National Implementation Plan (NIP) for the Stockholm Convention on Persistent Organic Pollutants (POP)

— 1 — The People’s Republic of China National Implementation Plan for the Stockholm Convention on Persistent Organic Pollutants (Enlarged Edition) The People’s Republic of China Ministry of Ecology and Environment — 2 — 1 Background The Chinese government signed the Stockholm Convention on Persistent Organic Pollutants (hereinafter referred to as the Convention) on May 23, 2001, and the Tenth Session of the Standing Committee of the Tenth National People’s Congress ratified the Convention on June 25, 2004. The Convention entered into force for China on November 11, 2004, which also applied to Hong Kong Special Administrative Region and Macao Special Administrative Region. As required in Article 7 of the Convention, China issued the National Implementation Plan for the Stockholm Convention on Persistent Organic Pollutants (hereinafter referred to as NIP) in April, 2007. For the initial group of 12 persistent organic pollutants (POPs) listed in the Convention, the NIP set objectives in stages and by region and industry for Convention implementation, developed implementation measures and specific action plans, and made action objectives in detail for the first stage (by 2010), the second stage (2010-2015) and the long-term future. Since the NIP was carried out, China has made a series of progress and solved a number of environmental hazards of POPs that seriously threaten human health and safety. Firstly, the production, use, import and export of the initial group of intentionally produced POPs has been stopped, the content level of which in the environmental and biological samples has an overall downward trend. Secondly, the emission intensity of Dioxins in key sectors such as iron ore sintering, secondary non-ferrous metal smelting, and waste incineration has decreased by more than 15%. Thirdly, over 50,000 tons POPs-containing legacy waste has been cleaned up and disposed. On August 30, 2013, the Fourth Session of the Standing Committee of the Twelfth National People’s Congress ratified the Amendment for Listing Nine New Persistent Organic Pollutants and the Amendment for Listing Endosulfan. On July 2, 2016, the Twenty-first Session of the Standing Committee of the Twelfth National People’s Congress ratified the Amendment for Listing Hexabromocyclododecane (HBCD). By December, 2017, the number of POPs restricted and controlled in China according to the Convention and its amendments has increased from 12 to 23. The Convention implementation progress of the 11 new POPs is shown in table 1. — 3 — Table 1: Convention implementation progress of the 11 new POPs restricted and controlled according to the Convention and its amendments Categories Entry into force date POPs list Convention implementation progress Annex A Elimination March, 2014 Pentachlorobenzene, hexabromobiphenyl, chlordecone, alpha hexachlorocyclohexane, beta hexachlorocyclohexane, tetrabromodiphenyl ether and pentabromodiphenyl ether, hexabromodiphenyl ether and heptabromodiphenyl ether The production, use, import and export has been stopped. lindane, endosulfan The production has been stopped. The use, import and export has been stopped (except for specific exemptions 1 ). December, 2016 Hexabromocyclododecane (HBCD) The production, use, import and export has been stopped (except for specific exemption 2 ). Annex B Restriction March, 2014 Perfluorooctane sulfonic acid, its salts and perfluorooctane sulfonyl fluoride （PFOS/PFOSF） The production, use, import and export has been stopped (except for specific exemptions 3 and acceptable purposes 4 ). Annex C March, 2014 Pentachlorobenzene Measures have been taken to 1 Specific exemption for lindane: human health pharmaceutical for control of head lice and scabies as second line treatment; Specific exemption for endosulfan: control of crop-pest complexes of tobacco and cotton. 2 Specific exemption for HBCD: production of expanded polystyrene and extruded polystyrene in buildings. 3 Specific exemptions for PFOS/PFOSF: photo masks in the semiconductor and liquid crystal display (LCD) industries, metal plating (hard metal plating), metal plating (decorative plating), electric and electronic parts for some colour printers and colour copy machines, insecticides for control of red imported fire ants and termites, chemically driven oil production. 4 Acceptable purposes for PFOS/PFOSF: photo imaging, photo-resist and anti-reflective coatings for semi-conductors, etching agent for compound semi-conductors and ceramic filters, aviation hydraulic fluids, metal plating (hard metal plating) only in closed-loop systems, certain medical devices (such as ethylene tetrafluoroethylene copolymer (ETFE) layers and radio-opaque ETFE production, in-vitro diagnostic medical decives and CCD color filters), fire-fighting foam. — 4 — Unintention al production synergistically reduce the release of this kind of chemicals from anthropogenic sources. As required in the Convention, China initiated the compilation of the National Implementation Plan for the Stockholm Convention on Persistent Organic Pollutants (Enlarged Edition) in March, 2014. The Enlarged Edition of NIP, fully referring to the interim Guidance for Developing a National Implementation Plan for the Stockholm Convention recommended by the Secretariat of the Convention, is developed specially for the Convention implementation of the 11 new POPs. — 5 — 2 Overall objective and objectives in different stages Overall objective: Reduce or eliminate the environmental and health risks posed by the new POPs through effective implementation of the Convention. Objectives in different stages: Ban the production, use, import and export of lindane and endosulfan, and ban the production, use, import and export (except for the acceptable purpose) of perfluorooctane sulfonic acid, its salts and perfluorooctane sulfonyl fluoride (PFOS/PFOSF) from March 26, 2019. Ban the production, use, import and export of hexabromocyclododecane (HBCD) from December 26, 2021. — 6 — 3 National action plan for Convention implementation 3.1 Strengthening of the building of institutional capacity and development of policies and rule of law Action 1: Strengthen the capacity building for related national institutions involved in Convention implementation Enhance the capacity of the National Coordination Group for Stockholm Convention Implementation (NCG) for unified coordination and implementation organization and improve the capacity of the member departments of the NCG on policy making, data collection, information exchange and supervision and management. Timely update the NCG and its expert committee. Strengthen the capacity building of the NCG Office 1 on Convention implementation management and technical support of the new POPs; improve the comprehensive capability for Convention implementation on negotiation and international tendency tracking, policy formulation and enforcement, fund planning and raising, development and implementation of projects, and information exchange and publicity; as well as establish a national information exchange platform for Convention implementation. Action 2: Strengthen the capacity building for local institutions involved in Convention implementation Improve the awareness and the capacity on Convention implementation of the new POPs at local levels; strengthen the capacity on developing and enforcing related policies and regulations and plans at local levels; enhance the capability on activity implementation and fund raising for Convention implementation; strengthen the capacity on information collection, analysis, reporting and management; and launch publicity, education and training. Action 3: Strengthen the capacity building for related sectors on Convention implementation Raise the awareness and the capacity of related sectors on Convention implementation of the new POPs; strengthen the organization and coordination capacity of institutions in related sectors regarding the work of Convention implementation; strengthen the capacity on information collection, analysis, reporting and management; strengthen the capacity on follow-up evaluation and promoting the application of Best Available 1 The NCG Office consists of the Department of Solid Waste and Chemicals, the Department of International Cooperation and Foreign Economic Cooperation Office of the Ministry of Ecology and Environment. — 7 — Techniques and Best Environmental Practices (BAT/BEP), alternatives/alternative technologies and disposal technologies; and launch publicity, education and training. Action 4: Include the new POPs in the negative list for market access Include the intentionally produced new POPs in the negative list for market access. Prohibit or strictly restrict the intentional production and use of the new POPs. Action 5: Strengthen enforcement Strengthen the capacity building of law enforcement forces including environmental monitoring, plant protection and quarantine, emergency management, customs supervision and market supervision; carry out training for the enforcement departments regarding Convention implementation. Intensify law enforcement and inspections on the illegal production and use of new POPs and launch joint enforcement actions. 3.2 Elimination of the production and use of new POPs listed in Annex A Action 6: Prohibit the production and use of lindane Release policy measures to prohibit the production, use, import and export of lindane from March 26, 2019. List lindane in the Catalog of Goods Prohibited from Import and the Catalog of Goods Prohibited from Export. Action 7: Prohibit the production and use of endosulfan Conduct research and formulate technical specifications for pest control in cotton planting; carry out publicity and training activities for alternatives of endosulfan; comprehensively promote alternative technologies of endosulfan; and stop the application of endosulfan on cotton planting. Release policy measures to prohibit the production, use, import and export of endosulfan from March 26, 2019. List endosulfan in the Catalog of Goods Prohibited from Import and the Catalog of Goods Prohibited from Export. Action 8: Prohibit the production and use of HBCD Carry out surveys and statistics on HBCD production/processing enterprises and conduct dynamic tracking on their production and use. Companies that use HBCD for production or release HBCD during production should implement cleaner production. Conduct research and develop product standards on the limit values of HBCD content — 8 — in building insulation materials. Make more effort on the research and development on HBCD alternatives as well as alternatives and alternative technologies of flame retardant insulation materials containing HBCD and carry out demonstration and dissemination activities. Release policy measures to prohibit the production, use, import and export of HBCD from December 26, 2021. List HBCD in the Catalog of Goods Prohibited from Import and the Catalog of Goods Prohibited from Export. 3.3 Restriction of the production and use of new POPs listed in Annex B Action 9: Rigidly restrict the production and use of PFOS/PFOSF Carry out surveys and statistics on PFOS/PFOSF production/processing enterprises and conduct dynamic tracking on their production and use. Companies that use PFOS/PFOSF for production or release PFOS/PFOSF during production should implement cleaner production. Conduct research and include the limit values of PFOS/PFOSF content in the standards of Fire-fighting Foam. Develop a tracking system for the production, transportation, storage, use and treatment of PFOS/PFOSF fire-fighting foam; carry out demonstration on the application of non-PFOS/PFOSF fire-fighting foam products. Action 10: Conduct research and development and promotion of alternatives and alternative technologies of PFOS/PFOSF Carry out research and development and promotion of alternatives and alternative technologies of PFOS/PFOSF for sectors including fire-fighting foams, metal plating (hard metal plating) only in closed-loop systems, aviation hydraulic fluids, photo imaging, photo-resist and anti-reflective coatings for semi-conductors. Action 11: Rigidly restrict and gradually eliminate PFOS/PFOSF Release policy measures to prohibit the production, use, import and export of PFOS/PFOSF from March 26, 2019 (except for acceptable purpose). 3.4 Reduction of releases of unintentionally produced new POPs listed in Annex C Action 12: Reduce or eliminate releases of unintentionally produced pentachlorobenzene — 9 — Continue to implement Dioxins pollution control measures to synergistically reduce the emission of unintentionally produced pentachlorobenzene. 3.5 Reduction of environmental releases from wastes Action 13: Carry out research on environmental management of new POPs wastes Track the progress of international POPs wastes environmental management; actively participate in the negotiation of relevant issues on the Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and Their Disposal; and carry out study on the environmental management of new POPs wastes. 3.6 Promotion of information exchange for concerned parties and public information Action 14: Promote information exchange for concerned parties Improve data collection and organization of the new POPs; maintain smooth information exchange with other parties to the Convention; regularly organize Convention implementation forum; and compile and publish related scientific research findings. Action 15: Improve public information, awareness and education Develop schemes for public awareness, education and training related to Convention implementation on new POPs; compile and publish readings suitable for different groups; launch educational and training activities related to Convention implementation; provide the public with information pertaining to POPs through websites or others that are accessible to the public. 3.7 Conduction of effectiveness evaluation and national report compilation Action 16: Carry out POPs monitoring in environmental media Progressively carry out monitoring on alpha hexachlorocyclohexane, beta hexachlorocyclohexane, lindane, chlordecone, pentachlorobenzene, hexabromobiphenyl, polybromodiphenyl ether 1 , endosulfan, and HBCD in air, and PFOS in water bodies; and evaluate regional differences and dynamic trend. Strengthen 1 Polybromodiphenyl ether refers to the indicative congener of tetraBDE, pentaBDE, hexaBDE, and heptaBDE. — 10 — the construction of POPs monitoring network in environmental media. Action 17: Conduct POPs monitoring in humans Carry out monitoring of new POPs (alpha hexachlorocyclohexane, beta hexachlorocyclohexane, lindane, chlordecone, pentachlorobenzene, hexabromobiphenyl, polybromodiphenyl ether, endosulfan, HBCD and PFOS) in breast milk and blood and assess the exposure risk of new POPs that the Chinese population has as well as the trends. Action 18: Submit the effectiveness evaluation report Relying on the information exchange mechanism for POPs Convention implementation, establish an information collection and reporting system that meets the requirements of the Convention's effectiveness evaluation report; submit the effectiveness evaluation report to the Secretariat of the Convention on time. Action 19: Complete the national report Regularly summarize data on the production, use, stockpiles, disposal, import and export of lindane, endosulfan, HBCD, and PFOS/PFOSF, and prepare the national report; submit the national report to the Secretariat of the Convention on time. Departments concerned under the State Council will conduct evaluation of their respective policies, laws, regulations and departmental rules pertaining to Convention implementation that they have formulated or have taken the lead to formulate as well as evaluation of the implementation of such policies, rules and regulations, and submit their evaluation reports to the NCG office. 3.8 Strengthening of research, development and monitoring Action 20: Develop detection methods of new POPs Carry out study on the standards and methods for monitoring PFOS (water bodies), endosulfan (air), hexachlorocyclohexane 1 (air), hexabromobiphenyl (air), polybromodiphenyl ether (air), and new POPs in breast milk and blood; develop detection techniques for potential POPs in air, soil, sediments and organisms. 1 Hexachlorocyclohexane refers to alpha hexachlorocyclohexane, beta hexachlorocyclohexane and lindane. — 11 — Action 21: Carry out environmental risk evaluation of potential POPs Organize the study on biological indicators that reflect environmental exposure to new POPs and potential POPs, dose-effect relationships with regard to the impacts of new POPs and potential POPs exposure on the biological environment and human health, and toxicity pathway analysis. Strengthen the study on alternative/technical economic and technical feasibility of potential POPs and strengthen environmental risk study on major alternatives. Action 22: Strengthen policy guidance for research and development and promotion Conduct research and formulate relevant policies and measures; give full play to the policy mechanisms of macro-control and market regulation; promote the research and development and promotion of alternatives to new POPs; encourage innovation; promote the R&D and application of alternatives, alternative technologies and pollution control technologies. 3.9 Improvement of the financial guarantee mechanism Action 23: Carry out study on financing mechanism and economic policies for Convention implementation Study the economic incentive and constraint mechanism that contributes to reducing or eliminating new POPs pollution; explore and establish a diversified investment mechanism combining the government, enterprises and civil societies to broaden the financing channels. Action 24: Guarantee the financial needs for Convention implementation Clarify and update the priorities and financial requirements. Actively seek support from the Global Environment Facility and dual-multilateral grant funds. Improve the long-term funding mechanism for national compliance, and ensure the funding needs of various compliance actions. — 12 — 4 Guarantee measures 4.1 Strengthen organizational mechanism Make full use of national implementation coordination mechanism. Member units of NCG should do their part, fulfill the Convention implementation work in various fields, put into place all sorts of funds for Convention implementation in accordance with the need of work, and corporate with each other closely, in order to ensure the achievement of the goals of NIP (Enlarged Edition). Local government should develop implementation plan for the NIP (Enlarged Edition), organize and carry out local actions to implement the Convention, ensure the fulfillment of the major responsibility of enterprises; assist the preparation and implementation of related Convention implementation projects. 4.2 Stable financial mechanism 4.2.1 Financial requirements for the implementation of the Convention Funds required for the NIP (Enlarged Edition) include: (1) Technical assistance expenses and incremental costs associated with capacity building at central and local levels and for sectors on management, monitoring, alternative technology research and development, data acquisition and information exchange, effectiveness evaluation and relevant risk assessment, technology development, and wastes and contaminated sites treatment. (2) The expenses and incremental costs for phasing out the production of endosulfan, HBCD and PFOS/PFOSF and applying alternatives and alternative technologies (including loss of profit, costs for environmentally sound management of contaminated sites, costs for alternatives introduction, alternative equipment research and development and operation, and costs for publicity and trainings). Based on the requirements under the Convention on new POPs reduction and control and the action plan, and according to Article 13 and Article 14 of the Convention as well as Global Environment Facility (GEF) funding principles, financial requirement for the implementation of the NIP (Enlarged Edition) are estimated as follows: — 13 — Table 2 Financial requirements for NIP (Enlarged Edition) implementation （Adopt prices in 2016, Unit：RMB 10,000 Yuan） No. Specific actions Aggregate Budget Incremental Cost Baseline Cost 1 Strengthening of the building of institutional capacity and development of policies and rule of law 10,491.5 2,098.3 8,393.2 2 Elimination of the production and use of new POPs listed in Annex A 75,280.9 15,158.5 60,122.4 3 Restriction of the production and use of new POPs listed in Annex B 120,530.0 16,490.0 104,040.0 4 Reduction of releases of unintentionally produced new POPs listed in Annex C * 0.0 0.0 0.0 5 Reduction of releases from wastes 360.0 72.0 288.0 6 Promotion of information exchange for concerned parties and public information 3,377.0 675.4 2,701.6 7 Conduction of effectiveness evaluation and the national report compilation 37,944.8 7,588.9 30,355.8 8 Strengthening of research, development and monitoring 27,750.0 5,550.0 22,200.0 9 Improvement of the financial guarantee mechanism 70.0 14.0 56.0 Total 275,804.2 47,647.1 228,157.0 Note*：The financial requirements for the “Reduction of releases of unintentionally produced new POPs listed in Annex C” are included in the emission reduction of Dioxins pollution. 4.2.2 Fund procurement mechanism for the implementation of the Convention Funds for China to implement the Convention are mainly from central and local financial budget, corporate and private funds, financial mechanisms of the Convention, and international multilateral and bilateral grants. — 14 — According to the financial mechanism requirements under the Convention, the incremental costs should be undertaken by GEF, the interim financial mechanism of the Convention, and the baseline costs should be undertaken by the government and relevant corporations. The above-mentioned expenses and incremental costs will be updated and supplemented with the increase of new POPs listed in the Convention and the update and supplementation of NIP in the future. Priorities requiring financial assistance for China from GEF include: (1) establishment and improvement of relevant policies, regulations, and technical specification, strengthening of institutional capacity, and improvement of public awareness; (2) promotion the research and development and promotion of alternatives and alternative technologies, and phase out the production and use of endosulfan, PFOS/PFOSF and HBCD step by step; (3) conducting research on waste management of new POPs; (4) carrying out study on environment and health risk assessment and regulation and control of potential POPs; (5) implementation of projects on POPs emission reduction; (6) research on and development of detecting standards and methods of new POPs. Hong Kong Special Administrative Region Implementation Plan for the Stockholm Convention on Persistent Organic Pollutants (POP) February 2016 Environmental Protection Department The Government of the Hong Kong Special Administrative Region Table of Content Page List of Tables List of Figures Abbreviations and Acronyms Executive Summary 1. INTRODUCTION .............................................................................................................................. 1 2. THE HKSAR BASELINE ................................................................................................................. 3 2.1 The HKSAR Basic Profile ........................................................................................................ 3 2.2 Environmental Policies and Legislative Framework for POPs Control and Management ...... 3 2.2.1 Legislative Framework on POPs Control ........................................................................ 3 2.2.1.1 Pesticides ........................................................................................................... 4 2.2.1.2 Hazardous Chemicals ........................................................................................ 4 2.2.1.2.1 Hazardous Chemicals Control Ordinance (HCCO) ....................... 5 2.2.1.2.2 Air Pollution Control Ordinance (APCO) ...................................... 5 2.2.1.2.3 Water Pollution Control Ordinance (WPCO) ................................. 5 2.2.1.2.4 Waste Disposal Ordinance (WDO) ................................................ 6 2.2.1.2.5 Environmental Impact Assessment Ordinance (EIAO) ................. 6 2.2.2 Roles and Responsibilities of Relevant Government Bureaux/Departments .................. 7 2.2.3 Obligations under Other Related Environmental Conventions Applicable to the HKSAR ........................................................................................................................... 9 2.2.3.1 The Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and Their Disposal .............................................................. 9 2.2.3.2 The Rotterdam Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade................ 9 2.3 Overview of the Current POPs Issue in the HKSAR ............................................................. 10 2.3.1 Source Inventories of POPs ........................................................................................... 10 2.3.1.1 Trade, Production and Use of Intentional POPs ............................................. 10 2.3.1.1.1 Pesticides ...................................................................................... 10 2.3.1.1.2 Industrial Chemicals ..................................................................... 10 2.3.1.2 Release of Unintentional POPs as by-Products .............................................. 14 2.3.1.2.1 PCDD (Dioxins) and PCDF (Furans) .......................................... 14 2.3.1.2.2 Hexachlorobenzene (HCB) .......................................................... 18 2.3.1.2.3 Polychlorinated biphenyls (PCB) ................................................. 19 2.3.1.2.4 alpha-Hexachlorocyclohexane (α-HCH) and beta-Hexachlorocylohexane (β-HCH) ......................................... 20 2.3.1.2.5 Pentachlorobenzene (PeCB) ......................................................... 20 2.3.1.3 Contaminated Sites ......................................................................................... 20 2.3.2 Environmental Levels of POPs ..................................................................................... 20 2.3.2.1 Contamination Levels of POPs in Environmental Media ............................... 20 2.3.2.1.1 Ambient Air .................................................................................. 21 2.3.2.1.2 Marine Water ................................................................................ 23 2.3.2.1.3 Fresh Water ................................................................................... 24 2.3.2.1.4 Marine Sediment .......................................................................... 25 2.3.2.1.5 River Sediment ........................................................................... 26 2.3.2.1.6 Surface Soil .................................................................................. 27 2.3.2.1.7 Vegetation ..................................................................................... 27 2.3.2.2 Contamination Levels of POPs in Aquatic Biota ............................................ 29 2.3.2.2.1 Freshwater Fish ............................................................................ 30 2.3.2.2.2 Marine Fish .................................................................................. 31 2.3.2.2.3 Marine Shellfish ........................................................................... 32 2.3.2.2.4 Water Bird Eggs ........................................................................... 33 2.3.2.2.5 Marine Mammals ......................................................................... 34 2.3.3 Dietary Exposure to POPs ............................................................................................. 36 2.3.4 Human Body Burden of POPs....................................................................................... 39 2.3.4.1 Human Breast Milk ......................................................................................... 39 2.3.4.2 Human Blood Plasma ...................................................................................... 40 2.4 Analysis of POPs Information Gaps ....................................................................................... 42 2.4.1 Environmental Levels of POPs ..................................................................................... 42 2.4.1.1 Contamination Levels of POPs in Environmental Media ............................... 42 2.4.1.2 Contamination Levels of POPs in Aquatic Biota ............................................ 43 2.4.2 Dietary Exposure to POPs ............................................................................................. 43 2.4.3 Human Body Burden of POPs....................................................................................... 43 2.5 Environmental and Human Health Risk Assessment of POPs ............................................... 43 2.5.1 Human Health Risk Assessment.................................................................................... 43 2.5.1.1 Human Non-carcinogenic Risk Assessment ................................................... 43 2.5.1.2 Human Carcinogenic Risk Assessment ........................................................... 45 2.5.1.3 Health Risk Assessment of POPs in the Local Marine Environment ............. 46 2.5.2 Comparison with Other Countries/Regions .................................................................. 47 2.5.2.1 Annual Release of Dioxins/Furans ................................................................. 47 2.5.2.2 Release of Dioxins/Furans in Ambient Air ..................................................... 47 2.5.2.3 Release of PCB, α-HCH, Lindane in Ambient Air ......................................... 48 2.5.2.4 Surface Soil ..................................................................................................... 49 2.5.3 Ecological Risk Assessment .......................................................................................... 49 2.5.3.1 Pelagic Organisms Risk Assessment ............................................................... 49 2.5.3.2 Benthic Organisms Risk Assessment .............................................................. 50 2.5.3.3 Marine mammals risk assessment ................................................................... 52 3 STRATEGIES, PRIORITIES, ACTION PLANS AND IMPLEMENTATION PROGRESS ......... 53 3.1 POPs Management Framework and Implementation Strategy ............................................... 53 3.2 Overall Assessment of Current POPs Pollution in Hong Kong .............................................. 53 3.3 Action Plans and Implementation Progress ............................................................................ 54 3.3.1. Strengthening of the Institutional and Regulatory Systems .......................................... 54 3.3.2. Validation and Refinement of the POPs Inventories ..................................................... 55 3.3.3. Measures to Reduce Emission of Unintentionally Produced POPs .............................. 58 3.3.4. Public Awareness Campaign ......................................................................................... 61 3.3.5. Regional Collaboration with the Mainland ................................................................... 61 3.3.6. Capacity Building .......................................................................................................... 62 3.3.7. Implementation Plan Review and Effectiveness Evaluation ......................................... 63 List of Tables Page Table 1: POPs listed in the Stockholm Convention ......................................................................................... 2 Table 2: Roles and Responsibilities of Relevant Bureaux/Departments in the HKSARG in Environmental and Human Health Protection ........................................................................................................... 7 Table 3: Summary of Annual PCDD/PCDF Emission Inventory in Hong Kong for the Year 2012 ............ 15 Table 4: Mean Levels of POPs Contamination in the Environment of Hong Kong for the Period 2002 2013 ................................................................................................................................................. 28 Table 5: Levels of POPs Contamination in the Aquatic Biota of Hong Kong for the Period 2002 - 2014 ... 35 Table 6: Numbers of Composite Samples in Total Diet Study Food Groups ................................................ 37 Table 7: Dioxin and Dioxin-like PCB Contents in TDS Foods of the 1st HKTDS ....................................... 38 Table 8: Ranges (lower bound and upper bound) of Dietary Exposure Estimates to the OCPs for the Average and High Consumers of the Hong Kong Population in Year 2011- 2014 .......................... 38 Table 9: Mean Levels of POPs Contamination in Breast Milk of Hong Kong Citizens for the Period 2009-2013 ........................................................................................................................................ 40 Table 10: Mean Levels of POPs Contamination in Human Blood of Hong Kong Citizens for the Period 2011-2013 ........................................................................................................................................ 42 Table 11: Non-carcinogenic Risk Assessment of POPs in Hong Kong in 2002-2013 .................................... 44 Table 12: Carcinogenic Risk Assessment of POPs to the Residents of Hong Kong ....................................... 45 Table 13: Comparison of the Level of POPs Contamination in Marine Fish and Shellfish sampled in Hong Kong Waters .......................................................................................................................... 46 Table 14: Comparison of Annual Emission of Dioxin/Furans in Hong Kong and Other Countries/Regions .. 47 Table 15: Comparison of Ambient Air Concentrations of Dioxins/Furans (PCDD/PCDFs) in Hong Kong and Other Countries/Regions ........................................................................................................ 48 Table 16: Comparison of Ambient Air Concentrations of PCB, α-HCH and Lindane in Hong Kong and Other Countries/Regions ........................................................................................................................... 48 Table 17: Comparison of the Level of POPs Contamination in Surface Soil of Hong Kong and Other Countries/Regions ........................................................................................................................... 49 Table 18: Tier 1 Ecological Risk Assessment of POPs to Pelagic Organisms in Hong Kong in 2009-2011 .. 50 Table 19: Tier 1 Ecological Risk Assessment of POPs to Benthic Organisms in Hong Kong in 2009-2011 .. 51 Table 20: Ecological Risk Assessment of POPs to Cetaceans in Hong Kong in 2010-2011 ........................... 52 List of Figures Page Figure 1 – Contribution of Various Emission Source Categories to Annual Dioxins/Furans Emission ............ 15 Figure 2 – Percentage of Dioxins/Furans Emission on a Vector Basis ............................................................. 16 Figure 3 – Contribution of Different Source Categories to Annual Dioxins/Furans Emission to Air ............... 16 Figure 4 – Contribution of Different Source Categories to Annual Dioxins/Furans Emission to Residues ..... 