti ox71µ<i,wv, ~U'ttocpopwv, TANK ECl>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: AEYTEPO) 1195 'OptlX X0AOU 10-3 Al 10-3 A2 0,74TBq (20 CF 37 TBq (1000 CI) 3.7 TBq (1000 Cl) 37 GBq (I CI) 10-4 A2 00-4 MCijCM2) 00-3 MCijCM2) (lo-s MCijCM2) CONTAINERS xaL 6oxetwv (CO­ NTAINERS). OuoaµilX. 13. A1ta1opauoatc; a1ti µtx,ric; cpop,c;,oawc; Ou6aµ11X 0L<i,a/;71. 14. A1toMµa11071 ox71µ<i,wv, ~U'tlOcpopwv, TANK CO NTAINERS xat 6oxa[wv (CONTAINERS) BAi1ta 1tapt8wpw 3695 (3) ,71c; TTpoo8rix11c; A.6. 15. 'iliac; Ot1X,<il;atc; (a) 6.ta,<il;atc; 1tapi a,uxTJµ&,wv - ~AE7ta 7tapt8wpLO 3695 (1) ,71c; TTpoo8rix71c; A.6. (~) A1t0Auµavo71 E\I a1to871xauoat - ~AE7tE 1tapt8wpLO 3695 (2) ,71c; TTpoo87jxT)c; A.6. (r) Pa6tavapraic; UAoc; 7t0U exouv iliac; amxt116u11ouc; L0L0 'tTj'tEI; 8a ouµµopcpouv,IXL ,1tio71c; µ, ,tc; OLIX,<il;,tc; ,7Jc; xa,IXA­ AljAOu x)..<ioawc;. TTi11ax1Xc; 4 E,txh,c; xL116u11ou a1ti ,wv x6Aw11. Ou6,µia. 1 .. ·nac; • Oprava xat Bt0µ7JX1X1107tOtTj9Ell'ta Ei6Yj 01twc;, wpoMrta ,oixou, TJAoX'tpovtxic; Auxviac; (Auxv[.c; 1Xoupµ<X'tOU) T} ou­ OXEUIXL, 7t0U exouv pa0Lollaprdc; UAoc; we; ouo,anxov µapoc; IXU­ 'tW\I, TJ ,vip1wx ,wv oitoiwv 6av u1t,p~a[v,t ,IX 1tooci 1tou 6i60 .11,at 0,011 1t1Xp1Xxii,w 1tivax1X XIXt m 01toiac; 6av 1tapLixou11 <ivw ,wv 15 G. (ypcxµµapiw11) oupaviou-235. <l>uotc; UAW\/ 'Opta Eloouc; • Opta KoAou :E,apa<i . Et6txric; µopcpric; 10-2Al Al Allw11 µopcpwv 10-2A2 . A2 Yrp<i l0-3A2 10-1A2 Aipt1X Tpi'ttO\I 0,74 TBq . .. ;.-.. '7,4 TB'* (20 Cl*) 200 c1° Et6txT}c; µopcpric; I0·3A 10-2A • Allwv µo·pcpwv 10-3~ 10-2A 1 2 fLCx µirµaw. pa0L01tUp7JlllXWII, ~AE7tE 7tEpL9WpLO 3691 'tTjc; Ilpoo9ri­ X1j<:; A.6 .• ,. Ot ,Lµic; 1llX 't0 ,p[,LO 81X loX,UOU\I xat 1llX ,pL'tlO .v.prou (f'W'tEl\10\1 x.pwµa,oc; xat ,pi,tov a1toppocpouµi;11ov ml o,apaw11 µa,1Xcpopiwv. 2. :Euoxauaoi1X/K0Aov (a) H ouoxauao[a 91X dvat ouµcpwvwc; 1tpoc; "tOuc; opouc; ,ou 1topt8w­ piou 3p00 'tlj<:; TTpoo9T}X1jc; A.6. . (~) Ta oprava xat a[OYJ 81X OUOXW<X~O\l'tlXl IXO(f'IXAWc;. 3. Avw,a,011 E7tL7toOO\I IXX'tl\lO~oAiac; ~0AOU 5 µSv /h (0.5 MREM/H) 0'tTJII ,mcp<iv,ta ,ou xo)..ou xat 100 µSv /h (10 MREM/H 71 10 CM a1to 01tmo6ri1tou 01jµaio a1t[ 'tlj<:; al;wuptx71c; amcp1X11ELIX<:; OLOU0Tj7tO'to µ71 ouoxau1Xoµa11ou opr<ivou Tj aioouc;. • 4. MtX'tTJ OUOXWIXOLIX • Ouo.µia 0l<X'tlX/;tc;. 5. Mo)..uvaLc; xo)..wv M71 wpLoµi11a optlX .l;w"toptxiJc; µoAuvoawi:;: • ~/r/xaµYJATJ<; ,ol;txo'tTJ,O~ IX 1toµ1toi: 37Bq/ax2 (10·3 µCi) <l>uotX0\I / ol;1Xo6a1111µa11011 oup<ivtO\I / (f'UOLX0\I 8opwv: 3 7Bq/ ax2 (10·3 µCi) • 'illm IX 1toµ1toi: 0,37Bq/ax2 (10·5 µCi) fLIX 1tAiJpatc; AElt'tOfJ-Epmc;, ~AE7tE 1tapt8wpw 3651 ,71i:; TTpoo87jXTJ<; A.6. 6. Evodl;ELc; (µapx<ipLOfJ-1X) mi 'tW\I X0AWII K<i8a opravov TJ ai6oi:; ( 7tATj\l p1X0lo-axnvo~oAW\I x.povoµhpwv TJ ou­ oxwwv) 91X cpipal 'tlj\l E\IOELl;Tj «PAMENEPfON». 7. 'E11p1Xcpa Ma,1Xcpop<ic; TO enpacpo11 (ia,1Xcpop<ic; 8a 1tapv.1Xµ~<i11at 'tT)\I 1tapl''fpacp1jll «Pa6ta11ap­ raic; UAac; ('Oprava) Tj (Btoµ11xa1101tOL1j8EV'ta ai611), 7, 1tiv1XI; 4, ADR», µa 'tlj\l ovoµ1Xoi1X11 u1torpaµµtoµav11. 8. A1to8iJxauo11 xat 1tpow811011 Ouoaµia 0L<X'tlX/;TJ, 9. Ma,acpopii X0AW\I µa oxiJµa,a xat ooxaicx (CONTAINERS) Ouoaµicx 0llX'tlX/;7]. • . 10. Ma,acpop<i ate; xuµcx µa ox71µcx,1X XIXl ooxaia (CONTAINERS) 6.av EXEL acpcxpµonv. 1196 E<DHMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) 11. Mnotcpopcx µE ~1mocpopot xott TANK CONTAINERS AEy EXEL Ecpotpµonv. 12. E1trypotcpE~ Xott E-ttxE'tE<; E7tt OX1J!LCX'tWV, ~U'ttocpopwv TANK CO­ NTAINERS ·xott 6oj:Eiwv (CONTAINERS) Ou6Eµtot. . 13. A1ta.yopEu0Et<; E1ti µtXTIJ<; cpop'twaEw<; Ou6Eµiot 6tcx'tot!;71. 14. A1toMµotv07J ox71µcx'tWV, ~U'ttocpopwv, TANK CONTAINERS 60 XELWV (CONTAINERS) • . ' Bl..i1tE 1tEpt8wpto 3695 (3) 't'1J<; Ilpo0871x71.;; A.6. 15. • AUE<; 6tot't<X!;Etc; (ot) Atot'tCX!;EL<; 7tEpi ot'tUX1J!LCX'tWV - ~M7tE 7tEpt0wpto 3695 (1) 't7j<; Ilpo0871x71<; A.6. (~) ~7tOAuµotV07j EV ot1to871xEUOEt - ~AE7tE 7tEpt0wpto 3695 (2) 't7j<; Ilpo0871x71.;; A.6. 1. 'UE~ ·nE<; xa.µ7JA7J<; Et61x71<; EvEpyEia..;; LSA (1), a.v71xouaE<; aE µ1cx 'twv 1ta.­ pa.xcx'tw oµcx6wv w<; opt,OV'tott 1tA71pw<; 0't0 7tEpt0wpto 2700 (2): (I) ME'totAAEuµot'tot oupotvtou 7l 0opiou 71 auµ1tUXVWi,,.ot'tot (Eocxcpto (otJ 'tOU optaµou ). (II) M71-otX'tLVO~OAOV cpuatxov 7l E!;ot08Ev71µivov oupcxvtov 7l µ71otX'tLVO­ ~OAOV cpuatxov 0optov (Eocxcptov (~) 'tOU optaµou). (III) O!;Ei6t0 'tOU 'tpt'tLOU OE U0ot'tW07j 6totAUµot'tot - auµ1tuxvwµot 10 Cl/I Xott XCX'tW, ( EOCXcpto ( r) 'tOU optaµou ). (IV) 'UE<; µE oµotoµopcpov EvipyEtotV U7t0 auv871xE<; Xot'tW'tCX'tOU oyxou oxt µEyotAU'tEpou 'tWV 10-4 A2/G (Eocxcpto (6) 'tOU optaµou). • (V) M71-pot6tEVEpycx d671 µoAuv0iv'tot oxt 7tEpt000'tEpo ot7t0 10 cpopi.;; 'tot optot XOAOU 'tot otvotcpEpoµEvot 0't7JV 7totpotXCX'tW 7totpcxypotcpo 5 Xott Xot'tCX 'tp07tOV wan 71 Et0tX7j EVEpyEtot U7t0 auv871xE<; Xot'.tW'tCX'tOU oyxou ou6i 7tO'tE Vot U7tEp~ottVEt 'tot 104 A2/G (Eocxcpto (E) 'tOU optaµou). Ilivotxot<; 5 E'ttXE'tE<; XtVOUVOU E7tt 'tWV XOAWV (8Ai1tE Ilpo0871x71v A. 9) Ex'to<; ECXV. µE'totcpipov'tott W<; 7tA7JpE<; cpop'ttO mxin.;; 'tWV µov'tEACt>V 7 A, 78 7l 7r 0ot 't07t00E'tOUV'totr E!;W'tEptxw.;; OE Mo otV't10E'tE<; 7tAEupic;, ~AE7tE 7tEpt0wpto 3653 EW<; 3655 't7j<; Ilpo0871x71.;; A6 ytot Xot't7jyopiot xoAou. To 7tEptExoµEvo 0ot 7tEptypcxcpE'tott'E7tt 'tWV E'ttXE'tWV w<; «Pot6tEVEp­ jOV LSA». I\EU'tEpEUOUGE<; ntxin.;;: (I) r tot Vt'tptxov 0optov Xott Vt'tptxov oupcxvtov - ot7tott'tOUV'tott E'ttXE'tE<; µoV'tEAou No 3. (II) ftot cp0optouxo oupcxvt0 - ot7totL'tOUV'tott E'ttXEnc;' No. 4. Ecxv u1tcxpxouv 0LotG7totG'tE<; UAE<; ot opot 'tOU 7ttVotXO<; II 0ot 't'1JPOUV'tott Em1tpOG8E'tW<; 'tWV opwv 'tOU 7totpOV'tO<; 7ttVotXO<;. 2. LUOXEUGtot/KoAov KoAot µE'totcpEpoµEvot oxt w<; GUOXEUotGtot 1tA71pouc; cpop'ttOU 0ot EtVott auµcpwvwc; 1tpoc; 'tO 7tEpt0wpto 3600, 7tEpt0wpto 3650 EW<; 2655 Xott 1tEpt8wpto 3656(1) iw<; (4) 't7j<; IlpoG871x71<; A.6. 'UEc; 't7j<; otVW'tEpw 1totpotypcxcpou 1 (II) U7t0 µot,tXTj G'tEpECX µopcp71 0ot GUGXEUCX,OV'tott Xot'tCX 'tp07t0V WG'tE Vot ot7tOcpEuynott 71 ot1to!;EGt<; ( EX'tpt~Tj), xott u1to CXME<; O'tEpEE<; µopcpi<; 0ot 1tEptEXOV'tott GE ouGtotG'ttXTj 8wpcixt07j. 3. Avwi:ot'tO E7tt7tE00 otX'ttVO~OAtotc; KoAou 2. mSv /h (200 MREM/H G't7IV EmcpcxvEtot 'tOU XOAOU Xott 0, 1 mSv /h (10 MREM/H GE 1 µhpo ot7t0 't7JV E7tt<pCXVEtot otU'tTJ (~AE7tE 7tEpt0wptot 3653 iwc; 3655 't7j<; IlpoG871x71<; A.6). Ex'tO<; 't7j<; 7tEpL7t'tWGEW<; 1tA71pou<; cpop'ttOU 07tO'tE 'tO optov EtVott 10 mSv/h (1.000 MREM/H) G't'1JV EmcpcxvEtot 'tOU XOAOU xott µ1topEi Vot U7tEp~Ei 'tot 0, 1 mSv /h (10 MREM/H) GE 1 µi'tpo ot7t0 't7jV EmcpcxvEtot otU'tTJ (~AE7tE 1tEpt8wpto 3659(7) 't'1J<; IlpoG871x71<; A.6). 4. MtXTIJ GUGXEUotGtot Bl..i1tE 7tEpt0wpto 3650 't7I<; IlpoG871x71i:; A.6. 5. M0Auv01J E7ti 'tw11 xoAwv ( ot) M 71 wptGµEvot op tot E!;W'tEptx71c; µoAUVGEW<; ytot, XO Act µE'totcpEpo­ µEvot oxt w<; 7tA7JpE<; cpop'ttO. ~/y /xa.µ71A71<;-'to!;txo't'1J'tO<; a. 1toµ1toi: 3, 7 8q/Ex2 (104 µCi) <l>uGtx.011 / ~!;otG8Ev71µivov oufcxvt0v / . cpuGtxov 8opto11: 37 8q/Ex (10·3 µC1) ·mm ot 1toµ1toi:, 0,37 8q/Ex2 (10·5 µCi) ftot 7tA7JpEtc; AE7t'toµipm<;, ~AE7tE 7tEpt0wpto 3651 't7j<; Ilpo0871x71c; A.6. (~) f tot xoAot µE'totcpEp<iµE11ot W<;7tA7JpEc; cpop'ttO • Ou6Eµtot 6tcx'tot!;t<;. 6. E116d!;Et<; (µa.pxciptGµot) E1ti 'twv x0Aw11 KoAot µE'totcpEpoµEvot W<;7tA7JpEc; cpop'tio - 1t0Auypotcp71µiv71 7l illw<; G7j· µEtouµi1171 iv6Et!;tc; «PAMENEPfON LSA». KciAot µE'totcpEpo(lEVot oxt we; 7tA7JpEc; cpop'ttO - 0ot µotpxcxpE'tott xa.0otpcx Xott otvE!;t't7JAot 'tO ~expo<; ECXV U7tEp~cxtVEt 'tot 50 KG. 7. "Eyypotcpot µE'totcpopcxc; To iyypotcpo µE'totcpopcx<; 0ot 7tEptAotµ~cxvEt 't7jll 1tEprypotcp7111 «Pot6LEVEp­ jEt<; UAE<; (Xa.µ71A7J<; Et6tx71<; mpyda.c; LSA(l)), 7, 1tiva.!; 5, ADR», µE 't7jll 011oµotGiotv u1toypa.µµtGµi117111 µE xoxxtvo, xott 'tt<; AE1t'toµipmc; 'tL<; opt,oµEnc; G'tot 7tEpt0wptot 3680 Xott 3681 't7I<; IlpoG871x71<; A.6. 8, A1to871xwGt<; Xott 1tpow871Gt<; (a.) A1to87JXEUGt<; Xott 61a.xwptGµoc; ot7t0 illot E7ttXt\10U\lot Eµ1topEuµot'tot ~AE7tE 1tEpt8wpto 3658(1) 't7I<; IlpoG871x71.;; A.6. (~) A1to871xw071 Xott 61a.xwptGµo<; ot7t0 XOAot cpipoV'tot E'ttXE'tot «FOTO» 7tEpt0wpto 240001 't7I<; IlpoG87Jx71c; 8.4 ytot 'tO\I 7tt\lotXot 6ta.xwpt­ Gµou. (y) "Opt0 0EtX'tOU OAtXTj<; µE'totcpopcxc; ytot ot1to871xEUGTj, ou6iv optov EX'tO<; 't7I<; 7tEpL7t'tWGEW<; XOAWII l\tot07tot0't7J<; KAcxaEw<; II 7J III, ~M7tE 7tE pt0wpto 3658(2) iwc; (5) 't7I<; Ilpo0871x71<; A.6. • . • 9. ME'totcpopcx XOAWV µE ox71µot'tot Xott 6oxEiot (CONTAINERS) (ot) l\1a.xwptGµoc; ot7t0 XOAot cpipov'tot E'ttXE'tot «FOTO» - ~AE7tE 1tEpt8w­ pt0 240 001 't7I<; IlpoG871x71<; 8.4 jLot 'tO\I Ilivotxot 6ta.xwptGµou. (~) "Opt0 0ELX'tOU OAtXTj<; µE'totcpopcxc; - 50. To opto otU'tO 0E\I tGXUEt jtot 7tA7JpE<; cpop'ttO, U7t0 'tO\I opo11 O'tt ECXV u1tcxpxouv XOAot l\totG7totGTij<; KAcx­ GEW<; II 7l III 0E\I 0ot U7tEp~ott\lE'totL O Em'tprnoµEYO<; otpt0µo<;, (~AE7tE 7tEpt 0wptO\I 3659(5) 't7I<; IlpoG871x71<; A.6). ( y) A 11W'tot'tot E7tl7tE0ot otX'ttVO~OAtot<; ytot ox71µot'tot xott µEj<XAot 6oxda. (CONTAINERS) 1tpoxEtµivou 1tEpi 1tA7Jpouc; cpop'tiou 2 mSv /h G't7III EmcpcxvEtot (200 MREM/H) 0, 1 mSv /h GE 2 µi'tpot ot7t0 't7III EmcpcxvELot (10 MREM/H) (~AE7tE 1tEpt8wpt0 3659(1) 't7j<; IlpoG871x71<; A.6) .. E1ti07Jc;, ytot ox71µot'tot - 20 mSv /h GE 07tOtot07j7tO'tE XotVO\ltXW<; Xot'tot­ A71 <P8EtGot 0fotv - ~AE7tE itEpt0wpto 3659(8) 't7I<; IlpoG871x71<; A.6. (6) KoAot µ71 GuµµopcpouµEvot 1tpo<; 'tOU<;,opou<; 'tOU 7tEpt0wpiou 3600 ~ot µE'totcpipoll'tott w<; 7tA7lpEi:; cp'op'tio, Xott 0EV 0ot U7tEp~ot~\IOU\I 'tot optot 'tOU mxpa.xcx'tw 1ti11a.xo<;: L'tEpEcx 0!;Et0t0 'tOU 'tpt'tlOU OE U0ot'tw671 6totAuµot'tot • J\Uot uypcx Xotl otEptot • Opto EYEpyEiot<; ox71µa.'toc; 71 µEj<XAOU 6oxEiou (CONTAI­ NER) Ou6i11 opto11 100 X A 2 10. ME'totcpopcx EL<; xuµot µE ox71µot'tot Xott 6oxEicit (CONTAINERS) Em'tpE7tE'tott U7t0 7tA7JpE<; cpop'tio U7t0 'tOV opov O'tt, µE'tCX 't7III cpop'tWG7I, Ol E!;wnptxii:; EmcpCXIIEtEi:; 'tWV ox71µcx'tW\I 0ot ixouv 7tpOGEX'tLXW<; xot0otpt­ G0Ei U7t0 'tOU ot7tOG'tOAEW<; Xott Ecp' OGOV ou6Eµiot 6totppo71 µ1topd \lot 1tpo­ xuq,u U7t0 Xot\lOVtX7JV µE'totcpopcxv. IloGO'ttXCX optot w<; Et<; 'tO\I 7tt\lotXot 't7j<; ot\lW'tEpw 7totpotypcxcpou 9, 11. ME'totcpopcx µE ~U'ttocpopot Xott TANK co NT AINERS . ot) Mnotcpopcx µE ~l.l'tfOcpopot: E7tt'tpE7tE'tott jtot uypcx 71 G'tEpEcx 7tA7JV 'tOU E!;otcp8opt0uxo:u oupa.11[ou Xott OUGlW\I U7tOXEtµivw11 OE otU'totvcxcpAE!;71 (~AE1tE IlpoG0. A.6, mpt0. 3660) .. ~) ME'totcpopdi GE 6E!;otµEvic; • XOV'tE7j11Ep<;: E7tt'tpE7tE'tott ytot uypcx 7j G'tE­ pECX auµ1tEptAotµ~ot11oµi11ou 'tOU cpuatxou 7J E!;ot08E1171µivou ( E!;TjV'tA 71µi 11ou) E!;otcp0optouxou oupotviou (~M7tE IlpoG87Jx71 A.6, 7tEpt0wpto 3661). 12. Emypotcpii:; Xott E'ttXE'tE<; E7tt ox71µcx'tWV, ~unocpopw11, TANK CO­ NTAINERS Xott 6oxEiw11 (CONTAINERS) (8AE7tE IlpoG07JXE<; A.9 xott 8.4). l\oxda. (CONTAINERS) - E'ttXE'tE<; µov'tiAwv 7A, 78 7l 7f E1ti OAWII 'tW\l 'tEGG<Xpw11 7tAwpwv. Ox71µot'tot Xott µEycxAot 6oxEiot (CONTAI­ NERS) - Emypa.cpii:; auµcpwvwi:; 1tpoc; 'tO µ011'tiAo 'tTJ<; IlpoG871x71<; 8.4 1tE­ pt8wpto11 240 010 GE xcx0E 7tAwpcx Xott 07ttG0to 'toixwµot 'tOU ox71µot't0<; (~Aa7tE 1tEptBwp1a. 3659(6) xa.1 71 500). l\w'tEpEUOUGE<; E'ttXE'tE<;: • . (I) ytot llt'tptxo 8opt0 G'tEpEo Xott \lt'tptxo oupci11to G'tEpEo, ~7tott't0U\l'tott E'ttxin<; µ011'tEAou No. 5, . (II) jtot E!;otcp8optouxo oupci11t0 XotL E!;oti.i6ptxo \lt'tpLXO oupcx11to GE 6tci­ AUµot, ntxhEc; µ011'tEAou No. 8. (III) ytot oua[Ec; 7tOU 7totpOUGtCX,OUV 1tpoG8En<; E7tLXl\lOUVE<; tOLO't7l'tE<; xott µE'totcpipoV'tott aa.11 7tA7JpE<; cpop'tio, ot7totL'tEt'tott ot11ci).oy71 E'ttXE'tot xtvou­ vou. 13. A1totyopEUGEt<; E7tt µtX't7J<; cpop'tWGEW<; 8AE7tE mpt0wpto 2700(3). • 14. A1t0Auµotv07J ox71µcx'tWII, ~U'tt0cpopwv, TANK CONTAINERS Xott OOXElWV (CONTAINERS) EG>HMEPII THI KYBEPNHIEQI (TEYXOI LlEYTEPO) 1197 (ex) ftlX IXltOO'tOAEc; 1tA11pouc; cpop'tiou, f,I.E't(X TT)II Excpop'tWOTj, 'tlX"'OX,11- Mncxcpop<i Etc; x.uµcx oaox.11µ1X't1X XIXt 00)'. ELIX (CONTAINERS) f,llX'tlX 6cx 1X1t0Auµcxi11011't1Xt u1to 'tOU 1t1XplXA1l1t'tou O'tlX E71:L1tEOIX 'tou Tiivcxxoc; AEII Em'tpE1tE't1Xt. XIX 't7I<; Tipoo611x71c; A.6 EX'toc; E<X\I x p71otµo1tot716ou11 -ytcx 't7I fLE'tlXcpopcx l~ ME't1Xcpopcx fLE (3u'ttocpop1X XIXt TANK CONTAINERS 'tWII iotw11 uAw11. BAEltE mio71c; 1tEpt6wpto 3695(4) 't7I<; Tipoo611x71c; A.6. L\Ev am'tpE1tE't1Xt. • ((3) ftlX IXltOO'tOAEc; O'/.,L 1tA11pouc; cpop'tiou, {3AE7tE 7tEpt6wpto 3695(3) 12. EnpcxcpEc; XIXt mxhEc; Elti OX,7lfL<X'tWII, (3u'ttocpopw11 TANK CO 't7I<; Tipoo611x71c; A.6. NT AINERS XIXt OOX,Eiwv (CONTAINERS) ({3AE7tE Tipoo611xac; A. 9 xcxt 15. 'AllEc; OtlX't<Xl;uc; B.4) . (ex) ~tlX't<X!;Eu;; 7tEpi IX'tUX,7lf.l<X'tWII - (3Ai1tE 7tEpt6wpto 3695(1) 't7I<; Tipo- • L\oxEilX CONTAINERS - mxhEc; 'tW\I 7 A, 7B 117r XIXt O'ttc; 'tEOOEptc; 0611x71c; A.6. ltAEUpEc;. ((3) A1toAUfLIXII07I Ell 1X1to671xEUOEt - (3AE1tE 7tEpt6wpto 3695(2) 't7lc; 0x.11f.llX'tlX XIXt µqcxAIX oox EilX (CONTAINERS - Em-ypcxcpEc; ouµcpWIIIX Tipoo611x71c; A.6. fLE 'to µ011'tEAo 't7lc; Tipooll11x71c; B.4, 1taptllwpto 240.010 oa x<i6E 1tAwp<i XIXt 01tiollto 'tOix wµcx 'tOU OX.11fLIX'tOc; ({3AE7tE 7tEptllwpt1X 3659(6) XIXt 71 1. ·nEc; 500). ·nEc; X~f.l71A11c; EtOtx11c; EIIEp-yEilXc; LSA(II) IXll11XOUOIXt OE 07totlX0117tO'tE 13. A1tcx-yopEUOEtc; mi µtx't11c; cpop'tWOEwc; 'tWll 7t1Xp1XX<X'tW oµcxowv we; opi,Oll'tlXt 1tA11pwc; O'tO 7t~ptllwpto 2700(2): BAEltE 7tEptllwpto 2700(3). · (I) 'TI.Ee; µa oµouiµopcpov a11ap-yucx11 oxt µa-y<XAU'tEp1X11 'tW\I 10-4 A2/G 14. A1t0Auµcx11071 ox71µ<X'tWII, (3u'ttocpopw11, TANK CONTAINERS XIXt (aocxcptoll (oc) 'tOU optoµou). ooxdwv (CONTAINERS) (II) M11-pocotEIIEp-y<i do71 µ0Au118a11't1X OE EltiltEOO µ71 U1tEp{3oci11011 'tOC 37 BAaltE' 7tEpt0wpto 3695(3) XOCt (4) 't7I<; Tipoo011x71c; A.6. kbq/ax2 (lµCi) -ytoc .f3 XIXt r 1toµ1touc; XIXt xcxµ71)..11c; 'tOl;tXO't7l'tO<; IX ltO- 15. 'Allee; OtlX't<Xl;Etc; µ1touc;, 113, 7 kBq/ ax2 -Y,tlX <XMouc; IX 1toµ1touc; (ao&cptoll ((3) 'tOU optoµou ). L\tiX't<Xl;uc; 7tEpi IX'tU)'. 7lf,l<X'tW\I - {3AE7tE 7tEpt6wpto 3695( 1) TT)c; Tipooll11 m11ixxixc; 6 XT](; A.6. • • Tii IIIXXIX<; 7 E'ttXE,Ec; Xt\lOU\IOU Elti 'tW\I XOAWII. • . . E'ttXE'tEc; Xt\lOU\IOU Elti 'tW\I XOAWII. OuoEµicx OCltlXt'tEL'tlXt EX'toc; E<XII u1tcxpxou11 OtlXOltlXO'tEc; UAEc;. ({3AE7tE m- Ouoaµ[cx IXltlXt'tEi't1Xt EX'tO~ E<XII U1tcxpx ou11 OtlXOltlXO'tEc; UAEc; ({3AE7tE 1ti \llXXIX II). • IIIXXIX II) Eiiv U1tcxpxou11 OtlXOltlXO'tEc; UAEc; ot opot 'tOU 1ti11cxxoc; II llcx 'tlJPOUll'tlXt l, ·nac; mmpoollhwc; 'tW\I opwv 'tOU 1t1Xpo111:oc; 1ti11cxxoc;. Xcxµ71Aou Em1ta6ou O'tEpEEc;' p1XOtE11Ep-yt[c; UAEc; LLS, IX1111XOUO~ OE 2. LuoxEUIXOi1X/KoAO\I 01totixo111to'tE 'tW\I 7t1Xp1XX<X'tW\I oµcxowv we; op[,OV'tlXt 1tA11pwc; O'tO 7tEpt H OUOXWIXOilX Bex Ei111Xt ouµcpwvwc; 1tpoc; 'tOuc; opouc; 'tOU 7tEpt0wpiou llwpto 2700(2): . 3600, 1tEpt0wpiou 3650 xm 1taptllwpiou 3651 TT)<; Tipoo011x71c; A.6. (I) ·n.ac; µa oµotoµopcpov a11ap-yEt1X11 ox t µEJ<XAU1:apcx11 'tWII 2 X 10 -3 ·3. A11w1:1X't0\I E1ti1tEOO\I IXX'ttllo{30Ai1Xc; KoAOU AiG (Eocxcpto\l (ex) 'tOU optoµou. . KAEtO'tlX ox11µcx1:1X UltO 'tOU<; opouc; 'tOU 7tEptllwp[ou 3659(7) (ex) 't'Tj<; (II) M~-p1X0tE11Ep-ycx Eio71 µ0AU111li111:1X OE mtltEOO µ71 U7tEp{31XtllO\I 'tlX 20 Tipoo011x71c; A.6 - 10 mSV /h 01:7111 Emcp<XIIEtlX 'tOU XOAOU XIXt (lltOpouv \/IX UCljCM rux (3 XIXt r 1toµ1touc; XIXt xcxµ71A11c;·1:ol;txo't71'toc; IX 1toµ1touc; 11 ump(3ou11 'tlX 0,1 mSV /h OE El/IX µhpo IXltO 't7lc; Emcp1X11Ei1Xc; IXU't11<;- "0)..cx 'tlX 2 UCI/CM2 -ytix <XMouc; IX 1toµ1touc; (ao&cpto ((3) 'tOU optoµou). 'tlX IXMIX ox.11µ1X'tlX ltOU OE\/ UltOXEt\l'tlXt O'tOUc; opouc; 'tOU 7tEptllwpiou Ecxv U1tcxpxou11 OtlXOltlXO'tEc; UAE<; ot opot 'tOU 1ti11cxxoc; II llcx 't"fjpOUll'tlXt 3659(7) (ex) 't7I<; Tipoo011x71c; A.6 - 2 mSv/h O't7IV amcpii11at1X 'tOU xoAou Em1tpoollhwc; 'tWII opwv 'tou 1tcxpo11'toc; 1ti11cxxoc;. - - ' • xcxt 0, 1 mSv /h oa EIIIX µhpo ix1to 't7lc; Emcpcx11Elcxc; IXU't11<;- 2. Luoxwixolcx/Ko)..011 4. Mtx't11 OUOXWIXO\IX (oc) H OUOXEUIXOilX 0ix Eill1Xt ouµcpwvwc; 1tpoc; 'tOU<; opouc; 'tW\I 7tEptllw BAE7tE 7tEpt0wpto 3650 't7I<; Tipoo011x71c; A.6. piwv 3600 XIXt 3650 1:71c; Tipooll11x71c; A.6 XIXt llcx Eill1Xt OE llio71 \/IX IXll6E 5. Mo)..u11071 mi 1:w11 xo)..wv l;at o'touc; EAE-yx.ouc; 'tou 1tEpt0wpiou 3635(4) xcxt (5) TT)<; Tipoo611x71c; M71 wptoµE111X optlX El;W'tEptx11c; µoAU\loEwc;: A.6. (3/r/xcxµ71)..11c; ,:ol;tXO't7l'tO<; IX 1toµ1toi 3, 7Bq/Ex 2 (l0· 4 µCi) ((3) Y1to ,:ouc; opouc; 'tW\I Ell (ix) IX111XcpEpoµi11~11 EAE'YX,WII OE\/ llix U1t<Xp <l>uotxo11 I al;ocolla1171µE11011 oup<Xllto\l / )(.Et: . q,uotXO\I 0opto11 3 7 Bq/ EX 2 ( 10· 3 µCi) (I) IXltWAELIX 11 OtlX07tOp<X 'tOU p1XOtE11Ep-you 1tEptEX,OµE11ou," • Allot IX 1toµ1toi 0,3 7 Bq/ EX 2 (10 5 µCi) (II) cxul;71071 'tOU IX\IW't<X'tOU ElttltEOOU IXX'ttllo{30Ai1Xc; 'tOU XIX'tlX)(.wp716a f t1X 7tA11PEtc; AElt'tOfLEpmc;, {3AE7tE 7tEptllwpto 3651 't7I<; I1pooll11x71c; 1/'tOc; 11 UltOAo-ytollE111:oc; O't7III al;w,Eptx11 Eltt<j)<XIIEtlX -ytcx TT)II 1tpo 'tOU EAE-y A.6. x.ou XIX't<XO'tlXOTj, 6. Evodl;Etc; (µcxpxiiptoµcx) XOAWII • . 3. AIIW'tlX'tO\I EltiltEOO\I IXX'ttllo{30Aiixc; KoAOU Tex XOAIX llcx µcxpxcxpov'tlXt «PAL\IENEPfON LSA» µa STENCIL. KAEtO't<X ox.11µcx1:1X UltO 'tOU<; opouc; 'tOU 7tEptllwpiou 3659(7) (ex) TT)c; 7. "Enpocq,ix µE'tlX<j)Opcxc; Tipooll11x71c; A.6 - 10 mSv/h (1000 mrem) OTT)\/ Eltt<j)<XIIEtlX 'tOU XOAOU To inpixq,o µE'tlX<j)Opcxc; llcx 1tEptA1Xµ(3cx11Et 't7III ltEpt-ypixq,1111 «PIX0tE11Ep-. XIXt µ1topai \/IX U7tEp{3Ei 'tlX 0, 1 mSv /h OE El/IX µhpo IXltO TT)\/ Eltt<j)<XIIEtlX IXU­ yaic; UAEc; (xcxµ71A11c; EtOtx11c; mp-yEilXc; LSA (II}, 7, 1till1XXIX 6, ADR», µE 't11II, 't7III 011oµcxoiix11 U1to-ypcxµµtoµe117111 XOCt 'ttc; AElt'toµepmc; ,tc; opt,OfLEIIE<; • OAIX 'tOC <XMIX ox.11µcx1:oc ltOU OE\/ UltOXEtll'tlXt O'tOUc; opouc; 'tOU 7tEpt6wpiou 01:ix 1taptllwptix 3680 xcxt 3681 't7I<; Tipoo611x71c; A.6. 3659(7) (cx).1:71c; Tipoo011x71c; A.6 - 2 mSv/h O't7III amcp<i11Et1X 'tou xoAou 8. A1to611xEuo71 xixt 1tpow871071 xm 0, 1 mSv /h oE evix µhpo 1X1to TT)II Emq,ii11Et1X IXU't11 Mo11011 UltO 1tA11pac; q,op'tiov. 4. Mtx-i11 OUOXEUIXOilX 9. ME1:1Xcpop<i XOAWII fLE oxrifLIX'tlX XIXt 00)(.EtlX BH1tE 7tEptllwpto 3650 1:71c; Tipoo011x71c; A.6. (ix) ME't1Xcpopcx µ011011 fLE 7tA11pEc; q,op'tiov. 5. M0Au11071 mi 'tW\I XOAWII ((3) Ecxv 71 IX7tOO'tOA11 1tEptA1Xµ(3cx11Et XOAIX L\tlXOltlXO't11c; KA<XOEW<; II 11 OuoEµiix Ot1X't1Xl;71. III, OE\/ 0ix U1tEp(3cxi11E'tlXt O mt'tpmoµE11oc; ixptllµoc; ({3AE7tE Tii111XXIX II). 6. Evliail;atc; (µcxpxcxptoµcx) Elti XOAWII (r) AvW'tlX'tlX miitEOIX IXX'tt\10(30Ai1Xc; 'YtlX OX.11fLIX'tlX XIXt µE-y<XAIX 00)(.EilX Toe XOAIX Bex µcxpxiipoll'tlXt «PAMENEPfON LLS» 11 µa STENCIL. (CONTAINERS) - • 7. 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Evoai!;Etc; (µexpxcxptaµex) XOAW\I Tex XOAex a(X µexpxcxpov,ext E!;w,Eptxwc; xex0expcx xext exvE!;i­ 'tl]Aex µE: (I) «TYTTOL B(U)» (II) ev6et!;l] ex\lex"(\lwpiaEwc; 'tljc; expµo6icxc; expx7Jc; (III) 'tO ~cxpoc; ECX\I CX\IW 'tW\I 50 KG . (IV) 'tO ,picpuAAo auµ~oAO E\lawµex,wµevo 7l a,exµ1texptaµevo E7tl 'tOtJ ·E!;w,Eptxou 'tOtJ exv0EX'tLXOU uc; 'tO 1tup xext u6wp 60 xatou. 7. 'Enpexcpex ME'tlXcpopcxc; (ex) r tex exvexxEcpexAexiwalj 'tW\I opwv 'tljc; E,xpiaEWc; xext XOL­ \107tOL7JOEWc;, ~Aem 7tEpt0wpt0 2704. (~) To·errpcxcpo fJ-E'texcpopcxc; 0ex 7tEptAexµ~cx\lEL 'tl]\I 7tEpt,pcx­ cp7j11 «PexotE\IEP'Yaic; UAEc; XOAW\I Tu1tou B(U), 7, 1tivcxxoc; 9, ADR», fJ-E 'tl]V ovoµexaiexv u1to1pexµµtaµivl]v, xext ,tc; AE1t,oµe­ pmc; ,tc; opt~OfJ-E\IEc; O'tex mpt0wptex 3680 XCXL 3681 'tl]c; TTpo­ a07JXl]c; A.6. (r) TTta't07tOLlj'tLXO\I fJ-0\107tAEUpou qxpiaEwc; 'tOtJ OXEOiou 'tO\J XOAOU ex1t(Xt,Ei,ext, ~Aim 7tEpt0wpto 36 72 'tljc; TTpoa07J­ Xl]c; A.6. (6) TTpo •'tl]c; cpop,waEwc; OLOU07J7tO'tE XOAOU O ex1tOO'tOAEuc; 0ex EXEL O'tl]\I xex't0x7J 'tOtJ OAex ,ex oXE'tLXCX 7tLO't07t0Ll]'tLXCX E,xpiaEwc;. (E) TTpo ,lJc; 1tpw,1Jc; cpop,waEwc; au1xExptµevou axEoiou xoAou, Ecxv lJ Evep1Etex Eivext µE1exAu,EplJ ,wv 3 X 103 A2 7J 3 X 103A1, we; E\IOEiXW'tCXt, 7l 3 X 104CI, 01tot0U07J1tou ,ou,wv O\l'toc; xexµl]AO'tepou, 0 ex1tOO'tOAEUc; 0ex e.!;exacpCXAi~et 01twc; exv,i­ rpexcpex 'tW\I 7tLO't07t0Ll]'tLXW\I e.rxpiae.wc; 'tljc; expµooiexc; expx7Jc; 1texpexaxe.Oouv a,tc; expµo6te.c; expxec; ,tc; 0t1oµe.vac; e.x ,lJc; µncx­ xt117Jae.wc;, ~Aem 1te.pt0wpto 3682(0 'tljc; TTpoa07JXljc; A.6. ( O't) TT po xcx0e. !op,wae.wc; o,exv lJ e.vep,e.tex e.ivcxt µa,exAU­ Upl] 'tW\I 3 X 10 A2 7l 3 X 103 Al we; e.voaixw,ext, 7l 3 X 104CI, 01totou67J1tou ,ou,wv ov'tOc; x.exµl]Ao,epou, o·ex1toa,o­ Ae.uc; ocpe.iAEL vex "(\IWO't07tOL7JOEL 'tOU'tO a,tc; expµoote.c; expxec; OAW\I ;tW\I xwpwv 'tW\I Ot,oµevwv e.x 'tljc; XL\11jOEWc;, xex,cx 1tpo­ 'tifJ-l]Ol] 1tpo oe.xex1tE\l'tE l]fJ-Epwv we; Ae.moµEpwc; exvexcpepe.,cxt O'tO 7tEpt0wpto 3682 'tljc; TTpoa07JXl]c; A.6. . (~) Oacxxtc; mwcpe.Aouµe.Oex 'tljc; e.m,p,moµivljc; l]U!;l]µEvljc; e.ve.p1aiexc; exvcx xoAov oto,t l] uA l] dvext e.totx7Jc; µopcp7jc;, (~AE1te. 1texpexrpcxcpouc; (ex) xext (a,) exvw,apw ), ex1texmhext µ01101tAe.upov 7tLO't07t0Ll]'tLXO\I e.rxpiaEwc; axe.oiou ELOLX7Jc; µopcp7Jc; (~AE7tE 7tE­ pt0wpto 36 71 'tljc; TTpoa07JXljc; A.6.). 8. A1to07JXEUOl] xext 1tpow0l]Ol] (ex) 01tOLE007J7tO'tE OOlJ'YLe.c; 'tOtJ 7tLO't07t0Ll]'tLXOU E,xpiae.wc; 'tljc; exp'µooiexc; expx7Jc; Oex 'tl]pOu\l'text. (~)A1to07JXWOl] xext Otexxwptaµoc; ex1to CXAAex Emxiv6wex. Eµ1tope.uµex,ex - ~AE7te. 1tEptOwpt0 3658( 1) 'tljc; TTpoa07JXl]c; A.6; . (r) A1to07JXWOl] XCXL Otexxwptaµoc; ex1to XOAex cpepov,ex 'tO\I 'tl'tAO\I «FOTO» - ~Ae7tE 1tEptOwpt0 240 001 'tljc; TTpoa07JXl]c; B.4 ,tex 1tivexxex Otexxwptaµou. (6) 'Opto oeix,ou OALX7Jc; µE,excpopcxc; ,tex ex1to07JXEUOl] - SQ exvcx oµcxoex fJ-E 6 µhpex µnex!;u 'tW\I oµcx6wv - ~Ae7tE 1te.ptOw­ pt0 3658(2) ewe; (5) ,lJc; TTpoa07Jxl]c; A.6. (e.) 0 ex1tOO'tOAe.uc; Oex exEL 'tlJP7JOEt 'tOtJc; 1tpo 'tljc; XP7JOEWc; xext 1tpo 'tljc; c:pop,wae.wc; opouc; 'tW\I 7tEpt0wp[wv 3643 Xext 3644 ,ljc; TTpoa07JXl]c; A.6. . (a,) H 0Epµ.oxpcxaiex ,wv 1tpoat,w11 e.mcpexvatwv ,ou xoAou OE Oex ump~exl\lEL ,ouc; 50°C tJ7tO OXLCX\I EX'toc; ECX\l l] fJ-E'texcpopcx 'tEAEl tJ7tO auv07Jxexc; ( opouc;) 7tA7Jpouc; cpop,iou, 07tO'tE 'tO optO\I Eivext 82 °C (~Ae1te. 1te.pt0wptex 3602(3) (~) xext 3603(8) 'tljc; TTpoa07JXl]c; A.6). (~) Ecxv lJ µfol] Emc:pexve.texX7J po7J 0EpfJ-O'tlj'tOc; CX7t0 XOAO\I u1tEp~exi11Et ,ex 15 W /M2, ,o,E ,o xoAov Oex µe.,excpepE,ext we; 1tA7JpEc; cpop,io. 9. Me.,exc:popii XOAW\I µe. ox71µex,ot xext 6oxE1ex (CONTAI­ NERS) (ex) ~texxwptaµoc; ex1to xoAex c:papov,ex 'tO\I 'tl'tAO\I «FOTO» ~AE7tE 7tEpt0wpLO 240 001 'tljc; TTpoa07JXl]c; A.4 ,tex 1tivcxxcx otexx wptaµou. (~) 'Opto OElX'tOU OALX7J<; µe.,exc:popiic; - 50. To opto exu,o oe.v taxue.t ,tex 7tA7Jpe.c; cpop,[o e.c:p' 000\1 EIX\I tJ7t1Xpxouv XOAex ~Lex a1texa,11c; KAcxae.wc; II Tj III oe.v tJ1te.p~exivnext O e.m,pa1toµe.voc; otpt0µoc;. BAi1ta 1te.pt0wpto 3659(5) 'tl]c; TTpoa07JXl]c; A.6. (r) Avw,ot,ex mi1taoex exX'tL\IO~OAtexc; ,tot oxriµex,ot xext µe.­ 'YIXAex ooxe.iex 1tpoxuµevou mp[ 7tA7Jpouc; <pop,iou 2 mSv /h 200 mrem/h O'tl]\I e.mc:piivucx 0, 1 mSv /h 10 mrem/h ae. 2 µhpex ex1to 'tl]\I e.mc:piive.tex BAe1te. 1te.ptOwpt0 3659(7) 'tljc; TTpoa07JXl]c; A.6. E1tial]c; 1 tex ox7Jµex,ex - 20 µSv /h aE 01totex61j1tO'te. xexvovt­ xwc; xex,exAl]c:p0e.iaex Ofol] - ~AE7tE mpt0wpto 3659(8) 'tl]c; TTpoa071xl]c; A.6. . (CO- 10. Me.,exc:popcx e.tc; xuµex µe. ox71µex,ot xext 0( NTAINERS) ~E\I exe.t ecpexpµo17JV. 11. Me.,exc:popcx. µe. ~tJ'ttoc:popex xext TANK CONTAI­ NERS ~E\I iXEL E<pexpµO'YTj\l, . 12. Em,pex<pec; xext E'ttXhe.c; mi OXlJfJ-CX'tW\I, ~tJ'ttocpopwv, TANK CONTAINERS xext ooxe.iwv (CONTAINERS) (BAe1te TTpoa071xe.c; A.9 xext B.4). • ~oxdex - mxhe.c; µo\l'teAW\I 7 A, 7B 7J 7r xext a,tc; ,foae.ptc; 1tAwpec;. Oxriµex,ot xext µqcxAex 6oxE1ex - e.m,pexcpec; auµcpwvwc; 1tpoc; 'tO fJ-0\l'teAO 'tl]c; TTpoa07JXljc; B.4 1te.ptOwpt0 240 010 ae. xcx0e. 7tAwpii Xott O'tO 01tia0to 'tOlxwµcx 'tO\J ox7Jµd:,o~ (~AE7te. 1te.pt­ Owptex 3659(6) xext 71 500). 13. A1tot1opwalJ mi µtx,71c; c:pop,waEwc; BH1te. mpt0wpto 2700(3). 14. A1toMµexvalj OXlJfJ-IX'tW\I, ~tJ'tt0c:popw11, TANK CO NTAINERS xcxt ooxe.iwv (CONTAINERS) B).em 1tEpt0wpto 3695(3) ,lJc; TTpoa07JXl]c; A.6. 1s. 'AAAe.c; otex,cx!;e.tc; (ex) ~tex,cx!;etc; 7tEpl A,UXlJfJ-IX'tW\I - ~AE7te. 1te.pt0wpto 3695(1) 'tl]c; TTpoa07JXl]c; A.6. (~) A1toAUfJ-CX\IOlj E\I ex1t00l]XEUae.t -· ~AE7te. 7te.pt0wpto 3695(2) 'tljc; TTpoa07JXl]c; A.6. 1. ·ne.c; PexotEve.p1e.lc; u).e.c; Tu1tou B(M) xoAwv 'Hwt oXEOLO\I XOAOU Tu 7t0tJ B w 01toiov OE\/ 1tA71poi evex\l 7j 1tEptOOO't~pouc; 'tW\I EL­ OLXW\I 1tpoa0hwv opwv ,tex XOAex Tu1tou B(U (~Ae1te. 7tE­ pt0wpto 3603 ,lJc; TTpoa07J­ xlJc; A.6). Ouoe\l optO\I mi 'tljc; 7tOOO'tl]'tOc; exvcx XOAO\I e.x,oc; we; 1tpo~AE7tE'text tJ7tO 'tOtJ 7tLO't07t0Ll]'tLXOU e.rxpi aEwc;. Ecxv tJ7t1Xpxouv Otex a1texa,ec; UAe.c; OL opot 'tO\J 1ti vexxoc; II Ocx 'tl]pouv,ext e.m 1tpoa0hwc; 'tW\I opwv 'tO\J 1texpoll'toc; 1tivexxoc;. 2. LUOXWotaiex/KoAO\I mvexxcxc; 10 E,txhuc; xtvouvou e.1ti 'tW\I XOAW\I B).em Ilpoa07JXl] A. 9) E 'ttxhe.c; 'tW\I µov,eAW\I 7 A, 7B 7J 7f Oex ,01to0Ewu­ v,ext e.!;wuptxwc; ae. ouo exv,i­ One.c; 1tAwpec;, ~Ae1te. 1te.pt­ Owptex 3653 ewe; 3655 'tlJ<; 1tpoa07JXl]c; A.6 1 tcx xex,lj10 picx XOAOU. Tu1toc; B(M), auµcpwvwc; 1tpoc; ,ouc; opouc; axe.oiou ,ouc; OL­ ooµevouc; O'tO 1te.pt0wpt0 3604 'tljc; i:ipoa07JXljc; A.6 ex1totL'tOU­ \l'totc; 7tOAU7tAWpov arxptat\l expµooiexc; expx7Jc;, ~AE7te. 1te.pt0w pto 3673 'tl]<; TTpoa071xl]c; A.6. • 3. Avw,ex,ov mi1tEOO\I exx'tt\lO~OAiexc; XOAOU 2 mSv /h a,lJV e.mcpcxve.ux ,ou xoAou xext 0, 1 mSv /h ae. 1 µhpo ot7t0 'tlj\l e.mcpcxve.tex extJ't7j (BAe1te. 7tEpt0wptex 3653 ECllc; 3655 'tljc; TTpoa07JXl]c; A.6), e.x,oc; 'tlj<; 1te.pm,wae.wc; 7tA7Jpouc; c:pop,iou 01to,e. ,o opto Eivcxt 10 mQv /h O'tl]V e.mcpiive.tcx ,ou xoAou xext µ1tope.i vex u1te.p~ai ,ex 0, 1 mSv /h ae. 1 µhpo ex1to 'tlj\l Emcpiive.tex\l extJ't1j\l (~AE7te. 1te.pt0wpto 3659(7) 'tljc; TTpo­ a07JXl]c; A.6). 4. Mtx,7J Luaxe.uexaicx BAE7tE 1te.ptOwpt0 3650 'tljc; TTpoa07JXljc; A.6. 5; MoAtJ\latc; e.1ti XOAW\I Mlj-Wptaµevcx optex e.!;wuptx7Jc; µo).uvae.wc;: ~/r/xexµl]A7Jc; ,o!;txO'tlJ'texc; ex 1toµ1toi:3,7 B/cm2 (10· 4MCI) 1199 1200 t!> EG>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) <I>uotxov / E;otollEvT)µe.vov ou~<ivwv / q,uotxov !lopwv: 37 B.Jcm (10·3 MCI/CM2) 'AMot ot 1toµ1toi: 37 H/cm2 (10·5 MCijCl\112 ) fLot 1tA7lpEi;; AE1t'toµe.pmi;;, ~AE1tE 7tEpt9wpw 3651 'tTJ<;; ITpoo!l71xT)i;; A.6. 6. Ev6e[;Eti;; (µotpxciptoµot) xoAwv . Tot XOAot !lot µotpx<ipov'tott .;wuptxwi;; xot!lotp<i Xott otVE;i­ 'tT)Aot µE 1:ov: (I) «Timov B(M)» (II) 'tT)V e.v6.t;tv otvotyvwp[oEwi;; 't'Tj<;; otpµo6toti;; otpx71i;; (III) ,:o ~<ipoi;; ,:ou xoAou otv Eivott 1tcivw ot1to 50 XLAto1potµµot (IV) To ,:p[q,uUo ouµ~oAo i;vowµot,:wµe.vo 71 01:otµ1totptoµe.vo O'tO E~W'tEptXO 'tOU otV!lEX'ttXOU O'tO 1tup Xott 'tO u6wp 6oXELOU. 7. 'Enpotcpot µE1:otcpopcii;; ( ot) r tot otVotXoq>otAotLWOT) 'tWV opwv EjXptoewi;; Xott yvwo,:o 1tot710.wi;; - ~AE7tE 1tept!lwpto 2704. (~) To e.npotq,o µe,:otcpopcii;; !lot 1teptAotµ~<ivi;t 'tT)V 1tEptjpot­ cp71v «Pot6tEVEpjEL<;; UAE<;; XOAWV Tu1tou B(M), 7' 7ttvot; 10, ADR», µE 'tTJV ovoµotoiot u1to1potµµLoµivT)V, xott 1:ti;; AE1t1:oµe.­ pmi;; 'tt<;; opt~oµEvEi;; O'tot 7tEpL9wptot 3680 Xott 3681 'tTJ<;; ITpo­ o!l71xT)i;; A.6. (r) A1tott'tOUV'tott 1ttO't01tOLTJ'tLXCX 1tOAU1tAEUpou EjXpioewi;; axe6[ou XOAOU, ~AE7tE mpt!lwpto 36 73 't'Tj<;; ITpoo!l71xTj<;; A.6. (6) E<iv 'tO XOAOV ElVott oxe6totoµe.vov Xot'tCX 1:po1tov WO'tE Vot 7totPEXE'tott OUVEX7I<;; E~otEptoµoi;; 71 E!XV 'tO OALXOV 1tEptExoµevov u1tEp~otivEt 1:ot 3 X 103 A 2 71 3 X 103 A 1, wi;; Ev6dxvu1:ott 71 'tot 3 X 104CI, 01totou6711to'tE 'tOU'tWV ov,:oi;; xotµT)AO'tEpou, 1tOAU 7tAEUpot 1ttO't01tOLT)'ttX!X cpop'tWOEW<;; ot7tott'tOUV'tott EX'tO<;; E!XV T) otpµo6tot otPX71 e;ouow601:710Et 't'T) µe1:otq,opci µe Et6tx71 6tci1:ot;T) O'tO 1ttO't01totT)'ttXO 't'Tj<;; C,XE6[ou XOAOU, ~AE1to 1tEpt!lwpto 3675 'tTJ<;; ITpoo!l71xT)i;; A.6. • (E) Oocixti;; mwcpeAouµe0ot 'IT}<; T)U~T)µEVT)<;; evep1e[oti;; otvci XOAOV 't'Tj<;; Em'tpmoµav'Tji;; ECXII Tj UAT) ElVO(t E\6Lx71i;; µopcp71i;;, • ~AE7tE 1totp<i1potq,ov (6) otvw,:e.pw, ot1tott1:Ei'tott µovo1tAeupov m 01:01tOLT)'tLxov e1xp[oEwi;; C,XE6[ou Et6tx71i;; µopcp71i;; (~AE1tE 1tepL­ !lwpw 3671 'tTJ<;; ITpoo!l71xT)i;; A.6). ( O't) IT po x<illE cpop,:woEwi;; 0 ot7tOO'tOAEot<;; O(j>E lAEt Vot yvwpi­ ~Et O'tt<;; otpµo6tEi;; otpxe.i;; OAWV 'tWII xwpwv 'tWV !ltjoµe.vwv EX 'tT)<;; µE1:otq,op<ii;; xot,:<i 1t"po1:[µ TJOLV 1tpo 6exot1tEV'tE T)µEpwv wi;; AE1t'tOµEpwi;; otvotcpEpE'tO(t O'tO 7tEpt9wpto 3682(2) e.wi;; (4) 't'Tj<;; ITpoo!l71xT)i;; A.6. (~) ITpo 1:11,;; q,op,:woewi;; owu6711to1:E xoAou, o ot1too1:0Ae.oti;; !lot EXEL O'tT)V xot1:ox71 ,:ou oAot 'tot c,xe1:tx<i mo1:01totT)'ttxci E1xpioEwi;;. 8. A1to!l71xw0Tj xm 1tpow!lT)OT) {ot) 0ot 'tT)pouv,:otL otE06711tou o6TjjtE<;; ,:wv mo1:01totT)'ttxwv EjXptOEW<;; 't'Tj<;; otpµo6Lot<;; otpx71i;;. (~) A1to!l71xw0Tj Xott 6totxwptoµoi;; ot7t0 ciUot Emxiv6uvot Eµ1topeuµot1:ot - ~AE7tE 7tEpL9wpwv 3658( 1) 't'Tj<;; ITpoo871xT)i;; A.6. (r) A1to871xEUOTJ XotL Stotxwptoµoi;; ot7t0 XOAot cpapov'tot m-, XE'tot «FOTO» - ~AE7tE 7tEpt0wpto 240 001 't'Tj<;; ITpoo871x7li;; B4 jtot 1tLVotXot 6totxwptoµou. (6) 'Opto 6dx,:ou 0Atx71i;; µE1:otq,opcii;; 1tot ot1to!l71xwoT) - 50 otll!X oµ<i6ot µE 6 fihpot µew;u 'tWV oµ<i6wv - ~AE7tE 7tEpt0wpto 3658(2) awi;; (5) 1:11,;; ITpoo!l71x11i;; A.6. ( E) 0 ot1too1:0Aioti;; !lot EXEL 'tT)p71ou wui;; 1tpo 'tTJ<;; xp71oewi;; Xott 1tpo 't'Tj<;; (j>Op'tWOEW<;; opou<;; 'tWV 7tEpt9wpiwv 3643 Xott 3644 't'Tj<;; ITpoo!l71x7Ji;; A.6. ( o,:) E<iv T) !lepµoxpotoiot Emq,otvE[oti;; ,:ou xoAou u1tEp~otiVEt ,:oui;; 50 ° C U7t0 OXLCXV 'tO XOAOV !lot µE1:otq,apE'tott wi;; 1tA7lpEi;; q,opi:[o - ~Ai1te mpt!lwpw 3602( 4) (~) 1:11i;; TTpoo871xT)i;; A.6. (~) E<iv Tj µfoT) po71 EmcpotVELotx71i;; 8epµo1:111:oi;; ot7t0 EVotll xo­ AOV u1tEp~ottVEL 'tot 15 W /M2 , 1:01:e ,:o xoAov !lot µe1:otcpe.pe1:ott wi;; 1tA7lpEi;; cpop,:[o. , (T)) KoAot et6Lxwi;; 1tpoopt~oµEvot 1/ot em,:pe.1touv ouvex71 .~ot eptoµov - ~AE7tE 7tEpt0wptov 3604(2) 't'Tj<;; ITpoo871xT)i;; A.6 0ot µE-totcpe.pov1:ott µovov u1to 1tA7lpEi;; cpoptio. 9. MEwcpop<i XOAWV (lE ox71µot1:ot Xott 6oxE[ot (ot) dLotxwpLoµoi;; ot7t0 XOAot q,e.pov,:ot E'ttXE'tot «FOTO» , ~AE7tE 1tEpt!lwpto 240 001 't'Tj<;; TTpoo!l71xTj<;; B4 jtot 'tOII 1tL­ VotXot 6tot;(Wptoµou. (~) 'Opw 6dxi:ou OALx71i;; µE1:otcpop<ii; - 50. To opw otu,:o 6Ev tox uu 1tot 1tA 71pE<;; cpop,:io, ecp' 00011 E<XV u1tcipx ouv xoAot Atot 01toto1:71i;; K;l.<ioEwi;; II 71 III 6Ev u1tEp~otivE1:ott o Em1:pmoµEvoi;; otpt!lµoi;; - ~AE1tE 7tEpt9wpwv 3659(5) 'tTJ<;; ITpoo!l71xT)i;; A.6. (r) Avw'tot'tot E1ti1tE6ot otX'ttllO~OAtoti;; jtot ox71µot1:ot Xott µE­ jCXAot 6oxe[ot 1tpoxEtµe.11ou 1tEp[ 1tA1jpoui;; q,op,:[oti 2 mSv/h (200 mrem/h) O'tT)V Emq,civELot 0,1 mSv /h (10 mrem/h) OE 2 µhpot ot1to 'tTJV emq,civuot ~AE1tE 1tEpt!lwpto 3659(7) 't'Tj<;; ITpoo971xT)i;; A.6. E1ttOTj<;; jtot ox71µot1:ot 20 - mSv /h. OE 01tOLot6711to'tE Xotl/Olltxwi;; Xot't(l(A1j­ q,9doot !le.OT) - ~AE1tE 1tEpt!lwpw 3659(8) 'IT}<; TTpoo!l71xT)i;; A.6. 10. ME'totq,op<i EL<; xuµot µe OX7l!J:ot'tot Xott 6oxEiot dEV €X Et ecpotpµonv. 11. ME'totcpopci µE ~U'ttocpopot Xott TANK CONTAI­ NERS Aev EXEL Ecpotpµonv. 12. Emrpotcpe.i;; Xott E'ttXE'tE<;; E1ti OXTJ!!CX'tWII, ~unoq,opwv, TANK CONTAINERS xott 6oxEiwv (CONTAINERS) (~Aim ITpoo871xT)V A9 xott B4) Aoxeiot - E'tLXE'tE<;; 'tWII µ0111:EAWII 7 A, 7B 71 7f xou O'tt<;; 'tEO­ oepti;; 7tAEUpai;;. Ox 71µot1:ot Xott µqciAot 6oxEiot - Emjpotq,ai;; ouµcpwvwi;; 1tpoi;; 'tO µ0111:EAO 't'Tj<;; ITpoo!l71xT)i;; B4, 1tEpt!lwpto 240 010 OE xcillE 7tAEUp!X XotL O'tO 07tto9to ,:o[xwµot 'tOU ox71µot1:oi;; (~AE7tE 1t'Ept 9wpLot 3659(6) XotL 71 500). 13. A1totjOpEUOT) E1ti µtX'tTj<;; q,op'tWOEW<;; BAi1tE 7tEpt0wpto 2700(3). 14. A1toMµotVOT) OX.TJ!!CX'tWII, ~u,:wq,opwv, TANK CO NTAINERS xott 6oxEiwv (CONTAINERS) BAe.1tE 7tEpt9wpto 3695(3) 't'Tj<;; Ilpoo871x7li;; A.6 .. 15. 'AUE<; 6tot't<X;EL<;; ( ot) Atot't<i;eti;; 1tEpi ot'tUXTJ!!CX'tWII - ~AE7tE mpt0wpto 3695(1) 'tTJ<;; TTpoo!l71xT)<;; A.6. (~) A1toMµotvo11 EV ot1tO!l1jXEUOEt - ~AE1tE 7tEpL9wpto • 3695(2) 'tT)<;; ITpoo!l71xT)i;; A.6. 1. AtM1toto1:ii;; ·n.i;; 711:ot: oupcivwv - 233, oup<ivtov 235, 7tAOU'tOVLOII - 238, 1tAOU'tOIILOII - 2 3 9 7tAOU'tO­ VLOII - 241, 71 otot6711tou UATJ 1tEpte.x ouoot OLotv6711tou ,:wv otvw,:apw, EX'tO<; ot7t0 µTj­ otX'ttllO~OAT)llEv q,uotxov Xott E;oto!lEvT)µi-11011 oupcivwv. OL 6tot07totO'tE<;; UAE<;; !lot ot1too1:e.Uo111:ott m[oT)i;; µe 1tA7lpT) 't7jpT)OtV 'tWV opwv 'tOU Evoi;; EX ,:wv illwv mvcixwv, wi;; E116dxvu1:ott 1 tot 'ITJ"' pot 6tEve.p1etotv. 2. ~UOXEUoto[ot/KoAOII Ilivotxoti;; 11 Enxhui;; xtv6uvou e1ti 'tWII XOAWII • ~AE1tE Ilpoo!l71xT) A. 9) Atoto1toto1:71 KA<ioT) I - m­ xhEi;; ouµcpwvotot 1tpo<;; 'tot µo 1/'te.Aot 7 A, 7B 71 7f. • Atot01totO't7I KAciOT) II E'ttXE'tE<;; ouµcpwvot 1tpo<;; 'tot µov-riAot 6B 71 6f. Atoto1totO'tTj KAcioT) III E'tLXE'tE<;; ouµq>WIIW<;; 1tpo<;; 'tO µone.Ao 7f µ011011 E1:txhei;; 0ot 1:01to!lEwu 111:ott E;w1:Eptxwi;; OE 6uo otll'ti 0eui;; 1tAwpii;;, ~AE1tE 1tEpt­ !lwptot 3653 iwi;; 3655 't'Tj<;; Ilpoo!l71x7li;;·A6 1tot Xot'tT)jO­ piot XOAOU. (ot) Ot Xot'tW'tEpw UAE<;; ot opt~oµEvei;; 7tATjpwi;; O'tO 7tEpt0w­ pto 3610 1:11,;; TTpoo!l71xT)i;; A.6 e~ottpou111:ott ,:wv opwv Et6tx71i;; ouoxwotoioti;; ,:ou 1totpov,:oi;; 1tt11otxoi;;: (I) Atoto1toto1:ii;; UAE<;; OE 1tOOO't1j'tot µTj u1tep~ot[vouoot 'tot 15 G. (II) <I>uotxov 71 E;otollEll'Tjµivov oupcivwv otx1:tvo~OA7Jlli11 (IRRADIATED OE 0Epµtxov otll'tt6poto,:71pot. (III) ApotLwµivot 6totAUf.tot'tot u6po1ovou OE 1tEptoptoµivot ouµ1tuxvwµot,:ot XotL 1tOOO'tT)'tE<;;. (IV) Eµ1tAOU'ttoµe.11011 oup<ivwv µE oxt !XIIW 'tOU 1 'tOt<;; EXot­ 'tOII oupotviou-23 5, ,:o 01to[ov 6Ev 1tpi1tEL vot oXT)µot,:i~EL 6t<i'tot ;tv 1tH1µot1:oi;; ECXV µhotUov 71 o;E[6tov. • (V) 'UEi;; StotvEµT)µEvE<;; OXL !XIIW 'tWV 5 G (fpotµµotp[wv otvci o1xov 10 Ahpwv. (VI) Il)..ou,:ovwv oi:otv ELiiott oAt1oupo ,:ou 1 KG otv<i-xoAov Xott O'totV ox t civw 'tOU 20 'tot<; EXot'tOII 't'Tj<;; µci~Tj<;; 1tEptAotµ~CXIIEt 7tAOU'tOIILOII - 239 71 241. (VII) Eµ1tAou1:Loµe.11011 6t<iAuµot 11t1:ptxou oupotvuAiou 1tEpti­ xo11 oupCXVLOV µE OXL !XVW 'tOU 2 'tot<; EXot'tOII OUpCXIILOV - 235. (~) • AUwi;;, 'tot XOAot !lot Eillott ouµq,wvot µE ,:oui;; opoui;; 'tOU ox E6[ou TIJ<;; dLot01toto1:71i;; KAcioEwi;; I, II 71 III ,:oui;; 6t6oµivoui;; O'tot 7tEpt9wptot 3611 iwi;; 3624 't'Tj<;; ITpoo!l71xT)i;; A.6 Xott !lot e.xouv 'ITJV EjXpLotv 't'Tj<; otpµo6toti;; otpx71i;;, oo<ixti;; ot1totmi'tott, wi;; AE1t1:oµEpwi;; otvotcpEpE'tott O'tO 1tEpt!lwpto 36 7 4 'IT}<; Ilpo­ o871x7li;; A.6. <l>EK 104 ECl>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: dEYTEPO) 3. Ay,w,d,o E1tiitEOO otXW.IO~OA.[otc;; XOAOU BA.i1t'E xot,ciMTJAOv 1tlvcxxot. 4. Mtx,iJ ouoxEuotalot BAa1tE 1tEptSwpto 3650 'tT)c;; IlpooSiJx71c;; A.6. 5. MoAuva71 E1tt xoA.wv 8A.E1tE Xot'tMATjAO\I 1tL\lotXot. 6. Ev6E1;Etc;; (µcxpxciptoµcx) xoAwv 8A.a1tE Xot'tCXMTjAO\I 1tlvotxot. 7. 'E1-ypcxcpcx µE,otcpopcic;; ( ot) f tot ot\lotXE(j)otA.otLWOTj 'tW\I opwv 'tTjc;; E1 XpLClEWc;; Xott XOt· \101tOlTJClEWc;; - ~A.altE 1tEptSwptO\I 2704. (~) To anpcxi:pov flE'totcpopcic;; Sot 1tEptAotµ~ci\lEL ,tc;; A.Elt'tOflE· pmc;; 'ttc;; opt~OflEVEc;; Cl'tO\I Xot'tCXMTjAO 1tL\lotXot ,tot 'tT} cpuo71 'tOU 1tEptEXOflEVOU flE 'tT)\I Aa;tv «~totClltotCl'tTJ» 1tpo,otoooµav7111 ,71c;; 1tEptjpotcpTjc;; Xott U1to1potfLfJ,tOfla\lTj\l, (r) M1topouv vex ot1tott,71Souv ma,01tot71,txci µ01101tA.Et>pou iJ 1tOAU1tA.Et>pqu E,xpioEwc;; OXEOiou XOAOU, ~A.altE 1tEptSwpto 3674 ,71c;; IlpoaSiJx71c;; A.6. • (6) Tot axiotot XOAW\I ~LotClltotCl'tljc;; KA.ciaEwc;; II auµµopcpot>­ flE\lot 1tpoc;; 'tO 1tEptSwptO\I 3620 ,71c;; IlpooSiJx71c;; A.6 Sot axouv 1ttO't01totTj'ttXci 1tOAU1tA.Et>pou E,xpiaEwc;; 'tTjc;; cpop,waEwc;;. 'Evot 'ta'tOtO axa5to XOAOU OE\I ot1totmi 1tpo71,ouµav7111 rvwo,01toi71 Clt\l EX'tOc;; ECX\I EtOtxwc;; opl~E'tott Cl'tTj\l a,xpto71 cpop,waEwc;; ,71c;; otpµo6totc;; cxpxiJc;;. ( E) Tot axiotot XOAW\I ~totClltotCl'tljt; KAciaewc;; III Sot ixouv mo,01tot71,txci 1tOAU1tAEt>pou E1xplaEwc;; ,71c;; cpop,waEwc;; EX'tOt; Eciv otpµo6tot cxpxiJ E;ouato6oni 'tTj flE'totcpopci Ot' EtOtxiJc;; Otot,ci;Ewc;; ow ma,01tot71,txo ,71c;; axEoiou xoAou, ~AE1tE 1tEpt­ Swpto 3675 ,11c;; IlpoaSiJx11c;; A.6. ( (l't) Ilpo xciSE cpop,waEwc;; XOAOU ~tot01totO'tTjt; KAciOEWt; III ,o 01tolov ot1tott'tEt 1tOAt>1tAEUpov i 1xptatv ,ou oXEOtou ,ou xo­ A.ou, ~AE1tE 1tEptSwpto 36 7 4 :tTjt; Ilpoa6iJx11c;; A.6, 0 otltOCl'tO­ A.aotc;; O(j)ELA.Et \lot EVTjflEpwaEt 'ttc;; otpµootEt; cxpxic; OAW\I 'tW\I xw­ pwv 'tW\I 6t,oµivwv EX 'tT)c;; flE'totXtVTjClEWt; Xot'tci 1tpo,iµ71atv 1tpo OEXotltE\l'tE TJfLEpwv we;; AE1t'tOfLEpwc;; otvotcpipE'tott Cl'tO 1tEpt 6wpto 3682(2) awe;; (4) ,TJc;; Ilpoa6iJx11c;; A.6. (~) Ilpo 'tTjc;; cpop,woEwc;; OtOUOTJ1tO'tE XOAOU O otltOCl'tOAaotc;; 6ot EXEL Cl'tTJII Xot'tOXTJ 'tOU OtotOTjltO'tE oXE'ttXci 1ttCl't01tOtTj'ttXci Ex1ploEwc;;. • 8. An:o6iJXEUClTJ Xott 1tpow611a11 (ex) Ilpa1tEt \lot 'tTJpOt>\l'tott 01totECl07J1tO'tE 0671,iEc;; 'tW\l 1ttO't0 1totT)'ttXW\I E,xplaEwc;; 'tT)t; otpµo6totc;; cxpxiJc;;. (~) 'Opto OE[xwu OAtxiJc;; µE,otcpopcic;; 1 tot ot1to6iJxEua71 - 50 otvci oµcioot flE 6 fLE'tpot flE'tot;u 'tW\I OfLCXOW\I - ~A.EltE 1tEpt~wpto 3658(2) awe;; (5) ,11c;; Ilpoa6iJx71c;; A.6. (r) 0 .otltOCl'tOA.Eotc;; 6ot EXEt auµµopcpw6Ei fLE ,ouc;; 1tpo 'tTjt; XPTJOEwc;; opouc; ,ou 1tEpt6wplou 3643 ,71c;; Ilpoo6iJx11c; A.6. 9. ME,otcpopci XOAW\I flE OXTJfLCX'tot Xott ooxElot. . (ex) 0cx 'tTjpouv,cxt 01totE06iJ1ton 06711 iEc;; ,wv ma,01tOtT)'tt­ xwv E,xplaEwc; 'tT)t; otpµo6totc;; cxpxiJc;; (~) 'Opto OELX'tOU OAtxiJc;; flE'totcpopcic;;- 50. To opto otU'tO OE\I tOXt>Et ,tot 1tATJpEc;; cpop,lo, Ecp' oaov, ECX\I tmcipxouv XOA.ot ~tot­ ClltotCl'tljt; KA.ciaEwc;; II TJ III, 0 E1tt'tpE1t0flEVOt:; otpt6µoc;; OE\I U1tEp~otL\IE'tott. BAa1tE 1tEpt6wpto\l 3659(5) ,71c;;· Ilpoa6TJXTjt; A6. 10. ME,otcpopci Etc;; Xt>flot flE OXTJflCX'tot xcxt ooxEiot (ex) Ou6Eic;; 1tEptoptaµoc;; ,tot OtotClltotCl'tO UA.tXO fl.!XPt OU\IOA.t- • xwc; 15G (,pcxµµciptot) iJ ,tot OtotMµcx,ot E\l'toc;; 'tW\I opiwv wptaµavou ouµ1tuxvwµcx,oc;; Xott 1tOOO'tTj'tOt;, ~A.a1tE 1totpci,pot­ i:pov 2(cx)(I), (III) xott (VII) xcxt 1tEpt6wpto 3610 'tT}c;; Ilpoo6TJ x11c;; A.6. . (~) ~E\I axEt Ecpotpµo,TJV ,tot XOA.ot ~tot01tCXO'tTjt; KA.a:oEwc;; I TJ II. (r) Em,pi1tE'tott Xot~ci 'tTj\l ~tot01tot01Tj\l Kiciotv III µ011011 ECX\I xot6,qpl~E'tott O'tO 1ttO't01t0tTj'ttXO 'tTjt; otpµoototc;; cxpxiJc;;. 11. • ME'totcpopci flE ~U'ttocpopot Xott TANK CONTAI­ NERS ~E\I axEt EcpotpfJ,OiTJ, 12. Em,potcpic; Xott E'ttXE'tEt; EltL 'tW\I ox71µci,wv, ~U'ttocpo­ pwv, TANK CONTAINERS xott ooxEiwv (CONTAINERS) (~AE1tE Ilpoa6iJxEc;; A9 xott 84). ~OXELot - E'ttXE'tEt; 'tW\I fLO\l'tEAW\I 6A, 6B 71 6f Xott O'ttt; 'tEO· OEptc; 1tA.EUpE~. Ox71µot,ot Xott flE,ciAot ooxElot - Em,potcpic;; auµcpwvwc;; 1tpoc;; 'tO flO\l'tEAO 'tT)t; Ilpoo6TjXT)c;; 84, 1tEpt6wpto 240010, OE xci6E 7tAEupci Xott O'tO 01tia6to ,oixwµoc 'tOU oxijµocwc; (~AE1tE 1tEpt 6wptoc 3659(6) xcxt 71 500). 13. A1toc,opEt>ClEtt; E1tl fLLX'tTjc;; cpop,woEwc;; BAE1tE 1tEpt6wpto 2700(3) 14. A1toA.t>flOCVClTJ OXTJflCX'tW\I, ~U'ttocpopwv, TANK CO NTAINERS X(Xt OOXELW\I 8Ai1tE xot,ciM71Aov 1tivocxcx. 15. 'AUEc;; OtOC'tci;Etc;; ~toc,ci;Etc;; 1tEpi ot'tUXTjflCX'tW\I - ~AE1tE 1tEpt6wpto 3695(1) 'tT)c;; Ilpoa671x11~ A.6. 1. 'TI.Et; Poc0tEVEP1Eic;; t>AEc;; flE'totcpEpo­ flEVEc;; U1t0 EtOtXTj\l OtEU6h11 Clt\l Eciv OEv Eivoct ouvoc,ov vat 't1jp7j60t>\I ot Opot 'tOU OXEOLOU XOAOU TJ 'tTJ<; cpop,woEwc; ot ot1too,0Hc;; 6oc µE,occpipov,cxt U1t0 EtOtx71v OtEU6E'tTjOTJ 71 01toicx 6oc E;ococpotA.i~Et o,t ,o 1Evtxov E1tl1tEOO\I ococpixAEiocc;; OE 6oc EL\l(Xt µtxponpov (X1t0 o, 'tt 6ot Tj'tO ECX\I E'tTjpOt>\l'tO OA.Ot ot LoXt>O\l'tEc;; opot. 8A.E1tE 1tEpt6wpto 3 6 7 6 ,71c;; Ilpo­ o671x11c;; A.6. LTJflELWOTj, ftot (X\lotXE(j)(X• A.otiWOTJ 'tW\I opwv 'tTj<; qxpi­ OEW<; X(Xt i\lWO't01tOt710EWt:;, ~AEltE 1tEpt6wpto 2704. Ilivocxocc;; 12 E,tXE't'tEc;; Xt\lOt>\IOU EltL 'tW\I XOAW\I 8Ai1tE Ilpoo671x71 A. 9) E'ttxhEc;; ouµcpwvwc;; npoc;; 'tO fJ-0\l'tEAO 7r 6oc 't01t06E­ 'tOt>\l't(Xt E;w,Eptxwc;; OE Mo (XV'ti6Enc;; 7tAEUpEc;; EX'tO<; (X\I IXMWt:; 1tpO~A.~1tE'tOCt U7t0 'tOU, 1ttO't07tOtTj'ttXOt> 'tTjt:; ocpµo­ Ototc;; ocpx71c;;. BAanE 1tEpt6wpw 3655(1) 'tTjt:; Ilpoo671x11c;; A6. AvocxEq>otA.cxlwoTJ opwv qxploEwc;; xott 1tpoEt601totiJ0Ewc;; (X) • E ,xptOTJ UAW\/ u5txiJc;; fLOpcpiJc;;, Xott oXEOLW\I XOAW\I AvnXELfLE\10\1 E,xpioEwc;; Apµo6toc cxpx71 'tTJ~ 01toiocc; (X7t(Xt'tEl'tott TJ e,xpto71 1 • n.71 Et0tx71c;; µopcpiJc; EX'tOt:; Xwpoc 1tpOEAEUClEWc;; 'tW\I EtOW\I EXEL\IW\I. 7tOU 2 3 4 5 opi~O\l't(Xt O'touc;; I11VotXE<; 3 X(XL 4 Tu1toc;; A, LSA XOCt LLS. OuoEµiot Ex,oc;; ECX\I ~o 1tE ptEXOflE\10 EL\l(Xt 0t(X07totCl'tO xoct OEV E;octpEhoct ,wv X(X'tlX 'tO 1tEpt6wpto 3610 ,71c; Ilpoo671x71c; A6 opwv 7tEpi 0t(X07totO'tOU: Xwpoc 1tpOEA.Et>OEWt:; Tu1toc; B (U) Xwpoc 1tpOEAEUOEWc;; Tu1toc;; 8 (M) Xwpoc 1tpOEAEUOEWc; X(Xt ~t(X07t(XO'tci XO.ACX OA.Ec;; Ot xoc6' 000\1 xwpEc; LXEOtoc xoA.ou ouµµopcpou- Ou6Eµicx flE\lot 1tpoc;; 'tO 1tEpt6wpto 3620, 3623 71 3624 'tTjt:; Ilpoa6TJxrjc; A6 I:xiotoc XOAOU ouµµopcpou- Xwpoc 1tpOEAEUOEWt:; flE\l(X 1tpoc;; 'tO 7tEpt6wpto 3616 iJ 3622 'tT}t:; flpo oS71x71c; A6 • 0Aoc 't(X IXM(X oXE0t(X XOAW\I Xwpoc 1tpOEAEUOEWt:; X(Xt OAEc;; 01 xoc6' 000\1 xwpEc; I:71µEiwa11: «Xwpoc 1tpOEA.Et>OEWt:;• (X\l(X(j)EpE't(Xt O'tT} xwpoc (X7t() 't7jll 07t0L(X 1tpo71A6E 'tO axioto. KoA.(X 'tW\I Otot07totO'tW\I XACXOEW\I Eµ1ti1t'tOU\I E1tfo71c; OE 1-1-iocv 71 ill7111 ,wv ocvw,ipw xcx,111optwv 2, 3 71 4 oXEOiwv xoAwv X(Xt Ot oXE'ttxic; Otoc,ci;Etc; iaxuouv EltLOTJ<; rt' otU'tlX. 1201 .2704 1202 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) (P) 'Eyxpta71 <Dop,waEwv xext ITpoEtoo1to[71a71 KoAov Apµo6tex TipoEt001tOi7J07J. xcic8£ Apxri 't7]c; cpop,waEwc; 01toiexc; ex1text ,Ei,ext 7J Eyxpta71 ytex XIX8E cpop 'tW07J 1. Tu1toc; A, LSA Ouoe:µiex Ou6Eµiex xoct LLS 2. Tu1toc; B(U) Ouoe:µ[oc Xwpex 1tpoEAEUOEwc; xext b).e:c; ot xoc8' oobv xw­ pEc; o,ocv 1tEptE)(oµEvov U7tEppexivEt 'tOC 3 x 103AI 7J ,ex 3 X 103 A'.!: we; EVOE1xvu,ext 7J 'tex j X 104 CI, OtOU 61j1tO'tE 'tOU'tWV ov,oc; xocµ71Aw,ipou 3. Tu1toc; B(M) ~uvExwc; e:!;exEpt~o­ µEvoc; Xwp9( 1tpoE- Xwpex 1tpOEAEUOEWc; XOCt AEUOEWc; xext OAEc; Ot icex8' o6bv xwpEc; oAEc; ot xex8' o6bv xwpEc; 4. Tu1toc; B(M) - Xwpex 1tpoe:- Xwpex 1tpOEAEUOEWc; xext M71-auvexwc; E!;cxEpt- AEUOEWc; xext OAEc; Ot xcx8' ooov xwpEc; ~oµevoc; OAEc; Ot xex8' oobv xwpEc; O'tCXV 'tO 7tE­ ptE)(OfLEVOV U7tEppcxiVEt 'tCX 3 X 103A1 ii 3 X 103A 2 , wc; EVOe[xvu­ 'text ii 'tCX 11.1 X 102 TBq (3 x 104CI, OtOU 6ii1to:tE ,ou­ ,wv bv,oc; X,CXfL7JAW'tE­ pou. 5. Lltexa1tOCO't(X KoAex Lltexa1tcxa,71 K)..cic- OuoEµiex. ate; I Ouoeµicx Atcxa1tCXO't'Yj KAcx- KoACX auµ- Ou6eµiex EX'tO<; EIXY op[ atc; II µoP,cpouµEvex ~next a,71v eyxpta71 cpop 1tpoc; 1tEptBw- 'tWOEW<; 't'T)c; expfLOOtcxc; pto 3620 't'T)c;expx.71.;;. At.:xa1tcxa,71 K)..cic­ atc; III ITpoaBiixTJc; A6 µovov: Xwpcx 1tpoe­ )..e:uaEwc; xext OAE<; ot xexB' o6bv X,WpEc;. Xwp.:x 1tpoE­ AEUOEWc; XCXt OAEc; ot xcxB' ooov xwpEc;. Xwpcx 1tpoe:AEUO£Wc; xext OAEc; ot xcxB' ooov xw­ pEc;. 6. KoAex U7t0 't7JV Xwp.:x 1tpOE- Xwpcx 1tpOEAEUOEWc; XO(t E1ttcpuA.:x!;71 'tTjc; fLE'tCX-AEUOEwc; XCXt OAEc; Ot x.:x8' oMv xwpEc;. ~'Opcicc; pocae:L EtOtXTjc; OAE<; Ot xex8' OtEBE,iiaEwc;. o6ov xwpEc; L7lfLELW07J: ITpo 't7)c; cpop,waEwc; XOAOU Tu1tou B(U) 'tO 7tEptE­ XOfLE\10 ,ou 01toiou u1te:p~cxiVEL ,.:x 3 X 103 A 1 7J 3 X 103 A2, we; Ev6e:1xvu,ext, ii ,ex 3 X 104CI, otou6ii1to,E ,ou,wv bv,o.;; xcx­ µ 7lAW,ipou, ytex 1tpw,71 cpopcic, o cx1toai0Aiexc; ocpEiAEt ~ex E!;~­ acpexAtaEt b,t exv,[ypexcpex xcic8E t~X,UO~'toc; 1tta,01tot71-ct~ou expµo 6texc; exp)(7lc; excpopwv,oc; 'tO axe:ato E;(OUY U1tOP~7JBEt O't'l)Y exp­ µo6tex cxpx 7I 'tWV X,WpWV EX:LVWV eu; 't1jV e6excpt x7lY 7tE~tcpEpEtexV 'tWV 07t0LWV 1tpoXEt'text 'tO XOAOV vex p.nexcpepBEt, Oc; xwpcx 1tpo­ EAEUOEW<; exvexcpe.pE'text 7J xwpex CX7t0 't7JV 01toiexv 1tpo71A8E T) cpop­ 'tWatc;. Kb)..ex 'tWV 6texa1texa,wv XAIXOEWV EfJ.7tL1t'tOUV mlaT)c; Et<; 't7lV µ[exv 71 'tTJY IXAATJV E1ttXECj)CXA[6ex 'tOU 1texpov,?c; mvexxex. xext ot crx ei:txic; 6tex,cic1;Etc; ix ouv rn[aT)c; e:cpexpµoyTjV Et<; exu,ex. 2705 2799 KAALH 8 AIABP.QTIKE~ O°fLIEL 1. Kex,cxAoyoc; ouatwv (1) ME,cx!;u 'tWV OUOtWV xext Et6wv 7t0U XCXAU1t'tOV'text ex1to 'tOV 2800 'tL'tAO 't'T)c; KAcxaEwc; 8, 1, oaEc; ocvcx,pcxcpov,ext O'tO 1tEptBwpto 2801 71 Excppcic~ov,cxt ex1tb auUo1txo ,h)..o ,ou t6iou 1te:ptBw p[ou, U7tOXEtV'tCXt O'ttc; 6tcx,cx1;Et<; XCXt opouc; 1t<lU EX'ti8EV'tCXt O'tex 1tEpt8wptoc 2800 (2) awe; 2822 XCXt O'ttc; Otex,cx!;Etc; 'tOU 1texpo v,oc; TTcxpocp,iiµcx,oc; xext Ticxpcxp,71µex,oc; B. Tim OE Bewpou v,cxt we; ouaie:c; xcxt Ei67J 't'T)c; ADR 2. Oua[Ec; 't'T)c; KAcxaEwc; 8 (1tA7JV 'tWV OUOLWY 'tWV 6, 24 XCXL 25) 1tOU 'tCX!;LYOfJ.OUY'tOCL O'tOC Otcxcpopcx EL07J 'tOU 1tEptBwp. 2801, Bex 1tpi1tEt voc cxviixouv aE µ[ex cx1to ,tc; cxxoAouBEc; op.cx6Ec; 1tou x cxpocx,11p[~ov,cxt µE ,o 1pcxµµcx (A), (B) 7J (C), cxvaAo1cx µE ,o PcxBµo Otcx~pw,tXO't7J'tOc;: fpcxp.µcx (A): E!;cxtpmxcx Otcx~pw,Lxic; fpcicµµcx (B): Lltcx~pw,txic; fpcicµµcx (C): EAcxcppcx OLCX~pW'tLXEc;. ·o,cxv, aexv OC7tO'tEAe:aµex 1tpoaB7JXW\I, oua[e:c; 't7J<; KAcxae:wc; 8 1tEpvouv OE XCX'tTjjOp[e:c; OtcxPpw'ttXO't1j'totc; CXMEc; OC7t0 EXEL\IEc; O'tL<; 01tOLEc; CX\17IXOUY Ot oua[Ec; 1tOU xcxBopi~OV'tCXt O'tO 1te:pt8wpto 2801, exu,cx ,ex µ[ jfLCX'tCX ii OLCXAUfLCX'tex Bcx 1tpi1tEt vcx ,cx!;tvoµou­ \l'text O'tCX Eio7J XCXL O'tCX <ji71cp[cx 7t0U CXViiXOUV ~CXOEL 'tOU 1tpCXjfLCX'tt­ XOU ~cxBµou OLCX~pW'ttXO'tTj't<Xc; 'tWV. 'O,cxv, aocv cx1to,eAe:aµcx 1tpoaB71xwv, ouaie:c; 't7]c; KA0taEwc; 8 1te:pvouv ae: xex,71,opicx 1tou EX,EL a71µelo cxvcxcpAE!;Ewc; xcic,w ,wv 21 ° C, ,cx µi1µcx'tCX 71 OtCXAuµcx,cx cxu,Ot Bcx 1tpE1tEt vex ,cx!;wo­ µouv,ext a,cx exv,ia,otx .:x d6Tj 71 <jiTjcplcx 't'T)c; K)..cicaEwc; 3, )..:xµpcx­ voµiv71c; u1t' o<jity 't7Jc; 6t.:xppw'ttXO't1j'tlXc; 'tWV. ·o,.:xv, a.:xv 0(1t0'tf.AEOfL.:X i:cpoaB71xwv OUOtW\I 't7Jc; KA0taEwc; 6.1, ouaiEc; 't7Jc; K).cicaEwc; 8 CX7tOX'tOUV U1tEpox.71 a,tc; ,o!;txec; tOLo,71,e:c;, ,.:x µ[yµcx,cx ii Ot.:xAuµ.:x,cx cxu,cx Bex ,cx!;tvoµouv,ext a,.:x .:xv,la,otxex Eio7J xext <ji71cpicx (1p0tµµ.:x,ex) ,Tjc; KA0taEwc; 6.1. (2) ft.:x w;; CX1tCXt't7IOEtc; OUOXEUO(OL.:Xc; 'tWV mptBwp[wv 2805(2), 2806(2) x.:xt 2807(2), ouaiEc; 71 µi1µ.:x,.:x ouatwv µE a71µE[o ,71!;Ewc; 1tcxvw ex1to 45 ° C, 8Ewpouv,.:xt aexv a,Epe:cic. (3) Llt.:xPpw,txcx EucpAEX'tO( u,pcx fLE a71p.Eio .:xvexcpAe.!;Ewc; x0t,w .:x1tb 21 ° C, Ex,oc; wptaµivwv o!;ivwv exAex1ovwv ,71c; l . 0 'tttAoc; TIJ, KAiioEwc; 8 xi:v,uitm ouoiec; ot oitolEc; f'• X'1f'LX11 8pii01) . 1tpoo/3iiUouv ,mBT)AtOtxouc; ,o.ouc; (8ipf,LOt, f3A•woyovouc; 11 ocpBi:v,f,loUc;) f'E .ouc; oitoloui; <p;(OV'tOtt OE E1t0tcp11 ""'' ouoiEc; o, oitoiec; o• 1t•pi1ttWOT) 8t0tppo11, EtVOtt tx0tvic; v Ot /3Aii<j,ouv 11 VOt X0t't0ta-tpi<j,ouv <XAAOt •f,litOpEUf-LOt'tOt 11 ""' (,lio0t f,l•­ 't0t<popiii; ""'' itou f'ltopouv e1t<o11i; v0t 1tpox0tAiaouv ""'' iiU,c; x0tt0tatpocpii;. 0 'tttAoc; Tij<; KAiioEwi; 8 xi:v,umot EitiOT), ouoi<c; itou "XT)f'Ottt~ouv 8t0t/3pwttxri uypo µovo 1t0tpouol<X u80ttoc;, 11 lt0U 611µwupyouv 8,cc/3pwttxouc; <Xtf-LOU<; 11 oµi­ X"'1 Eltt it<Xpouaicc cpuat0Aoy,x11c; uyp0taicci; tou 0tipoc;. • A1toual0t iiUwv 8ox,µ0to,wv, '1 8,cc/3pwttx11 8pii01) µitopei voc 1tpoo6,opi~•­ 't<Xt µ• lt!tp<XfL<X'tOt tlti ~wwv. OuoiEc; itou itpoxi:v,ouv •µcp0tv11 vixpWOTJ tou 8Epf,L<X ttxou tatou ato OTJf'ELO Elt<X<p11, 0t<XV oox,µii~OV't<Xt ""' 0t8lx,ou 0Epf-LOt'tO<; ~wou Elti XPOVtX11 1t•pio80 owe; 4 wpwv, EiVOtt ouo«i; 'tTj<; oµii8oc; (C). OuoiEi; ot oitoiEi;, Evw 8ev tivcu <ltLXtv8uv<c; ytoe ,ov eit,BT)At<XX0 to'to, f-Llt0· pouv VOt 8,ccf3pwoouv xiiAuf30t 11 i:v,ouµlv,o, ELV<Xt !lti<Tfj, ouoi«; TIJ, Of-L<Xlloi; (C). OuatE<; lt0U itpoxi:v,ouv •µcpccv11 VEXPWOT) 't0U 8tpf'Ot'tLXOIJ tO'tOIJ G't0 OTjf,l<iO tlt<X'l'11• o't<XV 80,uµccotouv OE iiB,x,o 8ipµcc ~wou ""' 1t•p,08ou itAiov twv ,p,wv AElt'tWV xcc, iwc; 60 Arn.ii, ttVOtt ouoi•,; 'tTj, oµii8o,; (B). ·m •• OUGtE<; XetAUlt't0f-LEYE<; Otlt0 t0V 'tt'tAO tT),; XA<io•wc; 8, o, OltOtE<; <tVOtt iteptaoonpo 11·,ccf3pw,LXic; ccito "'• ouotE<; TIJ<; of,L1X8o,; (B), ,ivcc, ouoi<c; Tij, Of,l<X 80,; (A). 2. f tOt tt,; ltOO0'tTj'tE,; OUOtWV lt0U <XV0typ<XtpOV't<Xt Ot0 1tEpt8wpt0 2801 X<Xt lt0U 8.- Ult0XEtV't<Xt Otte; 8,cctdtl;«c; 'tTj<; lt<XpOUOTJ<; KA<io•w,;, ., .. G't0 it<Xpov Ilcc­ piipTijfLOt •in ow Il0tpiip'tTjf'Ot B, (,Aim it,p,Bwp,o 2801cc. E<DHMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 1203 36 °. (B), ELVIXL ouoiEc; 'tT)<; KMau»c; 3 (/3Ai1tE 7tEpL0wpto 2301, 21 ° iwc; 26°). ( 4) ~L0t/3pww1.ic; ouoiEc; µE µE10LATJ 'to1;LXO'tT)'tOt O'tT)V EL 01tvo71, 01twc; 1tpoo6topi~E'tlXL O'tT)V umioT)µdwoT) 1 'tOU 7tEpL 0wpiou 2600(1 ), EiVOtL ouoiEc;; 'tT)<; KAcxoEwc;; 6.1 (/3AE1tE 7tEpL 0wpto 2601). (5) OL xTJµLxoi 0tO't0t8dc;; ouoiEc;; 'tT)c;; K)..ixoEwc;; 8 80t 1tpi1tEl VIX yivOV'tlXL OEX'tEc;; )'Lilt µE'tOtcpopix µovo IXV ixow AT)cp0Ei 'tilt XOt­ 'tOLAATJAOt µhp0t 1tpOATJq>Ewc;; 'tT)c;; E7tlXLV01JVOU Ot7tOOUll0EOEWc;; 'tWV TJ 7tOAUµEptoµou )(l)t't(X 'tTJ µn0tcpopcx. fLOt 'tO 0)(07t0 OtU'tO, 80t 1tpi1t1,L lOt0tinp0t VIX E1;0tocp1XAi~E'tlXL O'tL 'tilt ooxEiOt OEV 1tEpti­ xouv 01tot0t6711to'tE ouoi0t 1tou µ1topEi v0t 1tpox1XAEOEL 71 E7tl'tOtXU• vat 'tt<; OtV'ttOpcxoEtc;; OtU'tec;;. (6) To OT)µEio 0tv0tcpAi!;Ewc;; 1tou 0tv0tcpipE't0tL XOt'tW'tepw 80t 1tpE1tEl VIX X0t8opi~E'tOtt 1)-E 'tOV 'tp07t0 7t0U 7tEpL)'p1X(j)E'tlXL O'tT)V Ilpoo8iix71 A.3. IIAPATHPHLH: AxoµT) )(Ott O'tlXV x0tµµi0t ouoi0t OEV 'tOt!;t- 280] voµEi'tlXL U7t0 'tilt q>T)cptOt (A), (B) 71 (C) 'tWV OLOtcpopwv EtOwv·, ou OLE<;, Ot0tAuµ0t't0t, µiyµ0t't0t XIXL 1t0tp0tO)(EU1X0µ0t'tOt µ1topouv VIX 'tOt/;LVOµOUV'tOtl U7t0 'tlX q>7Jcpi0t IXU'tot, ouµcpwvOt µE 'tOt Xpt'tTjptOt 7t0U EX'ti0EV'tlXL O'tO 7tEpt0wpLO 2800. A. 'O!;tvac;; ouoiEc;; Avopr0tv0t o!;i0t 1. 0ottXO o1;u XIXL 1t0tpoµotEc;; ouofac;, 07tW<;: 0t) xpwµo0EtlXO o!;u, 'tpt!;ii6to 0Eiou, OLEUM (x0t1tvi,ov 0EttXO o!;u ). /3) OtAXUAo-oouAcpovtxcx XOtt 0tpuAo-oouAcpovLXOL o1;i0t 1tEpLE· XOV'tOt 1tEptoOO'tEpo Ot7t0 5% EAEu0apou 0utxou o1;foc;;, 0u'ix6 o1;u, XOt'tOLAOl7t0t 0Etfaou o1;foc;;, UOIX'tl)(IX Ot<XAUµOt'tOt OL0EtLXWV, VL'tp00EtlXO o!;u, LAU<; µ0Au/36ou 1tEptixouo0t 0Ett)(O o!;u .. (C) ... ilAP ATHPHLEiL: 1. I)..uc;; µo)..u[36ou 7tEptEXOUOOt 0ELlXO o!;u Al)'W'tEpo IX7tO 3% EAEU0Epo o!;u ELVIXL ouaiOt 'tT)c;; KAOLOEW<; 6.1. (/3AE1te 7tept0wpLo 2601, 63° (C)). 2. Ahu)..o-oouAcpovLxcx XIXL 0tpuAo-aou)..cpovLXOL o!;i0t, 1tepti­ XOV't0t 'tO 7t0AU 5% EAEu0ipou 0EL'ixou o!;foc;;, ELVCtL OUOtEc;; 'tT)c;; 34°. 2 ° N L'tpt1'0t o!;i0t, 61twc;: 0t) Vl'tplXO o!;u 1tEptEXOV 7tAEOV 'tOU 70% EAEU0ipou o!;foc;;, Epu0po XOt7tVL~OV VL'tptXO o!;u. • /3) VL'tpLXO o!;u mptEXOV 'tO 7tOAU 70% x0t80tpou o!;foc;;. 3 °. Miyµ0t't0t 0tvopycxvwv o!;awv, E1;0tLpEOEL 'tOU u6pocp0opt­ xou o!;foc;;, 01twc;;: 0t) µi1µ0t't0t 0EttXOU o!;foc;; µE 7tEpLOOO'tEp0 Ot7t0 30% Vt'tptXO o!;u. /3) µiyµ0t't0t 0EtlXOU o!;foc;; µE 30% 'tO 7tOAU x0t80tpou Vt'tpL­ xou o!;foc;;, µi-yµ0t't0t 0EtlXOU o!;foc;; µE uopox AWptxo o!;u, µiy­ fllX'tOt VL'tptxou o!;foc;; {1tEptiXOV't0t 'to 1toM 30% HN03)µE o!;ELXO o!;u XOtl cpwocpoptXO o!;u. .• • 1. Mi,µ0t't0t Vt'tptx.ou o!;foc;; µE uopox AWptxo o!;u OEV 80t -yi­ VOV'tOtl OEX'tOL "(tilt flE't0tcpop0t. 2. Miyµ0t't0t )(0t'tOtAOl7tWV 0EtlXOU XOtl Vt'tptxou o!;foc;; 7t0U OEV Ot7tOVt'tpw07JXOtV, OEV "(lVOV'tOtl OEX'tlX )'lilt flE'tOtcpopcx. 4 °. ~llXAUflOt'tOt U7tepx Awptxou o!;foc;: /3) Yo0tnxdt OllXAtlflOt'tOt U7tEPX AWplXOU o1;foc;; 1tEptEXOV'tOt 'tO 1toM 50% x0t80tpou o!;foc;;. IIAPATHPHLH: Y60t'tLXOL OtlXAUµOt'tOt U7tepx AWptxou o!;foc; 1tEptEXOV'tOt 1tepto­ oonpo Ot7t0 50% IXAAOL 'tO 7t0AU 72.5% x0t80tpou o!;foc;; dv0tt ouoiec;; 'tT)c;; KAcxoewc;; 5.1 (/3AE7te 7tEpt0wpto 2501,3 °). l\t0tAuµ0t'tOt 1teptEXOV'tOt 7tAEOV 'tOU 72,5% x0t80tpou o!;foc;; OEV yivoV'tlXt "(tilt µe'tlltcpopix. To 0tu'to LOXUEt XOtt )'Lilt µ(yµ0t't0t umpx AWptXOU o!;foc; µE 07tot001j7tO'tE u-ypo 7tA TJV vepou. 5 °. l\t0tAuµ0t't0t 0tA01ovtoiwv u6po16vou (µa i;!;0tipeo1J 'to u6pocp0opLXO o!;u ), 61twc;;: . /3) 6t0tAuµ0t't0t u6po/3pwµtxou o!;foc;, 0t1XAuµ0t't0t uopox)..wpt­ xou o!;foc;;, OlOtAUµOt'tOt tOptwOtXOU o!;foc;;, UOOt'tL)((X Ol1XAuµ0t'tOt OUOtWV 'tT)c;; 1t1Xp0typ, 21 XOtl 2 2 (/3) µE E!;0tipEOT) 'tilt UOOt'tlXOL OtlXAUµOt'tOt X AWptouxou OtAouµtviou )(Ott 'tilt UOIX'tl)((X OtOtAuµIX'tOt /3pwµwuxou IXAouµtviou. r) uoixnxcx oL0tMµ0t'tlX ouatwv 'tTJc; 1t0tp. 22 (r), u60t'ttxcx OllXAUµOt'tOt /3pwµtouxou IXAouµtviou, UOOt'tl)((X OtOtAUµOt'tOt XAW­ ptouxou 0tAouµtviou. TIAPATHPHEH: TO /3pwµwuxo uoporovo XOtl X AWptouxo u6poyovo EtVOtl ou­ oiec;; 'tT)c; KAixoEwc;; 2 (/3Ai1tE 7tEpt0wpto 2201, 3 ° (AT)x0tt 5 °). 6 °. 'Avuopo u6pocp0optx6 o!;u (cp0oplouxo uopoyovo), UOOt­ 'tlXOL OtOtAUf.1.0t'tOt u6pocp0optxou o!;foc; 7tEpLEXOV'tOt 7tAEOV 'tOU 85% cxvu6po u6pocp0optxo o!;u. IIAP ATHPHLH: r lilt 'ttc;; ouaiEc;; OtU'tE<; 1tpo/3AE7tOV'tlXL XIXL Ecp0tpµo~OV'tOtl ElOl­ xic;; ouv871xi;c;; OUOXEUOtoiEc;; (/3Ai1tE 7tEpt0. 2803). 7 ° . IX) UOOt'tlXIX OLOtAUµOt'tOt u 6pocp0optxou o!;foc; 1tEptEXOV'tOt 'tO 7t0AU 60% IXAAIX 'tO 7t0AU 85% dtvuopo u6pocp0opLXO o!;u, µiyµ0t't0t 0tvop1cxvwv o!;iwv µa uOIX'ttXIX OLOtAUflOt'tOt u6pocp0opL­ x.ou o!;foc;;. /3) UOOt'tLXIX OLOtAuµIX'tOt u6pocp0optxou o!;foc; 1tEpLEXOV'tOt 'tO 1t0Au 60% 0tvu6pou u6pocp0opLxou o1;foc;. 8 ° . ~LOtAuµOt'tOt UOpo/30tpocp8opLXOU o1;foc;: /3) l"OOt'tL)((X OlOtAUfllX'tOt u6pocp0optxou o!;foc;; 7tEplEXOV't0t 'tO 7tOAU 78% x0t80tpou o!;foc;;. IIAP A THPHLH: ~LIXAUµOt'tOt u6pocp0opLXOU o!;foc; 1tEpLEXOV'tOt 7tAEOV 'tOU 78% x0t80tpou o!;foc;; OEV rivoV'tlXL OEX'tOL )'Lilt µn0tcpopcx. 9°. /3) Yopocp8opL01tuprnxo o!;u (H2SiF6). 10 ° . Aomdt cp0opLo - o!;i0t, 01twc;: • 0t) cp0oplo - oouAcpovtxo o!;u /3) 0Lcp0opto - cpwocpopLXO o!;u (cxvu6po), cp0opto - cpwocpopLXO o1;u (otvuOpo), E1;0tcp8opto - cpwocpopLXO o!;u. 11 ° . Aomdt 0tvopr0tv0t o!;i0t, 01twc;;: IX) OEATJVLXO o!;u /3) 0t0tAuµ0t't0t XPWfllXOU o1;foc;;. IIAP ATHPHLH: TO cxvu6po 'tpto!;EtOto XPWµiou EtVOtL ouoi0t 'tT)c;; KAcxoEwc;; 5.1. (/31.i1tE 1tEpt8wpto 2501, 10°). "() X1.wpo1tAOt'tl\lLXO o!;u, cpwocpoplXO o!;u. Avopy0t110t OtAoyoviOtOt, o!;LVIX OLAOt'tOt XIXL OLAAE<; OtAorovwµi­ llec; ouoiEc;;. 21 °. Yrpix IXAO)'OVtOLOt X.IXL OLA.Ace;; U)"pic;; OtAoyovwµEvEc; ou­ oiEc;; (1tAT)II 't(l)V cp0opLouxwv E\IWOEWV), Ol 07tOiEc;, OE E1t0tcp71 µE uypo 0tEp0t 71 llepo EXAUOUV o!;tvouc;; Ot'tµouc;, 01twc;: 0t) x1.wpooouAcpOVLXO o!;u (SO (OH) CL), XAWptouxo XPW­ fl.UALO (o!;ux)..wpwuxo xpwµLo) (CR02CL 'OLXAWptouxo 0Lo0. 0Eio (S2CL2, XAWptouxo Olo!;Eioto 0.iou (SO;>..CL2), XAWptouxo o1;.i6to 0eiou (SOCL.)?, OtXAWpLouxo 0Eio (::;CL.t' 'tE'tPOtXAW­ pLouxo /30tvcx6to (VCL4), 'tpL/3pwµwuxo /3opLo (HBR3). /3) XAWptouxo 1tupooouAcpoupu)..to (S205CL 'cxvuopoc; XAW­ pLouxoc;; X.Otooinpoc;; (SNCL4, XAWptouxo iELOcpwocpopuAlO (PSCL~, o!;uxAwpLouxoc; cpwocpopoc;; (x)..wpwuxo cpwocpopuALO, POCL3J, o!;u'tpLXAWptouxo /30t11cx6to (VOCL3, 7tEV'tOtXAW­ ptouxo OtV'tLflOIILO ( SB CLS XIXL fl.TJ UOOt'ttXot Ot0tXuµ0t'tOt 7tEV'tOt­ XAWpLoUxou Ot\l'ttµoviou, µovoxAwptouxou tw6iou (ICL), 'tE· 'tPOtXAWpLOuxou 1tupL'tLOU (SiCL4, 'tE'tPIXXAWptouxou 'tt'tlXVtOU (TiCL4), ,pt/3pwµwuxou cpwocpopou (PBR3), 'tPLXAWptouxou /30U'tUAO-XIXOOl'tEpou (C4H9SN CL3), 'tptxAwptouxou cpwocpo­ pou (PCL ). IIAPATHPHLEIL: 1. 0 1teV'tOtiiOpLxoc;; XAWptouxoc; XOtooinpoc;; dv0tt ouoi0t 'tTj<; 1t0tp. 22 ° (y). 2) Y60tnxdt OL0tAuµ0t'tlX 'tW\I ouotwv 't'J)c;; 1t0tp. 21 ° ELVOtt ou­ oiEc;; 't'T)c;; 1t0tp. 5 ° (/3). 2 2 ° . L'tEpccx OtAO)"OViOtOt XOtt iliac; OtAorovwµavEc;; ouoiEc; (1tA7lll 'tWV cp0op(ouxwv E\IWOEWV), OL 01tOiec; OE E1t0tcp71 µE urpo 0tEp0t TJ vapo EXAUOUV Ot'tfl.OUc;;, cmwc;;: /3) dtvuopo /3pwµwuxo 0tAouµivto (AL BR~), cxvu6po XAw­ ptouxo IXAouµivto (AL CL3), o!;u/3pwµwuxoc;; cpwocpopoc;; (POBR3), 7te\l'tOtXAWptouxoc;; cpwocpopoc;; (PCL5), 'tPLXAW­ pt0uxo Otll'tLflOVlO (SB CL3), µiyµ0t't0t ~PLXAWptouxou 'tL'tlXVlOU, (.lTJ 1tupocpop0t. IIAP A THPHLH: To E!;OtiiOpLXO /3pwµwuxo IXA.ouµivto, 'tO a1;ixii6ptxo XAW- • ptouxo OtAouµivto )(IXL 'tO µovoiiOpLXO XAWptouxo OtAouµivto OE\/ U7tOXELV't0tL O'ttc;; OtOt'tOL!;ELc;; 't'J)c;; ADR. )") x1.wpwuxoc;; 1:pto8EY7lc;; OlOT)poc; ('tPLXAWpLouxoc;; oi67Jpoc;; ( cxvuopoc;) (F ecl3), 1tEV't0tiiOpLxoc; XAWptouxoc; XOtooinpoc;; (SN CL4.5Hp), XAWptouxoc; q>EUO!Xp-yupoc; (ZN <:;L ) 7tEV'tOtXAW­ ptouxo µo)..u/360tivto (Mo cl5), 'tE'tp0tx )..wptouxo ttpXOVLO (ZR CL4), 'tPLXAWptouxo /30tvdt6to (VCL3)• • 1204 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) TTAP ATHPH:EEl:E: 1. 0 E!;IXiiOptxoc; x},wpLouxoc; ai671poc;; OEV \lltOXEL'tlXL CJ'tlc; OLIX'tlX!;Etc; -c71c;; ADR. 2. YolX'tlXIX OtlXAUf!IX'tlX 'tWV OUCJtWV 'tTjc;; 22 ° EiVIXt ouaiec;; 'tTjc;; 5 o • • . S • ll " • !: • I> ll " IX 23 °. 0ettXIX IXAIX'tlX 7tEptEXOV'tlX urnxo o.,u XIXl ulUELLX IXAIX'tlX oitwc;;: f,) 6tllet'ixo IX(J-f!WVLO, 611let'ix6 XIXALO, 6~0EttXO .. V~'tPL? XIXL lleL'ixoc;; fLOAU~ooc;;, 7tEptEXOV'tlX 3 % XIXL ltAEOV -~E~tX? o!;u. r) 6t8u'ixo 0 1XµµwvLO, 618et'ix6 XIXALO XIXt 6t0rnxo VIX'tpLO, ltE­ p1exov'tlX AtjW'tEpo IXltO 3% EAEU0epo 0u'ixo o!;u. OAP A THPHI.EII.: 1. YolX'ttXIX OUXAUf!IX'tlX 6tllet'ixwv IXAOt'tWV EtVIXt ouaiec;; -c71c;; 1 0 (~)- • • 2. 0et'ixoc;; fLOAuf,6oc;.1teptexw11 AtjW'tEpO IXltO 3% EAeuOepo llet'ixo o!;u, ELVIXt ouaicx -c71c;; KAixaewc; 6.1 (f,AEltE 7tEpt0wpto 2601, 63°(j), 24 °. Bpwµt0. TIAP ATHPHI.H: i\tlX -c7111 ouaiOL IXU't'Tj Eq>OLp(Xo,ov-cOLt et6txec;; auvll71xec;; au axEuOLaiOLc;; (f,Aeite 1tep18wpt0 2804 ). , 25 °. E!;OLq,Ooptouxo µo)..uf,oOLiVtO. TIAPATHPHI.H: . r tlX 'tTJV ouailX IX\l't'Tj eq,cxpµo~OV'tCXt EtOtxic;; auv871xec;; (1\) 0XE\llXQLCXc;; (f,Aeite 1tep18wpt0 2803). 2 6 °. Aomic;; evwaetc;; q,0opiou, 61twc;: ex) 7tEV't1Xq>0optouxo f,pwµt0, 'tptq>0optOUX? f,pwµLO. • f,) 'tpLq>0opwuxo 1Xf!f!WVLO, 6tq,0opwuxo XIXALO, OLJ0opLOuxo VOt'tpLO, q,lloptouxo XAWptO, ltEV't1Xq>llopt0uxo IXV'tlf!OVLO. TTAPATHPHI.H: TO q,8opt0uxo cxµµwvt0, q,8opt0uxo XIXALO, q,0opwuxo VIX­ 'tptO XIXt Ot q,Oopt0uxec;; atAtXOVEc; ELVIXt ouoiec; -c71c;; K).dtaewc;; 6.1 (f,Aelte ·1tep1llwpt0 2601, 65° (r) xcxt 66° M): 2 7 °. Ouaiec;; cxvopydtvwv o!;iwv itou 6ev fL7topouv vex -ccx!;tvo fLTJ0ouv \lltO OtMouc;; ouMOjtXOuc;; 'tt'tAOUc;;, oitwc;;: f,) ltEV'tO!;EiotO q>Waq,opou (citvuopo (j)WCJ(j)OplXO o!;u). j) XAWptouxo X\lOtVtO, 8et'ix71 u6poxu).cxµiv71. Op11Xvtxic;; ouaiec;; . . . . 31 ° . faepedt xcxpf,o!;uAtxcx xcxt 61xcxpf,o!;u).1xcx o!;eOL, o'tE~Ecx cx)..oyovwµivcx xcxpf,o!;uAtxix o!;icx XIXt o'tEpeoi OLvuopi'tEc;; IXU'tWV, oitwc;: f,) f,pwµo-o!;etxo o!;u, );Awpo-o!;etxo o!;~ (µovox~wpo­ o!;etxo o!;u), -cptxAwpo-o!;EtXO 'tflLXAwpo-o!;ELXoc;; cxvu6p1-c71c;;. j) (J-TJAE'ivtxoc;; cxvu6ph71c;;, q,OIXAtXoc;; IXVU6ph71c;;, 'tE'tp1Xii6po­ q,llcxAtxoc;; cxvu6ph71c;;. 32 °. Y ypdt XIXpf,o!;uAtxdt o!;iOL xcxt uypcx cxAo1ovwµivcx o!;icx XIXt uypoi IXWOpt-cec; cxu-cwv, Oit(l)c;; • ex) -cptcpOopt0-o!;etxo o!;u, 1) xpuo-ccxMtxo o~etxo XIXt u6cmxcx 6t1XAuµcx-c1X o!;etxou o!;foc; 7tEptEXOV'tlX ltAEOV 'tO\l 80% xcx0cxpo o!;u, cxxpuAtXO oxu, OtlXAU(J-IX'tCX f,pwµo-o!;etxou o!;foc;;, OLIXAUf!IX'tlX X Awpo-o!;etxou o!;foc; (µovo~xAwpo-o!;etxou o!;foc;;), µiyµcx-ccx XAwpo-o!;e1xou o!;foc; (µovoxAwpoo!;EtXOU o!;foc;), µiyµcx-ccx XAWpo-o!;EtXOU o!;foc;, OtXAWpo-o!;EtXO o!;u, µupfL7JXLXO o!;u ltEpLEXOV 7tEptoo6 'tEpo IXltO 7 0% XIX0cxp6 o!;u, llEtOj AUXOAtXO o!;u, OllXAU(J-IX'tlX cptXAWpo-o!;etxou o!;foc;;, o!;etxoc;; 1Xvu6ph71c;;. . r) o!;ELXO o!;u,1tep1exov IXltO 50 ewe;; 80% xcx0cxpii o!;u, 2-x).wpoitpomovtxo· o!;u, 5-xAwpof,IXAEpLXO o!;u, µupµ71xtxii o!;u ltEpLEX.OV CXltO 50 ewe; 70% xcxllotpo o!;u, Elt'totq,Oop1of,ou­ 't\lptxii o!;u, f!E'tlXXpUALXO o!;u, 1tpomov1xii o!;u ii:Eptexov At"(W· 'tEpo IX-ito 50% XIX9cxp6 o!;u, ~0\l'tUptxoc;; IXWOpi~c;;, itpomovt • I>. u xoc;; cxwupt-c71c;;. TIAP ATHPHI.H: • Mupµ71xtx6 o!;u, o!;EtXO o!;u XIXL itpomOVLXO o!;u (J-E 7tEpLEx o­ µevo xcx0cxp6 o!;u o!;u AL')'W'tEpO IXltO 50% OEV \lltOXELV'tlXt O'ttc;; OliX'tOt!;ELc;; 'tTj<; AD R. 33 °. I.uµitAOXEc; EVWOEtc;; EVWOEL<; -cptcp0opwux.ou ~opiou, oitwc;;: ~) -cptq,Oopt0ux.o f,6pt0 - o!;ELXO o!;u (ouµitAOXO OtAIXc;), ou­ fLltAOXO f,opt0 - itpomovtxo o!;u, OU(J-ltAOXO -cptq,Ooptoux.o f,6 pto - cx1871p, OU(J-ltAOXO -cptq,lloptouxo f,opto - q,ottVOATJ, 3 4 ° . AAxu)..o - oou).cpovtxdt xcxt cxpu)..o - oou).q,ovtxdt o!;ecx oitwc;: f,) Vt-cpo-f,ev~EVtO-OOUAcpOVLXO o!;u, q,ottVOAO-OOUAcpovtxo o!;u. ,) 3-~EV~LVLOtO-OOUAcpovtxo o!;u, fLEllcxvo-oou~cpovLXO o!;u, co).ouEvt0-oouAcpovtxdt o!;icx XIXL 61cxMµcx-ccx cxu-cwv. TIAPATHPHI.H: • AhuA0-00\lA(!)OVLXOt XIXL otpUA0-00\lA(!)OVlX(X o!;ecx it~ptexo­ V'tlX 7tEptoa6-cepo IXltO 5 % EAEU0Epo 0Et'ixo o!;u ELVIXL O\lOLEc; 'tTj<; 1 0 (f,). • . . . . . 3 5 °. I.'tEpE<X op1cxvtxcx o!;tvcx ~oyov16tcx, ?itwc;: . f,) 6tx Awpo-xtvo!;cx)..1vo-xcxpf,ovu).10 x ).wp~ ouxo, XAWPL?U· xoc; otVtOOATJ, XAWptou"l:o 2,4-61xAwp of,ev~O\lAtO, XAWpt~uxo vt-cpo-f,ev,Evo-ooiiAq,owAt0, XAWpt0uxo p-v1-cpo-f,ev,ouAt0, XAWptouxo ta oq,81XAoiiA'.O. . . . · 36 °. Y ypei op11XvtxlX 1XA01ovt6tcx, oitwc;. . . f,) f,pwµt0uxo CXXE'tUALO, f,pw(-ltOUXO f,pwµ?·otXE't\lALO, XAWpt0uxo f,ev,oiiAtO, XAWpt0uxo XAwpo:otXE't\lAtO, "l:AW­ ptouxo OtlXLllUAtXO 0etocpwoq,o'(JuALO: x. AWpt0uxo cp?UfLotp.uAto, X. AWptouxo mf,IXAOUALO (x Awpt0uxo ;PLfLEllUAOIX~E't\lAtO ), X,AWptouxo -cptxAwpo-otXE'tUAto, XAWpt0uxo f,1XpEpuAtO, LW OtOUXO IXXE'tUAtO. . . . r) XAWptouxo f,EV,EV0-00\lA(!)OV\lAtO : XAWptouxo. o-xAwp­ O~EV~OUALO, XAWptouxo p-xJ..wpof,Ev,OUAtO, XAWptouxo Ot(-lE· lluAO·'tptq,woq,opuAtO, . 