18 Abbreviations and Acronyms AFCD Agriculture, Fisheries and Conservation Department AFFF Aqueous fire fighting foam BDL Below detection limit bw Body weight (kg) C-octaBDE Hexabromodiphenyl ether and heptabromodiphenyl ether C-pentaBDE Tetrabromodiphenyl ether and pentabromodiphenyl ether CEDD Civil Engineering and Development Department CFS Centre for Food Safety CityU City University of Hong Kong COP Conference of the Parties CPG Central People’s Government of the People’s Republic of China CUHK Chinese University of Hong Kong CWTC Chemical Waste Treatment Centre DDT Dichlorodiphenyltrichloroethane DL Detection limit dw Dry weight DH Department of Health EEA European Environment Agency EPD Environmental Protection Department EU European Union FAO Food and Agriculture Organization of the United Nations FEHD Food and Environmental Hygiene Department GL Government Laboratory HBB Hexabromobiphenyl HBCD Hexabromocyclododecane HCB Hexachlorobenzene HCCO Hazardous Chemicals Control Ordinance HCH Hexachlorocyclohexanes HKBU Hong Kong Baptist University HKSARIP HKSAR Implementation Plan HKU University of Hong Kong HOKLAS Hong Kong Laboratory Accreditation Scheme HW High Technology Hazardous Waste HQ Hazard quotient I-TEF International Toxicity Equivalency Factor I-TEQ International Toxic Equivalents LRTAP Long-range Transboundary Air Pollution lw Lipid weight NIP National Implementation Plan OCPs Organochlorine pesticides PBDE Polybrominated diphenyl ethers PCB Polychlorinated biphenyls PCDD Polychlorinated dibenzo-p-dioxins PCDF Polychlorinated dibenzofurans PeCB Pentachlorobenzene PFOS Perfluorooctane sulfonic acid PFOSF Perfluorooctane sulfonyl fluoride POPs Persistent Organic Pollutants PRC People’s Republic of China UNEP United Nations Environment Programme UNECE United Nations Economic Commission for Europe US EPA United States Environmental Protection Agency WHO World Health Organization WSD Water Supplies Department ww Wet weight α-HCH Alpha hexachlorocyclohexane β-HCH Beta hexachlorocylohexane γ-HCH Lindane EXECUTIVE SUMMARY The Stockholm Convention is a global treaty to protect human health and the environment from the potentially harmful effects of persistent organic pollutants (POPs). In implementing the Convention, Parties will need to take measures to control/restrict the trade, domestic production and use of intentionally produced POPs and, where possible, to reduce and to ultimately eliminate the production and release of unintentionally produced POPs by-products. The Stockholm Convention became effective to the People’s Republic of China (PRC), including the Hong Kong Special Administrative Region (HKSAR), on 11 November 2004. In accordance with the Convention requirements, the PRC submitted a National Implementation Plan (NIP), which includes the HKSAR Implementation Plan (HKSARIP), to the Conference of the Parties of the Stockholm Convention in 2007. The fourth and fifth meetings of the Conference of Parties (COP) to the Convention held in 2009 and 2011 adopted amendments to Annexes A, B and C to the Convention to list 10 new POPs in the respective Annexes. The amendment entered into force for PRC, including the HKSAR, on 26 March 2014. In accordance with the Convention, the PRC will submit an updated National Implementation Plan (NIP) which includes the updated HKSARIP for the new POPs to the COP within two years of the date on which these amendments enter into force (i.e. by 26 March 2016). In updating the HKSARIP, we have reviewed the existing control framework for POPs in Hong Kong. The POPs pesticides are controlled under the Pesticides Ordinance (Cap. 133) and the Import and Export Ordinance (Cap. 60). A number of environmental ordinances are also in place to impose “downstream” control of air and water pollution and waste disposal. Since the inception of the first HKSARIP, the Hazardous Chemicals Control Ordinance (HCCO) has been enacted specifically for regulating the import, export, manufacture and use of non-pesticide POPs through an activity-based permit system. After a review of the control framework, an inventory on the current status of POPs in Hong Kong was updated. This inventory provided a scientific basis for assessing the environmental and human health impacts of POPs and was fundamental to the prioritization of the proposed action items in the HKSARIP to reduce or eliminate POPs. The POPs inventory framework was updated in accordance with relevant UNEP guidance documents. Existing data on emission sources, environmental contamination levels, dietary exposure and human body burden of the 23 Convention POPs in Hong Kong from all available sources (relevant government databases, local academia and open literature) were collated and assembled. Data screening and quality assurance checks were conducted at initial information retrieval and all data entries were cross-checked during data compilation. All 15 Convention POPs pesticides (i.e., aldrin, chlordane, DDT, dieldrin, endrin, heptachlor, HCB, mirex, toxaphene, α-HCH, β-HCH, chlordecone, γ-HCH, PeCB and endosulfan) were either never registered or had been banned from all uses and purposes in the HKSAR for many years. The 2011-2013 non-pesticide POPs inventory indicated only a very small quantity of PCB in electrical transformers and PFOS/PFOSF in aqueous fire fighting foam in import/use/stockpile. Dioxins (PCDD) and furans (PCDF) are unintentional by-products of industrial and combustion processes. In 2012, there was an annual emission of 46.5 g TEQ dioxins/furans to the local environment via all vectors (air, water, land, product and residues). The major route of release was “residues”, responsible for 84.3% of the total, followed by “air” (10.7%) and “land” (4.0%). On a “per capita” basis, the 2012 annual dioxin/furan release in Hong Kong was generally similar to those of Switzerland and the US, and comparable with the EU countries. The level of POPs contamination in the local environment (ambient air and surface soil) was generally comparable to the range reported in most other urban locations in Asia, Europe and Africa. Assessment based on available data indicated that overall, there was unlikely to be any unacceptable ecological risk of toxicological significance associated with exposure of the local marine life to the current level of POPs contamination in the marine environment of Hong Kong. Total monthly exposure of local residents to dioxins/furans was estimated to be 21.9 pg TEQ/kg bw/month (based on the total daily exposure estimate of 0.73 pg TEQ/kg bw/day for the Hong Kong population and 30 days per month), a value falling at the lower end of the tolerable monthly intake of 70 pg TEQ/kg bw/month set by the Joint FAO/WHO Expert Committee on Food Additives. Dietary intake was the major route, accounting for 98.6% of total exposure of local residents to dioxins/furans. Results of human health risk assessment indicated that there was no unacceptable inhalation nor dietary chronic/carcinogenic risk of toxicological concern associated with a lifetime exposure of local residents to the current levels of POPs contamination in the local environment and locally consumed foods. Levels of POPs in the local marine biota were found to be well below national/overseas Food Safety Standards/Action Levels of Mainland China, the US and the EC. Review of the HKSAR’s current control framework and POPs inventories was performed to identify areas that need to be continuously followed up or enhanced to ensure proper implementation of the Stockholm Convention. Strategies and action plans were developed to reflect local priorities. The key issues to be pursued are as follows:  Update relevant ordinances as and when necessary – to update the Pesticides Ordinance and HCCO to ensure that all amendments to Annexes to the Convention are properly incorporated;  Characterize local dioxin/furan emission sources – to validate annual production activities and estimate emission levels;  Continue with our systematic monitoring of all currently and potentially listed POPs in the environmental media, locally consumed foods and human breast milk;  Continue to implement control measures to reduce emission of unintentional POPs to the local environment;  Continue to enhance public awareness;  Continue to enhance regional collaboration with the Mainland – to harmonize POPs monitoring and analytical protocols, and to facilitate information exchange and knowledge sharing; and  Capacity building – to promote best available techniques (BAT) / best environmental practices (BEP), and to enhance local POPs analytical capabilities. It is envisaged that the second HKSARIP will provide useful data for updating and refining the POPs inventories which are instrumental to a science-based re-assessment of the local POPs situation and evaluation of the effectiveness of the HKSARIP in reducing dioxin/furan emissions. 1 1. INTRODUCTION Persistent organic pollutants (POPs) are organochlorine compounds that persist in the environment, bio-accumulate and bio-magnify through the food chain. Their movement within environmental compartments and long-range transport often result in serious threat to the environment and human population around, and also distant from their original point of release. The United Nations Environment Programme (UNEP) has identified an initial set of 12 POPs for global restriction of production/use and, where possible, ultimate elimination under the Stockholm Convention (the Convention). The Stockholm Convention was adopted on 22 May 2001 in Stockholm, Sweden and entered into force on 17 May 2004. The Convention became effective to the People’s Republic of China (PRC), including the Hong Kong Special Administrative Region (HKSAR), on 11 November 2004. The HKSAR has developed a HKSAR Implementation Plan (HKSARIP) in accordance with the Convention which formed part of the PRC’s National Implementation Plan (NIP) submitted to the Conference of the Parties (COP) of the Stockholm Convention in April 2007. The fourth and fifth meetings of the COP to the Convention held in 2009 and 2011 adopted amendments to Annexes A, B and C of the Convention to list 10 new POPs in the respective Annexes. The amendment entered into force for PRC, including HKSAR, on 26 March 2014. In accordance with the Convention, the PRC has to submit an updated NIP which includes the updated HKSARIP for the new POPs to the COP within two years of the date on which these amendments enter into force (i.e. 26 March 2016). At the sixth and seventh meetings of COP to the Convention held in 2013 and 2015 respectively, the COP agreed to list hexabromocyclododecane (HBCD) in Annex A, polychlorinated naphthalenes (PCN) in Annexes A and C, hexachlorobutadiene (HCBD) in Annex A, pentachlorophenol and its salts and esters (PCP) in Annex A to the Convention. Opportunity is taken to include also these new POPs into the present updated HKSARIP. The following Table 1 summarizes the types of use of the 12 initial POPs and 14 new POPs identified by the UNEP under the Convention. 2 Table 1: POPs listed in the Stockholm Convention POPs Year of Listing Type of POPs Pesticide Industrial Chemicals By-product Aldrin 2001  Chlordane  DDT  Dieldrin  Endrin  Heptachlor  Hexachlorobenzene (HCB)   Mirex  Toxaphene  Polychlorinated biphenyls (PCB)   Polychlorinated dibenzo-p-dioxins (PCDD)  Polychlorinated dibenzofurans (PCDF)  Alpha hexachlorocyclohexane (α-HCH) 2009   Beta hexachlorocylohexane (β-HCH)   Chlordecone  Hexabromobiphenyl (HBB)  Lindane (γ-HCH)  Pentachlorobenzene (PeCB)    Perfluorooctane sulfonic acid (PFOS), its salts and perfluorooctane sulfonyl fluoride (PFOSF)  Hexabromodiphenyl ether and heptabromodiphenyl ether (C-octaBDE)  Tetrabromodiphenyl ether and pentabromodiphenyl ether (C-pentaBDE)  Technical endosulfan and its related isomers (Endosulfan) 2011  Hexabromocyclododecane (HBCD) 2013  Polychlorinated naphthalenes (PCN) 2015   Hexachlorobutadiene (HCBD)   Pentachlorophenol and its salts and esters (PCP)  The POPs Unit of the Environmental Protection Department (EPD) of the Government of the HKSAR (HKSARG) is responsible for preparing and updating the HKSARIP, working on new legislation and its amendment to regulate non-pesticide hazardous chemicals, and coordinating matters relating to the implementation of the Convention in the HKSAR. The pesticide POPs are controlled by the Agriculture, Fisheries and Conservation Department of the HKSARG. Stakeholder consultation is an important process in the preparation of the 2nd HKSARIP. A stakeholder consultation workshop was convened on 23 March 2015 to seek views from relevant stakeholders on the POPs-related issues in Hong Kong 3 2. THE HKSAR BASELINE 2.1 The HKSAR Basic Profile The HKSAR is situated in the Pearl River Delta (PRD) at the south-eastern tip of Mainland China. It has a total area of 1,104 km2, comprising Hong Kong Island, the Kowloon Peninsula, the New Territories and 262 outlying islands. Hong Kong's climate is sub-tropical. Hong Kong has one of the finest deep-water ports in the world and is a well established international financial, trading and business hub. It is widely recognized as the world's freest economy (Heritage Foundation’s 2015 Index of Economic Freedom) and one of the most competitive economies in the world (ranked 4th by International Institute for Management Development in its World Competitiveness Yearbook 2014). Over the past few decades, there has been a structural transformation of the Hong Kong economy from manufacturing to service orientation. The local industrial activities have shrunk to a substantial extent in both variety and size as manufacturing enterprises have progressively relocated their production lines to the Mainland. On the other hand, trading and logistics, finance and banking, tourism, and a wide range of business services are becoming more important. With a population of 7.2 million, Hong Kong is one of the world's most densely populated cities (6,520 persons per km2 according to the 2014 data of the Census and Statistics Department). Over the years, Hong Kong has developed an efficient wholesale and retail network to cater for the growing consumption needs of a more affluent population. The dense population coupled with a high level of dynamic economic activities has exerted intense pressure on Hong Kong’s environment. This is further compounded by the effects of immense economic growth in the PRD, one of the fastest developing regions in the world. Since the 1980s, the HKSARG has been implementing various plans and programmes to meet the local environmental challenges. Pollution by toxic substances including POPs is an area of focus in Hong Kong, but one that has received increased attention in recent years. Programmes and researches for monitoring air, water, soil, sediment toxic pollutants have been established to assess background pollution and to better safeguard the environment and human health. 2.2 Environmental Policies and Legislative Framework for POPs Control and Management 2.2.1 Legislative Framework on POPs Control In implementing the Stockholm Convention, Parties will take measures to control/restrict the import, export, domestic production and use of intentionally produced POPs (pesticides and industrial 4 chemicals), to reduce and where possible to ultimately eliminate the production and release of unintentional POPs (dioxins/furans) from anthropogenic sources to the environment, and to impose proper handling and disposal of POPs-containing wastes. 2.2.1.1 Pesticides The pesticides are controlled under the Pesticides Ordinance (Cap 133) administered by the Agriculture, Fisheries and Conservation Department (AFCD) under the Food and Health Bureau (FHB). The import, manufacture, supply and retail of pesticides in Hong Kong are regulated by a licensing/permit system. In addition, all pesticides entering/leaving Hong Kong are required to be covered by an import/export licence issued under the Import and Export Ordinance (Cap 60) which, however, does not apply to pesticides that are in air transhipment cargoes and pesticides in transit. The Pesticides Ordinance, Cap 133, was amended in 2013 to include new provisions to ensure full compliance with the requirements of the Stockholm Convention on the control of POPs pesticides and the Rotterdam Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade (the Rotterdam Convention). The amended legislation came into operation on 27 January 2014. On 17 January 2014, the Office of the Commissioner of the Ministry of Foreign Affairs of PRC notified the Government of HKSAR that ratification for inclusion of the six pesticides ((i) alpha hexachlorocyclohexane, (ii) beta hexachlorocyclohexane, (iii) chlordecone, (iv) lindane, (v) pentachlorobenzene, and (vi) technical endosulfan and its related isomers) added to Stockholm Convention in 2009 and 2011 was completed and would take effect from 26 March 2014. PRC has also confirmed that the ratification would apply to HKSAR and enter into force on the same effective date. To such end, AFCD has completed legislative amendment exercise to add the six pesticides to Cap 133. The amendment commenced operation on 1 June 2014. 2.2.1.2 Hazardous Chemicals Control of hazardous chemicals is within the ambit of environmental policies administered by the Environmental Protection Department (EPD) under the Environment Bureau (ENB). Legislation and licensing are the major regulatory instruments. A number of environmental ordinances are also in place to deal with the control of air and water pollution and waste handling and disposal. They cover a wide range of chemicals which include hazardous chemicals. Relevant key environmental legislation includes:  Hazardous Chemicals Control Ordinance (Cap 595)  Air Pollution Control Ordinance (Cap 311)  Water Pollution Control Ordinance (Cap 358) 5  Waste Disposal Ordinance (Cap 354)  Environmental Impact Assessment Ordinance (Cap 499) 2.2.1.2.1 Hazardous Chemicals Control Ordinance (HCCO) The HCCO (Cap 595) came into operation on 1 April 2008 to regulate, through an activity-based permit system, the import, export, manufacture and use of non-pesticide POPs that have potentially harmful or adverse effects on human health or the environment. At present, the non-pesticide hazardous chemicals under the HCCO include such chemicals that are subject to regulation of the Stockholm Convention or the Rotterdam Convention. In view of the amendment in May 2009 to list 5 new non-pesticide POPs ((i) hexabromobiphenyl, (ii) hexabromodiphenyl ether and heptabromodiphenyl ether, (iii) pentachlorobenzene, (iv) tetrabromodiphenyl ether and pentabromodiphenyl ether and (v) perfluorooctane sulfonic acid, its salts and perfluorooctane sulfonyl fluoride), EPD amended the Schedules to the HCCO and the amendment order has come into operation since 1 January 2015. 2.2.1.2.2 Air Pollution Control Ordinance (APCO) The APCO (Cap 311) enacted in 1983 is the principal law for managing air quality. The Ordinance provides a statutory framework for controlling air pollution from stationary and mobile sources and enables the promulgation of subsidiary regulations to deal with specific air pollution problems. A number of subsidiary regulations targeted at major industrial sources, combustion processes and vehicle emissions could contribute to the reduction in emission of unintentionally produced POPs to the atmosphere are in place to control pollution from combustion sources. These include:  Air Pollution Control (Specified Processes) Regulations (Cap 311F)  Air Pollution Control (Furnaces, Oven and Chimneys) (Installation and Alteration) Regulations (Cap 311A)  Air Pollution Control (Smoke) Regulations (Cap 311C)  Air Pollution Control (Open Burning) Regulation (Cap 311O)  Air Pollution Control (Motor Vehicle Fuel) Regulation (Cap 311L)  Air Pollution Control (Vehicle Design Standards) (Emission) Regulations (Cap 311J)  Air Pollution Control (Emission Reduction Devices for Vehicles) Regulation (Cap 311U) 2.2.1.2.3 Water Pollution Control Ordinance (WPCO) The WPCO (Cap 358) enacted in 1980 is the principal law for managing water quality. The Ordinance provides for the establishment of Water Quality Objectives (WQOs) in relation to the 6 beneficial uses of water bodies and defines Water Control Zones (WCZs) for the entirety of Hong Kong waters within which discharges of effluent are subject to licensing control. The WQOs set for all WCZs specify that toxic substances in the water should not attain such levels as to produce significant toxic, mutagenic, carcinogenic or teratogenic effects in humans, fish or any other aquatic organisms, with due regard to biologically cumulative effects in food chains and to interactions of toxic substances with each other. The standards for effluent discharged into the various WCZs are specified in the Technical Memorandum on Standards for Effluents Discharged into Drainage and Sewerage Systems, Inland and Coastal Waters (TM). The TM prohibits the discharge of toxic substances (including fumigants, pesticides, polychlorinated biphenyls (PCB), polyaromatic hydrocarbons (PAHs), chlorinated hydrocarbons, flammable or toxic solvents, petroleum oil or tar and calcium carbide) to foul sewers, inland and coastal waters. It also specifies numerical discharge limits for total suspended solids, Biochemical Oxygen Demand (BOD), oil and grease, toxic metals and chemical compounds such as cyanide, phenol, sulphide, total residual chlorine and surfactants. 2.2.1.2.4 Waste Disposal Ordinance (WDO) The WDO (Cap 354) enacted in 1980 is the principal law for environmentally sound management of waste collection and disposal. The Ordinance provides control over the handling and disposal of livestock waste and chemical waste, the import and export of wastes (including implementation of the Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and their Disposal) and the licensing of waste collection services and waste disposal facilities. Its subsidiary legislation, the Waste Disposal (Chemical Waste) (General) Regulation (Cap 354C), provides for the control, through licensing requirements, of packaging, labeling, storage, collection and disposal (including treatment, reprocessing and recycling) of chemical waste, and the registration of chemical waste producers. Chemical waste is defined under the regulation in a schedule of specific substances and chemicals based on their potential risk to human health and/or pollution to the environment. Disposal of chemical wastes containing PCB and unintentionally produced POPs is controlled under the WDO. 2.2.1.2.5 Environmental Impact Assessment Ordinance (EIAO) The EIAO (Cap 499) enacted in 1997 provides a legal instrument for assessing potential environmental impacts of designated projects at the planning stage and for the protection of the environment. The Ordinance contains provisions to avoid, minimize and control adverse impacts to the local environment of designated projects through an environmental permit and environmental monitoring and audit system. The Technical Memorandum for Environmental Impact Assessment 7 Ordinance (EIAO-TM) sets out the technical requirements for the EIA process and the criteria for determining the environmental acceptability of designated projects, stipulating that any adverse environmental effects should be avoided to the maximum practicable extent and minimized to within acceptable levels. 2.2.2 Roles and Responsibilities of Relevant Government Bureaux/Departments Table 2 summarizes the roles and responsibilities of Government bureaux/departments in protecting the environment and human health against the potential harmful effects of hazardous chemicals including POPs. Table 2: Roles and Responsibilities of Relevant Bureaux/Departments in the HKSARG in Environmental and Human Health Protection Bureaux/Departments Relevant Roles and Responsibilities Legislative Instruments Development Bureau Drainage Services Department  Provide an effective system for sewage collection, treatment and disposal in an environmentally responsible manner to ensure public safety and health  Maintain a database on effluent/sludge production in sewage treatment works  Sewage Services Ordinance (Cap 463) Water Supplies Department  Provide quality water services and ensure public health and safety through routine monitoring of toxic chemicals in drinking water Environment Bureau Environmental Protection Department  Regulate the import, export, manufacture and use of non-pesticide POPs through an activity-based permit system  Impose “downstream” control on air emission, effluent discharge and waste disposal (including chemical waste) of environmental toxic pollutants  Conduct environmental monitoring to assess compliance and provide a basis for the planning of pollution control strategies  Set out technical requirements for the environmental impact assessment (EIA) processes at the planning stage, to avoid, minimize and control  Hazardous Chemicals Control Ordinance (Cap 595)  Air Pollution Control Ordinance (Cap 311)  Water Pollution Control Ordinance (Cap 358)  Waste Disposal Ordinance (Cap 354)  Environmental Impact Assessment Ordinance (Cap 499) 8 Financial Services and Treasury Bureau Census and Statistics Department  Maintain a database of vital statistics to facilitate research, planning and decision– making within the Government and in the community Food and Health Bureau Agriculture, Fisheries and Conservation Department  Control the manufacture, import, supply, storage, and retail sale of pesticides in Hong Kong  Administer the import and export licensing control system of pesticides in Hong Kong  Pesticides Ordinance (Cap 133)  Import and Export Ordinance (Cap 60) Department of Health  Execute health care policies and statutory functions and safeguard the health of the community through promotive, preventive, curative and rehabilitative services Food and Environmental Hygiene Department  Ensure food safety through food surveillance and certification, conduct dietary risk assessment and risk communication and advice on food safety standards  Public Health and Municipal Services Ordinance (Cap 132) Government Laboratory  Provide laboratory analytical services to Government departments on samples of various matrices to meet client departments’ respective responsibilities for environmental protection, public health and safety Labour and Welfare Bureau Labour Department  Control the manufacture, process or work involving certain specified hazardous chemicals (such as carcinogenic substances) to protect workers’ safety  Factories and Industrial Undertakings Ordinance (Cap 59)  Occupational Safety and Health Ordinance (Cap 509) Security Bureau Customs and Excise Department  Control the import and export of commodities and certain prohibited articles by air, land and sea.  Import and Export Ordinance (Cap 60) Fire Services Department  Control the manufacture, labelling, packaging, storage, transport (on land and at sea) and use of dangerous goods (including corrosive, flammable and poisonous substances, etc)  Dangerous Goods Ordinance (Cap 295) Transport and Housing Bureau Marine Department  Prevent, mitigate and repair pollution of and damage to the waters of Hong Kong arising from oil spillage, and from contamination of the sea by hazardous substances discharged from ships  Merchant Shipping (Prevention and Control of Pollution) Ordinance (Cap413)  Merchant Shipping (Safety) Ordinance (Cap 369) 9 2.2.3 Obligations under Other Related Environmental Conventions Applicable to the HKSAR 2.2.3.1 The Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and Their Disposal The Basel Convention aims to protect the environment and human health from the harmful effects of hazardous waste. The Convention defines the global means to: (a) minimize hazardous waste at source; (b) strictly control the transboundary movement of hazardous waste; and (c) ensure that the hazardous wastes are disposed of in an environmentally sound manner. The Convention requires that a prior informed consent system be put in place to control and monitor the transboundary movement of hazardous waste among the Parties to the Convention. The Convention was adopted by the Conference of Plenipotentiaries in Basel in 1989 and entered into force in May 1992. The Central People’s Government (CPG) of PRC deposited its instrument of ratification with the Secretary-General of the United Nations on 17 December 1991. The Convention is also applicable to the HKSAR. The Ministry of Environmental Protection (MEP) is the National Focal Point of the PRC for the Convention and EPD is the designated Competent Authority of the HKSAR for implementing the Convention in Hong Kong. Transboundary movement of hazardous waste as specified in the 7th Schedule to the WDO is subject to import/export control provided for in that Ordinance. EPD has established an information exchange network with both local and oversea control authorities to monitor waste shipment activities and to collect intelligence of dubious waste shipment for joint enforcement action to effectively combat illegal shipment of hazardous waste in the region. 2.2.3.2 The Rotterdam Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade The Rotterdam Convention aims to promote shared responsibility and cooperative efforts among the contracting parties in the international trade of certain hazardous chemicals and pesticides in order to protect human health and the environment from potential harm. The Convention has introduced a mandatory prior informed consent procedure (PIC procedure) to monitor and control the import and export of certain hazardous chemicals and disseminate national importing decisions to the contracting parties. The Rotterdam PIC procedure applies to 33 pesticides, (including 3 severely hazardous pesticide formulations) and 14 industrial chemicals. The Convention was adopted at the Diplomatic Conference held in Rotterdam on 10 September 1998 and entered into force on 24 February 2004. The Convention became applicable to the PRC and the HKSAR on 20 June 2005 and 26 August 2008 respectively. AFCD is responsible for the control of PIC pesticides while EPD is responsible for the control of PIC industrial chemicals by enforcing the Pesticides Ordinance and the Hazardous Chemicals Control Ordinance respectively. 10 2.3 Overview of the Current POPs Issue in the HKSAR 2.3.1 Source Inventories of POPs 2.3.1.1 Trade, Production and Use of Intentional POPs 2.3.1.1.1 Pesticides Nine pesticides (aldrin, chlordane, DDT, dieldrin, endrin, heptachlor, HCB, mirex and toxaphene), five pesticides (α-hexachlorocyclohexane (α-HCH), β-hexachlorocyclohexane (β-HCH), chlordecone, lindane (γ-HCH), PeCB) and one pesticide (endosulfan) have been identified as intentionally produced POPs by the Convention and its amendments approved by PRC, targeted for elimination or restriction on production and use. In Hong Kong, these pesticides were either never registered or had their registration status cancelled for many years due to toxicological or environmental concern. Initial POPs Aldrin Chlordane DDT Dieldrin Endrin Heptachlor HCB Mirex Toxaphene 1988* 1991* 1988* 1988* NR NR NR 1997* 1984* New POPs α-HCH β-HCH Chlordecone γ-HCH PeCB Endosulfan NR 1991* NR 1991* NR 2013* *: The year in which all use and trade activities prohibited unless under a pesticide permit granted in exceptional NR: Never registered Source: AFCD, 2014 Except for the import of 1,000 kg of endosulfan for local consumption in 2011, there was no import, export, manufacture, use, stockpiling, nor transshipment of the other 14 pesticide POPs in Hong Kong for the past 3 years (2011–2013). These 14 pesticide POPs include aldrin, chlordane, DDT, dieldrin, endrin, heptachlor, HCB, mirex, toxaphene, α-HCH, β-HCH, chlordecone, γ-HCH and PeCB. 2.3.1.1.2 Industrial Chemicals To identify the trade, use and manufacture of the 10 industrial POPs listed in the Stockholm Convention, a comprehensive survey was conducted in 2014 with the relevant trade and industries of Hong Kong. The use of POPs in laboratories is not controlled under the Convention. This specific use is however included in the survey to show the usage of these chemicals in HKSAR. 11 Polychlorinated biphenyls (PCB) In total, 25 stakeholders in Hong Kong have a stockpile of 1.9 x 10-2 kg of PCB and all these PCB are stored as the reference standard in laboratory testing. On the other hand, a stakeholder stored and used 1.6 x 103 kg of electrical transformers that contains PCB for the purpose of welding power supply during the years from 2011 to 2013. For the usage of chemicals, during the years from 2011 to 2013, there were about 1.7 x 10-3 kg of PCB consumed for the purpose of reference standard in laboratory testing. Within the same period, the purpose of importing and exporting PCB was to re-sell to local and overseas laboratories, and the total quantities of PCB imported and exported were around 3.0 x 10-2 kg and 1.5 x 10-2 kg, respectively. Hexabromobiphenyl (HBB) 18 stakeholders in Hong Kong have a stockpile of 3.3 x 10-3 kg of HBB and all these HBB are stored as the reference standard in laboratory testing. For the usage of chemicals, during the years from 2011 to 2013, there were about 1.8 x 10-3 kg of HBB consumed for the purpose of reference standard in laboratory testing. Within the same period, the purpose of importing and exporting HBB was to re-sell to local and overseas laboratories, and the total quantities of HBB imported and exported were around 6.0 x 10-2 kg and 1.5 x 10-2 kg, respectively. Tetrabromodiphenyl ether and pentabromodiphenyl ether (C-pentaBDE) 16 stakeholders in Hong Kong have a stockpile of 2.4 x 10-3 kg of C-pentaBDE and all these chemicals are stored as the reference standard for laboratory testing. For the usage of chemicals, during the years from 2011 to 2013, there were about 1.4 x 10-1 kg of C-pentaBDE consumed for the purpose of reference standard in laboratory testing. Within the same period, the purpose of importing and exporting C-pentaBDE was to re-sell to local and overseas laboratories, and the total quantities of C-pentaBDE imported and exported were around 1.1 x 10-1 kg and 1.5 x 10-2 kg, respectively. Hexabromodiphenyl ether and heptabromodiphenyl ether (C-octaBDE) 14 stakeholders in Hong Kong have a stockpile of 2.4 x 10-3 kg of C-octaBDE and all these chemicals are stored as the reference standard in laboratory testing. For the usage of chemicals, during the years from 2011 to 2013, there were about 2.9 x 10-2 kg of C-octaBDE consumed for the purpose of reference standard in laboratory testing. Within the same 12 period, the purpose of importing and exporting C-octaBDE was to re-sell to local and overseas’ laboratories, and the total quantities of C-octaBDE imported and exported were around 1.1 x 10-1 kg and 1.5 x 10-2 kg, respectively. Pentachlorobenzene (PeCB) 12 stakeholders in Hong Kong have a stockpile of 2.4 x 10-2 kg of PeCB and all these chemicals are stored as the reference standard in laboratory testing. For the usage of chemicals, during the years from 2011 to 2013, there were about 4.2 x 10-3 kg of PeCB consumed for the purpose of reference standard in the laboratory testing. Within the same period, the purpose of importing and exporting PeCB is to re-sell to local and overseas laboratories, and the total quantities of PeCB imported and exported were around 9.3 x 10-2 kg and 3.0 x 10-3 kg, respectively. Perfluorooctane sulfonic acid (PFOS), its salts and perfluorooctane sulfonyl fluoride (PFOSF) 15 stakeholders in Hong Kong have a stockpile of 1.5 x 10-1 kg of PFOS/PFOSF and all these chemicals are stored as the reference standard in laboratory testing. On the other hand, one of Government Departments (Fire Services Department) imported (1.2 x104 L), used (5.9 x103 L) and stored (7.8 x104 L) the aqueous film forming foam that may contain PFOS/PFOSF for the firefighting purpose during the years from 2011 to 20131. For the usage of chemicals, during the years from 2011 to 2013, there were about 5.3 x 10-3 kg of PFOS/PFOSF consumed for the purpose of reference standard in the laboratory testing. Within the same period, the purpose of importing and exporting PFOS was to re-sell to local laboratories, and the total quantities of imported PFOS/PFOSF was around 1.5 x 10-1 kg and there was no export on chemicals containing PFOS/PFOSF from Hong Kong. Hexabromocyclododecane (HBCD) 9 stakeholders in Hong Kong have a stockpile of 1.0 x 10-1 kg of HBCD and all these chemicals are stored as the reference standard in laboratory testing. During the years from 2011 to 2013, there was no either import or export on chemicals containing HBCD in Hong Kong. 1 China has applied for using PFOS/PFOSF in fire-fighting foam as an acceptable purpose in accordance with Annex B of the Convention. As required under Article 6 of the Convention, the stock of PFOS/PFOSF and its waste should be managed and disposed of in an environmentally sound manner. HKSAR has taken measures in accordance with Articles 6 of the Convention to achieve proper management of PFOS/PFOSF containing aqueous film-forming foam fire extinguishing agent (see page 55, Action item No. 8). 13 Chlorinated naphthalenes 3 Industry Groups (HOKLAS Certified Laboratories, Government Departments and Other HCCO Permit Holders) involved in import, storage and/or use of chlorinated naphthalenes. These Industry Groups include 5 stakeholders. In total, relevant stakeholders in Hong Kong have a stockpile of 2.4 x 10-4 kg of chlorinated naphthalenes and all these chemicals are stored as the reference standard in laboratory testing. For the usage of chemicals, during the years from 2011 to 2013, there were about 2.0 x 10-5 kg of chlorinated naphthalenes consumed for the purpose of reference standard in the laboratory testing. Within the same period, the purpose of importing chlorinated naphthalenes was to re-sell to local laboratories, and the total quantities of imported chlorinated naphthalenes was around 9.0 x 10-5 kg and there was no export on chemicals containing chlorinated naphthalenes from Hong Kong. Hexachlorobutadiene (HCBD) 4 Industry Groups (Academic, HOKLAS Certified Laboratories, Government Departments and Other HCCO Permit Holders) involved in import, storage and/or use of hexachlorobutadiene. These Industry Groups include 8 stakeholders. In total, relevant stakeholders in Hong Kong have a stockpile of 1.3 x 10-1 kg chemicals of hexachlorobutadiene and all these chemicals are stored as the reference standard in laboratory testing. For the usage of chemicals, during the years from 2011 to 2013, there were about 9.5 x 10-3 kg of hexachlorobutadiene consumed for the purpose of reference standard in laboratory testing. Within the same period, the purpose of importing hexachlorobutadiene was to re-sell to local laboratories, and the total quantities of imported hexachlorobutadiene was around 9.0 x 10-2 kg and there was no export on chemicals containing hexachlorobutadiene from Hong Kong. Pentachlorophenol and its salts and esters (PCP) 4 Industry Groups (Academic, HOKLAS Certified Laboratories, Government Departments and Other HCCO Permit Holders) involved in import, export, storage and/or use of pentachlorophenol and its salts and esters. These Industry Groups include 17 stakeholders. In total, relevant stakeholders in Hong Kong have a stockpile of 5.7x 10-1 kg chemicals of pentachlorophenol and its salts and esters and all these chemicals are stored as the reference standard in laboratory testing. For the usage of chemicals, during the years from 2011 to 2013, there were about 6.5 x 10-3 kg of pentachlorophenol and its salts and esters consumed for the purpose of reference standard in laboratory testing. Within the same period, the purpose of importing pentachlorophenol and its salts and esters was to re-sell to local laboratories, and the total quantities of pentachlorophenol and its salts and esters imported and exported were around 1.5 x 10-1 kg and 3.0 x 10-3 kg, respectively. 14 Short-chained chlorinated paraffins (proposed POPs to be listed) 2 Industry Groups (HOKLAS Certified Laboratories and Other HCCO Permit Holders) involved in import, export, storage and/or use of short-chained chlorinated paraffins. These Industry Groups include 10 stakeholders. In total, relevant stakeholders in Hong Kong have a stockpile of 1.3 x 10-3 kg chemicals of short-chained chlorinated paraffins and all these chemicals are stored as the reference standard in laboratory testing. For the usage of chemicals, during the years from 2011 to 2013, there were about 1.4 kg of short-chained chlorinated paraffins consumed for the purpose of reference standard in laboratory testing. Within the same period, the purpose of importing and exporting short-chained chlorinated paraffins is to re-sell to local laboratories, and the total quantities of short-chained chlorinated paraffins imported and exported were around 1.5 x 10-1 kg and 2.0 x 10-3 kg, respectively. 2.3.1.2 Release of Unintentional POPs as by-Products 2.3.1.2.1 PCDD (Dioxins) and PCDF (Furans) Dioxins (PCDD) and furans (PCDF) are unintentional by-products of industrial and combustion processes. The source inventory of PCDD/PCDF in the HKSARIP 2006 was prepared according to the “Standardized Toolkit for Identification and Quantification of Dioxin and Furan Releases, Edition 2.1” which was established in 2005. Subsequently, the new “Toolkit for Identification and Quantification of Releases of Dioxins, Furans and Other Unintentional POPs” was published in January 2013 by the UNEP. This new toolkit is used to update the local Source Groups and categories of the local emission inventory for 2012. The number and order of the proposed source inventory for 2012 are intentionally kept according to the “Guidance for Developing a National Implementation Plan for the Stockholm Convention on Persistent Organic Pollutants (updated in 2012 to include the POPs listed in 2009 and 2011)”. Regarding the 9 source categories identified for the source inventory of PCDD/PCDF in Hong Kong, EPD has provided the latest environmental monitoring result of the 9 sources and estimated the annual releasing quantity from these sources through air, water, land, product and residue in the year of 2012. The TEQ of the unintentionally released PCDD/PCDF from each of 9 identified source categories and through 5 emission routes (i.e. air, water, land, product and residue) is shown in Table 3. 15 Table 3: Summary of Annual PCDD/PCDF Emission Inventory in Hong Kong for the Year 2012 Group Source Categories Annual Release (g TEQ/a) All Routes (g TEQ/a) Air Water Land Product Residue 1 Waste incineration 0.0010 0.0000 0.0000 0.0000 0.2549 0.2559 2 Ferrous and non-ferrous metal production 0.0003 0.0000 0.0000 0.0000 13.2052 13.2055 3 Heat and power generation 1.9092 0.0000 0.0000 0.0000 0.2465 2.1557 4 Production of mineral products 0.0895 0.0000 0.0000 0.0000 0.0495 0.1390 5 Transportation 0.9898 0.0000 0.0000 0.0000 0.0000 0.9898 6 Open burning processes 1.8746 0.0000 1.8510 0.0000 0.0000 3.7256 7 Production of chemicals and consumer goods 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 8 Waste disposal 0.0000 0.4686 0.0000 0.0040 25.3386 25.8112 9 Miscellaneous 0.1121 0.0000 0.0000 0.0000 0.0987 0.2108 Total (g TEQ/a) 4.9765 0.4686 1.8510 0.0040 39.1934 46.4935 Source: EPD 2014 In 2012, there was an annual release of 46.5 g TEQ dioxins/furans to the environment via all vectors. Relative contributions of different categories are shown in Figure 1. The top 3 contributing categories of dioxin/furan emission were “Waste disposal” (55.5%), “Ferrous and Non-Ferrous Metal Production” (28.4%) and “Open Burning Process” (8.0%). Together, they represented 91.9% of the total. A “zero” emission value was assigned to Category 7 “Production of Chemicals and Consumer Goods” due to a general lack of local data on the contamination level of dioxins/furans in consumer goods. Figure 1 – Contribution of Various Emission Source Categories to Annual Dioxin/Furan Emission Waste disposal 55.5% Ferrous and non‐ ferrous metal production 28.4% Open burning processes 8.0% Heat and power generation 4.6% Transportation 2.1% Waste incineration 0.6% Miscellaneous 0.5% Production of mineral products 0.3% 16 On a vector basis (Figure 2), the major route of release was “residues”, responsible for 84.3% of the total, followed by “air” (10.7%) and “land” (4.0%). The “water” and “products” together contributed to only 1.01% of the total annual release. It was observed that for the “land”, “water” and “products” vectors, a “blank” release value was assigned to many classes of potential emission sources due to a general lack of data on emission factors. Figure 2 – Percentage of Dioxin/Furan Emission on a Vector Basis Release of Dioxins/Furans to Air The 2012 annual dioxin/furan release to the atmosphere was 5.0 g TEQ. The relative contributions of different source categories to air emission are presented in Figure 3. A further breakdown of the nine categories of emission sources revealed that the top 3 contributing classes of local processes were: “Heat and Power Generation” (38.4%), “Open Burning Processes” (37.7%) and “Transportation” (19.9%). These three classes of processes together accounted for 96% of the total annual air emission while the others were responsible for the remaining percentage. Figure 3 – Contribution of Different Source Categories to Annual Dioxin/Furan Emission to Air Residue 84.3% Air 10.7% Land 4.0% Water 1.01% Product 0.01% Heat and power generation 38.36% Open burning processes 37.67% Transportation 19.9% Miscellaneous 2.3% Production of mineral products 1.8% Waste incineration 0.02% Ferrous and non‐ ferrous metal production 0.006% 17 Release of Dioxins/Furans to Water The 2012 annual dioxin/furan release to the local marine environment was 0.47 g TEQ, contributed solely by the “Waste Disposal” category. Sewage treatment and landfill leachate contributed to the total annual release of dioxin/furan to water. Release of Dioxins/Furans to Land For release “to land”, the only category with an EF available was “Open Burning Processes”, which amounted to 1.85 g TEQ. Burning of biomass and accidental fires contributed to the total annual release of dioxin/furan to land. There was a general lack of local information on other potential sources of dioxin/furan release to land. Release of Dioxins/Furans in Products The 2012 annual dioxin/furan release “in products” was 0.004 g TEQ, from the “Waste Disposal” category. Within this category, the sole contributing class of emission sources was “composting”. Release from composting was estimated using an UNEP generic EF for composting of organic wastes separated at source or green material. The compost was used as product for landscaping and horticulture work. There was a general lack of local information on other potential sources of dioxin/furan release in products. Release of Dioxins/Furans in Residues The 2012 annual dioxin/furan release “in residues” was 39.19 g TEQ. The relative contributions of different source categories to emission in residues are presented in Figure 4. A further breakdown of the nine categories of release sources revealed that the top three contributing categories of local processes were: “Waste Disposal” (64.7%), “Ferrous and Non-Ferrous Metal Production” (33.7%), and “Waste Incineration” (0.7%). These three classes of processes together accounted for 99.1% of the total annual dioxin/furan release in residues. 18 Figure 4 – Contribution of Different Source Categories to Annual Dioxin/Furan Emission to Residues 2.3.1.2.2 Hexachlorobenzene (HCB) Among the 7 types of unintentionally produced POPs, PCDD/PCDF have never been intentionally produced for any reason but unintentionally produced, and PCB, HCB and PeCBs are also unintentionally formed, usually from the same sources that produce PCDD/PCDF. However, unlike PCDD/PCDF, PCB, HCB and PeCBs have also been manufactured and used for specific purposes, their intentional production and use being higher than the unintentional formation and release. HCB has been widely used as a pesticide to protect the seeds of onions and sorghum, wheat and other grains against fungus. It has also been used to make fireworks, ammunition and synthetic rubber. It is also used as a solvent in the production of pesticide. HCB can be unintentionally produced as a by-product or waste material in the production of several types of organic pesticides, such as tetrachloroethylene, trichloroethylene, carbon tetrachloride, chlorine, dimethyl tetrachloroterephthalate, vinyl chloride, atrazine, propazine, simazine, pentachloronitrobenzene, and mirex. It is also a contaminant in several pesticides including dimethyl tetrachlorophthalate and pentachloronitrobenzene. By reviewing the “Toolkit for Identification and Quantification of Releases of Dioxins, Furans and Other Unintentional POPs” updated in January 2013, there is incomprehensive estimation for all emission source of HCB as a by-product in the toolkit. Among the 10 Source Groups provided by the toolkit for the identifying and estimating the release source of PCDD/PCDF, there are 5 Source Groups including 12 Source Categories and 45 Source Classes being available for estimating the emission factors of unintentionally released HCB. Waste disposal 64.7% Ferrous and non‐ ferrous metal production 33.7% Waste incineration 0.7% Heat and power generation/cooking 0.6%Miscellaneous 0.3% Production of mineral products 0.1% 19 However, there is limited information on the comprehensive release of HCB as an unintentionally produced POP from combustion and/or as an intermediate during industrial processes in Hong Kong. HCB is a raw material for the production of many agricultural chemicals such as pentachlorophenol (PCP), quintozene (PCNB), chlorthal-dimethyl (TCTP), chlorothalonil and picloram, and remains as an impurity in these products. Apart from PCP, all other four agricultural chemicals are registered pesticides in Hong Kong. Records of their trading for the period 2011 – 2013 revealed that PCNB and chlorothalonil had been imported for local use. In the absence of information on the actual percentage of HCB as impurity in any of these pesticides, the potential annual release of HCB as an unintentional by-product to the local environmental due to their domestic applications could not be estimated. However, the relative contribution was likely to be insignificant. 2.3.1.2.3 Polychlorinated biphenyls (PCB) PCB are a class of synthetic organic chemicals. Since 1930, PCB were used for a variety of industrial uses (mainly as dielectric fluids in capacitors and transformers but also as flame retardants, ink solvents, plasticizers, etc.) because of their chemical stability. PCB have been used as coolants and lubricants in transformers, capacitors and other electrical equipment because they do not burn easily and are good insulators. Among other things, products that may contain PCB include old fluorescent lighting fixtures and electrical devices containing PCB capacitors. PCB are also fire resistant, have a low electrical conductivity, high resistance to thermal breakdown and a high resistance to oxidants and other chemicals. By reviewing the “Toolkit for Identification and Quantification of Releases of Dioxins, Furans and Other Unintentional POPs” updated in January 2013, there is still incomprehensive estimation for all emission source of PCB as by-products in the updated version of toolkit. Among the 10 Source Groups provided by the toolkit for identifying and estimating the release source of PCDD/PCDF, there are 5 Source Groups including 15 Source Categories and 59 Source Classes being available for estimating the emission factors of unintentionally released PCB. Similarly with HCB, there is also limited information on the comprehensive release of PCB as unintentionally produced POPs in Hong Kong. PCB are known to be produced as unintentional combustion by-products of incineration and combustion processes. The Annexes of the “Toolkit for Identification and Quantification of Releases of Dioxins, Furans and Other Unintentional POPs” from UNEP contained emission factors and sources for PCB. Local information on the release of PCB from known emission sources is scarce. PCB emission factors to air have been determined in a measurement campaign in France (Delepine et al. 2011). For high technology MSW incinerators, emission factors in the range of 0.004 – 0.017 μg TEQ/ton of MSW incinerated are calculated for dioxin-like PCB, and between 2 and 64 μg/ton of MSW incinerated for indicator PCB. For high technology hazardous waste (HW) incinerators, emission factors in the range of 0.0004­0.237 μg TEQ/ton of HW incinerated are calculated for dioxin­like PCB, and between 6 - 154 μg/ton of HW incinerated for indicator PCB. Lastly, 20 for high technology sewage sludge incinerators, emission factors in the range of 0.001 ­ 0.004 μg TEQ/ton of sewage sludge are calculated for dioxin­like PCB, and between 12 – 28 μg/t of sewage sludge incinerated for indicator PCB. 2.3.1.2.4 alpha-Hexachlorocyclohexane (α-HCH) and beta-Hexachlorocylohexane (β-HCH) α-HCH and β-HCH are unintentionally produced as by-products in the production of the insecticide lindane, which has been ceased to produce in Hong Kong. Furthermore, HCHs were banned (deregistered) in Hong Kong in 1991 by the Pesticides Ordinance. The relative contribution, therefore, was likely to be insignificant. There are currently no standardized toolkits available for identifying and estimating the release sources of α-HCH and β-HCH. 2.3.1.2.5 Pentachlorobenzene (PeCB) PeCB is produced unintentionally during combustion, thermal and industrial processes. There was comparatively little local information on the release of PeCB as an unintentionally produced POP from combustion, thermal and industrial processes in Hong Kong. There are currently no standardized toolkits available for identifying and estimating the release sources of PeCBs. 2.3.1.3 Contaminated Sites Three local dioxin-contaminated historical activity sites were identified and documented by EPD during 2000-2004. The Choy Lee Shipyard site (located at Penny’s Bay in Lantau Island) was the major contaminated site, contributing to 98.6% of the estimated total dioxin stockpile due to historical improper open burning of waste materials on-site. Decontamination of the Choy Lee Shipyard site and incineration of all dioxin-residue recovered from the contaminated soil at the Chemical Waste Treatment Centre (CWTC) was completed in March 2005. The other two minor contaminated sites were phased-out incineration plants at Kwai Chung, the New Territories and Kennedy Town, Hong Kong Island. Together, they were responsible for only 1.4% of the estimated total dioxin stockpile. The remediation of dioxin-contaminated soil or removal of dioxins containing materials for these sites has been completed. There were no known existing sites with major PCB or POPs pesticides contamination in Hong Kong. In addition, the landfills and the confined contaminated mud disposal facility at East Sha Chau would represent potential sinks of POPs, not posing immediate threats to the environment or human health. 2.3.2 Environmental Levels of POPs 2.3.2.1 Contamination Levels of POPs in Environmental Media The aim of this section is to present the quantities of the POPs contaminating the surrounding through environmental media (e.g. ambient air, water, soil, sediment, vegetation). The EPD initiated a Toxic Substances Monitoring Programme in 2004. The purpose is to monitor and assess the extent of toxic 21 substances pollution in the Hong Kong marine environment, including marine water, sediment and biota, and potential land-based pollution sources, such as sewage effluent as well as river water and storm runoff. The recent monitoring data about most of the initial and new POPs were collected in 2010 to 2012 from 10 sampling stations in 7 coastal locations (Deep Bay, North Western, Southern, Victoria Harbour, Junk Bay, Mirs Bay and Tolo Harbour). Regarding the updated contamination levels of the 10 new POPs of ambient air, river water, soil and marine sediment, except for HBCD, EPD conducted a consultancy study “Investigation on the Use of PFOS in Aqueous Fire Fighting Foam and the Environmental Levels of New POPs Listed under the Stockholm Convention” in 2013 (EPD Investigation Study 2013) that tested the levels of PFOS and PFOSF in aqueous firefighting foam (AFFF) found in major AFFF users, and the environmental levels of 10 new POPs in ambient air, water, soil and sediment. A summary of the contamination levels of POPs in the representative environmental media including ambient air, surface water, surface sediment, surface soil and vegetation is presented in Table 4. 2.3.2.1.1 Ambient Air For inventory of period 2002 to 2004, contamination level of ambient air was mainly compiled based on government’s monitoring studies. Ambient levels of total PCB and dioxins/furans (PCDD/PCDF) have been routinely monitored at two urban locations (Tsuen Wan and Central & Western District) in Hong Kong since mid-1997. In addition, dioxin data collected from a year-long dioxin-monitoring project (2000-2004) that targeted suspected local emission source at Tsing Yi (where Chemical Waste Treatment Centre (CWTC) is located) and from an ad hoc study conducted at Tai Mo Shan (2000-2001) were included in the calculation of the mean ambient air dioxin/furan concentration. Furthermore, ambient levels of aldrin, chlordane, DDT, dieldrin, endrin, HCB, heptachlor, mirex, PCB, toxaphene were monitored on a project basis at Tap Mun, Yuen Long and Tsuen Wan in 2004 by EPD. The results of this study are contained in the “First Regional Monitoring Report for Asia – Pacific Region (Dec. 2008)”. The recent ambient air contamination levels of POPs monitored by EPD during 2011 to 2013 covered 19 out of the 23 concerned POPs including all 12 initial POPs and 7 newly listed POPs, except 3 newly listed POPs (HBB, C-octaBDE and C-pentaBDE) as well as the proposed POP, HBCD. EPD Investigation Study 2013 covered ambient air contamination levels of 10 newly listed POPs, except for HBCD, which included HBB, C-octaBDE and C-pentaBDE that were not covered by the EPD monitoring programme of POPs. . A recent academic study conducted by Wang, W. et al. from HKBU in 2014 also covered the levels of PBDE which can represent the levels of C-octaBDE and C-pentaBDE. 22 In addition, the environmental level of HBCD in the ambient air is lack of local academic research or published data between 2006 and 2014. Initial POPs Only 9 initial POPs were reported with ambient air contamination levels in the HKSARIP 2006, while chlordane, mirex and toxaphene were not reported. However, all 12 initial POPs (the Dirty Dozen) were reported in the EPD monitoring programme of POPs (during 2013). Covered by the EPD monitoring programme of POPs (during 2013), all contamination levels of the 9 initial POPs, including aldrin, DDT, dieldrin, endrin, heptachlor, HCB, PCB, PCDD and PCDF, in the ambient air can now be renewed. The recent contamination levels of 6 initial POPs including DDT (12.19 pg/m3), heptachlor (2.39 pg/m3), HCB (44.88 pg/m3), PCB (dioxin-like PCBs: 0.003 pg WHO-TEQ /m3and marker PCBs: 19.1 pg/m3) and PCDD/PCDF (0.044 pg I-TEQ/m3) were detected to have a lower value than the contamination levels reported in the HKSARIP 2006 (DDT: 0.05 ng/m3, Heptachlor: 0.03 ng/m3, HCB: 0.16 ng/m3, PCBs: 0.48 ng/m3 and PCDD/PCDF: 0.06 pg I-TEQ/m3). Regular monitoring of dioxin-like PCB (PCB with TEFs (12 congeners: 77, 81, 105, 114, 118, 123, 126, 156, 157, 167, 169, and 189) from January 2010 was commenced as well as marker PCB (7 congeners: 28, 52, 101, 118, 138, 153, and 180) to replace total PCB monitoring from May 2010. The contamination levels of 3 other initial POPs (aldrin, dieldrin and endrin) were detected to be lower than the detection limit (0.02 ng/m3) in the HKSARIP 2006. Due to recent technological advances, the latest EPD monitoring programme had reported the contamination levels of these 3 initial POPs using lower detection limits. Therefore, by adopting different detection limits, the 2006 and current ambient air contamination levels of aldrin, dieldrin and endrin are not directly comparable. Another 3 initial POPs, including chlordane, mirex and toxaphene, were newly measured in the EPD monitoring programme of POPs (during 2013) and were detected at values of 4.61 pg/m3, 5.3 pg/m3, and below the detection limit (0.3 pg/m3), respectively. Newly Listed POPs The EPD Investigation Study 2013 that also measured the contamination levels of 10 newly listed POPs in ambient air, except for HBCD, but concentrations of all the air samples were found to be below the detection limits. The more recent EPD monitoring programme of POPs (during 2013) covered 7 out of the 11 newly listed POPs including α-HCH (2.22 pg/m3), β-HCH (2.33 pg/m3), Chlordecone (BDL), γ-HCH (3.32 pg/m3), PeCB (4.88 pg/m3), PFOS/PFOSF (4.12 pg/m3) and endosulfan (143.53 pg/m3) by adopting lower detection limits than the previous limits in the EPD Investigation Study 2013. Only the EPD Investigation Study 2013 found contamination levels of C-octaBDE and C-pentaBDE in ambient air. Wang, W. et al. from HKBU published a study report in 2014 on the contamination levels of PBDE in residential air particulate phase (Total PBDE: 43.8 pg/m3, BDE-99/pent-BDE: 17.3 pg/m3). 23 No references, including official monitoring data and published academic studies, could be found on the contamination level of HBCD in the ambient air. 2.3.2.1.2 Marine Water The major information sources of contamination levels of surface water were government studies, while data from local academia was very limited. In HKSARIP 2006’s report, only marine water was included in the measurement of surface water for the contamination levels of all 12 initial POPs. In which, only PCDD/PCDF could be detected with a value above the detection limits, while the other 10 initial POPs were identified to be below the detection limits. Initial POPs Among the 12 initial POPs, an academic research on levels of chlordane, DDT and PCB in the marine water in Hong Kong was conducted by Wurl, O., et al. from CityU in 2006, which could be used to update the contamination levels of these 3 initial POPs in the HKSARIP 2006. Provided by this local academic research, contamination levels of chlordane, DDT and PCB in marine water were reported at 0.0418, 1.908 and 0.356 ng/L respectively. As the reported values were lower than the previous detection limits (DDT: 15 ng/L, PCB: 100 ng/L & chlordane: 10 ng/L) adopted in the HKSARIP 2006, the equivalent concentrations between HKSARIP 2006 and local academic research are not directly comparable. According to the Toxic Substances Monitoring Programme conducted by EPD since 2004, the latest sampling data on marine water covered levels of all 12 initial POPs. In which, except for PCDD/PCDF (average: 0.003 pg WHO-TEQ/L) and dioxin-like PCB (0.00003 pg WHO-TEQ/L), the other 9 initial POPs were below detection limits. All 12 initial POPs can be updated by the contribution from the local academic research and the latest EPD Toxic Substances Monitoring Programme including chlordane, DDT, PCB and PCDD/PCDF that are above detection limits in the local marine water and the other 10 POPs comprising of aldrin, dieldrin, endrin, heptachlor, HCB, mirex and toxaphene, chlordecone, HBB and PeCB that are below detection limits. Newly Listed POPs Among the 10 newly listed POPs, the Wurl, O., et al. also measured the levels of α-HCH, β-HCH, γ-HCH and endosulfan in local marine water. Another local academic research on the contamination level of PFOS in Hong Kong coastal water was conducted by So, M.K., et al. also from CityU in 2004. 24 These two local academic studies contributed in identifying the contamination levels of 5 newly listed POPs including α-HCH (0.119 ng/L), β-HCH (0.246 ng/L), γ-HCH (0.215 ng/L), endosulfan (0.0485 ng/L) and PFOS (0.02-12 ng/L) in the local marine water environment. The latest sampling data from the Toxic Substances Monitoring Programme on marine water also covered levels of 8 newly listed POPs except for endosulfan, PFOS/PFOSF and HBCD. Among these 9 tested new POPs, except for C-octaBDE (0.041 ng/L) and C-pentaBDE (0.232 ng/L), the other 6 new POPs were below detection limits. In addition, there is not recent data for PFOS/PFOSF under the Toxic Substances Monitoring Programme on marine water. Provided by local academic studies and the Toxic Substances Monitoring Programme, the figure for HBCD could not be found by the desktop research. 2.3.2.1.3 Fresh Water As the contamination levels of POPs in the surface fresh water is a newly added media in the environment levels in the 2nd HKSARIP, which was not provided in the original HKSARIP, therefore, there is no recorded figure can be compared on the contamination levels of POPs in local surface fresh water. The sampling data from the Toxic Substances Monitoring Programme on river water covered levels of all 12 initial POPs and 9 newly listed POPs except for endosulfan and HBCD. The latest sampling data were collected from 2 locations from local rivers (Shing Mun River and River Indus) in 2012. The EPD 2013 Investigation Study also covered 3 types of newly listed POPs, namely, PFOS/PFOSF, PeCB and endosulfan, for their contamination levels in local river surface water. Initial POPs According to the latest Toxic Substances Monitoring Programme conducted by EPD in 2012 on river water, among the 12 tested initial POPs, 9 POPs were below detection limits except PCDD/PCDF (0.025 pg WHO-TEQ/L) and dioxin-like PCB (0.0003 pg WHO-TEQ/L). Newly Listed POPs The latest sampling data from the Toxic Substances Monitoring Programme on river water also covered levels of 9 newly listed POPs except endosulfan and HBCD. Among these 9 tested new POPs, except for PFOS (1.75 ng/L), C-octaBDE (0.055 ng/L) and C-pentaBDE (0.15 ng/L), the other 6 new POPs were below detection limits. The EPD 2013 Investigation Study also covered 3 types of newly listed POPs, namely, PFOS/PFOSF, PeCB and endosulfan, for their contamination levels in local river surface water. The results showed that 2 of the 3 measured POPs, PeCB and endosulfan were below their detection limits and the other measured POP, namely PFOS, was detected with a contamination value of 5.81 ng/L in the local river surface water. 25 Data of river water is based on the Toxic Substances Monitoring Programme and the EPD 2013 Investigation Study, and there are no local academic studies on the contamination levels of either initial or newly listed POPs in fresh water that could be found. 2.3.2.1.4 Marine Sediment Contamination of local marine sediment by toxic chemical pollutants has been relatively well documented. The inventory for the period between 2002 to 2004 was compiled based primarily on data generated from major consultancy studies on local toxic substances pollution reported in 2003, EPD’s routine and ad hoc marine monitoring programmes (2003-2004) and study reports published by local academia. Initial POPs The contamination levels in local marine sediment of all 12 initial POPs were measured and summarised in the HKSARIP 2006. For the updating period between 2005 to 2012, results of several local academic research studies, a government-funded consultancy study examining the environmental levels of 10 new POPs (2011-2012) except for HBCD, and a consultancy monitoring report focusing on mud pits’ sediment contamination (2008) contributed to the updated data on the environmental levels of 4 initial POPs – DDT, PCB, PCDD and PCDF in marine sediment. Comparing to the equivalent data collected from 2002 to 2004, the recent contamination level of PCB generally decreased (from 24.1 to 18.36µg/kg dw) , while that of DDT increased (from 6.81 to 17.4µg/kg dw). According to the Toxic Substances Monitoring Programme conducted by EPD, the latest sampling data on marine sediment covered levels of all 12 initial POPs from 2010 to 2011. In which, except for toxaphene that was below the detection limit, the other 11 initial POPs were detected from local marine sediments. Among these detected levels of 11 initial POPs during 2010 and 2011, 10 values (aldrin, chlordane, DDT, dieldrin, endrin, heptachlor, HCB, PCB, PCDD and PCDF) are lower than the measurements reported in HKSARIP 2006 except for mirex (2006: BDL; 2010/11: 0.471 μg/kg dw). However, the detection limit of mirex adopted in HKSARIP 2006 was 10 μg/kg dw, which is higher than the detected value of Mirex (0.471 μg/kg dw) in the latest Toxic Substances Monitoring Programme, the comparison of contamination levels of mirex in marine sediment between 2006 and 2010/11 could not be concluded. Provided by the latest Toxic Substances Monitoring Programme and academic researches, the levels for all 12 initial POPs in the marine sediment are updated from the HKSARIP 2006. Newly Listed POPs Among the 11 newly listed POPs, the EPD Investigation Study 2013 measured 3 newly listed POPs including PeCB, PFOS/PFOSF and endosulfan with values of 0.122 μg/kg dw, below detection limit and 7.08 μg/kg dw respectively. 26 The latest sampling data from the Toxic Substances Monitoring Programme on marine sediment also covered levels of 8 newly listed POPs except PeCB, endosulfan and HBCD conducted by EPD in 2010/11 from 10 sampling stations in 7 costal locations (Deep Bay, North Western, Southern, Victoria Harbour, Junk Bay, Mirs Bay and Tolo Harbour). Among these 8 tested new POPs, chlordecone and PFOS were below the detection limit and the other 6 new POPs (α-HCH: 0.035 μg/kg dw, β-HCH: 0.021 μg/kg dw, HBB: 0.002 μg/kg dw, γ-HCH: 0.064 μg/kg dw, C-octaBDE: 0.089 μg/kg dw and C-pentaBDE: 0.077 μg/kg dw) were detected with contamination levels in the marine sediments. However, there is still a lack of published information about the contamination level of the proposed HBCD in the marine sediment. 2.3.2.1.5 River Sediment Only 2 initial POPs, namely DDT and PCB, were reported with contamination levels in the river sediment in the HKSARIP 2006. Initial POPs According to the Toxic Substances Monitoring Programme conducted by EPD, the latest sampling data on river sediment covered levels of all 12 initial POPs collected from Shing Mun River, Lam Tsuen River and River Indus in 2012. In which, 4 initial POPs (aldrin, endrin, heptachlor and toxaphene) were below detection limits and the other 8 initial POPs were detected in the river sediments (chlordane: 0.86 μg/kg dw, DDT: 1.2 μg/kg dw, dieldrin: 0.79 μg/kg dw, HCB: 0.59 μg/kg dw, mirex: 1.89 μg/kg dw, and total PCB: 3.17 μg/kg dw, dioxin-like PCB: 0.54 pg WHO-TEQ/kg and PCDD/PCDF: 3.12 pg WHO-TEQ/kg). Comparing with the values reported in the HKSARIP 2006, the more recent values of DDT and PCB are significantly lower. Newly Listed POPs For the newly listed POPs, Zhao, Y.G., et al. from HKBU conducted a study in 2012 on the environmental contamination of PFOS in Asian countries and revealed that the concentration of PFOS in fresh water sediment (or river sediment) was not significantly different from marine water sediment in Asian countries. The latest sampling data in 2012 from the Toxic Substances Monitoring Programme on river sediment also covered levels of 9 newly listed POPs except endosulfan and HBCD. Among the tested 9 newly listed POPs, 3 of them were below detection limits including chlordecone, PeCB and PFOS. The other 6 POPs (HBB, α-HCH, β-HCH, γ-HCH, C-octaBDE and C-pentaBDE) were detected with contamination levels of 0.006 μg/kg dw, 0.07 μg/kg dw, 0.02 μg/kg dw, 0.19 μg/kg dw, 0.66 μg/kg dw and 1.29 μg/kg dw respectively from the 3 sampling locations. 27 However, there is still a lack of published information about the contamination levels of endosulfan and HBCD in the river sediment. 2.3.2.1.6 Surface Soil Contamination levels of 6 initial POPs including DDT, endrin, HCB, PCB, PCDD and PCDF in the local surface soil for the period 2002 to 2004 was summarised primarily on an ad hoc territory-wide background monitoring of surface soil in 46 locations in Hong Kong’s rural area by the HKSARIP 2006. Initial POPS A local academic study conducted by HKBU in 2007 by Zhang , H.B., et al. reported the updated value of PCB (2.45 μg/kg dw) in the rural area of Hong Kong, which showed an increased value of PCB in the background surface soil measured in the period between 2002 and 2004. More recent data on the contamination levels of the other 11 initial POPs in natural surface soil could not be found from officially published data or academic research results. Therefore, the levels for those 5 initial POPs (DDT, endrin, HCB, PCDD and PCDF) in the surface soil that were summarised in the HKSARIP 2006 are kept for the updated environmental levels, while the level of PCB can be updated according the local academic study conducted in 2007. Newly Listed POPs The EPD 2013 Investigation Study also covered the concentrations of 10 newly listed POPs in the rural surface soil, except for HBCD. The contamination levels of these 10 newly listed POPs in the local soil were generally very low, in which, 7 of them, namely α-HCH, chlordecone, HBB, PeCB, C-octaBDE, C-pentaBDE and endosulfan, were identified below the detection limit. For the concentrations of the other detected POPs, namely, β-HCH, γ-HCH and PFOS, the values were 0.876 μg/kg dw, 1.15 μg/kg dw and 0.197 μg/kg dw, respectively. 2.3.2.1.7 Vegetation The initial inventory of contamination level of vegetation was compiled by government consultancy studies conducted between 2001 and 2002 that targeted suspected local dioxin emission sources. 40 samples of ground vegetation and 10 samples of tree barks were taken at five locations near landfills, CWTC or livestock waste composting sites. No data on initial POPs in local vegetation were available. Moreover, more recent data on the local published result on Ground Vegetation and Tree Bark could not be found between 2005 and 2014. Therefore, the inventory of PCDD and PCDF published by HKSARIP 2006 for the concentrations in vegetation are kept in the updated environmental levels. 