3 7 °. AAxuAo-x.AwpootAOtVLIX xcxt cxpuA•XAwpooLAIXVtlX (J-E 01jµEio cxµ1XcpAE!;Ewc; itdtvw 1X1to 21 °, iiitwc;: . f,) IXMUAO·'tpLX Awpool.A<XVLO, IX(J-UAO·'tptx AWP?OI.AIXVtO, f,ou-cuAo--cp1x)..wpoo1.Acxvto, X AwpocpotLVLAO·'tPLX AWOAIXVto, ~u­ xAo-E!;otwAo--cp1x )..wpoatAdtvto, xutlo-E!;uAo--cptX Awpoo1.A1XV­ t0, 61x ).wpo-q,1X1wAo--cp1x AwpootA0tvt0, 611Xt8u1,.o-6tx).wp?atA­ <XvLO, 6tipcx1wAo-61x )..wpootAdtvto, 6w6EXUA--cp1x).wpoo1A~vt0, e!;uA--cp1x MwpootA<XVtO, µe9u).o-cp1XLWA0·0tX. Aw~oatAcxv10, µovuA--cptX, ).wpootAOtvto, ox-ccxoexuAo--cptX, Awp?o1Acxvt0, q,1X1 vu).o--cp1x Awpoo1.Adtvt0, 1tpo1tuAo--cp1x Awpoo1.A1XVt0. y)... . iIAPATHPHI.H: XAwpoa1.Acxv1cx itou etluouv EU(!)AEX'tlX IXEpLIX OE EltlX(!)Tj ~E vepo Tj uypo otipcx, ELVCXL ouaiec;; -c71c;; IO.dtoew~ 4.3. XIXL OEV ~pE­ ltEL VIX jLVOV'tlXL OEX'tE<; jLIX (J-E'totq>opix, EX'tOc; IXV O'tTjV I0.1X01j IXU'tTj IXVIXcpipov-clXL OE ELOlX~ E!;cx(pEOTJ,. 38°. 'O!;tVOL cpwocpopLXOt EO'tEpE<;, OltW<;: . 1) 6!;1110 q,wocppoptx~ 61[,ou~u)..10,. 6!;1vo q,woq,op1~0 6mp?· ltUALO, o!;tvo cpwocpoptxo f,ou-cuAtO, o!;tvo cpwocpop1xo Loox-cu .. ALO, o!;LVO cpwocpopLXO L007tp07tUAt0, • 39°. 'O!;tvEc;; op11Xvtxic; ouoiec;; 1tou 6Ev.µ1topouv VIX -cot!;tvo­ µ718ouv uito cxMouc;. ouMo1 txouc;; -ch~ouc;, imwc;: f,) cxxE-coitoAuoLAotvux, IXXE'to!;uoLAIXVLIX, cx18uAo--cptotXE'to!;­ uo1.A0t1111X. B. Bcxotxic;; ouoiec; Avop11XvEc; ouoiec;; . . 41 ° . B1Xotxic;; o'tEpEic;; evwoEtc; IXAXIXALxwv µa-cillwv oitwc;;: . ,. f,) u6po!;Ei6to x1X1olou, u6po!;el610 At~iou, u6po!;Et6'.o x~tou (xcxuonxo ltO't<Xoot), uopo!;EtOLO vcx-cptou (xcxua'ttX"l oo6otk o!;Ei6t0 xlXAiou, o!;d6t0 VIX-cpiou. 1) cxof,Eo'tOc;; o66otc; (µi,µcx-cot Xot\lO'tlXTjc; ooocxc; Xott l-'-"l eof,Eoµiv71c; 1Xaf,fo-cou ). . . . • 42 °. i\tiXAUfLCX'tlX IXAXIXALXWV ouotwv, oitwc;: . f,) OLIXAUfL<X'tlX otp"(LALXOU vot-cpiou, OLIXAU(J-IX'tot uopo!;EtOLO\l XotAtO\l (POT ASH LYE) XIXL uopq!;ELOtO\l VIX'tpiou (xlXUO'ttXTjc; aoocxc;), IXAXIXALX<X 6LIXAU(J-IX't0( xpao~6)..11c;, cp1XLVOA1jc; XIXL !;uAE­ VOATjc;, IXAXIXAtxdt xcx-cixAomcx (it,X,, !hiiAiaEwc;). 43 ° . i\totAUfLIX'tot IX(-l(-lWVill(<;: . 1) 6t1XAU(J-ot'tot otµµwvilXc;; 1tap1exov-ccx -couA<XXLO'tOV 10% xcxt co. noAu 35% otµµwvilX. TIAPA THPHLE:II.: • 1. i\tlXAU(-llX'tlX CX(-lfLWViotc;; 1tEptE"l:OV'tlX ltEpLa?o'tEpTJ O(~O 35% CX(lfLWViot, Eivott ouaiec; 'tTj<; IO.cxoEwc; 2 (f,AE7tE'1tEptllw pto 2201, 9°, (cx-c)). . 2. i\t<XAUfL<X't<X IX(l(lWYiotc; 7tEptexo~ot ,AL)'W'tEpO IXltO 10% <XfLfLWViot, oEv uitoXELV'tlXL a-cic; 611X'tot~Etc; :71c; AD R. 44 °. Y6pcx1;iv71 xcxt uoot-cLXIX OLIXAU(J-IX'tot 'tTjc;: . 1X) cxvu6p71 u6pot1;i'J"l, \lOIX'tLX<X OLIXAUfLIX'tlX u6p1Xl;iv71c; 7tEplE XOV't<X 7t!ptaoo'tEpo IXltO 64% u6pcxl;iv11: . f,) uocx-ctxdt OL<XAUfLIX'tOt u6pcxl;iv11c; itEpte~ov-ccx -co ltOAU 64% u6pcxl;iv71.. . . 45 °. :Eou)..q,i6tot xcx1 u6p101ovoao1JAq>t6tcx, oitwc;: EG>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) 1205 ~) 6u:XAUf'-CX'tCX 0Etouxou cxµµwviou XCXL facx)..uµcx,cx 7tOAU 0Etouxou cxµµwviou, 0Etouxo XIXAlO XCXl 0Etouxo \IIX'tpto 7tEpta­ xov,cx 'tOUAIXXLO'tO\I 30% VEpou xpua,CXAAWOEWc;; XCXL u6po,o­ \lOOOUAcpi6to \ICX'tpiou 7tEptixov 'tOUAIXXLO'tO\I 25% VEpou xpu­ O'tCXAAWOEWi;;. ITAP A THPHEH: 'Avu6po 0uouxo XIXALO XCXL 1Xvu6po 0Etouxo \IIX'tpto we;; XCXl "CCX u6po!;Ei6tcx CXU't"W\I ltOU 7tEptaxouv Atjwnpo CX7t0 30% 11Ep0 xpua,cxUwaEwi;;, EitiOT}i;; u6po1ovoaouAcpi6to vcx-cpiou 1tEpta­ xov 'tOUAIXXLO'tO\I 25% npo xpua,CXAAWOEWi;; EiVCXt.ouaiEi;; 't"Tji;; KA1XaEwi;; 4.2 (~)..am mpt0wpto 2431, 6° (1)). 1) u6cxttXIX 6tcxMµcxtcx aouAcpt6[wv xcxt uopo1ovoaouAcpt 6[wv f'-E E!;cx[pEOTJ "CO 0EtoUXO CXf'-f'-W\lto OE foii)..uµoe Xoet "CO 7tO­ AU0EtOUXO cxµµwvto OE 6t1XAuµcx. Op1cxvtxac;; ouaiEi;; 51 °. Y6po!;Ei6tcx 'tEtpcx-cxAxu)..cxµµwviou, 61twc;;: ~) u6po!;ai6to ,Etpcx-µE0u)..cxµµwv[ou 52 °. L,EpEii;; cxAxu)..cxµivEi;;, cxpu)..cxµ[vEc;; xcxt 1t0Aucxµi11Ei;; 61twi;;: 1) 6tcxt0uAEvo-6tcxµivTJ (1tmEp~i111j), E!;cxµE0u)..o6tcxµivTJ, 53 °. Ywac;; CXAXUAcxµ[ni;;, cxpuAcxµivEi;; XCXL 7tOAucxµivEc;;, 61twi;;: ~) ~Ev~uAo-6tµE0u)..cxµ[vTJ, xu0.o-E!;u)..cxµivTJ, 6tCXAuµcx,cx XCXAXE8UAE11-6tcxµiv1ji;;, 6t-11-~ou-cu)..cxµ[111j, 6tE0UAEvo,ptoeµ[vTJ, N, N-6t-cxt0UAE0uAEv-6tcxµ[vTj, N, N-6tµE0uAoxuxAo-E!;u)..cxµ­ ivTJ, oet0uAEvo-6toeµ[vTj, 6tcx)..uµcxtoe E!;cxµE8u)..ovo-6tcxµiv1ji;;, ,ptcxt0uA-VE 'tE 't pcxµi VTJ. 1) ~Ev~u)..cxµ[v'Tj, 6tacxµtvo-1tpo1tuAcxµivTJ (6mpo1tuAEVE,ptcx­ f'-LVTJ, 3,3-tµtvo-6mpo1tuAcxµiv1j), 6txuxAo-E!;u)..cxµivTJ, 6tcxt8u­ Aoµtv-1tpo1tuAcxµivTJ, 2-cxt0uAoE!;u)..cxµivTJ, taoppovE6tcxµivTj, mv,cx-cxt0u)..EvoE!;cxµivTJ, n,poe-cxt0uAEvomv,cxµivTJ, ,pt~ou-cu­ AcxµivTJ, ,ptµE0uA-xuxAoE!;uAcxµivTj, ,ptµE0uA-E!;cxµE0uA-vE6 tcxµivEi;;. 54 °. AµtvocxhooAEc;;, 61twc;;: 1) cxt0cxvoAcxµivTJ xcxt 6tcxAuµcx-ccx cxu,71i;;. r. Aomac;; 6tcx~pW'tlXEc;; oua[Ei;; 61 °. Y1tox:i..wptw61j 6tcxAuµcx,cx, 61twi;;: ~) 6tcxAuµcxtcx u1tox Awptw6oui;; xcxAiou xcxt 6toeMµcx,oe uito­ X AWptw6oui;; vcx,piou 7tEptaxov,oi 'tOUAIXXLO'tOV 16% Elttq>E­ AoUc;; x:i..wp[ou. j) facx)..uµcxtcx U7tOXAWptw6oui;; XCXAiou xoet 6tCXAuµcx,oe U7tO­ XAWptw6ouc;; vcx,p[ou 1tEptaxov,oe 7tAEOV 't"OU 5% oeAAIX "CO ltOAU 16% 6tcx0Eaiµou ;(AWpiou. ITAPA THPHLH: Y1toxAwptw611 6tcxMµcx,oe 7tEptaxov,oe -co TCOAU 5% 6toe0E­ aiµou x:i..wpiou 6Ev uitoxEtv,cxt one; 6toe,1X!;Eti;; 't"Tjc;; ADR. 62 °. 8tCXAuµoe,cx U7tEpo!;Et6[ou u6po,ovou. ~) u6cx,lXIX 6tCXAuµcx,cx U7tEpo!;Et6iou u6pojOVOU 7tEptixov-ccx 'tOUAIXXlO'tO\I 20% XCXl "CO 7tOAU 60% U7tEpo!;Et6iou u6po,o,. vou. 1) u6oe,txlX 6toeAuµoe,oe u1tEpo!;Et6[ou u6po16vou 1tEptixov,oe couAIXXtci,ov 8% xoet -co 1t0Au 20% u1tEpo!;Et6iou u6po16vou. ITAPATHPHLEIL: 1. 8tCXAuµoe-ccx 7tEptaxov,oe 7tAEOV 'tOU 60% U7tEpo!;Ei6to u6po,ovou aivoet oua[Ec;; 't"Tji;; KAIXOEwi;; 5.1 (~AEltE mpt0wpto 2501, 1 °). 2. 8toeAuµoe-ccx 7tEptexov,oe ALjW't"EpO oe1t6 8% U7tEpo!;Ei6to u6po16vou 6Ev uitoxEtv-coet a,tc;; 6toe,1X!;uc;; ,Tjc;; ADR. 63 °. ~toeAuµoe,oe cpopµoeA6Eii61ji;;: 1) u6cx,txlX 6toeAuµoe,cx cpopµoeA6Eii611c;;, 7t-X· cpopµcx)..ivTJ, µE 5% ,ouAIXXta,ov cpopµoe)..6Eii61j. E1ticr1Ji;;, µE 35% -co 1t0Au µE 0oev6ATJ, ITAPATHPHLH: Y6cxttx~ 6tcx)..uµcx,oe cpopµcxA6Eii61jc;; µE At1w,Epo oeito 5% cpopµoe)..6Eii6'1j, 6Ev uitoxuv,cxt a-ctc;; 6toe,1X!;Eti;; ,Tjc;; ADR. 64 °. Ea,ipEc;; op1cxvtxwv xoet oevop11Xvwv o!;iwv, ot t6t6,TJ­ cEi;; ,wv 01toiwv Eivoet xupiwi;; 6toe~pw,txac;;, 61twc;;: oe) XAwpocpopµtxo[ Ea,ipEc;;, 61twc;;: XAwpocpopµtxo oeUuAto, XAWpocpopµtxo ~E\l~UAto. ITAPATHPHLH: Ea-cipEi;; op1cxvtxwv xcxt oevop11Xvwv o!;iwv, ot t6t6,1J,Ei;; ,wv 01to[wv Eivoet xupiwc;; to!;txai;;, Eivoet ouaiEi;; 't"Tjc;; KA1XaEwc;; 6.1 (~AE7tE mpt0wpto 2601 16° xcxt 11°). 65 °. LnpEic;; 6toe~pw,txii;; ouai;.c;; xcxt 1tcxpoeaxc.u1Xaµcx,oe 1tou 6Ev µ1topouv vex ,oe!;tvoµTj0ouv a;. illouc;; auUo1 txouc;; ,i­ cAouc;;, 61twi;;: ex) ... ~) ~pwµtouxo 6tcpoet\lUAoµE0UAlO j) ... • 66 °. Y1pac;; 6toe~pw,txic;; ouaic.c;;, 6toeAuµoe,oe xoet 1toepcx­ axw1Xaµoetoe, 1tou 6 .. v µ1topouv voe -coe!;tvoµTj0ouv a;. 1XAAoui;; OUAAOjlXouc;; ,i,Aouc;;, 61twc;;: ex) ... ~) BENZOTRICHLORIDE (,ptXAwpo-µ .. 0uAo-~ .. v~ivto), 1-PENTOL (3-ME0~ J\0-2-PENTENE-4-YNE-l-OL). j) ... 8. Kc.VIX d6TJ auaxwoeaioec;; 71 °. Kc.VIX d6TJ auaxEuoeaicxc;;, x;.111X ~u,t0cp6pcx ox71µcx,oe, xEvai;; )..uoµEvEi;; 6 .. !;oeµ .. vic;;, x;.vec;; 6 .. !;cxµ;.vic;;-xov,iTjvc.pc;; xoet • Xc.VIX µtxp1X XOV'tETJVEpc;; Of. xuµcx, oexcx81Xpta,oe, 7tOU 7tEptc.ixoev oua[;.c;; t'Tji;; KAiia;.wi;; 8. OuaiEi;; ,wv 1toepoe1 p. 1 - 5,7 - 11, 21 - 23, 26, 27, 31 - 280loe 39, 41 - 45, 51 - 54 XCXL 61 - 66, f'-c.'tCXCj)EpOf'-c.Vc.c;; OUf'-Cj)WVCX µt ,Le; cxx6)..ou0Ec;; 6tcx,1X!;ui;;, 6;.v uitoxuv-coet oun a,tc;; 6toe,1X!;c.ti;; 't'Tjc;; 1tcxpoucr1ji;; KA1Xaawc;; ltOU 7teptA.oeµ~IXVEl "CO 1toepov IToep1Xp 'tTJfloe, oup,a a,ti;; 6toe,1X!;ati;; 7t0U 7teptEXEL "CO IToep1Xp't"TjµCX B: 1) ex) Ouaiac;; toe!;tvoµouµavai;; u1t6 -co (jiTJcpio (oe) x1X8a 1toepcx­ jp1Xcpou: • Y,poe: "CO 7tOAU 100 xa,A. oeVIX aawnptxo 6oxc.io xoet -co 7tOAU 400 XO'tA. xoe,IX 6aµoe. . L'tc.pc.lX: -co ltOAU 500 iP· xoe,IX ;.awnptxo 6oxc.io xoet "CO 1t0Au 2 xtA<X xoet&: 6iµoe. . ~) Ouaiai;; tcx!;tvoµouµEvc.i;; a-co (jiTjcpio (~) x1X8c. itoepoe1p1X­ cpou: Y,p&:: "CO 7tOAU 1 )..i-cpo oev& aawnptxo 6oxaio xoet "CO 7tOAU 4 Aitpoe oev1X 6iµex. . L'tepe1X: "CO 7t0AU 3 XLAIX exvlX aaw,aptxo 6aµex xoet "CO 7tOAU 12 )..[,poe exv& xoAov. 1) Ouaiac;; -cex!;tvoµouµavac;; a-co (jiTjcpio (j) x&:0a 1texpoe1pa­ cpou: Y,pex: "CO 7t0AU 3 Ai,poe xoe't<X aawnptxo 6oxaio xoet "CO ,7t0AU 12 )..i-cpex xex,IX xoAov. • • LnpE<X: 'tO 7tOAU 6 XLA<X exVIX aaw,aptxo 6aµex xoet "CO 7tOAU 24 XlAIX exvlX XOAO\I, Ot 7tOOO't'Tj'te<; oeu-cac;; OUOLWV 1tpa1tat vex µa,oecpipov,oet OE auv 0auc;; auaxwexaiai;; 1tou 7tATJpouv ,OUAIX)(.ta,ov ,ti;; 1tpo6tex1 pex­ cpac;; '!OU 7tEpt0wp[ou 3538 (~) XCXl (6). Ot «r e\llXEi;; 6tex,1X!;ati;; xext opot auaxwexaioec;;» '!OU 7tept0w­ piou 3500 ( 1 ), (2), xext ( 4) iwi;; (7) 1tpi1tat vex ,71pounoet 01twa 6711to,a. (2) AhexAtx<X 6texMµex,ex 71 o!;ioe aa µ1tex,expiac;; avoe1to871xau­ aawi;; µa,oeUtxlX 71 1tAexa,tx1X 1tapt~A71µex,ex. Ot µ1tex,oepiac;; 0oe 1tpa1tat vex aivoet atat 1tpocpu)..oe1µivEc;; wan vex Eµ1to6i~a,ext xext 1tpoAexfl~IXVe'texl ,uxov ~poexuxuxAwµoe ' OAia0TjOTJ, 7t't"WOTJ 71 ~71µiex. ITpimt vex aivext acpw6texaµavac;; µa xatpoAoe~ic;;. Oa,oao, ot xatpoAoe~ii;; 6av aivoet ex1toepex[,71,ac;; exv ot µ1toe,oepiac;; aivext ,o 1to8a,71µavai;; xoet µa exacp1XAatex auaxwoeaµavac;; xoet<XAATJAoe, 1t,X, 7t<XVW aa 1tCXAini;;. Kexvivex amxiv6uvo [xvoc;; CXAXIXAawi;; 71 o!;foc;; 6av 1tpi1tat voe aµcpoev[~atoet a!;w oe1t6 ,TJ auaxwexa[ex. 2. 8toe,a!;ui;; A. Ko:i..oe 1. r e\lLXOL opot auaxwoeaioec;; (1) Ot auaxwoea[ac;; 1tpi1tat voe 7tATJpouv ,oui;; opouc;; -cou floe- 2802 poep,71µex-coc;; A.5 ax,oi;; exv a,oe 7tept0wptoe 2803 - 2808 1tpo 6tex,p1Xq>OV'tCXl at6txac;; 6toe,1X!;ati;; xext opot 1 tex ,71v auaxauexaioe wptaµavwv OUOLWV. (2) Luµcpwvex µa ,tc;; 6tex,1X!;atc;; ,wv 1tapt8wpiwv 2800 (1) xext 3511 (2) 0oe 1tpi1tat voe x p71atµo1totouv,oet ,oe a!;71c;;: LuaxauexaiEc;; ,71c;; 0µ1X60i;; auaxauexaiexi;; 1, µoepxoeptaµivEc;; µa co jp1Xµµoe «X» 1 tex ,ti;; a!;oetpa,txlX 6toe~pw,txac;; oua[Ec;; 1tou ,oe !;tvoµouv,oet a-co (ji71cpio (ex) x1X8a 1toepexjp1Xcpou. • LuaxwexaiEi;; t71i;; oµ&:6oi;; II xext I, µexpxoeptaµivac;; µa -co 1 p<iµµex «Y» 71 «X» 1 tex nc;; 6tex~pw,txic;; ouaiac;; 1tou ,ex!;tvoµou v-cext a-co (ji71cp[o (~) x<i0a 1toepex1p<icpou. . Luaxauoea[ac;; ,wv oµ5t6wv III, II 71 I, µoepxexptaµivai;; µa -co 1 p<iµH,oe «Z» ,« Y» 71 «X» 1 toe ,tc;; aAexcpp<i 6toe~pw,txai;; ouai;.i;; 1tou ,oe!;tvoµouv,ext a-co (ji71cpio (1) x<i0a 1toepoe1 p<icpou. 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IX AoxtµotoiEc; EltL UALXWII 7t01.) 1X1totpt8µou11'tott O'tO 1tEpt8w p10 3103, 1. • (1) Mo OEirµcx'tot EXpTjX'tLXOU, µE f10t,0( f10Yat6oc; lOr 0ot 't01to8t"C7)8Ei OE ru<XAtlllX XUAtvoptx<X q>LUIXALOtlX 'tWII 01toiw11 7l EOW'tEpLXT) 6tOtf1E'tpoc; ELIIIXL 3 EX. 'tO u4oc; 5 EX. µaxpt 't'Tjll xci'tw EmcpcivELot ,ou X0t1totxtou 1t0Au XotAci XAEtOfLEVot fl-E 'tO 1twµ0t 'tOU<; XIXL 0Epp.1Xt110fLE111X OE 0Epf11X11'tT)pto, 07tOU 7totp1X't'Tj· pouv'totL xOtAwc; e1ti 3 wpEc; f1E ouvEXT) o't1X8EpT) 8Epf10Xp1Xal1X 90°C. (2) Kot't(X 'tO OLOtO'tTjfl.lX IXU'tO OE\/ 1tpE1tEt VIX 1t0tp0t't7lp718ou11 Vt'tptxci otiptot. H OLIX1tLO'tWO'lj XIXI EX'tLfLTjOTj 07tW<; 'tO 1tEp18w­ p10 31510t. ~- Aoxtµotaiot EltL 'tWII UALXWV 7t01.) 0t1t0tp18µoull't1XL O'tlX 1tEp1- .. 6wpt1X 310 3, 2 XIXL 3105. (1) Mo OELTP.IX'tlX EXPTJX'tLXOU µe f1<X~IX f10111X6oc; 101'P· 'tO· 1to8E'tO\IV'tlXL OE ru<XAIIIIX XUAt116p1x<X cp11XAi610t 'tWV OltOLWII 7l EOW'tEpLXT) 6LCXf1E'tpoc; ELIIIXL 3 EXIX't. 'tO u4oc; 5 EXIX't. fLE')(pL 'tTJII X<X'tW Eltl(j)CXIIEtlX 'tOl.l X0t1tlXXtOU 'tWV XO(t XIXACX XAELOfl-EVIX XIXI 6Epf10ttvoµEv0t aE 0EpfL1X11'tT)pto 01tou 1t0tp0t't7Jpouv't0tl XIXAW<; Eiti 48 wpEc; f1E ouve.x71 O'tot0EpT) 8Epµoxp0toi0t 75 °C .• (2) Kot,ci 't'TjV 1tEpio60 IXU'tT) OEv 1tpE1tEL vot 1t0tp0t't'1)pouv't0tt Vt'tptxci 0tip10t. Ex'tiµ71071 XotL 1t1Xp0t'tT)p7lOTJ we; O'tO 1tEp18wpto 31 s 1 IX. 0ep1-1oxp0toi0t 0tvcicpAE!;71c; (~AE1tE 1tEpt8wpto 3101 XIXt 3102). (1) H 8Epµoxp0toi0t cxviicpAE!;Tjc; x0t8opi,E,1Xt µE 'tO vot 8Ep­ µotivou1-1E 0,2 rP• UALXOU XAEtoµevo OE "'(tl<XAtVO OOXtfLIXO'tLXO owA71vot nou ~u0i~E'tlXL OE µndtvto 0t1to xpdtµ0t 'tOU WOOD. H 6ox1µ0tO'tLXT) OWAT)VIX 't01to8E'tEl't0tL O'tO µ1tcivto O'tlXV OtU'tO EXEL 6Epµoxp0toi0t 100 ° C. H 8Epµoxp0toiot 'tou µniivtou 1Xu!;citvE't0tL CXXOAOu0wc; 'tf17JfL0t'tlXCX µE 5 °C 'tO AE7t't0. . (2) Ot6ox1µ0tO'ttXoi OWAT)VE<; 1tpE1tEL YIX exouv 'tt<; E!;71c; OLIX· O't<XOEt<;. 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Acpou 7) XCX'tlXGtpocp71 'tOU cpuaLniou ELVCXL 6uvex't7j 71 6ip­ µcxva711tpex,µcx"to1t0Le.hex1 ae. xou,i 1tou 1tpoa,exnue.L cxito llpexu­ aµex"tot, CX'tGIXAL\10 1tixxou,;; 1 Oµµ au,xoU71µivo XCXl CX\IOlX'tO exlto 't7) µlot ltAtupdt 1tpo,;; 'tCX EltlX\IW, To cpuainL xpEµthott µE­ 'tCX~U Mo pdt~owv OLcxµhpou 4µµ, ElGEflXOfLE\10 G'tt,;; ex\lOL"'(µE­ ve.,;; 'tpuite.c; 'tWV O:V'ti0E'tWV 'tOLXWfl-lX'tW\I 'tOU XOU'tLOU XOt.t µe.-cdt llepµcxivoV'tot,;; µ.E 4 xcxua't1)pEc; TECLU (E/;W'tEpLx71i:; OLcxµE­ 'tpou 't7),;; awA71vcxc; 19µµ) cxu,ou 1tou ~piaXE'tCXL 1tpo,;; 'tCX xii-cw, 9e.pµcxiVEl 't7)V ~IXGT} 'tOU XOU'tlOU, CXU'tOU ltOU ~piaXE'tCXl etpl­ G'ttpdt XIXL OE/;LIX 'tOU 'tOLXWµet'tO<; ltLGW G'tO XAELGLµo. OL awA71vs'i:; ,wv X0tUO"t7Jpwv ELGEPXOV'tCXL XCXL a't0t6spo 1totouv,0tL as 01tic; 20µµ OLetµhpou ltOU ix ouv etvotx0e:i G'tllt 'tOLXW(lOt'tCX -cou 1tpoa,cxnu'tLXOU xou'tLOU -cwv 0petuaµdt-cwv. OL x0tuG't1)pec; etvdt~oV'tCXL ,0tu'tOXPOV0t 0t1to XOtV'tTjAL xcxt pu9 µi~ov-cetL as µe.1dtA71 1tpoacpopix etipoc; wa,e. ot dtxpe.i:; ,ou e.aw­ 'ttpLxou xwviOLOU µ1tAE OtltO <pAojCX Vilt cx,,i,ouv axe.oov 'tO cpu­ aint. '0).71 T\ E"'(XCX't/XG't0ta71 ~piaxe:'tOtL ae: 6oxLµota,7JpLo XOtL e:ivcxL xwpLaµivo CXltO 't7IV 0ti0oua0t 1tcxp0t,71p71a71c; µe: xov,po -coi­ xwµcx OltOU 1tcxp0t-c71p71nxdt rucxAiet ixouv E<petpµoa9e.i HE 'tE~ 9wpetxLaµivo 1uetAi xcxt et,aiiAtvEi:; 1tAdtxE,;; µE oXLG[,LEc;. To 1tpoa"totuu-cLxo aE 8p01:uaµ0t'tCX xou-ci EXEL -co1to8e,710Ei µE 't7)V 1tAEupix 0tvotx,71 1tpoi:; 't7)V cxi0ouacx 1tcxpcxi:71p71aEwi:;. 0cx 0t1to­ cpu1ouµE vex rn71pEIX~O\l'tlltL Ot cpAOjE<; OtltO pEuµ0t OtEpoi:;. H cxi 9ouacx 6oxtµcxai0tc; EXEL EcpoOtota,e.i µE EVOt aua't'Jj(lllt 1tou Em­ 'tpE1tEL 't7IV cx1toppocp11a71 OtEpiou CX1toauv8e.a71c; XOtt XOtlt\lOU EXPT\~7Ji:;. EUe.i~Et 0te.piou ltOAewc; 71 0ipµ0tva11 OU\IOt'tCXt VIX jLVEt µe. cxEpLo 1tpo1t0tviou. To 1tpo1tdtvto ,pot~tE-cCXL -co'tE 0t1to e.µ1toptx71 <pLIXA'Yj e.cpo0l0taµEv71 fl-E EMOt'tW't1jpLO (4,9 KPa(0,049BAR) E<J>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: .6EYTEPO) 1ttpv1X CX1t0 µnpT)'tTj (µttpT)'tTj µE cpUOT)'tlXO µT)XIXVT)µex 7tEplE­ X'tlXO'tT)'tCXc; 2 Ahpwv µE 4,9 KPa(0,049BAR) xext xexnu8u­ VE'text ex1t6 OlCXvoµeex 1tpoc; 'touc; 4 xexuo'tTjpEc; 'tWV 01toiwv 'tex O'tOµtCX EXOUV OtlXµE'tpO (1XVOl''fµex) 0,8µµ. 'Exexotoc; xexuo'tripexc; xex'texVCXAWVEL 'tO 1toM 1tEpi1tou 1, 7 Ai'tpCX 7tp07tlXVlO 'tO AE1t't0. Tex cptCXALOlex exEpiou XCXt O µE'tpT)'tTj<; 't07t08E'tOUV'texl a!;w ex1t6 "to 6oxlµexo'tTjpLO. 4. Ex'tEAEOT) 'tT)<; 6oxlµexoiexc;. fEµi~ouµE 'tO cpuoinl µE EXpT)X'tlXO IJAlXO µaxpl l5fLfL XIX'tW CX7t0 'tO XEiAoc;, OT)Aexori E7ti u4oc; 60fLfL· Av 'tO IJAlXO Ei­ vext OXOVT) 07tpWXVOIJfLE fLE 1tpOOEX'tlXE<; XlVTjOEt<; X'tlJ7tTjfLex'to<; "tOIJ cpuolniou xexl fLE'tlX fLE EAexcppii 7tlEOT) fLE EVex !;UAIXXl. Eiiii 'tO ~AlXO Eivexl ~EAex'tlVWOE<; ElOIX,~'texl O,'tO cpuoinl fLE µlex 01t1X't01JAex, xii8E cpopii 1to1.1 ELoii1ofLE o' exu'to fLlex 7tOOO'tT)'tex 'tT)V mE~ouµE EAexq>pii f1E !vex !;uAIXXl ex1toq>Eu1ovtexc; vex 611 µwupr118ouv cpuoilli6Ec; exipoc;. Acpou ~u,ioouµE 'tT)V etoexr6fLEVT) 7tOOO'tT)'tex I AlO'tp!XfLE 'tO olpfLCX't01tOl1jµlvo oncpiivl o'to q>uoi11l, 't01to8Eni'texl o 6ioxoc; cp<u'tO<; XCXl T) IJ7t000l(Tj 'tT)<; (3ioexc;, ocpiTTE'tQ!l fLE 'tO l(Epl. 0ex 1tpooi!;oufLE vex µ11v 1.11tcxpXEl UAlxo fLE,ex!;u onq>6:v11c; xexl 'tou 6ioxou OU'tE O'tex 6ixtuex. Ton 'tO (j)UOi,rl 't07t08Ent'tCXl OE 61.1 vex'tcx otEpE07tOlT)fLEVO auocpl1X'tTjpex fLE 1tpoo'texoiex xex'tcx !;exq>vt­ xric; axp11!;71c; xexl o 1.11to6oxaexc; 'tTJ<; (3i6exc; • oq>inE,exl fLE avex XAElOt. To E'tOlfLO 1tpoc; OOXlfLexoiex cpuoi,rl xpEµlE'texl fLE'tex!;u 't(J)V 6uo pcx(36wv 'tOIJ 1tpoo'tex'tEIJ'tlXOU XOIJ'tlOU 8pexUOfLCX­ "t(J)V. Avcx(3ouµE 'tO xexVOTjAl xexl fLE'tlX 'tO XAElOlfLO 'tOIJ OOXlfLexO't'Tj­ piou, CXVOL101JµE 'tT)V 1texpO)(Tj exEpLOIJ O'tOIJ<; 4 XexlJO'tTjpE<;. ~1.11 XPOVW<; !vex XPOVOfLE'tpo 'ti8E'texl oE Amoup1iex 1 lex vcx fLE'tpT)0Ei 0 XPOVOc; ( d) fLE'tex!;u 'tOIJ exVCXfLfLex'toc; xexl 'tT)<; exvo:cpAE!;Tjc; 'tOIJ UAlxou 1to1.1 xexpexx'tT)pi,E'texl ex1t6 'tTJV !!;060 fLlexc; cpA61 exc; ,ou <p<u'tO<; 'tOIJ OlOXOIJ Xexl O xpovoc; 't2 fLE'tex!;u 'tOIJ exVCXfLfLex'tOc; Xexl "tTJ<; axp711;1Jc;. Acpou 'tEAElWOEl 11 OOXlfLexoiex 11 Eloexrwrri exEpiou O'texµex'tcx xexl 'tO ouO'tT)fLex exvexpp6q>7jo1jc; µfoex o'to OOXlfLexo,ri­ plo 'ti0E'tCXl OE AEl'toup,iex. 0ex fL7t0UfLE O, exU'tO 'tO OOXlfLexO'tTjpLO µovov µE'tCX ex1t6 rnexp­ xac; XPOVlXO OlCXO'tT)fLex, r lex vex E!;exocpCXALOOIJfLE 'tEAElex Amoup,iex 'tOIJ 0EpfLexV'tLXOU OIJO'tTjfLex'toc;, m OOXtfLexOiEc; 0ex 1tpo11rouv'texl ex1t6 'tT)\I OOXl[J.ex­ oiex ev huxw. (5) EpfLT)VEiex 'tWV CX7tOnAEOfLCX'tW\I, H CJXE'tLXTj µi'tpT)OT) 'tT)~ E1Jexlo811oiexc; Evoc; IJAlXOU, O'tT) 8ap­ µexVOT) fLEOex O'tO cpuoi,rt CX7t0 ex'tOCXAL, EX(j)p!X~E'texl ex1t6 'tT) OllX­ f!t'tpo-oplO 7t01J El\lexl T) fLE,lO'tTJ OlCXfLE'tpoc; 'tOIJ (j)W'toc; 7tOIJ EX­ cppii~E'text OE fLtAL(,J.E'tpex (,LE 'tO 01toio OE 'tpEic; obXlfLexoiEc; ex1to­ X't1X(,J.E 'touAcxxto'tov µtex axp11!;11 'tou cpuolnwu OT)Aexori T) xex­ "texotpocpri exu'tou OE 'tOIJAO:XlO'tov 3 0pexuofLex'tex. H 0EpfLlXTj euexla011oiex exu!;O:VE'texl fLE 'tO )(P0\10 'tl xexL 't2 (3ex8[J.texioc fLELWOTJ, 0ex (,J.7tOpouoexµE \ICX 0E<upTj001JfLE 'tex op1exVLXIX IJ7tEpo!;ELOlex ( EX'toc;) exlJ'tWV 7t01J 1.1,po1tOlOUV'texl Tj OlCXAUOV'texL µE 7t't1j'tLXEc; ouoiEc; 1tX vepo 1 lex 'tex 01toiex 'to opw 'tT)c; 6texfLE'tpou Eivext loo iJ µE1CXAtinpo ex1t6 0,21,LfL 61twc; EXpT)X'tlXcx UAlXIX 'tcx!;11c; lex (3AE1tt mio11c; OT)fLtiwoT) 1tEpl0<upiou 2550. . E. ~oxlµexaiex 0lpfLexVoT)c; oE OO)(Eio fLE 7tLEOT), fLE 6ioxo XE­ 'll'tplxou cp<u'toc; xexl fLEfL(3pcxv11 (OOXlfLexoiex O'tO OO)(ELO fLE 7ttEOT)) BAE1tE 7tEpt0wplo 3112 ( 1) r lex 'tex op,exV\XCX umpo!;Eiolex Ol OOXlfLexOiEc; Ol exvexcpepo­ (,J.E\ltc; 1.11t6 oc, (3 xexl o otivocv'texl vex OUfL7tAT)pw0ouv fLE 'tTJV E!;Tjc; 6oxlµexoiex (2) Iltplrpexcpri 'tOIJ OO)(ELOIJ 7tLEOT)<; ( ElX 4 awe; 6) Ol Elxovac; 4 awe; 6 xexl Ol OXE'tlxic; E!;T)r"lOElc; ex1to6i6ouv ,le; AE1t'toµapmc; 'tT)c; )(PT)OlfL01tOtT)fLEVT)<; ouoxEuric; onwc; xext ot 6texotdtoelc; Xl:'l 'tex UAlXCX 'tWV ouo'tex'tlXWV 't<uv E!;exp,T)[J.IX­ "t<uv. IlpE1tEt vex OT)fLEtWOOl.lfLE O'tl 11 XP"lOTJ 24 6ioxwv cpw'toc; 1tpo(3AE1tE'texl xexl T) OlO:fLE'tpoc; exu'twv Eivexl 1, 0-1, 2-1, 5-2, 0-2, 5-3, 0-3, 5-4, 0-4, 5-5, 0-5, 5-6, 0-7, 0-8, 0-9, 0-10, 0-11, 0-12, 0-14, 0-16, 0-18, 0-20, 0-22,0 XexL 24,0µµ Ot 6ioXOL exu'toi axouv 7t1Xl(Oc; 2,0µµ - 0,2fLfL· H µEfL(3pcxv11 OLcxppTj!;T)c; x6(3e'texL (,LE 7t07ttOL OE cpuUo opEi­ XCXAXOIJ o,o5µµ 1to:xouc; 1tou exv,axE1 oE 1tiE01J 6Lcxpp111;11i:; 0,53 MPcx- 0,05 MPex (5,3 BAR - 0,5 BAR) oE xexvovLXTj 0epµoxpcxoicx O fLT) e1tcxvcx411µivoc; EACXOfLCX't07tOLT)fLEVoc; opEi0 xcxhoc; fLE 67% XCXAXO CXpfLO~EL, • (3) ~UO'tT)fLCX 0EpfLCXVOT)c; To ooxeio fLE 1tiEOTJ 0EpfLexive,CXL fLE (3ou'tCXVLO 'tE)(VLXTjc; 1tOtO'tT)'toc;, 1tou 'tpex(3Le'tcxt cx1t6 cplotAT) axouocx EACX't'tW'tTjpLO. H 1texpcxrwrri 0EpfLO'tT)'tOc; 1tpemL vex eivexL 1tEpi1to1J 3,1 KW Av cxu'to 'tO cxipto El(Et 0epfLexV'tLXTj ouvexfLT) xex'tw'tipex ex1t6 113 MJ/[J-3 (ex1to 100 KPex(IBAR) xexl 200 C) T) 1tcxpoxiJ Ocx 1tpe. 7tEl vex Eivexl 0, 1 µ3 / wpex 1tepi1tou. fivE'texL XP"lOTJ xexuo,ripcx TECLU 1 lex (301.1't1X\ILO. H 1too6 "t71c; exEpiou fLE'tpCX'tCXl fLE 7tEplo'tpE7t't0fLE'tpo 1l fLE fLE'tpT)'t7I 7t01J El(EL pu0fLtoni fLE 'tT)V (3puoTJ 'tOu xexuo,ripcx. Av'ti ,tex (301J'tlXVlO fL7tOpouµE vex XPT)OLfL07tOlTj001JfLE exEpLo 1t6Aewc; 71 1tpo1t1X\ILO fLE 'tT)V l(PTjOT) xex,cxU T)AOIJ xexuo,ripex, ecp' • oaov T) 1texpexrwrri 0EpfLO'tT)'toc; exEpiou 0cx EivcxL rnio11c; 1tEpi1to1.1 3, 1 7t,X, oE 1tepi1t'tWOT) 8epµ1x71c; 6tivcxµ11c; µ1xpo'tEpT)c; cx1t6 'to cx!pto 1t6Aewc; 't<uv 17 MJ/µ3 1tpi1tEL vex 1texpix u 1tEpi1tou 0,6 7 [J-3 / wpex. H cpLotAT) exEpiou, 'tO 7tEpLo'tpE7t'tOfLE'tp0 71 0 fLE­ "tpT)'tTjc; 1tpi1tEL vex 't01to8E'tOUV'texL e!;w ex1t6 'tT)V exi0ouoex 'tT)c; 60 XtfLexoiexc;. 4. Ex'tEAEo~ 'tT)c; ooXLfLCXoiexc;. flex xexvovlXTj 6oxt[J.exoiex 't01to8E,OUfLE 10 1 pexfLfLCXpLex 'tou uAtxou o'to OO)(Eio. Av npoxEL'tCXL 1 Lex IJALxo 'tou onoiou exyvo­ OUfLE 'tT)V E1Jexto871oiex expxi~OIJfLE fLE fLLXpcmpEc; 7tOOO'tT)'tEc;, 1tpw'tex fLE 1 rp (,J.E'tCX !XV EivexL 6uvex'tO\I, fLE 5 ,pexfLµcxptex, xexL "tEAoc; fLE 10 1pexµfLcxpLex. 0 (31.186c; 'tOIJ OO)(Eiou 1tpE1tEL vex EX,EL E7tlXCXAUcp0Ei OfLOLoµopcpex fLE 'tO IJALXO, Toito0E'tOUfLE 'tT)\I fLEfL­ (3pcxv11 6LexppTj!;Ewc;, 'tOV OtOXO XEV'tpLXOU q>W'tO<; XexL 'tO O'tEq>CXVL 'tT)c; 1expvt'toupexc;. OL 1.11toooxac; ow; (3i6Ec; µE 'tOL mcxo'tpcxxLex ocpinov'texL µE 'tO l(EPL xext OL IJ7tOOOXEic; 'tT)c; (3i6exc; 7t0IJ 'tO E7tl­ XCXAU7t'tEL fLE avex XAELOL. H fLEfL(3pcxv11 ~hexpp71!;Ewc; XCXAU1t'tE'texL fLE VEpo OE E7texpXTj 7tOOO'tT)'tCX wan vex OlCX'tT)p1j8Ei TJ fLEfL(3piiv11 oe x exµT)A7I 0EpfLoxpexoiex. To 6oxEio fLE 7tLEOTJ 't07t00Enhext OE Evex 'tpi1to6ex (fLE Eown,-­ ptXTj 61cxµE'tpo 'tOIJ o'tEcpexvtou 671,LfL) 1tou (3pioXE'tCXl fLEOex OE !vex 1tpoo'tex'tE1J'tLXO xu).1v6po. To oncpo:vt 1to1.1 (3pioxE'texL O'tO XCX'tW fLEpoc; 'tOU ooxEiou 'tOito0E'tEt'text o,ov ,pi1to6ex. Avii(301.1µE 'tO\I xexuo'tripex H Eioo6oc; 'tOIJ cxEpiou pu0fLi~E,ext fLE 'tT)V 1tpo(3AE7tOfLE\11j 1texpox71 xext TJ itexpoxri VEpou WO'tE 'tO xpwµex 'tT)c; cpM,exc; vex Eivext (,J.ltAE xexL O EOW'tEpLxoc; xwvoc; 'tT)c; cp).6,exc; vex EL\lexL fL7tAE exVOlX'toc;. 0 'tpi1to6cxc; 7tpE7tEL vex EXEL u4oc; 'tOOO WO'tE O EOW'tEpLxoc; xwvoc; vex exni,EL 1tEpi1tOIJ 'tO (31.106 'tOIJ 6oxEiou. Axo).ou0wc; 0 xexuotripcxc; 't07t08E'tEt'texL XIX'tW ex1t6 'tO OO)(EtO ex1t6 E\lex civol1 fLex O'tOV 1tpoo'tex'tE1J'tLXO xuALv6po. H exi0ouoex 61to1.1 EX'tEAEhexL TJ 6oXLfLexoiex 1tpE1tEL vex El(Et xCXAo E!;exEploµo xexl 6Ev Em'tpE1tE,exl 1J Eioo6oc; xex'tci 'tTJV 6oxL­ µexoiex. To OO)(ELO 1texpex't1jpEhexl ex1t' a!;w µfow xex0pE1t'tWV 7I fLEOW 01tric; 1texpex't71p1JOT)c; o'tov 'toixo, Ecpo6LexofLEVTJ fLE ,.0wpaxl­ oµevo yucx).L Me'tpiiµE 'tO xpovo d fLE'tcx!;u 'tTjc; apxric; 'tT)c; 0apµcxva11c; XO(L 'tT)c; expxric; (,J.lexi:; OCV'ti6pexo11c; ( q>A6,exc; O(VIX7t'tl.l1;1jc; xex7t\lOU <pUOTjfLOC'tOc;) xexl O x povoc; 't2 fLE)(pL 'tO 'tEAOc; 'tT)c; O(V'ti6pcxo11c; (axp11!;11 'tEAOc; 'tOIJ cpuorifLex'toc; xexl exVIX7t'tlJ!;Tj XCX7tVOU ri of3riol­ µou 'tT)c; cp).6,exc;). ~'tTJ OIJVEXELO( xpuW\IOl.lfLE 'tO OO)(EtO fLE VEpO xexl 'tO xex8expi~ouµE. • (5) EpfLTJVEiex 'tWV ex1tO'tEAEOfLIX'tW\I, H CJXE'tlXTj fLE'tPTJOT) 'tTJ<; E1Jexlo811oiexc; Evoc; IJAlXOU O'tTJ 0ip­ µexvo11 µfocx o'to 6ox eio niEOT)c; ExcppO:~E'texl ex1t6 'to 6pw OlexfLE­ "tpou, exU'tTj Et\lexl TJ fLE1CXAunp11 OLCXfLE'tpoc; 'tOIJ cpw'toc; 7t0IJ EX­ cppcx,E'texl OE fLlAlfLE'tp fLE 'tT)\I OltOtCX OE 'tpe[c; 60XlfLexOtE<; T) fLE­ (3p6:vT) axi,E'texL 'tOIJACXX,LO'tOV fLLCX cpopo: 6,exv fLE\IEL o:0LX'tT) Xex'tcx "tlc; 'tpEic; 6oxLµexoiEc; µE 'tT)V ex[J.fowc; µqexAu'tapex 6lO:fLE'tpo. H 0EpµlXTj E1JCXL0811oiex exu!;cxvE,exl µE exu!;exvOfLEVO op Lo 6tex­ µhpou xexl OLexOO)(LXCX (,J.ELWfJ-EVOUc; xpovouc; d xexL ,2. 0ex 1tpE1tEl vex 0EwpriooufLE op1exvlxo: 1.11tEpo!;Ei6lex ( EX'toc; exU'tWV 7t01J urpo1tOlOUll'texL 71 OlexAUOV'texL fJ-E 7t'tTJ'tLXEc; ouoiEc; 7tl( VEpo) rlex 'tlc; 07tOLEc; 'tO opLO OlexfLhpou EL\lexL ioo 1l fLE,exAU'tEpo ex1t6 9µµ 61twc; Exp11xnxcx UAlXCX 'tT)c; 'tcx!;11c; lex ((3Ai1tE E1tio11c; OT)fLELWOT) IJ7t0 7tEpl0 2550) ~OXlfLexOiex EIJexlo011oiexc; O'tT) ourxpoUOT) ((3AE7tl, 7tEpl0. 3103 ewe; 3110 Xexl 3112. • 1213 3.155 214 E<DHMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) &oxtµ0tai0t µE 'tOV X01t0tVO airyxpoua11c; 1 ( EtXOVIX 7 XOtL 8. ME XP1JOTJ µt0tc; Expix·rnu au1xpiaewc;. (1) To 0t1to;11p0tµEvo u1to 'tti:; 1tpo01to8foEtc; 'tOU 1tEp18wpiou , 3150 EXPTJX'tLXO 'ti8E't0tL x0t't' cxxoAou8icxv u1to 'tTJV E;ijc; µopcpij ex. Tex auµ1t0tj'TI EXPTJX'ttxix 'tpi~oV't0tt cxpXE'tlX AE1t'tdt wan vat Mvcx'tcxt vex 1tEp0taEt 0t1to xoaxtvo µE cxvoi1µ0t't0t 1 µµ xcx1 xp0t'tixµE 110t 'tTJV 6ox1µcxai0t 'to 0t1toµEh10tv uA1xo aE xoaxivo µE cxvoi1µ0t't0t 0,5µµ Tex xovtop'to1tot1jµiv0t EXPTJX'tLXIX 1tEpvwu­ V't0tt 0t1t0 XOOXIVO µE OtVOLjl.l-Ot'tOt 1 µµ XOtL xpOt'tlX!.1-E jlOC- 'tTJV 00 Xtµcxaicx aurxpouaEwc; 'tO OIJVOAO 'tOU xAdtaµ0t'toc; 1t0\) 1tEpvdt 0t1to 'to xoaxtvo cxu'to. T · T 0t 'EAOt'tlVWOTJ XOtl 1tA0tO'tlXIX EXpTJX'tlXIX 'tHlEV'tlltl \)1t0 µopcpiJ µtxpwv acp0ttp1xwv XOt1t0tXtWV µix,0tc; µrnx.;u 2 5 XOtl 35µy. (2) H auaxwij 110t 'tTJV EX'tEAEOTJ 'tT}c; 6ox1µcxaicxc; 0t1tO'tEAEi­ 't0t1 0t1t0 µ10t µix,Ot 1t0\) T AtO'tpdt µE't0t;u Mo pdt~owv Xlltt 1t0\) µ1topouv Vilt O't0t8Ep01t011j801JV OE X0t8op1aµivo u4oc; 1t'tWOTJ<;. 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To EXpTJ'tLXO u1to µopcpij acp0t1p1xou X0t1t0tXL01J (cxv 1tpoxEt­ 't0tt 110t 1tA0tO'ttxo) ri µE'tp1jµivo µE µi'tpo 1oµwa11c; 6uv0t'tO'tTJ­ 'toc; 0,05 xu~ EXOt't (cxv Eivcx1 xovtop'tWOEc; ri u1to µopcpTj 'tptµ­ µix'twv) 't01t08E'tEL't0tl 1tpoaEX'tlXIX µE'tcx;u 'tWV OIJO 't!.1-TJI.I-IX'tWV 'tOU 1161oxo1tdtvou 'tOU 01toiou 01 EmcpdtvuEc; E1t0tcpijc; OEV 1tpi1tE1 vex Eivcx1 u1pEc;. H Emxp0t't01Ja0t 8Epµoxpcxai01 OEV 1tpi1tEt vex ;E1tEpvdt 'tOuc; 30°c oun vex Eivcx1 xdt'tw cx1to 15 °c. Kdt8E oEi1µ0t 'tou Exp11 x't1xou 1tpE1tEL Vilt OEXE'tOtl 'tT}V auyxpoua11 µovov µtcx cpopdt. ME'tlX 0t1t0 xdt8E ooxtµcxaicx 'tO ljOLOX01t0tVO XOtt 'tO O'tEcpdtvt­ OOTJjOIJ 1tpi1tEt Vilt x0180tpi,OV't0tt oXOAOtO'ttXIX XOtt 'tuxov U1t0 AOl1t0 EXPTJX'tlXOIJ 1tpE1tEI Vilt 0tcp0ttpE8EL ~- 01 OOXLµ0taiEc; 1tpE1tEI Vilt 0tpxi,ouv µE u4oc; 1t'tWOEW<; 1tOU m8cxvov vex 1tpox0tAouv 'tTJV 0t1toAU'tTJ ixpTJ~TJ 'tWV 6ox1µcxaµi­ vwv EXpTJX'tlXWV. 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"Ev0t ;uAtVO XOU'tL 1tOU 1tpoa't0t'tEIJEI 0t1t0 'tilt 8p0tuaµ0t't0t µE EOW'tEptxij E1tEVOUOTJ 0t1t0 µoAIJ~t 2µµ 1tixxouc;, 'tO 01toio 0tvoi­ jEt EIJXOAOt 1tEptXAELEL 'tTJV auaxwij µixp1 'tO E1tL1tE00 'tTj<; XIX'tW "Evcx OIJO'tT}!.1-0t 0tvcxppocp1101Jc; Em'tpE1tEI 'tTJV 0t1t,O~OA1J OtE­ piwv Expij;Ewc; XOtt 'tTJ<; axov11c; 'tOU uA1xou. 3. TIEp11p0tcp71 xo1tdtvwv. Kdt8E xo1tatvoc; E)(EL Mo 0tuAdtx10t auvo6Ei0tc; 1tou 'tov OtOt'tT}­ pEi µE'tllt;IJ 'tWV EjX01twv 0Aia811a11c; X0t'tdt 'tTJV µE't0txiv11a11 'tWV (X1t0 EVOt 'tµijµ0t 0tv0tp't1jOEW<; £Vilt XIVTJ'tO XUA1v6p1xo lj0tO­ X01t0tVO XOtl EVOt OIJO'tTJ!.1-0t 1tllt1J0Tjc; 1tOU anpE01tOtEh0tt O'tOV xo 1t0tVO µE ~ioEc;, (EIXOVOt 11). 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ME'tlX 'tO OtACj)IXOLOtoµex 'tO\J 7tAEOVIXOfLex'tOc; 'tTj<; ME~oupexc; 'tO 6Ei,µex ex1t007tCX'texL fLE TT} ~0718Etex Evoc; !;uAexxtou. ftex ,:ex pEUO'tlX EXPTJX'tLXIX UALXIX, XPTJ­ OLfL07tOLOUfLE evex fLLXpo Oltj)WVIXXL 40 µµ 3 Arn't!X 'tEV'tO(J,EVO, To OEi,µex 't01t08E'tEL'texL O'tO OUO'tTjfLex xpouo11c; exvoLX'tO 'tO 01toio ~pioXE'tOtL O'tO Ev6tcxµEoo OtfLOVL fLE 'tO O'tECj)CXVL E7tLXE­ vi:pwoEwc;, xexL jLex 'tOt xovtop,w611 71 ~uµex,WOTJ UALXCX O cxvw Ot'tOIXALVOc; XUAtv6poc; 7tLE~E'tOtL 1tpooEX'tLXCX EAexq,pa fLE 'tOV 6Ei­ X't7I fLE)(pL VOt exni!;ouµE 'tO 6EijµOt, xwpic; VOt 'tO mE~OfLE oµwc;. ftOt 'tOt pEUO'tlX UALXIX 'tO avw Ot'tOCXALVO XUAtv6piixL mE~E'texL fLE µtex ouppOfLEV7I pix~OO µtexc; oupOfLEV7I<; ~ao71c; fLEXptc; ex1to­ O't0t0Tjc; 1 µµ ex1t6 ,o xai:w xuAtv6po xext 6tex't'JJPEt'texL 0,71 a,:ixa71 exu,71 fLE EVOt o,Eq,cxvt ex1t6 xocou,:aou, 1tou E)(EL 1tpo711ou­ µevwc; Eq,expµoo'tEL ElXOVex 13. To ouaTT}µex EXEl ,01to8E1:718Ei XOtL EmxEnpwBEi o,o ocµovL, 'tO 1tpOO'tOt'tE\J'tLXO !;uALVO xou,:i E)(EL XAELOEl, 0 x61t0tvoc; EXEl xpE(J,OtO'tEi O'tO ucj,oc; 1t'tWOEW<; 1COU EL)(E 1tpo~AEq,8Ei xexL ex1tE­ AEU8EpWVE'texL XOtL fLE'tlX ,iBE'tOtL OE AEL'toup,iex 'tO OUO'tTjfLex 0tv0tpp6q,71071c;. H OOXlfLOtOtOt E1texV0tAexµ~txVE'texl 6 q,opic; OE xcx0E ucj,oc; 1t'tW 071c;. 7. Epµ71vEl0t ,wv ex1to,EAEoµai:wv r LOt 'tT)V Ex,iµ71071 'tWV ex1tO'tEAEOfLCX'tWV 1:71c; ooxtµexoiexc; CJXE'tlXIX fLE 't7IV EUexto871ai0t OTT} OUjXpOU07I XIXVO\JfLE 'tT)V 6tex­ q,opix fLE't0t/;u «xexµµiexc; exv,iop0t01j<;» «ex7tOOUV8EOTj<;» (xwpic; q,A61ex ou'tE ixp71!;71, 1tou ocvocrvwpi~E,exL ex1t6 ,ov ;icp wµex,toµ6 71 'tTJV 00µ71 xm ixp71!;71 (µE ex1texA71 µexpt 6uvex,71 ixp71!;71) 1tex (J,Eptxa UAlXCX Ot7tOX'tCXfLE µi0t OtVCXCj)AE!;Tj xwpic; Bopu~o EXp7J­ !;71i:;~. H exv,i6p0t01j exu't'rj BEwpEi'text oµwc; oexv ixp71!;71 (xext 071µEt­ wvE,0tl (-LE ,ouc; 6pouc; EV'toc; ElOexjWjLXWV) 6tO'tL exq,opcx OAO 'tO 6.t1µoc XOtL u1t6 toiwv 1tpoii1to8ioEwv 71 ixp71!;71 6uvex,0tt vex 1i­ VEt). ftex vat µnp71oouµE ,71v wexL0871oi0t ou1xpouo71c; ,ou UAL­ xou, X0t8op[~OfLE 't7IV µa~ex 'tO\J X07texVOU OE "(X xext 'tO ucj,oc; 't7I<; 7t'tWOTjc; 'tO mo xexµ71M OE 7tOV'tOU<;, O'tO 01toio ucj,oc;, jLVE'texL i:ou).axtai:ov µioc ixp11!;71 xoc,a ,tc; i!; ooxLµexotEc;, 61twc; xexL O'tT}V EV~ pjELOt 'tOU X'tU1C7lfLOt'tO<; OE j 7tOU 1tpOXU1t'tEL. H EUexL­ a871at0t OTT} au1xpouo71,Ev6c; uAtxou Eivoct ,600 mo fLEjCXA7I 600 Tj EVEpjELex i:ou xi:u1t71µexi:oc; OE j Eivext mo xexµ71).71 (J = JOULE - TZOYA). &oxtµexoiex 'tT)c; Euexto871oiexc; 0,71v ,pt~71 (~AE1tE 1tEpt8wpw 3103 (J,EXfJl 3110 XexL 3112), Ot. &oxtµ0taiex 'tpt~71c; µioex OE ,ouoi ex1t6 1topoEAIXVTj, (I) TO EXp7IX'tlXO 1tpE1tEl vex ex1to!;71pexivov'texL OE X Awpwuxo OtO~EO'tl. 'Evex OEi,µex 'tOU EXp7IX'tLXOU ouµme~E'texL xexL ouv,pi­ [3E'texL µioex oE ivex 1ou6i 0t1t6 1topoEAIXV7I (µ11 1tEpexoµivo fLE [3Epvixt) fLE evoc t16wx61t0tvo (t0 01toio E1tio71c; 6Ev EXEL 1tEpex­ a,Ei fLE [3Epvixt). To rouoi xexL 'tO LjOLOX01texvo 1tpE1tEL VOt E)(OUV 8Epµoxp0toiex 1tEpi1tou 10 ° ucj,71A6,Ep7I 0t1t6 ,71v Emxpex,ouoex 0Epµoxpocoiex. (15° C fLE 30° C ), • • Tex 0t1tO'tEAEOµexi:ex ,71,; 6oxtµexai0tc; ,iBEv,ext oE 1texpexAATJAL- 3156(2) aµ6 fLE ,ex ex1tO'tEAEOfLex'tex 1tou Aexµ~cxvov,ext fLE ,o Exp71x,Lx6 au1xpioEwc; xext otexxpivov,ext we; E!;TJc;»: L. XOtVEVex Ot7tO'tEAEOfLex, u. Ao0evEic; µEµovwµivm xpoi:exAtoµ,oL m. l:u;icvoi xpo,OtAtaµot 71 1t0Au ouvex,ot µEµovwµivoL xpo­ 'tCXAtoµoi. 3. Tex Exp71x,txix 1tou xex,cx ,71v 6oxtµexoi0t 6ivouv ,:o ex1to,i­ AEoµex l BEwpouvtexL we; oXEOOV fLTJ wexto871,0t O't7IV tpL[.371. ElEwpouvtexL we; (J,Eaexiex Euexto871,0t exv oivouv ex1tO'tEAEoµex Lt. BEwpouvi:ext we; 1t0Au wexio671,ex o,exv 6tvouv ,o 0t1tO'tEAE0µ0t m. ~- &oxtµexoi0t fLE 't7IV OUOXE\J7I 'tTj<; 'tptf.371,; ( ELXOVOt 14 XCXL 15). I H 6oxtµexot0t 7t0U ocvexq,epE'texL O'tO ex 6uvex'tOtL vex exv,Lxex,ex­ O't0t6Ei fLE TT}V E!;71c; 6oxtµexot0t. 2) IlEpljp0tq,71 't7I<; OUOXEUT)<; H auoxEu71 ,71,; ,ptf371c; ex1tO'tEAEt'texL ex1t6 µtex iµf30to7J OE :X,U'tO ex'tOCXAL rnavw O'tTJV 01totex 't01to6E,71871xE 'tO i6to au­ OTTJ(-lex TT}<; i:ptf.371,; 7t OU ex1tO'tEAEh0tL ex1t6 o'tEpEa pcxf.360 1topoE­ AIXVTj<; XOtL XLV7l't'rj 1tAexxhex ex1t6 1topaEAIXVTJ, ( ELx6v0t 14 ). fLOt fLEptxa UAlXIX EXOfLE «µLex exvaq,AE!;71 xwptc; 86puf3o Exp71!;Ewc;» Aui:71 Tj exvi:i6p0to71 llEwpEi,ext we; oexv exp71!;71 (xexL Otvexq,epE,exL fLE ,ouc; opouc; Ev,6,; ELOOtjWjLXWV, OLO'tl OtvexcpipE­ 'tOtL aE 6).o to OEi1µex XOtL 6t6,t u1t6 ,Le; iotEi:; 1tpoii1to8EOEti:; µ it!)-. pEi vex 071µEtw8Ei 71 ixp71!;71. H 1tAaxex 1topaEAav71c; o,Epw 1tOLEh0tL OE evex exµoc!;cxxL 7t0U 0671,EhOtL OE 6uo EXj01tE<; OAi­ a87101jc;, &tat µioou µtexc; µmiAAexc; EVOt fLE'tex'tpE7t'tLXO op,exvo 'tCXAexV'tEUOEW<; xexL ivex ,pexvaptaµex 'tO ocµex!;cxxL ,iBE,exl OE xt-. V7IOTJ fLE 7IAEX'tptx71 µ71;icexv71, excpou 'tO exva[3ouµE fLE 6texX07t't7I (-LE 1ttEa71, wo'tE 71 1tAixxex 0t1t6 1topaEAav71 EX'tEAEt xix,w ex1t6 'tTj paf.360 1topaEAcxv71c; µtex xtv71071 1t711extvE-EAex» 10 µµ µ71xouc;. H [3aa71 TT}<; pcx~oou 7tEpLO'tpECj)E'texL ,upw ex1t6 ivex ii!;ovex jLOt vex Em,pex1tEt 71 illex,71 ,71,; pcxf36ou 1topoEACXVTj<; 1t0tpextEtVE'texL Ot7t0 f3p0t;iciwvex f30tpwv fLE ii; EjX01tEi:; jLex 't7IV 0tvap,to71 µtcxi:; µa~Otc;. H taoppo1tiex O't7I 8io71 µ716Ev (xwptc; [3ixpoc;) 1tpex,µex­ 't01tOLEh0tL Ot7t0 µiex µa~Ot taopp61t71071c;. 'O,exv 71 ~IXOTJ 'tTjc; pcx­ [36ou ,01to6EtEh0tt OTTJV 1tAcxxex ex1t6 1topaEAav71, o Emµ71x11c; a!;wv TT}<; paf36ou ex1t6 1topoEACXVTj EivexL xii0E't0<; O'tTJV 1tAaxex. Mt0t EX ,:wv µoc~wv exvocp,cx,ext µiow ex1xuA71c; 0,71v 1tpo[3AE1to­ µEv71 EjX01C7I, To ~expo,; 'tTj<; pixf3oou xuµexiVE'texl fLE'tOt/;u 0,5 xexL 36 K,. 3) Ilept,pexcp71 ,71,; 7tAaxexc; xexL 'tTj<; paf.360 1topaeAav71c; Ot 1tAaxEc; ex1t6 1topoeAixv71 xex,exaxw&a,71xexv ex1t6 'tEXVLX7I AEUX7I x0t6exp71 1topaEAIXVTJ 1toui:x,ouv ,Le; e!;71c; 6texa,iiaEti:; 25x25x5 µµ. Ot 6uo mq,ixvmc; tptf371c; 'tWV 7tAOtXWV exouv 1ivEL (1tptv to cj,71otµo) 1t0Au ,pex;icEic; fLE 'tTJ [30718uex ,pL[.371,; fLE EVOt oq,ounapt. To 1tepexaµex aq,ounexpwu· dvOtL TCOAU q,exvEpo. Ot XUAlVOptaµoi Otte; pix~oouc; EtVOtL E1ti01jc; ex1t6 'tEXVLX7I AEUXTJ 1topaEAav71. 'Exouv µ71xoc; 15 µµ xext 6tixµE,po 10 µµ, xexL OL exxp0ttEc; Emq,avELEc; ,pexxdc; a,pOjjUAE<; fLE exx,ivex xup­ 'tO'tTj'tOt<; 10µµ. &Ei1µex,:oc ,wv pixf36wv xext 1tAexxh,wv 0t1t6 1topaEAIXV7I exu 1:Tjc; TT}<; 1t0lO'tTj'tOt<; 7t0\J 7tEpt,paq,E,exL exvw,ipw X0t'tex,E071xexv OTTJV •BUNDESANSTALT FUR MATERIALPRUFUNG» O'tO BEpoAivo DAHLEM, xexL µ1topEi vex 6waEl 't7IV 6tEu8uva71 'tWV XOt'texaxEUexO'tWV. E1tEL07I TJ ix6LX't7I q,uoLX7I 1:pexxu,71,; 'tWV 7tAexxwv xexL pix­ [36wv, 0t1tou).ouv xupt0t 1tpoii1t66Ea71 1 tex ,71v exv,i6pexa71 ,ou 3156 EXp7IX'tlXOU UAlXOU, xa0E ,µ71µex Emq,0tvEiexc; 1tpE1tEL vex XP7IOL­ (J,01COl7l6Et (J,OVOV µtat q,opa. l:uvE1twc;, ot Mo ocxpextEc; Eritq,avmc; Exiiai:71,; pii[36ou 0t1t6 1216 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 7t0pGEA<XV'lj rxpxouv jLO( "Mo 6oxLµrxGiEc;, ot 6uo Eiticpavmc; ,pL­ (371c; µtrx<; ltAO(XE't'tO(<;, EX<XG'tTJ jLO( ltEpiitou 3 ewe; 6 6oxtµrx­ GLEc;. 4) Ilpoa,otµrxGlrx ,wv 6at:yµa,wv T rx EXPTJXnxci UALX<X 6oxtµa,OV't0(l GE l;Tjp<X XO('t(XG'tO(GTj. 'tO( uAtxdt ,ou itapt0wptou 2101, llo iwc; 140, 6oxLµa,ov,rxL OltW<; 1trxprx6i60V't0(L Ecp' OGOV TJ ltEptEX'tlXO'tTJ<; 'tOU<; GE VE po OCV'tO(ltOXpivnrxL G'tTJV itprx,µrx,LXTJ rxl;trx ltOU rxvrxcpipE'tO(L 0(7t() 'tOV XO('totGXEUO(G'tTJ. • Av TJ ltEptEX'tlXO'tTjc; GE VEpO fLVO(t fLEjotAU'tEpTJ, 'tO( µt,µrx,ot 0rx 1tpi1tEL vrx rx1tol;7Jprxlvonrxt itpLV 'tTJV 6oxtµrxGtrx fLEXPL vrx cp0ciGat ,o ltOGOG'tO u1prxGirxc; itou rxvrxcpipnrxL. EmitAiov 1Lrx ,rx G,apEa uALXa- 1tiprxv rxito ,rx ,uµrx,w6TJ 1tpi1tEL vrx GTJfLELWVOUfLE 'tO( El;71c;». 0(, Trx xovtop,w6Tj UALX(X XOGXlVL,OV'tO(L (avot,µrx XOGXLVOU 0,5 µµ) 6, ,t itEpvci rxito ,o xooxwo XPTJGLfl-OltotEi,rxt 1trx 'tTJV 6ox1µrxGirx. (3. Trx GUfLlttEGfLEVrx UAtxci A~twµivrx 1J xrx'tci xaitoLo aUo ,p61to Gu1xanpwµivrx xoµµrx,ta,ov,rxL GE itoAU µtxpa xoµ­ µrx,cixtrx XO(t XOGXLVL,OV'tO(L. ·o, 'tl ltEpvix otltO 'tO XOGXLVO fLE cxvot1µrx 0,5 µµ XPTJGLfLOltOLEi,m 1Lrx 'tTJV 6oxtµrxGlrx. 5) Ex,iAEGTJ ,wv 6oxtµ0tGLWV Mtot 1tAcix0t OtltO itopGEACXVTJ G,apwitoLEi 'tOtl G,o 0tµ0tl;ixxL 'tT}c; GuGxEu71c; ,ptf371c;, WG,E ,et iXVTJ ,ou Gcpoun0tpiGµ0t,oc; vet ELVott EjXCXpGtot G'tT}V XOt'tEu0uvGTj 'tTjc; XLVTJGTjc;, H ltOOO'tTjc; ltOU 6oxtµa,E't0tt ELVOtt 1tapl1tou 10 µµ3 Xotl µa,piX'tOtl jLOt 'tOt xo­ vt0p-rw67J UALX(X µa XUALV6pLXTJ fLE,oupet (2,3 p x 4 µµ) jLOt 'tOt ,uµot,W6Tj UALX<X 'tO 6ai,µot fl-E'tpcx,Ott fLE XUALv6ptx71 GWATJVIX 7t0U )(WVE'tlXl O'tTJ µa,IX. Acpou 1XCj)1XtpE0Ei 'tO ltAEOVIXOfl-lX 'tT}c; µa­ ,ouprx<; 'tO 6EijµIX OtltOOltlX'tlXt fLE EVOt l;uAIXpiXXt XO(L 'tOlt00E'tEL­ 'tlXt O'tTJV ltAIXXIX otltO 1tOpGEAav71. L'tT}V ou1xav,pwµivT} itooo­ 'tTj'tot ,oito0a,ouµE 'tTJ pixf36o otltO itopoEAIXVTJ itou Eivott jEpa nv,wµivT} 61twc; O'tTJV atxOVIX 15. 0 f3P1XXLWVIXc; 'tOU (3ixpouc; EPfLIX'tL,E'tlXl fLE 'tTJV 1tpof3AEltO­ fLEVTJ fl-lX'IX XIXl falXXOlt'tTJ<; lttEOEWc; ,i0E't1Xl GE AEl 'tOUpjilX». IlpiitEL VIX itpooix ouµE, TJ pixf36oc; VIX (3pioXE'tlXt O'tO 6EijµIX xett VIX uitixpx Et µitpoo,ix ,Tjc; E1t1Xpit71c; 1too6,7Jc; UALxou itou 01X 6oxtµ1Xo'tEi jtlX VIX epx.E,IXt xix,w IXltO ,TJ pixf36o 6,IXv xLVEL'tlXL TJ 7tAIXXIX. 6) EpfLTJVELIX 'tWV IXltO'tE).Eoµa,wv. fLIX 'tT}V EX'tLfLTJOTJ 'tWV IXltO'tEAEOfLIX'tWV XIXVOfLE 6LaxpLGTJ fLE'tlXl;u «XIXfLfLLIX<; 1Xv,i6p1Xo7Jc;» «IXltOOUV0EGTjc;» (x.pwµ1Xnoµoc; 00µ71) «IXV<X(j)AEl;Tjc;» «XpO'tlXAlGfLOU» XIXL «iXpTJl;Tjc;». H OX,E'tLXTJ fl-E'tPTJGTJ 'tTjc; EUIXL007Jol1Xc; O'tTJV ,ptf371 avoc; UAl­ xou EV'tO<; 'tTJ<; OUGXEU1jc; ,pL(37Jc; OltW<; ltEpljp<XCj)E'tlXL XOtl EX­ cppiX,E'tlXL x.wpic; VIX ATJcp0Ei uit' o4TJ O OUV'tEAEG't7Jc; ,ptf371c;, fLE 'tO fLLXpo'tEpO (3apoc; EltL 'tTjc; paf36ou EXCj)plX,OfLEVO OE Xj O'tTJV 01tol1X µaooA1Xf3Ei XIX'tlX ,tc; al; 6oxLµ1Xoiec;, ,OUAIXX,LG,ov fLLIX. q,opix fLLIX IXVIX({lAEl;TJ, iv1Xc; xpo,ixltoµoc;, µi1X ixpTJl;TJ. Il1Xp1X6ex oµa81X 7167J on TJ IXVIXCj)AEl;Tj X<Xt Ot xpo,IXAlOfLOi ei­ VO(t amxiv6uvac; IXV'ttl'ipixoatc;. H EUIXLG07JOLIX O'tTJV ,pLf37J avoc; EXPTJXnxou UALXOU, ELVIXl 'tOOO mo fLEjlXATJ OGO 71 XIX01Xpl,OfLEVTJ 1Xl;i0t 'tOU (3ixpouc; O'tTJ pixf36o (fLIX~ot cp6p,wo7Jc; ox mxix fLE ,o fLTJXOc; o,u f3potx[wv0t (3ixpouc;, ltOU ELVOtl mo fl-lXpo. Tet pEUa'tlX EXPTJX'tlX<X XOtL 'tOt UALXIX ltOU exouv ,uµ0t,W67j cpuGTJ 6av alvott jEVLX<X au0tio87J,0t O'tTJV ,ptf37J uito ,Le; 1tpoii1to 0iow; IXU'tTJ<; 'tT}c; 6oxtµ0tGi0tc;, 6Lo,L 71 EAIXl(LO'tTJ 0ap1-1oxp1Xoi0t ,pL(371c; itou 1t0tp<XjEL 6av etpxai, we; ouvix ELOt ,Tjc; 1)..olwo7Jc; jLOt VOt jLVEt TJ OtV<XCj)AEl;Tj, Me 'tot UAtxa 0tu,ix 71 0t1touol0t 0tv,i6p0to7Jc; 6Ev EivetL f,LLOt iv 6Etl;Tj o,L ,o UAtxo aivetL 0txiv6uvo. H a'tet0Epo'tTj'tOt 'tWV ltpOtOV'tWV ltOU 0(V0tjp1XcpoV't0tl O'tO ltE­ pt0wpto 3111 EAE"(Xt'tlXt OUfLCj)WVot fLE ,Le; XOtVOVLXic; µa066ouc; ep10to't7Jpiwv. ~ox11-10toi0t 0tcpl6pwo71c; .,wv 6uv0tµt,wv itepL0. 31.07. 1. H ouoxeu71 jLOt 'tTJV 6ox11-10toi0t 0tcpi6pwo7Jc; ,wv 6uv0tµ1 'tWV ( atx6v0t 16 fLE 18.) OtltO'tEAEL'tOtL Otlto xoucpto xuALv6po Otlto µitpoun,o. 0 XUALVl'ipoc; OtU'toc; 0 Oltoioc; ELVOtt XAELO'toc; OtltO 'tTJ µlet 3157 3158 7tAEupa OtltO 6ioxo 'tOU t6lou fLE'tlXMOU, EX.El EGW'tEpLX7j 6Laµe­ 'tp0 15, 7 µµ XOtt (3a0oc; 401-11-1- "Ex.al ,pUitTj0Ei OE 20 GTJfLELOt OtltO 0,5 fl-fL l'iL<XfLE'tpO (4 OEtpec; 'tWV 5 ,puitwv) O'tTjV 1tEplcpE­ pEt0t. 'Evet µ1tpouv,~1vo xuAtv6pLxo iµf30Ao aiti 48µµ 1tou EX,EL OUVOALXO utj>oc; 52µ1-1 6uvet't0tl VOt jAUo,pix O'tOV XUALV6po ltOU 'tE07JXE xdt0E,Ot, etu,6 ,o iµf30Ao µa 6tixµE,po 15,6 µµ EX,Et amf30tpuv0El µa fLlet µix,et 2,220 iP· won vet 1tpox0tAEOEt 1tlEGTJ 118 KPA (1,18 BAR). 2. ~Letµopcpwvouµa fLE 5, - 8,p 6uv0tµi't7J ivot fLLXpo AOU­ X<XVLXO 30µµ µ71xoc; xett 15 µµ 61ixµE,po itou ,uAl1oµa oa ltOAU AElt'tO ltOtVi XOtt 'tOV 'tOlt00E'tOUfLE O'tOV xu ALv6po. ME,IX 't01t00E'tOUfLE EltlXVW 'tOU 'tO EfL{30AO XOtL 'tTJ µa,Ot Emcpop'tWOTjc; . ,ou wo,E o 6uv0tµi,7Jc; vot u1tof3A7J0Ei oe itiEOTJ 118 KP A ( 1, 18 BAR). L7Jµe1wvouµa ,o x povo o,o ,iAoc; ,ou 01tolou aµcp0tvl,ov,0tt 'tOt 1tpw,0t LXVTJ EAOttw6wv O'tOtjOVWV (vt,pOjAUXEpiv7Jc;) one; el;wnpLxic; oitic; ,wv 01twv ,ou xuAiv6pou. 3. H 6uv0tfLi'tT}c; 0EwpEh0tL LXOtVOltOLTJ'tLXTJ etv o XPovoc; itou 'tpEX,EL itptv 'tTJV EfLq><XVLOTJ 'tWV pEUO'tWV Ll'ipwµa,wv ELVOtL OtVW­ 'tEpoc; 0t1to 5 AElt,Ot. H 6oxtµ0toi0t 1ivE,OtL oE 0EpfLoxp0toi0t l5°C µe 25°C. ~oxLµ0toi0t x0tto7Jc; fiopL0WpLO 3154 j, :-' I : • • I I I (;)--------1 : I g : . ..... ELxovet I. A,o<XALVO XOU't<XXL, (itixx oc; .. ,OLX, 11-11-1) 6LOtO't, GE fLfL·) 1) jEVlXTJ Otj>Tj , 2) XIX0E'tTJ 'tOfLTJ 3) 'tOfLTJ A-B 4) AVIXlt'tUl;Tj 'tOU 'tOLX,WfLOt'tOc; 5) Avixmul;Tj 'tTj<; (3aG7Jc; XOtL 'tOU XOtltOtXLOU 6) X,EiAoc; itou 6mAwvE,0tL. 3159 3199 <l>EK 104 (!) 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Kou'ti 1tpoa't0t'tet>'ttx6 cx1to 0pcxuaµcx'tcx. 9, 2 p<i~1iot ytcx 'tTJV CXV<Xp'tl07j 'tOU 'f)UOlj"(tOU, 10. ~uvcxpµoloyouµevo q>uaint, 11. 0fo71 xcxua't~pcx 't01to8e'tT)f1.EV7J 1tiaw. 01 <iUot xcxua't'T)pec; eivcxt w1to8e't7Jµivot EfJ.q>Otvwc;. 12. Kcxv't~At. 1217 / :,.;.:.. . 1218 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI .6EYTEPO) .1oxtµocoicx 0ipµcxvaric;; o' ivcx 6oxeio µe 1tiiari, 6ioxo xev-rptxoti cpw,oc;; xoct µeµ~pdtvri (et<; 1tept8 3154,E • l ! J .... ®--~ e-----v~a..1-i ::~~~ @' ~ ®' ----tll~:Y Etxcivcx 4 .1oxoio mfoewc;;. LuvcxpµoAo1otiµevo. Lx71µcx,txic;; ci4etc;; OE xcx8e-r71 X07t7j l((Xt OE !1tl1t!60. • 1 Aoxeto 1ti.071c;; ( OE cxvo!;d6w,o (X'tOIXAL) Etxcivcx 5 .1ox-to miaew.;. (lcx) 1u1xoU71µev7J ivW07J. 2 Y 1to6ox7l ~i6cxc;; 1tou emxcx).ti1t,et ( ou,xo).71µµivo cx,odtAt). 3 .1iaxoc;; XEV'Cptxoti cpw,oc;; (cxvo!;ei6w,o (X'tOIXAL). 4 (Xl(LVTj't"Tj pooeUa; ,cxpvt,oupcxc;; 7t0t;(OU<; 0,5. 5 Acxx,uAto<; miaewc;; (cxvo~eiow,o cx,odt).t). 6 Acx~Tj opeixcx)..xou. 6cx. Bi6cx opetxcxhou (uAtxci M4 x 8 DIN 88) 7 Meµ~pdtv71 6tdtpp71!;7Jc;; (1ux ,o UAtx6 ~Ai1te 1tep 3154-E,2 8 Y1to6ox7l ~iocxc;; µe mcxotp0tXL(X (opEl;(CXAXO<; M 6 DIN 315) Bex. Acxx,ti).wc;; opeixdtAxou 6 DIN 125) 9 M 7tOUAOVt µe µcx,t ( cxvo!;ei6w-ro (X'tOIXAL) 10. 'A!;wv 1tcx ,71v u1to6ox7l •'l'jc;; ~i6cxc;; µe mcxo,pdtxtcx (cxvot cx,odt).t). 'Eva: cxvo!;Ei6w,o cx,odtAt itou cxpµo,Et µ1topei voc exet n1v E~Tjc;; otiv 8eo71 CR 18%NI 9%Mv< 2%, St< 1%,0< 0,12%. . . .. E<DHMEPll'. THI KYBEPNHIEQI (TEYXOI AEYTEPO) fl{))HµaoC O'. BepµavaT)<;;; OE oo'x,£ CO TI I. £0EW«; µE oC 0)1.0 'X. E:V1:pl.'KOU TW't6«; MO'.L µEµ~p&vn ( EL«; TIEp 3154 E) E1.'Kova 6 ~eot1:UALoc; n:1.foEwc; 1:ou 6oxeCou AEn~oµepE1.ac; oe x.a-8-E'tf) KOTI~ XO::l. en:CnEOT) .(61.a:o'taOEL<; OEµµ) 1219 1220 E<l>HMEPII THE KYBEPNHIEQI (TEYXOI ~EYTEPO) , , µs xonavo ouyxpouoEwc; ELKOVO: 7 0£ µµ , , , A. BO:OT) cmo 'tOLµEV't"O B A 't' OCX/\. I, VO µnAox r , npo O't'CX't E U't"I, XO c; xuil.1,v6poc; Iy6oxono:vo , D avw µspoc; Iyoox6no:vo , , E XO:'t"W µspo c; . . . • "A. . ... . . . . I •· I . . . c. ... , . . . ·. . . . ' , .. . . ---·-r .... • -·· -. . ·. .. . • . . ' . . , , , xpouaT)c; xa~E'tT) xonn, 01,0:0't"QOEL<; OEµµ EG>HMEPlt THr KYBEPNHrEor (TEVXOt AEYTEPO) , f:IO'KLµCXOl,CX 'WU it.OTIO'.VO·U ouy>-<.pOUOT)~ II ,o 0 Etxovcx 9 xo1tcx11oc; airyxpoua7Jc; II f EIILX~ 04TJ CX7t0 (L7tpOO"rlX XCXL CX7t0 7tAIX"(tCX otcxa-rixaEtc; aE µµ 1. 'Eµ~CXOTJ 450X450X60 ® 2. A-radtAt110 µ1tAox 230X250><200 3. Aµovt 1000 X70 4. K0Aw11cx 5. Mfo7J -rpcx~ipacxc; 6. 2 E"(X01tec; OAt007Ja7Jc;. 7. 06011-rw67Jc; pdt~ooc;. 8. ME,oupcx 9. Komx11oc; 10. LUO"rTJ(LCX cx11cxp-r7J07Jc; XCXt CX7tEA.u0epwa7Jc; 11. I1Acitxcx E7ttXE11"rpwa.wc;. 12. Ev1ltdtµeao cxµovt (E110tAdt;tµo) 26 0 x 26 13. Lncp1X117J E7ttXE11-rpwaEwc; (LE Ot1hpt07j (01t~) 14. LUO"rTJ(LCX xpoua7Jc;. • ( EI.~ nEp 3155~ . r' . 100' I . I I I Etxo11cx 10 X07tCXIIOc; auyxpoua7Jc; II xdt-rw µepoc;. • 1221 ··r • ~« 1222 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI '1EYTEPO). , , , 60H L µaoL a HOTI((VOU ouyxpo UOY)<; II 0 0 , E1.x.ova II (x.onavo<; ) µa~a 71:fDWOT)<; 5 Ky. I) TµDµa av&p-rrioric; 2) avayvwpL O'rl,'KO OY)µEC o uq;ovc;. 3) E)'XOTID ooriyou 4) IyooKonavo -xvALVOpLKO 5) Euo-rriµa nauari<;. E<l>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: dEYTEPO) 1223 EntrHMH META<t>PAtH , , , IT TRADUCTION OFFICIELLE L'iOlU.µ0:01, a x.onavou OU')'XPOUOT)£ ( ELS nEp 3155 ~,. ,a-:s:1 r--;----1 ~ffil i..-,,---1 w EL'XOVCX I2 Euo1:~µa -xpouons yLa x.ov1,op1:w6n T) ,uµa1:won u~1,x& OLCXO't<XO£Ls OE µµ Ei.xova- I3 . 2 I:'tECJ>CXVT) ouvooEC a<;- j'L a: a:1:crM L vou<; xuA. C v6pou<;. ;t 3. L'tEcpaVT) £'JtLXEV'tpWOEWs µE OTTT). , a xa-8-E'tT) XOTTT) ~ e:nCne:on 4 , , , E'te:cpaVT) crno XCXOU't"OOU'X 5 PE~O'tO UALXO (40µµ3) 6 OLO:O'tT)µa xwpC<; pe:uo;o 11111111 To Cl'tOML OU\/Cl't'O:L Va: EXEL 'tT)\I El;T)<; cruv-8-EOT) CR j: I, 55% C 3: I, 0% a:v Ma:l; O, 25% , MV 3: O, 35% HRC 58 , •...... 65 ( CX'tOML crno -8-EpµLx~ OLEpya:aCa). 1224 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) @ ® ELxOva 14 , 6 , , E1Cl,7tE T) li.UL xa-S:E'tT) 'K01CT). I) a-roaAt, VT) Eµl3aoT) 2) }i.l, VT)'tO aµa~roi.L 3) re A ox a am5 no p OEA o:vT) Q) @ ~ Q) I Q) I @ I E1.x :'ova: 15 8EOT) a:vaxwpT)0T)<; ~T)c; p&Boou a-ro oECyµa ~5X25X5 µµ o-re:pe:ono LT)µEVT) o-ro aµal;rotL 4) I09> X I5µµ j.tiECyµa rcou -S:a el;e:'ta:O'te:C nc:pCrcou I0µµ3 6) LUO(j)L')'X 't·rjpo:c; pcxl30Ci1JV. 7) BpaxCwvac; f3apouc; 8 )Ma:?,:a L 00 ppon C o:c; .. · 9) ro) , LH, ax. ore TT) c; Mav1.l3EAAa y1,a 'tT)V pu-&µ1,oT) 'tou aµal;1,ou oe: -8:EOT) avaxw pT)OT)~ • II} Tipo~ 'tTJV T)A£WtpLKD µrixavi,. Cl>EK 104 E1,x6va I6 ECJ>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: 61:!VTEPO) 1225 (Et.<; nE:p 3158) a ... In "' Cl) CD .. ltl 'tWV ouvaµt.'tWV I I I I I ~- --- -- - -- - · <: .'-:7-'-'r-~~~-Y.,lt---'­ I ' 1 . I I ' I I I I I I ..,.E L x o v a:.:... --'I:::...!.7 : Bex.po c; a£ µo p cpn . x, aµ n a:v a:<; , 2 nou 6uva-rat. Ma:C:o: 22 C 'YP VO: avap'tD~EL C'tO µnpovv-rC:t.vo Eµ~OAO. I i i" I . I .. ,. . I I Koucpt.oc; µnpou'tl';t.voc; X.UAt.Vopoc; X.AEt.·aµfvoc; ano 'tT) µt.a: TIAEUpa:. En:CnEooc; µE X.O:~E'tD X.OTID 01.aa--ra:0£1.c; OEµµ Et.x.ova IB Mnpou't~l,VO X.UALVOpt.XO Eµ~OAO I 4 0£1.pEc; ano 5 onfc; 'tWV o,5 ~ 2 XaAXO<; 4 4 avo C yµa'ta , , , , nEpt.nou 46 X56 TTOU Et.Vat. X.O:VOVLKO: ax.opnt.aµEVO: 1226 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) TI0tplXO'tTjfLOt A. 2 A. Lxmxic; a67Jyitc; fLE 'tTJV qJUOTJ 'tWV 6ax Eiwv Ot7CO xp1XfL­ fLOt't0t OtAaUfLLiliau jLOt fLEPLXIX cx.iptoe 'tTJ<; 'tlX;Tjc; 2. r. na1onic; ul1xau I. Toe UALXIX 'tWV 6axtiwv oe1to xplXfLoe OtAaUfLLViau 1tau riva­ V'tOtL 6tX'tlX 11oe 'toe oeip1oe 1tau oevoeqiipav'toet o'ta 1tEp18wpt0 2203. 2,B. TipE1tEL voe 1xoeva1ta171oauv 'ttc; E;71c; oe1toeL't710ELc;. Avtox,~ OTIJV EA~Tj RM OE A B C D MPa(=N/µµ2) 49 JJ,E 186 196 JJ,E 372196 JJ,• 372343 JJ,E 490 opto EJ,Lipavotii; EA(.( G'tLXO'tlj't(.(c; RE a. MPa(=N/µµ2) (µo VLJJ,Tj 1tapaµopipWOTj ).=0,2%). 10 JJ,E 167 59 JJ,• 314 137 JJ,• 334206 JJ,• 412 EltlJJ,~XUVOTj O'tTj p~~Tj (1=56)% 8oXLfL~ Aurioµa,oi; (6ui1mpoi; ,opvou 6=V.E 12 JJ,E 40 V=5 (Rµ~98) 12 JJ,E 30 12 JJ,E 30 11 JJ,E 16 V=6 V=6 V=7 (Rµ~325) (RJ,L~325) (Rµ~392) E= 11iixoi; 'tljc;. 8ox1µaa,tx~c; owA~v~. ap19. aupiic; tT}c; AMERICAN ASSOCIATION V=6 V=7 V=7 V=8 (Rµ>98) (Rµ>325) (Rµ>325) (Rµ>392) 1000 5000 6000 2000 *B)... •ALUMINIUM STANDARDS AND DATA» 57j ix6ao7J Ioevau<iptac; 197 6, 07JfLaoiwo7J oe1to 'tTJV «AL­ UMINIUM ASSOCIATION, 750, 3MB. Nioe Yopx7J. 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M10t EA<X)(.LO'tTJ oetioc emµ71xuvo11c; mo µ1xp71 1ive1:oe1 1t0t­ poc6ex'tiot, eqi' ooav µ1oc ouµ1tA71pwµ0t'tLx71 6ox1µ711tou qxpi­ vnoc1 oe1to 'tTJV oepµo610t OtPX71 'tTJ<; x.wpoec; 01tau xoe'toeOXEUOt,0 V'tOtL 'toe 6oxeioc, oe1ta8ttXVUEL O'tt 7J oeoqi0tAELOt 'tTj<; flE't0tqiopixc; EtocoqioeAi,E'toeL U7CO 'tWV t6iwv 1tpoii1to0foEWV µE 'tOt 6ox.Eioe 1taU XOt'tOtOXEU<X,OV'toet OU(lqJWVoe flE 'tL<; oe;iEc; 'taU 1tiV0tXOt ( U1t n. . (3) To EAOLX,tO'tO 1t<ixac; 'tau 'tOLX,Wµoe'tOc; 'tWV Box.Eiwv O'tO mo ocBuvoe'tO 07Jµtio 'tau 1tpE1tEt VOt EiVCX.L 'tO E;71c;: 'O't0tv TJ Bt<iµt'tpoc; 'tau BoX,Eiau Eivoct µtxpo'tEPTJ 0t1to 50 µµ 1,5 µµ 'taUA<XXtO'taV, 'O'tocv 7J Bt<iµnpac; 'tau 6oX,Eiau Eivoct 0t1to 50 µµ µiJ(pL 150 µµ 2 µµ 'taUA<XX,tO'tOV. • • 0 O't0tV 7J BL<Xf.lE'tpac; 'tOU 6aX,EtOU EivoeL flE,oeAU'tEPTJ oe1to 150 µµ, 3 µµ 'taUA<X'X LO'tav. 4. Ot (3<ioEtc; 'tWV Box.Eiwv eoc EX,OUV Tjµt-1tEpto'tpoqi1xo 1tpaqii).. 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'O't0tV 1tpoxeL't0tt 110t xp0tµ0t oeAouµ1viou X,OtAXau, 7J 6ax1 µocoi0t yivE'tOtt Ot7t0 'tav XOt'tOtOXEUoeO'tTj Xoe't<X 'tTjV Emxupwo7J E<l>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) evoc; vfou xp0tµ0t'toc; Ot7t0 't7IV 0tpµo6t0t OtPXA 00t m0t110tA71cp0d XOt't' OtXOAOu0i0tv XOt'tlX 't7JV 1t0tp0trwr71 '(tOt xa0e xumµo 'tOU ·Xp0tµ0t'tO<;. 3. "O't<XV 1tpoxm0tt 1t0t xp0tµ0t OtAouµtviou / µ0trv71aiou, 71 6oxtµ0tai0t •1LVE't0tt Ot7t0 'tOV XOtt'OtlJXEUOt1J't7I XOt'tlX 't'TjV E1ttXU­ pwa71 EVO<; VEOU xp0tµ0t'tO<; X0tt 7I 6t0t6tX0t1JL0t X0t't0tOXEU7I<; 0t7t0 't7IV 0tpµo6t0t 0tpz71. H 6oxtµ71 m0tVOtA0tµf30tVE'tOtt O'tOtV Emcpe.pE­ 'tOtL 'tp07t07tOL7lllTJ O't7I OUV0E07I t'OU xp0tµcnoc; 7I t'Tj<; 6t0tfox0t­ oi0tc; XOt't0tOXEU7I<;, 4. et) Ilpon0tµ0tai0t xp0tµ0t'tWV OtAouµtviou / zrxAxou. Ilptv V(X 6oxtµ0tani 'tO xpaµrx OtAouµtviou / xrxhou O't7III 6oxtµ71 6t0t(3pwa71c;, 'tOt 6d1µ0t't0t xrx0rxpi,011-r0tt rxno ,rx Ain71 'touc; µfow o:pµo~OVt'oc; 6t0tAUt'OU xrxt OtXOAou0wc; rx1to!;71prxivo­ V'tO:t. B. IlpOE't0tµ0toio: xpo:µa-rwv O:Aouµtviou / M0trv71aiou. Ilptv VO: uno[3A710ei t'O xpaµo: rxAouµtviou /%/ µo:rv71oiou O't7JV 6oxtµ71 fo0t(3pwa71c; t'Ot 6Ei1µ0t,O: 0o: 0EpµetiVOVT0tt mi 7 71µe.pEc; aE 0Epµoxpo:ai0t .100 ° C. Mna 00t xo:00tpi,011,0tt 0t1tb -ro: Ai1t71 ,wv µE xo:'tlXAATJAO 6to:­ Au:txo xo:t OT7J ouve.zEtOt 0o: 0tno!;71p0ti11ono:t. y. Ex'tEAE071. To EOW'tEptxo -roizwµ0t Evoc; 6Eirµ0twc; 1000 µµ2 (33,3 x 30 µµ) t'OU UALXOU 7tEpte.zonoc; XOtAXO, 00t ETCE/;Ep­ '(0:0'tEL µE ,71v emxpet,ouoo: 0epµo!(p0tai0t mi 24 wpEc;, µa 1000 JJA u60t,lXO 6t0tAatµµ0t 7tEptezov-roc; 3% No: CL XOtl 0,5% HCL. 6. E!;h0to71 Acpou 7tAU0Ei XO:L Ot'E'(IIWOEL t'O 6drµrx 0o: E/;Et'o:O'tEL µtxpo­ rp0tcptx0t f-lE µa1i0UIIIJ'Tj 100 f-1-E 500 OE µto: ,0µ71 20µµ [J-7I· xouc;, xo:,a 1tpo-riµ71a71 f-1-ETIX 0t1t6 71Aax-rp0Au,lx71 o,[)..,. [3wa71. To [3a0oc; ,71c; E1ti0Ea71c; 6Ev ;cpe.nEt v0t !;map110t ,7111 6au,EpTJ 0Etp0t xoxxw11 0t1t6 ,7111 Emcp0tvEt0t nou unof3iAE,0tt 0,7111 6oxtµ71 6t0tf3pwo71c;. Ko:,Ot XOtllOIIOt Ot\l 71 npw,71 OEtpix XOXXW\I EXEt TO· 7t00E't7j0Ei TJ 6eunp71 OEtpix 1tpE1tEt VOt e.zat t'Olt00Et'Tj0e:i µ611011 'tµ'ljµo:,txci. fto: ,tc; 1tA0t1to1po:cp71µe.vac; (npocpiX) TJ e!;h0ta71 00t 1ivu µe i07J '(WVL0t <JXEt'tX7I fJ-E t'7III E7tt(fllXIIEt0t. }.;e nepi1t,WO'lj nou µe,ix o:no 7JAEx,poAu,tx71 a,i)...f3wa71 0E­ wplj0Ei o:vo:rxo:io 110: npoxOtAouµe Et6tx71 eµcpii11to71 t'WII EIIW­ aewv 'twv x6xxw11 1to: 1tEp0tt,epw e!;ho:071, 0tu,7171 µi0o6oc; 00t EiVO:t 'lj µi0o6oc; 7I E'(XEXptµEIITJ 0t7t0 t'7III o:pµofoet 0tpz71. III. flpoo-ro:aiet 't7Jc; eow'taptx71c; mtcp0tvEi0tc;. H EIJW'tEptx71 Emcpdr.vEtOt 'tW\I 6ozdwv O:ltO xpdr.µ0t,0t OtAOU- . µtviou, npinet vo: emxo:Aucp0ei µe o:pµo,ouoet npoo,0tai0t nou 0o: eµno6i~et 't'IJV 6tdr.f3pwa71 0,0:11 ot 0tpµo6t0t ow0µoi 6oxtµ 71c; 80: ,o 8ewp71oou11 0t1to:po:i,71,o. BAE7tE o6lJriec; ozmxix µe TOt UAtXIX XOtt TTjll xrx-ro:axeu71 'tWII 6ozeiw11 nou 1tpoopi~o11,0tt 1t0t ,7111 µe-ro:cpopdr. pauo,onot 71µevw11 o:epiwv µe ltOM7I ~U!;'lj ,71c; T0t!;71c; 2. 1. To: 6ozeio: 1tpe1tEt VOt XOtt'(J.OXEUIX~O\lt'Ott OtltO OtTIJIXAt, OtAouµivw, xpdr.µ0t o:Aouµt11iou, XOtAxo 71 xpdr.µrx zetAxou, n.z. opeizo:Axo. To: 6ozeio: O:ltO xo:ho 71 xpaµo: XOtAXOU Elmpeno­ V'tOtt µovov '(tO: 0tepto: ltOU 6ev 7tEptezouv OtXETUAE\ltO. To Ott0u­ AE\lt0 6uv0t't(J.t oµwc; VO: 7tEptEEt t'O ltOAU 0,005% 0:XEt'UAEVtO. 2. Mvo:Vt'Ott 110: zp71atµo1tot710ouv µovov UAtXIX XOtTIXAA 7JAO: O't7JII EA<XXtllT'lj 0epµoxp0toio: un71paoi0tc; ,w11 6ozaiwv xrxt ,wv e!;o:p'tTJfJ-IXt'WV -rouc;. • ft0t 't7JV XO:t'O:OXEU7I t'WV 6ozdwv t'O: a!;71c; UAtXIX rivovt'Otl 0:1t06EX't0t: o: To: O:'tOIXAtvo: nou 6ev ucpio,0tv'to:t aAo:cpp0t p71!;71 ( ondr.otµo) µE 't7JV EA0tzta:t710apµoxpo:aiet un71peoi0tc; ([3AE1tE nep. 3265). Kavouv 1to: zp71a71: 1. To o:,oOtAt µ71 evwµevo ( 0t1to xpixµo:) µiXPt 0epµoxp0toio:c; - 60°C. 2. To o:'taOtAt E11wµe.vo (xpaµo:) µE ,o vtxEAto (µE ,t,Aoµe.­ 'tPTJ07J o:no 0,5% µE 0, 9% NtxiAto) µe.zpt 0Epµoxp0toi0tc; l 96°C O:VIXAO'(Ot µE ,7111 1tEptEXt'tXOt'7lt'O: t'OU NtXEAiou). 3. To 0:UO'tE\ltt'tXO O:t'OIXAt µE xpwµto XOtt VtXEAtO µizpt 0Ep­ µoxp0toi0tc; - 270°C. B To o:Aouµi11t0 µE 'tt,Aoµe.,p71071 99,5% ,ouA0tzto-ro11 71 xpciµo:,0t OtAouµtviou ([3Ae.1tE 7tEpt0. 3266). 3202 3204 3249 32.50 3251 1' · 0 OtltOOEtOwµe.voc; z0thoc; µE t't'tAoµhp71071 99' 9% 'tOU­ AIXXtOTOV 71 xpdr.µo:'tO: 0:ltO xo:Axo ltOU e.xouv mptEXt'tXO't7ITOt IJE xwo n)...fov ,ou 56% (f3Ae.ne nEpt0wpw 3267). 1. To: oozEio: 6ev µnopou11 VOt eivo:t 1t0tp0t µovov xwpic; EVW07J 71 ourxoU 71µe.110:. 2. T0t 6ozei0t ouµcpw110t µE 'tO 7tEpt8wpto 2207 0tlt0 OtUOt'E­ vmxo 0:'tlJIXAl OtltO xwo 71 xpixµ0t XOtAXOU, µnopouv E1tio71c; VO: axouv ourxoU710Ei OXA7lp0t. 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UtXIX - 6ozEi0t. o: i\ozeiet Ot7t0 O:'tOIXAt To: UAtXIX ltOU zp71atµo1tOLOU\ITOtt 0,7111 XOtt'O:OXEU7I 6ozeiw11, xett ,o: xopobvto: ou1xoU71071c; npemt 0,7111 eAdr.zto't71 0Epµo­ xpo:oio: -rouc; vet txo:vonotouv ,ouAdr.ztowv -rte; E!;71c; npoiino0e.­ OEtc; oze-rtx0t µE 't7IV 0tnoz71. Ot 6oxtµo:oiEc; 6uv0tVTOtt \10t ri11ouv µE 6oxtµ0to'ttXouc; OWA7l­ vec; µe E'(X07t7] 00:11 u 716oxtµ0to,txe.c; OWATJIIEc; f-1-E E'(XOltTJ 00:11 V. }.;uvriµµe.vo A.2 Utxo E1t0tVOtTOtX'ttXO't7lc; 0t) TWII A0tµ0tptllWV XOtt rwv xop6ovtw11 ouyxoU71071c; 0,7111 EAIXXLO't'TJ 0epµoxp0toi0t Amoup1ietc;. J/mp. EX. f3) J)mp. ax. C). ot'tOIXAL ozt OE xp0tµ0t xpuwµe.110 • 34,3 27,4 ot671ptxo Ot'tOIXAt OE xp0tµo: 21.6 Nt<5% 34,3 at67jptxo Ot'tOIXAL ae xp&:µo: 34,3 5%~ Nt~9% 44,1 O:O'tEVL'ttXO 0:'tOIXAt µe C't - Nt 39,2 31.4 o:. Ot 'ttµe.c; mo:vo:'t0tX'ttX0,7J't0tc; nou x0t0opio't71x0tv µE 6t0t­ cpopE'ttxouc; 6oxtµ0tO'ttXOU<; OWA7IVE<;, 6Ev ou1xpivOV'tOtt f!E'tO:/;u .'tWV. 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Tet (l7tLV't0\ILOt 1tou E)(OW µe1a.).u,epec; 01tEc; 81:.wpotill't'OtL we; "t01J 'tl>7t01J JJ-E E7tlX\IW 't(lT)(lOt XI\ITj't0 (3A2). 6) H tle.160tp1dt 1tpE1tE1 \lot el110t1 -cou -cu1tou aupµot't07tOtTj(lE· vou 671Aot67J vet (l7tope.l 110t EX,EL e.!;otacpa.A.10,el ot7to aup(l0t,01to1 TJJJ-EIIO aua't'Tj(lOt, TJ illo 'tuito e.!; iaou ot1tO't'EAEO(l0tt1xo. e) Me.1io't'Tj 1tEp1ex,1xo't'Tjc; 'tW\I µm11-co11tw11. 60 Ahp0t. Q Mi1ta't'Tj x0t80tp7J (lix,0t 120 X1. B0tpEAIOt Ot7t0 X011'tpOt-7tAOtXE. 1D ot) To !;uAO 7t01J XflTjOl(l07tOIEL'totl, EX,EL !;e.pet8e.i Xa.AWc;, E(l7t0ptxdt IX7tOtAAOti(lEIIO Ot7t0 urpotaiet XOtl xot80tpo Ot7t0 EAIX't­ "t'W(lot 't'Tj<; <pUOTj<; 7t01J E(l7t06l,Et 't'TjY ot7tO'tEAEO(lot'tlX0'tTj't'ot 't'01J {10tpe.1,.1ou "(Let ,riv 1tpof11.e.1to(lEIITj XPTJOTj, Av XflT)Ot(l07tOIEL't'Otl dtllo Ot7t0 't0 X0\l'tf10t·7tAOtXE 1JAIX0 rtet 't'Tj\l Xot'tOtOXEUT) 't'W\I ~ixOEWII, 1tpE1tEI 1/0t EX.EL 't'Tjll l6t0t 7t0t0't'Tj't'ot JJ-E EXEt\lTj 't01J X011't'p0:-7tAOtXi. (3) To xov,pet 1tA0txE 1tou xp71atµo1to1eh0t1 1tpE1tEL vet ix e.1 rouAotX,LG't'O\I 2 1t,ux Ec; 1tet 't0II xplxo x0t1 ,ouAotXtO'tov 3 7t't'1J­ xec; iLIX 'ttc; {1dtoe.tc;. 01 muxEc; 1tpE1tEI \let O't0t1Jpw11011't0tt 0'tTj\l Xot't'E1>81Jll07j 'tW\I 111:.pwv XOtL \let EX,OU\I xollri8Ei re.pix (LE X0AAOt 1tou 0t11'tex Et G't'o 11Epo. r) 0 xplxoc; Xott 01 ~IXOEtc; 7tflE7tEI \let EXOW XOt'tOtOXElJOtO't'El Ol>IJ.<pWIIOt µe. 't'Tj\l 7tEf11EX't'IX0'tTj't'ot 't01J ~o:pEAIOU Xotl 'tTj<; XPTJ· GTjc; riot 't'Tjll Oitolot 1tpoopl,011'tott. 6) ftot vet 0t1tocpwx 8Ei Tj 6to:ppo71 ,ou 1tEp1Ex oµE11ou 0t1to 'tet e1161dtµe.a1X 010:0't'7j(J.IX't'IX ( 1Xpµouc;) 'tlX XO:AU(l(J.Ot't'IX 81X EX,01J\I e.1te.116u8Ei 0t1to x Otpti KRAAFT TJ ixllo o:vdt).o1o u1,.1xo 1tou 7tpE7tEL \lot OtEpE07tOLEl't'ott re.pix G't'0 xdu..uµµet XIXI \let E7tEXtet9Ei Gm' il;w ae. 0ATj 't'Tj\l 1te.ptcpEpE10t. E) MEjLO't'Tj 7tEptEX'tlX0't'Tjc; 'tW\I ~0:flEAtW\I 250 Altpet. Q Mirta't'Tj x0t80tp7J (lix,ot 400 Kr. B0tpEAlot Ot7t0 cpua1xo !;uAo. 2Cl Me. 07t7J x0t1 tlela1µ0. 2C2 Me Eitcivw tµ71µ0: x111Tj't'0. 0t) To XflTjOtµo1tOtOUJ'-EIIO !;uAo 7tflE7tEt \let EX,EI XOtATJ 7t0t0 't'Tj't0t µe. ioe.c; lvec; \/Ot EXEi 0:1tO/;Tjp0t118ei XotAwc;, O:ltTjAAO:iflE\10 (X7t0 xoµ~ouc; XOtl cpAotouc; Ot7t0 (LOUX, AOt XOtl X0(l~Ouc; TJ illet EAO:'t't'W(lot'tOt 'tW\I 07tolwv 71 cpua71 E(l7t06l,Et 't'Tj\l Ot7t0't'EAEO(l0t· "t'IX0'tTj't'ot 't01J ~otpEAIOU ,to: 'tTj\l 7tpO~AE7t0(lEIITj XPTJOTj, 3522 3523 3524 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) 1237 ~) 0 xpbtoc; Xott ot ~aow; 7tpE7tEt vex E)(.OUV XCX'tCXOXEUIXO'tEt <JU(.l,<pWVCX (.l,E 'tTjV 7tEptEX'ttXO'tTJ'tlX 'tOU ~otpEALOU Xott 'tTJV XP'TlOTJ 1LIX 't'T)V 07t0tot 1tpoopt,E'tCXt, . r) Ot 6ourEc; Xott ot ~aouc; 1tpE1tEt vex E)(.OUV 1tptOVtO'tEt ri ocvcxax,to8Ei 1tpoc; 'tTjV xcxnu8uvo11 'tOU !;uAou WO'tE xcxvavcxc; E'tTjOLOc; xo~oc; vex (.l,TJV E7tEX'tot8Ei 1tAfov CX7t0 'tO 1 /2 'tOU 7ta­ xouc; 'tTjc; 6ourcxc; :iJ 'tTjc; ~ao11c;, 6) Toe on<pavtoc 'tOU ~otpEAtou 1tpE1tEt vex EtVCXt CX7t0 IX'tOIXAt 7l ai611po Xott X!XAT)c; 7tOLO'tTJ'tOc;. ftot 'tot ~cxpaALCX 7tOU 'tO IXVW 't(.l,T)(.l,CX 'touc; aivcxt XLVTJ'tO 2C2 Ejxpivov'tott xcxt owpdtvtcx cx1to Xot'tillTJAO OXATJpO !;uAo. • a) BcxpaAtot IX7t0 <pUOtXO !;uAo 2Cl. H 6uiµa'tpoc; 'tTjc; Awpi8cxc; OEV 1tpE1taL vex E!;EX,Et o'to µtoo 'tOU <p&:p6ouc; 'tTjc; 6ourcxc; 07t0U 't07t08E'tEl'tott TJ 01tT) XAEtoiµcx­ 'tOc;. Q BocpEAtot CX7t0 <pUOLXO !;uAo 2C2. Ot ~IXOELc; 1tpa1tEt voc E<potpµo,ouv X!XAIX O'ttc; U1to6ox.ac;. 8) MejtO'tTJ 7tEptEX'tLXO'tTjc; ~otpEAtwv 250 Ai'tpcx. t) MEjtO'tTJ xcx8cxpri µa,cx 400 X.i· BotpEALCX CX7t0 )(.CXp'tOVt. lG ?t) 0 xpixoc; 'tou (3ocpEAt0u 1tpa1tEL v0t EX,Et xo:'to:oxEuo:o'tei fLE 7tOAAOt7tAEc; 7t'tU)(.Ec; CX7t0 7t0:XU x.o:p'ti 11 X,otp'tOVt (µ11 XUfLO:'tW 6Ec;) 1tou ax.ouv xoU1j8Ei T) EA0:oµcx'to1tot1j8Ei 1Epot xo:t µ1topEi vo: 0:7tO'tEAEt'tO:t CX1to fLEptxii O'tpwµot'tot o:ocpdthou 1to:po:q,tvo 1tOLTJ(.l,EVOU )(.0:p'ttOU KRAFT fLE'totAAtxo q,uUo, 7tAOtO'tLXO x.A1t. ~) Ot ~ll:OEtc; 1tpE1tEL VO: EtVO:L CX7t0 <pUOLXO !;uAo, x.o:p'tOVL, µa­ 'to:AAO XOV'tp0:-7tAo:xi T) 7tAO:O'tLXO 7tOU (.l,7tOpouv vex E)(.OUV E7tEV 6u8Ei µe 1 ri 1toUoc1tAdt o'tpwµo:'tex 1tpoo'texoio:c; o:1to &:o<p!XA ,o, 1totpo:cptvo1tOlTJfLEVO )(.Otp,i KRAFT µe,exUtxo q,uUo, 1tAex­ (J'ttXO x.A7t. r) 0 xpixoc; 'tOU ~otpEALOU Ot ~ll:OEtc; XO:L m EVWOEtc; 'tOU 1tpi 7tEt vex E)(.OUV Xex'tO:OXEUexO'tEt OUfL<pWVOt fLE 'tO 7tEptE)(.OfLEVO 'tOU (30:pEAtou xext µe 'tTJ XP'TlOTJ jtex 'tTJV 01toiex 1tpoopi,E'tO:t. 6) H ouvo:pµoAo1ouµEVTJ ouoxEuo:oiex 1tpi1tEt vex. eiv0tt 0tp­ XE'tot 0tv8EX'tlXT) O'tO vepo ytex V(X fLTJV U7totp)(.Et 0:7tOXOAATJOTJ 'tWV o'tpwµ&:'twv u1to xexvovtxac; ouv8rixec; µe,0tcpopdtc;. e) ME1tO'tTJ 7tEptEX'ttXO'tTjc; 'tOU ~OtpEAtOIJ 45 0 AITP A. Q ME1tO'tTJ xex8o:pri (.l,IX'(X 400 X y. Bo:pEAto: xo:t µmv,ovto: o:1to 1tAexo,txo. 1 H 1 Bo:pEAtOt fLE 7tlXVW 'tfL'TjfLO: fLTJ XtVTj'tO .• 1 H2 Bo:piAtOt fLE IXVW 'tfLT)fLIX XLVTJ'tO. 3Hl MmV'tovto: fLE dtvw 'tfLT)fLOt fLTJ XLVlJ'tO. 3H2 Mmv,ovto: fLE dtvw 'tfLT)fLO: XLVlJ'tO. ex) Ot ouoxeucxoiEc; 1tpE1tEL vex µ1topfoouv vet cxv8a!;ouv o,tc; <pUOtXEc; (Et0tXIX fLTJ)(.O:Vtxac; Xott 8Epµtxac;) XO:t X.TJfLLXEc; CXVO:'TJ~ 'tTjOEtc; oX,E'ttXEc; fLE 'tTj fLE'tOt<popot XOtt VO: 7totpO:fLELVOUV o,q0tvot. Tipi1tEL vex µ1topfoouv vex OtV'te!;ouv o,0t Emxiv8uv0t uAtxdt xcxt <J'ttc; cxvcx8uµt&:oEtc; ,wv. Ilpi1tEt mio11c; vot µ1topfoouv vex cxv,a­ !;ouv xot'tot 'to ot1tott'tOUfLEVo µhpo O'tTJV mxAotLWOTJ xcxt oi:tc; u1tEptw8Etc; o:x'tivEc;. Ot ouoxeucxoiec; 1tpa1tet vex 1tpooq,ipov,cxt rtcx OtjOUPTJ fLE'tCX)(.EiptOTj, ~) H E7tt'tpE7tOfLEVTJ X.P'TlOTJ 'tWV OUOXEUIXOtWV jtcl 't'Jj fLE'tot­ <popot Emxiv6uvwv cpop'tiwv ELVCXL 7tEV'tE x.povta: CX7t0 'tTJV XIX'tCX­ <JXEUTj 'tWV, Ecpooov Ot ouv8rixEc; 't'Jjc; fLE'tOt<popdtc; 'tWV 6texcpopwv XAotoEwv 6Ev 1tpo~Ai1touv ouv'toµonplJ 8tdtpxELot X.PTJOTJc;, r) E&:v XPEtot~E'tott 1tpOO'texoicx jLex 'ttc; U7tEptw6Etc; exx,ivEc;, 1tpE1tEt voc EX,Et 1tp0tj(.l,0t't07tOLTJ8Ei (.l,E EVOWfLIX'tWOTJ µocupou 'tOU dtv8pocxoc 7l dtUwv XOC'tiXAAlJAWV X.PWO'ttXWV TJ exV'tEVEpywv. Toe 1tpoo8E't0C OCU'tot 1tpi1tEt :voc Eivext ouµ~t~IXOLfLOC fLE 'tO 'ltE­ ptE)(.OfLEVO xoct 1tpi1tEt vex 6tot't'Jjpouv 'tlJV ex1to,EAeoµoc,txo,11'tot ,ouc; xoc8' OAT) 'tTJ 6tdtpxEtot 't'Jjc; X.PTJOTjc; 'tTjc; ouoxeuexoiexc;. • :E; 7tEpt7t'tW<JTj XPTJOT)c; µocupou 'tOU dtv8pocxoc - X.PWO'tLXWV 71 O:V'tEVEpytxwv - 7tOU Btexq,ipouv ·ex1to EXEtvex 7t0U X.PTJOLfL0 7tOLOUV't0tt 1tot 'tTJV xoc'texOXEUT) ,ou 'tU1tou Boxtµocoiexc; i:7Jc; xot­ 'totOXEUT)c;, µ1topouµE voc fLTJV !;ocvocxdtvoµE nc; BoxtµocoiEc; ocv TJ 1tEptex'ttXO't7Jc; OE µocupo 'tou dtv8pocxoc; 6Ev u1tEp~ocivet ,ex 2% aE fLIX,oc T) ocv lJ 1tEptEX'ttxo,11c; oe XPWO'ttxdt 6Ev ump~exivu 'tex 3%' OE fLll:~OC. H 7tEptEX'ttXO'tTjc; OE exV'tEVEpydt U7tEptwowv OCX'tLVWV 6ev ex.Et optoc. 3525 3526 6) Toe 1tpoo8E,tXot 1tou XPTJOt(.l,07tOLOUV'tott 1toc dtUouc; oxo 1touc; CX7t0 'tTjV 1tpOll't0toioc Ot7t0 U7tEptWOEtc; ocx,ivec; (.l,7tOpouv VOC EtoiA8ouv O'tTjV ouv8EOTJ 'tTjc; 7tAOCO'tlXTjc; UATjc; E<pooov 0EV exA­ Aotwvouv ,tc; X.TJ(.1-txic; xcxt cpuotxic; t8to'triuc; 'tou uAtxou ou­ oxEucxoiocc;. :Ea tOtOCU'tTj 7tEpL7t'tW<J'Jj ,7J U7tOXPEW<JTj voc E1texvexA11cp8ouv Ot 6oxtµocoiec; µ1topEi voc E!;ocq,ocvt<J'tei. • 3. Ilpa1tEt voc A1jcp8ouv XOC'tlXAATJAOC µhpoc ytex voc e!;ocoq,otAL­ <J'tEi O'tt TJ XPTJOt(.l,07tOtlj8Eiooc uATJ 1 tcx 'tTJV Xot'totoxeuri 'tTj<; ou­ oxauocoiocc; Eivoct oup.~t~dtotµTj µa ,ex Eµ1topeuµot't0t 1tou ot ou­ axEuocoiEc; 1tpoopi~oV't0tt voc 1tEptax.ouv (~A. 1tEpt8. 3551(5). Z) Ot ouoxEuocoiEc; 1tpE1tEt voc xot'totoxeua,ov'tott oc1to xoc,iiA­ ATJAO 7tAOCO'ttxO UAtxo 7t0U TJ 1tpoEAEUOTJ XOCt EL0tXIX 'tot O'tOt)(.ELot EtVOCt rvwo'tot. H Xot'texOXEUT) 'tWV 1tpE1tEt Vot otp(.1,0,Et 'tEAELOC O'tex 7tAOCatLXIX UAtXIX Xott voc CXV't0t7t0Xpt8Ei O'tTJV exvot7t'tU!;Tj 't'Jjc; 'tE­ x vtx71c;. ftot 'tll; XottvoilpjtEc; OUOXEUOCOLE<; Bev µ1topouµE vex XPTJOtµo1totouµE XPTJOt(.l,01tOt1jµiiioc UAtxdt, 8toccpopmx&: 0t1to 'tot U7tOAOt7tOC 'tTjc; 1t0tpexrwr71c; 7tOU 7tpoip)(.OV't0tt ex1to 'tTJV iotoc <JEtpCX. 8+ To 1texx,oc; 'tOU 'totX,wµocwc; 1tpE1tEL voc Eivoct oE xdt8e 011 (.1,EiO 'tTjc; OUOXEUotoiocc; OCVotAOjO O'tTJV 1tEptEX'ttXO'tTJ'tll: 'tOU xoci <J'tTj XP710TJ rtoc 'tlJV 01toioc 1tpoopt,E't0tt, Aocµ~dtvovw.c; U1to<Ji11 p.occ; 'ttc; ouv871xEc; o,tc; 01toiEc; µ1topai vex ex'ti8e'tott xii8E 011 µEio. • t} Ot 01tic; jEµioµocwc;, oc6udtoµex,oc; xext e!;exEptop.ou o,ov xpixo 71 O'ttc; ~otOEtc; 'tWV ~otpEAtwv fLE &:vw 'tfLT)fLOC fLTJ XtVlj'tO (lHl) Xott 'tWV (.l,7tlV'tOVLWV fLE IXVW ,µ71µex fLTJ Xtvlj'tO (3Hl) 6av 1tpimt vex ix.ouv 6t&:fLE'tpo &:vw 'tWV 7 EXOt'tOO'tWV. Toe ~ocpiAtoc xoct ,oc p.mv,ovtoc 1tou ax ouv fLEjexAu,EpEc; 01tac; 8uupouV't0tt we; 'tOU 'ttl7t0U fLE XLVTJ'tO &:vw ,µ71µex (1 H2, 3 H2). 4. Toe ~otpEAtoc (.l,E E1totvw XtVTJ'tO 'tfL7lfLOC (1H2) xext 'tot µm­ V'tovtoc (3H2) avw XtVTj'tO 'tfL7lfLOC 7t0U XPTJOlfL07tOLOIJV'tOCL jLOC O'tEpE&: uAtxdt 1tpE1tEt voc 1tocpocµivouv oE xa8E oriµEio o,qexv&: oX,E'ttx&: fLE ~o UAtxo 1Ep.iop.oc,oc;. ~ . , p • T oc ouO't7lfLOC't0t XAEtoip.oc'toc; 'tWV ~expEAtwv xoct µmv,ovtwv (.l,E avw 't(.l,7lfLOC XtVlj'tO ,1tpE1tEt voc XOC'tOCOXEUll:,OV'tott E'tOt WO'tE vex 1tocpocµavouv xtXAdt xAEto'tot xoct on1ocvdt u1to xocvovtxic; ouv 871xac; fLE'tot<popdtc;. . Toe dtvw xtVTj'tot 't(.l,7l(.l,0t'tex 1tpi1tEL vex ecpo6tdt~ov'totl ·µe evw­ oetc; ou1otVO'tTJ'tOc; EX'tO<; EIXV OC7t0 'tTJV <pt>OTJ XOCL XOC'texOXEU7I 'tWV 'to ~ocpiAt 71 ,o p.mV'tOVt Eivoct ou1ocvo otXOfLTJ o,ocv 'to dtvw XtVT)'tO 'tfL7lfLOt O'tEpE01totEL't0Cl OWO'tot. x) H p.e1io'tTJ em'tpmoµav11 otoc1tep0t,o't7lc; (PERMEA TION) 1toc 'tot eucpAEX'tot peuo,&: Eivcxt 0 1 ,0?8:r fLE 23 °C. wpcx BAE7tE 7tEpt8. 3556. B-4 7 /11/100~105 A) MEjLO'tlj 1tEptEX'tLXO'tTJ<; 'tWV ~otpEAtwv xext µmv'to­ VtWV lHl xoct 1H2 450 Ahpoc. 3Hl xoct 3H2 60 Ai'tp0t. µ) Mqio'tlJ xoc80tpT) µa,oc lHl xoct rn2 400 xr 3Hl XOtL 3H2 120 Xi· Kt~W'ttot 0t7t0 cpuotXO !;uAo. 3527 4Cl - XOLVIX. 4C2 - ME o,ex1exvdt o,oc xovtop'twOTJ uA. 'tOL)(.WfLOC'tex: :Elj(.l,EtWOlj, ftoc 'tot XL~W'ttot ex1to XoV'tpot 1tAexxe, ~AE7tE 3528, ytoc ,ex Xt~W'tLOC 0t7t0 ocvocxex,exoXEUT) !;uAou ~AE7tE mp. 3529. Ot. To !;uAo 7tOU X.PTJOl(.l,07tOtEl't0tt 1tpE1tEL vex EX,Et xexAot ex1to­ !;11pocv8Ei oc1to Ep.1toptXT) dt1to<Ji11, ex-itocUocyp.avo oc1to u1pocoioc xoct xot8ocpo ex1to EAOC't'tWfLOC'tex 7t0U 'tU)(.OV (.l,Etwvouv' 'tTJV exv8E­ X'ttXO'tTJ't0t EXIXO'tOU OUO'tex'ttXOU O'tOt)(.ELOU 'tOU Xt~W'ttOU. H. o:v8EX'ttXO'tTJ'tOt 'tOU XPTJO(fL01tOLTJfLEVOU uAtxou XOCL O ,pcmoc; XOC'tOCOXEUT)c; 1tpi1tEL voc E)(.OUV 1tpooexpp.oo,Ei O'tljV 1tEptEX'tLXO­ 'tTj'tOC 'tOU Xt~W'ttOU xext O'tTJ X.PTJOTJ jtot 'tlJV 01toiex 1tpoopi,E't0CL. 1238 E<l>HMEPII: THI KYBEPNH1:EQ1: (TEYXOr aEYTEPO) To dtvw (J-Epoc;; XC(t TJ (3iitori µ1topouv VC( ElVC(t C(7t() C(VC(XC('tC(­ OXEUC<oµivo ;uXo, a.v0EX'tLXO O'tO VEpo, 01twc;; OXATJPTJ oa.vi6a., oa.vi6a. C(7t() µtxpo,Epe< O'tOLX,ELC( TJ otAAO XC('t(XAATjAO 'tU7tO, (3. Kt(3C:ma. C(7tO oa.vl5Ec;; O'tE'(CI.VEc;; O'tC( xovtop,w6ri 402. Kot0E OUO'tC('ttXO O'totX,ELO 'tOU xt(3w,iou 1tpE1tEL VC( ELVC(t µo­ voxoµµa.,o TJ C(VotAoyo. Ta. O'totX,ELC( 0EwpouV'tC(L we;; C(VotAO'(C( OE µovoxoµµa.,a. O'totX,ELC( O'tC(V ouva.pµoXoyouV'tC(L C(7t() ou­ rxoAATjQTj, ouµqiwva. (J-E µia. C(7tO ,tc;; E!;Tjc;; (J-E0o6ouc;;. ~uva.pµoMrriori LINDERMANN (µE oupdt X,EAt6ovwu) (J-E PEAL XC(t yXwoohoa., (J-E Tjµt-;uXo TJ 7tACI.XE EVWOTJ, (J-E 'tOUAotX,L­ cn:ov 6uo xuµa.,w6ri ouv6E,txdt EAotoµa.,a. a.1to µha.Ao oE xiit0E EVWOTJ, 1. ME'(LO'tTJ xa.8a.p71 µot~C( 400 'X.r · Kt(3w,to C(7tO xov,pa. 7tACI.XE. 4D. C(. To XPTJOL(J-07tOLTJ(J-EVO xonpa. 7tACI.XE 1tpi1tEL VC( EX.EL 'tOU­ AotX,LO'tOV 3 7t'tUX,Ec;;. Tipi1tEt va. C<7tO'tEAEhe<t a.1to qiuUa. 1tou EX,OUV a.1to;ripa.v8Ei XC<Awc;; XC(t 7t0\l EX,OUV yivEt 6tdt !;E'tUAiyµa.wc;;, C(7t0X07t1jc;; 'tE­ µa.x.taµou TJ 1tpwviaµa.,oc;;, C(7t() E(J-7t0ptXTj ot1to4ri C(7tC(AACl.'(­ (J-EVC( C(7t() uypa.aia. XC(L C(7t() EACl.'t'tW(J-Cl.'tC( 'tTjc;; q>uaric;; VC( EAC('t­ 'tWOEL 'tTJ 6u11a.,o,ri,a. ,ou xt(3w,iou. 'OXEc;; ot 7t'tUX,Ec;; 1tpE1tEL VC( XOAAOUV'tC(L (J-E XOAAC( 7t0U C(V'tE­ XEL (J'tO VEpo. ·ma. 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Me1ia'tTJ xa.8a.p71 µdt~a. 400 x.r E<l>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: ~EYTEPO) 1239 :Eixxxot ucpotap.ixi:1vot. 3533. 5Ll Xwpi,; cpoopot Tj Eawnp1x71 E1tEVOUOTj, 5L2 MT} xoax1vwoat,; 5L3 Av8Exi:1xoi a,:o vEpo. ot) Tot ucpixap.oti:ot 1t01) XP7Ja1p.01tOIOUV'totl 1tpE1tEI Vot EXOUV XotATJ 1tOIO't7j'tot. H otv8axi:1x61:7J'tot i:ou ucpciap.oti:o,; xot1 7l xoti:otaxau71 i:ou aixxxou 1tpE1ta1 vot aivot1 otvixAO"(TJ ai:7JV 1tap1axi:1x6i:7Ji:ot i:ou aixxxou xot1 1:TJ<; XPTJOTJ<; 11ot 'tTJV 01toiot 1tpoopi,ai:ot1. ~) MTj xoax1vwoa1,; aixxxot. 5L2. Ot aixx~ot 1tpE1tEt Vot EXOUV anjotVO'tTj'tot ai:ot xovt0p'tW07J 6tot 1t-X· EVot xotpi:i xoM7Jf.1.EVo a'tT}V aawnp1x71 amcpcitvatot ,:ou acix­ xou p.a p.iot xoMot 1tou otV'tEXEL ai:o vapo 61tw,; 7l ciaq,otA i:o,;. f.1.E p.tot 'tottviot 1tAotai:1x71 XOM7Jf.1.EVTJ a1:7Jv aawi:ap1x71 am­ cpixVElot i:ou aixxxou. f.1.E p.iot TJ 1tOMot1tAE<; aawi:iptxE,; cp66pa,; ot1t0 xotp't[ 71 1tAotai:1xo. . • r) :Ecixxoc; 1tOU otvi:ixa1 a,:o vapo 5L3. 0 acitxxo,; 1tpi1tat Vot EXEi jLVEL otOLIX~poxoc; wan Vot ot1t0 q,aux8ai xix8a ELaotjWj'Tj Ujpotaiot,; 1t-X· f.1.E aaw,:apLXE<; !;axwptai:E,; cpoopa,; ot1t0 xotpi:i otv8axi:LXO a,:o vapo 1t-X· xotpi:i KRAFT 1totpotcpLV01tOl7lf.1.EVO Tj otaq,otAi:o 1tOITJf.lEVO xotpi:i Tj Xotpi:i KRAFT Emxillup.ivo f.l.E 1tAota'tLXO. p.a 1tAotai:1x71 i:ottviot 1tou EXEt xoM7J8ai ai:7Jv aawnp1x71 amcpixvELot i:ou acitxxou. p.iot 71 1tEptaaoi:Epac; aawnpLXE<; q,oopac; ot1t0 1tAotanxo. 6) Mqiai:7J xot8otp'Tj p.ix,ot. 3534 :Eixxxot ot1t0 1tAota'tLXO uq,otap.ot. 5Hl Xwpic; cpoopot 71 aawi:apLXTJ a1tivoua7J, 5H2 M7J xoaxww6u,;. 5H3 Av8axi:txoi ai:o VEpo. ot) Ot acitxxm 1tpe.1tEL vot EXouv xoti:otaxauotani ot1t6 i:ottviE,; 71 p.ovo-viJp.oti:ot ot1t0 Xot'tOtMTJAO 1tAota'tLXO 1t0\l Vot EXOUV i:pot~Tj­ xni f.1.E EA!;'Tj, H otv8axi:1x6i:7Ji:ot i:ou XPTJa1p.01t017lf.1.EVou UALXou xotL 7l xot­ i:otaxwiJ i:ou acitxxou 1tpe.m1 vot EiVotL otVIXAOjE<; ai:7JV mp1axi:t­ x6i:7Ji:ot i:ou acixxou XotL i:7J,; xpiJa7J,; a1:7Jv 01toiot 1tpoopi,ai:otL. ~) Ot a!XXXOI p.1topouv Vot EXOUV 1tpo~Aaq,8Ei ot1t0 Eawnp1x71 a1tEvoua7J ot1t6 1tAotai:1xiJ i:ot1viot iJ ot1t6 AE1t'tTJ aawnp1xiJ a1tEV­ OUOTJ ot1t0 ltAota'tlXO. j) Av 'tO q,uMO ucpciap.oti:oc; ltOU XPlJa1p.01tOIEt'totl ELVotl E1tt­ m6o, ot acixxo1 1tpi1taL vot xoti:otaxauci,ovi:ott f.1.E potcpiJ 71 ciAAo p.iao itou vot a!;otacpotAt,EL ,:o xAEiatp.o 't'TJ<; ~1Xa7J,; xot1 'tTJ p.iot ltAEUpiX. Av ,:o ucpotap.ot EtVotl aWAlJVOa16Ec; Tj ~cia7J 'tTj<; i:acivi:ot,; 1tpEltEt Vot XAELVE'totl f.1.E potcpiJ TJ f.1.E uq,otVa'Tj TJ f.l.E IXMO 'ttlltO XAE1aip.oti:o,; 1tou 1tpoacpEpa1 i:ho1ot otv8Exi:1x61:7Ji:ot. 6) M7J xoax1vwoE1r:; acixxo1 5H2. • H i:alXV'tot 1tpEm1 Vot EXEi jLVEI anjotVTj ai:ot xovtopi:wOTJ 6tot 1t-X· Evor:; ltAota'tLXOU xcipi:ou TJ 'totLl/totc; XOM7Jf.1.EV7Jr:; a'tTJII aaw­ 'tEpLXTJ Emcp!XVELot ,:ou a1Xxxou. f.1.E f.1.Lot TJ ltEptaaO'tEpa,; !;EXWpta't&<; aawnpLXE<; cpoOpE<; otlto xotpi:i iJ ltAotai:1xo. a) }.;(ixxour:; ltOU otll'tixouv a,:o vapo 5H3. 0 acixxor:; 1tpEltEI Vot EXEL jtVEL O'tEjotvor:; wan \lot ot1tocpw­ x8Ei x(i8a aiaooor:; Ujpotaiotr:; p.a 1t-X· aawnptXE<; !;axwptai:Ec; cpoopa,; ot1tO Xotpi:i 1t0\l otl/'tEXEL a,:o vapo (1t,x, Xotpi:i KRAFT) 1totpotcpLVOltOl7lf.1.EIIO - OL1tAO otacpotA't07tOt7Jf.1.E110 TJ E1tEIIOEOUf.1.EVO f.1.E ltAotai:txo). f.1.E 1tA0tai:1xiJ i:ottviot XOM7Jf.1.EV7J ai:7Jv aawnp1xij 71 E!;wi:a ptxij amcpcivEtot i:ou acitxxou. f.1.E p.iot TJ itaptaaonpac; aawnptxEr:; cpoopa,; OtltO 1tAota'ttXO. ~) Ma1lai:7J xot8otpij p.ci~ot 50 Xi· :Ecixxot otlto 1tAotanx71 i:ottviot. 3535 5H4 ot) Ot acixxot 1tpe.1tat vot EXOUV xoti:otaxauotani otito xoti:citA­ ATJAO 1tAotai:1xo. H ot118ax,:1x6i:7Ji:ot ,:ou XP7Jatp.01to1oup.a11ou uAtxou XotL 7l xoti:otaxauij i:ou a1Xxxou 1tpE1taL vot EivotL otVIXAO"(TJ p.a 'tTJV 1taptaX'tLXO't7l'tot ,:ou aixxxou XotL 'tTJ<; XPTJOTJ<; a'tT}v oitoiot itpoop[,ai:ott. Ot avwaatc; 1tpa1taL vot otvi:ixouv ai:tc; miaat,; xotL ai:tc; au yxpouaatc; ltOU p.itopai \lot \l1tOa'tEt 7j ,:aiXV'tot \lltO Xotl/01/IXE<; auv8ijxac; f.1.E'totcpopci,;. • ~) Ma1ia't7j xot0otpij f.1.IX~ot 50 Xi· :Ecixxot ot1tO xotpi:L 3536 SM 1 TToAUit'tUXOL 5M2 TT0M1ti:uxo1 otv8axi:1xoi ai:o vapo. ot) Ot acixxot 1tpe.1taL vot Xot'totaxauci~ovi:ott otito xoti:illriAo xotp'ti KRAFT iJ ot1to otvlXAo1o xotpi:i auv1ai:wp.a110 otlto 'tOUAIX­ x1ai:011 3 lt'tUXEr:;. H 0tv8axi:1x61:7Ji:ot 'tou XIXpi:ou xott 7l xoti:otaxauij i:ou alXxxou itpfoat vot aivott otVIXAo1ac; p.a 'tTJII 1tEptEX'tLXO't7l'tot i:ou acitxxou xotL 'tTJ<; xpiJaTJ<; 1tot 'tTJII oitoiot 1tpoopi~ai:ot1. Ot EVWaEt<; XotL OL XAEt6otpLE<:; itpEltat \lot EtVotL an-yotvEc; ai:ot xovt0pi:w67j, • ~) foxxot otlto Xotp'ti 5M2. TipaltEL \lot XPlJaLf.1.0ltOl7j0Ei xotpi:i ltO\l otV'tEXEI a,:o vapo jLot i:tc; a!;wnptxic; iti:uxic; iJ jLot axaivov itou 0ot EA8at ai aitotcpij p.a ot\l'tOII. Av \l1t1XPXEL xivouvoc; ot11i:iopota7Jc; 'tO\l ltEpLEXOf.lEIIO\l f.1.E 'tTJV Ujpotatot TJ otV 'tO 1tEpLEXOf.lEIIO auaXE\l<X,E'totl aa UjpTJ Xot't<X­ O'totaT}, TJ aawnp1xij lt'tUXTJ 8ot 1tpa1tE1 E1tt0Tj<; \lot otl/'tEXEI a,:o vapo. Ot avwaat,; 'tTJ<; ltAwpcic; oitwc; xott ot IXVW xot1 x(i,:w XAELOot­ p1Ec; itpEltEL Vot aivotL an-yotve.c; ai:ot xo11t0pi:w67J Xotl otv8ax,:1xic; a'tO vapo. 1 ) Ma 1 iai:7J xot8otp71 p.ci'ot 50 X 1 . Luv0anr:; auaxwotaia,; (1tAota'tLXO UAtxo). 3537 6 HA 1 TIAota'tLXO 6oxaio f.1.E a!;wi:EpLXO ~otpiAL otltO oti:aciAL. 6HA2 TIAotO'tLXO ooxaio f.1.E E!;W'tEpLXTJ OLX't\lW't'Tj auaxauota aiot TJ E!;W'tEptxo ot'ta<XAIVO XL~W'tLO. 6HB1 ITAota'tLXO ooxaio f.1.E E!;Wi:Eptxo ~otpiAL ot1t0 otAoup.i­ Vto. 6HB2 TIAota'tLXO 6oxaio f.1.E a!;w,:aptxij OtX't\lW'tTJ auaxwot­ aiot TJ a!;wi:aptxo otAOUf.1.LVLO Xt~W'tLO. 6HC TIAOta'tLXO ooxaio f.1.E a!;wi:aptxo !;uALl/0 Xl~W'tLO.,. 6HD1 ITAota'tLXO ooxaio f.1.E E!;wi:ap1xo ~otpEAL ot1t0 xovi:pot 1tAotxi. 6HD2 ITAota'tLXO ooxaio f.1.E a!;wi:aptxo XL~W'tLO otltO xovi:pot 1tAotxe.. 6HG 1 TIAota'tLXO ooxaio f.1.E a!;wnptxo ~otpEAL otltO xotp'tOVL. . 6HG2 ITAota'tLXO 6oxaio f.1.E a!;wnptxo XL~W'ttO ot1t0 xotp­ TOVL. 6HH ITAota'tLXO ooxEio f.1.E a!;wnptxo ~otpEAL otltO ltAot­ anxo. ot. Eawi:aptxo 6oxaio. (1) To aawnptxo ltAota'tLXO 6oxaio 1tpiitaL \lot ltA7Jpai 'tt<; 6tot't1Xl;atc; 'tOU itapt0wpiou 3526 ot Xott I f.1.EXPt e. (2) To Eawi:Eptxo ltAota'ttXO ooxaio itpEltEt \lot acpotpf.1.0~E'tott xwpic; aup.1tA7Jpwp.oti:1xo auai:ljp.ot, a,7JV a!;wnptxij auaxauot­ aiot 1tou 6av 1tpi1tat vot aup.mptAotp.~civat otvwp.otAiac; ( a!;oxE,;) 1tou p.itopouv vot itpoxotAouv otito!;uaatc; i:ou 1tAotai:1xou. (3) Mqiai:7J itaptEX'ttXO'tTj<; • 'tO\l aawi:aptxou ooxaiou 6HA1, 6HB1, 6HD1, 6HG1, 6HH 250 Ati:pot. 6HA2, 6HB2, 6HC, 6HD2, 6HG2 60 )..i,pot. ( 4) Ma1ia,7J xot0otpij p.ix~ot. 6HA1, 6HB1, 6HD1, 6HG1, 6HH 400 Xi· 6HA2, 6HB2, 6HC, 6HD2, 6HG2 75 Xi· B. E!;wnptxij auaxwotaiot (I) TIAIXa'ttXO ooxaio f.1.E a!;wi:aptxo oti:aciAtl/0 TJ otltO otAoup.i 1110 ~otpiAt 6HA1 iJ 6HB1. H a!;wi:aptxiJ auaxwotaiot 1tpe.1taL vot 0tvi:ix1toxpi11ai:ixt otvci­ AOjlX f.1.E 'tTJII 1tapi1t'twa7J ai:ot Xotpotxi:7Jpta'tLXIX TTJ<; xoti:otaxauijc; 1t0\l otvotcpEpov'totL a'to itapt0wpto 3520 ot f.1.EXPL L TJ 3521 ot) f.l.EXPL 6. (2) ITAota'ttxo 6oxaio p.a a!;wi:aptxij 6txww-riJ auaxauotaiot iJ a!;wi:aptxo XL~c;mo otltO ot'ta!XAL iJ OtAOUf.lLIILO 6HA2 iJ 6HB2. H a1;wi:aptxiJ auaxwotaiot 1tpE1tE1 vot otvi:ot1toxpi11ai:0tt ai:ot xotpotXTT)pLa'tLXIX 't'T)<; auaxwotaiixc; ltO\l otvotcpEpE'totL a,:o ltEpL 0wpto 3532. (3) TIAotO'tlXO 6oxaio f.1.E a!;wnptxo XL~W'ttO otltO 1;uAo 6HC. H a1;wnptxij auaxwotaiot 1tpi1tEL vot otvi:otitoxpivai:ott ai:ot xot­ potxi:7Jptai:1xci Xot'tlXOXEUTJ<; ltO\l IXVotcpEpOV'totL O'tO 1tapt8wpt0. ( 4) TIAotO'ttXO 6oxaio f.1.E a!;wi:aptxo ~otpfo otltO xovi:pot ltAotxi. 3 5 2 7 1240 E<DHMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 6HD 1 H e!;wnp1x71 OUOXEUCXOtO( 1tpbm vex CXV"CCX7toxplVE"CCXI a-ccx xcxpcxx-c71p1cmxix xcx-ccxaxw71c:; 1tou cxvcxcpipov-ccx1 o-co 1tEp1 6wp10 3523. (5) TI),CXO"CIXO 60XEtO !J.E E!;wnptXO Xl~W"CIO CX7t0 XOV"Cpot• 1tAotxi 6HD2. H E!;wnp1x71 ouaxEucxalcx 1tpE1tEt vex cxv-ccx1toxpi­ VE"CCXL a-ccx xcxpcxx-c71p1a-c1xix "CT)C:: xcx-ccxoxw71c:; 1tou cxvcxcpipov-ccx1 O"CO 7tEpt6WplO 3528. ( 6) TTAotO"CtXO 6oxElo !J.E E!;W-cEptxo ~otpEAI CX7t0 xcxp-covt 6HD 1. H E!;w-cEp1x71 auoxEuotolcx 1tpi1tEt vot cxv-ccx1toxplvE-cott O"CCX XotpotX"CTjpta"CtXIX "CT)<;; XCX"CotOXEUTJ<;; "7tOU CXVCXCj)EpOV"CCXI O"CO 7tEpt6wpw 3525 ex µixp1 B. • (7) TTAotO"CIXO 6oxElo !J.E E!;w-cEptXO Xl~W"CIO CX7t0 xcxp-covt 6HG2. H E!;w-cEp1x71 ouaxwcxoicx 1tpE1tEt vex cxv-cot1toxpivE-ccx1 O"Cot XotpotX"CT)ptO"ClXIX "CT)<;; XCX"CCXOXEUTJ<;; 7tOU CXVCXCj)EpOV"CCXI O"CO 7tEpt6Wpto 3530. ex !J.EXPt 1 . 8. TTAotO"CIXO 6oxElo !J.E E!;W-cEptxo ~otpEAt CX7t0 7tACXO"C IXO 6HH. H E!;w-cEptXTJ auoxEuotolcx 1tpE1tEt vot cxv-ccx1toxplvE-cot1 o-ccx xcxpcxx-c71p1a-ctxix "CTj<;; xcx-ccxaxEUTJ<;; 1tou cxvcxcpepov-ccx1 a-co 7tEpt6wpto 3526 CX Xott I !J.EXPL 6. Luv6totaµivEc; ouaxwcxo[Ec:;. ex. Eownp1xec; auaxwotalcxc;. M1topouv vex XPT)OL!J.07tOLT)60uv OUOXEUCXOLE<;; 0(7t() ,uCXAl, 1topoEAIXVT) TJ <j,cxµµo)..160 7tOU µ1topouv vex 7tEptexouv "CO 7tOA1J 5 Ai-cpcx pEUO"CIX TJ 5 xr a-cEpEIX UAIXIX. OIJOXEIJCXOLE<; 0(7t() 7tACXO"CtXO 7t01J µ1topouv vex 1tEp1exouv "CO 7tOAU 30 )..l-cpcx pwo-cix TJ 30 xr a-cEpEIX UALXIX. OIJOXEUCXOLE<; CX7t0 µi-cotAACX 7tOU µitopouv vex 7tEptexouv "CO 7tOAU 40 Al-cpcx pwo-cix TJ 40 xr anpEIX IJALXIX, T OIXV"CE<;; TJ OIXXXOIJ<; 0(7t() xcxp-cl, ucpcxaµcx TJ 7tACXO"CIXO TJ 7tACXO"CLXTJ "Cottvlcx 7tOIJ µ1topouv vex 7tEptexouv "CO 7t0AU 5xr pw­ o-cix • UAIXIX OE "COIXV"CE<; XCXI 5 xr OE oixxxouc;. .-: XOU"CIIX xcxp-covEVICX 7t0U Au,I;ouv XCXI Xl~W"Ctot CX7t0 xcxp­ cov1· TJ 7tACXO"CIXO 7tOU µ1topouv vex 7tEpLEXOUV "CO 7t0AU 10 xr O"CEpEIX IJAIXIX. Mtxpec; OIJOXEIJCXOLE<; IXAAOIJ "C1J7tOU, 07tW<; OWATJVE<; 7tOU µ1topouv vex 1tEp1exouv "CO 7tOA1J 1 Al-cpo PEIJO"CO TJ 1 xr anpEO UALXO. ~- E!;w-cEptxec; OIJOXEIJCXOLE<;;. M1topouv vex XPT)OL!J.07t0tT)6ouv: a!;w-cEptxec; OIJOXEIJCXOLE<; CX7t0 CX"COIXAL TJ CX7t0 CXAOU!J.LVLO (1tept6wpto 3532). Kov-cpcx 7tACXXE (1tEpt6wpto 3528 Cj)IJOLXO !;uAo (1tEpt6wpto 3527) xcxp-covt (1tEpt6wpto 3530) CXVotXCX"CCXOXEIJCXO!J.EVO !;uAo 7tEpt6wpw 3529 xm 1tAcxa,txo 1tEp16wpw 3531, B. LUOXEIJCXOLE<;; 7tOIJ µ1topouv· vex auµcpwvouv a-cot 7tEpt6w ptot 3510 (1) TJ (2). Luv6Ew:; OUOXEIJCXOLE<; (ruotAi 1topaEAIXVT) TJ <j,cxµµoA16oc;) 6PA1 - 6oxElo !J.E a!;w-captxo ~otpEAL CX7t0 CX"COIXAI. 6PA2 - 6oxElo !J.E a!;w-cEpLXTJ 6tX"CIJW"CTj OIJOXEUotolcx TJ E!;w­ "CEptxo CX"COIXAIVO XL~W"CLO. 6PB1 - 6oxElo !J.E E!;w"CEptxo ~otpEAL CX7t0 CXAouµlvto. 6PB2 - 6oxEio µE E!;wnp1x71 Btx-clJW"CTj OUOXEIJotoicx TJ E!;w "CEptxo XL~W"Cto CX7t0 CXAOIJµivto. 6PC 6oxElo !J.E E!;W-cEptxo Xl~W"Cto CX7t0 !;uAo. 6PD 1 6oxEio µE E!;w-cEptxo ~otpEAL CX7t0 xov-cpot 7tACXXE. 6PD2 BoxElo !J.E E!;wnptxo M,LVo XCXAIX6t. 6PG 1 6oxalo p.E E!;wnptxo ~otpEAI 0(7t() xcxp-covt. 6PG2 6oxEio µE E!;wnptxo Xl~W"Cto CX7t0 xcxp-covt. 6PH 1 6oxi;lo !J.E E!;W-cEptXTj OUOXEIJO(OLCX 0(7t0 6tota-cCXAµevo 7tAotO"ClXO. 6PH2 6oxEio µ~ E!;w-cEptXTj OIJOXEIJotalcx 0(7t() oxA71p6 7tACX­ O"CIXO. ex) Eawnp1x6 6oxElo. (1) Tot Boxalcx 1tpE1tEL VO( exouv Xot"CIXAAT)AT) µopcpTJ (x1JAlV 6p1x71 TJ 0(7tl0Et671) XCXl VO( exouv Xot"CCXOXEUotO"CEL CX7t0 IJAIXO xcx­ ATJ<; 7t0LO"CT)"CO<; 0(7t0(/\A(l(rµevo CX7t0 EACX"C"CW!J.ot"CCX 7tOU exouv "CT)V cpuo71 vex EAot-c-cwvouv -c71v cxv-cox71. T cx -cmxwµot-ccx 1tpi1tEL vex aivcxt aE xii6E 071µaio cxpxE-cii 1tot­ xeot XCXl CX7tCXAAot11J.EVCX CX7t0 EOW"CEptXE<; 7tlEOEt<;. (2) Lupµcx-co1t0t7JllEVEc:; XAEt6wvtic; cx1t6 1tAota-ctxo 1t<i>µcx-ccx cx1t6 -cptµµivo ruCXAl 71 IXAAE<; XAEt6wv1ic; a!; !aou ex1tonAEoµcx­ ctxic;, µ1topouv vex XPT)OL!J.07t017J6ouv ocxv XAEt6wvtic; "CWV 60 XELWV. ·o;>..cx -cot -cµ71µex-ccx -cwv XAEt6wv1wv 1tou 6cx µ1topouaexv vex eA6ouv o' E1tcxcp71 µE -co 1tEptEXO!J.EVO -cou 6oxi;lou 1tpE1tEt vex El­ vott cxv6Ex-c1xix O"CTj 6piio7J mu 1tEptexoµivou. TTpE7tEI vex 1tpooexouµi; "CT)V ouvexpµoMrriori "CWV XAEL6ex­ ptwv WO"CE VO( Elvext a"CErcxvic; XCXl vex !J.7tAOX1XpOV"CCXI XCX"CIX "CT)V µE-cotcpopix, 1 tot vot ex1tocpau1 i;-cot1 7J XCXAiipwOTJ -cwv. Av OL XAEt6wvtec; µi; exEptoµo XPEtix;ov-cext 6cx 1tpE1tEI vex i;lvext o-cqexvec;. (3) To 6oxEio 1tpE1tEL VO( Ecpexpµo;a-ccxt XCXAIX O"CT)V i;!;wnptXTj auoxwotalot µeaw uA1xwv 1tou µi;-cp1ix;ouv -couc; xpcx6exaµouc; 71 µa cx1toppocp7J-ctxix UAtxix. ( 4) Ma,la"CTj 7tEptEX"CIXO"CT)<; "COU 6oxelou 60 )..I-cpex. ( 5) Ma1lo,7J xex6otp7j µix;ex 7 5 X 1 . B. E!;wnptx71 auaxauexaicx. (1) i\oxaio !J.E a!;wnptxo ~otpEAt ()(7t() ex-caiiAt 6PA1. H a!;wnp1x71 auaxwotolcx 1tpi1tE1 vex exv-ccx1toxpiva-cext o-cex . xcxpotX-CT)pta"CtXIX "CT)<;; xex-cotaXEIJTj<; 7t0U cxvexlpipov-cext O"CO 7tEpt 3528 . 6wpto ex µexpt 1). • To XIVT)"CO 1twµot 7tOU XPEtix;e-cext ,tex "COV "CU7t0 exu-co au­ OXEIJotaicxc; µ1topal vex EXEL -c71 µopcpTJ xex1texxtou. (2) i\oxalo µ E a!;w-captx716tx"CIJw-c71 auoxwexo1ex 71 µi a!;wn­ ptxo Xt~W"CLO 9(7t0 ot"COIXAI 6PA2. H e!;w-ceptx71 auaxauexaiex 1tpE1tEt vex exv-cex1toxplvE-cot1 o-cex xcxpotX-CT)ptO"CIXIX "CTj<; xex-cexaXEIJTj<; 7t0U CXVCX(j)Epov-cext O"CO 1tEpt~ 6wpto 3532 ex µexp1 ,. Av "CCX 6oxeiex ELVotl XUAtv6ptxlX xext OE xii6E"CTj 6fo717J a!;w-cE­ pLXTJ OIJOXEIJCXOLO( 1tpE1tEL vex IJ7top~otlvi;t c,i; u<j,oc; IXAAWO"Co XCXI Ol x)..i;16wv1ic; -cwv. Av T) a!;w-ci;ptx71 ouaxwcxaiex oi; µopcpTJ i;!;w-ci;p1x716tx-cuW"CTj OIJOXl;UO(OLCX 1tEp1-cuAi,i;1 EVO( otmoi;16ic; 6oxalo XotL CXV 7J µopcpTJ cou 1tpoacxpµo;i;-ccxt o' exu-co 1tpi1tu vex Eivcx1 Ecpo6totoµivo cx1t6 ivcx 1twµot 1tpoo-ccxalotc; (xcx1tiAo). (3) i\oxElo !J.E E!;w"CEptxo ~otpEAl ex1t6 CXAouµlvto. 6PB1. H E!;wnptx71 auaxEuexaiex 1tpE1tEt vex exv-cex1toxplvE-cott a-cot xotpexx-c7Jpto-c1xix -CTJ<; xot-cotoxw71c; 1tou otvcxcpepov-cext a-co 1tEpt 6wpto 3521 ex µixpt 6. 4. i\oxElo µi; E!;w-cEplXTJ 6tX"CUW"CTJ auaxwexalot TJ e!;wnptxo xt~W"ClO ex1to otAouµiv10. 6PB2. H • i;!;w-cEptXTJ ouaxEuotolex 1tpE1tE1 vot otv-cex1toxplvE-ccx1 a-cex xexpotX"CT)pta"CtXIX "CT)<; Xot"CexOXEIJTj<; 7t01J exvcxcpepov-cext a-co 7tEpt 6wpto 3532. (5) i\oxEio !J.E E!;w-cEptxo Xl~W"CIO ex1to !;uAo. 6PC. H E!;wnp1x71 ouaxi;ucxaiex 1tpi1ta1 vot exv-ccx1toxplvE-cot1 o-cex xexpotX"CTjpta"CtXIX 7tOIJ otVCXCj)Epov-cext O"CO 1tEpt6wp10 3527, (6) i\oxEio !J.E i;!;w-cEptxo ~otpEAL ()(7t() xov-cpcx 1tAexxi. 6PD1. 3539 H a!;w-cEptXTJ auoxEuotolot 1tpi1tE1 vex cxv-ccx1toxplvE-cott o-cex. XotpotX-CT)pto-ctxix -CT)<; xcx-ccxaxw71c; 1tou otvexcpipov-ccxt a-co 1tEpt 6wpto 3523. (7) i\oxdo !J.E E!;w"CEptxo Au,tvo XotAIX6t. 6PD2. Tot M1 tvex xCXAix6tcx 1tpi1tEt vex xex-ccxoxEuix;ov-cext xot-ciiA­ AT)Aot Xotl ()(7t() IJAIXO XCXATJ<; 7tOtO"CT)"CO<;. TTpE7tEI VO( Ecpo6ux;o­ v-cex1 cx1t6 1tpoa-cex-cEu-ctx6 1twµex (xex1tiUo) wo-ci; vex cx1tocpEu 1ouµE "CT) ;7Jµicx "CWV 6oxElwv. (8) i\oxEio !J.E a!;w-cEptxo ~expEAI ex1t6 Xotp-covt. 6PG1. H E!;w-cEp1x71 ouaxwexaiex 1tpi1tEt vex exv-cex1toxplvE-cot1 a-ccx XCXpotX"CTjptO"CLXIX "CT)<; xex-cotOXEUTJ<; 7tOU OIJVIO"CWV"Coti O"CO 7tEpt 6wpto 3525 0( µexp1 6). 9. i\oxaio !J.E E!;w-cEptxo Xl~W"CIO 0(7t() Xotp-covt 6PG2. H E!;wnptXTJ ouoxEuotaiot 1tpE1tEt vcx otv-cex1toxpivE-cot1 o-c9t x.expexx-c71p1a-c1xoc -c71c; xex-ccxaxEUTJ<; 1tou exvexcpipov-cext o-co 7tapt 6wpto 3530 ex µexp1 r 10. i\oxEiot !J.E E!;w-cEptXTj OUOXEUCXOLO( 0(7t() 6toto-cexAµivo 7tAO(O"CIXO TJ 0(7t0 OXAT)pO 1tAexa-c1x6. 6PH1 TJ 6PH2. Tex IJALXIX "CWV Mo (l(IJ"CWV E!;w-cEptxwv ouaxEuexatwv 1tpE1tEI vot cxv-cot1toxplvov-cot1 a-et<; 6tcx-cii!;Et<; 1tou cxvotcpipov-cext a-co 1tEpt 6wp10 3531 0( !J.EXPI ;. 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X(X't!X 'tTj 6te!;<X-yw-y11 'tWV 6oxtµ<Xatwv O't(X uAtxix <XU't!X ii fl-E 't'fj 6t<X,iiPTJOTJ ,wv 6u1 µix,wv ii ,wv o,ot­ XEiwv 'tWV UALXWV. 5. Eixv XPELIX/;E,<Xt Eaw,Eptxii rniv6ua'fj 1 t<X Ao1 ouc; <XOq><X-. AEi<Xc;, 1tpE1tEL V(X 6t<X't1JpiiaEL ,tc; 1tpOO't(X"tW'tLXEc; 't"ljc; t6tO't"lj'tEc; <XXOfl-<X X<Xt fl-E't!X ,tc; 6oxtµ<XoiEc;. ITpoE,OtfJ-<XOi<X ,wv auoxw<Xatwv x<Xt ,wv 6Eµix,wv 1 t<X ,tc; 6oxtµ<XaiEc;. . • • 1. Ot 6oxtµ<XaiEc; ·1tpE1tEL v<X EX'tEAOUV't<Xt mi ouaxw<Xatwv X<Xt 6Ef1-1X"tWV 1tou Eiv<Xt hotµEc; 1tpoc; <X1too,0Aii ouµ1tEptA<Xµ­ ~<Xvoµivwv X<XL 'tWV EOW'tEptxwv OUOXEU(XOLWV X(Xt 'tWV ouv 6u<X./;oµivwv. Ot ~;w,Eptxic; OUOXW<XaiEc; ii 6oxEi<X ii f1-0V<X6txic; OUOXEU(X­ oie;c; 1tpE1tEt v<X 1 Eµil;ov-r<Xt 'tOUAIXXta,ov 1 t<X 95% 't'fjc; 1tEpLEX'tt­ XO't7]'t6c; ,ouc; 1 t<X ,<X o,EpEix UALXIX X<Xt ,o 98% 1 t<X 't<X pwa,ix. T<X UALXOL 7tOU 1tpimt V(X fl-E't<X(flEpOV't(XL O't(X 6iµ<X,(X µ1topouv V(X (XV'tLX<Xllto,OUV't(XL (X7t() IXM(X UALXOL Ex,oc; EIXV ixouv 'tTJV q>UOTJ V(X 6l6ouv cJ>w611 (X7t0'tEAEOf1-<X't(X 'tWV 6oxLf1-<XO'tWV. r L(X 't(X O'tEpEa UALXIX (XV XPTJ0:µ01tOLEh<Xt OLMO UALXO, 1tpim.L V(X EX Et nc; l6tEc; t6t6,Tjnc; (µix/;<X a1tetpoµhpTJOTJ x.A1t.) fl-E ,o UAtxo 1tou 8<X fJ-E't<X(flEp8e;L Em,pE?tE't<Xt "I} XPTJOTJ 1tp6a8e;,wv ~<Xpwv 61twc; OIXXXWV fl-E o/TJ"Yfl-<X't(X fl-OAu~6ou )'"L(X V(X (X7tO 3540 3541 3549 3550 3551 X't!Xfl-E 't'fjV (X7t(XL't0Uf1-EVTJ OUVOAtXii µix/;<X 6Ef1-<X't0c; E(flOOOV 't07t0 8E"tOUV't(XL hot wo,E v<X fl-TJV E1t1jpEi/;ouv <XpVTj'tLXIX 't<X <X7tO'tEAE­ ofJ-<X,<X 't"lj<; 60XLfJ-<XOt(Xc;. K<X,OLM1JA<X µi-yµ(X,(X a,EpEwv XOVtop,w6wv UALXWV 61twc; 7t-X· ax6vTj 1toAu<Xt8uAivtou TJ PVC fl-E 1tptovi6t AE1t,ii ixµµo x.A7t. µ1topouv V(X XPTJOLf1-07tOLOUV't(XL O(XV UALXIX 1EfJ-iOfJ-<X'toc; we; (XV'tLX(X'tOLO't<XOTJ 't~V UALXWV 7tOU e.xouv fJ-E 2 3 ° C µi<X tl;w 6o,Tj't(X µq<XM,Ep1] ix.1to 2680µµ2/6Eu,. • • 2. ft(X 'ttc; 6oxtµ<XoiEc; 7t'tWOEWc; OXE'tLXOL fl-E 't(X pwa'tOL O't(XV XPTJOLfJ-07tOtEi,<Xt ixMo uAtxo 1tpi1tu vr1. i-x u 1t\lXVO't1j't<X oXE­ 'tLXTJ x<Xt tw6o,Yj,<X <X~AO"Y7J we; 1tpoc; ,o UAtxo 1tou B<X fl-E't<X­ q>Ep8d. To vEpo µ1topd rnio"ljc; V(X XPTJOLfl-07tOtEh<Xt -yt(X 'ttc; 6oxtµ(X­ oiEc; 1t'tW0Ewc; u1to ,Le; 1tpou1to8foEtc; 1tou x<XBopil;ov,<XL o,o m.­ pt8wpto 3552(4). 3. Ot ouoxw<XoiEc; <X7tO X<Xp,i ii X<Xp,ovt 1tpE1tEL V<X XALfl-<X,i­ l;ov,<Xt 1tpW't(X E7tL 24 wpEc; 'tOUAOLXLO'tOV OE <X'tfl-OOq><Xtp<X exouo<X oXE'ttxii u1 p<Xoi<X x<Xt 8Epµoxp<Xoi<X 1tou EAE)'"XOV't<Xt. 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TIX 6Eij"µIX,IX 1tpimt \/IX exouv 1tpo-1X1to0rixw0Ei [-LE 'tO IXU 0Ell'tlXO UALXO "(Eµ[a~IX'tO<; auµcpw111X µE 'tO 7tEpt0wpto 3551 (5) 71 1tlX ,t,; auaxEu1XaiE::; IXltO 1toAu1Xt8uA1Xi11to µE u47J'-71 µo­ ptcxx71 µii~IX µE 'tO 'tUltOltOl7Jµi110 pEUO''tO µi"(µIX u61X't1X110piixw11 (WHITE SPIRIT) auµcpw111X [-LE 'tO 7tEpt0wpto 35 51 ( 6 ). ( 4) ME0o5o,; 6oxtµ1Xa[1X,;. TIX 5Ei"(µIX,IX 6oxtµ1Xat1X<; 1tou 1Evi~OV't1Xt µE ,o UALxo "(tlX ,o 01toio 8cx Em,p1X1tEi 7J auaxw1Xai1X 1tpi1tEt VIX ~u1i~ov,IXL 1tptv XIXl µE,IX 't7JII 1X1to871XEUO'Tj 2 8 7JµEpw11 µE 23 ° C XIXl 50% axE­ 'ttx71 cx,µoacp1Xtptx71 u1pcxaicx. ftlX auaxw1Xa[E::; 1X1t6 1toAu1Xt8uA1Xivt0 µE u4ri'-71 µoptcxx71 µ<i~IX. TJ ooxtµ1Xa[1X µ1topEi vex 1tp1X1µ1X,01tot7J0Ei µE ,o ,u1to 1tOt7Jµi110 pwa,6 µ[1µcx u61X,1X110piixwv (WHITE SPIRIT) cxv,[ ,ou ~Ev~oAiou ,oAouoAiou 71 ;uAoAiou. 5. Kpt,71pt0 cx1to6ox71::;. H 5tlX7tEp1X'tO'tTjt; 5EII 1tpE1tEl VIX U7tEp~1XtllEl 'tlX 0 , 008re Iw. Luµ1tA7Jpwµ1X,LXTJ 5oxtµcxaicx 1 tcx ,ex ~cxpiAtcx 1X1to cpuatx6 ;uAo µE 07t7J, ( 1) Apt0µ6::; 5Et1µii,wv 6oxtµcxai1X::; 1 ~cxpEAt (2) ME0o5o,; 6oxtµ1Xaicx::; NIX 1Xcp1Xtpa0ouv oAot Ol xuxAOl 7t0U ~piaxOV'tlXl rn&.vw IX7t0 ,o xu,o::; ,ou ii5Etou ~cxpEAtou auvcxpµoAo1ouµivou ,ouAixxt­ a,011 2 µepE<; 1tptv. (3) Kpt,71pt0 OClt06ox71::; H cxu;riaTJ 'tTj<; 6t1Xµhpou 'tOU IXVW ,µ71µoc't0::; 'tOU ~IXpEAtOU 5Ev 1tpimt VIX EtVIXt IXVW,Ep7J cx1t6 10%. 'E1xpta7J ,wv auv6t1Xaµivwv auaxw1Xatwv. L7J[-l «Ot auvotcxaµivE,; auaxw1XaiE::; 1tpi1tEt vex ooxtµii~o­ V'tlXL auµcpwvac [-LE 'tl<; 5tcx,<i;Et,; 'tt<; Ecp1Xpµoa'tEE<; a,t::; E;w,Ept­ xi::; CIUCIXEUIXCltE<;. ( 1) Kcx,ii ,t::; 6oxtµ1XaiE,; mi ,wv ,u1twv x1X,cxaxw71::; ,wv auvfo1Xaµevw11 O'UO'XWIXCllWV µ1topouv 'tlXU'tOXPOIIIX \/IX E"(Xpt110 V't1Xl Ol CIUO'XWIXO'LE<;». IX, ME EO'W'tEptXE<; CIUO'XEUIXCltE<; µtxpo,Epou Oj"XOU. ~- Kcx0cxp71,; µ&.~ex::; xcxµ7JAW'tEp7J<; IX7t0 EXELVTj 'tOU 't1)7t0U XIX'tlXCIXEU71::; 7tOU 6oxtµ1Xa't7JXE. (2) Av 5tiicpopot ,unot auv5tcxaµevwv auaxEucxatwv 1tEpti­ xov'tE::; 5uxcpopou,; 'tU7tOU<; ECIW'tEptXWV CIUCIXWIXCllWV, E"(Xp[vo­ V'tlXl Ol 5tiicpopE<; ECIW'tEptxe.::; O'UCIXWIXO'tE<; µ1topou11 E7tt01j<; \/IX EVWVOV'tlXl O'E µ[ex µovov E;w,EptX'Tj CIUCIXWIXCltlX µE 't'TjV 1tpoii 1to8EC1Tj O'tt O IX7tOO''tOAE.IX<; ~E~IXlWVEl cm 'tO 5e.µIX IXV'tlX7tOXpivE­ 'tO(t O''tlt; fo1X,&.;Et<; OOXtµacatlX<;. (3) Ecpoaov 7J t5tO't7J'tlX 'tTj<; IXV'tOXTJ<; 'tWV EO'W'tEptxwv au­ CIXWIXO'lWV IX7t0 7tAIXO''tlXO, 'tWV auv6t1Xaµe11wv OUOXWIXOLWV, OEV ,p07tOltotOUV'tlXl ariµcxv,tx&. IX7t0 't'Tj opixari 'tOU UAlXOU "(E­ µiaµoc'tO::;, 5Ev Et\llXl 0(7t1Xp1XL't7J't0 VIX 1tpoaxoµta8Ei 7J 1X1to6Et;Tj 'tOU rncxpxou<; X7JµtXOU auµ~t~cxaµou. L7Jµcxv,tx71 ,po1to1toiriari ,wv t6t0,71,wv cxv0Exnxo,ri,cx::; EV\IOU[-J-E» IX. Micx ariµcxv,LXTJ Eu0pocua,6,7J,IX, ~- MilX ariµcxntx71 µEtWOTj n1,; EAIXO'ttx71,; 7ttEOTj<; EX'to::; IXV auv5E.E't0Cl µE µicx ltAE.OV 71 EAcxaaov IXVIXAO"(O cxu;riari 't'Tjt; EAIX­ O'tLx71::; E7tlfl71XUV07J<;, 3557 3558 Micx ix0Ecr7J 6oxtµ1Xai0t,; 1tpimt vex x1X,cxp,i~E't1Xt xcxt 01X cxvcxcpipu ,ouAiixta'tOv ,t::; E;71::; 1tA7JpocpopiE::;». 1. Op"(IXlltCJµo ltOU 1tpOE~Tj Cl'tt<; 6oxtµ1XaiE::;. 2. At'tOU\l'tlX. 3. K1XCJ't1XO'XWIXCl't71 't'Tj<; O'UOXEUIXO'tlX<;, 4. TIEpt"(p1Xcp71 't'Tjt; CIUOXWIXO'LIX<; (1t,x, CITj[-J-IXV'tlXIX xcxp1XX't7J­ ptCl'tlXIX 61tw,; 'tO uAtxo, 'tTjV Eaw,Eptx71 E1ti116uari, ,t::; 5tcxa,ii­ aEt::;; 'tO 1tiixo::; 'tWV ,mxwµii,wv µii~IX XAEt5wvtii XPWfllX'tl­ aµo 'tWV 7tAIXO''tlXW11). 5. LXiSto XIX'tO(axw71::; 't'Tj<; auaxwlXaioc::; xcxt ,wv XAEt5w vtwv (iiAAw,; cpwwrp1XcptE,;). 6. Tp61to x1X,1Xaxw71::;. 7. ITpiX"([-llX'tlXTJ 7tEptEX'tlXO'tTj'tlX. 8. Em,prnoµEVIX UAtXIX "(E[-lLO'[-llX'tO<; (Et5txlX [-LE 'tTjV IXIIIX­ cpop&. 'tWII CIXE'tlXWV 7tUXIIO't71'tWV XIXl 'tWV ltlEO'EWV E;cx,µiaEWV O'E 50°C TJ 55°C). 9. T4o,; 1t,WaEw::;. 10. mECITj 6oxtµ1Xai1X::; XIX'tlX 'tTj 6oxtµ1Xaicx O''tE"(IXVO'tTj'tO<; O't1µcpWVIX µE 'tO 7tEpt8Wpto 3553. 11. TILEa7J 6oxtµ1Xaicx,;, ,ri,; 6oxtµcxai1Xc; Eaw,Eptx71,; 1tiEa7J<; auµcpwYIX µE 'tO 7tEpt8Wplo 3554. 12. T 4o::; 6Eµ1X,01toiriari::;, 13. A1to,EAfoµcx'tlX ,ri,; 6oxtµcxai1X::;. 14. L7JµEiwari a,ri auaxwlXaiac xact 1tA7JpocpopiE::; 1tou IXVIX­ cpiponm a,riv 'tlXU'tO't'Tj'tlX ,ri,; xAEt5wvtii,;. B. ~oxtµIXaicx a,E1cxv6,ri,o::; "(tlX oAE::; ,t,; xocwoup1tE,; au­ axw1XaiE,; 71 7t0U OCVIXXIX'tOCOXEUIXO'tTjXIXV Ol 07tOtE<; 1tpoopi~o­ V't0Cl 110( 7tEptexouv pwa't!X UAlXIX. 3559 (1) Ex,E.AEOTj 'tTj<; 5oxtµcxailX::;. 3560 Ex<XO't'Tj ooxtµ1Xaicx 7t0U 1tpoopi~E't1Xl VIX ltEptEXEl pwa,IX uAtx<i 1tpE1tEt vex u1to~IXME't1XL a,ri 6oxtµcxai1X a:rqocvo,ri­ ro,;. 1tptv XPTJOl[-l07t0lTj0Ei "(llX 1tpw-rri cpop<i "(llX 't'Tj µe-rcxcpop<i. µE,IX 'tTJV IXVOCXIX'tlXOXW71, 1tptv E7t1XVIXXP7JOLµo1tot7J0Et "(llX 'tTj µE,1Xcpop1X, H 5oxtµcxatlX IXU't71 5Ev IX7tlXl'tEt'tlXl oµw::; "(llX :t<; EOW'tEptxe,,; auaxwcxaiE,; 'tWV OUVOLIXO[-J-E.VWV auaxwcx- \ OlWV. 'tlX EOW'tEptXIX 5oxEtlX 'tWV OUV0E'tWV CIUOXEUIXOlWV ("(UIXAt, 1topaEAIXVTJ, 71 4cxµµ6At0o) auµcpwvlX µE ,:o 7tEpt0wpto 3 510 (2). 'tt::; auaxwacai.::; µa IXVW ,µ71µcx XlVTj'tO ltOU 1tpoopi~Oll't1Xl VIX 7tEpte.xouv UAtXIX 'tWV 07t0tWV 7J t;w56,ri::; µE 23 ° C EtVIXl IXVW­ 'tEP7J cx1t6 200µµ2/Sw,. ,t::; auaxwcxaiE,; cx1t6 EAcxcppo µi,illo auµcpwva::; µE ,o 1tEpt 0wpto 3510(2). (2) ME0o5o::; ooxtµIXaicx::;. 0 auµm1t1aaµevo::; IXE.pcx,; 0cx ElOCXX0Ei "(llX xii0E OUOXEUIXOLIX IX7t0 't'Tjll 01t71 "(Eµiaµcx,o::;. Ot OUOXEUIXOtE<; 1tpe.1tEl VIX 't07t00E 'tOUV'tlXl x&.,w IX7t0 'tO VEpO. . 0 ,p61to::; 6tcx"t7JpTJ07J<; 'tWII OUOXWIXOlW\I XIX'tW IXltO 'tO VEpo 5Ev 1tpe.1tEL vex cxAAotwvEt ,ex cxitonAfoµcx'tlX -rri::; 5oxtµcxaicx::;. Ot EIIWOEL<; xcxt ,ex <iAAcx ,µ71µcx-r1X ,wv auaxwcxatwv 61tou 0cx µ1topouaE \/IX 7t1XP1XX0Ei µicx Otcxppo71 µ1topouv rniari,; VIX XIXAU 7t'tOll'tlXl µe cxcppo OIX7tOUVtoU, [-LE ~cxcp71 Acx5tou, 71 [-LE 01toto671 1tO'tE <iAAo xcx-r<XMTJAO pEua,6. 'AME::; µe.0o5ot a; iaou IX7tO'tE­ Aeaµcx,txe,; µ1topot1V E7tlOTjt; VIX )Cp7lOlp.01tOl7J80t1V. ~EV XPELIX~E'tlXl m CIUOXWIXCltE<; VIX acpo6t1X~OV'tlXl µE 5txi,; ,ou,; XAEt5wvte.,;. Oµii5cx auax. 1 Oµ<iolX CIUCIX. 2 Oµ<i61X auax. 3 rouA/a,ov 30KP1X ,ouA/a,ov 20KPcx ,ouAjai:011 20KPcx 3559 1246 E<l>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: aEYTEPO) (4) KpL'tTjpto 0t1to6ox11c;;, Llcll 1tpi1tct IIOt EXEL 6t0tppoic;; Otepoc;;. TµTjµ0t V - µc,0tf30t,tXTj 1tcp1o6oc;;. Ot OUOXEUOtOicc;; ltOU 6c11 1tA11po{111 'ttc;; 6t0t't0t;uc;; 'tOU 1t0tpo­ ll'tOc;;, illdt ltOU µ1topou11 IIOt X?11otµo1tOtOUll'tOtt ouµcpw110t µc ,tc;; 6t0t,dt;cLc;; ,ou ADR taxuouocc;;·,1111 30 A1tptAiou 1985 jtOt 'tOt Otll'tLO'totXOt UAtXOt 'tWII XAOtOEWII 3 6.1 XOtt 8, 80t µ1topou11 110t X?11otµo1totou11,0tt E1ti µtdtc;; µc,0tf30t,tx11c;; 1tcpt66ou 5 E'tWII µixpt 'tTJII 30 A1tptALOU 1990 jtOt ,1111 µn0tcpopdt 'tWII UAtXWII OtU'tWII. Ot OUOXEUOtoicc;; ltOU 6E11 1tA11pou11 'ttc;; 6t0t,0t;Etc;; 'tOU 1t0tpo­ \l'tOc;;, ltOU XP11otµo1totOUll'tOtll oµwc;; jtOt 'tOt UALXOt 'tOt µ11 XOtllOllt­ oµi110t 0t1to ADR, ,1111 30 Aurouo,ou 1985 OtAAOt 1tou 0t111j­ xou11 o,tc;; XAOtOEtc;; 3,6.1 x0tt 8, µE Ecp0tpµoj1j 0t1to ,1111 l 11 Mdt11 1985, µ1topou11 110( OU\IEXL,Oll'tOtt IIOt X?11otµo1totOUll'tOtL jtOt 't11 µc,0tf30t,tXTj 1tEpio60 5 E'tWII µi)(Pt ,111130 A1tptAiou 1990 jtOt 'tTJ µc,0tcpopdt ,w11 uAtxw11 0tu,w11, Eq,00011 ot 6t0t,dt;ctc;; ,w111t0t­ p0tjpdtcpw11 1, 2, 4, 5, 6 x0tt 7 ,ou mpt9wpiou 3500 ,ou 1t0t po11't0c;; 'tTJpou11,0tt. • Lw11µµi110 'tOU A.5. Tµ11µ0t I Tu1to1tot11µi110t pcUO'tOt jtOt IIOt Otlt06EtX9Ei O x11µtxoc;; OU~t­ (30toµoc;; 'tWII OUOXEUOtOtW~ OtltO ltOAU0tt8uAi11to µc utj,11).11 µo­ ptOtXTj µet'Ot oUµ(j)WIIOt µE 'tO 7tEpt9Wpt0 3551 (6). T0t c;Tjc;; 'tUlt01tot11µi110t pEUO'tOt 80t X?11otµo1tot118ou11 jtOt 'tO ltAOtO'ttXO OtU'tO UAtXO. Llt0tf3pEx,txdt 6t0tAuµµ0t,0t . Llt0tf3pEx,txo 6tdtAuµµ0t jLOt ,Ot uAtxdt ,w11 01toiw11 'tOt cx1ton­ ).foµ0t,0t axtoµou UltO lttE011 O'tO ltOAUOtt9UAElltO EtllOtt 6u110t't0t Et6txdt jtOt oAOt 'tOt 6t0tAuµ0t,0t x0tt 1t0tp0toxcudtoµ0t,0t 1tou 1tEpti­ xou11 6t0t{3pEX'ttXOt, 00t X?110t(J,Olt0tTjOOUµE u60t'tLXOt 6ttxAUµ0t,0t OtltO 1 ewe; 10% E11oc;; 6t0tf3pEx,txou. H Emcp0t11rnxx11 1tiE011 ,ou 6t(X).uµ0t­ ,oc;; OtU'tOU 1tpi1tEL IIOt EtllOtt µE 23 °C OtltO 31 µE 35µN%µ. H 6oxtµ0toi0t 6Eµ0t,01toi11011c;; 80t 1tp0tjµ0t,01tot118~l A0tµ(3dt 11011,0tc;; (3dto11 µt0t oXE'tlXTj 1tux110,11,0t ,ouAetXto,011 1,2. E0t11 0 E1t0tpx11c; x11µtxoc;; ouµ(3tf30toµoc;; Otlt06EtXIIUE't0tt µE EIIOt 6t0tf3pEX'ttXO 6tdt).uµ0t 6EII )(?EtOt,E'tixt IIOt 1tpo(3ouµE OE x0tµ­ µi0t 6oxtµ0tOLOt ouµf3t{30toµou (J,E o;tXO o;u. B. O;txo o;u jtOt 'tOt UAtXOt XOtL 1t0tp0tOXEU0toµ0t,Ot ltOU exow OtltO'tEAfoµ0t,Ot axtoµou UltO ,1111 ltLE011 ltOAUOtt9UAEIILOU, Et6txdt jtOt 'tO µ011ox0tpf3o;uAtXO o;u XOtt jtOt 't11 µ011008EIITj OtAXOOA11· 00t )(?110tµ01tOtTjOOUf1E o;tXO o;u OE OUjXEll'tpWOTJ 98 (J,E 100%. LXE'ttXTj ltUXIIO'tTjc;; 1,005. H 6oxtµ0toi0t 6Eµ0t,toµou 80t 1tp0tjµ0t,01tot118El A0tµ(3dt110 ll't0tc;; 00t11 (3dto11 µt0t oXE'ttXTj 1tux110,11,0t ,ouAetXto,011 1.1. L,tc;; 1tEpt1t'tWOEtc;; ,w11 uAtxw11 jEµloµ0t,oc;; u1to ,1111 E1top­ po1j 'tWII OltOLWII 'tO ltOAUOtt9UAElltO (j)OUOXWIIEL ltcptooonpo 0t1to o, ,L u1to ,1111 rntppo11 ,ou o;txou o;iwc; µi)(PL ,ou 011µEiou 61tou 11 µdt,0t ,ou 1toAu0tt8uAi11tou 80t 0tu;118Ei ,o ltOAU 4%, o E1t0tpx11c;; xwtxoc; ouµf3tf30toµoc;; 80t µ1topEl IIOt Ot1t06EtXIIUE'tOtt µE,Ot OtltO 1tpo-0t1t081jxEuo11 3 c(36oµaow11 µc 40 ° C ouµcpw110t µE 'tO 7tEpt9wpto 3551 (6) OtAAOt µE 'tOt OtU9Ell'ttXOt Eµ1topEu­ µ0t,0t jEµloµ0t,oc;;. 3561 3569 3570 3571 3599 j) O;LxO ,ou (3ou,uA!ou (x0t11011txo) /6t0tf3pEX'ttXO 6tdt).uµ0t xopEoµi110 0t1to o;txo ,ou (3ou,uAlou x0t11011txo jLOt ,Ot uAtxdt x0tt 1t0tp0toxEudtoµ0t,0t 1tou cpouoxw11ou11 ,o 1toAu0tt8uH11to OE ,hoLo. 011µEio 1tou 11 µdt,0t 0t1t6 1toAU0tt8uAi11to 0tu~0t11E,0tt µc ,o ltOAU 4% XOtt ltOU 1t0tpouotdt,ou11 'tOtU'toxpo110t EIIOt OtltO'tEAEoµOt axtoµou UltO ,1111 lttEOTj XOtt ct6txdt jtOt 'tOt (j)U'tO-UjtEtllOt 1tpoi:o­ ll't0t, 'tOt pEUO'tot XPW(J,Ot'tOt XOtt 'tOt EO'tEpOt. 00t X?110t(J,OltotTjOOUµE o;txo (3ou,lAt0 -'to XOtllOlltXO- OE ou­ jXEll'tpwo11 98 µE 100% jtOt 't1111 1tpO-Ot1t081jXEU011 ouµcpw110t µc 'tO 7tcpt9wpto 3551 (6), r tOt ,11 6oxtµ0toi0t 6cµ0t,toµou 80t xp11otµo1tOtTjOOU(J,E ouµ­ (j)WIIOt (J,E 'tO 7tEpt9wpto 3555 EIIOt ooxtµOtO'ttXO UjpO ltOU OtltO­ 'tEAEL'tOtt 0t1t6 6t0tf3pEx,txo u60t,txo 6t0tAuµ0t 0t1to 1 iwc;; 10% 0t110tµcµtjµE110 µE 2% XOtllOlltXO o;txo 'tOU (3ouwAiou, ouµ­ (j)WIIOt µE 'tO Ot OtllW'tEpW. H 6oxtµ0toi0t 0Eµ0t,toµou 80t 1tp0tjµ0t,01tot118ci 1t0tlp11011,0tc;; 00t11 (3dto11 µt0t oXE'ttXTj 1tux110,11,0t ,ouAOtXto,011 1,0. L,tc;; 1tEpt1t,woEtc;; ,w11 uAtxw11 jcµloµ0t,oc;; u1to 'tTJII cmppo11 'tWII OltOLWII 'tO ltOAUOtt9UAEllt0 (j)OUOXWIIEt 1tEptooonpo OtltO o, 'tL UltO EXELll11 'tOU XOtllOlltXOU o;txou 'tOU (3ou'tUAtOU XOtL OE 'tE-. 'tOtO 011µEio ltOU 11 µdt'Ot 'tOU ltOAU0tt8UAElltOU µi)(Pt 'tO ltOAU 7,5% XOtt O E1t0tpx'ijc; X11µtxoc;; ouµf3tf30toµoc;; 80t µ1topEt IIOt 0t1to6Etx11un0tt µE,et 0t1to µl0t 1tpo-0t1to81jxEVOTJ 3 c(36oµdt6w11 µE 40 ° C, ouµcpw110t (J,E 'tO 7tEpt9wpto 3 5 51 ( 6) illdt µE OtU9E­ ll'ttXO cµ1topcuµ0t jEµto11c;, 6. 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OL ouolEc; 1tou ixow xpL'tLX7I llEpµoxpotoiot xdt'tw ot1to 50 ° C 71 o' otU'tTj 't7I llEpp.oxpotoiot 'tCXOTj ot'tµou (J,EjotAt'.mp71 ot1t0 3 00 KPot (3 BAR) 1tpi1tEL VO( 7tEptiXOV'tO(L µfoot OE 6oxEiot 1tou <XV'tot1toxpivov'totL mio71c; O'tLc; 1tpo~).icjiuc; 'tWV 1tEpL6w­ piwv 2202 XotL 2211 iwc; 2218. B. LU(-t1tA71pwµot'tLxic; 06711 iEc; jLot 'tot 6iµot'tot 'tou 'tU1tou A. 1. Kcx6E 6iµot 1tp£1tEL \lot EXEL E<po6LotO'tEL E;W'tEpLXOt 0(7t() £\10( fL71XotVLO(J,O 61twc; µiot ocppotjiOot 7tOU 6Ev EL\lotL EU6potUO't7j XotL 7tOU E\l't07tL,EL xcx6E CX\IOLj(J,ot 'tOU 6iµot'toc;. 2. Kot'tCX 'to µhpo 'tou 6wot'tou, 'to E;wnpLxo µipoc; 'tTjc; ou­ oxwotolotc; OE\I 7tp£7tEL \lot 7totpOUOLCX,EL xotµiot E;ox71, 3. To µov'tiAo 't7lc; ouoxwotoicxc; 1tpi1tEL vex Acxµ~cxvEt u1tocji71 'tou 'tLc; µe'tcx~o).ic; 't7lc; 0epµoxpcxoicxc; 1tou 0cx µ1topouoE vex U7tOO'tEL 71 OUOXEUotoicx XCX'tOt 'tTjll µncxcpop&: XCXL 't7IV ot1to671 XEU07I, Oc; 1tpoc; otu'to OL llEpµoxpcxoiEc; ot1t6 - 40 ° C xcxL + 7 0 ° C EivcxL 'tot 1totpcx6Ex'ticx opLcx 1Lcx 't71v E1tLAo"1'71 'twv uALxwv 1tpi1tEL oµwc; \lot 6o6ei ELOtX7I 1tpoOOX7I O'tO 07tOtoLµo, jLCX EUCXL0671oiot O'tLc; llepµoxpcxoiec; otu'tic;. 4. OL ourxoll71µivec; E\IWOELc; 71 IXAAEc; E\IWOELc; E7tt't7j6Euµi­ VEc; jLCX 't7I OUV't71;71 1tpE1tEL VO( e.xow XCX'tCXOXWCXO'tEL 71 vex ixow EX'tEAEoni ouµcpwvcx µe 'tLc; ellvLxe.c; 71 6Le6veic; 06711iEc; 71 µE 7t1Xpot6EX't£Ec; jLCX 'tLc; otpµo6tEc; cxpxe.c; 06711[Ec;. 5. To 6iµcx 1tpi1tEL vex Eivcxt E'tOL WO'tE u1to xcxvovLxic; ouv671 xec; fl-E'tot<popcxc;, xcxµicx cxu;71071 'tCXXU't7l'totc;, 661171071 71 CXV't7I­ X71071 vex µTj ~AIX7t'tEL O't7I\I CX7tO'tEAEOfl-CX'tLXO't7l'tCX 'tW\I OUO'tTj(J,CX­ 'tW\I 'tW\I XAEL6WVLW\I 'tW\I 6LCX<popwv ooxEiwv, OU'tE .vex cxllm­ W\IOU\I 'tO 6e.µcx o'to auvoAo 'tOU. EL6L~IX OL u'li:o6oxic; ~L6wv, 'tot (-t7t0UAO\ILCX XCXL illcx OUO't7l­ (-tCX'tCX 1tou ot7tO'tEAouv 't'Tj XAEL6wvtcx 6ev 1tpi1tEL vex µ1t9pfoouv vex XCXAotpwoow OU'tE vex CX\IOLjOU\I XO('tCX X&'lloc;, otX6µ71 Xott fl-E'tCX cx1t6 mcxvEv.71µµiv71 XP7107l· 6. Tex pcx6w-evep1cx uAtxcx u1to ELOLX7I µopip71 µ1topouv vex 8ewp716ouv OCX\I O'tOLXELO 'tOU 7tEpL'tUALj(-tot'toc; 'tW\I ouvopwv. 7. To µov'tEAO 1tp£1tEL vot ouµ1tepv.cxµ~ti11EL ivcx 1tEpL'tU­ AL1µcx ouvopou 7tOU VO( 6tot't71pd'totL XAELO'tO µe CXO<pCXAEc; ou 3600 O't7lfl-lX, 67jAot671 ivcx OUO't7lfl-CX 1tou vex µ71 µ1topd VQt cxvoi;EL cx1to µovo 'tOU, 7t0U vex CX\IOLjEL µovov 716e).71µivcx XCXL 7tOU vex O(\l't£XEL O't7I ouvixeLcx 'tuxov cxu~7j07jc; 't7lc; mfoewc; EV'toc; 'tOU 7tEpL'tU­ Ai1µcx'toc;. 8. Av 'tO 7tEpL'tUALjµot ouvopou 6ev 0(7tO'tEAEi E\lot E\ILOtLO ou-· vo).o µe 'to U7tOAOL7tO 'tTjc; ouoxeucxoicxc; 1tpe.1tEL vex EXEL Eipo6Lcx­ ani µe CXO<potAic; OUO't7j(-t0t XAEt6wvLcxc; E\l'tEAwc; CXVE;CXP'tTj'tO cx1t6 't7I ouoxeucxoicx. 9. Tex UALXCX 't7lc; ouoxwcxoicxc; XotL 6).cx 'tot O'tOLXdot 'tOU XotL OL 6oµe.c; 1tpi1tEL vex dvcxL cx1t6 <pUOLX7I XCXL X71fl-LX7I &:1tocji71 ouµ­ ~L~CXoLµot (-tE":ot;u 'tOUc; XCXL (J,E 'tO 7tEptEXOflE\IO 'tOU 6iµot'toc;. Tipe.1tEL vex A71<p6Ei U1tocji71 XOtL 71 ouµ1teptipop&: 'tOUc; XCX'tW CX7t0 otX'ttvo~oAicx. 10. L't7I µeAE't7I xcx0E O'tOLXELOU 'tOU 7tEpL'tUALj(J,CX'tOc; owo­ pwv 1tpe.1tEL vex A71ip6ei u1tocji71 71 pcx6toAU'tLX7I CX7tOOUV6E07I 'tW\I pEUO'tW\I Xott 'tW\I cxllwv EUotio671'tW\I OUOLWV, Xott 't7lc; 1tcxpcx­ jWj7lc; otEplou 6tcx x71µtx71c; CXV'tl6pcx071c; XCXL p0tOLOAUOEWc;. 11. To 1tEpL'tUALjµot 1tpi1tEt vex 1tcxpcxxp0t'tcx 'to pot6LO-EvEp16 1tEptExoµevo 'tOU, u1to 't7IV EAIX't'tWOTj 't7lc; Emxpcx'touocxc; 1tiE071c; flE 25 KPcx (0,25 BAR). 12. Ot 6tXAELOEc; 'tTjc; CX\l'tAiotc; OL Otot<popmxe.c; CX7t0 'ttc; Ot­ XAd6ec; CX7t07ttEOEWc; µfow 'tW\I 07tOLW\I 'tO potOLOEVEpjo 7tEptE­ xoµEvo llcx µ1topouoE \lot Otot<pEUjEt, 1tpe.1tEL \lot 1tpOO'tot'tEUOV'tott CX7t0 XCX0E CXVE7tL'tpE7t't7j fl-E'tCXXELpLOTj XCXL \lot EL\ICXL Eip06LotOµ£vEc; cx1t6 e.vcx ouo't71µcx 6w.xp.Evo vex 1tcxpcxxpot'tTjOEt xcxllE 6totipu"1'71 cx1to nc; OLXAEi6Ec; otV'tAicxc;. I 3. Av ivot o'totxeio 'tTjc; ouoxwcxolcxc; cx1to'tEAEi mi't7j6Ec; µipoc; 'tOU 1tEpL'tUAi1µcx'tOc;, EXEL 'tUALXllEi µe e.vcx x<XAuµcx 1tpo­ o'totoicxc; Xot'tCX 'tTjV-otX'ttvo~oAicx 1tpi1tEt vex EXEt xot'totoxEucxoni hot WO'tE 'tO O'tOLXELO \lot µ71 µ1topEi vex 6totipEUjEL XCX'tCX ).cxlloc;. . Av 'to x,x).uµcx XotL 'to O'tOLXEio cx1tonAouv ivcx ouvoAo µ71 EVLotio ex 1t6 'to u1t0Aomo 'tTjc; ouoxeucxoicxc;, 'to x<XAuµcx 1tpi1tEt vex elvcxL ecpo6Lcxoµivo cx1to cxoipotAic; ouo't7l(-tCX xAEtowvt&:c;, 'tE­ AEiwc; O(VE;1Xp't7l'tO CX7t0 't7I OUOXEUotoicx. 14. K.xllE OUO't7l(-tCX O'tOL~ot;71c; E\ILotio (-tE 'tO oiµcx 1tpi1m vex EXEL XCX'tCXOXEUCXO'tEl E'tOL WO'tE OL 6uvcxµ£Lc; 7t0U O(VCX7t'tUOO\l'tCXL a' cxu,6 'tooo u1to xcxvovtxe.c; ow67)i(Ec;, boo XotL aE 1tEpL1t'tWOEtc; Ot'tUX7lflCX'tOc; VO( µ7111 Eµ1to6i,ouv 'tO oiµcx \lot tXCX\107tOtd nc; 007jj~Ec; 'tOU 1t0tpov'toc; XE<pCXAotiou. 15. Micx ouoxwcxolcx 'tOU 'tU7tOU A 1tpi1tEL u1to 1tpoi.i1to6iaEtc; 7tOU llcx 1tpOEXU7t'tCX\I CX7t0 'tLc; ooxtµcxoiEc; 7t0U 1tpo~AE7t0\l'tO(t O'tO 1tEpt6wpLo 3635 vex fl1t?pfoEL \lot eµ1to6i0Et. 3601 ex. K&:lle cx1twAELot 71 6tcxo1topdt 'tOU pot6w-EvEp1ou 1tEpLEXO µivou. ~- K&:llE cxu~11a71 't7)c; µe1ia't11c; iv'tcxaric; 't7lc; xcx'tcx1pcxipoµE­ v71c; 71 u1toAOjt,oµev71c; otX'ttvo~oAicxc; O't7IV e;wnpLx71 Emip&:­ vetcx, xcx'tw ot1to auv671xEc; 1tou emxpot'tOUV 1tptv 't7) 6oxtµcxoicx. 16. Mlcx ouoxwcxoicx 'tOU 'tU1tou A 1tou 1tpoopi,E'totL 1tcx 't7I (-tE'totipop&: 'tWY pwo'tWV 1tpi1tEL E1tio71c; vot CXV'tot1toxpivE'totL O'ttc; 6tot'tCX~Etc; 't7lc; 1totp. 15 U7t0 'ttc; 1tpoi.i1to6iaetc; 7tOU llcx 1tpoxu 7t'tOW cx1to nc; 6oxtµcxoiec; 1tou 1tpo~A£1tOV'totL o'to 1tEpt6wpw 3636. ·oµwc; Ot 6oxtµcxoiec; CXU'tEc; 6EY CX7tott't01J\l'tott O'tot\l 'tO 7tEpt­ "CUALj(J,0t 7tEptEXEL EOW'tEptxcx µtot E1totpx71 7tOOO't7j"COt 0t1toppci­ <p711:txou UALXOU jLOt \IOt 0t1toppocpcx Mo cpope.c; "COIi OjXO "COU peu­ O"COU 1tou 1tEptE)(Et, XOtL 110t EXEL 1tA71pw6ei µtot EX 'tWV e;71c;-· • 1tpoi.i1to0foewv. - . • Ot. To 0t1toppo<p71'ttx6 UALxo ~pioxE'tOtL µfoot 01:0 xcx).uµµcx 1tpoo1:0tolcxc; 71 ~- To cx1toppo<p711:tx6 uAtxo ~ploxe1:0tt i;w cx1t6 0tu1:6 'tO xcx­ ).uµµcx xott µ1topd vet 0t1to6EL)(6Ei O'tL otv io peuoi:6 1tEptexoµevo cx1toppoqi&:1:cxt 0t1t6 0tu1:6, 71 e.111:0t071 1:71c; otX1:tvo~oAicx,; 6ev llcx U1tEp~0tLYEt 2 µE/wpot (200 MREM/wpcx) O't7)\I Em<pCXVELCX "COU 6e.µ0t1:oc;. 1 7. Miot ouoxeuotolot ,:ou 1:u1tou A 1tpoopL,oµe.1171 1 tcx 1:71 µe­ 'toti:pop&: OU(-t7tE7tLEO(-tE\IOU 71 oxt ote.pot, 1tpE1tEt m[o71c; \IOt EL\IOtL <l>EK H.14 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) \tot wou v0t Ep.1to6i~Et xii8E 0t1twAEta. T) 6t0to1topii tou 1tEptE­ xoµivou, umi ouv87JxE<; 1tou 80t 1tpoixu1t:0tv 0t1to tt<; 1tpo~~E 1toµEvE.:; Oto 7tEpt8wpto 3636 6oxtµ0tcitE<;. Ot OUOXEUOtOtE<; 7t0U 1tpoopi~ovt0tt jtot 'tT) p.Et0tq,opii tOU tpinou 7j tOU OtpjOU 3 7 U7t0 otEptouxo µopq,T) XOtt EVEpjEt(X µix pt 7 ,4 TBQ (200Ct) 6Ev u1toXEtvt0tt O'tT)V 0671ji0t 0tUtT), C. I:uµ1tA71pwµ0tttxi.:; ouototottxi.:; 0671jiE<; jtOt tot 6iµ0tt0t tOU t\l7t0U B(U) XOtt tOU t\l7t0U B(M). (1) IUp0t 0t1to tL<; 1tEpmtwoEt<; 1tou 1tpo~Ai1tovt0tt ot0t 1tEpt- 3602 0wpt0t 3603 (1) 0t) x0tL 3604 (2) 0tvtiototx 0t, tOt 6iµ0tt0t tou t\l7tOU ~(U) Xott tou t\lltOU B (M) 1tpi1tEL VOt 7tA7jpOUV OAE<; tt.:; ouµ1t1..71pwµ0tttxi.:; 0671yiE.:;, itou E7tt~IXAAOll'tOtt )"tot tot 6iµ0tt0t tou tu1tou (A) oto 1tEpt8wpto 3601 (1) iwi; (15) ouµmpv.0tµ­ ~0tvoµivou. (2) H ouoxEu0toi0t 1tpi1tEt v0t Eiv0tt totOtU'tT) won xchw 0t1to ouv87jxE<; 1tou 00t 1tpoixu1tt!XII 0t1to tL<; 6oxtµ0toiE.:; 1tou 1tpo~Ai 1toll't0tt OtO 7tEpt8wpto 363 7, VOt 6t0t'tT)pEL otpXEtlX 'tT)V Amoup­ jLOt tou xa.Mµ0tto.:; 1tpoot0toia.:; jtOt v0t µ7111 u1tEp~0tivEt TJ EVtotOTJ OtXtLVO~OAL!X<; tou.:; 10 MSV /wp0t (IREM/wp0t OE 1 µ. Ot7t0 'tTjV E7tt<j)IXVELot tOU 6iµ0tto.:; O'tT)V 1tEpi1ttW07j 07tOU to 6iµ0t 0ot 1tEpLELX,E m0tpx11 1tOOO'tT)t0t tpt6iou -192 )"tot VOt EX1ti­ µ1tu, 1tpt11 tt<; 6oxtµ0toiE<;, µiot 0txttvo~0Ai0t ivt0to71.:; 100 µSv/wp0t (IOMREM)/wp0t OE 1 µ. Ot7t0 t7jV E7tt<f'IXVEt0t. Av 71 ouoxEu0toiot 1tpoopi~Et0tt jtot ivcx 6E6oµivo pii6to­ vOuXAEtOto, 0tuto µ1topEi v0t 0Ewp710Ei ootv O'tOtX,EtO 0tv0tcpopii.:; otvti tOU tpt6iou -192. Exto.:; tO\ltOU otV 71 OUOXEUotOLOt 1tpoopi­ ~Etott ytot 1toµ1tou.:; vnpoviou 00t 1tpfou mio71.:; VOt x p71otµo1tot 718ei x0tt1XAA7JATJ 7t7Ji7J VEtpoviou 00t ototx Eio 0tvotq,opii.:;. t:.Ev Elliott 07tW067J7tOtE ot1totp0ti'tT)tO Vot 1tpo~ouµE OE µhp71071 Ot7t0 µi0t 7t7Ji7J 6oxtµ0tottx71.:; 0txttvo~0Ai0t.:;. ApxEi v0t rivovt0tt ot u1t0Aoytoµoi wiiAo-y0t µE 'tT)V 7t7Ji7J Et 6txrii; exxttvo~oAiex.:; itou x p71otp.EUEt 00t otOtX,Eio exv0tq,opii.:;. (3) Tor; 6iµottot tOU t\l7tOU B(U) XOtt tOU t\l7t0U B(M) 1tpE1tEt VOt ix ouv XOttOtOXEUOtO'tEL )t(XL 1tp0tyµott01tot718ai XOtt 1tpOEtot­ µexO'tEL ytex to oxo1to 'tT)<; p.Etexcpopii.:;, itot wotE, u1to tt<; Em­ xpottouoE<; ouv811xEi; 7t0U OtV!XAUOVtOtt O'tTJV 1totpiiyp0tq,o ( 4) VOt 1t1..71pouv tt.:; 1tpoii1to8ioEt<; twv E6excpiwv 0t x0tt ~ we; E~.:;: Ot. H 1totpotyoµiv71 8Epµo'tTj<;, µio0t Oto 6iµex Ot7t0 to pot6to­ EVEp')"O 1tEptEx oµEvo, 6Ev 1tpi1tEt uito x0tvovtxi.:; ouv0rixE<; µE- . t0tcpopii.:; ( 1tp0typ.0tto1tot71µivE<; 0t1to tt.:; 6oxtµ0toiE<; 1tou 1tpo­ ~Ai1tovt0tt O'tO 7tEpt8wpto 3635) VOt ~AIX7ttEt to 6iµot, WOtE VOt µ7111 µ1topioEt m0t vot 1tA71p'ei tt<; 1tpoii1to8foet.:;, ot 01toie.:; ecp0tp­ µo~ovt0tt yt0t 'tTJV opto0i:r71071 x0tt 1tpoO't0toi0t 0tv 1t0tp0tµdvEt x wpi.:; mi~AE<jlTJ jtOt 1 E~6oµii60t, 8ot 8woouµE Et6tx71 1tpo­ oox.11 O'tt<; ouvi1tEtE<; t71.:; 8Epµo'tT)tot.:; 1tou u1tiip)(Et xiv6uvo.:; vex 1. Vot tp07t07totO\lV tTj 6tEU8E'tTj07j, 'tT)V jEWp.Etptx71 µopq,71 .11 'tT)V cpuotx71 Xot:IXOtOlOTJ tOU potOtO-:VEp-you, 7tEptEX,~µevou .11 or;v to uAtXo 1tEptEX,Etott oe. p.EtotAAtxo 1tEpttUAtyµot 71 OOX,Eto (1t.x . Ev87jxwµiv0t EU<pAEXtex uAtxii) vot 1tpoxaAouv 'tT) OUV'tT)~ tou µEtotAAtxou mpttUAtjp.Ot'tO<; tou 6ox Eiou T) 'tT)<; ouoiot.:;. tt. fil0tnwvouv t71v ot1tO'tEAEop.0tttXO'tT)tot 'tT)<; ouoxEuotoiex.:; p.Etii 0t1to 6tiicpopE<; 1tpoxu7t'touoE<;, ex1to 0Epµt~716ta.otOAT), ou­ V'tT)~Et<; 11 ox toµi.:; tOU X!XAUµµexto.:; 1tpoot0tota.:; tWV exxttvo­ ~OAtwv. m. Au~iivouv t71 6tii~pW07J 1totpouoiex uypa.oia.:;. B. H 8Epµoxpotoiex tWV EU1tpoottWV Emcpa.VELWV E\10<; 6iµot­ to.:; tou tu1tou B(U) i) tou tu1tou B(M) 6Ev 1tpi1tEt vot u1tEp~exi­ VEt tou.:; 50° C u1to oxtiiv, Exto.:; !XII to 8iµex p.Eta.q,ipetott 6tii 7tAi)pou.:; cpoptiou. ( 4) f t(X 'tT)V Ecp0tpp.oj7j tOU E6otcp[ou (3) ot 8a. 8Ewp71oouµE ott ot EmxpextouoE<; ouv8T)XE<; aivott ot ~ri.:;: • or;, 0Epµoxpexoiot 38° C (100%). . E,, IDior:071 1tpoii1to8i0Eti; ouµcpwv0t µe tov 1tivax0t 1. fta. 'tT)\I E<potpµoj7j tou e6otcpiou (3) B 8ot 8Ewp11oouµE Ott ot EmxpottouoE<; ouv8T)XE<; Eiv0tt: 0ipµoxp0toiex 38° C (100° F). 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Mt0t ouoxEu0toi0t ouµ1te.ptAexµ~cxvovt0t.:; 8Epµtxi) 1tpootex­ oi0t 1tpoopt~oµiv71 vex E1tttp0t1tai o' OtUtT)V VOt 7tATJpEi tt.:; 0671yiE<; t71.:; 8Epµtxi).:; 6oxtµ0toia.:; 1tpo~AE7t0f,lEV'IJ Oto 7tEpt8wpto 363 7 (3) 1tpi1tEt va. x0tt0toxe.u0toni hot won 71 1tpoot0toiot 0tuti) VOt 1totp0tµEiVEL CX7tO'tEAEoµcxtLXT) U7t0 ouv8ijxE<; 7tOU 8ex 1tpoixu 7ttotV ot7t0 tt.:; 6oxtµotoiE<; 7tOU 7tpO~AE7t0Vtott O'tot 7tEpt8wptot 3635 )tott 3637 (2). H 8EpµtxT) 1tpoototoiot i;w otito to 6iµot OEV 1tpi1tEt vor; -yive.t !J."l or:1totEAEoµotttxi) Aciyw twv ouv871xwv 1tou 1totpouotii~o­ VtotL 'ouvi)8w.:; XottlX t'l)V XotVOVLXT) µe.tot)(Eipto71 11 OE 1tEpi1ttWOTJ CXtUX,T)p.ot'tO<;, XotL 7t0U OEV 7tp007t0to\lVtotL Ott<; ot\/Wtipw 6oxt­ µor:oie..:;, oitw.:; 7t,X,, ox iotµo, xo<jltµo, O!XA7t1Xptoµot, ot7tO~UOTJ 11· ~[ottex f,lEtOt)(aiptO'I), t:.. I:uµ1tA71pwµexttxi.:; rcpoo8Eni; 1tpoii1to8foEt<; ytot tot 6i­ µor:tot t\lltOU B(U). ( 1) H ouoxEu0toiot 1tpi1m vot EX,Et Xottexoxe.uototEt itot WO'tE: or;. 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(3) A1twAwx a1tO'tEAEaµ.a,tx6,~tai; ,w11 a1topp0<p71,txw11 µ.fow11 T} ,w11 ouo,7Jµ.a,w11 (3pa6u1topEiai; ,w11 E11awµ.a,wµ.i 11w11 11E,po11iw11. r) Tpo1to1to[71071 ,71,; 6tEuOh7Ja71i; 'tWII 1tEptEXOfl-EIIW\I E1tt­ cpipo11'tai; fl-E,aAunp71 a11,t6paa,tx6,71,a, Tj'tOL Ell'toi; 'tOU 6i­ µ.a,oi; T} (.J.E'tlX a1tWAEta 'tOU 1tEpLEXO(.J.EIIOU EX'tOG; 'tOU 6iµ.a,oi;; 6) EAIX't'tWOTJ 'tW\I a1tOO'tlXOEW\I µ.a,a1;u 'tWII 6Efl-lX'tW\I T} (,LE­ ta1;u 'tWII 1tEpLEXOfl-EIIWII. E) Ka,af3uOto71 'tWII 6aµ.ii,w11 O'tO npo T} xa,ixxwa71 XIX'tW a1t' 'tO XlO\lt. ~) T uxo11 au1;7Ja71 't'T]<; a11,t6paatt)(O't7ltai; fl-E'tlX a1t6 fl-E'ta­ (3oAT} ,71i; 6apµ.oxpaoiai;. 2. E1ti07Ji; 6,a11 1tp6xmat 1ta ax,t110(30AT]fl-EIIO 1tUp7J11tx6 xauatµ.o T} yux EAIXXta,a UAtXIX fl-TJ xaOopt~O(.lElla ot E;Tji; 1tpoii 1toOicmi; 1tpi1tEt 11a ,71pou11,at: a) To ax,t110(30).71µ.i110 1tup7111tx6 xauatµ.o ,ou 01toiou o (3a6µ.oi:; ax,t110(30Aiai; 6a11 al11at jllWO'tOG; xat 'tOU 01tOLOU 71 a11n6paottXO't7J'ta fl-ELWIIE'tat µ.a~[ fl-E 'tO 1tOOOO'tO xauo71i:;, 1tpi1tat 11a 6awpEhat oav µ.71 ax,t110(30A7Jfl-EIIO 1 ta ,011 oxo1t6 ,ou EAirxou ,w11 xt116u11w11 x,71,txo,71,ai;. A11 71 a11,t6paa,tx6,71i; au1;ii11Etat µ.a ,o 1toooa,6 'tT]<; xau­ OTJ<;, 1tpi1tat 11a 0EwpEi,at aa11 ax,t110(30AT]fl-EIIO xauatµ.o 1tou (3piaxa,at o,ti:; awOTjXEG; ,71i:; fl-E1ia,71i; a11,t6paa,tx6,71,ai;. A11 o (3a0µ.6i:; ax,t110(30).iai; Eivat jllWOtoi;, 71 a11,t6paa,tx6 t71i:; 'tOU xauaiµ.ou Oa µ.1topfoat OU\IE1twi:; 11a EX'ttf-1-T]OEL (3) 1:,7111 mpi1t,wa71 ,w11 auaxta,w11 uAtxw11 1tou 6E11 6tEU­ xpt11[~011,at 61twi:; u1tOAEiµ.µ.a,a ri ow,piµ.µ.a,a ,w11 01toiw11 o aµ.1tAou,taµ.oi:;, TJ µ.ii~a, 71 auyxi11,pwa71, 716u11aµ.71 am(3pii6w 07J<; ri TJ 1tux116t7Jc; 6E11 alvat jllc.>a,ii:; ri 6E11 µ.1topou1111a xaOopt­ atouv, 1tpi1tEt 11a a1to6i6ouµ.a OE xiiOa IXjllWa,71 1tapiiµEtpo ,7111 'tLfl-T} 1tou EmcpipEt 71 f-1-E"(LO'tTJ a11,t6paa,tx6't7]i; a,ti:; 1tpo­ /3AE1toµ.a11Ei; awOrixEi;. 3. Ta 6iµ.a,a ,w11 Euaxta,w11 uAtxw11 iiUa a1t6 au,ii 1tou 1tpof3Ai1to11,at O'tO mptOwpto 3610 1tpi1tEt 11a E\l'tlXOOO\l'tat OE µia EX ,wv E1;Tji; xAiiaaw11.' a) EuaxtO'tTJ XAIX07I I. Mµ.a,a 1tOU 6E11 1tapoUOLIX~OW xa 11i11a 1tUpTJ11lXO xi116wo 61totoi:; xci.t a11 ai11at O aptOµ.oi; xat T] 6twOi,71071, a' OAE<; nc; 1tpo(3Amoµ.E11Ei:; owOrixai:; (.J.Etaqm­ piii:;. P) Euaxta,71 XAIX07J II. Mµ.a,a 1tOU 6E11 1tap~uOtlX~OUII xa 11i11a 1tup7111tx6 xi116wo av (3pioxoll'tat aE optaµ.i110 apt0µ.6, 61totcx xcxt cx11 aivcxt 71 6tauOh71ari ,ou xcxt a' 6).ai:; ,ti:; 1tpo/3AE1t6 µ.a11Ei; owOrixac; µ.ncxcpopiii:;. y) Euaxto,71 XAIX07I III. Mµ.cx,cx 7tOU 6a111tcxpouot1X~OU\I xcx 1/E\ICX 1tup7111tx6 xi116wo a' OAEc; ttc; 1tpo/3AE1t6µ.a11ai:; au110rixai:; µa,cxcpopiii; Myw ,w11 1tpocpu).ii!;Ew11 Tj 'tWII Et6txw11 µ.i,pw11 T} 'tW\I Et6txw11 6tcxxptttXWII EAE"(XWII 1tOU E1tt/31XMOll'tCXt XCX'tlX 'tT] f-1-Etcxcpopii ,71i:; cxi'toa,oATjc;, C. Et6txii:; 6tcx,ii1;ati; 1tou acpopou11 ,o 6iµ.cx ,71,; EUa;(to,71,; XAIXOT]G; I. 1. KiiOE 6iµ.cx 'tTJ<; EuaxtatT]i; XAIX07J<; I 1tpi1tEt 11cx EXEt xcx,cx­ axwcxani i,at wan u1t6 awOrixEc; 1tou Oa 1tpoixu1ttcx11 cx1t6 ,ti; 1tpo(3).m6µ.a11Ei; 6oxtµ.cxaiEi; 1tou cx11cxcpipoll'tcxt oto mptOw pto 3635. • ex) Ncx µ.7111 µ.1topfoEt 11cx ataiAOEt 11Ep6 aE xcx11i11cx µ.ipoi; ,ou oiµ.cx,oi; OU'tE \ICX ExpiEt EX'tOG; CX\I TJ E.tOCX"(W"(Tj 'tOU 11apou a' auto ,o µipoi; ri ,7111 axpori ,ou i 1tva E1tttpE1tt'Tj 1tcx ,oui; oxo 1toui:; 'tOU 1tEptOwpiou 3614(1) O'tO fl-E"(tO'tO 1tpo/3AE1t0fl-E\10 µ.i­ tpo. (3) H 6tcxµ.6pcpw07J ,ou 1taptaxoµ.i11ou xcxt TJ "(EWf-1-Etpia ,ou optaxou 1tEpt,uAi1µ.a,oi; 11a fl-TJII ,po1to1tmou11,at a,o 071µ.Eio xcxt au1;riaow ,o cxiaOTjµ.a 'tTJ<; a11,t6paa,tx6,71tai;. 2. Ta 6iµ.a,a tlji; EUa;(taµ.71,; xAiia71i; I 1tpi1tEt va 1tA71pou11 ,a xptt'Tjptcx ,71i; 1tup7111txrii; aocpaAEtai; 1tou a11aypiicpo11,at otcx 1tEpt6wpta 3613 xat 3614. l. f ta 'tO a1tOfl-OIIWfl-EIIO 6aµ.a. 1. 0cx 1tixpouµ.E aav u1to6iaati; tti; E;T}i; awOTjxEi;. a) . To 6iµ.a aivat «Em/3Aaf3ii:;». H Aa1;71 «a1tt/3Acxf3ii;» a71µ.cxi11Et aow 't'Jjll au116rix71 1t0\J EXEt EXttµ.718Ei ri a1to6ux8Ei 1tpOXU1t'tOll'tai; ytcx 'tO 6iµ.a O'tt Ot 1tpo­ /3AE1t0fl-EIIE<; 6oxtµ.aaiEi; ,w111tEptOwpiw11 3635 xat 3637(1) 3612 3613 iwi; (3), 1tou axoAouOaitat cx1t6 EX~i1171 ,ou 1tEpt6wpiou 3638 Tj'tOt 'tW\I 6oxtµ.aatW\I 1tpo/3AE1toµ.i11w11 O'ta 1tEptOwpta 3635 xlXt 3 63 7 ( 4) auµ.cpwvcx fLE ,011 mo 1tEptoptattx6 aw6u1Xaµ.6. (3) To 11Ep6 µ.1topEi VIX EtoiAOEt Tj vex Expe.Et 1X1tO oAa ,a xEva 6t1Xa,riµ.crnx ,wv 6aµ.ii,w11 auµ.1tEptA1Xfl-/3cx110µ.i11w11 xott au,w11 1tOU (3piaxo11t1Xl µ.foot O'tO optotXO 1tapttUAt"(fl-lX, ·oµ.wi; IX\/ 'tO (.lOll'tEAO 'tOU 6iµot,oi; OUfl-1tEptACXf-1-/3CX11Et Et6txci xotplXXt71pt­ O'ttXCX 1tpoopt~6µ.a110t ·110t aµ.1to6iaou11 otu,ri tT]II ataotywrri T} Expo'Tj µ.foot ri ax,oi; µ.aptxw11 xa11w11 6totO'tT]fl-lX'tW11, otXOfl-TJ au 11a1talot 1X118pw1ti11ou Aci6oui;, Oot 1t1Xpot6axOouµa cm 6a11 U1t1Xf>X,E\ OU'tE EtOCX"(W"(Tj OU'tE Expori 11Epou. Au,cx ta Et6txa xcxpotx,71pt­ O'tLXIX µ.1topou11 \/IX ELI/Ott: t. TToMIX1tAIX O'tE"(IX\ICX 6tcxcppcxyµ.ot,IX U~TJATj<; 1tOt0'tTJ'tCX<;, 'tW\I. 01toiw11 xcxOa i11a 6cx 6tlX'tT]flOUOE 'tTJII IX1tO'tEAEOfl-a'ttXO­ 'tT]'tlX. A11 to 6iµ.ot Oot u1tof3a).6,0t11 a,oui; ow6uotoµ.oui; ,w11 60 xtµototw11 1tou 1tpof3Ai1to11,~t a,o E6cicpto 1 )a) T} • lt. 'Evoti; CXUO'tljp6i:; EAE"(XOG; 'tT]<; 1t0t6,71,ai:; xa,cx ,7111 XIX'ta­ OXWTj XIXt 't7I 6tottTjpTJ07I ,71i; OUOXEUotaioti;, aw6ucxaµivoi; (,LE ,ti; at6txii; 6oxtµ.otaiai; 1tot 111X cx1to6EtXOai ,o xAaiatµ.o Exiia,ou 6iµ.ot,oi; 1tpo ,71i; cx1toa,OATjG;, 2. To 6iµ.ot 1tpi1tat 110t (3pioxet1Xt u1t6 xptttXTj µ.a E1totpxii; 1taptOwpto (2) U1t0 'tWII au11871xw111tou 1tpof3Aa1tO\l'tat O'tTJll 1tlX­ pcxypcxcpo ( 1) A1Xµ.(3cx11ov,0ti; \J1tO~TJ 'tlX XTJfL!XCX XIXt cpuatXCX XIX­ p1Xxt71pta'ttXCX auµ1taptA0tµf30t11oµi1171i; xcxOE ,po1to1toi7Ja71i; a,ot xapotx'tT]pta'ttXCX 1t0U Oot µ1topouoot11 VIX 1totpotx6ou11 U1t0 'tW\I au11871xw11 'tT]G; 1t1Xfl1X"(pCXcpou (1) XIXt umi 'tW\I OUll87IXW\I 'tOU fLE'tptaaµ.ou XIXl ,71i:; IX\l'tCX\ICXXACX07IG; wi; E;Tji;»: (2) 1t-X· 6ot 0Ewpriaouµa O'tt TJ fl-CX~IX 'tOU auaxta,ou UAtXOU CX1tO'tEAEL'tlXt IX1t0 µiot iyxupT] 1totpcxµ.a,po EAE"(XOU, Oa axoµE E1totpxii; 1tEpt6wpto IX\/ 1tEptopiaoµ.E 't7I fl-CX~IX OE 80% a1t6 ExEi1171 .1tou 61X ri,a11 xpmxri oa ouyxp71,io auo,71µ.ot. ot) Ma 'tO UAtXO µaad O'tO optotXO 1tEpttUAt"((,LIX, t. AtotµopcpwaT] XIXt µ.a,picxaT], ax ,wv mo 0t11,t6pao,txw11 1tOU µ1topou11 VIX 8Ewp710ou11 cmi; auv6rixEi; ,71,; 1totp1Xypcxcpou (1). ll. TaAELIX a11t1X\ICXXAIXOTJ a1t6 'tO 11Epo yupw a1t6 'tO optotXO mpttUAt"((,LIX Tj 'tE'tOtlX fLE"(IXAU'tEp7I IXll'tlXIICXXAIX07I ,u·pw IX1t0 IXU'tO 'tO 1tapttUAt"((,LIX 1tOU µ1topouaE \/IX amcpotpOai a1t6 ,a UAtxcx ,ou t6iou ,ou 1tapt,uAi1µ.ot,oi; xott B. A11 6uxcpEu1at xcx1toto 'tfLTJfl-lX ,ou uAtxou ('tT]i; ouaioti;) ,ou optlXXOU 1tEpt'tUAL"(fLIX'tO<; U1t0 tti:; aw6rixai; ,71,; 1totpotypcxcpou (l): t. Atotµ6pcpwa71 Xott µa,piota71 EX ,wv mo 1X11,t6paa,txw11 1tOU 6awpoull'tott we; 1tt61X11CX. tl. TEAELIX CX\l'tlX\IIXXAIX07I IX1t0 'tO 11Epo yupw IX1t0 IX\J'tlX 'tot UAtXCX. 2. ftot ,7111 0t1toa,0A1J a116i; ri 1taptaao,ipwv 6Eµcx,w11. 1. 'E110ti:; 01tOl006Tj1tO'tE otpt0µ6i:; 6aµcx,w11 µ71 E1tt/3Aot/3w11 'tOU t6iou fLOV'taAOU, 6tw0E'tT]fLE11a at 01tOtot6Tj1tO'tE 6i07J 1tpi 1tEt \/IX 1tCXp1XfLEIIEt U1tO-~ptttXTj, ftot ,011 axo1t6 au,6 «fl-TJ am/3Aot/3ii:;» 071µ0ti11u ,1111 owOrix71 XIX'tW IX1t0 'tTJII 01tOLIX 'tlX 6iµot,IX xa'tlXOXEUIX~Oll'tlXt "(tilt \/IX 1t1X­ pouotota6ou11 O't7I fl-E'totcpopcx. 2. 250 1X1to cxu,cx 6iµot,ot, 6,cxv ai110tt «am(3Acxf3ri• 1tpi1tEt 11a 1tapaµ.i11ouv u1to-xpmxri a11 a,ot(3ci~ov,at a' 01tota6ri1to,a Ofo71, µa, O'tT]\I cxµ.aa71 "(Et'tlliaa71, i11a a11,a11axAaotT}pCX a1t6 tao,tµo a,o 11Ep6 UAtxo, OE OAE<; tti:; 1tAEupii; ,ou auv6Aou au­ tou. Qi; 1tpoi; ,011 axo1t6 ,ou,o «E1tt/3Acx/3ii;» a71µ.ai11Et ,7111 aw­ Orix71 1tOU ixu EXttµ716ai TJ a1to6Etx6ai 1tpoxu1ttouaa yta xcx6E 6iµ.ot Tj'tOt Ot 1tpo/3AE1t0fLEVE(i 6oxtµaaiEi; a-ca 1tEptOwpta 3635 xat 363 7 (1) iwi; 3) 1t0U ax0Aou6ou11,at a1t' IXU'tT} 1t0U 1tpo­ (3Ai1tE'taL O'tO 1tEpt6wpto 3638, TJ'tOt 'tWII 6oxtµaatWII 1tOU 1tpof3Ai1tO\l'tat a,a mpt6wpta 3635 XIXl 3637 (4) auµ.cpwvcx µa ,011 mo 1tEptopta,tx6 ow6ucxoµ6. 0a 0Ewpriaouµa a1tia71i; u6po10VW(,LEIIO fl-E'tptlXOfl-0 (3) (,LE'ta;u 'tWV 6E(,LCX'tWII XIXt (,LtlX EtOIX"(W"(Tj 11Epou O'tO 6e.µcx Tj axpo71 EX'tO<; IXU'tOU, auµ/3t/3CXal(,L7I (,LE ,a a1tou).foµot,0t ,w11 6oxtµaatw11 xat cxv,0t1toxpt116µEvo • a,7111 mo taxupri 0t11,t6pcxa,tx6t7Jta. (3) 0 u6poyo11wµi11oi; µa,ptaaµoi:; µ1topEi va 6awp718Ei aav 11a TJ'tCX\I oµotoµopcpo atpwµ.a pEUO'tOU 11Epou 1t0U 1tEptXAUEt xcx6E 6iµ.a T}'tOL 11Ep0 (1tixyo T} a,µ6) µtcxi; xa'taMTJATj<; 1tux116 't7ltai; 1tOU 6ta11Efl-E'tat (,LE OfLOj'EIITJ tp07t0 fl-E'ta;u 'tWII 6E(,LCX­ 'tWV. 1251 3614 C\IIMIVICt"IL I ML I\ Yt:St:.t"'NHl:EQI: (TEYXOI ~EYTEPO) 3. Mov,EAa ,wv 6Eµdt,wv 1 ta ,a 01toia 1.ua 7tOAU7tAEUPTJ E1 xptaTj X,PEtot,E'tat: flapdt6Et1 µa 1 0 U7tOAoytaµoc; 1tpE1tEt va yh1nat E7ti 'tWV E;Tjc; ~otOEWV. a) Kdt0E 6Eµa 1tpE1tEt va auµcpwvEi µE ,a xpt,7jpta ,a 01toia ava1 pdtcpov.at a,a 1tEpt8wpta 3612 xat 3613 (1). ~) Kdt0E 6Eµa Em~Aa~Ec; TJ oxt 1tpE1tEt va EXEt xa,aaxEua­ ani hat wa,E ,a EUoXtO"ta uAtxdt 1tou 1tEptEXEt va 1tpoO'ta,Euo­ v,at ami ,a 0Epµtxdt vE,povta. r) ·o,av 1tapill1jATj 6foµTj VE'tpoviwv 7t0U EXEt cpdtaµa EvEp1 Etac; xa0optaµEvo a,ov 1tivaxa IV,. 1tpocp8dtvEt Eva µTj Em~Aa~Ec; 6Eµa u1to 01tota67J1tO,E 1 wvia 1tpoa1t,waEwc; o 1ta­ pdt1 wv 1toAAa1tAaataaµou ,wv E7tt0Epµtxwv vnpoviwv a,~v EmcpotVEta, 61jAa67J TJ oXEOTJ µE,a;u 'tOU apt0µou 'tWV E7tt0Ep­ µtxwv VE'tpoviwv 7t0U EX7tE(J-7tOV'tat a1to 'tO 6Eµa xat O apt0µoc;· 'tWV E7tt0Ep(J-LXWV VE'tpOVLWV 7tOU ELOEPXE'tat O'tO 6Eµa 1tpE1tEt va Eivat lAaaaov ,ou 1 xat ,o cpdtaµa ,wv VE,poviwv 1tou EX1tE­ p.1tE,at a1to 'tO EV Aoyw 6Eµa, 7t0U 0EwpouµE O'tt a1tO'tEAEi µE­ poc; Evoc; a1tEptopia'tOU auvoAou ,hotwv 6Eµdt,wv, 6Ev 1tpE1tEt va Eivat mo OXATjpo. a1to ExEivo ,wv 1tpoam1t,wv,wv VE,po­ viwv. 6) To µov.lAo ,ou Mµa'tOc; 1tpE1tEt va Eivat auµcpwvo µE ,a xpt,Tjpta 1tou ava1 pdtcpov,at a,o 1tEpt8wpto 3614(2). TTivaxac; IV EvEprTJ'ttxo cpdtaµa ,wv ve,poviwv a EvEp1 eta VE,poviwv E 11.0 MEV 2,4 MEY 1,1 MEY 0,55 MEY 0,26 MEY 0,13 MEY 43 KEV 10 KEV 1,6 KEY 0,26 KEY 42 EV 5,5 EV 0,4 EV Iloaoa,o ,wv vE,poviwv 1tou EXOUV EVEPYEta µtxpo,EpTj a1to E. 1.000 0,802 0,590 0,460 0,373 0,319 0,263 0,210 0,156 0,111 0,072 0,036 0 a}" Au,o ,o cpdtaµa av.a1toxpivE,at a,o E1tt8Epµtxo µEpoc; ,ou cpdtaµa'tOc; a,TjV xa,dtO"taaTJ taoppo1tiac; 1tou EX1tEp.1tEt Eva 3615 6Eµa 7tEptEXOY'tac; Eva ;uAtVO xdtAuµµa 5 EX. 1tdtxouc; xat 7t0U a1tO'tEAEL µEpoc; EVOc; xpmxou OUVOAOU 'tE'tOtWV 6Eµdt,wv. 4. Mov,lAa ,wv 6Eµdt,wil 1 ta ,a 01toia XPEtdt,nat µovoµE­ p7Jc; E1 xptaTj. flapdt6Et1 µa 1 1. H auaxEuaaia xa,aaxEuot,E,at hat wa,E ,o EUoXtO'tO 3616 UAtXO va 7tEpt'tUAiyE,at µE EVa a,pwµa Evoc; UAtXOU 7tOU imo pEi va a1toppocpdt oAa ,a 0Epµtxdt 1tpoa1ti1t,ov,a vE,povta, (au,o ,o a,pwµa µ1topEi va Eivat 7tEpt,uAt1 µa xdt6µtou ,ouAdt Xta,ov 0,38 µµ 7t1Xxouc; iaov (J-E 0,325 rP xdt6µto avdt 'tE'tp. EX.) xat va 7tEpt,UAiyEt 'tOV i6to 'tOV a1toppocp7j,7jpa 'tWV VE,po viwv (J-E Eva 7totxoc; 'tOUAotXtO'tOV 10,2 am'i ;uAO 7tOU va EXEt . 1tEptEx,txb,7j,a aE u6po1ovo ,ouAIXXta,ov 6,5% aE µdt,a xat TJ µtxpo,EpTj E;wuptXTj 6tdta,aOTj 'tOU ;uALVOU 7tEpt'tUAiyµa,oc; au,ou 6Ev 1tpE1tEt va Eivat µtxponpTj a1to 30,5 EX. 2. H auaxwaaia xa,aaxwix,E,at µE ,E,oto ,po1to wa,E av dvat «Em~Aa~Tjc;» ( «E7tt~Aa~Tjc;» EX Et E6w 'tTjV Mota ,ou 1tEpt 8wpiou 3613(t)), ,o Euaxta,o uAtxo 1tapaµEvEt 7tEpt,UAt1 µEvo a1to 'tO. a1toppocp1j'ttXO a,pwµa 'tWV VE'tpoviwv, va 1tapaµEVEt 1tEptwAtyµEvoc; au,oc; o a1toppocp1j,7Jc; ,wv vE,poviwv, va µTj 'Tjµtw0d 'tO ;uAo OE OTj(J-ELO 'tE'tOto 7tOU 'tO U7t0Aot7t0 1tixxoc; va Eivat p.txpo,Epo a7tO 9,2 EX. Tj Tj (J-tXpO'tEpTj E;wuptXTj 6t!X­ O'ta0Tj 'tOU a1toµEivav,oc; ;uAOU va Eivat µtxpo,EpTj a1to 28,5 EX. 3. To 7tEptEXOfJ-EVO 6Ev 1tpE1tEL va u1tEp~aivEL nc; 1tapa6E­ X,EEc; µix,Ec; Euaxia,ou UAtxou 1tou avacpEpov,at a,ouc; 1tivaxEc; V Ewe; XIII auµ~t~aaµEvo µE: a) TTjv cpua"l ,ou uAtxou. ~) To µEyta'tO µE,ptaaµo xat r) TTj fJ-E1LO'tTj 6tdtµE,po (Tj oyxo) 7t0U Ba 1tpOEXU7t'tE av Tj auaxwaaia 7J,av «Em~Aa~Tjc;» ( Tj AE;Tj «E7tt~Aa~7Jc;» EXEL E6w 'tTjV EWOLa ,ou 1tEpt8wpiou 3613(1.)). ~Tjp.ELWOTj, "Evac; avaAu,txoc; u1toA01 taµoc; 1 ta Eva 6E6oµEvo µov,EAO 6Eµa,oc; auµcpwva (J-E 'tTj µE0o6o 7tOU EX'ti0E,at O'tO 7tEpt0wpto 3 615 µ1topEi va 1tapaxwp7JOEL ,tµEc; Atyo,Epo 7tEptopta,txEc; a1to au,Ec; 7t0U avacpEpov.at a,ouc; 1tivaxEc; V Ewe; XIII. KE<plXA.ottO A.6 Ili11otxoo;; V ,.,, Y6ot,tXIX i\uxAuµµot,ot cp6opwuxo oupot11uAio*) iJ \lt'tptxo oupot11uAio*> E1mpE1t,Eot µii~ot oupot11to ot\llX 6iµot ot\llXA.Ojot µE 'tTj\l 1tUXIIO't7j'tot ,ou ~i>Aou 'tTjc; ouoxEuoto!otc; 1. I1Epwptoµi117J 0t1t0 't7j µijtO't'lj Em'tpE1t'tEot 6tiiµE,po 'tOU EOW'tEptxou 6oxdou i\iiiµnpo ,ou Ilux110't7j'tot ,ou ~uAou µ7J11 U1tEp~ott11011,ot 1,25 1p./xu~. Ex. xott oxt xot,w,Ep'IJ ot1to EOW'tEptxou 6oxdou 0,6 0,65 0,7 0,75 0,8 0,85 0,9 0,95 1,0 1,05 µ7J11 u1top~oti11ouaot {cm) Xi oupii11w ot\llX 6iµot ' 10,16 A1tEptoptO'to A1tEptopio,o 0,084 0,120 0,157 0,193 0,231 0,267 0,301 0,335 0,370 0,400 2. IloptoptoµE\l'lj ot1t0 'tO µEjtO'tO EOW'tEptXO OjXO 'tOU EOW'tEptXOU 6o)(EtOU • '01xo 'tOU IluX\IO't'lj'tot 'tOU ~UAOU µ7J11 ump~ott\lOUOot 1,25 ,p./xu~. EX. Xott O'.)(t Xot'twnpo ot1t0 &OW'tEptXOU 6o'X ElOU 0,6 0,65 0,7 0,75 0,8 0,85 0,9 0,95 1,0 1,05 µ'lj\l U1CEp~ott\lOU\I (1) Xi oupii11w ot\llX 6iµot 2 0,152 0,380 0,66 1,01 1,47 2,00. 2,60 3,50 4,64 6,04 3 0,084 0,223 0,416 0,65 0,93 1,25 1,58 1,96 2,34 2,74 4 0,084 0,120 0,157 0,193 0,231 • 0,274 0,356 0,498 0,73 1,05 5 0,084 0,120 0,157 0,193 0,231 0,267 0,301 0,495 0,57 0,66 7 0,084 0,120 0,157 0,193 0,231 0,267 0,301 0,347 0,406 0,467 Amptopta'tO 0,084 0,120 0,157 0,193 0,231 0,267 0,301 0,335 0,370 0,400 *) Oupii11w µ'I) 1tEptE)(O\l'tot ,011 too,01to 233 xott ,ou 01toiou 7J 1tEptEX'ttXO't7j'tot aE ouplXllw 235 6E11 urcEp~oti11Et 93,5% OE µii~ot. ' 1,1 1,15 1,2 0,429 0,456 0,478 1,1 1,15 1,2 7,62 9,39 11,3 3,16 3,57 3,99 1,47 2,02 2,70 0,74 0,84 0,92 0,53 0,60 0,66 0,429 0,456 0,478 1,25 0,498 1,25 13,3 4,42 3,55 1,02 0,73 0,498 m e :I: s: m "O M I :I: M ;i.: < m m "O 2 :I: M m :0 M =i m < X 0 M t> m ~ m "O .9 ...... ~ (,/1 c,, KEcp!XMtO A6 Iliva:xetc; VI M71 uopo1ovoµivet ouv0E,<X 71 µEi1µ0t,0t oup<ivto ·i ,ou 01toiou 71 ou1xiv.pWOT) OE oup<ivto-235 OEV u1tEp~0tivEt 4,8,p/xu~. Ex .. l (ouµ1tEpu..0tµ~0tvoµEvo xett µh<XAo oup<ivto ,ou 01toiou 'tO 1t0000't0 Eµ1tAOU'ttoµoi> OE oup<ivto 6Ev ump~OttVEt 25% OE µcx,Ot, xwpic; E1tt,pE1t'tEOt µcx,Ot oup<ivto OtV<X 6iµ0t 0tv<iAo,0t µE 'tT)V 1tUXVO'tT)'tOt 'tOU 1.;i>AOU 'tT)c; OUOXEU0toi0tc; 1. IlEptoptoµiv71 OtltO 'tOV µi,tO'tO EOW'tEptxo 6t<iµE,po 'tOU Eowuptxoi> 6oxdou i\t<XtJ,E'tpoc; EOW'tEptxoi> I IluxVO'tT)'tOt 'tOU l.;i>AOU tJ,T)V UitEp~etivov.oc; 1,25,p/xu~. EX oxt XOt'tW'tEpet Ot1t0 0,6 6t0tµhpou µ71v un:Ep~0tivouo0t (CM) Kg oup<ivto OtV<X oiµet 10,16 Ot1tEptoptO'tO OtitEptoptO'tT) 0,69 2. IlEptoptoµEVT) <X7t0 'tOV µa1to't0 o1xo 'tOU EOW"tEptXOU 60XEtOU "01xoc; 'tOU TiuxVO'tT)'tOt "tOU l.;i>AOU µ71v UitEp~<Xivov,oc; 1,25,p/xu~. EK oxt XOt'tW'tEpOt OtltO EOW'tEptxoi> 0,65 0,7 0,75 0,8 0,25 0,9 6oXELOU µT)V un:Ep~0tivouo0t (1) Kg oup<ivto OtV<X 6iµ0t 3 7,0 10,0 12,2 14,5 14,5 14,5 4 4,8 7,8 7,8 7,8 7,8 7,8 5 3,63 3,63 3,63 3,63 3,63 3,63 7 1,41 1,41 1,41 1,41 1,41 1,41 OtitEptoptO'tO 0,69 0,69 0,69 0,69 0,69 0,69 ·i Oup<XVLO µ71 itEptixov 'tOV tOO'tOltO 233 XOtt 'tOU on:oiou 71 1tEptEX'ttXO'tT)'tOt OE oup<ivto 6Ev UitEp~OttVEl 93,5% OE p.<X,Ot. "') Tat µEi,µcx,cx itEptEXOV"tet,; ~1)flUAALO 71 6Eu,ipto Ot1tOXAELOV'tOtt XOtt T) µcx,cx <iv8p0tx0t 6Ev 1tpE1tEl vex ELVOtt ltAEOV CX1t0 5 cpopic; OtVW'tEpo O'tT)V µcx,Ot oupOtViou. ,.... t-:1 c.n ,.,. m e ::i: s: m :!! M t ::i: M " -< CD m '"Cl 2 ::I: M m IO M ~ m < X 0 M t> m < t m '"Cl .9 . . . KtcpaAexto A.6 Ilivcxxex,; VII MTJ u6po1ovoµevex auv8&,ex 71 µ&i1µex,ex oupexviou·>,ou 01toiou TJ au1xev,pwOTJ a& oupixvto-235 6ev u1ttp~exiv&t 9,6 1p/xu~. &x (auµ1tepv,.exµ~exvoµevou ,o µhcx).o oup!XVto ,ou 01toiou ,o 1toaoa'to eµ1tAou,taµou a& oupixvw-235 6&v u1ttp~exivt 50% a& µix~ex xwpi,; &m~ex6uv71,;) Em,pt;c,eex µix~ex oupixv;o cxvix 6eµex cxvaAo1o µe 'tTJV 1tuxvw'tT},ex ,ou ~uAou auax&uexaicx,; 1. TTtptoptaµEVTJ ex1to 'tTJ µe,tO'tTJ &OW't&ptXT) 6tixµt,po 't0U &awnptxou 6oxeiou Atixµt,po -rou TTuxV0'tTj'tex 't0U ~UAOU µTjV U1t&p~exivouaex 1,25 ,p./xu~. &X. xext oxt xex,w,tpo ex1to &OW'tEptXOU 60XELOU 0,6 0,65 0,7 0,75 0,8 0,85 0,9 0,95 1,0 1,05 1,1 1,15 1,2 1,25 µTjv u1t&p~exivouaex (Ex) Kg oupdtvt0 exvix Mµex 7,5 Amptopta,o 8 6 Amptoptaw 8,5 6 7 8 A1ttptopta-ro 9 6 7 8 9,2 10 11 A1ttptopta,o 9,5 6 7 8 9,2 10 11 12 14 15 A1teptopta'to 10 6 7 8 9,2 10 11 12 14 15 16 17 17 17 19 A1ttptoptO'tTJ 0,69 0,69 0,69 0,69 0,69 0,69 0,69 0,69 0,69 0,69 0,69 0,69 0,69 0,69 2. TTtpt0ptaµEVTJ ex1to 't0 µe,ta,o &awnptxo o,xo 'tOU &awnptxou 6ox&lou •o,xo 't0U TTuXVO'tTj'tex 'tOU tuAOU µT}V U1tEp~exivouaex 1,25 ,p./xu~. ex. xext oxt xex,w,tpo ex1to &awnptxou oox&iou 0,65 0,7 0,75 0,8 0,85 0,9 0,95 1,0 µTjv 1>1ttp~exivov (1) Xi oup!XvtO exV!X 6eµex 3 7 8 9,2 10 11 12 14 14,5 4 4,8 7,8 7,8 7,8 7,8 7,8 7,8 7,8 5 3,63 . 