28 Table 4: Mean Levels of POPs Contamination in the Environment of Hong Kong for the Period 2002 – 2013 a Chemical Ambient Air b (pg/m3) Surface Water (ng/L) Surface Sediment (µg/kg dw) Surface Soil e (µg/kg dw) Vegetation (µg/kg dw) Marine Water c Fresh Water d Marine Sediment c River Sediment d Ground Vegetation Tree Bark Aldrin 1 (0.65-4.8) BDL BDL 0.164 (BDL – 2.49) BDL Chlordane 4.61 (3.2-9.9) 0.0418 (0.039- 0.048) BDL 0.135 (BDL – 1.44) 0.86 (BDL – 1.58) DDT 12.19 (4.95-25.85) 1.908 (0.78 - 5.58) BDL 1.671 (0.15 – 4.51) 1.20 (0.417 – 2.82) 0.52 # (<0.004-6.00) Dieldrin 5.21 (0.60-23) BDL BDL 0.254 (BDL – 2.52) 0.79 (BDL – 2.2) Endrin 0.6 (0.55-0.60) BDL BDL 0.014 (BDL – 0.54) BDL 0.01 # (<0.004-0.10) Heptachlor 2.38 (1.95-6.7) BDL BDL 0.148 (BDL – 0.41) BDL HCB 44.88 (1.05-138) BDL BDL 0.041 (BDL - 0.28) 0.59 (0.25 - 1.21) 0.01 # (<0.001-0.30) Mirex 5.3 (0.50-48) BDL BDL 0.471 (BDL – 12.9) 1.89 (BDL – 4.88) Toxaphene BDL BDL BDL BDL BDL PCBs* Dioxin-like PCB: 0.003 (0.002-0.008) Marker PCB: 19.1 (7.2-42.8) Dioxin-like PCB†: 0.00003 (BDL 0.0002) Total PCB‡: 0.356 (0.27 - 0.43) Dioxin-like PCB:0.0003 (BDL 0.001) Total PCB: BDL Dioxin-like PCB†: 0.071 (0.0003 – 0.763) Total PCB†: 0.15 (BDL - 4) Total PCB‡:18.36 (18-45) Dioxin-like PCB: 0.54 (0.01 – 1.05) Total PCB: 3.17 (BDL - 7) 2.45 (0.04-9.87) PCDD* 0.044 (0.008-0-182) 0.003 (BDL - 0.021) 0.025 (0.007 – 0.039) PCDD/F†: 2.931 (0.65 – 10.24) PCDD‡: 4.33 (2.4-6) PCDF‡: 1.34 (0.071- 0.3) 3.12 (0.49 – 8.45) 5.33 # (0.35-32.8) 2.13 # (0.29-14.1) 1.47 # (0.49-3 .57)PCDF* α-HCH 2.22 (0.85-6.6) 0.119 (0.071- 0.23) BDL 0.035 (BDL – 0.24) 0.07 (BDL – 0.135) BDL β-HCH 2.33 (0.60-21) 0.246 (0.11- 0.34) BDL 0.021 (BDL – 0.18) 0.02 (BDL – 0.059) 0.876 (<1-3.69) Chlordecone BDL BDL BDL BDL BDL BDL HBB BDL BDL BDL 0.002 (BDL – 0.071) 0.006 (BDL – 0.012) BDL γ-HCH 3.32 (0.65-13) 0.215 (0.149-0.282) BDL 0.064 (BDL – 0.4) 0.19 (0.114 – 0.225) 1.15 (<1-5.54) PeCB 4.88 (1-20.3) BDL BDL 0.122 (0.1-0.381) BDL BDL PFOS, PFOSF 4.12 (1.2-8.6) PFOS: 0.02 12 PFOS†: 1.75 (BDL – 7) PFOS‡: 5.81 (5- 11.9) PFOSF‡: BDL PFOS: BDL PFOSF: BDL BDL PFOS: 0.197 (<0.3-0.624) PFOSF: BDL C-octaBDE Total PBDE:43.8 (0.25-160) BDE-99: 17.3 (0.25 - 139) 0.041 (BDL - 236) 0.055 (0.016 – 0.096) 0.089 (BDL – 1.431) 0.66 (0.336 – 3.013) BDL C-pentaBDE 0.232 (0.066 - 638) 0.15 (0.033 – 0.318) 0.077 (0.012 – 0.333) 1.29 (0.331 – 1.037) BDL Endosulfan 143.53 (16.6-426) 0.0485 (0.046- 0.055) BDL 7.08 (7.2-14.7) BDL HBCD 29 a: Results are expressed as mean (minimum, maximum) values b: The mean levels of POPs contamination in ambient air of Hong Kong (except HBB and PBDE) are based on the 2013 data of the EPD monitoring programme on POPs; “BDL” indicates values were below detection limits; Detection limits of toxaphene, chlordecone and HBB in ambient air = 0.3 pg/m3, 0.6 pg/m3 and 0.016 ng/m3, respectively; dioxin-like PCB in ambient air was detected by PCB with TEFs (12 congeners: 77, 81, 105, 114, 118, 123, 126, 156, 157, 167, 169, and 189); marker PCB in ambient air was detected by 7 congeners: 28, 52, 101, 118, 138, 153, and 180; PBDE levels in ambient air measured by Wang, W., et. al. 2014 from Hong Kong Baptist University are “PBDE in particle phase”; HBB levels are based on the EPD Investigation Study 2013. c: “BDL” indicates values were below detection limits; Detection limits of C-octaBDE, C-pentaBDE, DDT, HBB, PCDD/PCDF, toxaphene and chlordane in marine water = 0.005, 0.01, 2, 0.1, 0.00025, 200, and 200 ng/L, respectively; Detection limits of all POPs except PCDD/PCDF, dioxin-like PCB, DDT, HBB, C-octaBDE, C-pentaBDE, PCDD/PCDF toxaphene and chlordane in marine water = 10 ng/L; Detection limits of aldrin, chlordane, dieldrin, endrin, heptachlor, mirex, toxaphene, HCB, α-HCH, β-HCH, γ-HCH, HBB, chlordecone and C-octaBDE in marine sediment = 0.2, 0.2, 0.2, 0.5, 0.2, 0.2, 2, 0.1, 0.05, 0.05, 0.05, 0.01, 1, and 0.01 µg/kg dw respectively; Detection limits of PFOS and PFOSF in marine sediment = 0.3 and 10 μg/kg dw, respectively. d: “BDL” indicates values were below detection limits; Detection limits of DDT, toxaphene, C-octaBDE and HBB in fresh water = 2, 150, 30 and 0.1 ng/L, respectively; Detection limit of all POPs except PCDD/PCDF, dioxin-like PCB, DDT, toxaphene, C-octaBDE and HBB in fresh water = 10 ng/L. Detection limits of aldrin, chlordane, dieldrin, endrin, heptachlor, mirex, toxaphene, HCB, α-HCH, β-HCH, γ-HCH, HBB, chlordecone and C-octaBDE in river sediment = 0.2, 0.2, 0.2, 0.5, 0.2, 0.2, 2, 0.05, 0.05, 0.05, 0.01, 1, and 0.01 µg/kg dw; Detection limits of PFOS and PFOSF in river sediment = 0.3 and 10 μg/kg dw, respectively. e: “BDL” indicates values were below detection limits; Detection limits of α-HCH, chlordecone, HBB, PeCB, C-octaBDE, C-pentaBDE and endosulfan in surface soil = 1, 0.1, 1, 0.1, 0.5, 1 and 7 μg/kg dw, respectively; *: Unit of PCDD/PCDF and dioxin-like PCB in ambient air = pg I-TEQ/m3; Unit of PCDD/PCDF and dioxin-like PCB in marine/fresh water = pg WHO-TEQ/L; #: Values from HKSARIP 2006; †: Values from the Toxic Substances Monitoring Programme; and ‡: Values from the EPD 2013 Investigation Study. 2.3.2.2 Contamination Levels of POPs in Aquatic Biota The inventory of the contamination levels of POPs in aquatic biota, including freshwater fish, marine fish and shellfish, water bird eggs and marine mammals, is mainly based on local academia research studies and government-funded consultancy studies. It is found that most local academia focused their research on contamination levels of 3 POPs in aquatic biota, including DDT, HCH and PBDE, probably because the contamination of these POPs would be more influential to the chance of survival or reproduction of aquatic biota. Studies of other types of POPs on aquatic biota are scarce, and mainly rely on comprehensive monitoring studies conducted by EPD. The Toxic Substances Monitoring Programme also measured the contamination levels of all 12 initial POPs and 9 newly listed POPs except endosulfan and HBCD from 3 species of marine fish (Belanger’s croaker) and shellfish (Mantis shrimp and Jinga shrimp) caught from 3 local marine areas (Deep Bay, North Western and Southern) in 2010/11. It was found that the contamination levels of POPs in marine fish, shellfish, water bird eggs and marine mammals were measured and presented on various weight basis, including µg per kg wet weight, dry weight and lipid weight in different research studies. There is no proper conversion method among these different measuring units due to the markedly varying water and lipid content between individuals and 30 tissues, which are also largely affected by how samples are handled and stored but these information are not mentioned in the monitoring studies. Hence, the original units of the research are reported in this section. A summary of contamination levels of POPs in aquatic biota including freshwater fish, marine fish, marine shellfish, water bird eggs and marine mammals is presented in Table 5. 2.3.2.2.1 Freshwater Fish There is a general paucity of information on POPs in freshwater biota. Studies conducted by local academia contributed to all the data compiled in this section of the inventory. For the period between 2002 and 2004, 4 freshwater fishes from one to three sampling sites were examined for the contamination levels of aldrin, chlordane, DDT, endrin and heptachlor, while another study measured the levels of PCB in one fish species from two locations. DDT and PCB were the only POPs measured above the detection limits in the HKSARIP 2006. Initial POPs A recent study on the residual levels of DDT in freshwater fish from Hong Kong markets was conducted by Cheung, K.C., et al from HKBU in 2007 and the available data can be used to update the contamination level of DDT in aquatic biota. 10 freshwater fish species with 30 fish samples were taken from local wet markets for chemical analysis. Comparing to the equivalent data collected summarised in the HKSARIP 2006, the contamination level of DDT in freshwater fish increased from 6.78 to 29.3µg/kg ww. No recent data on the contamination levels of the other 11 initial POPs in freshwater fish can be found from officially published data or academic research results. Therefore, the levels for the other 5 initial POPs (aldrin, dieldrin, endrin, heptachlor and PCB) that were measured in the HKSARIP 2006 are kept for the updated environmental levels. Newly Listed POPs A local academic study conducted by Zhao, Y.G., et al. from HKBU in 2011 that studied the concentration of PFOS in the freshwater fish showed that an average concentration of 1.03 μg/kg ww was summarized from 8 marine fish species investigated from the local wet market. 2 recent local academic studies both conducted by HKBU in 2008 (Cheung, K.C., et al.) and in 2011 (Wang, H.S., et al.) respectively measured the contamination levels of PBDE in freshwater fish, and an average value of 9.25 μg/kg ww could be summarised for 10 species of freshwater fish investigated from local markets. However, no recent data could be found for the contamination levels of the remaining 8 newly listed POPs in freshwater fish. 31 2.3.2.2.2 Marine Fish Compared with freshwater fish, more information on POPs in local marine fish were available. For the initial inventory summarised by HKSARIP 2006, data were retrieved primarily from four studies, including two toxic substances consultancy studies reported in 2003, an ad hoc baseline survey on trace toxics in Hong Kong marine biota conducted by EPD in 2003, and a monitoring report of contaminated mud pit at East Sha Chau conducted in 2004 by CEDD. The Toxic Substances Monitoring Programme also measured the contamination levels of all 12 initial POPs and 9 newly listed POPs except endosulfan and HBCD from 1 species of marine fish (Belanger’s croaker) caught from 2 local water control zones (Deep Bay and North Western) in 2010/11. Initial POPs All 12 initial POPs were measured and summarized by HKSARIP 2006 with the contamination levels in marine fish. Within the initial POPs, the same academic study on the contamination level of DDT in freshwater fish (Cheung, K.C., et al., 2007) also reported the level of DDT in marine fish in 2007. Comparing with the figures given by HKSARIP 2006, the updated contamination level of DDT in marine fish increased from 27.6 to 112.3 μg/kg ww. Including the updated measurement on DDT in marine fish conducted by local academic, the levels for all the 12 initial POPs were also covered by the latest Toxic Substances Monitoring Programme conducted by EPD in 2010/11. In which, 3 initial POPs (heptachlor, HCB and toxaphene) were below detection limits and the other 9 initial POPs (aldrin: 0.06 μg/kg ww, chlordane: 0.26 μg/kg ww, DDT: 4.12 μg/kg ww, dieldrin: 0.04 μg/kg ww, endrin: 0.06 μg/kg ww, mirex: 0.72 μg/kg ww, dioxin-like PCB: 0.08 pg WHO-TEQ/kg ww and PCDD/PCDF:0.03 pg WHO-TEQ/kg ww) were detected from samples of local marine fish species. Newly Listed POPs The same local academic study conducted by Zhao, Y.G., et al., from HKBU in 2011 that studied the concentration of PFOS in the freshwater fish also investigated the contamination level of PFOS in the marine fish, and an average concentration of 0.71 μg/kg ww was summarized from 7 marine fish species investigated from the local wet market. The Toxic Substances Monitoring Programme also measured the contamination levels of 9 newly listed POPs in local marine species except endosulfan and HBCD. 3 out of 9 tested new POPs (HBB, PeCB and PFOS) were identified to be below detection limits through the monitoring programme and the other 6 POPs were detected with values from marine fish samples, including α-HCH (0.08 μg/kg ww), β-HCH (0.04 μg/kg ww), γ-HCH (0.08 μg/kg ww), chlordecone (2.1 μg/kg ww). C-octaBDE (0.13 μg/kg ww) and C-pentaBDE (0.38 μg/kg ww). 32 However, there is still a lack of published information about the contamination levels of endosulfan and HBCD in the marine fish species. 2.3.2.2.3 Marine Shellfish All 12 initial POPs were summarised with contamination levels in the marine shellfish by the HKSARIP 2006. The latest sampling data of the Toxic Substances Monitoring Programme included all 12 initial POPs and 9 newly listed POPs only except endosulfan and HBCD. The measurements conducted on 2 local marine shellfish species (Mantis shrimp and Jinga shrimp) caught from the North Western and Southern water control zones in 2010/11. Initial POPs Among the contamination levels of all the 12 initial POPs in local marine shellfish tested by the Toxic Substances Monitoring Programme in 2010/11, there were 4 POPs (endrin, heptachlor, HCB and toxaphene) below detection limits, while endrin, heptachlor, HCB were reported with detected values in the HKSARIP 2006 and toxaphene was also below the detection limit as reported in the HKSARIP 2006. The other 8 initial POPs, namely, aldrin, chlordane, DDT, dieldrin, mirex PCB, PCDD and PCDF were detected with values of 0.11μg/kg ww, 0.21 μg/kg ww, 3.27 μg/kg ww, 0.09 μg/kg ww, 0.86 μg/kg ww, 0.13 ng WHO-TEQ/kg ww (dioxin-like PCB) and 0.17 ng WHO-TEQ/kg ww (PCDD/PCDF). Comparing with the values reported in the HKSARIP 2006, 8 initial POPs including chlordane, DDT, dieldrin, endrin, heptachlor, HCB, PCDD and PCDF were recorded with a lower contamination level in the more recent measurement. Another 3 initial POPs, namely, aldrin, mirex and toxaphene were below detection limits in the HKSARIP 2006, and could not be compared with the updated values due to the different detection limits adopted before 2006. Regular monitoring of dioxin-like PCB (PCB with TEFs (12 congeners: 77, 81, 105, 114, 118, 123, 126, 156, 157, 167, 169, and 189) from January 2010 was commenced as well as marker PCB (7 congeners: 28, 52, 101, 118, 138, 153, and 180) to replace total PCB monitoring from May 2010. The available contamination level of PCB was tested by dioxin-like PCB in the recent data in the Toxic Substances Monitoring Programme, which were incomparable to the previous value of PCB reported as total PCB in the HKSARIP 2006. Newly Listed POPs Among the newly listed POPs, a local study with the results of a 6-year (1998-2003) survey of trace toxics in the intertidal mussel Perna viridis published by EPD in 2005 (Liu, J.H. and Kueh, C.S., 2005) revealed that local mussels were contaminated with 2 newly listed POPs, namely C-octaBDE and C-pentaBDE, with concentrations of 16.85 and 14.43 μg/kg dw respectively. The Toxic Substances Monitoring Programme also measured the contamination levels of 9 newly listed POPs in local marine species except endosulfan and HBCD. 4 out of 9 tested new POPs (β-HCH, HBB, 33 PeCB and PFOS) were identified to be below detection limits through the monitoring programme and the other 5 POPs were detected with values from marine shellfish samples, including α-HCH (0.11 μg/kg ww), γ-HCH (0.05 μg/kg ww), chlordecone (0.8 μg/kg ww). C-octaBDE (0.07 μg/kg ww) and C-pentaBDE (0.57 μg/kg ww). However, there is still a lack of published information about the contamination levels of endosulfan and HBCD in the marine shellfish species. 2.3.2.2.4 Water Bird Eggs Studies conducted by local academia contributed to all the data compiled in this section of the inventory. For the initial inventory from 2002 to 2004, data were retrieved primarily from a local study on the body burden of chlordane, DDT and PCB in eggs of two species of water birds sampled at two locations in the New Territories. Initial POPs Among the 12 initial POPs, 4 of them, namely chlordane, DDT, PCDD and PCDF, were reported with contamination levels in the water bird eggs in the HKSARIP 2006. Two recent academic studies on the contamination levels of all 12 initial POPs in water bird eggs were conducted by Wang, Y., et al., from CityU in 2011 and in 2012 respectively. According to the results from these 2 academic studies, the reported values of chlordane, DDT, PCDD and PCDF in the HKSARIP 2006 can be updated to 158-975, 2,490-16,100, 484-520 and 80.1-167 μg/kg lw respectively. However, the units of the updated levels were reported in lipid weight by the recent academic studies, which is different to the previously reported units (wet weight), hence, the contamination levels of these 4 initial POPs between previous levels summarised in HKSARIP 2006 and recent levels measured by recent studies cannot be directly compared. In addition, the other 8 initial POPs that were not reported by the HKSARIP 2006 were identified with contamination levels in the water bird eggs by Wang, Y., et al., from CityU in 2011 (aldrin: 0.492-8.41 µg/kg lw, dieldrin: 8.36-114 µg/kg lw, endrin: 9.32-31.3 µg/kg lw, heptachlor: 7.81-99.8µg/kg lw, HCB: 40.2-241µg/kg lw, mirex: 84.2-255µg/kg lw, toxaphene: 36.1-395µg/kg lw and PCB: 881-4,310µg/kg lw). Newly Listed POPs The topic of PFOS contamination levels in water bird eggs was also conducted by Wang, Y., et al., from CityU in 2008 in another academic study. An average of 65.2 μg/kg ww of PFOS could be concluded from the 19 samples of water bird eggs measured by this study. Another academic study reported by Connell, D.W., et al., in 2003 detected the total levels of HCH in the water bird eggs (19 μg/kg lw), which can represent the contamination levels of 3 newly listed POPs 34 including α-HCH, β-HCH and γ-HCH. No other recent data on the contamination levels of the other newly listed POPS in water bird eggs could be found from officially published data or academic research results. 2.3.2.2.5 Marine Mammals Studies conducted by local academia contributed to all the data compiled in this section of the inventory but research data was scarce for monitoring the trend. The initial inventory was compiled based on three studies of stranded cetaceans, the Indo-Pacific humpback dolphin (Sousa chinensis) and finless porpoise (Neophocaena phocaenoides), published in the literatures (1995-2000, 2000-2001 and 2003-2011). They provided baseline data for contamination levels of DDT, mirex, toxaphene, PBDE and PCB in marine mammals. Initial POPs Among the 12 initial POPs, 4 of them were reported with contamination levels in the marine mammals in the HKSARIP 2006. Provided by a local academic study conducted by Ramu, K., et al. in 2005 on 2 local cetaceans species, namely finless porpoise and Indo-Pacific humpack dolphin, an average concentration level of 134.5 μg/kg lw of DDT was found in the marine mammals. Despite the updated concentration of DDT in the marine mammals, no recent data after 2006 could be found on the contamination levels of the other 11 initial POPS in marine mammals from officially published data or academic research results. Therefore, the summarised levels for 3 initial POPs, namely mirex, toxaphene and PCB in the marine mammals reported in the HKSARIP 2006 are kept as the updated environmental levels. Newly Listed POPs The study conducted by Ramu, K., et al. in 2005 also measured the contamination of HCH in the 2 investigated cetacean species, namely finless porpoise and Indo-Pacific humpback dolphin, and an average concentration of 0.455 μg/kg lw could be identified, which can represent the contamination levels of 3 newly listed POPs including α-HCH, β-HCH and γ-HCH. Another local academic study conducted by Lam, J.C.W., et al., from CityU in 2009 analysed the concentrations of PBDE and HBCD in the same 2 cetacean species. The results of PBDE (1,955.2 μg/kg lw) can be used to represent the total contamination levels of C-octaBDE and C-pentaBDE in the marine mammals. The contamination level of HBCD (93.4 μg/kg lw) summarised by the study is the only available contamination data of HBCD for all environmental medias and aquatic biotas. The results of PBDE levels in marine mammals in the latest published study by Zhu, B.Q., et. al. from CityU in 2014 fell within the range of the study conducted by Lam, J.C.W., et al., from CityU in 2009. 35 Table 5: Levels of POPs Contamination in the Aquatic Biota of Hong Kong for the Period 2002 – 2014a Chemical Freshwater Fish b (µg/kg ww) Marine Fish c (µg/kg ww) Marine Shellfish c (µg/kg) Water Bird Eggs d (µg/kg) Marine Mammals e (µg/kg) Aldrin BDL # 0.06 (BDL – 0.24) 0.11 (BDL – 0.15) 0.492-8.41 Chlordane 0.26 (BDL – 0.54) 0.21 (BDL – 0.48) 158-975 DDT 29.3 (1.1 to 127) 4.12† (0.92 – 6.73) 112.3‡ (2.3-1,018) 3.27 (BDL – 8.66) 2,490-16,100 134.5 (9.9-470) Dieldrin BDL # 0.04 (BDL – 0.08) 0.09 (BDL – 0.2) 8.36-114 Endrin BDL # 0.06 (BDL – 0.12) BDL 9.32-31.3 Heptachlor BDL # BDL BDL 7.81-99.8 HCB BDL BDL 40.2-241 Mirex 0.72 (0.56 – 0.88) 0.86 (BDL – 1.94) 84.2-255 178 # (70.5-286) Toxaphene BDL BDL 36.1-395 32.0 # (19.7-44.2) PCB* 57.8 # Dioxin-like PCB: 0.08 (0.004 – 0.15) Dioxin-like PCB: 0.13 (0.04 – 0.21) 881-4,310 8,190 # PCDD* PCDD/F: 0.03 (0.019 – 0.041) PCDD/F: 0.17 (0.02 – 0.47) 484-520 PCDF* 80.1-167 α-HCH 0.08 (BDL – 0.16) 0.11 (BDL – 0.23) HCH: 19 (8.4-30) HCH: 0.455 (0.032 - 2.2) β-HCH 0.04 (BDL – 0.085) BDL γ-HCH 0.08 (BDL – 0.16) 0.05 (BDL – 0.1) Chlordecone 2.1 (BDL – 4.16) 0.8 (BDL – 1.6) HBB BDL BDL PeCB BDL BDL PFOS, PFOSF 1.03 (0.27-4.5) 0.71 (0.27-1.5) BDL 65.2 (14.1-34.3) C-octaBDE PBDE: 9.25 (0.53-130) 0.13 (0.08 – 0.17) 0.07† (BDL – 0.15) 16.85‡ (2.31 - 31.46) PBDE: 1,955.2 (103-51,100) C-pentaBDE 0.38 (0.22 – 0.53) 0.57† (0.03 – 1.3) 14.43‡ (5.69-33.1) Endosulfan HBCD 93.4 (4.1-519) a: Results are expressed as mean (minimum, maximum) values b:“BDL” indicates values were below detection limit; Detection limit of pesticides in freshwater fish = 0.10 μg/kg ww; c: “BDL” indicates values were below detection limit; Detection limit of aldrin, mirex, DDT, chlordane, dieldrin, heptachlor, PeCB, PFOS and HCB in marine fish/shellfish = 0.1 μg/kg ww; Detection limit of HBB, endrin and toxaphene in marine fish/shellfish = 0.01, 0.2 and 2 μg/kg ww; Detection limit of α-HCH, β-HCH and γ-HCH in marine fish/shellfish = 0.05 μg/kg ww; Unit of C-octaBDE and C-pentaBDE in marine shellfish = μg/kg dw; Units of other POPs except C-octaBDE, C-pentaBDE and PCDD/PCDF in marine shellfish = μg/kg ww. d: Unit of PFOS/PFOSF in water bird eggs = μg/kg ww; Units of other POPs except PCDD/PCDF in water bird eggs = μg/kg lw; e: Units of mirex, toxaphen, PCB in marine mammals = μg/kg ww; Units of other POPs in marine mammals = μg/kg lw; 36 *: Units of PCDD/PCDF and dioxin-like PCB = ng WHO-TEQ/kg ww #: Values from HKSARIP 2006 †: Unit of value = μg/kg ww ‡: Unit of value = μg/kg dw 2.3.3 Dietary Exposure to POPs In 2011, the Centre for Food Safety (CFS) of the Food and Environmental Hygiene Department (FEHD) conducted The First Hong Kong Total Diet Study on dioxins and dioxin-like polychlorinated biphenyls (PCB) to obtain the contamination level of 142 composite samples involving 71 common food items of Hong Kong citizens. In 2014, the CFS also conducted a study on organochlorine pesticide (OCP) residues to obtain the contamination level of 14 OCPs in 600 composite samples involving 150 common food items of Hong Kong citizens. The numbers of composite samples with detectable levels of one or more of the 14 OCPs and dioxin and dioxin-like PCB in the 15 food groups are summarised in Table 6 and Table 7. Furthermore, in 2012, CFS published “The first Hong Kong Total Diet Study: Polybrominated diphenyl ethers (PBDE)” to include the dietary exposure levels of PBDE found in 71 food items involving 142 composite samples. Human exposure to POPs through dietary intake was estimated based on measurements of contamination levels of POPs in various types of foods and information on daily diets of the local population. In general, the inventory of the dietary exposure to POPs is well-documented for both 12 initial POPs (aldrin, chlordane, DDT, dieldrin, endrin, heptachlor, HCB, mirex, toxaphene, PCB, PCDD and PCDF) and 7 new POPs (α-HCH, β-HCH, γ-HCH, PeCB, C-octaBDE, C-pentaBDE and endosulfan). A summary of POPs contamination in foods and estimated daily exposure is presented in Table 8. Due to the lack of local data before 2005, the HKSARIP 2006 report adopted food consumption patterns of Far East Countries (including China) published by WHO (2003) for the estimation of daily dietary exposure of Hong Kong citizens. In view of this information gap, the CFS conducted a Hong Kong Population-Based Food Consumption Survey in 2005-2007 to obtain food consumption habits of local Hong Kong citizens. Therefore, a better estimation of daily dietary exposure could be made by adopting the food consumption data fitting the local context. As the methodology of calculating the estimated daily dietary exposure in the HKSARIP 2006 report is different from the new study conducted by the CFS, in which the data presented in this report is considered to be a better estimation, the equivalent data collected in 2003 presented in the 2006’s report would not be compared for analysing the trend of estimated daily dietary exposure of Hong Kong citizens. CFS has published the contamination levels and dietary exposure levels of some important POPs in each food item analysed in the relevant reports of The First Hong Kong Total Diet Study. 37 Table 6: Numbers of Composite Samples in Total Diet Study Food Groups 38 Table 7: Dioxin and Dioxin-like PCB Contents in TDS Foods of the 1st HKTDS TDS Food Item Number of composite samples % of test results < LOD Mean (pg TEQ/g) [range]# Cereals and their products 24 45 0.021 [0.007- 0.058] Meat, poultry and game and their products 24 23 0.091 [0.012 – 0.257] Eggs and their products: 6 16 0.137 [0.020 – 0.302] Fish and seafood and their products 38 20 0.44 [0.009 – 1.270] Dairy products 10 57 0.021 [0.007- 0.072] Fats and oils 4 33 0.094 [0.011 – 0.282] Beverages, non-alcoholic 6 58 0.011 [0.007 – 0.015] Mixed dishes 22 40 0.018 [0.007 – 0.039] Others 8 53 0.013 [0.008 – 0.030] Total 142 34 Notes: # As less than 60% of results are below limits of detection (LODs), half of LOD is used for all results less than LOD in calculating the concentrations. Table 8: Ranges (lower bound and upper bound) of dietary exposure estimates to the OCPs for the average and high consumers of the Hong Kong population in year 2011- 2014 OCPs Dietary exposure estimate (µg/kg bw/day) * # Average High consumer Aldrin+Dieldrin 0.0003-0.0059 0.0012-0.0096 Chlordane 0.0002-0.0142 0.0010-0.0230 DDT 0.0238-0.0399 0.0912-0.1099 Endosulfan 0.0085-0.0166 0.0258-0.0359 Endrin 0.0010-0.0091 0.0021-0.0145 Heptachlor 0-0.0084 0-0.0136 HCB 0.0024-0.0048 0.0052-0.0084 HCH (α,β,γ and δ) 0.0008-0.0120 0.0023-0.0195 Lindane (γ-HCH) 0.0001-0.0029 0.0002-0.0046 Mirex 0-0.0028 0.0001-0.0045 PeCB 0.0003-0.0030 0.0008-0.0049 Toxaphene 0.0002-0.0171 0.0011-0.0276 Dioxins and Dioxin-like PCB (pg TEQ/kg bw/day) 0.7307 1.9983 PBDE 0.00134 0.0029 * Figures for dietary exposure estimates were rounded to four and one decimal places, respectively; the daily dietary exposure of dioxin and dioxin-like PCB was calculated from the monthly dietary exposure with an assumption of 30 days per month. # Values of “0” denote < 0.00005 µg/kg bw/day for dietary exposure estimates. Note: Chlordecone was not detected in any sample so dietary exposure estimation was not conducted. 39 2.3.4 Human Body Burden of POPs 2.3.4.1 Human Breast Milk POPs in the environment can enter the food chain, bio-accumulate and bio-magnify as they move up the trophic levels and ultimately end up in the human body. It is expected that POPs will continue to accumulate in the body fat and their average concentration will increase with age. Levels of POPs in human blood/serum and breast milk are good indicators of their body burden. As human breast milk could be obtained by non-intrusive method, it is a more common and acceptable method for testing human body burden of chemicals compared to the other two types of indicators. A summary of POPs contamination in breast milk of Hong Kong mothers is presented in Table 9. Initial POPs 4 academic studies conducted by HKBU (Tsang, H. L., et al., 2011), HKU (Hedley, A.J., et al., 2010) and CUHK (Wong, T.W., et al., 2010 and 2013) covered all the 12 initial POPs with the concentration levels in human milk. The data from Wong, T.W., et al. (2010 and 2013) of CUHK were originally a government-funded research study. This government-funded research study was reference to WHO/UNEP (2007) Guidelines for Developing a National Protocol of Fourth WHO – Coordinated Survey of Human Milk for POPs in Cooperation with UNEP, in which lactating mothers were selected based on several requirements, such as (a) age, (b) primiparae, (c) healthy, (d) exclusively breastfeeding one child (i.e. no twins), and (e) residing length in Hong Kong. Jointly provided from the 2 studies from CUHK and HKBU, the ranges of the contamination levels of DDT and PCB in human milk were 129.9 – 4,507 μg/kg lw and BDL – 93 μg/kg lw respectively. The most recent value of dioxin-like PCB (3.79 pg TEQ/g lw) was measured by CUHK (Wong, T.W., et al.,) in 2013, which recorded a decreased value compared with the previous value (4.67 pg TEQ/g lw) in the HKSARIP 2006. A similar decrease can be also found in the recent data for PCDD/PCDF (7.48 pg TEQ/g lw) in the human milk reported in the CUHK studies in 2013 while comparing with the previous reported level (8.25 pg TEQ/g lw). The 8 other types of initial POPs that were not covered in the HKSARIP 2006 were also studied in these 4 recent academic studies, and except for aldrin, heptachlor, and endrin which were all below the detection limits, chlordane, dieldrin, HCB, mirex and toxaphene could be detected in the human milk with a contamination level range of 2.4 – 9.4, 0.5 – 3.04, 9.53 – 136.77, 0.52 – 6.85 and 0 – 2.5 μg/kg lw respectively. Newly Listed POPs 7 out of the 11 newly listed POPs, except chlordecone, HBB and PFOS as well as HBCD, were also identified with contamination levels in human milk by these academic studies. In which, the contamination levels of endosulfan investigated by Wong, T.W., et al., in 2010 and 2013 respectively 40 were both below detection limits, while the detected ranges of α-HCH, β-HCH, γ-HCH, PeCB and PBDE were 0.2 – 8.38, 45 – 1,380, BDL - 2, 0.49 – 1.3 and 1.7 – 4.2 μg/kg lw respectively. 2.3.4.2 Human Blood Plasma Contamination levels of the concerned POPs in human blood were not studied in the HKSARIP 2006 as a human body burden of POPs. For recent studies, two local academic studies both conducted by HKBU in 2011 and 2013 respectively (Qin, Y.Y., et al., 2011 and Wong H. S., et al., 2013) on 5 of the concerned POPs, including DDT (1,120 μg/kg lw), HCB (1.5-49.5 μg/kg lw), PCB (110 μg/kg lw), α-HCH (206 μg/kg lw) and PBDE (5.56 μg/kg lw) showed a similar figure that was identified on POPs in the human breast milk. A summary of POPs contamination in blood plasma of Hong Kong citizens is presented in Table 10. Table 9: Levels of POPs Contamination in Breast Milk of Hong Kong Citizens reported in the Period 2009-2013 Chemical Human Breast Milk Concentration a (μg/kg lw) Reference Aldrin BDL (age: mean 27.2; range 20 – 29) Wong, T.W., et al., 2010 Chlordane 4.9 (2.4-9.4) (age: mean not given; range 17 – 42) Hedley, A. J., et al., 2010 DDT 53.6 (129.9 – 1,847.7) (age: mean 27.2; range 20 – 29) Wong, T.W., et al., 2010 3,099 (2,098 – 4,507) (age: mean 33.8; range 25 – 44) Tsang, H.L., et al., 2011 Dieldrin 1.27 (0.5 – 3.04) (age: mean 27.2; range 20 – 29) Wong, T.W., et al., 2010 1.36 (0.7 – 2) (age: mean not given; range 17 – 42) Hedley, A. J., et al., 2010 Endrin BDL (BDL – 0.14) (age: mean 27.2; range 20 – 29) Wong, T.W., et al., 2010 BDL (age: mean not given; range 17 – 42) Hedley, A. J., et al., 2010 Heptachlor BDL (age: mean 27.2; range 20 – 29) Wong, T.W., et al., 2010 0.9 (0.8 – 1) (age: mean not given; range 17 – 42) Hedley, A. J., et al., 2010 HCB 22.34 (9.53 – 136.77) (age: mean 27.2; range 20 – 29) Wong, T.W., et al., 2010 20.84 (17 – 27) (age: mean not given; range 17 – 42) Hedley, A. J., et al., 2010 Mirex 1.71 (0.52 – 6.85) (age: mean 27.2; range 20 – 29) Wong, T.W., et al., 2010 1.3 (no range provided) (age: mean not given; range 17 – 42) Hedley, A. J., et al., 2010 41 Chemical Human Breast Milk Concentration a (μg/kg lw) Reference Toxaphene 1.6 (no range provided) (age: mean 27.2; range 20 – 29) Wong, T.W., et al., 2010 0.74 (0 – 2.5) (age: mean not given; range 17 – 42) Hedley, A. J., et al., 2010 PCB* PCB: 24.1 (no range provided) Dioxin-like PCB: 3.28 (no range provided) (age: mean 27.2; range 20 – 29) Wong, T.W., et al., 2010 PCB: 49 (BDL – 93) (age: mean 33.8; range 25 – 44) Tsang, H.L., et al., 2011 Dioxin-like PCB: 3.79 (2.93 – 5.07) (age: mean 29.6; range 25 – 37) Wong, T.W., et al., 2013 PCDD* PCDF* 6.56 (no range provided) (age: mean 27.2; range 20 – 29) Wong, T.W., et al., 2010 7.48 (6.56 – 8.32) (age: mean 29.6; range 25 – 37) Wong, T.W., et al., 2013 α-HCH 1.17 (0.2-8.38) (age: mean 27.2; range 20 – 29) Wong, T.W., et al., 2010 0.7 (0.5 – 1) (age: mean not given; range 17 – 42) Hedley, A. J., et al., 2010 β-HCH 221.82 (45 - 792.9) (age: mean 27.2; range 20 – 29) Wong, T.W., et al., 2010 1133 (606 – 1380) (age: mean not given; range 17 – 42) Hedley, A. J., et al., 2010 Chlordecone - HBB - γ-HCH BDL (BDL – 0.64) (age: mean 27.2; range 20 – 29) Wong, T.W., et al., 2010 0.94 (BDL – 2) (age: mean not given; range 17 – 42) Hedley, A. J., et al., 2010 PeCB 0.8 (0.49 – 1.3) (age: mean 27.2; range 20 – 29) Wong, T.W., et al., 2010 PFOS, PFOSF - C-octaBDE PBDE: 4 (1.7 – 4.2) (age: mean not given; range 17 – 42) Hedley, A. J., et al., 2010 C-pentaBDE Endosulfan BDL (BDL – BDL) (age: mean 27.2; range 20 – 29) Wong, T.W., et al., 2010 BDL (BDL – BDL) (age: mean not given; range 17 – 42) Hedley, A. J., et al., 2010 HBCD - *: Unit of PCDD/PCDF/dioxin-like PCB = pg TEQ/g lw a: Detection limits of aldrin, endrin, heptachlor, and endosulfan in human milk = 1 μg/kg lw; Detection limits of PCB and γ-HCH = 0.5 μg/kg lw. 42 Table 10: Mean Levels of POPs Contamination in Human Blood of Hong Kong Citizens for the Period 2011-2013 Chemical Human Blood Plasma Concentration (μg/kg lw) Aldrin Chlordane DDT 1,120 (308.25-2,749) Dieldrin Endrin Heptachlor HCB 1.5-49.5 Mirex Toxaphene PCB* 110 (245.4-254) PCDD* PCDF* α-HCH 206 β-HCH Chlordecone HBB γ-HCH PeCB PFOS, PFOSF C-octaBDE PBDE: 5.56 (4.52-16.54) C-pentaBDE Endosulfan HBCD *: Unit of PCDD/PCDF/dioxin-like PCB = pg TEQ/g lw 2.4 Analysis of POPs Information Gaps 2.4.1 Environmental Levels of POPs 2.4.1.1 Contamination Levels of POPS in Environmental Media Among the five categories of environmental media, ambient air and surface soil contain a comparatively more complete set of data on the Convention POPs, though several POPs (e.g. endosulfan and HBCD) were not shown to have monitoring data in the past decade. Moreover, not all 23 concerned POPs were routinely monitored in the ambient air, surface water and surface sediment. In particular, local data on POPs in fresh water and river sediment are limited, while that in vegetation (ground vegetation and tree bark) are particularly lacking. 43 2.4.1.2 Contamination Levels of POPs in Aquatic Biota DDT is identified as the POP being the most frequently studied among all categories of aquatic biota. The contamination levels of the 12 initial POPs (DDT and PCB in particular) in local marine fish and shellfish had been well studied, yet only HCH, PFOS/PFOSF and PBDE among the 11 new POPs have been studied. Limited data of contamination levels of POPs in freshwater fish, local water birds and marine mammals were available. 2.4.2 Dietary Exposure to POPs To better understand the local food consumption pattern and to assess the overall dietary exposure of the local population to POPs, a population-based local food consumption survey and The First Hong Kong Total Diet Study were conducted by FEHD from 2005 to 2007 and from 2010 to 2014 respectively. However, as the study involved many types of common locally consumed mixed food items (e.g. steamed barbecued pork bun, hamburger, raisin bread, and turnip cake), the analysis for the contamination level of POPs in individual food category (e.g. meat, poultry, cereal, vegetable) could not be clearly distinguished. Besides, not all 23 Convention POPs were adequately analyzed in all food categories. Among the 11 new POPs, only HCH, chlordecone, PeCB and endosulfan were studied while the data of the remaining seven POPs were unavailable. 2.4.3 Human Body Burden of POPs Local data on the local contamination levels of 19 POPs in breast milk of lactating mothers were well documented in two recent studies of Hong Kong residents, but there is no available data for Chlordecone, HBB, PFOS/PFOSF, and HBCD. Research data on DDT, PCB, PCDD and PCDF are especially enriched in local academic studies. There is limited data available for the contamination levels of POPs in human blood. 2.5 Environmental and Human Health Risk Assessment of POPs 2.5.1 Human Health Risk Assessment 2.5.1.1 Human non-carcinogenic risk assessment Results of assessment of non-carcinogenic risk associated with exposure of local residents to POPs in the locally consumed food items and the ambient air are presented in Table 11. The calculated hazard quotients (HQs) of all the POPs with the necessary information available under the Stockholm Convention were well below unity, indicating that there was no unacceptable non-carcinogenic risk of toxicological significance associated with a lifetime exposure of local residents to the current levels of POPs contamination in locally consumed food items and the ambient air. The estimated level of exposure of local residents to dioxins/furans (0.73 pg TEQ kg-1 bw d-1 or 21.9 pg TEQ kg-1 bw month-1, assuming 44 negligible intake via the drinking water route) was below the provisional tolerable monthly intake (PTMI) of 70 pg TEQ kg-1 bw month-1 , which was set by the Joint FAO/WHO Expert Committee on Food Additives (2001). Dietary exposure was the major route, accounting for 98.6% of total exposure to dioxins/furans, while inhalation exposure accounted for only 1.4%. Table 11: Human Non-carcinogenic Risk Assessment of POPs in Hong Kong in 2002-2013 Chemical Daily intake (mg kg -1 bw day-1) Reference dose (RfD)/ tolerable daily intake (TDI) (mg kg-1 bw d-1)e Hazard quotient (total daily intake/ RfD or TDI) Dietaryb Inhalationc,d Total Aldrin 5.90 x 10-6 2.88 x 10-10 5.90 x 10-6 3.00 x 10-5 <1 Chlordane 1.42 x 10-5 1.33 x 10-9 1.42 x 10-5 5.00 x 10-4 <1 DDT 3.99 x 10-5 3.51 x 10-9 3.99 x 10-5 5.00 x 10-4 <1 Dieldrin 5.90 x 10-6 1.50 x 10-9 1.50 x 10-9 5.00 x 10-5 <1 Endrin 9.10 x 10-6 1.73 x 10-10 9.10 x 10-6 3.00 x 10-4 <1 Heptachlor 8.40 x 10-6 6.88 x 10-10 8.40 x 10-6 5.00 x 10-4 <1 HCB 4.80 x 10-6 1.29 x 10-8 4.81 x 10-6 8.00 x 10-4 <1 Mirex 2.80 x 10-6 1.53 x 10-9 2.80 x 10-6 2.00 x 10-4 <1 Toxaphene 1.71 x 10-5 BDL 1.71 x 10-5 - PCBs - 5.5 x 10-9 5.5 x 10-9 2.00 x 10-5 <1 Dioxins/ furansa 0.72 0.01 0.73 (monthly intake = 21.9 pg TEQ kg -1 bw month-1) Provisional tolerable monthly intake = 70 pg TEQ kg-1 bw month-1 <1 α-HCH 1.20 x 10-5 6.39 x 10-10 1.20 x 10-5 β-HCH 6.71 x 10-10 - Chlordecone - BDL - 3.00 x 10-4 HBB - BDL - - Lindane 2.90 x 10-6 9.56 x 10-10 2.90 x 10-6 3.00 x 10-4 <1 PeCB 3.00 x 10-6 1.41 x 10-9 3.00 x 10-6 8.00 x 10-4 <1 PFOS, PFOSF - 1.19 x 10-9 1.19 x 10-9 - PBDEf 1.34 x 10-6 (Total PBDE) 7 x 10-8 (BDE-99, penta- only) 1.26 x 10-8 (Total PBDE) 5 x 10-9 (BDE-99, penta- only 1.35 x 10-6 (Total PBDE) 7.5 x 10-8 (BDE-99, penta- only) 1.00 x 10-4 (BDE-99, penta- only) <1 (BDE-99, penta- only) Endosulfan 1.66 x 10-5 4.13 x 10-8 1.66 x 10-5 6.00 x 10-3 <1 HBCD - - - - a Unit for daily intake/RfD/TDI of dioxins/furans = pg TEQ kg-1 bw d-1. The provisional tolerable monthly intake (PTMI) of 70 pg TEQ/kg bw per month, set by the Joint FAO/WHO Expert Committee on Food Additives (2001), is used for dioxins/furans. b Dietary intake estimated based on the measurements of contamination levels of POPs in various types of foods conducted by the Centre for Food Safety (CFS) of Hong Kong. Marker PCB in ambient air was detected through 7 cogeners – 28, 52, 101, 118, 138, 153 and 180. PBDE levels in ambient air are based on Wang, W., et. al. 2014; chlordecone and HBB levels are based on the EPD Investigation Study 2013. c Assuming a respiratory rate of 20 min-1 and a tidal volume of 600 ml, for an average adult of 60 kg bw. d“BDL” indicated that the values were below detection limits; detection limits of toxaphene, chlordecone and HBB in ambient air = 0.3, 0.002 and 0.016 pg/m3 respectively. e Data from USEPA Integrated Risk Information System (IRIS) database, except for dioxins/furans (TDI from WHO1998). The TDI of PCB has been determined from the Lowest Observed Adverse Effect Level (LOAEL) of one specific PCB mixture, Aroclor 1254. f Only BDE-99 (one congener of penta-BDE) has a RfD value available therefore this congener was used to determine hazard quotient. 