3,63 3,63 3,63 3,63 3,63 3,63 3,63 7 1,41 1,41 1,41 1,41 1,41 1,41 1,41 1,41 ex1t&ptopta't0 0,69 0,69 0,69 0,69 0,69 0,69 0,69 0,69 ·) Oup!Xvto µTj 1tEptexov 't0V tO0't01tO 233 xext 't0U 01toiou TJ 1t&ptEX'ttX0'tTJ'tex a& oup!Xvto-235 6&v U1t&p~exiV&l 93,5% OE µix~ex. .. ) Tex µ&i,µex,ex 1tEptexov,exi; ~TJPUAAlO 71 6&u,Epto ex1tOXAELOV'text xext TJ µix~ex !XV8pexxex 6&v 1tpE1t&t vex &ivext 1tAEOV ex1to 5 qiope,; exvwnplj ex1to 'tT}V &m'tpE1t'tEex µix~ oupexviou. m e :::c s: m :!! M 4 :::c M " -< IJJ m ,:, 2 :::c M m :0 M ~ m < X 0 M t> m < 4 m "C .Q >-­ N) (./1 (./1 KEq>~otto A. 6 ITivotxotc; VIII OupiXYLO*) (.1-E"tlXAAO xwpic; Em~pot6uv,ic; Em,pE7t'tEot µix,ot oupotYiou otYIX 6iµot otY~Ojot µE T7JY 7tUXYOT7j'tot ,ou ~u).ou auoxEuotoi~ 1. TIEpLOptoµiYTJ ot7t0 T7J µijtGT7j EownptxiJ 6tiiµE,po 'tTjc; EownptxiJc; 6tot(.I-E'tpou dtlX(.1-E'tpo ,ou TiuxYOT7j't0t 'tOU ~UAOU µTjY ump~otLYOY'totc; 1,25 jp./xu~. EX. Xott oxt Xot'tW'tEPTJ ot7t0 EGW'tEptxou 6oxdou 0,6 0,65 0,7 0,75 0,8 0,85 0,9 0,95 1,0 1,05 µTjY U7tEp~ottYOY'totc; (cm) (ax) kg oupwLO otYIX 6iµot 6 A1tEptiiptGT7j 6,5 6 7 A1tEptiiptOT7j 7 6 7 8 9,2 10 A1taptoptOT7j 7,5 6 7 8 9,2 10 11 12 14 15 16 10 6 7 8 9,2 10 11 12 14 15 16 A1taptoptGT7j. 0,69 0,69 0,69 0,69 0,69 0,69 0,69 0,69 0,69 0,69 A1taptiipto,7J**l 6 7 8 9,2 10 11 12 14 15 16 2. TiaptoptoµivTJ ot7to ,o µijto,o aownptxii orxo ,ou aownptxou 6oxdou ·orxo T7jc; TiuxYOT7j'tot 'tOU ~UAOU (.1-TJY U7tEp~otLYOUGot 1,25 jp./xu~. EX. , oxt Xot'tW'tEPTJ ot7t0 Eaw,e.plxiJc; 6La.1.1-i-tpou 0,6 0,65 0,7 0,75 0,8 0;85 0,9 0,95 1,0 1,05 µ7JY U7tEp~otLYOUGot ·(l) kg oupixvLO otvix 6iµot 2 6 7 8 9,02 10 11 12 14 15 16 3 6 7 8 9,02 • 10 11 12 14 14,5 14,5 4 6 7 7,8 7,8 7,8 7,8 7,8 . 7,8 7,8 7,8 5 3,63 3,63 3,63 3,63 3,63 3,63 3,63 3,63 3,63 3,63 7 1,41 1,41 1,41 1,41 1,41 1,41 1,41 1,41 1,41 1,41 A1taptiipto't7J 0,69 0,69 0,69 0,69 0,69 0,69 0,69 0,69 0,69 0,69 A1taptoplaT1J**> 6 7 8 9,2 10 11 12 14 15 16 I 1,1 1,15 17 17 17 17 0,69 0,69 17 17 1,1 1,15 17 17 14,5 14,5 7;8 7,8 3,63 3,63 1,41 1,41 0,69 0,69 17 17 *) OupiivLo (.1-TJ 1tEplixov ,o lGO't07tO 233 xa.t ,ou 01toiou TJ 1tEptEX'ttXOT7J'ta. GE oupixvto-235 6av u1tEp~otive.t 93,5% oe. µix~ot. . 1,2 1,25 17 19 17 19 0,69 0,69 17 19 1,2 1,25 17 19 14,5 14,5 7,8 7,8 3,63 3,63 1,41 1,41 0,69 0,69 17 19 **> Au,ic; Ol mo 07Jµotntxic; µix,ac; e.m,pi1tov,m o,otv ,o EU<JXto,o 1tpoiov 7totpouotix,e,a.t u1to T7JY 1.1-opq>TJ xoµµot,twv jE(.1-IX,a. (µotoiqi) µi,illa. µ7JY ~uri,ov,~ Atjonpo ot1tii 2 XT· ixoto,ov xott ,wv 01toiwv ot e.mq>IXYELEc; Et\lott ot7t7JAAotjµivEc; ot7to EtGotjWjtXIX ,µiJµot,ot. >-' Is:) c.n °' m e ~ s: m :!! M t ~ M ;i:: < ttl m "'tJ 2 ~ M m :0 M ~ m < X 0 M I> m < t m "'tJ .Q ,;. Ka<p~otto A.6 Tiivotxot<; IX '<'. 'C0 • • • *) • • • • " A • 26,44 / A L-\IV E,ot TJ p.aryp.ot,ot oupotvwu ,:wv oitotwv TJ ouyxavi:pWOlj OE oupotvto uEV uitap,,ottVEL H/U+ l,4 l yp. xu,,. EX, Emi:peit-rioc p.a,ot oupotviou otva Up.ot otv~o"YTJ µE ,lJV ituxvo,711:ot wu ~u)..ou ouoxEuotoiot<; 1. Ile.ptoptoµivlj otltO 1:TJ p.iytO'tlj EOW'tEptXT} Otap.a,:po 'tOU EOW,e.ptxou oox aiou l\tiiµe1:po wu Iluxvo'tlj'tot 1:ou ~uAou p.TJv u1tEp{3otivov1:ot<; 1,25 1p./xu(3. Ex. Xott ox L xot-rw, .. pTJ otito eow,Eptxou oox .. iou 0,6 0,65 0,7 0,75 0,8 0,85 0,9 0,95 1,0 tJ.TJV U1te.p{3ott\lO\l'tot (ex) kg oupavw otva oiµot 6 Aiteptopto'tO 6,5 2,80. 6,0 A1teptopto1:0 7 2,80 6,0 6,0 6,0 6,0 7,5 2,80 6,0 6,0 6,0 6,0 6,0 6,0 14 15 10 0,330 0,87 1,10 1,80 2,50 3,50 4,6 7,1 7,7 AiteptoplO'tO 0,084 0,120 0,157 0,193 0,231 0,267 0,301 0,335 0,370 2. IlEptoptop.iv71.a1to w µiyto,o eowi:eptxo oyxo ,:ou e.OW'te.ptxou 00)(.ElOU 0 01xo 1:0U Iluxvo,:711:ot 1:ou ~uAou p.71v u1tep(3aivouoa 1,25 1p./xu(3. ex. ;t(X.L ox t xot1:wnp71 otito eow-reptxou oox eiou • 0,6 0,65 0,7 0,75 0,8 0,85 0,9 0,95 1,0 p.71v u1tep{3otivov1:a<; (1) kg oupcxvto (X.V(X oiµot 2 0,152 0,380 0,66 1,01 1,47 2,00 2,66 3,50 4,64 3 0,084 0,223 0,416 0,65 0,93 1,25 1,58 1,96 2,34 4 0,084 0,120 0,157 0,193 0,231 0,274 0,356 0,498 0,73 5 0,084 0,120 0,157 0,193 0,231 0,267 0,301 0,495 0,57 7 0,084 0,120 0,157 0,193 0,231 0,26'? 0,301 0,347 0,406 Aiteptopto-ro 0,084 0,120 0,157 0,193 0,231 0,267 l 0,301 0,335 0,370 1,05 A1teptopto1:o 15,2 9,6 0,400 1,05 6,04 2,74 1,05 0,60 0,467 0,400 *) Oupcxvw P.71 lte.plE)(.0\1 w tOO'tOltO 233 Xott 'tOU OltOlOU 7l ltepteX-rtX01:lj't'(X. OE oupavw-235 OE\I UltEp{3aivEt 93,5% OE p.cx,ot. 1,1 1,15 1,2 • 15,2 15,2 15,2 11,6 13,8 16,1 0,429 0,456 . 0,478 ' 1,1 1,15 1,2 7,62 9,39 11,3 3,16 3,57 3,99 1,47 2,02 . 2,70 0,74 0,84 0,92 0,53 0,60 0,66 0,429 0,456 0,478 1,25 15,2 18,3 0,498 1,25 13,3 4,42 3,55 1,02 0,73 0,498 e M ~ ..... 0 ~ m a J: s: m :!! M I J: M " -< CD m ~ 2 J: M m :0 M '=i m < X 0 M I> m < I m ~ .9 ...... "' (./1 :i KE<pW..<J.LO A.6 Iliv<1.xoo; X M71 u8porovoµiv<1. ouv9E't<J. ~ µeirµot-rot 7tAOU'tWVtOU 'tOU 01toiou 7l ourxEV'tPWOTJ OE 1tAOU'tWVL0-239 8ev U1tepf3<1.tVEL 10yp/xuf3. ex.' Em'tpE,.;'tEIX µdt~ot 1tAOU'tWVtOU <1.VOt 8tµ<1. cxvw..or<J. µe 'tT)V 1tUXVO'tT)'tlX 'tOU ;u).ou OUOXEU<J.Ot<J.c; 1. Ilep1optoµiv71 IX1t0 'tT) µirLO'tT) EOW'tEplX~ fadtµnpo 'tOU EOW'tEpLXOU 8ox eiou 11tdtµe-rpo -rou ITuxvO'tT)'t<J. -rou ;u).ou µ71v u1tepf3otivouo<1. 1,25 'Y?•fxv(3. ex. XotL ox L x<1.-rw-rep71 <1.1to eownptxou 6ox dou 0,6 0,65 0,7 0,75 0,8 0,95. 1,05 1,1 . 1,15 µ71v 1mepf3otivouoot (cm) x r 1tAou,wvw <1.vdt oi!J.<1. 6 <1.7tEpl0pLO't0 6,5 3,60 4,2 IX1tEptopLO'tO 7 3,60 4,2 4,7 5,3 A1teptopto,o 7,5 3,60 4,2 4,7 5,3 5,9 7,1 A1tEpLOpLO'tO 10 3,60 4,2 4,7 5,3 5,9 7,1 8,1 8,3 8,6 A1teptopto'tO 0,405 0,405 0,405 0,405 0,405 0,405 0,405 0,405 0,405 2. ITeptopLO!J.EVT) IX1t0 'tO !J.E1LO'tO eownptxo orxo 'tOU EOW'tEptxou 6ox eiou '01xo 'tOU ITuxVO'tT)'tlX 'tOU ;u).ou µ71v U7tEp(3otivouoot 1,25 rp,/xuf3. EX. KIXL OXL KIX'tW'tEPTJ <1.1t0 eownp1xou 60-, dou 0,6 0,65 0,7 0,75 µ 71v u1tepf3otivov (1) kg 1tAOV'tWVLO otvdt 6iµot· 3 3,60 4,2 4,7 5,3 4 3,60 3,84 3,84 3,84 5 2,44 2,44 2,44 2,44 7 1,20 1,20 1,20 1,20 IX1tEpLoptcl'tO 0,405 0,405 0,405 0,406 0,8 5,9 3,84 2,44 1,20 0,405 ·) Tot µeirµot'tot 1tEptiX,OV'totc; f371puAALO ~ OEU'tEpLO IX1tOKAELOV'tlXL XIXL 7l µdt~ot dtv9potxot OEV 1tpi1tEL VIX ELVIXL IXVW'tEPTJ IX1t0 1/10 -r71c; µdt~otc; E1tL'tpE1t'tOU 7tAOU'tWVtOU. 1,25 8,9 0,405 ...... t-., (Jl 0:, m e :::c s: m .,, M t :::c M " -< IJJ m .,, 2 :::c M m :0 M "=i m < X 0 M I> m ~ m .,, .9 ' Ki.cpcitA<Xto A.6 Ilill<XX<X<; XI Mhcxllo 1tAou,w11iou x wpi,; i.m~p<Xow,ic; Em,pE1t'tE<X µcx~<X 1tAOU'tW\ILOU <X\ICX OEfJ-<X <X\ICXAOj<X µi. 'tTj\l 1tUX\IO'tTj't<X 'tOU ~UAOU <JU<JXW<X<JL<Xc; 1. Ili.ptoptaµEVlj <X1t0 't'lj fJ-Ejt<J'tTj E<JW'tEptXT} focxµi.,po 'tOU i.awnptxou oox i.iou l\tcxµa,po 'tOU Ilux110'tTj't<X ,ou ~uAou µ7J11 u1ti.p~<Xi11oua<X 1,25 1p./xu~. i.x. xm ox i x<X,wnp7J <X1to E<JW'tEptXOU OOX,ELOU 0,6 0,65 0,7 0,75 fJ-lj\l U1tEp~<XL\IOU<J<X (cm) Kg 1tAOU'tW\llO <X\ICX OEfJ-<X 4 3,20 <X1tEptopta'tTj 10 3,20 3,60 3,90 4,2 <X1tEptoptO'tO 0,405 0,405· 0,405 0,405 <X1tEptopta'tO . 3,20 3,60 3,90 4,2 2. IlaptoptaµEVlj <X1t0 'tO fJ-Ejl<J'tO Eawnptxo OjXO 'tOU Eawnp:xou oox aiou . '(}y-xo ,ou Ilux110'tTj't<X ,ou ~uAou µ7J11 u1ti.p~<Xi11oua<X 1,25 1p./xu~. Ex. 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'~ Av Tj ~!WpTJ'tLX1J 7tLEO'Y] O'tO opLCXXO 7tEpt'tU~Lr~ex Eivext cxvc;mp11 otr.o 35KPcx (0,35 BAR) - µcxvoµE,pLXTJ mEoTJ) 8cx 1tpi1tEL vex E~cxocpexALo,ouµE O'tL ,o opLotx6 1tEpti:VAtTfl-lX xci0E 6aµex'toc; ouµcpwvEi (-LE ,ouc; opLoµoui; 'tOU µov'tEAOU axmxoui; µE 't'YJV 6uvex,O'tTJ'tex 1tEpt-cuAirµex,oc; exu,ou vex 8LCXtljp1JoEL 'tlJY OAOXA TJPO-Clj'tot 'tOU U7t0 7tLEOTJ T · ·o,cxv ,Lex vex LXexV07tOLOUY'texL 'tCX xpL,iJptcx 'tljc; 7tUpTjVlXYjc; cxocpCXAEiexc; EOWXAEtO\l'tlXL 0EA riµex'ttXOt 1LIX 'tO Mro CXU'tO Ot cxr.oppocpljtiJpEt;; vE,poviwv, ocxv o'tOLXEiex ouoxEucxoiexi; 1tpi1tEt VIX EX'tEAOU\l'texL 6oxLµexoiEc; TLIX vex otroupEU'tOU(-l.E 1LIX''t'Yj\l 7tlX­ pouoicx xexL 11111 OLexvoµiJ exu,wv ,wv OTjATJ111piwv. 1267 3642 1268 EG>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 2. ITptv x1X8E 1t1Xp1X60071 1 tix (J-E'tixcpop!X. ITptv IX7t0 xlX0E 7t1Xp1X600TJ j'LIX 'tTj\l fLE'tiXcpOpiX evcic; 6aµix't0c;, 0 IX7tOO'tOA.EIXc; 0e 7tpE7tel VIX 't7lp710EL 'ttc; e!;71c; 007lj'LEc;. ix. 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't7lc; 0EwpouµEv71c; emcpixvdixc; µe EV(X !;epo x ixp't[ cpihpo 11 µe uopbcptAO ~IXfl~IXXL 11 illo oµoet6ic; UALXO. ftlX 'tlX 6EflCX'tlX 7t0U 1tpoop[,OV'tlXL j'tlX 'tTJV (J,E'ttxcpopot ptx6LO­ EVEpj'WV ovotwv, 61tw~ 1XX'ttvo~o).71µivo xixuotµo, 0ix 1tpo­ ~ouµe oE ex'tiµ71071 1tcx vix xix0op[oouµe cxv 71 6p1Xo'tTjptci't7l'ttx µ1topE[ vix oup0Ei (J-• 1tAuo71 O'tTJV EmcpotVELIX 7t. X· µE ~71 ~pox 71. H oux vo't71c; (J-Lotc; 'tOLCXU'tTjc; EX'ttµ71071c; 0cx E!;1Xp't7]0E[ IX7t0 't"f]V m01XVO't7l'tlX IX1toppocp71071c; 'tTjc; ptx6LO-EVEpj'OUc; flOAUVOTjc; (X7t() 'tO e!;w-i:Eptxci O'tpW(J-CX XCXL ELOlXIX (X7t() 'tO O'tpwµix 1:71c; ~IX­ cp71c;. Av 71 6pixo-c71ptci't7]'tCX EX.EL 't"f]V OUVIX'tO'tTj'tlX vex ovp0ei OLIX 1tAuoEwc; o'tO E1ti1tE60 't0V 6aµix'toc; 0ix µnopfoovµE vix ouvEx i­ oouµE vex x p71otµo1totouµE 'tE'totcx 6iµix't,IX µovov µE 'tTJV 1tpoii 1tci0Ea71 VIX rivEL IX7t0 E!;ELOLXWflEVO IX'toµo µiix EX'tLflTjOTj 'tTjc; IXOCfllXAELtxc; 'tTjc; x p71071c; IX7t0 IX7tO<p7] 'tWV IXXtLVO~OAL6>V. ITivcxxixc; XIX Me,tanc; E7tL'tpE7t0f!EVEc; 'tLµec; 't7lc; µ71 xix8opt,oµiv71c; piXOLO­ EVEpj'OUc; (J-OAUVO,Tjc;. MoAVV'tLX7l ouoiix Mi1tO't7] Em 'tpE7t. 'tL(J-7! ix) <Dvatxci xcxt E!;cxo8Ev71µivo BQ/EK2 µC1/CM2 oupoevto XIXL CflUOLXO 0opto µovov 37 10-3 TT0µ1tot 8 XIXL f XCXL 1toµ1toi A fLE EA1Xcppdt 'tO!;LXO'tTj'tlX, 7t0U CX7t1XpL0f!OUVtlXL O'tO OTj µEio B cxvwtipw 3,7 10-4 0 0AOL OL oeAAOL 1toµ1toi A 0,3 7 10-5 IX. Tix E7tL7tEOIX 7t0U IXVIX1'PIXCflOVtlXL (XV~'tEpW ELVIXL 't(X µioix Em'tpo1toµEvcx o1ti1te6cx 1 tcx 300 CM2 Emcpcxveiixc;. 3644 B. IT0µ1toi A µE EA1Xcppdt 'tO!;txci't7]'tCX oupixviou -235 1J ou pdtvto -238, 06pto -232 06pto -228 xcxt 06pto -230 6tCXAu­ µivix WO'tE VIX u1toepx EL OUj'XEXPLflE\17] 6ptxa'tTjpLO'tTj'tCX 'tTj<; t6icxc; tdt!;71c; µE txU't1j 'tOU cpuotxou oupixviou XIXL cpuatxou 0opiov pix6to-VOVXAELOWV 7t0U ix ouv 7tEpio6o XIX'tW tWV 10 TjflEpwv. f. Kcxt711opiEc;. . Tix 6iµixtix XIXL 'ttx Kov'tEtvep (µtxpdt xcxt µE1<XAix) 1tpE1tEL vex EVtixx 0ouv OE µicx IX7t0 nc; tpEic; E!;71c; XCX'tTJ1'0PLEc;. I. Ktx'tTj1opiix I - Ae:ux71 (I) M(,l-1Xt(X 0 0't1XV OE xcxµiix O'tLr!-'-71 µ1ixc; µnixcpopoec; 7t01) 1tpcxrµo't07tOLELt(XL U7t0 XCXVOVLxic; auv071xEc; 71 EV'ttxa71 't7lc; IXX'tLVO~o).[cxc; 7t01) £X7tE(J,7tEL 'tO 6eµix OEV 1tpE1t£L VIX 1)7t£p~cxive:L 'tovc; 5µSV /w (0,5 µ peµ/w) oe; xcxvivix 071µeio 't7lc; e!;w'tept­ x71.;; e:mcpixvEitx<; 't0V oiµcx'toc; XCXL O'tO 6iµix vex µ71v e:ivcxt outE 't7lc; EUOX,LO't7I<; XAIX07I<; II OU'tE euox LO'tTJ<; XAIX07I<; III. (2) KoV'tELVEp 0 0'ttxV 'tO Kov'tELVEp avµ1teptAcxµ~otVEt OE­ (J,IX't(X µe; pix6to-Eve;prec; OVOLE<; OL 07tOL£<; xcxµµicx OEV IXV1JXEL OE Xtx't711opiix ixvwte:p71 cx1t6 t71v xcx't711opicx I AEvx71. 2. Ktx'tTj1op[ix II K['tptv71. (I) 1\iµix'ttx "Otcxv 71 EV'ttxo71 'tTjc; ixxttvo~oAicx.;; 1tou ixvcxcpipE­ 'tlXL O'tO 7tEpt0wpto 3653 (I) U7tEp~cxive:L 71 O'tL 'tO OE(J,IX OCV7lXEL 3650 O'tTJV EUOX.LO't7I XAIXOTJ II Ecp' 000\1. oc. H EV'ttxo71 'tTjc; IXX'tLVo~oAiocc; 1tov EX7tEfL7tEL to 6iµcx OEv U7tEp~oc[vEL OE xcxµ[cx OtLj'(J,1} (J,LIX<; (J,E't1Xcpop1X<; 7tOU 1tptxj'(J,IX't0 7tOLELtlXL v1t6 xixvovtxi.;; avv01JXEc; 0,5µSV /w (50 µ pe:µ/w) OE xixvivix 071µ.Eio tTj<; e!;wtEptx71c; e:mcpcxvdcx.;; 'tOU 6iµcxto.;;. ~- 0 auv'tEAEOt1jc; µewcpopdtc; OEV u1tEp~ixivEL 'tO 1,0 OE xix­ µicx OtL1'fL11 µtocc; fLE'tiXcpop&c; 7t01) 1tpcx,µtx't07tOLEL'tCXL 1)7t() xcxvo 3651 vtxic; ouv071x.c;. 2. Kov'tELVEP "O'ttxv ae xcxµ[cx a'tt1µ71 µ1occ; fLE'tiXcpop&c; 1tou 1tpcx1µcx'to1totEit1XL v1t6 xixvovtxi.;; ouv071xEc; o OW'tEAEat71c; 't7lc; µetixcpopdtc; 'tou Kov'titvep OEv U1tEp~cxivEL 'tO 1,0 xcxt on 'tO xo­ V'tELVEp OEv 1tEpLEX.EL xixvivcx 6iµix 't7lc; Euox tat71c; xAaa71c; III. 3. KIX'tTjj'Opicx III - Ki'tptv71. (I) MµtxtlX: ·o't(X\I TJ µtcx 1171 IXAATJ EV'tCXOTJ t71c; IXX'tL\IO~oAitxc; 7tOU cxvcxcpipE'tiXL O'tO 7tEpt0wpto 3654 (I) 1tpoo1tEpVottOCL 11 O't(XV 'tO oiµcx OCV7lXEL O'tTJV EUOX,LO'tTJ XAIXOTJ rr 11 OtTjV EUOY,.LO'tTJ XAIXOTJ III 11 cxx6µ71 O't(X\I 'tO oiµix (J.E'tlXCflEPE't(XL (J.E EL6LXO 6tcx­ xcxvovtoµ6, ecp' oaov. (X. H EV'tCXOTj 't7lc; CXX'tLVO~OAicx.;; 7t0U EX7tE(J.7tEL 'tO 6eµcx 6e:v U7tEp~1Xt\lEL OE xcxµicx OtLj'fl7l (J.LIXc; flE'ttxcpop&c; 7t0U 1tptxj'(J.IX't0 7tOLELt(XL u1to xcxvovtxec; avv071xE<; tlX 2[-LSV /w (200 µ pe:µ/w) ae xcxvivoc 07JµEio 'tTJ<; E!;W'tEptx71c; Emcpcxvdix.;; 'tOU 6ip.tx't0<;, EXtoc; CXV TJ (J.Etotcpop& 1tp1Xj'(J.CX't07tOLEt't(XL 6tcx 1tA71povc; cpop'tw 071c; u1t6 ouv071xEc; 1tou xcx0opi,ov'tcx ao ne:pt0wpto 3659 (7) a' OCU't71 tTjV 1te:pi1t'tWOTJ TJ flE1LOtTj E7tL'tpE7tOfLEVTJ EV'tCXOTJ EtVCXL lOp.SV /w (1000 µ pe:µ/w). ~- 0 OUV'tEAEO't7l<; 'tTJ<; p.e:tixcpopa<; OEV 1)1tEp~ixlveL 'tO 10 OE xixµicx O'tLj'f-l1j, (J.LIXc; (J,Et!Xcpopdtc; 7tOU 1tptxj'(J.CX't07tOLELt(XL 1)7t0 XIXVOVLXE<; OVV01JXE<; EX'tO<; CXV 'tO oiµcx f-lE'tlXCflEPE'tOCL 6tlX 7tA7l­ pouc; cpop'two71c;. (2) Kovtitvep: 0 0'tOCV ae; 07tOLCX07!7t0tE Ot'Lj'(J-7! µtote; µnixcpo­ p1Xc; 1tou 1tptxj'(J,IX't01tOLEitocL v1t6 xocvovtxic; auv071x.c;, o ouvn­ AEO't1j<; 't"f]c; flE'totcpop!Xc; 'tou KoV'titvEp u1tEp~ixivet to 1,0 7! 'tO Kov'tELVEp 1tEptix EL 6aµcx't1X 1tou cxv71xouv O't7IV Euox LO'tTJ XAIXOTJ III 1J cxxoµ71 OtOCV 'tO KoV'tELVEp µnixcpEpE'tlXL fLE Et6Lxo XOtVOVL aµo. • I\ EmrpixcpoxOMTJOTJ XOCL OTJf-llXOEf-lCX (BA auv. A9) (I) K&0. 6iµcx 11 KovtELVEp - (J.Ej'IXAO 11 µtxpo - 1tpE1tEL vex 1tpo~AE1tEtOCL 'tOVAIXX.LO'tOV OC7t0 2 emrpcxcpi.;; tOU 'tU7t01) 7 A 7 8 11 7f ouµcpwv<X µ. tTjV XOt'tTJ10PLIX (~A- 7tEpt0. 3652 awe; 3655) O'tTJV 01toicx cxv71xEt 'tO 6ip.0t 1J 'tO KoV'tELVEp. (2) Ot emrpcxcpic; 0cx to1to0etouvt<XL OE ouo Otvti0Enc; e:!;w­ 'tEptxi.;; 'tOU 6iµoc't0c; 71 one; 4 e:!;wnptxi.;; 1tAwpic; 'tOV Kov'tEL­ vEp. (3) Ot E7tLj'ptxcpac; 80t 11:pi1tEL vex OU(J,7tATjpWVOV't0tt we; e:!;11c;, (J,E 'tp07t0 wcxvarvwa'tO XOtL CX(J.E't<X~ATJ'tO - OtVE!;LtTjAO ). Ot. Y 1to 'tTJ" Ai!;71 «7tEpLE)(Of-lEVO» 00t ocvcx1p°'cpE'ttxL 'to poc6to­ vouxAEi6to 71 'to uALXo 'tou 01toiov 71 1tcxpovoicx IX7tO'tEAEL tov xu­ pto xiv6uvo OE 1tEpi1t'tWOTJ ,Tjp.icx.;; 'tOV OE(J.tx'to (1tX, otpOV'tLO 90 0tX'ttvo~oA71p.ivo oupdtvto LSA poc6to-Eve:p16). 3652 3653 3654 3655 3656 E<l>HMEPII: THI: KVBEPNHI:EQI: (TEVXOI: aEVTEPO) ~- 11to 'tTjV AEtTJ «6pixa,1jpt6't1j't1X» 0ix ixvix-ypixcpei 1l 6pixa,1j­ pt6,1ji; aa KtoupL LTjµ: H 6pixa,1jpt6't1j:CIX IXIJ'TT] 0ix µ1topfoet rniaTji; VIX ixvix­ jpixcpd ae µtxpo, µ[AL, 71 XLALOXt01Jp[ 71 XLALO - IX\11X"fp1XcpOV'tlXt oAo-ypiicpwi;. 'Y· L'tTJV am-ypixq,71 ,ou ,u1tou 7B XIXt 7-y 0ix ix11ix-ypiicpa,ixt XIXt ae ixpt0µoui;, 'tOU<;; mo µq&.Aoui; Buvix,oui;. 0 L1JV'tEAea,71i; 'tTj<; µa,ixcpop&.i; a,o 1tA1Xtato 1tou cpuAiiaaa­ 'tlXt "fLIX 'tO OX07t0 IXIJ'tO. ( 4) Kii0e Beµix EXOV'tlX<; µtx,71 µiil;ix <X\IW'tEPTJ IX7t0 50 X r 0ix 1tpE1teL VIX cpepet O't'Tj\l atw,eptx71 'tOIJ e7tLq>IXIIELIX 'tTj\l ev6attTJ 'tTj<;; µiil;ixi; 'tOIJ µa iµcpix1171 XIXL 6tixpx71 ,p61to. ( 5) Kii0a 6eµix 1tou ix1tonAahixt 1X1to µiix auaxwixa[ix ,ou ,u1tou A 0ix 1tpe1tet VIX cpipet O'tTJV atw,aptx71 ,ou amcpiiveLIX ni; Aatati; «'tU7tOIJ A» -ypixµµivei; µa aµcpixv71 XIXt 6tixpx71 ,po1to. ( 6) Kii0a 6iµix a-yxaxptµivou µov,iAou auµcpwvix µa ,ix 7te­ pt0wptix 3672 ewi; 3674 0ix 1tpE1tet VIX cpipet anarpixµµivo O'tTjV atwnptx71 ,ou amcpiivatlX µa aµcpix1171 xixt 6tixpx71 ,p61to ,o IXVIX"fVWpta'tLXO a,otxdo 7t01J XOPTJr7181jXe O'tO µ011,iAo IXIJ'tO IX7t0 't'Tj\l ixpµofaix IXPX71 XIXL ae mpt7t'tWOTj 'tOU 6iµix,oi; 'tOIJ 'tU 7tOIJ B(U) 71 B (M) 'tL<;; Aatati; «Tu1toi; B(U)» 71 «'tU7tO<; B(M)». (7) Kii0a 6iµix itou IX7tO'tEAet'tlXt 1X1to auaxwixa[ix ,ou ,uitou B(U) 71 ,u1tou B(M) 0ix 1tpi1tet VIX cpipet O'tTJV a;wnptx71 ,ou emcpiiveLIX 'tOIJ mo e;wnptxou Boxeiou ixv0exnxo O'tTj cpw'ttlX XIXt 'tO vapo µe eµcpixv71 ,p61to 'tO auµ~oAO 'tOIJ ,ptq>IJALOU aµcpix­ v[l;E'tlXL a,ti; em-ypixcpii; 'tOIJ fJ,OV'tEAOU 7 A iwi; 7f xixpix-yµivo, ,uitwµivo 71 ixvix1tixpix-yoµevo µe 01toto6711ton iillo ,poito itou 0(\l'tEXEL O't'Tj <j)W'tLIX XIXt 'tO vepo. E. Xwptaµoi; 'tW\I PixBto-E\IEP"fW\I OIJOLWV. ftix 'tTJV µe,ixcpopii XIXL 'tTJV 1X1to871xE1JOTj ,IX BiµO(,IX 'tTj<; xix­ 'tTj"fOpiixi; u - KhptvTji; 71 III xhptVTj, 0ix xwp[l;o\l'tlXL IX7t0 'tlX 6iµix,ix 1tou cpipouv em-ypixcp71 µe 'tTJII AE;Tj «FOTO» 6tix ,w11 IX7tOO'tlXOEW\I IXO<j)IXAEtlX<; 7t0U IX\11X"fp1Xq>OV'tlXL O'tOV 7tt\llXXIX 'tOIJ 1tept8wpiou 240001 ,ou 01J111jµµi11ou B4. <l>. TTpoawpt1171 Tpixvl;h 1X1to871xwa1j (I) Tix 6eµix,ix µa pixfao-evep-yeii; ouaiai; 6av 1tpi1tEL vix 0(1to 81jxeuov,1Xt O'tO\I i6t0 't07t0 µe 'tlX emx[v6wix cpopttlX µe 'tlX 07t0tlX IX7tlX"fOpEUE'tlXL VIX cpop'tW\10\l'tlXL µixl;L (~A. 7tEpt0wpto 2700 3). (2) 0 1Xpt0µoi; 'tW\I 6eµ&.,wv XIXL 'tW\I KoV'tELIIEP 'tW\I XIX'tTj·· yoptwv II xhpt110 71 III xhptvo 0(7t001JXEUµavix O'tO i6to xwpo 1;wv1l 1tpoawptv71i; 1X1to871xwa1ji; (T pixvl;h) 6tii6poµo cpop,iwv 71 1X1to871x1ji;. 0ix opto0E,1J0Ei hat wa,e 1l ii0potaTj ,wv auv,EAEa,wv µe­ ,ixcpopiii; µtixi; iBt°'i; oµix6°'i; ixutwv ,wv 6eµii,wv 71 ,wv xo­ v,ii:vep VIX fLTJV U7tEp~1Xt\/Et 'tlX 50. Miix IX7tOO'tlXOTj 'tOIJAIXXLO'tO\I 6 µ. 0ix 7tpE7tEL VIX 6t1X't1jp1j8d fLE'tlX;u 'tWV oµii6wv 'tW\I 6aµii­ 'tWV 71 ,wv KoV'tatvep ixu,wv ,wv XIX'tTJ"fOptwv XO(L ,wv iillwv. oµii6wv 6aµiitwv 71 xo11tit11ap ,w11 t6[wv X°''tTJ"fOptwv. 3. ·o,ixv O Ue-yxoi; 'tTj<; auaawpeUOTj<; 'tW\I 6aµii,wv "fL\le'tlXL fJ,E IX\IIX<j)OpiX an,; XOXXLVE<;; "f PIXfLµE<;; 'tW\I E7tL"fp1X<j)WII, fLLIX tfalX oµii6ix 6aµ&.,wv 6av 0°' 1tpE1tEt \IIX 1tEpLA1XfJ,~IXVEt 7tAEOV IX7tO 50 Baµix,IX 'tTj<; XIX'tTj"fOptO(i; II - Xt'tpLIIO 71 7tAEOV IX7t0 5 Baµix,IX 'tTj<; XIX'tTJ"fOptixi; III - xhptvo. ·o,ixv 'tlX 6iµix,IX 'tWV 2 XIX'tTj"fOPLW\I et\llXL 7t1XpOV't0( 0ix 7tlX­ pix6ex0ouµe O'tL E\IIX 6iµix 'tTj<; XIX'tTj"fOptiX<; III x[,ptvo Et\llXt tao,tµo µe 10 Biµix,ix 'tTJ<;; XIX'tTJ"fOpiixi; II x[,ptvo. 4. Ex,oi; 1X1t' O,'tL ixcpopii 'tlX Beµix,IX 'tWV EUOXLO'tW\I XAIX­ OEWV II XO(L III ot 1tEptopta,txii; Btix,ii;ui; ,ou 1tEpt8wp[ou • 3658 (2) Bev acpixpµo1;011,1Xt a,ix 6iµix,ix 1tou cpipouv ,ti; Ai;eti; «LSA pixBto-EVEp-yo» 'tlX 07t0tlX 7tEpLEXOUII UALXIX µtxp71i; au-yxe­ xpLfJ,EVTj<; 6pixa,1jpto't1j't1X<;, oun a' ixu,ii itou cpipouv ,ti; Ai;eti; LLS pixfaoevep-yo» XIXL 7t01J 7tEptexow anpe&. IJALXIX µtxp71i; 6p1Xa't1jpLO't7l'tlX<;, IX\/ IX7tO'tEAOU\I O'tOL~IXrµevlX E\IIX auµitix-yii; OU\IOAO 71 0(\1 EOWXAEtO\l'tlXL OE XO\l'tELVEp. (5) Em,piitE'tlXL"\IIX IXVIXfJ,EL"fVUOV'tlXt 6eµix,IX 6tixcpopwv 'tU 7tW\I µa,ix;u IXMWV, 6eµixtlX 'tTj<; eUOXLO'tTj<;; XAIXOTj<;; I XIXL 6e­ fJ,IX'tlX 'tTj<;; euaxta't'Tji; XAIXOTj<; II. Matixcpop&.. I Mµix,ix . (I) Tix 6iµixtlX cpop'tW\10\l'tlXL atlX OX7lfJ-IX'tlX hat wan \IIX µTjv µitopfoouv oun vix µnixcpipo11,1Xt emxiv6uvix oun vot otv1X1to 60-yup[1;0V't1Xt 71 VIX iticp,ouv. (2) Ecp' oaov Tj fLEOTj 8epµtx71 po71 Cl'tTj\l E7tLq>IXVELIX Oe\l IJ7tEp • 3657 3658 • 3659 ~ixivat ,o 15W /µ2 XIXL 'tlX cpop,i~ 1t~u 'tTjV 1teptxAe[ouv Bev· aawxAetoV'tixt' oe aiixxoui; ivix 6iµ110ix µ1topai vix µa,ixcpepatotL Cl'tTj µfoTj OLO(cpopw11 OIJOXEU1Xaµi11wv cpop,iw11 xwpii; etOLXE<;; OOTj"fLE<; Cl'tOt~IX;Tji;, Ototcpope'ttXE<; IX7t0 O(U'tE<; 7tOIJ TJ otpµoOLIX °'PX710ix µ1topouae vix ot7t0(L'TT]OEL µa XIX't!XMTJATJ ~a~ixiwoTj, Av Tj 8epµtx71 po71 IJ7tEp~1Xt\/Et 'tO 15W /µ2, 'tO 6eµix 0ix 1tpE1tEL VIX !J.E't1Xcpep0ei [J.e 7tA71PTJ cpop,waTj, (3) Tix OEfLIX'tlX 'tWV XIX'tTj"fOptwv I AelJX7I, II xhptVTj 71 III Xt'tpLVTj OeV 1tpi1tEL VIX fLE't!Xcpapov'tlXL ae xwpoui; 7t01J µnO(cpE­ pouv 'tlX;Etfawni; EXtoi; O'tlj\l .7tEpbttWClTj 'tW\I xwpW11 7tOIJ E7tL­ q>UAIXClOOV'tlXL IX7tOXAEta,txii "fL°' ,IX ii,oµix 1tou eivott ecpoBtix­ aµevot fLE ELOLX7I IXOeLIX VIX OU\IOOEUOUV 'tlX Beµot,ot IXU'tlX. ( 4) Em,pE7tE'tlXL 1l ixv&.µet;Tj 'tWV 6eµii,wv Ototcpopwv 'tU 7tWV xixt 671 6aµ&.,wv 't'Tj<; euaxto,Tji; XAIXOTj<;; I XIXL 6eµii,wv ,Tji; auoxta,Tji; XAIXOTJ<; II. • . . (5) H ouoowpeuoTj 6eµii,wv xixt KoV'tatvep.1tpi1tEL 11ix EAe-y­ XE'tlXL wi; e;71i;. IX. 0 1Xpt0µoi; 'tWV OefLIX'tWV XIXL 'tWV KoV'tatVEp 7t01J cpop,w­ VOV'tO(L a' EVIX [Oto OXTJfLot 0ix 7teptopta0ei µa ,po1to WO'te 'tO ii0potaµot ,wv auv,EAEo,wv µe,otcpopiii; vix fLTJV u1tap~ixivat to 50. 0,IXV O iAe-yxo,;; 't'Tj<; auoawpEUOTj<; 'tWV 6eµii,wv "fLVE'tlXL µe ixvixcpop&. a,ti; xoxxtvai; 'YP°'fLfLE<; ,wv em-ypixcpwv, ~A. 7te­ pt0. 3658(3). ~- ftlX 'tlX 7tA71PTJ cpop'ttlX 'tO ,ixvwnpo opto µ1topei VIX ;e1tEp­ VIX'tlXt acp' ooov 1l E\l'tlXOTJ IXXttvo~oA[ixi; u1to xixvovtxei; aw871 xai; µe,ixcpopiii; Bav 1J1tep~ix[vat ,o 2µSY /w (200µ paµ%/w) aa xixvevix OTJfLELO 'tTj<; e;w,eptx71i; amcpotveiixi; ,ou KoV'tELVep 71 ,ou ox71µix,oi; xott 0, 1 µSY /w (10µ paµ/w) aa 2µ ot1t' otu,71 'tljV E7tLq>IXVELIX, 'Oµwi; O'tTJV 1tep[1t,WOTJ 6eµii,wv ,wv auoxt,wv XAiioawv II XIXL III 71 fJ,EL"ffLIX'tW\I 'ta'totWV 6aµ&.twv O 1Xpt0µoi; 'tW\I 6aµii­ 'tWV avoi; t6[ou cpop,[ou 6av 1tpe1tet vix u1tep~ixivat ,ov 1tixpix6a­ x,fo 1Xpt0µo (~A. ClTJfL· 'tOU 7tep. 2700). 6. 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Aixµ~IX\10\l'tlXL µhpix "fLIX VIX O'tOL~Ot.1;0\/'tlXt 'tlX OEfLIX'tlX O'tO OXTJfLIX hat WO'tE VIX fl-Tj\l µ1topouv VIX fLE'tlXXL\IOUV'tO(t XIX'tlX 'tTj 6tiipxELIX µtixi; µe,!Xcpopiii; 7t0.IJ 7tp1X"ffLIX't07totEt'tlXL IJ7t0 XIX\10\IL­ xei; auv871xei;. tLL. ~.v U7t1XPXEL 6tixBtXIXCltlX cpoptWOTj<; 71 tecpop,WaTji; µa­ 't1Xtu 'tTJi; ixpx71i; xixt ,ou ,aAoui; ,1Ji; µa,ixcpopixi;. Av ot 1tpou1t~8foati; ixu,ii; 6av 1tA1jpouv,ixt 1l iv,1Xa1J 'tTJ<;; otX1:LVO~OAtoti; OE\/ 1tpi1tEL VIX IJ7tEp~1Xt\/Et 'tO 2µSY / w (200 µpeµ/ w ), OE XIX\IEVIX ClTjfLElO 'tTj<; e;w,Eptx71i; E7tL<j)IXVEtlXi; 'tOIJ OEfLIX'tO<;. 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H EV'tlXOTJ 'tTj<; otX'ttvo~oAiixi; OE xii0e ,01to8eaiix ,ou ox71µix't0i; 7tOU etVIXL XIXVOVLXIX XIX'tELATjfLfLEVTj Bev 1tpE1tEL VIX u1tep~ixivat ,o 20µSY /w (2µpaµ/w) XO('tlX 'tTjV µe,otcpopii. t7t ixutii; ,ti; ow871xai; o µa,ixcpopeixi; 1tpi1tat vix e;ixocpixAta,ei 6,t o OOTj"fO,;; 71 'tO 1tpoawmxo ClU\IOOEtlXi; OEV 1X1t0Be.xov't1XL 7tAEO\I 1269 i I I I I 1 I 1270 E<DHMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) cxmi SµSV (0,5pEµ) xcx-cii µicx 01totcx6ij1tO"CE 1tEpio60 12 µTj­ vwv. 0 µE-ccxqiopEcxc; 1tou OE~E-ccxt -ctc; EAIXXta-cEc; cx1toa-cii0Etc; 1tou cxvcxypixqiov-ccxt a-cov 1tivcxxcx -cou mptflwpiou 240000 -cou au­ VTJfJ-fJ-EVou B.4 cxxoµcx xcxt fJ-E omouaicx Evoc; 1tpOO"CCX"CW"CLXOU xcxAuµµcx-co.; flex flEWp7j9d w.; OE~OfJ-EVOc; "CO opto "COU 20µSV / w (2µpEµ/w). •• ~- Av-ci -cwv 067J1twv -cou E5cxqi[ou ex cxvw-cEpw o µE-ccxqio­ pEcx<; µitopEi vex -CTjpd "CO ~t~Aio "COU xpovou, E')'XEXptµµEvo CX7t0 "C'Tj\l cxpµo6tcx cxpxTJ, 7t0U 7tEpvouv ot auvo5oi O"C(X OXTJfJ-CX"CCX, X(Xt "C'Tj\l EV"CCXOTJ "C'Tjc; CXX"CL\IO~oAicxc; 7t0U 6Exo11-ccxt WO"CE XCX\IEIIOt<; vex fJ-Tjll EX"CiflE-COtt XCX"CIX µi0t 07t0t0(6Tj7t0"CE 7tEpio6o -cptw\l fJ-TJIIW\I Oe MaTJ o,;vw-cEpTJ 0t1to 3,7~ µSV/ (375µpEµ) 2. 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H E')'Xpta'Tj "CW\I r,.pf1o6iwv cxp,:wv 5EV XPEtlX,E"CO(t ')'t(X "CO( f,lO­ \l"CEAO( 5Eµii-cwv itou 1tpoopi,ov-ccxt 1tr,. uAtXIX 1tou r,.1toa-ciMo 11-co,;t aUfLcpwvo,; µE -co,; 5EA-cio,; 1 Ewc; 4 ou-cE 1to,; -co,; µov-ciAo,; 5E­ µii-cwv 71:0U 1tpoop[,OV't(XL ')'t(X "CO( UALXIX "CW\I 5eA "CLW\I 5 ewe; 8 eq, 000\1 "CO 7teptEXOfLEVO -cou.; 5Ev 0(7tQ"CEAEL"CO(t 0(7t(l EUOXtO"CO( UAtXIX 7t0U (X7t(Xl"COU\I E')'XPLOTJ auµq,wvr,. µe "CO 7tept9wpto 3674. • A 'E,xptOTj "CW\I pr,.6to-evep,wv UAtXW\I U7t0 it6tXTJ µopcpTJ ( 1) Mio,; µovoµEpTjc; E')'XptOTj ')'t(X xiiflE µov-ciAo axrnxo (LE "C(X UAtXIX U7t0 ELtltXTJ f!OpqJTJ ex-coc; "CW\I UALXWV "CWV 5eA "ClWV 3 Xcxt 4. ' H o,;["CTJOTJ 1Lo,; "CTJV i 1xpta'Tj 1tpE1tEt vo,; mptEXEt 0(. Mto,; Arn-coµepTJ 1tEpt,p0tq,7J "CW\I UAtXW\I TJ (XV 1tpoxmo,;L 1 Lo,; xiiqiouAOt -co 1tEpLEXOfLEVO µE 7tATjpoq,opiEc; -CTjc; q,uatx7Jc; 7J XTJ(LtXTjc; XO("CIXO"C(XOTjc;. ~- Mir,. 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H ~E~O(lWOTj flo,; o,;vo,;qiipEt "C'Tj\l AE7t"CO­ µipELO( "CW\I po,;6to-EIIEP')'W\I OtJOtW\I, B 'E1xpLOTJ -cwv µ011-ciAwv 5.µii-cwv. 1. H E1xpta'Tj -cwv µ011-ciAwv 5eµii-cwv -cou -cu1tou B(U) au­ µ1tepLA(Xµ~o,;11oµivwv XO(L "CWV 5Eµii-cwv "CWV EUOXtO"CWV XAIXO­ OEW\I I, II xo,;t III itou u1toXEL11-co,;t rnia7Jc; a-ctc; 5Lcx-cii!;uc; -cou 7tE­ pL9wpiou 3674. ( 1) Kii0e µ011-ciAo 6iµr,.-coc; -cou -cu1tou B(U) 1tou 'tEAeto 7tOtEi-cm OE µ[o,; xwpo,; µiAouc; "C'Tjc; ADR 1tpE1tEL \l(X E')'XpiVE-CO(t 0(7t0 "CTJV o,;pµo5t(X (XPXTJ "C'Tjc; xwpo,;c; (XU-C'Tjc;, Av TJ xwpo,; 07tOtJ xo,;-cr,.axeulX,E-CO(L -co µov,i).o 5ev dvo,;t µiAoc; -cou ADR, TJ µe-co,; ipopii 9r,. eivr,.t 5uvo,;-cTJ Ecp 00011 . ex. Mir,. ~-~r,.iwo'Tj xo,;0opi,ovio,;c; o-cL :rn 6iµr,. o,;v-c0t1toxpivE­ co,;L a-ctc; -CEXVLxi.; itpo6to,;1pr,.ipEc; -CTjc; ADR xop7j1Ei-cr,.t cxito -CTJ xwpo,; O(lJ"C'Tj XO(t flEWpTjflE[ 0(7t0 "C'Tj\l o,;pµo5L(X o,;pXTJ "C'Tjc; 1tpW-CTjc; xwpr,..; "COU ADR 7tOlJ o,;ni,e-C(Xt 0(7t(l "CTJV 0(7t00"COATJ, ~- Av xo,;µ[o,; ~E~O(lWOTj 5Ev xoprrrTJflTJXE, "CO µov-CEAO "COU 3660 3661 3662 3669 3670 3671 3672 6Eµ0t-coc; 00t e')'XptVE"CO(t 0(7t0 -CTJ o,;pµo6to,; o,;pxTJ -CTjc; 1tpW-c7Jc; xw­ pr,.c; ADR 7t0lJ O(HL,E"CO(L (X7tO "C'Tj\l (X7t00"COATJ, (2) H o,;[-cTjOTJ 1to,; -CTJV i 1xpta'Tj 1tpE1tet vex 1tEptEXEL o,;, MLo,; AE1t-coµEpTJ mpt1po,;ipTJ -cou 1tpo~AE1toµEvou 1tEptEXO­ µivou 1tou vo,; r,.vo,;ipe.pEL µE,o,;!;u illwv -CTJV q,uatXTJ xr,.t XTJfLLXTJ xo,;-cixa-co,;aTJ xcxt -CTJV q,ua7J -CTJ<; o,;x-cLvo~o)..lo,;c; itou EX1tiµ1te­ cr,.t. ~- Mio,; Arn-coµep7Jc; 1tepL1po,;cpTJ -cou µov-ciAou itEptixov-co,;c; "CO( 7tATJPTJ oxi6to,; 01twc; XO(L "CO( 6to,;xpmxii XO(t 0(\IO(')'IIWpLa"CLXIX 0-CotXEL(X "CWV tJALXW\I XO(t "CW\I µEflo6w11 X(X"C(XOXW7Jc; 7t0tJ XPTJ­ OLfJ-07tOtTj9TjXO(\I. 1. 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VEpii, -co,; µE-cpr,. 1tou A7Jq,87Jxr,.11 1to,; \10( E')'')'UTj8d O"Ct Tj µoAtJ\IOTj O"CTj\l E7tt(j)IX\IEUX 'tOtJ 6iµo,;-co.; 6.11 ei­ \lO(t r,.vw-cEpTJ (X7to -c(X Em-cpEma opt(X. e) Av -co 6Eµo,; EXEL xo,;-cr,.axw0ta-cEi i'tat wa-cE vo,; cxv,EXEL ae µt(X XOt\lOVLXTJ µi,LO't'Tj 7tlEOTJ XPTJOTjc; 0(\IW'tEPTJ 0(7tO 0, 1 MPo,; (IBAR) - µ0tvoµE-cpLx7Jc; 1tiE07Jc;, TJ o,;[,TJOTJ 1to,; -CTJII E1xpta'Tj 1tpE1tEL E7tlOTjc; \l(X O(VO(l'f'EpEt, oaov o,;cpopii 't(X tJAtXIX 7t0lJ XPTJOL­ µ01totOU\l't(Xt 1to,; -CTJV xr,.,o,;aXWTJ ,ou opLo,;xou 7tEpt,uAi1µo,;-coc;, CO( 6to,;xpt-CLXIX 0-COtXELO(, 'tOt 5ei,µo,;-co,; 7t0tJ 1tpE1tEt V(X A7Jq,9ouv xo,;t -ctc; 5oxtµo,;aiEc; itou 1tpE1tEt vo,; 1tpr,.1µr,.,01tot7J8ou11. ') 'O,o,;v "CO 1tpo~Arnoµe110 7tEptEXOfJ-E\IO El\l(Xt 0(\l'tLVO~OATj­ µEvo xr,.uatµo Tj o,;[-c7JOTJ 1tpE1teL vo,; o,;110tcpipEL xo,;L vo,; 5txcxtoAo 17JaEL xii0E tJ1t08EOTj 't'Tjc; 0(\IIXAUOTjc; 't'Tjc; OtO(j)IXAEt(Xc; axrnxii fJ-E 't(X xr,.p0tX-C7jptO'ttXIX 'tOU xo,;uatµou O(tJ'tOU. TJ) KiiBE Et5LXTJ 5tix,r,.!;Tj a-coi~o,;!;Tjc; o,;vr,.1xo,;[r,. 1to,; vo,; E!;r,.­ oipo,;ALa-ce.i TJ e!;ii,µLa'Tj 't'Tjc; 0Epµo"C'Tj,r,.c; E!;w 0t1to ,o 6iµo,;, 0r,. 1tpE1tEL V(X A7jcp0ei U7t o<JiTJ O 'tU1toc; "COlJ OXTJµo,;-coc; TJ "COlJ XO\l"CEL­ vEp (~). itEpt0wpLo 3681 I) o,;)(. 0) Mio,; 0(\l(X7t(Xpo,;1w1tµTJ EtxovowixipTJaTJ 21 Ex. x 30 Ex ,o 7t0AU 5dxvu 7tW( EXEL XO("CO(OXElJOtO'td "CO 6iµ0t. (3) H 0tpµo6L0t o,;pxTJ Sr,. xopTJ,TJOEt µlo,; ~-~o,;iwaTJ 1tou vo,; ma,oitotEi o-ct ,o E')'XExpLµEvo µov,iAo o,;11,r,.1toxpi11E't0tL o-ctc; axrnxic; 1tpo6LO(')'PO(Cj)Ec; fJ-E 't(X 5iµcx,cx "COlJ 'tU7t0tJ B(U). BAE7tE 7tEp. 3677 XO(t 3678). 2. 'E1xpLa7J ,wv µov,iAwv 1tr,. 5Eµo,;-co,; -cu1tou B(M) auµm­ ptAo,;µ~cxvoµEvwv ,wv 5Eµii,wv -cwv EUOXLa-cwv xAiiaEwv I II X(XL III 1tou u1tOXELV't(Xt E1tia7Jc; a-ctc; 6to,;,ii!;Et<; -cou itept0wpiou 3674. (1) MLo,; 1toAu1tAeUpTJ i 1xpta'Tj XPELIX,E'tOtt 1to,; xii8E µov-ciAo 36 73 6Eµo,;-coc; ,ou ,uitou B(M). (2) H o,;[-c7JOTJ E1xpiaEwc; Evoc; µov,iAou 5Eµo,;-coc; -cou -cu1tou B(M) 1tpE1tEt vo,; 1tEptAo,;µ~ii11Et 1tAEO\I cx1to -ctc; 1tA7jpoipopiec; 1tou 0(7t(XL'tOUV't(Xt O'tO 7tEpL8wpto 36 72 (2) '(t(X "C(X 5Eµcx,cx "COU 'tU 7tOlJ B(U). 0(. 'Evr,.c; XO('tlXAO')'Oc; 'tWV 1tpoa8nw11 auµ1tATjpWµ(X-ctXW\I 1tpo6t0t')'PO(l'f'W\I ')'LCX -CO( 6Eµ0t"CCX "COlJ "CU7t0lJ B(U) O'tO 7tEpt8wpLo 3603 a-co oitoio -co 5Eµcx 6E11 Eivo,;t auµipwvo. B. H 07JµEiW07J ,wv auµitATjpwµo,;-cLxwv µi'tpwv itou 1tpo­ ct8Ev,cxt vat A7Jl'f'0ouv xr,.-cii 'tTJV µncxipopii 5· 1L0t vex r,.v-cta,r,.9 µi,E-co,;L 'tO fJ-Tj auµipwvo 7tOU o,;vcxq,EpE-c(Xt O'tO o,;) w.; IXVW. 5 57J).,o,;67J µhp0t xcx,ii 'tTJV µnr,.ipopii 1tou fav 1tpo~AE1to11-co,;L XO(VOVLXIX O'tO 1to,;pov Xe(j)IXAO(tO CXAAIX 7tOlJ xpivoV't(Xt cx1tcxpo,;i­ "C'Tj"C(X 1Lcx vo,; E!;r,.acpMtaflEi TJ 0taq,iiAEto,; -cou 5Eµcx,oc; xo,;,ii "CTJV µE-co,;q,opii 7t,x, fJ-LOt o,;118pw1tt\1Tj fJ-EOOAIX~TJOTJ ')'tOt \IOt µE,p7j8Ei Tj 8Epµoxpo,;a[o,; 7J Tj 1tiEOTJ 7J yLcx vo,; 1tpcxyµo,;-co1tot7JflEi 7tEpto5tx~ ,,s<> ., cx1toauµ1tieo7j. Au-cii -er,. µi'tpo,; 0cx 1tpE1tEt E1t[o7J<; vat Aii~oiiv u1toqi7J XOtL w; 5uvo,;,O'tTJ'tEc; r,.1tpo~AE1t-cwv xcx0ua-cEp7JaEwv. ,. Mir,. 57JAWOTJ axrnx7J (LE -cou.; Et5txouc; -cpoitouc; ipop-cw­ OTjc; fJ-E't<Xcpopiic; !;Eq,op-cwa7Jc; TJ fJ-E'tcxxdpta7Jc;, 5. H OTjfJ-ElWOTJ 'tW\I µe,tO"CW\I X(Xt eAIXOOO\IW\I emxpo,;a-cou­ OW\I au1187Jxwv (Bepµoxpo,;a[r,. TjAt(XXTJ 0tX'tL110~0).[o,;) 1tou axE­ it-coµo,;a'tE vr,. o,;v-cLµnwit[aouµe xo,;-cix -CTJV µe-cr,.q,opii xcxt -ccx 01to[o,; eA7Jq,87Jao,;v u1toqi7J xo,;,ix 'tTJV xr,.,r,.axw7J -cou µ011-cEAou. (3) H o,;pµo6L(X o,;pxTJ 0cx XOPTJ,TJOEL µt(X ~-~(XLWOTJ 7t0tJ 0cx ma,oitoLd o-ct ,o E')'XEXpLµEvo µ011-ciAo r,.11-co,;noxpive't(Xt a-et.; E<l>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) 1tpOOl1Xjp0tcpEc; ttc; ox. EttXEc; (LE tCX OE(J.CXtCX tU7tOIJ B(M) ~AE7tE 1tEptGwptOt 3677 Ewe; 3679. 3. 'E-yxpto71 twv µovtiAwv OE(J.IXtWV twv Euox totw~ xAix­ oEwv I II III. (1) f tQ( tCX (J.OVtEACX OE(J.IXtWV 7t01J ouµcpwvouv OtQ( 1tcxpcx 0Eirµcxtcx tou 1toptGwp[ou 3620 xcxt 3623 Tj 3624 x0tµicx ixU71 EjXpto71 t71c; cxpµ60tcxc; cxpx Tjc; OE x pEtlX,EtCXL. (2) Mi0t µovoµEpTjc; EjXpto71 X.PELIX~EtOtL jLOt tcx µoVtEACX twv OEfllXtWV 7t01J ouµcpwvouv Otex 1tcxpcxOE[yµcxt0t tWV 7tEptGwp[wv 3616 XCXL 3622. (3) Micx 7tOAU7tAEUp7] EjXpto71 x paux,atott jllX OACX tQ( µo­ \ltEAQ( oaµixtwv. (4) H 0tit71071 1tcx EjXpto711tpE1tEL vex 1toptEX,EL 6)..ac; ttc; cx1tcx­ pcxit71tac; 1tA71pocpoplEc; 1tcx vex 1tat0Gai 7] cxpµ60tcx cxpx Tj otL to µovtEAO 0tncx1toxp[vat0tt ottc; 1tpootcxyp0tcpEc; twv 1taptGwp[wv 3610 Ewe; 3624. (5) H 0tpµ60tcx cxpx Tj Gcx x op7JjTjOEL ~a~cx[wo71 (~A. 1tEp. 3 7 66 xcxt 3 6 79) 1to u vex moto1tota[ Ott to a1xExptµEvo µo­ VtEAO cxvt0t1toxp[vnott otcx 1taptGwpux 3610 Ewe; 3624. f. 'E jXpto71 tWV CX7tOOtOAWV (1) l10Au1tAwpac; .yxpiouc; cx1totttOUVtCXL 1tcx t71v cx1tootOATj tWV E;Tjc; 0Ef11XtWV, • ex. AEµcxtcx tou tu1tou ~(M) µa ouvax Tj cx1toouµ1tla07J, B. Mµcxtex tOIJ tU7tOIJ B(M) tWV pcxoto-avapywv OUOtWV twv 01toiwv 71 6pcxot71pt6t71t0t aivcxt otvwtap71cx1t63 X 103 Al ~ 3 X 103 A2 cxvo:Ao1cx µa t7]V 1tapi1ttwo71 Tj 1110 TBQ (3 X 104 Ci) OtVIXAOjCX (LE CXIJt'Tj tWV ttµwv CXIJtWV 7tOIJ aivcxt 7] mo µtxp'Tj tWV CXVWtEpwv ttµwv. i. Mµcxtcx t71c; auax Lat71c; XAIX07Jc; II ouµcpwvcx (LE to 1tapt­ Gwpto 3620. o. Mµcxtcx t71c; auox Lot71c; XAIXO'J]c; III M[cx cxpµoOLot cxpx Tj oµwc; µ1topa[ µa EtOtXTj OtlXtOt;7] trjc; .yxptttXTjc; t71c; ~a~cxiwo71c; vex amtpE7tEL t'J]V µatcxcpopix oto iocxcpoc; t71c;, x.wpic; 1tpo71,ouµav71 EjXpto71. (2) H 0tit71071 t71c; EjXpto71c; t71c; cx1tootOATjc; 1tpE1tEL vex cxvcx­ CflEpat: ex. T71v 1tap[ooo jLCX t1jV 01toi0t 7] EjXpto71 t71c; CX7t00tOATjc; ,71 taitCXL. ~. To 1tpcxyµcxttx6 1taptax 6µavo, tov tu1to .tou OX,Tj(J.CXtoc; xcxt to 1tpotcxGEv Tj mGcxvo opoµoA61to. 1. l1wc; Gcx 1tpcx1µcxto1totouvt0tL 1tpocpu)..ix;Etc;, tOt (J.Etpcx Xottcit trJV µatcxcpopii XotL touc; EtOtxouc; OtoLX7Jttxouc; EAEjX,OIJc; 7t01J 1tpo~AE1tOvtCXt Otte; ayxptttxEc; ~E~OttWOEtc; 7t01J x.op71,ou­ VtCXt OUfl(flWVCX flE tQ( 7teptGWptCX 36 73 XCXt 36 7 4. 3. Mt,cx Xott a,xpivatCXt 71 CX7tOOtOATj·7] otpµo~LCX cxpx Tj 6ot x.o­ p7jjTjOEL µt0t ~a~cxiwo71 (~A. 1taptGwptot 3677 Ewc; 3679). ( 4) Ot ~.~cxtwoatc; ax rnxic; µa tot OE(J.ottCX XCXt µa tTJV CX7tO­ OtOATj µ1topouv vex OUVOIJIX~OV'tott OE µicx µovov ~a~0tiwo71. A. 'E1xpto71 µtcxc; µatotcpopiic; µa uotxo OL0txotvovtoµ6. ( 1) Mt0t CX7tOOtOATj p0toto-avapywv OUOtc;;V 7t01J OE\I CXVtot7tO­ xpivatCXL a' 6)..ac; ttc; acpotpµootiac; Otottix;uc; tou 1totp6vtoc; xa­ cpotAotiou 6av 1tpi1tat vex µatcxcpipatcxt 1tcxpii µovov µa atotx6 6tot­ xcxvovtoµo 1tcx tov 01toio µtcx 1toAU1tAwp71 EjXpto71 1tixvtot CX7totttEltOtt. 0 EtOtxoc; OlCXXCXVOVtoµoc; 1tpi1tat Vat a;cxocpCXAi,aL OtL 71 ,a­ VtXTj CXO(fllXAEtCX XCXtOt t'J]\I f1Etcxcpop1X OEV Gcx aivcxt (ltXpotep'J] CX1t' 6, tL Gcx Tjtotv otv Gcx aix cxv t71p71Gai 6)..ai;; ot acpcxpµootiac; otcxtii­ ;atc; tou 1tcxp6vt0c; xacp0tAcxiou. (2) H cx[t71071 t71i;; EjXpto71c; 1tpi1tat vOt 1taptix at tti;; CX7totttou­ µavac; 1tA71pocpopiac; twv 1tapt6wpiwv 3672 xott 3675 xcxt 1tpE 1tat rn[o71c;: ex. vex 0tvotcpEpEL oa 1toto (J.Etpo xcxt 1tcx 1toiouc; )..61ouc; 71 ot1to­ otOATj 6av 'µ1topai vex 1ivatotL µa 7tATjp7] cxvtcx1t6xpto71 one; acpcxpµootEac; OLottix;uc; tou 1tcxp6vtoi;; xacp0tAcx[ou. ~- Ncx cxvcxcpapGouv ot 1tpocpuAii;atc; xcxt tcx atotxii µitpot 1tou 6ot 1tpi1tEL vex A7jcpGouv Tj Ot at6txoi OtotX7]tLXO[ EAEjX,Ot 7tOU ecx 1tpE1tEL vex rivouv XCXtlX t7]V µatotcpopix jtCX \IQ( CXVttcitot6µtotei 71 µ71 t'Tjp71071 twv acpcxpµoatEWV otcxtiit;awv tou 1totp6vtoc; xacpcx­ Acxiou. (3) Acp' OtOU EjXpt6ai O u1itxoc; OtCXXotVO\ILO(J.Oc;, 7] cxpµoOLCX otp;(Tj ecx XOP7J~OEL µicx ~E~CXLW07J (~A. 1tapt8. 3677 EWc; 3679). 3674 3675 3676 E. EyxptttxEc; ~E~OtLWOetc; trjc; cxpµootcxc; cxpx'Tjc;, 1. L7](J.Etwµcxtex tWV CXVCXjVWptotLXWV otmxalwv 1t0\) xo­ p7jjOUVtott CX7t0 t'J]V cxpµoOLCX CXPX'Tl· (1) Kii0E a,xpttLXTj ~.~cxiwo71 7t01J xop71,aitott CX7t0 otpµo­ OLCX otpx;ij ecx 1tpE1tEL vex cxvcxyvwpi,etotL 0t' CX\lotjVC.UptotLXOU OtOLXELOIJ. Auto to cxvcxyvwptottxo ototxaio 1tcxpouotix,atotL u1to t71v a;Tjc; jEVtXTj µopcpTj. LU(J.~OAO t71c; IJ7t7]XOOt7Jt0tc; t71c; xwpotc; 6) cxpt0µ6c; / XWOL­ xoc;. 6. Tix av AOjW OTjfJ.IXtCX Eivott Ol!Xxpmxii OtOLXElCX tWV ox11 µiitwv ot71 otaGVTj xuxAocpopicx. ot. 0 ixpt0µoc; ecx xop71j7j8ai ot7t0 t'J]V cxpµootot IXPX'Tj, l1pi1tat vex ELVotL µovot6txoc; XCXL u6txoc; jLot EVIX oaooµivo µovtEAO Tj jLIX µ[ex oaooµiv71 ot7tOOtOATj, To otVotjVWptottXO ototxaio t71c; i 1xpto71c; t71c; ot7tOOtOATjc; 1tpE1tEt vat totuti,atott auxoAot µa axaiv71 t71c; i 1xpto71c; tou µovtEAou tou 6Eµottoc;. ~- Ot a;Tjc; xwotxac; ecx XP7JOL(J.07tOLOUVtlXL µa t7]V a;ijc; oatpix jLIX Vat OEl;(VOUV touc; t\.l7tOUc; tWV EjXptttXWV ~E~CXLWOEWV 7tOU xop7JjOUVtlXL, A. MovtEAO OE(J.ottoc; tOU tU7tOU A ( OtCXV a1tio71c; XP7JOLf.l0 7tOLEl'tCXL OE ouvouotoµo we; OE(J.ot t71c; auoxtot71c; XA0to71c;. B.(U) MovtEAO tOU oiµixtoc; tOU t\.l7tOU B(U). B(M) MovtEAO tOIJ OE(J.IXtOc; tOU tU7tOU B(M). F MovtEAO t01J OE(J.IXtOc; t71c; auox tot71c; XAIXO'J]c;, S 'E1xpto71 twv UAtxwv u1t6 atOLXTj µopcpTj, T A,:i:ootoATj, X Etotxoc; OLotXotVOVtoµoc;. (2) Ot XWOLXOi CXIJtoi ecx acpotpµo~ovtcxt we; a;Tjc;: ex. Kii0a ~E~CXLW07] XIXL xii0E OE(J.CX Got CflEPEL to XottlXAA'J]AO cxvcxyvwptottx6 ototx;aio ix1totaAouµavo ot1t6 ouµ~oAcx t71c; 1tix­ pcx1piicpou (1) axtoc; ot71v 1tapi1ttwo71 twv 6aµixtwv 01tou 7J 6autap71 ayxixpotot ,pixµµij 0ot CXXOAou0ai µovov tOV XWOLXO tOU f.1.0\ltEAOU tOU oiµcxtoc;. Ma ii:Uac; AE~atc; tCX jpixµµixtcx «S», T» ij «X» oav ecx aµcpcxvto0ouv Oto CX\lotjVWptO'ttXO OtOL­ xEio toU OEfJ.CXtoc;. Av 71 EjXpto71 tou µovtEAOU tou llEµottoc; xcxt 7] EjXpto71 t71c; ot1tootOATjc; yivovtcxt ourx.povwc; oav Got aivott ix1tcxpotit71to vex E7tot\lCXA7]cp0ouv Ot XWOlxoi 1t-X· A/132/B(M) F Mµottot t71c; auax tot71c; xAixo71c; B(M) ayxaxptµEV7J ot1to t7111 Auotpiot 1 tcx to µovtiAo tou Mµixtoc; exp. 132 (1tpi1taL rn[07Jc; vix cxvot1piitcpatott totutoXPOVot oto ioto to OE(J.ot Xott Ot'J]V EjXpttLXTj ~.~cxiwo71 tOU µovtEAOU tOIJ oiµix­ toc;). A/132/B(M) FT. AvcxrvwptotLXO ototxaio t71c; EjXpLtL­ XTjc; ~a~cxiwo71c; jL' otuto to µovtiAo oiµottoc; ( 1tpE1tat vex cxvix­ ypiitcpatcxt µovo ot71 ~a~cxiwo71). A/ 13 7 /X. AvixrvwptotLXO OtOL;(ElO t71c; a,xptttx'Tjc; ~a­ ~ixiwo71c; )(Op7]jOU(J.EV7Jc; jLIX to µovtEAO 137, a,xaxptµiV7Jc; • ix1to t7]V Auotpiix µa 0xo1t6 µtcx ot1tootOATj u1toxaiµav71 oa at 6tx6 OLIXXCXVOVtoµo ( 1tpE1tEt vex IXV1Xjp1Xcpal µovov Oto Ejjpotcpo ). B. Av 71 1tOAU1tAwp71 EjXpto71 1tcxipvat t71v µopcpTj µtcxc; am­ xupwo71c; µovov tCX CXVotjVWptottXIX OtOLXELCX xop71,ouµavcx ot7t0 t'J] xwpcx 1tpOEAEU07Jc; t01J µovtEAOU Tj t71c; ot7tOOtOATjc; ecx XP7JOLfl07tOL7]GOuV. Av 7] 7tOAU7tAEUp7] EjXpto71 amcpEpat t1j xo­ pTjj7J07] ~E~ottWOEW\I IX7t0 ttc; OtcxooxtxEc; xwpac; xix0a ~a~oti­ W07J eix cpEpet to XIXtlXAA7]AO OtOLXElO XotL to OEflot tou 07tOLOU to µovtiAo ayxpi071xa µa ixut6 tov tp61to, 0cx cpipat 6)..cx tot xcx­ t1XAA7JAIX ixvcxrvwptottxii ototxaiix 7t,X, (A/132/B (M) F) (CH/28/B(M) F) 0ix TjtlXV tlX CXVIXjVu>ptotLXIX ototxaiix avoc; 0Ef11Xtoc; 7t0U Otp­ XLXIX ayxpi071xa ix1t6 t71v Auotpiet Xott 0tp16tap0t 0t1to tTJV EA­ ~atiet µa VEOt EjXpto71. Tet ouµ1tA71pwµotttxii OtVOt)'VWptottXIX OtOLXEiot 0ot Ot1t0tpt8µi,ovt0tv µa tOV ioto tp61to Oto oiµet. 1. H rn0tv0t8awp7107J avoc; 0tpt8µou ~a~ottwoawc; 0ot 0tv0tcpap 8ai µa f.lLOt Excppixo71 avtoc; 1t0tpav8foawv 1tou 80t 0txoAou8TjoEL to OtVOtjVWptottxo ototx;aio 1tou 0cx ~piaxatott ot71 ~a~0tiwo71. 'Etot A/132/B(U)F (REV.2) 0ot otvOtcpEpat OtL 1tpoxatt0tt jtOt tTJV 0tvot8awp7107J u1t' exp. 2 t71c; ~a~0tiwo71c; tou µovteAou OE­ µ0ttoc; a1xaxptµEvou 0t1t6 trJV Auotpiot XOtt A/132/B(U) F (REV.O) Gcx 07J(J.OtL\IEl OtL 1tp6xm0tt jLot tOV 0tpxtx6 0tpt8µ6 1271 3677 1272 ECl>HMEPII: THI KYBEPNHI:EQI: (TEYXOI: LlEYTEPO) TI)<; /3E/3otiw07jc:; ,:ou µonH.ou i:ou EjXExpLfLEIIOU otmi 1:1111 Au 01:piot. fLot 'tO\I otpXLXO otpL0µo TJ EXq>potOTj E\l'toc:; 7totpE110EOEW\I (REV.O) 6E11 EL\lotLtl1tOXPEW'tLX7j. M1topouµE E7tLOTjc:; \lot XPTJOL­ fL07tOLTJOOUfLE CXAATJ EXq>potOTJ 7t.x, «otPXLXO otpL0µo» E\lot otpL0µo /3E/3otiw07jc:; 1tou EXEL ot11ot8Ewp1j8Ei XotL µ1topEi \lot xopTJjTJ0Ei µ011011 ot7t0 TI) xwpot 7tOU Sot EXEL Ex6ooEL 'tO\I otpXLXO otpL0µo. 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TJ) 'EAET;(Oc; 'tTjc; 7t0tO'tTj'texc; 'tTjc; xex'tlXOXEUljc; xext 01JV't'TjpTJ­ OTjc; 'tWV 01JOXWIXOtWV. 0 xex,exoxatiexo,11c;, 0 ex1tOO'tOAEexc; 11 07tOL000117tO'tE XPTJOt• µ01t0Ld µiex ouaxau1Xoi1X qxExptµivou µoniAou, 1tpi1tat VIX ai­ VIXL OE OfoTj VIX IX7t00El!;Et OE xcx0a expµooLex 1Xp;(lj, O'tl IX. OL µiBooOL XIXL 'tex UALX<X 7t01J XPTJOlf1-07tOLOUV'tlXt rtex 'tT}V xex'texOXW11 'tTjc; OlJOXEUexoiexc; ELVIXL OIJ[-1-CfiWVEc; [-1-E 'tlX ETXEXpl• µev1X xpt,11pL1X rtex ,o µoniAo. H expµo6L1X 1XPX11 µ1topEi vex 1tpo[3Ei OE EAirxouc; 'tT}c; auoxwcxoim; xcx,ci 'tTJV xcx,cx­ oxw11, [3. 'OAEc; Ol 01JOXE1JOtOLEc; 7t01J xex'tCXOXWCX~OV'tlXt ouµcpwvcx µa qxExpLµivo µov,aAo OLex'tTJpouncxt oE XOtA 11 x0t,cxo,1X07J, won VOt 01JYE;(l001JV VOt 7tA7JpOuv OAOt 'tex acpcxpµoo'tEIX xpt,11ptcx ouµ­ cpwvex µa 'tOV XIXVOVLoµo CXXOµTj XOtl µa,CX CX7t0 E7tOtVEtATj[J-µEVTJ XP11°TJ· 1273 3683 3684 3685 3689 ..... ~ J ~ I 3690 T1-1711-1cx VI - optcx 6pcxo't'l)ptoTI)'tO<; - xcxOopto!,10<; 'tOU Al xcxt A2 1. KcxOcxpii Pcx6tovou0.at6tcx 1) 0 1tivcxxcx<; n 6i6at 'tt<; 'ttp.t<; Al xcxt A2, 11cx 'tCX xcxOcxpii pcx6w-voux)..at6tcx 'tWV omowv cxvcx"l"'wptG'ttXIX G'tOtXEicx ('tcxu'tOTI)<;) aivcxt "t"'W<J'tot. Ot 'tl!,LE<; A 1 XCXl A2 aq,cxp1-10~0V't(Xt £1tio71<; <J't(X pa.OLO-VOUXAElOlCX 7t0U 1tEpttXOV't(Xl G'tl<; 1t7\1'E'i vnpoviwv ( ex, 71) 71 ( r' 71). mva.xa.<; Y:t.· Ttµic:; 'tOU Al XCXl A2 1'l<X 't(X pcxOLOVOUl<AElOl(X. LU!,1(10AO 'tOU A'tOµtxoc:; Al i\ Et6tx71 6pcx<JTI)ptoTI)'tCX Ii Pa.6tovouxAi;i:6iou cxpt61-1oi; xa.~ G'tOlXELO TB (Ci) TB (Ci) TBq/g (Ci/q) q q s: 227 Ac Ax'ttVtO (89) 37 1000 1,llxl0--4 0,003 2,7x10-1 7,2Xl0 m ,, 228 Ac 0,37 10 0,15 4 8,lxl04 2,2xl06 M' 105 Ag 'Ap1upoc:; (4 7) 1,48 40 1,48' 40 1,2xl03 3,1Xl04 -+ 110m Ag 0,26 7 0,26 7 l,7xl02 4,7xl03 :::c M 111 Ag 3,7 100 3,7 100 5,9xl03 l,6xl05 " 241 Am A1-1apixto (95) 0,3 8 3xl0-4 0,008 1,2x10·2 3,2 -< m 243 Am 0,3 8 3xl0-4 0,008 7,0xl0-3 1,9Xl0;1 m ,, 37 Ar ( auµmi;o1-1ivo z 71 1-171 ouµmEG!,LEVO Ano (18) 37 1000 37 1000 3,7xl03 1,0xlOS :::c M 41 Ar (µ71 <JU!,17ttECJp.tVO 0,74 20 0,74 20 l,6Xl06 4,3Xl07 m IO 41 Ar ( CJU!,17ttE<J!,1EVO) 0,74 1 0,04 1 l,6xl06 4,3xl07 M 73 As Apoavtxo (33) 37 1000 14,8 400 8,9xl02 2,4Xl04 '=i 74 As 0,74 20 0,74 20 3,7xl03 1,0xl05 m < 76 As 0,37 10 0,37 10 5,9xl04 l,6Xl06 X 0 77 As 11,1 300 11,1 300 4,lxl04 l,lxl06 M 211 At Ao'tcx'to (85) 7,4 200 0,26 7 7,8xl04 2,lxl06 t> m 193 Au Xpuo. (79) 7,4 200 7,4 200 3,4xl04 9,3xl05 ~ 196 Au 1,11 30 1,11 30 4,4xl03 l,2Xl05 m 198 Au 1,48 40 1,48 40 9,3xl03 2,5Xl05 ,, 0 199 Au 7,4 200 7,4 200 7,8xl03 2,1Xl05 131 Ba Bdtpto (56) 1,48 40 1,48 40 3,2xl03 8,7Xl04 133 Ba 1,48 40 0,37 10 1,5xl0 4,ox102 140 Ba 0,74 20 0,74 20 2,7xl03 7,3xl04 7 Be B71puUt0 (4) 11,1 300 11,1 300 l,3xl04 3,5xl05 206 Bi BtoµouOto (83) 0,19 5 0,19 5 3,7xl03 9,9xl04 207 Bi 0,37 10 0,37 10 8,1 2,2xl02 '-, mVOtxoo; XX (aUVEX£tCXf :Euµ~oAo 'tOU A'tO(.lLXOc;; Al Pcx6wvouxMi6iou cxpt0µoc;; XCXL CJ'tOLXElO TB (Ci) q 210 Bi (RaE) Btaµou0LO (83) 3,7 100 (auvixucx) 212 Bi 0,22 6 249 Bk M1tepxEALO (97) 37 1000 82 Br Bpwµw (35) 0,22 6 14 C cxv0pcxxcxc;; (6) 37 1000 45 Ca A~!Cl'tLO (20) 37 1000 47 Ca 0,74 20 109 Cd Kcx6µw (48) 37 1000 115m Cd 1,11 30 115 Cd 2,96 80 139 Ce I\T)(.l7l'tpLO (58) 3,7 100 141 Ce 11,1 300 143 Ce 2,22 60 144 Ce 0,37 10 249 Cf KCXAupop\lLO (98) 0,08 2 250 Cf 0,26 7 252 Cf 0,08 2 36 Cl XAwpw (17) 11,1 300 38 Cl 0,37 10 242 Cm Kwupto (96) 7,4 200 243 Cm 0,33 9 244 Cm 0,37 10 245 Cm 0,22 6 246 Cm 0,22 6 56 Co Ko~<XA'tLO (27) 0,19 5 57 Co 3,33 90 58m Co 37 1000 58 Co 0,74 20 60 Co 0,27 7 51 Cr Xpwµw (24) 22,2 600 131 Cs KcxiaLO (55) 37 1000 134m Cs 37 1000 134 Cs 0,37 10 • ., "' A2 TB (Ci) q 0,15 4 0,22 6 0,04 1 0,22 6 3,7 100 1,48 40 0,74 20 2,59 70 1,11 30 2,96 80 3,7 100 7,4 200 2,22 60 0,26 7 7,4xl0·5 0,002 2,59xl04 0,007 7,4xl0·5 0,002 1,11 30 0,37 1 i,2 7,4xl0·3 3,33xl04 0,009 3,7Xl04 0,01 .2,22xl04 .0,006 2,22xl04 0,006 0,19 5 3,33 90 37 1000 0,74 20 0,26 7 22,2 600 37 1000 37 1000 0,26 7 Et6tx71 6paCJ'tTjpLo'tTj'tCX TBq/g (Ci/q) 4,4xl03 l,2Xl05 5,6xl05 l,5xl07 6,7Xl0 l,8Xl03 4,lxl04 l,1Xl06 l,7xl0·1 4,6 7,0xl02 l,9xl04 2,2Xl04 5,9xl05 9,6Xl0 2,6xl03 9,6Xl02 2,6xl04 l,9Xl04 5,lxl05 2,4xl02 6,5xl03 l,Oxl03 2,8xl04 2,4xl04 6,6Xl05 l,2xl02 3,2xl03 1,2x10·1 3,1 4,8 l,3xl02 2,4Xl0 6,5xl02 l,2xl0·3 3,2xl0·2 f:~~l8: l,3xl08 . 3,3xl03 1,6 4,2xl0 3,0 8,2Xl0 .3,7xl0·3 1,ox10·1 3,7x10·2 3;6xlQ·1 l,lxl03 3,0xl04 3,lxl02 8,5xl03 2,2Xl05 5,9xl06 l,2Xl03 3,lxl04 4,lxlO l,lxl03 3,4Xl03 9,2Xl04 3,7Xl03 1,0Xl05 2,7xl05 7,4x106 4,4xl0 l,2Xl03 m e :::c ~ m ""Cl M f :::c M " -< to m ""Cl z :::c M m :0 M "=i m < X 0 M t> m ~ m ""Cl g ...... N) .j (,n ...., t-:i 1 °' I mvcxxcxi; XX (auvixeLot) I:uµ~oAO 'tO1J A'tOµtxoc:; Al ,\ Et6tx~ 6potO't'fjpto't'l)'tot Pcx6tovouxAe'i6iou cxpt0µoc:; xcxt a'totxeio TB (Ci) TB (Ci) TBq/g (Ci/q) q q 135 Cs Kcxiato (55) 37 1000 2,22 60 3,3xl0·5 8,8xl04 (auvixetot) m 136 Cs 0,26 7 0,26 7 2,7Xl03 7,4xl04 e 137 Cs 1,11 30 0,34 9 3,6 9,8Xl0 J: s: 64 Cu XCXAxoc:; (29) 2,96 80 2,96 80 1,4X105 3,8xl06 m 165 Dy i\ta1tpoato (66) 3,7 100 3,7 100 3,0Xl05 8,2Xl06 .,, 166 Dy 37 1000 7,4 200 8,5Xl03 2,3Xl05 M 169 Er 'Ep~to (68) 37 1000 11,1 300 3,0xl03 8,2Xl04 -I 171 Er 1,85 50 1,85 50 8,9xl04 2,4xl06 J: M 152m Eu Eupwmo (63) 1,11 30 1,11 30 8,1Xl04 2,2xl06 ,. 152 Eu 0,74 20 0,74 20 7,0 l,9xl02 -< 154 Eu 0,37 10 0,19 5 5,6 l,5x102 m m 155 Eu 14,8 400 3,33 90 5,2Xl0 1,4Xl03 .,, 18 F <I>0opto (9) 0,74 20 0,74 20 3,4Xl06 9,3Xl07 2 52 Fe I:i671po~ (26) 0,22 6 0,22 6 2,7xl05 7,3Xl06 J: M 55 Fe 37 1000 ,37 1000 8,lXlO 2,2xl03 m 59 Fe 0,37 10 0,37 10 l,5Xl03 4,9xl04 :0 72 Ga fcxUto (31) 0,26 7 0,26 7 l,1Xl05 3,lxl06 M 153 • Gd fo6o;l.ivto (64) 7,4 200 3,7 100 1,3xl02 3,6Xl03 '=i m 159 Gd 11,1 300 11,1 300 4,1Xl04 l,lxl06 -< 71 Ge fepµlivto (32) 37 1000 37 1000 5,9Xl03 l,6Xl05 X 3 H Y6porovo (1) 0 M m,.T-Tpt'tto t> 181 Hf Aq,vt0 (72) 1,11 30 1,11 30 5,9xl02 l,6Xl04 m 197m Hg Y6pliprupoc:; (80) 7,4 200 7,4 200 2,4xl04 6,6Xl05 -< -I 197 Hg 7,4 200 7,4 200 9,3xl03 2,5Xl05 ·m 203 Hg 2,96 80 2,96 80 5,2x102 l,4Xl04 .,, 166 Ho OAµto (67) 1,11 30 1,11 30 2,6xl03 6,9Xl05 .Q 125 I Iw6to (53) 37 1000 2,59 70 6,3xl02 1,7xl04 126 I 1,48 40 0,37 10 2,9xl03 7,8xl04 129 I 37 1000 7,4xl0·2 2 5,9xl0-6 l,6Xl04 131 I 1,48 40 0,37 10 4,4xl03 l,2xl05 132 I 0,26 7 0,26 7 4,lxl05 l,lxl07 133 I 1,11 30 1,11 30 4,lxl04 l,1Xl06 134 I 0,3 8 0,3· 8 l,0xl06 2,7Xl07 "' • Tiivixxoo; XX (ouvix atix) :Euµ~oAO 'tOU Atoµtxo<;; Al A2 faOtXTj Op<Xo'tTjptO'tTj't<X P<XOtOVOUXAai:o[ou ixptOµo<;; X<Xl O'tOtX,Eio TB (Ci) TB (Ci) TBq/ (Ci/q) q q g 135 I Iwow (53) 0,37 10 0,37 10 l,3xl05 3,5xl06 ( OUVEX,El<X) 113m In Ivow (49) 2,22 60 2,22 60 5,9xl05 1,6xl07 114m In 1,11 30 0,74 20 8,5xl02 2,3xl04 115m In 3,7 100 3,7 100 2,3xl05 6,lxl06 m 190 Ir lptOlo (77) 0,37 10 0,37 10 2,3xl03 6,2xl04 ~ 192 lr 0,74 20 0,74 20 3,4Xl02 9,lxl03 ~ 194 lr " 0,37 10 0,37 10 3,2Xl04 8,5xl05 m 42 K Kcill (19) 0,37 10 0,37 10 2,2Xl,05 6,0xl06 :E 85m Kr (M71 ouµ1mmoµivo) Kpu1ti:o (36) 3,7 100 3,7 100 3,lxl05 8,4xl06 M 85m Kr (ouµ1tamaoµivo) 0,11 3 0,11 3 3,lxl05 8,4xl06 :i 85 Kr (M71 ouµ1tamaoµivo) 37 1000 37 1000 l,5Xl0 4,0xl02 M 85, Kr (ouµ1tamaoµ"ivo) 0,19 5 0,19 5 l,5Xl0 4,0xl02 " 87 Kr (M71 ouµ1tamaoµivo) 0,74 20 0,74 20 l,0X106 2,8><107 -< 87 Kr (ouµ1tamaoµivo) 0,02 0,6 0,02 0,6 l,0X106 2,8xl07 ~ 140 La Aixvocivto (57) 1,11 30 1,11 30 2,1Xl04 5,6xl05 "'C LLS (:Ei:apaci UAlXCX, µLxp7J<;; op<Xoi:71- ~ plO'tTj'tO<;;) M ~A. 1taplOwpw 2100 (2) ~ LSA (TI.Lxci µLXpTJ<;; ElOtXTj<;; opixo'tTj- M ptO'tTj'tO<;;) ~A. 1tapl8wplo 2700 (2) rri 177 Lu Aou'tTJi:lo (71) 11,1 300 11,1 300 4,lxl03 l,lxl05 -< MFP Mairµix 1tpoi:ovi:ix ox.cioaw<;; 0,37 10 0,015 0,4 ~ 28 Mg Mix-yv11olo (12) 0,22 6 0,22 6 l,9xl05 5,2xl06 M 52 Mn Mixncivw (25) 0,19 5 0,19 5 l,6Xl04 4,4xl05 t> 54 Mn 0,74 20 0,74 20 3,1Xl02 8,3xl03 ~ 56 Mn 0,19 5 0,19 5 8,lxl05 2,2xl07 -4 99 Mo MoAu~oixivw (42) 3,7 100 3,7 100 l,7xl04 4,7xl05 ~ 22 Na Ncii:pto (11) 0,3 8 0,3 8 2,3xl02 6,3Xl03 O 24 Na 0,19 5 0,19 5 3,2xl05 8,7xl06 93m Nb NLo~t0 (41) 37 1000 37 1000 4,lxl0 l,lxl03 95 Nb 0,74 20 0,74 20 l,4xl03 3,9xl04 97 Nb 0,74 20 0,74 20 9,6Xl05 2,6Xl07 147 Nd Naoouµw (60) 3,7 100 3,7 100 3,0Xl03 8,0xl04 149 Nd 1,11 30 1,11 30 4,lxl05 l,lx107 >-' Nl ., -.J .J ~ 1-..:l :i (X) I Ilivotxot,; XX ( auVE)(Etot) Luµ~oAo 'tOU A-coµtxo,; Al A2 Et6tx~ 6potaTI)pt6TI)~ot Pcx6wvouxAEi:6iou otpt8µ6,; Xott O'tOt)(ElO TB (Ci) r TB (Ci) TBq/g (Ci/q) q q 59 Ni NtxiAto (28) 37 1000 33,3 900 2,3x10-3 8,1 x10-2 63 Ni 37 1000 3,7 100 1,7 0,46xl02 65 Ni 0;37 • 10 0,37 10 7,0xl05 1,9 xl07 m 237 Np NE7t'tOU\ltO (93) 0,19 5 l,85xl0-4 0,005 2,6xlo-s 6,9 xl0-4 e :I: 239 Np 7,4 200 7,4 200 8,5xl03 2,3 Xl05 s: 185 0s Oaµto (76) 0,74 20 0,74 20 2,7xl02 7,3 Xl03 m 191 0s 22,2 600 14,8 400 l,7xl03 - 4,6 xl04 :2 191m 0s 7,4 200 7,4 200 4,4xl04 1,2 xl06 M 193 Os 3,7 100 3,7 100 2,0xl04 5,3 xl05 -f 32 p cpwacpopo,; ( 15) 1,11 30 1,11 30 l,lxl04 2,9 Xl05 :I: M 230 Pa 1tpOX'totX'tl\ltO (91) 0,74 20 0,03 0,8 l,2Xl03 3,2 xl04 " 231 Pa 0,07 2 7,4x10-5 0,002 l,7xl0-3 4,5 x10-2 -< 233 Pa 3,7 100 3,7 100 7,8xl02 2,1 xl04 m m 210 F'b M6).u~6o,; (82) 3,7 100 0,007 0,2 3,3 8,8 XlO "'ll 212 Pb 0,22 6 0,22 6 5,2xl04 1,4 xl06 2 103 Pd Ilill<i6to (46) 37 1000 25,9 700 2,8Xl03 7,5 xl04 :I: M 109 Pd 3,7 100 3,7 100 7,8xl04 2,1 xl06 m 147 Pm Ilpoµ~8to (61) 37 1000 2,96 80 3,5Xl0 9,4 xl02 :0 M 149 Pm 3,7 100 3,7 100 l,6xl04 4,2 xl05 "=i 210 Po IloAwvto (84) 7,4 200 0,007 0,2 1,7xl02 4,5 Xl03 m 142 Pr Ilpotaeo6uµto (59) 0,37 10 0,37 10 4,4xl04 1,2 Xl06 -< 143 Pr 11,1 300 7,4 200 2,4xl03 6,6 xl04 X 191 Pt AEUXO)(pUOO<; (78) 3,7 100 3,7 100 8,5xl03 2,3 xl05 0 M 193 Pt 7,4 200 7,4 200 7,4xl03 2,0 Xl05 t> 197m Pt 11,l 300 11,l 300 4,4xl05 1,2 xl07 m 197 Pt 11,1 300 11,1 300 3,3xl04 8,8 Xl05 -< f 238 Pu IlAOU'tW\ltO (94) 0,11 3 l,llxlO 0,003-4 6,6Xl0 1,7 x10-1 m 239 Pu 0,07 2 7,4x10-5 0,002 2,3xl0-3 6,2 x10-2 "'ll 240 Pu 0,07 2 7,4x10-5 • 0,002 8,5xl0-3 2,3 x10-1 .9 241 Pu 37 1000 0,004 0,1 4,1 1,1 x102 242 Pu 0,11 3 1,llxl0-4 0,003 l,4xl0-4 3,9 Xl0-3 223 Ra P<i6to (88) 1,85 50 0,007 0,2 1,9xl03 5,0 Xl04 .. Tiivotx~ XX (auviXEtot) LUfL~OAO TOU AToµtxoc;; Al A2 Pot6tovouXAEI6lou otpt0fLoc;; xott aTOlXEio TB (Ci) TB (Ci) q q 224 Ra Pcx6to (88) 0,22 6 0,02 0,5 ( auvix Etot) 226 Ra 0,37 10 0,002 0,05 228 Ra 0,37 10 0,002 0,05 86 Rb Pou~i0to (3 7) 1,11 30 1,11 30 87 Rb AnEptoptaTTj A7tEptoptaTTj A1tEptoptOTTj A1tEptoptaTTj Rb ( cl>uatxo) AnEptoptCJTTJ A1tEptoptaTTj AneptoptOTTj AneptoptaTTj 186 Re Privto (75) 3,7 100 3,7 100 187 Re A1tEptoptaTTj AnEptoptaTTj A1tEptoptaTTj A1tEptoptaTTj 188 Re 0,37 10 0,37 10 Re ( el>uatxo) AnEptoptCJTTJ A7tEptoptaTTj A1tEptoptOTTj A1tEptoptaTTj 103m Rh Po6to (45) 37 1000 37 1000 105 Rh 7,4 200 7,4 200 222 Rn • Pot6ovto (86) 0,37 10 0,07 2 97 Ru Pou0rivto ( 44) 2,96 80 2,96 80 103 Ru 1,11 30 1,11 30 105 Ru 0,74 20 0,74 20 106 Ru 0,37 10 0,26 7 35 s 0do (16) 37 1000 11,l 300 122 Sb AvTtfLWYto (51) 1,11 30 1,11 30 124 Sb 0,19 5 0,19 5 125 Sb 1,48 40 1.n 30 46 Sc Lxcxv6to (21) 0,3 8 0,3 8 47 Sc 7,4 200 7,4 200 48 Sc 0,19 5 0,19 5 75 Se LEAT)Yto (34) 1,48 40 1,48 40 31m Si. ITupt1:to (14) 3,7 100 3,7 100 147 Sm faµcxpw (62) A1tEptoptaTTj AnEptoptaTTj A1tEptoptOTTj A7tEptopta'tlj 151 Sm 37 1000 3,33 90 153 Sm 11,1 300 11,1 300 113 Sn KotaahEpoc;; (50) 2,22 60 2,22 60 125 Sn 0,37 10 0,37 10 85m Sr L'tpOY'tto (38) 2,96 80 2,96 80 85 Sr 1,11 30 1,11 30 87 Sr 1,85 50 1,85 50 Et6tx1) 6potCJ't'JjptOTTjTot TBq/g (Ci/q) 5,9xl03 l,6xl05 3,7x10-2 1,0 8,5 2,3xl02 2,3xl03 8,1Xl04 2,4x10-9 6,6Xl0-B 6,7x10-10 l,8xl0-B 7,0xl03 l,9Xl05 l,4x10-9 3,8xlQ-B 3,7xl04 l,0xl06 8,9x10-10 2,4xl0-B l,2xl05 3,2xl07 3,0xl04 8,2xl05 5,6Xl03 l,5Xl05 2,0xl04 5,5Xl05 l,2Xl03 3,2xl04 2,4xl05 6,6xl06 l,3xl02 3,4Xl03 l,6xl03 4,3xl04 1,4Xl04 3,9xl05 6,7xl02 l,8xl04 5,2xl0 l,4Xl03 l,3xl03 3,4xl04 3,0xl04 8,2Xl05 5,6xl04 l,5xl06 5,2x102 l,4Xl04 l,4xl06 3,9xl07' 7,4x10-10 2,0xlQ-B 9,6x10-1 2,6Xl0 l,6Xl04 4,4xl05 3,7xl02 l,0xl04 4,lxl03 l,1Xl05 1,2xl06 3,2xl07 8,9xl02 2,4xl04 4,4Xl05 l,2xl07 " E :c s: " -,:, ,.. z ,.. ~ < CD " -,:, 2 :c ,.. " ... ... ,.. " -< > C ,.. 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Ot emrpcxq,ic:; xt116uvou 7t01.) 1tpo~AE1COll'tlXt iLIX 'tlX UALXOt XIXt 'tlX 1X11,txelµe111X 'tWII xAdtoewv I ewe:; 8 ~AE7te' ou11711-1µi110 1tl 11cxxcx O'ljfJ.IXt\lOUII, Apt8. I (MiXUp'lj ~Ofl.~IX OE 7t0p'tOXIXAt (j)Oll'tO), U7tOXEt'tlXt O't'ljll EXpTj;'lj ( 1tpo~A. O'tlX 7tEpt0wptcx 2117 (I), 2145 XIXt 2563. Ap. 2 Au'toc:; 0 cxpt8µoc:; E7tL(j)UAOtOOE'tlXt O't'ljll EtXOIIIX 7t0U IX7tOOEXE'tlXt 6te811wc:; XOtt 7tOU IXll'tt1tpoow1teUEL q>t<XA'lj cxepiou OE 1tpdtoL110 q,611,0 oe mpi1t'tWO'lj fLEAAOll'ttXT}c:; XPTJO'ljc:;, Kcx1-11-1icx e1trypcxcp71 cpipouocx 1XU't7I 'tTjll etxo11cx 6e11 npo~AE7tt't1Xt 'tWpcx rtcx 'tlX UALXOt 'tTjc:; XA<XOT)c:; 2 'tOU ADR. • Ap. 3 (l\fcxup'lj <pAoycx OE XOXXt\10 (j)(Jll'tO 1tpo~Ae1t6f1.EIITJ O'tlX, 7tEpt0wptcx) 2312(1) 2479(2) 2612(3) XIXL 28}2(3) Klv6woc:; 1tupxcxrtdtc:; (peua't<X eu<pAEX'tOt uAtxdt). Ap 4.1 Mcxup'lj q,Mrcx OE q,611'tO IX7tO'tEAOUf,LEIIO 0t1t6 xix8e'tec:; iP~fLfLEc:; 1-1e l67J cx1too't1XOTJ µn1X;u 'touc:; e11cxUcxx'ttxix xoxx11171 xcxt Aeux71, 1tou 1tpo~Ai1tncxt o'to 1tEpt8wpto 2414(1) «xi116u-. 11oc:; 1tupxcxrtixc:;» (a'tepeix EV(j)AEX'tlX UAtxix). Ap 4.2. (Mcxup'lj (j)AOilX ae Aeuxo cp611'to 'tOU XIX'tW 'tPLiW• \IOU 't'lj<; emrpcx<pTjc:; XOXXL\10 ). Tipo~AE7tE'tlXL O'tO itept0wpt0 2443(14. 390] 3902 2225 E<DHMEPII: THI: KYBEPNHI:EQI: (TEYXOI: AEYTEPO) 1285 DLxo u1toxdµEvo oE ;cx<p11Lx71 Eii<pAE1;TJ. Ap 4.3 (McxupTJ q,Ab1cx oE µ1t).a <poll'to. Tipo/3Aa1tE'tlXL O'tO 1tEpt8wpto 24 79 (I). Kiv6uvoc; EX1toµ1t71c; EuqiAEX'tou cxEp[ou xcx,ci 't"lj\l E1t1X<p7J µE VEpo. Ap 5. (<l>Abycx E1tcivw IX1t0 XUXAO µcxup"lj OE xi,pLVO Cj)O't\10. Tipo/3Aa1tE,cxt o,cx 1tEpt8wptcx 2511(1) 2563(1) 2703 6Ehio 5 XIXl 2812(3). Avcx<pAEx,txo uAtxo 71 opycxvLxo U1tEpo;ai6Lo. Ap 6.I Kpcivoc; rnavw oa Buo o,cx µcxupcx E Aauxo q,ov,o, 1tpo/3Ai1ta,m o,cx 1tepL8wptcx 2312(2), 2612(1) xcxt 2812(3) To;Lx71 ouoicx vex cxn:oµowv0a[ 1X1to 6tcx,pocpac; 71 ci).).cx IXV'ttxEi­ µavcx 1tOU 1tpoopi,OV'tlXL j'llX XIX'tlXVciAWOTJ, O'tlX OX,7lfLIX'tlX, O'tOUc; X,Wpouc; cpop,WO"ljc;, 1;acpop'tWO"ljc; 7I µa,cxcpop'tWOTjc;. Apt0. 6. IA. :E,cxupoc; 'tOU A,. Av6pacx OE O'tlXX,U ohou µcxu­ pou 71 AEUXO <pOll'tO, 1tpo/3Aa1te't1Xl O'tlX mpt0wptcx 2312(2) XIXL 2612(2). B).cxf3ap71 ouo[cx. N ex cx1toµovw8ai cx1to 6Lcx,po<p71 o,cx ox.71 µcx,cx O'tOUc; X,Wpouc; <pOp'tWOTjc; 1;acpop'tWOTjc; 7I fLE'tlXCjlOp,w­ OTjc;. Ap. 6.2 Au,oc; 0 cxpt0µoc; amcpUAAIXOe'tlXl O'tO O'tl TJ 6ta8v71c; cx1to6ax,71 atxovcx 1tou cxv,01tpoow1teUEt avcx xuuo cpop,wµavo µa ,p[cx xpoucxociv oa 1tEpi1t,WOTJ µaAAOV'ttx71c; X,P7IO"ljc;, ~cxµicx amypcxcp71 cpapouocx CXU'tTJ 'tTJV ELxovcx 6av 1tpo/3Aa1tE'tlXL OTJfLepcx j'llX 'tCX UALXIX 't"ljc; XAIXOTjc; 6.2 'tOU ADR. Ap. 7 A (axTJµCX,Loeµvo ,ptcpUAl OTJ(,LdWOTJ RADIOAC­ TIVE - pcxOLo - EVepyo) µ[ex xci0e't'Tj ypcxµµ71 O'tO µtoo XIX'tW µapoc; fLE ,o E;71c; xEiµavo. Tiaptax.oµavo. .1p1XO't"ljpto't"lj'tlX. :Euµf,oAO XIXl OTjµeiWOTJ µa fLIXUpo Oe AEUXO cpOV'tO, xci0e'tTJ XOXXlVTJ j'p1Xµµ711tpo/3Ae1toµeV7J O'tlX 6eA'tLIX 5 awe; 12 'tOU 1te­ pt0wpiou 2 7 03, IXVIXAOj'IX µE 'tTJV 1tEpi1t'tWOTJ XIXl O'tO 1tepL8w­ pto 3656(1) (2) XIXl (3) p1XOLO - mpyo UAlXO OE 6i(,LIX'tlX 't"ljc; XIX'tTJj'OpilXc; I - AEux71, aE 1tEpi1t'tWOTJ ,TJfLLIXc; ,wv 6Eµci,wv: xtvMvou 1tcx 'tTjV u1td1X OE 1tEpi1t,WOTJ XIX'tlX1t00Tjc; EL01tvo71c; TJ E1t1XcpTjc; µE ,o uAtxo 1tou 81X EiX,E 6t1X01t1Xp8EL Ap. 78. ·011:wc; 'tO 1tpo7J1ouµEvo, Mo xci0Enc; 1p1Xµµic; o,o XIX'tW µtoo µapoc; (,LE 'tO E;71c; XEifLEVO. 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(011:wc; ,o 1tpOTJj'OUfLEVO IXAAci µE ,pdc; xix9E,Ec; yp1Xµµac; O'tO XIX'tW µtoo µapoc;) 1tpo/3Aa1tE'tlXl O'tlX . BEA 'tLIX 5 Ewe; 1-2 'tOU 1tEpt8wp[ou 2703 IXVciAOj'IX µE 'tTJV 1tEp[1t'tWOTJ XIXL O'tO 1tEpt8wpto 3656(Il ), (2) XIXL (3 ). . Pci6Lo EvEp1o uAtxo o,IX 6iµ1X,cx ,Tjc; x.ot'tTj1opi1Xc; III - xi­ ,pLVTJ OE(,LIX'tlX 1tOU 1tpE1tEl VIX 6L1X'tTJpOUV'tlXl OE CX1tOO'tlXOTJ IX1t0 ,IX OEfLIX'tlX 1tou mptax.ouv µT} EfLcplXvt,oµEvEc; <pw,oypcxcptxic; 71 pcx6to1p1XcpLxac; 1tA0txac; 71,aAcx,iv~c;, oa 1tapi7:,woTJ ,TJfLllXc; , w~ OeµOt,WV XtV6UVOU j'LIX 'tT}V Uj'LELIX µE XIX'tlX1tOOTJ, el01tVOTJ TJ a1t1Xcp71 µa ,o uAtxo 1tou 81X aix.a OLIX01t1Xpai 01twc; XIXt xiv6uvoc; E;w,Ept"71c; 1XX,tvo/30Ai1Xc; 1X1to 1X1too,1Xo7J. Ap. 7D. 0 cxpt0µoc; IXU'tO', IXVIXcpape'tlXl O'tTJV Emypcx<p71 1tOU 1tpo/3AE1te't1XL O'tO 1tept8wpLo 240010 'tOU XECj)OtAIXiou B4. Ap. 8. (o,IX1ovac; 11:ou 1ticp,ouv 1X1to (,LLIX 6?XLfLIX?'tLX7I ~w­ ).71vcx oa µ[ex 1tA0txcx XIXt 1X1to ciAATj 6oxtµIXo'tLXTj oWATjVIX oa e~IX X,EPL, fL1XUp1X Oe AEUXO cpono, 'tO XIX'tW ,p[ywvo 't"ljc; am,p1Xcp1jc; ElVIXl µ1Xupo µa AEUX7I j'p1XfLfL71 yupw ), 1tpo/3AE1tE't1Xl O'tlX 1tepL 0wpt1X 2312(2) 24 79(2) 2511(1) 2612(3) 2703 oahio 5 XIXL 2812(1). OL1X/3pw,tx71 ouoicx. Ap. 9 Au,oc; 0 1Xpt0µoc; amcpuAIXOOe'tlXl O'tTjV XAIXOTJ 9 1tOU 81X µn:opouoe VE EV't1XX,0Ei O'tO ADR. • Ap. 10. (1XVOLX't7I µcxupTJ 0µ1tpaAA1X OE AEUXO q,ov,o) 1tpo­ /3AE1tE'tlXl O'tO 1tEpL8wpto 24 79( 1) EU1Xio871,oc; O'tTJV u1p1Xa[1X. Ap. 11. (6uo /3EATj OE AEUXO cpono) 1tpo/3AE1tE'tlXl O'tlX 1tEpt 0wpt1X 2117(2) 2224(2), 2312(4), 2414(2) 2443(2) XIXL 23), 2479(3) 2511(2), 2563(2) 2612(5) 2664 XIXl. 2812(5). • Avw µipoc; VIX ,01to8n718Ei 71 rnrrpcxcp71 µE ,tc; cixpEc; ,wv /3EAWV cxn:ixvw o,Lc; 2 cxv,i0E,Ec; 1tAaupic; ,ou 6iµ1X,oc;. Ap. 12. KoAWVIX'tO 1tO't1JpL OE AEUXO cpov'tO. Tipo/3AE1tOV't1Xl O'tlX 1tEpt8Wpt1X 2117(2) 2188(2) 2224(1) XIXl (2), 2414(2) 2443(3) 2479(3) 2511(2) 2562(2), 2612(4) 2664 XIXL 2812( 4) VIX µE,1XX,etpto0Ei fLE 1tpooox.71 71 VIX fLTJV 1XV1X1to6oyu­ pto8EL Ap. 13. Au,oc; 0 1Xpt0µoc; x.p71otµo1totEi;IXL IX1tOXAEtO'tll~ci O'tTj OtE8v71 µE,1Xcpopci Emxtvouvwv cpop,twv fLE ot671po 6poµo. 1286 E<l>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: aEYTEPO) Kitq>CXA!XtO A-9 Emyp!Xcpi; XtVOUVOU. (BA!7tE 1tept8wpto 3902) No. 3 No. 4.2 No. 6.1 No. 6.1 A No. 7A No. 78 No. 10 No. 11 No. 4.1 / / No. 5 No. 8 No. 7C No. 12 ECJ>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: dEYTEPO) OIKONOMIKH KOMILION fIA THN EYPQTTH ETTITPOTTH ELOTEPIKHL META(l)OPAL EYPQTTAIKH Ll'MBALH .1uxcpopo,:; e:;01tAlOfLO<:; 'E1xpto'lj O)(ljfLCmuv 7t0\l tXcpopat 't'lj Otdlv'Tj fLS:'ttXcpopat rntXL\10\l\lW\I ofL7tOpe:UfLOt'tW\I ootxwi; (ADR) xtXt 1tpw,cix0Mo u1to1ptXcpT)<:; 1tou i1 tve: O't'lj fe:11.i.111 o,t,:; 30 Le: 7t't•fL~plou 195 7 IlA "lPWfLtX'ttX O)(ljfLOt'tW\I EtOtXT) e:x1ttXloe:uo11 oomwv E7tl~A•~"l O)(ljfLOt'tW\I Me:,tXcpopat e:m/3tX,w11 Xp'T)Olj 1tupoo~e:o,Lxw11 ouoxwwv TOMOL III (IltXpatp,ljfLtX B) HNQMENA E8NH NitX Ycipx11, 1985 CTAPAPTHMA B: i\IATA'.:.EIL TIOY A(l)OPOYN E::.OCTAILMO META(l)OPAL KAI EPfALIH ME­ TA(l)OPAL CTEPIEXOMENA (l)op11,i,:; (l)w,to,txi,:; puox~ui,:; A1ttX-yope:uo11 XtX7t\lLOfLtX~o,:; 'Aom,:; oe:;tXfLolli<:; ·EnptXcptX 1tou 1tpi1te:t \10( u1t0tpxou11 o,11 fLOllatOtX fL••tXcpopix,:; r ptX1t,i,:; 0811-yle:,:; Ilixpixypixq:ioc; 4 Etotxi,:; 0ttX,0t;e:t,:; 1tou tXcpopouv ,TJ cpop­ ,waTJ, e:xepop'tWOTJ XtXL X•tptoµo Tie:pt8wpttXxo IlEpt0pLOfLO<:; 'tW\I fLE'ttXcpe:pcifLE\IW\I 7tOOO­ 't'T)'tWV L)(EOtO 'tO\l CTtXptXp't'TjfLtX'tO<:; EcptXpfLOOLfLO't'lj'ttX (XMW\I OLtX'tat;e:wv, e:8\ILXW\I 'Tj OLe:811w11 EcptXpfLOOLfLO•'lj•tX ,wv OLtX,at;e:wv ,ou Mipou,:; I MEPO~ I rENIKH i\IAT A'.:.EIL E(l)APMOLI­ MH HH META(l)OPA ETTIKINLH­ NQN Ol'LinN OAQN TQN KATHfO­ PIQN fe:VLXOt TIAtXLOLO 'tO\l 7ttXpono,:; CTtXptXp,TjfLtX'tO<:; ( 1te:ptAtXfL~tXVOfLivwv 1te:ptoptofLivwv 1to­ oo,-ip:w11) OpLOfLOt llixpixypixq)Oi; I T pci1to,:; µntXcpopix,:; Mi~ooo,:; 0(7tOO'tOATj<:;, 1te:ptopLOfLOL O'tlj fL•­ 'ttXcpopat TTAT)pe:,:; cpop,lo MntXcpopix )(UfLtX 1'frttXcpopat oe: xo11,i11ve:p,:; MntXcpopat oe: oe:;tXfLoVE<:; XtXptXx,11ptofLci,:; oe;tXfLEvoxov,i11v.p,:; & O\lO'tOt)(LWV OO)(ELWV nixpixypixq:ioc; 2 Etotxe,:; 1tpoii1to8ioe:t,:; 1tpo,:; e:X7tA~PWGTJ tX1to m µi;,tXepoptxat µfotX XtXL ,011 e:;01tAt­ oµci ,ou,:; Tu1toL ox11fLat,wv O)(TjfLtX'ttX fL• o,tXBe:pi,:; 'Tj tXcptXtpOt>fLS:VE<:; oe:~tXfLEVE<; 'Tj O\lO'tOl)(ie:,:; ooxe:lwv Tiupoo~e:o,txi,:; ouoxwi,:; H)..x,poAo1txci,:; .~o7tAtofLci,:; 10 000 10 001 10 002 10 010 & rncifL. 10 010 & rnofL, 10 014 10 000 & rnofL, A1tix-ycipwo11 fLLX't'Tjc; cpop,woe:w,:; OE EVO( ci)("lfLtX A1ttX,opEUOlj fLLX't'Tj<:; cpop,woe:w,:; OE ivtX XOV'tE'ljV•P A1ttX-yopwo11 fLlX't'Tj<:; q,op,woe:w,:; fL• EfL7tOpEUfLtX'tO( 7tEptE)(OfLEVtX OE XOV'thj11Ep KtX8tXptOfLO<:; 1tpo 't'lj cpop,woEw,:; XuptofLo<:; xtXt o~oL~tXOttX KtX8tXptofLcic; fLE'tat 't'ljV e:xcpcip,wo11 IlpocpuAix~u,:; 1LtX ljAEx,poo,tX,txi,:; q,op,l­ oet,:; (l)op'tWOlj XtXl EXcpop'tWOlj E7tLXt\10\lVWV O\lOLWV OE XOV'tEljVEp,:; 8EOlj OE Xt\lljO'lj 't'lj<:; fJ.lj)(tXVTj<:; XtX'tOt 't'lj 8tixpxe:ttX ,11,:; cpop,woEw,:; 'T) ,11,:; i;xcpop,w­ o.w,:; 10 105 Ilixpixypixcpoc; 5 Et8txi,:; OLtX'tat;Et<:; 7t0\l tXcpopouv 'tTJ AU 10 108 'tOUpJitX 'tWV OX7}µat,WV 10 111 10 118 L'TjfLtXVOlj 'tW\I O)(ljfLOt'tWV 10 121 L'tOt8fLWOlj ,e:VLX(X L,1X8fLe:UOlj 't'lj vux,tX 'T) oi; XtXXT) optX,o 10 130 't'lj'ttX 10 200 & e:1tofL. 10 204 10 220 10 240 10 251 L,at8fLEUOlj O)(TjfLtX,o,:; 1tou tX1to,e:AEt e:L­ OLXo Xt\10\l\lO • AM.,; OttX'tlX;EL<:; Ilixpixypixq:ioi; 6 ME,tX~tX,txe,:; OttXtat~EL<;, tXVtXXA~oe:ti; XtXt ottX,at;.ti; t8tcippu8µ.i; yttX optoµiv.,:; xw ~ TtX)(EttX OttXOtXO((JLO( 1LtX \ltX E7tL'tptX7tOU\17tO(­ pEXAiOEtc; 1tpo,:; ,o oxo1tci ooxtµwv 1287 10 260 10 282 & 10 283 10 300 & e:1tofL·· 10 311 10 315 10 3.21 10 325 10 340 10 353 10 374 10 378 10 381 10 385 10 400 & rncifL. 10 401 10 403 • 10 404 10 405 10 413 10 414 10 415 10 417 10 419 10 431 10 500 & rnciµ. 10 500 10 503 10 505 10 507 10 599 10 600 & rnciµ. 10 602 1288 E<l>HMEPII: THI: KYBEPNHI:EQI: (TEVXOI: ~EVTEPO) MEPm: II Kcxnrropiec; Jex, I~ & 11 Kcn711opicx 2 EIMKEi d!ATA:::Eii rror EXOYN E<l>APMOfH iTH META<I>OPA EITI­ K!Nd YNQN onmN TQN KA THfO­ PIQN I MEXPI 8 Exp71x'tlXic; ouoiec; Xotl e[o71 Eio71 1eµLoµivcx µe Exp71xnxic; ouoiEc;· CXVCX<pAEX't'Tj'tE<;, 7tUpO'tE)(V'Tj(lCX'tCX Xotl 1totpo~ (lOlCX EL07j Aiplot: LuµmEoµivcx, u1po1toL71µivcx 7J OlotAuµivcx u1to 1tiao71 Kcxnrropicx 4.1 Eu<pAEX'tCX onpacx Kcx't711opicx 4 .2 Ouoiac; u1tox.iµavac; oE otl<pvioLot xcxuo71 Kcxt71ropicx 4.3 Ouo[ac; 7t0U oivouv EU<pAEX'tCX cxiplot OE E7tCX<pT) (lE 'tO vapo Kcxt71rop[cx 5.2 Op,otVlXCX Y1tEpo!;aiolot Kcxt711opicx 6.1 To!;Lxic; ouoiec; Kcxt711op[cx 6.2 A1toxpouo'tLxic; ouoiac; xcxl ouoiEc; 1tou µ1topEi vex 1tpoxCXAioouv µ0Auvo71 Kcxt71ropicx 7 PotOlEVEp"'(ic;; ouoiec; TIAPAPTHMATA ~lot'tcx!;etc;; xoLvic; o'tcx ITcxpotp't7J(lCX'tot B.! 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A e;1X1pei 1X1to 'ttc; 811X't1X;eu;; 'tOU 1t1XpoV'toc; To1touc; cpop'twaawc; XIXI axcpop'twaawc; (1tap10wpl1XX(l 11407, 21407 XCXl 6}407)• XIXI Tri Amoup-yi1X OX.TJ(-llX'tWV (oAIX 'tlX 't(-lTj(-llX'tlX 5 'tWV Mapwv I XCXI II), µ.e 'tTJY mLcpUAIX;Tj, oµ.wc;, auµ.µ.opcpwaEwc; 1tpoc; 'tic; 10010 8LIX't<l;t1c; 'tOU 7tEpL0Wp11XXOU 61515. 10011 1290 EG>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) OTIIEL AvoYtlXtYj (lt)\IOALXlj 1tOOOtYjtlX XIXtlX p.emi:popLXlj µov&oix (µtxtoi:; oyxoi:;) A B C D E F G KATHfOPIE~ TT0Uix1tA1Xatixatii:; 1 tix wv u1to- 200 50 20 10 3 2 1 A1teptopL<nlX )..oytaµo "CW\/ (lt)VOALXW\I 1tOOO tlj"CWV 1tou e~ixtpouv"CIXL 1 tix <pop'tio 1tou 1tepLA1Xp.~&veL 1toA )..ii:; ouaiai:; 1tou T) x&0e µiix m, pwpi~etlXL ix1to Otixi:popettx& opLIX o1xou (~AE7tE 7t1Xp1XXIX"CW OT)fLEtWOT) I) 5 20 50 100 333 500 1000 KG KG KG KG KG KG KG 1 IX, 2 (µovo "CIX IXEptlX 1tOU "CIX~LVOµOu\l"CIXL µe Kavii:; auaxwixaiei:; (1teptAixµ~ixvoµevwv (ix) XIXL (~), 3, 4.2 4.3, 5.1, 5.2, 6.1 XIXt 8 'tWV OO)(eiwv, ix1toXAetoµevwv "CWV Oe~IX µeVOl\l) X lix 1° -14° X 1~ 20 (~). 40 X 'mix IX\lttXEtfLE\IIX X 1 ° (ix) X lr 30 X •mix IXVttXELfLE\IIX X 2 CYANOGEN CHLORIDE "Cwv 3 ° X FOSGENE twv 3 °, FLUORINE 1 ° (AT) X } 0 (ix) XIXL (~), 2 ° (ix) XIXL (~) X ·me,;; ouaiei:; xixt xevlj auaxwix aio: l'COU 7tepLEt)(e ixipto tlX~L\IOfLYj· µivo µe (AT), (BT), (1) 1J (CT) X 12 °' 13 ° XIXL ouaiei:; tOU (ix) X "CW\/ 11 ° XIXL 14 ° fLE)(pt 26 ° Ouaiei:; tou (~) twv l l O xixt X 14 ° fLE)(pl 26 ° 3 1 ° (ix), 2 ° (a) XIXL (~), 3 ° (~) 4 ° (ix) XIXL (~), 5 ° (ix), 6 o (ix) XIXL (~) 32° (ix) XIXL 34° (r) X • mei:; ouaiei:; X 9°' 10° X 4.1 2 ° (ix), 11 ° (~) X • mei:; ouaiei:; X 4.2 5° - 13° X 4.2 5° - 13° X Av0pixxo:a~icmo 'tWV 2 ° (ix), • " CALCIUM SILICIDE 1J J.. MANGANESE CALCIUM SILICIDE "CWV 2 ° (o) X 4.3 ·me,;; ouoiei:; X ECl>HMEPII: THI: KYBEPNHI:EOI: (TEYXOI: aEYTEPO) 5.1 5.2 6.1 8 20 1 °, 3° Xetl 10° • AM.c; OIJOlE<; 45° (~), 46° (et), 47° M XOtl X* (~) OIJOXEIJ0tOµE11et auµcpw110t µa 'tO 1tEpt8wptetxo 2559 1° -22°, 30°, 31° QIJOXEUet­ aµi11et auµcpw11et µE 'tO 7tEpt8W­ ptetXO 2561 1° - 22°, 30°, 31°, 40° au­ axwetaµi11et auµcpwvet µ. 'tO ltEpt 8wptetXO 2553 µixpt 2556 Xetl 2558 Ouai.c; 'tet~t110µ71µi11Ec; µ. (r) OuaiEc; ,et~woµ71µi11.c; µ. (~) 'A)J..c; ouai.c; (1tA7111 1 ° xett 2 °) SODIUM SULPHIDE ,w11 45 ° (~) 1 ° (et), 2° (et), 6°, 8° (~) 21 ° (et), 22° (~). 24°, 25°, 26°, 26 ° (et), 36 ° (et), 3 7 (et) 44 ° (et), 53° (~) 21 ° (~), 26° (~), 33 ° (~) 36° (~), 3 7 ° (~), 44 ° (~), 52 ° (y), 53 ° (r), IXME<; OIJOLE<; IJ7t() (a) Xetl (~) X r E11LXEc; OLet'tlX~EL<; 7t01J EXOUY Ecpetpµoy71 Cl't'Jj Me,etcpopix E7tlXL\IOIJ11W11 OIJOl<il11 OAW11 'tW11 Xet,71-yoptw11 X X X 1:HMEIQI:H: I. Ot et11W'tet'tE<; 1t'oao't7J'tE<; 7tOIJ aµcpet11i~o- l O O 11 1/'tetl O't011 1tetpet1t0l1/W 7tL11etXet et11'tlltpOaWltE1JOIJ11 ~et8µo Xl1101J 1/0IJ o o'1toioc; µ1topai, etito µtet 1toM et1tA01tot71µi1171 iit1to4>71. 11et 8awp718ai aet11 LO()'tlµoc; ytet xiit8a µiet etito ,tc; et11et-ypetcpoµa11«:; ouaiac;. Q xi11owoc; etlJ'tO<; OE11 0et ~E1tap11t1hetL etXOf!TJ Xetl O'tet11 E11et cpop'tio ltOIJ OE11 8iynett etltO OltOLOtOTjltO'tE etitet-yopEUa'T) Eltl µtx,71c; cpop't<i!OEW<; 1tt.ptAetµ~0t1/EL iteptaao,EpE<; et7t0 µiet E7tl xi116u11ac; ouaiac;. '01tou ,o ioto opto E~ettpfoawc; toxuat 1tet ,tc; ouaiEc; 1tet ,tc; X X X X X X X 01toiac; 1tpoxu,ett, ot etv,ia'totxot oyxm ,ouc; 1tpoa0i,011,·ett xm 'tO ·au110Ao OE11 1tpi1tEl 1/et IJltEp~el EXEL110 'tO opw. '01tou e11 ,ou,mc;, taxuow 1tet 'ttc; oual.c; 6tetcpopa,txiit optet .~ettpfoawc;, OL etYW'tet'tac; 1toao't7l'tEc; 1tou am,pi1to11,ett 1tet xiitlla µiet llet u1toA01i~o11,ett 01twc; itetpetxiit,w: (et) H OAlXTJ 1tpet1µetnx71 µiit~et xiit0E ouaietc; itou etvetcpipe,ett ae 01tot0t6711to'tE O'tTjATJ ,ou 1ti11etxet 8et 1tOMet1tAetaL0t~E'tetL µa 'tO Q\)\l'tl:.AEO'tTJ 7t01J 0t11etcpEpE,etl O'tTJ11 XEcpOtATJ 't'T)<; O'tTJATj<;" (~) Tet itpoi:011,et 7tOIJ E1tl'tlJ'YXOlll01/'tetl Xet't' etlJ'tO 't011 ,poito llet 1tpoa,i0E11't0tt µet~i xett ,o au110M 'touc; 6.11 0et 1J1tEp~eti11u ,o 1,00-0 .• MiXPt etlJ'tO 't011 etptllµo, 7J Oletcpopiit Olettpouµ.1111 f!E 'tO au 1/'tEAEO't'Tj 1tou et11'ttO'totXEi itpoc; xiit1totet atM'T) o'uaiet 6i11EL 'tO opto E~ettpfoawc; 7t01J OE\/ EXEL etXOf!TJ XetAucpllai. X TTapiitouyµet etlJ't<il\l 'tW11 1JltOAoytaµw11 Ket,71-y. Ouaiet AIIW'tet'tTj 7tOQO't'T)'tet • 5 20 50 100 333 500 1000 KG KG KG KG KG KG KG 2 2° (et) 100 3 31° 50 4.1 70 (et) 2 6.1 60 (~) 3 6.1 •6° (r) 25. LUVOAO µa,0tcpapoµa11w11 7tOOO'tTj'tW\I 5 25 50 100 n 0Uet1tA0tat0ta,TJc; 200 50 20 10 3 2 1 Tipo'io11 (1tOMetltAeta. X 7tOOO'tTj'tOt) 100 250 100 100 Lu110Ao 1tpoi:onw11 100 +250 +100 +100= 550 1291 1292 E<J>HMEPII: THI KYBEPNHI:EQI: (TEYXOI: l1EYTEPO) Acpou 'tO OU\IOAO 'tW\I 1tpoi:i)ll'tW\I ELIIIXL ALj'O'CEpo IX7t0 1,000, Tj 7t1Xp1X7t<XIIW 7tEpL7t'tWOTJ 1Xcp7111at OtlX0iatµIX !J.EOIX O'CO opLO E;1Xtpiaewc; 1,000 - 550 = 450 1tou (.Lltopd VIX J(p71otµo1tot­ Tj0d j'tlX 111X OU(J-1tA71pw81d -co cpop-clo (J-E, 1t1Xp1XOEtj'(J-1Xto,; J(<XpT), xu)..l116pou,; IXEplou -c71c; K1X-c71ropl1Xc; 2, II° (IX) (opto 333 KG) OE IX;llX 450: 3= 150 KG. Au-col ot 1toUot1tA1XOt1XO(J-Ot TJ OtlXlpfoat,; (J-7tOpal VIX 1X1tocpau­ x8ou11 (J-E "tT) XPTJOL(J-07tol71071 "t(t)\I 7tLll(XX(t)Y (J-<X~IX<; 7t0U U1t<Xp xou11 mxpotXOC'CW. . A11wtlX"tTj fL<X~ot x<i0e (J-Uitc; 1X1to Mo OL1Xcpoprnxi.:; ouole.:; 1tou 0t11otcpipo11"t1Xt one; O"tTJAEc; A (J-EJ(pt G -cou 1t1Xp1X1to:11w 1tly1XXIX 1tou (-L1topel 111X cpop"tw0ou11 (J-IX0 oE µE"t1Xcpoptx-i] µ0110:61X x.wplc; \lot U1tEp/31Xl11ou11 "tot opLIX E~IXLpioewc; ( OE KG): • L"tTJAEc; A XotL E1t6µ. A A A Xott B A XIXt C A XIXL D A Xott E A XIXL F A XO(L G 1 4 1 16 1 40 -1 80 1 266 1 400 1 400 2 3 2 12 2 30 2 60 2 200 2 300 2 600 3 2 3 8 3 20 3 40 3 133 3 200 3 400 4 1 4 4 4 10 4 20 4 66 4 100 4 200 505 05 05 05 05 05 0 L"tTJAEc; B Xott E1t6µ. B B B XIXt C B Xott D B XIXt E B Xott F B XIXt G 2 18 2 45 2 90 2 300 2 450 2 900 4 16 4 40 4 80 4 266 4 400 4 800 6 14 6 35 6 70 6 233 6 350 6 700 8 12 8 30 8 60 8 200 8 300 8 600 1010 10 25 10 50 10 166 10 250 10 500 12 8 12 20 12 40 12 133 12 200 12 400 14 6 14 15 14 30 14 100 14 150 14 300 16 4 16 10 16 20 16 66 16 100 16 200 18 2 ,18 5 18 10 18 33 18 50 18 100 20 0 20 0 20 0 20 0 20 0 20 0 C C 5 45 10 40 15 35 20 30 25 25 30 20 40 10 45 5 50 0 Cxcxt D 5 90 10 80 15 70 20 60 25 50 30 40 40 20 45 10 50 0 ~"t¥Ec; D Xott E7tO(J-. D D Dx1Xt E 10 90 10 300 20 80 30 70 40 60 50 50 60 40 70 80 90 100 30 20 10 0 20 266 30 233 40 200 50 166 60 133 70 100 80 66 90 33 100 0 C XIXl E 5 300 10 266 15 233 20 200 25 166 30 133 40 66 45 33 50 0 D XIXt F 10 450 20 400 30 350 40 300 50 250 60 200 70 150 80 100 90 50 100 0 C Xott F 5 450 10 400 15 350 20 300 25 250 30 200 40 100 45 50 50 0 D Xott G 10 900 20 800 30 700 40 600 50 500 60-400 70 300 80 200 90 100 100 0 C XIXt G 5 900 10 800 15 700 20 600 25 500 30 400 40 200 45 100 50 0 ~"tTJAEc; E Xott E7tO(J-. E E Ex1Xt F E Xott G 25 308 25 462 25 925 50 283 50 425 50 850 75 258 75 387 75 775 100 233 100 350 100 700 125 208 125 312 125 625 150 183 150 271 150 550 175 158 175 237 175 475 200 133 200 200 200 400 225 108 225 162 225 325 250 83 250 125 250 250 275 58 275 87 275 175 300 33 300. 50 300 100 325 8 325 12 325 25 333 0 333 0 333 0 ~"t¥Ec; F Xott G F F Fxcxt G 50 450 50 900 100 400 100 800 150 350 • 150 700 200 300 200 600 250 250 250 500 300 200 300 400 350 150 350 300 400 100 400 200 450 50 450 100 500 0 500 0 A11, A1X(J-{3<XIIO\l"totc; U1t04TJ "tO\I oyxo "t"Tjc; 1tpW"t7Jc; 1tpoc; cpop­ "tWOT) ouol!Xc; (imwc; cp1XlllE"tott OE fLLIX ot1t6 nc; O"t7IAEc; 1tl111Xxot "tot­ xeloo; ot11cxcpop<ic;), 6E11 E1tmux.0al 11 ot\lW"tot"tT) 7tOOO"tTj"tlX j'LIX "tTj 6EU"tEPTJ ouolot (O"t"Tjll <XAAT) O"tTJAT) "tOU tOLOU 7tt\lotX1X) 0 orxoc; 1tou ot7tOfLE-11Et Ot1X0icnµoc; (J-7tOpal \/IX x p7lotµo1tot7J0al 1tlX "tPt"tT\ ouol1X. ftot 11ix a;1Xxpt/3w0al o E1tt-rpe1t6µe11oc; 61xoc; Exel1171c; "tT)c; ouolotc;, 1tpE1tEt \/IX ylvu IXllotcpopoc O"tO\I 1tlllotXot "tlXJ(ELIX<; 0t11otcpop<ic; 1tou EX.Et emxecp1XAl6ot 1X1to "tot yp<iµµot"tot o"t71h1c; 7t0U otll"ttO"tot;(OU\I O"tTJ OEU"tEpTJ Xott "tpl"t"Tj OUOtlX. A11 Xott 71 ot\lW­ "tot"t"Tj 1tooO"tTj"tot ytot "tTJII "tpt"tT) ouolot 6e11 E~IXll"tAT)llal, µ1topel 111X OtXOAOU07J0El TJ l6tot 6tlXOtXIXOLot ox mx<i (J-E "tTJ cpop-rwo71 µtote; TJ 1tEptooo-ripw11 o:Uw11 ouotw11. L"tTJII otptoup1x71 O"tTJATJ xo:0E 1tl11otxot, µ11X e1161&:fLEOTJ u471 )..6-rep1j ot~IX j'lot "tT)II 1tp1Xj'(J-ot"ttxo: cpop"tw0eloot 1too6-c1j"t1X (1t.x . O"tO\l 1tL\lotXot B Xotl D, 9 (J-E'tot~U 8 XIXt 10) µ1topal \/IX o-cporru­ AEU"tEL O"tTj )(otµTjAO"tEPTJ EfLcp1X111oµE111j ot~tlX ( o' IXU"t"TJ "tT)II 1tEpl 1t"tWOT) 8). L"tTj 6E~t<X O"tTJATj, 1X1to -ro o:Uo µipoc;, (-Ltot e116t<it­ !J-EOT) ot;iot j'tlX (-LtlX 1tpotj'(-Lot"ttX<X cpop"tw0EtOIX 7tOOO"tTj"tot (it.;(. o"to11 l6to 1tl11otxot, 55 ot11"tl 1tot 60) fL7tOpEl 11ot o"tpO')'iUAEU"tEt O"tTJII u4TJAO"tEp1j E!J-cp1Xt11oµe1111 ot~llX ( o' otU"tTJ "tTJII 1tept1t"tWOTJ 60). fE11txic; 6tot"t<X~Etc; tox uouoEc; ytot "tTJ Me"totcpopo: Emxl116ww11 OUOtWII OAWII "tW\I XIX"tTJroptWII. • LHMEIQ1:H 2: ftot "tT)II ecpotpfLOiTJ otu"tov "tOU 1tEpt0wptot­ xou Xott "tOU 7tt\lCXX<X "tOU, Ot OjXOt "tWII Uj'pWII 7I otEptW\I 7tOU 7tE­ ptE)(Oll"totl o"tt<; ow71810(-Li11ec; o"tot0epic; 6e~otfLEIIE<; fLEOWII (J-E"tot­ cpop<ic; jtot "tT)II 1tpowfl710Tj "touc; TJ j'tot "tTJ AEl"tOUpj'tot "tOU E~EIOt 10 011 (ou11.) EG>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: AEYTEPO) 1293 xauµivou a;o1tA1aµou "touc; ( 4ux'ttXEc; auaxwEc;, rux mxpix 6a1rµcx) T) r1cx 'tT}II a;cxaq>1XA1a71 'tTjc; cxacpiXAEtcxc; cxu'twv 6av 0cx AOl(J-~IXVOV'tOll u1to471. I.'tTjV 1tapi1t"twa71 a;cxtpfouuv 1tou 1tpo~AE1tOV'tCXL a'to 1tap1 8wp1cxxo 10 0 ll' 'tO Enpcxcpo µa'tcxcpopixc; ltOU 1tpo~AEltE'tOll cx1to 'to 1tap10wptCXlto 2002 (3) 0cx cpEpet 'tTJII 1tcxpCXXIX'tW ar­ TPl!tq>T) µa't!X cx1to 'tCX CJ'tOLXEicx 1tou xcx0opi~ov'tcxt a'to xacp!XAcxto B 'tWV u6txwv 1tpoo1to0foawv r1cx xix0a XCX'tTJ)'opicx "tou Tipo­ acxp'tT)µcx"tOc; A: «<l>op"tio µ71 u1tap~cxi11ov 'tCX optcx a;cx1pfoawc; 1tou 1tpo~AE1to 11"tcx1 CJ'tO 1tEpt0WplCXXO 10 011 ». (I) 01 µovac; OlOl'tlX;ELc; 'tOU 1tcxpov"t0c; Tipoacxp"tT)µCX"tOc; 7t0U EX,OUV acpcxpµon )'lOl 'tTj µa'tcxcpopix E7tlXII/OUVWV OUCJIWV -c71c; KCX't'Tj)'Opicxc; 6.2 0cx ELVOll EXELIIE!; -cou MEpouc:; II ltOU axa-ci~o­ V"COll (,LE CXU-CT) 'tTjV KCX't'Tj)'Opicx XOll axaivac; -cwv mp18wp1cxxw11 'tOU 1tcxpo11't0c; Mipouc; J ltOU PTJ'tlX XOl'tEO'tTjOOl\l Ecpcxpµoa1µac; cx1to EXEivEc; ,:1c; 61cxi:ix;a1c; ,:ou Mipouc; II. (2) IlcxpEXXALCJELc; OlltO 'tic; OtOl'tlX;Etc; 'tOU 1tcxpovi:oc; Tipoacxp­ 't'rj(J-Ol'tOc; (J-1tOpEL VCX )'LIIOUII OE 1tEpL1t'tWOTj EltEL)'OUCJCXc; µEi:CXcpO­ pcxc; )'lOl 'tTj CJW'tTjpicx cxv0pwmvwv ~WWII. Optaµoi (I) dtcx 'tTjll EcpcxpµorT) ,:ou 1tcxpo111:oc; Tipoacxpi:T)µcxi:oc;: 0 opoc; «cxpµo61cx cxpxT)» a71µcxi11u 'tTjV CXPXT) 1tOU EXEL Ult0 0ELX,0Ei CJCXV 'tE'tOIOl OE XIX0E XWPCX XOll OE XIX0E OU)'XEXptµEYTj mpi1t'tWGTJ cx1to -c71v Ku~ipYTJGTJ' 0 opoc; «Eu0pcxuCJ'tTj CJUCJXEUCXCJLOl» OTj(J-OlLVEl auaxwcxaicx ltOU mp1ixu Eti0pcxua,:o 6oxaio (6TjA, 6oxEio OlltO )'LOLA[, 1topaa­ ACXVTj, ltT)AlVO T) OlltO 1tcxpoµmcx UAIXIX) ltOU OEV 1teptEXE'tOll OE auaxwcxaicx µE 1tAT)pE1c; 1tAEupic; 1tou -co 1tpoai:cx1:Euou11 cx1toi:E­ AEaµcx,:1xcx XOl'tlX 't'Tjc; xpouaEwc; (~AEltE EltLOTjc; XCXl Tipoaixp­ 'tTjµCX A, 1tEp18wp1cxxo 2001 (7): 0 opoc; «CXEplO» OTjµCXiYEl CXEplO T) CX'tµoc;· 0 opoc; EmxivouvEc; ouaiEc;, O'tOl\l XP7lOLµo1tOlEL'tOll µovoc; GTjµcxivu 'tlc; ouaiEc; XOll ,:ex OlV'tlXEiµEvCX ltOU opi~OV'tOll O'tl ElVOll ouaiac; xcxt cxvi:txaiµEvcx -cou ADR 0 opoc; «RID» OTjµcxivEt 61cx,:ix;a1c; ltOU cxcpopouv OLE0VT) µE­ ccxcpopix amxi116uvw11 aµ1topauµixi:wv µE at8Tjpci6poµo 1tou cx1to'tEAouv ,:o Tipoaotpi:TjµCX I 'tTjc; COTIF - I.uv0T)XTj 1tou cxcpopix w:; CJIOTjpOopo1-1-1xic; µai:cxcpopic; µE a1671po6poµo, Ticx­ potp'tTjµcx B - E111cxim xcxvovac; 1tou cxcpopouv -co au1-1-~0Acx10 r1cx 61a8111) µa-ccxcpopix aµ1topwµix,:w11 µa 1:011 aLOTjpci6poµo (CIM)· 0 opoc; «µE'tOlq>OpiX xuµcx» OTjµCXiVEl 'tTj µEi:cxcpopot CJ'tepEIXc; ouaicxc; xwpic; auaxwcxaicx· • • 0 opoc; •~O\l'tETjVEp» GTjµcxivat OlV'tlXelµEYO a;o1tA1aµou µa­ ccxcpopotc; ( cxvu<j10uµEvo OXTjµCX, AuoµEYTj oa;cxµEVT) Tj IXMEc; 1t0l­ po1-1-01ac; XOl'tCXCJXEUEc:;): Movt(J-OU xcxpCXX't'TjpCX XOll Xllt't(X CJU\IEltElOl cxpXE'tlX anpao jlOl vex aivcxt xcx-cill71).oc; r1cx E1tcx11ELA7lµiv71 X.PT)OTj' EtOlXIX axa61cxaµivoc; jlOl vex OlEUXOAUVEl 'tTj µai:cxcpopix E(J-1topauµix,:wv, µa ivcx Tj 1tap1aao,:apcx µidcx µai:cxcpopixc;, xw­ pic; 0pcxuGTj ,:ou q>op-ciou· E;o1tA1aµivou µa auaxwic; 1tou ami:pi1tow 1:011 EjXCXtpo x a1p1a1-1-o ,:ou, a161xoi:apcx oi:cxv (J-E'tcxcpopi:wvai:cxt cx1to ivcx µfoov (J-E'tCXcpopotc; OE illo· fav1xic; 61cx-cot;E1c; 1tou ex.ow acpcxpµoTT) O'tTj Mai:cxcpopix Em­ xiv6uvwv Oua1wv OAWV 't(l)\I Kcxi:71rop1wv (awixa1cx) I.x a61cxaµavoc; XOl'tlX 'tE'tOIO ,:po1to wan \ICX ELVOll ,:o jEµtaµcx XOll 'tO IXOElCXO(J-CX, XOll vex EXEL ECJW'tEptxci OjXO ox1 AljO'tepo CXltO 1 (J-3. 0 opoc; «xovi:iTjVEp» 6av xcxAt11ti:a1 auµ~cx-c1xic; auaxaucx­ aicxc;, T) OX,T)(J-Ol'tOl, T) XOll'tETj11Ep-6a;cxµavEc:;' 0 opoc; •(J-E)'IXAO XOV'tETjVEp» GTjµCXillEl XOV'tETjVEp ltOU EX,El ECJW'tEptxo orxo ltlXYW OlltO 3 1-1-3. 0 opoc; «µ1xpo XOV'tETjYEp» GTjµCXiYEl XOV'tETjVEp ltOU EXEL ECJW'teplXO orxo ox1 Al)'O'tEpo OlltO 1 µ3 XOll OXL mptaCJO'tEpo CXltO 3 µ3• 10 012 10 013 10 014 10 014 (ow) 0 opoc; «XOV'tETjllEP - 6a;cxµav'Tj» OTjµcxivEL ai6oc; a;o1tA1aµou (J-E't0l<j>Op1Xc:; ltOU 'tCXlpliX~El µa 'tOV optaµo 'tOU opou «XOV'tETjYEp ltOU 6ivE'tOll 1tcxpcx1t1XVW XOll XCX'tOlCJXEUIXaµivo jlOl vex 1teplEXEl urpic:;, cxapw6w:;, OE CJXOVTj ij OE xoxxouc:; ouaiEc:;,, CXMIX ltOU e,xEt XWPTj'tlXO'tTj'tOl ltlXVW OlltO 0.45 µ3 • 0 opoc:; «CJUCJ'tOIXlOl 6oxEiwv» 07lµcxiva1 aurxpo,:TjµCX ltOU ltE­ pLAcxµ~IXVEl cxp10µo ooxaiwv ( OlltOXCXAOtiµavwv «O'tOlXEicx») 'tW\I 01toiwv 71 1X1:oµtxT) T) µfoTj xwp7lnxcii:7l'tCX Eiv1X1 1tixvw 1X1to 15 0 AhplX, 'tilt 01toi1X CXMTjAOouv6fo11-ccx1 µE 1toAACX1tAo IXjW)'O xcxt Eivcxt µ0111µcx i:01to0E,TjµEvlX 1tixvw aE 1tAcxia10 ( r1cx 1tAcxio1cx xu­ Aiv6pwv CXEpiou, ~AEltE Tipoaotpi:Tjµcx A, 1tEpt8wp1cxxci 2212 (I) (6))· 0 opoc:; «cx1toouvcxpµo).orouµEv7l oEl;cxµEv'Tj» a7lµcxiva1 6El;cx­ (,LEIIT) ill71, Exi:oc:; cx1to oi:cx0Ep'Tj 6al;cx1-1-avij, 6E;cxµEvoxov'tE7lYEp TJ auo,:01xEicx 6ox.dwv, 1tou EX,EL xwp7li:Lxoi:7l,CX 1tix11w 1X1to 1000 ).ii:pcx, OEV ai111X1 axa61cxo1-1-iv7l 11cx i!"Tj µai:cxcpopix Eµ1to­ pauµcxi:w11 xwpic:; 0pcxuOTj cpopi:iou, XOll ouv'Tj0wc:; XEtptaµoc:; 'tTjc:; (,LltOpEi \ICX rival µovo O'tCXV Et\lCXl IXOELCX. 0 opoc:; «oi:cx0ap71 oa;cxµEVTJ» GTjµCXi\1£l oa;cxµEY'Tj ltOU ElVOll 60µ1xcx 1tpoocxp,:TjµEv7l OE oxTjµCX {1tou 'tO'tE TiYE'tlXl OXTjµCX 6a­ ~Ol(J-E11Tj) Tj cx1tO'tEAat 1Xvcx1toa1tcxo'to µEpoc:; i:ou 1tA1Xtoiou cxu,:ou 'tOU OXT)µ1X1:oc;· 0 opoc:; •OE;cxµav71» O'tCXV XPTJOtµo1tOLEl'tCXl xwpto'tlX, 011µcxi­ VEI 6a;CX(J-EV'Tj XOV'tETjllEP ij oa;cxµEV'Tj xwpTj'tlXO'tTj'tCXc; ltOU ;a 1tep111X ,:o 1 µ3, ltOU µ1topai vex ELVOll CJ'tlX0epTj 6a;1Xµa11Tj, IXltOOU­ vcxpµoAO)'OtiµEVTj 6e;IXµEVT) 71 CJUO'tOLXElOl ooxEiwv. (BAEltE, EV'tOU'tOtc;, 1tEptoptO(J-O O't'Tjll E\1\/0lOl 'tTjc; AE~awc; «OE;IXµev'Tj» O'ttc:; OlOl'tot;Etc; 'tWII TI1XpCXp'tTjµoti:w11 B .I, 1tap18wp1cxxo 200.000 (2))· 0 opoc; «µovotOIX µa,:cxcpopixc;» OTjµIXiYEl IXU'tOXl\lTj'tO OXTjµIX x.wpic; 1tpoacxp-c71µEvo puµouJ..xouµEvo, Tj aupµo cx1to1:EAouµE110 CXltO OlU'tOXiVTj'tO ox.11µcx XIXl 1tpoacxpi:7lµEVO puµouJ..xouµavo· 0 opoc:; «XAElO'tO OXT}µIX» OTjµCXtVEl oxTjµCX ltOU EXEL cxµcx­ ~wµcx ltOU µ1topai VIX XAEiVEl. 0 opoc; «OlVOlX'tO axiiµcx» OTjµCXt\lEl OXTjµCX 'tOU OltOlOU 7l 7tACX'tcpopµcx OE\/ EXEi U1tepXCX'tCXOXEUTj Tj EXEi CXltAWc:; ltAEUptxcx xcxt 01tia81cx ocxv16wµcxi:cx • 0 opoc; «OXTjµCX µa xixAuµcx» OTjµCXt\lEl OlVOlX'tO oxTjµCX acpo­ OlCXO(J-E\10 µa xixAuµIX r1cx 'tTjY 1tpoa1:1Xoicx i:ou cpopi:iou· 0 opoc; «OXTJµCX Oa;cxµEYTJ» OTjµCXLVEl OXTjµCX XCX'tCXOXEUIX· O(J-EVO )'lilt 'tTj (J-E'tcxcpopdt urpwv, cxapiwv Tj OUOIWV OE OXOVTJ Tj OE xoxxouc; ltOU 1tEptAcxµ~cxvow iitcx Tj 1tap1aaoupac; oi:cx0Epac; 6a;1Xµavic;· 0 opoc; «OXTJ(J-Ol OUO'tOlXtlX» OTjµCXiYEl oxTjµIX - 6a;cxµEYT) 7tOU 1tEplACX(J-~Ot\lEl cxp18µ0 ai:cx9apwv 6E;cxµavw11 ( ltOU CXltOXIX­ AOUV'tOll O'tOlX,Eicx) ltOU CJUVOEOll'tOll µa XAIXOW'tO cxrwro, (2) ftCX 'tTjV ecpcxpµoTT) 'tOU 1tCXp011'tOc; TipoaCXp'tT)µ1X1:oc;, Ol 6E;1Xµa11ic; (~AE1ta optaµo a,:o 1tcxpcx1tdtvw (I)) 6av ai11cx1 i:01to6a­ 't'Tj(J-Evac; ltOtVW O'tTjV iotlX ~OtOTJ 01twc:; 'tOl OOXELCX, 'tOU opou 00· X,Eillt XPTJOl(J-01to1ouµavou µa 1tap1op1aµEVTJ E\I\IOLCX. 01 61cxi:dt­ ~Etc:; ltOU cxcpopouv ooxaicx EXOU\I acpcxpµorii OE oi:cxBEpEc; OE;IX­ (J-EYEc;, CJUCJ'totXiEc:; OOXELWV, OlltOOUYCXpµoAO)'Otiµavac:; OE/;cxµa­ VEc; XOll 6e;1XµevEc; XOV'tETjVEpc:; µoVO\!XV CXU'tO xcx0opi~E't1Xl PTJ'tOt. 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E1ttxi116u11ac; ouoiec; 71 ex11'ttxaiµe11ex 'tWII Kot'tTJjOptw11 1 ex, 1 [3 xext 11 µitopel vex µe'texcpipo11'text µ6110 ae xAetatix ox71µex'tex 71 ae e1te116uµi11ex ox71µextex ecpo6texoµi11ex µe 1tAauptxa 1texpex1thex xext 01tia8LO 1texpex1tho. To q>uUo e116c; e1te116a6uµi11ou oxriµcnoc; 1tpi1tet vex ei11ext ex1t6 ex6Lix[3poxo UAtXO ltOU 6E11 exvot<pAEjE'text eu­ XOACX, IlpiiitEt vex ELIICXL n11'twµe.110 wan vex XlltAUltnt 'tO OXTJfl-CX ex1t6 OAE<; 'ttc; ltAeupic;, µE ElttXO:AUtj>Tj oxt µtxpO'tEPTJ 'tWII 20 ex 1tpoc; tex xixtw e1ti tw11 tmxwµixtw11 'tou oxiJµex'toc; xext vex au 1xpexnhext O'tTJ 0i07J tou µe µatexUtxic; pix[36ouc; iJ ex)..uaai6ec; ,cou xJ..u6w11011'text. Kex'tTj1opiec; ox71µdt'tw11 rtex 'tTJII a<pcxpµoyiJ tou 1texpoll'toc; TTpoaexp't'Yjµex"tOc;, fl-E'tot<popt­ xic; µ011dt6ec; itou ixou11 dt6Etex µe'texq,opdtc; emxi116u11w11 ouatw11 T) exll'ttXetµe11w11 'tWII Kex'tTjjOptWII 1 ex, 1 [3 xext l j xextex't!X000 1/'text 61twc; 1texpexxdttw: (1) Metexq>optxiic; µovcx6ec; «A»: Metexcpoptxic; µ011dt6ec; tw11 OltOLWII Qt XLIITJ't'Yjpec; XPTJOtf107tOtOUV u,po xexuatµo OE OTjµEio ex110tc?Ai~ewc; xdt'tw 'tWII 55 ° K. . (2) MeTexq>optxic; µ011dt6ec; «B»: Me'totcpoptxic; µ011dt6ac; 'tWII OltOLWII Ot XtllTj'tTjpEc; XPTJOtf107tOtOUII u,po xexuotµo µa 071µaio cx110tcpAi;awc; 55 ° K ri 1texpex1tdt11w· exu't71 7J XOt'tTJjOpiex B mpt­ ).exµf3dt11at 'ttc; itcxpexxdt'tw u1toxex't7J1opiac;: (ex) Me'texcpoptxic; µovdt6ac; «B.I.»: Au'tac; £in 6a11 exou11 oup6µa110 ehe exou11 aup6µe110 itou xex­ Auitnt Touc; itcxpexxdt'tw opouc;: H auoxeuri au116e071c; 'tou ex1toou116incxt jpTj1opcx xext ei11ext anpEdt·. xext Ei110tt acpo6texaµi110 µE exitonAEaµexnxij auaxeuri 1te671aewc; 7tOU e11eprai ae OAouc; 'tOUt; 'tpoxouc;, XtllOUfJ-EIITJ ex1t6 OUO'tTJfl-CX EAETXOU 1te611aewc; 'tOU aupo11'toc; O)(Tjfl-llt'tO<; xext O'tetµextix exu­ 'toµex'tex 'tO aup6µe110 ae 1tepimwa71 Opexuaewc; 'tTjc; au116i0Ewc;. ([3) Metcxcpoptxic; µ011dt6Ec; «B.11»: Au'tic; exou11 ,'tex 1texpexxdttw xexpexx'tTjptO'ttXdt 1tipex ex1t6 EXEtll(X 'tTjc; UltOXOt'tTjjOpiexc; B .I. ( t) Kt117J't'Yjpexc; xext auo'tTjµex e;ex1wyiJc; xexuoexepiw11 0 Xtll7J't'Yjp0tc; xext 'tO (JUO'tTjµex E;cx,wrric; 'tWII xcxuaexepiw11 ei11ext 'to1to8e't7Jµi11ex µnpoatdt cxno TO µ1tpoa'tt116 'toixwµex 'tou cxµex;wµcxtoc;. To O'toµto 'tOU OWATjlllX e;6t,wrric; 'tWII xexuacxe­ piw11 xexnu8u11E't1Xt 1tpoc; 'tex e;w IX7t0 'tO OXTJl'-ex, (tt) Ae;exµel/Tj xexuaiµw11 H 611.;exµe1111 xcxuoiµw11 Ei11cxt 't01to8E'tTJfl-EIITJ expxnix µcxxptdt cxito 'tOII XtllTj't'Yjpex, 'ttc; TJAEX'tptxic; xcx)..w6twouc; xext 'tOII ow­ A11llex e;extµrioewc; xcxt µE thoto tp61to won oe 1tepi1ttWOTJ 6tcxpppo11c; ex1t6 'tTJ 6e;exµE1111 to xcxuatµo atdtCet cxit' eu8elcxc; O'tO e6excpoc; xext 6e11 µitope.i vex q>8ixaet 'tO cpoptio 'tWII EXPTJX'tt­ XWII. H 6e;exµe1111 xexuaiµw11 f3piaxetext expxndt µexxptix ex1t6 'tTJ µ1tex'texpiex ex1to871xeuoewc;, 11 'tOUAOtXLO'tO xwpiCe'text ex1t6 exU'tTj ae an,ex116 xwptaµcx. Ei11ext 't01t08£'t7Jµi1171 Xex'tdt 'tE'totO 'tp07t0 WO't! I/ex Etl/lXL 000 ELI/ext 6U11ex'tO 7tpOO'texUU!LEIITJ Ge 7tEpL7t'tWOTJ aurxpouae.wc;. 0 Xt\11)'t1jpexc; 6e11 'tpoq>o6onhext µe 't'/J [3cxpu­ 'tTJ'tex (ttt) Kouf3ouxAtO 0671,ou AEII ex.et XPTJOLf107tOt1j8Ei e.ucpAeX'tO UALXO jtlX 'tTJII XCX'tex­ OXEU11 'tOU xouf3oux)..iou tou o61J1ou, extoc; ex1to tWe;o1tAtoµo 'tWV xex6toµdt'tWV. 11 106 11 117 11 118 11 119 11 199 11 200 11 203 11 204 11 205 ("'() Me'texcpoptxic; µovix6ec; "B.III": Au'tic; ex,ouv OAex 'tex x,expexxt71pta'ttXIX 'tTJ<; U7tOXex't7JjOpiexc; B.II xext, mi 1tAfov, 'to explt~wµci 'touc; nexpouatixCet 'tlX 1tcxpex­ XIX'tW rvwpioµcx'tex: (t) Etllext XAetO'tO xext ix,et aU11ex11 erctq>dtvetex xwpiCe~ext ex1to 'tO xouf3ouXAtO 'tOU OOTJjOU ex1t6 ,cwpo 7tOU 0£11 ei11ext AtjO'tepo CXltO 15 ex. ELIICXt O'tepecx XCX'tCXOXEUCXoµi110 xex'tCX 'tE'tOLO tpoito xext.exito 'tS.'tOtex UALXIX wan itpoa'tex'tEUEt expXE'tlX 'tex µe'texcpepo­ µevex eµitopeuµex'tex • 'tex xp71at µo1totouµev~ UAtXCX jlex EltS.~ 6u07J 6ev µitopouv. vex 7tpoxexAaaouv amv871pec;· ot µovwttxac; xext exv'tt8epµex11t1xic; t6t6'tTjnc; tou exµex;wµextoc; ei11ext oa 6)..ex 'ta. 07Jµeicx touAix:xta'to tao'ttµac; µe exeivac; a116c; xwpiaµex'to? cxitonAouµavou ex1t6 O"tpwµex exµtixv'tou 1t1itx,ouc; 5 )(LA. µa'tex;u ouo µeta.AALXWV 'tOL)(Wfl.lX'tWV 11 axaivac; xwpiaµextoc; exltO'tE­ AOU(J.EVOU exito e;wnptxo (J.E'texAAlXO ,oixwµcx Elt1!.ll6uµi110 µe O'tpwµex IXCj)AEX'tOU ;uAOU itdtxouc; 10 )(tA. (tt) H itop'tex 1121:opnc; ei11ext eq,o6texoµe.vec; µe xAet6exptdt xext x)..et6i· o>.ot ot expµoi xcxt 'tex XAetaiµex,ex ei11ext tou e1ttXexAu1t,o­ ll'tO<; 'tuitou. H itoptex ij 1topnc; 1tpi1tet vex eivext xextexaxeucxoµi­ vac; µe 'tE'tOLO tp61to wan vex µetwvetext TJ exV'tOX1l 't~U exµex;w­ µextoc; 000 'tO 6UIICX't0 AL10Upo. TTapt0ptoµoi O'tTJ XPTJOTJ ox1Jµixtw11 optaµevwv xext711o ptwv . .., "A" . . (1) Ot µetexcpoptxec; µ011exoec; µ1topouv vex µetexcpepouv µovo exvttxeiµevex 't'IJ<; Kcx't7J1opiexc; 1[3, 2 ° ([3), 4 ° (ex), ([3) xext (e), xext 'tTj,; KextTjjOpiex,;· l r, 1 ° (ex) xext 3 °. Ae.11 1tpof3Ai1tetext et6tx6,; 1teptoptaµ6c; µcxCexc; 1 tex 'thotex µa­ 'texcpopcx. (2) Ot µe.Texcpoptx!c; µovcx6e.c; "BJ" µ21:opou11 vex µnexcps.pouv (ex) x wpi,; Et6txouc; iteptoptoµouc; µcxCexc;, ei67J 'tTJ<; Kex't7J1'0· piexc; 1[3, 2°([3) xott 4°' xext 'tTJ<; Kext71ropicxc; lr, 1 ° (ex) xext 30, ([3) Me 'tTJV Eltt<pUA!lt;TJ 'tWV 1tept0ptaµwv µix,exc; ltOU 1tpo­ [3A£1tOV'text O'tO 1tep18wp1exx6 11 401, 'ttc; emxiv6wec; ouaiec; 1tou cxvexcpipovtext o' exeivo to 1tept8wptexx6. (3) Ot 6textix;etc; nou a;icetiCovtext µe touc; neptoptaµouc;, u1,.:. 'tO q,w,; 'tTjc; µdtCexc; xext 'tTjc; (j)UOEW,; 'tOU cpoptiou, ltOtVW O'tTJ XP710TJ 'tWII µnexq>optxwv µovii:6w11 "B.II" xext "B.III" xex6o­ piColl'tlXt ato 1tapt8wptexx6 11 401. TI..tXIX 7tOU 0ex )(PTJOt(J.07tOL7j80uV 1tex 'tTJV xextexoXeUTj 'tWV exµex ;wµdt'tWV 0X7Jµdttwv . ftcx 'tTJV xextexaxeuri tou exµex;wµexto,;, 6ev Oex XPTJotµo1totou­ v'text uAtxdt nou aivext av6axoµevo vex a;(Tjµextiaouv amxtv6uvcx µi,µextex µa 'tex µnexcpepoµavex expTJX'ttXIX (21:,x, µ6).uf36oc; O'tTJV 1tapi1t'tWOTJ µnexq>opdtc; e;u>.iou, mxptxou o;foc;, PICRA TES: EXPTJX'ttxdt µirµex'tex vhpou 6texAu'tdt O'tO vepo, iJ expTJX'ttXex o;tvTjc; cpuoewc; (f3Ai1tE ElttoTjc; 7tEpt8wptexxo 11 205 (2) (r)). Kouf3ouxAt0 06TJ,OU . (B'>-ine 1tept8wptcx3t6 11 205 (2) (f3), (m). l:uv6uexaµ6c; oupovtoc; ox 11µextoc; xcxt aupoµavou (B'>-im nept8wpuxxo 11 205 (2) (cx).) Kt117J't'Yjpcxc; xcxt auO'tTjµcx a;cx1wrric; xexuaexapiwv (BJ..iite nept8wptexxo 11 205 (2) (f3), (t).) Ilupoof3eottxs.c; ouaxeuic; Ot 6tcxtcx;etc; tou itept8wptexxou 10 240 (1) ([3) xext (3) 6ev 8ex ix ow ecpcxpiiorri 1tcx 'tTJ µnexq>opdt emxt11oww11 ouatw11 'tTj<; Kex'tTj1optcxc; 11, l O µi)(Pt 3°, 5° µi)(Pt 20°, 24°, 25° xext 27°. HAEX'tptxoc; e;o1tAtoµoc; (l) H xcx8optaµi117J 'tlXOTJ tou TjAtxtptxou oua't'Yjµex'toc; cpw­ 'ttoµou 6ev 6a 1>1tepf3aivet 'tex 24 V. (2) Aev 8cx e1xextaatex8ei iitoex atex cxµ~wiiatex twv µetex • " "B II" "B III" ' • • c:poptxwv iiovaowv . xaL . T}AEXtptxo xu 11 206 11 207 11 209 11 210 11 211 11 215 11 216 11 217 11 224 11 225 11 226 11 230 11 231 11 232 11 239 11 240 11 241 11 250 11 251 XAwµcx. 11 252 'E,xpLOTJ O;(Tjµot'tW\i . . . 11 281 Ot a1t1Xt't1jOEt,; tou 1ttpt8wp1axou 10 282 8cx ax ouv eq>cxpµon 11 282 O'ttc; µncxcpoptxec; µ011dt6ec; "B.III" 1300 E<DHMEPII: THI: KYBEPNHI:EQI: (TEYXOI: aEYTEPO) Ilotp0tjpotcpoc; 3: fe:11txic; 6t0t,0t;etc; e:;u1t71pe:,1joe:wc; Il).71pWf1.0t'tOt OX7lfl.0t'tW\I ~e: x<i8e: fl.E'tOtcpoptXT} f1.0110t0ot 80t U1t0tpxe:t ~0718oc; 0671,ou. Av Ot e:811txic; 6iex,<i;e:tc; 'tO 1tpo~A£7tOUII, 71 otpf1.00t0t expxTJ OUf1.~0tA­ AOf1.Ell7lc; xwp0tc; 1,1.1topd vex ~71'tTJae:t 110t u1t<ipxe:t a,o ox711,1.0t e:;ouat000't'Tjf1.£110c; xp0t,txoc; u1till71Aoc; fl.E i;o6ex 'tOU 1,1.e:,excpo­ piex. Em8e:wp71071 OX7lfl.0t'tW\I . Ot 6tex't~Etc; 'tOU 1te:pt8wpt0tXOU 10 321 80t ixouv e:cp0tpf1.0iTJ 1 tex ,ex e:mxi116u11ex e:1,1.1tope:u1,1.0t,0t 1tou 0t11excpipo11,exL 1texp0txcx,w ae: 1toao,71,e:c; 1tou u1te:p~0ti11ou11 nc; xex8opt~o1,1.e:11e:c;: Kot't71jOpi0t l0t: Ouaie:c; xext e:i671 ,ou 1 ° - 14 °: 5KG Kex't711opiex 1~: El671,ou 1 ° (~), (j) x0tt (6) 5 ° - 7 ° x0tt 9 ° 11 ° : 50 XI.A<X, Xext Kex't"lropi0t 11: Eto71 ,ou 21 ° 1,1.expt 23 °: 50 xtAcx. E1ti 1tAfo11, exu,cx ,ex e:1,1.1tope:u1,1.ex,0t 8ex e:m~Ai1to11,0tt 1tcx11,o,e: jtex \lot ex1tocpe:ux8d OOAtOt e:vipjetOt XOtt jtex 1/0t Xlll7l't01tot718e:i 0 o6~yoc; xext Ot exp1,1.06te:c; 0tpxic; ae: 1te:pi1t'tW07I Ot7tWAe:l0tc; TJ 1tup­ xext0tc;. Ilexpcxjpexcpoc; 4: EL6txic; 6tex,cx;e:tc; 7t0U 0tcpopou11 't7I cpop,w071 e:xcpop,wa71 XOtt xe:tpLOfl.O Ile:ptopta1,1.oc; 'tW\I fl.E't0tcpe:po1,1.e:11w11 7tOOO'tTj'tW\I H 7tOOO't71'tex 91ttxi116u11w11 OUOtW\I TJ Et0W\I 'tW\I K0t,71,optw11 lex, I~ xext lj 7t0U 1,1.1topou11 vex fl.E'tOtcpe:p8ou11 7tCX\IW ae: 1,1.i0t fl.E'tex­ cpoptXT} 1,1.0110t60t 80t 1te:ptopi~e:,ext 01twc; 1t0tpexxcx,w (~Ai1te: e:1ti 071~ 'tO 1te:pt~Wpt0tXO 11 403 00011 excpopcx 't7III ex1texjope:ua71 f1.l­ X't71c; cpop,wae:wc;). . (1) Miex 1,1.e:,0tcpoptXT} 1,1.0110t6ex «B.I» 1,1.1tope:i vex 1,1.e:,excpipe:t µ0110 • (ex) 'E110t ex1to ,ex cpoptiex 1tou e:m,pi1to11,0tt 0t1to ,ex mpt89w­ ptexx<i 11 206 (1) xext (2) (ex)· TJ @) 'Oxt 1te:ptaaoupo Ot7t0 500 xv.ex 'tW\I Et0W\I ,71c; K0t't71 ropicxc; Ij, 1° (~)· 1J (j) 'Oxt 1te:ptaaoupo ot7t0 300 XI.A(X OUOtW\I ,71c; K0t't71jO picxc; Jex, 12 ° • TJ . (6) 'Oxt 1te:ptaao,e:po ot7t0 100 XI.ACX OUOtW\I ,71c; K0t't7ljO­ picxc; Jot, 11 °, 13 ° xext 14 °, . (2) Miex 1,1.e:,excpoptXTJ 1,1.011cx6ex «B.11» 1,1.1tope:i 110t 1,1.e:,0tcpipe:t µ0110 ... (ex) 'Evex 0t1to ,ex cpop,iex iou e:~t,pi1te:,0tt 1,1.e: ,o 1texp0t1tcx11w (1) jtex µe:,excpoptxic; µ0110t60tc; «B.I»· TJ . @) 'Ox! 7t:ptaaoufo ex1to 5~0 XtAex OUOtW\I ,71c; K0t't7ljO­ ptcxc; Iex, I !J.EXPt 10 XOtt 12 ' xex8wc; XOtt Ot\l'ttxe:i1,1.e:110t 't71c; Kex't"lropicxc; I~, 1°, 2° (ex), (j) x0tt (6), 3 ° xext 6° µiXPt 11 °, 71 e:mxi116uvot e:µ1tope:uµex,0t 't71c; Kex,71ropi0tc; 11 · Ev,ou,otc;, ouaie:c; 't71c; Kex't711opiexc; Jex, 3 °, 4 ° x0tt 5 °, 1tpi1te:t vex e:i110tt au­ oxe:uexaµivot auµcpw110t µe: ,tc; ex1text'tT}ae:tc; jtex 0t1toat0Aic; 1tou • µncxcpipo11,ext 6texcpop ~ttx<i 0t1to 1tA TJpe:c; cpop,io. ,.(3YMtex µe:-iexcpoptXT} µ011cx6ex «B.III» µ1tope:i vex fl.E'texcpipe:t µovo (ex) 'Evex ex1to 'tOt cpopti0t 1tou e:m,pi1to11,0tt µe:·,o 1texp0t1tcxvw (2) jtex µnexcpoptxic; µ0110t60tc; «B.11»· TJ @) Me: ,OIi opo o,t 71 1,1.cx~0t ,ou cpop,iou e:mxi116uvw11 ouatw11 8~11 U1t!p~exi11e:t ~o 90 a,ex EX~'tO ,71c; µcx,Otc; 'tOU cpop,iou XOt­ ~W\I E:!J,7t0fEU!J,ex'tW~ 7tOU X~pux871xex11 E7tt'tpE7t'tEOt jtOt 'tO ox71µex .ot7t0 't7lll ex~µo6t0t ex~X71 't"lc; xwpexc; e:np0tcp1jc; 'tOU ox11 µexwc; O)(t 1te:ptaaoupex ex1to 9,000 xv.ex ,wv e:mxi118uvw11 ou­ atw11 ~ .CX\l'ttXEt!'-~\IW\I 'tW\I ~ex't71jOptw11 lex, I~ TJ lj XOt'tCX exp 8pw,o ox71µex 71 ox71µex xwptc; puµouAxouµe:110, TJ oxt 1te:ptaao­ i:e:po ex1to 15,000 xv.ex exU'tW\I 'tW\I e:mxi116uvw11 OUOtW\I xex,cx µe:i:excpoptXTJ µ011<i8ex illou e:i8ouc;. Ev,ou,otc;, exv ,o cpop~io 1te:ptAexll-'3tit11e:t µiex TJ 1te:ptaaoupe:c; ouaie:c; 't71c; xex,71ropietc; Jex, 11°, 13 ° Tj 14 °' TJ El/ex TJ 1te:ptaaoupex CX\l'ttxe:iµe:vex 't71c; Kot,71 roptetc; I~, 5 °, 6 ° Tj 11 °' exU't0t ,ex optex 8ex µe:tW\10\l'text ae: 6,000 XI.A0t Xext 10,0~0 XI.A0t ex11,ia,otxex, 11 283 11 299 11 300 11 310 11 311 11 312 11 320 11321 11322 11 399 11 400 11 401 11 402 A1texrope:u071 fl.lX'tTjc; cpop,wae:wc; ae: £1/0t OX7lfl.Ot (1) Ouaie:c; xext Ot\l'tLXe:iµe:vex 't71c; Kot,71jopiexc; lex 6e:11 80t cpop­ "1:W\10\l'tOtt µexO ae: i110t ox71µ0t j..te:: (ex) A11,txe:i1,1.e:110t ,71c; K0t,711opi0tc; I~ 1te:pte:xo1,1.e:110t ae: au­ axe:u0taie:c; 1tou cpipouv Mo e:,Lxi,,e:c; au1,1.i,>w110t 1,1.e: ,o u1to 8e:tjµ0t No. l • @) I:uaxe:u0taie:c; 1tou i,>ipouv ntxi,,0t au1,1.cpw11ex µe: 01t0Lo 81j1tou 0t1to 'tOt u1to6e:ijµ0t,ex No. 4.3, 7 A, 7B TJ 7f· (j) I:uaxe:u0taie:c; 1tou i,>ipouv µi0t ntxh,Ot TJ Mo E'tLXE't'te:c; auµi,>w110t 1,1.e: 01toto61j1tou 0t1to ,Ot u1to6e:i11,1.0t,0t No.3, 4.1, 4.2, 5, 6.1, 6.IA, 1J 8. (2) A11nxe:i1,1.e:110t 't71c; K0t,71ropi0tc; I~ 1te:pte:xo1,1.e:110t ae: au­ axe:u0taie:c; 1tou cpipouv e:,tXE't'tex 1tou e:i110tt au1,1.i,>w1171 1,1.e: 01toto­ OTJ7tO'te: ot1to 'tot u1to6e:ijµ0t,0t No. I 6e:11 Oot i,>op,w11011,0tt 1,1.0t~i oe: i110t ox71µot 1,1.e:: • (ot) All'ttxe:iµe:11ot ,71c; K0t,711opi0tc; I~ 1te:pte:xoµe:11ot ae: au­ axe:uexaie:c; 1tou i,>ipouv Mo e:,txhuc; auµi,>Wllot 1,1.e: ,o u1to 8e:tjµ0t No. l • • (~) I:uaxe:u0taie:c; 1tou i,>ipouv e:i:txh,0t au1,1.i,>w11ot µi 01toto 81j1tou 0t1to 'tot u1to6e:irµot,0t No. 4.3, 7 A, 7B TJ 7f· (j) I:uaxe:u0taie:c; 1tou i,>ipouv e:,txi't'tex TJ Mo mxh,e:c; au1,1.­ cpw11ot µe: 01toto61j1tO,e: 0t1to 'tOt u1to6e:ijµ0t,0t No. 3, 4.1, 4.2, 5, 6.IA TJ 8. . (3) A11,tXe:i1,1.e:110t 't71c; Xot't7ljOpi0tc; I~ 1te:pte:xoµe:110t ae: au­ axe:uexaie:c; 1tou cpipouv Mo e:,txhuc; au1,1.i,>w11ot µe: ,o u1to 8e:t1µex No. 1 oe:11 80t i,>Op'tW\10\l'tOtt µot~i ae: E\lot ox711,1.0t µe:: (0t) Ouaie:c; TJ ot\l'ttxe:iµe:110t 'tW\I K0t't71jOptw11 l0t, I~ TJ I, 7t0U 1te:ptixo11,ext ae: auaxe:u0taie:c; 1tou cpipouv e:,txh,0t ouµcpwv0t 1,1.e: co u1to6e:tjµ0t No. I· TJ (~) Ttc; auaxe:u0taie:c; 1tou 0t11oti,>ipo11,0tt 1,1.e: ,Ot 1t0tp0t1tcx11w (2) (~) XOtt (j), (4) A11,txe:iµe:110t ,71c; K0t,71jopi0tc; Ij 7t0U 1te:ptixo11,0tt ae: au­ oxe:uotaie:c; 1tou cpipouv n1xh,0t auµcpwv0t µe: ,o u1to6etjµ0t No. I 6e:11 80t cpoptW\10\l'tOtl µ0tO ae: £1/0t ox711,1.0t µe:: (ex) All't1xe:iµe:110t ,71c; Kex,71ropi0tc; I~ 7tOU 1te:ptixo11'tott OE au­ axe:uexaie:c; 1tou i,>ipouv Mo e:,txh,e:c; OUfl.',)Wllot µe: ,o u1to 8e:tjµex No. I (~) I:uaxe:u0taie:c; 1tou i,>ipouv e:,txh,0t auµi,>w1171 µe: 01toto 81j1tou ex1to ,Ot u1to6e:ijµ0t,ot No. 4.3, 7 A, 7B TJ 7f· (j) I:uaxe:u0taie:c; 1tou cpipouv 1,1.t0t TJ Mo e:,txhw;; au1,1.cpwv0t µe: 01toto61j1tou 0t1to ,ex u1to6e:ijf1.0t'tot No. 3, 4.1, 4.2, 5, 6.1, 6.IA TJ 8. Kex't71jOpie:c; l0t, I~ XOtt Ij A1tex,ope:u071 fl.lX'tTjc; i,>Op,wae:wc; ae: £\lot XO\l'tE7llle:p H. ot7totjope:u071 fl.lX'tT}c; i,>op,wae:wc; e:1,1.1tope:u1,1.cx,w11 7t0U exvexcp e:pe:,ext 0:0 1te:ptOwptotXO 11 403 8ex ixe:t e:cpexpfl.OiTJ fl.EOOt oe: xex9e: XO\l'tE:7IIIEp . • A1texrope:u~ !J,lX'tT}~ cpop,wae:wc; 1,1.e: e:1,1.1tope:u1,1.exi:ot 7t0U 7tE­ pte:)(Oll'text ae: e:vex xo11u7111e:p. O t 61ex,cx~e:tc; 'tOU 1tEf t8wptotXOU 11 403 80t ixouv Ei,>0tp­ !J,01'71 fl.Etex;~ 'tWII E7ttXt\10~\IW\I Ef1.7tO~EUf1.CX'tW\I 7t0U 1te:ptEXO­ \l'text ~e: xo11u7111e:p xext ,wv otUwv e:1ttxt116u11w11 e:1,1.1tope:u1,1.cx,w11 nou e:t110t.t ~op,w1,1. i110t ~'to iota 0~711,1.0t, ;-he: ,Ot ,e:Ae:u,0ti0t 1te:pti­ ,co11,ott 71 oxt ae: E\IOt 71 1te:ptaaoup0t OtMOt XOll't£7l11Ep, To1tot i,>Op,wae:wc; XotL EXi,>Op'toae:wc; ( 1) Ot 7totpOtXCX'tW EpjetOie:c; Ot7tOtjOpe:uo11't0tt: . (ex) «l>op,wa71 TJ e:xrop,w071 e:mxi116u11w11 OUOtW\I Tj ot\l'ttXEt­ !J,E:IIW\I 't~\I K0t,71roptw11 I0t, I~ XOtL I,, ae: 6711,1.oato xwpo ae: xex't?tX71fl.E:1171 1te:ptox11 xwpic; Et0tXTJ EjXpt071 Ot7t0 'ttc; 0tp1,1.06te:c; otPXe:c;· • @) Cl>op, w0711J !X',)Op'tW07I E~txi116uvw11 OUOtW\I TJ ot\l'ttXEL­ !J,~~W\I exU'tW\I :W\I Kex,711optw11 ae: 6711,1.oato xwpo exUotxou . 0L7t0 xex,?tx711,1.e:1171 ~e:ptox71. xwptc; 1t~o71,ou1,1.e:1171 e:t601toi71071 ,:w~ expµo6tw11 expxwv, e:x,oc; Ot\l otu,e:c; Ot e:p,0taie:c; OLXOttoAO­ jOUll'text jtex ao~expouc; Mrouc; exai,>CXAe:iexc;. (2) Av jLot 07t0t01101j7t0U AOjO, OL e:p,exaie:c; xe:tpta1,1.ou 1tpi 1t!I vex jt\lOU\I ae: 8711,1.oato xwpo, 'tOU: Ouaie:c; Xott ex11,txe:i1,1.e:11ex 6texi,>opw11 e:t6w11 Oex xwpi,Oll'tOtt OU!J,<pWllex fl.E 'ttc; E'ttXE't'te:c;• XotL I:ua~e:uexaie:c; e:;?1tA7101,1.i11e:c; µe: 1,1.foex xe:tpLOfl.OU 8ex 't71pOu \l'totL e:1tt1te:oe:c; xex,ot ,011 xe:tptc.fLo. ·ll 403 11 404 11 405 ll 406 11 407 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 1301 Ka:8a:pu,µoc; 1tpL11 <X7t0 'tTJ cpop'twa71 flpLII cpop'tw8ou11 Ol Emxi116U11E,; ouaiec; TJ <Xll'tLXEL(J-Ell<X 't(l)II Ka:niyop1w11 la:, If, 71 Iy, OA<X 't(X X<X'tCXAOL7t(X a:x.upou, xoupE­ AIWII, X,<XP'tLOU X<XI 1t<Xpoµo1w11 \JAIXWII, X<XL OA<X 'tex a16epa11Lex OLll'tLXeiµe11a; (xexpcp1ci, f,i6ec;, x.An.) 1tou 6E11 ex1ton"Aou11 ex11ex1to­ anexa'to µe.po,; 'tO\J a;µexl;w(.Lex'toc; 'tOIJ OX,7l(.Lex'toc; 8ex ex7tO(.LexXpu­ llOll't0LI, XE1p1aµoc; xexL O't01{3a;a[ex (1) H XPTJOTJ 1t0Au Eucp"Ae.x'tw11 1JALXW11 y1ex ·'t7I a'toLf,exoiex 'tWII 6Eµci'tWII 'tex ox.71µex'tex ex1texyopEuE'texL. (2) LuaxEuexaiEc; nou 1tEp1e.x ow Emxi116wEc; ouaiEc; TJ ex11't1 XEiµE11ex 'tWII Kex't711opLw11 Iex, If, xexL I 1 8ex cpop'tw11011'tex1 xex'tci 'tE'tOLO 'tp07t0 WO'tE 11ex fJ-7tOpou11 I/ex EX(j>Op'tw8ou11 µ[ex (,!Lex O'tO OTjµE[O 1tpoop1oµou X,Wpic:; I/ex X,pEICX~E'texL rnex11ex'texX't01tOL7I07I 'tO\J cpop'tiolJ. (3) 01 auaxeuexaiEc; 8ex a'tmf3&.~011'tex1 µfoex O'tO ox 71(.Lex (.LE 'tE­ 'tOLO 'tpono WO'tE 11ex µ71 (.LE't0L'to1ti~o11'tex1 (.Lfoex o' exu'to. 0ex 1tpo­ a'texnuo11'tex1 Xex'tci 01t01exo61j1tO'tE 'tp1{3iic; ii 1tpoaxpoUOEW<;, A11 f-LE'texcpipo11'tex1 f,expiALex xex81aµa11ex (.LE 'tO 7tAEupo 'touc; 8ex 'texX't07tOLOUll'texL XOL'tCX 'tE'tOLO 'tp07t0 WO'tE O Xex'tci (.LTJXO<; cil;o 1/<Xc:; exu'tWII vex ei11cx1 1ta:pciU71"Aoc; (.LE EXEi110 'tou ox.iifLex'toc; xex1 8a; 't01t08E'tO\lll'tOLI O(j>TJIIEt; 11ex vex E(.L7t06[~E'texL 7tAEUpLXTj XL IITJOTJ• L'tCXOELc:; y10L OIEAEIJ07I ex1to 'tO TEAWIIEtO 'O't<XII (.LLOL µE'texcpopLXTj µ011&.6ex ii OLll'tLXEt(.LE11ex 'tWII Kex't71yo­ p1w11 lcx, If, X(XL I I npoxm<XL vex 6La"A8ou11 ex1to 'tO T EAWI/ElO O't<X au11opex, 71 (.LE'texcpop1x71 (.L011ci6ex ( 71 cp&."Aexr,ex) 8ex o'tex(.Lex'tci 'tou­ Aa)'. LO'to11 50 (.Lhpex cx1to 'tO Te"Aw11Eio. 0 {307180,; 'tOU 067Jyou 8ex µE'texf3exi11e1 O'tO oix7Jµex 'tOU T EAW11Eiou 11ex 11ex 1tA7jpocpopTJ­ aEL 't1c:; expx ic:; y1ex 't7III &.cp1l;71 nic:; (.LE'texcpop1xiic:; (.L011ci6exc; (ii cpci­ Aex,rexc;) 1tou (.LE'tcxcpipou11 emxi116u11ex E(.L1topeuµcx'tex. :E'tciauc; 1tEp1wp1oµa1171c; 6LcipxE1exc:; yLex ex11cijxEc:; oapf31c; 'Oao Ei11ex1 ou110L'to, OL o'tcioEL<; 11ex ex11ci1xEc; aapf31c; OE11 8ex 1i 11011'tex1 xo11'tci OE xex'tmx71µa11Ec:; 1tEpwx.ic; TJ 8ipe'tpex. Miex o'tcia7J XOll'tlX OE 'tE'tOIO x.wpo 6EII µ1topd 11ex 1texpex'tex8Ei 1texpci µ0110 f-LE 'tTJII ijXpL07I 'tWII expµo6LWII expX,WII. <J>ciAexnE,; ( 1) 'O'texl/ ox.iiµex'tex 7tOU (.LE'texcpapow ouoiEc; TJ exll'tlXEL(.LEllex 'tWII Kex't71yop1w11 lex, If, X<Xl lr 'texl;u6EUO\JII OE cpci"Aexyrex, 8ex 61exnipEL'tOll f-LE'texl;u xci8E fJ-E'tOlq)OpLXTjc; µ011ci6exc; xex1 't7Jc; E7tO­ fJ-EIITjt; ex1tOO'texOTj OX,1 µ1xpo'tEp7I ex1to 80µ. (2) A11 110L 01tmo61j1tO'tE Myo, T\ cpci"Aexr,ex u1toX,pEw8Ei 11ex O'tOlfJ-ex't'TjOEI XOll <XII EIOIXIX, 1tpa1tEI vex jtl/0\JII EPYOlOtEc; cpop,w­ OEW,; OE 071µ0010 x.wpo, µE'texl;u 'tWII OX,Tj(.LCX'tWII 7t0U o,ex8(.LEU­ OIJII 80l 01ex'tTjpEhex1 Ol7tOO'tex07J OX,I µ1xponp7J 'tulll 50(.L, (3) 01 Olp(.L06LEt; Olpx a,; (.L7tOpEt 11ex Xex'texp'ttOOUII XOll/01/Et; jl<X 'tTJ aE1pci ii 'tTJ ou118Eo71 'tw11 cpOLAciyxw11 ITOlpcxrpexcpoc; 6: ME't<Xf,exwcac; 7tEpioom, ex11<XXATJOE1c; xex1 610l'tCXl;E1,; E161xac; jl<X op1aµe.11Ec; x.wpEc; ALOl'tCX!;EL,; EL61xac; jlOL opLO(.LillE,; X,WpE,; H µ1mxcpopci Emxiv6u11w11 ouo1w11 ii ex11'tLXEL(.Li11w11 'tWII Kex­ 't7\yop1w11 Iex, If, XOll Ir 80l U1toxmex1 O'tTJII Emxpcin1ex 'tO\J H11wµa11ou BOlatAEIO\J O'tLc; 6Lex'tcil;uc; 7t0\J LO;(UOIJII a' exu'tii 'tTj x.wpOl XOl'tCX 'tO XPOIIO nic; µnexcpopci,;. Kex'tTjjOpiOl 2: Aap1ex: fILEaµa11ex, Ujp07t01Tj(.Lillex 'T] 6LOlAU(.Lal/Ol tl7t0 7ttEOTj fe.111xci ('Ex.ow Ecpexpµon µ0110 Ol jE.IILXac; OLOl'tlXl;EL,; 'tOIJ Mapouc; I) ITOlpcijpOLcpoc; I: T po1toc; !J.E'texcpopcic; 11 408 11 412 11 413 Mi8oooc; ex1tOO'tOATjc; XOlL 7tEpLOp10(.LOL XOl'tCX 'tTjll ex1to O'tOATj . To 6wl;Et0l0 'tOU cill8pexxex X<XI 'tO VL'tp1xo ol;li 'tOtl 7 ° (Cl), µi1µ0L'tex 7tOU mp1aX,O\JII 6LO!;ELOLO 'tOtl civ6pexxex XexL 1/L'tpLXO o!;u . 'tOU 8 ° ( (X) X<XI 'tex exip10l 'tO\J 7 ° (f,) xex1 8 ° (f,) µ1topEi 11ex (.LE'tex­ cpipo11'tex1 µovo OE O'tex8e.pi,; ((.LOIILµEc;) 6el;ex(.LElla,;, o·E ex1toaU11exp­ µoAOjOU(.L&IIEt; OEl;exµE11ic;, OE. OtlO'tOLX,tEc; 7tEpLEX'tWII T\ OE 6El;ex- . µEvoxo11'tETjllEp. • 21 105 21106 21 U7 11 414 ME'tOLcpopci aE xo11'ti7111ep 11 414 11 415 11 499 11 508 11 509 11510 11 519 11 520 11 521 11 599 11 600 11 609 11 610 21 000 21 099 H (.LE'texcpopci aE µ1xpci xo11'te.7111Ep auaxEuexa1w11 1tou 1tEp1e.- 21 118 X,Otlll exe.pLex 'tOtl 7° (ex) xexL 8° (ex) ex1texyopEUE'tex1. Xa:pexxnipia(.Loc; X,EL~II 21 119 6El;ex11oxoll'tETJ11Ep xex1 aua'tOLX,LWII 60- -2i .129 (1) AE!;ex(.LE11oxo11'ti7111ep xexL auo'tOLX,iEc; 60X,Eiw11 1tou 1tEp1i­ x.ou11 ouaiec; 'tOU 1 ° (f,)· 2 ° (f,)· 3 ° (f,)· X,AWpoE8ci1171 (ETHYL CHLORIDE) 'tOU 3 ° (f,'t)' ouaiEc; 'tou 3 ° (y)· TJ ouaiEc; 'tOU 4 ° (f,), 4 ° (1)ex, 5 ° (f,), 6 ° (,), 7 ° (f,) 71 8 ° (f,) 6ex cpipow xexL O'tLc; ouo 7tAEUpic; E'tLXE't'tOL auµcpw1171 µE 'tO U7t00Elj(.Lex No. 3. ,2) Ae!;OLµE11oxo11'ti7111Ep xcx1 aUO'tOLX,iEc; 6ox.Eiw11 1tou mp1i­ x.ou11 o!;u,0110 'tOtl 1 ° ( Cl)' µiyµex'tex 7tEpLEX,Oll'tOl mp1aao'tEpo <X7t0 20 O'tOl EXex'tO ol;u,0110 XOl't' O"('XO ,:ou 2 ° (ex)· 111'tpw6ec; ol;u (ol;Eio10 'tO\J ex~W'tOll) 'tOIJ 5 ° (ex)· VL'tpw6e.,; ol;u 71 o!;u,0110 'tou 7 ° (ex)· Tj uypo1tm71(.Li110,; exipOL,; T\ (.LL"('(.L<X'tOl 1tou 1tepLe.x.ow m.p1aaonpo ex1to 2 0 O'tex EXex'tO ol;u10110 Xex'tcx f,cxpoc:;, 'tOU 8 ° ( ex), 60L cpipow O'tlt; 6uo 7tAEupic; E'tlXE't'tex auµcpw1171 µe. 'tO tl7t0 6e1yµex No. 5. (3) AE!;OLµe.11oxo11'ti7111Ep xex1 aua'tmX,iE,; OOX,Eiw11 1tou 1tEp1e.­ x.ou11 BORON TRIFLUORIDE 'tO\J 1° (ex 't), ex!J.µwviex, BRO­ MOMETHANE, x>.wpi1171 Tj 61ol;Ei610 'tOU 8Et0\J 'tOU 3 ° (ex 't) 8a: cpipouv aE <X(.Lcp6npec; 'ttc; 1tAeupic; mxfrtex ouµcpw1171 (.LE 'to . tl7t06EL1fJ-ex 6,1, (4) AE!;<XµE11oxo11'ti7111Ep xex1 auo'to1x iEc; 6ox Eiw111tou mp1e- • x ou11 cxe.pLex 'tou I O (f, 't) TJ 'tOu 2 ° . . (f, , ), 7l . DIMETHYLAMINE, ETHYLAMINE, HYDROGEN SUL­ PHIDE, METHYLAMINE, METHYL CHLORIDE, METHYL CHLORIDE, METHYL MERCAPTAN TJ TRI­ METHYLAMINE 'tou 3 ° (f, 't), VINYL BROMIDE TJ METHYL VINYL ETHER 'tOu 3 ° ( 1 , ) TJ ouaiEc; 'tou 4 ° ( 1 't), 6ex cpipow aE OL(.LcponpE,; i:1c; 1tAEupe.c; Enxe.nEc; auµcpw11ex µE 'tex u1to6Ei1(.Lex'tex No. 3 xex1 6.l. (5) AEl;Ol(.LEIIO-XOl/'tE.TJIIEp 'T] OtlO'tOLX,iEc; 6oX,ELWII 7t0tl mp1i­ X,Otlll 61ol;Ei6w 'tou <X~wi:ou TJ cpwo1e.1110 'tou 3 ° (OL 't) 6ex cpe.pou11 xex1 a't1c; Mo 1tAEupic; E'ttxhnc; ouµcpw11ex µE 'tex u1to6Eiyµex't0l No. 5 xex1 6.1. (6) AEl;exµE110-xo11'te.7111Ep xex1 auo'tOLX,iEc; 6ox Eiw11 1tou 1tE­ p1e.x ow HYDROGEN BROMIDE 'tou 3 ° (ex 't) TJ HYDRO­ GEN CHLORIDE 'tOtl 5 ° (ex 't) 8ex cpe.pouv xexL o't1c; Mo 1tAEu­ pic; E't1xe.nEc; ouµcpw110L µE 'tex u1to6Eiyµex'tex No. 6.1 xexL 8. flexpciypa:cpoc; 2: Ei61xe.c; 1tpou1to8foE1c; npoc; EX7tATJPWOTJ, ex1to 'tix µfoex (.LE'tOLcpopcic; xex1 ,:011 E!;o1tALO!J.O 'touc; . AEp10µ0,; A11 auaxEuexaiEc; 1tou mp1e.x ow exe.pLex 'tOu I O µe.x.p1 6 ° xex1 9° (y) (.1E'texcpipo11't<Xl OE XAELO'tO OX,7Jµex, i:o OX,Tjfl-Ol 80L EtlllXl ecpo6Lexaµe.110 (J-E xex'tciM71Ao El;cxEp1aµo. flupoaf3EO't1xac; auaxEue.c; 21 130 21 131 21 199 21 200 21 211 21 212 21 213 21 239 01 01ex'tci!;E1c; 'tOtl 1tEp18wp1exxou 10 240 (I) (f,) xexL 3 6E11 0ex 21 240 EX,O\JII Ecp<Xpµon OE (.LE'texcpopci IXMTJ ex1to EXEi1171 'tWII EucpAE- . X't(I)~ exEpiw11 T\ ex;1'tLXEl!J.E.~(l)II 7t0tl <X11;Xcpe.po11-i;ex1 O'tO 1tEpL6w p1exxo 220 0?2, T\ OE XE11ec; auaxeuexaLE,; 'tOll, 14 ° 7t0tl 1tEp1Ei X,1X11 'tE't~lex exEplex, 21 241 21 259 21 100 'O'tOl~ fJ-E'texcpipo11't<XL mEaµe.11ex 0Le.p1ex ii uypo1tm7Jµi11ex OLe.pLOL 21 260 21 104 ~>.exf,Epex 11ex 'tex exva:1t11Eua't1xci op1ex11ex ii 1tou Ejxuµo11ou11 xi11 1302 E<J>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) OIJ\10 OTjA1J'tTjpt1XOEwc; XIXt xo:plXX'tTJPL~OV'tlXt fl.E 'tO -ypixµµo: «'t» O'tO\I 1tiVIXXIX 'tW\I OIJOtWV, 'tO 7tATJPWfl.lX 'tOIJ OXTJfl.lX'tOc; 0o: EL\IIXt Ecpooto:aµivo: fl.E o:acpu~to1ovou~ 1tpoaw1ti8Ec; ( IXIIIX7tVWO'tTJpEc;) 't\17t01J XIX'tlXAA1JAlOIJ jllX 'tlX fl.E'tlX<pEpOfLE\IIX o:ipto:. 21 261 TTo:pix1po:cpoc; 3: .1tlX'tlX~Etc; 1EvtxiJc:; E~1J1t7lpE'tTJOEwc:; (aip~tc;) -21 299 21 300 21 320 Ot OtlX'tlX~Etc:; 'tOU 1tEp10wpt1XXOU 10 321 0o: ixou11 E<p1Xp- 21 321 µoriJ 1to: 'tlX Emxivou110: Eµ1topEuµo:-ro: 1tou o:vo:cpipoV'to:t 1to:po: xdc1:w OE 1toao1:11nc; 1tou ump~o:ivou11 o:ui:ic; 1tou xo:0opi~o v-i:o:t: BORON TRIFLUORIDE xo:t FLUORINE wu 1 ° (ix 't)' Ot ouaiEc; 'tOU 3 ° (ix 't) 'tOU 3 ° (~ ,:) EX'toc; 'tO!J ETHYL CHLO­ RIDE xixt i:ou 3 ° (r 't)· HYDROGEN CHLORIDE 'tou s 0 (ix ,:)· XIXt 'tlX u-ypo1tOt7l(-lE.IIIX o:iptiX ~IX0Eio:c; XIX'tlX<ptl~Ewc; 'tO!J 7 ° (ix) XIXL 8 ° (ix): 1000 XtAIX' Ot ouaiEc; i:ou 3 ° (~)· ETHYL CHLORIDE ,:ou 3 ° (~ 't)' VINYL CHLORIDE 'tOU 3 ° (r)· Ot ouaiEc; 'tO!J 4 ° (~)· XIXt 'tlX u-ypo1tOt7lµt110: o:ipto: ~o:0Etixc; xo:-i:o:cj,u~Ewc; 'tOU 7 ° (~) xo:t 8 (~): 10000 XtAIX <I>op111:ic; cpw1:t01:txic; auaxEuic; ·01:o:v µEi:o:cpipovi:o:t EU<pAEX'tlX dt&pto: iJ o:v1:tx&iµ&110: 1tou o:vo:cpipovi:o:t 01:0 1tEpt6wpto:xo 220 002, aE ivo: XAEta'to OX1Jfl.lX OE\I µ1topouv \/IX Etaipxoll'tlXl 1tpoaw1t1X 7t0U cpipou11 cpw­ 'ttO'ttXEc; OUOXEuic; EX'toc; IX7t0 cpop711:ouc; AIXf1.7t'tTjpEc:; <JXEOllXOfl.E­ vouc; XIXL XIX'tlXOXEUIXOfl.EVOUc; XIX'tlX 1:po1to WO'tE \/IX µ 71 µ1topouv vo: o:vo:cpAi~ouv 01toto:6iJ1ton o:ipto: 1tou µ1topEi 110: ixou11 Et­ axwpiJaEt O'tO EOW'tEptXO 'tOU OXTJfl.lX'tO<;, K&vi.:;; OE~IXµEvi.:;; rto: O'tlX8Eptc; OE~IXfl.EVE<; (OE~IXfl.EVOIXU'tOXLV7J't1X), IX7tOOUV1Xp­ (-lOA010UfLEVE<; OE~IXfLEVEc;, OUO'tOtXLE<, 6oxEiwv XIXt OE~IXf1.EVO­ XO\l'tE7lVEp, ~AE7tE E1ti07Jc; ,:o Ilpoa0tp't7]fl.lX A, 1tEpt6wpto:x6 2201, 14°, ~71µEiwa7J I. TTo:pdc-ypo:cpoc; 4: Et6txic; OtlX'tlX~Etc; 1t0U o:cpopouv 'tTJ cpop'tW07], Excpop1:wa71 XIXl XEtptaµo A1to:,opEU01J µtx'tTjc; cpop,:waEwc; OE E\IIX OX1Jfl.lX Avi:txetµEvo: 'tTjc; Ko:'tTj1opio:i; 2 XAEtaµivo: OE auaxEuo:aiE,; 1tou cpipouv E'ttxino: auµcpwvo: µE 1:0 u1to8Etjf1.IX No. 3 OEV 0o: cpopi:wvovi:o:t µix~ OE ivo: ox71µ0: µE ouaiE,; iJ o:vi:txEifLEVIX i:wv KiX'tTjjOptowv lo:, I~ TJ I, 1tOU 7tEptEXOV'tlXt OE OUOXEUIXOiE,; 7tOU <pipouv µio: iJ ouo E1:txi1:1:Ec; auµcpwvo: µE 'to u1t66Et1µo: No I. T61to1 cpop'twaEwc; XIXt Excpop'tWaEwc; (1) Ot 1tixpo:xix'tw Ep1o:aiE,; 1X1to:1opEuov'to:t (ix) Cl>op'tW07J YJ Excpop,:wori 'tW\I 7t1Xp1XXIX'tW OUOtW\I OE 07]­ µoato xwpo OE XIX'tOtXTjµiv71 7tEptoxiJ xwpic; EtOtXTj IXOEtlX IX7t0 i:ti; o:pµ66tEc; o:PXic;: HYDROGEN BROMIDE, XAwpiv7J, 8to~Ei6to ,:ou o:~w,:ou, oto~Eioto ,:ou 0Eiou iJ cpwo1i11to (3 ° ( IX i:))· HYDROGEN SULPHIDE (3 ° (~ 't)· xo:1 HYDROGEN CHLORIDE (5° (ix i:))· (fj) <Dop'tW07J "I EX<pOp'tWOT) 'tW\I 7t1Xp1Xm~vw UltO (ix) IXVIX<pE­ poµivwv OUOtW\I OE 67JµOato xwpo o:Uo:xou IX7t0 XIX't0tx71µiv71 1tEPtoXTJ xwpic; 1tpo71-youµEV7j EI001toi71071 'tW\I 0tpµo8iwv o:p­ xwv, exi:6c; o:v 0t 1tpocxvo:cpEp6µEvEc; Ep1o:oiE,; 81xo:toA01ou111:ixt rux aof30tpouc; Ao-you.; IXO<plXAELIXc;. (2) A11 ,10: 01tOto01J7tOU M-yo Ot Ep-yixafac; XEtp1aµou 1tpE1tEt VIX jLIIOU\I OE 87]µ6010 xwpo, 'tO'tE: 01 OUOLE<; XIXt 'tlX IXll'ttXELl'-EIIIX 6to:cpopE'ttXWII EtOWII 60: xwpi­ ~01/'tlXI auµcpw111X µE i:tc; E'ttXE't'tE<;' XIXt ~UOXEUIXOiEc; EipOOtlXoµi11Ec; 1,!E µialX XEtptaµou 61X OtlX't7]­ pouvi:1X1 E7tL1tEOE<; XIX'tCX 'tO XPOVO 'tOU XEtptaµou. 21 322 21 352 21 353 21 354 21 377 21 378 21 379 21 399 21 400 21 402 21 403 21 404 21 406 21 407 21 408 21 413 XE1p10µ6c; XIXI O'tOt~IXOlot ( 1) 01 OUOXE!JIXOLE<, OEII 60: pi1t'tO\l't1Xt TJ U1tO~IXAAO\l'tlXl OE 1tpoaxpoua7J. (2) To: 6oxEio: flex O'tOt~IX~Oll'tlXl XIX'tot 'tE'tOto i:pcmo WO'tE O'tO OXTJfLIX IIIX µ7] µ1topot1V I/IX IXll1X'tp1X7t0tlll TJ I/IX 7tEOOU\I XIXt 0o: xCXAu1t1:0111:cxt ot 1tixpotxdt1:w 1tpoii1to6iaEti;: ( ex) 01 xuA1118pot 1tou o:votcpipo111:ott 01:0 1tEpt6wptcxxo 2212 (I) (ex) 60: 1:01to6E1:ou111:o:t 1tcxpill71Ao: iJ aE op0ic; 1w11iEc; 1tpoc; 'tOII XIX'tlX µiJxoc; ot~Ollot 'tOU oxiJµo:1:0.;· Ell'tOU'tOt,;, IXU'tOL ltOU [3piaxo111:o:t 1tA71aiov wu E1xdtpatou i:mxwµot'toc; µ1tpoa1:ix flex 't01tOf1E'tOUll'tlXt OE opfle,; 1<,.llliEc; 1tpo,; 'tOII 1tpOIXIIIX<pEpOf1.EIIO Ot:~01/IX, Ot xo111:oi xuAtvopot µE1ii)..71c; oto:µhpou ( 1tEpi1tou 3 0 EXcx 1:oai:dt XIXL 1t1XIIW) µ1topE[ \lot O'tot{jCX,OV'tott XIX'tlX µiJxoc; µE 't'1) OUOXEUTJ 1tpoa1:o:aio:c; 't'1)<, ~IXA~i6o:c; a1:po:µiv71 1tpoc; 'tO µiao11 'tOU OXTJfLCX'toc;. Ku1,.t116pot 1tOU Elliott o:pXE't(X O'tCX0Epoi 11 µE1:o:cpipo11't1Xt OE xcxi:ill1JAE<; auaxEuic; 1tou Eµ1to8i~ou11 1X1tO'tEAEaµcx1:txdt 't'1)11 IXIIIX'tp01tTJ µ1topEL I/IX 't01tOflE'tOUll'tlXt opfltot. KuAtv6pot 1tOU 't01t06E'tOUV't1Xt Eltl1tEOIX 60: acp1111w.110111:1Xt 11 flex 1tpoaOtVOV'tlXt µe 'tE'tOtO 'tp07t0 WO'tE I/IX fL7J µ1topouv I/IX fLE 'tlXXt\1'1}6ou11• (fj) i\OXELIX 7tOU 1tEpttXOU\I 1Xtpt1X 'tOU 7 ° (IX) TJ 8 ° (IX) flo: 't0 1tOflE'tO\lll'tlXt 1tlXll'tlX µE 't'1J 6ia71 jtlX 't7]11 07tOLIX ixow <JXEOtlX­ ani XIXt flo: 1tpOO'tlX'tEUOll'tlXt XIX'tot 07tOtOU6TJ7tO'tE E116EXOµEVOU VIX U7tOO'tOUII [3)..dtfjE,; IX7t0 CXAAE<;; OUOXEUIXOLE,;. TTcxpixypcxcpoc; 5: Et6txe.c; 6tcxi:~Eti; 1tou cxcpopou11 1:71 AEti:oup1icx 1:w11 ox71i,.tcx1:w11 ~Tjµ1X1107J XIXt X1XPIXX't'1)ptaµoc; ox71µdt1:w11 OxiJµcxi:o: µE ai:o:0Epe.c; TJ cx7:oawo:p~oA01ouµE~Ec; 6E~cxµE­ ve.c; 7tOU 7tEptE.XOUII TJ ELXIXII 7tEptE~Et ( XE\IE<, 6E~1XµE11Ec;, IXX0tfl0tp­ 'tE<;) ouaiEc; 1tou o:votcpipovi:cxt 01:0 Ilo:pixpi:71µ0: 8.5 0ct cpipouv i:tc; 1:1Xpixxix,:w ntxi-i:i:Ec; xo:t 01:tc; Mo 1tAEupic; xixt 1tiaw. Aipctc;, Ujpoc;, ~ct0Et<X<, XIX'tCX(jlu~7Jc; Aµµwvict Aµµwvict, Ot1XAuµµiv71 OE vEpo Boui:ct6tE\ltlX Boui:dtvto 1-BUTYLENE (I-BUTENE) CIS-2-BUTYLENE (CIS-2-BUTENE) TRANS-2-BUTYLENE (TRAN S-2-BUTENE) CARBON DIOXIDE 1tEpte,xov ETHYLENE OXIDE XAwpi1111 I-CHLOR0-1, 1-DIFLUOROETHANE (R 142[3) KuXA01tpo1t1XVto DICHLORODIFLUOROMETHANE 1tEpti­ xov 12 O'tlX EXIX'tO ETHYLENE OXIDE OE 61xo I, 1-DIFLUOROETHANE (R 152ct) I, 1-DIFLUOROETHYLENE (VINYLIDENE FLUORIDE) DIMETHYLAMINE DIMETHYL ETHER ETHANE ETHANE, urpo, f3o:0Etotc; XIX't0tt/iu;Ewc; ETHYLAMINE, cxvu8p71 ETHYL CHLORIDE ETHYLENE, u-ypo, f30t6E1cxc; XIX'tctcj,u;ewc; ETHYLENE OXIDE 1tEptix o11 61o;Ei6to i:ou 1XVflp1XXIX ETHYLENE OXIDE 1,!E IX~W'tO HEXAFLUOROPROPYLENE (R 1216) l'opOj0\10, UjpO, ~ctflEt<Xc; XIX'tctcj,U;EW<, Bpwµtoux o u6po16vo XAwpwuxo u6po16vo 8etoux.o u8po,ovo 5 6.1.-'- 8 6,1.-i- 8 3 3 3 3 3 3 6.1 + 8 3 3 3 + 6.1 3 3 3 + 6.1 3 3 3 3 , 6.1 3 + 6.1 3 3 + 6.1 3 + 6.1 6.1 3 6.1 , 8 6.I + 8 3 + 6.1 21 414 21 415 21 499 21 500 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI .dEYTEPO) 1303 Ioo~ou'tci:11to laof3ou'tuAEvto (foof3ou'te11t0) M£8ci:11to, u1po, ~ex8£tci:c; xex'texcj>u!;Ewc; M£8u).exµ!1171, ci:w6p71 METHYL BROMIDE METHYL CHLORIDE M£8t>Atxii p.Epxex1t'tci:1171 METHYL VINYL ETHER Mi1µex'tex I, 3-BUTADIENE xexL u6po1011&:11 8pexx£c; Mi1p.ex'tex u6po1011exv8p&:xw11 (Mi1exp.'tex A, A 0, A I, B xext f) Mi1µcx.'tex METHYLACETYLENE xext PROP ADIENE µ£ u6po1011&:116pexxac; (Miy­ µex--cex P I xext P2) Mi1µex'tex METHYL BROMIDE xext XAwpo 7tLXpillTj Miyµex'tex METHYL CHLORIDE & XAwpo 1ttxpi1171 Miyµex'tex METHYL CHLORIDE & METHYLENE CHLORIDE Cl>uotxo 'exepio, u1po, (3ex8atci:c; xex'tcxcj>u!;71c; &to!;ai6t0 'tou ex~w'tOu N~z (NITROGEN PEROXIDE, NITROGE1~ TETROXIDE) Movot£i6to 'tOU ex~wou N O • Movot£i6to 'tOU ex~W'tOU i-&20, uypo, f3ex0uixc; Xex'texcj>u ~£We; Otuyovo, uypo, f3ex0£t1Xc; xex'texcj>u!;Ewc; Cl>w01ivto TTpon:ci:vto . 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Tiexpci:1pexcpoc; 6: Me.i:exf3exi:txic; 6tex'tcxtEu;, exvexxA TJOEtc; xext 6Lex't1X/;Etc; Et6txac; 1tex optop.E11Ec; x wpEc; CExouv Ecpexpµon µovo Ot YEVtxic; 6texi:ci:!;Etc; 'tOU Mipouc; I) Kex't'lj,optex 3: EucpAExi:ex u1pix fEvtxci: ("Ex ouv Ecpexpµon µovo Ot TEVLXic; 6texi:ix1;uc; -:ou Mipouc; I) Ton:o8i't'ljO'lj Em1pexcpiic; oE 6EtexµE110-xo111:e7111Ep. Tex 6E!;exµE­ vo-xOVta71vEp n:ou n:Eptax ouv TJ ex ouv n:e.ptitu ouoiEc; ,:ou 1 ° µix.pt 6 ° , 11 ° µix.pt 2 6 °, 31 °, ii 3 3 ° Sex cpipow xext ow; Mo 1tAEupic; E'ttXE't'tex ouµcpwv71 µ£ 'tO un:o6EL"(µex No 3. ExEi11ex 7t0U 7tEptixow TJ ixou11 1tEptitEt ouoiEc; ,:ou 6 ° Sex cp!pow E1ti 1tAEOII £'ttxE'tUc; ouµcpw11Ec; p.E 'tO un:o6uyµex 6. IA. ExEivex 1tou 1te.ptixow TJ ix.ow 1tEptitEt ouoiEc; i:ou 11 ° iii­ x.pt 20 ° 8ex cpipow £1tt n:Hov E'ttXE't'tEc; ouµcpwvEc; (LE 'tO un:o 6£tTp.<X 6.1. '' Ex£i11ex 1tou 1tEptixow TJ ix ouv mptitEt ouoiEc; 'tOU 21 ° µi­ X?t 26 ° 8ex cpipow £1ti n:Hov E'ttx!'tnc; ouµcpw11Ec;- p.E ,:o un:o 6e.t1p.cx No 8. 21 509 21 510 21 599 21 600 30 999 31 000· 31 099 31100 31 129 31 130 31 131 31 199 TTexpcx1pexcpoc; 2: Et6txic; n:pou1to6icmc; 1tpoc; EX1tAiipwo71 exn:o ,:ex µiaex p.E'texcp9pixc; xext 1:011 E!;On:Atoµo 'touc; • ('Ex ou11 Ecpexpµo"(TJ µovo ot 1E11txic; 6Lex'tixl;Etc; i:ou Mipouc; 1) 31 200 TTexp&:1pexcpoc; 3: fEvtxic; 6tex'tixl;uc; E!;u1t71pE1:iioEwc; (oip(3tc;) -31 299 En:i{3AEo/71 ox 71µ&:i:wv Ot 6tex'tixl;uc; 'tOU 1tEpt8wptexxou 10 3 21 Sex axow Ecpexp(LO"(Tj 1tex 'tex Emx!v6wex E(L1tOpEu(Lex,:ex 1tou exvexcpipo111:ext n:expo:x&:,:w OE n:ooo't71uc; n:ou umpf3exivow i:tc; n:expexxix'tw: . OuoiEc; 'tOU 1 ° µix.pt 5 ° (ex) xexL ((3), 6 ° (ex) XO:L (~) XCXL 21 ° µix pL 26 ° 10.000 XLAIX. 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Xup1aµoc; ltCXI ato1(3cxaicx ( 1) fi.oxeicx XCXI OUGltEUCXOiac; ltOU 1tEptEXOUV OUaiac; 'tOU } 0 xcx1 tou 3·0 6Ev 9cx u1to(3iiUovt0tt OE 1tpoaxpoua7].' 0cx ,:orco0a­ 'touvtcxt xcxtcit 'thoto tp61to wa'ta vex µT] µrcopouv vex cxvcxi:pcx 1touv i) vex 1tiaouv i) vex µEi:cxtomatouv xcxtix 01to1ov67l1toi:a ,:po1to. • (2) H XPTIOTJ Euxo>.cx cxvcxcpAE1oµEvwv u1.1xwv 1tcx 'tTJ aw1 (3cxGicx auaxEu0ta1wv. atcx ox'T]µoti:cx cx1tcx1opi;uncx1 Ilotpcit1pcxcpoc; 5: Et6txac; 61cx'tcx!;Etc; 1tou cxcpopouv 'tTJ AEt'toupricx ,:wv oxr1µ1i'twv W1µcxva71 Xotl xcxpotlttT]ptGµoc; ,:wv OXTJIJ-IX'tWV (1) Ot 6tottix!;E1c; tou 1tEpt9wptcxxou 10 500, 1tcxp<i1pcxcpot (1 ), (7) ltott (8), 9ot EXOUV Ecpotpµo1T) IJ-OVO "(tot tTj IJ-Etotcpop,x OUGIWV 'tO\I } 0 IJ-EXPI 4 ° ltotl 'tOU 6 °. 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ExEivac; ltOU 1tap1ixouv T) 7tEptEixcxv ouaiEc; 'tO\I ~ 0 9ix cpipouv, mi 1tAiov, attxinEc; auµcpwvcx µa to umj6E11µcx No 4.3 I1cxpii1p. 6: Mncx(3cxt1xic; 61ott<X!;Etc;, cxvotXAT)GEtc; xcx1 6tott<X!;Etc; EL6titEc; "(lot optOf.1.EVEC, xwpEC, ('Exouv acpcxpµon µovo 01 "(EVtXEc; 6tcxtix!;a1c; tO\I Mipouc; I) Kott7]1opicx 4.3: OuaiEc; 1tou cxvcx6i6ouv EucpAaxtcx <XEptot OE EltlXCj)1I fl-E tO vapo fEvtxii CExouv Ecpotpµon µova 01 '(EVtxic; 61ot't1X!;atc; tOU Mipouc; I). 42 300 42 320· 42 321. 42 322 42 377 42 378 42 379 42 399 42 400 42 402 42 403 42 404 42 413 42.414 42 415 42 499 42 500 42 501 42 599 42 600 42 999 43 000 43 099 Tiotpix,pixcpoc; 1: Tpo1toc; µE'totcpopcxc; 43 100 MEi:otcpopa xuµcx -43 110 Koxxo1 µot)'VT]aiou, Emxp1aµivo1, i:ou 1 ° (6), cxv9pcxxcxa~e.- 43 111 a,:10 i:ou 2° (ex) xcx1 1tupmxo cxa(3iatto (CALCIUM SIU CID E) aa (3w1.ouc; tou 2 ° (6) µ1topouv VIX µEi:otcpipovtott xuµcx oE Et6txcx E!;o1t1.1oµe.vcx oxTJµ<Xi:cx. Tex cxvoi1µcxi:cx 1tou XPTJOtµo 1to1ouv'tott itiX cpop1:WGTJ 11, EXcpop,:waTj 0cx ELVCXt GE 0fo7] YCX ltAELVOVt<Xl apµ711:1xcx. ME'totcpopcx OE XOV'tETJVEpc; Mtxpii xovi:E'l}VEP 1tou XPTJOtµo1totouvtot1 11cx 'tTJ µE1:0tcpopcit xuµcx tWV OUOIWV ltOU cxvcxcpe.povi:cxt G,:O 7tEpt0wptotxb 43 111 6cx Eivcx1 auµcpwvcx (J.E ttc; 61cxtcit!;uc; cxu,:ou i:ou 1tEp10wptixxou 1t0U <Xcpopouv OXTJ(J.IXtlX Xott tCX 6oxaicx tWV O;(Tj(J.<X1:WV • XotpCXXtljptaµoc; tWV 6E!;otµEvO-XOV'tETJVEp dE!;otµEvo-xovti71vEp rcou rcap1i;couv 11 1taptEi;ccxv ouaiEc; 'tTjc; Kcxt711opicxc; cxu't11c; 9cx cpipouv xcxt ottc; Mo 1tAaupic; Ettxhtcx ouµcpwvcx µE to U1t06atrµcx No.4.3. ExEivot ltOU 7tEpti;co:iv T) 7tEptEL;(IXV OUGiEc; tOU 4 ° 9ix cpipouv Elti ltAiov E1:tltE'ttEc; auµ­ cpwvcx µE to u1tooE11µcx No. 3 xcxt 8. Ticxpix,potcpoc; 2: E161xe.c; 1tpoc; X<XAU<j,T] 1tpoii1to0aaEtc; IXTCO tot µe.acx µEi:otcpopcitc; ltCXI ,:ov a!;o1tAtaµo 'tOUc; TultOI OXTJf.lCXtoc; Emxiv6uvEc; ouGiac; tljc; Kott7]1opicxc; 4.3 OE ouoxaucxGiEc; 9cx µatotcpipovtotl OE ltAEIOtlX 1l E1tEVouµivcx O;(ljµottot. Evtoutotc;, • 6oxeiix ltO\I 1tEptEXOUV otll9potltotU0(3E01:tO tOU 2 ° (ex) µrcopou\l ETCLO'l}c; vex µEi:otcpipovi:cxt OE cxvoLxtcit OXT)f.1.CXtot. 43 112 43 117 43 119 43 129 43 130 43 131 43 199 43 200 43 203 43 204 43 205 43 299 Ilotpixrpcxcpoc; 3: r a111xic; Olot't<X!;Etc; E!;U1tT]pEt1IOEWC, ( oip(31c;) Ot 61ottct!;E1c; tou 1tEp18wp1cxxou 10 321 6cx i;couv E',)otp- • 43 321 µon 01:IX ElttXLV6UVot Ef.l.ltOpEuµoti:ot ~OU CXVotcpEpOvtott 7totpot XIXtW oe rcoaot'l}tEc; rcou urcEp(3cxivouv w;; xcx0op1,oµE11Ec;: AAx<XAtxcx µhcxUcx xcx1 ouGiEc; 1tou 1tEpti;couv otAXCXAtxcx µe.­ tCXMot tou 1 °, u6pi61cx cxAxcx1.1xw11 f.La1:IXAWV i:ou 2 ° ((3) xott ouGiEc; tou 4 ° : 10 000 XtA<i. • 43 322 n . 4 E O . 6 ·i:- • • -43 399 cxpcx1pcxcpoc; : t txEc; 1cx1:cx-.E1c; 1tou cxcpopouv 'tTJ cpoptWOTJ EX<j>OptWOTJ XCXt XElptGfLO AmxropEUOTj µ1xti)c; qmptWGEWc; OE e.vot O;(ljfJ,CX OuoiEc; 'tTJC, Kott'l}1opicxc; 4.3 6av 0cx cpop1:wvo111:cx1 µcxl;i aE EVIX o;c71µcx µE otiaiEc; 11 IXVttltaiµavcx 1:W\l -ltllt1:lj"(Optwv 1 ex, 1 (3 11 11 1tou 1tap1e.xo11tcx1 aE auaxEucxaiac; 1tou cpe.pouv µicx 1l Mo E'tt­ xhtEc; auµqiwvcx µE i:o u1tooa11µcx No 1. XEtptaµoc; ltotl O'tOL(3otoicx 01 ouaxwcxaiac; 6cx a1:01(3ix,011tcx1 ato O;(l]µot xott<X thoto rpo1to ~an vex fJ,'I} µ1topou11 VIX µai:ottomatouv µe.ocx a' ot\ltO. 0ot 1tpoatottEUO\ltott XCX1:IX Oltotota6111totE 1:p1(311c; 11 1tpoaxpou­ OEWc;. Kot'tet. to XEtptoµo twv ouoxEuototwv, 0cx 1.cxµ(3citvov'tott Et6txcx µhpot WCltE VIX fJ,l)V e.A6ouv OE Eltllt<plj fJ,E ,:o 11Epo. Ilotp<X"(potcpoc; 5: E161xic; 6toti:<i!;Etc; ltO\I cxcpopouv 1:Tj Aettoup1icx twv o;c71µiitw11 ~TJl'-IXVOTJ Xott xcxpotx'tTjptoµoc; tWV OX"ll'-IXtWV. 0xTJf.l.CX'tcx fLE oi:ot0Epe.c; 1l cx1toouvcxpµo1.01ouµEvEc; 6E!;otµE 11ic; ltOU 1tap1e.xouv 11 7tEpLEL;(IXV ( ltEVEc; 6E!;otµavic;, cxxcx0cxpt­ ottc;) ouaiEc; 'tTjc; KottTj1opicxc; otUtl)c; 1tou cx11cxcpipovtott oto Ticx­ pixp'tT]µot B. 5 6ot qie.pouv XCXt Otte; 6uo ltAaupic; XCXt 1tiaw m­ XE'ttot ouµcpwvcx µa to U1to6urµcx No. 4.3. ·ooac; 7tEptEXOUV Tj 1tEptElxcxv ouoiac; tO\I 4 ° 0cx cpe.pouv Elti ltAE.OV Ettxh,:ac; ouµ­ cpwvot µE 'tot u1to6Ei1µcxtot No.3 xcxt 8. Tiotpix1pcxqioc;· 6: Mai:cx(3cx'ttxic; 61cxt<i!;E1c;, cxvcxu11ouc; xcxt 6tot1:1X!;uc; Et6tXEC, 1tot optOfJ,EVEC, ;(Wpac; 'Exouv aqicxpµon µ0110 Ot "(EVtltEc; 6tcxtdt!;atc; 1:0\1 Me.pouc; I) 43 400 43 402 43 403 43 404 43 413 43 414 43 415 43 499 43 500 43 501 43 599 43 600 50 999 1306 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) Kcxnrropicx 5 .1: Ol;Etowwcic; ouoiEc; fEIILXCX: ('Exou11 Ecpcxpµon µ0110 OL "'(EIILXE<; OLCX,cxl;w;; 'tOU Mipouc; I) ME,cxcpopcx X,VµIX (1) OuoiEc; 'tOU 4 ° µexpt 6 ° XIXL 7 ° (ex) XIXL (f3) µ1topEi vex µn1XcpEpOV'tCXL xuµIX O(XV 7tA7jpEc; cpop,io. (2) OuoiEc; ,ou 4 ° XIXL 5 ° 8cx µE,cxcpipoV'tCXL oE µE,CXMtxouc; Otl/OLX'tOU<; «xcxoouc;• ( OXTJµCX,IX xcxoouc;) XIXAuµivouc; µE CXOLCX­ f3poxo XCXL µ71 EU<pAEX'CO cpuUo, TJ OE µE,CXMLXCX XOV'tE7IVEP ((,AE7tE 1tEpt8wpLcxxo 51 118 (2). (3) OuoiEc; 'tOU 6 ° XCXL 7° (ex) XCXL (f3) 81X µE,cxcpipov,CXL OE XAEL<J't(X OXTJµCX,IX TJ OE OXTJl-'-CX't(X XCXAuµivcx µE IXOLcxf3poxo <X(j)AEX'tO cpuMo, 'tWV ox71µcx,wv XIX'CCX<JXEUCXaµivwv xcx,' CXU'tO ,011 ,po1eo Ei,E 1tcx,i 71 ouaicx oav µ1eopEi vex eA8Et aE rncxcpTJ µa ~UAO TJ 07tOLOOTJ1tO'tE illo XCXU<JLµo UALXO Et'tE O'tL OAOXA TJPTJ E1ttcpCXVELIX 'tOU OCX7tEOOU XIXL 'tWV 'totxwµcx,wv, a.v XIXt"'(E'tlXL, EXEL EcpootCX<J'tEt µa cxouxf3pox71 XCXL OCXCXUO'tTj EmcpcxvEL(X TJ EXEL "'(LI/Et E7tEl;EP"'(CX<Jt(X µa ouaiEc; 7COU xcx8to'tOUV 'tO l;uAo cxcpAEX'tO. 51 000 51 099 51100 51 110 51 111 51 112 ME,IXcpopcx OE XOV'tE7IVEP -51 11 7 Eu8pcxuauc; (JU<JXEUIX<JtEc; µE 'tTJV EVVOLCX 'tOU mpt8wptcxxou 51 118 10 014 (1) XCXt EXEtVE<; 7COU 7tEpEtXOUV U7tEpOl;ELOLO 'tOU uopo "'(OVOU TJ OtCXAUµIX,CX 'tOU U7tEpol;EiOtOU 'tOU uopO"'(OVOU 'tOU 1 ° TJ TETRANITROMETHANE 'tOU 2 ° OEV µ1eopouv VIX µe,cxcpi poV'tCXt OE µtxpcx XOV'tETJVEp. (2) KoV'tETJIIEP 7tOU 1tpoopi~OV't(Xt "'(LCX 't7I µE,cxcpopcx OU<JtWV ,ou 4 ° xcxt 5 ° 81X Eivcxt xcx,1Xaxwcxaµev1X cx1eo µhcxUo, 81X Ei­ vcxt <J'tE"'(IXIICX, 8cx EtVCXL XCXAuµevlX µE XCX7tCXXt TJ µE IXOLcxf3poxo q>uMo 1eou 80t IXll'tEXEt 0,71v x1Xua71, xext 8cx EtVIXt i-cat XIX'tCX­ axEuataµivo wau ot ouaiEc; a,o xov,arivep VIX µ71 µnopouv 111X EA80UII OE E,~CX(j)TJ µE l;u)..o TJ 07tOL007J7tO'tE CXMO xcxuotµo UAtXO. (3) KoV'tETJVEp 7COU 1tpoopi~OV'tCXL "'(llX 'tTJ µE,cxcpopcx OUOLWV ,ou 6 °, 7 ° (ex) xcxt (f3) 80t EtVCXL xcx1,.uµe.v0t µE xcx1ecxxt TJ IXOLCX­ (,poxo cpuMo 7COU OtV'tEXEt O'tTJV X0tua71 X(Xt 81X ELVCXL XCX't<X­ OXEUCXaµivat xcx,cx ,po1eo wau 1l ouoicx µfoot o,o xov-ciTJvEp vat µ71 µ1topEi VIX EA8Et OE E1tCXcp7j µE l;uAO TJ 01tOLOOTJ1tO'tE CXMO xcxuatµo UAtXO TJ O'tt OAOXATJP71 71 EmcpOCVEtot 'tOU OIX1tEOOU Xotl 'tWII 'tOtXWµOC,WV, Otl/ EtVOtt XCX'tCX<JXEUIXoµe.vot ot1t0 l;UAO, e.xouv E1ttXCXAucp8Ei µE otOtcxf3poxTJ E7CL(j)CXVELIX 1t0U IXV'tEXEt O'tTJV XotUOTJ T) EXEL EmXPt~Ei µE SODIUM SILICATE TJ 1t0tpoµotcx ouaicx. EmxoU71071 E'ttxEnwv OE 0El;0tµEvo - xov,e.71vEp 6El;CXµEVO XOll'tE7IVEp 1t0U 1tEptEXOUV TJ 1tEptELXCXV OUOtE<; CXU'tTJ<; 51 130 ,71.;; Kcx,71ropicxc; 80t cpipouv XIXL O'ttc; Mo 1tAEUpec; E'tLXE't'tE<; auµcpw110t µE 'tO U1t00Et"'(µot No. 5. ExEivEc; 1tOU 1tEpLEXOUV TJ 1tEptEtXOtll U1tEPXAWptxo ol;u (PERCHLORIC ACID) (aE Otot AUOTJ) ,ou 3 ° i 8cx qiipouv, E1ti 1tAe.ov EnxinEc; auµcpwvcx µE ,o unoou1µcx No. 8. 15 131 51 199 Ilcxpot"'(patqioc; 2: Etotxic; 1tpoii1to8fouc; 1tpoc; EX7tA7JpWaTj IX7t0 't(X µe.~cx µE,atcpopdtc; Xott 'tOV El;01tAtoµo -coui;. 51 200 0xTJµOt,Ot µE a,0t8Epe.c; TJ CX1tO<JUVotpµo)..o1ouµEvEc; OE!;IXµE- -51 219 vie;. Ot 1tcxp0tX<X'tW OtCX'totl;Etc; 8ot EXOUII Ecpcxpµon "'(LOt 't7J µE,IX- 51 2 2 0 (j)OpCX U"'(pWII 'tOU 1 ° : ( 1) Kou(,outlto (at) Ex,oc; (XV 'tO xouf3ouxAtO 'tOU OOTJ"'(OU ELIICXL XIX'totOXEUot­ oµe.110 Ot1t0 1tupiµ1Xxcx UAtXCX, 8cx 't01t08E'tEt'tlXt O't7IV 1tAIX't7J 'tOU xouf3ouxAtOU 'tOU 007J"'(OU µE,CXMLXTJ (X01tt0ot 'tOU iotou 1tA<X 'tOU<; µE 'tTJ oEl;cxµEVT) • • (f3) 01totcx07J1tO'tE 1tcxpix8up0t o,o 1tiow µe.poc; ,ou xouf3ou­ XALOU ,ou 00711ou Tj O'tTJ µE,CXMtx71 0to1tiocx ( 1tcxpcx1th1Xoµot) 8ot tlEi11011,cxt Epµ71,txix. 0<X Eivcxt xcx,cxoxwcxoµe.vcx cx1to 1tupi­ µcxxo "'(tCXAi CXO(jl<XAEicxc; XotL 80t EXEL 1tupiµcxxcx 7tA<Xiotcx· (r) 8cx U1t1XPXEt EAEU8Epo OtlX<J'tTjµ<X oxt µLxpo,Epo CX1t0 15 EX. µE,cxl;u ,71,; OEl;cxµEVTj<; X<Xt 'tOU xouf3ouxALOU 'tOU 007l"'(OU 71 'tTj<; 0ta1tiocxc; {1totpCX1tE'tCX<Jµcx,oc;). (2) Aµcxl;wµcx Ox7Jµcx,oc; /!av 8cx Xfl7IOtµo1tOtEt't(Xt l;uAo ( Ex,oc; <XV XCXAU1t'tE't<Xt µE µe. ,CXAo 71 xcx,cxU71)..o ouv8E,txo uAtxo) 1tcx -c71v xcx,!XOXEUTJ 01eowuo711eo,E ,µ71µcx,oc; .ou oxTJµcx,oi; 1tou f3pioxE,<XL o,o Eµ1tpoc; µipoc; 'tOU 1tioow ,mxwµix,oc; 1tpoo,cxoi1Xc; {1t1Xp<X1tE'tCX­ aµ1X,oc;) 1eou 1tpof3Ae.1tE,cxt 0,71v mxpcx1edtvw mxplX"'(plX(j)O (I). (3) Kt1171,7Jpcxc; 0 XtV7l'tTjpCX<; XIXt ( EX'tO<; 07tOU 'tO OX7J(lCX XLVfr:~t (lE XtV7J­ 't7lpCX ll'tTJ~EA) 71 OE!;IXµEVTJ xcxuoiµou 81X Eivcxt wr:08E,71µe.v1X µ1tpoo,cx IX7t0 'tO 7tt0W ,oixwµIX 'tOU xouf3ouxAtOU 'tOU OOTJ"'(OU "I ,ou 1t1Xp1X1tE,dtaµ1X,oc;, TJ cxv ELVIXt -co1eo8E,71µe.v1X OtlXcpopE,txcic 81X 1tpOO'tlX'tEUOV't1Xt EtOtXCX. (4) Etotxoc; El;o1tAtaµoc; TIX OXTJ(llX'tot 81X e.xouv 1tlXVW a' IXU'CIX OE!;cxµEVTJ XWPTJ'tLXO­ 't7l'tlX<; 1tEpi1tou 30 )..[,pw11 vapou. H OEl;IX(lEVTJ VEpou 81X EllllXl ,01to8E,71µiv71 oao -co ou11cx-co11 mo El;1Xocp1XAtaµe.1171, XIXt 81X EXEL µfolX a-co vEpo 1eou itEpte.XEL IXV'tt<pux-ctxo itou OEV 1tpoof31XAEt ,o oe.pµIX XIXt ,ti; f3AEVO"'(OVOU<; IXOE.VEi:; XIXt OEV CXV'ttopcx x71µtxdt (lE ,o cpop-cio. 51 221 51 299 Ticxpcx1p1Xcpoi:; 3: fEvtxe.i:; oux,cxl;uc; El;u1t71pE,7JOEwi:; (oipf3u;;) E1tif3AE<p7J ox71µcx,wv Ot Ot<X'tCXl;Eti:; 'COU 1tEpt8wpLIXXOU 10 321 81X exouv Ecpcxp­ µon <J'CIX E7tLXtVOUIIIX Eµ1topEuµ1X,IX 1tOU IXVIX<pEpOV'tlXL 7t1Xp1X­ XCX'CW OE 1tOOO'C7l'tEi:; ltOU U1tEpf3cxi11ouv ,tc; IXVIX<pEpoµEvE,;: Ou­ oiEi:; -cou 1 ° µe.XPt 3° xcxt 9°(cx): 10.000 XtAot 51 300 51 320 51 321 51 322 51 399 Ticxpcxrpcxcpoc; 4: Etotxe.c; Ot<X'totl;Et<; ltOU cxcpopouv 't7J cpop,wo71, EX(j)Op-CWOTJ XIXt xuptaµo Ait<X"'(OpEUOTJ µtX'tTj<; cpop,woEwi:; OE EV<X ox71µcx (1) OuoiEc; -c71c; Kcx'tTj1opi1Xc; 5.1 itou 1tEptexov,cxt OE ou­ oxwcxoiEc; itou cpipouv µicx 71 Mo Enxe.nE,; ouµcpwvcx µE ,o u1eooat1µ1X 5 OEV 81X cpop,w11ov,cxt µcx~i OE e.vcx OXTJ(l<X µE ouoiac; "I CXV'ClXEtµEv<X 'CWV Kot'tTj"'(Optwv llX, lf3 TJ 11 ltOU 7tEpte.xov,cxt OE <JU<JXEUOtOLEi:; 7t0U cptpoUY (lL<X TJ O\JO E'ClXE't-CEi:; ouµcpWIIIX µE co uitoOEt"'((llX No. 1. (2) OuaiE,; ,71,; K<X'tTj"'(Opiotc; 5 .1 7tOU itEpte.xov-ccxt OE ou­ OXEUCXOLE<; ·1tOU cpe.pouv O\JO E'CLXE'C'tE<; ouµcpwvcx µE 'CO U7t0 8Et"'(µ<X No. 5 OEV 8cx cpop-cwVOV'tlXL µcx~i OE EV<X OX7Jl-'-IX µE: (ex) OuaiE<; 'tWV K1X't7J"'(Optwv 3, 4.1 TJ 4.2 ltOU 1tEpte.xov,1Xt OE <JUOXE<XOLE(i 7COU cpepouv OUO E'ttXE't'tEi:; auµcpw11cx (lE 'tot Ult0 8Et"'((llX'tlX No 3, TJ 4.1 TJ 4.2· (f3) OuaiEc; 'tTJ<; Kcx,711opi1Xi:; 6.1 itou itEpte.xov,cxt OE au­ axEu1XoiEc; ltOU cpe.pouv auo E'tlXE.'t'tE<; auµcpwvot µE 'CO U7t00EL"'(­ µcx,ot No. 6.1 "I 6lcx· (r) OuaiE,; 'CTJ<i K1X't7J"'(Opicxc; 8 7tOU itEptEX,OV'CIXl OE <JUOXEUIX­ oiEc; itou cpe.pouv ouo mxhui; ouµcpwvcx µE -co uitoOEL1µcx No. 8. TipocpuAcxl;Et<; <JXE'tLXIX (lE El07J X<X'tlXVIXAWOEW<; LE OXTJl-'-IX'C(X X<Xt OE 'C01touc; cpop,woEwc;, Excpop-cwoEwi:; TJ µE­ 't<Xcpop,woEwc; TETRANITROMETHANE 'tOU 2 °' BA­ RIUM CHLORATE -cou 4° (cx), BARIUM PERCHLO­ RATE ,ou 4 ° (f3), BARIUM NITRATE xcxt VL,pLxo µ0Auf300 ,ou 7 ° ( 1 ), <XIIOP"'(IXVWV vt,pt-cw11 ,ou 8 °, OLol;eiotou -cou f3cx­ piou -cou 9° ((,) xcxt BARIUM PERMANGANATE -cou 9° ( 1) 81X xpcx-coUll'CIXt µcxxptot <XltO ,pocptµcx, IXMIX Et07J XCX'tlXVIX­ AW<JEW<; xcxt ~wo,pocpe.c;. XEtptoµoc; XIXt o-cotf3otoiot • ( 1) LU<JXEUotOiEc; ltOU 7tEptEXOUII ouoiEc; -c71c; Kcx,71ropioti:; 5 .1 81X' -co1to8nouv-ccxt Eitiitaocx rni -cwv nu8µe.vwv "tOuc;. Eiti 1tAEOII, oox ai<X 1tOU 1tEpLe.x ouv urpix -c71c; K1X't7J"'(Opicxc; 5.1 8cx acp7111wVOll't<Xt W<J'tE vex µ71 µ1topouv I/IX IXV1X'tpot1tOUV. (2) H XP71071 EUXOAIX wcpAe.x-cwv UAtxwv 1 tlX 'C7J o,otf31Xoi1X ou­ axEucxotwv OE OXTJl-'-IX'C(X <XltlX"'(OpEUE'tlXt. K1X8cxptaµoc; (lE'tlX ,7111 EXcpOp'tWOTJ Mncx 'CTJII axqiop-cwa71, 'CCX ox 71µ1X-c1X ltOU µne.cpap1Xv ouoiEc; 'COU 4 ° µiXPt 6 ° XIXt 7 ° ( (X) XIXt (f3) xuµcx 1t0U 81X xcx8opi~OV't1Xl 1tpoaEX'CtXCX µE otcp80110 vepo. 51 400 51 402 51 403 51 404 51 409 51 410 51 411 51 413 51 414 51 415 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) 1307 Tiixpcx1p1Xcpoc; 5: fa6txic; /)llX'tCX/;etc; ltOU 1Xcpopou11 'tTj Amoupriix 'tW\I OXT)µdt,wv ~TJ(.LIXIIOTj XIXl XIXPIXX'tT)ptaµoc; OXT)µ<X'tW\I ( 1) Ot 6tix,dtl;etc; 'tOU 1tept8wpt1XXOU 10 500, 1tixpcx-ypixcpot ( 1 ), (7) XIXl (8), 0ix EXOUII ecp1Xp(.LO'YTJ µ0110 O'tTj (.LE't1Xcpopdt OUOlW\I 'tOU 1 °' 2 °' 3 °' XAWplXW\I IXACX'tWII XIXl IXIIOp"(1X-xAwptouxw11 ,l,IX\llOX'tO\IW\I 'tOU 4 ° (ix), BARIUM PERCHLOARATE 'tOU 4° (~), ouaiec; ,ou 8° xixt 9° (~) xixt BARIUM PERMAN­ GANATE ,ou 9° (r) (2) OxiJµix,ix µe a,ix0Epic; iJ 1X1toau11ixpµo).o-youµE11Ec; 6El;ixµe­ vic; ltOU ltcplEXOU\I TJ mptElXIXII (xevec; 6el;ixµe11ic;, IXXIX0CXpl­ Q'tE<;) ouaiec; 1tou ix11ixcpipo11,ixt a-co Ilixpcxp,T)(.LIX B.5 0ix cpipouv XIXl a,tc; Mo ltAEUpic; XIXl ltlOW E'tlXE't'tlX ltOU 0ix eivou auµcpw11Tj µe 'tO U1to6etrµix 5. Exeivec; ltOU 1tepteixixv iJ 1teptaxouv ump­ X AWptxo ol;u (PERCHLORIC ACID) (ae /)t(XAUOT)) 'tOU 3 ° TJ AMMONIUM NITRATE (~Ea'tec; auµ1tux11wµi11ec; u6iimEc; OtixAuaetc;) 'tOU 6 ° 0ix cpipouv e1ti 1tAfov rnxh'tec; auµcpwvix µe 'tO U1to6etrµix No. 8. 