45 2.5.1.2 Human carcinogenic risk assessment Results of assessment of dietary and inhalation carcinogenic risks associated with exposure of local residents to POPs in the locally consumed food items and the ambient air are presented in Table 12. The calculated dietary or inhalation or total excess lifetime cancer risks of POPs all fell within the 1 x 10-4 – 1 x 10-6 range, indicating there was no unacceptable dietary or inhalation or total cancer risk of toxicological concern associated with a lifetime exposure of local residents to the current levels of POPs contamination in the locally consumed foods and the ambient air. The total excess lifetime cancer risk is the sum of the excess lifetime dietary cancer risk (= daily intake x slope factor) and excess lifetime inhalation cancer risk (= mean ambient air concentration x inhalation unit risk). Table 12: Human Carcinogenic Risk Assessment of POPs to the Residents of Hong Kong Chemical USEPA Cancer Classification b Dietary Inhalation Total Excess Lifetime Cancer Risk Acceptable Range of Excess Lifetime Cancer Risk (USEPA) Daily Intake (mg kg-1 bw d-1) Slope Factord (per (mg/kg)/ day) Excess Lifetime Cancer Risk Mean Ambient Air (pg/m3) (Dioxin: pg I-TEQ/m3) Daily Intakee (mg kg-1 bw d-1) Unit Riskd (per µg/m3) Excess Lifetime Cancer Risk Aldrin B2 5.90 x 10-6 1.70 x 101 1.00 x 10-4 1 2.88 x 10-10 4.90 x 10-3 4.90 x 10-9 1.00 x 10-4 1 x10-4 – 1 x 10-6 Chlordane B2 1.42 x 10-5 3.50 x 10-1 4.97 x 10-6 4.61 1.33 x 10-9 1.00 x 10-4 4.61 x 10-10 4.97 x 10-6 1 x10-4 – 1 x 10-6 DDT B2 3.99 x 10-5 3.40 x 10-1 1.36 x 10-5 12.19 3.51 x 10-9 9.70 x 10-5 1.18 x 10-9 1.36 x 10-5 1 x10-4 – 1 x 10-6 Dieldrin B2 5.90 x 10-6 1.60 x 101 9.44 x 10-5 5.21 1.50 x 10-9 4.60 x 10-3 2.40 x 10-8 9.44 x 10-5 1 x10-4 – 1 x 10-6 Endrin D 9.10 x 10-6 - - 0.6 1.73 x 10-10 - - - Heptachlor B2 8.40 x 10-6 4.50 x 100 3.78 x 10-5 2.38 6.88 x 10-10 1.30 x 10-3 3.09 x 10-9 3.78 x 10-5 1 x10-4 – 1 x 10-6 HCB B2 4.80 x 10-6 1.60 x 100 7.68 x 10-6 44.88 1.29 x 10-8 4.60 x 10-4 2.06 x 10-8 7.70 x 10-6 1 x10-4 – 1 x 10-6 Mirex 2Bc 2.80 x 10-6 - - 5.3 1.53 x 10-9 - - - Toxaphene B2 1.71 x 10-5 1.10 x 100 1.88 x 10-5 BDL BDL 3.20 x 10-4 - 1.88 x 10-5 1 x10-4 – 1 x 10-6 PCB B2 - 4.00 x 10-1 Dioxin-like : 0.003 5.5 x 10-9 1.00 x 10-4 - - 1 x10-4 – 1 x 10-6 Dioxins/ furansa B2 0.72 1.00 x 105 7.2 x 10-5 0.044 0.01 3.30 x 101 1.45 x 10-6 7.35 x 10-5 1 x10-4 – 1 x 10-6 α-HCH B2 1.20 x 10-5 6.30 x 100 7.56 x 10-5 2.22 6.39 x 10-10 1.80 x 10-3 4.00 x 10-9 7.56 x 10-5 1 x10-4 – 1 x 10-6 β-HCH C 1.80 x 100 2.16 x 10-5 2.33 6.71 x 10-10 5.30 x 10-4 1.23 x 10-9 2.16 x 10-5 1 x10-4 – 1 x 10-6 Chlordecone - 10 - BDL BDL - - - HBB - - - BDL BDL - - - Lindane 2.90 x 10-6 - - 3.32 9.56 x 10-10 - - - PeCB D 3.00 x 10-6 - - 4.88 1.41 x 10-9 - - - PFOS, PFOSF - - 4.12 1.19 x 10-9 - - - PBDE D 1.34 x 10-6 - - 43.8 1.26 x 10-8 - - - Endosulfan 1.66 x 10-5 - - 143.53 4.13 x 10-8 - - - HBCD - - - - - - - - aUnit for daily intake of dioxins/furans = pg I-TEQ kg -1 bw d-1. bUSEPA Weight-of-Evidence Cancer Classification System (B2 = probable human carcinogen; C = possible human carcinogen; D = not classifiable). cInternational Agency for Research on Cancer (IARC) Cancer Classification (2B = possible human carcinogen). dUSEPA Integrated Risk Information System (IRIS) database. eAssuming a respiratory rate of 20 min-1 and a tidal volume of 600 ml, for an average adult of 60 kg bw. 46 2.5.1.3 Health risk assessment of POPs in the local marine environment The level of POPs contamination in marine fish and shellfish sampled in the local waters was examined against Food Safety Standards/Action Levels published by other regulatory authorities (Table 13). The level of POPs contamination in marine fish and shellfish from Hong Kong waters was well below (by 1–2 orders of magnitude) the Food Safety Standards/ Action Levels set by the US, Mainland China and/or the European Community. The results indicated that there was no unacceptable risk of toxicological concern associated specifically with a lifetime exposure of local residents to the current level of POPs contamination in the local marine environment via dietary intake of locally caught seafood (marine fish and shellfish). Table 13: Comparison of the Level of POPs Contamination in Marine Fish and Shellfish sampled in Hong Kong Waters Chemical Mean concentration (µg kg-1 ww) Food safety standards / action levels Marine fish Marine shellfish Aldrin 0.06 0.11 300 (USFDAb) Chlordane 0.26 0.21 300 (USFDAb) DDT 4.12 3.27 5000 (USFDAb) 500 (PRCc) Dieldrin 0.04 0.09 300 (USFDAb) Endrin 0.06 BDL Heptachlor BDL BDL 300 (USFDAb) HCB BDL BDL Mirex 0.72 0.86 100 (USFDAb) Toxaphene BDL BDL PCBa Dioxin-like PCB: 0.08 Dioxin-like PCB: 0.13 500 (PRCc) Dioxins/ furansa 0.03 0.17 4 (ECd) α-HCH 0.08 0.11 β-HCH 0.04 BDL Chlordecone 0.08 0.05 300 (USFDAb) HBB 2.1 0.8 Lindane BDL BDL PeCB BDL BDL PFOS, PFOSF 0.71 BDL C-octaBDE 0.13 0.07 C-pentaBDE 0.38 0.57 Endosulfan - - HBCD - - aUnit for dioxins/furans and dioxin-like PCB = ng WHO-TEQ kg-1 ww bUSFDA Chemical Contaminant and Pesticide Action Levels, and Guidance Levels; unit = µg kg-1 ww. cPRC Food Safety National Standard; unit = µg kg-1 ww. dEuropean Commission Seafood Standard for fish and fish products; unit = pg WHO-TEQ g-1 ww. 47 2.5.2 Comparison with other countries/regions 2.5.2.1 Annual Release of Dioxins/Furans In 2012, the estimated annual release of dioxins/furans to the environment of Hong Kong via all vectors was 46.5 g TEQ. A comparison of the local annual dioxin/furan emission between the years of 2007 and 2013 with those of EU Regions (EEA, 2015), USA (USEPA, 2015), Switzerland (Bogdal, C., et al., 2014), Australia (Australia Government, 2014) and Iranian Provinces (Azari., M. R., et al., 2007) on a “per capital” basis was made, due to these countries and regions are also well economically developed (EU Regions, USA, Australia and Switzerland) or Asian country (Iranian Provinces). Among the six countries/regions collected with annual dioxin/furan emission in Table 14, Hong Kong’s total annual dioxin/furan release per capita was similar to Switzerland, USA, Australia and EU countries (i.e. in the same order of magnitude), but significantly lower than that of Iranian provinces. Table 14 Comparison of annual emission of dioxin/furans in Hong Kong and Other Countries/Regions Country/Region Year PCDD/PCDFs annual emission (g I-TEQ annual 1 ) PCDD/PCDFs emissions per-capita (ng I-TEQ capita 1 ) Hong Kong 2012 46.5 6,498 Switzerland 2011 64 8,030 USA 2013 1,372 4,403 Australia 2012 60 2,686 Iranian provinces 2007 1,282 16,997 EU countries 2012 1,771 3,581 2.5.2.2 Release of dioxins/furans in Ambient Air Table 15 compares the reported ambient air concentrations of dioxins/furans in Hong Kong and other countries/regions worldwide. Overall, the mean local ambient air dioxin concentration of 0.044 pg I-TEQ m-3 measured in 2013 was highly comparable to the range reported in most other countries/regions such as Europe (Castro-Jimenez, J., et. al., 2011; Bruckmann, P., et. al., 2013; Ragazzi, M., et. al., 2014; Mari, M., et. al., 2008) Asia (Shin, S. K., et. al. 2011; Chi, K. H., et. al. 2008, 2013) and was lower than that reported in North Africa (Moussaoui, Y., et. al., 2012). 48 Table 15: Comparison of Ambient Air Concentrations of Dioxins/Furans (PCDD/PCDF) in Hong Kong and Other Countries/Regions Location Period Concentrations of PCDD/PCDF (pg I-TEQ m-3) mean (min-max) Reference Hong Kong 2013 0.044 (0.008-0.182) EPD, EPD monitoring programme of POPs 2014 France 2007-2008 0.067-1.7 Castro-Jimenez, J., et. al., 2011 Germany 2011 0.017-0.024 Bruckmann, P., et. al., 2013 Italy 2009-2010 0.081 in Susa 0.061 in Torino Ragazzi, M., et. al., 2014 North Africa 2009 0.21-0.78 Moussaoui, Y., et. al., 2012 South Korea 2008 0.028 (ND*-0.617) Shin, S. K., et. al. 2011 Spain 2005-2006 0.018 Mari, M., et. al., 2008 *The values below the limit of detection (LOD, 0.05 pg m-3) were noted as “ND” (not detected). 2.5.2.3 Release of PCB, α-HCH and Lindane in Ambient Air Table 16 compares the reported ambient air concentrations of PCB, α-HCH and Lindane in Hong Kong and other countries/regions worldwide. Overall, the mean local ambient air PCB concentration of 0.003 pg WHO-TEQ m-3 (dioxin-like PCB) and 19.1 pg m-3 (Marker PCB) measured in 2013 was highly comparable to the range reported in most other locations in Asia (Hogarth, J. N., et. al., 2013; Shin, S. K., et. al. 2011), and was lower than that reported in Europe (Castro-Jimenez, J., et. al., 2011; Mari, M., et. al., 2008) and North Africa (Moussaoui, Y., et. al., 2012). The mean concentrations of α-HCH and lindane measured in 2014 in Hong Kong was much lower than North Africa (Moussaoui, Y., et. al., 2012). Table 16: Comparison of Ambient Air concentrations of PCB, α-HCH and Lindane in Hong Kong and Other Countries/Regions Location Period Concentration (pg m-3) – mean (min-max) Reference PCBs α-HCH Lindane Hong Kong 2013 Dioxin-like PCB*: 0.003 (0.002-0.008) Marker PCB*: 19.1 (7.2-42.8) 2.22 (0.85-6.6) 3.32 (0.65-13) EPD, EPD monitoring programme of POPs 2014 France 2007- 2008 Dioxin-like PCB: 1-8 Indicator PCB: 11-87 - - Castro-Jimenez, J., et. al., 2011 Japan 2008 33-1125 - - Hogarh, J. N., et. al., 2013 North Africa 2009 Dioxin-like PCB: 0.04-0.15 16-888 106-974 Moussaoui, Y., et. al., 2012 South Korea 2008 Dioxin-like PCB#: 0.008 (ND-0.016) - - Shin, S. K., et. al. 2011 Spain 2005- 2006 SAB area: 159 (62-127) BK area: 95 (62-127) - - Mari, M., et. al., 2008 49 * Unit of Dioxin-like PCB in ambient air = pg WHO-TEQ/m3; dioxin-like PCB in ambient air was detected by PCB with TEFs (12 congeners: 77, 81, 105, 114, 118, 123, 126, 156, 157, 167, 169, and 189); marker PCB in ambient air was detected by 7 congeners: 28, 52, 101, 118, 138, 153, and 180. # Unit of Dioxin-like PCB in ambient air = pg WHO-TEQ/m3; the values below the limit of detection (LOD, 0.05 pg m-3) were noted as “ND” (not detected). 2.5.2.4 Surface Soil Table 17 shows that the levels of PFOS contamination of surface soil in Hong Kong recorded in 2007–2013 was found to be lower than that reported in South Korea (Kim et al., 2014). As the levels for HBB, PeCB, PFOSF, PBDEs and endosulfan were all below the detection limit in Hong Kong (Zhang, H. B., et. al., 2007; EPD 2013 Investigation Study), a direct comparison with South Korea cannot be made. Table 17: Comparison of the Level of POPs Contamination in Surface Soil of Hong Kong and Other Countries/Regions Location Period HBB (µg/kg dw) PeCB (µg/kg dw) PFOS, PFOSF (µg/kg dw) PBDE (µg/kg dw) Endosulfan (µg/kg dw) Reference Hong Kong 2007 2013 BDL* BDL* PFOS: 0.197 (<0.3-0.624) PFOSF: BDL* BDL* BDL* Zhang, H. B., et. al., 2007; EPD 2013 Investigation Study South Korea 2010 2012 ND# 0.083 (ND#-0.531) PFOS: 0.29 (ND#-0.92) 0.68 (ND#-4.78) 2.19 (0.058-8.42) Kim, E. J., 2014 *“BDL” indicates values were below detection limits; Detection limits of PFOS and PFOSF in surface soil = 0.3 and 10 μg/kg dw, respectively; Detection limits of HBB, PeCB, C-octaBDE, C-pentaBDE and endosulfan in surface soil = 1, 0.1, 1, 0.1, 0.5, 1 and 7 μg/kg dw, respectively. # ”ND” indicates values were below detection limits; Detection limits of PFOS and PFOSF in surface soil = 0.05 μg/kg dw; Detection limits of PBDE and endosulfan in surface soil = 0.01 and 0.02 μg/kg dw, respectively. The detection limits for HBB and PeCB were not provided in the reference paper 2.5.3 Ecological Risk Assessment 2.5.3.1 Pelagic organisms risk assessment The calculated HQs for POPs, except DDT, were all below unity, indicating that there was no unacceptable risk of toxicological significance associated with exposure of local pelagic organisms to these POPs (Table 18). The mean concentration of DDT in marine water is slightly higher than the conservative screening chronic toxicity value, but significantly decreased from the level reported in the HKSARIP 2006 (<15 ng/L). DDT was subject to further evaluation by the in-depth Tier 2 Probabilistic Risk Assessment (PRA). The conclusion published by Ma, S.W.Y., et al. in 2006 illustrated that the higher value of DDT (<15 ng/L) in ambient marine water was within a tolerable range by adopting the screening value of 1.4 ng/L. The results of the PRA indicated that the lower 5th centile of the estimated chronic DDT toxicity distribution was not exceeded by the upper 5th centile of aquatic DDT exposure distribution, suggesting the potential ecological risk posed by exposure of local pelagic organisms to DDT was within a tolerable range. The same conclusion 50 can be also applied to a much lower value (1.9 ng/L) of DDT detected recently than in 2006, therefore, there is no significant ecological risk posed by exposure of local pelagic organisms to DDT. Table 18: Tier 1 Ecological Risk Assessment of POPs to Pelagic Organisms in Hong Kong in 2009-2011 Chemical Mean concentration in Hong Kong’s marine water b (ng L-1) Conservative screening chronic toxicity value (ng L-1) Hazard quotient Aldrin <5 21.3c <1 Chlordane 0.0418 88 c <1 DDT 1.908 1.4 c >1 Dieldrin <5 22 c <1 Endrin <5 44 c <1 Heptachlor <5 68 c <1 HCB <5 600 c <1 Mirex <5 400 d <1 Toxaphene <5 43.2 c <1 PCB Total PCB: 0.356 7800 c <1 Dioxins/ furansa 0.003 10 e <1 α-HCH 0.119 - β-HCH 0.246 7 c <1 Chlordecone <5 - HBB <5 - Lindane 0.215 7 d <1 PeCB <5 - PFOS, PFOSF PFOS: 0.02 -12 - C-octaBDE 0.041 - C-pentaBDE 0.232 - Endosulfan 0.0485 10 d <1 HBCD - - a Unit of PCDD/PCDF and dioxin-like PCB in marine/fresh water = pg WHO-TEQ/L. b: The value reported Below Detection Limit was calculated assuming 0.5 Detection Limit. c: The value represents LC50 divided by 50; LC50 = lethal concentration that kills 50% of the organisms under a specified time duration. d; Value from ANZECC – Australian and New Zealand Guidelines for Marine Water Quality 2000. e: Value from Human Health and Ecological Risk Assessment Work Plan (USEPA, 2004) and from Development of Aquatic Quality Standards for Dioxins (Final Report to the Department for Environment, Food and Rural Affairs, UK, 2003). 2.5.3.2 Benthic organisms risk assessment The calculated HQs for all POPs in the marine sediment, against the range of published SQC/Guidelines, were <1 (Table 19). The mean contamination level of POPs in the marine sediment of Hong Kong generally fell at the lower end of the range of screening concentrations published in the SQC/Guidelines of the US, Canada and Australia/New Zealand. The results indicated that there would be unlikely to be any risk of toxicological significance associated with exposure of local benthic organisms to the current level of POPs in the marine sediment. 51 Table 19: Tier 1 Ecological Risk Assessment of POPs to benthic organisms in Hong Kong in 2009-2011 Chemical Mean concentration in Hong Kong’s marine sediment (µg kg-1 dw)b Screening sediment quality criteria Reference Aldrin 0.164 9.5 NOAA, SQuiRTsTM, AETc Chlordane 0.135 4.50-8.87 0.5-6 0.5-6 Canadian Sediment Quality Guideline, ISQG to PELd NOAA, SQuiRTsTM, ERL to ERMc ANZECC ISQG, Low to highe DDT 1.671 6.15-20.03 1.58-46.1 1.6-46 Canadian Sediment Quality Guideline, ISQG to PELd NOAA, SQuiRTsTM, ERL to ERMc ANZECC ISQG, Low to highe Dieldrin 0.254 2.85-6.67 0.02-8 0.02-8 Canadian Sediment Quality Guideline, ISQG to PELd NOAA, SQuiRTsTM, ERL to ERMc ANZECC ISQG, Low to highe Endrin 0.014 2.67-62.4 0.02-8 Canadian Sediment Quality Guideline, ISQG to PELd ANZECC ISQG, Low to highe Heptachlor 0.148 0.3 298 NOAA, SQuiRTsTM, AETc Sediment Quality Criteriaf HCB 0.041 6 NOAA, SQuiRTsTM, AETc Mirex 0.471 96 Sediment Quality Criteriaf Toxaphene BDL 0.1 43.2 Canadian Sediment Quality Guideline, ISQGd Sediment Quality Criteriaf PCB Total PCB†: 0.15 Total PCB‡:18.36 34.1-277 22.7-180 23 237 Canadian Sediment Quality Guideline, ISQG to PELd NOAA, SQuiRTsTM, ERL to ERMc ANZECC ISQG, Lowe Sediment Quality Criteriaf Dioxins/ furansa PCDD/F†: 2.931 PCDD‡: 4.33 PCDF‡: 1.34 0.85-21.5 16.6 Canadian Sediment Quality Guideline, ISQG to PELd Sediment Quality Criteriaf α-HCH 0.035 - β-HCH 0.021 - Chlordecone BDL - HBB 0.002 - Lindane 0.064 0.94-1.38 0.32-1 Canadian Sediment Quality Guideline, ISQG to PELd ANZECC ISQG, Low to highe PeCB 0.122 - PFOS, PFOSF PFOS: BDL PFOSF: BDL C-octaBDE 0.089 - C-pentaBDE 0.077 - Endosulfan 7.08 - HBCD - - a Unit for dioxins/furans = ng I-TEQ kg-1 dw. b The average organic carbon content in Hong Kong marine sediments is approximately 0.8% (2004 data); 1% is assumed for ease of calculation and comparison in this table. 52 c US National Oceanic and Atmospheric Administration (NOAA) Sediment Guidelines, Screening Quick Reference Table for Organics (SQuiRTTM), 1999; AET = Apparent Effects Threshold; ERL = Effect Range Low; ERM = Effect Range Medium. d Canadian Sediment Quality Guideline for Protection of Aquatic Life, 2002; ISQG = Interim Sediment Quality Guideline; PEL = Probable Effect Level. e ANZECC recommended interim sediment quality guideline (ISQG) (normalized to 1% organic carbon), 2000; the ISQG low and high values correspond to the ERL and ERM used in the NOAA listing. f Sediment quality criteria adopted in EPD’s consultancy study ‘‘A Study of Toxic Substances Pollution in Hong Kong, Agreement No. CE 22/99 (Environmental)’’; unit for dioxins/furans = ng I-TEQ kg-1. †: Values from the Toxic Substances Monitoring Programme; and ‡: Values from the EPD 2013 Investigation Study 2.5.3.3 Marine mammals risk assessment Results of the ecological risk assessment of POPs in the marine environment to local cetaceans (the hump-backed dolphins and the finless porpoises) showed the HQs for 8 initial and 7 newly listed POPs studied (chlordane, DDT, dieldrin, heptachlor, HCB, toxaphene, PCB and dioxins/furans, chlordecone, HBB, lindane, PeCB, C-octaBDE, C-pentaBDE and endosulfan) were all less than unity, suggesting that there was no unacceptable risk of toxicological significance associated with exposure of local cetaceans to the current contamination level of these POPs in the marine environment (Table 20). The adopted toxicity values pertain to terrestrial mammals as values for marine mammals could not be found from the literature, which is identified as information gaps. Table 20: Ecological Risk Assessment of POPs to cetaceans in Hong Kong in 2010 - 2011 Chemical Overall exposure dose (μg kg-1 bw d-1) Adopted toxicity value (μg kg-1 bw d-1) Hazard quotient (exposure dose / toxicity value) Dolphin Porpoise Dolphin Porpoise Aldrin 4.23 x 10-3 6.38 x 10-3 Chlordane 1.66 x 10-2 1.76 x 10-2 1.88 x 101 <1 <1 DDT 2.62 x 10-1 2.77 x 10-1 1.00 x 102 <1 <1 Dieldrin 2.93 x 10-3 4.88 x 10-3 6.25 x 10-1 <1 <1 Endrin 4.16 x 10-3 6.00 x 10-3 Heptachlor 3.25 x 10-3 3.75 x 10-3 1.25 x 100 <1 <1 HCB 3.25 x 10-3 3.75 x 10-3 1.00 x 101 <1 <1 Mirex 4.77 x 10-2 5.93 x 10-2 Toxaphene 6.50 x 10-2 7.50 x 10-2 4.38 x 101 <1 <1 PCB 5.53 x 10-6 7.88 x 10-6 6.25 x 100 <1 <1 Dioxins/ furans 2.86 x 10-6 7.50 x 10-6 1.25 x 10-4 <1 <1 α-HCH 5.40 x 10-3 7.13 x 10-3 - - β-HCH 2.50 x 10-3 2.44 x 10-3 - - Chlordecone 5.01 x 10-3 4.88 x 10-3 8 x 102 <1 <1 HBB 1.28 x 10-1 1.09 x 10-1 2 x 103 <1 <1 Lindane 1.63 x 10-3 1.88 x 10-3 3.3 x 102 <1 <1 53 Chemical Overall exposure dose (μg kg-1 bw d-1) Adopted toxicity value (μg kg-1 bw d-1) Hazard quotient (exposure dose / toxicity value) Dolphin Porpoise Dolphin Porpoise PeCB 3.25 x 10-3 3.75 x 10-3 8.3 x 103 <1 <1 PFOS, PFOSF 4.19 x 10-2 2.85 x 10-2 - - C-octaBDE 8.06 x 10-3 7.50 x 10-3 4.5 x 102 <1 <1 C-pentaBDE 2.59 x 10-2 3.56 x 10-2 3.5 x 102 <1 <1 Endosulfan - - 6 x 102 - HBCD - - - 3 STRATEGIES, PRIORITIES, ACTION PLANS AND IMPLEMENTATION PROGRESS 3.1 POPs Management Framework and Implementation Strategy  Update the Pesticides Ordinance and HCCO as and when necessary to ensure that all amendments to Annexes to the Convention are properly incorporated, with the view to effectively controlling, minimizing and preventing the potentially adverse impact of POPs on human health and the environment.  Uphold the principle of environmental sustainability in pursuing community development, and apply best available techniques (BAT) / best environmental practices (BEP) to reduce environmental pollution by POPs.  Continue with our structured monitoring programme to characterize and quantify the local POPs emission profile which is vital to the planning and development of a practical and successful action plan to reduce or ultimately eliminate POPs. 3.2 Overall Assessment of Current POPs Pollution in Hong Kong  On a “per capita” basis, the current (2012) annual dioxin/furan release in Hong Kong was generally similar to similar to Switzerland, USA, Australia and EU countries, but significantly lower than that of Iranian provinces.  The mean local ambient air dioxin concentration measured in 2013 was highly comparable to the range reported in most other countries/regions such as Europe (France, Germany, Italy, Spain) and Asia(South Korea).  Assessment based on available data indicated that overall, there was unlikely to be any unacceptable ecological risk of toxicological significance associated with exposure of local marine life to the current level of POPs contamination in the marine environment of Hong Kong. 54  Total monthly exposure of local residents to dioxins/furans was estimated to be 21.9 pg TEQ/kg bw/month, a value falling at the lower end of the provisional tolerable monthly intake (PTMI) of 70 pg TEQ/kg bw per month set by the Joint FAO/WHO Expert Committee on Food Additives (2001). Dietary intake was the major route, accounting for 98.6% of total exposure of local residents to dioxins/furans.  Results of human health risk assessment indicated that there was no unacceptable inhalation nor dietary chronic/carcinogenic risk of toxicological concern associated with a lifetime exposure of Hong Kong residents to current levels of POPs contamination in the local environment and locally consumed foods.  Levels of POPs in local marine biota were found to be well below national and overseas Food Safety Standards/Action Levels of the Mainland, the US and the EC. 3.3 Action Plans and Implementation Progress 3.3.1. Strengthening of the Institutional and Regulatory Systems A summary of action items on institutional and regulation systems to meet the Stockholm Convention requirements and their implementation progress is presented in Action Plan 1. Action Plan 1 - Legislative Framework for POPs Management and Control No. Action Item Responsible Party Implementation Progress POPs Pesticides 1. To review the overall pesticide control system in Hong Kong. AFCD  The Pesticides Ordinance (Cap 133) was amended in 2013 to include new provisions to ensure full compliance with the requirements of the Stockholm Convention on the control of POPs pesticides and the Rotterdam Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade.  The amended legislation came into operation on 27 January 2014. Non-Pesticide POPs 2. To enact new legislation to regulate the import, export, manufacture and use of non-pesticide hazardous chemicals in Hong Kong. EPD  The Hazardous Chemicals Control Ordinance (HCCO) (Cap 595) came into operation on 1 April 2008.  In view of the listing of 5 non-pesticide new POPs under the Stockholm Convention in May 2009 and the acceptance of the listing by China in December 2013, EPD amended the HCCO and the amendment order has come into operation starting from 1 January 2015. 55 3.3.2. Validation and Refinement of the POPs Inventories The compilation of a robust and reliable POPs inventory is vital to the planning and development of practical and relevant action plans to effectively reduce and ultimately eliminate POPs in Hong Kong. Action Plan 2 summarizes the list of action items and their implementation progress to fill critical data gaps identified in the current POPs inventories, including the dioxin/furan source inventory, environmental levels of POPs contamination, dietary exposure to POPs and human body burden of POPs. Action Plan 2 - Validation and Refinement of the POPs Inventories No. Action Item Responsible Party Implementation Progress Source Inventories on POPs - Release of Unintentional POPs as by-Products 3. To establish a more representative local annual activity and emission level of the “aluminium production” process. EPD  Study of a local factory was completed and a locally derived emission factor made available in October 2006. EPD has updated the dioxin emission inventory using this local emission factor for aluminium production process. 4. To further analyze sewage effluent and sewage sludge at source. EPD  Further study on field sampling and laboratory analysis of toxic substances for effluent, sludge and treated landfill leachate in landfills and sewage treatment works was commissioned in October 2011 and completed in June 2012. 5. To collate information on local stormwater production and analyze the stormwater for level of dioxin/furan contamination. EPD  EPD conducted baseline information gathering survey for the 3-year-cycle Toxic Substances Monitoring Programme (TSMP) from 2004 to 2012 and collected stormwater samples from 8 locations around Hong Kong. EPD will continue to collect storm water samples from 3 of the above 8 locations every 3 years for comparison with the baseline data, starting from the fourth cycle (i.e. 2013 to 2015). 6. To analyze local livestock waste composting and establish a local dioxin/furan emission factor specific trade. EPD  Study was completed in February 2007. Local emission factor was available for the update of local POPs inventory. 7. To further study the composition and fate of boiler ash residues generated from coal fired power boilers plants. EPD  Study was completed in February 2008. Local emission factor was available for the update of local POPs inventory. 8. To control the PFOS/ PFOSF containing aqueous film forming foam EPD  EPD requested proper storage of the foam and conducted regular monitoring of PFOS/PFOSF levels in the environment.  The disposal of PFOS/PFOSF containing foam is controlled by the Waste Disposal Ordinance. 56 No. Action Item Responsible Party Implementation Progress Environmental Levels of POPs - POPs in Local Environmental Media and Aquatic Biota 9. To include all 12 Convention POPs in the routine monitoring programme for local ambient air. EPD  EPD has regularly monitored ambient air levels of dioxins, furans and PCB in Hong Kong since mid-1997. In view of the listing of 10 new POPs under the Stockholm Convention in May 2009 and May 2011, we have worked with the Government Laboratory and commenced regularly monitoring of organochlorine pesticides in January 2011 with a view to including other POPs in our reporting programme in phases. 10 To include all 12 Convention POPs (dioxins/furans in particular) in the routine monitoring programme for local marine water, sediment and biota. EPD  Starting from the second cycle of the TSMP (2007-2009), all 12 Convention POPs have been included in the test list for local marine water, sediment and biota samples.  Since 2011, 9 more new POPs have been added to the monitoring list and thus EPD has regularly increased the number of POPs monitor for local marine water, sediment and biota to 21 11. To conduct further studies of POPs in local water birds on a project basis AFCD  The Study was finalized in October 2007. The final report was forwarded to EPD in November 2008. 12. To conduct further studies of POPs in local marine mammals on a project basis AFCD  The Study on Tissue Analyses and Ecological Risk Assessment for Marine Mammals in Hong Kong was finalized in October 2009. 13. To monitor the level of POPs contamination in local inland water and river sediment on a project basis. EPD  EPD conducted baseline information gathering survey for the 3-year-cycle Toxic Substances Monitoring Programme (TSMP from 2004 to 2012 and collected inland water and sediment samples from 7 locations around Hong Kong. EPD will continue to collect inland water and sediment samples from 2 of the above 7 locations every 3 years for comparison with the baseline data, starting from the 4th cycle (i.e. 2013 to 2015), 14. To monitor the level of POPs contamination in local surface soil and vegetation on a project basis EPD  Field sampling and laboratory analysis of POPs in local surface soil samples was commissioned in November 2009 and completed in March 2010. 57 No. Action Item Responsible Party Implementation Progress Dietary Exposure to POPs – POPs Contamination in Locally Consumed Foods and Drinking Water, Food Consumption Patterns and Food Safety Standards/Action Levels 15. To include all 12 Convention POPs for analysis in all main locally consumed food groups in the routine food surveillance programme. FEHD  Eleven of the 12 Convention POPs (i.e., except toxaphene) are now included in the Food Surveillance Programme. 16. To consider including all 12 Convention POPs in the routine drinking water surveillance programme. WSD  The surveillance program for the analysis of 12 Convention POPs in drinking water commenced in November 2006. 17. To conduct the Hong Kong Population-based Food Consumption Survey commissioned by FEHD To conduct Total Diet Studies (TDS) in the future when additional resources are made available. FEHD  The results of the population-based food consumption survey were released in the CFS website in April 2010.  The food consumption data has been used for estimating the exposure of various nutrients and contaminants in many our risk assessment projects (e.g. Dietary Iodine Intake in Hong Kong Adults) as well as in the TDS for enhancing our understanding on the size of the risk from exposure to various contaminants and food additives and which population groups may be most at risk. Such information is vital for the Government in formulating public policies and education strategies to promote food safety in Hong Kong.  The reports on dioxins and dioxin-like PCB and polybrominated diphenyl ethers (PBDE) have been released in December 2011 and April 2012, respectively.  The laboratory testing for the other POPs in food, i.e. aldrin, dieldrin, endrin, chlordane, DDT, heptachlor, hexachlorobenzene (HCB), mirex and toxaphene, chlordecone, pentachlorobenzene, endosulfan, alpha-hexachlorocyclohexane, beta-hexachlorocyclohexane, and lindane has completed and the whole TDS project was completed in 2014. 58 No. Action Item Responsible Party Implementation Progress 18. To consider setting Food Safety Action Levels on POPs specific to Hong Kong FEHD  Reference to national and international food safety standards is made when considering food safety action levels. The action levels will be set, if necessary, subject to the findings of the Total Diet Study. Human Body Burden of POPs - Human Breast Milk and Blood/Serum 19. To participate in the 4th and subsequent WHO-Coordinated Survey of Human Milk for the 12 Convention POPs DH  Study on POPs level in human milk for Hong Kong population has been finalised in January 2011. 20. To consider, taking into account international best practices, initiating measurements of POPs in the blood/serum of local residents on a project basis DH  Study to be considered later when resources are available. 3.3.3. Measures to Reduce Emission of Unintentionally Produced POPs Article 5 of the Stockholm Convention calls for Parties to take measures to reduce the production and release of unintentionally produced POPs, i.e., dioxins/furans, and for BAT/BEP to be applied for new sources in the source categories identified in Part II of Annex C. In the HKSAR, all Annex C, Part II source categories identified, including incinerators (crematoria and chemical waste incineration works), aluminium (secondary) works and power plants, are Specified Processes subject to licensing control under the Air Pollution Control (Specified Processes) Regulations. Operators are required to implement best practicable means (BPM) to control and minimize air emission from their operations. The BPM set out minimum technical requirements for plant/process designs, work practices and emission standards. To ensure that the emission requirements are in line with the latest best international practice, the BPM will be reviewed from time to time and revised, as required, taking into consideration relevant international BAT/BEP guidelines including those of the Stockholm Convention on POPs. Any new development of the above source categories is also subject to a rigorous environmental impact assessment process under the EIAO. Measures to reduce emissions of unintentionally produced POPs, i.e. dioxins/furans, and their implementation progress are summarized in Action Plan 3. These measures are being pursued as part of the HKSARG’s environmental portfolio in accordance with the established timetable. 59 Action Plan 3 - Measures to Reduce Emission of Unintentionally Produced POPs No. Action Item Responsible Party Implementation Progress Emission of Dioxins/Furans to Air 21. To optimize the use of existing generating capacity of gas-fired power plants and to progressively phase out old coal-fired generation units and replace with gas-fired plants EPD  We promulgated in December 2010 and November 2012 and December 2014 the Second and Third and Fourth Technical Memorandum to further tighten the emission caps on the power sector from the 2010 emission caps level starting 2015, 2017 and 2019 respectively and in effect the power companies need to maximizing the use of their existing gas fired generation units and prioritizing the use of coal-fired generation units with retrofits to meet the tightened emission caps requirement.  For the long term strategy, we propose to revamp the energy mix to further increase the use of cleaner energy and reduce the reliance on coal generation by 2020. 22. To tighten dioxin emission standards for crematoria under best practicable means and progressively phase out or replace old cremation units. EPD / FEHD  The revised guideline on the best practicable means for crematoria issued in September 2008 has tightened the dioxin/furan emission standard to 0.1ng I-TEQ/m3 for new installations. Plans are being worked out to progressively replace the old cremators in public crematoria without causing major disruption of service.  Replacement work for the cremators in Wo Hop Shek Crematorium completed in late 2012. In addition, Phase 1 of replacement work for cremators in Cape Collinson Crematorium had been completed in late 2012 and Phase II be completed at about end of 2015. 23. To introduce more stringent motor vehicle emission standards. EPD  We implemented the Euro V vehicle emission standards in phases starting from 1 June 2012.  All newly registered vehicles have to comply with Euro V emission standards starting from 31 December 2012.  Subject to the availability of compliant vehicle models, we will consider the timetable to implement Euro VI emission standards as soon as practicable. 60 No. Action Item Responsible Party Implementation Progress Emission of Dioxins/Furans to the Marine Environment 24. To implement a territory-wide sewage improvement programme, including the Harbour Area Treatment Scheme (HATS) Stage 2A and upgrading of sewage treatment works EPD  With major works under the HATS Stage 2A completed in 2014, Stage 2A is expected to be commissioned in the third quarter of 2015 after the testing and commissioning progamme.  The construction of new sewage treatment works (STW) in Yung Shue Wan and Sok Kwu Wan of Lamma Island has commenced in 2010 for completion in 2014.  