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(3) H XPT)Ol(.LOltOlTjOTj u-ypou ixapix Tj urpou ol;urovou OIX\I 4u­ X'tlXO UAlXO IXltlX'(Opeue'tlXl. ( 4) H 0epµoxpixalix 4ul;ewc; 0ix emAi1E't1Xt XIX't<X -chow 'tpo1to 1 wa'ta vix ix1tocpeu1nixt o xi116u11oc; 1tou µ1topei vix 1tpoxu4et ix1to ~O ~UXXWPlO(.LO 'tW\I CjlCXOEWII. 51 416 51499 51 500 51 501 51 599 51 600 51 999 52 000 52 099 52 100 52 104 52 105 52 106 Me'tixcpopcx Of. XO\l'tETjllEP -5211 7 Eu0pexauc; OUQXEUIXOiec; µe 'tTjll E\I\IOllX 'tOU 1tept8wptexxou 10 52 118 014 (1) /)ell 0ix (.LE'tlXCj)EpOll'tlXl Of. (llXp<X XO\l'tETjVEp. Xcxpixx'tT)ptaµoc; 6el;ixµevo-xo11'tiTj11ep del;eµevo-xo\l'tET)IIEP ltOU ltEptaxouv TJ 1tepteixixv ouaiEc; 'tOU 10 °' 14 ° Tj 15 ° 0ix cpapouv XIXl O'ttc; Mo ltAEUpe.c; E'tlXE't'tlX auµcpwvix µe 'tO U1to6urµcx No 5. 52 119 52 129 52 130 Ilixpiirpixcpoc; 2: Et6txic; 1tpou1t08iaetc; 1tpoc; EXltATJpWOTj exlto 'tlX µiaex (.LE'texcpopcxc; xext 'tO\I El;01tAtaµo 'tOUc; Tt.11t0l OXTJ(.LIX'tOc; (1) Ouaiec; 'tOU 1 ° µiXPt 22 °, 30° XIXl 31 ° 0ix µe'tixcpipo11't1Xl ae XAElQ't(X TJ e1te116e6uµa11ex OXT}µIX'tlX. Ouaiec; 'tOU 45 ° µe.xpl 55 ° 1tou 1tEptexo11't1Xt ae 1tpoa't1XUU'ttxic; auaxeuixaiEc; -yaµdt'tec; µe 4ux'ttXO UAtXo 0ix µe'tixcpe.po11't1Xl aE xAeta'tii 7J E1tev6e6uµe.11ex oxiJµix'tex. Av 'tex OXTJ(.LIX'tlX 1tou xprioiµo1totou11't1Xt eivixt XAet­ O'tCX 0ix exepi~ov'text xex't<XMT)AIX. Tex eitev6uµi11ex OXTJ(.LIX'tlX 0cx ei­ vtu el;o1tAlO(.LEIIIX µe ltAEUptxdt cpuUix XIXl 01tia8to cpuUo. 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( 4) ~UOXEUexaiEc; 7tOU 1tEp1ixouv ouoiEc; 'l'T)c; Oµcxoixc; t OEV 8ex 'to1toBE"touv'toc11tixvw oE illex Eµ1topEuµoc"tex' E1ti 1tAfov, Bex O'l'Ot(3ix~wv-c:ex1 XOC'tlX 'tpo1tov WO'tE voc µ1topEi EuxoAix voc 't<X q,8iiaE1 xexvEic;. (5) Ouaiec; 'tT)c; Oµiioocc; E Boe cpop'tWVOV'tCXL XCXI Boe EX<pOp­ 'tWVOV'text xwpic; EVOIIX(-LEGTj OC1toB71xEUGTj, XOCI OE 7tEpt1t'tW01j, (.LE'texcpop'twaew~ 8cx fLE't<X<pipov'toct ex1t' EuBEiocc; ix1to -co ivcx ox11µex O'tO illo. Ot 1tpo(3AE1toµEvEc; OCVW'tOC'tEc; BEpµoxpcxoiEc; OEV Bex u1tep(3exivov'tOCI xex'tlX 'tT)V OtiXpXEtex ()(ll'tOU 'tOU 'X ELptoµou ((3Ai1tE 1tEp1Bwpuxxo 52 105 (1 )). flexpcx,pexcpoc; 5: E161xic; OLCX'tlX~Etc; 7tOU cxcpopouv 'tT) AmoupjiOC 'tWV 0'X 1j(.llX'tWV 1;71(.llXVGTj xext xocp<XX'tT)ptoµoc; 'l'WV OXTJfJ-IX'tWV Qx71µcx"tex µe o'texBepic; 71 ex1toouvexpµ0Aorouµevec; oetocµEvic; 7tOU 1tep1ixouv 71 7tEpteixcxv (xevic; OE~<XµEvic;, ocxocBixptanc;) ouaiEc; nou cxvexcpipoV'text o'to Ilcxpiip't1JfJ-ex B.5 Bcx cpipouv E1ti 1tAiov xext O"ttc; Mo 1tAeupic; xext 1tiow ntxhnc; ouµcpwvcx µE 'to U7t00£1jfJ-ex 5. i;'tlXOE~ mp1wp1oµiv71c; 6tixpxEtexc; jL<X exvii1xEc; oip(3tc; i;'tT) 6tixpxetoc tT)c; fJ-E'texcpopiic; OUOIWV 'l'OU 46 ° (ex), 4 7° ( ()() X<Xt 49°(ex), Ot O'tlXOEtc; r1ex IXVIXjXE<; oip(3tc; OEV Bcx rivov"text, 000 exu'to Eivext 6uvex'to, XOV'tlX OE Xex'tOIXT)µivec; mp1oxtc; 711tep10 xic; exvex~uX7Jc;.·H O'tlXOT) 7tA1JOtOV OE 'l'i°tOt()( 7tEPtOX71 OEV µ1topEi vex 1texpex'tex8Ei 1texpii µovo µE 'tT)V i 1xp1011 'tWV ocpµo61wv exp­ xwv. 0 i61oc; xcxvovexc; Bex iXEt E<pocpµojTJ o"tcxv µ1cx µnexcpop1x71 µovii6cx eivex1 cpop'tW(.lEVTJ µE 1tep1ooo'tEpex cx1to 2,000 ictAix ou 52 400 52 401 52 402 OtWV 'tOU 45°, 46((3) xex1 (r) 48°, 49°((3) XOCI 50° µixp1 55°. Ilexpiijpatcpoc; 6: ME't0t(3at't1xic; 61ix'tixte1c;, ocvatxA71oe1c; xoct 61cx­ 't1XtE1c; EtOtxic; ,tat optoµivec; xwpEc; ("Exouv E<patpµor71 µovo Ol jEVtxic; OICX'tlXtEt<; 'tOU Mipouc; I) Ilatpiijpatcpoc; I: Tpo1toc; fLE'tOC<popcxc; ME'tOt<popa xuµcx (1) OuoiEc; "tou 44 ° ((3), 60 ° (r) xix1 63 ° (r) µ1topouv vcx µe­ 'tatcpipoV'tatt xufiat O()(V 1tA71pEc; cpop'ttO, (2) OuoiEc; 'l'OU 44 ° ((3), a' ocu"t71,71v mpi1t'l'W07J Bix µrnxcpa­ pov'tatL oE XAELO'tlX 71 E1tEv6uµivcx ox71µoc'toc· ExeivEc; ,ou 60 ° (j) 71 63(r) OE enevouµivat atVOLX'tlX OXTJfLOC'tCX. 52, 404 Xcxpatx'tT)ptoµoc; 'tWV 6Etexµevo - xov,i71vEp 52 412 AEtatµEvo - XOV'tET)VEp 7t0U 1tEp1ixouv T) 1tEp1Eixcxv ouoiEc; 'tOU 2 ° T) 3 ° 71-ouoiEc; illwv Etowv ,atttvoµ71µivEc; µE (ix) T) ((3) 52 413 Bex <pipouv xatt o-ctc; Mo 1tAeupic; E'l'tXh'tix ouµcpwvix fJ.E -co u1to­ OE11µex No. 6.1: . Exeivat 1tou 1tEp1e.xouv T) 1tEp1EiXatV ouoiec; 01totou6711to-ce , illou Ei6ouc; 'l'att1voµ71µivEc; µe (r) Bat cpipouv E'ttXE't'tEc; ouµ 52 414 cpwvat µe 'tO uno6Et1µcx No. 6.lA. Exeivat 7tOU 1tEp1ixouv TJ 7tEpteixatv ouoiEc; 7t0U ixouv 071µeio atvatcpAitEwc; 55 °KT) XOCfJ.T)AO'l'Epo Bix cpipouv e1ti 1tAiov mxi-c­ nc; ouµcpwvix µE -co u1to6E1jµat No. 3. ExEiVat 7t0U 1tEp1ixow T) 1tEp1dxatv IXAOC't()( 'tOU x1o.wpocpop­ µiou ,oi> 16 ° TJ 1 7 ° Bix cpipouv mi 1tAiov E,tXE't'tEc; ouµq,wvcx µE 'l'O u1toOE11µat No. 8. • 52 510 52 599 52 600 60 999 61 000 61 099 61 100 61 110 61 111 61 112 61 129 61 130 61 131. 61 199 Ilexpii1poc<poc; 2: E161xic; 1tpou1toBioE1c; 1tpoc; ex1tA71pwo11 cx1to 52 415 52 499 52 500 52 501 52 508 52 509 ,at µioat µE,at<popiic; xoct wv E~01tA10µ0 -couc; Ilupoo(3Eo,1xic; ouoxeuic; Ot Otex'l'1Xte1c; 'tOU 7tEpt0wptocxou 10 240(1)((3) XOCt (3) 0ix EXOUV E<pixp(l0"'(7l fLOVO "'(Lat 't1j (lE'tix(jlOpiX U"'(pWV 7t0U EXOUV 07)­ µEtO exvcxcpAe.tEwc; 55 ° K TJ At1o,Epo. 61 200 61 239 61 240 61 241 EL61xoc; Eto1tA1oµoc; -61 259 . '01ton µE,at<papov,ex1 CXAxuAtat ,ou µoAu(36ou ,ou 31 ° (cx) 71 61 260 6oxEi<X 7t0U 't()( 1tEp1dxcxv, 0 001jjOc;, O't()(V 'tOU 1tocpcx6iVE't()(t 'CO • e.npexcpo µe,occpopcxc;, 0cx 'tOU 7tatpcxuiOE'tatt ourxpovwc; cpop1j't0 x1(3w,10 E~07tAtaµou µe XEtpoAoc(371 X<Xt mp1ixov: T picx OCV'tt"'(pat<pat 'tWV rpixmwv 001J,tWV 7t0U xoc0opiZ:ouv 'l'Lc; rwip1mc; 11:ou 1tpbm voc rivouv OE 1tEpi1t,wo11 at,ux71µocwc; TJ auµ(3ixv,oc; O'tT) 61iipxELex ,71c; µE-catcpopiic; ((3Ai1tE 1tEpt8wp1exxo 61 385)· Mo ~EUY'J rixv,1ex xoct Mo ,EUY'J µmhEc; xex'texoxEucxoµivcx ()(1tO EAexo'l'LXO 71 XIX1t010 XOC'tlXM1JAO 7tAOCO'tLXO UALXO" Mo exvex1tVEUO'tTJpEc; µE cpuoinLO eveprou iiv0pixxix tXatVO­ 'tT)'tatc; 500 xu(3. EX. <I>1iiA71 (xex,rioxEuexoµiv71 1tex 1texpii6E1rµoc cx1to (3cxxeAi'l'71) 1tep1ixouoex 2 XLAIX POTASSIUM PARMANGANATE XOCt q,ipouoex 'tT)V iv6Et;1J «6texAUoexn oE vEpo :i:ptv cx1to ,1J XPTJOT)»' "Et111tpoe1601tOtTJOE~ µe 'tT)V iv6Et;1j «KINAYNO~ - xuµivo 11:'tT)'ttxo 01JA1j't7lpto. M11 7tA1JOtlX,E'tE x.wpic; ocvat1tveuo,71pcx» O'tT) "'(AWOO(X 71 r:>..wooec; xii0E xwpcxc; O'tO iocxcpoc; 'tWV 01toiwv Aexµ(31XVEt XWP<X 1J fLE'l'<X<popcx. Au-co 'CO XL(3W'tt0 0cx <pUMIXOOE't<Xt O'tO xou(3ouXAIO (xcx­ µ1t(voc) 'tOU 0611rou OE µipoc; 07tOU µ1topEi vcx (3pE0Ei EIJXOACX ex1to 'tT)V oµii6cx cx1to:>..uµexv07Jc;, E<l>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI:·AEYTEPO) 1309 61 261 61 299 Ilcxpixrpcxcpoc; 3: fe11txe.c; OlCX'tlX!;Etc; e!;U1t7lpE'tTjOEW<; (ae.p[3tc;) Eve.prate<; 7t0U 1tpE1tEl \ICX jLVOU OE 1tEpl1t'tWOTJ rnuxflflCX'tO<; (BAe.1tE 1tEpt8wpicxxo 61 385) '· Ilpocpu)..ix!;w; ae CJXE.OTJ µE EtOTJ xcx'texvexAwaewc; (BAe.7tE 7tEpt0wptcxxo 61 410) E1tl{3AEcj,TJ ox 11µix'tw11 Ot Otex'tix!;etc; 'tTJ<; 1texpexjpixcpou 10 321 eex e.xou11 ecpexpµojTj a'tex emxivouvex eµ1topeuµex,ex 1tou exvexcpe.pov'text 1texpexxhw aE 1tooo't7l'tE<; 1tou u1tEp[3exivou11 'tt<; xex0opt1;oµevec;: OualEc; 'tOU 1 ° fLE.XPt 3 ° xcxt oua[e.; 'tex!;tvoµ11µe.11E<; µa (ex) OAW\I 'twv ElOwv: 1,000 KG OuaiE<; 'tex!;tvoµ11µe.vac; µe ([3) OAWV 'tW\I ElOwv: 5·,000 KG. <l>opTJ'tE<; cpw'tta'ttxe.,; auaxwe.c; /iev eex e.xouv ecpexpµOjTj m 6tex'tcx.!;atc; 'tOU 7tept0wptexxou J 0 374. r pex7t'tE.<; OOTJjLE<; ·o7to'tE p.e;texcpe.poV'texl exAXUAlex µo"'Auf36ou 'tOU 31 ° (ex), Tj 60 x Eiex 7tOU 7tEplELXCXV exU'tlX, 'tO xeiµEvo 'tW\I jpex1t'tW\I OOTJjlW\I ecx xex0opi1;El, p.E'tex!;u IXAAWV, 'tex 1texpexx1X'tW: (A) IIpocpuAcx.!;Et<; 1tpo.; tTjpTJOTJ H oualex Eivext e!;extpmxcx. 'tO!;tx71. LE 1tEpi1t'tWOTJ 6texcpuj7j<; CX7t0 E.\lex CX7t0 'tex OOXELex 1tpE.1tEl VCX 1texp8ou11 Ol 1texpexX1X'tW 1tpo­ Cj)UAIX!;Et<;: 1. A1tocpEUjE'tE: (ex) E1texcp71 µe 'to 6e.pµex • ([3) Eta1tvo71 ex'tµwv • (j) faOIXjWjTj 'tOU UjpOU O'tO O'tOp.ex. 2. ·o'tcxv jLVE'tlXl XEtptoµoc; [3expEAlWV 7t0U e.xou11 07tlXOEl Tj 1.moonl [3).ixf311 71 u1pexv0ei f.J.E u1po, EivlXt u1toxpEw'ttx71 7J XPTJOTJ 'tWV 1texpexX1X'tW: (1X) A111Xlt\lEUO't7jpwv (µcxaxwv) ([3) flXV'tlWV ex1to EAIXO'tlXO Tj XIX7t0l0 xex'tlXAATJAO ltAexO'tlXO (r) EAexo'tlXW\I µito'tW\I 71 ex1to XIX't!XAAYjAO 7tACXO'tlXO. LE 1tEpi1t'tWOTJ 00{31Xpou ex'tux71µex'tO<; µE OU\IE.7tEl(X 'tO XAEL­ otµo 't7j<; e811LX7j<;. OOOU, Et\llXl IX7t1Xp1Xi'tTJ'tO IICX El007tOLTJ00uV jllX 'tO\I xlv6uvo 7t0U U7t1XPXEl 'tex 1tpoaw1tex ltOU epxo\l'texl ytex \iex EAEU0apwoouv 'tO xwpo. (B) Eve.pjELE<; 1tou 1tpe.1tEt vex 1ivouv '0).Ec; ot 1tp1XX'ttxe.c; EVE.pjELE<;, 1tEptAexµ{31X11oµe.1111c; 'tTJ<; XPTJ­ OEW<; 'tW\I El007t0t7j0EW\I ltOU ex111Xcpe.pov't1Xl O'tO 7tEpt0wptotXO 61 260, 81X jt\lOU\I jlot Vex xp1X't1)00U\I 'tex 1tpoow1t1X OE ot7tO­ O'tlXOlj oxi µtxpo'tEP7J 'tW\I 15 µe.'tpwv exito 't"l)\I 't07t00Eoiex 'tOU Ot'tUX.TJl:'-IX'tO<;" Ol 1tpoEL007t0lTJOEl<; 7t0U 7tEplE.XOV'texl O'tO Xl{3Wtt9 E!;07tAtaµou e(X 't01to8en18ouv 7tE.pt!; 't'Tj<; 7tEptcppix!;ew,; xext Ol 7tEpiEpjot 81X xplX'tO\l\l't(Xl µexxptcx.. Ot IXVexlt\lEUO'tTjpE<; (µex.axe.;), jlXV'tlex Xotl µ1tow:; 01X xex'tot­ O'tTjOOU\I 6uvex'to OE E\l(X 1tpoow1to vex ltA'TjOllXOEl 'tO cpop'tlO Xotl vex EAe.1!;et 't"l)II X1X't1Xa'tcxa71 'tOu. Av x1Xve.v1X {31XpEAt 01tix0Et xcxt cxvoi!;Et, 1tpemt vex 1ivouv 'tot 7totpotXIX'tW: (ex) Ilpe.7tEl VIX jL\/El 1XfLEOTJ 1tpoµ718etot 1tpoa8E'tWV ex11ot1tVEU­ O'tTjpwv, 1exv'ttWV xcxt p.itO'tW\I µE 'tlX oitoicx 111X Ecpo6tcxa'touv m epjiX'tE<;" ([3) TIX {3otpEAtlX 1tou eivext cx.0tX'tlX vex 1totpotµEpta'touv· (r) To x.uµe.vo UjpO 7tlXIIW O'tO ox.1111-ex 11 O'tO e.6excpoc; 1tpE.1tEl vot E!;ouOE'tEpw0Ei µE ixcp80110 !;e.1tAuµex µ. UOIX'ttvo 6tcx."'Auµcx POTASSIUM PERMANGANATE (e!;ou6mpw,txoc; 1totpix 1 w11, µicx cpt1XA71 ot1to 'tov 01toio cpullcx.ooE,IXt o,o xi{3w'tto e!;o 7tAtoµou)· 'tO OtlXAuµcx E'totµcx.!;E'totl EUXOACX exvotXot'tEUOll'tot<; 0.5 XlAO PERMANGANATEµ. 15 Ai'tplX vEpo OE rxou[3cx.· 'tO !;e. 1tAuµex 1tpe.1tet vot 1ivet itoUe.,; cpope.,; OtO'tl XP•tix!;ov'totl ouo xv.ex otito 'to POTASSIUM PERMANGANATE ( 1tot vot a!;ou6napw8Ei 1tA71pw,; 1 xv.o otlto 't'TJ p.E'tlX<PEPOfLEVTJ ouoilX. 61 300 61 301 61 302 61 303 61 304 61 320 61 321 61 322 61 352 61 353 61 375 61384 61 385 '01tou ELIXl 7tp1XX'ttXCX OU\IIX'tO, 0 XCXAlJ'tEpo,; 'tpo1toc; jlex vex 0t1to"'Auµcxv8ei o x wpo,; Eivcxt vot x u0Ei 1tix11w o' otu,ov 1tnpe.Acxto Xott \lot CXVCXcj,El \/IX XCXEL. (f) L7lµexv'ttx71 1tpoEL601toir1011 LE 1tEpi1t'tW07l ex'tux 71µex'toc;, µtot IXltO ,tc; 1tpW'tE<; Eve.p1mc; ltOU 1tpe.1tEl vex jLIIOU\I EL\l(Xl \/IX Et007t0l1)0ei 't"l)AEypotcptxwc; Tj 'tl]AECj)W\llXW<; ........... ( ypixcj,'tE EOW 'tl<; OlEu8u110El<; XIXl 'tOU<; 1Xpt0µouc; 't"l)AECj)WIIOU 'tW\I t6puµcx.-rw11 7t0U 1tpE.1tEl VIX El 007t0llj00U\I OE xcx.0E µiot (Xlt() 'tl<; x.wpE<; O'tTJV EmxplX'tEllX 'tW\I OltOLW\I ecx AIX{3Et XWPIXII 7l p.E't1Xcpopix). ·oxriµex 'tO 01toio E.XEl µoAuv8ei µe 'tTjV OUOL(X 7t0U fJ.E'totcpe.pEl OEV ecx 'ti8E'texl ltlXAt OE U7tYjpEOL(X µe.x ptc; O'tOU CX7tOAUp.1Xv8d fLE 't"l)V E1tif3AEcj,7J 1Xpµo6tou 1tpoow1tou. 01totex6711to'tE !;u"'Atvot µe.p"I) 'tOU ox71µ0t,O<; 'tot 07t0Lot E.XOU\I 1tpoof3ATJ8Ei Ot7t0 'tTJV OUOLot 7t0U fJ.E'tlXCj)E.pE'totl 8ot otcpotlpOUV'totl Xotl 0ot XotLjOll'totl. 61 386 61 399 Ilotpixrpexcpo,; 4: Et6txe.c; Olex'tlX!;ELc; 7t0U excpopouv 't7l cpop,wori, Excpop'tWOTJ xexl x ELptoµo < A1t0t"(opwo11 µtx't71c; cpop'twoEwc; oe. e.vex ox 11µot . ( 1) Ouoiac; 't"I)<; xex'tri1opiotc; 6 .1 1tou 1tEpte.xov'totl OE ou­ oxaucxoiEc; 7tOU. cpe.pou11 E'tlXE.'t'tot 71 ouo E'tlXE.'t'tE<; oucpµwvex fl-E 'tO u1to6Etjp.ot 6.1 71 6.1 A 6av 0ot cpop'twvov,ott µcx!;i OE evcx OX7JfJ.IX µe ouoiec; 71 otV'ttXEiµEvot ,wv Kcx,ri1opiwv lot, 1[3 71 11 1tOU 7tEplE.XOV'totl OE OUOXEUotoiEc; 7t0U cpe.pouv µicx Tj 6uo E'tlXE.'t­ nc; ouµcpwvcx µE 'tO U7t00El1P.CX No. 1. (2) Ouoiec; 't"I)<; XCX't1J10piotc; 6.1 7t0U 7tEplE.X.OV'totl OE ou­ OXEUIXOLE<; 1tou cpe.pouv· Mo E'ttxe.nEc; ouµcpwvcx fl-E -ro u1to­ OEtjp.ot No 6.1 716. lA 6ev 8ot cpop'tW\10\l'tott p.1X1;i OE E\lot ox.111.1-cx µ.: (ex) Ouoiec; 'tW\I Kexnnoptwv 3, 4.1 Tj 4.2 7t0U mpte.x OV'tott OE OUOXEUCXOLE<; 7t0U cpe.pou11 6uo E'tlXE.'t'tE<; auµcpw11ot p.E 'tO U7t0 0El"(µot No. 3, 4.1 Tj 4.2· ((3) OuoiEc; 'tW\I Kot'tTJjOptwv 5.1715.2 7t0U 7tEpte.xov'totl OE OUOXEUCXOLE<; 7tOU cpepOU\I Mo E'tlXE.'t'tE<; ouµcpwvot µi; 'tO U7t0 0Etjp.ot No. 5· (r) OuoiEc; 'tTJ<; Kot'tlj"(Opicxc; 8 7tOU 7tEpte.x oV'totl OE OUOXEUot­ oiEc; 1tou cpe.pou11 Mo E'ttXE't'tE<; ouµcpw11cx fLE -ro u1to6Et1µcx No. 8. Ilpocpu).ix!;Et<; oE <JXEOTJ µ. 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(2) 'Ox.TJP.IX 'to 01toio EX.Et µoAuv0Ei OE ouoiE<; -rou 31 °(cx) 71 µE µijµIX IXU'tW\I OE\I eex ti8E't1Xl 7tlXAl OE U7t1jpEoilX µe.x ptc; O'tOU (X1tOAUp.1Xv8ei U7t0 'tTJV e1ti{3AEcj,7l otpµootou 1tpoow1tou. 01tot1X 6711to'tE !;uAtvlX µe.pTJ 'tOU ox 71µot-roc; 7tOU e.xouv 1tpoaf3A1j8Ei ex1to ouaiE<; 'tou 31 ° (IX) 81X excp1Xtpoull'tcxt xext 0ix xexi1ov'text. (3) Av ouoiE.; 1Xu't71<; 'tTJ<; K1X't7l"(Opi1X<; e.x ou11 6tcxcpu1Et xext xu8ei OE OXT)fJ.IX, OE\I µ1topei V(X !;otVCXXPTJCltµo1tOL1j8Et µe.XPt<; O'tOU xlX0otptani µe Emµe.AEtcx XIXL, exv XP•tlXO'tEi vex ex1toAUfJ.1XV 8Ei. '0AIX 'tCX IXAACX. E!,L7tOpeup.ot'tlX XIXl ot\l'ttXiiµEllot 7tOU p.e-totcpe. • 61 400 61 402 61 403 61 404 61 409 61 410 61 411 61.412 61 413 61 414 61 415 1310 E<DHMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) pov-t(Xt O'tO i6to OX7Jfl-<X 6<X El;E't<X~O\l't(Xt ,t(X E\10EX0f1-EV7J µo­ AIJ\IOlj. 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Tex cxµdt!;wµot 'tOU o:x,71µ0l-coc; 0cx aivOlL a!;o1tAt­ aµi110 µa xex'totAATJATJ XOll cxpxa't<X :x,0116p71 aaw'tapLXTj a1tiv6uo7j. Av "tO O:X,Tjµot EL\IOll mavBUfLEIIO µa (j)UAA.Ol, 'tO cpuUo 0cx El\/Oll 't0 1to0a'tTjµivo xcx'tcx 'tE'tOlO 'tpo1to wo,a vex µTj µ1topai VOl cx11i!;at co q,op'tio. Ma-cexq,opcx a£ XO\l'tETJVEp M1xpcx XO\l'tETJVEp 7t01J X.PTJOLµo1tOU\l'tOll ilot 't'I) µa'tCX(j)Op<X 01JOLWV "t01J 23 ° T) Ol7tO~ATJ"tOl µoAU~001J 7t01J 7tEpti:x,ouv 0ai:txo o!;u 't01J 1 ° (~) :x,uµOl, 0cx E:X,OIJ\I 7tAT)p7] 'tOL:X,Wµot'tot XOll XOl'tCXA­ ATJATJ a1tavBuOTJ XexpCXX'tTjploµoc; 6a!;otµa110-xo11'tE7]\IEP Aa!;Olµavo-xov'tETjVap 1tou 1tEpLix ouv 71 1tEpLai:x,otv oua[ac; 'tTjc; 1tcxpouocxc; Kcx't7]1opicxc; 0cx cpipouv xott O'tLc; Mo 1tAwpic; rn­ xinot auµq,wvix µa 'tO u1to6at1µcx No. 8. Exaivcx 1tou 1taptix ou11 ri 1tEpLaix cx11 ouoiac; 'tTjc; 1tcxpouaotc; Kot'tTffOpicxc; 1tou ix ouv 011µaio cxvcxq,Ai!;awc; 55 ° K 71 X,CX(lTJAO­ capo 00l q,ipouv mi 1tAfov E'ttxincx auµcpwvcx µa 'to u1t0Bat1µcx No. 3. Exaivcx 7t01J 7tEpti:x,ouv ii 7tEptai:X,ot\l 7tUpo0ati:xo o!;u ( Ol110l01J­ µLcx~ov 0attXO o!;u) 't01J 1 °(cx) T) ouoiac; 'tOIJ 6°' 7°' 24 °' 26° T) 44 ° 0ex cpipouv mi 1tAfov E'ttxhuc; auµcpwvcx µa 'tO u1to6u1µcx · No. 6.1. Exaivcx 1tou 1tap1ix ou11 71 1tapud:x,cx11 ouoiac; 'tOU 62 ° 0cx cpi­ pouv a1t[· 1tAfov E'ttxh'tac; ouµcpwvcx µa 'tO u1tooaL1µcx 5. Ticxpdt1pOlcpoc; 2: EtBtxic; 1tpoii1to0iaatc; 1tpoc; ax1tAiipwo7j Ol7t0 'tot µfocx µrnxcpopiic; XOll 'tO\I a!;o1tAtoµo 'tOUc; Tiupoo~EO'tlXEc; 01JOXEIJ&c; Ot otex'tcx!;atc; ,ou 1tapL0wptexxou 10 240 (1) (~) xott (3) 0cx E:X,OU\I acpcxpµo,71 µ0110 ,tex 'tTJ µa-ccxq,opcx u,pwv 7t01J E:X,OU\I OT]· µaio Olvcxq,)..i!;awc; 55 ° K T) X,ot(lT]AO'tEpo, 71 1t0l ouoiac; 'tOIJ 2°(cx) Xotl 3°(ot). • E1ti~AEcj,7] O:X,Tj(lOl'tW\I 01 OICX'tot!;ai.c; 't01J 1tap18wp1otxou 10 321 0cx EX,OU\I acpotp­ µon ,tot 'tot E1ttxi11Buvot aµ1topauµot'tot 7t01J otvotcpipo\l'totl 7totpot­ XCX"tW OE 7tOOO'tTj'ttc; 7t01J 1J7tEp~otL\101J\I i:tc; otvcxcpapoµavac;: Ouoiac; 'tOl!;tvoµT]µivac; µa (ot) oAwv 'tWV a1 6wv: 10,000KG Bpwµ10 'tou 24°: 1,000KG 81 000 81 099 81100 81 llO 81 111 81 ll2 81 117 81 118 81 119 81 129 81 130 81 131 81 199 81 200 81 239 81 240 81 241 81 299 81 321 81 322 cl>op7]i:ic; (j)W'ttomxic; auoxwic; -81 352 Aav 0ot E:X,OUV E~cxpµon Ol Olot'tot!;atc; 't01J 7tEpt0wptotXOU 10 81 353 353. • 81 354 A1tot,opEU07] XCX7t\l[aµot'toc; . -81 3 73 Aav 0cx E:X,01JV aq,cxpµon 01 Ol0l'tot!;a1c; 't01J 7tEpt0wp1cxxou 10 81 3 7 4 374. Ticxpdt,pcxcpoc; 4: EtBtxic; OlCX'ta.!;atc; 7t01J Ol(j)Opouv 'tTJ Cj)Op'tWOTJ, EX(j)Op'tWOTJ XCXL :l(,Elptoµo A1tcx,opaua7j µtX'tT)c; cpop,waawc; OE E\ICX OX,T]µOl { 1) Oua[ac; 'tTjc; KOl'tTj1opiotc; 8 XAEtaµivac; oa auoxwotaiac; 7t01J cpipow µicx Tj ouo E'tlXE't't£c; 7t01J El\lOll auµq,wvac; µa 'tO 81 375 81 399 81 400 81 402 81 403 1312 ECJ>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: AEYTEPO) U7t00Et,µot No. 8 OEII 0ot cpop'tWIIOll'totl µot~i OE Eliot ox 71µot fl-E OUOLa', T) otll'tlXEtµE11ot 'tWII Kot,:711optWII 1 ot, 1 (3, 11 µfoot OE OUOXEUotoiac; 7t0U cpipou11 µiot .T) Mo E'tlXE't'tE', ouµcpw11ot fl-E 'tO u1to6E11µot No. 1. (2) Ouoiec; i:71c; Kot't'Tj1opi0tc; 8 µfoa OE ouoxwaoiec; 1tou cpi­ pow E'ttXE't'tE', ouo ouµcpw110t µE 'tO U1tOOEt,µ0t No. 8 OEII 80t cpopi:WIIOll'totl µot~ OE Ell0t ox 71µ0t fl-E: (a) OuoiEc; i:71c; Koti:71,opiotc; 3, K0ti:711opiotc; 4.1 "I Koti:7110 piotc; 4.2 µfoot OE ouoxauotoiEc; 1eou cpipou11 ouo E'ttxinac; ouµ­ cpw110t fl-E i:o u1to0Et1µot No. 3, 4.1 "I 4.2· ((3) OuoiEc; 't'Tj', K0ti:71,opiotc; 5 .1 "I Koti:riropiotc; 5. 2 µfoot OE ouoxEuotoiEc; 1tou cpipou11 ouo Ei:txii:i:Ec; ouµq,w110t fl-E ,:o u1eo­ OE11µ0t No. 5· (r) OuoiEc; 't'Tj', K0t't'Tj1opiotc; 6.1 µfo0t OE ouoxwotoiEc; 1tou cpipow Mo Ei:txinEc; ouµcpw110t fl-E i:ot u1eo6Ei-yµ0ti:ot No. 6.1 "I 6.lA. K0t8otp1oµoc; 1tp111 ot1to 1:71 cpopi:w071 0x.TJfl-0t'tot 'tot 01toiot 1tpoxE11:0t1 \lot µEi:otcpipow ouoxwaoiEc; 1tOU 7tEpLE)(.OUII ouoiEc; 'tOU 2 ° ( ot) "I 3 ° ( 0t) 80t xot80tpi~oll't0tt 1tpooexi:txix x0t1 E101xix 11ot Ei110t1 x wpic; xotuotµot 0t1toppiµµ0ti:0t ( IX)(.Upot, x opi:ot, j(.Otpnix, X.A7t. ). Xe1p1oµoc; XOtL o,:m(30toi0t tuoxeuotoiac; 1tou 1tEp1ix ow ouoiEc; i:ou 2°(ot), 3°(0t), 61 ° "I 62 ° 80t 't01t00E't01Jll't0tL OE 1EPO OIX7tEOO XotL 80t Et110tL fl-E 'tot 0t11oi1µoti:ix i:ouc; 1tpoc; ,:0t 1tix11w. H X.PTJ071 EUXOAot EU<pAExi:w11 u:>..1xw11 01twc; ixx upo 1tot o,:01(3otoiot 0tui:w11 i:w11 ouoxEu0to1w11 0t1tot1opEuEi:ot1. Ilotpix,potcpoc; 5: E161xic; Olot'tlX!;EL', 7tOU 0tcpopou11 ,:71 AEl'tOup,i0t 'tWII ox 71µcxi:w11 tT)fl-OtllO'Tj XOtL j( otp0tX't7lpLOf1-0', 'tWII Oj(.7lfl-CX'tWII 0x.TJfl-ot't0t µE oi:0t8Epic; "I ot1toou110tpµ0Ao1ouµE11Ec; 0E!;otµE 11ic; 7tOU 7tEpLEj(.OUII "I 7tEpLELj(.0tll ouoiEc; 'tTj', 1totpouo0tc; Koti:71,0 piotc; 80t cpipow XOtl O'tl', Mo 7tAEUpic; XOtL 1tiow E'tLXE't'tOt ouµ­ <j>Wllot µE i:o u1eooE11µot No. 8. ExEillot 7t0U 1tep1ix ou11 "I 1tEpLEtX0tll ouoiEc; i:71c; 1t0tpouo0tc; Kot"t7J,opi0tc; µe 071µEio 0t110tcpAi!;ewc; 5 5 ° K "I xoiµ TjAO'tEpo 0ot cpipoUII E7tt 7tAEOII E'tLXE't'tE', ouµcpw11ot fl-E ,:o U1tOOEt,µ0t No. 3. 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'I\01'(lt 1:ii3 • :,1rl1xog :,1i 31110x1 no:it i:iox1g13 noi 10g1.l10dcb0 110x 'Is I lI 6 110x OS 1 II 6 ~x101d(l)91d3l/. 101 3rJ 1011(1)dirlt:0 :,f.t.rl1xog :,!f.x1go1d3:it :,b10di09d:it 1101'(:it :,li.i 1'.IOX :,f.t.rl1xog :,f.t.x1Xd10 ;b (:,011 110x 101\!f.rl) 1011\u.rlod37l!J. 11!J.i • '()I .OZ- 9:it10 (l)i,px '-!- )I.OS+ 9:ii10 (1)11~:it 1101113 1110 0119rl) t:orl0101g.X0 101010dxorld.9 .nopX1oi0 39~x 101b9xuu.d(l)X '-!- '10pX1oi0 ~'(ltlO'('(Olt .Ti 11(1)1~rl!J.'(91dw u.O(l)l.:itJdw .0 - 10dl.]'( 30 10i!J.i9x1i\J.d(l)X (!f.1u.di.rl !J.0.1:ii) dlO:itrl '-!- 10dJAJ 30 :,f.t.rl1xog u.001:ii .:,f.t.mx010i10x :,oi~ LI£1 (Od31A3V lOXA3.1) l03lHNd38A>I lH.1 lld31/\1HG>3 1318 E<DHMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 7tLE01I U7tOAOjtOµou oxt µtxponp11 Ot7t0 0,4 MPrx (4 µmxp) ( rciEOT} µE,p11ni) 0,1111 1tEpi1t,wo11 µ<1.A0txou X<XAU~Ot XOtL OXL µtxponp11Ot7t00 .2 MP0t (2 µit<ip) ( lttEOTJ µE,p7J,Tj) 0,1111 7tEpi 7t'tWOT} <1.Aouµt11iou XOtL µLyµ<i,w11 11.Aouµwiou. fL0t <XMEc; Ex,oc; Ot7t0 XUXALXEc; Ot0t'tOµtc; 'tW\I OE;0tµE11w11, 7l OL<XµE,poc; 7t0U 60t XP1IOLµorcoL116Ei OOt\l ~<io11 lJltOAOjLoµou 60t ELV<1.l EXEi1111 xutlou ,ou 01toiou 11 Emip<inLOt Ei110tL io71 µE ExEi1111 ,71c; 1tp0tyµ0t,tX7Jc; OL0t,0µ7Jc; ,11c; OE;0tµE117Jc;. Ot rtEplOOLXEc; OOXLµic; jlOt o,0t0Epic; od;0tµE11ic;, ( ox7Jµ0t,Ot 211 182 6E;0tµE11ic;), 0:7tOOU110tpµoAoyouµE11Ec; OE;0tµE11Ec; X.11.l OUO'tOL XiEc; OOXELW\I 7t0U Ot0t,11pou11't0tL OE u1t11pEoi0t X.<X'tW (X7CQ OtU'tEc; ,Le; µE,0t[3rz,txic; otrz,<i;ELc; 6a OLE;<i1oll'toi:L ouµipw11oi: µE ,Le; OtOt't<X;Etc; ,11c; Ifapoi:ypixipou 5 XOl:L µE ,Le; oxmx.ec; ELOLX.Ec; Btoi: 't<X;Etc; jLOt ,tc; Bt<iipopEc; Klll'tTjjOpiac;. Ex,oc; Olli 1tpo11youµE11Ec; OLrz,ii;Etc; 1tpoi[3AE1toi:11 µeyrxAunp71 1tiE071 oox.LµTjc;, µLoi: 1tiE011 6oxLµTjc; 0.2 MPoi: (2 µit<ip) (1tiE01I µE,p7J,TJ) 6a Ei11m oi:px.E,TJ jtOt 1tEpt[3A7Jµoi:,oi: oi:1to 0tAouµi11t0 Tj oi:1to µiyµoi:,oi: oi:ito 0tAouµi 11to. L,0t6Eptc; OE;rxµE11ec; ( oxTJµfZ,Ot OE;0tµE11ic;), (XltOOUIIOtpµoAo- 211 183 ,ouµE11Ec; OE;0tµE11ic;' XOl:L OUO'totXiEc; OOXELW\I ltOU (X\l'tlllrtOXpi \10\l'tllll O,Lc; µE,0t[30t,Lxec; Btoi:,ix;ELc; µrcopou11 \IOI: XPTJOtµo1tOL7J 6ou11 jLOt E\l(X XPOlllXO Ol<XO't7Jµ0t 15 E'tW\I OlltO ,11v l 11 Ox,w [3piou 1978 ytoi: ,11 µE,oi:ipop<i ,w11 Emxivouvwv Eµ1topeuµ<i 'tWII jL(X 'till 07tOLOt exou11 EjXpL6eL H µE,oi:~rz,LXTJ fZU'tTJ 7tepioooc; OEV 60t EXEL Eiprzpµo,TJ jLlll O't0t6epec; Oe;rzµavec; X(XL OUO'totXtEc; OOXEtWV ltOU 1tpoopt,O\l't(Xt 1 tet 'tTj µa,etipopix ouotw11 't7Jc; Krx,71-yopioi:c; 2, TJ o,oi:6apic; OE;rz­ µEvec; (ox7Jµ0t,(X OE;oi:µevec;), Ol7tOOU\llllpµoAOjOUµEvEc; oe;aµa­ vic; XOtl OUO'totXtoc; OOXELWV 'tW\I OltOLWV 'tO 7t<XXOc; 'tOU 'totXW­ µet'tOc; XOtL ,et Eio11 ,ou E;oitALoµou rzv,0t1toxpivoll't0tL o,Lc; 0t1t<1.t­ TijOEtc; ,ou 1trzpov,oc; IToi:przp,7Jµrz,oc; . L,0t6Epec; OE;oi:µevec; ( OX7Jµ0t,(X OE;rzµE11ic;), Ol7tOOUVOtpµoAo- 211 184 jOUµE11Ec; OE;0tµE11ec; X(XL OUO'totXtEc; OOXEtWV ltOU XOl't(XOXEU<X O'tT}XOtV itptv Ot7t0 ,1111 l 11 Metfou 1985 ouµipwvoi: fJ-E ,Le; Otltlll:L TijOEtc; 'tOU ADR 7tOU L<JXUE µE,0t;u 111c; Ox,w~piou 1978 X.Ol:L 30T}c; A1tp1.Aiou 1985. etM<X OEV Ei11oi:L ouµipwvEc; µE ,Le; Btoi:,<i ;ELc; 1tou ixouv Eipoi:pµo,TJ arco 'tTJV l 11 Moi:tou 1985 µ1topEi voi: ouvExioou11 11oi: XP1IOLµo1totou11,oi:L µE,<i oi:1to axeiv7J ,7JV 7JµEpo µ7Jvi0t. 211 185 ITrxp<ip,7Jµoi: B .10t -211 199 MEPOL II: EIMKEL AITAITHLEIL nor LYMITAHPQ NOYN H TPOITOITOIHLH TIL AITAITHLEIL TOY ME POYL I •• Ket'tT)yopirz 2: Aiptet, ouµmEoµivrz, uypo1tot7Jµiv0t TJ Auwµevrz U7t0 7tLE07J 211 200 n · 1 r • , . < . ., i:: • ) • -211 209 0tp0typ0tipoc; : EVLXOt' 7tAOtLOLO XPTJOT} uE<,0tµavw11 opLoµoL XpTJ011 Aiptet 'tT)c; K0t,7Jyopi0tc; 2 Ex,oc; 0t1to Exai11oi: rcou rzvrxyp<iipo- 211 21 O 11:etL 1t0tp0tx.<i,w µrcopEi vrz µn0tipipo11'tlll:L OE o,rz0Epic; OE;oi:µE 11Ec;, oE 0trcoou110tpµoAoyouµEvEc; oe;oi:µE11ic; TJ oE ouo,otXiEc; oo xaiw11: FLUORIDE xoi:L SILICON TETRAFLUORIDE 'tOu 1 ° (et,)· VL'tpLXO o;u 'tOU 1 ° (CT)· µiyµrz,oi: uopoyovou µE OXL mpLooo,Epo Ot7t0 10 O'tlll EXOl'tO HYDROGEN SELENIDE TJ PHOSPHINE TJ SILANE TJ GERMANE xrx,' oyx.o TJ µe oxL 7t!ptoobnpo CX7t0 15 O'tOt !XOt'tO ARSINE Xet,' oyxo· µiyµet,Ot CX~<:>'tOU TJ 07tCXlltW\I cxep!euv (1tOU 1t1tpti;cou11 OXL 1teptooonpo CX7t0 10 CJ'tCX !XCX'tO ~ivov xcx,' bjxo) µe ox1 7t!ptooO'tepo CX7t0 10 O'tCX !Xcx,b HYDROGEN SELENIDE TJ PHOSPHINE iJ SILANE TJ GERMANE xcx-i' orxo iJ µe o;c11rep1ooonpo cx1to 15 O'tCX !XCX'tO ARSINE xcx-i' OjXO 'tOU 2° (BT)· µi:rµcx-icx u6porovou µ, o;c1 1tep1aaonpo CX7t0 10 O'tCX !XCX'tO DIBO­ RANE xcx-i' bjxo· µ!r1-1cx-icx cx~w-iou 7J 01tcxv!eu11 cxtp!euv (1tou 1tep1ixou11 ox1 1tep1aoO't1tpo cxoo 10 O'tCX iXCX'tO ~E\10\1 xcx-i' orxo) 1-1' 0-, 1 1teptoaoupo cx1tb 10 O'tCX EXCX'tO DIBORANE xcx-i' orxo -iou 2 ° (CT), BORON CHLORIDE, CHLORINE TRIFLUORIDE, NITROSYL CHLORIDE, SULPHURYL FLUORIDE XCXI TUNGSTEN HEXAFLUORIDE 'tOU 3 ° (AT)· METHYLSILANE 'tOU 3 ° 'tOU 3 ° ([3)· ARSINE, DI­ CHLOROSILANE, DIMETHYLSILANE, HYDROGEN SELENIDE XCXI TRIMETHYLSILANE 'tOU 3 ° (BT) CYA­ NOGEN, CYAN OGEN CHLORIDE xcxt ETHYLENE OXIDE 'tOU 3° (CT) µ!rµet-icx METHYLSILANES 'tOU 4° (BT) ETHYLENE OXIDE 7t0U mpti;ce1ox11tep1aaO'tEpo CX7t0 50 O'tCX excx-io METHYL FORMATE xet-iix µ<i~cx -iou 4 ° (CT) SILLANE -iou 5 ° ((3)· ouoiec; -iou 5 ° (BT) xcx1 (CT)· 61.CXAu­ !UVT} cxoe-iuA!v11 'tOU 9°(r)· cxip10t 'tOU 12 ° XCXI 13 °. IT0tp<iyp0tipoc; 2: K0t-i0taxau7J 211 211 211 219 ITEp1[3A7Jµ0t,0t 1tou rcpoopi,oll'tetL 1Lrz 'tT) µE,etipopix ouaLwv 211 .220 'tOU 1 ° fLEXPl 6 ° XCXL 'tOU 9 ° 60t El\lllll XOt'tlll:OXEU0tCJµi110t oi:rco • xcUu[30t. Ket't(X 1t0tpEXXALCJ7J Ol7t0 'tO 1tEpt6wpL0tXO 211 12 5 (3 ), . µ1topd 110t yi11EL . 0t1toOEX'tTJ EA<XXLCJ'tT) Emµ7JXUIICJ7J CJ'tT) 6p0tU07J 14 CJ'tTjll 1tEpm,wa11 1tEpL[3A7Jµii,w11 xwpic; auyxo A7J07J. Ot 1tpoi>1to6foELc; 'tOU IT0tp0tp,7jµ0t,oc; B .16 90t exou11 Eljllllp- 211 2 21 µojTJ o,Ot UALX<X XOtL 't7JII xrx,etaxEUTJ ,w11 auyxoA7Jµi11w11 rcepL­ [3)..11µ<i,w11. TiepL~ATjfJ.Ot'tOt itpoopL,OfJ.EIIOt jLOt 'tTJ µE,etipopix X Awpi1111c; xett ipeuoyivLou ,ou 3 ° ( Ot't) 60t Ei110tL <JXEOL0taµi11oi: jLOt rciECJ11 ,ouA<XXLa,ov 2.2 MPet (22 µrc<ip) (1tiEa7J µa,p71,7j). IT0tp<iyp0tipoc; 3: Eio11 E;oitALaµou 211 222 211 229 OL aei>ATJIIEc; xa11waEeuc; ,w11 mpL~A71µix,w11 6oi: EivetL aE 6fo7J 211 230 110t XAEi11011,0tL DXL µ0110 µa ,Le; ouax.Euic; itou 1tpo~Ai1to11,0tt o'tO 1tEpt6wpL0txo 211 131 rxU<i Erci 1tAfo11 µE xAELCJ'tTj ipAixv,,et TJ XIX7tOLOt !XM1I 'tO iot0 et;Loma,11 CJUOXEUTJ. ITEpL~A7Jµ0t,0t rcpoopL,oµE110t ytet •11 µE,rxipop<i uypo1tot7Jµi- 211 231 11w11 0tEpiw11 µrcopEi, ax,oc; etrco ,Ot oi:voiyµrx,et 1tou 1tepLjpixipo 11,0t~ O'tO 1tEpL6wpL0tXO 211 131, \IOI: EL\IOtL Eipo6toi:oµe110t µE OtllotjµOt,Ot jLOt 'tT)II 't01to6h7JCJ7J µE,p11,wv, 1tEptA0tµ[30t11oµE \IW\I 't(u\l µE,pT)'tW\I ltlECJEWc;, XOtL 6epµoµhpw11 XOtL Ol\lotrµix 'tW\I 0t1too,p0t11iaEwc;, oitwc; 0t1t0tLnh0tL 'YLlll 'tT) AEL'toupyiet XOtL 'tT}II OtOljlCXAELOt OtU'tWII. OL auoxEuic; 0toip0tAd0tc; 9et x0tAU1t,ou11 ,tc; rc0tp0txix,w 0t1t0tL- 211 232 'tTJOEtc;: (1) Tat Ot\lOLjfJ.Ot'tOt 1tA11pwaEwc; X.OtL X.EIIWCJEWc; 'tW\I 1tEpL­ (3A71µtit,w11 1tou rcpoopi~oll'tOtL jLOt 'tT) µE,oi:ipoptit uypo1tOL7Jµi 11w11 EUljlAEX'tWV TJ XOtl 'tO;txwv 0tapiw11 6oi: EL\IOtl EljlOOLetCJµEvOt µe Eow,EptxTj ouaXEUTJ 0taip<1.Aai0tc; etµfoou AEL ,oupyietc; xAEL­ o~rxµ,oc; rcou XAEillEL OtU'tOfJ.Ot'tlll CJE 1tapimw07J 0tp1toCJEX't7Jc; XL 117JOEWc; ,7Jc; 0E;0t~Ell7Jc;, ITpi1tEL 110t ai110tL ou11oi:,o 110t XAEioEL 71 OUCJXEU11 Ot7t0 Ot7tOO't0tCJ11. (2) 'OAet 'tilt 0t110iyµ0t,0t, EX,oc; oi:rco EXEt\lOt 7tOU U7t00EXOll't0tl [30tA[3t0E<; 0taip0tAEi0t<; xett XAELa,ic; 01tE<; 0t1toa,p0t11iaawc;, ,wv 1tEpL[3A11µdt,w11 itou rcpopi~o11,0tt jLOt ,7] µa,etipop<i uypo1toL11 µi11w11 EUljlAEX'tW\I TJ/ XOtl ,o;LXW\I 0tEpiw11 Ot\l 7j 01/0fJ.OtCJ'tLXTJ Ot<iµE,po<; 0tu,w11 ai110tL 1t<i11w 0t1to 1,5 XLA., 60t Ei110tL Eipo6t0t­ oµi110t fLE EownpLXTJ auoxEUTJ XAELaiµet,oc; (6txAaioet). (3) Ket,dt 1t0tpixxALCJ1I etrco ,Le; OL0t,ot;Etc; ,w11 1t0tp0typdtipwv (1) X~L (2), 1tEpt/3A7Jµ0t,0t itou 1tpoopi,oll't0tL jLlll ,11 µE,etipopdt (3cx6Et0t XOt't0t<j,uyµe11w11 EUljlAEX'tW\I Tj XOtL ,o;LXW\I uypo1tOL7J­ µi11w11 0tEpiw11 µ1topEi 110t Ei110tL Eipoot0taµi110t µE E;wnptxec; ou­ oxeuec; Otll'tL 'tWY ECJW'tEpLXWY CJUCJXEUW\I Ot\l OL a;wnpLxic; CJU­ OXEUE<; Otll'ti 'tW\I ECJW'tEpLXW\I OUCJXEUW\I OtV Ol E;w,Eptx.ec; CJU­ OXEuic; 1t0tpixow 1tpoa,0toi0t ,ouAotXLCJ,011 tao,tµT) µE axEi117J 7tOU 7tOtPEXE't0tl Ot7t0 '° ,oixwµet 'tOU 1tEpl~A7jp.0t'tOc;. . ( 4) A 11 ,et rtEpt~A ~µ0t,0t ai110tL E;orcAtaµi11w11 µE µe,p11,ec;, ot ,EAw,rxLoL 0E11 60t Et\lOtL x0t,rxox.E0taµi110L rxrco 1h0tiprx11ec; uALxo OE 0t1tEu6Ei0tc; E7tOtljlTJ !J-E 'tTJ µE,0tipEpoµE117J ouaiet. A11 EilletL 6Ep­ µoµnpet, OE\/ 60t e;exou11 dtµearx (J.EOOt CJ'tO OtEppto Tj 'tO uypo µe 0011 'tOU ,otxwµet,oc; ,ou rcept~ATJµoi:,oc;. . (5) ITept~~Tjµ0t,0t rcou rcpoopi,011,etL 1tet 'tT) µE,etipopdt XAW­ pt117Jc; 7J Oto;eLOLOU 'tOU 6eiou ,ou 3 ° (et,) TJ METHYL MER­ CAPTAN TJ HYDROGEN SULPHIDE ,ou 3° ([3,) OEII 6oi: exow 07tOlOOTJ7tO't! ot11otyµ0t X!X'tW Ot7t0 'tO u<j,oc; ,11c; emipdt­ \lELOtc; 'tOU urpoµ. Erci 7tAEOII, OE\/ 60t Em,pE7tOll'tlll:L 6upi0Ec; X0t 60tpwµou orcwc; Ot110tjEp011'tOtL O'tO mpL6wpL01:XO 211 13 2. (6) A11oiyµ0t,0t 7tA7JpWCJEWc; XOtl Exipop,woEwc; (xEIIWCJEWc;) 7tOU ~pLOXO\l'tOtL CJ'tO 7tot\lW µepoc; 'tW\I 1tEpL[3A7J(J.0t'tW\I 9et EL\IOtl e;o1tALoµe110t oxt µ0110 µE O'tl 7tEpljpotljlE'tOtL O'tT)II 1t0tpdtyp0tipo ( 1 ), illdt Erti 1tAfo11 µE oau,Ep7], E;wnpLXTJ ouax.EUTJ x.AELaiµet­ ,oc;. ~u't'ij 11 auo.xEUTJ 6~ µ1topEi 110t xAEtoni µE dt,purc11 ipAot­ V't~Ot 11 xetrcotet 0tM1I E;taou 0t1to'tEAEaµoi:,tx.7j ouax.EUTJ. Ot ~11.A~tOEc; 0taip<1.AEi0tc; 60t xrxAurc,ou11 ,tc; 1t0tp0txdt,w 0t1t0tL'tTJ- 211 233 OEL<;: ECJ>HMEPII: THI: KYBEPNHI:EQI: (TEVXOI: AEYTEPO) 1319 (1) TIEpt~Aljp.Ot'tOt 1t0U 1tpoopi~O\l't0tl jlOt 't1j p.E'tetq,opoc OtE· piwv 'tOU 1 ° µi)(pl 6 ° XOtl 'tOU 9 ° µ1topei 110t ei110tL eq,06Lcxaµiv0t µe ox1 1tEpLaaimpo r:x1t6 ouo f30tAf3ioec; 0toq,0tAEL0tc; 'tW\I 01t0lW\I 7JP.E\1(1)\I atEpiwv 1tOU El(OU\I 01j[J.El0 [3pocaµou XIX'tW t:Y.7t0 182 ° K aE at'tµoaq,at1p1x71 1tiEa71 OE\/ 0or. 1tEptA0tµ(3ocvou11 01to1067l1tOte xcxua1µ0 uAtxo eha G'tTJ 8Epµ1x11 µ611wa7J ahe. atix µiacx 1tpoaatp't7Jae.wc; a'to 1tA0tioLO. 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EXat'tO't7jc; µovwaewc; e.voc; 1tEpL[3A71µ0t'tO<; µE µovti 'tOL)(WflOC'toc, 'TI ~<XA(3i6oc ataq,0tAEiatc; xoct o ei>Opatua'to<; 6iaxoc; 0at em'tpbtouv t'Tj\l e.xpo71 Xattti 'tpono WG'tE. ri ltLEG1j G'tO 1tEpif3A riµoc \IOC µ Tj\l U1te.pf30ti11e.1 't7j\l 1tiEG1j OOXLJl 71c;. (3) OL [3ocAf3i6e.c; ocaq,cxAEiatc; 'tWV 1tEpL~A 7Jµot'tW\I itou 1tpoo­ pi,ov't0tt jlOt t7j µe.t0tq,opdt atEpiwv 'tOU 7 ° XOtl 8 ° 80t El\lCXL OE ei07J 110t OtVoi1ouv at11v itie.a11 Amouniocc; itou cxvor.1pcxcpE'tcxL 1t0(\IW ato 1te.pif3A7Jµat. @at El\lr:1.t axe61ataµi11ec; Xat'tOC 'tE'tOLO tpono WO'tE \IOt Amouprou\l )(Wpic; acpa.Aµcx G't1j l(OCµljAO'tEp1j 6apµoxpcxaiat AEL'toupyLat<; 'touc;. H atl;101tta'ti0t t7Jc; AEl'toup1icxc; touc; a' OtU't7J 't7J llepµoxpcxaicx llcx OLOCltLG'tW\IE'tatL xcxL EAEY)(E'tOCL EttE µe. 6ox1µ71 xdt0e f30tAf3[6otc; ehe. µe OOXLP.TJ u;i,:ooe.trµcxwc; (3<XA(3i6occ; xdt8e. tunou. 8e.pµ1x71 µovw07J 211 234 (1) Av 1tEptf3A7Jp.0ttcx itou 1tpoopi~o\l't0tt 1Lcx 't7J µe.'tOtq,opdt u1po1tot7Jp.i11w11 attpiwv tou 3 ° xoct 4 ° ei11cx1 e.q,061ataµi11cx µa 8e.pµLXTj µovwa7J, atUtlj 7J fl0\IW07j 0cx GU\ILG't0tt0tt atltO tin: 01\l'tL1jAtatXT) cxaitt8at xatAU1t'touacx Ol(L ALjO'te.po o:1t6 -co 1t01\IW µLao -CTj<; rnupatve.icxc; -cou 1tEptf3A71µcx-coc; XOlt 8or. xwpi~E­ tOtL at1tO to 1tEpif3ATjflat µa xwpo cxipcx 'tOUAOC)(IG'tO 4 EX,, Ei-CE µe 1tATjp7J EltE\IOU07J, cxpxE'tOU 1t01l(OU<; OtltO µ011w-c1xoc UAtxat. (2) TitpL[3A71µ0tt(X 1t0U 1tpoopi,OV'tOtL jLOt 'tTJ JlE'tOtq:>opoc OtE­ piwv 'tou 7 ° xcxt 8 ° 0cx Ei11cx1 8Epp.1xcx µ011wµi11oc. H 8apµ1x71 µovWO'Tj 801 a!;or.aq,or.Ai,Et01t µa au\lE)(TJ E1ti116u07J. 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Ot 1tpor,:i..emiµ,11ec; ltlaGEL<; BoxLµiic; ,lvlltl: (ot) Av -co 1tepl~A71µot aivo:l .cpoBlctaµavo µe 8apµtxri µovwo71, 'tOuAotX,lO'tov ioec; itpoc; 'tTJY 1tlao71 ,to:'tµioewc;, µELwµivT) xot'tot 100 KP A ( I M 1t0tp ), wu uypou a-couc; 60°K, XotL OX,L At1onpo ot1t6 1 MPcx (10 M1totp)· (~) 0:11 'tO 1tEpl~A71µot Bev elvctL e~oJtALO[liVo µa 0Epf1-LX'1\ µ6vwo11, -couMxlo'tO LOT) f,tE 'tT)\I JtLE07I EtO:'tfl-LOEwc;, [J.ELW[LEIIT) XO:'tlX 100 KPct (1 M1totp), 'tOU u,pou o-couc; 65°x, Xlltt OXl 1uxponp11 OlltO 1 MPct (10 M1totp). 2. Ev o~El 't'>'jc; µe10.A71c; 'to~LXO't7l'tctc; 'tOU q,wo1eviov 'tOV 3 ° (o:'t), 71 oA<XXLO'tTj 1tiE01j 6oxLµT)c; 1t' ctU'tO 'to o.epw xot0opi~E'totL oE 1.5 MPct (15 M1tctp) o:v 'to 1tepi­ f,A·,1µot elvott E~OJtAlop.ivo µe 0,pµtxT) µovwori Xctl oE 1. 7 MPot ( 1 7 M1tctp) otv Bev Ei\lt,Xl E~OltALaµevo Xott' OlO'tO -cov -cpoito. 3. OL otvwtctw; 'tlf',i.c; nou 1tpo/3Ai1tovtotl oe Kf /1,,ltpo 1 lot ·ro /3019µ6 1tA71pw­ ae.wc; u1t0Ao1i~ov-rotl 01twc; notpotxo.'tw: ctVW-Cotto /3otpoc; mplexoµivou otvo. Attpo )('.WpT)-CLltO'tT)-COt<; = 0.95 x EtlilXO f,otpoc; tTj<; VjpT)c; ipo.aric; otouc; 50°K. 1320 E<DHMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) EAatX,LO'tTJ 7ttEOTJ Docx Lcr'tTJ 7ttEOTJ Avwtet.'tO ~ocpo,; OOXlfLTj<; 'YLO( OOXlfLTj<; 'YLO( 7tEplE)'.,OfLeVOU IIept1potcpTj oucrlcx,; Apt0µo,; 7tEpt~ATjfLCt.'tCt. 7tEplWTJfLCt.'tO( cxvoc ).[,:po Eioou,; fLE 0EpfLLXTj M Pet. x wpi:; µovwcrTJ MPet. X,WPTJ'tlXO'tTJ'tCt.<; BROMOCHLORODIFLUOROMETHANE (R 12 81) 3°(cx) 1.0 1.0 1.61 CHLORODIFLUOROMETHANE (R 22) 3o(et.) 2.4 2.6 1.03 CHLOROPENTAFLUOROETHANE (R 115) 3°(cx) 2.0 2.3 1.08 l-CHLOR0-2,2?2-TRIFLUORO-ETHANE (Rl 33cx) 3°(cx) 1.0 1.0 1.18 DICHLORODIFLUROMETHANE (Rl2) 3°(cx) 1.5 1.6 1.15 DICHLOROFLUOROMETHANE (R 21) 3°(cx) 1.0 l.O l.23 1,2-DICHLORO-l,l,2,2- TETRAFLUOROETHANE (R 114) 3°(oc) 1.0 1.0 1.30 OCTAFLUOROCYCLOBUTANE(RC318) 3°(et.) 1.0 1.0 1.34 Aµµwvlcx 3 °(cx,:) 2.6 2.9 0.53 XAwpto 3o(et.1:) 1. 7 l.9 1.25 HEXAFLUOROPROPYLENE (Rl216) 3o(et.1:) 1.7 1.9 1.11 Bpwµtoux o uopo1ovo 3 °(cx,:) 5.0 5.5 1.20 Bpwµtoux.o µe0UALO 3°(et.t) 1.0 1.0 1.51 &to~eioLO i:ou cx~w,:ou N02 3 ° (oci:) 1.0 1.0 1.30 <l>wcrrevLO 3 ° (oci:) 1.5 1. 7 1.23 &to~EiOLO i:ou 0elou 3 ° (ex,:) 1.0 1.2 1.23 Boui:atvLO 3 o(~) l.O 1.0 0.51 I-BUTENE 3 o(~) 1.0 l.O 0.53 l-CHLOR0-1, 1-DI.FLUOROETHANE (R 142~) 3 o(~) 1.0 1.0 0.99 CIS-2-BUTENE 3 o(~) 1.0 1.0 0.55 KuxA01tpo1t0tvto 3 o(~) 1.6 1.8 0.53 1,1-DIFLUOROETHANE (R 152cx) 3 o(~) 1.4 1.6 0.79 DIMETHYL ETHER 3 o(~) 1.4 1.6 0.58 foo~OU'tOCVLO 3 o(~) 1.0 1.0· 0.49 lcro~oui:ivto 3 o(~) 1.0 1.0 0.52 IIpo1t0tvto 3 o(~) 2.1 2.3 0.42 IIpo1tUAEVLO 3 o(~) 2.5 2.7 0.43 TRANS-2-BUTENE 3 o(~) 1.0 1.0 0.54 1,1,1-TRIFLUOROETHANE 3 o(~) 2.8 3.2 0.79 &tµe0u).ocµlvTJ 3 o(~,:) 1.0 1.0 0.59 E0u).cxµlv1J 3 0 (~,:) 1.0 1.0 0.61 ETHYL CHLORIDE 3 o(~,:) 1.0 1.0 0.80 Yop60eLO 3 o(~,:) 4.5 5.0 0.67 Me0u).ocµivTJ 3 o(~,:) 1.0 1.1 0.58 METHYL CHLORIDE 3 o(~,:) l.3 1.5 0.81 METHYL MERCAPT AN 30(~,:) 1.0 1.0 0.78 T ptµe0u).cxµlvTJ 3 °(~t) 1.0 1.0 0.56 1,2-BUTADIENE 3 o(,) 1.0 1.0 0.59 1,3-BUTADIENE 3 o(,) ,l.O 1.0 0.55 VINYL CHLORIDE 3 o(,) l.O 1.1 0.81 METHYL VINYL ETHER · 3°(CT) 1.0 1.0 0.67 TRIFLUOROCHLOROETHYLENE (R 1113) 3°(CT) 1.5 1. 7 1.13 VINYL BROMIDE 3°(CT) 1.0 1.0 1.37 Ml1µcx F 1 4°(et.) 1.0 1.1 1.23 Ml1µcx F 2 4°(et.) 1.5 1.6 1.15 Mlrµcx F 3 4°(cx) 2.4 2.7 1.03 Ml1µcx oceplwvR 500 4°(cx) 1.8 2.0 1.01 · Ml1µcx cxeplwvR 502 4o(et.) 2.5 2.8 1.05 Mt,µcx,:cx 'tOU 19 fLEX,PL 21 01:0( EXCt.'tO )(O('tO( µoc~oc DI CHLORODIFLUOROMETHANE (R 12) xcxt 79 µix pt 81 0,:0( EXOC'tO )(O('tO( fLOt~Ct. BROMOCHLORODIFLUO ROMETHANE (R 12 BI) 4o(et.) 1.0 1.1 1.50 Ml1µcxi:cx METHYL BROMIDE xcxt X).wpomxplvTJ<; 4 C (et.,:) 1.0 1.0 1.51 Mt,µcx A ( EfL7t0plXO ovoµcx: Boui:OCVLO) 40(~) 1.0 1.0 0.50 Mirµcx A O (eµ1top. ovoµcx Boui:ocvto) 40(~) 1.2 l.4. ·o.47 Ml1µcx A 1 40(~) 1.6 l.8 0.46 Ml1µcx B 4 o(~) 2.0 2.3 0.43 Mlrµcx r (1tpo1t0tVLO) 4 o(~) 2.5 2.7 0.42 Ml,µcx,:cx uopo,ovcxv8pocxwv 7tOU 7tEpLEX,OUV fLE0atvLO 40(~) 22,5 0.187 30.0 0.244 Ml1µcxi:cx METHYL CHLORIDE xcxt METHYLENE CHLORIDE 4 o(~,:) l.3 1.5 0.81 Ml1µcxi:cx METHYL CHLORIDE xcxt x AwpomxplvTj<; 40(~,:) 1.3 1.5 0.81 Ml1µcxi:cx METHYL BROMIDE xcxt ETHYLENE BROMIDE 4 o(~,) 1.0 1.0 1.51 Mi-yµcx-.cx METHYLACETYLENE PROPADIENE xcxt u6po,ovocvopcxxcx Ml1µcx P 1 40(,) 2.5 2.8 0.49 <l>EK 104 t:wHMt:PIL I Hz. ", .. EP,~, ,z. ... !!.lL I 1 ... , J\Ul. ~ ... , 1 ... , u1 EA&xta,TJ 1tiea1J n&xta,TJ itiEalJ Avwww ~&po.; 6oxtµTj<; 1 tot 6oxtµTjc; 1 tot itEptEXOfl-EVOU Ilept1potcp'Tj ouoiot.; Apt8µ6.; ltEpt~ATj[l-ot'tot itEpt~ATj[l-ot'tot otv& Ahpo Ei6ou.; fl-E 0EPfl-lXTj MPot xwpi<; fl-OVWOTJ MPot XWPlJ'tlXOTT]'tot<; Miyµix P 2 4 o(r) 2.2 2.3 0.47 Mi1µix,ix 1,3-BUTADIENE xa.t u6po1ovotv0p&xwv ,ou 3 o(~) 4 o(,) 1.0 1.0 0.50 ETHYLENE OXIDE 1tEptaxov OXL 1tEptoo6,apo IXltO 10 O'tlX EXIX'tO 6to~ai6to 'tOU &v0pixxix Xot't!X µix,ot 4 ° (CT) 2.4 2.6 0.73 ETHYLENE OXIDE µa (X'(l)'tO µaxpt OUVOAlXTj ltLEO'Tj 1 MPot (10 µ1tdtp) O'tOU<; 50°K 4°(CT) 1.5 1.5 0.78 DICHLORODIFLUOROMETHANE 1tou mptiXEt 12 O'tot EXIX'tO ETHYLENE OXIDE XIX't(X fl-<X'IX 4°(CT) 1.5 1.6 1.09 (3) ftlX 1tEpt~ATj[l-ot'tot ltOU itpoopi~OV'tlXL 1llX 'tlj fl-E'totcpopdt IXEp[wv 'tOU 5 ° Xotl 6 ° (ot) (XV 'tot ltEPL~ATj[l-(X'tot 6ev axouv E1tiv6uo7J "(lot 0epµtXTj fl-OVWO'Tj: 'tot E1timB1X ltOU IXVotcpEpOV't(Xt O'to mpt0wptotXO 2220 (3) Xotl (4)· (~) otv 't(X 1tEpt~ATj[l-ot'tot ixouv E1tiv6uol] 1 t(X 0epµtx'Tj µ6vwo7J 61tw<; xot0opi,E,a.t o,o 1tEpt8wptotx6 211 234 (1 ): 't(X rnimfo itou otvotcpipoV'tott 1totpot­ xdt,w: BROMOTRIFLUOROMETHANE (Rl3 B 1) &to~Ei6t0 'tOU <XV0potX!X CHLOROTRIFLUOROMETHANE (R 13) HEXAFLUOROETHANE (R 116) Ilpw,o~Ei6to ,ou ot~W'tOU (NAO) SULPHUR HESAFLUORiuE TRIFLUOROMETHANE (R 23) :::avo HYDROGEN CHLORIDE At0<ivto At8UAEVlO 1, 1-DIFLUOROETHYLENE VINYL FLUORIDE Mi1µix,ix otEpiwv R 503 &t0~Ei6to 'tOU <iv0pixxlX ltOU 1tEptEXEl oxt 1tEptoo6npo IXltO 35 O'tlX exix,6 ETHYLENE OXIDE xix,<i ~<ipo.; O~ai6to ,ou At0uAEviou 1tou 1tEptEXEt it<ivw ix1t6 10 ow Exix,6 cxndt 6x t 1t<ivw ix1t6 50 o,ot axix,6 6to~ai6to wu <iv0potxlX xot,dt ~<ipo<; 5°(ix) 5°(ot) 50(1X) 5 °(ot) 5°(ot) so(ix) 5 °{ot) 5°(1X't) so(~) 5 o(~) 5 o(,) 5 o("() 6°(ot) 60(,) 6°((CT) Avw'tot'tlj ltLEOlj 6oxtµTj<; MPot 12.0 19.0 12.0 22.5 16.0 20.0 22.5 12.0 • 19.0 25.0 12.0 12.0 12'.0 12.0• 22.5 12.0 22.5 12.0 22.5 3.1 4.2 10.0 19.0 22.5 19.0 25.0 Avw,(X,lJ µdt~ot 1tEptEXOµEVOU ()(Vat ),['tpo XWPlJ'tlXO'tlj'tot<; KGS • 1.5 0.73 0.96 1.12 1.28 1.34 0.78 1.34 0.92 0.99 1.30 0.69 0.32 0.25 0.36 0.66 0.78 0.58 0.65 0.11 0.21 0.76 0.73 0.78 0.66 0.75 ·01tou mpt~ATjfl-lX't<X EltEV6uµivix "(l<X 0EpµtXTj fl-OVWO'Tj XPlJOlfJ.OltOlOUV'totl, 'tot OltOLot axouv UltO~A7J0Ei OE 6oxtµTj mfoaw<; X.otfl-ljAO'tEPlJ otltO EXELVlj 1tou otvotcpipa,ott o,ov itivcxxot, lJ IXVW'tlX'tlJ µ<i,cx ,:ou itEptaxoµivou cxv<i Ai,po x wpl]'ttXO'tlJ1:<X<; Sot aivixt ,hotix woi:E lJ 1tiEOlJ 1tou Em,urx<ivE,ott o,:o 1tEpt~Al]µot ix1t6 TT]V EV A61w ouoiot o,ou<; 55 °K 6Ev U1tEp~otivEL 'tl]V 1ttEOlJ 6oxtµTj<; 1tou EtVotL cx1to,u1twµivl] 1t<ivw o,o itEpi~Aljfl-<X. LE ,hotix 1tapi 1t'tWOlj ,o cxvw,ix,o E1tt'tprn,6 ~<ipo<; Sot xix0opi,E,IXL ix1t6 ,ov Et6tx6 1tou qxpivat lJ ixpµ66tix IXPXTJ· (4) ftix 1tEpt~ATjµ1X't1X 1tpoopt,aµEvot 1 tot 't'TJ µE't1Xcpop<i cxµµwviix.; 6t1XAU[J-EVTJ u1t6 1tiEC1TJ. 'tOU 9° (cx't): Ilapt1pixcpTJ ouoiix.; Aµµwvicx 6tixAuµivlj u1t6 1tiEC1TJ oE vapo µa 1tEptCICIO'tEpO otltO 35 Cl'tot EXIX'tO otAA(X oxt lt(XVW IXltO 40 Cl'tlX EXot'tO otµµwviot xot'tor. µ&~ot µE itEptooo'tEpo ix1t6 40 o,:ix EXIX'to ixnor. oxt 1tEptoo6npo ot1t6 50 O'tot EXot'to cxµµwviot otµµwviix XIX't<X µor.,ix AvW't!X'tTJ 1ttEC1TJ 6oxtµTj<; MPix 1.0 1.0 Avw'tlX1:TJ µ<i,ix ltEptEXOfl-EVOU ixv<i Ahpo xwplj'tLXO'tTJ'tlX<; KG 0.80 0.77 1322 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) (5) ftcx 1tEpt(3A7l(..I.CX"tCX 7tOU 1tpoopi~OV"t0tl "(LOt ,;71 (..I.E"t0tcpopdt cxepiw11 i-ou 7 ° xoct 8 °: oxt ).ryonpo cxno 1.3 cpopic; ,;71v cxvw­ "tCX't71 E1tt"tpE1tO(..I.EV711tiE071 EpjCXOi0tc;, 01twc; cxvcxrpdtcpE"tCXL lt(XYW o,;o 1tEpi(3).71p.cx, illdt ox t At1onpo cxito 0.3 MPcx (3 p.1tdtp) (1tiE071 µE,;p71,;ij)· jLCX 1tEpt(3A71µa,;0t fJ-E µovwo71 XEYO\I 7j 1tieo71 6oxtµijc; 6Ev Oa Eivat AtjO"tEpo 0t1to 1.3 cpopic; 71 0tvwt0tt7j Em­ rpe1toµev71 1ttE071 Ep10toi0tc; 0tu!;71p.iv71 xatct 0.1 MPa (1 (..l.7t1Xp). H 1tpW't7l 6oxtp.71 u6pauAtxijc; mfoewc; Oa 1ivEtOtt 1tptv ,;o- 211 252 1toOE-t7lOd <1't7l Oi071 't7lc; 71 Oepp.tx71 µovwo71. H xwp71-rtXO't7JtOt xctOE 1tEptf3A 71µ0t,oc; 7tOU 1tpoopt~E"tOtl jlOt 211 2 5 3 ni µnacpopix aep[wv ,ou 3 ° µix pt 6 ° xat 9 ° Oa xaeop[~Etott U7t0 't71V E1ti(3AE<f11 Et6txou EjXptVOfJ-EVOU Ot7t0 'tTJY 0tpµo6t0t cxpx ij, (..I.E ~1JTL071 11 orxoµE-rptxij p.i-tp71071 ,71c; 7t000"t1j"t0t<; VE pou 71 01to[a yeµi~Et -ro 1tepif3).71p.0t· 01toto6711ton ).a;Ooi:; 0,11 p.i-tp11ori 't7lc; x.wp71,oco't11-rac; ,ou 7tEpt(3A71µawc; Oa eivat Atyo npo ano !vex o-ra, Exoc-ro. Ilpoo6toptoµoc; µE u1to).01toµo (3aot l;oµEvo O'ttc; 6totO't!XOEtc; ,;ou 1tEpt/3A1j(..l.ot'toc; 6Ev Em'tpEltE'tOtt. Ot 00/W"tCX"tEc; µot~Ec; 1tA71pwoewc; 7tOU E7tt'tpE7tOV't0tl ouµcpwva fLE 'tOt 1tEptewpt0tXot 2220 (4) XOtl 211 251 (3) ea opi~OV'tott otltO ETXptVO(..I.EYO Et6txo. 0 EAEjXOc; "tWY ourxoll710EWV Oa jtYE'tOtl ouµcpwvOt (..I.E ,tc; 211 254 ot7t0tt't1j0Etc; 'tOU OUV'tEAEO'tT) AtX(..l.60t 1. 0 'tOU 1tEptewpt0tXOU 211 127 (7) . Ka,;a; 1t0tpixxAta71 ,;wv 0t1t0tttj0Ewv -rou 1tEptOwpt0txou 211 211 2 5 5 151, Ol 1tEpto6txic; 6oxtµic; ea jlVOV'tOtt: (1) XIX0E -rpi0t x povtOt O't71V 1tEpi1t-rw071 1tEpt(3).71µix,wv 1tou 1tpoop[~ov,0tt jtOt ,71 iimccpopix BORON TRIFLUORIDE ,;ou 1 ° (a,), cpw,0tEpiou ,;ou 2° (BT) HYDROGEN BROMIDE, x ).wpiv71c;, 6to!;Ei6t0u ,;ou a~w-rou, 6to!;Ei6tou -rou eE[ou ii cpworEviou -rou 3 ° (a,), HYDROGEN SULPHIDE ,ou 3 ° (BT), 71 HYDROGEN CHLORIDE -rou 5° (a,)· (2) XCX0E E/;7) x poVtOt O't71V 1tEpi1t"tW071 1tEpt(3A71µdt,wv 7tOU 1tpoop[~OV'tOtl jlOt 't"Tj f-'E'tCXcpopix cxllwv ouµ1ttEaµivwv XOtl urpo1tot71µivwv OtEpiwv 71 6totAuµiv71c; U7t0 1tiE071c; 0tp.µwvi0tc; 'tOU 9° (a,;)· XOtl • (3) (.I.E't!X 0t7t0 E!;anij U7t1jpEoia XOtl Ot7t0 EXEl XOtl 1tip0t xdtOE 6w6EX0t x pOVLOt. O-t7lY 1tEpi1t,;wa71 1tEptf3A71µcx,wv 1tou 1tpoopi,ov-rm 1tcx •TJ f-'E'tCXcpopdt CXEpiwv 'tOU 7 ° 71 8 °. 0 EAETXO,; o-ce.rcxvo,:71,;cxc; Ocx "'(LYE'tCXt CX7t0 E.jXpt(..I.EYO Et6tXO El;Tj x povtot (..I.E't<X CX7t0 Xctee. 1te.­ pt06tx1j 6oxtµ.ij. :I:'t71V 1tEpi1t'tW071 1tEptf3A71µcti:wv 7t0U ixouv µ011wo71 XO("t(X 211 256 nic; 8Epµo't7l,cxc; µe XEYO, 71 6oxtµij u6pcxuAtxijc; mfoEwc; xcxt o • u..Erxoc; 't7lc; eawuptx71c; xcx-rcxa-raoEwc; µ1tope.i, µe TT) ouvcxi ve071 'tOU ET"PlfJ-EYOU Et6tXOU, VCX CXV"tlXCX"tCXO"tCX00UV CXltO 60XL(..I.Tj O"tET0010't7l"tCXc; xcxt µii:p71a71 ,ou xevou. Av exouv yivEt CXYOLj(..I.CX"tCX, (..I.E ,:71v EUXCXtpicx "tWY 1tEpt06txwv 211 2 5 7 E1tt81twp71oewv, OE 1tEpt(3A71µcxi:cx npoopt,oµe.vcx 1toc i:71 µEi:0t q,opix CXEpiwv ,;ou 7° 71 8 °, 71 p.e0o6oc; µE 't71Y 01tolcx xAe.ivov,cxt EP(..I.TJ'ttXIX 1tptv -rcx 1te.pt(3A71µcx,cx u0ouv EX vfou oi u1t71pe.oicx 0cx EjxpivE'tOtt CX7t0 'tOY EjXptµivo Et6txo XCXL 0cx E!;cxocpcxAi~ouv 't71V cxxepcxtO't7l'tCX -rou 1teptf3A71µcxwc;. 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Aauxoc; Tj xhptvoc; cpwocpopoc; 'tOU itapt0wpt1XXOU 2 431, 1 °, 211 4 71 cx.v XPTJotµoitotai-cixt vapo ocxv 1tpoo1:oc-caunxoc; 1t1Xpli1wv, 0cx XIXA\llt'tO\l'tOtt µa f,liOoc; ox1 µtxpo,apo IXltO 12 ax. vapou XCX'tlX 'tO XPOVO 'tOU yaµioµcx-coc;· 0 f,IXOµoc; ltATJpwoawc; oa 0apµo xpcxoilX 60 ° K 6av 0ot uitapf,otivat 'tO 96 o-ccx axot-co. Q otitOµEVW\I xwpoc; 0ot 1aµi,e'tott µa ot'W'tO Xot'tot 'tE'tOto 'tp07t0 won, otxoµTj Xott µa-cli 'tO xpuwµ1X, Tj 7tLEOTJ OE xcxµµtot o-ctyµTj 6av 0ot 1ticpnt XIX'tW otito 'tTJV ot-cµoocpottptxTj 1tiao7J, To 1tapif,A7Jµot 0ot aivott apµ7J1:txli xAatoµivo wo,a vex µTjv 1tcxpou­ ota.,a-cott 6totppori otapiou. rtot 'tTJ µa-cotcpopli OUOtWV 'tOU itaptOwptotXOU 24 71, 1 ° (ot), 'tot 211 4 72 • 1twµot't(X 0ot aivott XAatowµivot ouµcpwvot µa 'tO 1tapt8wpt0txo 211 432. riot 'tTJV TRICHLOROSILANE (SILJCOCHLOROFORM) 211 473 'tOU 1tapt8wptcxxou 24 71, 4 ° (ex) Tj ytlX 'tTJ METHYLDICH­ LOROSILANE ri ETHYLDICHLOROSILANE -cou 4 ° ((,), 0 {31X8µoc; ltATJpwoawc; 6av 0ot u1tapf31XiVaL 'tO 1.14 Tj 0. 95 Tj 0.93 KG IXVIX Ahpo XWPTJ'tlXO'tTj'totc; IXV'tLCl'totXCX, ~\I 'tO ,aµ1 0µ1X 1iva-cott XIX'tlX µot'IX ri 85 o,IX axcx-co 1XV -co yiµtoµ1X 1iva,1Xt µa oyxo. Tiaptf,ATjµIX'tlX 'tot OltOLIX lteptaixcxv cpoocpwpo 'tOU 1taptOwptotXO\l 211 4 7 4 2431, 1 °, O'totV 1totpot6i6ov-ccxt ytcx cpop'tWOTj: • - aha 81X 1afLi,o1(,ott µa a,w'to· o ot1too1:0Ai1Xc; Ocx mo-co 7tOtai O'tO enpotcpo µa1:1Xcpopotc; O'tt 'tO 1tapi(,ATJfLIX, µa-cot 'tO xAai­ atµo, aivott otapoanyic;, aha 81X raµi,a'tOtl µa vapo µexpt oxt At,o-capo IX7t0 'tO 96 O'tlX EXot'tO Xotl ox1 1teptooonpo ot7t0 'tO 98 O'tot Eltot'tO 'tTjc; xw­ PT)'tlXO'tTJ'tlXc; 1:ouc;· µa-cot!;u 17Jc; Ox-cwf3piou xcxt 3171c; M1Xp1:[ou IXU'tO 'tO vapo Oot 7tEptEXEL EVIX Tj 1taptoOO'tEpot otvw}ux'ttXot cx.itillotyµivot ot1to o!;at6w-c1xri avip1wi, fl.TJ u1toxaiµav1X oa IXV'tiOpoto71 µa 'tO cpwocpopo XIXt OE 'tE'totot OUfLltUXVWOTj WO'tE vex xot0tO'tot otouvotw -co itli1wµot "tou vapou xcx-cli 1:11 µa'tcxcpopli. ~a!;otµavic; ltOU 1taptaixotv cpwocpopo 'tOU 1taptOwptcxxou 2 431, 1 ° 1tpi1tat vot 0awpouv-cott, ooov 1Xcpopot -c11v acpotpµo1ri 'twv 6tlX'tlX!;EWV.'tOU itapt0wpt1XXOU 42 500 (1), cm EtVIXt «xavac; 6a­ !;1Xf1.E\IE<;,' ·01xot61ipto'tac;». 0 [3ix0µoc; ltATjpwaawc; ,tix itaptf,ATjµIX'tOC ltOU mptixouv ou- 211 4 7 5 aiac; wu mpt0wptixxoii 2431, 3 °, ri -cou 1tap10wpuxxoii 24 71, 2 ° (a) 6av 0ix u1tapf3ixivat 'tO 90 CJ't(X EltlX'tO. xwpoc; 5 Cl'tlX EXOt'tO 0ix 1t1Xp1Xµiva1 xavoc; r1ix IXClcpaAatlX O'tlXV 'tO urpo atVIXI aa µtlX µiOTj 0apµoxp1Xaiix 50 ° K. L'tTJ 6tlipxatix 'tTjc; µa-coccpopotc;, ot ouoiEc; 0ix f,pioXOV'tlXt ltot'tW IXltO a-cpwµcx ix6pcxvouc; cxapiou, TJ 1tiao7J µa'tpTJ'tTj 'tou oitoiou 6av 81X u1tapf31Xivat -co 50 KPix (0.5 µitixp). Tix mptf3ATjµ1X,1X 81X aivlXt apµTj'tLXot XAato-ci0/ xoct ,IX 1tpOO'tlX'tEUWtlX 1twµ0t,1X ouµcpwvcx µa 'tO 1tapt8wptcxxo 211 433 Ooc aivixt xAat6wµivoc. Tix xavot 1taptf3ATjµoc1:oc. 1Xx1XOotpt 01:0t, o-ccxv 1t1Xp0t6i6ov-c1Xt 1 tlX µa,cxcpopli, 81X Eiv1Xt 1aµ<h1X µa cx6pcxvic; CXEpto oa ltLECITJ µa-cpTJ'tTj µixpt 50 KPcx (0.5 µitcxp). K0t1:7J1opicx 5 .1: O!;at6w~txic; ouoiac; Kcx,7J1opicx 5.2: Op1cxvtxli u1tapo!;ai6tcx Ticxplirpcxcpoc; 1: favtxli· 7tAIXLOt0 (XPT}OTJ 6a!;1Xµavwv )· • Optoµoi XpiJOTJ 211 476 211 499 211 500 211 509 Ot 1totpot.1 tot,w ouoiac; 'tTjc; Kcx-c111opicxc; 5 .1 µ1topouv VIX µa'tlX- 211 510 cpipov-cott aa o'tot0apic; ri ot1toauvcxpµoA01ouµavac; 6a!;1Xµavic;: ouoiac; 'tOU 1 ° µexpt 3 °, 6tcxAuµot,Ot 'tOU 4 °(a1tio11c; SODIUM CHLORATE O't'Tj\l urpri iJ 'tTJ O'tE"(\11) XCX'totCl'tlXOTJ) XIXL Oapµot UOot'tW6Tj 611XAuµot'tot AMMONIUM NITRATE 'tOU 6° (oc) oa ouµ1tuxvwo11 itotvw 1X1to 80 o-ccx axoc-co IXAAot oxt 1taptooo-capo IXltO 93 O'tot EXot'tO µa 'tOV opo O'tt: (ot) TJ 'tlfl.Tj 'tOU PH, fl.E'tpouµav11 oa u61X-cw6a:; 6totAUfl.lX 10 o'tot axot'to -c11c; µa-cotcpapoµav11c; ouaiocc;, aiv1Xt µa,1X!;u 5 XIXL 7, Xott ((,) 'tot 6totAUf1.ot't(X oav 1taptexouv 07tOtCX6TjltO'ta XIXUCJLµTj ou­ OLOt aa 7tOCIO'tTj'tot µaylXAU'tEpTj otltO 0.2 O'tOC axcx,o ri OltOto6-iJ 7tO'tE µi,µ1X x:~.wpivTjc; oa 'tE'totot ltOOO'tTj'tlX WO'tE 'tO 1taptaxo­ µavo xAwpivTjc; u1tapf3otivat 'tO 0.02 O'tlX axot-co. Ouoiac; -cou 1 °, 10 °, 14 °, 15 ° xcxt 18 ° 'tTjc; Kot-c111opicxc; 5.2 µitopai VIX µa-ccxcpipov'tcxt oa a,1X8apic; iJ 1X1toou111Xpµ0Ao- • 1ouµavac; 6a!;1Xµaviq. lHMEIOlH: ftcx 'tTJ µa,1Xcpopot oa xuµcx OUOIW\I 'tOU 4 ° µexpt 6 ° XIXL 'tOU 7 ° ( ot} XOCL (f,) 'tTjc; K1X'tTJ10Pi1Xc; 5 .1 (3AEltE 'tO 1tap10wpt1XXO 51 111. Tiotpot1potcpoc; 2: Kot-catoxauri 211 511 211 519 Tiaptf,ATjµoc-cot itpoopt,OfLEVIX YLIX 'tTJ µa1:1Xcpopot aa urpri Xot'tlX- 211 520 O'totOTj OUCILWV 7tOU otVotq>EpOV'totl O'tO 1tapt8wptOCXO 211 510 0ot aivott axa6t1Xoµivot 1 tlX 1tiao11 -couAliXto,o 0.4 MPcx (4 µ1t1Xp) (itlEOTJ fl.E'tpTJi:Tj), I1aptf,A71µcx'tot, xcxt -cot aiBTJ -cou a!;o1tAtoµou -couc;, itou 1tpoopi- 211 521 'OV'tott 1 tot 'tTJ fl.E'totcpopot U1tapo!;at6tOU 'tOU U0po10VOU Tj U0CX 'tW6wv 6t1XAuµot-cwv u1tapo!;a16iou wu u6po1ovou -cou 1tap10w p1otxou 2501, 1 °, Tj u1pwv op10tVLXWV UltEpo!;at6tW\I 'tOU 7tE­ pt0wpt0tXOU 2 5 51, 1 °, 10 °, 14 °, 15 ° xlXt 18 ° Bcx aivott x1X­ 't0toxaucxaµivot IXltO IXAouµivto xot01XpO'tTj'tOCc; oxt Atyo-capo ot7t0 99,5 O'tot EXOC'tO ri OCltO XCX'tOIMTJAO xitAuf,ot ltOU 6av 0ot 1tpoxcx AECIEl ot1toouv8ao11 'tOU Ultapo!;at6iou 'tOU uopoyovou ri 'tWV op yotvtXW\I u1tapo!;a16iwv. Tiap1f,H1µot-coc 1tpoop1,oµavot 1 tot 'tTJ µa-coccpopot ouµ1tuxvwµi- 211 522 vwv xcxt 0apµwv u6po6tcxAuµli-cwv AMMONIUM NITRATE 'tOU 1tap18wptotxoii 2501, 6° (ot), 0oc aivoct XIX'totoxauotoµevot IXltO WO'tE\lt'ttXO xaAuf,ot. 211 523 Tiotpli1p1Xcpoc; 3: Ei6TJ a;o1tAtoµou ·-211 529 IIapt{3AiJµot,ot 1tpoop1,oµavot 1 tcx 'tTJ µa,1Xcpopii u1tapo!;at6[ou 211 53 0 'tou u6po1ovou xott u6ot,0611XAuµli-cwv -cou u1tapo!;a16iou wu uopo,ovou ltOU 1tap1exouv 7tlXVW otltO 7 0 O'tot EXCX'tO uitapo!;ai 610 'tOU uopoyovou 'tOU itaptOwptcxxoii 2501, 1 °' 0ot ixouv 'tot 0tvoiyµ01-cot 'touc; mxvw ot7t0 'tTJV O'totOµTj 'tOU uypou. E1ti ltAEOV, 'tOt 01voi1µot,ot xocOcxptoµou 01twc; otvOtcpipov-ccxi o-co 1tap10w ptocxo 211 132 6av Ooc am-cpi1tov-coc1. L'tTjV 1tapi1t,WOTJ 6tocAu µli'tWV ltOU itaptEXOUV U7tapo!;ai6to 'tOU u6po10VOU ltlXVW CX7t0 60 O'tOt EXot'tO OtAAOt ox11taptooo-capo Ot7t0 70 O'tot EX(X'tO 0ot am 'tpE7tOV'tOtt 1Xvo[1µot,01 xii-cw 1X1to 'tTJV amcpiiva101. 1:ou u1pou. ~'tTJV 1tapi1t-cwo11 otU'tTj -co auo'tTJfl.lX xavwoawc; -cou itap1[3A Tjfl.lX 'to<; 801 aivlXt a;oitAtoµivo µa Biio aµot[3otilX cxva;otp,TJ'tE<; ou oxauic; xAatoiµot'toc; -co1to8a,11µivac; aa oatpii, 'tTJ<; 1tpw,11c; 1326 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) ).ocµf3ixvouaotc; 'TT} fLOpcp7j Eac,mptxric; f3oc).f3[6occ; ,otXEiotc; AEt­ ,oup1i~ XAEtOtfLot'toc; E1xptfLEVOU ,u1tou xm ,7Jc; OEu,Ep7Jc; EXEiv7Jc; 'TT}c; (3otAf3io~ Exporic; aE xix9E ixxpo ,ou aWA7jV<X xEvw­ aEwc;. E1tiG7Jc; 9ot U7tlXPXEL 't07t09E't7JfLEV7J AEUX'Yj cpAIX\l't~(X 1j IXAA7J OUOXEU7j 7totpixouaot 'tO iota fLE'tpo otacpotAEiotc; O'tTj\l i!;ooo xix9e E!;wnptxijc; ~<XA~ioocc; ,ocxeiocc; XE\IWOEwc;. H EOW'tEptxiJ f3~ioot XAEtOtfL<X'toc; Bot Et\lott 'tE'tOtot wan, (XV O OWATJV<Xc; !;E­ f31owlM 7J f3otA~ioot \lot 7totpotfLEL\IEt otXEpotL7j fLE 'tO 7tEpi~A7JfL<X Xott OE XAEtG't'Yj 9fo7J. Ot OWOEGEtc; 1tpoc; 'tOUc; E!;wnptxouc; OWA7jVEc; XE\IWOEWc; 'tW\I 211 531 7tEpt~ATJfLIX'tW\I Bot Xot't<XOXEUIX~O\l'tott 0(7t() UAtXIX 'tot 07t0tot OE\/ 1tpoXEl'tott \lot 1tpoxotAiaow ot7tOOUV9EaTJ 'tOU U7tEpo!;Etoiou 'tOU u6po16vou. TTEptf3ATJfL<X'tot 1tou 1tpoopi,onott 1tot 't7J fLE'totcpopix U7tEpo!;Ei- 211 532 6tou ,ou u6po16vou 7j u6oc,o6totAUfLIX'tWV U1tEpo!;Et6iou ,ou 1 °, 71 OUfL7tUXVWfLE\IW\I Xott 9EpfLW\I UOot'tOOtotAUfLIX'tW\I AMMO NIUM NITRATE 'tOU 6 ° (ot), 'tOU 1tEpt8wpt9txou 2501 80: Et VO:I E!;o1tAtafLEVot G'tO 1tavw fLEpoc; 'tOUc; fLE auaxwri Ot<XX01tiJc; 1to:poxric; 7tOU EfL7tOOt,EI 't7j OTJfLtOUpyiot U1tEp~oAtxiJc; mfoEwc; µfoot O'tO 6oxElo, 07tOt0:0TJ7tO'tE Ot<Xppori uypou XO(t 01tOI0:07j 1tO'tE Etao6o !;ivwv OUOIW\I fLEGO: O'tO ooxaio. Ot auaxEuic; Ot<X X07t7jc; 1to:poxric; 7tEpt~A7JfLIX'tW\I 7t0U 1tpoopt,O\l'tO:t y10: 't7j fLE 'totq>opix OUfL7tUX\IWfLEVW\I XO:t 0Epµwv UO<X'tOOIO:AUfLIX'tW\I AM MONIUM NITRATE 0o: Et\10:t r:JXEOtO:OfLEVEc; Xot'tO( 'tE'tOtO ,p61to wan VO: (X7tOXAEtOW ot1t6cppot!;7J 'tW\I auaxwwv ot7t0 an­ pE01tOt7jfLEVO AMMONIUM NITRATE X<X,a 't7J ouxpim<X ,7Jc; fLE'totq>Op!Xc;. ·01tou 1tEptf3A7jfL<X'tO: 1tpoopt~ofLEVO: 11oc 't7J fLE,o:q>opa OUfL7tU- 211 533 XVWf!E\IW\I X0:1 0EpfLW\I OtotAUfLIX'tW\I AMMONIUM NIT RATE 'tOU 7tEpt0wptotXOU 2501, 6° (ot), ixow E7tE\IOU07J fLE UAtXO 9Epµtxric; fLOVWOEwc;, 'tO UAtXO 80: Et\10(1 ot116pyot117Jc; q>u OEWc; xo:1 'tEAEiwc; Ot7tO:AAot1fLEVO o:1t6 x0tuatfLO UATJ. TTap1~A1J(.L<X'tot 1tou 1tpoopi,onoct 1tot '"l fLE'totcpopix u1pwv op- 211 534 10tVtXW\I U1tEpo!;Et0tW\I 'tOU 7tEpt0wpt0:XOU 2551, 1 °, 10°, 14 °, 15 ° Xott 18 °, 0o: Et\lott E!;o1tAtOfLE\IO: fLE auaxEU'Yj O:Ept oµou Eq>o61ocaµi117J fLE cpAo101tot1i6oc xoc1 80: ocxoAou0Ei'to:1 OE OEtp<X ot1to ~otA(3i6oc otoq>otAEiotc; 1tou lloc ocvoi1Et OE 1tiEa7J fLE 'tPTJTIJ 0.18 fLEXPt 0.22 MPot (1.8 fLEXPt 2.2 fL1to:p) Ilept~A7jfL0t't(X 1tpoopt~OfLE\IO: ytot 'TT} fLE'tot<popa uypwv opym11- 211 53 5 xwv umpo!;EtOiwv 'tOU 1tEp18wp1otxou 2551, 1 °, 10 °, 14 °, 15 ° xott 18 ° llot Et\lott E!;o1tAtOfLEVO: fLE otAE!;7jAtO ot\l't.ot1toxptv6 µE110 O'ttc; ot7t0:l't7j0Etc; 'tOU 7tEpt9wpto:xou 211 234 (1). To otA£!;7jAtO Xotl 'tO ocxaAU7t'tO 'tfL'YjfLOt 'tOU 7tEpt~A1jfL<X'tOc; 0ot Et\lott XPW(.Lot'ttOfLEVot AEUXIX xo:t ,o XPWfL<X 80: xo:llocpi,no:t 1tptv ot1t6 xalle fLE'tot<poptxo ,ot!;ei6t l((Xt llot (X\l(X\IEW\IE'tott OE 7tEpt7t'tWOTJ Xt'tptviafL<X'tO<; ri q,9opac;. Tot otAE!;7jAtot llot Et\lott ot7totAA<XifLE\lot CX7t0 X<XUOlfLTJ UATJ. TT01po:1pot<poc;4: "E1xpta7J 'tU1tou ( &ev u1tixpxouv Et6txic; 1tpoii1tolliaEtc;) Ilo:pix1pexq,oc; 5: &oxtfLic; 211 536 211 539 211 540 211 549 IlEpt~A7lfL<X't0t 1tpoopt,oµE11ot 1tot ,7J p.E,o:<popix u1tEpo!;Etoiou 211 550 'tOU uopo,ovou 71 UOot'tOOtexAUfLIX'tW\I U7tEpo!;EtOiou 'tOU uopo-yo vou 'tOU 1 °' 7j CJUfL7tUX\IWfLEVW\I xext llEpfLW\I OtotAUfLIX'tW\I AM MONIUM NITRATE ,ou 6° (oc), i:ou 1tEptllwp1ocxou 2501 ri u-ypw11 op-yotvtXW\I U7tEpo!;EtOiwv 'tOU 7tEpt9wpto:xou 2551, 1 °' 10 °' 14 °' 15 ° xext 18 °' 9ot U7t0~<XAAO\l'tott OE ooxtµ'Yj OE 1tiEG7J 0.4 MPex (4 µ1tocp) TTocpix1pexq,oc; 6: :E71µotvG7J ( Ae11 u1totPXOW et6txic; 1tpoii1to8iaEtc;) Tiotpiit1pot<poc; 7: Amoup1ioc 211 551 211 559 211 560 2li 569 To EOW'tEptxo 'tOU. 7tEptf3AY\(.L<X'tOc; xext OA<X 'tot µip7J 7t0U ip- 211 5 70 X.OY'tott OE E1texq>i\ fLE ouaiEc; 7t0U ocvexq,ipov'text O'tO 7tEpt9wptotx6 211 510, lloc 6tex'TT}pouv,ext xocllocpiit. AE11 lloc Xfl7JOLfL07tOtet,ott r1cx 'ttc; ot\l'tAtEc;, f3otAf3i6Ec; xext IXAAEc; auaXEUE<;; At7tot\l'ttXO 7t0U µ1topEi voc aw6uotG'tat Emxivouvex fLE 'TT} fLE,ot<pEpOfLEY7J ouoloc. Tiapt~A7jfL<X'tot 1tpoop1,ofLE11ot 1tot 'TT} fLE'tot<popix u1pwv ,ou 211 5 71 7tEptllwptotxou 2501, I O fLEXPt 3 °' llot iEf!t,O\l'text fLEXPt ox1 1tEp1aoonpo ot1tci 95 o,ot Exot,6 'TT}<; xwp7Ji:txci'TT}'t1Xc; i:ouc; oE EYOEtX'ttx71 8EpfLoxpexoioc 15 ° K. TTEptf3A7lfL<X'tot 1tpoopt,oµevot ytot 't7j fLE't<X<popa llEpfLWV u6ot~ ,o6totAUfLIX'tW\I AMMONIUM NITRATE ,ou 1tEpt0wpto:xou 2501, 6° (ot), llot iEfLt,O\l'tott fLEXPL ox1 7tEptaao,Epo (X7t() 'tO 97 a,ot Exex,6 'tT\c; xwpTjnXO'tTJ'tlXc; ,ouc; xext 7J ot\lW't<X't7J llEpfLO­ xpexalex fLE'tlX ,o "['EfLtOfLex OE\/ 80t u1tEp~exl11Et ,ouc; 140°K. &e!;otfLEVEc; XP7J01fL07tOtoUfLEVEc; "['tot 't7j !J-E'tex<popix 8epµw11 211 u6ex,001otAuµai:wv AMMONIUM NITRATE ,:ou 7tEpt9wptex xou 2501, 6 ° {ot), OE\/ 9ot XPTJOt!J-07tOIOU\l'text y1ex 'tT) p.E,ex<popa ixUwv ouotwv xwpic; 1tpw,ot vex xexllexpta'touv 1tpoaEx,1xa ex1t6 572 07tOtlX07j7tO'tE xex,o:Aomex. 211 573 211 599 211 600 r , ( 0 i: • ) • -211 609 TTotpix1pexq,oc; I: EYtxa· 1t"exlato XPTJO'J\ E-.<XfLEVWY • optaµot XpriG7J 011totpcxxo:'tw ouolec; 'tT)c; Kex't1)1oplexc; 6.1 fL7tOpEi voc fLE'tex- 211 610 q>ipov'text ae G'tot9epic; ri ex1toaw0tpµoA01ouµevEc; oe!;ocµE11ic;: {ot) 7t0AU 'tO!;txic; oualEc; Otll<Xq>EpoµE11Ec; ovoµoto'ttXO( O'tO 2 ° Xotl 3°• (~) 7tOAu 'to!;txic; oualec; ,ex!;tVOfL7l!J-EVEc; fLE (ex) a'to 11 ° fLE­ XPt 24 °' 31 °' 41 °' 51 °' 55 ° xext 71 ° fLEXPt 88 °' fLE'tex<pE­ pOfLEYEc; OE U"['p1j Xot'tixa,ota7J, xex1 1texp6µ01ec; oualEc; 7j 6totAu­ p.ot'tot 1tpoc; Xot'tii,o:!;T) fLE (ex) otu'tw11 ,w11 et6wv· ("[') 'tO!;txic; 7j Emf3Aot~elc; ouolec; ,ex!;tvoµ7Jµi11Ec; µE (~) 7j (r) 'tOU 11 °, 24 °, 51 ° fLEXPL 55 °, 5 7 ° fLEXPt 68 ° XOtt 71 ° µi­ Xflt 88 °, fLE'texq,EpO!J-EYE<; OE u1p7I Xex't!XO't<XG7), Xott 1texpOfLOLEc; ouoiEc; 11 OtotAUfLOt'tot 1tpoc; xex,1X'tex!;71 u1to ((3) 71 ("[') ocu,wv 'tW\I EtOW\I" (6) To!;txic; ri emf3Aotf3eic; ouaiEc; oE ax6111j 7j xoxxouc; 't0t!;t­ VOfL7lf!EYEc; u1to (f3) i\ ("[') 'tou 12°, 14°, 17°, 19°,21 °,23°, 24 °' 51 ° fLEXPI 55 °' 5 7 ° f!EXPt 68 ° l((Xt 71 ° µixpt 88 ° xext 1totpoµmac; ouaiEc; oa ox61111 11 xoxxouc; 1tpoc; xex,ix'tex!;7J u1to ((3) 71 (r) exu'tW\I 'tW\I EtOW\I. :EHMEIO:EH: ftex 'tT) fLE'texcpopix xufL<X ouatwv ,ou 44 ° ((3), 60° (r) l((XI 63° (r) f3Ai1tE 7tEptllwpt<XXO 61 111. 211 611 Ilocp1x-ypot<poc; 2: Kot,otOXEU7I -211 619 IIeptf3A11fL<X'tot 1tpoopt,Of!E\lot ytex 'TT} fLE'tex<pcipix ouatwv 7tOU 211 620 CXYotypii<pO\l'tott ovoµexo'ttXIX CJ'tO 2 ° xext 3 ° 0ot Et\lott r:JXEOtot CJfLE\lot 1tex 1tlEaT) u1toA01tafLOU U/ 6-,.t fLtxpimp71 oc1to 1.5 MPoc (15 µ1texp) 1ttEa71 fLE'tP7J'11· TIEptf3A11fL<X'tlX 1tpoopt,OfLEVot 1 tot 't'J\ µnoccpopix 'tWY ouotwv 211 621 1tOU -otVot<pipoV'tott G'tO 1tEp18wp1otxo 211 610 ((3) llot Et\lott r:JXE 6totOfLE\lot ytot 7tLEG7J U7t0A0itoµou !2./ oxt fLtXpo'tEp'J\ ot7t0 1.0 MPot (10 fL7t<Xp) 7tLEG7J fLE'tp7J't11 TIEptf3A11fL<X'tex 1tou 1tpoopl,ov't1Xt 1tex 'TT} µnexcpopix 'tWY ou- 211 62 2 OIW\l 1t01) otllot<pipov'totl O'tO 7tEpt8weocxo 211 610 ( r) 9ot Elvext ax E6tota!,Livot r101 1tLEG7J fLE'tP'J\TIJ 2/ ox1 µ1xpo,Ep7J ot7t0 0.4 MPot ( 4 µ1totp) OE 1ttEG7j fLE'tP7JTIJ· • TIEptf3A7lfL<X'tot 1tpoopt~OfLE\IOt y1ot 'TT} fLE'tOL<popa OUOIW\I OE 211 623 ox61171 11 xcixxouc; 1tou exvot<pipov'tott a'to 1tap18wptexxci 211 610 (6) 8ex Et\lott r:JXEOtotOfLEYot aufLcp~vot fLE 'ttc; ot7text'tT)OEtc; 'tOU iElltxOU fLEpouc; 'tOU 7totpov'toc; Tiotpotp,iJµoc,oc;. 211 624 211 629 ·o:i..oc 'tot (X\IOLifLOt'tot 'tW\I 1tEptf3A7JfLOl'tW\I 7tOU 1tpoopl~ov.,ex1 211 630 ytot 'TT} fLE'totcpopi:i( 'tW\I OUOIW\I l'tOU ot\lotcpipov'text O'tO 1tep18w pt0!XO 211 610 ( ot) xott ((3) 8oc ~piaxov'tott 1tixvw ex1t6 't'J\ O'tlX8fL7j 'tOU uypou. Miaw 'tWV 'tOtXWfLO('tWV 6Ev 8ot 1tEp11ouv .OWA1j11Ec; 1j OWOEOEtc; OWA7I\IW\I XIX'tW ot7t0 't'J\11 Emq>aYEtot 'tOU uypou. TJX 1tEpt~A7l!J-<X'tex 8ot EiVotl OE 0ia71 \IOI XAEt\10\l'text EpfL7j 'ttxlX ~/ x011 'tot XAEtoifL<X'tot 8ot d11ex1 aE 8iG7J 11ot 1tp oG'tot'tEu011'tott fLE 1tWfLCX'tot 7tOU XAE16w11ouv. Tot exvoiyfLot't(X xoc8otptaµou 7tOU 1tpof3Ai1tO\l'tott O'tO 1tEp18wptexxo 211 132 0£\1 llot Em'tpi1to \l'tO!t E\l'tOu'totc; 1tot 1tep1f3A11(.L<X'tot 1tou 1tpoopi,ov'tott 1tot 't'J\ fLE 'totcpopix OtotAUfLIX'tW\I uopoXUot\ltXOU o!;foc; 'tOU 2 ° . Ilaptf3A1jfLO!'tot 1tpoopt,OfL£\l(X r10: 'TT} fLE'tot<pOpot 'tW\I ouatW\I 211 631 1tOU ot\lot<pEpOll'totl O'tO 7tEpt8wptotXO 211 610 {r) Xotl (6) fL7tO pEt \lot £l11ex1 E1tiG7Jc; 'tOU 'tu1tou XEVWOEWc; oc1to ,ov 1tu8fLE\lot. Tex 1tEptf3AY\fLOt'tot llot Et\lotl OE lliG7J \lot XAEt\lOW EPfLT)'ttXot ~/. E<DHMEPII: THI: KYBEPNHI:EQI: (TEYXOI: dEYTEPO) 1327 Av ,Ot 1tEpl~ATUJ.0t't0t ei110tl E<pOOL0taµi110t µe ~IXA~ioec; 0ta<p0t- 211 632 Ad0tc;, 80t 't01t08E'tOU\l'tOtl 1tplll Ot7t0 'tTJ ~OtA~ioOt oiaxoc; Ol0tpp71 yvuoµevoc; 71 OE ~OtA~ioOt 0ta<p0tAEi0tc; 80t EL\/Otl 'tE'tOlOt wan 1/0t Lx0tvonmEi 'tTJII 0tpµoot0t OtPX7l· TI0tpayp0t<poc; 4: 'E 1xpta71 ,unou 211 633 211 639 (dEV U1totpxouv ElOlXEc; 1tpoii1to8foEtc;) TI0tpayp0t<poc; 5: !1oxtµic; 211 640 211 649 TIEpl~AT)µ0t,0t 1tpoopt,oµE110t jlOt 'tTj µn0t<pop<X ,wv ouatwv 211 650 7t01) Otll0t<pipo11't0tl 0't0 1tept8wpl0tX0 211 610 (0t), (~) XOtl (r) 80t U7tO~<XAAOV't0tl 0'tTJV OtPXlXT) XOtl ,le; 7tepl00lXEc; ooxtµic; OE 7ttEOTJ µnpTj't'Tj 0Xl µtxpo,EpTJ Ot7t0 0.4 MP0t (4 µ1t0tp). flOt 1te­ pl~Ar1µ0t,0t 7t01) 1tpoopi,OV'tOtl jlOt 'tTJ µE,Ot<pop<X OUOlW\I 't0U 31 ° ( Ot ), Ol 7tepl00lXEc; ooxtµic; 80t yivoV'tOtl OE OlOtO't'TjµOt,Ot oxl µqotAU'tEp0t 'tW\I ,plW\I E'tW\I XOtl 80t 1tEplA0tµ~<X\IOU\I 'tTj 00 xLµT) uop0tUAlXT)c; mfoewc;. TIEpt~AT)µ0ti:0t 1tpoopt,oµE110t jlOt ,71 µE,Ot<popa i:wv ouatwv 211 651 7t0U OtVOt<ptpov'tOtl 0't0 1tEpt8wpl0tX0 211 610 (o) 80t 1)7t0~<XA AO\l't0tl 0'tTj\l OtPXlXT) XOtl 'tlc; 7tEpl00lXEc; ooxtµic; 0'tTJV 1t[EOT) ,ouc; unoAo1taµou onwc; opi,E,Otl aw 1tEpt8wpt0txci 211 123. TI0tpayp0t<poc; 6: L1jµ0tva71 211 652 211 659 (l1EV U7t<Xpxouv ElOlxic; 1tpoii1to8foEtc; TI0tpayp0t<poc; 7: Amoup1i0t 211 660 211 669 0 ~0t6µcic; 7tATjpWaEWc; 1tEpl~A71µai:wv 7t01) 1tpoopi,OV'tOtl 211 670 jlOt 'tTj fA.E't0tcpop<X 'tW\I OUOlW\I 7t01) OtVOt<ptpOV'tOtl 0't0 1tEpt6w pl0tX0 211 610 (0t), (~) XOtl (j) 60t EL\/Otl auµ<pwvoc; µE w 1tEpl 6wpl0tX0 211 172 (1) (o). TIEpl~AT)µOt,Ot 1tpoopt,oµE110t jlOt 'tTj µE,Ot<pop<X OUOlW\I 't0U 211 6 71 3 ° OEV 60t jEµi,ov'tOtl aE 1tEptaaoi:Epo 0t1to 1 xtAci OtV<X Aii:po X.WPTJ'tlX0'tTJ'tOtc;. Tot 1tEpl~AT)µ0t,0t 60t xAEivoV'tOtl EpµTj'tlX<X ~/ a,71 Ot<Xpxu0t 211 6 72 nic; µE,Otcpopac;. Tot XAEtaiµ0ti:0t 'tW\l 7tEpl~ATjµ<X,WV 7t0U 1tpoo pi,OV't0tl jlOt 'tTj µE,Otcpop<X OUOlW\I 7t01) Otll0tcpipov't0tl 0't0 1tEpl 6wpl0tX0 211 610 (0t) XOtl (~) 60t 1tpoa'tOt'tEUO\l'tOtl µE 1twµ0ti:0t lt0U XAElOW\101)\1, Qx1jµ0t,Ot OE!;0tµEvic; XOtl 0t1toauv0tpµ0AoyouµE11Ec; OE!;OtµE- 211 6 7 3 vie; EjXptµivEc; jlOt 'tTJ µE,Ot<pop<X 'CW\/ OUOlW\I 7t01) OtVOt<ptpOV'tOtl a,o 1tEpt6wpt0txci 211 610 oEv 60t xp71atµo1totou11,0tt jlOt i:71 µE,0tcpopdt ,pocpiµwv, Etowv x0t,0tv0tAwaEwc; XOtl ~wo,po cpwv. K0t,711opi0t 7: P0tOLEVEp1ic; ouaiEc; 211 674 211 699 211 700 II . I r . , . ( . ., t: • ) • -211 709 0tp0tjp0tcpoc; : EVlXOt • 7tl\Otl0lO XP'YJ0TJ uE.,0tµavwv • optaµot XpT)OTJ Luµcpw110t µE 't0 ltJXUO\I 1tpoyp0tµµ0t 't0U 1tEpt6wpl0tXOU 2 w. 710 2703. • LHMEIOLH: Yypic; T) anpdc; ouaiEc; µE x0tµ7lAci at6txci ~<Xpoc;, LSA (1), ,ou 1tEpt6wpt0txou 2703, 1ti110tx0tc; 5, axi:cic; 0t1to URANIUM HEXAFLUORIDE x0tl ouaiEc; 1tou u1tcixat 11,0tl aE <XtcpviOLOt 0tv<XcpAEl;7l, µ1topEi 110t µEi:0tcpipovi:0tl OE a,0t8a­ pic; T) OtltOOU110tpµoAoyouµa11Ec; oal;0tµavic;. Il0tpayp0tcpoc; 2: K0t'tOtOXEUT) 211 711 211 719 Ilapt~AT)µ0t,0t 1tpoopt~oµE110t )'lot 't'YJ µa,0tcpopa ,wv ouatwv 211 720 lt0U OtVot<pEpOV'tOtl 0't0 7tept6wplotX0 2703, Tii110tx0tc; 5, 1t0tp<X jp0t<poc; 11, 80t ai110tL tJXE0L0taµi110t jlOt 1tiaa7J µe,pTJ'tT) ,ouA<XXL a,ov 0.4 MP0t (4 µ1t0tp). 