There are now plans to progressively expand and upgrade the regional STWs at Shek Wu Hui,Yuen Long, San Wai, Sha Tau Kok, Tuen Mun, Mui Wo, Tai O and Cheung Chau within the next five years. Integrated Environmental Waste Management 25. To implement integrated waste management in a sustainable and environmentally sound manner, including waste prevention and recycling as top priority and adoption of BAT and BEP to treat clinical waste, sewage sludge and unavoidable municipal solid waste EPD  “A Policy Framework for the Management of Municipal Solid Waste (MSW) (2005-2014)” was published in December 2005 to achieve sustainable waste management.  In May 2013, the "Hong Kong: Blueprint for Sustainable Use of Resources 2013-2022" (the Action Blueprint) was published. The Action Blueprint maps out a comprehensive strategy, targets, policies and action plans for waste management in Hong Kong for the coming 10 years, and it aims to reduce the per capita disposal rate of municipal solid waste (MSW) by 40 per cent by 2022.  The Government plans to build the first phase Integrated Waste Management Facilities (IWMF) with a daily capacity of 3,000 tonnes. Using advanced incineration as the core technology, the facility will reduce the volume of MSW treated by 90 per cent. The BAT and BEP would be adopted in designing and constructing the IWMF. We have commenced the tendering procedures for the project and plan to commission the facilities in 2022-23.  BAT and BEP will also be adopted in treating clinical waste and sewage sludge. A sewage sludge treatment facility (STF) with a capacity of 2,000 tonnes per day has been built at Tuen Mun. Sewage sludge from local sewage treatment plants has been diverted to the STF for high temperature incineration. All clinical waste has been collected for disposal by high temperature incineration at the designated Chemical Waste Treatment Centre (CWTC) starting from August 2011 61 3.3.4. Public Awareness Campaign A summary of the action items to raise local public awareness of POPs-related issues and their implementation progress is presented in Action Plan 4. Action Plan 4 - Public Awareness Campaign No. Action Item Responsible Party Implementation Progress 26. To develop a dedicated POPs thematic website under EPD’s website. EPD  EPD’s thematic website on POPs was launched in May 2006 and updated in September 2014 27. To produce POPs information pamphlets for distribution to the public, and to design exhibition panels for display in EPD’s Environment Resource Centres and other appropriate venues. EPD  POPs publicity leaflets, posters and POPs thematic souvenirs were distributed to the public (students, adult visitors) through their visits to the Environment Resource Centres. 28. To organize publicity events, education/training programmes and visits to various target groups on POPs-related themes and topics. EPD  POPs-related topics are included in the guided tours organized in the Environment Resource Centres. About 640 and 680 guided tours in 2013 and 2014 respectively covered topics related to POPs for primary and secondary students.  To celebrate the 10th anniversary of the signatory of the Stockholm Convention on Persistent Organic Pollutants (POPs) and to enhance public awareness on POPs, a "Roving Exhibition on Persistent Organic Pollutants" was held in 9 locations of Hong Kong from November 2011 to March 2012 3.3.5. Regional Collaboration with the Mainland Hong Kong is geographically located at the Pearl River Estuary. Sound and effective environmental management of environmental pollution of POPs must encompass the PRD Region as a whole. Action Plan 5 presents the action items and their implementation progress for strengthening regional collaboration with the Mainland especially the PRD. Action Plan 5 - Regional Collaboration with the Mainland 62 No. Action Item Responsible Party Implementation Progress 29. To organize regional technical workshops and training seminars on POPs monitoring and analytical protocols, and risk assessment methodologies. EPD/GL  With EPD’s coordination, GL participated in the Asian component of the “First Worldwide UNEP Intercalibration Study on Persistent Organic Pollutants” organized by the Chemicals Branch of UNEP. GL’s representatives attended a project inception workshop in Beijing in April 2009. The project final workshop was held in February 2010 in Hong Kong.  A POPs Workshop was organized and held on 10-11 April 2012 in Hong Kong with participants from Pan-PRD provincial and municipal environmental authorities and various local academics. 30. To conduct joint regional POPs monitoring programme on a project basis. EPD/GL  A pilot joint project on the analysis of POPs in water/sediment samples in Deep Bay was completed successfully by EPD/GL and SZ Environmental Monitoring Centre (SZEMC) / SZ Centre for Disease Control in 2009.  EPD and SZEMC also collaborated on the development and refinement of dioxin inventory in both places and joint regional dioxin monitoring prgramme at SZ and HK was held in September 2012. SZEMC and HKEPD exchanged the dioxin monitoring data in April 2013 for review. 3.3.6. Capacity Building To achieve the objectives of the HKSARIP, the following capacities would need to be built up and/or strengthened within the HKSAR. The action items and their implementation progress are summarized in Action Plan 6. Action Plan 6 - Capacity Building No. Action Item Responsible Party Implementation Progress 31. To improve legislative and management systems for comprehensive and effective POPs control in Hong Kong. EPD/AFCD  The Pesticides Ordinance (Cap 133) and the Hazardous Chemicals Control Ordinance (Cap 595) have been enacted to set out legislative and management systems for comprehensive and effective POPs control in HKSAR. 63 No. Action Item Responsible Party Implementation Progress 32. To promote BAT/BEP in local community activities, industrial processes and public utilities. EPD  It is an ongoing process to review from time to time the best practicable means (BPM) guidelines on combustion related processes and the dioxin/furan control. Requirements would be revised, as necessary, in line with “Guidelines on Best Available Techniques and Provisional Guidance on Best Environmental Practices relevant to Article 5 and Annex C” of the Stockholm Convention on Persistent Organic Pollutant.  The dioxin/furan control requirements of the BPM guidelines for major emitting sources like crematoria, various types of waste incinerators, secondary steel production (Electric Arc Furnace) and cement production have been updated accordingly. The BPM guidelines for asphalt concrete production are being reviewed. 33. To enhance local POPs monitoring and analytical capabilities, in close collaboration with the local academia and commercial laboratories. EPD/GL  The Government Laboratory is one of POPs laboratories under the UNEP Databank of Laboratories Analysing Persistent Organic Pollutants and participated the Inter-calibration Study for POPs laboratories - Asia Region in 2009 34. To update the POPs database and refine the POPs inventories. EPD  EPD has commissioned a study to review the contamination levels of the 5 non-pesticide new POPs under the Stockholm Convention. The study assessed the levels of new POPs in our environment. The study was completed in May 2013. 3.3.7. Implementation Plan Review and Effectiveness Evaluation Articles 15 and 16 of the Stockholm Convention call for periodic progress/effectiveness review of a National Implementation Plan and reporting to the Conference of the Parties. The HKSARIP has included action plans to control/restrict the import, export, manufacture and use of the intentionally produced POPs, to reduce dioxin/furan emission, and to improve local and regional control and management of POPs. 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Geoderma 138 (2007) 244–251 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27th March of 2018 附件三 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 1 Table of Contents 1 Introduction ............................................................................................ 4 2 Basic Information of the Macao SAR .................................................... 5 2.1 Overview of the Macao SAR ................................................................. 5 2.1.1 Geographical Location ........................................................................... 5 2.1.2 Population, Tourists and Language ........................................................ 6 2.1.3 Economic Development ....................................................................... 6 2.1.4 State of the Environment ....................................................................... 7 2.1.4.1 Atmospheric Environment ..................................................................... 7 2.1.4.2 Water Resources ..................................................................................... 8 2.1.4.3 Waste ...................................................................................................... 9 2.1.4.4 Nature and Ecosystems ........................................................................ 11 2.1.5 Medical Service ................................................................................... 11 2.2 System, Environmental Policies, Regulatory Framework and Associated Implementation Mechanisms ............................................ 12 2.2.1 Political System ................................................................................... 12 2.2.2 Environmental Policies ........................................................................ 14 2.2.3 Departments involved in the Implementation of the “Convention” or Management of POPs and their Functions and Responsibilities ......... 15 2.2.4 International Conventions Concerning the Control of POPs and Applicable to the Macao SAR ............................................................. 19 2.2.5 Rules and Regulations Concerning the Control of POPs..................... 20 2.2.6 Regulatory Framework and Associated Implementation Mechanisms 20 2.3 Assessment of the POPs Issues in the Macao SAR ........................... 20 2.3.1 Assessment of POPs Pesticides in Annex A of the “Convention” ...... 20 2.3.2 Assessment of Polychlorinated Biphenyls (PCBs) in Annex A of the “Convention” ....................................................................................... 21 2.3.3 Assessment of Polybrominated Diphenyl Ethers (PBDEs) and Hexabromobiphenyl (HBB) in Annex A of the “Convention” ............ 22 2.3.4 Assessment with Respect to HBCD in Annex A of the “Convention” 22 2.3.5 Assessment with Respect to DDT in Annex B of the “Convention” .. 23 2.3.6 Assessment of PFOS, its salts and PFOSF in Annex B of the “Convention” ....................................................................................... 24 2.3.7 Assessment of Releases of Unintentional Produced Chemicals in Annex C of the “Convention” ............................................................. 24 2.3.8 Status of Stockpiles and Contaminated Sites ....................................... 31 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 2 2.3.9 Requirements for Exemptions .............................................................. 31 2.3.10 Existing Programmes for Monitoring Releases and Environmental and Human Health Impacts ........................................................................ 32 2.3.11 Current Status among Target Groups ................................................... 37 2.3.12 Mechanism on Reporting and Information Exchange with Other Parties to the “Convention”.............................................................................. 37 2.3.13 Relevant Activities of Non-governmental Stakeholders ...................... 37 2.3.14 Linkage to POPs-related Projects to International Programmes and Projects ................................................................................................. 38 2.3.15 Identification of Impacted Populations or Environments .................... 38 2.3.16 System for the Assessment and Listing of New Chemicals ................. 38 2.3.17 System for the Assessment and Regulation of Chemicals Already in the Market .................................................................................................. 38 3 Strategy and Action Plans for the Implementation Plan of the Macao SAR ...................................................................................................... 39 3.1 Policy Statement .................................................................................. 39 3.2 Strategy for Implementation ................................................................ 39 3.3 Activities, Strategies and Action Plans ................................................ 40 3.3.1 Activity: Institutional and Regulatory Strengthening Measures .......... 40 3.3.2 Activity: Measures to Reduce or Eliminate Releases from Intentional Production and Use .............................................................................. 41 3.3.3 Activity: Production, Import and Export, Use, Stockpiles, and Wastes of Annex A POPs Pesticides ................................................................ 42 3.3.4 Activity: Production, Import and Export, Use, Identification, Labeling, Removal, Storage, and Disposal of PCBs and Equipment Containing PCBs .................................................................................................... 42 3.3.5 Activity: Production, Import and Export, Use, Stockpiles, and Wastes of Hexabromodiphenyl Ether and Heptabromodiphenyl Ether, Tetrabromodiphenyl Ether and Pentabromodiphenyl Ether................. 43 3.3.6 Activity: Production, Import and Export, Use, Stockpiles, and Wastes of DDT ................................................................................................. 43 3.3.7 Activity: Production, Import and Export, Use, Stockpiles, and Waste of PFOS, its salts and PFOSF .................................................................. 43 3.3.8 Activity: Production, Import and Export, Use, Stockpiles, and Waste of HBCD .................................................................................................. 43 3.3.9 Activity: Register for Specific Exemptions and the Continuing Need for Exemptions ..................................................................................... 44 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 3 3.3.10 Action Plan: Measures to Reduce Releases from Unintentional Sources .............................................................................................................. 44 3.3.11 Activity: Measures to Reduce Releases from Stockpiles and Wastes .. 45 3.3.12 Strategy: Identification of Stockpiles, Articles in Use and Wastes ...... 45 3.3.13 Activity: Manage Stockpiles and Appropriate Measures for Handling and Disposal of Articles in Use ............................................................ 46 3.3.14 Strategy: Identification of Contaminated Sites and Remediation in an Environmentally Sound Manner .......................................................... 46 3.3.15 Activity: Facilitating or Undertaking Information Exchange and Stakeholder Involvement ..................................................................... 46 3.3.16 Activity: Public Awareness, Information and Education ..................... 47 3.3.17 Activity: Effectiveness Evaluation....................................................... 47 3.3.18 Activity: Reporting .............................................................................. 47 3.3.19 Activity: Research, Development and Monitoring .............................. 48 3.3.20 Activity: Technical and Financial Assistance ...................................... 48 3.4 Development and Capacity-building Proposals and Priorities ............ 48 3.5 Timetable for Implementation Strategy and Relevant Implementing Bodies .................................................................................................. 49 3.6 Implementation Status of the Macao SAR Implementation Plan ........ 51 3.7 Resource Requirements ....................................................................... 55 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 4 1 Introduction Persistent Organic Pollutants (POPs) mainly come from human industrial and agricultural activities. As POPs are of severe toxicity, persistency (hard to degrade), easy to evaporate (long-distance transmission), able to accumulate in organisms and can be largely scattered in air, soil, lakes and oceans, they may pose serious threat to and have huge impact on human health and the whole ecosystem. In order to control and ultimately eliminate the production, use, discharge and storage of these toxic chemicals, and to avoid mankind and the environment from potential hazard, the People’s Republic of China (P.R.C) had signed the “Stockholm Convention on Persistent Organic Pollutants” (hereinafter referred to as “Convention”) in 2001. The “Convention” became effective for the P.R.C on 11 th November of 2004, and was applied to the Macao Special Administrative Region (Macao SAR) since 22 th November of 2004, according to the Chief Executive’s Notice No. 41/2004. The P.R.C deposited its note referring to the fourth meeting (COP4) held from 4 th to 8 th May of 2009, which adopted amendments to Annexes A, B and C to the Stockholm Convention to list nine new persistent organic pollutants as well as the ratification of the fifth meeting (COP5) held from in 25 th to 29 th April of 2011, which adopted an amendment to Annex A to the Stockholm Convention to list technical endosulfan and its related isomers, to the United Nations Secretary-General on 24 th December of 2013. The above amendments were entered into force in the P.R.C on 26 th March of 2014, and are applicable to the Macao Special Administrative Region since 23 rd April of 2014, according to the Chief Executive’s Notice No. 13/2014. The P.R.C accepted the Amendment of listing Hexabromocyclododecane (HBCD) to the Stockholm Convention on Persistent Organic Pollutants on 27 th September of 2016, which entered into force in the P.R.C on 26 th December of 2016. And according to the Chief Executive’s Notice No. 3/2017, this amendment entered into force in Macao SAR on 6 th February of 2017. Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 5 2 Basic Information of the Macao SAR 2.1 Overview of the Macao SAR 2.1.1 Geographical Location The Macao SAR (hereinafter referred to as Macao, except for some particular terms) is part of the territory of the P.R.C, located at the southern coast of mainland China, on the seashore of the Pearl River Delta, with longitude at 113°35’ and latitude at 22°14’. Macao consists of Macao Peninsula, Taipa Island, Coloane Island and Cotai reclamation zone. The total area of Macao by the end of 2016 was 30.5 km 2 , of which Macao Peninsula covered 9.3 km 2 , Taipa Island 7.6 km 2 , Coloane Island 7.6 km 2 , and Cotai reclamation zone 6.0 km 2 . 1 According to the Chief Executive’s Notice No. 128/2015 on 20 th December of 2015, announcing the Decree of the State Council of the People's Republic of China (No. 665), the Central People's Government decided to define the maritime areas of the Macao Special Administrative Region as 85 square kilometers. Figure 1 Map of Macao (2018) 2 1 Sources: Statistics and Census Service, 2017 2 Sources: Cartography and Land Registry Bureau, 2018 http://www.dscc.gov.mo/ Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 6 2.1.2 Population, Tourists and Language The total number of Macao’s population was about 645,000 by the end of 2016, with an average population density about 21,000 per km 2 . The total number of visitor arrivals was around 30,950,000. In addition to Chinese being the official language, Portuguese can also be used within the administrative, legislative and judiciary system in Macao. English is another commonly used language. 0 100 200 300 400 500 600 700 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 Population ('000) year Figure 2 Macao’s Population Change (2007-2016) 3 2.1.3 Economic Development 4 Macao is positioning as a “World tourism and leisure centre” in its regional development orientation. Currently its major income comes from tourism and gaming industry. The Macao Pataca (MOP) is the legal tender in the Macao SAR. In 2016, the GDP of Macao at current prices was MOP 358.2 billion (or USD 44.8 billion). The average GDP per capita was MOP 555,000 (or USD 69,000). The number of workforce of Macao in 2016 was 397,000, of which 390,000 were in employment. The labor participation rate was 72.3%, with an unemployment rate of 1.9% and underemployment rate of 0.5%. 2.1.3.1 Foreign Trade 5 3 Sources: Statistics and Census Service, 2008-2017 4 Sources: Statistics and Census Service, 2017 5 Sources: Statistics and Census Service, 2017 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 7 The total value of import goods of Macao in 2016 was MOP 71.35 billion (or USD 8.92 billion), with food and beverages, industrial supplies not elsewhere specified, fuels and lubricants, capital goods (except transport equipment), transport equipment and parts and accessories thereof, consumer goods not elsewhere specified accounting for 17.4%, 9.1%, 8.6%, 16.9%, 3.3% and 44.7% respectively. The total export value of Macao in 2016 was MOP 10.05 billion (or USD 1.26 billion), of which 80.5% was re-export. Mainland China and Hong Kong are the major export markets. 2.1.3.2 Industries 6 Manufacturing is the major industry in Macao. There were 883 operating industrial sites in 2016, including 877 sites for manufacturing activities, accounting for 99.3% of the total. The remaining 6 industrial sites include mining and production and distribution of gas and water. Based on the information available, the Macao Refuse Incineration Plant, the Macao Special and Hazardous Waste Treatment Plant and the wastewater treatment facilities are estimated to be the potential sites for unintentional release of POPs stated in Annex C of the “Convention”. 2.1.4 State of the Environment 2.1.4.1 Atmospheric Environment Currently, Macao’s air pollution sources are mainly from stationary sources and mobile sources. The former includes sites of waste incineration facilities, wastewater treatment facilities, power plants, commercial and industrial boilers, cement manufacturing, chemical and pharmaceutical industry, as well as oil storage facilities, while the latter comes from the exhaust emissions of vehicles. 6 Sources: Statistics and Census Service, 2014 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 8 0 50,000 100,000 150,000 200,000 250,000 300,000 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 Number of vehicles (no.) Year Heavy motorcycle Light motorcycle Industrial vehicle Light automobile Heavy automobile Figure 3 Change of Number of Vehicles in Macao (2007-2016) 7 Besides the above mentioned factors, air quality in Macao is also affected by the weather conditions, and also the climate and air quality of neighboring areas. Based on the impacts on human health, the Air Quality Index (AQI) in Macao is divided into six levels: good, moderate, poor, very poor, severe, and harmful. In July of 2012, the AQI of Macao was raised to the advised level of interim target-1 (IT-1) by the World Health Organization (WHO), and fine suspended particulate with diameter less than 2.5μm (PM2.5) has since been included as a parameter for index calculation. According to the air quality monitoring data in 2016, the monitoring stations recorded “Good” and “Moderate” air quality on more than 95% of the monitoring days. There was no record of “Very Bad” air quality in 2016. 8 2.1.4.2 Water Resources 2.1.4.2.1 Drinking Water 96% 9 of drinking water in Macao comes from Mainland China. The total amount of water consumption in Macao was 86.703 million m 3 in 2016, among which industrial and commercial sectors account for 50.9%, while household usage takes up 42.6%. 10 The treatment of drinking water in Macao is the responsibility of a specialized company, and the quality of drinking water fulfills relevant EU standards. 7 Sources: Statistics and Census Service, 2008-2017 8 Sources: Statistics and Census Service, 2017 9 Sources: Statistics and Census Service, 2017 10 Sources: Statistics and Census Service, 2017 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 9 Figure 4 Change of Water Consumption in Macao (2007-2016) 11 2.1.4.2.2 Wastewater Treatment There are 5 wastewater treatment facilities in Macao, including the WWTP in Macao Peninsula, WWTP in Taipa, WWTP in Coloane, WWTP in Transborder Industrial Zone and WWTP of Macao International Airport. Most of the wastewater in Macao is treated before discharge. In 2016, the average daily treated volume of water by the WWTPs in Macao is about 229,000 m 3 . 2.1.4.2.3 Water Conservation Planning The Macao SAR Government published the “Macao’s Water Conservation Planning Outline” in 2010 in order to develop Macao into a society dedicated to water conservation, establishing development plan and guidelines for relevant work between 2010 to 2025., 2.1.4.2.4 Quality of Coastal Waters There are 12 coastal water quality monitoring points in Macao. According to the monitoring results in 2016, the non-metal evaluation indexes of 7 monitoring points were higher than or equal to the upper limits of the standards, which reflects a rather severe non-metallic pollution in some parts of coastal waters in Macao. 12 2.1.4.3 Waste Currently, waste is mainly treated through incineration, with landfill as a 11 Sources: Statistics and Census Service, 2008-2017 12 Sources: Health Bureau, 2017 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 10 supplementary method. In recent years, the total quantity and volume of waste in Macao shows a continuous increasing trend along with the urban development. 0 1,000 2,000 3,000 4,000 5,000 6,000 100,000 200,000 300,000 400,000 500,000 600,000 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 Volume ('000 m3)Weight (tonne) year Municipal solid waste Construction waste Figure 5 Waste Types and Quantity in Macao (2007-2016) 13 Municipal solid waste in Macao is transferred to the Macao Refuse Incineration Plant for treatment, while special and hazardous waste (including waste vehicle tyres, solid and liquid hazardous waste, dead bodies of horses and dogs, waste from slaughter houses, medical waste, sediment of diesel waste, etc.) is treated at the Macao Special and Hazardous Waste Treatment Plant while construction waste is treated at the construction waste landfill zone. In the aspect of recycling, taking the relevant import and export statistics for estimation of recyclable paper, recyclable plastic and recyclable metals etc., the waste recovery rate maintains at a relatively stable level in recent years, around 18-20%. Figure 6 Recovery Rate of Recyclable Waste in Macao in Recent Years 14 Note: (1) Including recoverable waste of plastics, rubber, paper and metals, etc. 13 Sources: Statistics and Census Service, 2008-2017 14 Sources: Statistics and Census Service, 2017 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 11 (2) Since the waste collected in Macao has been mainly exported to the Mainland China and other countries or regions for recycling, the above estimation is made with reference to the DSEC import and export data, including statistics of recyclable paper, recyclable plastics, recyclable metals, etc. 2.1.4.4 Nature and Ecosystems In the preservation of the natural environment, the Cotai Ecological Zone, the Baía de Nossa Senhora da Esperança Wetland Ecological Viewing Zone, the Simulation of the Ecological Zone of Alto de Coloane, and the Ká Hó Reservoir Freshwater-Wetland Ecological Zone are the major wetlands for ecological conservation in Macao. The Cotai Ecological Zone, located at the west side of the Cotai Reclamation Area, reported the highest number of 45 endangered Black-faced Spoonbills within the area in the year of 2016. Meanwhile, a total area of 198,060 m 2 has been declared as a protection zone in Macao, and the areas in Coloane that are over 80 meters above sea level are also listed as designated protection zones in order to protect the natural resources of Macao. As of 2015, there were 416 species of trees in Macao, and 19,000 trees were planted along the pavement areas. There were a total of 25,000 trees in the city and the green area under the jurisdiction of Civil and Municipal Affairs Bureau was 8.7km 2 15 . There were 126 species of birds recorded in 2016, while the number of species of fish, amphibians, reptiles, mammals and insects were recorded as 218, 9, 26, 27 and 373 respectively. 16 2.1.5 Medical Service 17 In 2016, there were 5 hospitals in Macao, 14 government health establishments. In addition, there were 302 establishments of health care services, 150 western clinics, 57 dental clinics and 193 Chinese medicine clinics, which provide comprehensive medical service to Macao residents and visitors. Based on the statistics in 2016, the average life expectancy at birth of Macao residents for men was 80.3 years old, and for women 86.4 years old. The infant mortality rate was 1.7%. These health indicators are among the best levels in the 15 Sources: Report on the State of the Environment of Macao 2016, 2017 16 Sources: Statistics and Census Service, 2017 17 Sources: Statistics and Census Service and Health Bureau, 2017 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 12 world. 2.2 System, Environmental Policies, Regulatory Framework and Associated Implementation Mechanisms 2.2.1 Political System The People’s Republic of China resumed its sovereignty over Macao on 20 th December of 1999. According to Article 31 of the “Constitution of People’s Republic of China”, Macao Special Administrative Region is established and will retain its capitalistic system and life style for 50 years in light of the “One Country, Two Systems” principle. “The Basic Law of the Macao Special Administrative Region of the People's Republic of China” (Basic Law) is the constitutional document of the Macao SAR. The National People’s Congress authorizes the Macao SAR to exercise a high degree of autonomy and enjoy executive, legislative and independent judicial power, in accordance with the provisions of the “Basic Law”. The exception includes defense, foreign affairs, as well as other matters outside the limits of the autonomy of the Macao SAR as specified by the “Basic Law”. The Chief Executive of the Macao SAR shall be the head of the Macao SAR and shall represent the Region. Based on the "Method for the Selection of the Chief Executive of the Macao Special Administrative Region", the Chief Executive of the Macao SAR shall be selected by election or through consultations held locally and be appointed by the Central People's Government. The Government of the Macao SAR shall be the executive authorities of the Region. The Legislative Council of the Macao SAR shall be the legislature of the Region. The Macao SAR shall be vested with independent judicial power, including that of final adjudication. The Macao Pataca (MOP) is the legal tender in the Macao SAR. The authority to issue Macao currency shall be vested in the Government of the Macao SAR. Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 13 Figure 7 Organization Chart of the Macao SAR 18 18 Sources: The Macao SAR Government website, http://202.175.23.93/web/guest/org-chart, 2018. http://202.175.23.93/web/guest/org-chart Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 14 The principal officials of the Macao SAR Government are Secretaries of Departments, Commissioner against Corruption, Commissioner of Audit, the leading members of the Police and the Customs and Excise. Currently there are five Secretariats in the Macao SAR in the following order, Secretariat for Administration and Justice, Secretariat for Economy and Finance, Secretariat for Security, Secretariat for Social Affairs and Culture, and Secretariat for Transport and Public Works. Subordinate departments of each Secretariat manage administrative affairs within certain governing areas. The executive authorities are established based on the following structure levels and modes: general secretariats, directorates of services, departments and divisions. 2.2.2 Environmental Policies According to the Article 119 of the “Basic Law” stipulates that Macao SAR Government shall carry out the protection of environment in accordance with law. The Macao SAR Government maintains a policy objective to promote the city’s sustainable development, and gradually improve the overall quality of life for Macao citizens. “Law of Environmental Framework” defines guidelines and principles for the development of Macao’s environmental policies. Macao published the “Environmental Protection Planning of Macao (2010-2020)” in 2012, which will be an important guiding document for future environmental works and policies in Macao. Through the vision of “Building a Low Carbon Macao, Creating Green Living Together”, and the short-term, medium-term and long-term implementation of the planning to achieve the planning objectives, the environmental quality in Macao will be improved gradually. In 2016, Macao published the “Five-Year Development Plan (2016-2020) of the Macao Special Administrative Region”, determining strategies and action plans for social, economic and environmental development. Among them, “Strengthening Environmental Protection and Promoting Green Living” is an important element for building a livable city. In 2017, Macao published the “Macao Solid Waste Resources Management Programme (2017-2026)”, defining solid waste policy as well as specific targets and action plans for waste reduction. It is hoped to promote “waste reduction at the source Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 15 and resources recycling” through policies, economic incentives and control, together with the optimization in resource recycling and environmental infrastructure. 2.2.3 Departments involved in the Implementation of the “Convention” or Management of POPs and their Functions and Responsibilities 2.2.3.1 Departments under Secretariat for Administration and Justice 2.2.3.1.1 Legal Affairs Bureau (1) Functions concerning the implementation of the “Convention” or management of POPs: Administrating research and technical support work on overall legal policies and legislation; implementing specific policies such as drafting and translation of legal documents, international and regional affairs as well as promotion of laws. (2) Responsibilities concerning the implementation of the “Convention” or management of POPs: 1) To assist in the development of legal policies; study and provide suggestions for the legal system in the Macao SAR; 2) To implement centralized legal work, assist in legal plans formulation and supervise the implementation; 3) To draft and assist in the draft of legal proposals, regulatory documents or other documents needed to be published in the Official Gazette of the Macao SAR within the jurisdiction of Chief Executive or the Macao SAR Government; 4) To provide legal assistance on international and regional legal affairs, international and regional legal assistance; 5) To promote and provide legal advocacy and promotion work in the Macao SAR. 2.2.3.1.2 Civil and Municipal Affairs Bureau (1) Functions concerning the implementation of the “Convention” or management of POPs: Public health and cleanliness, maintaining and safeguarding the environment as well as resident’s quality of life, and regulating food safety. (2) Responsibilities concerning the implementation of the “Convention” or management of POPs: Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 16 1) To promote environmental health, particularly ensuring the cleaning-up of public places and management of animals; cooperating with entities or public agencies that exercise the power of health authority; 2) To promote people’s quality of life, especially the reconstruction of urban areas, upgrade of related facilities and improvement of environment; 3) To supervise the compliance of requirements applicable to all above items according to the laws and regulations, particularly in the fields such as public health, management of animals, environmental protection and activities and projects subject to administrative permit; 4) To coordinate food safety supervision, management, and its corresponding risk prevention, control and response measures. 2.2.3.2 Departments under Secretariat for Economy and Finance 2.2.3.2.1 Macao Economic Services (1) Functions concerning the implementation of the “Convention” or management of POPs: Responsible for assisting in drafting and implementing economic policies in the economic areas. (2) Responsibilities concerning the implementation of the “Convention” or management of POPs: 1) To cooperate in the planning of economic policies and assist in the development of economic activities, in the ambit of the responsibilities described by the Macao SAR Government; 2) To issue licenses for industrial premises and organize and supervise an industrial registrar and keep it up-to-date; 3) To issue licenses for, and supervise the operation of, petrol companies, shippers, warehouses, duty-free shops and other non-industrial enterprises whose licensing is, by law, the responsibility of Macao Economic Services; 4) To issue licenses for foreign trade-related operations; 5) To manage foreign trade operations under quota; 6) To issue certification of origin documents, pursuant to the provisions of the legislation in force. 