'Onou ot p0tOlEVEpjic; ouaiac; ~piaxovi:0tl OE Ol<XAua71 T) OtlW- 211 7 21 p71a71 OE ouaiEc; illwv x0t,711optwv XOtl ot mfoEtc; u1t0Ao1t ·aµou 7t01) 1tpo~AE1tO\l'tOtl jlOt 'tOt 1tepl~AT)µ0t,0t T) 'tlc; OE!;aµEvic; 1tou 1tpoopi,011,0tt 1t0t ,71 µE,Otcpop<X i:wv 'tEAEu,0tiwv 0tui:wv . OUOlW\I ELI/Ott µEjOtAU'tEpEc;, 60t E<p0tpµo,OV'tOtl m 'tEAEU'totiE<; 0(1) 'tEc; mfouc;. • TI0tp<Xjp0tcpoc; 3: Eio71 El;o1tALaµou TIEpl~AT)µOt,Ot 1ttoopt,oµE110t jlOt 'tTJ µE,Ot<pop<X uypwv pot- 211 7~0 OLEVEpjWII OUOLW\I -/ 60t axouv 'tOt OtVOijµOt,<X wuc; 7t<X\IW Ot7t0 't7j a,a6µ71 't0U uypou. K0tvi110tc; OWAT)VOt<; T) OUVOEOTJ OWAT)IIOt OE\/ 60t Ol0t7tEpv<X 'tOt 't0lxwµ0t,Ot 't0U 1tEpl~AT)µ0t,oc; X(X'tW Ot7t0 't7j O'tot6µTj 't0U uypou. TI0tpayp0tcpoc; 4: 'Eyxpl01J 'tU7t01) 211 731 211 739 dEl;0tµEvac; EjXptµavEc; jlOt 't'YJ µE,Ot<pOp<X p0tOlEVEpjWII OU- 211 7 40 atwv OEV 60t EjXpivov,Otl jlOt 'tTJ µE,0t<popdt ,pocpiµwv, atowv XOt'tOt\lOtAWOEWc;, ~wo,pocpwv, XOtMU\l'tlXWV T) <p0tpµaxwv, T) ouatwv 1tou XP1Jatµo1totouv,0tt jlOt 't'YJV 1t0tp0taXEUT) 0tu,wv i:wv 1tpoi:civ,wv. 211 741 211 749 TI0tp<Xyp0tcpoc; 5: i\oxtµic; TIEpl~AT)µ0t,0t 1tpoopt~ciµE110t jLOt 'tTJ µai:0tcpop<X i:wv ouatwv 211 1tou 0t110tcpipo11,0tl a,o 1tapt6wpt0txci 2703, Tii110tx0tc; 5, 1t0tp<X 10tcpoc; 11, 60t ooxtµot~O\l'tOtl OtPXlX<X XOtl 7tepl00lX<X OE ltLEO'YJ µE,pTJ'tT) 0.4 MP0t (4 µ1t0tp). K0t,ot 1t0tpaxxAlOTJ Otlt0 'tlc; OtltOtl'tT)Oelc; 't0U ltept6wpl0tXOU 211 211 151, Tj 7tepl00LXT) EOW'tEplXT) E7tl8eWp1JOTJ µitopai VOt Ot\l'tlXOt'tOtO't0t6ai Ot7t0 EAEjXO 't0U 7t<Xxouc; 't0U ,mxwµ0t,oc; µE 750 751 U1tEp1jxouc;, lt0U 60t jLIIE'tOtl xa6E i:pi0t E't'YJ, I10tpayp0tcpoc; 6: L1jµ0tva71 211 752 211 759 211 760 211 769 TI0tp<Xjp0t<poc; 7: Amoup1i0t 0 ~0t6µcic; ltA1jpwaawc; 0't'YJ 6Epµoxp0tai0t 0t110tcpopac; 'CW\/ 211 770 15 ° K OEV 60t u1tEp~0tivEL ,o 93 a,ix Ex0ti:ci ,71c; awoALXT)c; xw­ p7l,LX0'tT)'t0tc; ,ou 1tEpL~AT)µ0t,oc;. de;0tµEvic; 7t01) axow XPTJOLµo1t0l7j6d jlOt 'tTj µai:0tcpop<X pot- 211 771 0leVEpjWII OUOlW\I OE\/ 60t XPTJOLµoitOlOU\l'tOtl jlOt 't'YJ µn0tcpop<X ,pocpiµwv, ELOW\I XOt'tOtVOtAwaawc;, ~wo,pocpwv, XOtMU\l'tlXW\I 71 cp0tpµaxwv, T) OUOlW\I 7t01) XPTJOLµoitOlOU\l'tOtl jlOt 'tTj\l 1t0tp0t OXEUT) 0tu,wv ,wv npoi:ov,wv 211 772 K0t't7ljOpi0t 8: Ol;at6wnxic; ouaiEc; -211 799 211 800 TI0tp0Ljp0tcpoc; 1: felllXot' 7tAOtLOlO (XPT)OTJ oal;0tµEvwv)· optaµoi-211 809 XpT)OTj Ot 1t0tp0txdt,w ouaiac; ,11c; K0t'tT)yopi0tc; 8 µ1topai 110t µE,0tcpi- 211 810 poV'tOtl OE G't0t6Epac; 7l Ot7tOOUVOtpµoAoyouµEvec; OE!;0tµEvic;: (a) ouaiEc; 0t110tcpapoµE11Ec; 0110µ0ta,txdt a,o 6 °, 7 ° XOtl 24 ° XOtl ouaiac; 1t0tpciµotEc; µE axE[vac; ,ou 7 ° • (~) 1t0Au ol;ELOW'ttxic; ouaiEc; ,0tl;llloµ7Jµi11Ec; µE (a) ·mu 1 °, 2°, 3°, 10°, 11 °, 21 °, 26°, 27°, 32°,.33°, 36°, 37°, 64 °, 65 ° XOtl 66 °' µn0tcpEpoµEvEc; OE uypT) XOt'totO't0t01j, XOtl 1t0tpciµotEc; ouaiEc; T) Ol0tAUµ0t,0t 1tpoc; x0ti:ot,0tl;7l µE ( 0t) 0tui:wv 'tW\I ELOW\I, {r) Ol;El0W'tlXtc; T) EA0tcppot ol;ElOWnxac; ouaiEc; 't0tl;t110µ7Jµi 11Ec; µE (~) T) {r) 't0U 1 ° µaxpl 5 °, 8 ° µaxpl 11 °, 21 °, 26 °, 27°, 31 ° µiXPl 39°, 42° µixpl 45°, 51 ° µexpl 54° x0tl 61 ° fJ.EXPl 66 °, µE,0t<pEpoµEvEc; aE u1p1j X0t'tota't0tOT}, XOtl. 1t0t­ poµotEc; ouaiac; 7l 0lotAUfJ.Ot'tOt itpoc; XOt'tot't0tl;1j 1)7t0 (~) 7l ( r) EXEt\lW\I 'tW\I OUOlW\I' (6) Ol;atow,txac; T) EA0tcppot ol;Etow,txic; ouaiEc; aa axo1111 T) X0XXouc; 't0tl;l\10µ7JµEVE<; U7t0 (~) T) (1) 't0U 22 °, 23 °, 26 °, 27°, 31 °, 35°, 39°, 41 °, 45°, 52° XOtl 65° XOtl 1t0tpo 1328 E<DHMEPII: THI: KYBEPNHI:EQI: (TEYXOI: ~EYTEPO) µote.c; ouaie.c; ae. aKOVTJ iJ KoKKOU<; 1tpoc; K(X'tlX,ot;TJ u1t6 ((3) iJ ( 1) E.KE.L\IW\I 'tW\I e.16wv. LHMEIQ:EH: ftcx 'tTJ µe.wcpopii xuµcx Aota1tw6wv ot1tof31,.ij­ ,wv µoAiJ(36ou 7t0U 1te.ptEXOUV 0e.tLXO o!;u 'tOU 1 ° ((3) Xott OU­ OtW\I 'tOU 23 °' [3Ai1te. 'tO 1te.pt0wptotx6 81 111. 211 811 Ilcxpiiypcxcpoc; 2: Kot'tcxaxe.uij -211 819 Ile.pt[3Aijµcx,cx 1tpoopt,oµe.vcx ytcx 'tTJ µe.'totcpopii ouatwv cxvcx- 211 820 jpotcpoµe.vwv Cl'tO 6 ° Kott 24 ° 0cx eivott axe.Btcxaµivcx ,tot 7tLE.OTJ U7tOAO,taµou ~/ oxt µtxpo'tEpTJ (X7t0 2.1 MPcx (21 µ1tcxp) ae. 1tie.a7J µe.,pTJ'tT)• Ile.pt[3Aijµcx'tot 1tou 1tpoopi,ovtott 1tcx 'tTJ µe.,cx cpopcx [3pwµiou ,ou 24 ° 0cx eivcxt e.!;01tAtaµivcx µe. e.1tiv6ua7J µo Aii[36ou oxt AE7t'tO'tEPTJ (X7t() 5 XtA. 1tiixouc;; iJ tOO'tt(,l,Tj e.1tiv6ua7J, Ile.pt(3Aijµcx,ot 1tpoopt,oµe.vot ,tot 'tTJ µncxcpopii ouatwv 'tOU 7 ° (ex) 0cx e.ivott axe.6tcxaµivcx ,tot 1tiEOTJ U7tOAo,taµou ~/ oxt µtxpo,EpTJ (X7t() 1.0 MPcx (10 µ1tcxp) Xott 1te.ptf3A7)(,l,CX'tot jtot 'tTJ ~E'totcpopii OUOtW\I 'tOU 7 ° ((3) Kott (I) ,tot 7tLEOTJ U7tOAoytaµou .l/ oxt µtxpo,EpTJ (X7t() 0.4 MPcx (4 µ1totp). Ot CX7tott't7)0Etc; 'tOU Ilcxpcxp,ijµot'toc; B.16 ecx ixouv e.cpcxp­ µoriJ 1tcx uAtxii Kott Kot'totaKe.uiJ au1xoU7Jµivwv 1te.ptf3A7Jµii­ 'tWV 1tou 1tpoopi,ov,cxt 1 tcx 'tTJ µe.,cxcpopii HYDROGEN FLUORIDE Kott u6po6totAuµii'twv ,ou u6pocp0optxou o!;foc; 'tOU 6°, Ile.pt[3Aijµcx,cx 1tpoopt,6µe.vcx 1tcx 'tTJ µe.,cxcpopii ,wv ouatwv 211 821 7t0U ot\lCX(j)EpOV'tott O'tO 1te.pt8wptotXO 211 810 ((3) 0ot EL\lott C,XE 6totO(,l,E\lot ,tot 7tLEOTJ U7tOAo,taµou ~/ oxt µtKpo'tEpTJ (X7t() 1.0 MPcx (10 µ1tcxp) ae. 1tie.07J µe.'tpTJ'tT), '01tou TJ XP'YJOTJ otAouµtviou e.ivcxt cxvcx1Koticx 1 tcx 1te.ptf3Aij­ µcx'tot 1tou 1tpoop[,ov,cxt 1 tcx ,TJ µe.,cxcpopii vt'tptKou o!;ioc; "tOu 2° (ex), otU'tlX 'tot 1te.p1(31,.ijµot'tot 0cx e.ivcxt Kot'totaxe.ucxaµivcx ot1to 1XAouµiv10 Kot0otp6,7J,otc; 'tOUAIXXLO'tO 99, 5 a'tot e.xot'to, 01to'te. Kot't<X 1totpEKXAta7J ot1to ,tc; Otot'tii!;e.tc; 'tTJ<, 1totpot1tixvw 1totpcx1pii­ cpou, 'tO 1tixxoc; 'tOU ,01xwµcx,oc; XPELIX,E'totl \lot U1te.p[3cxive.1 'tot 15 xv., Ile.pt[3Aijµot,(X 1tpoop1,oµe.vcx ,tot 'tTJ µe.,cxcpopix 'tW\I OUOIW\I 211 822 7tOU (X\ICX(j)EpOV'totl O'tO mpt0wptotx6 211 810 (y) 0cx e.ivott ax e. Ototaµivcx ytcx 1tie.a7J U7tOAoytaµou ~/ oxt µtKpo'tEPTJ (X7tO 0.4 MPcx ( 4 µ1tcxp) ae. 1tie.a7J µe.'tpTJ't'YJ, Ile.p1[3)..ijµcx,cx 1tpoopt,oµe.vcx 1tot 'tTJ µe.'totcpopii µovox Awpo­ o;tKou o!;foc; (MONOCHLOROACETIC) 'tou 31 ° ((3) 0cx e.i­ vcxt e.!;01tA1aµivcx µe. e.1tia,pwa7J aµiiA,ou 7) tao,tµTj e.1tiv6ua7J OC\I 'tO UAtKO 'tOU 1te.ptf3Aijµot'toc; E.1t7Jpe.1X,E'tott (X7t() EKEL\10 'tO o!;u. Ile.pt(3Aijµcx,cx Kott 'tot e.i67J e.!;01tAtaµou 'touc; 1tou 1tpoopi,o­ V'tott 1tcx 'tTJ µe.,cxcpopix u6ot'tOOtotAuµix,wv u1te.po!;e.t6iou 'tOU uopo,ovou 0cx e.ivott KCX'tCXOKe.uotaµivcx cxrio otAouµivto Kot0otp6 't7j'totc; 'tOUAIXXtO'tO 99. 5 iJ ot7to Kot'tlXMTJAO x cx)..u[3cx 1tou 6e.v 1tpoK1XAe.t cx1toauv8e.07J 'tOU u1te.po!;e.t6iou 'tOU u6po16vou. Ave.!;ixp'tTJ'tot cx1t6 'ttc; 6tot'tii!;e.tc; ,7Jc; 1tpW't7Jc; 1totpcx1piicpou, 'tO 1tCXXO<; 'tOU 'totXWfl-CX'tO<; 6e.v XPEtlX,E'tott \lot E.L\lott µe.,otAU'te.po ot1t6 15 xv.. o'totV ,ex 1te.ptf3Aijµcx,cx e.ivcxt Xot'totaKe.ucxaµivcx ot1t6 xcx0cxp6 1XAouµiv10. Ile.pt[3Aijp.cx'tot 1tou 1tpoopi,ov,cxt 1tcx 'tTJ µe.,cxcpopix 'tWV ou- 211 823 a1wv ae. ax6117J iJ ae. xoxKouc;; 1tou cxvcxcpipov'tcxt a'to 1te.p18w ptocx6 211 810 (6) 0cx e.ivcxt axe.6tcxaµivcx auµcpwvcx µe. ,tc; CX7tott'tT)OEt,; 'tOU re.vtxou µipouc;; 'tOU 1totpov't0c;; Ilotp(Xp,iJµcx 'tOc;. 211 824 211 829 '0).cx ,ex cxvoi1µcx,cx ,wv 1te.ptf3A7Jµii,wv 1tou 1tpoopi,ov"tott 211 830 1tcx 'tTJ µncxcpopix oua1wv ,ou 6 °, 7 ° xcxt 2 4 ° 0cx (3piaxov"tott 7tiXIIW CX7t0 'tTj\l e.mcpixve.tot 'tOU u,pou. Mfoov 'tW\I 'tOLXWfllX'tW\I 'tOU 1te.p1[3Aijµot't0c; oe.v 0cx 1te.pvouv OWA7)VE.c; 7) auv6foe.tc; OWAij \lW\I KCX'tW (X7t() 'tTJV e.mcpcxve.tot 'tOU u,pou. Tex 1te.ptf3Aijµot't(X 0cx eivcx1 ae. 0i07J vex ue.ivov'tott e.pfJ.TJ'ttKIX ~/ Kott ,ex xAe.taiµcx,cx 0cx eivott ae 0i07J vot 1tpoa,cxnuov'tott µe 1twµot'tot 1tou KAe.t6wvouv. E1ti 1tAfov, ,ex cxvoiyµot'tot Kot0cxptaµou 1tou cxvcxcpipov'tott a,o 1te.p18wptotKO 211 132 6e.v 0cx e.m'tpi1tov'tott. Ile.pt[3Aijp.ot'tot 1tou 1tpoopi,ov'tott 1tot 'tTJ µe.'totcpopii 'tWV ou- 211 831 atW\I 7tOU otv<Xcpepov'totl O'tO 1te.pt8wpt<XKO 211 810 ((3), (j) Xott (6) µ1tope.i e.1ti07J.; v<X e.ivcxt ,ou 'tu1tou Ke.vwae.wc; cx1t6. 'tOV 1tu0 iiivcx. Tex e.!;cxp'tijµot'tot Ke.vwae.wc; cx1t6 'tOV 1tu8µivcx 'tWV 1te.p1 f3).7Jµdc'twv 1tou 1tpoopi,ov'tott 1 tot 'tTJ µe.,cxcpopix 'tWV ouatwv 7tOU ot\lCX(j)EpOV'totl O'tO 1te.pt8WptotKO 211 810 ((3) Xott (I) 0ot e.[­ \lott auµcpwvot (J,E 'ttc; ot7tCXL'tT)OEL,; 'tOU 1te.pt8wptotXOU 211 131. Av 'tot 1te.p1[3Aijµcx,<X 1tou 1tpoopi,ov,cx1 1tcx 'tTJ µe.'totcpopix 211 832 'tW\I OUOIWV 7tOU cxvcxcpipov,cxi O'tO 1te.p18wp1cxx6 211 810 ((3) e.ivcxt e.!;01tA1aµivcx µe. [3CXA[3[6e.c;; cxacpcxAe.i<Xc;;, 0cx 't01to8e.'te.i 'tott 1tptv ot1t0 'tTJ [3ix).[3i6(X 61ixpp7Jrvuoµe.voc; 6iaKoc;. H pu0µt0Tj 'tOU OtotppTJrvuoµe.vou 6iaKOU Kott 'tTJ<; [3CXA[3i6cxc; cxacpotAEiotc;; Sex e.[ \l(XI 'tE'tOL(X WO'tE \l(X tKCXV07totEL 'tTJV (Xp(J,OOUX otpX'YJ Ile.ptf3A7)(J,CX'tot 1tpoop1,6µe.vcx ,t(X 'tTJ [J.E't(X(j)Opoc 'tpto!;e.t6iou 211 833 ,ou 0e.iou ,ou 1 ° (<X) 0cx e.ivcxt 0e.pp.tKIX µovwµivcx Kott e..cpootcx aµiv(X µe. auaKe.uiJ 0e.pµixvae.wc; a'to i!;w µipoc;. Ile.p1(3A7)[J.(X't(X K(Xt O e.!;01tAtaµoc; e.!;u1t7JpE'tT)OEWc; CXU'tWV 7tOU 211 834 1tpoopi,OV'tott ,tot 'tTJ [J.E'totcpopix U7tOX Awptouxwv OtotAU(J.IX'tW\I ,ou 62 ° xcxt uocx,ootcxAuµix'twv u1te.po;e.16iou ,ou u6po1ovou 'tOU 62 ° 0cx e.iv<Xt axe.otcxaµivcx E'tOI WO'tE \lot e.µ1to6i,ouv 'tTJV e.iao6o !;avwv ouatwv, Ototppoij u,pou 7) 'tTJ 07Jµtoupyicx 07tOtota 07j1tO'tE u1te.pf30A1K71c; mfoe.w.; e.mxivouv7Jc; cpuae.wc; µfo(X a,o 1te.pif3A7J(J.CX, 211 835 211 839 (i\e.v u1tixpx ouv EtOtKic; 1tpoii1to8foe.tc;) Il(Xpix1pixq>0c; 5: i\oKtµic; 211 840 211 849 Ile.p1(3).71µot'tot 1tpoop1,oµe.vcx 1 tcx 'tTJ µe.,cxcpopdc ocvuopou 211 850 uopocp0optKOU o!;foc; 71 u6ot't00totAU[J.OC'tW\I u6pocp0optKOU o!;foc; 'tOU 6 ° 0ot U1tof3filoV'tott Cl'tTJV otpXtKTj Kott 1te.pt06tKE,; OOKt[J.E<; ae. 1tie.a71 µe.,p71TT) ,ouAocx1a'tOV 1. 0 MPcx ( 10 µ1tcxp) Kott e.Ke.ivcx 7t0U 1tpoopi,OV't(Xt jLCX 'tTJ µe.,cxcpopix OUOIWV 'tOU 7 ° 0cx U7t0 ~<XMOV't<Xt O'tTj\l cxpxtKTj Kott 'ttc; 1te.ptOOtKic; 6oxtµi,; ae. 1tie.a7J µt'tpTJ'tT) oxt µ1xpo'tEpTJ cx1to 0.4 MPcx (4 µ1t<Xp ). Ile.p1[3A71µot,(X 1tpoopt,oµe.vcx jtCX 'tTJ µe.,cxcpopix OUOIW\I 'tOU 6 ° Kott 7 ° e.m8e.wpouv,cx1 Koc0e. 3 E'tTJ ,tot CXV'tOX'YJ O'tTj\l o!;e.i­ OWOTJ, µe. XCX'tlXMTJACX opycxvcx (1t,x, u1te.p71xouc;). Tex UAIKOC xoc0e. KOMT}µivou 1te.p1(3).71µcx'toc; 1tou npoopi,e.,cxt 1 tcx 'tTJ µe.­ ,cxcpopoc HYDROGEN FLUORIDE Kott UOCX'tOOtotAU[J.OC'tWV uopocp0optKOU o!;foc; 'tOU 6 ° 0ot OOKl[J.OC,OV't<Xt µe. 'tTJ µiSooo 7tOU 1te.p1,pixcpov,ot1 O'tO Ilixpocp'tTJ(J.CX B. lo. Ile.p1(3).71µot'tot 1tpoop1,oµe.vcx ytot 'tTJ µe.,<Xcpopoc f3pwµiou 'tOU 211 851 24 ° 7} 'tW\I ouatW\l 7tOU CXV<Xcpipov'tott 71 'tW\I ouatwv 7tOU cxv<Xcpi povtotl a,o 1te.pt8wpt<XKO 211 810 ((3) xcxt (r) 0cx u1to(3ixUo V't(Xt O'tTj\l <Xpxtx71 K(Xt 'ttc; 1te.pt06tKE,; OOKtp.ic; ae. 1tie.a7J µe.,p7J't7l oxt µtKpo'tEpTJ (X7t() 0.4 MP(X (4 µ1tcxp). H ooxtp.71 uOp(XUAtKTjc; 1tie.07Jc; jt(X 1te.p1(3A71p.ot't<X 1t0U 1tpoopi,011'totl r1cx 'tTJ µe.,cxcpopix ,pt0!;e.16iou 'tou 0e.iou 'tou 1 ° (ex) 0ix e.1tcxvcx).cxµ[3ocve.'tcx1 K<i0e. ,pi<X E'tTJ, Ile.p1[3A71µ<X'tot Kot't(XOXf.U(XOfJ.EVCX (X7t() Kot0<Xpo (XAOU µivto Kott 1tpoopt,O(J,S.\lot 1tot 'tTJ (J.S.'tCX(j)OpOC \lt'tptKOU o!;foc; 'tOU 2 ° ( (X) K<XI UO<X'tOOtotAuµoc,wv 'tOU U1te.po!;e.t6iou 'tOU uopoyovou 'tOU 62 ° 6e.v XPEl<X,e.'totl \lot U1tof3ixUov,ix1 O'tTj\l cxpx1K71 Kott 'ttc; 1te.p106tKic; OOKtµic; ae. 1tie.a7J µe.,p7J't7l µe.,<XAU'tEPTJ ot7to 0.25 MP(X (2.5 µ1tcxp)~ H Kot't<XO'totOTJ 'tTjc; e.1te.v6uae.wc; 'tWV 1te.p1 [3A7Jf11X'twv 1tou 1tpoopi,ov'tott 1 tcx 'tTJ µe.,cxcpopdc [3pwµiou 'tOU 24 ° 0cx e.m0e.wpe.i'tcxt K<X0e. xpovo (X7t() e.tOtKO 'tTJ<; e.,Kpiae.wc; 't7jc; otpp.oOt(X,; cxpx71c;, 0 07tOLO<; 0ot e.m0e.wpe.i 'tO EOW'tEptXO 'tOU 1te.p1f3).71µcx,oc;. Iie.p1(3A7l(,l,(X't(X 1tpoop1,oµe.vcx ,tot 'tTJ µe.,cxcpopcx 'tW\I CJOOlW\I 211 852 7t0U (XV(Xcpipov'tlXI O'tO 1te.p10wptotKO 211 810 (6) 0ix U1to/31XA AO\l't<XI O'tTJV (XPXLK71 Kott 'ttc; 1te.p106tKac;; OOKtp.ic; O'tTJV 7tLS.OTJ . u1t0Ao11aµou <Xu,wv 61twc; xcx0opi,e.,<Xt a'to 1te.p18wpt<XK0 211 123. ... 21-1 l53 211 859 Ile.p1(3)..71µ(X't(X 1tpoop1,oµe.11(X 1tcx 'tTJ µe.,(Xcpopoc ixvuopou 211 860 uopoq,0optKOU o!;fo,; iJ UOCX'tOOtotAU[J.OC'tW\I 'tOU uopocp0optKOU o!;ioc; 'tOU 6 °, 71 [3pwµiou 'tOU 24 °, 00( cpipouv 1tipcxv cx1t6 'tot O'tOL)(ELCX 7tOU CXV<X(j)EpOV'totl!(l'tO 1te.p18wpt(XKO 2 } l 160 EVOe.t!;Tj 'tOU. E7tt'tpimoµe.vou <X\IW't<X'tOU xcx0cxpou cpop'tiou ae. KtAOC XCXI 'tT)V 1jµe.poµ7Jvicx (µ71110(, hoe;) ,7Jc; mo 1tpoacpot't7\c; e.awnp1Kijc; e.m8e.wp71ae.wc; ,ou 1te.p1[31,.71µot'toc;. <l>EK 104 E<l>HMEPIL I Hl.. KYBt.t"NH2.t.u2. ( I t.Y AUL de, I .. Pu) 1..,LY Ticxpac1pcxcpoc;; 7: Au-coup1i<i 211 861 211 869 TIEpt(3ATjfJ.CX'tCX ltOU 1tpoopi~OV'tCXt jtCX 'tTJ fJ.E'tCXlj)Opac -cpto~Et- 211 870 6iou -cou 0Eiou -cou 1 ° (ex) OEv 0cx 1Ep.i~ov-ccxt 1tacvw cxrco -co 88 O'tCX Excx-co 'tT}c;; XWPTJ'tLXO'tTJ'tCXc;; cxu-cwv· EXEivcx 1tou 1tpoopi~o v-ccxt jtCX 'tTJ fJ.E'tCXlj)Opac ~pwp.iou 'tOIJ 24 ° 0cx jEfJ.L~OV't(Xt oxt At yonpo CXltO "CO 88 O't(X EXCX'tO XCXt oxt ltEpLOOO'tEpo CXltO "CO 92 CJ't(X EXCX'tO 'tT}c;; XWPTJ'ttXO'tTJ'tCXc;; (XtJ'tWV TJ 2. 86 XtAIX cxvac Ai-cpo XWPTJ'ttXO'tT}'tcxc;;. TIEpt(3ATjfJ.CX'tCX 1tpoopt~OfJ.EVCX jtCX 'tTJ fJ.E'tCXlj)Op!X acvu6pou u6pocp0optxou o;foc;; TJ u6cx-co6tcxAup.ac-cwv u6poq>0optxou o;foc;; 'tOU 6 ° OEV 0cx jEp.i~OV'tCXt p.ixpt ltlXVW cxrcci 0.84 XtAIX cxvac Ai 't()O XWPT}'ttXO'tTJ'tCXc;;. • TIEpt(3ATjfJ.CX'tCX 1tpoopt~OfJ.EV(X jt<X 'tTJ [J-E'tCXlj)Opac OtJOtWV 'tOU 211 871 6 °' 7 °. xcxt 24 0cx XAELVOV'tCXt EP~TJ'tLXIX ~/ O'tTJ 6tacpxEtCX 'tT}c;; p.E-ccxcpopacc;;, -ccx OE x>..m1ip.cx-ccx 0cx 1tpoo-ccxnuov-ccxt p.E 1twp.cx-ccx ltOU XA.EtOWVOUV. 21 l 872 211 999 Ticxpacp'tTJp.CX B .1 (3 MATA::En.: nor A<l>OP01N AE'.::AMENOKONTEH­ NEP LHMEinLH: To p.ipoc;; 1 xcx0opi~Et -ctc;; 1tpoii1to8foEtc;; rcou e.xouv Eljl<Xpp.oiTJ 't(X OE;<Xp.EVOXOV'tETJVEp ltOU 1tpoopi~OV't<Xt jtCX 'tTJ fl.E'tcxcpopac ouotwv OAWV TWV KCX'tTJjOptwv. To p.ipoc;; II ltE­ ptEXEL Et6txic;; 1tpoii1to.8foEtc;; 1tou crup.1tA7Jpwvouv TJ -cporco 1totouv -ctc;; 1tpoii1to8foEtc;; -cou Mipouc;; I. 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H an1ix116,1j't1X 'tW\I 1tEpt~A7Jµix'twv nou npoopi~oV'tlXL 1tix 212 258 't'1} µE'tlX<pOp!X IXEp[wv 'tOU 1 ° µe.xpL 6 ° XIXL 'tOU 9 ° (Jix OOXLµIX ~E'tlXL OE 1tiE01J OXL µLxp6,Ep1J ix1t6 0.4 MPix (4 µnixp) XIXL OXL 1tixvw ix1t6 0.8 MPix (8 µnixp) 1tiE01J µE,p7J-c71. Tiixpixypixcpoc; 6: L71µixvo1j 212 259 E1ti 1tAfov 6ix cxvix1pixcpov'tlXL µE acppix1ioix 71 01tOL1Xo711to,E 212 260 ill7J Laoi:LµTj µE6o6o ,ix nixpixxix-cw ai:OLXEiix nixvw 0,11v 7tAIXXIX nou mpL1pixcpE,IXL a,:o 1tEpt8wpLixx6 212 160, 71 ixnw 0dixc; 1tlX\IW O'tlX "COlxwµixi:ix tou 1tEpL~A71µixi:oc; IXV 'tlX i:mxw µixi:IX El\llXL EVltJXUµe.vlX XIX'tlX ,p61tov wan VIX µ'1}\I IXOUVIX'tl~El TJ IX\l'tOXTJ 'tOU 1tEpL~A71µix-coc;: ( 1) LE OE!;IXµEvO-XOV"CETJVEp 1tOU 1tpoopi~OV"CIXL "(LIX "CTJ µE,IX­ cpopix µLixc; ouaiixc; µovo: 1J 1tA7lp7lc; ovoµixaiix i:ou cxpEpiou. 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(2) LE 6E!;ixµEvo-xovi:i7lvEp noAAwv axonwv: ot 1tA71pELc; ovoµixaiEc; i:wv ixapiwv 1LIX 'tTJ µEi:ixcpopa i:wv 07tOLW\I EXEL qxpt8Ei ,:o OE!;IXµEVO-XOV'tE.T)\IEP, IXXOAou8ouµa­ \lEc; ixno ai:oLXEilX i:ou Em1:pE1ti:ou ixvwi:ixi:ou cpopi:iou, aa XLAOL, jLIX xa6E E.\IIX IX1t0 IXU'tlX, (3) LE OE!;IXµEvO-XOV'tE.T)\IEp E!;o1tALaµe.vix µE (3ixA~ioac; ixacplXAEiixc; XIXL npoopL~oµEvix "(LIX ,TJ µei:ixcpopix ixEpiwv i:ou 7 ° (ix) XIXl 8 ° (ix) XIXL OE 6E!;ixµEvO-XOV"CETJVEp 1tOU 1tpoopi~OV'tlXL jLIX "CT) µE1:1Xcpopa IXEptWY 'tOU 7 ° ((3) XIXL 8 ° ((3): 7l 1tiEOTJ Amoup1icxc;. (4) LE oe!;ixµEvo-xovi:e.T)VEp e!;o1tALaµe.vix fLE 8EpfLLX7l µ6 VWOTJ 1J cppci(OTJ «0EpfLLXO( µOVWfLE.VO>> 8ix IXYIX"(p!X<pE'tlXL OE µ[ix IX1t0 'tLc; EltLOT)fLE<; 1 AwaaEc; 't7Jc; AD R. To 1tAIXLOlO 'tOU OE!;IXfLEYO-XOV'tE.'T)V•P 1tOAAIX1tAWV O'tOlX•lW\I 212 261 0ix El\llXL E!;01tALaµevo XOV'tlX O'tO 07JµEio 1tA7JpW0Ewc; fLE 1tAO(XIX ixvix1pixcpouoix: 't7JV 1tlEOT) 6oxtµ71c; 'tW\I o,:mxaiwv· 't7JV 1tiE01J AEL'toup1iixc; ,:wv 01:0LXEiwv nou npoopi~ovi:o:t 1LIX auµmEoµe.vix ixe.pLIX • i:ov cxpL0µ6 'tWV o,OLXEiwv· 'tT) OUVOAlXTj XWPTJ'tLXO'tTj'tlX 'tWV O'tOLi(ElW\I OE Aii:po:· 'tTjV 1tA71pT) ovoµixoicx i:ou cxapiou· XIXL O'tTj\l 1tEpt1t'tW07J uypo1tOL7JµEVW\I ixapiwv: 'to am'tprnoµEvo cxvwi:ixi:o cpopi:io xo:i:ix oi:oLxEio, oa XLAO(. Tiixpo:1pixcpoc; 7: Amoup1iix 212 262 2] 2 269 ~E!;IXµE\10-XO\l'tE.TJVEp XPTJOLµo1tOLO\lfLE\IO oa 6tixcpoprnxouc; 212 270 XPOVouc; "(LIX 1:'1} µa,ixcpopo: OLo:cpopwv u1po1tOL1jµe.vwv IXEpiwv 'tOU 3 ° µe.XPL 8 ° (oa!;IXfLE\10-XO\l"CE.TJVEp 1tOMIX1tAWV OX01tW\I) OEY µ1topEi VIX µEi:ixcpe.pEL ouoiEc; o:Uac; ix1t6 ExaivEc; nou ixvix jpciLcpov'tlXL OE µiix XIXL µov7J IX1t0 'tL<; 7t1Xp1XXIX'tW oµo:oac;: Oµcxoix 1: IXAO"(O\lwµe.voL uopoyovavSpixxEc; 'tOU 3 ° ( ix) XIXL 4 °(at). Oµcxoix 2: uopoyovixv0pixxac; "COU 3 ° ((3) XIXl 4 ° ((3), 1,3 BUTADIENE 'tou 3° (r) xcxL µi1µix'tix i:ou 1,3 BUTADIENE XIXL uopoyovav8pixxac; 'tOU 4° (r)· Oµa.oix 3: ixµµwviix i:ou 3 ° (AT)· DIMETHYL ETHER 'tou 3 ° ((3)· DIMETHYLAMINE, ETHYLAMINE, ME­ THYLAMINE XIXL TRIMETHYLAMINE 'tOU 3 ° (BT)· XIXL VINYL CHLORIDE i:ou 3 ° (1)· Oµa.oix 4: METHYL BROMIDE i:ou 3 ° (AT)· ETHYL CHLORIDE XIXl METHYL CHLORIDE 'tOU 3 ° (BT)· OµciLoix 5: Mi1µcxi:ix ETHYLENE OXIDE µa 0to!;Eioto i:ou a.v8pixxix xcxt ETHYLENE OXIDE µa a~w,:o i:ou 4 ° (CT)· Oµix6cx 6: ixJptlX 'tOU 7 ° (ix) XIXL µi1µix'tlX ixapiwv ,:ou 8 ° (at)· Oµixoat 7: IXL00(YLO, IXL0UAE.\ILO XIXL µa0avto 'tOU 7 ° ((3)· XIXL µiyµati:IX 1Xl80tviou µa µa8avto, E1tl0Tj<; ~'tlX\I 1tEpLEXOU\I 1tp01tOl­ \lLO Tj (3ou,:O(\ILO 'tOU 8 ° (~) • ~a!;atµEvo-xov,:eT)vEp ,:ix 01toi0t e.x.ouv 1Eµtoi:Ei µE ouoicx 1:7Jc; 212 2 71 oµcxoixc; 1 71 oµixoixc; 2 0ix IXOELOl~O\l"CIXL IX1t0 'tO uypo1tOL'T]µe.vo ixipLo 1tpLv cpopi:w0ouv fLE OLMTJ ouoiix nou ixv71xEL o,7JV i6tix oµixocx. ~.!;ixµEvO-XO\l'tE.'1}\IEP "CIX 01tOllX e.xouv "(EµLO"CEL fLE ou aiat µtcxc; IX7t0 ,Le; oµix6Ec; 3 µe.xpL 7 0ix IXOELIX~OV'tlXL 'tEAEiwc; IX1t0 ,:o uypo1tOLTjµe.vo cxe.pLo XIXL 0 IXOLO)(.EWJE"CIXL ixe.pixc; 1tpLv cpop'tw0ouv fLE IXMT) ouaiix 7tOU IX\ITjXEL O"C'T)V tOLIX oµo:oix. H 7tOMCX1tATj XPTJOTJ OE!;IXµEvO-XO\l'tE.Tj\lEP "(LIX 'tTJ fLE't1Xcpopo: 212 272 u1po1tOLTjµe.vwv IXEpiwv 'tTJ<; i6tixc; oµo:ocxc; 0ix Em'tpe.m,IXL ixv oAEc; Ol 1tpoiio1to8e.oEtc; nou 1tpo(3AE1tO\l"CIXL "(LIX ,ix ixiptix 1tpoc; fLE"C1Xcpop1X OE E.\IIX XIXL "CO IXU'tO OE!;1XµEVO-XO\l"CE.7J\IEP "CTJpTJSOuv. AU't'Tj TJ 7tOMIX7tATj X.PTJOTJ \/IX U7tOXEL'tlXL OE eyxpLOTJ IX1t0 E."(XpLOTJ IX7t0 qxptµe.vo EL6LXO. • • H 1tOMIX1tA71 XP'TIOTJ OE!;IXµEVO-XOV'tE.Tj\lEP "(llX 'tTJ µE't!Xcpopo: 212 273 IXEpiwv OLIXcpopwv oµo:owv 6ix E1tl'tpE1tE'tlXL IX\/ 'tO ayxp[vouv eyxpLµe.voL atotxoL ·o'tlX\I cpop,wµe.vix OE!;IXµEvO-XO\l'tETJVEp 71 XEYIX IXMIX IXXOl- 212 2 7 4 0ixp't1X 6E!;cxµEVO-XO\l'tETj\lEP 1t1Xpixoi6ov't1XL "(LIX µei:ixcpopo:, µovo 'tlX O"COLXEtlX 7tOU E.i(OU\I acpixpµorii XIX'tOl 'tO mpL0wpL1XXO 212 161 "(LIX ,:o cpop,wSe.v ixe.pLo 71 µoALc; axcpopi:w0e.v Sex eivixL oplX'tlX' OAIX 'tlX O'tOLXEllX 1t0U ixcpopouv IXMIX IXe.pLIX 0ix Et\llXL XIX Auµe.vcx. 'OAIX 'tlX O"COLi(EtlX OE!;ixµavo-XO\l"CE.'T)\IEP 1tOMIX1tAW\I O'tOL- 212 275 xEiwv 0ix ltEpLexouv E.\IIX XIXL ,:o IXU'tO ixe.pLO. L't1j\l mpi1t"CW07J . oa!;ixµEVO-XOV'tE.Tj\lEp 1tOMIX1tAW\I O'tOLXElW\I 1tOU 1tpoopi~E1:IXL 1LIX "CTJ µE-cixcpopcx u1po1totT)µe.vwv ixEpiwv Em(3Aix~wv "(LIX ,ix 0t\11X1t\lEUO'tLXOl opyixvix 71 ouvanixyoµEvwv xiv6uvo 61jATJ'tTJpLo: 0Ewc; l:!./, ~/ ,:ix O'tOLXEtlX 0ix 1Eµi~o\l'tlXL x.wpLa'tOl XIXL Six OLIX­ 'tTJpouv-ccxL ixnoµovwµe.vix fLE ocppix1Loµe.v11 (3ixA(3i6ix. Ot IX\IW'tlX'tOL E7tl'tpE7t0fLE\IOL ~ixSµoi 1tATJpWaEwc; OE XLAO / 212 2 7 6 Ahpo nou 1tpo(3Ae1to\l't1Xl a-ccx 1tEpLSwpLixxix 2219 (2), 2220 (2), (3) XIXL (4) XIXl 211 251 (2), (3) XIXl ( 4) 0cx 't1jpOU\l'tlXL. 0 (30t8µ6c; 1tA1jpwaawc; 'tW\I 1tEpt(3A7Jµix,:wv "CW\/ OE!;ixµavo- 212 277 XO\l'tE.'1}\IEP 1t0U El\llXL a!;o1tAtoµe.v1X µE (3ixA(3ioEc; IXO(j)IXAELIXc; XIXl 1tpoopi~OY"t1XL "(LIX "CTJ fLE'tlXcpopo: IXEpiwv 'tOU 7 ° XIXL 8 ° 0ix El\llXL 'tE.'tOLoc; WO'ta O'tTJV 0Epµoxpixaiix «EmcpuAixx71c;», O'tTJV onoiix TJ 7tlE01J E!;ix-cµioEwc; ai111XL io7J µE 'tTJV niEOTJ ixvoi1µix-coc; 'tWY (31XA~iowv, 0 oyxoc; 'tOU uypou .OE\/ U1tEp(3ixivu 'tO\I ami:prno µavo ~ix8µ6 1tA7JpwaEwc; i:ou 1tEpL(3A71µcxi:oc; o' ExaivTJ "CTJ 0Ep µoxpixoicx, OTJA, 95 o'tlX axixi:o O'tTJV m:pi1ti:wo1j EucpAaxi:wv IXE piwv XIXL 98 a-cix EXIX'to O"CTJV 1tEpi1t,WOTJ o:Uwv 1XEpiwv. E1ti 'tW\l 1tEpL~A7JµOl,W\I 'tW\I OE!;ixµEVO-XO\l'tE.Tj\lEp 1tOU 1tpo- 212 278 opi~ov'tlXL 1tix 'tTJ µEi:cxcpopo: o!;u16vou i:ou 7 ° (ix) 71 ixipix iJ µL1 µix'twv o!;u16vou µE ix~wi:o i:ou 8 ° (ix), oEv 0ix XP1Jotµo1t0Lou \l't1XL ouoiEc; 7tOU 1tapLEXOU\I ypo:aoo Tj AIXOL "(LIX \/IX E!;ixocp1XAL01:El 7J O'tE"(IX\IO"CTJ"CIX "CW\/ auvoe.oµwv ii YLIX "CTJ ouvi:71p7JOTJ 1:W\I XAEL atµcx-cwv. Xp7101J KIX,7J"(Opiix 3: EucpAEX"tlX uypix Tiatpaypixcpoc; 1: fEVLXIX' 1tAIXlOLO (XPTJ07J OE!;IXµEVO-XO\l'tE.'1}\IEp )• opLoµo[ 212 279 212 299 212 300 212 309 Ot 1tixpixxo:,:w ouoiEc; 't'TJ<; Kat,Tjyopiixc; 3 µ1topEi vix µa,ixcpe.- 212 310 pOV"CIXL OE OE!;IXµE\10-XO\l'tE.Tj\lEp: . (ix) ouoiEc; XIX'tlXXWPTJflEYEc; ovoµixo,Lxo: oi:o 12 °. (~) OUO[Ec; XIX'tlX'tlX"(µE.\IE<; µE (IX) 'tOU 11 °, 14 ° µe.xpL 2 3 °, 25 ° XIXl 26 ° XIXl 1t1Xpoµotac; ouoiEc; 1tpoc; XIX"CIX"CCX!;Tj U7t0 (ix) 1336 E<l>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: AEYTEPO) cxu,wv ,wv EtOwv, µE -i:71v E;cxipEOTj ,ou ISOPROPYL CHLO­ ROFORMATE ,ou 25 ° (ex)· (j) OUOLE<; X1X'tex'texjµEvEc; Umi (~) 'tOU 11 °, 14 ° µixpt 20°, 22 ° xexl 24 ° µiXPt 26 ° xext 1texpoµotEc; ouoiEc; 1tpoc; xex,hex;71 UltO (~) exu,wv 'tW\I EtOW\I' (o) ouoiEc; 'tOU l O µixpt 6 xext 31 ° µixpt 34 ° xext 1texpo­ µotEc; ouoiEc; 1tpoc; xex,ot,ex;71 o' exu,ot ,ex ElOTj, µE E;exipEOTj ,ou Vl'tpoµESexviou 'tOU 31 ° (1). • • 212 311 212 319 IlEpt~A7Jµex,ex 1tpoopt,oµEvex 1 tex ,71 µE,excpopot ouotwv ,ou 212 320 12 ° Sex Eivext oXEOtexoµivex ytex ltlEOTj UltOAOjLOµou !!!./ oxt µt xpo,EpTj exito 1.5 MPex ( 15 µ1texp) OE ltlEOTj µE,pTj'tlj, IlEpt~A7Jµex,ex 1tpoopt,oµEvex 1 tex ,71 µE,ex<popot ouotwv 1tou 212 3 21 cxvexqiiponext O'tO 7tEptSwptexxo 212 310 (~) Sex Eivext OXEOtex oµivex ytex 1tiEOTj UltOAOjLOµou !!!. / oxt µtxpo,EpTj exito 1. 0 MPex ( 10 µ1texp) oE 1tiEOTj µE,pTj,lJ, IlEpt~A7Jµex,ex 1tpoopt,oµEvex 1tex 'tTj µHex<popot ,wv oumwv 212 322 ltOU exvex<piponext O'tO 7tEptSwptexxo 212 310 (r) Sex El\lCXt oXE Otexoµivex ytex ltlEOTj UltOAoytoµou !!!. / oxt µtxpo'tEpTj exito O. 4 MPex ( 4 µ1texp) oE 1tiE071 µE,pT)'tlJ, IlEpt~A7Jµex,ex 1tpoopt,oµEvex 1tex ,71 µE,ex<popot ,wv ouotwv 212 323 ltOU exvexqiipov,ext O'tO 7tEptSwptexxo 212 310 (o) Sex Eivext oXE Otexoµivex ouµqiwvex µE ,tc; ex1text,7JOEtc; 'tOU 1Evtxou µipouc; ,ou 1texponoc; Ilexpexp,7Jµex,oc;. Ilexpotypexqioc; 3: Eio71 E;o1tAtoµou 212 324 212 329 '0).,ex ,ex exvoi1!J-CX,ex 1tEpt~A71µot,wv 1tou 1tpoopi,ov,ext 1tex 212 330 'tTj !J-E'tex<popot 'tWV OUOtW\I ltOU exvexcpiponext O'tO ltEEptSwptexxo 212 310 (ex) xext (~) Sex ~pioxov,ext 1totvw exito 'tTj o,otSµ71 ,ou uypou. Kot'tW exito 'tTj\l Eltt<potVELex 'tOU uypou OEV Sex 7tEpvouv CXltO ,ex 'tOtxwµex,ex OU'tE OWATjVWOEtc; OU'tE OU\IOEOELc; OWAlj VW\I, Tex 1tEpt~A7Jµex,ex Sex Eivext OE Sfo71 vex xAeivov,ext Epµ71 'ttXot ~/ xext ,ex XAEtoiµex,ex Sex Eivext OE Sfo71 vex 1tpoo,ex,Euov,ext µE 1twµex,ex 1tou xAEtOwvouv. IlEpt~A7Jµex,ex 1tpoopt,oµEvex 1tex ,71 µE,excpopot ,wv ouotwv 212 331 ltOU exvex<piponext O'tO 7tEptSwptexXO 212 310 (1) Xcxt (o) µ1to pei E1tio71c; vex Eivext ,ou ,uitou xEvwoEwc; exito ,ov 1tuSµivex. IlEpt~A7Jµex,ex 1tpoopt,oµEvex 1tex ,71 µE,excpopot ,wv ouotwv ltOU exvex<piponext O'tO 7tEptSwptexxo 212 310 (r) Sex Eivext OE SiOTj vex XAEivov,ext Epµ71,txot ~/. Av 1tEpt~A7Jµex,ex 1tpopt,oµEvex 1 tex ,71 µE,ex<popot ,wv ou- 212 332 OtW\I ltOU exvexcpipov'text O'tO 7tEptSwptexxo 212 310 (ex) xext (~) Tj 11 ° 7J 14 ° µixpt 20 ° 'tOU 7tEptSwptexxou 212 310 ( i) Eivext E;o1tAtoµivex µE ~exA~ioEc; exocpexAEiexc;, 1tptv exito ,71 ~exA~ioex Sex 't01tOSE'tEL'text EuSpexuo'tOc; oioxoc;. H 'texX'tOltOlTjOTj 'tOU EuSpexu O'tOU oioxou xext ,71c; ~exA~ioex~ exo<pexAEiexc; Bex Eivext 'tE'tOLex WO'tE . vex txexVOltOtEi 'tTj\l expµootex expxlJ• Av 1tEpL~A7Jµex,ex ltOU 1tpoo pi,ov,ext jtex 'tTj µE,ex<popot 'tW\I OUOtW\I ltOU exvexqiipoV'texL O'tO mptSwptexxo 212 310 (o) Eivext E;o:riAtoµivex· µE ~exA~ioEc; cxo<pCXAEiexc; 7J ouo,71µex exEptoµou, exu'tot Bex txexvoitotOUV 'ttc; exitext'tTjOELc; 'tW\I 7tEptSwptexxwv 212 13 3 µiXPt .212 13 5. IlEpt~A7Jµex,ex 1tpoopt,oµEvex ytex 'tTj µe,exqiopot 'tWV OUOtWV ltOU exvex<piponext O'tO 7tEptBcuptexXO 212 310 (0) ltOU EXOUV OT)µEio exvexcpAi;Ewc; 1tou OEv uitEp~exivEt ,ouc; 55 ° K xext Eivext E;o1tAtoµivex µE ouo,71µex exEptoµou 1tou OEV µ1topEi vex XAEto,Ei Sex ixouv <pAoyoitexyioex O'tO ouo,71µex exEptoµou. Ilexpot1pex<poc; 4: 'Eyxpto71 ,uitou 212 333 212 339 212 340 212 349 (~EV Uitotpxouv EtOtxic; 1tpoi.i1toBfoEtc;) Ilexpot1pexqioc; 5: ~oxtµic; IlEpt~A7Jµex,ex 1tpoopt,oµEvex 1 tex ,71 µE,ex<popix ,wv ouotwv 212 3 50 ltOU exvexqiiponext O'tO 7tEptBwptexxo 212 310 (ex),(~) 7J (r) Sex UltOXEtV'text O'tTj\l expxtXlj xext nc; 7tEptoOtxic; ooxtµic; OE ltlEOTj µE,pTj'tlj oxt µtxpo,EpTj exito 0.4 MPex (4 µ1texp). IlEpt~A7Jµex,ex 1tpoopt~oµEvex 1 tex ,71 µE,ex<popot ,wv ouotwv 212 351 ltOU exvexqiiponext O'tO 7tEptBwptexxo 212 310 (o) Sex UltOXEt \l'text O'tTj\l expxtXlj xext nc; 7tEptoOtxic; ooxtµic; O'tTjV 1tiEOTj UltO Aoytoµou exu,wv 61twc; xexSopi,E'text O'tO 7tEptBwptexxo 212 123 212 352 Ilexpix1pex<poc; 6: L7Jµexvo71 -212 359 212 360 212 369 Ilexpot1pexqioc; 7: Amoupyiex 0 ~exSµoc; 1tA71pwoEwc; 1tEpt~A71µot'tWV 1tpoopt,oµEVWV ytex 212 3 70 ,71 µE,ex<popot ,wv ouotwv 1tou exvexcpiponcxt o'tO iteptBwptexxo 212 310 (ex),(~) 7J (r) Sex Eivext ouµ<pwvoc; µE 'tO 7tEptSwptexxo 212 172 (1) (o). Tex itept~A7Jµex,ex Bex Eivext epµTj'ttXO( XAEtO'tO( ~/ xex,ot 'tTj OtotpxEtex ,ou ,ex~ELOtou. Tex XAEtoiµex,ex mpt~ATj µot,wv 1tpoopt,oµEvwv jtex 'tTj µe,excpopix 'tW\I OUOLWV ltOU exvex cpipoV'text o,o 1tEptBwptexxo 212 310 (ex) xext (~) Bex 1tpoo,ex 'tEuov,ext µE 1twµex,ex 1tou exocpexAi,ouv. ~E~exµEvO-XOV'tETjVEp ltOU ixouv EjXptSEi jlex 'tTj µnexqiopix 212 3 71 OUOtW\I 'tOU 6 °' 1 l O ' 12 ° xext 14 ° OEV Bex xp71otµo1totOUV'texL 1 tex 'tTj µe,ex<popot ,po<piµwv, EtOwv xex,exvexAwoEwc; 7J ,wo,po cpwv. IlEpt~A7Jµex,ex exito µiyµex exAouµtviou OEV Bex xp71otµo1totou- 212 3 72 v,ext 1tex 'tTj µE,ex<popot exxE,exAOEfio71c; ,ou 1 ° (ex) ex,oc; exv ,o 1tEpi~A71µex xp71otµo1totEhext exitoxAEto,txot 1t' exu,7J ,71 µE,ex <popot xext Tj IXXE'texAOEUOTj Eivext ex1texUexyµiv71 o~foc;. Aito 'tOV Ox,w~pto µixpt 'tOV Motpno, µirµex,ex uopoyo- 212 3 73 vexvSpotxwv ltOU exouv ltLEOTj e;ex,µioEwc; ltotVW exito 110 KPex (1.1 µ1texp) exUa ltOU OEV UltEp~exivEL 'tex 150 KPex (1.5 µ1texp) (ex1t0Au,71 1tiE071) o,ouc; 50° K, 61twc; optoµivex EAex<ppot exito o,ot1µex,ex jLex Ototo1texo71, µ1topEi vex 'µe,excpipo\l'texL OE 1tEpt~A 7J µex,ex 'tOU 'tUltOU ltOU 1tEptjpotcpE'text O'tO iteptScuptexXO 212 133 212 374 212 399 Kex,71yopiex 4.1: Eu<pAEX'tex O'tEpEot Kex,71yopiex 4.2: OuoiEc; ltOU UltOXElV'text OE cxtcpviotex xexuo71 Kex,711opiex 4.3: OuoiEc; 1tou exvexououv EucpAEx,ex exiptex oE Eltex<plj µE 'tO VEpO Ilexpot1pexqioc; 1: fEvtxot· itAexioto (XPlJOTj OE~exµEvo­ xov'tETjVEP' optoµoi Xp7JOT) 212 400 212 409 OuoiEc; ,ou 2 °, 8 ° xext 11 ° ,71c; Kix,711opiexc; 4.1 xext 1 °, 212 410 3 ° xext 8 ° ,71c; Kex,711opiexc; 4.2 xext ,o vhpto, xotUt0, µi1 µex,ex vex,piou xext xexUiou, ,ou 1 ° (ex), ouoiEc; ,ou 2 ° (E) xext ,ou 4 ° ,71c; Kex,711opiexc; 4.3 µ1topEi vex µE,excpipov,ext OE OE~ex­ µEvo-xov,i71vEp. I:HMEIQI:H: ftex 'tTj µE,ex<popot xuµex BEiou 'tOU 2 ° (ex), vex­ cpSCXAiv71 'tOU 11 ° (ex) xexL (~), Otexo,EUoµEvwv ltOAUO'tEptvwv 'tOU 12 ° 'tTj<; Kex,71yopiexc; 4.1, OUOLWV 'tOU 5 °' oxov71c; exito cpiA,pex uq,txexµivwv ,ou 6 ° (ex) xext·ouotwv ,ou 10 ° ,71c; Kex,71 yopiexc; 4.2 Xext XOXXWV µexjVTjOLOU, E7ttXptO!J-EVWV 'tOU 1 ° (o), cxvSpexxexo~Eo,iou ,ou 2° (ex) xext CALCIUM SILICIDE OE o~wAouc; 'tOU 2 ° (o) 'tTjc; Kex,71yopiexc; 4.3, ~AEltE iteptSw­ ptexxot 41 111 xext 42 111 xext 43 111. 212 411 Ilexpot1pexqioc; 2: Kex,exoxeu7J -212 419 IlEpt~A7Jµex,ex 1tpoopt,oµEvex ytex 'tTj µE,ex<popot AEUXOIJ xext 212 420 xhptvou cpwoqiopou ,ou 1tEptSwptexxou 2431, 1 ° 7J ouoiEc; ,ou 2° (E) xexL 'tOU 4° 'tOU 1tEptBwptexxou 2471 Bex Eivext oXEOtex oµivex ytex ltLEOTj UltOAOjLOµou oxt µtxpo,EpTj exito 1.0 MPex ( 10 µ1texp) OE 1tiEOTj µE,pTj'tlj, IlEpt~A7Jµex,ex 1tpoopt,oµEvex 1 tex ,71 µE,excpopot ouotwv ,ou 212 421 1tEptSwptexxou 2431, 3 °, Sex Eivext oXEOtexoµivex 1tex 1tiE071 UltOAOjtoµou oxt µtxpo'tEpTj ex1to 2 .1 MPex (21 µ1texp) OE 1tiEOTj µE,pTj'tlj Ilexpixypex<poc; 3: Eio71 E~OltAtoµou 212 422 212 429 Tex 1tEpt~A7Jµex,ex OE~exµEvo-xov,i71vEp 1tpoopt,oµEvex 1tex ,71 212 430 µE,ex<popot SEiou ,ou itEptBwptexxou 2401,2° (~), xext vexqiSex Aiv71c; 'tOU 1tEptSwptexxou 2401, 11 ° (r) Bex Eivext E~OltAtoµivex µE BEpµtx7J µoVWOTj exito uAtX(X ,ex 01toiex OEV Eivext EIJXOAex EIJ cpAEX'tex wo,E 71 BEpµoxpexoiex a 'tT)v E~w'tEptXlJ Em<potVEtex OEV 16. BAEltE 7tEpt9wptcxxo 212 127 (2). <DEK 104 t:wHMt:, 1L I HL "', ... EPN, ,Lt:!.l, 11 . , ;,UL u .. , 1 . , vJ µ1topEi \l(X (X\IEA0Et 7tCX\IW (X7t0 50 ° K XIX'tCX 't7I otcipxEtlX ,71i;; µE­ 'tCX<popcii;;. M1topEi 11cx Ei11cxt E;o1tAtoµ.i11cx fl-E ~cxA~ioEc; 1tou cx11oi 1ow cxu,oµ.cx,cx 1tpoi;; ,ex µiocx TJ 1tpoi;; ,cx i;w u1to ,7111 mi ' opcxOT} otcx<popcic; mfoEwi;; 20 KPcx (0.2 µ.1tcxp) µ.ixpt KPcx 30 0. 3 (,.l7t<Xp ). Ot ouoxEuic; XE\IWoEwc; cx Ei11cxt OE 0i01j 11cx 1tpoa,cx­ 'tEUO\l'tCXL (X7t0 o<pp<Xjl~Ofl-E\10 fl-E'tlXAALXO 1twµ.cx. Tex 7tEpt~ATJfl-lX'tCX 0E;cxµ.E110-xo11,i7111Ep 1tou 1tpoopi~wccxt 212 • 431 1 tex ,71 fl-E,cx<popci AEuxou xcxt xhpt11ou q,wa<popou ,ou 1tEptBw ptcxxou 2431, 1 °' 0cx XIXAU7t't0U\I 'ttt;; 7t1Xp1XXCX'tW 1tpoii1toBi GEti;;: (1) H OUOXEUTJ 8Epµ.ci110Ewc; 5EII 0cx uoxwpd µiacx O'tO awµcx 'tOU 7tEpt~ATJ(-llX'tOt;;, cxllci 0cx ELIIIXL 't01t08E't7lµi1171 i;w CX7t0 (XU'tO. 'AM.Er;; OWA7IIIWOEtc; 0cx Etaipxo\l't(XL O'tO 1tEpi~A7lfl-lX G'tO 7tCXIIW 't(-lTJ(-llX CXU'tOU' IXI/OLj(-llX'tlX 0cx u1tcipxou11 7tCXIIW IX7t0 ,o uc JAO'tEpo rnrt:pE1t'to OT}(-lEio 'tou <pwa<popou xcxt 0cx Ei11cxt oE 6i01j I/IX XAELIIOl/'tlXt 'tEAEiwc; (-LE 1twµcx't1X 7tOU IXO(j>IXAL~OUI/. (2) To 1tEpi~)..71µcx 0cx Ei11cxt E;o1tAtoµi110 (-LE ouo,71µcx (-lE'tpTJ­ aEwll jLIX 't7III E;cxxpi~WOTj 'tOU utj>ouc; 'tOU • <pwa<popou XIXt, !XII XP7lOl(-l01tOt7l8Ei 11Epo OCXII 1tpOa'tlX'tEU'ttXOt;; 7tCXpCXjWII, (-LE O't1X 0Ep0 OTj(-lELO (-lE'tpTjoEwc; 1tou 11cx OELXIIEt 'to cx•1w'tEpo Em'tpE1t'tO utJ>oc; 'tOU 11Epou. Tcx CXIIOij(-lCX'tCX XCXt Ot 01tic; (~tXA~ioEc;, cx1w1oi, cx118pw1to- 212 432 0upioEi;;, X.A7t.) O't(X 7tEpt~ATj(-lCX't(X OE;1X(-lEIIO-XOll'tE7IIIEP 7t0U 1tpoopi~O\l't(XL jtCX 't7I !,1,E'tlX<popci ouatwll ,:ou 7tEpt0wpt1XXOU 24 71 °, 1 ° (ex), 0cx Ei11cxt E;o1tAtoµi11cx (-LE O'tEjCXllci cxo<pCXAt~o µE11cx 7tW(-llX'tlX xcxt IXU'tCX ,ex 1tEpt~ATJ(-l1X'tlX 0cx Ei11cxt d;o1tAtaµi11cx fl-E 0Epµtx7] µ011wo71 xcxt xcx'tcxoxwcxaµi1171 cx1to uAtxci 1tou 5E11 <pAEjOll'tlXL EUXOAIX OE ,po1to WO'tE 71 0Epµoxpcxaicx O'tTjll E;W'tE ptx11 Em<pcillEtlX vex µ7111 µ1topd 11cx cx11iA8Et 1tci11w cx1to 50 ° K G'tTj otcipxEtlX 'tTjt;; µE,cx<popcic;. IlEpt~ATj(-llX'tlX 1tpoopt~oµ.E11cx 1tcx 't7I µE,cx<popci ouotw11 'tOu 212 433 7tEpt0wptCXX01J 2431,3 °, Tj 'tOU 7tEpt0wpt1XXOU 24 71,2 ° (E) OEII 0cx ii,ou11 CX11oi1µcxi:cx "I ou11ofoEti;; xci,:w ix1to 't7I O'tci8µ71 'tOU u,pou, cxxoµ71 XIXL (XII IXU'tCX 'tlX IXIIOLj(-llX'tCX Tj OUI/OEOEti;; ELIIIXL OE 0i01j \/IX XAEL\101/'tlXt. E1ti 7tAEOII, 'tlX CXIIOij(-lCX'tlX xcx0cxptoµou 1t:ou 1tpo~Ai1toll'tcxt O'tO 1tEpt8wptcxxo 212 132 OEII 0cx Em'tpi 1t:011,cxt. f 11oi1µcx'tcx o'to ci11w 't(-lTJ(-llX ,ou 1tEpt~ATJ(-lCX'tor;;, 1tEpt­ Acxµ~cx11oµE11w11 ,w11 E;cxp't Tj(-lCX'tWII 'tour;;, 0cx e.i11cxt OE 8ia71 vex 1t:poo'tCX'tEUO\l'tlXL cx1to 1twµcx. (AEII U7tcipxou11 EtOtxic; 7tpOii7to0iaEtc;) Ticxpci1pcx<poi;; 5: Aoxtµii;; 212 43L 212 43~ 212 44( 212 44< ; TIEpt~AT]fl-lX't(X 1tpoopt~oµE111X jL~ 'tTj µE't1X<popci: '212 450 0Eiou OE Auwµi11'7] XIX'tCXO'tlXOTj ,ou mpt0wptcxxou 2401 2 (~). 11cx<p81XAtll'Tjc; OE Auwµi1171 XIX'tCXO'tlXOTj 'tOU 7tEpt0wptcxxou 2401, 11 ° (,). AEUXOIJ TJ xhptvou <pwo<popou 'tOU 7tEpt0wptcxxou 2431,1 °. 11cx'tpiou, xcxlliou Tj µ.tjfl-CX'tWll lliX'tpiou TJ xcxlliou 'tOU 7tEpt 6wptcxxou 2471, 1 ° (cx). ouatw11 i:ou 1tEpt8wptcxxou 2471, 2° (E). ouotw11 'tou 7tEpt0wptcxxou 2 4 71, 4 ° 0cx u1to~cilloll't1Xt O't7III cxpxtxT] xcxt w;; 7tEptoOtxii;; 5oxtµic; GE 1tiEa71 µE,p7l'tTJ 'tOUACXXtO'tOII 0.4 MPcx (4 µ7tcip). IlEpt~ATJ(-llX't(X 1tpoopt~oµE111X jtlX 't7I µE'tlX<popci OUOLWII 'tOU 212 451 7tEpt0wptcxxou 2431, 3 ° 0cx U7tO~cilloll'tlXt O't7III cxpxtx71 XIXt ,tc; 7tEpto5txic; ooxtµic; µE Ujpo 7tOU bEII IXll'tt5pci µE ,7111 7tpoi;; !-l-;•cx<popci ou~icx, aE 7ttE07I 5oxtµT]c; 1.0 MPcx (10 µ7tcip) aE ?ttE07I µE'tp7l't7I, • Tex uAtxci xci0E 1tEpt~AT]µcx,:oi;; 7tou 1tpoopi~E't1XL 1 tcx 't7I µE­ 'tcx<popci ouatwv 'tou mpt0wptcxxou 2431, 3 °, 0cx 5oxtµci~o­ ll't1Xt µE 't7I µi0ooo 7tOU 7tEptjpCX<pE'tlXt O'tO TTcxpcip't71µcx 8.15. • IlEpt~ATJ!lCX'tcx 1tpoopt~oµE11cx 1 tcx 't7I µ.-rcx<popci 0e.iou (mpt- 212 452 Acxµ~cx11oµi11w11 'tWII cxv8iw11 'tOU 0Eiou) ,:ou 2 ° (cx), PHOS PHORUS SESQUISULPHIDE xcxt PHOSPHORUS PE­ ~TASULPHIDE 'tOU 8 °, cxxcx'tip1cxo"t71t;; TJ xcx8cxp71c; 11cxq,8cx At1171c; ,ou 11 ° (ex) xcxt (~) 'tOU 7tEpt0wptcxxou 2401 TJ <ppEoxo­ a~71oµi11ou ;uAciv0pcxxcx 'tou 7tEpt0wptcxxou 2431, 8 °, 0cx U7tO~CXAAOll't(Xt O't7III cxpxtxTj XIXt 'ttt;; 7tEpto5txii;; 5oxtµii;; 01:7111 1tiE071 U7tOA01toµou CXU'tWII o7twi;;,..xcx0opl~E't1Xt a-co 7tEpt0w­ ptcxxo 212 173. 212 453 212 459 TIEpt~ATJ(-llX'tlX 7tou 1tpoopi~ov-ccxt 1 tcx 't7I µE,cx<popci ouatw11 21 2 460 ,ou 7tEpt0wptcxxou 2431, 3 ° 0cx <pipow ml 7tAEOII 1:w11 a1:0t XEiw11 7tOU 7tpO~AE7tOll'tlXL (l'tO 7tEpt0wptcxxo 212 161 'ttt;; AE ;Etc;: «M7111 cxvoi1E'tE xcx,ci 'tTj BtcipxEtlX 'tou 1:cx;Et6lou. Y 7tOXEl fl-EIIO OE IXt<plltbLIX XIXUOTj», IlEpt~ATJ(-llX'tlX 7tOU 1tpoopi~oll't1XL 1tcx 't'Tj fl-E'tcx<popci ouatcilll ,ou mpt0wptcxxou 2471, 2° (E), 0cx qiipou11 mi 7tAio11 'tw11 o'totXEiw11 7tou 1tpo~AE7tOll'tlXL a,o 7tEpt0wptcxxo 212 161 ,ti;; ).i;Etc; «M7111 cx11oi1E'tE O't'Tj 5tcipxucx i:ou 'tlX~EL5iou. Avcx5ioEt EU<pAEX1:IX cxiptcx OE EltlX<pTj µE 'tO 11Epo». Tex O'tOLXELIX CXU'tCX Bex Etl/lXL OE E7tia71µ71 jAWOOIX 't'Tjc; xwpcxc; qxpiaEwc;, mio'Tjc; 5., cx11 CXU'tTJ T\ 1Awaacx 6E11 Eivcxt A11AtXT], fcxlltXT] Tj fEpµcx11tx71, O't'TjV AjjAtXT], fcxlltXT] TJ fEpµcx11tXT], Exi:oc; !XII 07tOtEOb7]7tO'tE auµ<pw11iEi;; 7t0U ixou11 auvcxqi0Ei µE­ ,cx;u 'tW\I E\IOtlX<pEpoµEIIW\I xwpwv jLIX 't'Tj µE'tlX<pOpci 7tpO~AE 7tOUI/ Otcx<popE'ttxci. 212 461 212 469 T cx 1tEpt~ATJ!llX't1X 6E;cxµE110-xo11,i7111Ep 7tou xcx8opi~o11't1XL 212 4 70 1 tcx 't7I µE'tcx<popci 0e.iou ,ou 7tEpt0wptcxxoti 2401, 2 °, 0cx 1Eµi- • ~01/'t(Xt µiXPt oxt 7t1Xp1X7tCX\IW 'tOU 98 O'tlX EXIX'tO 'tTj<; xwp71'ttXO 't7l't1Xc; IXU'tWII, 0 ).wxoc; TJ xhptvoc; <pwo<popoc; "tou mpt0wptcxxou 2431. 212 4 71 1 °' (XII xp71atµ07tOLEL'tlXL 11Epo (l(XI/ 0 1tpOO'tlX'tEU'ttXOc; 1tcxpci,w11. 0cx XIXA1J7t'tOV'tlXL OE ~ci0oc; oxt µtxpO'tEpo 'tWII 12 EX. 11Epou XIX't(X 'tO\I i po110 't7lc; 7tA7]pwaEwc;· 0 ~cx0µoi;; 1tA71pwaEwc; OE 0Epµoxpcxaicx 60°K bEII 0cx u1tEp~cxiv·u 'tO 98 a'tlX EXIX'tO. A11 XP71atµo1totEhcxt ci~w'to acx11 o 1tpoo,1X'tEU'ttxoc; 1tcxpci1w11. o ~cx0µoc; 7tA71pwaEwc; oE BEpµoxpcxaicx 60 ° K 6E11 Bex ump~cxi11Et 'tO 96 O'tlX EXIX'tO. 0 1X1toµi11w11 xwpoc; 0cx jEµi~E1:IXt µE IX~W1:0 xcx,:& 'tE'totO i:po1to WO'tE, cxxoµ71 XIXt µE'tCX 'tTjll 4>u;71 (5poatµcx ). T\ 7ttE07I OEII 7tE<p'tEL 7tO'tE x&,:w IX7t0 ,7111 IX'tµoaq,cxtptXTj 7tLEOTj, To 7tEpi~)..71µcx 0cx XAEtllE'tlXt Epµ71,txci wa'tE vcx µ7111 u7tcip;u otcxppoTJ, • •• ftcx .'tTj (-lE'tCX<pOpci OUOtWII 'tOU 7tEpt0wpt1XXOU 24 71, 1 ° (ex), 212 4 72 'tCX 7tW(l-CX'tlX 0cx XAEillOl/'t(Xt ouµ.<pwlllX (l-E 'tO 7tEpt0wptcxxo 212 432 xcxt 71 0Epµoxpcxaicx ,71c; E;wi:EptXT]c; Em<pci11Etcxc; 'tou 1tEpt ~A1l(l-CX'toc; OEII 0cx u1tEp~cxi11Et 'tOuc; 50 ° K. ftcx ,71 TRICHLOROSILANE (SILICOCHLORO- 212 473 FORM) ,ou 1tEpt8wptcxxou 24 71, 4 ° (cx) TJ 1tcx METHYLDI­ CHLOROSILANE TJ ETHYLDICHLOROSILANE i:ou 4° (~). 0 ~cx0µ.oc; 1tA71pwaEwc; bEII 0cx U7tEp~1XLIIEL 'tO 1.14 71 0. 95 11 0.93 XtAO IXIICX Ahpo xwp71'ttX0'1:7l'tCXc; IXll'tLO'totXIX, IX\/ 'tO ,i µtoµ.cx Ei11cxt xcx'tci µ.ci~Ot, TJ 85 O'tOt EXIX'tO cx11 'tO 1iµ.taµcx Ei11cxt XCX't' OjXO. T Ot 7tEpt~A11(l-CX'tOt 'tWII 6E;0tµ.E110-XOl/'tE7IVEp 7t0U 7tEptEixcx11 212 4 7 4 <pwo<popo 'tOU 7tEpt0wptcxxou 2431, 1 °' O'tCXI/ 1tcxpcx6ioo11't1Xt jllX (l-E'tCX<popci El'tE 0cx: jE(-l!~Oll'tCXt fl-E ci~W'tO' 0 IX7tOO'tOAEIXc; Oq>EiAEL 1/(X 7ttO't0 7totEi G'tO inpcx<po (l-E'tlX<popcic; O'tt 71 5E;cxµ.EIIT], (l-E'tCX 'tO XAEi­ otµ.o, Ei11cxt cxEpOO'tEjT]c;' El'tE 0cx jE(l-i~Oll'tlXt (-LE 11Epo µixpt oxt AtjO'tEpo IX7t0 96 O'tlX EXCX'tO X(Xl oxt 7tEptoaoi:Epo Ot7t0 98 01:IX EXCX'tO 'tTjc; xwp71'ttXO­ 'tT)'tCXc; cxu'tw11· µ.e.'tcx;u 'tT}c; 171c; Ox,w~piou xcxt 'tT)c; 31 Mcxp­ ,iou 'tO 11Epo CXU'tO 0cx 7tEptixe.t El/(X Tj 1tEptooo'tEp0t IXll'tttj>ux'ttxci Ot7tCXAACXj(l-EIICX IX7t0 o;EtOW'ttXT] EIIEpjEtlX, 7tOU bEII 1tpoxEt'tlXl I/IX 1t:pox1XAEOOUII Otll'tiop0to71 (l-E- 'tO <pwo<popo XCXL atpXE'tlX ouµ.1tu­ x11wµ.ivcx wo'tE 110t Efl-7to5iaou11 ,o 7tci1wµ.cx 'tou 11e.pou xcxi:& 1:71 µe.,cx<popci. AE;IX(l-EIIO-XOll'tET)IIEp• 7tOU 7tEptELXCXII <pWO<popo 'tOU 7tEpt0w­ ptCXXOU 2431, 1 °' 1tpi1tEt 1/(X 0EwpoU\l'tCXl, 00011 IX<popci ,7111 E<pcxpµ.ojTJ 'tWII OtCX'tlX~EWI/ 'tOU 7tEpt0wptcxxou 42 500 (1 ), CJ(XI/ «XEI/CX oE;cxµ.E110-XOll'tE7IIIEp, atxciBcxp'tcx». 0 ~cx6µ.oc; 1tA71pwoEwc; jtlX 7tEpt~A7l(l-CX't(X 7tOU 1tEptixou11 OU- 212 4 7 5 aiEc; 'tOU 7tEpt0wptCXXO\I 2431, 3 o, 117tEpt0wptCXXOU 24 71, 2 ° (E), OEII 0cx U1tEp~cxi11Et 'tO 90 O't(X EXOt'tO' xwpoc; 5 O't(X EXCX'tO 6oc 1t:cxpcxµ.i11Et XE11oc; jlCX CXO<pCXAEl(X O'tCXII 'tO UjpO ~ptOXE'tCXl OE (-lEOTj 6e.pµoxpcxoicx 50 ° K. Kcx'tci 't7I otcipXELIX 't7lc; (l-E'tCX<popcic;, Tj ouaicx 0cx ~pioXE't(Xl XCX'tW (X7tO O'tpwµ.cx cxop0t11ouc; CXEpiou, TJ 1338 E<DHMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 1tiE07j µe-rp71'ITj -rou 01toiou OEII 80t u1tep~0ti11Et -rix 50 KP0t (0.5 µ1t0tp). Tix 1tEpt~ATjµ0t-r0t ~Ot ELI/Ott Epj.1-7JW(IX xAEtaµi110t ~/ xixt TIX 1twµ0t-r0t x0t-r0t -ro 1tEpt8wpt0txo 212 433 80t 0ta<ptXAL,011-rm. 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( 4 1-t1t1Xp) OE 7tlEOTJ p.E'tPTJ'tTJ· IlEpt~A71µcx't1X 1tpoopt~oµEVIX jtlX 'tTJ p.E'tCXtpopix 'tWV OUOtWV 212 623 OE OXOVTJ 7I XOXXOU<; 7COU IXIICXq>EpOll'tCXt O'tO 7tEpt6wptCXXO 212 610 (6) Ila. E[VIXL oXE6Lcxoµevcx ouµcpwvlX p.E 'tt<; IX7tCXt'tT)OEL<; 'tOU '(ElltXOU µepouc; 'tOU 1tcxpo11'toc; Ticxpcxp't7lp.CX'toc;. 212 624 212 629 'OAcx 'tlX a.voi1µa.'tlX 1tEpt~A7Jµix,w11 rcou 1tpoopi~oll'tcxt 1 tcx 212 630 'tTJ µe.'ta.cpopix 'tWV ouotwv 1tou cxvcxcpepov'tcxL o'to 1t~pLllwp1cxx6 212 610 (ex) xixt (~) Ila. ~pioxov'ta.t rcixvw cx1to 'tTJV emcpixvucx 'tOU yrpou. Ka.viva.c; owA71vcxc; 71 ouv6EOTJ 6ev Ila. OtEPXE'tlXt µi aov 'tWV 'tOtXWp.ot'tWV 'tOU 1tEpL~A7lp.lX'tO<; Xot'tW IX7t0 'tTJV E7tt (j)CXVELIX 'tOU urpou. Tix 1tEpt~A71µcx't1X Ila. El\llXt OE 6fo7J VIX xAd 110\l'tlXt Epµ7Jnxcx ':!./ xixt 'tCX xAEtoiµa.'tlX Ila. Eivcxt oE 6i07J va. rcpo­ O'tlX'tEUOll'tlXL fJ.E rcwp.lX'tlX 7CO\J IXOCj>IXAi~ouv. TIX IXIIOljfJ.IX'tlX XIX llixptoµou 7t0U rcpo~AE7tOV'tlXt O'tO 7tEpt6wpL1XXO 212 132 6ev Ila. E7tt'tpE7tOV'tlXt oµwc; jLCX 1tEpt~A7lp.lX'tCX 7t0U rcpoopi~OV'tlXL jLIX 'tTJ p.E'tcxcpopix u6poxua.111xou o!;foc; 'tot> 2 °. IlEpL~A7lfJ.CX'tlX 7t0U 1tpoopi~OV'tCXL jllX 'tTJ fJ.E'tlXCj>Opix 'tWV OU- 212 631 OLWV 7t0U IXVIXq>EpOll'tlXL O'tO 7tEpt6wptCXXO 212 610 (j) XIXt (6) • 1,1-1tope.i E7tlOTJ<; VIX ElVIXt 'tOU 't1J7COU XEVWOEW<; CX7CO 'tOV 1tu6µe111X. Tix 1tEpL~A7lp.1X'tlX Ila. EiVIXt OE llfoTJ VIX XAELVOV'tlXt EPP.TJ'tLXIX ':!.j. Av 'tlX mpt~A7lp.1X't1X Eiva.t e!;o1tAtoµi11a. µa ~IXA~i6Ec; citocpa.- 212 632 A.e.ia.c;, Ila. 'to1tollE'tEl'tlXt 1tptv 1X1to 'tTJ ~IXA.~i6a. a.ocpa.AEia.c; EU llpa.uo'tOc; 6ioxoc;. H pullµtOT) 'tOU EullpotUO'tOU 6ioxou XIXt 'tTJ<; ~IXA.~i6a.c; IXOq>IXAEilXc; Ila. El\llXt 'tE'tOtlX WO'tE VIX LXot\107t0tEi 'tTJV 01pµo6La. a.px.71 . (AE11 U7totpxouv at6Lxic; 1tpoii1to6foEtc;) Ila.pix1pa.cpoc; 5: Aoxtµic; 212 633 212 639 212 640 212 649 Ile.pt~A7lp.1X't1X 1tpoop1~oµE11ot jtlX 't'J) f1-E't1Xcpopix 'tWV ouotwv 212 650 1tOU IXIIIXq>ipov'tlXL O'tO 7tEpt6wptotXO 212 610 (ix), (~) XIXt ( 1) . 6a. U1tO~illOV'tlXt O'tTj\l 1XpX,tX7I XIXt 'tt<; 7tEpmOtXE<; 6oxtµec; OE 1tlEOTJ p.E'tPTJ'tTJ OX,t µtxpo'tEpTJ IX1t0 0.4 MPa. (4 µ1totp). TIEpt~A7lp.1X'tlX 1tpoopt~oµEvot jtlX 'tTJ fl-E'tlXq>Opcx 'tWV OUOtWV 212 651 1tou ixva.cpipov'tlXl o'to 1tEpt6wptixxo 212 610 (6) Ila. u1to~ixA A.OV'tlXL O'tTJV ixpx1x71 XIXt 'ttc; 7tEpto6Lxic; 6ox1µic; O'tl)V 1tiE07I ' 'touc; \J7tOA.OjtOµou 01twc; xa.llopi~E'tlXt O'tO 7tEpt6wpt1XXO 212 123. (AEv \J1tcxpxou11 EtOI.XE<; rcpoiim,Gbotc,) Ilotpdt1pa.cpoc; 7: Amoup1 [a. 212 652 212 659 212 660 212 669 0 ~a.llµoc; 7tA.7JpwaEwc; mpt~ATJP.CX'tWV 7t0U 1tpoopi~OV't1Xt 212 670 jllX 'tTJ µE,!Xq>op& 'tWV OUOtWV 7CO\J IXll1Xq>ipo11't1Xt O'tO 7tEpt6w- • ptiXXO 212 610 (ix), (~) XIXL (r) Ila. ELIIIXt auµcpwva. µE 'tO 7tEpt 8wpt1XXO 212 172 (1) (6). Tiapt~ATJp.lX'tlX 1tpoopt~oµEVIX jtlX 'tTJ fJ.E't!Xq>opdt OUOLW\I 'tOU 212 6 71. 3 ° OE\/ 6a. 1Eµ[~OV'tCXt µi)(Pt 1tcxvw a.rco 1 XLAO a.vdt Ai'tpo xws 1 PlJ'tlXO'tTj'ta.c;. Tix mpt~A71µot't1X Ila. Eivixt EPP.lJ'ttXIX xAatO'tlX ':!./ xot'tcx 't'J) 212 672 6tixpxEtot 'tTJ<; p.E't!Xq>opcxc;. Tix XAEtoiµIX'tlX 'tWV 7tEpL~ATJp.CX'tWV 1t0U 1tpoop[~O\l'tlXL jllX 't1'J p.E'totq>opcx 'tWV OUOtWII 7t0\J IXVIXq>Ep0 1/'tlXt O'tO 1tEpt6wp1a.xo 212 610 (ix) xotL (~) Ila. 1tpoo't1X'tEUO ll't1Xt p.E IXOq>IXA.t~Op.EVot rcwp.ot'tlX, AE/;IXp.EVO-XOV'tETJVEp EjXptµavlX jLIX 'tTJ f.lE'tlXq>Opoe 'tWII OU- 212 673 otwv 1tou a.va.cpepoll't!Xt O'to 1tEpt6wpLa.xo 212 610 6e.v 6ot XPTJ 01µ01t0to1J11't1Xt jLIX 'tTJ µa'tixcpopdt 'tpocpiµwv, Etowv XIX'totVa.Aw oEwc; 7I ~WO'tpO(j)WV. Xp710TJ Ilotpcxjpotcpoc; 1: f Elltx&· 7CAIXioto (XP710TJ OE!;a.µEvo-xov'tETJIIEp) • optoµoi 212 674 212 699 212 700 212 709 Luµcpwva. (,LE 'tO 1axuov rcpoypa.µµot 'tO\J 7tEpt6wpt1XXOU 212 710 2703. }:;HMEIOtH: Movo t>jpic; 71 O'tEpEic; xixµ7JA71c;-Et6tx71c; EVEpjEtixc; ouoie.c;, LSA (1 ), 'tot> 1tEp16wp1a.xou 2703, rciva.xa.c; 5, 7tEpl.A.1Xfl-~IX\IOµavou, 1XoXE'tlX IX7t0 't'J) OtlX'tlX/;TJ O'tO 7tEpL0w­ pt1XXO 212 100, ruotXO\J 71 E/;IXV'tA7lµivou URANIUM HE­ XAFLUORIDE ':..../ µ1topEi va. fJ.E'tlXq>epov'tlXL OE 6E!;otµEvo­ xo11'te7J11Ep. 212 711 212 719 AE!;otp.E110-XOV'tETJ11Ep 7COU rcpoopi~OV'tlXt jtlX 't1'J f.lE'tlXq>Opix 212 7 2 0 'tW\I OUOLWV 7tOU IXIIIXq>EpOV'tlXt O'tOV IlilllXXIX 5, fJ.E E/;a.ipEOT) 'tOU URANIUM HEXAFLUORIDE, llE ELVIXt oXE6tixoµava. jlot 1tlEOTJ \J7tOA.OjtOµou 'tOUAIXX,lO'tO\I 0. 4 MPa. ( 4 µrca.p ). L'tTJV 7tE pi1t'tWOTJ OE!;a.µEvo-xov'tETJVEp 1tou 1tpoopi~ov't1Xt jtlX 'tTJ fJ.E'tlX <popcx URANIUM HEXAFLUORIDE, TJ 7tlEOTJ U7tOAOjtOµou 6a. Eivixt xot6op1oµiv7J O'tO 1 MPa. ( 1 µ1ta.p ). '0'tlXII TJ pot6LEVEp 1oc; ouoia. ~pioXE'tlXt OE OLCXAuµa. 71 IXtWPTJP.IX OE E7ttXl\lOUVE<; ou aia,; illwv Kix,11roptw11 XIXt O'tlXV Ot ot7CIXL't01Jf.lEIIE<; 7ttEOEl<; u1t0Ao11oµou 1tot 'tlX 6a!;a.µEvo-xo11'tETJVEp 1tou rcpoopi~oll'tott '(llX 'tTJ (.lE'tlXq>op& 'tWV 'tEAEUOtlW\I IXU'tWV ouotwv ElVott (J-EjlXAU 'tEpEc;, ea. Ecpa.pµo~ov,ott a.u,ic; 01 maaELc;. • 212 721 Ila.pix1pixcpoc; 3: E!;o1tAto!)'.oc; -212 729 Tix IX\IOljp.lX'tOt 'tWV OE/;IX(.lEIIO-XOV'tETJIIEp 7COU 1tpoopi~Oll't0tt 212 730 iliX 't7l p.E't!Xq>opcx pa.6LEVEpjWV ouotwv g / Ila. ~pioxOV'tOtt 1tCXIIW IX7t0 'tTJII E7ttq>CXIIEt0t 'tOU urpou XOtL XIXVEVIXt;; OWATJVIX<; 71 au110EOTJ owA71vw11 6Ev Oot OLEPX,E'tlXL µfoa. 1X1to 'tlX 'tOtX,W(.llX'tlX 'tOU 1tEpt~A7jp.1X'tO<; XCX'tW IX7t0 't7lV E7tl,:PIXVEIIX 'tOU t>jpou. • 212 731 212 739 AE!;a.µEvO-XOll'tETJIIEp EjXptµEVIX jllX 'tTJ p.E'totq>opcx p1X6LE11Ep- 212 7 40 rwv 0\JOtWV 6Ev 6a. EjxpivOll'tlXt jLIX 'tTJ (.lE'tlXq>Opoe 07tOLIXOOTj 1tO'tE ill71c; ouoia.c;. • 212 741 212 749 1:cx OE!;otµEvo-xo11'tETJIIEP llcx u1to~cxMoV't1Xt, 'tOUAotX,tO'tO µtcx 212 750 <F?P<X 'tlX 1tEV'tE x.povtcx: OE ooxtp-71 u6pa.uA.1x71c; 7ttEOEW<; fJ.E 1ttEOTJ 0.4 MPa. (1 µrccxp). AvE!;<Xp'tTJ't<X <X7t0 'tO 7tEpt6wptcxxo 212 150, TJ :tEptO~lXTJ EO~'tEptXj E7tt~EWp7l07l µ1tope.i .vex Ot\l'ttXCX't<XO'tCX6Et p.E 'tEO't \J7tEpTJXWV 'tO\J 7tlX)(OUt;; 'tOU 'tOtX,W(.l<X 'tO<; OtEVEpjouµEvo xot6E 610µ1ou x.pow.c. ( AEv \J1tcxpxou11 EtOtxec; 1tpoii1to6e~ELc;) Ticxp&:1pixcpo,; 7: AEt~ounicx· 212 751 212 759 212 760 212 769 0 ~~Oµoc; 1tA71pC:mw,; O'tTJ 6Epµoxp0ta~ a.vcxcpopcxc;c'tWII 212 770 ll/ r101 eµ1tAou-r1aµi110 URANIUM HEXAFLUORIDE f3Ai1te 1tept8wptotxo 2703, Tiivotxot 11. • ' 1340 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) 15 ° K OEV 0ex u1tEpf3exivEt ,o 93 a,ex Exex,o ,ric; auv0Atx71c; xw­ pTj,tXO't"Tj'tex,; ,ou 1tEptf3A71µex,oc;. L\el.;exµEvo-xov,ETjVEp 1tou ixouv XPTIClt(l07totTj0Ei ytex 'tTj (lE'texcpopci pexOtEnp,wv OUCltWV 6Ev 0ex XPTjC1tµo1totounext 1 tex 'tTj µE,excpopci ocUwv ouatwv Kex,riropiex 8: 01.;Etownxi,; OUCltE,; 212 771 212 799 212 800 TTexpoc,pexcpo,; 1: fevtxoc· 7tAexiatO (XPTJCITj OE/.;exµi::vo--212 809 xov,erivi::p )· optaµoi Xp71CITj Ot 1texpexxci,w ouaii::c; 't"Tjc; Koc,ri1opiexc; 8 µ1topEi voc µe,occpi- 212 810 pov,ext CIE 6e1.;exµEvo-xonerivep: (ex) ouaiE,; exvexcpepoµEvE,; OVO(lOCCl'ttXOC Cl'tO 6 °. 7 ° xext 2 4 °' xext OUCILE<; 1texpoµotEc; (lE EXElVE<; 'tOU 7 ° ' . ((3) 1t0Au o/.;EtOW,txi,; ouaiEc; xex,oc,ex1µevi::c; uito ( oc) ,ou 1 °, 2°, i 0 , 10°, 11 °, 21 °, 26°, 27°, 32°, 33°, 36°, 37°, 64 °, 65 ° Xext 66 °, (lE'tOCcpEpO(lEVEc; CIE U-ypTJ XOC'tOCCl'texCITj, XOCt 1texpoµotEc; OUCltE,; TJ OtOCAU(lOC'tO( 1tpo,; XOC'tOC'tOC/.;Tj UltO (oc) EXEt­ vwv 'tWV EtOWV' (r) ol.;etow,txi,; 71 1t0Au ol.;etow,txic; ouaie,; xex,oc,ex1µive,; U7t0 ((3) TJ (r) 'tOU 1 °' µexpt 5 °. 8 µiXPt 11 °. 21 °. 26 °' 27°, 31 ° µexpt 39°, 42° µexpt 45°, 51 °, µexpt 54° xoct 61 ° fLEXPt 66 °, µE,occpepoµevec; ae u-yp71 xoc,oca,ocari xm 1toc­ poµotec; ouaiec; 71 OtexAuµex,oc itpoc; xex,ci,ocl.;ri U7t0 ((3) 71 (r) txeivwv ,wv ·etowv· (o) ol.;EtOW'ttXEc; TJ EAexcppci o/.;EtOW'ttXE,; ouaie,; CIE CIXOVTj TJ CIE xoxxouc;, xex,ex,ex1µivec; uito ((3) 71 (r) ,ou 22 °, 23 °. 26 °, 27°, 31 °, 35°, 39°, 41 °, 45°, 52° )(O(t 65° )(O(t itocpo­ (J,OtE,; ouaie,; ae axovri 71 xoxxouc; itpoc; xoc,oc,ocl.;ri uito ((3) 71 ( 1) EXELVWV 'tWV EtOWV. I.HMEIQI.H: ftex 'tTj (lE'tOCcpopoc xuµex OUCltWV 'tOU 23 ° )(O(t 1.AUO<; (J,OAU(3oou ltOU itEptEXEt 0u"ixo ol.;u 'tOU 1 ° ((3), (3AE7tE 7tE­ pt0wptexxo 81 111. Ilexpci1 pexcpoc; 2: Kex,exaxi;u71: Ileptf3ATJ(J,ex,ex 1tpoopt,oµevoc 1 toc 'tTj µe,occpopoc ouatwv itou 212 820 exvex1pcicponext Cl'tO 6 ° xext 24 ° 8ex i::ivext axeotocaµevoc 1 tex 7tLECITj U7tOAo,tap.ou ox t µtxpo'tEpTj 0(7t0 2 .1 MPoc (21 µitocp) aE 1tiECITj µE,pTj't"Tj, Ileptf3A71µex,oc itou itpoopi,onext 1 toc ,ri µE ,cxcpopci f3pwµ[ou 'tOU 24 ° 0ex ixouv EltEVOUCITj µo)..uf36ou ltCl xouc; oxt Atyo,Epo exito 5 X,tA. 71 tCIO'tt(lTj EltEVOUCITj, Ileptf3A71µex,ex 7t0U 1tpoop[,ov,ext ytex 'tTj (lE'texcpoft°' 'tOU 7 ° (cx) 0cx ELVCXt CJXEOtlXCJµevex ytcx 7tLECITj U7tOAoytaµou -2/ oxt µt­ xpo,EpTj ex1to 1.0 MPex (10 µitcip) XCXt 7tEptf3ATJ(lCX'tCX yux 'tTj ~E,excpopci OUCltWV 'tOU 1 ° ((3) xext (r) -ytoc lttECITj U7tOAO,taµou ~/ oxt µtxpo,EpTj exito 0.4 MPex (4 µ1tocp). Ot exitext'tT}CIEt,; 'tOU .TTexpocp,Tj(lOC'tOc; B.16 0ex exouv Ecpocp­ µon Cl'tex UAtXtX xext 't"TjV xex,exaXEUTj XOMTj(lEVWV mptWTjµtX­ 'tWV 1tpoopt,oµevwv yux 'tTj fLE'tOCcpopoc HYDROGEN FLUO­ RIDE xext UOex'tOOtexMµex,oc u6pocp8optaµou ol.;foc; 'tOU 6 °. Ilep1(3)..71µex'tex itpoopt,oµEvex 1 toc 'tTj µi::,occpoptX ,wv ouatwv 212 821 7tOU CXVexcpEpOV'text Cl'tO 7tEpt0wptOCXO 212 810 ((3) 8oc EtVext CIXE 6texCl(lEVex ytex 7tLECITj U7tOAoytaµou }j / oxt µtxpo,EpTj exito 1.0 MPcx (10 µ1texp) CJE 1tiEC1Tj µE,pTj,Tj, "01tou Tj XP71CITj CXAouµtviou Eivext ocvex1xoc[ex 1 tex 1tEptf3A71 µcx,cx 1tpoopt,oµevcx 1 tex ,ri µe,excpopci vt,ptxou ol.;foc; wu 2 ° ( ex), exU'ttX ,ex 1tEptf3A71µex,ex 8ex xex,exaxeuci,ov,ext exito ex~ouµi­ VLO xex8expO'tTj'texc; oxt XCl'tW 'tOU 99. 5 Cl'tex EXex,o, 07tO'tE, xex,tX 1texpixXAtCITj 'tWV Otex,cil.;Ewv. 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Avel.;cip't"Tj'tex ex1to ,tc; otex,cil.;etc; 't"Tj<; 1tpw,ric; 1texpex1pcicpou, 'tO 1tcixo,; 'tOU ,mxwµexwc; OEV XPEttX~E'text vex Eivext fLE,exAu'tEpo ex1to 15 x,J., o,exv ,ex 1tEptf3A71µex,ex EtVext xex,exaxwocaµivex CX7t0 xex0expo CXAouµivt0. Ileptf3A7jµex,cx 1tpoopt,oµEvex 1 toc ,ri µE,excpopci ,wv ouatwv 212 823 <JE CIXOVTj 71 xoxxou,; ltOU exvexcpipov,ext Cl'tO 1tEpt0wptexxo 212 810 (6) 0ex EtVext CIXEOtexaµevex CIU(lcpWvex (lE 'ttc; ex1text'tTjCIEl<; 'COU 1EVtXOU µepouc; 'tOU 1texponoc; Ilocpexp,71µex,oc;. Ilexpci,pexcpoc; 3: Eiori E/.;01tAlCl(lOU 212 824 212 829 "0)..ex ,ex exvoi1µex,ex ,wv 1tEptf3ATj(ltX'tWv itou 1tpoopi~onext 212 830 ytex 'tTj µe,excpopci ouatwv ,ou 6 °, 7 ° xext 24 ° 8ex f3piaxonexi 1tor.vw ex1to 't"TjV Emcpor.vetex ,ou u-ypou. Kexvivex,; awA 71vexc; 71 auv 6EaTj CIWAT}Vex OEV 0ex 6tex1ti::pvdc ,ex w1xwµextex xci,w ex1to 'tTjV E7ttcp1XVEtex 'tOU u-ypou. 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OO)TI(l)ds '0 9 OOl. ,0130 i:iox1do9diod90 l\(1)1iprlo11019011090 If: :>0~30 i:iox1do9diod90 098 z 1 z ood9Mip ipdodil0l3TI b 1011 1011-arl9j1dood1£ l0ll0rlt,,.191d-au 6S8 ZIZ­ £S8 Z1Z !J.011l0rllf.1 :9 ,odilOdlipdlOIJ "£Z1 Z1Z 9xl01d(l)91d.1t 010 1l01.j1do9iox !,(l):itq :>001. i:iorlo110101to !J.o3JlL 11!J..1.o ,1rl1xo9 ,1x1g01d-aii ,11 1lOX t,,.x1Xd10 11!J.10 1l0ll\O'('(lp801£0 lOQ (9) 018 z 1 z QXl01C(l)Q1C31£ 010 llOl.l\OC ZS8 z I z -~dil011l0 ooJL ipdodil01-arl !J.i l01..l l011-arl9j1doodJL lOllOTilf,'(91d-a11 ·,01l0rlt,,.191d'3:it 00.1. 9x1d'3l(l)03 01 1.ot,,.d(l)o91:1t'3 l09 oo:it •t,,.XdlO l0199rldl0 11!J.1 (.)lLlO 011~rl1dx1'3 9x191-a QlLlO ,01.1-eipx 1l0l.]'3C (1)381:lti l08 0 tz 001 001rl(l)d9 ipdodil0l'3TI b l0111lO.l.llOjJdoodu ooJL l\(l)l.lpTI!J.'(91d'3JL ll(l)l !,(1)'30!.)911w-a ,!J.1 !J.olO.l.OlpllOX H lt£1 (Od3.lA3V lOXA3.l) l03lHNd38A)I lH.l lld31/\1H<D3 1342 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) jt!X 7t1Xp1XOElj(J-IX XIXtCXAu"CEc;, E7tttlX)(U\l'tEc;, µovoµEpTJ, OXA7jpu­ \lte.c;, 91;otpomxe.c; ouoiEc;, ouµcpwvix µE 00711iEc; tou xixtix­ oxEUIXO'tTJ 't'Tjc; p7jtlY7lc;, ({3) &tCXAUtlXCX, )(pWOttxe.c; ouoiEc;, XIXI CXMIX itpo"ioYtlX ltOU f30719ouv \/IX E7tttEU)(90U\I 01 IXltlXl'tOU(J-EYEc; IOIOt7jtEc;, OllX ltlX­ piXOElj(J-IX TJ IXU;1')0Tj t'Tjc; IX\ltlOtCXOEWc; Ot'Tj cpwttCX, (J-E 'tO\I opo cm OE\/ itpoxcx).ouv µi;iwo71 ot71v ixocp<XAEtOt XPTJOEwc; ,wv tot­ xwµ,i'twv 't'Tjc; OE;0tµEY7Jc;, 213 121 ITixpcxjp1Xcpoc; 3: &oµTj tW\I tOl)(W(J-CXtW\I t'Tjc; 0E;0tµEY7Jc; -213 129 To E;WtEptXO E7ttcp1XYEIIXXO otpwµix tW\I tOl)(W(J-CXtW\I t71c; 213 130 OE;IX(J-EYTjc; 1tpE1tEI \IIX IX\ltE)(El Otte; IXt(J-OOcp0ttptxe.c; E7tt0pCXOEl~ XIXl mi071c; OE OU\lt0(,17j E7t1Xcp1j (J-E t'Tj\l itpoc; µEt1Xcpopix ouoilX. T0t tOl)(W(J-IXtlX t71c; 0E;0tµEv7Jc; xixt ot ocppix1 toµe.vot 0tpµoi 213 131 1tpe.1tEl \/IX lXIX\/OltOLOU\I tti; IXltOtl'tTJOELc; (J-Tj)(IX\llXTj<; Ot\ltiot0to71c; 1tou ix110tcpe.povt1Xt O't'Tj\l itixpcx1pixcpo 4. To EOWtEpLXO EmcplltllEllXXO otpwµix tW\I tOl)(W(J-CXtW\I itpe.- 213 132· 7tEI \/IX Ot\ltE)(OUII Otte; OU\IE)(EL<; EmopixoEti; 1:71c; itpoc; (J-E't0tcpopcx ouoiixc;. To otpwµix IXU'tO 1tpi1tEl \/IX EL\IIXl XIX'tOtOXEUIXO(J-EVO 0t1to E11tcix.uµiv71 p711:ivix EACX)(tO,ou itcxxouc; 1 )(LA, 01 xp71otµo 1totouµEvEc; ivEc; OEV 1tpi1tEt vex µEtwvouv 1:71 )(Tj(J-lXTJ ixv1:io,0to71 tOU otpW(J-IX'tOc;. To EOWtEptXO µe.pouc; tOU o,pW(J-IX'tO<; itpe.mt vex Eivixt 1tAouo10 oE p711:inc; xix11tpE1tEt vex E)(Et EACX)(to,o itcxxoc; 0.2 )CIA. • Ot 1tpoii1to9ioetc; ltOU IXYIXcpipovtlXl AElttOµEpwc; •O'tlX ltEpL 9wpt1XXCX 213 140 (6) XIXl 213 142 (2) 1:71c; lt1Xp1Xjpcxcpou 4 1tpE1tEI VIX IXOt\/Olt017j90U\I Tix tEAE1wµiv0t tOt)(W(J-IX'tlX 1tpe.1tE1 vex XCXAu1t1:ouv ,ti; itpoii- 213 133 1to9e.oEtc; ltOU IXYIXcpEpOYtlXI AmtoµEpwc; O'tO ltEpt9wpt1XXO 213 140 (3) 't'Tj<; itixpix1pcxcpou 4. To EACX)(toto itcxxoc; ,ou to1xwµixwc; 9ix EtYIXt 213 134 3.5 )(LA- IX\I Tj )(Wp7jtlXO't7jtOt 1:71c; OE;0tµEY7Jc; OE\/ U1tEpf30ti \/Et tlX 3 µ3 , 5 .0 ~LA- Ill\/ 71 xwp71ttXO't'Tj'tlX 1:71c; OE;0tµEY1j<; EL\IO(t ltlX\IW a1to 3 µ . 213 135 ITO(pCXjp1Xcpoc; 4: Mi!looot ooxtµTjc; XO(t IXltO(l'tOU(J-EYE<; tOtO'tTj--213 139 uc; A1t1XttOU(J-EYEc; ooxtµe.c; XO(I 10tO't7j'tEc; jllX UAIXCX jtO( 'tO itpw,o- 213 140 tUltO 't'Tj<; OE;O((J-EYTJ<; ( 1) A TJ47l OElj(J-CX'tW\I T0t IXltotttouµEvlX OEi1µixtix 1tix 1:11 ooxtµTj itpimt oitou ELYIXL ou11ixto vex Aixµf3cx11onix1 ixito ,ix ,01xwµcx,O( , 71c; 0E;0tµEv1Ji;. rtcx to OX07t0 IXUtO, (J-ltOpEi \IIX )(p7j01(,10lt017j90UV XO(J-(J-CX'ttO( ltOU 1tpoe.pxov10tt IXltO 't'TjV XOt't~OXEUTJ tW\I IX\/Olj(J-IX'tW\I X.Alt. (2) ITooooto UIXA0{3cxµf30tx1X H OOXl(J-Tj 1tpe.1tEI \lilt jl\/EtlXI ouµcpwvlX (J-E ,ti; µE9ooouc; ltOU 1tpof3Ae.1tovt0t1 O't'Tjll ISO RECOMMENDATION R 11 72 1970. To itEptE)(O(J-EVO 1tlXAtou ,ou oEi1µix,oc; 1tpe.1t~1 vex Eivixt ltCX\IW IXltO 25 O'tlX EXIXtO XIXt AljO'tEpO IXltO 75 O'tlX EXIX'tO XIX'tlX f3itpoc;. (3) Bix9µoc; ltOAUf!Eptoµou (ix) Toixwµix (J-E i11Ec; ltOAUEOtEplX To XIXtlXAOtltO itEptE)(O(J-E\IO owpE11iou OE\I µitopEi vex EL\IIXt fLEj<XAUtEpo IXltO 2 O"tlX EXIXtO, u1toA011,oµE110 Eiti 1:11c; oAtXTj<; ltOOO't'Tj'tlXc; p711:111wv. H OOXl(J-Tj 9ix jlVE'tO(t ouµcpwvix (J-E XIXtlXA­ ATjA1J µi9ooo. ~/ ((3) Toixwµix (J-E mo;up71tivEc; To EXXUAtoµix 1XXEto1111c; OE\I µitopEi vex Ei110t1 (J-EjlXAutEpo a1to 2 otix EXIXto u1toA011,oµEvo mi 't'Tjc; oAtXTj<; 1tooot71,0(c; 't'Tj<; p71tiv11c;. H ooxtµTj 9ix jL\IEtlXt ouµcpw111X (J-E XIXtlXAA7jA7j µi!looo ~/ (4) Anox71 xixµtj,Ewc; XIXI E\ltlXOEW<; Ot µ71X0tYtxic; tOtO't'Tj"CE<; 1tpi1tEt vex 1tpoootopi,ov1:0tt: 1tix 1:0 1tEpif3A71µ0t, O't'Tj\l ix;o11tXTj XIXt itEptcpEpEtlXXTJ xixnu 6w071· • jtlX tlX IXXplX XIXI tlX tOl)(WfJ-IXtlX tW\I OtlXf!Eptoµcx,W\I itpoc; OltOIIXOT)ltOtE xixuu9u11071. A11 Ot xuptEc; XIX"CEU9u110Etc; 'TTjc; E\IIO)(UOEWc; OE\/ ouµitimouv fLE 't'Tjll Ot;OlltxTj XIX t ltEptcpEpEtlXXT) XIX"CEU9UV07j (jtlX lt1Xp1X OEtj(J-IX O't'Tj\l 1tEpi1t1:wo71 OtO(;ovtx7Jc; iteptEAi;Ewc;) 71 IXV'tO)(TJ 1tpE1tEt \IIX 1tpoootopton[ O'ttc; xuptEi; XIX'tEu9u110Etc; 1:71c; E\ltO)(U­ OEW<; XIXI \IIX UltOAOjtOtEi jllX ,ti; ix;ovtXTj XO(t ltEptµE,ptXTj xoc­ tEU9uvoEtc; Ecpixpµo,onocc; to 1tocp1XXIX'tW 'tUltO: E111:ix0Ewc; oT,1 - 2 oT,H SIN2oc (cxAcpix) oT,IX - 2 oT,H COS2oc (ixAcpix) Kcxµtj,Ewc; oF,1 = 2 oF,H SIN2ix (cxAcpcx) oF,IX = 2 oF,H COS20( (ixAcp1X) T = E\l'tCXOEW<; j = ltEpt(J-E'tptXTj ix = oc;o11tXTj H = EAtXOEtOTj<; F = xixµtj,Ewc; IX (<XAcpix) = 1tponµ71otOCXTJ 1wviix itEptEAi;ewc; H OC\ltO)(Tj E\ltlXOEW<; 1tpi1tEt \10( ooxtµO(O'tet ouµcpwvoc µe ,ti; fLE9ooouc; ltOU 1tpof3Ai ltO\l'tlXt O'tO e.npoccpo ISO /TC6 l / WG2/TG «&oxtµic; 1tA0to,txw11 ElltO)(U(J-EIIWY µE 1uocAi» No 4 tou <l>E{3pouixpiou 1971. H OC\l'tO)(Tj xixµtj,Ewc; 1tpE1tEt \IIX ooxtµix,EtlXt ouµcpwYO( µe 'tl<; µe9ooouc; ltOU 1tpof3AEltO\l'tO(l O't'Tj RECOMMENDATION ISO/TC61 No. 1540 tou A1tptAiou 1970. ITpoiiito9ioEtc; Ot ve.Ec; 0E;0tµEvic; 1tpe.1tet \IIX xocAuit,ouv ,ouc; itO(pO(xcxtw OUV'tEAEO'tE<; IXOcpO(AEioo; XOCtlX 1:71c; 9pixuoewc;: I:u11uAEo't'Tjc; ococpcx).e[ixc; 1tix 01:ix,txo cpop,io 7. 5 LU\ltEAEo't'Tjc; 0tocpocAeiixc; 1tlX ouvO(µtxo cpop,io 5 .5. Ot ,tµic; EltttOC)(U\IOEwc; ltOU 9ix Ecpocpµo,OV'tO(t O'tO\I UltOAO jlO(J-0 ,ou ouvixµtxou cpop,iou El\lO(t ot itO(pO(XCXtw: 2 G Ot7jll xoc,eu9uvo71 itopEiixc;· 1 G OE op9ic; rwv[ec; itpoc; XIX'tEU0u11071 itopeiixc;· 1 G xcx9e,oc itpoc; 'tO( ltCXVW' XOCl 2 G xix9E'tlX itpoc; 'tlX XCX'tW. EitElOTJ 'tlX xixpocx1:71ptottXCX cpuAAou MO)(U(J-E\IOU ltAIXO'ttXOU µitopei \/IX ltOtXiAOUV ouµcpw111X µa 'tO OO(J-Tj 'tOU, EACX)(tO'tEc; 'tt­ µic; oa11 1tpof3Ai1to111:ixt 1tix xixµtj,71 xixt e.11t0(07l ocAAix 1toc cpop­ tiix: . A = a6 T oitou 1:0 6 T e[11oct 71 IX\ltO)(TJ av,cxoawc; O't7J 9pO(uo71 • B = E26F oitou 1:0 6F Eivoct 71 ocvtO)(TJ xixµtjiawc; 01:71 9pocuo11· OltOU E Ell/Ott 'tO ltCX;(O<; 'tOU tOl)(WfLO(tOc;. Ot EACX)(tOtEi; ttµic; jtOC ttc; ouvcxµati; A XO(t B EL\IO(t: ftlX .xcxµtj,71: Xwp71ttXOt7ltO( oe;ocµEIITj<; ;;;;,, 3 µ 3 mpt(J-EtptXTj XOCtEu9uvo11 B = 600 DO(N oc;o11tXTj XIXtEu9uvo71 B = 300 DixN Xwp1')ttXO't'TjtOC OE;ocµa1171c; > 3 µ3 ltEptµatptXTj XIXtEu9u11071 B = 600 DixN ix;o11tXTj XIXtEu9u11011 B = 600 DixN ftlX EVtlX07j: ltEptµEtptXTj XIXtEu9u11071 A = 100 DixN/MM ix;ovtXTj XIXtEu9u11071 A = 70 DixN/MM . To OtOl)(ElO E Ot1j\l xcxµtj,11 µatpaitixt otouc; -40 ° K XIXt otouc; +60° K. Ot ouo ttµic; OEV µitopEi 110t otoccpipow xixtcx ltEptooonpo IXltO 30 OtlX EXIXtO IXltO t71v tl(J-Tj ltOU E)(Et amtau'­ x9Ei otouc; 20°K. I:uµitcptcpopcx UAlXOU tOt)(W(J-IXtOc; Ot7j OtCXpXEIIX ooxtµTjc; E\ltcxoawc; ltOU OtlXpXEi ltEptoootepo IXltO 1000 wpec;. G T H e.nixo11 oox1µ71c; eivixt 7 " ,;) L't'Tj otixpxetix 't'Tjc; oox1µ71c; o ouvteAEOt'Tjc; K oev µitopEi 11ix Ei11ix1 µe1CXAutepoc; ixito 1. 6. 1/ H µt8o6o,; itou 1tpo~AE1tE'tO(t o-ro 1tpchu1to DIN 16945 1:ou lowiou 1969, 1t0tp. 6.4.3 8Ewpai-t0tt xet,illT)ATJ, 1/ H µi8ollo,; 1tou 1tpo~AE1tE,0tt o-ro 1tpfrtu1to DIN 16945 louviou 1969, 1t0tp. 6.4.2 xpivEtOtt xettillT)AT), EG>HMEPII THI KYBEPNHIEQI (TEYXOI .dEYTEPO) 1343 i;O = E1ttµTjxu11071 cpop'twµivou u1to6fryµix'toc; 0,7111 IXPX'Tl 'tlJ<; 00Xlf1Tj<;, dOOO = E1ttf1TjXUIIOlJ cpop'twµivou u1tood1µix't0c; o,;o ,EAoc; 'tTjt; 00Xlf1Tj<;, (5) I;uµ1tEplcpop<i 1tpooxpou0Ewc; (ix) <l>uo71 'tlj<; ooxtµTjc; H ouµ1tEptcpop6t 1tpooxpou0Ewc; 1tpoo6topi~E't1Xt 1t6t11w OE- • 0EL"(f11X cpuUou ltOU IX\l'ttO'tOIXEL O'tO XIX"CIXOXEUIXO'ttXO UAIXO 7tOU XPlJOlf101tOtTjSlJXE "(llX 'tlJII XIX'tlXOXEUTj 'tlJ<; OE~1Xf1E11Tj<;, H ooxtµTj "(lVE'tlXt pi1t'tOV'tlX<; OtOEpivto f36tpoc; 5 XtAW\I ltOt\lW O'tlJII Emq>OtllEllX 'tOU cpuUou ltOU IX\l'tLO'totXEL O'tljll E~W'tEpLXTj rnLcpet VELIX 'tTj<; OE;1Xf1E11Tjt;' • (f3) I;uvEp"(IX TIX OUVEp"(IX IXltO'tEAOU\l'tlXl IXltO OtOEpavLO f36tpoc; 5 XLAWII, flLIX OUOXEUTj XIXSOfilJ"(TjOEW<; 'tOU f30tpouc; IXU'tOU XIXt f1LIX f30tOlj 't01tOSE't'TjOEWc; 'tOU 0El"(f11X'tOt;. fEVtXO 6L<X"(p1Xf1f11X 'tW\I ouvep­ jWII oivE'tlXt O'tljll ELXOVIX 1. 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EmcpCtVEtotXTJ exvi:ia1:oca11 (R 100) - (11011wi:tXTJ cxvi:iai:oca71) OE OHMS, 7JAEX1:po6tot OCjWjOU µ1tojtcic:; auµcpwvoc [LE 't11V Et )(()VO( 3 i:11c;; RECOMMENDATION !EC 167 1:ou 1964, µE i:pouµev7J O't1111 )(OCVO\ltlCT) ot'tµoacpOCLpot 23/50 OUfL(f>WIIOC fLE 1:11 RECOMMENDATION ISO R291, 1tocp&.1poccpoc;; 3.1 i:ou 1963. 2. H ocv-.iai:oca11 XEIIWOEW<; 1tpoc;; 1:11 i11 OE OHMS Eivoct 11 <JXEOTJ µE'toc!;u 'TTjc;; ciµEa11c;; 'tOtOEWc;; µEi:pouµE1111c;; µEi:ot!;u 11AE­ x-.po6iou 1teprypexcpoµEvou 1totpCtxci1:w aE mcxcp71 µE i:7111 emcpci 1/Etot 1:11c:; 6E!;otµE117Jc;; ,:OU ox71µoc-.<ic:; )(O(t 1:0 OUVOAtXO 7JAEX'tplXO peuµo:. H 1tpOE'totµcxaicx 'tWII U7t00Etjµ&,:wv EtVOCl 7l iotcx 01twc:; ai:7111 1texpciypcxcpo I. To 11AEXi:p66to Etllott 6laxoc;; µE Emcpci11Et1X 20 EX2 XCXt 6t1xµei:po 50 XtA. 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Kp) ftix)..[ f: I,uv6EOTJ Xllt'tOt fLOt~ot: Atol;Eioto 'tOU 1tupt'tlOU (SI 0) AAouµivix (AL20:J 'Aof1e.o,:oc; (CA 0) Mot')'V'T]Olllt (MG 0) Boptxo o~u (8 2 0 3) I.ioTJpoc; (FEp 3) Ol;Eioto ,:ou vot,:piou (Not00) O~e.ioto ~OU xilliou (K20) 52 - 55% 14 - 15.5% 16.5 - 18% 4 - 5.5% 6.5 - 21% 0.2 - 0.6% < 1 O'tot EXot'tO < 1 O'tot EXot'tO 63.5 - 65% 4 - 4.5% 14 - 14.5% 2,5 - 3% 5 - 6.5% 0.3% 7 - 9% 0.7 - 1% '§./ To RELLUMIT 5 xpi0YJXE: o,i e:ivm XOl'tCXMYJAO. 1346 EG>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) Appendix a.le figure 1 E i, xova: I Device for measuring impact resistance by means of a spherically-ended fallir.g weight EUOKEV~ y1,~ µf~p~a~ O'.V~l,OT&OEW½ xpo6aEw~ µE B&po~ µE a~a1,p1,xo 1xpo - ---- ----r Section AA• Wt!ight guid an ce 0◊~y6½ TOU j3apou½ 1 0 0 A 400 A' r 0 0 0 M 7 0 0 to c.naui1 I'wv urn.~ paj3 6cc; ~-----.,. ,-. ......,.T"'-~0~~~µ€V~ OTQ n11.a Ca 1,0 steel chassis Concr•t• bes• BaaT) axupo5tµa EG>HMEPII THI KYBEPNHIEOI (TEYXOI 6EYTEPO) 1347 A:p:Pendix a. le Figure 2 E 1, l-f.6va: 2 Device to test resistance to chemical agents 190 ,-~- . ,p ~ Q"' -- # -z,/ ,,,.✓ ---~ v /' / ~ucn-1.e:uf, 00K1.µ~c:; avt 1,c11;&cre:tuc; O'tCX lflµ I, '1-t&· Ttgluening ring (c16m~) ~cp I, 'H/tf)pO:c:; . 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To CITJ!!Eio «++» <J'tlj <J't'T)ATJ (a) C11J(J-1Xi11at: H amxoAATJOTJ E'ttXE't'ta.c;; ae 6e;1Xµa110-XOV'tETJIIEP XIXt <JU<J'totx[ac; ooxaiwv ai­ VClt <JU(J-cpWVTJ µa 'ttc; IX'ltlXl'tYj<JEtc; 'tOU 7tEpt0wpt1XXOU 21 130, TJ amxb).).TJOTJ m11ixxi6w11 ( E'ttXE't'tWII) aa O)(YJfJ-IX'tlX µe a'tix0apic;; YJ 1X1toauvixpµo).01ouµa11ac;; 8e;ixµe11ic;; ai11ixt auµcpw111j µa 'ttc; 1X1t1Xt't'Tjaetc;; -cou napt0wptixxou 21 500. To <JTjµaio «-» O'tYJATJ (3) aljµixivet: ilev npo~AE'ltE'tlXt anxe.t'tlX. 1354 E<J>HMEPll: THI: KYBEPNHl:EQl: (TEYXOl: ~EYTEPO) K0t't7l"(Opi0t Apt0. OtVOt"(VWpi- No 0tv0trvwpi XOtl 0tpl0µoc; ae:wc; xLvouvou aewc; ouaiatc; Ovoµ0tai0t ouaiatc; d6ouc; ( cxvw µe.poc;) ( XCX'tW µe.poc;) Enxe.'t'tOt (at) ([3) (r) (6) (e) ACETAL (1,1-DIETHOXIETHANE) 3, 3 °(B) 33 1088 3 Axe'tOtA6e:0671 (AA6e067J) 3, 1 °(0t) 33 1089 3. O;uto o;u xpua'tOtAlXCX XOtl u60t't06lOtAUfJ-Ot'COt o;LXOU o;foc; 7t0U 7topte.xouv 7tCXVW Ot7t0 80 Cl'tOt EXOt'tO x0t80tpo o;u 8 32°((3) 83 2789 8-+-3 O;txo o;u 7tOU 7tEptEXEt 7tCXVW Ot7t0 50 µe.xpt 80 Cl'tOt EXOt'CO x0t80tpo o;u 8, 32 °(1) 80 2790 8 • O;txoc; OtVu6pi'CTJc; 8, 32 °((3) 83 1715 8+3 ACETOIN (ACETYLMETHYLCARBINOL) 3, 31 °(1) 30 2621 3 AxE'tOV71 ( OtCle'COV) ACETONE CYANOHYDRIN 6.1, 11 0(0t) 66 1541 6.1 ACETONITRILE 3, 11 0((3) 336 1648 3 + 6.1 ACETYL ACETONE: BUm PENTAN-2,4-DIONE ACETYL BROMIDE 8, 36°([3) 80 1716 8 ACETYL CHLORIDE 3, 25 °((3) X338 1717 3 .... 8 ACETYLENE TETRABROMIDE: 8)..e.1te 1,1,2,2- TET RABROMOETHANE ACETYLMETHYLCARBINOL: BAe.1te ACETOIN ACROLEIN 3, l7°(0t) 336 1092 3 + 6.1 ACRYLAMIDE . 6.1, 12 0 (r) 60 2074 6.lA ACRYLAMIDE, 6tcxAuµ0t .6.1, 12o(r) 60 2074 6.lA AxpuAtXO o;u 8, 32 °((3) 89 2218 6+3 ACRYLONITRILE 3, 11 °{0t) 336 1093 3 + 6.1 ADIPONITRILE 6.1, 12°(r) 60 2205 6.lA Ae.patc;, u,po, f30t0Etcxc; XOt'tat<j>u;ewc; 2, 8°(0t) 225 1003 5 OtV07tVEUfJ-Ot'tOt, uypcx, µ71 'tO;txcx x0t80tpcx ~ CIE µiyµat,Ot, fJ-7) x0t8opt,oµev0t 6t0tcpopE'ttXCX Cl'tO 1t0tpov TT0tpcxp,7Jµ0t ·7tOU e.xouv C17Jp.Eio 0tv0tcpW;ewc; µe-cat!;u 21 ° K XOtt 55 ° K (1toptA0tp.f30tVoµevwv 'CWV optatXWV 'ttµwv) 3, 31 °(r) 30 1987 3 ·7tOU e.xou Cl7)P,El0 OtVOtcp)..e.;awc; mivw Ot7t0 55 ° K 3, 32°(r) 30 1987 AA6e067J: f3Ae.1ta Axa-c0tA6a0671 AA6a06ac; 1tou 6av x0t8op1,ov-c0tt 6t0tcpopa'ttXcx aw 1t0tpov TT0tpcxp,7Jµ0t. 7tOU e.xouv C17JfJ-ElO OtV~cpAe.;awc; XCX'tW Ot7t0 21 ° K 3, 3 0((3) 33 1989 3 7tOU e.xouv 071µaio 0tv0tcpAi;awc; µa,0t!;u 21 ° K XOtt 5 5 ° K ( m,pv..0tµf30tvoµavwv 'tWV optOtXWV 'ttµwv) 3, 31°(1) 30 1989 3 7tOU e.xouv Cl7)fJ-ElO OtVOtcpAe.;awc; 7tCXVW Ot7t0 5 5 ° K 3, 32°(r) 30 1989 ALDOL (BET A-HYDROXYBUTYRALD E-HYD E) 6.1, 13°([3) 60 2839 6.1 AAxOtAtxe.i; 0tvopy0tvec; ouaiec;, 6t0tMµ0t-c0t, 1tou 6ev xat0opi,o V'tOtt 6t0tcpopa-ctXCX Cl'tO 1t0tpov TT0tpcxp-c71µ0t 6t0tf3pw'ttxe.c; 8, 42°([3) 80 1719 8 EA0tcppcx Ot0tf3pw'ttxe.c; '8, 42o(r) 80 1719 8 ALKYL PHENOIS, µe 0tAuaati; C 2 C 8 , 1tou 6ev xa0opi,o V'tOtl 6t0tcpopmxcx Cl'CO 1t0tpov TT0tpcxp-c71µ0t 6.1, 14 o(r) 60 2430 6.lA AKYL 'SULPHONIC ACIDS, 1tou 6ev xa0opi,ov-tatt 6t0tcpo pmxdt Cl'tO 1t0tpov TT0tpCXp'tTjµ0t 7tOU 7tEpte.xouv 7tCXVW Ot7t0 55 Cl'tOt EXOt'CO EAau0epo 0uixo o!;u 8, 1 0((3) 80 2584 8 7tOU 6ev 7tEpte.xouv 7tCXVW Ot7t0 5 Cl'tOt EXOt'tO 0e:tixo o!;u, 6t0tf3pw-ctxdt 8, 34°((3) 80 2586 8 ·7tOU 6av 1te:pie.xouv mivw Ot7t0 5 Cl'tOt e:XOt'tO EAe:u0e:po 0e:tixo o!;u, EAotcppdt 6tot[3pw'ttXot 8, 34°(,) 80 2586 8 ALL YL ACET ANE 3, 1 7 ° ([3) 336 2333 3 + 6.1 ALLYL ALCOHOL 6.1, l3°(0t) 663 1098 6.1 + 3 ALLYLAMINE 3, l5°(0t) 336 2334 3 + 6. ALLYL BROMIDE 3, l6°(0t) 336 1099 3 + 6.1 ALLYL CHLORIDE 3, l6°(0t) 336 1100 3 + 6.1 ALL YL CHLOROFORMATE 8, 64°(0t) 88 1722 8 ALL YL ETHYL ETHER 3, 17°([3) 336 2335 3 + 6.1 ALLYL FORMATE 3, l7°(0t) 336 2336 3 + 6.1 ALLYL GL YCIDYL ETHER .(1 ALLYLOXY-2,3-EPOXY-PROPANE) 3, 31 o(r) 30 2219 3 ALLYLISOTHIOCYANATE 6.1, 20°@. 69 1545 6.1 + 3 l-ALLYLOXY-2,3-EPOXYPROPANE: f3)..e.1ta ALLYL CLYCIDYL ETHER • ALLYL TRICHLOROSILANE 8, 37°((3) 839 1724 8+3 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) 1355 (ot) ((3) (-,) (6) (E) ALUMINIUM ALKYL HALIDES, 6totAuf1.ot'tot 4.2,3° X333 2220 4.2 + 4.3 ALUMINIUM ALKYL HALIDES 4.2, 30 X333 2221 4.2 .... 4.3 AAxuAtot AAoup.wiou 4.2 ALUMINIUM TRIETHYL 4.2, 30 X333 1102 4.2 + 4.3 ALUMINIUM TRISOBUTYL 4.2, 30 X333 1930 4.2 + 4.3 ALUMINIUM TRIMETHYL 4.2, 30 X333 1103 4.2 + 4.3 ALUMINIUM BROMIDE, ixvuopo 8, 22((3) 80 1725 8 ALUMINIUM BROMIDE, UOot'tOOtotAUµot'tot 8, 5°(,) 80 2580 8 ALUMINIUM BROMIDE, ixvuopo 8,22 ° ((3) 80 1726 8 ALUMINIUM CHLORIDE, uoot'toototAup.ot'tot 8, 50("() 80 2581 8 N-AMINOET,HYLPIPERAZINE 8, 53°("() 80 2515 8 Ap.tvocpottvoAE<; 6.1, 12°(,) 60 2512 6.lA Aµµwviot 2, 3°(AT) 268 1005 ++ Ap.µwviot OtotAUfl.EVTJ OE vapo ltOU 1tEptEX,Et ltlX\ICJ) otltO 40 o'tot EXot'tO illix OX,t 1tixvw ot1to 50 O'tot EXot'tO otµµwviot Xot'tlX [3ixpo<; 2, 9°(AT) 268 2073 ++ Ap.p.wviot OtotAUfl.E\ITj OE vapo fJ,E ltlX\IW otltO 3 5 O'tot EXot'tci illix OX,L 1tixvw ot1to 40 o'tot EXot'tO otµµwviot (NH3) xot'tlX [3ixpo<; 2, 9°(AT) 268 2073 ++ i\totAUfl.ot'tot otp.p.wviot<; 1tou 1tEptix.ow OX,L At"(O'tEpo ot1tci 10 o'tot EXot'tO xotL OX,L 1tixvw ot1tci 3 5 O'tot EXot'tci otp.µwviot 8, 43°("() 80 2672 8 AMMONIUM BIFLUORIDE 8, 26°((3) 80 1727 8 + 6.1 AMMONIUM BIFLUORIDE, OLotAUµot'tot 8, 26°((3) 80 2817 8 .... 6.1 AMMONIUM BISULPHATE 7t0U 7tEpLEX,Et 3 O'tot EXot'tO 71 1tEptoocinpo EAEu0Epo 0Et'ixci o~u 8, 23 ° ((3) 80 2506 8 AMMONIUM FLUORIDE 6.1, 65°("() 60 2505 6.lA AMMONIUM POLYSULPHIDE, ototAuf!.ot'tot 8, 45 °((3) 86 2818 8 AMMONIUM SILICOFLUORIDE 6.1, 66°("() 60 2854 6.lA AMMONIUM SULPHIDE; oLotAuµot'tot 8, 45 °((3) 86 2683 8 AMYL ACETATES 3, 31 °(1) 30 1104 3 N-AMYL ALCOHOL 3, 31 °("() 30 1105 3 SEC-AMYL ALCOHOL 3, 31 °("() 30 1105 3 AMYL ALCOHOL, 'tpL'to(3ix0µw 3, 3 0 ((3) 33 ll05 3 N-AMYLAMINE 3, 22 ° ((3) 338 ll06 3-+-8 AMYL BUTYRA TES 3,31°(:y) 30 2620 3 AMYL CHLORIDE 3, 3°((3) 33 1107 3 AMYLENE, xotvovtxo (I-PENTENE) 3, 1 °(ot) 33 ll08 3 AMYL MERCAPTAN 3, 3°((3) 33 1111 3 AMYL METHYL KETONE 3, 31 °(,) 30 1112 3 AMYL NITRATE 3, 31 °(,) 30 lll2 3 AMYL TRICHLOROSILANE 8, 37°((3) 80 1728 8 Avv.ivTJ 6.1, ll 0 ((3) 60 1547 6.1 Avtotv'tivE<; 6.1, 12°(,) 60 2431 6.lA ANISOLE: {3Ai1tE PHENYL METHYL ETHER · ANISOYL CHLORIDE 8, 35 ° ((3) 80 .1729 8 ANTIMONY PENT ACHLORIDE (SBOL5) 8, 21 °((3) 80 1730 8 ANTIMONY PENTACHLORIDE, fl.TJ uoot'ttxix ototMµot'tot 8, 21 ° ((3) 80 1731 8 ANTIMONY PENTAFLUORIDE 8, 26 ° ((3) 86 1732 8-+- 6.1 ANTIMONY TRICHLORIDE (SBCL 3 8, 22 ° ((3) 80 1733 8 Ap,ov, u,pci, [3ot0ELIX<; Xot'tlXcj>U~Tjc; • 2, 7°(ot) 22 1951 ApoEVLXO o~u, u,po 6.1, 7 ° (ot) 66 1553 6.1 ApoEVLXO o~u. onpEO 6.1, 51 °((3) 60 1554 6.1 ApoE\ILXE<; E\IWOEL<;, u,pa<;, otvcip"(ot\lE<;, fl.TJ xot0opt~oµavac; Ototcpopmxix O'tO 1totpov TTotp1Xp'tTjµot 6.1, 51 °(ot) 66 1556 6.1 ARSENIC BROMIDE 6.1, 51 °((3) 60 1555 6.1 ARSENIC CHLORIDE 6.1, 51 °(ot) 66 1560 6.1 ARSENIC PENTOXIDE 6.1, 51 °((3) 60 155• 6.1 ARSENIC TRIOXIDE (AEuxci) 6.1, 51 °((3) 60 1561 6.1 ARYL SULPHONIC ACIDS, µTj xot0opt~oµE\IOL OtotcpopE 'ttXIX O'tO 7totpov Ilotpixp'tTjµot 1tEpLEX,O\l'tOL 7tlX\ICJ) ot7t0 5 % 0aL'ixci o~u 8, 1 0 ((3) 80 2584 8 1tEpLEX,OV'tOL OX,L 7tlX\IW OL7t0 5% EAEu0Epo 0at'ixci o~u, 2586 8tot{3pc..>'tLXO 8, 34°((3) 80 8 1tEpLEX,O\l'tot OX,L 7tlXVW otltci 5% EAEu0apo 0EL'ixci o~u, EAotcppix OLot{3pc..>'tlXO 8, 34 ° ((3) 80 2586 8 BARIUM CARBONATE 6.1, 60(,) 60 1564 6.lA BARIUM OXIDE (O~eioto 'tou) 6.1, 60(,) 60 1884 6.lA BE\l~OAW 3, 3°((3) 33 lll4 3 BENZENE SULFONYL CHLORIDE 3, 36°(,) 80 2225 8 BENZONITRILE 6.1, l1°((3) 60 2224 6.1 . BENZOQUINONE 6.1, 14°((3) 60 2587 6.1 BENZOTRICHLORIDE (TRICHLOROMETHYLBEN ZENE 8, 66°((3) 80 2226 8 1356 E<DHMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) (ix) ([3) (r) (o) (E) BENZOTRIFLUORIDE 3, 3 0([3) 33 2338 3 BENZYL CHLORIDE 8, 36°([3) 80 1736 8 BENZYL BROMIDE 6.1, 15°([3) 60 1737 6.1 BENZYL CHLORIDE 6.1, 15°([3) 60 1738 6.1 BENZYLCHLOROFORMATE 8, 64°(1X) 88 1739 8 BENZYL CYANIDE (PHENYLf CETONITRILE) 6.1, l2°{r) 60 2470 6.lA BENZYL DIMETHYLAMINE 8, 52°([3) 83 2619 8+3 BENZYLIDENE CHLORIDE 6.1, 17°([3) 68 1886 6.1 BICYCLOHEPT ADIENE 3, 3 0([3) 33 2251 3 BIS-AMINOPROPYLAMINE (DIPROPYLENETRIA MINE, 3,3'-IMINOBISPROPYLAMINE) 8, 53°(,) 80 2269 8 1,2 BIS (DIMETHYLAMINO) ETHANE (TETRAME THYLENEDIAMINE) 3, 31 °(,) 30 2372 3 BORON TRIBROMIDE (BORON BROMIDE) (BBR: 1 ) 8,21°(ix) X88 2692 8 BORON TRIFLUORIDE auµ1tAE'YfllX o~Lxou o~fo.; 8, 33°([3) 80 1742 8 BORON TRIFLUORIDE ETHER, aUf.1-1tAE'(fJ-IX 8, 33°([3) 83 2604 8 + 3 BORON TRIBLUORIDE PROPIONIC ACID, atiµ1tAE1 f.1-ix 8, 33°([3) 80 1743 8 BORON TRIFLUORIDE DIHYDRA TE 8, 33([3) 80 2851 8 Bpwf.1,i6w 8, 24° 886 1744 8 + 6.1 BROMINE PENTAFLUORIDE 8, 26°{1X) 856 1745 8 + 6.1 BROMINE TRIFLUORIDE 8, 26°(ix) 856 1746 8 +1 6.1. BROMACETIC ACID 8, 31 °([3) 80 1938 8 BROMOACETONE 6.1, 16°([3) 60 1569 6.1. wp.e.1o:-BROMOACETOPHENONE: [3Ae.1tE PEHENACYL BROMIDE 8, 36°([3) X80 2513 8 BROMOACETYL BROMIDE 8, 36°(8) X80 2513 8 BROMOBENZEN E 3, 31 °(,) 30 2514 3 w..qio:-BROMOBENZYL CYANIDE 6.1, l 7°(ix) 66 1694 6.1 2-BROMOBUTANE 3, 3 0([3) 33 2339 3 BROMOCHLORODIFLUOROMETHANE (R 1281) 2, 3°(ix) 20 1974 BROMOCHLOROMETHANE 6.1, 15°([3) 60 1887 6.1 I-BROMO-3-CHLOROPROPANE 6.1, 15(1) 60 2688 6.lA 2-BROMOETHYL ETHYL ETHER 3, 3 0([3) 33 2340 3 BROMOFORM 6.1, 15°(,) 60 2515 6.lA I-BROMO-3-METHYLBUTANE • 3, 3 0([3) 33 2341 3 BROMOETHYLPROPANES 3, 3 0([3) 33 2342 3 2-BROMOPENTHANE 3, 3 0([3) 33 2343 3 BROMOPROPANES 3, 3 0([3) 33 2344 3 BROMOTRIFLUOROMETHAN E (Rl381) 2, 5°(ix) 20 1009 Bou'to:6te.vto: 2, 3 o(r) 239 1010 3 Bou'tot11to 3, 3 0([3) 23 1011 3 BUTANEDIONE (DIACETYL) 3, 3 0([3) 33 2346 3 BUTANOL: [3AE1tE Bou'tUAtx~ o:AxooA71 N-BUTANOL-2: [3A. Bou'tuAtX~ o:AxooA71 BUTANOL, 'tpt'to1Eve..; ('tpL'to1e11~.; [3ou'tuALX~ 1XAX00A71) 3, 3 0([3) 33 1120 3 I-BUTENE: [3A. 1-BUTYLENE • CIS-2-BUTENE, ~A. CIS-2-BUTYLENE TRANS-2-BUTENE:[3A.TRANS-2-BUTYLENE BUTOXYL (METHOXYBUTYL ACETATE) 3,31 °{r) 30 2708 3 N-BUTYL ACETATE 3,31 °{r) 30 1123 3 BUTYL ACETATE, 6Eunpo1eve..; 3, 3 0([3) 33 1123 3 BUTYL ACID PHOSPHATE 8,38°{r) 80 1718 8 N-BUTYL ACRYLATE 3,31 °{r) . 39 2348 3 N-BUTYL ALCOHOL (Bou'tix110A71) 3,31 °(r) 30 1120 3 SEC-BUTYL ALCOHOL (N-BUTANOL-2) 3,31 °{r) 30 1120 3 BUTYL ALCOHOL, 'tpL'to1e11~.;: [3A. Bou'tix110A71, 'tpL't01E11~.; N-BUTILAMINE 3,22 °([3) 338 1125 3 + 8 N-BUTILANILINES 6.1, 12°([3) 60 2738 6.1 BUTYL BENZENES 3,31 °(r) 30 2709 3 BUTYL BROMIDE, xix110111xo 3, 3 0([3) 33 1126 3 BUTYL CHLORIDES (CHLOROBUT ANES) 3,3 °([3) 33 1127 3 N-BUTYLCHLOROFORMATE 6.1, 16°([3) 638 2743 6.1 + 3 + 8 TERT-BUTYLCYCLOH.EXYLCHLOROFORMA TE 6.1. 17°(,) 68 2747 6.lA + 8 1-BUTYLENE (I-BUTENE) 2. 3 °((1) 23 1012 3 CIS-2-BUTYLENE (CIS-2-BUTENE) 2. 30([3) 23 1012 3 TRANS-2-BUTYLENE (TRANS-2-BUTENE) N-BUTYL ETHER: [3Aim DI-N-BUTYL ETHER 2. 3 0 ([3) 23 1012 3 N-BUTYL FORMATE 3. 3 0([3) 33 1128 3 N,N-BUTYL IMIDAZOLE 6.1. L2°([3) 60 2690 6.1 BUTYL ISOCYANATE, x1X11011txo 3. 14°([3) 336 2485 3+6.1 BUTYL MERCAPTAN 3, 3 0 ([3) 33 2347 3 N-BUTYL METHACRYLATE- 3. :11 °(r) 39 . 2227 3 ECJ>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: 6EYTEPO) BUTYL METHYL ETHER BUTYL.PHENOLS, oe: Auwµev71 xcxi:cxoi:0:071 BUTYLPHENOLS uypo BUTYL PROPIONATE BUTYL TOLUENES BUTYLTRICHLOROSILANE BUTYL VINYL ETHER BUTYNE: ~Um CROTONYLENE Bou1:upcxAoe:'io71 BUTYRALDOXIME N-Boui:uptxo o1;u Bou,uptxo,; cxvuopiTTJ<; BUTYRONITRILE BUTYRYL CHLORIDE CAESIUM HYDROXIDE CAESIUM HYDROXIDE UOCX"CtXIX OtCXAU(J-CX'tCX CALCIUM ARSENATE CALCIUM CHLORATE, otcxAuµcx-ccx &to1;e:tOtO "COU cxv0pcxxcx &to1;e:ioto "COU cxv0pcxxcx, uypo. ~cx0e:LIX<; xcx-ccxqiul;e:w<; &to1;e:ioto "COU cxv0pcxxcx, ltOU 1te:ptEXEt ltCXVW CXltO 6 O'tCX EXCX"CO CXMCX oxt ltCXVW CXltO 35 01:CX e:xcx-co ETHYLENE OXIDE xcx-ccx p.cx~cx •• &to1;e:ioto "COU cxv0pcxxcx, ltOU oe:v 7tepLEXE:t ltlXVW CXltO 6 01:CX EXCX"CO ETHYLENE OXIDE XCX"CIX (J-IX~(X &to!;e:ioto "COU ixv0pcxxcx, ltOU oe:v 1te:ptEXEt oxt XIX'tW <XltO 1 O"C(X EX<X"CO X<Xl OXL ltCXVW <XltO 1 0 O"CCX e:xcx-co o1;uyovo XCX"CCX µcx~cx CARBON DISULPHIDE CARBON TETRABROMIDE Kcxuo-ttx711to-cixocx: ~Hite: POTASSIUM HYDROXIDE Kcxuo-ctx71 ooocx: ~Hite: SODIUM HYDROXIDE CHLORAL ~A.TRICHLOROACETAL DEHYDE XAwpiv71 CHLOROACETALDEHYDE CHLOROACETIC ACID (MONOCHLOROACETIC ACID), o-ce:pe:o CHLOROACETIC ACID (MONOCHLOROACETIC ACID), AUW(J-EVO CHLOROACETIC ACIDS, p.iyµcx-ccx CHLOROACETIC ACID (MONOCHLOROACETIC ACID), Ot<XAU(J-CX't(X CHLOROACETONE wµiycx-CHLOROACETOPHENONE: ~A. PHENACYL CHLORIDE CHLOROACETYL CHLORIDE CHLOROANISIDINES CHLOROBENZENES (PHENYL CHLORIDE) CHLOROBENZOTRIFLUORIDES CHLOROBENZYL CHLORIDES CHLOROBUTANES: ~Aiite: BUTYL CHLORIDES CHLOROBCRESOLS l-CHLOR0-1,1-DIFLUOROETHANE (R 142~) CHLORODIFLUOROMETHANE (R22) CHLORODINITROBENZENE 2-CHLOROETHANOL: ~A. ETHYLENE CHLOROHYD­ RIN XAwpocpopµto CHLOROMETHYLCHLOROFORMATE CHLOROMETHYL ETHYL ETHER 3-CHLOR0-4-METHYLPHENYL ISOCYANATE CHLORONITROANALINES CHLORONITROBENZENES CHLORONITROTOLUENES CHLOROPENTAFLUOROETHANE (Rll5) 2-CHLOROPHENOL 3-CHLOROPHENOL 4-CHLOROPHENOL CHLOROPHENYL TRICHLOROSILANE CHLOROPICRIN CHLOROPRENE 1-CHLOROPROPANE (PROPYL CHLORIDE) 2-CHLOROPROPANE (ISOPROPYL CHLORIDE) 3. ;-{ 0(1) 6.1. 14°(1) (>.l. 14°(1) 3. 31°(1) 3. 32°(y) 8. :n°(~) 3. 3 °(~) 3. 3°(~) 3. 32°(y} 8. 32°(y) 8. 32°("() 3. 11 ° (~) 3. 25°(~) 8. 41 °(~) 8. 42°(~) 6.1. 5.1 °(~) 5.1. 4°(cx) 2. 5°{cx) 2. 7°(cx) 2. 6°("() 2. 6°(-y) 2. 6°(cx) 3. l8°(cx) 6.1. 15°(1) 2. :1°(AT) 6.1. 16°(~) 8, 31 °(~) 8. 31 °(~) 8. 32°(~) 8. 32°(~) 6.1, 16°(~) 8. :36°(~) 6.1. l 7°(y) 3.31°(y) 3.31°(,) 6.1. 17°(,) 6.1. 14°(~) 2. 3°(~) 2. 3°(cx) 6.1.12°(~) 6.1, 15°(~) 6.1. 16°(~) 3, 16°(~) 6.1, 19°(~) 6.1, 17°(,) 6.1, 12°(~) 6.1, l7°(y) 1, 3°(cx) 6.1, 16°(y) 6.1, l7°(y) 6.1, l 7(y) 8, 37°(~) 6.1, l6°(cx) 3, l6°(cx) 3, 2°(~) 3, 2°(~) (y) 33 60 60 30 30 83 339 33 30 80 80 336 338 80 80 60 50 20 22 239 20 336 60 266 60 80 80 80 80 60 X80 60 30 30 60 60 23 20 60 60 638 336 60 60 60 60 20 68 60 60 80 66 336 33 33 (o) 2350 2229 2228 19134 2667 1747 2352 1129 2840 2820 2739 2411 2353 2,82 2681 1573 2429 1013 2187 1041 1952 1014 1131 2516 1017 2232 1751 1750 1750 1750 1695 1752 2233 1134 2234 2235 2669 2517 1018 1577 1888 2745 2354 2236 2237 1578 2433 . 1020 2021 2020 2020 1753 1580 1991 1278 2356 3 6.lA 6.lA 3 8-+-3 3 3. 8 8 3+6.1 3-+-8 8 8 6.1 5 ++ ++ 3+6.1 6.lA ++ 6.1 8 8 8 8 6.1 8 6.lA 3 3 6.lA 6.1 ++ 6.1 1357 6.1 6.1-+-3-+-8 3 + 6.1 6.1 6.lA 6.1 6.lA 6.lA 6.lA 6.lA 8 6.1 3 + 6.1 3 3 1358 EG>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) (0() ((3) ('y) (6) (E) 3-CHLOROPROPA.NE-1,2 DIOL,[3).. CLYCEROL AL PHA-MONOCHLOROHYDRIN 3-CHLOR0-1-PROPANOL 6.1, 16°(,) 60 2849 6.lA l~CHLOR0-2-PROPANOL 6.1, 16°((3) 63 2611 6.1 + 3 2-CHLOROPROPENE 3,1 °M 33 2456 3 2-CHLOROPROPIONIC ACID 8. 32°(,) 80 2511 8 2-CHLOROPYRIDINE 6.1, 11°((3) 60 2822 6.1 CHIA TROSILANES 1tOU OEV O(VO(O[oouv EUcpAEX'tO( O(EptO( OE E1tO(cp7l (.LE 'tO npo, 7tOU OEV X0(0opi,oV'tO(l OlO(cpOpE'tlXO( O'tO 1tO(pov TTO(pO(p'tTllLO( 3, 21 °(0() X338 2985 3+8 (.LE OT)(J.EiO O(VO(cpAE~EW<; XO('tW 0(7t() 21 ° K 3, 21 °(0() X338 2985 3+8 (.LE 01)(.1.Eio O(VO(cpAE~Ew<; (J.E'tO(~U 21 ° K XO(t 5 5 ° K 8, 37°([3) 83 2986 8+3 (.LE OTJ(J.dO O(VO(cpAE~EW<; 7tO(VW 0(7t() 5 5 ° K 8, 37°([3) 80 2987 8 CHLOROSULPHONIC ACID(S0 2 (0H)CL) 8,21°(0() 88 1754 8 CHLOROTOLUENES 3, 31 °('() 30 2238 3 CHLOROTOLUIDINES 6.1, 17°(,) 60 2239 6.lA I-CHLOR0-2,2,2-TRIFLUORO-ETHANE (R 1330() 2, 3°(0() 20 1983 CHLOROTRIFLUOROMETHANE (Rl3) 2, 5°(0() 20 1022 CHROMIC ACID, OtO(AU(J.O('tO( 8, 11 °((3) 80 1755 8 CHROMIC FLUORIDE 8, 26°((3) 80 1756 8 + 6.1 CHROMIC FLUORIDE, OtO(AU(.I.O('tO( 8, 26°((3) 80 • 1757 8 + 6.1 CHROMIUM OXYCHLORIDE: [3Ai1tE CHROMYL CH LORIDE CHROMOSULPHURIC ACID • 8, 1 °(0() 88 2240 8 CHROMYL CHLORIDE (CHROMIUM OXYCHLORIDE) (CRO CL 2 ) KoUo13tO(, H1.1.t-xoUoOlO(, OlO(AV(.I.O('tO( XO(l ci()J..O( OtO(A\lflO('tO( 8, 21 °(0() 88 1758 8 Vl'tpOEAOUAO,TJ<; (.LE OTJ(J.Eio O(VO(cpAE~Ew<; xci('tw 0(1to 21 ° K XO(l OTJ(.I.Eio [3pO(O(J.OU OXl 1tO(VW 0(7t(J 3 5 ° K 3, 4°(0() 33 2059 3 (.LE OTJ(.I.Eio O(VO(cpAE~Ew<; xci('tw 0(1to 21 ° K XO(t OTJ(.I.Elo [3p0(0(.I.OU 7tO(VW 0(7t() 3 5 ° K 3, 4°((3) 33 2059 3 µE OT)(.I.EtO O(VO(cpAE~EW<; (.I.E'tO(~\) 21 ° K XO(l 5 5 ° K 3, 33°(,) 30 2060 3 µE 01)(.1.dO O(VO(cpAE~EW<; 7tO(VW 0(7t() 5 5 ° K 3, 34°("() 30 2060 Kp.ooATJ 6.1, 14°((3) 60 2076 6.1 CRESYLIC ACID 6.1, 14°((3) 60 2022 6.1 CROTONIC ALDEHYDE (CROTON-ALDEHYDE) 3, 3°((3) 33 1143 3 CROTONYLENE (2-BUTYNE) 3, 1 °(0() 339 1144 3 CUMENE (ISOPROPYBLENENE) 3, 31 °(1) 30 1918 3 CUMYL HYDROPEROXIDE: f3U1te d().cpO(, d().cpO( DIME THYLBENZYL HYDRO"PEROXIDE CUPRIETHYLENEDIAMINE, 6t0().uµO('t0( 8, 53°((3) 86 1761 8 CYANIDES, O(IIOP"(O(VO( OlO(AU(.I.O('tO( 6.1, 41 °(0() 66 1935 6.1 CYANURIC CHLORIDE. 8, 27°('() 80 2670 8 CYCLOBUTYL CHLOROFORMATE 6.1, 16°((3) 638 2744 6.1+3+8 1,5, 9-CYCLODODECATRIENE 6.1, 24°(r} 60 2518 6.lA CYCLOHEPTANE 3, 3°((3) 33 2241 3 CYCLOHEPTENE 3, 3°((3) 33 2242 3 CYCLOHEXANE 3, 3°((3) 33 1145 3 CYCLOHEXANONE 3, 31 °(1) 30 1915 3 CYCLOHEXENE 3, 3°((3) 33 2256 3 CYCLOHEXENYL TRICHLOROSILANE 8, 37°((3) 33 2256 3 CYCLOHEXYL ACETANE 3, 32°(r) 30 2243 CYCLOHEXILAMINE 8, 53 ° ((3) 83 2357 8+3 CYCLOEXYLISOCYANATE 6.1, 18°([3) 63 2488 6.1 + 3 CYCLOHEXYL TRICHLOROSILANE 8, 37°((3) 80 1763 8 CYCLOOCT ADIENE 3, 31 °(1) 30 2520 3 CYCLOOCTATETRAENE 3, 31 °('() 30 2358 3 CYCLOPENTANE 3, 3°((3) 33 1146 3 CYCLOPENTANOL 3, 31 °(r} 30 2244 3 CYCLOPENTANONE 3, 31 °(1) 30 2245 3 CYCLOPENTENE 3, 2°((3) 33 2246 3 CYCLOPROPANE 2, 3°([3) 23 1027 3 CYMENES (METHYL ISOPROPYL BENZENES) 3, 31 °(r) 30 2046 3 DECAHYDRONAPHTHALENE (DECALIN) 3, 32°(r) 30 1147 N-DECAN E 3, 31 °{r) 30 2247 3 DIACETONE ALCOHOL, 'tEXVlXO 3, 3°((3) 33 1148 3 DIACETYL: (3Ai1tE BUTANEDIONE DIALLYLAMINE 3, 22 ° ((3) 338 2359 3+8 DIALL YL ETHER 3, 17°((3) 336 2360 3 + 6.1 DIAMINODIPHENYL METHANE: LE AUW(.I.EVT) XO('tO(O'tO(OT) 6.1, l2°(r) 60 2651 .lA DI-N-AMYLAMINE 6.1. 12°(-y) 60 2841 • 6.lA E<l>HMEPII THI KYBEPNHIEQI (TEYXOI 6EYTEPO) 1359 (et) (~) (y) (6) (a) DIBENZYLDICHLOROSILANE 8, 37°(~) 80 2434 8 DIBROMOBENZENES 3, 32°(,) 30 2711 1,2-DIBROMOBUTAN-3:ivet 6.1, 16°(~) 60 2648 6.1 1,2-DIBROMO-3-CHLOROPROPANE 6.1, 15°(,) 60 2872 6.lA' SYM. DIBROMOETHANE: ~Abee ETHYLENE DIBRO MIDE DIBROMOMETHANE: ~Aiita METHYLENE BROMIDE Dl-(N-BUTYL) AMINE 8, 53°{~) 83 2248 8+3 DIBUTYLAMINOETHANOL 6.1, 12°(,) 60 2873 6.lA DI-N-BUTYL ETHER (N-BUTYL ETHER) 3,31 °{r) 30 1149 3 DICHLOROACETIC ACID 8, 32°{~) 80 1764 8 SYM.-DICHLOROACETONE 6.1,16°{~) 63 2649 6.1 + 3 DICHLOROACETYL CHLORIDE 8, 36°{~) X80 1765 8 DICHLOROANILINES 6.1, 12° 0{~) 60 1590 6.1 1,2-DICHLOROBENZENES 6.1, 15°(,) 60 1591 6.lA 2,2-DICHLORODIETHYL ETHER 6.1, 16°{~) 63 1916 6.1 + 3 DICHLORODIFLUOROMETHANE (Rl2) 2, 3°(0t) 20 1028 • DICHLORODIFLUOROMETHANE ,cou iteptiX,EL 12 oi:et axeti:o ETHYLENE OXIDE xai:ii µii~et 2, 4°{CT) 236 1028 ~ ~ 1,1-DICHLOROETHANE (ETHYLIDENE) CHLORIDE 3, 3°(~) 33 2362 3 1,2-DICHLOROETHANE (ETHYLENE CHLORIDE) 3, 16°(~) 336 1184 3 .... 6.1 1,2-DICHLOROETHYLENE 3, 3°(~) 33 1150 3 DICHLOROFLUOROMETHANE (R2 l) 2, 3°(0t) 20 1029 1,3-DICHLOROHYDRIN l,3-DICHLORO-2-PROPAN OL) 6.1, 16°(~) 60 2750 6.1 DICHLOROISOPROPYL ETHER . 6.1, 16°(~) 60 2490 6.1 DICHLOROMETHANE: ~A. METHYLENE CHLORIDE 1, l-DICHLORO-1-NITROETHANE 6.1, 16°(~) 60 2650 6.1 DICHLOROPENTANES 3, 31 °(1) 30 1152 3 3,4-DICHLOROPHENYL ISOCYANATE 6.1,19°(~) 60 2250 6.1 DICHLOROPHENYL TRICHLOROSILANE 8, 37 °(~) 80 1766 8 1,3-DICHLORO-2-PROPANOL: ~Hm 1,3-DICHLOR OHYDRIN 1,3-DICHLOROPROPENE 3, 31 °(1) 30 2047 3 1,2-DICHLORO-l, 1,2-2-TETRA-FLUOROETHANE (R 114) 2,3 °(et) 20 1958 DICYCLOHEXYLAMINE 8, 53°(,) 80 2565 8 DICYCLOPENT ADIENE 3, 31 °(r} 30 2048 3 1,1-DIEXOXYETHANE: ~Aiita ACETAL 1,2-DIETHOXYETHANE (ETHYLENE) GLYCOL DIE THYL ETHER) 3,31°(,) 30 1153 3 DIETHOXYMETHANE 3, 3°(~) 33 2373 3 3,3-DIETHOXYPROPENE 3, 3°(~) 33 2374 3 DIETHYLAMINE 3,22°(~) 338 1154 3 .... 8 DIETHYLAMINOETHANOL (N, N-DIETHYLETHAN OLAMINE) 3, 32°(,) 30 2686 DIETHYLAMINOPROPYLAMINE 8,53°(,) 80 2684 8 N,N-DIETHYLANILINE 6.1, 12°(,) 60 2432 6.lA DIETHYLBENZENES 3, 32°(,) 30 2049 DIETHYL CARBONATE (ETHYL CARBONATE) 3, 31 °(r} 30 2366 3 DIETHYLDICHLOROSILANE 8, 37°(~) 83 1767 8+3 DIETHYLENEDIAMINE (PIPERAZINE) 8, 52°(,) 80 2579 8 DIETHYLENETRIAMINE 8, 53°(~) 80 2079 8 N,N-DIETHYLETHANOLAMINE: ~Hita DIETHYLAMI NO ETHANOL N,N-DIETHYLETHYLENEDIAMINE 8, 53°(~) 83 2685 8+3 DIETHYL KETONE 5, 3°(~) 33 1156 3 • DIETHYL SULPHATE 6.1, 14°(~) 60 1594 6.1 DIETHYLTHIOPHOSPHORYL CHLORIDE 8, 36°(~) 80 2751 8 1,1-DIEFLUOROETHYLENE (VINYLIDENE FLUORIDE) '2,5°(,) 239 1959 3 1,1-DIFLUOROETHANE (R 152a) 2, 3°(~) 23 1030 ~ ~ DIFLUOROPHOSPHORIC ACID, iivu6po 8, 10°(~) 80 1768 8 2,3-DIHYDROPYRAN 3, 3°(~) 33 2376 3 DIISOBUTYLAMINE 3, 31 °(r} 30 2361 3 DIISOBUTYLENES 3, 3°(~) 33 ·2050 3 DIISOBUTYL KETONE 3, 31 °(r} 30 1157 3 DIISOOCTYL ACID PHOSPHATE 8, 38°(,) 80 1902 8 DIISOPROPYLAMINE 3,22°(~) 338 1158 3+8 DIISOPROPYLBENZENE HYDROPEROXIDE (ISOP ROPYL CUMYL HYDROPEROXIDE) µa 45 O'tOt EXOt'tO µlyµeti:oi:; OlVOltVEuµeti:oi:; XOU XE'tOV'Tj<; 5.2. 18° 539 2171 5 1360 EG>HMEPII: THI: KYBEPNHI:EQI: (TEYXOI: aEYTEPO) (ex) (f:l) (y) (o) (E) N,N-DIISOPROPYLETHANOLAMINE 8, 53°(1) 80 2825 8 DIISOPROPYL ETHER 3, 3°((:l) 33 1159 3 DIKETONE 3, 31 °{1) 39 2521 3 I,I-DIMETHOXYETHANE 3, 3°((:l) 33 2377 3 1,2-DINETHOXYETHANE 3, 3 o((:l) 33 2252 3 DIMETHOXYMETHANE (METHYLAL) 3, 2 o{(:l) 33 1234 3 DIMETHYLAMINE, <ivuopTJ 2, 3 °(BT) 236 1032 3 + 6.1 DIMETHYLAMINE, u6ex1:06texAup.ex1:ex f.lE OTJf.lEtO f:lpexoµou oxt lt<XVW ex1to 3 5 ° K 3, 22 °{ex) 338 1160 3 + 8 f.lE OTjf.lELO f:lpexoµou oxt lt<XIIW ex1to 3 5 ° K. 3,. 22 °({:l) 338 1160 3 + 8 DIMETHYLAMINOACETONITRILE 6.1, 11°((:l) 63 2378 6.1 + 3 DIMETHYLAMINOETHANOL: (:lAi1tE DIMETHYLE THANOLAMINE DIMETHYLAMINOETHYL METHACRYLATE 6.1, 11 o((:l) 69 2522 6.1 N,N-DIMETHYLANILINE 6.1, 11 o((:l) 60 2253 6.1 DIMETHYLBENZENES: (:l).. XYLENES. ci).cpcx, ci).cpex DIMETHYLBENZYL HYDROPEROXIDE (CUMYL HYDROPEROXIDE) f.lE 7tEptEXWC01:Tj'tex U7tEpo;EtO[ou oxt 1t<XIIW CXltO 95 <J't(X EXCX'tO 5,2 10° 539 2116 5 1,3-DIMETHYBUTYLAMINE 3, 3 o((:l) 33 2379 3 N, N-DIMETHYLCARBAMOYL CHLORIDE 8, 36°((:l) 80 2262 8 DIMETHYL CARBONATE 3, 3 o{(:l) 33 1161 3 DIMETHYCYCLOHEXANES 3, 3 o((:l) 33 2263 3 N,N-DIMETHYLCYCLOHEXYLAMINE 8, 33°((:l) 83 2264 8 + 3 DIMETHYLDICHLOROSILANE 3, 21 °(ex) X338 1162 3 + 8 DIMETHYLDIETHOXYLANE 3, 3 o{(:l) 33 2380 3 DIMETHYLDIOXANES f.lE <JTjf.lElO cxvcxcpAi;Ewi:;; x<i,w cx1to 21 ° K 3, 3 o{(:l) 33 2707 3 f.lE OTJf.lEto exvcxcp).i;Ewi:;; f.lE,cx;u 21 ° K xexL 55 ° K 3, 31 °(1) 30 2707 3 f.lE OTJf.lELO exvexcp).i;cwi:;; 1t<i11w cx1to 5 5 ° K 3, 32°(1) 30 2707 DIMETHYL DISULPHIDE 3, 3 o{(:l) 33 2381 3 DIMETHYLETHANOLAMINE (DIMETHYL-AMINOE THANOL) 3, 31 °{y) 30 2051 3 DIMETHYL ETHER 2, 3 o{(:l) 23 1033 3 N,N-DIMETHYLFORMAMIDE 3, 32°{1) 30 2265 1,1-DIMETHYLHYDRAZINE 3, 23°(ex) 338 1163 3 + 8 1,2-DIMETHYHYDRAZINE 3, l5°{cx) 336 2382 3 + 6.1 .DIMETHYL-N-PROPYLAMINE' 3, 22°((:l) 338 2266 3 + 8 DIMETHYL SULPHATE 6,1 l3°(cx) 66 1595 6.1 DIMETHYL SULPHIDE 3, 20(~) 33 1164 3 DIMETHYL THIOPHOSPHORYL CHLORIDE 8, 36°{1) 80 2267 8 DINITROANILINES 6.1 12°((:l) 60 1596 6.1 DINITROBENZENES 6.1 12°{~) 60 1597 6.1 DINITRO-ORTHOCRESOL° 6.1 75°((:l) 60 1598 6.1 DINITROTOLUENES, o,EpEti 6.1 12°((:l) 60 2038 6.1 DINITROTOLUENES, AUWf.lEV(X 6.1 12°((:l) 60 1600 6.1 DIOXANE 3, 3 o{(:l) 33 1165 3 DIOXOLANE 3, 3 o((:l) 33 1166 3 DIPENTENE 3,31°((:l) 30 2052 3 DIPHENYLDICHLOROSILANE 8, 37°(~) 80 1769 8 4,4· -DIPHENYLMETHANE DIISOCY ANA TE 6.1, 19°(1) 60 2489 6.IA DIPHENYLMETHYL BROMIDE 8, 65 "((:l) 80 1770 8 DIPROPYLAMINE 3. 22°(~) 338 2383 3+8 DIPROPYLENETRIAMINE: {:lAi1te BIS-AMINOPROPYL AMINE DIPROPYL ETHER 3, 3°((:l) 33 2384 3 DIPROPYL KETONE 3,31 ° (y) 30 2710 3 DISULPHUR DICHLORIDE (SfOL2 8,21 °{ex) 88 1828 8 DITERTIARY BUTYL PEROX DE 5.2, 1 ° 53() 2102 5 DODECYL TRICHLOROSILANE 8.37°((:l) 80 1771 8 ENAMELS ((:lepv[xLcx) f.lE OTJf.lELO cxvcxcp).i;Ewi:;; x<i,w ex1t6 21 ° K 3. 5° 33 1263 3 f.lE OTJf.lELO exvexcp).i;ewi:;; f.lE,cx;u 21 ° K xm 55 ° K 3,31 °(1)+/ 30 1263 3 µe <JTjf.lELO cxvcxcp).i~Ewi:;; 1t<ivw ex1t6 5 5 ° K 3,32°{1)-+-/ 30 1263 ERIBROMOHYDRIN 6.Ll6°{cx) 66 2558 6.1 EPICHLOROHYDRIN 6.1,]6°{(:l) 63 2523 6.1 + 3 1,2-EPOXY-3-ETHOXYPROPANE 3,31 °{1) 30 2752 3 ETHANE 2, 5°(8) 23 1035 + -: ETHANE, uypo, f:lex6et<ii:;; xex,<i~U~Tji:;; 2. 7°((:l) 223 1961 + + ETHANOL (ETHYL ALCOHOL) xexL ,ex uocx,tx<i ,7Ji:;; Otex AUf.lCX'tCX 1tEptixo111:cx lt<XVW ex1t6 70 a,ex EXCX'tO OLV01tvwp.ex 3. 3 °((:l) 33 1170 3 <l>EK 104 EG>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) 1361 (ix) (~) (j) (o) (e) ETHANOL (ETHYL ALCOHOL) UOIX"CLXIX OtlXAUµIX,IX IX7t0 24 a,ix axix,o µtxpt xixt 70 a,ix axix,o 3.31 °(r) 30 1170 3 ~ /BAErta, oµc.uc;, tHMEIQ~H UrtO TTixpii-ypixcpo ~ "COU 1tapt6wpt1XXO\l 230 l. ETHANOLAMINE xixt otixAuµix,ii ,TJc; 8.54°(y) 80 2491 8 2-ETHOXYETHANOL (ETHYLENE GLYCOL MO:\:OE THYL ETHER) 3.31 °(-1) 30 1171 3 2-ETHOXYETHYL ACETATE (ETHYLENE GLYCOi. 'v MONO ETHYL ETHER ACF.TATE) 3.3I°(-y)· 30 1172 3 ETHYL ACETATE 3. 3°([:I) 33 1173 ·3 ETHYL ACRYLATE 3. 3°([:I) 339 1917 3 ETHYL ALCOHOL: f:IA. ETHANOL ETHYLAMINE, iivuopTJ 2. 3 °(HT) 236 1036 3 -s- 6.1 ETHYLAMINE, UOIX'tOOLIXAUµIX,IX µa OT]µEio f:lpixaµou OXL 7t!XVW IX7t0 3 5 ° K 3.22°(ix) 338 2270 3 ..: 8 µa OT]µdo f:lpixoµou mxvw IXrtO 35 ° K 3.22°([:I) 338 2270 3-s-8 ETHYL AMYL KETONE 3.3 \ 0 (y) 30 2271 3 2-ETHYLANILINE 6.1.12°(1) 60 2273 6.1A N-ETHYLANILINE 6.Ll2°(y) 60 2272 6.lA ETHYLBENZENE, 'tEXVLXTj 3. :1 °([:I) 33 1175 3 N-ETHYL-N-BENZYLANILINE 6.1.12°(1) 60 2274 6.1A ETHYL BROMIDE 6. J. I 5 °([:I) 60 1891 6.1 ETHYL BROMOACET ATE 6.1.16°([:I) 63 1603 6.1 -s- 3 2-ETHYLBUTANOL 3.:32°(y) 30 2275 2-ETHYLBUTYL ACETATE :3.31 °(1) 30 1177 3 ETHYL BUTYL ETHER ;3 :3 °([:I) 33 1179 3 ETHYL BUTYRATE 3.31 °(-y) 30 1180 3 ETHYL CARBONATE: f:IA. DIETHYL CARBO\IATE ETHYL CHLORIDE 2. 3°(BT) 236 1037 ~ -+ ETHYL CHLOROACETATE 6.1 .. 16°([:I) 63 1181 6.1 + 3 ETHYL CHLOROFORMATE 3.16°(:x) 336 1182 3 -s- 6.1 ETHYL CROTONATE 3. 3 °([:I) 33 1862 3 ETHYL CY ANOACET ATE 6.1.12°(1) 60 2666 6.lA ETHYL DICHLOROSILANE 4.3. 4 °([:I) X338 1183 4.3 -s- 3 + 8 ETHYLENE- 2. 5°([:I) 23 1962 3 ETHYLENE, u1p6, f:lix0uiic; xix-cix~u~.w~ 2. 7°([:I) 223 1038 3 ETHYLENE CHLOROHYDRIN (2-CHLOROETHA\OL) 6. 1.16°([:1) 60 1135 6.1 ETHYLENEDIAMINE 8.5:3°([:I) 83 1604 8+3 ETHYLENE DIBROMIDE (SYM.-DIBROMOETIIANE) 6.1.15°([:I) 60 1605 6.1 ETHYLENE DICHLORIDE: f:IHrta 1.2-DICHLOROE THANE ETHYLENE GLYCOL DIETHYL ETHER: f:IA. 1,2-DIETHOXYETHANE ETHYLENE GLYCOL MONOBUTYL ETHER 6, J.]3°(y) 60 2369 6.lA ETHYLENE GLYCOL MONOETHYL ETHER: [:IA. 2-E THOXYETHANOL ETHYLENE GLYCOL MONOETHYL ETHtR ACE TATE: f:IAErtE 2-ETHOXYETHYL ACETATE ETHYLENE GLYCOL MONOETHYL ETHER ACETATE: 3.3] 0 ( 1) 30 1189 3 ETHYLENEIMINE :1. 12° • 336 1185 3 -s- 6.1 ETHYLENE oxml:'.: rtaptitxov oxt rtiivw ixrto 10 a-cix axix-co oto~ai5to -cou iiv0pixxix xix-cii µii~ix 2, 4°(CT) 236 1041 3 -+-6.1 ETHYLENE OXIDE rtEptEXOV 7t!XVW IX7t0 10 O'tlX EXIX'tO IXAAtX OXL 1tiivc.u ixrtci 50 o-cix axix,:6 oto~ai◊to -cou iiv0pixxix 6°(CT) 236 1041 3 +6.1 XIX'ttX f.ltX~IX 2, ETHYLENE OXIDE 1tEptEXOV Oto~ai5to -cou tXv6pixxix: fjAErtE dto~ai1ito -cou iiv0pixxix 1tEpLEx ov ETHYLENE OXIDE 4°(CT) 236 1040 3 + 6.1 ETHYLENE OXIDE µa ii~w-co 2, ETHYL ETHER 3, 2 ° (ix) 33 1155 3 ~THYL paua-cci 6.1, 31 °(1X) 66 1649 6.1 ETHYL FORMATE 3, 3 o(~) 33 1190 3 2-ETHYL HELALDEHYDE 3, 31 °(1) 30 1191 3 2-ETHYLHEXYLAMINE 8, 53°(y) 83 2276 8 + 3 2-ETHYLHEXYL CHLOROFORMATE 6.1, l6°(f:I) 68 2748 6.1. + 8 ETHYLIDENE CHLORIDE: f:IAirta 1,1-DICHLOROE THANE ETHYLISOBUTYRATE 3, 3o(f3)' 33 2385 3 ETHYL LACTATE 3, 3} 0 ("'() 30 1192 3 ETHYL MERCAPT AN 3, l8°(f3) 336 2363 3 + 6.1 ETHYL METHACRYLATE 3, 3 0 (f3) 339 2277 3 ETHYL METHYL KETONE 3, 3 o(f:I) 33 1193 3 1362 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI .6EYTEPO) (ex) (13) (r) (o) (e) ETHYL ORTHOFORMATE 3, 31 °{r) 30 2524 3 ETHYL OXALATE 6.1, 13°(r) 60 2525 6.IA ETHYL PHENYL DICHLOROSILANE 8, 37 ° (13) 83 2435 8 + 3 1-ETHYLPIPERIDINE 3, 3 ° (13) 33 2386 3 ETHYL PROPRIONATE 3, 3 ° (13) 33 1195 3 ETHYL PROPYL ETHER 3, 3 ° (13) 33 2615 3 ETHYL SULPHIDE 3, 18 ° (13) 336 2375 3 + 6.1 ETHYLSULPHURIC ACID 8, 34 °(13) 80 2571 8 ETHYL TOLUIDINES 6.1, 12°(13) 60 2754 6.1 . ETHYL TRICHLOROSILANE 3, 21 °(cx) X338 1196 3 + 8 FERRIC CHLORIDE (IRON TRICHLORIDE) awopo (FECL) . FERRfc CHLORIDE (IRON TRICHLORIDE) uocx'tootcx 8, 22°(r) 80 1773 8 Auµomx 8, 5o(r) 80 2582 8 FLUOBORIC ACID, \JOCX'tOOtcxAuµcx'tCX tteptex,011 ox,t 1t<XIIW IX1t0 78 O't<X EXCl'tO xcx0cxpb ol;u (HBF,) 8, 8 ° (13) 80 1775 8 FLUOROBENZENE . 3, 3 ° (13) 33 2387 3 FLUOROPHOSPHORIC ACID, awopo 8, 10°(13) 80 1776 8 FLUOROSULPHONIC ACID 8, l0°(cx) 88 1777 8 FLUOROTOLUENES 3, 3 ° (13) 33 2388 3 FLUOROSILICIC ACID (HYDROFLUOSILICIC ACID) (H SIF) FeffiMXLDEHYDE, u6cx't06tcxAuµcx'tcx (n:.x,. FORMALIN), 8, 90(13) 80 1778 8 n:eptix,ouacx ox,t n:a11w cxn:o 5 O't<X excx'to FORMALDE HYDE, ttEptix,ouocx en:[a71c; oxt 1t<XIIW ixtto 35% µe0cx110A7] µe 071µe[o (lt\llXCflAE~Ewc; µe'tcxl;u 21 ° K l((ltL 55 ° K 8, 63°(r) 83 1198 8 + 3 µe 071µe[o cx11cxcpAel;ewc; n:a11w cxn:o 55 ° K 8. 63 °(r) 80 2209 8 FORMIC ACID ttEptix,0117t<XIIW (lt7t0 70 O't(lt EX<lt'tO xcx0cxpo ol;u 8,32°(13) 80 1779 8 FORMIC ACID 11:eptex,011 (lt1t0 50 µix,pt 70 (l't(lt EXIX'tO l((lt 8cxpo ol;u 8,32°(r) 80 1779 8 FUMARYL CHLORIDE 8,36 °(13) 80 1780 8 FURAN 3, 1 °(cx) 33 2389 3 FURFUAL(FURFURALDEHYDE) 3,32°(r) 30 1199 FURFURYLAMINE 8,53°{r) 83 2526 8+3 FURFURYL ALCOHOL 6.1,13°(r) 60 2874 6.lA Mlyµcx cxep[ou R 500 2, 4°(cx) 20 2602 Mlyµcx cxeplou R 502 2, 4°(cx) 20 1973 Mi1µcx cxepiou R 503 2, 6 °(cx) 20 2599 GLUCEROL <iAcpcx-MONOCHLORYDRIN (3-CHLOR OPROPANE-1,2-DIOL) 6.1,17°(1) 60 2689 6.lA GLYCIDALDEHYDE 6.1,13 °(13) 63 2622 6.1 + 3 HELIUM, urpo, l3cx0etac; l(IX'tCX<pul;ewc; 2, 7°(cx) 22 1963 HEPTANES • 3, 3°(13) 33 1206 3 HEPTENES 3, 3°(13) 33 2278 3 HEXACHLOROACETONE 6.l,17°(r) 60 2661 6.lA HEXACHLOROBENZENE 6.l,l 7°(y) 60 2729 6.lA HEXACHLOROBUTADIENE 6.1,l 7°(y) 60 2279 6.lA HEXACHLOROCYCLOPENTADIENE 6.l,17°(cx) 66 2646 6.1 HEXADECYLTRICHLOROSILANE 8,3 7 ° (13) 80 1781 8 HEXADIENES 3, 3°(13) 33 2458 3 HEXAFLUOROACETONE HYDRA TE 6.1,17°(13) 60 2552 6.1 HEXAFLUOROETHANE (R 116) 2, 5°(cx) 20 2193 HEXAFLUOROPHOSPHORIC ACID 8, 10 ° (13) 80 1782 8 HEXAFLUOROPROPYLENE (R 1216) 2, 3°(AT) 26 1858 + + HEXALDEHYDE 3,31 °(r} 30 1207 3 HEXAMETHYLENEDIAMINE 8,52°(y) 80 2280 8 HEXAMETHYLENEDIAMINE 6tcxAuµcx'tcx 8,53 ° (13) 80 1783 8 HEXAMETHYLEN E DIISOCYANATE 6.1,19°(!3) 60 2281 6.1 HEXAMETHYLENEIMINE 3,32 ° (13) 338 2493 3+8 HEXANES 3, 3°(13) 33 1208 3 I-HEXANE 3, 3°(13) 33 2370 3 HEXYLTIUCHLOROSILANE • . 8,37°(13) 80 1784 8 HYDRAZINE, \JOIX'tOOL<XAUµCX'tCX, ttEptEX,Oll'tClt OX,L 7t<XIIW IX1t0 64 (l't(lt EX<lt'tO HYDRAZINE 8,44 °(13) 86 2030 8 + 6.1 HYDRIODJC ACID, 6tcxMµcx'tcx 8, 5°(!3) 80 1787 8 HYDROBROMIC ACID, facx)..uµcx'tcx 8, 5°(!3) 80 1788 8 Yoporo11a118pcxxec;, uypol, xcx0cxpo[ ~ OE µlrµcx'tcx, 7t0\J OEII xcx0op[,011't1Xt 6tcxcpoprnxa o'to 1tcxpo11 ITcxpa't7Jµcx µe 071µEio cx11cxcpAil;ewc; X<X'tW cxn:b 21 ° K 3, 3°(13) 33 1203 3 .µE a71µEio CltllClt'f)AE!;Ewc; µe'tcxl;u 21 ° K )((XL 55 ° K 3,31 °(r} 30 1223 3 µe a71µEio cx11cxrp)..el;ewc; 1ta11w cx1to 55 ° K 3,32°(,) 30 1202 E<l>HMEPII: THI: KYBEPNHI:EtU: (TEYXOI: AEYTEPO) (o:) HYDROCHLORIC ACID, oto:Auµarnx , HYDROCYANIC ACID, uoo:·rnoto:Auµo:'to: 1taptexov'to: oxt 7tlXVW Ot7t0 20 O'tO: EXOt'tO xat0atpo o~u HYDROFLUORIC ACID xatt SULPHURIC ACID, µtyµo:'to: HYDROFLUORIC ACID ixwopo (HYDROGEN FLUO­ RIDE) HYDROFLUORIC ACID UOO:'tOOto:Auµo:'tO:, mptEXO\l'tO: 7tlX\IW 0:7t0 85 O'tO: EXO:'tO IXWOpo uopocp0optxo o~u HYDROFLUORIC ACID uoo:'tooto:Ai.iµ0t't0t, 1taptexov'to: 7tlX\IW 0:7t0 60 O'tO: EXOt'tO o:MIX oxt 7tlXVW Ot7t0 85 O'tOt axo:io ixvuopo uopocp0optxo o~u HYDROFLUORIC ACID UOOt'tOOto:Auµo:'to:, mptEXO\l'tO: ltlXVW 0:7t0 60 O'tO: EXOt'tO ixvuopo uopocp0optxo o~ii HYDROFLUOSILICIC ACID: ~Ae1ta FLUOSILICIC ACID HYDROGEN, uypo, ~at0atixc; xo:'to:<J,ii~awc; HYDROGEN, BROMIDE HYDROGEN, CHLORIDE HYDROGEN, FLUORIDE: ~Ae1ta HYDROFLUORIC ACID, ixvuopo HYDROGEN PEROXIDE, O'to:0ap07tOLTjµevo XO:l OE UOO:'tO­ Oto:Auµo:'tO: 1taptexo\l'to: 7tlXVW 0:ltO 60 O'tO: EXO:'tO HYDRO­ GEN PEROXIDE, O't0t8apo1tOL1jµevo HYDROGEN PEROXIDE, UOO:'tOOtOtAUµ(X'tO: 1taptEXO\l'tO: oxt xix'tw o:1to 20 a'to: axo:'to o:Mix oxt 1tixvw o:1to 60 a'to: axo:'to HYDROGEN PEROXIDE, HYDROGEN PEROXIDE, UOOt'tOOtatAiiµat'tO: 1taptexov't0t oxt XIX'tW 0:7t0 8 O'tOt EXO:'tO O:MIX XIX'tW 0:7t0 20 O'tO: EXOt'tO HYDROGEN PEROXIDE, HYDROGEN SULPHIDE, HYDROGEN SULPHIDES, UOO:'tOOto:Aiiµo:'tO: 7t0\J oav xo: 6opt~O\l't0:l Otatcpopmxix O'tO 1to:pov Tio:piXp'tljµO: HYDROQUINONE ~~'to:-HYDROXYBUTYRALDEHYDE: ~Ae1ta ALDOL HYDROXYLAMINE SULPHATE HYPOCHLORITE, oto:Aiiµat'to: 1taptexov't0t oxt Atyoupo 0:7t0 16 O'tO: EXOt'tO Oto:0eotµTj xAwptv71 HYPOCHLORITE, oto:Aiiµo:'to: 1taptexov't0t 1tixvw 0t1to 5 O'tO: EXOt'tO o:llix XIX'tW Ot7t0 16 O'tOt EXOt'tO Oto:0eotµTj X Awptv71 3,3'-IMINO-BIS-PROPYLAMINE: ~A. BIS-'-AMINOPROPYLAMINE IRON PENTACARBONYL IRON TRICHLORIDE: ~Ae1ta FERRIC CHLORIDE ISOAMYL FORMATE ISOBUTANE ISOBUTANOL: ~A. ISUBUTYL ALCOHOL ISOBUTENE: ~A. ISOBUTYLENE ISOBUTYL ACETATE ISOBUTYL ACRYLATE ISOBUTYL ALCOHOL (ISOBUTANOL) ISOBUTYLAMINE ISOBUTYLENE (ISOBUTENE) ISOBUTYLENE TRIMER: ~H1ta TRIISOBUTYLENE ISOBUTYL FORMATE ISOBUTYLISOBUTYRATE ISOBUTYLISOCYANATE ISOBUTYL METHACRYLATE ISOBUTYL PROPIONATE ISOBUTYRALDEHYDE ISOBUTYRIC ACID ISOBUTYRIC ANHYDRIDE ISOBUTYRONITRILE ISOBUTYRYL CHLORIDE ISOCY AN A TES, fao;).i,µ(i'to:, µa 071µato o:vo:cpAe~awc; xli'tw 0:7t0 21 °K ISOCYANATOBENZOTRIFLUORIDES 3-ISOCYANATOMETHYL-3,5, 5- TRIMETHYLCYC­ LOHEXYL ISOCYANATE: ~Ae1ta ISOPHORONE DIISOCYANATE ISODODECANE: ~A. PENT AMETHYLHEPT ANE ISOPENTANE 8, 5 °(~) 6.1, 2° 8, 7°(0:) 8, 6° 8, 6° 8, 7°(0:) 8, 7°(~) 2, 7°(~) 2, 3°(AT) ·2, 5°(AT) 5.1, 1 ° 8,62°(~) 8,62°(~) 2, 3°(BT) 8,45°(r) 6.1,}'1.o(r) 8,27°(r) 8,61 °(~) · 8,61 °(r) 6.1, 3° 3, 31 °(r) 2, 3°(~) 3, 3°(~) 3,31°(y) 3, 31 °(r) 3, 22°(~) 2, 3°(~) 3, 3°(~) 3, 3} 0 (r} 3, 14°(~) 3, 31 °(r) 3,31°(1) 3, 3°(~) 8, 32°(1) 8, 32°(1) 3, 11 °(~) 3, 25°(~) 3, 14°(~) 6.1, 18°(~) 3. 1 °(o:) (r) 80 663 886 886 886 886 886 223 286 286 559 85 85 236 80 60 80 85 85 663 30 23 33 39 30 338 23 33 30 336 39 30 33 80 80 336 338 336 , 60 33 (o) 1789 1613 1786 1052 1790 1790 1790 1966 1048 1050 2015 2014 2984 1053 1719 2662 2865 1791 1791 1994 1109 1969 1213 2527 1212 1214 1055 2393 2528 2486 2283 2394 2045 2595 2530 2284 2395. 2478 2285 1265 1363 (a) 8 6.1 + 3 8 + 6.1 8 + 6.1 8 + 6.1 8 + 6.1 8 + 6.1 + + 8 + 6.1 8 + 6.1 5 8 + 5 8+5 3 + 6.1 8 6.lA 8 8 8 6.1 + 3 3 3 3 3 3 3 + 8 3 3 3 3 + 6.1 3 3 3 8 8 3 + 6.1 3+8 3 + 6.1 6.1 3 1364 ECl>HMEPII THI KYBEPNHIEQI (TEYXOI 4EYTEPO) (oc) ((3) (r) (6) (e) ISOPHORONEDIAMINE 8, 53°(r) 80 2289 8 ISOPHORONE DIISOCYANATE (3- ISOCYANATOME THYL ~3,5,5- TRIMETHYLCYCLOHEXYL ISOCYA NATE) 6.1, 19°(r) 60 2290 6.lA ISOPRENE 3, 2°(oc) 339 1218 3 ISOPROPANOL (ISOPROPYL ALCOHOL) 3, 3°((3) 33 1219 3 ISOPROPENYL ACETATE 3, 3°((3). 33 2403 3 ISOPROPYL·ACETATE 3, 3°((3) 33 1220 3 ISOPROPYL ACID PHOSPHATE 8, 38°(r) 80 1793 8 ISOPROPYL ALCOHOL: (31,. .. ISOPROPANOL ISOPRO PYLAMINE 3, 22 °(cx) 338 1221 3+8 ISOPROPYLBENZENE: (31,.. CUMENE ISOPROPYL BUTYRANE 3, 3°((3) 33 2405 3 ISOPROPYCHLORIDE: (31,.. 2-CHLOROPROPANE ISOPROPYL CUMYL HYDROPEROXIDE: ~"· DIISOP ROPYLBENZENE HYDROPEROXIDE ISOPROPYLE THYLENE: (31,.. 3-METHYL-I-BUTENE ISOPROPYL ISOBUTYRA TE 3, 3°((3) 33 2406 3 ISOPROPYLISOCYANATE 3, l4°(oc) 336 2483 3 + 6.1 ISOPROPYL NITRATE 3, 3°((3) 33 1222 3 ISOPROPYL PROPIONATE 3, 3°((3) 33 2409 3 KRYPTON, uypo, (3oc9eLoec; XO('t0(4U!;Tjc; 2, 7°(oc) 22 1970 LEAD ACETATE 6.1, 62°(r) 60 1616 6.lA LEAD ALKYLS f!E OCAOYOVOfJ.EIIE<; opyocvLXE<; E\IWOEL<;, f!lr f!OC'tOC 6.1, 31 °(oc) 66 1649 6.1 LEAD evwaEL<;, 1toti oev xoc9opi~oll'tOCL OLoccpopE,LXoe, • a,o 1toc pov Ilocpdep'tTjfJ.OC 6.1, o2°(r) 60 2291 6.lA LEAD SULPHATE 7tEpLEXOV 3 O'tOC EXOC'tO ~ 7tEpLoao,Epoc EAEU9epoc 9et"ixo o!;u 8, 23°((3) 80 1794 8 LITHIUM HYDROXIDE 8, 41 °((3) 80 2680 8 MAGNESIUM ARSENATE 6.1, 51 °((3) 60 1622 6.1 MALEIC ANHYDRIDE 8, 31 °(y) 80 2215 8 MALONONITRILE 6.1, 12°((3) 60 2647 6.1 p-METHANYL HYDROPEROXIDE f!E 1tEpLEX'tLXO't7l'tOC uopo1eepo!;eLoiou ILTJ u1tep(3ocivouaoc 'tO 95 o,oc exoc,6 5.2, 14° 539 2125 5 MERCAPTOETHANOL (THIOGL YCOL) 6.1 20°((3) 60 2966 6.1 MERCURIC CHLORIDE 6.1, 52°((3) 60 1624 6.1 MERCURY ACETATE 6.1, 52°((3) 60 1629 6.1 MESITYLENE (1,3,5-TRIMETHYL- BENZENE) 3, 31 °(r) 30 2325 3 MESITYL OXIDE 3,31°(1) 30 1229 3 METHACRYLALDEHYDE 3,17°((3) 336 2396 3 + 6.1 RETHACRYLIC ACID 8, 32°(r) 89 2531 8 METHALLYL ALCOHOL 3, 31 °(r) 30 2614 3 METHANE, urpo (3oc9etdec; XOC'tOC4u!;ewc; 2, 7°((3) 223 1972 3 METHANOL (METHYL ALCOHOL) 3, 17°((3) 336 1230 3 + 6.1 METHOXYBUTYL ACETATE, (31,.. BUTUXYL 4- ME THOXY-4-METHYLPENTAN-2-ONE 3,31°(1) 30 2293 3 METHOXYETHANOL 3, 31 °(r) 30 1188 • 3 METHOXYMETHYLISOCYNATE 3, l4°(oc) 336 2605 3-+- 6.1 METHYL ACETATE 3, 3°((3) 33 1231 3 METHYL ACRYLATE 3, 3°((3) 339 1919 3 METHYLAL: (31,.. DIMETHOXYMETHANE METHYL ALCOHOL: (31,.. METHANOL METHYL ALLYL CHLORIDE 3, 3°(~) 33 2554 3 METHYLAMINE, oevu6p7J 2, 3°(BT) 236 1061 -+- + METHYLAMINE, UOOt'tOOLOCAUfJ.OC'tOC fJ,E OTjfJ.ELO (3p0tOfJ.OU OXL 7CO(\IW Ot7CO 3 5 ° K 3, 22°(oc) 338 1235 3+8 !LE CJTjfldO (3pocaflOU 1tde11w oc1to 35 ° K 3, 22 ° ((3) 338 1235 3-+-8 METHYL AMYL ACETATE 3, 31 °{r) 30 1233 3 METHYL AMYL ALCOHOL (METHYL ISOBUTYL CARBINOL) 3,31°(1) 30 2053 3 N-METHYLANILINE 6.1, 11°(1) 60 2294 6.lA METHYL BROMIDE 2, 3°(AT) 26 1062 6.1 METHYL BROMOACETATE 6.1, 16°((3) 63 2643 6.1 + 3 3-METHYL BUT AN-2-ONE 3, 3°((3) 33 2397 3 I-METHYL-I-BUTENE 3, 1 0 {0t) 33' 2459 3 3-METHYL-1-BUTENE (ISOPROPYLETHYLENE) 3, lo(Ot) 33 2561 3 2-METHYL-2-BUTENE 3, 2 0 ((3) 33 2460 3 METHYL TERT - BUTYL ETHER 3, 30((3) 33 2398 3 METHYL BUTYRATE 3, 3 0 ((3) 33 1237 3 METHYL CHLORIDE 2, 3°(BT) 236 1063 • 3 + 6.1 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) 1365 (o:) (~) (y) (6) (E) METHYL CHLOROACETATE 6.1, 16°(~) 63 2295 6.1 ... 3 METHYL CHLOROFORMATE 3, '16°(0:) 336 1238 3 -+- 6.1 METHYL CHLOROMETHYL ETHER 3, 16°(~) 336 1239 3 + 6.1 METHYLCYCLOHEXANE 3, 3 o{~) 33 2296 3 METHYLCYCLOHEXANONE 3, 31 °{y) ·30 2297 3 METHYLCYCLOPENTANE 3, 3 o(~) 33 2298 3 METHYL DICHLOROACETATE 6.1, l6°(y) 60 2299 6.iA METHYLDICHLOROSILANE 4.3, 40(~) X338 1242 4.3 ... 3 + 8 METHYLENE BROMIDE (DIBROMOMETHANE) 6.1, l5°(y) 60 2664 6.lA METHYLENE CHLORIDE (DICHLOROMETHANE) 6.1, 15°(y) 60 1593 6.lA 5-METHYL-5-ETHYL PYRIDINE 6.1, 11 °{y) 60 2300 6.lA METHYL FORMATE 3, 1 o(o:) 33 1243 .3 2-METHYLFURAN 3, 3 o(~) 33 2301 3 5-METHYLHEXAN-2-0NE 3, 31 °(y) 30 2302 3 METHYLHYDRAZINE 3, 23°(0:) 338 1244 3 + 8 METHYL IODIDE 6.1, 15°(~) 60 2644 6.1 METHYL ISOBUTYL CARBINOL: ~A. METHYL AMYL ALCOHOL METHYL ISOBUTYL KETONE 3, 3 o(~) 33 1245 3 METHYL ISOPROPYL BENZENES: ~Ai1ta CYMENES METHYLISOTHIOCYANATE 6.1, 20°(-y) .63 2477 6.lA + 3 METHYLISOVALERATE 3, 3 o(~) 33 2400 3 METHYL MERCAPTAN 2, 3°(BT) 236 1064 6.1. + 3 METHYL METHACRYLATE 3, 30°(~) 339 1247 3 METHYLMORPHOLINES µ.a 01J(J-Eio 0:110:rp>..ttu..ic; xcx,w o:1to 21 ° K 3, 22°(~) 338 2535 3 + 8 µ.a 01J(J-ELO 0:110:rp>..itawc; 21 ° K xo:t 1tcx11w 8, 53°(~) 83 2535 8 + 3 METHYL ORTHOSILICATE (TETRAMETHOXYSI .LANE) 3, 17°(0:) 336 2606 3 + 6.1 METHYLPENTADIENES 3, 3 o(~) 33 2461 3 3-METHYL-2-PENTENE-4-YNE-l-OI: ~Ai1ta 1-PENTOL METHYLPHENYLDICHLOROSILANE 8, 37°(~) 83 2437 8 -+- 3 I-METHYL PIPERIDINE 3, 3 o(~) 33 2399 3 METHYL PROPIONATE 3, 3 o(~) 33 1248 3 METHYL PROPYL ETHER 3, 20(~) 33 2612 3 METHYL PROPYL KETONE 3, 3 o(~) 33 1249 3 METHYLPIRIDINES: ~A. PICOLINES cx>..rpo:-METHYLSTYRENE 3, 31 °{y) 30 2303. 3 METHYLTETRAHYDROFURAN 3, 3 o(~) 33 2536 3 METHYL TRICHLOROACETATE 6.1, l6°(y) 60 2533 6.lA METHYL TRICHLOROSILANE 3, 21 °(ot} X338 1250 3 + 8. 2-METHYL VALEHALDEH '\: LJE :3. 3 V ([1) 33 2367 3 2-METHYL VINYL ETHER 2. 3°(WT) 236 . 1087 -+--+ 2-METHYL VINYL KETONE :1. 3 0/~) 339 1251 ·3 Miyµo:,o: Fl, F2 X(Xt F3 2. ,1°(,x) 20 1078 Miyµ.o:,:a; 1, 3 BUTADIENE XIXt uopoyovo:v0p&.xwv 2. ..J. o(y) 239 1010 ..,.. ..,.. Miyµ.o:,:a; XIXUO'ttx71c; 0600:c; XIXt O~UO(J-EVTjc; o:a~ioi:ou: ~AEJtE SODA LIME Miyµo:,:o: uopoyovo:v0p&.xwv (uypoitOLTjfLE\10 o:epto) (Miyµ.o:m A, AO, Al, B XIXt f) 2. 11 C (~) 23 1965 3 Miyµ.o:-co: METHYLACETYLENE xo:t PROPADIENE fl-E uopoyov&.v0po:xac; (Miyµo:,:o: P 1 XIXt P2) 2. 40(:y) 239 1060 3 Miyµo:,:o: ME.THYL BROMIDE xo:t CHLOROPICRIN ( uypo1tOtT]µi110 o:ipto) 2. 4°(AT) 26 158] -+-: Miyµo:,:o: METHYL CHLORIDE xo:t CHLOROPICRIN ( uypo1tot'Y]µ.e110 o:ipt0) 2. 4°/HT) 236 ]582 -+-: Miyµ.o:,:a; METHYL CHLORIDE xo:t METHYLENE CH LORIDE (uypo1tot'Y]µ.i110 o:ipt0) 2. 4°(BT) 236 1912 +: Miyµ.o:-co: SULPHURIC ACID xo:t 1t&.vw o:mi 30 a-co: Exo:,6 xo:0o:po •mptxo otu 8. 30(0:) 885 1796 8 Miyµ.o:-co: 0attXO\I otfoc; XIXL O'f L 7t(X\IW (X7tQ 30 Ot(X EXIXtO \lt'tptxo 8. 3 o(~) 88 1796 8 MOLYBDENUM PENTACHLORIDE (MoCL) 8. 22°(-y) 80 2508 8 MONOCHLOROACETIC ACID. mpEo: ~A. t':HLOROA CETIC ACID, OtEpao MONOCHLOROACETIC ACID OE AUWf.lE\ITj X0:1:(XO'tlXOTj: ~AE7tE CHLOROACETIC ACID. OE AUWf.lEIIT] XIX'tll.01:IXOTJ MONOCHLOROACETIC ACID oto:Mµo:to:: ~A. Cl-lLO ROACETIC ACID, oto:Aup./x-co:: MONOCHLOROACETONITRILE 6.1. 11 °/~) 60 2668 6.1 MONOCHLOROANILINES. uypo 6.1. 12°([3\ 60 2019 6. l 1366 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI AEYTEPO) (ex) (~) (rl (o) (E) MONOCHLOROANILINES, a·np.6 6.1. 12 °(~) 60 2018 6.1 MONONITROANILINES, 6.1. 12 °(~) 60 1661 6.1 MONONITROTOLUENES, 6.1. 12°(~) 60 1664 6.1 MORPHOLINE 3 .. 31 °(1) 30 2054 3 NAPHTHALENE oa Auwµiv71 xcx1:cxa1:cxo71 4.1, 11°(1) 44 2304 4.1 '31j1:cx NAPHTHALAMINE 6.1. 12°(8) 60 1650 6.1 NATURAL GAS ( cpuotxo cxipt0) u1p6. ~cx0auic,; xcx1:cx4u!;71,; 2. 80(~) 223 1972 3 NEON, u1p6, ~cx0atcx,; xcx1:cx4u!;71,; 2. 7°(cx) 22 1913 NICKEL TETRA V ARBONYL 6.L 30 663 1259 6,1-+-3 NICOTINE SYLPHATE 6.1. 0 77°(~) 60 1658 6.1 NITRATING ACID µiyµcx1:cx 8. 3 0({1} 80 1826 8 NITRIC ACID epu0µ6,; cx1:µ6,; 8. 2°(cx} 856 2032 8 NITRIC ACID 1taptixov 1tcxvw 0t1t6 70 01:cx EX0t1:6 xcx0cxp6 Vt'tptXO o!;u 8. 2 °(cx) 885 203'2 8 NITRIC ACID, µiyµcxw µE 0etYx6 o!;u: ~AE1te Miyµcx1:cx 0aLYxou o!;fo,; xcxt Vt'tptxou o!;fo,; NITROANISOLES 6.1. 12o(r) 60 2730 6.lA NITROBENZENE 6.1. 12°{~) 60 1662 6.1 NITROBENZENESULPHONIC ACID 8. 34°({1} 80 2305 8 NITROBENZOTRIFLUORIDES 6.1. 12°(~) 60 2306 6.1 NITROBROMOBENZENES 6.1. 12°/y) 60 2732 6.lA NITROCELLULOSE otcxAuµcx1:cx: ~A. COLLODIONS. otcx Mµcx1:cx 3-NITR0-4-CHLOROBENZOTRI-FLUORIDE 6.1. 12°(~) 60 2307 6.1 NITROCRESOLS 6.1. 12°(1) 60 2446 6.lA NITROETHANE 3. :; I 0(1) 30 2842 3 NITROGEN urpo, ~cx0atcx,; XIX't0t4u!;aw,; 2. 7°(cx) 22 1977 NITROGEN DIOXIDE NOl\/(NITROGEN PEROXIDE. NITROGEN TETROXIDE 2 04) 2. 3°(AT) 265 1067 5-+-6.1 NITROPHENOLS 6.1. L2°(y) 60 1663 6.lA NITROPROPANES 3. 31 °(1) 30 2608 3 NITROSYLSULPHURIC ACID 8. l o ((3) 88 2308 8 NITROUS OXIDE N.,O 2. 3°(cx) 25 1070 s NITROUS OXIDE N;o.~cx0atcx,; x0(1:cx4v!;aw,; 2. 7°(cx) 225 2201 5 NITROXYLENES 6.1. 12 °((1) 60 1665 6.1 NONANE 3, 31 °(r} 30 1920 3 NONYLTRICHLOROSILANE 8. 37°((3) 80 1799 8 OCTADECYL TRICHLOROSILANE 8 .. 37°(~) 80 1800 8 OCTADIENES µe aTjµEio cxvcxcpAi!;aw,; xcx,w 0(1tO 21 ° K 3, 3 o(~) 33 2309 3 µE 071µaio cxvcxcp1.i!;aw,; µa,O(!;u 21 ° K xcxt 55 ° K 3, 31 °(r) 30 2309 3 OCTAFLUOROCYCLOBUTANE (RC 318) 2, 3 ° (cx) 20 1976 OCTANES 3, 3 0((3) 33 1262 3 OCTYLTRICHLOROSILANE 8, 37°((3) 83 1801 8 + 3 OLEUM (Ilupo0atYx6 o!;u) 8, 1 °(cx) X886 1831 8 + 6.1 OXALATES, OtO(Au,cx a,o vepo 6.1, 67°(,) 60 2449 • 6.lA 0::'.1TONO, u1p6, ~cx0aicx,; xcx,cx4u!;aw,; 2, 7°(cx) 225 1073 5 PAINTS (xpwµcx,cx) µe 011µeio cxvcxcpAi!;Ew,; xcx,w cx1t6 21 ° K 3, 5 33 1263 3 µe aTjµeio cxvcxcp)..i!;aw,; µa,cx!;u 21 ° K XO(t 5 5 ° K 3, 31(,).:!:/ 30 1263 3 µe 01jµEio O(VCX<pAe!;aw,; 1tCXVW CX1t0 55 ° K 3, 32(,).!/ 30 1263 PARALDEHYDE 3, 31 °('y) 30 1264 3 PENTACHLOROETHANE 6.1, 15°(~) 60 1669 6.1 PENTAMETHYLHEPTANE (ISODODECANE) 3, 31 °(r) 30 2286 3 PENTAN-2, 4-DIONE (ACETYL ACETON) 3, 31 °(r} 30 2310 3 PENT ANE; XCXVOVtXTj 3, 20(~) 33 1265 3 1--:-PENTEN E: ~AE1tE AMYLENE, l(O(VO\ltXTj 1-PENTOL (3-METHYL-2-PENTENE-4YNE-1-0l) 8, 66°(~) 80 2705 8 .:!:/BAE1tE, oµw,;, :EHMEIQ:EH 't1jc; 1t0tpO(rpcxcpou t:,,. 'tOU 1tEpt6wptcxxou 2301. PERCHLORIC ACID, UOO('tOOLO(Atiµcx,cx 1taptixo11,cx 1tcx11w cx1to 5 o a,cx axcx,o illcx oy. t 1tcx11w cx1to 7 2. 5 a,cx excx,o xcx0cxp6 o!;u (HCIO ) PERCHLORIC ACTD, u6cxwotO(Auµcx,cx 1taptixo11,cx 1tdt11w 5.1, 30 558 1873 5 + 8 CX1t0 50 O'tOt EXIX'tO xcx0cxp6 o!;u (H CIO ) PERCHLOROETHYLENE: ~Ai1ta TETRACHLOROE 8, 40 85 1802 8 THYLENE PERCHLOROMETHYLMERCAPTAN 6.1, l6°(cx) 66 1670 6.1 PESTICIDES (~t~cx11tox,611cx) op1cxvocpwacpoptxic; avwaatc;- 6.1, 71 °(cx) 66 2783 6.1 aupaiit 6.1, 71 °((3) 60 2783 6.1 6.1, 71 °(r} 60 2783 6.1 uypiit, µe 01jµEio cxvcxipAi!;awc; xcx,w cx1t6 21 ° K 3, 19° 336 2784 3 + 6.1 60 33 2784 3 + 6.lA E<DHMEPII: THI: KYBEPNHI:EQI: (TEYXOI: AEYTEPO) 1367 ( ix) (~) (y) (o) (e) Ujpot, µe OTJ!J-Eio IX\IIX(j)AE;uu; !J-E'tot;u 21 ° K XIXL 55 ° K 6.1, 71 °(ot) 663 3017 6.1 + 3 71 o(~) 63 3017 6.1 + 3 71°(j) 63 3017 6.lA + 3 PESTICIDES, XAWpLaµivm uopoyovdtv6potxe;, aupedt 6.1, 72°(0t) 66 2761 6.1 72 °(~) 60 2761 6.1 72°(j} 60 2761 6.1 u1pdt, µe aTjµeto otvotq,Ai;ew; Xot'tW oi1to 21 ° K 3, 19° 336 2762 3 + 6.1 60 33 2762 3 + 6.lA u1pdt, µe OTJµeto otvotq,Ae;ew; 21 °K - 55°K 6.1, 72°(ot) 663 2995 6.1 + 3 72°(~) 63 2995 6.1 + 3 720(,) 63 2995 6.lA + 3 u1pdt, ot(j)AEX'tot 71 µe aTjµdo otvixq,U;ew; 1tdtvw ot1to 5 5 ° K 6.1, 72°(ix) 66 2996 6.1 72 °(~) 60 2996 6.1 72°(j} 60 2996 6.lA PESTICIDES, XAwpo-q,otwo;uo;Lxot 1totpdt1w1ot aupedt • 6,1, 73°(ot) 66 2765 6.1 73 °(~) 60 2765 6.1 73°(y) 60 2765 6.lA u1pot µe aTjµeio otvotq,Ai;ew; xot'tW ot1to 21 ° K 3, 19° 336 2766 3 + 6.1 60 • 33 2766 3 + 6.lA Ujpot, µe OTjµEio IX\IIX(j)AE;ew; !J.E'tot;u 21 °K XIXL 55°K 6,1, 73°(ot) 663 2999 6.1 + 3 73°(~) 63 2999 6.1 + 3 73°(j} 63 2999 6.lA+-3 u1pot, ot(j)AEX'tot 71 µe OT}µeto otvotq,Ai;ew; 1tdtvw ot1to 5 5 ° K 6.1, 73°(ot) 66 3000 6.1 73 °(~) 60 3000 6.1 73°(,) 60 3000 6.lA PESTICIDES, CARBAMATES aupedt 6.1, 76°(ot) . 66 2757 6.1 • 76°(~) 60 2757 6.1 76o(r) 60 2757 6.lA u1pdt, µe OTjµeio otvotq,Ai;ew; Xot'tW ot1to 21 ° K 3, 19° 336 2758 3 + 6.1 60 33 2758 3+6.lA Ujpot, µe OTJ!J-Elo IX\IIX(j)AE;ew; !J-E'tot;u 21 ° K XIXL 55 ° K 6.1, 76°{ot) 663 2991 6.1 + 3 76°(~) 63 2991 6.1 + 3 76°{r) 63 2991 6.lA + 3 u1pdt, ot(j)AEX'tot 71 µe aTjµeto otvotq,Ai;ew; 1tdtvw ot1to 55 ° K 6.1, 76°(ot) 66 2992 6.1 76°(~) 60. 2992 6.1 76°(,) 60 2992 6.1.k PESTICIDES, THIOCARBAMATES 6.1, 76 °(ot) 66 2771 6.1 76°(~) 60 2771 6.1 76o(r) 60 2771 6.lA u1pdt, µe OTjµdo otvotq,Ai;ew; Xot'tW otito 21 ° K 3, 19° 336 2772 3 + 6.1 60 33 2772 3 + 6.lA u1pdt, µe OT}µeto otvotq,Ai;ew; µnot;i> 21 ° K xotL 55 ° K 6.1, 16°(ot} 663 3005 6.1 + 3 76°(~) 63 3005 6.1 + 3 76 o(r) 63 3005 6.lA + 3 u1pot, otq,AeX'tot 71 µa aTjµdo otvotq,Ai;aw; 1tdtvw ot1to 55 ° K 6.1, 76°(ix) 66 3006 6.1 76°(~) 60 3006 6.1 76°(r) 60 3006 6.lA PESTICIDES, ORGANOTIN COMPOUNDS aupadt 6.1, 79°(ot} 66 2786 6.1 79°(~) 60 2786. 6.1 79°(,) 60 2786 6.lA u1pdt, µa <J7Jµeio otvotq,Ai;ew; Xot'tW ot1to 21 ° K 3, 19° 336 2787 3 + 6.1 60 53 2787 3 + 6.lA Ujpot, µa aTjµeto IX\IIX(j)AE;ew; !J-E'tot;u 21 ° K XIXL 55 ° K 6.1, 79°(ot} 663 3019 6.1 + 3 79°(~) 63 3019 6.1 + 3 79°(r} 63 3019 6.lA + 3 u1pdt, otq,AeX'tot 71 µa OTJf.lEtO otvotq,Ai;aw; 1tdtvw ot1to 55 ° K 6.1, 79°(ot) 66 3020 6.1 79°(~) 60 3020 6.1 79o(r) 60 3020 6.lA PESTICIDES, 1totpdt1w1ot 'tou· BIPYRIDYL 6.1, 82°{ot) 66 2781 6.1 82°(~) 60 2781 6.1 82°(r) 60 2781 6.lA u1pdt, µa aTjµeio IX\lot(j)AE;ew; xot'tw ot1to 21 ° K 3, 19° 336 2782 3 + 6.1 60 33 2782 3 + 6.lA urpdt, µa <J7Jµdo IX\IIX(j)AE;ew; f.lE'tot;u 21 ° K- Xott 5 5 ° K 6.1, 82°(ot} 663 3015 6.1 + 3 82 °{~) 63 3015 6.1 + 3 82°(r) 63 3015 6.lA + 3 1368 E(J)HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) (at) (~) (r) (6) {E) uypdt, dtcpAEX'tot 71 µE 071µEio oi:voi:cpW;uu.:; 1tdt11w oi:1to 5 5 ° K 6.1, 82°(ot) 66 3016 6.1 82 °{~) 60 3016 6.1 82°(,) 60 3016 6.lA PESTICIDES, ot\lopyotvE.:; E\IWOEt<; otpaE\ltXOU anpEOt 6.1, 84°(ot) 66 2759 6.1 84°(~) 60 2759 6.1 84°(,) 60 2759 6.lA uypdt, µE 07JµEio oi:votcpAi/;Ew<; xdt,w oi:1to 21 ° K • 3, 19° 336 2760 3 + 6.1 60 33 2760 3 + 6.lA uypdt, µE OTjµtio ot\lot(j)AE/;Ew<; µE,ot/;u 21 ° K Xott 5 5 ° K 6.1, 84°(ot) 663 2993 6.1 + 3 84 °(~) 63 2993 6.1 + 3 84°(,) 63 2993 6.lA + 3 u1pdt, dtcpAEX'tot 71 µE 071µEio oi:votcpAi/;Ew<; 1tdt11w ot1to 5 5 ° K 6.1, 84°(ot) 66 2994 6.1 84°(~) 60 2994 6.1 84°(,) 60 2994 6.lA PESTICIDES, ot\lOpj'ot\lE<; E\IWOEt<; u6poi:yupou O'tEpEOt 6.1, 86°(ot) 66 2777 6.1 86°(~) 60 2777 6.1 86°(,) 60 2777 6.lA u1pdt, µE 071µEio oi:votcpAi/;Ew<; xdt,w oi:1to 21 ° K 3, 19° 336 2778 3 + 6.1 60 33 2778 3 + 6.lA uypdt, µE 07JµEio ot\lotcpAE/;Ew<; µE,ot/;u 21 ° K Xott 5 5 ° K 6.1, 86°(ot} 663 3011 6.1 + 3 86°(~) 63 3011 6.1 + 3 86°(,) 63 3011 6.lA + 3 u1pdt, dtcpAEX'tot 71 µE 07JµEio oi:11otcpAi/;Ew<; 1tdt11w oi:1to 55 ° K 6.1, 86°(ot} 66 3012 6.1 86°(~) 60 3012 . 6.1 60 3012 6.lA PESTICIDES, ot\lOpj'ot\lE<; E\IWOEt<; XotAXOU O'tEpEOt 6.1, 87°(ot} 66 2775 6.1 87 °(~) 60 2775 6.1 87°(,) 60 2775 6.lA ·u,pdt, µE 071µEio oi:votcpAi/;Ew<; xdt,w oi:1to 21 ° K 3, 19° 336 2776 3 + 6.1 60 33 2776 3 + 6.lA uypdt, µE 071µEio ot\lot(j)AE/;tw.:; µe,ot!;u 21 ° K Xott 5 5 ° K 6.1, 87°(ot) 663 3009 6.1 + 3 87°(~) 63 3009 6.1 + 3 87°(r} 63 3009 6.1A + 3 uypdt, dtcpAEX'tot 71 µE 071µEio oi:votcpAi/;Ew<; 1tdt11w ot1to 55 ° K 6.l,87°(oi:) 66 3010 6.1 87°(~) 60 3010 6.1 60 3010 6.lA PHENACYL BROMIDE (wµiyoi: - BROMOACE-TO PHENONE) PHENACYL CHLORIDE (wµi1oi: -CHLOROACETOP 6.1,17°(~) 60 2645 6.1 HENONE) 6.1,17°(~) 60 1697 6.1 PHENETIDINES 6.1,12°(,) 60 2311 6.lA PHENOL at Auwµi1171 xat,dtai:oi:071 6.1,13°(~) 68 2312 6.1 PHENOL 6totAuµoi:,oi: 6.1,13 °(~) 68 2821 6.1 PHENOSULPHONIC ACID, uypo 8,34°(~) 80 1803 8 PHENYLACETONITRILE: ~A. BENZYL CYANIDE PHENYLACETYL CHLORIDE 8,36°(~) 80 2577 8 PHENYLCARBYLAMINE CHLORIDE 6.1,l 7°(ot) 66 1672 6.1 PHENYL CHLORIDE: ~Ai1tE CHLOROBENZENE PHENYLCHLOROFORMATE 6.1,16°(~) 68 2746 6.1 + 8 PHENYLENEDIAMINES 6.1,12°(,) 60 1673 6.lA PHENYLHYDRAZINE 6.1,12°(~) 60 2572 6.1 PHENYL ISOCYANATE 6.1,18°(~) 63 2487 6.1 + 3 PHENYL METHYL ETHER (ANISOLE) 3,31 °(r} 30 2222 3 PHENYL PHOSPHORUS DICHLORIDE 8,36°(~) 80 2798 8 PHENYLTHIOPHOSPHORYL DICHLORIDE 8,36°(~) 80 2799 8 PHENYLTRICHLOROSILANE 8,37°(~) 80 1804 8 PHOSGENE 2, 3°(AT) 266 1076 5 + 6.1 PHOSPHORIC ACID 8,11 °(r} 80 1805 8 PHOSPHORIC ACID, dtvu6po: ~A£1tE PHOSPHOROUS PENTOXIDE PHOSPHOROUS, )..wxo.:; & xhptvo.:; OE Auwµi1171 xoi:,dto,oi:071 4.2, 1 ° 446 2447 4.2 O'tEpEO<; 4.2, 1 ° 46 1381 4.2 PHOSPHOROUS OXYBROMIDE (POBR3) 8,22°(~) 80 1939 8 PHOSPHOROUS OXYBROMIDE (POBR~), Auwµivo.:; 8,22°(~) 80 2576 8 PHOSPHOROUS OXYCHLORIDE (PHO PHORYL CH- ~ LORIDE (POCL) 8,21 °(~} 80 1810 8 PHOSPHOROU§ PENT A CHLORIDE (PCL 5 ) 8,22°(~) 80 1806 8 F:HOSPHOROUS PENTASULPHIDE 4,1, 8° 40 1340 4.1 ' l>EK 104 ECJ>HMEPII THI KYBEPNHIEQI (TEYXOI dEYTEPO) 1369 (ix) (~) (y) (o) (e) PHOSPHOROUS PENTOXIDE (cpwacpopLxo o;u, dt11uopo) 8,27°(~) 80 1807 8 PHOSPHOROUS SESQUISULPHIDE 4.1, 8° 40 1341 4.1 PHOSPHOROUS TRIBROMIDE (PBR() 8,21 °{~) 80 1808 8 PHOSPHOROUS TRICHLORIDE (PC ) 8,21 °(~) 80 1809 8 PHOSPHORYL, CHLORIDE: ~Ai1te PlfOSPHORUS OXYCHLORIDE PHTHALIC ANYDRIDE 8,31 °{j) 80 2214 8 PICOLINES (METHYLPYRIDINES) 3,31 °{j) 30 2313 3 PINANE HYDROPERO~IDE (PINANYL HYDROPERO XIDE): ~Ai1te 2,6,6-TRIMETHYL NORPINANYL HYD RO PEROXIDE ixAcpot-PINENE 3,31°(1) 30 2368 3 PIPERAZINE: ~A. DIETHYLENEDIAMINE PIPERIDINE 3,22 °(~) 338 2401 3 + 8 PIV ALOYL CHLORIDE (TRIMETHYL ACETYL CHLO RIDE) 8,36°(~) 83 2438 8 + 3 POTASH LYE (5LiiAuµix): ~Ai1te POTASSIUM HYDRO XIDE (OLixAuµot'tot) POTASSIUM (Killw) 4.3, 1 ° (ot) X423 2257 4.3 POTASSIUM ARSENATE 6.1,51 °(~) 80 1677 6.1 POTASSIUM ARSENATE 6.1,51 °(~) 60 1678 6.1 POTASSIUM BIFLUORIDE 8,26°(~) 80 1811 8 + 6.1 POTASSIUM BISULPHATE, 1t0\) 1tEpLEJ(EL 3 O'tot EXot'tO 11 7tEpLaOO'tEpo EAEu6apo 6at'(xo o;u 8,23°(~) 80 2509 8 POTASSIUM CHLORATE, OLot~uµot'tot 5.1, 4°(ot) 50 2427 3 POTASSIUM FLUORIDE 6.1,65°(1)" 60 1812 6.lA POTASSIUM HYDROXIDE (Kcxua'tLXO KdtULo) 8,41 °(~) 80 1813 8 POTASSIUM HYDROXIDE, OLotAuµot'tot (0L0t1..uµot xcxUiou) 8,42°(~) 80 1814 8 POTASSIUM OXIDE 8,41 °(~) 80 2033 8 POTASSIUM SULPHIDE 1tEpLEJ(O\I OJ(L AL1onpo ot1to 30 O'tot EXot'tO 11apo xpua'totAAwaaw,;; 8,45°(~) 80 1847 8 POTASSIUM SULPHIDE uoot'toOLotAUµot'tot 8,45°{j) 80 1847 8 PRINTERS INKS, (µEAIXIIE<;;) µa OT)(J,ELO ot\1/XcpAe;w,;; XQt'tW 0t1t0 21 ° K 3, 5° 33 1210 3 µa O'lj(J,ELO otllotcpAe;ew,;; (lE'tot;u 21 ° K XotL 55 ° K 3, 31 ° (y).±./ 30 1210 3 µe OT)(J,ELO otllotcpAe;aw,;;. 1tlX\IW ot1t0 55 ° K 3, 32°(")').±./ 30 1210 PROPANE . 2, 3 o(~) 23 1973 3 N...:.PROPANOL, 'tEJ(IILXO 3, 3 o(~) 33 1274 3 PROPIONALDEHYDE 3, 30(~) 33 1275 3 PROPIONIC ACID 1taptEJ(O\I OJ(t AL1o'tepo ot1to 50 a'tot EXot'tO xix6otpo o;u 8, 32°(1) 80 1848 8 PROPIONIC ANHYDRIDE 8, 32°(1) 80 2496 8 PROPIONITRILE 3, 11 °(~) 336 2404 3 + 6.1 PROPIONYL CHLORIDE 3, 25°(~) 338 1815 3 -+- 8 PROPYL ACETATE 3, 3 o(~) 33 1276 3 N-PROPYLAMINE 3, 22°(~) 338 1277 3 -+- '8 N-PROPYLBENZENE 3, 31 °(1) 30 2364 3 PROPYL CHLORIDE: ~A. I-CHLOROPROPANE 3 PROPYLENE 2, 3 o(~) 23 1077 PROPYLENEDIAMINE 8, 53°(~) 83 2258 8 + 3 PROPYLENE DICHLORIDE 3, 3 o(~) 33 1279 3 PROPYLENEIMINE 3, 12°· 336 1921 3 + 6.1 PROPYLENE OXIDE 3, 2 ° (ot) 33 1280 3 PROPYLENE TETRAMER: ~Ai1te TETRAPROPYLENE .±./BH1te, oµw,;;, I:HMEIQI:H 't'lj<;; 1totpotypdtcpou tJ. 'tOU 1tEpt6wptotXOU 2301. PROPYLE TRIMER: ~H1te TRIPROPYLENE PROPYL FORMATES 3, 3 o(~) 33 1281 3 PROPYL ISOCYANATE, xcx11011txo 3, l4°(ot) 336 2482 3 + 6.1 PROPYL MERCAPTAN 3, 3 o(~) 33 2402 3 PROPYL TRICHLOROSILANE 8, 37°(~) 83 1816 8 -+- 3 PYRIDINE 3, 15°(~) 3l6 1282 3 -+- 6.1 PYROSULPHURYL CHLORIDE (S20 5CL2) 8, 21 °(~) 80 1817 8 PYRROLIDINE 3, 22°(~) 338 1922 3 + 8 QUINOLINE 6,1, 12°(1) 60 2656 6.lA R 12: ~A. DICHLORODIFLUOROMETHANE R 12BI: ~A. BROMOCHLORODIFLUOROMETHANE R 13: ~A. CHLOROTRIFLUOROMETHANE R 13B1: BROMOTRIFLUOROMETHANE R 21: ~A. DICHLOROFLUOROMETHANE R 22: ~)... CHLORODIFLUOROME1HANE R 23: ~A. TRIFLUOROMETHANE R 114: ~A. 1,2-DICHLORO-l, 1,2-, 2- TETRAF LUOOROMETHANE 1370 E<l>HMEPII THI KYBEPNHIEQI (TEYXOI aEYTEPO) (ix) (~) (r) (o) (E) R ll5: ~).. CHLOROPENTAFLUOROETHANE R 116: ~).. HEXAFLUOROETHANE R 133ix: ~).. I-CHLORO-2,2,2-TRIFLUOROETHANE R 142~: ~).. I-CHLORO-I,I-DIFLUOROETHANE R 152ix: ~A. I,I-DIFLUOROETHANE R 500: Mirµoc IXEpiou R 500 R 502: ~A. Mi1µix IXEpiou R 502 R 503: ~A. Mirµix IXEpiou R 503 R 1113: ~).. TRIFLUOROCHLOROETHYLENE R 1216: ~).. HEXAFLUOROETHYLENE R 318: ~).. OCTAFLUOROCYCLOBYTANE RESINS (P711:[11E,;) OE Ol~UOTj OE EU(j)AEX'tlX urpoc µE OTj(LELO IX\IIX(j)AE!;Ew,; xdt,:w 1X1to 21 ° K 3, 5° 33 1866 3 (LE 071µEio IX\IIX(j)AE!;Ewi; (LE'tlX!;u 21 ° K XIXl 5 5 ° K 3,31 °(j).±/ 30 1866 3 µE 071µEio IX\IIX(j)AE!;Ewi; 1tdt11w 1X1to 5 5 ° K 3,32°(,).:t./ 30 1866 3 RESORCINOL 6.l.14o(r) 60 2876 6.lA SELENATES 6.1.55 °{1X) 66 2630 6.1 SELENIC ACID 8.ll 0 (ix)· 88 1905 8 SELENITE$ 6.1,55 °{1X) 66 2630 6.1 SELENIUM DISULPHIDE 6.1,55°(~) 60 2657 6.1 SELENIUM (LE'tlXMO 6.l.55°(r) 60 2658 6.lA SILICOCHLOROFORM: ~).. TRICHLOROSILANE SILICON TETRACHLORIDE (SiCL4) 8,21°(~) 80 1818 8 SODA LIME (Mij(LIX'tlX XIXUO'tlX~,; oooixi; XIXl IXO~fo,:71,;) 8,41°("'() 80 • 1907 8 SODA LYE: ~AE7tE SODIUM HYDROXIDE OllXAU(LIX'tlX SODIUM 4.3, 1 °(ix) X423 1428 4.3 SODIUM ALUMINATE, otixAuµix,:ix 8.42°(~) 80 1819 8 SODIUM ARSENITE 6.1,5 J 0 (~) 60 1685 6.1 SODIUM ARSENATE UOIX'tOOllXAU(LIX'tlX ,:o!;txdt 6.1,51 °(~) 60 1686 6.1 E7tl~AIX~~ 6.1,51 °(j) 60 1686 6.lA SODIUM BIFLUORIDE 8.26°(~) 80 2439 8 + 6.1 SODIUM BISULPHATE, UOIX'tOOllXAU(LIX'tlX 8, 6°(~) 80 2837 8 SODIUM BISULPHATE, 7tEplEX,O\I 3 O'tlX EXIX'tO ~ 7tEploOO'tEpo EAEullepo llettxo o!;u 8,23°(~). 80 1821 8 SODIUM CHLORATE, mpeo 5.L 4°(ix) 50 1495 5 SODIUM CHLORATE, OllXAU(LIX'tlX 5.1. 4o(r) 50 2428 5 SODIUM CHLORITE, otixAuµixi:ix 5.1, 4°(j) 50 1908 5 SODIUM FLUORIDE 6.1.65 °(j) 60 1690 6.lA SODIUM HYDROGEN SULPHIDE 1tou 1tEplEX,El o·;,,l At1oi:epo 0(7t() 2 5 01:IX EXOC'tO VE po xpUO'tlXMWOEW,; 8,45°(~) 80 2949 8 SODIUM HYDROXIDE (Kixuoi:tx~ oooix) 8,41 °(~) 80 1823 8 SODIUM HYDROXIDE Btix).uµixi:ix 8,42 °(~) 80 1824 8 SODIUM METHYLATE IXAXOALXOC OllXAU(LIX'tlX 3,24°(~) 338 1829 3-+-8 SODIUM OXIDE .. 8,41 °(~) 80 1825 8 SODIUM PENTACHLOROPHENATE 6.Ll 7°(~) 60 2567 6.1 SODIUM POTASSIUM xpdtµixi:ix 4, 3, 1 °(ix) X423 1422 4.3 SODIUM SULPHIDE, 1tEptix o11 OX,L AL1oi:epo ix1to 30 01:ix exix,:o VEpo xpuO'tlXMWOEW<; 8,45°(~) 80 1849 8 SODIUM SULPHIDE, UOIX'tOOLOCAU(LIX'tlX 8, 45°(r) 80 1849 8 STANNIG CHLORIDE, ocvuopo (SNCRAL) 8, 21 °(~) 80 1827 8 STANNIG CHLORIDE PENTAHYD TE (SNCL -5H 0 8, 22°{r) 80 2440 - 8 STYRENE tyINYLBENZENE) 3, 31 °{r) 39 2055 3 SULPHIDES, UOIX'tOOllXAU(LIX'tlX, µ71 1tpoooLOpl,O(LE\IIX OllX(j)O· pE'tlXOC O'tO 7t1Xpov Ilapdtp1:71µa 8, 45°(r) 80 1719 8 SULPHIR (!lEio) 4.1, 2°(0t) 40 1350 4.1 SULPHUR OE ).uwµi1171 xix1:dto1:ixo71 4.1, 2°(~) 44 2448 4.1 SULPHUR DIOXIDE 2, 3°(AT) 26 1079 -+- ... SULPHUR HEXAFLUORIDE 2, 5°(ix) 20 1080 SULPHURIC ACID (8ELLXO o!;u) 8, 1 °(~) 80 1830 8 SULPHURIC ACID, ixvalluµllx,011: ~AE1tE OLEUM (ai:µi,011 llELtxo o!;u) SULPHURIC ACID, (LL"((LIX'tlX (LE \ll'tplXO o!;u: BAE7tE Mir µ0t1:1X 8Et'Cxou & vti:ptxou o!;foi; SULPHURIC ACID, 0t1toppiµixi:0t 8, 1 °(~} 80 1832 8 SULPHUR TRIOXIDE 8, 1 °(0t) X88 1829 8 SULPHURYL CHLORIDE (SO 2 CL 2 ) 8, 21 °(ix) X88 1834 8 TARS {1t!o0Ei;) u1pii; 3, 32°(r) 30· 1999 TERRENE u6porovdtv9p0txE,;, 7t0U OE\/ 1tpoool0pt,O\l't1Xl OllX· qiopmxa: o,:o 1tixpo11 Ilixpa:p1:71µix ·(LE OTj(LELO IX\IIX(j)AE!;Ewt; (LE't1X!;u 21 ° K XIXl 55 ° K 3, 31 °{r) 30 2319 3 µE ariµEio IX\IIX(j)AE!;Ewc; 1ta:11w 0t1to 55 ° K 3, 32°(r) 30 2319 . E<l>HMEPII• THI KYBEPNHIEQI· (TEYXOI 6EYTEPO) 1371 (ot) (/3) (-y) (o) (E) fERPINOLENE 3, 31 °(1) 30 2541 3 1,1,2,2-TETRABROMOETHANE (ACE'FYLENE TET RABROMIDE) 6.1, 17°(1) 60 2504 6.lA 1, 1,2,2-TETRACHLOROETHANE (ACTYLENETETRA :HLORIDE) .. 6.1, 15°(/3} 60 1702 6.1 fETRACHLOROETHYLENE(PERCHLOROETHY LENE) 6.l,15°(r) 60 1897 6.lA fETRACHLOROPHENOLS 6.1, 17°(1) 60 2020 6.lA fETRAETHYLENEPENTAMINE 8, 53°(1) 80 2320 8 fETRAETHYL LEAD (µ0Au/3ooc;) 6.1, 31 °{ot} 66 a 1649 6.1 1,2,3,6-TETRAHYDROBENZALDEHYDE 3, 32°(,) 30 2498 TETRAHYDROFURAN 3, 3°(/3) 33 2056 3 TETRAHYDROPHTHALIC ANHYDRIDE 8, 31 °(r} 80 2698 8 1,2,3,6-TETRAHYDROPYRIDINE 3, 3°(/3) 33 2410 3 TETRAHYDROTHIOPHENE 3, 3°(/3) 33 2412 3 TETRAMETHOXYSILANE: /3AE1te METHYL ORTHOSILICATE TETRAMETHYLAMMO NIUM HYDROXIDE 8, 51 °(/3) 80 1835 8 TETRAMETHYLETHYLENEDIAMINE: /3A. 1,2-BIS (DIMETHYLAMINO) ETHANE TETRAMETHYL LEAD (µoh/36oc;) 6.1, 31 °(ot) 663 1649 6.1 + 3 TETRAMETHYLSILANE 3, 1 °(ot} 33 2749 3 TETRANITROMETHANE, ot1totM0t"(fLEVTJ ot1t0 XotUOL(J,Ec; !;lvec; i>Aec; 5.1, 2° 559 1510 5 TETRAPROPYLENE (PROPYLENE TETRAMER) 3,32°(,) 30 2850 TETRAPROPYLORTHOTITANATE 3, 3l"('y) 30 2413 3 4-THIAPENT ANAL 6.1, 20(1) 60 2785 6.lA THIOACETIC ACID 3, 3°(/3) 33 2436 3 THIOGLYCOL: /3A.MERCAPTOETHANOL THIOGLYCOLIC ACID 8, 32°(/3) 80 1940 8 THIONYL CHLORIDE (SOCL 2 ) 8,21°(ot) X88 1836 8 THIOPHENE 3, 3°(/3) 33 2414 3 THIOPHENOL 6.1, 20°(ot) 663 2337 6.1 + 3 THIOPHOSGENE 6.1, 20°(/3) . 60 2474 6.1 THIOPHOSPHORYL CHLORIDE (PSCL3) 8, 21 °(/3) 80 1837 8 TITANIUM TETRACHLORIDE (TiCL4) 3; 21°(/3) 80 1838 8 TITANIUM TRICHLORIDE, µi1µot-cot, fLTJ 1tupO(popLxcx. 8, 22°(/3) 80 2869 8 TOLUENE 3, 3°(/3) 33 1294 3 TOLUENE SULPHONIC ACIDS, a-ceptcx. 8, 34°(r) 80 2585 8 TOLUENE SULPHONIC ACIDS, ouxAuµottot 8, 34°(,) 80 2586 8 TOLUIDINES 6.1, 12°(/3) 60 1708 6.1 2,4-TOLUYLENEDIAMINE 6.1, 12°(r) 60 1709 6.lA 2,4-TOLUYLENE DIISOCYANATE xotL Laoµep~ µi1µ0(tot 6.1, 19°(/3) 60 2078 6.1 TRIALL YLAMINE 3,31°(,) 30 2610 3 TRIALLYL BORATE 6.1, l3°(r} 60 2609 6.lA TRIBUTYLAMINE 8, 53°(1) 80 2542 8 TRICHLOROACET ALDEHYDE (CHLORAL) 6.1, 16°(/3) 60 2075 6.1 TRICHLOROACETIC ACID 8, 31 °(/3) 80 1839 • . 8 TRICHLOROACETIC ACID, OLotAuµottix 8, 32 ° (/3) 80 2564 8 TRICHLOROACETYL CHLORIDE 8, 36°(/3) X80 2442 8 TRICHLOROBENZENES 6.1, 17°(,) 60 2321 6.lA TRICHLOROBUTENE 6.1, 17°(/3) 60 2322 6.1 1,1,1-TRICHLOROETHANE 6.1,15°(1) 60 2831 6.lA TRICHLOROETHYLENE 6.1, 15°(1) 60 1710 6.lA TRICHLOROMETHYLBENZENE: /3AE1te BENZOTRICH LORIDE TRICHLOROPHENOLS 6.1, 17°(r) 60 2020 6.lA TRICHLOROSILANE (SILICOCHLOROFORM) 4.3, 4°(ix) X338 1295 4.3 + 3 + 8 TRICRESYLPHOSPHATE µe 1tcx.vw mto 3 a-cix exot-co opOo taoµep~ 6.1, 23°(/3) 60 2574 6.1 TRIETHYLAMINE 3, 22 ° (/3) 338 1296 3+8 TRIETHYL BORA TE 3, 3°(/3) 33 1176 3 TRIETHYLENETETRAMINE 8, 53 ° (/3) 80 2259 8 TRIETHYL PHOSPHITE 3, 31 °('y) 30 2323 3 TRIFLUOROACETIC ACID 8, 32 °(ot) 88 2699 8 TRIFLUOROCHLOROETHYLENE (Rl 1132) 2, 3 °(CT) 236 1082 + + l,1,1,-TRIFLUOROETHANE 2, 3 °(/3) 23 2035 -+- + TRIFLUOROMETHANE (R23) 2, 5 °{ot) 20 1984 TRIISOBUTYLENE (ISOBUTYLENE TRIMER) 3, 11 °(1) 30 2324 3 TRIMETHYL ACETYL CHLORIDE: /3A. PIV ALOYL CHLORIDE TRIMETHYLAMINE, cx.vuopTJ 2, 3°(BT) 236 1083 3 + 6.1 TRIMETHYLAMINE uBcx-coOLIXAUfLllt'tot µE OljfLEtO /3pixaµou OX,L 1tlX\IW ot1t0 3 5 ° K 3, 22°(ix) 338 1297 3+8 1372 ECl>HMEPII: THI KYBEPNHI:EQI: (TEYXOI: ~EYTEPO) (IX) ((:f) <r) (6) (e) µE 07JµEtO {3p1Xaµou mi:vw alto 3 5 ° K 3, 22 °({3) 338 1297 3+8 1,3,5-TRIMETHYLBENZENE: {3AaitE MESITYLENE TRIMETHYL BORA TE 3, 3°((3) 33 2416 3 TRIMETHYLCHLOROSILANE 3, 21 °M X338 1298 3-+-8 TRIMETHYLCYCLOHEXYLAMINE 8, 53°(r) 80 2326 8 TRIMETHYLHEXAMETHYLENEDIAMINES 8, 53°(r) 80 2327 8 TRIMETHYLHEXAMETHYLENE DIISOCYANATE x1Xt taoµEpTJ µirµ0t't1X 6.1, 19°(r) 60 2328 6.lA 2,6,6-TRIMETHYL NORPINANYL HYDROPEROXIDE (PINANYL HYDROPEROXIDE? PINATE HYDROPE ROXIDE) µE 1tEptEX'ttXO"t7)'tlX tmEpotEtOtOU oxt 7trl\lW IX7t0 9 5 O'tlX EXIX'tO 5.2, 15° 539 2162 5 TRIMETHYL PHOSPHITE 3,31°(1) 30 2329 3 TRIPROPYLAMINE 8, 53 ° ({3) 83 2260 3,..3 TRIPROPYLENE (PROPYLENE TRIMER) 3, 31 °{r) 30. 2057 3 TURPENTINE (Nicp'tt) 3, 31 °(r) 30 1299 3 UNDECANE 3, 32°(r) 30 2330 VALERALDEHYDE 3, 3°({3) 33 2058 3 VALERYL CHLORIDE . 8,36°((3) 80 2502 8 VANADIUM OXYTRICHLORIDE (VOCL) 8, 21 °((3) 80 2443 8 VANADIUM OXYTRICHLORIDE (VOCL3), uo1X'toot0tAu 8, 5 °({3) 80 2443 8 µ0t'tlX VANADIUM PENTOXIDE 6.1, 58°({3) 60 2862 6.1 VANADIUM TETRACHLORIDE (VCL4) 8,21°(1X) 88 2444 8 VANADIUM TRI CHLORIDE (VCL3) 3, 22°(,) 80 2475 8 VARNISHES (BEplltXtOt) 3 -µE 07JµEio 0t11ixcpAitEwc; xa'tw 1X1to 21 ° K 3, 5° 33 1263 µe 07JµEio 1X110tcpAitEwc; µE'tOt~u 21 ° K XOtt 5 5 ° K 3, 31 °(y):/ 30 1263 3 µE a71µEio 1X111XcpAEtEwc; 1ta11w 1X1to 5 5 ° K 3, 32°(r):; 30 1263 VINYL ACETATE 3, 3°({3) 339 1301 3 VINYLBENZENE: {3Ai1tE STYRENE VINYL BROMIDE 2, 3°(CT) 236 1085 -+ T VINYL BUTYRATE 3,3 ° ({3) 339 2838 3 VINYL CHLORIDE 2, 3o(r) 239 1086 3 VINYL CHLOROACETATE 6.1, 16°((3) 60 2589 6.1 VINYL ETHYL ETHER 3, 2°({3) 339 1302 3 VINYL FLORIDE 2, 5°(r) 239 1860 ~ ~ VINYLIDENE CHLORIDE 3, 1 °(1X) 339 1303 3 VINYLIDENE FLUORIDE: {3Ai1tE 1,1 DIFLUOROETHYLENE VINYL ISOBUTYL ETHER 3, 3 0 ({3) 339 1304 3 VINYL ISOBUTYL ETHER VINYL TOLUENE, µtx'ta taoµEpTJ 3, 31 °(r) 39 2618 3 VINYLTRICHLOROSILANE 3, 21 °(0t) X338 1305 3-+-8 WHITE ARSENIC: {3).i1tE ARSENIC TRIOXIDE XENON 2, 50(0t) 20 2036 XENON, uypo {30t8wi:c; X0t'tacjiu~71c; 2, 70(0t) 22 2591 XYLENES (DIMETHYLBENZENES) 3, 31 °(r} 30 1307 3 XYLENOIS 6.1, 14°({3) 60 2261 6.1 XYLIDINES 6.1, 12°({3) 60 1711 6.1 XYLYL BROMIDE 6.1, 17°((3) 60 1701 6.1 ZINC CHLORIDE (ZNCL2) 8, 22°(,) 80 2331 8 ZINC CHLORIDE (ZNCL2) u60t'to6tixAufL1X't1X 8, so(r) 80 1840 8 ZIRCONIUM TETRACHLORIDE (ZRCL 4 ) 8, 22°(,) 80 2503 8 Ilixpap't7)µ0t B. 5 Oi110tx0tc; II mvixxixc; OUOtWII 'tWII KIX'tT)'(OptWII 3, 6.1 XOtt 8 7t0U OEY IXYOtcpEpOY'tOCt ovoµocO'ttXOC O'tOY mvocxix I XIXt OEY eµ1ti1t'tOUY XOC'tW IX7t0 'ttc; OUAAO"(txic; E7tLXEcp1XAtOEc; 7t0U 1tEptAocµ{3a110Y't0tt a' EXEl\10 'tOY m11ixx0t, IXAAO( Ot 07tOtEc; oµwc; 1tpE1tEt YIX 1tEptA71cp8ou11 O'ttc; 1t1Xpouaec; KiX'tT)'(OptEc; XIXt O'ttc; 01to!ec; OEY 6tOE'tlXL OU"(XEXpt(lEIIO<; •1Xpt0µoc; IXIIIX'(YWptaEwc; OUOL!Xc;». Ot OUOtE<; OU"(XEY'tpWIIO\l'tlXt OE 0(-LOCOE<; XOCt OU(lq>WIIIX (-LE 'tO\I 1Xpt8µo EtOOU<; 7t0U IXY'ttO'tOtXEt O'touc; XtYOUYOUc; 7t0U 1tixpouatot~O\l't1Xt O't7) 6tcxpxEtlX 'tTj<; (lE'tlXq>opo:c;. 1:HMEIQ I:H: 0 1t0tpw111tt11ixxixc; iXEt ecpotpµo"(TJ 1,1-0110 "(tlX oua!ec; 'tWY K0t't7)yoptw11 ~• 6.1., xott 8 1tou 6ev 1teptAocµ(30C11011't0tt a'toY Ilivotxot I. :/ 8Ai7tE, ciµwi; ~HMEIQ~H nii; 1t1Xp1X1pixq,ou 11 ,ou 1tEpt8wpt1Xxou 2301 E<J>HMEPII THI KYBEPNHIEQI (TEYXOI ~EYTEPO) 1373 Oµaoot Oucnw11 ApL0. 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