2.2.3.2.2 Statistics and Census Service (1) Functions concerning the implementation of the “Convention” or management of POPs: Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 17 Guiding, coordinating, integrating, enforcing and supervising statistical activities of the Macao SAR. (2) Responsibilities concerning the implementation of the “Convention” or management of POPs: 1) To prepare statistics on the quality and quantity of demographic, social, economic and environmental aspects; 2) To study, develop and employ statistic methods for compilation, induction and analysis; 3) To coordinate and centralize relevant official statistics on the Macao SAR to foreign countries and international organizations. 2.2.3.3 Departments under Secretariat for Security 2.2.3.3.1 Macao Customs Service (1) Functions concerning the implementation of the “Convention” or management of POPs: Leading, enforcing and inspecting measures concerning customs policies, providing police service of managing and supervising customs affairs. (2) Responsibilities concerning the implementation of the “Convention” or management of POPs: 1) To prevent, combat and suppress commercial fraud; 2) To prevent and suppress illicit smuggling activities; 3) To monitor and control external trade in order to contribute to the development of external trade activities as well as to safeguard the international reputation of the Macao SAR; 4) To endeavor to carry out international obligations of the Macao SAR within the customs' jurisdiction; 5) To endeavor to protect the safety of lives and properties so as to preserve social order and security of the Macao SAR; 6) The Checkpoint Enforcement Department, in accordance with law, carries out inspection at designated locations on import, export or transit goods, transportation, travelers and carried luggage, and monitors items sent out from or sent in to the Macao SAR. 2.2.3.4 Departments under Secretariat for Social Affairs and Culture 2.2.3.4.1 Health Bureau Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 18 (1) Functions concerning the implementation of the “Convention” or management of POPs: Promoting health and disease prevention and control through coordination with staffs in public and private health organizations and by providing primary and specialized health care services needed in public welfare for Macao residents. (2) Responsibilities concerning the implementation of the “Convention” or management of POPs: 1) To prepare and implement tasks that promote and guarantee public health and prevent diseases; 2) To study health science, conducting training of health care personnel and providing assistance to the training; 3) To supervise and assist entities engaged in health care services; 4) To provide technical assistance to other health units of the Macao SAR. 2.2.3.5 Departments under Secretariat for Transport and Public Works 2.2.3.5.1 Environmental Protection Bureau (1) Functions concerning the implementation of the “Convention” or management of POPs: Assisting in the formulation of environmental policies of the Macao SAR, and ensuring the promotion and enforcement of relevant policies, plans and measures. (2) Responsibilities concerning the implementation of the “Convention” or management of POPs: 1) To assist in the formulation of environmental policies of the Macao SAR; 2) To study and advice the environmental legislative measures; 3) To facilitate and coordinate activities of environmental infrastructures, particularly activities of the Solid Waste Incineration Center, Hazardous Waste Treatment Station, Wastewater Treatment Plant, Sanitary Landfill and Special Waste Landfill as well as the Ecological Zone; 4) To assist in the implementation of environmental conventions, treaties, agreements and protocols and other international regulations applicable in the Macao SAR; 5) To advise, organize and conduct environmental education publicity, training and information activities; Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 19 6) To conduct environmental monitoring and study as well as to promote scientific surveys and technological development in the environmental field. Following the establishment of the Environmental Protection Bureau, relevant infrastructure facilities including the Macao Refuse Incineration Plant, the Macao Special and Hazardous Waste Treatment Plant, the wastewater treatment plants, the construction waste landfill zone, and the Cotai Ecological Zone are under the supervision of the Environmental Infrastructures Management Center of the Environmental Protection Bureau. 2.2.4 International Conventions Concerning the Control of POPs and Applicable to the Macao SAR Currently, international conventions related to POPs and applicable to the Macao SAR includes: 1) “Basel Convention on the Control of Transboundary Movement of Hazardous Wastes and Their Disposal” (1989), applicable to the Macao SAR on 27 th May of 2002 according to the Chief Executive’s Notice No. 32/2002; the amendment to Annex I of the Basel Convention on the Control of Transboundary Movement of Hazardous Wastes and Their Disposal, as well as Annex VIII, Annex IX and amendments thereto, are applicable to the Macao SAR on 17 th January of 2017 according to the Chief Executive’s Notice No. 1/2017. 2) “Stockholm Convention on Persistent Organic Pollutants” (2001), applicable to the Macao SAR on 22 nd November of 2004 according to the Chief Executive’s Notice No.41/2004; its amendments (2009 and 2011) is also applicable to the Macao SAR on 23 rd April of 2014 according to the Chief Executive’s Notice No. 13/2014; The P.R.C accepted the Amendment of listing Hexabromocyclododecane (HBCD) to the Stockholm Convention on Persistent Organic Pollutants on 27 th September 2016, which entered into force in the P.R.C on 26 th December 2016. And according to the Chief Executive’s Notice No. 3/2017, this amendment entered into force in Macao SAR on 6 th February of 2017. 3) “Rotterdam Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade” (1998), applicable to the Macao SAR on 31 st May of 2005 according to the Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 20 Chief Executive’s Notice No.12/2005. 2.2.5 Rules and Regulations Concerning the Control of POPs Rules and regulations concerning the control of POPs include the “Foreign Trade Law”, and the Dispatch of Chief Executive No. 487/2016. According to the Dispatch of Chief Executive No. 330/2012, when importing hexachlorobenze, DDT, alpha-hexachlorocyclohexane (α-HCH), beta-hexochlorocyclohexane (β-HCH), lindane, and other products such as pesticides, rodenticides, fungicides and herbicides, an import permit issued by the Health Bureau is required. In fact, Macao has ceased the import and use of aldrin, chlordane, DDT, dieldrin, endrin, heptachlor, lindane and toxaphene since 1994 in order to protect residents’ health and the environment. Currently, the Macao SAR Government is drafting legislation on the control of import and export of POPs. The Macao SAR Government has also assigned individual codes for listed POPs in the “Nomenclature for the External Trade of Macao / Harmonized System” (6 th Revision), which provides convenience for competent entities to control and collect data on the import and export of such goods. Major sources of unintentional release of POPs of Macao include the Macao Refuse Incineration Plant (MRIP) and Macao Special and Hazardous Waste Treatment Plant (MSHWTP). The new-built facility at the MRIP (finished in 2008) and the MSHWTP were equipped with advanced exhaust emission purification system. The Directive 2000/76/EC is adopted as the standard of limit for treated exhaust emission. 2.2.6 Regulatory Framework and Associated Implementation Mechanisms To cope with the obligations of the “Convention”, relevant functional departments under the Macao SAR Government has been working together to follow up with the tasks related to the “Convention”, and the implementation of the action plans through cross-departmental collaboration. 2.3 Assessment of the POPs Issues in the Macao SAR 19 2.3.1 Assessment of POPs Pesticides in Annex A of the “Convention” 2.3.1.1 Investigation on Current Status of POPs Pesticides 19 In 2014, the Macao SAR submitted the effectiveness evaluation report related to the “Convention” to the P.R.C, which has included the detailed analysis of POPs issues. Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 21 In 2010, a study was conducted to investigate the production, circulation and use of organochlorine insecticides in Macao. The study mainly focused on those organochlorine insecticides controlled in the annex A and annex B of the “Convention”, and their production, circulation, use and waste treatment and disposal in Macao. Insecticides controlled in the original “Convention” including: aldrin, chlordane, dieldrin, endrin, heptachlor, hexachlorobenzene, mirex and toxaphene in Annex A (intentional release) were included in the study. Besides, DDT, as listed in Annex B (intentional release), is discussed separately in Section 2.3.4. According to the results of desktop study and site visits indicated that there was no manufacturer producing POPs insecticides controlled in the original “Convention” in Macao. On the aspects of circulation and use, the purchased quantity of insecticides by relevant enterprises was determined by business volume of the year. The purchased insecticides were for part for sale, part for self-use. No POPs insecticides controlled in the original “Convention” was founded in the study. In addition, inspection on pesticide residue is required in Macao on imported fruits, vegetables, and frozen food items whenever necessary. 2.3.1.2 Import and Export Statistics of POPs Pesticides According to the statistics in the “Nomenclature for the External Trade of Macao / Harmonized System” (5 th Revision), between 2005 and July of 2014, there were no import, export and transit records of the above 8 types of POPs insecticides that are controlled in the original “Convention”. 2.3.2 Assessment of Polychlorinated Biphenyls (PCBs) in Annex A of the “Convention” 2.3.2.1 Investigation on Current Status of PCBs To cope with the obligations of the “Convention”, a basic study was conducted for equipment containing PCBs in 2010 in Macao. The study mainly identified and indicated, in both electrical and non-electrical systems, the capacitors and transformers (both in use and disuse) that may possibly contain PCBs. Information including names of equipment, manufacturers, specifications and models was recorded. The study also identified the disposed quantity and treatment status of PCBs containing equipment of the above organizations, as well as the storage and disposal sites of such PCB containing equipment in Macao. Based on interviews with the person in charge of the investigated organizations, Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 22 site visits and desktop study, there is no use record and status on PCBs containing capacitors and transformers in non-electrical systems in Macao, and the electrical industry in Macao has discontinued the use of PCBs containing capacitors. 2.3.2.2 Import and Export Statistics of PCBs According to the statistics in the “Nomenclature for the External Trade of Macao / Harmonized System” (5 th Revision), there were no import, export or transit records of PCBs between 2005 and July of 2014. 2.3.3 Assessment of Polybrominated Diphenyl Ethers (PBDEs) and Hexabromobiphenyl (HBB) in Annex A of the “Convention” 2.3.3.1 Investigation on Current Status of PBDEs and HBB A relevant study is being conducted between the end of 2014 and 2015 for the inventory of PBDEs, which includes the investigation of PBDEs containing electronic and electrical equipment and its waste, transport sector and other uses. The study also includes the investigation of sites contaminated by PBDEs. 2.3.3.2 Import and Export Statistics of PBDEs and HBB According to the statistics in the “Nomenclature for the External Trade of Macao / Harmonized System” (5 th Revision), there were no import, export or transit records of PBDEs between 2005 and July of 2014. 2.3.4 Assessment with Respect to HBCD in Annex A of the “Convention” 2.3.4.1 Investigation on Current Status of HBCD A relevant study is being conducted between 2017 and 2018, in which air monitoring of POPs including HBCD is conducted. 2.3.4.2 Import and Export Statistics of HBCD 2.3.4.2.1 HBCD (substances) According to relevant survey, there were no registered industrial establishments using HBCD and related substances as raw materials or producing them. According to the statistics in the “Nomenclature for the External Trade of Macao Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 23 / Harmonized System” (6 th Revision), there were no import and export records of HBCD between January and November of 2017. 2.3.4.2.2 Goods that may contain HBCD In the “Nomenclature for the External Trade of Macao / Harmonized System” (6 th Revision, 2017), independent HS codes for HBCD (substances) were established. Independent codes for other polystyrene goods that may contain HBCD are not available yet. Therefore, these goods may not contain HBCD. According to the statistics, there were import records for polystyrene products that may contain HBCD between January and November 2017. Details of the import data: “Nomenclature for the External Trade of Macao / Harmonized System” code Name Import statistics between 1 st January to 30 th November of 2017 (kg) 1 29038930 hexabromocyclododecane (substances) 0 2 39211110* Plates, sheets, film, foil and strip, of expanded polystyrene (EPS) 180,893 3 39211120* Plates, sheets, film, foil and strip, of extruded polystyrene (XPS), not self-adhesive 140 * As independent codes are not available yet, these goods may not contain HBCD. 2.3.5 Assessment with Respect to DDT in Annex B of the “Convention” 2.3.5.1 Investigation on Current Status of DDT A study was conducted to investigate the production, circulation and use of organochlorine insecticides in 2010 in Macao. According to the study results, there was no DDT identified in Macao existing enterprises which were involved in the use or sale of insecticides. In addition, inspection on DDT residue is required for imported fruits, vegetables, and frozen food items whenever necessary. Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 24 2.3.5.2 Import and Export Statistics of DDT According to the statistics in the “Nomenclature for the External Trade of Macao / Harmonized System” (5 th Revision), there were no import, export or transit records of DDT between 2005 and July of 2014. 2.3.6 Assessment of PFOS, its salts and PFOSF in Annex B of the “Convention” 2.3.6.1 Investigation on Current Status of Perfluorooctane Sulfonic Acid (PFOS), its Salts and Perfluorooctane Sulfonly Fluoride (PFOSF) A relevant study is being conducted between end of 2014 and 2015 in Macao in order to investigate the production and use of PFOS and PFOS related chemicals in industry; the products, extinguishers, aviation hydraulic fluids and insecticides containing PFOS and PFOS related chemicals in the consumer market, as well as the status of waste, stockpiles and contaminated sites, etc. 2.3.6.2 Import and Export Statistics of PFOS, its salts and PFOSF According to the statistics in the “Nomenclature for the External Trade of Macao / Harmonized System” (5 th Revision), there were no import, export and transit records of PFOS, its salts and PFOSF between 2005 and July of 2014. 2.3.7 Assessment of Releases of Unintentional Produced Chemicals in Annex C of the “Convention” 2.3.7.1 Annual Emissions and Emission Inventory of Release of Unintentionally Produced Dioxin in Macao The emissions of unintentionally produced polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) (hereinafter collectively referred to as Dioxin) from emission sources were estimated in 2009 and 2012 in Macao. The inventories were compiled based on the emissions. The emissions of unintentionally produced Dioxin decreased from 1,652 mg TEQ/a in 2009 to 341 mg TEQ/a in 2012 in Macao, among which waste incineration accounted for 85.31% of the total emissions. The municipal solid waste incinerated was a majority portion of the waste incinerated. The decrease in emissions of Dioxin was due to a drop of exhaust concentration of Dioxin in the incineration process of municipal solid waste, from 0.190-1.12 ng TEQ/m 3 in 2009 to 0.0176-0.418 ng TEQ/m 3 in 2012. Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 25 Figure 8 Emissions of Unintentionally Produced Dioxin by Source Categories in 2009 Figure 9 Emissions of Unintentionally Produced Dioxin by Source Categories in 2012 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 26 Table 1 Annual Emission Inventory of Unintentionally Produced Dioxin Cat. Source category 2012 2009 Annual emissions (mg TEQ/a) All routes (mg TEQ/a) Annual emissions (mg TEQ/a) All routes (mg TEQ/a) Air Water Land Product Residue Air Water Land Product Residue 1 Waste incineration 145 -- -- -- 146 291 1,197 -- -- -- 388 1,585 1.1 Municipal solid waste incineration 143 -- -- -- 144 287 1,184 -- -- -- 386 1,570 1.2 Hazardous waste incineration 2.33 -- -- -- 1.89 4.22 11.8 -- -- -- 1.60 13.4 1.3 Sewage sludge incineration 0 -- -- -- 0 0 1.23 -- -- -- 0 1.23 2 Ferrous and non-ferrous metal production -- -- -- -- -- -- -- -- -- -- 3 Power generation and heating 7.44 -- -- -- -- 7.44 23.0 -- -- -- -- 23.0 3.1 Heavy oil generators 7.39 -- -- -- -- 7.39 18.8 -- -- -- -- 18.8 3.2 Light diesel generators 0.0477 -- -- -- -- 0.0477 4.16 -- -- -- -- 4.16 3.3 Natural gas generators 0 -- -- -- -- 0 4 Mineral production -- -- -- -- -- -- -- -- -- -- -- 5 Production of chemicals and consumer goods -- -- -- -- -- -- -- -- -- -- 6 Waste treatment -- 35.5 -- -- -- 35.5 -- 34.6 -- -- -- 34.6 6.1 Landfill for fly ash -- 0.0270 -- -- -- 0.0270 -- 0.0270 -- -- -- 0.0270 6.2 WWTP of Macao International Airport 0 -- -- -- 0 -- -- -- -- -- 6.3 WWTP in Taipa -- 0.632 -- -- -- 0.632 -- 0.538 -- -- -- 0.538 6.4 WWTP in Coloane -- 2.92 -- -- -- 2.92 -- 1.58 -- -- -- 1.58 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 27 Cat. Source category 2012 2009 Annual emissions (mg TEQ/a) All routes (mg TEQ/a) Annual emissions (mg TEQ/a) All routes (mg TEQ/a) Air Water Land Product Residue Air Water Land Product Residue 6.5 WWTP in Macao Peninsula -- 31.9 -- -- -- 31.9 -- 30.5 -- -- -- 30.5 6.6 WWTP in Transborder Industrial Zone 0.0450 -- -- -- 0.0450 -- 2.01 -- -- -- 2.01 7 Open burning process -- -- -- -- -- -- -- -- -- -- -- 8 Transport 7.13 -- -- -- -- 7.13 9.43 -- -- -- -- 9.43 8.1 4-stroke engines (cars) 0.0537 -- -- -- -- 0.0537 -- -- -- -- -- 8.2 4-stroke engines (motorcycles) 0.996 -- -- -- -- 0.996 0.797 -- -- -- -- 0.797 8.3 2-stroke engines 1.96 -- -- -- -- 1.96 5.56 -- -- -- -- 5.56 8.4 Diesel engines 4.12 -- -- -- -- 4.12 3.07 -- -- -- -- 3.07 9 Miscellaneous 0.0574 -- -- -- -- 0.0574 0.104 -- -- -- -- 0.104 9.1 Dry cleaning 0 -- -- -- -- 0 -- -- -- -- -- 9.2 Tobacco smoking 0.0574 -- -- -- -- 0.0574 0.104 -- -- -- -- 0.104 Total 160 35.5 0 0 146 341 1,230 34.6 0 0 388 1,652 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 28 2.3.7.2 Annual Emissions and Emission Inventory of Release of Unintentionally Produced PCBs in Macao The emissions of unintentionally produced PCBs from emission sources were estimated in 2009 and 2012 in Macao and the inventories were compiled based on the emissions. The annual emissions of unintentionally produced dioxin-like PCBs in Macao decreased from 202 mg WHO-TEQ/a in 2009 to 85.1 mg WHO-TEQ/a in 2012, while the emission of indicator PCBs decreased from 89,610 mg in 2009 to 77,506 mg in 2012. The major reason for decrease was due to the drop of energy consumption in power generation. Figure 10 Emissions of Unintentionally Produced Dioxin-like PCBs by Source Categories in 2009 Figure 11 Emissions of Unintentionally Produced Indicator PCBs by Source Categories in 2009 Figure 12 Emissions of Unintentionally Produced Dioxin-like PCBs by Source Categories in 2012 Figure 13 Emissions of Unintentionally Produced Indicator PCBs by Source Categories in 2012 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 29 Table 2 Annual Emission Inventory of Unintentionally Produced PCBs in 2009 Cat. Source category Annual emissions of dioxin-like PCBs (mg WHO-TEQ/a) All routes(mg WHO-TE Q/a) Annual emissions of indicator PCBs (mg/a) All routes (mg/a) Air Water Land Products Residue Air Water Land Products Residue 1 Waste incineration 66.1 -- -- -- 13.2 79.3 2,210 -- -- -- 26,590 28,800 1.1 Municipal solid waste incineration 65.5 -- -- -- 13.2 78.7 2,160 -- -- -- 26,510 28,670 1.2 Hazardous waste incineration 0.57 -- -- -- 0.0035 0.574 48.4 -- -- -- 79.5 127.9 1.3 Sewage sludge incineration 0.000267 -- -- -- -- 0.000267 2.03 -- -- -- -- 2.03 2 Power generation and heating 122.5 -- -- -- -- 122.5 12,910 -- -- -- -- 12,910 2.1 Heavy oil generators 84.7 -- -- -- -- 84.7 8,960 -- -- -- -- 8,960 2.2 Light diesel / natural gas generators 37.8 -- -- -- -- 37.8 3,950 -- -- -- -- 3,950 3 Waste treatment -- 0.0796 -- -- -- 0.0796 -- 47,900 -- -- -- 47,900 3.1 Landfill for fly ash -- 0.0782 -- -- -- 0.0782 -- 46,000 -- -- -- 46,000 3.2 WWTP in Taipa -- 0.0011 -- -- -- 0.0011 -- 1,110 -- -- -- 1,110 3.3 WWTP in Coloane -- 0.0003 -- -- -- 0.0003 -- 820 -- -- -- 820 Total 188.6 0.0796 -- -- 13.2 202 15,120 47,900 -- -- 26,590 89,610 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 30 Table 3 Annual Emission Inventory of Unintentionally Produced PCBs in 2012 Cat. Source category Annual emissions of dioxin-like PCBs (mg WHO-TEQ/a) All routes(mg WHO-TEQ/a) Annual emissions of indicator PCBs (mg/a) All routes (mg/a) Air Water Land Products Residue Air Water Land Products Residue 1 Waste incineration 45.1 -- -- -- 6.51 51.6 1,624 -- -- -- 21,444 23,068 1.1 Municipal solid waste incineration 44.4 -- -- -- 6.51 50.9 1,567 -- -- -- 21,350 22,917 1.2 Hazardous waste incineration 0.672 -- -- -- 0.00413 0.676 57.1 -- -- -- 93.8 150.9 1.3 Sewage sludge incineration 0 -- -- -- -- 0 0 -- -- -- -- 0 2 Power generation and heating 33.4 -- -- -- -- 33.4 3,530 -- -- -- -- 3,530 2.1 Heavy oil generators 33.3 -- -- -- -- 33.3 3,520 -- -- -- -- 3,520 2.2 Light diesel / natural gas generators 0.0764 -- -- -- -- 0.0764 7.98 -- -- -- -- 7.98 3 Waste treatment -- 0.0953 -- -- -- 0.0953 -- 50,908 -- -- -- 50,908 3.1 WWTP of Macao International Airport 0 -- -- -- 0 -- 0 -- -- -- 0 3.2 WWTP in Taipa -- 0.00131 -- -- -- 0.00131 -- 1,302 -- -- -- 1,302 3.3 WWTP in Coloane -- 0.000585 -- -- -- 0.000585 -- 1,504 -- -- -- 1,504 3.4 WWTP in Macao Peninsula -- 0.0817 -- -- -- 0.0817 -- 48,092 -- -- -- 48,092 3.5 WWTP of Transborder Industrial Zone 0.0118 -- -- -- 0.0117 -- 9.58 -- -- -- 9.58 Total 78.5 0.0953 0 0 6.51 85.1 5,154 50,908 0 0 21,444 77,506 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 31 2.3.8 Status of Stockpiles and Contaminated Sites A detailed investigation and assessment on sites contaminated by Dioxin and PCBs was conducted in Macao in 2012. Major sites in Macao that are possibly contaminated by Dioxin and PCBs include the Macao Refuse Incineration Plant, WWTPs, the landfill for fly ash, cement manufacturing zone and the temporary fly ash storage site. Through initial investigation of the above sites and surrounding soil/sediment, the soil samples in such contaminated areas was within an acceptable range of mid to low levels of Dioxin toxic equivalent when comparing with standards in other countries or other research results. The levels were lower than that of the most stringent standards in Sweden and New Zealand, which would not cause adverse effects to surrounding human activities. PCBs were also recorded at mid to low levels. 2.3.9 Requirements for Exemptions Currently, the P.R.C has registered specific exemptions for the following 4 types of POPs, and the relevant specific exemptions are applicable to the Macao SAR. Table 4 Uses with Specific Exemptions Chemical Purposes on specific exemptions Lindane Use on human health pharmaceutical for control of head lice and scabies as second line treatment. Technical endosulfan and its related isomers Production and use on prevention cotton bollworm and tobacco budworm PFOS, its salts and PFOSF Production and use on photo masks in the semiconductor and liquid crystal display (LCD) industries, metal plating (hard metal plating), metal plating (decorative plating)， electric and electronic parts for some colour printers and color copy machines, insecticides for control of red imported fire ants and termites, and chemically driven oil. Table 5 Acceptable purposes Chemical Acceptable purposes PFOS, its salts and PFOSF Production and use on photo-imaging, photo-resist and anti-reflective coatings for semi-conductors, etching agent for compound semi-conductors and ceramic filters, aviation hydraulic fluids, metal plating (hard metal plating) only in closed-loop systems, certain medical Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 32 devices (such as ethylene tetrafluoroethylene copolymer (ETFE) layers and radio-opaque ETFE production, in-vitro diagnostic medical devices, and CCD color filters) and fire-fighting foam. 2.3.10 Existing Programmes for Monitoring Releases and Environmental and Human Health Impacts 2.3.10.1 Overview To reflect the baseline situation of POPs in Macao and execute tasks stated in different stages of the implementation plan, monitoring works, which included the 12 POPs controlled in the original “Convention” (DDT, aldrin, chlordane, dieldrin, endrin, heptachlor, hexochlorobenzene (HCB), mirex, toxaphene, PCDDs, PCDFs and PCBs), and the 11 POPs listed in the three amendments (α-HCH, β-HCH, lindane, chlordecone, pentachlorobenzene (PeCB), technical endosulfan and its related isomers, tetrabromodiphenyl ether and pentabromodiphenyl ether, hexabromodiphenyl ether and heptabromodiphenyl ether, HBB, hexabromocyclododecane (HBCD), and PFOS, its salts and PFOSF, were conducted in 2010 and 2012 in Macao at various environmental media including ambient air, sea water, sediment, soil and aquatic biota for the sake to have a preliminary understanding of the levels of POPs and their distribution. In the meantime, the “Study of POPs’ content in human breast milk” was started in March of 2013 in Macao. 2.3.10.2 Monitoring and its Results Related to Environmental Impact The selection of sampling points for various environmental media (ambient air, sea water, sediment and soil) was based on consideration of different functional purposes and uniformity of sampling points. Two periods of monitoring were carried out respectively in 2010 and 2012-2013. It should be to point out that currently there is lack of specific environmental standards for most POPs, so the monitoring data will serve as comparison for future local monitoring and support for follow-up studies. 2.3.10.2.1 Ambient Air In the aspect of ambient air, sampling was carried out twice during summer and winter, in both 2010 and 2012-2013 in Macao. Sampling points included residential areas, surrounding areas of pollution sources and background. Monitoring results are briefed below: Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 33  In ambient air, DDT, HCH, chlordane and endosulfan were the major pollutants among other POPs pesticides; this was obviously related to these pesticides or pesticides made from such raw materials still existed in the surrounding environment. For some banned or restricted pesticides, or pesticides that were not produced or use (e.g. toxaphene, aldrin, dieldrin, endrin, heptachlor, HCB, mirex, chlordecone, PeCB), their environmental concentrations were lower than 100 pg/m 3 or below the detection limit.  PCBs concentration remained relatively stable in ambient air for the two periods of monitoring.  Compared with 2010, the total toxic equivalent concentration of PCDFs and PCDDs increased slightly in 2012-2013.  Since the ban of PBDEs by the “Convention” in 2009, its concentration in ambient air showed a decreasing trend; according to sample analysis in 2012-2013, along with the brominated flame retardants, HBCD had a higher concentration, while HBB had a lower concentration.  Compared with 2010, the concentration of perfluorinated compounds (short as PFCs, sum of PFOS compounds and perfluoro-octanoic acid (PFOA)) increased slightly in 2012 to 2013. 2.3.10.2.2 Marine Water and Sediment Regarding marine water and sediment, 14 sampling points were chosen, in which the sampling was carried out twice during summer and winter of 2010 in Macao. In 2012-2013, the sampling work was optimized and a more representative selection of 8 sampling points was selected. Monitoring results are briefed below: Monitoring results related to marine water:  Similar to that in ambient air pollution, for marine water samples, DDT, HCH, chlordane and endosulfan were the major pollutants among other POPs pesticides; concentrations of other pesticides were lower than 1.0 ng/L or below the detection limit.  Although there was an increasing trend of PCBs in marine water from 2010 to 2012-2013, its concentration was still at a very low level, lower than the relevant PCBs standard stated in the Clean Water Act of USEPA and the. Environmental Quality Standards for Surface Water of the P.R.C. The concentration of Dioxin reflected a decreasing trend.  For the marine samples of brominated flame retardants in 2012-2013, HBCD had a higher concentration. Concentrations of tetrabromodiphenyl Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 34 ether and pentabromodiphenyl ether, and hexabromodiphenyl ether and heptabromodiphenyl ether remained rather unchanged compared with 2010, lower than the requirement of relevant environmental quality guidelines in Canada. HBB had a very low concentration.  Compared with 2010, the concentration of PFCs increased slightly in 2012-2013. Monitoring results related to sediment:  For sediment samples, within POPs pesticides, concentrations of DDT and HCH were between 10-20 ng/g, while concentrations of endosulfan, mirex, HCB, PeCB and chlordane were between 1.0-5.0 ng/g. Other pesticides had concentrations lower than 1.0 ng/g or below the detection limit.  PCBs in e sediment reflected a similar pattern as in marine water, there was an increasing trend of PCBs in sediment from 2010 to 2012-2013 but its concentration was far lower than the standard limits of the first category specified in the P.R.C Marine Sediment Quality (GB18668-2002) for marine sediment; the total toxic equivalent concentration of PCDFs and PCDDs decreased slightly in 2012-2013.  Within the brominated flame retardants sediment samples, HBCD had a higher concentration, which was 5.9 times higher of PBDEs (sum of tetrabromodiphenyl ether and pentabromodiphenyl ether, and hexabromodiphenyl ether and heptabromodiphenyl ether), and 3.4 times higher of HBB.  Concentration of PFCs remained relatively stable. 2.3.10.2.3 Soil In the aspect of soil, 17 soil sampling points including residential areas, industrial areas, reclamation areas, background, pollution sources and their surrounding areas, etc. were selected in 2010 in Macao. The samples collected were all surface soil samples. Sampling works were optimized in 2012 and a more representative combination of 7 sampling points was selected. Monitoring results are briefed below:  For soil samples, DDT, HCH and mirex were the major pollutants among other POPs pesticides; concentrations of other pesticides were lower than 1.0 ng/g or below the detection limit.  As in marine water, there was an increasing trend of PCBs in soil from 2010 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 35 to 2012-2013 but its concentration was lower than the requirements in the P.R.C Environmental Quality Standards for Soils (revised version for consultation); the total toxic equivalent concentration of PCDFs and PCDDs showed a decreasing trend.  Within the brominated flame retardants soil samples, HBCD had a higher concentration than others.  Concentration of PFCs remained relatively stable. 2.3.10.2.4 Aquatic Biota Regarding the aquatic biota sample collection, it was carried out twice between 2012 and 2013. The sampling points selected were as consistent as possible with those of marine water and marine sediment. Monitoring results are briefed below:  For aquatic biota samples, DDT, HCH, endrin and endosulfan were the major pollutants among POPs pesticides; lipid contents of other POPs pesticides were relatively lower.  The high concentration levels of PCBs, PCDFs and PCDDs in aquatic biota indicated a consistency in strong bioaccumulation of them in organisms, due to their lipophilicity and low degradability.  Within the brominated flame retardants aquatic biota samples, tetrabromodiphenyl ether and pentabromodiphenyl ether had a similar concentration level to HBCD, while hexabromodiphenyl ether and heptabromodiphenyl ether and HBB had a relatively lower concentration. 2.3.10.3 Monitoring and its Results Related to Human Health Impact According to the results of the “Study of POPs content in human breast milk”, conducted by the Health Bureau of Macao, among the 26 organochlorine POPs pesticides tested, the following POPs were detected, while the rest were below the detection limit: beta-HCH, cis-heptachlor epoxide, cis-chlordane, cis-nonachlor, trans-nonachlor, endosulfan sulfate, o,p'-DDE, p,p'-DDE, p,p'-DDD, o,p'-DDT, p,p'-DDT, PeCB and HBB. The total amount of PCBs and PBDEs indicators in mothers’ breast milk in Macao were 14.9 ng/g lipid weight and 3.89 ng/g lipid weight respectively. Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 36 The total detected amounts of Dioxin and dioxin-like PCBs were:  TEQPCDD/Fs-TEF2005：5.1 pg TEQ/g lipid  TEQDLPCBs-TEF2005：2.7 pg TEQ/g lipid  Total TEQTEF2005：7.8 pg TEQ/g lipid Table 6 Amounts of POPs Pesticides in Mothers’ Breast Milk in Macao Chemical Amount (ng/g lipid weight) Chemical Amount (ng/g lipid weight) alpha-HCH ND dieldrin ND beta-HCH 116.1 endrin ND gamma-HCH ND alpha-endosulfan ND delta-HCH ND beta-endosulfan ND Heptachlor ND endosulfan sulphate 0.4 trans-heptachlor epoxide ND o,p'-DDE 0.8 cis-heptachlor epoxide 2.6 p,p'-DDE 394.5 oxychlordane ND o,p'-DDD ND cis-chlordane 0.1 p,p'-DDD 1.9 trans-chlordane ND o,p'-DDT 2.3 cis-nonachlor 0.6 p,p'-DDT 24.3 Trans-nonachlor 4.3 PeCB 0.1 aldrin ND HBB 18.4 Note: ND means not detected. Table 7 Amounts of Indicator PCBs in Mothers’ Breast Milk in Macao Chemical Amount (ng/g lipid weight) PCB28 0.8 PCB52 0.1 PCB101 0.2 PCB138 4.0 PCB153 7.0 PCB180 2.8 Total 14.9 Table 8 Amounts of PBDEs in Mothers’ Breast Milk in Macao Chemical Amount (ng/g lipid weight) BDE28 0.33 BDE47 1.30 BDE99 0.12 BDE100 0.29 BDE153 1.59 BDE154 0.08 BDE183 0.20 Total 3.89 Table 9 Amounts of Dioxin and Dioxin-like PCBs in Mothers’ Breast Milk in Macao PCDD/Fs pg /g lipid dl-PCBs pg/g lipid 2,3,7,8-TCDD 0.71 PCB-77 2.9 1,2,3,7,8-PeCDD 1.85 PCB-126 20.9 1,2,3,4,7,8-HxCDD 1.02 PCB-169 13.5 1,2,3,6,7,8-HxCDD 2.97 PCB-81 4.5 1,2,3,7,8,9-HxCDD 0.78 PCB-105 738.9 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 37 1,2,3,4,6,7,8-HpCDD 7.12 PCB-114 130.6 OCDD 61.55 PCB-118 2109.0 2,3,7,8-TCDF 0.68 PCB-123 44.9 1,2,3,7,8-PeCDF 0.63 PCB-156 686.4 2,3,4,7,8-PeCDF 4.61 PCB-157 157.3 1,2,3,4,7,8-HxCDF 1.81 PCB-167 231.2 1,2,3,6,7,8-HxCDF 1.73 PCB-189 71.3 2,3,4,6,7,8-HxCDF 0.90 1,2,3,7,8,9-HxCDF 0.10 1,2,3,4,6,7,8-HpCDF 1.47 TEQPCDD/Fs-TEF2005 5.1 pg TEQ/g lipid 1,2,3,4,7,8,9-HpCDF 0.09 TEQDLPCBs-TEF2005 2.7 pg TEQ/g lipid OCDF 0.54 Total TEQTEF2005 7.8 pg TEQ/g lipid 2.3.11 Current Status among Target Groups To raise relevant groups’ understanding to the “Convention” and POPs, various forms of publicity and education activities are continuously launched. This included the organization of the roving exhibition “What should you know about the environmental conventions?” in 2006; publishing the book “Environmental Treaties and Macao” in 2007, which introduces the “Convention”, the relationship between POPs and human beings and its hazards to the environment, etc.; organizing youth and children to participate in the event of “National Youth Environmental Art Competition on POPs” in 2011, which promoted scientific popular knowledge of POPs; and in 2012, making publicity boards to deepen groups, like women’s understanding about POPs. 2.3.12 Mechanism on Reporting and Information Exchange with Other Parties to the “Convention” In past few years, the Macao SAR had dispatch officials to attend annually the “Technical Coordination Group Meeting on the implementation of the Stockholm Convention in China” to understand the national implementation progress of the “Convention” and latest experience on implementing action plans of various parties. At the same time, the Macao SAR, according to the relevant obligations of the “Convention” and our national requirement and arrangement, submits reports on the implementation of the “Convention” as well as the effectiveness evaluation reports. 2.3.13 Relevant Activities of Non-governmental Stakeholders No information is available on relevant activities of non-governmental stakeholders. Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 38 2.3.14 Linkage to POPs-related Projects to International Programmes and Projects No relevant information is available regarding to the works with the international community to start programmes related to the “Convention”, or linkage to international projects. 2.3.15 Identification of Impacted Populations or Environments No relevant information is available regarding to the identification of impacted populations or environments. 2.3.16 System for the Assessment and Listing of New Chemicals A study is being conducted between the end of 2014 to 2015 to integrate the existing results of POPs relevant investigation and studies, analyze existing systems about assessment, listing and management of new chemicals and provide technical support suggestions in Macao. 2.3.17 System for the Assessment and Regulation of Chemicals Already in the Market According to the Dispatch of Chief Executive No. 487/2016, the substances listed in the Import Table B of Annex 2 under Clause 2 of the dispatch, are subject to the application of an import permit prior to entering Macao. Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 39 3 Strategy and Action Plans for the Implementation Plan of the Macao SAR 3.1 Policy Statement To fulfill the obligations of the Article 7 of the “Convention”, according to our national requirement, the Macao SAR carries out and completes POPs study on an ongoing basis, and submits reports on the implementation of the “Convention” as well as the effectiveness evaluation reports. On the basis of executing the “Implementation Plan of the Macao Special Administrative Region for the Stockholm Convention on Persistent Organic Pollutants” (2006-2015) in “The People’s Republic of China National Implementation Plan for the Stockholm Convention on Persistent Organic Pollutants”, the Macao SAR will further work on the implementation of the “Convention” and update its implementation plan to reflect the inclusion of additional POPs. 3.2 Strategy for Implementation According to the “Implementation Plan of the Macao Special Administrative Region for the Stockholm Convention on Persistent Organic Pollutants” (2006-2015) in “The People’s Republic of China National Implementation Plan for the Stockholm Convention on Persistent Organic Pollutants” and based on Macao’s implementation progress (2006-2015), the Macao SAR, coping with the latest requirements of the “Convention”, proposes its subsequent actions plans (2016-2025) for the implementation of the “Convention” (for details please refer to Section 3.3): (I) Short-term action plans (2016-2020):  To complete investigation about the industries involved in the intentional production and use of the new POPs and chemicals proposed for listing under the “Convention” as well as to complete the investigation and emission inventory about the industries involved in unintentional production of such POPs;  To gradually improve the management system of POPs or related goods, with a purpose to help eliminate and restrict the production, use, import and export of intentional production and use of new POPs;  To update the dynamic emission inventories for Dioxin and PCBs;  To strengthen the control of unintentional emissions from incineration Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 40 facilities;  To improve the dynamic database for POPs stockpiles and POPs containing waste;  To identify POPs contaminated sites and manage them in an environmentally sound manner;  Tasks including regular exchange mechanisms, cooperation on implementation, as well as publicity and education on the implementation of the “Convention”;  To conduct regular environmental monitoring and submit regularly effectiveness evaluation reports as well as reports on the implementation of the “Convention”. (II) Medium- and long-term action plans (2021-2025):  To study on the establishment and continuous improvement of long-term mechanism for the control of unintentionally produced POPs;  To improve the environmentally sound management system and managerial capacity for POPs waste;  To identify POPs contaminated sites and manage them in an environmentally sound manner;  To submit regularly reports on POPs effectiveness evaluation reports and reports on the implementation of the “Convention” as required;  Tasks including regular exchange mechanism and cooperation on implementation as well as publicity and education on the implementation of the “Convention”;  To conduct regular environmental monitoring for POPs and effectiveness evaluation on the implementation of the “Convention". 3.3 Activities, Strategies and Action Plans 3.3.1 Activity: Institutional and Regulatory Strengthening Measures To strengthen the regulatory of POPs through formulating and improvement of management laws and regulations related to POPs, establishment of specific industry management standards for POPs, revision or formulating of the relevant existing management lists of POPs, etc. Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 41 Table 10 Action Plans for Institutional and Regulatory Strengthening Measures No. Action Details Relevant implementing bodies Period of implementation 1 To continuously promote the development or revision of laws and regulations related to POPs. To continuously promote to introduce POPs control into the existing law and regulation system, thus providing a legal basis for the control of POPs. To propose legislative plans so as to improve the management system of POPs or related goods. Macao Customs Service, Legal Affairs Bureau, Civil and Municipal Affairs Bureau, Macao Economic Services, Statistics and Census Service, Health Bureau, Environmental Protection Bureau and other relevant agencies 2016-2025 2 To strengthen the management for reduction and control for the unintentional release of POPs. To combine previous investigation results and study to study and formulate the reduction and control management measures for the unintentional release of POPs during waste incineration processes. To study and formulate the pollutants emission standards (e.g. Dioxin) for waste incineration facilities, thus strengthening regulatory on emissions. Environmental Protection Bureau and other relevant agencies 2016-2025 3 To gradually implement administrative supervision on the import of POPs pesticides and the food containing related substances. By the means such as administrative supervision to continuously improve regulatory of the import of POPs pesticides, and to carry out continuously inspection of POPs pesticide residue on imported fruits, vegetables, and frozen food items. Macao Customs Service, Civil and Municipal Affairs Bureau, Health Bureau, Environmental Protection Bureau and other relevant agencies 4 To gradually supplement POPs relevant content while study and formulate the hazardous waste list or inventory of Macao. To cope with the requirement and development on the implementation of the “Convention”, will increase POPs relevant content (e.g. PCBs) in the study on the development of Macao hazardous waste list or inventory in the future, so as to gradually strengthen the control of POPs. Environmental Protection Bureau and other relevant agencies 2016-2020 3.3.2 Activity: Measures to Reduce or Eliminate Releases from Intentional Production and Use Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 42 Table 11 Action Plans for Measures to Reduce or Eliminate Releases from Intentional Production and Use No. Action Details Relevant implementing bodies Period of implementation 5 To investigate the production and use of the new controlled POPs, and their produce industries. To investigate the production and use of the new controlled POPs, and their produce industries, so as to collect information of industry types, production volume, usage volume, produce and release. Macao Customs Service, Macao Economic Services, Environmental Protection Bureau and other relevant agencies 2016-2020 3.3.3 Activity: Production, Import and Export, Use, Stockpiles, and Wastes of Annex A POPs Pesticides Currently no manufacturers in Macao are producing insecticides controlled in the original “Convention”. The purchased quantity of insecticides by enterprises is based on the demand of annual business volume, and such insecticides are either for self-use or for sale. Related study did not find insecticides controlled in the original “Convention”. Meanwhile, related POPs pesticides, listed in the Import Table B of Annex 2 under Clause 2 of the Dispatch of Chief Executive No. 487/2016, are already subject to apply an import permit prior to entering Macao. Therefore, the management of the above substances will be improved based on actual circumstances in the future. 3.3.4 Activity: Production, Import and Export, Use, Identification, Labeling, Removal, Storage, and Disposal of PCBs and Equipment Containing PCBs Currently no premises are producing or using PCBs and PCBs containing equipment in Macao, and according to the statistics in the “Nomenclature for the External Trade of Macao / Harmonized System” (5 th Revision), there were no import and export records of PCBs between 2005 and July of 2014; therefore, the management of PCBs or PCBs containing equipment will be improved based on the import and export circumstances of PCBs in the future. Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 43 3.3.5 Activity: Production, Import and Export, Use, Stockpiles, and Wastes of Hexabromodiphenyl Ether and Heptabromodiphenyl Ether, Tetrabromodiphenyl Ether and Pentabromodiphenyl Ether Currently no premises are producing or using PBDEs in Macao, and according to the statistics in the “Nomenclature for the External Trade of Macao / Harmonized System” (5 th Revision), there were no import and export records of PBDEs between 2005 and July of 2014; therefore, the management of PBDEs will be improved based on the import and export circumstances of PBDEs in the future. 3.3.6 Activity: Production, Import and Export, Use, Stockpiles, and Wastes of DDT Currently no premises are producing or using DDT in Macao, and existing marketing enterprises that use pesticides are not involved in selling DDT. According to the statistics in the “Nomenclature for the External Trade of Macao / Harmonized System” (5 th Revision), there were no import and export records of DDT between 2005 and July of 2014. Meanwhile, DDT is listed in the Import Table B of Annex 2 under Clause 2 of the Dispatch of Chief Executive No. 487/2016, and is already subject to apply for an import permit prior to entering Macao. Therefore, the management of DDT will be improved based on the import and export circumstances of DDT in the future. 3.3.7 Activity: Production, Import and Export, Use, Stockpiles, and Waste of PFOS, its salts and PFOSF As no sites are producing or using PFOS, its salts and PFOSF in Macao, and according to the statistics in the “Nomenclature for the External Trade of Macao / Harmonized System” (5 th Revision), there were no import and export records of PFOS, its salts and PFOSF between 2005 and July of 2014; therefore, the management of PFOS, its salts and PFOSF will be gradually improved based on the import and export circumstances of PFOS, its salts and PFOSF in the future. 3.3.8 Activity: Production, Import and Export, Use, Stockpiles, and Waste of HBCD No sites are producing or using HBCD in Macao. According to the statistics in the “Nomenclature for the External Trade of Macao / Harmonized System” (6 th Revision), there were no import and export records of Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 44 HBCD (substances) between January and November of 2017. However, there were import records for polystyrene goods that may contain HBCD. As independent codes for polystyrene goods that may contain HBCD are not available yet, these goods may not contain HBCD. Therefore, studies and control of related polystyrene goods that may contain HBCD will be gradually improved based on the import and export circumstances in the future. 3.3.9 Activity: Register for Specific Exemptions and the Continuing Need for Exemptions Table 12 Action Plans for Register for Specific Exemptions and the Continuing Need for Exemptions No. Action Details Relevant implementing bodies Period of implementation 6 To analyze relevant needs for exemptions. To carry out study and analyze the needs for exemptions based on the existing investigation results production and use of POPs. Environmental Protection Bureau and other relevant agencies 2016-2025 3.3.10 Action Plan: Measures to Reduce Releases from Unintentional Sources The third phase expansion project of the Macao Refuse Incineration Plant is being planned. The expansion of incineration facilities will make reference to the requirements of the EU directives. Table 13 Action Plans for Measures to Reduce Releases from Unintentional Sources No. Action Details Relevant implementing bodies Period of implementation 7 To establish the dynamic emission inventories for Dioxin and PCBs. To establish the dynamic database system for Dioxin and PCBs, for storage and analysis the changes of the emission inventories. Environmental Protection Bureau and other relevant agencies 2016-2020 8 To strengthen the control of unintentional emissions from incineration facilities To carry out feasibility study on the overall expansion and consecutive optimization of incineration facilities, in order to implement best practicable technology/best practices for production for achieving better Dioxin emission levels through relevant facility improvement works. Environmental Protection Bureau and other relevant agencies 2016-2020 Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 45 9 To study on the improvement of policy mechanism for reduction and control of unintentionally produced POPs To carry out integrated assessment, analysis and propose reducing and controlling directions for unintentionally produced POPs at waste incineration facilities, based on the existing management of such facilities Macao Economic Services, Environmental Protection Bureau and other relevant agencies 2021-2025 3.3.11 Activity: Measures to Reduce Releases from Stockpiles and Wastes Table 14 Action Plans for Measures to Reduce Releases from Stockpiles and Wastes No. Action Details Relevant implementing bodies Period of implementation 10 To improve the management system and managerial capacity for the environmentally sound management of waste containing POPs. To continuously improve the related management measures for the import and export of POPs waste; establish or refer to technical specification system on managing and disposing POPs waste in an environmentally sound manner; conduct promotion and trainings on management awareness and techniques to personnel related to the management of POPs waste; and strengthen the supervision capability for the environmentally sound management of POPs waste. Environmental Protection Bureau and other relevant agencies 2021-2025 11 To establish or increase the handling capability for the environmentally sound treatment of waste containing POPs. To gradually introduce advance technology for the environmentally sound treatment of POPs waste; ad organize demonstration activities for the environmentally sound treatment of waste (especially electrical and electronic waste), which includes centralized recycling for waste containing POPs such as electrical and electronic waste in environmentally sound manner, thus reducing POPs related environmental pollution caused by improper treatment of such waste. Environmental Protection Bureau and other relevant agencies 2016-2020 3.3.12 Strategy: Identification of Stockpiles, Articles in Use and Wastes Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 46 Table 15 Action Plans for Identification of Stockpiles, Articles in Use and Wastes No. Action Details Relevant implementing bodies Period of implementation 12 To improve the dynamic database system for POPs stockpiles and waste containing POPs. To carry out investigations on POPs-related industries; improve the database of POPs stockpiles and waste and contaminated sites under the information system framework, thus achieving the information updates of POPs stockpiles and waste containing POPs. Macao Customs Service, Civil and Municipal Affairs Bureau, Macao Economic Services, Statistics and Census Service, Health Bureau, Environmental Protection Bureau and other relevant agencies. 2016-2020 3.3.13 Activity: Manage Stockpiles and Appropriate Measures for Handling and Disposal of Articles in Use To develop further measures on managing stockpiles, handling and disposal of articles in use according to investigation results and needs as in Section 3.3.11. 3.3.14 Strategy: Identification of Contaminated Sites and Remediation in an Environmentally Sound Manner Table 16 Action Plans for Identification of Contaminated Sites and Remediation in an Environmentally Sound Manner No. Action Details Relevant implementing bodies Period of implementation 13 To identify and manage POPs contaminated sites in an environmenta lly sound manner. To identify POPs contaminated sites with reference to identification standards and ecological risk assessment standards, and progressively carry out study on environmental measures and remediation technologies for POPs contaminated sites, thus strengthening the environmentally sound management of such sites. Environmental Protection Bureau and other relevant agencies 2016-2025 3.3.15 Activity: Facilitating or Undertaking Information Exchange and Stakeholder Involvement Table 17 Action Plans for Periodic Information Exchange and Cooperation on the Implementation of the “Convention” No. Action Details Relevant implementing bodies Period of implementation Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 47 14 To periodically exchange and cooperate on the implementati on of the “Convention” To facilitate the exchange between relevant agencies having close contact with the Macao SAR in the region regarding to the implementation of the “Convention”. Relevant agencies involved in the implementation of the “Convention” Ongoing basis 3.3.16 Activity: Public Awareness, Information and Education Table 18 Action Plans for Raising Public Awareness, Information and Education No. Action Details Relevant implementing bodies Period of implementation 15 To enhance public awareness, information and education. To strengthen public awareness on POPs and POPs control laws and regulations, through various forms of publicity and education activities. Legal Affairs Bureau, Health Bureau, Environmental Protection Bureau and other relevant agencies. Ongoing basis 3.3.17 Activity: Effectiveness Evaluation Table 19 Action Plans for Effectiveness Evaluation Submission No. Action Details Relevant implementing bodies Period of implementation 16 To conduct effectiveness evaluation on the implementati on of the “Convention ” To provide detailed descriptions of measures taken for the implementation of the “Convention” according to the information management mechanism on implementation, and assess the effectiveness of such measures; to carry out effectiveness evaluation every 4 years as required; to establish a reporting mechanism and to strengthen relevant capacity building. Relevant agencies involved in the implementation of the “Convention” To conduct effectiveness evaluation every 4 years according to requirements listed in the “Convention” 3.3.18 Activity: Reporting Table 20 Action Plans for Report Submission No. Action Details Relevant implementing bodies Period of implementation Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 48 17 To submit reports on the implementati on of the “Convention ” To submit reports on the implementation of the “Convention”, coping with our national implementation requirements. Relevant agencies involved in the implementation of the “Convention” To submit reports on the implementation of the “Convention”, coping with our national implementation requirements. 3.3.19 Activity: Research, Development and Monitoring Table 21 Action Plans for Research, Development and Monitoring No. Action Details Relevant implementing bodies Period of implementation 18 To regularly monitor POPs levels in environmental media, human breast milk and biota. To select representative points to monitor the changing trends of POPs concentration in ambient air, soil and water bodies, and gradually carry out periodic monitoring. To launch the “Study of POPs content in Macao human breast milk” and follow up with the POPs content in mothers’ breast milk in Macao. Civil and Municipal Affairs Bureau, Health Bureau, Environmental Protection Bureau and other relevant agencies 2016-2025 19 To periodically monitor major pollution sources and surroundings of contaminated sites. To progressively conduct investigation and identify contamination levels of sites; including the temporary storage site of fly ash, waste incineration plants, wastewater treatment facilities, and their surrounding area. To organize and carry out periodic monitoring for POPs content in contaminated sites and their surrounding soil, surface water, leachate and groundwater. Environmental Protection Bureau and other relevant agencies 2016-2025 20 To strengthen scientific research on POPs. To carry out relevant supporting studies, so as to align with the latest trend of the “Convention” and also the technological development related to POPs research and elimination. Environmental Protection Bureau and other relevant agencies 2016-2025 3.3.20 Activity: Technical and Financial Assistance Not applicable. 3.4 Development and Capacity-building Proposals and Priorities To achieve the above mentioned objectives of the implementation plan, the following work tasks will be of a prior focus: Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 49  To clearly define the organizational framework for the implementation of the “Convention”, and to strengthen the implementation capacity of the Macao SAR on its implementation.  To sequentially propose relevant laws, regulations or plans, thus improving the management system for POPs or related goods.  To strengthen technical forces and personnel training on research, development and monitoring related to POPs.  To promote the continuous adoption of BAT/BAP for unintentional release sources in Macao.  To carry out publicity and education tasks, thus strengthening the POPs awareness of relevant groups. 3.5 Timetable for Implementation Strategy and Relevant Implementing Bodies The implementation timetable for activities, action plans and strategies mentioned in Section 3.3 and the relevant implementing bodies are as below: Table 22 Timetable for Implementation Strategy No. Action Relevant implementing bodies Suggested action period 2016-2020 2021-2025 1 To continuously promote the development or revision of laws and regulations related to POPs Macao Customs Service, Legal Affairs Bureau, Civil and Municipal Affairs Bureau, Macao Economic Services, Statistics and Census Service, Environmental Protection Bureau and other relevant agencies 2 To strengthen the management for reduction and control for the unintentional release of POPs. Environmental Protection Bureau and other relevant agencies 3 To gradually implement administrative supervision on the import of POPs pesticides and the food containing related substances Macao Customs Service, Civil and Municipal Affairs Bureau, Health Bureau, Environmental Protection Bureau and other relevant agencies 4 To gradually supplement POPs relevant content while study and formulate the hazardous waste list or inventory of Macao. Environmental Protection Bureau and other relevant agencies 5 To investigate the Macao Customs Service, Macao Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 50 No. Action Relevant implementing bodies Suggested action period 2016-2020 2021-2025 production and use of the new controlled POPs, and their produce industries Economic Services, Environmental Protection Bureau and other relevant agencies 6 To analyze relevant needs for exemptions Environmental Protection Bureau and other relevant agencies 7 To establish the dynamic emission inventories for Dioxin and PCBs. Environmental Protection Bureau and other relevant agencies 8 To strengthen the control of unintentional emissions from incineration facilities Environmental Protection Bureau and other relevant agencies 9 To study on the improvement of policy mechanism for reduction and control of unintentionally produced POPs Macao Economic Services, Environmental Protection Bureau and other relevant agencies 10 To improve the management system and managerial capacity for the environmentally sound management of waste containing POPs Environmental Protection Bureau and other relevant agencies 11 To establish or increase the handling capacity for the environmentally sound treatment of waste containing POPs Environmental Protection Bureau and other relevant agencies 12 To improve the dynamic database system for POPs stockpiles and waste containing POPs Macao Customs Service, Civil and Municipal Affairs Bureau, Macao Economic Services, Statistics and Census Service, Health Bureau, Environmental Protection Bureau and other relevant agencies 13 To identify and manage POPs contaminated sites in an environmentally sound manner Environmental Protection Bureau and other relevant agencies 14 To periodically exchange and cooperate for the implementation of the “Convention” Relevant agencies involved in the implementation of the “Convention” 15 To enhance public awareness, information and education Legal Affairs Bureau, Health Bureau, Environmental Protection Bureau and other relevant agencies 16 To conduct effectiveness evaluation on the Relevant agencies involved in the implementation of the “Convention” To conduct effectiveness evaluation every 4 years according to requirements listed Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 51 No. Action Relevant implementing bodies Suggested action period 2016-2020 2021-2025 implementation of the “Convention” in the “Convention”. 17 To submit reports on the implementation of the “Convention” Relevant agencies involved in the implementation of the “Convention” To submit reports on the implementation of the “Convention” according to the implementation requirements by the P.R.C. 18 To regularly monitor POPs levels in environmental media, human breast milk and biota Civil and Municipal Affairs Bureau, Health Bureau, Environmental Protection Bureau and other relevant agencies 19 To periodically monitor major pollution sources and surroundings of contaminated sites Environmental Protection Bureau and other relevant agencies 20 To strengthen scientific research on POPs Environmental Protection Bureau and other relevant agencies Note: ▆▆▆ indicates the suggested action period. 3.6 Implementation Status of the Macao SAR Implementation Plan The Macao SAR Government, according to “Implementation Plan of the Macao Special Administrative Region for the Stockholm Convention on Persistent Organic Pollutants”, has promoted relevant works and completed action plans as required for the early-phase implementation of the “Convention” between 2006 and 2014. The completion progress of various works is evaluated as below. Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 52 Table 23 Completion Progress of Action Plans for the Early-phase Implementation of the “Convention” No. Item Sub-item Content Completion progress Action plans of the first phase 1 To develop relevant mechanisms to implement the “Convention” and identify implementation bodies Relevant agencies of the Macao SAR Government continuously follow up the tasks in the “Convention”, maintain close collaboration through relevant communication mechanisms, hold periodic meetings, and implement action plans according to their functions, so as to fulfill the provisions in the “Convention” and our national requirements. Ongoing 2 To develop laws to forbid or control the import, export and transfer of chemicals listed in the Annex A and Annex B of the “Convention” The Macao SAR Government revises the “Foreign Trade Law” on an ongoing basis and has also assigned individual codes for listed POPs in the “Nomenclature for the External Trade of Macao / Harmonized System”, which makes it convenient for the competent bodies to control and collect data on the import and export of such goods. Ongoing 3 To gradually carry out systematic surveys and evaluation of POPs in Macao To conduct surveys and evaluation of the basic situation of PCBs in Macao To conduct investigations to enterprises and industrial premises in Macao, identify and indicate equipment containing PCBs, especially the following: equipment in use with the capacity larger than 5L and containing over 10% of PCBs, capacity larger than 5L and containing over 0.05% of PCBs, capacity larger than 0.05L and containing over 0.005% of PCBs, and other equipment in use containing over 0.005% of PCBs. To conduct systematic investigation and monitoring for PCBs concentration in the environment, collect information of concentrations and distribution in water body, ambient air, sediment, soil and biota in Macao. Completed relevant content in 2010 4 To conduct surveys and evaluation of basic information on unintentional release of POPs in Macao To conduct investigation to emission sources, prepare inventories for emission sources and estimated emissions. To conduct systematic research studies and monitoring plans for POPs unintentionally released in the environment, collect information of POPs concentrations and distribution in water bodies, ambient air, sediment, soil and biota. Between 2000 and 2012, 2 periods of environmental monitoring were completed 5 To conduct surveys and evaluation of basic information on POPs (used as pesticides) in Annex A of the “Convention” in Macao To conduct surveys to related organizations, factories, importers and pest control companies, so as to obtain quantity data on production, use, stockpiles of POPs pesticides, and goods or waste containing such POPs. To conduct research study and monitoring plan, and systematically collect information of POPs pesticides concentrations and distribution in water body, ambient air, sediment, soil and biota. Relevant content was completed in 2010 6 To conduct surveys To conduct surveys to related organizations, factories, importers and pest control companies, Relevant Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 53 and evaluation of basic information on DDT in Macao so as to obtain quantity data on production, use, stockpiles of DDT, and goods or waste containing DDT. To conduct research studies and monitoring plans, and systematically collect information of DDT concentrations and distribution in water bodies, ambient air, sediment, soil and biota. content was completed in 2010 7 To conduct surveys and evaluation of sites contaminated by POPs To conduct further investigation and risk assessment on POPs contaminated sites based on POPs status and assessment of information from previously completed studies. Ongoing 8 To control the emission of new sources of unintentional release of POPs To adopt more advanced equipment for the proposed expansion of the Macao Refuse Incineration Plant and the Macao Special and Hazardous Waste Treatment Plant, so as to ensure that the emission concentration of Dioxin is lower than the design standard 0.1 ng-TEQ/Nm. Implementing 9 To gradually establish a data collection mechanism and database on POPs status in Macao To establish a data collection mechanism and database to consolidate POPs information from all relevant departments; to consolidate research information; and to collect other POPs relevant information. Ongoing 10 To conduct initial campaigns in publicity, awareness and education on POPs To cope with the national activities on environmental publicity and education, so as to strengthen residents’ knowledge on POPs. The book “Environmental Treaties and Macao” was also published to serve this purpose. Completed in 2007 Action plans of the second phase 11 To develop specific action plans to eliminate and control PCBs, the unintentional production and release of POPs, POPs used as pesticides in Annex A of the “Convention” and DDT Based on the results of POPs investigation and assessment in the first phase as well as the actual circumstances in Macao, to develop regulations, rules and measures to eliminate and control the intentional production and use of PCBs; to develop regulations, rules and measures to eliminate the intentional production and use of POPs pesticides in Annex A of the “Convention”; to develop regulations, rules and measures to eliminate and control the intentional production and use of DDT; to develop regulations, rules and measures to reduce and eliminate the unintentional production and emission of POPs in Annex C of the “Convention”; to develop regulations, rules and measures to reduce and eliminate the stockpiles and waste of the original 12 POPs in the original “Convention”. To further develop specifications and measures for the management and remediation of contaminated sites based on the results of POPs contaminated sites investigation and assessment in the first phase. Ongoing 12 Strategy and action plans for continuous publicity, public awareness and education Building on the publicity and education plans stated in the first phase, relevant promotional activities and trainings to personnel in agencies responsible for the implementation of the “Convention” have been held, so as to strengthen knowledge awareness on the “Convention” as well as our national implementation plan. Ongoing Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 54 13 To carry out action plans for relevant studies, development and monitoring Building on the research and study plans in the first phase, to gradually start other studies, development and monitoring projects subject to the scientific and technical capacity in Macao, including monitoring of POPs sources and environmental emissions; their existence in the environment, concentration and development trends; environmental monitoring and impact assessment, etc. Ongoing 14 To submit reports and the mechanism to evaluate the effectiveness of the implementation of the “Convention” The Macao SAR Government has submitted reports on the implementation of the “Convention” in 2010 and 2014, and submitted a report on the effectiveness evaluation in 2014 according to the national requirements of implementation. In 2010 and 2014, reports on the implementation of the “Convention” were submitted; in 2014, the report of the effectiveness evaluation was submitted. Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 55 3.7 Resource Requirements To implement the various activities, action plans and strategies in the implementation plan (2016-2025), a capital investment of around 477.5 million MOP is required by the preliminary estimation of the Macao SAR Government. As there is a possibility for the “Convention” to control more POPs in the future, the budget may be revised or updated. Table 24 Initial Estimation for Capital Investment on the Implementation of the “Convention” 20 No. Action Estimated costs input (ten thousand MOP) 1 To continuously promote the development or revision of laws and regulations related to POPs 300 2 To strengthen the management for reduction and control for the unintentional release of POPs. 300 3 To gradually implement administrative supervision on the import of POPs pesticides and the food containing related substances 300 4 To gradually supplement POPs relevant content while study and formulate the hazardous waste list or inventory of Macao. 100 5 To investigate the production and use of the new controlled POPs, and their produce industries 600 6 To analyze relevant needs for exemptions 100 7 To establish the dynamic emission inventories for Dioxin and PCBs. 100 8 To strengthen the control of unintentional emissions from incineration facilities 40,100 9 To study on the improvement of policy mechanism for reduction and control of unintentionally produced POPs 300 10 To improve the management system and managerial capacity for the environmentally sound management of waste containing POPs 300 11 To establish or increase the handling capacity for the environmentally sound treatment of waste containing POPs 1,000 12 To improve the dynamic database system for POPs stockpiles and waste containing POPs 100 20 Not aligned with the previous implementation plan in 2007. Revised Implementation Plan of the Macao Special Administrative Region of the People’s Republic of China for the Stockholm Convention on Persistent Organic Pollutants 27 th March of 2018 56 No. Action Estimated costs input (ten thousand MOP) 13 To identify and manage POPs contaminated sites in an environmentally sound manner 150 14 To periodically exchange and cooperate for the implementation of the “Convention” － 15 To enhance public awareness, information and education 150 16 To conduct effectiveness evaluation on the implementation of the “Convention” 100 17 To submit reports on the implementation of the “Convention” 100 18 To regularly monitor POPs levels in environmental media, human breast milk and biota 1,500 19 To periodically monitor major pollution sources and surroundings of contaminated sites 1,500 20 To strengthen scientific research on POPs 650 Estimation of total invested capital 47,750